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Technical Data Sheet Page 1 of 2 Version: 2/28. Feb 2014 Revised: 12-16-2014 Printed on: 12-16-2014 BioAdimide® 100 PL-ADDTIVES Function BioAdimide® 100 is used to extend service life of bio-based polyesters. BioAdimide® 100 is especially suitable for bio-based polyesters. Product description Chemical composition: Physical form: Color: Density (20 °C): Melting range: Viscosity (50 °C): Solubility: Carbodiimide content Aromatic carbodiimide crystallized melt pale yellow approx. 0,97 g/cm³ 43 - 50 °C (109 - 122°F) approx. 20,0 +/- 4 mPa.s soluble in organic solvent, e.g. ethylacetate, acetone, ethanol, tetrahydrofuran, toluene, petrol; insoluble in water min. 9,8 % Use Bioadimide® 100 is an effective additive to prevent polymer degradation due to an exposure to humidity and acids. BioAdimide® 100 helps maintain the molar mass and, thus, mechanical properties as well as melt strength of your bio-based polyester in spite of detrimental processing steps. Bioadimide® 100 stabilizes bio-based polyesters and blends thereof. The chemical composition of BioAdimide® 100 enables stabilization of bio-based polyesters with processing temperatures below 200°C (392°F). Dosing: We recommend a dosage of 0.5 pbw to 2.0 pbw. However, the right dosage of BioAdimide® 100 depends on the content of acid end groups, moisture content of the bio-based polyester, processing and drying conditions, and the derived protective effect. To determine the required dosage level according to your needs, prior tests should always be carried out. For a dosage of more than 2.0 pbw a plasticizer effect may be observed. BioAdimide® 100 is added as molten liquid. We recommend to melt BioAdimide 100 at 60 - 80°C (140 - 176 °F) according to the handling information of the material safety data sheet. Equipment: BioAdimide® 100 can be incorporated with standard equipment suitable for processing polyesters and polyamides which allow for a proper additive dispersion. It is advisable to extrude with a twin screw extruder providing a L/D ratio > 38:1. BioAdimide® 100 may be fed separately or as a dry-blend of the bio-based polyester at a pressure-less feeding zone. A heated liquid feeder is recommended to prevent re-crystallization of BioAdimide 100 within the dosing equipment. Although the stabilizing effect is present, BioAdimide® 100 is not recommended for processing at temperature above 200°C (392°F). At processing temperature traces of volatile matters can escape which may temporarily

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  • Technical Data Sheet

    Page

    1 of 2

    Version:

    2/28. Feb 2014

    Revised:

    12-16-2014

    Printed on:

    12-16-2014

    BioAdimide 100

    PL-ADDTIVES

    Function BioAdimide 100 is used to extend service life of bio-based polyesters. BioAdimide 100 is especially suitable for bio-based polyesters.

    Product description

    Chemical composition: Physical form: Color: Density (20 C): Melting range: Viscosity (50 C): Solubility: Carbodiimide content

    Aromatic carbodiimide crystallized melt pale yellow approx. 0,97 g/cm 43 - 50 C (109 - 122F) approx. 20,0 +/- 4 mPa.s soluble in organic solvent, e.g. ethylacetate, acetone, ethanol, tetrahydrofuran, toluene, petrol; insoluble in water min. 9,8 %

    Use Bioadimide 100 is an effective additive to prevent polymer degradation due to an exposure to humidity and acids. BioAdimide 100 helps maintain the molar mass and, thus, mechanical properties as well as melt strength of your bio-based polyester in spite of detrimental processing steps. Bioadimide 100 stabilizes bio-based polyesters and blends thereof. The chemical composition of BioAdimide 100 enables stabilization of bio-based polyesters with processing temperatures below 200C (392F). Dosing: We recommend a dosage of 0.5 pbw to 2.0 pbw. However, the right dosage of BioAdimide 100 depends on the content of acid end groups, moisture content of the bio-based polyester, processing and drying conditions, and the derived protective effect. To determine the required dosage level according to your needs, prior tests should always be carried out. For a dosage of more than 2.0 pbw a plasticizer effect may be observed. BioAdimide 100 is added as molten liquid. We recommend to melt BioAdimide 100 at 60 - 80C (140 - 176 F) according to the handling information of the material safety data sheet. Equipment: BioAdimide 100 can be incorporated with standard equipment suitable for processing polyesters and polyamides which allow for a proper additive dispersion. It is advisable to extrude with a twin screw extruder providing a L/D ratio > 38:1. BioAdimide 100 may be fed separately or as a dry-blend of the bio-based polyester at a pressure-less feeding zone. A heated liquid feeder is recommended to prevent re-crystallization of BioAdimide 100 within the dosing equipment. Although the stabilizing effect is present, BioAdimide 100 is not recommended for processing at temperature above 200C (392F). At processing temperature traces of volatile matters can escape which may temporarily

  • Page

    2 of 2

    Version:

    2/28. Feb 2014

    Revised:

    12-16-2014

    Printed on:

    12-16-2014

    cause irritation of skin, eyes, and respiratory passages. In any case it is necessary to provide sufficient local ventilation at all places where bio-polyesters are exposed to temperatures exceeding 100C (212F). In particular it is necessary to avoid direct contact with liberated vapors.

    Packing Metal cans, content 10 kg (22 lbs)

    Storage stability BioAdimide 100 can be kept for at least 1 year under cool and dry conditions.

    Handling Consult material safety data sheet (MSDS) for additional handling information on BioAdimide 100.

    Our technical advice - whether verbal, in writing or by way of trials - is given in good faith but without warranty, and this also applies where proprietary rights of third parties are involved. It does not release you from the obligation to test the products supplied by us as to their suitability for the intended processes and uses. The application, use and processing of the products are beyond our control and, therefore, entirely your own responsibility. Should, in spite of this, liability be established for any damage, it will be limited to the value of the goods delivered by us and used by you. We will, of course, provide products of consistent quality within the scope of our General Conditions of Sale and Delivery.

    Rhein Chemie Rheinau GmbH Duesseldorfer Strasse 23-27 68219 Mannheim, Germany Tel.: +49-621-8907-0 Fax: +49-621-8907-675 E-Mail: [email protected] www.rheinchemie.com

    Rhein Chemie Corporation 145 Parker Court Chardon, OH 44024, USA Telefon: +1 440-285-3547 Fax: +1 440-285-2462 [email protected]

    Rhein Chemie Japan Ltd. Marunouchi Kitaguchi, Bldg. 23 F 1-6-5 Marunouchi, Chiyodo-ku Tokyo 100-0005, Japan Telefon: +81-03-5293-8041 Fax: +81-03-5219-9779 [email protected]

    Lanxess Chemical (China) Co.Ltd. Business Unit Rhein Chemie 16F, Park Place NO. 1601, Nanjing Road (West) Shanghai 200040, VR China Telefon: +86-21-6109 8308 Fax: +86-21-6109-8309 [email protected]