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  • 7/26/2019 Upravljanje opasnim otpadom

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    , ,

    ,2010

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    GEOGRAPHIC INSTITUTE JOVAN CVIJISERBIAN ACADEMY OF SCIENCES AND ARTS

    SPECIAL ISSUES

    80

    Milena Pani

    HAZARDOUS WASTE MANAGEMENT

    systemplanning, organization, functioning

    BELGRADE

    2010.

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    80

    , ,

    2010.

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    / PUBLISHER 11000 , 9, Geographical institute Jovan Cviji SASA11000 Belgrade, Djure Jaksica 9, REPUBLIC OF SERBIATelephone / fax: +381 11 2637597, E-mail: [email protected]

    / ACTING PUBLISHER /Milan Radovanovi

    25.05.2009. /Accepted at the meeting of the Scientic board of the Institute on May 25th, 2009

    / EDITOR () / eljko Bjeljac (Belgrade)

    / REVIEWERS. / Prof. dr Marina Ili. / Prof. dr Milutin Ljeevi. / Prof. dr Dejan Filipovi

    / LANGUAGE EDITING /

    / TECHNICAL EDITOR / Milena Pani

    / COVER DESIGN / Dejan Atanasovski

    E

    PRINTING OF THIS PUBLICATION WAS SUPPORTED BYMinistry of Science and tehnological development of the Republic of Serbia

    / CIRCULATION300

    / PRINTED BY , / Slubeni glasnik, Belgrade

    WEB / WEB PRESENTATIONhttp:/www.gi.sanu.ac.rs

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    :

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    -...............................................................................41.............................................................................................43

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    .......................60

    .......................................61....................63

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    ..............................77

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    ..................................................................................88

    ...........................................................................................................89

    .......................................90

    , ............................................93

    ........................................115

    ................................104

    ...............................................................................................97

    .....................100

    ....................122

    .........................................................................................107.........................110

    .....................................111

    ......................................................113

    .............................................................114

    .......................115

    .............122

    ............124

    ..............128

    ...........................................129....................................131

    .........................134

    ......................................................136

    .................................138

    ........................................................................138

    ....................142

    .................................144, -............144

    -......145

    -

    .................................................................149

    ....................................................................................................150SUMMARY.......................................................................................................153

    ................................................................................................159

  • 7/26/2019 Upravljanje opasnim otpadom

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    20.

    ,

    . ,

    .

    , ,

    , , .

    ,

    .

    ,

    .

    ,

    , .

    . ,

    ,

    .

    , , . ,

    .

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    9/166

  • 7/26/2019 Upravljanje opasnim otpadom

    10/166

    ,

    ,

    ,

    .

    ,

    ,

    ,

    ,

    . , , ,

    , ,

    , ,

    .

    ,

    . , cradle-

    to-grave, ,

    , , , ,

    .

    ,

    , ,

    ,

    .

    , , ,

    ,

    ,

    . , ,

    . ,

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    11/166

    ,

    ,

    ,

    ,

    .

    , cradle-to-grave. ,

    ,

    , ,

    .

    , ,

    ,

    ,

    .

    ,

    , , ,

    ,

    ,

    . ,

    ,

    , ,

    .

    , ,

    , ,

    ,

    , , , , , (La Grega et al,

    2001). ,

    (,

    , 2000):

    -

    : , , ,

    ;

    -

    : , , , ,

    , , ;

    -

    : , .

  • 7/26/2019 Upravljanje opasnim otpadom

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    13

    ,

    ,

    . ,

    , , , , , , , .

    , ,

    , ,

    , ,

    , ,

    .

    (Household Hazardous Waste)

    , , (, , ,

    ),

    (http://www.epa.gov/garbage/hhw.htm). ,

    , , , ,

    , , , (La Grega et al, 2001). ,

    ,

    ( 1),

    (Dorian, 1988). -

    ,

    ,

    ,

    (La

    Grega et al, 2001).

    ,

    , ,

    . EPA1,

    1000 kg

    , (La Grega et al,

    2001).

    ( 1.): ,

    ,

    ( -,

    1(US Environmnetal Protection Agency)

  • 7/26/2019 Upravljanje opasnim otpadom

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    14

    , 85%

    ), ,

    (, , 2000; La Grega et al, 2001).

    1.

    Table 1. Prticipation of hazardous waste from household and commercial sector

    40,0%

    30,1%

    16,4%

    , 7,5%

    , 2,5%

    3,5%

    Izvor:,, 2000

    , (, ,

    )

    .

    ,

    .

    , , ,

    , ,

    , . ,

    ,

    20. EPA, , 2

    (Pichtel, 2005).

    ,

    ,

    - ,

    , ,

    .

    2Medical Waste Tracking Act 1988. 1991. ,

    (Pichtel, 2005).

  • 7/26/2019 Upravljanje opasnim otpadom

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    15

    ,

    , ,

    .

    ,

    , -.

    ,

    .

    20. -

    ,

    -. ,

    ,

    , .

    91/689/EC ,

    ( I);

    (II) (III).

    (2).

    , 91/689/EC

    , -

    .

  • 7/26/2019 Upravljanje opasnim otpadom

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    16

    2.

    Table 2. Properties of wastes which render them hazardous

    21-55C

    21C;

    ,

    ,

    ,

    :, European Waste Katalogue (2002)

    -,

    .

    ,

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    17

    ,

    , , .

    , ,

    EPA, (La

    Grega et al., 2001). ,

    , Solid Waste Disposal Act 1965.

    , . Resource

    Conservaton and Recovery Act (RCRA)3,

    : ,

    , , : 1) ,

    , ; 2)

    ,

    , ,

    .

    , RCRA-,

    : 1) ; 2)

    ; 3) ; 4)

    4.

    ,

    .

    3RCRA ,

    EPA . , .

    : .

    , (Watts, 1998:13-14).

    4C, , (1)

    , , ; (2); (3)

    , , . .

    (4)

    , (EPA,

    2001).

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    18

    (http://www.epa.gov/epaoswer/hotline/training/defsw.pdf). ,

    , :

    , ,

    (Watts, 1998). ,

    (Blackman, 2001):

    -

    ;

    - ;

    -

    ;

    -

    , .

    .

    .

    ,

    (Watts, 1998):

    (3)

    ,

    (Watts,

    1998). EPA

    (Blackman,

    2001):

    -

    ,

    ;

    -

    .

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    19

    3. ()

    Table 3. USHazardous waste characteristics

    - , , 24% , 60C;

    -

    , , ;

    - ;

    - ;

    - pH 2.0 12.5;

    - 6.36 mm/;

    - ;- ;

    - ;

    - ,

    ;

    - , pH 2 - 12.5,;

    -

    ;-

    ;

    - , ;

    - ,

    Tohicity Characheristic Leaching Procedure (TCLP),

    ,.

    31 8 .

    , . ,

    .

    : Watts, 1998

    ,

    ,

    .

    ,

    ,

    ,

    .

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    20

    ,

    . ,

    . 1994.

    5

    6,

    -

    .

    ,

    (2002) 20

    .

    . ,

    91/689/C

    (*).

    :

    1.

    , , ,

    ;

    2.

    , , ,

    , ;

    3.

    , , ;

    4. , ;

    5.

    ,

    ;

    6. ;

    7. ;

    8.

    , ,

    , ;

    9.

    ;10.

    ;

    11.

    ;

    12.

    ;

    13.;

    5European Waste Catalogue (94/3/EC 75/442/EEC )6

    Hazardous Waste List (94/904/EC 91/689/EEC )

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    21

    14.

    , ;

    15.

    , , ;

    16.;

    17.

    ( );

    18./

    (

    ,

    );

    19.

    , off-site

    ;20.

    (,

    ),

    .

    ,

    , -. EPA

    ,

    , 3

    (http://www.epa.gov/epaoswer/osw/hazwaste.htm):

    1. ;

    2.

    ;

    3.

    ;

    , .

    .

    F. EPA ,

    , , ,

    ,

    (La Grega et al, 2001).

    , (Blackman, 2001).

    . :

  • 7/26/2019 Upravljanje opasnim otpadom

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    22

    , , ,

    , , ,

    , ,

    , , , , , , ,

    (La Grega et al, 2001).

    , , , ,

    (,

    , 2000).

    () ,

    ( U),

    (La Grega et al,

    2001). ,

    , , (DDT) (Blackman, 2001).

    , EPA ,

    , ,

    (, , 2000).

    ,

    , e

    , .

    , . ,

    (),

    ()

    .

    , ( )

  • 7/26/2019 Upravljanje opasnim otpadom

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    23

    ,

    ,

    . (, ,

    ) ,

    ,

    . ,

    creadle-to-grave ,

    , .

    , -

    RCRA-, (Blackman, 2001):

    1.

    (LQG) 1000 kg

    1 kg 7;

    2.

    (SQG) 1000 kg,

    100 kg , 1 kg

    ;

    3.

    () (CESQG)

    100 kg 1 kg

    ;

    ,

    RCRA Hazardous Waste Reporting System,

    .

    , , Toxic Release Inventory

    600

    (McGlinn, 2000). ,

    ,

    (Blackman, 2001).

    , -,

    ,

    (),

    7 EPA

    , . F P.

  • 7/26/2019 Upravljanje opasnim otpadom

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    24

    , ().

    . ,

    , -.

    --

    ,

    , ,

    . ,

    , ,

    .

    ,

    , -.

    , 30-80%

    ,

    25% 68-76% (, 2001).

    , ,

    ,

    ,

    ,

    .,

    ,

    (, 1999).

    , - 36

    (, 1999).

    (, , , , , , , ,

    , , , , , , ,

    , ),

    (25%),

    (13%),

    (13%),

    (10%), (8%),

    . ,1%

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    25

    , ,

    (, 2001).

    4. e --

    Table 4. The total amount of hazardous waste in EU and US

    1992 423 000

    1994 513 000

    1995 577 000

    1996 606 000

    1990 66 000

    1992 99 000

    .

    1995 248 000

    1996 230 000

    1990 3 246 000

    1991 3 387 000

    1995 2 708 000

    1996 3 401 000

    1990 1 040 000

    1992 1 513 000

    1993 1 520 000

    1994 890 000

    1995 868 000

    1996 959 000

    1997 1 271 000

    1994 3 394 353

    1990 2 936 000

    1992 2 452 000

    1993 2 077 000

    1991 305 000 000

    1993 258 000 000

    1995 214 000 000

    2003 30 000 000

    RCRA

    : , 1999; , 2002, McGlinn, 2000

  • 7/26/2019 Upravljanje opasnim otpadom

    25/166

    26

    e

    ,

    ( 4).

    20. , , /

    (, 1999).

    -

    ,

    .

    , 4,

    , .

    ,

    ,

    (McGlinn, 2000).

    ,

    , ,

    .

    ,

    ,

    , .

    , ,

    , (, ,

    2000). , on-site, ,

    off-site

    cradle-to-grave (La Grega et al., 2001).

    ,

    ,

    , .

    , , 90 ,

  • 7/26/2019 Upravljanje opasnim otpadom

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    27

    ,

    (Watts, 1998; Pichtel, 2005):

    - (, 8

    ), , ( hazardous waste);

    -

    .

    ;

    -

    .

    ,

    .

    180 ( 270 ),

    6000 kg ,

    (Pichtel, 2005).

    ,

    .

    , , , ,

    ,

    .

    ,

    ,

    . ,

    . , -

    ,

    (Liu, 2000).

    8EPA , , , ,

    . ,

    , , .

  • 7/26/2019 Upravljanje opasnim otpadom

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    28

    ,

    , .

    ,

    , ,

    (McGlinn, 2000). ,

    ,

    .

    ,

    , , (

    ).

    ,

    .

    : , ,

    , ,

    ,

    (, , 2000).

    1997. ,

    98,6% ,

    80% . 1,4%

    , 20%

    (Blackman, 2001).

    . ,

    ,

    , ,

    ,

    .

    ,

    , , ,

    , .

  • 7/26/2019 Upravljanje opasnim otpadom

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    29

    RCRA- (),

    (Blackman, 2001):

    -

    , , ;-

    ,

    ;

    -

    ,

    .

    , ,

    -,

    (Blackman, 2001):

    ,

    Uniform Hazardous Waste Manifest,

    .

    EPA,

    ,

    (Blackman, 2001).

    Uniform Hazardous Waste

    Manifest,

    ,

    .

    ,

    , , ;

    ;

    ;

    .

    ,

    , (Blackman,

    2001). ,

    (Pichtel, 2005). ,

    ,

    ,

    .

    , EPA

  • 7/26/2019 Upravljanje opasnim otpadom

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    30

    .

    ,

    , , , , ,

    .

    ,

    ,

    ,

    , .

    ,

    .,

    -, ,

    ,

    ,

    (, ,

    2000). ,

    ,

    10 ,

    (Blackman, 2001).

    ,

    , , ,

    .

    ,

    . ,

    (Pichtel, 2005):

    , , ;

    ,

    (23 );

    , ,

    ;

    (),

    ;

  • 7/26/2019 Upravljanje opasnim otpadom

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    31

    ,

    ;

    , EPA;

    , ; , Uniform Hazardous

    Waste Manifest

    .

    ,

    ,

    .

    . ,

    , , 1957.

    ADR,

    (Jovanovi, 2004).

    ,

    , 9 (5).5.

    Table 5. The classes of dangerous goods

    1

    1

    1 ,

    2 ,

    3

    4.1

    4.2

    4.3

    5.1

    5.2

    6.1

    6.2

    7

    8

    9 : Jovanovi, 2004

  • 7/26/2019 Upravljanje opasnim otpadom

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    32

    1: a (:ADR)Fig. 1. Table advisories for transport vehicles marking (ADR)

    ,

    . ,

    (, ,

    ) ( 1).

    (2 3 )

    (6), (4 )

    .

    6.

    Table 6. Basic and addition danger on table advisories

    2

    3

    4

    5

    6 8

    0

    1

    2

    3

    5

    6

    8

    9

    : Jovanovi, 2004

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    33

    ,

    , X ,

    ,

    (Jovanovi, 2004).

    ,

    ,

    ,

    .

    ,

    , ,

    ,

    .

    .

    ,

    .

    Assante-Duah Nagy (2001)

    :

    -

    ;

    - ,

    ;

    -

    ;-

    ;

    -

    ;

    -

    ;

    - ,

    ;

    -

    ,

    , ;

  • 7/26/2019 Upravljanje opasnim otpadom

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    34

    -

    ,

    ;

    - ,

    .

    ,

    OECD-9.

    ,

    OECD ,

    ,

    (, , 2000).

    , ,

    ,

    ,

    ( ,

    ,

    ),

    (Toovi i dr,

    1998). ,

    . ,

    (Mihajlov, Petkovi, 1998).

    , 1992.

    OECD-

    ,

    ,

    .

    (Krueger, 1999).

    OECD-

    .

    9

    (Organisation for Economic Co-operation andDevelopment)

  • 7/26/2019 Upravljanje opasnim otpadom

    34/166

    35

    , ,

    , 259/93/C10

    .

    OECD-,

    -

    ,

    .

    ,

    ,

    (Krueger, 1999).

    1995. -,

    , 1.665.500 , 85%

    -, 8% OECD-,

    , -, , , 6%

    .

    OECD- ,

    ,

    . , .

    16.000 1%

    , , ,

    (, 1999).

    ,

    .

    75% -,

    20% .

    , ,

    , , .

    ,

    , ,

    10

    Council Regulation 259/93/C on Supervision and control of shipments of waste within, intoand out of the European Community

  • 7/26/2019 Upravljanje opasnim otpadom

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    36

    .

    ,

    , ,

    .

    ,

    ,

    , ,

    (Blackman, 2001).

    ,

    , , (Adeleke, 2001).

    , (2),

    ,

    ,

    (Blackman, 2001; Soesilo, Wilson, 1995).

    ,

    ,

    .

    2.

    Fig 2. The waste hierarchy

  • 7/26/2019 Upravljanje opasnim otpadom

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    37

    , ,

    ,

    , , , .

    (La Grega et al, 2001):

    ,

    , (,, 2000).

    11,

    .

    ,

    ,

    (Pichtel,

    2005).

    ,

    ,

    ,

    cradle-to-grave. -

    RCRA-,

    , .

    , RCRA

    ,

    .

    , ,

    , .

    11Treatment, Storage and Disposal Facilities TSD Facilities

  • 7/26/2019 Upravljanje opasnim otpadom

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    38

    ,

    ,

    ,

    .

    , ,

    ,

    .

    , EPA

    , .

    ,

    , ,

    ,

    . ,

    ,

    , (),

    ,

    ,

    (Pichtel, 2005).

    ,

    ,

    .

    ,

    , ,

    .

    ,

    , ,

    .

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    38/166

    39

    . ,

    , ,

    , .

    ,

    , ,

    , ,

    .

    ,

    , .

    ,

    ,

    (, ,

    2006). ,

    ,

    .

    :

    ,

    ,

    , .

    , ,

    (EPA, 1997; Miloevi et al,

    2009).

    ,

    (Pichtel, 2005).

    ,

    (EPA, 1997).

  • 7/26/2019 Upravljanje opasnim otpadom

    39/166

    40

    ,

    ,

    , , .

    ,

    . ,

    (1)

    (2) ,

    .

    ,

    .

    ,

    ,

    .

    ,

    , ,

    .

    ,

    :

    ;

    ; ;

    ( ). ,

    .

    ,

    , ,

    ,

    , EPA

    ,

    61

    (Pichtel, 2005).

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    40/166

    41

    ,

    . ,

    , .

    , ,

    . ,

    .

    , ,

    , .

    ,

    , .

    ,

    .

    ,

    .

    -

    :

    , , , , ,

    , , .

    .

    20 ,

    ,

    , ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    41/166

    42

    ,

    :

    ;

    ; , (Theodore, Reynolds, 1987).

    .

    , .

    ,

    . , ,

    ,

    . ,

    .

    ,

    , ,

    .

    , , .

    (Jaki, Ili, 2000; La Grega et al, 2001).

    /

    ,

    .

    ,

    ,

    .

    ,

    , .

  • 7/26/2019 Upravljanje opasnim otpadom

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    43

    , .

    , . ,

    ,

    .

    ,

    , ,

    (),

    ()

    (Wiles, 1988; Jaki, Ili, 2000).

    , ,

    , ,

    (http://glossary.eea.europa.eu/EEAGlossary/C/

    Chemical_treatment_of_hazardous_waste).

    , ,

    (

    ), ()

    (Pichtel, 2005).

    , .

    , ,

    ,

    ,

    (, , 2000).

    ,

    (7), , :

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

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    44

    7.

    Table 7. Common chemical treatment processes for hazardous waste

    -

    ,

    -

    /

    - ,

    .

    .

    : Pichtel, 2005

    ,

    ,

    , pH

    .

    ,

    . pH

    2-12.5, , 6-8,

    (Pichtel, 2005; Blackman, 2001; , , 2000).

    ,

    ,

    . ,

    ,

    . , , ,

    .

    , ,

    ,

    .

    (Pichtel, 2005).

    ,

    , ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

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    45

    , .

    ,

    (Pichtel 2005). ,

    (8).

    8.

    Table 8.Commonly used oxidizing and reducing agents

    : Pichtel, 2005

    ,

    ,

    . ,

    , , pH

    . ,

    : , .

    , .

    (, , 2000).

    . , ex-situ, ,

    (Blackman,

    2001).

    ,

    ,

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    45/166

    46

    . ,

    , ,

    . 1900. -

    , , , ,

    (La Grega et al, 2001).

    , ,

    ,

    , , ,

    ,

    (Blackman, 2001).

    ,

    , , ,,

    (, ,

    2000). , EPA

    ,

    , ,

    ,

    , .

    (Jilani, 2004):

    ;

    ;

    .

    ,

    :

    , -, ,

    , pH, , ,

    .

    , ,

    .

    ,

    ,

    (Jilani, 2004). ,

    ,

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    46/166

    47

    (, ,

    2000).

    ( ) ,

    (, , , .), (PCB, DDT .).

    , ,

    4-15 3-6 .

    ,

    ,

    . , ,

    , (Blackman, 2001).

    , ,

    ,

    . ,

    , ,

    : ;

    ,

    ; .

    ,

    , .

    , ,

    , , (Pichtel,

    2005; Blackman, 2001)

    , ,

    ,

    .

    , , , ,

    (, , 2000).

    , , ,

    , ,

    (Pichtel, 2005).

    , , , (

  • 7/26/2019 Upravljanje opasnim otpadom

    47/166

    48

    ) (Blackman, 2001).

    (http://www.wau.boku.

    ac.at/fileadmin/_/H81/H813/IKS_Files/Lehre/Archiv/813359_0607/5_incinerati

    on_hazardous.pdf ): ;

    ;

    ( CO2,

    ,...)

    ().

    (Theodore, Reynolds, 1987). ()

    .

    ,

    ,

    , ,

    .

    ,

    .

    (http://www.epa.gov/epaoswer/hotline/training/incin.txt):

    ;

    ;

    .

    (, , 2000):

    ;

    ;

    ;

    ;

    ;

  • 7/26/2019 Upravljanje opasnim otpadom

    48/166

    49

    .

    ,

    , 90% .

    , ,

    .

    ,

    . , .

    ,

    ,

    .

    ,

    (, , 2000).

    , ,

    , ,

    ()

    ,

    . , ,

    ,

    , ,

    (Pichtel, 2005).

    ,

    (Theodore, Reynolds, 1987):

    ;

    , , ;

    ;

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    49/166

    50

    ,

    ,

    .

    , , (, , 2000).

    , ,

    , 648 C 1694 C,

    ,

    (Blackman, 2001).

    , ,

    ,

    . ,

    , , (, , 2000).

    , ,

    ,

    , ,

    .

    ,

    (La Grega et al., 2001).

    ,

    ,

    ,

    .

    ,

    , ,

    ,

    .

    , .

    ,

    .,

    ,

    : 25-30%

    ,

    (, , 2000).

    , .

  • 7/26/2019 Upravljanje opasnim otpadom

    50/166

    51

    :

    ,

    . ,

    425-760 C

    .

    99.9999% (Shah, Schulz, Daiga, 1988).

    ,

    ,

    (, , 2000):

    ; :

    1.

    ;

    2.

    (NaCl, FeCl2, Zn, Pb);

    3.

    , .

    ,

    ,

    , ,

    ,

    .

    ,

    , .

    , , ,

    ,

    .

    ,

    , -1997. ,

    1400 , 1999. , 1205 (Kiel, Zabel,

    2001).

    , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    51/166

    52

    .

    , Superfund12 ,

    -,

    (, ,

    , .

    , ,

    .

    , .

    ,

    ,

    : , , , ,

    ,

    ,

    .

    , ,

    ,

    ,

    (La Grega et al., 2001).

    ,

    (Watts, 1996).

    12 1980. , - Comprehensive Response,Compensation and Liability Act (CERCLA Superfund), .

    SuperfundEPA,

    . 25 , EPA ,

    ,

    , . ,

    , ,

    (http://www.epa.gov/superfund/25anniversary/index.htm).

  • 7/26/2019 Upravljanje opasnim otpadom

    52/166

    53

    ,

    . (La Grega et al, 2001):

    ,

    .

    :

    ; ,

    , ;

    ;;

    .

    ,

    .

    .

    ( )

    .

    ,

    ,

    ,

    .

    ,

    .

    , .

    ,

    ,

    .

    ,

    .

    , ,

    (La Grega et al., 2001; Watts, 1996):

  • 7/26/2019 Upravljanje opasnim otpadom

    53/166

    54

    ,

    ;

    ;

    ;

    , .

    ,

    .

    ,

    .

    ,

    , .

    ,

    (, , )

    (

    , ) (Watts, 1996).

    ,

    ,

    .

    (Wetzel, 1988).

  • 7/26/2019 Upravljanje opasnim otpadom

    54/166

    55

    , ,

    (, , 2000; Watts, 1996):

    in-situ ,

    , .

    , (Miloevii dr, 1998).

    : ,

    /, .

    ex-situ

    , ,

    .

    , ,

    (Miloevi i dr, 1998).

    : ,

    , ,

    , ,

    , ,

    /.

    ,

    ,

    , x-situ ,

    ,

    , ,

    . in-situ

    ,

    ,

    , (Watts, 1996).

    ,

    ,

    , ,

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    55/166

    56

    , . ,

    ,

    ,

    (Miloevi i dr,1998).

    ,

    (Kiel, Zabel, 2001).

    EPA

    .

    , ,

    cradle-to-grave,

    ( ) , ,

    ,

    . ,

    ,

    , ,

    .

    20%

    , ,

    (, , 2000).

    2001. , -

    69% .

    , ,

    . -, () (

    ) 16 ,

    1,4 (Pichtel,

    2005).

    ,

    :

    , ,

    . ,

  • 7/26/2019 Upravljanje opasnim otpadom

    56/166

    57

    .

    ,

    ,

    .

    ,

    .

    ,

    , . , ,

    , , ,

    .

    ,

    .

    , ,

    , ,

    .

    -, 1999/31/C ,

    , ,

    ,

    ,

    ,

    . ,

    .

    , ,

    ,

    .

    , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    57/166

    58

    ,

    .

    .

    ,

    ,

    . -

    1999/31/C

    ,

    ,

    , .

    , ,

    .

    :

    ,

    ;

    ;

    , ,

    ;

    .

    -, EPA

    . RCRA-

    ,

    .

    CFR-13 (Subpart N Landfills)

    , ,

    ,

    , ,

    13 Code od Federal Regulations (CFR) predstavlja kodifikaciju optih i dugoronih

    pravila, propisanih od strane nadlenih federalnih organa i agencija, a publikovanih u

    Federalnom registru. Sadri 50 odeljaka, koji obuhvataju irok obim pitanja koja

    zahtevaju regulaciju na federalnom nivou. Podaci se auriraju na godinjem nivou(http://www.gpoaccess.gov/cfr/index.html).

  • 7/26/2019 Upravljanje opasnim otpadom

    58/166

    59

    , ,

    ,

    , ,

    , .

    ,

    ,

    (Wright, Ross, Tagawa, 1988).

    ,

    ,

    , (Watts, 1998).

    , ,

    ,

    . ,

    ,

    ,

    ,

    (Pichtel, 2005).

    ,

    ,

    , .

    ,

    .

    25-

    24 (Wright, Ross, Tagawa, 1988).

    ,

    : , ,

    . , ,

    ,

    . EPA

    14,

    (, , ),

    .

    ,

    14Sensitive Environments and the Siting of Hazardous Waste Management Facilities

  • 7/26/2019 Upravljanje opasnim otpadom

    59/166

    60

    ,

    , .

    , e ,

    e

    ,

    .

    ,, ,

    ,

    .

    ,

    ,

    ,

    ,

    .

    50-80% (Wright,

    Ross, Tagawa, 1988).

    ,

    .

    ,

    :

    , ,

    ; ,

    ,

    .

    .

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    60/166

    61

    , : 1)

    , , ,

    ; 2)

    (Wright, Ross, Tagawa, 1988).

    ,

    , ,

    .

    ,

    . ,

    , (,

    , 2000):

    ;

    ;

    ;

    ;

    .

    ,

    (Watts, 1998).

    ,

    (

    ).

    ,

    .

    (), ,

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    61/166

    62

    ()

    (), (Pichtel, 2005).

    ,

    , ,

    ,

    (Pichtel, 2005).

    (La Grega et al, 2001).

    ,

    (, , 2000). ,

    ,

    ,

    .

    , ,

    ,

    (3).

    3.

    (: , , 2000)

    Fig. 3. Scematic of a hazardous waste landfill

    . ,

  • 7/26/2019 Upravljanje opasnim otpadom

    62/166

    63

    (),

    .

    ,

    , ( ).

    .

    ,

    ,

    .

    ,

    (Pichtel, 2005).

    ,

    20. RCRA-,

    .

    (Soesilo,

    Wilson, 1995). Land

    Disposal Restrictions Program(LDR) EPA, ,

    ,

    .

    ,

    ,

    . ,

    , ,

    .

    ,

    ,

    (Pichtel, 2005).

    (1999) :

  • 7/26/2019 Upravljanje opasnim otpadom

    63/166

    64

    1.

    .

    :

    -

    ,

    , ;

    -

    .

    2.

    ,

    ,

    , .

    .

    3.

    , ,

    . ,

    ,

    , ,

    .

    ,

    .

    , ,

    ,

    , .

    ,

    ,

    . ,

    ( 4), (, ,

    2000):

    , (30 cm)

    ,

    ,

    .

    ,

    , ;

  • 7/26/2019 Upravljanje opasnim otpadom

    64/166

    65

    (61 cm)

    3%.

    0,5

    mm;

    (30 cm),

    .

    ,

    3% ,

    ;

    ,

    30 cm;

    (61 cm)

    . , ,

    () 3%.

    ,

    (30 cm),

    61 cm .

    ,

    30-50 ,

    , ,

    .

    ,

    (La Grega et al, 2001).

    ,

    , .

    , ,

    ,

    . ,

    ,

    ,

    . ,

    , ,

    (La Grega et al, 2001).

  • 7/26/2019 Upravljanje opasnim otpadom

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    66

    4.

    (: , , 2000)

    Fig. 4. Closing phase of hazardous waste landfill

    ,

    , ,

    . ,

    ()

    ,

    .

    ,

    .

    , .

    ,

    (Pichtel, 2005).

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    66/166

    67

    (Blackman,

    2001).

    ,

    5 , . ,

    . 2001. , -

    473 I , 123 (26%)

    , 350 (73%) (EPA, 2001).

    . ,

    ( 50%

    ), (25%), (12%), (5%), -

    (1%) (Warner, 1988).

    ,

    . 1975. ,

    ,

    46 ,

    (Blackman, 2001).

    ,

    .

    (, , 2000):

    ,

    , ,

    ,

    , ,

    : ,

    , ,

    , ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    67/166

    68

    , ,

    .

    ,

    , ,

    ,

    ,

    .

    , ,

    ,

    ,

    .

    ,

    , ,

    (Watts, 1998).

    , ,

    ,

    , .

    .

    , ,

    , ,

    ,

    .

    ,

    .

    ,

    , ,

    .

    ,

    99% 10 ,

    , (Watts, 1998; LaGrega et al, 2001). ,

  • 7/26/2019 Upravljanje opasnim otpadom

    68/166

    69

    ,

    (

    ),

    (Watts, 1998; Hunt, Schecter, 1988).

    : , , ,

    ,

    (La Grega et al, 2001).

    ,

    (Hunt, Schecter, 1988). ,

    ,

    , (Watts, 1998).

    ,

    ,

    (La Grega et al, 2001). -,

    ,

    ,

    .

    .

    ,

    . , ,

    ,

    (Blackman, 2001; Watts, 1998).

    , -

    IPPC (2008/1/C)15, BAT (Best Available

    Techniques) BREF (Best Available Techniques REFerence Document).

    IPPC

    ,

    ( ,

    , , ,

    ),

    15Integrated Pollution Prevention and Control

  • 7/26/2019 Upravljanje opasnim otpadom

    69/166

    70

    - .

    BAT, :

    ()

    ,

    -, je

    -, BREF-16

    (http://www.europeansealing.com/publications/BREF_note.htm).

    BREF-,

    -

    IPPC-. ,

    , ,

    (http://eippcb.jrc.ec.europa.eu/).

    16 BREF-,

    , , IPPC-, IPPC-(European IPPC Bureau) .

  • 7/26/2019 Upravljanje opasnim otpadom

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    ,

    . ,

    20. , ,

    ,

    .

    -,

    , .

    , . ,

    , ,

    ,

    .

    , , , ,

    ,

    ,

    -. -

    , ,

    , ,

    ,

    -

    (, 2002; , 2006). ,

    ,

    ,

    , ,

    ,

    .

    -

    , , , ,

    , .

  • 7/26/2019 Upravljanje opasnim otpadom

    71/166

    72

    72

    , ,

    , ,

    , . ,

    ,

    ,

    (Grupa autora, 2003).

    ,

    ,

    . , ,

    (s),

    .

    75/442/C ( )

    91/689/C , ,

    .

    :

    (http://www.wasteonline.org.uk/resources/Wasteguide/mn_legislation_european

    _euaffect.html).

    75/442/C ()

    , 1975.

    ,

    , .

    ,

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    72/166

    73

    -(Grupa autora, 2004). , ,

    -,

    ,

    , .

    : ,

    ; ;

    ; .

    ,

    , ,

    , , ,

    , , (Grupa

    autora, 2003).

    , , ,

    , ,

    . -

    ,

    ,

    .

    . , 1

    , 19

    , .

    22

    , ,

    ,

    .

    ,

    2006/12/C, 2008/89/EC : , ,

    () .

    91/689/C

    ,

    ,

    . (Grupa autora, 2003).

  • 7/26/2019 Upravljanje opasnim otpadom

    73/166

    74

    74

    1978.

    78/319/C ,

    . ,

    , 91/689/C. ,

    , 91/689/C

    , ;

    ;

    ;

    .

    (2(2)).

    ,

    . , 11

    , , ,

    3

    2 3. 2

    ,

    3. 3

    , .

    ,

    (Grupa

    autora., 2004).

    ,

    (Grupa autora, 2003).

    ,

    , , ,

    ,

    .

    , ,

    .

    , , -

  • 7/26/2019 Upravljanje opasnim otpadom

    74/166

    75

    .

    84/631/C

    -.

    ,

    .

    ,

    . 84/63//

    1994.94/31/166/2006.

    91/31/

    ,

    . 75/442/

    ,

    , .

    :

    ;

    ;

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    .

    ,

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    .

    ,

    (,

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    ,

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    ,

    , , . 1

  • 7/26/2019 Upravljanje opasnim otpadom

    75/166

    76

    76

    , , :

    ;

    ; ;

    ; ;

    ;

    . 2

    ,

    . 3

    50

    (Ili, 1998),

    . : ;

    ,

    ; ;

    .

    2000/76/

    2000 .

    , ,

    -

    , , , ,

    . ,.

    , ,

    ,

    (Ili, 1998). ,

    ,

    . ,

    , .

    ,

    ,

    (PCB, PCP,

    , , ).

    , , ,

    . ,

  • 7/26/2019 Upravljanje opasnim otpadom

    76/166

    77

    , ,

    .

    , 80/68/S (,

    1989).

    75/442/C 91/689/C,

    ,

    .

    259/93/C

    1994. , ,

    OECD

    .

    , (

    ).

    (http://www.ncte.ie/environ/waste.htm).

    1013/2006, 1379/2007

    669/2008 (

    ).

    -

    , ,

    ,

    .

    ,

    (, , , )

    , :

    (,

  • 7/26/2019 Upravljanje opasnim otpadom

    77/166

    78

    78

    ) (

    ) (, 2002). ,

    ,

    (,

    2002). ,

    , , .

    -

    ,

    .

    , ,

    ,

    ,

    .

    ,

    ,

    , ,

    .

    20.

    ,

    ( 1983.

    "" 1986. .), ,

    ,

    ,

    (Krueger, 1999).

    1989. UNEP1 , 1992.

    (20

    ), ,

    170 (http://www.basel.int/ratif/convention.htm).

    ,

    ,

    1

    (The United Nations EnvironmentalProgramme)

  • 7/26/2019 Upravljanje opasnim otpadom

    78/166

    79

    , OECD-

    2, UNEP-, ,

    . OECD

    ,

    OECD-. ,

    ,

    ,

    .

    . , UNEP

    ,

    OECD- (Krueger, 1999),

    .

    OECD

    , 1984.

    84/631/

    ,

    , ,

    (http://www.ncte.ie/environ/waste.htm).

    ,

    69 , , 1993.

    259/93/

    . Nj

    .

    UNEP 20.

    ,

    ,

    ,

    ,

    . ,

    Cairo Guidelines and Principles for the Environmentally Sound Management of

    Hazardous Wastes,

    2

    (Organization for Economic Cooperation andDevelopment)

  • 7/26/2019 Upravljanje opasnim otpadom

    79/166

    80

    80

    , (Krueger, 1999).

    ,

    , ,

    .

    ,

    ,

    .

    ,

    ,

    . 1

    ,

    . 2

    , 3

    (Krueger, 1999).

    8 9,

    (

    3)

    (

    1 3).

    ,

    , 3,

    (http://www.basel.int/convention/basics.html).

    ,

    (Krueger, 1999). , ,

    ,

    3Environmentally Sound Management

  • 7/26/2019 Upravljanje opasnim otpadom

    80/166

    81

    , UNEP

    .

    ,

    , ,

    (

    ).

    ,

    . 1995.

    , ()

    -, OECD- ( 7)

    . , ,

    ,

    69 (http://www.basel.int/ratif/ban-alpha.htm).

    , ,

    ,

    (2000-2010. ), :

    ;

    ;

    ;

    ;

    .

    , (Grupa

    autora, 2003).

    OECD

    OECD-

    ,

    , , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    81/166

    82

    82

    ,

    .

    ,

    -(http://www.ec.gc.ca/wmd-dgd/default.asp?lang=En&n)

    86013F77-1). 4,

    , ,

    . OECD

    ,

    OECD-.

    , .

    OECD-

    ,

    ,

    ,

    (Krueger, 1999).

    ,

    ,

    , , OECD

    ,

    ,

    1992.

    C(92)39/FINAL OECD-

    (http://www.ec.gc.ca/wmd-

    dgd/default.asp?lang=En&n=86013F77-1). ,

    ,

    .

    ,

    , .

    , .

    , , , ,

    .

    4 ( 41

    ), ..

  • 7/26/2019 Upravljanje opasnim otpadom

    82/166

    83

    .

    , , .

    PCB, ,

    .

    ,

    ,

    (Krueger, 1999), ,

    , , , OECD-

    .

    , ,

    ,

    , .

    , (

    ),

    , . ,

    OECD-

    C(92)39/FINAL.

    ,

    , OECD ,

    ,

    .

    (POPs) ,

    , , ,

    . , 2001. .

    2004, 50

    . , 152

    , , 147 .

  • 7/26/2019 Upravljanje opasnim otpadom

    83/166

    84

    84

    ,

    , , (Grupa

    autora, 2003).

    ,

    , (, 1995). ,

    , ,

    : , ,

    , ,

    (, 2003).12

    ,

    , :

    1.

    Aldrin

    ,

    ;

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    Hlordan

    ;

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    DDT ,

    II

    ,

    .

    ;

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    Dieldrin ,

    .

    5. Dioksin

    ,

    , . ,

    , , ;

    6.

    Endrin

    , ,

    ;

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    Furani

    , PCB;

  • 7/26/2019 Upravljanje opasnim otpadom

    84/166

    85

    8.

    Heptahlor

    , ,

    ;

    9.

    Heksahlor benzen (HCB) .

    ,

    ;

    10.Mireks

    ,

    , ;

    11.Polihlorovani bifenili (PCBs)

    ,

    , , ,

    ,

    (., 1995);

    12.

    Toksafen ,

    , , .

    ,

    ,

    . ,

    ,

    ,

    ,

    .

    ,

    : ,

    . ,

    ,

    21,

    .

    , ,

    , 2025.

  • 7/26/2019 Upravljanje opasnim otpadom

    85/166

    86

    86

    (, 2003). ,

    (polihlorovani dibenzo-p-dioksini dibenzo-p-furani; heksahlor benzen;

    PCBs), ,

    .

    20. ,

    ,

    1985.

    1987. .

    1989.

    (PIC),

    2004.

    . UNEP-, (Klaus Topfer)

    ,

    ,

    (http://www.fao.org/newsroom/en/news/2004/37667/index.html).

    :

    ,

    ;

    ,

    ,

    .

    ,

    PIC

    .

    39 ( 3) ,

  • 7/26/2019 Upravljanje opasnim otpadom

    86/166

    87

    24 , 4 11

    . 27 ,

    (http://www.pic.int/home.php?type=t&id=5&sid=16). ,

    . 9

    ,

    () . ,

    ,

    ,

    (Grupa autora, 2003).

    (http://www.pic.int/home.php?type=t&id=5&sid=16):

    -

    ;

    -

    ;

    -

    ,

    , ;

    -

    ;

    -

    PIC,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    87/166

    ,

    ,

    , -

    .

    , ,

    , .

    ,

    , ,

    . ,

    ,

    , , ,

    Waste Management Act (2002),

    Federal Waste Management Plan, .

    , , ,

    , , ,

    ,

    -

    .

    , ,

    , ,

    ,

    ,

    (http://www.umweltbundesamt.at/en/ueberuns/). 1990. .,

    ,

    ,

    . ,

    (, 1999):

  • 7/26/2019 Upravljanje opasnim otpadom

    88/166

    89

    ,

    ;

    , ;

    ,

    (,

    ), ;

    o .

    ,

    , ,

    .

    ,

    .

    ,

    Waste Management Act(1990-2007),

    (6thReport on

    the State of the Environment in Austria, 2002):

    , ,

    ;

    ;

    (, , , ,

    );

    ,

    ;

    .

    , ,

    ,

    -.

    , ,

    ,

    (Federal Waste Management Plan, 2006):

  • 7/26/2019 Upravljanje opasnim otpadom

    89/166

    90

    90

    ;

    ,

    ;

    ,

    , ,

    , ,

    .

    (2006) ,

    1992, 1995, 1998. 2001. , ,

    , .

    -(. ,

    ),

    ,

    ,

    (http://www.Bundesabfallwirtschaftsplan.at/article/articleview/52746/1/13192/).

    ,

    ,

    .

    1999. (Federal Waste Management plan,

    2001) 49

    , 54 (2004, ).

    5 ,

    (

    ),

    2 .

    ,

    ( 9),

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    90/166

    91

    .

    9.Table 9. Hazrdous waste structure in Austria

    (

    /)

    0.9

    3.2

    7.5

    () 20.0

    4.1

    , 3.8

    ,

    2.3

    2.2

    4.6

    : 7th State of the Environment Report, 2004

    , 19992004,

    , (7th State of the Environment Report, 2004):

    138.000 1999. ,

    398 kg;

    1999. : (, ,

    .) 75.000 , -

    21.000 ;

    10%

    100.000 ,

    -

    , 1997.

    ,

    240.000 (1998) 1

    (2001).

    19932002. ,

    ( 1). ,

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    91/166

    92

    92

    0

    200000

    400000

    600000

    800000

    1000000

    1200000

    1400000

    1993 1994 1995 1996 1998 1999 2000 2001 2002

    1.

    (: , 2002; 7th State of the Environment Report, 2004)

    Graph.1. Hazardous waste in Austria (in tons)

    ,

    ,

    . , 1996. ,

    60% ( 1999),

    (6thReport on the State of the

    Environment in Austria, 2002).

    ,

    -

    (94/904/) 1998. .

    (668 )

    322 ,

    (, 1999). 2001., 1.200.000 ,

    ,

    ,

    920.000 .

    1999. ,

    (10).

    , 1. 2009. ,

    , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    92/166

    93

    (List of Wastes Ordinance)

    , .

    10.

    Table 10. Hazardous waste structure in Austria

    (%)

    18.4

    14.5

    12.6

    4.7

    3.8

    3.0

    () 3.0

    , , 2.5: 6thReport on the State of the Environment in Austria, 2002

    ,

    , ,

    ,

    (, 2002).

    ,

    20. ,

    , Waste Management ActFederal Waste

    Management Plan,

    ,

    . ,

    ,

    .

    , 1

    ,

    :

    , ,

    ,

    .

    1The Waste Prevention and Recovery Strategy 2006-2011

  • 7/26/2019 Upravljanje opasnim otpadom

    93/166

    94

    94

    ,

    ,

    , 2000. 194 (

    ), 1.2 ( 1).

    ,

    (6thReport on the State of the Environment in Austria,

    2002). ,

    .

    , 2002. Waste Management Act

    ,

    . 2004. 0.8

    ,

    .

    , ,

    (Federal Waste Managament Plan, 2006).

    ,

    ,

    () .

    , ,

    ,

    ,

    (, 1999).

    , ,

    ,

    OECD- 7

    . ,

    - 259/93/EEC

    -OECD-.

  • 7/26/2019 Upravljanje opasnim otpadom

    94/166

    95

    1.

    Sketch. 1.Geographical rearrangement of TSD facilites in Austria

    (: 6thReport on the State of the Environment in Austria 2002)

    , 1989. ,

    Act on the Remediation of Contaminated Sites,

    .

    ,

    .

    ,

    , ,

    ,

    .

    e

    , -,

    -.

    ,

    ,

    . ,

  • 7/26/2019 Upravljanje opasnim otpadom

    95/166

    96

    96

    , ,

    ,

    , ,

    , .

  • 7/26/2019 Upravljanje opasnim otpadom

    96/166

    97

    , , ,

    ,

    -. ,

    ,

    .

    ,

    ,

    , (http://www.environ.ie/en/Environment/Waste/):

    1990.

    , ,

    .

    ,

    .

    1992.

    ,

    2,

    , ,

    ,

    . ,

    .

    , ,

    ,

    .

    1994. ,, .

    .

    .

    1996. Waste Management Act,

    P

    2Environmental Protection Agency, Ireland

  • 7/26/2019 Upravljanje opasnim otpadom

    97/166

    98

    98

    (National Hazardous Waste Plan),

    .

    1999.

    .

    2001.

    , 20012006,

    ,

    ,

    ,

    ,

    . (http://www.environ.ie/en/

    Environment/Waste/WasteManagementPlans/). ,

    , .

    ,

    -.

    ,

    .

    ,

    Environmental Protection Agency Act (1992),

    (P),

    :

    ,

    ,

    ;

    ,

    , ;

    ;

    ;

    ;

    , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    98/166

    99

    ;

    , ;

    ,

    ;

    , ,

    ,

    ;

    .

    ,

    ,

    ,

    (

    10 ) ,

    ,

    .

    20082012. :

    ;

    ,

    ;

    , , ,

    ,

    .

    ,

    . ,

    ,

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    99/166

    100

    100

    ,

    ,

    .

    ,

    (, 2007).

    , :

    ,

    ,

    ;

    ,

    ;

    ,

    ;

    ();

    .

    1996. , ,

    : on-site,

    off-site, , ,

    (, 1999).

    ,

    National Waste Report.

    Waste

    Management Act 1996 je 91/689/.

    ,

    ,

    . ,

    (, , ).

    ,

    (

    ) (, 1999).

  • 7/26/2019 Upravljanje opasnim otpadom

    100/166

    101

    19902006.

    , ( 11). 1992.

    , , ,

    1995. .

    ,

    . ,

    ,

    . 1998. ,

    29%, ,

    , ( 21.5% 1996.

    ), 15% (, 2001).

    11.

    Table 11.Hazardous waste in Ireland

    1990 66 000

    1992 99 000

    1995 248 000

    1996 229 634

    1998 296 017

    2001 258 0002004 307 778

    2006 284 184

    : , 2002;PIreland, 2007

    ,

    , 2006.

    8% 2004. , 10%

    2001. .

    , 2002. ,

    , , ,

    , ,

    , , ,

    (, 2007).

    ,

    , , 29 888 (2006. ),

    (P, 2001).

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    101/166

    102

    102

    20082015,

    .

    0 100000 200000 300000

    1996

    1998

    2001

    2004

    2006

    2.

    Graph 2. Industrial hazardous waste in Ireland

    (: , 2007)

    ,

    , , .

    ,

    19962006. ( 2),

    , , .

    ( 3),

    (62%

    ), , (8%),

    (7%) , (6%)

    (, 2007).

  • 7/26/2019 Upravljanje opasnim otpadom

    102/166

    103

    3.

    Graph 3. Most important hazardous waste generators

    19962006. .,

    ( 12, 4),

    ,

    .

    ,

    (P,2007).

    12. 1996-2006 ()

    Table 12.Options for hazardous waste management 1996-2006 (in tons)

    1996 1998 2001 2002 2003 2004 2005 2006

    On-site

    141.151 131.738 95.565 - - 86.328 - 88.409

    Off-site

    33.470 39.055 48.013 - - 55.952 - 60.872

    51.727 99.598 115.366 109.545 180.678 165.498 146.811 134.904

    : , 2007; R, 2001.

    n-site 19962006. ,

    2004. ,

    . off-site

    , , ,

    , 17% 20012004.. 9% 20042006. .

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    103/166

    104

    104

    ,

    , 2003. ,

    ,

    (, 2007). 8% ,

    ,

    (, 2007).

    0

    20000

    40000

    60000

    80000

    100000

    120000

    140000

    160000

    180000

    1996 1998 2001 2004 2006

    tone

    izvoz opasnog otpada

    on-site tretman u industrijskim post rojenjima

    off site tretman u autorizovanim postrojenjima

    4.Graph 4. Comparison of different options of hazardous waste management

    2006. .,

    , 47,5% (

    ) (

    ) .. 31%

    n-site IPPC

    (, ,

    ), 21%

    ( 15 ,

    ) (, 2007).

    ,

    ,

    , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    104/166

  • 7/26/2019 Upravljanje opasnim otpadom

    105/166

    106

    106

    2.

    Sketch. 2.Hazardous waste recovery and disposal facilities in Ireland

    (: EPA, 2001)

  • 7/26/2019 Upravljanje opasnim otpadom

    106/166

    107

    , ,

    .

    , ,

    , ,

    -, ,

    e ,

    , . ,

    ,

    ,

    (http://www.azo.hr/default.aspx?art=146).

    , ,

    , , ,

    ,

    , .

    :

    ,

    .

    , ,

    ,

    , ,

    , , .

    , 2002. ,

    ,

    , ,

    (),

    .

    ,

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    107/166

    108

    108

    .

    , ,

    : ,

    (),

    (http://www.azo.hr/default.aspx?art=146).

    -

    -,

    2000. , (NN 178/04,

    111/06, 60/08),

    , .

    ,

    (NN

    50/05, 39/09)

    .

    (NN MU 3/94)

    (NN 69/06, 17/07, 39/09).

    ,

    (NN 130/05)

    (NN 85/07).

    (NN

    46/02),

    ,

    ,

    , .

    , ,

    ,

    , ,

    .

    :

    ;

    ;

  • 7/26/2019 Upravljanje opasnim otpadom

    108/166

    109

    ;

    ;

    ;

    ;

    ;

    ;

    .

    ,

    -,

    20072015, , .

    20072012

    :

    ,

    ;

    ;

    ;

    ;

    .

    . ,

    ,

    .

    . ,

    ,

    . , 8 ,

    . ,

    , 200 kg,

    4 .

  • 7/26/2019 Upravljanje opasnim otpadom

    109/166

    110

    110

    , 13.2 ( 13), 2.97 per

    capita. , ,

    ,

    . ,

    ,

    ,

    , , ,

    , .

    13.

    Table 13.Estimates of the annual amount of waste

    /

    1.2

    2.6

    1.6

    - 7.1

    0.1

    0.2

    0.4 13.2

    : , 2005

    ,

    , (),

    ,

    ,

    (NN50/05, 39/09).

    , ,

    ,

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    110/166

    111

    0

    10000

    20000

    30000

    40000

    50000

    60000

    70000

    2001 2002 2003 2004 2005

    5. (2001-2005)

    Graph 5. Reported hazardous waste quantities (2001-2005)

    (: Plan gospodarenja otpadom u Republici Hrvatskoj 2007-2015)

    , -

    ,

    ,

    , ,

    , .

    ,

    ( 5),

    213.000 ,

    .

    , , - ,

    . ,

    47 ,

    (3) 43

    ( 4),

    .

    , .

  • 7/26/2019 Upravljanje opasnim otpadom

    111/166

    112

    112

    3.

    Sketch 3.Facilities for hazardous waste collection and storage

    (: Plan gospodarenja otpadom u Republici Hrvatskoj 2007-2015)

    :

    , ;

    , ; ;

    /; .

    ,

    .

    , ,

    ,

    .

    ,

    ,

    ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    112/166

    113

    4.

    Sketch 4.Facilities for hazardous waste treatment(: Plan gospodarenja otpadom u Republici Hrvatskoj 2007-2015)

    , ( 1994.

    ). 2004. 2005. , 12.805 , ,

    13.157 ,

    , 2005. ,

    ,

    .

    :

    , , , ,

    .

  • 7/26/2019 Upravljanje opasnim otpadom

    113/166

    , ,

    ,

    , ,

    .

    .

    ,

    , ,

    . ,

    ,

    . ,

    ,

    ,

    .

    , ,

    ,

    .

    , ,

    ,

    (Djordjevic, Panic, 2007). ,

    . ,

    ,

    . ,

    2000. ,

    ,

    , .

    ,

    , . ,

    . ,

  • 7/26/2019 Upravljanje opasnim otpadom

    114/166

    115

    , -

    , ,

    . ,

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    .

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    , ,

    (

    ) ().

    ( 30)

    ,

    . ,

    , (Grupa autora, 2004).

    (. 135/04, 36/09),

    1,

    . : , ,

    , ,

    . :

    ,

    ,

    ,

    , .

  • 7/26/2019 Upravljanje opasnim otpadom

    115/166

    116

    ,

    ,

    , ,

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    ,

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    , , , , ,

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    . ,

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    , ,

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    . 60/09);

    o

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    o

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    o

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    ,

    (. , . 113/05, 6/07,

    8/10)

    , ,

    ,

    ,

    ;

  • 7/26/2019 Upravljanje opasnim otpadom

    116/166

    117

    o ,

    (.

    , .113/05);

    o

    (. , . 5/10).

    (. , . 66/91, 83/92, 53/93, 67/93, 48/94, 53/95)

    :

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    : , ,

    , ,

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    29 11

    ,

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    (. , . 36/09)

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    ),

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  • 7/26/2019 Upravljanje opasnim otpadom

    117/166

    118

    , , ,

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    ,

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    o ,

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    (. , . 60/09).

    (.

    , . 135/04) ,

    ,

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    (. , .

    135/04, 36/09) ,

    , ,

    ,

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    .

  • 7/26/2019 Upravljanje opasnim otpadom

    118/166

    119

    .

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    . 69/05);

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    (. , . 69/05).

    (. , . 135/04)

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    , . 84/05);

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    (. , . 30/06);

    o (.

    , . 84/05);

    o

    (. , . 108/08).

  • 7/26/2019 Upravljanje opasnim otpadom

    119/166

    120

    (. , . 36/09)

    , ,

    ,

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    101/05), :

    o (. , . 38/97);

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    , . 79/91). (. , . 24/94, 28/96,

    21/99, 44/99, 68/02; . , . 36/09)

    , ,

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    , . 36/09)

    (, ).

    (. , . 36/09)

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    .

    (. ,

    . 2/99)

    ;

  • 7/26/2019 Upravljanje opasnim otpadom

    120/166

    121

    (. , . 46/91, 54/96)

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    31/82);

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    o (. ,

    . 42/98, 44/99);

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    , . 33/78);

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    23/94).

    (. , . 44/95,

    101/05) ,

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    (. , . 30/97);

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    (. , . 54/92, 30/99, 19/06).

    (. , . 62/06, 65/08) ,

  • 7/26/2019 Upravljanje opasnim otpadom

    121/166

  • 7/26/2019 Upravljanje opasnim otpadom

    122/166

  • 7/26/2019 Upravljanje opasnim otpadom

    123/166

    124

    o

    ;

    o

    ;o ()

    (EIONET),

    .

    (. , . 135/04)

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    .

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    . (,

    , ),

    ,

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    () 2008. ,

    2012. ,

    -,

    -,

    . , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    124/166

    125

    .

    , ,

    ,

    , ,

    .

    (. , . 57/08)

    2008. ,

    ,

    ,

    . ,

    , , .

    ,

    , ,

    . :

    ;

    ;

    (,

    , );

    , ;

    ; BREF- (

    );

    .

    :

    o

    -;o / ,

    ;

    o ,

    ;

    o

    BAT-.

    , , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    125/166

    126

    (2003). ,

    , : ,

    ,

    , . ,

    , :

    , , ,

    , .

    , ,

    :

    o

    -;

    o

    ;

    o ;

    o

    ;

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    20102019 (. , .

    29/10) ,

    . ,

    .

    , :

    ,

    ,

    ;

    , ;

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    126/166

    127

    ,

    ;

    ;

    (, , ,

    );

    ,

    ,

    ,

    ;

    ,

    ,

    ,

    .

    ,

    , ,

    .

    .

    (20102014) (20152019).

    -,

    ,

    (

    ).

    ,

    . ,

    , ,

    2020. . ,

    ,

    ,

    . , ,

    , ,

  • 7/26/2019 Upravljanje opasnim otpadom

    127/166

    128

    .

    (. , .

    12/10) , :

    ;

    ,

    -; ,

    (, , 2007).

    ,

    (, , ) , ,

    (, ,, , ). ,

    ,

    ,

    .

    , ,

    ,

    ,

    .

    (.

    , . 17/09) ,

    .

    ,

    .

    ,

    .

    (. , . 12/10)

    10 .

    ,

    .

    ,

    , ,,

  • 7/26/2019 Upravljanje opasnim otpadom

    128/166

    129

    . ,

    ,

    , .

    ,

    ,

    (14).

    14.

    Table 14.Hazardous waste properties

    : , 2007

    ,

    ,

    ( ,

    . , . 55/01).

    ,

    (

    ,

    ,

    ). ,

    .

    ,

    .

    ,

  • 7/26/2019 Upravljanje opasnim otpadom

    129/166

    130

    . ,

    , ,

    ,

    , . ,

    , ,

    .

    European Environment Agency

    (2007), 19992005. ,

    , ( 6).

    ,

    . ,

    ,

    . ,

    ,

    (Grupa autora, 2002). ,

    ,

    .

    2007. , 5.200.000 , 2008. ,

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    131

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    Graph. 6. Hazardous waste in Serbia

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    132

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    133

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    Graph 7. Conditions of storage facilities

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    134

    15

    Table 15. Hazardous waste temporarily stored or disposed on landfills (historical amounts)

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  • 7/26/2019 Upravljanje opasnim otpadom

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    135

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    136

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    Sketch 5. Spatial distrubution of storage facilities and industrial landfills

    (, 2007)

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    137

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    138

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    Table 16.Transboundary movement of hazardous waste in 2007

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  • 7/26/2019 Upravljanje opasnim otpadom

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    140

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  • 7/26/2019 Upravljanje opasnim otpadom

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    142

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    6.

    Sketch 6.Regional hazardous waste management

  • 7/26/2019 Upravljanje opasnim otpadom

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  • 7/26/2019 Upravljanje opasnim otpadom

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  • 7/26/2019 Upravljanje opasnim otpadom

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    SUMMARY

    How are human needs suddenly began to grow, and intensive development

    of science and technology made them freely meet, there was a production ofsignificant quantities of different types of waste, which features in the beginning

    were not fully known. Detection of a large number of new artificial materials

    especially applicable in industrial production, resulting in the generation of

    specific types of waste - hazardous waste, its characteristics and long-term

    seriously threaten human health, other living organism and the environment in

    general. It is for the aforementioned reasons, it is necessary to consider the

    whole issue related to hazardous waste, that is, become familiar with its

    characteristics, behavior in nature, where at the beginning of massive

    uncontrolled delayed, subdivisions, which includes, anthropogenic processesthat generate and grade the severity of the expected consequences .

    Industrialized countries that were due to accelerated industrialization first met

    with the aforementioned problem, have initiated detailed studies that have

    produced a series of rules and principles defined in the form of legal provisions

    governing the operation of hazardous waste management system. This system,

    also called the system of cradle-to-grave, encompasses all phases of his

    generation, or generation of hazardous waste, through collection, transportation,

    storage, treatment and final disposal. For the proper functioning of each phase

    and the behavior of the participants in this complex system, it is necessary to

    establish an appropriate legislative, institutional and planning framework and

    mechanisms for their implementation, thus reducing the risk of potential adverse

    effects.

    Hazardous waste management system is an organized approach of

    continuous direct and control the same from the moment of its creation,

    collection, storage, treatment and final disposal. It is characterized by extreme

    complexity, due to very pronounced risk of his release and penetration into the

    environment, which directly affected all living organisms and environmental

    quality. Guidelines for sustainable management, regulating the responsibilities

    of all stakeholders mentioned system and prescribe for each phase individually.Generation of hazardous waste is a particularly problematic phase because of the

    complex organization of the system for monitoring the quantitative and

    qualitative variations within a general trend of the waste generated, and the

    establishment of effective mechanisms to control the generators themselves,

    especially when it comes to industrial plants, which bear great responsibility for

    future the fate of waste generated. As a logical continuation, after the generation

    of hazardous waste, usually lead to its temporary storage, which involves storing

    hazardous waste on its way to the facility for treatment and final disposal. Due to

    the accumulation of large quantities of hazardous waste in one place, this phase

    represents a major challenge in the sense of order to prevent possible accidents.

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    SUMMARY 157

    For this reason, the constant control, not only by the direct responsible parties,

    but also by the competent authorities of a state. Further functioning of the

    management of hazardous wastes usually involves its removal from the plant for

    its treatment, which significantly increases the risk of accidents and threat topopulation and environment in wider areas, along routes that are used. In order

    to partially or completely neutralized characteristics of hazardous waste have

    been developed various forms of treatment, possibly followed and disposal in

    landfills that are specially equipped for the said function. Today, after a long

    experience in the pursuit of a system of hazardous waste as more aligned with

    high ecological standards have been created more options for managing

    hazardous waste relating to the promotion of technologies that generate less

    waste, substitution of hazardous substances less hazardous, recycling and reuse

    existing hazardous waste and the like. This situation resulted in theestablishment of new technological standards have further improvements to

    measure very short intervals, and further progress in this field is inevitable. Like

    many developing countries, the Republic of Serbia started with a serious change

    in the field of environmental protection, which resulted in separation of a

    number of serious problems that require a special approach to the resolution.

    How is the current practice of hazardous waste ocenjana as extremely poor and

    completely unsustainable in the future to Serbia's EU flows, it became clear that

    the crucial changes are necessary. First of all, we started the construction of a

    new regulatory system must be fully adapted to EU standards, the institutional

    framework that should enable the implementation of all provisions prescribed

    and planned basis to be Put the short-and long-term objectives in establishing a

    system of hazardous waste. The competent authorities must have open

    communications and cooperation among themselves and with the responsible

    parties and the public who are the unavoidable future system. In this sense, it is

    necessary to implement adequate training and then continuous control, which

    will ensure the implementation of established principles for managing hazardous

    waste.

    In addition to these changes, the extent to which the work began, the

    problem must be mentioned non-availability of network facilities for hazardouswaste management, ie, lack of facilities for some form of treatment or disposal

    of hazardous waste. It is clear that a country with its industrial production and

    the desire to preserve environmental quality, is unable to support such an

    approach, but it has accelerated its approach to the creation and construction.

    This begins with the realization of one of the basic principles presented in the

    EU directives, which points to the necessity of self-sufficiency of each Member

    State in addressing hazardous waste on its territory. Of course, it is clear that

    introduced changes involve significant financial investment and to a large extent

    on the economic strength of a country, which can be partly alleviate a goodassessment of real needs and a clear definition of short and long term goals. This

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    158

    is supported by the attitude of the developed European countries, which on the

    said road support countries that are in the process of establishing a system of

    hazardous waste, to look at my options and choose an acceptable option,

    regardless of their position in the hierarchy of options for addressing waste.Accordingly, it is justified presented a regional approach to hazardous waste

    management in Serbia, which will initially dispose of its development with one

    facility for treatment and disposal at the national level and more central regional

    warehouses, which are determined in the districts with the greatest production of

    hazardous waste. This will directly influence the reductio