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"" RMIS View/Print Document Cover Sheet""

This document was retrieved from the Boeing ISEARCH System.

Accession #: Dl96058027

Document #: SD-WM-ER-421

TitlelDesc: TANK 241 BY1 07 HEADSPACE GAS & VAPOR CHARACTERIZATION RESULTS FOR SAMPLES COLLECTED IN 311 994 & 1011 994

ENGINEERING CHANGE NOTICE Page 2 o f 2

18. Change Impact Revieu: I n d i c a t e t h e r e l a t e d docunents (o ther than the engineering docunents i d e n t i f i e d on Side 1) t h a t u i l l be af fected by the change descr ibed i n Block 12. Enter the af fected d o c w n t nunber i n Block 19.

SDDIDO

1. ECN (use no. frol pg. 1)

625441

r i Sei.mielStress Analysis

15. Design V e r i f i c a t i o n Required

[ X I NO

[ I yes

Functional Darign Criteria

oparating Spadficatio"

Criticality Specification

Concaptual Design Report

Equipment Spec.

const. spec.

Pmcuremont Spec.

Vendor Information

OM Manual

FSARISAR

Safety Equipment List

Radiation Wmk Permit

Environmental Impact Statemam

Envimnmemal Report

Environmental Permit

16. Cost Impact 17. Schedule Impact (days) ENGINEERING CONSTRUCTION

[ I 11 $ Delay [ I

[ I f [ I $

[ I $ Improvement Add i t i ona l

Savings

A d d i t i ona I Savings

StresslDssign Report

Interface Contml Drawing

Calibration Pmceduro

innallation Pmcsdum

Maintenance Pmcadum

Enginoorlng Procedure

Operating innruction

Oponting Pmoodure

Operational Safety Requirement

lEF0 Drawing

Cell Anangemant Drawing

Essential Material Specification

Fao. Pme. Samp. Schedule

Inspection Plan

Inventory Adjustment Request

Tank Calibration Manual

H d t h Physics Pmcedum

Spares Multiple Unit Lining

Teat Pm,dureslSpoEifiCation

Component Index

ASME Coded item

Human Factor Consideration

Computer Software

Electtic Circuit Schedule

ICRS Pmcodure

Procam Control ManuollPlan

Pmcass Flow Chart

Purchase Requisition

Tickler File

L J [ I 19. Other A f fec ted Docunents: (NOTE: DocMents l i s t e d belou u i l l no t be rev ised by t h i s ECN.) Signatures belou

i n d i c a t e t h a t t h e s ign ing organizat ion has been n o t i f i e d of other a f fected docMents l i s t e d belou. DocMent NunberlRevision D o c m n t NunberlRevision D o c m n t Nunber Revis ion

20. Approvals

DPERATIONS AND ENGINEERING ARCHITECT-ENGINEER

Cog. Eng. D. R . B r a t z e 9 4 Ws QA PE

Cog. Mgr. T. .I. Ke l l ey

1A Safety

Safety

Inv i ron.

l t h e r

J ro j .

) r o j .

) r o j .

) r o j .

Signature Date Signature

" Design

Environ.

Other

DEPARTMENT OF ENERGY

Signature o r a Contro l Nunber t h a t t racks the Approval Signature

ADDITIONAL

~

~

Date

A-7900-013-3 (11/94) GEF096

I SUPPORTING DOCUMENT I 1. Total Pages qP

TANK 241-BY-107 HEADSPACE GAS AND VAPOR CHARACTERIZATION RESULTS FOR SAMPLES COLLECTED I N MARCH 1994 AND OCTOBER 1994

1 2. T i t l e 1 3 . Nunber I 4. Rev No.

WHC-SD-WM-ER-421 2

5. Key Words

CHARACTERIZATION OBJECTIVES, TANK HEADSPACE, SAMPLING EVENT, INORGANIC GASES, ORGANIC VAPORS

6 . Author

NW: D . R. BRATZEL

Organizationlcharge Code 7 5 6 4 0 / N 4 A B I

8. RELEASE STAMP

GFF!Ci,AL RELEASE-@ LYY ‘A li c

DATE SEP 2 6 1995 [,-- I A-6400-073 (08 /94) UEF124

(1) D o c m n t Nunber RECORD OF REVISION

WHC-SD-WM-ER-421

A-7320-005 ( 0 8 / 9 1 ) UEF168

~ ~ ~

Page 1

WHC-SD-WM-ER-421 REV. 2

2.0 SAMPLING EVENT

2.1 March 1944 In Situ Sampling Event

Tank BY-107 was sampled using ISS methods on March 25, 1994 by WHC Sampling and Mobile Laboratories. This sampling was conducted to satisfy requirements of Safefy Assessment for Gas Sampling A// ferncyanide Tanks (Farley 1991). Samples were collected from a point approximately 6.7 m below the top of the flange on riser 12A, between 10:44 a.m. and 1230 p.m. Though the sorbent traps were physically lowered down into the headspace to minimize loss of analytes through condensation, adsorption, or absorption by condensate, the SUMMAM canister samples were collected using unheated transfer tubing.

Huckaby et al. (1995) give a general description of the ISS method and equipment. Pingel (1994) provides field sampling information for the tank BY-I07 March 1994 ISS event. In addition to the TNMOC measurement results presented below, Sharma et al. (1995) and Rasmussen (1994) provide other sample analysis results.

2.2 October 1994 Vapor Sampling System Sampling Event

Headspace gas and vapor samples were collected from tank BY-107 using the VSS on October 26.1994 by WHC Sampling and Mobile Laboratories (WHC 1995b). Sample collection and analysis were performed as directed by the tank characterization plan (Carpenter 1994). The tank headspace temperature was determined to be 33.1 "C. Air from the tank BY-107 headspace was withdrawn via a 5.5 m-long heated sampling probe mounted in riser 5, and transferred via heated tubing to the VSS sampling manifold. All heated zones of the VSS were maintained at approximately 50 'C.

Sampling media were prepared and analyzed by WHC, Oak Ridge National Laboratories (ORNL), and Pacific Northwest Laboratories (PNL). The 40 tank air samples and 2 ambient air control samples collected are listed in Table 2-1 by analytical laboratory. Table 2-1 also lists the 14 trip blanks and 2 field blanks that accompanied the samples.

A general description of vapor sampling and sample analysis methods is given by Huckaby et al. (1995). The sampling equipment, sample collection sequence, sorbent trap sample air flow rates and flow times, chain of custody information, and a discussion of the sampling event itself are given in WHC (1995b).

3


3.2 Carbon Dioxide and Carbon Monoxide

The average measured headspace carbon dioxide concentration, 94 ppmv, is about one-fourth of the normal ambient air concentration of about 400 ppmv. Carbon dioxide introduced by air exchange with the atmosphere is readily absorbed by caustic supernatant and interstitial liquids of the waste tanks, and converted to carbonate in solution. It is reasonable to expect the level of carbon dioxide in a tank headspace will therefore depend on the tank's breathing rate, and the pH and surface area of aqueous waste (i.e., supemate, interstitial liquid, and condensate) in the tank. The 94 ppmv carbon dioxide concentration measured in tank BY-IO7 is typical of other tanks sampled to date.

Carbon monoxide in the tank BY-107 headspace was measured to be 20 ppmv. Its concentration in ambient air typically ranges from 0.05 to 0.15 ppmv. Elevated waste tank headspace carbon monoxide concentrations are common, and have been measured to be as high as p6.7 ppmv] in tank C-1032 (Huckaby and Story 1994). Elevated carbon monoxide concentrations are thought to be due to the decomposition of organic waste in the tanks.

3.3 Nitric Oxide, Nitrogen Dioxide, Water and Tritium

Nitric oxide and nitrogen dioxide concentrations in the tank BY-I07 headspace were determined to be 0.13 ppmv and ?: 0.02 ppmv, respectively. These are both acid gases that would have very low equilibrium concentrations above the high pH waste in tank BY-107. The measurable presence of nitric oxide may be due to its formation from oxygen and nitrogen in the radiation field of the headspace. These constituents could potentially serve as oxidizers to support combustion. but at the measured concentrations would have a negligible effect on the flammability of the tank BY-I07 headspace.

The water vapor concentration of tank BY-I07 was determined to be about 13.0 mglL, at the tank headspace temperature of 33.1 "C and pressure of 981 mbar (735.7 torr), (WHC 1995b). This corresponds to a water vapor partial pressure of 18.31 mbar (13.7 torr), to a dew point of 16.1 "C, and to a relative humidity of 36 %.

Tritium was tested for using silica gel sorbent traps. It is assumed that tritium ions produced by the waste combines with hydroxide ions to form tritium-substituted water. Evaporation of the tritium-substituted water would then result in airborne radioactive contamination. Silica gel sorbent traps adsorb virtually all (normal and tritium-substituted) water vapor from the sampled tank air, and are analyzed at the WHC 222- S laboratory. Analysis of the silica gel indicated the total activity of the headspace to be below 50 pCilL (WHC 1995b).

3.4 Discussion of Inorganic Gases and Vapors

Aside from water vapor and carbon dioxide, the most abundant waste constituents in the tank BY-I07 headspace are ammonia, hydrogen, and nitrous oxide. These have been detected in most tank

The carbon monoxide measurement in tank C-103 was made by Oregon Graduate Institute of Science and Technology, and placed in brackets to emphasize it should be considered secondary data

5


6.0 REFERENCES

29 CFR 1910.120,1993. "Hazardous Waste Operations and Emergency Response", Code ofFederal Regulations.

Bumum, S. T., 1995, Qualification of Reported WHC Vapor Program Data, (letter 95-CHD-065 to president, Westinghouse Hanford Company, August 18), Department of Energy, Richland Operations Ofice, Richland, Washington.

Carpenter, B. C., 1994, Tank 241-BY-107 Tank Characterization Plan, WHC-SD-WM-TP-274 Rev. OA,

Cashdollar, K. L..,M. Herhberg. 1. A. Zbchwer, C. E. Lucci, G. M. Green, and R. A. Thomas, 1992,

Westinghouse Hanford Company, Richland, Washington

Laboratory Flammability Studies of Mixtures of Hydrogen, Nitrous Oxide, and Air, WHC-SD-WM- ES-219 Rev. 0, Westinghouse Hanford Company, Richland, Washington.

Clauss, T. W., M. W. Ligotke, K. H. Pool, R. B. Lucke, B. D. McVeety. G. S. Klinger, J. S. Young, M. McCulloch, J. S. Fruchter, and S. C. Goheen, 1995, Vapor Space Characterization of Waste Tank 241-BY-107: Results from Samples Collected on 10126194, PNL-10468 UC-606, Pacific Northwest Laboratory, Richland, Washington.

Dougherty, L. F., 1995, Single Shell Tank lnterim Operational Safety Requirements, WHC-SD-WM-OSR- 005 Rev. 0, Westinghouse Hanford Company, Richland, Washington.

EPA 1988, Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, PB90-127374, U.S. Environmental Protection Agency, Washington, D.C.

EPA 1992, Test Methods for Evaluating Solid Waste. SW-846 Rev. 1, US. Environmental Protection Agency, Washington, D.C.

Farley, W. G., 1991, Safety Assessment for Gas Sampling All Ferncyanide Tanks, WHC-SD-WM-SAD- 009 Rev. 2. Westinghouse Hanford Company, Richland, Washington.

Hendrickson, R. W., 1995, Tank Vapor Characterization Oak Ridge National Laboratories Quality Assurance Assessment, TWRSQA-95-0012, Westinghouse Hanford Company, Richland, Washington.

Homi, C. S., 1995, Vapor Sampling and Analysis Plan. WHC-SD-WM-TP-335 Rev. OG, Westinghouse Hanford Company, Richland, Washington.

Huckaby, J. L., 1994a. Vapor Sampling System (VSS) and In Situ Sampling (ISS) Method Comparison, WHC-SD-WM-RPT-101 Rev. 0, Westinghouse Hanford Company, Richland, Washington.

Huckaby. J. L.. 1994b. Tank 241-C-103 Headspace Flammability, WHC-EP-0734 Rev. 1, Westinghouse Hanford Company, Richland, Washington.

Huckaby, J. L.. H. Babad, and 0. R. Brakel, 1995,Headspace Gas and Vapor Characterization Summary for the 43 Vapor Progfam Suspect Tanks, WHC-SD-WM-ER-514, Rev. 0, Westinghouse Hanford Company, Richland. Washington.

12


Huckaby, J. L., and D. R. Bratzel, 1995b. Tank -BY-108 Headspaca Gas and Vapor Characterization Results for Samples Collected in March 1994 October 1994, WHC-SD-WM-ER-442 Rev. 2 , Westinghouse Hanford Company, Richland, Washington.

Huckaby, J. L., and M. S. Story, 1994, Vapor Characterization of Tank241-C-103. WHC-EP-0780 Rev. 0. Westinghouse Hanford Company, Richland, Washington.

Jenkins, R. A,, 1995a, Untitled, (Letter 090195A to D. Bratzel, September l ) , Oak Ridge National Laboratory, Oak Ridge, Tennessee

Jenkins, R. A,, 1995b. Untitled, (Letter 091495A to D. Bratzel, September 14). Oak Ridge National Laboratory, Oak Ridge, Tennessee.

Jenkins, R. A, A. 9. Dindal, C. E. Higgins. C. Y. Ma, M. A. Palausky, J. T. Skeen, and C. K. Bayne, 1994, Analysis of Tank 241-BY-107 Headspace Components, ORNL-CASD-FR-241 BY107.95. Rev. 0. Oak Ridge National Laboratory, Oak Ridge, Tennessee.

Jenkins, R. A, A. 9. Dindal, C. Y. Ma, M. A. Palausky, J. T. Skeen, and C. K. Bayne. 1995, Analysis of Tank 241-TY-104 Headspace Components, ORNL-CASD-FR-241TY104.95 Rev. 1, Oak Ridge National Laboratory, Oak Ridge, Tennessee

Keller. K.K., 1994, Quality Assurance Project Plan for Tank Vapor Characterization, WHC-SD-WM-QAPP- 01 3 Rev. 2, Westinghouse Hanford Company, Richland, Washington.

Ligotke. M. W. 1995, PNL Vapor Project Analytical Holding Times, (Letter to D.R. Bratzel, September 23, 1995). Pacific Northwest Laboratory. Richland, Washington.

Ligotke, M. W.. K. H. Pool, T. W. Clauss. 9. D. McVeety. G. S. Klinger. K. 9. Olsen. 0. P. Bredt, J. S. Fruchter, and S. C. Goheen, 1995, Vapor Space Characterization of Waste Tank 241-U-103: Results from Samples Collected on 2/15/95, PNL-10813 UC-606, Pacific Northwest Laboratory, Richland, Washington.

Lucke, R. B., M. W. Ligotke, K. H. Pool, T. W. Clauss, A. K. Sharma. B. D. McVeety, M. McCulloch, J. S. Fruchter. and S. C. Goheen, 1995, Vapor Space Characterization of Waste Tank 241-C-108: Results from Samples Collected Through the Vapor Sampling System on 8/5/94, PNL-10351 UC- 606, Pacific Northwest Laboratory, Richland, Washington.

Mahlum, D. D., J. Y. Young, and R. E. Weller, 1994, Toxicologic Evaluation ofAnalytes from Tank 231-C-

McVeety, 9. D., T. W. Clauss, M. W. Ligotke, K. H. Pool, R. 9. Lucke. G. S. Klinger, J. S. Young, M.

103. PNL-10189, Pacific Northwest Laboratory, Richland, Washington.

McCulloch. J. S. Fruchter, and S. C. Goheen, 1995, Vapor Space Characterization of Waste Tank 241-BY-108; Results from Samples Collected on 10/27/94. PNL-10495 UC-606. Pacific Northwest Laboratory, Richland, Washington.

Meacham, J. E., H. Babad, R. J. Cash, G. T. Dukelow, S. J. Eberlein. D. W. Hamilton, G. D. Johnson, J. W. Osborne. M. A. Payne, D. J. Sherwood, D. A. Turner, and J. L. Huckaby, 1995, Approach for

13


Tank Safety Characterilation of Hanford Site Waste, WHC-EP-0843 Rev. 0. UC-2070, Westinghouse Hanford Company, Richland, Washington.

NFPA 1992, Standard on Explosion Prevention Systems, NFPA 69, National Fire Protection Association, Quincy, Massachusetts.

Osbome, J. W., and J. L. Huckaby, 1994, Program Plan for the Resolution of Tank Vapor Issues, WHC- EP-0562 Rev. 1, Westinghouse Hanford Company, Richland, Washington.

Anderson, 1994, Data Quality Objectives for Generic In-Tank Healtb and Safety lssue Resolution, WHC-SD-WM-DQO-002. Westinghouse Hanford Company, Richland, Washington.

Osborne, J. W., J. L. Huckaby, T. P. Rudolph, E. R. Hewitt, D. D. Mahlum. J. Y. Young, and C. M.

Pingel, L. A,, 1994, DraR Results from the Vapor Sampling of Waste Tank BY-107, (Internal memorandum 12920-SAS94-082 to J. L. Huckaby, April 13), Westinghouse Hanford Company, Richland, Washington.

28, 1994 by Westinghouse Hanford in 6-L SS SUMMA@ Canisters, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon.

Rasmussen, R. A,, 1994, Air Samples Collected at Waste Tanks BY-107 and BY-108 on March 25 and

Sharrna, A. K., R. B. Lucke, T. W. Clauss, B. D. McVeety. J. S. Fruchter, and S. C. Goheen. 1995, Vapor space Characterization of Waste Tank 241-BY-107: Results from the IN Situ Sample Collected on 3/25/94, PNL-10257 UC-606, Pacific Northwest Laboratory, Richland, Washington.

Hanford Cor&any, Richland, Washington. WHC 1995a, Operating Specifications for Watchlist Tanks, OSD-T-151-00030, Rev. B-9, Westinghouse

WHC 1995b, Vapor and Gas Sampling of Single-Shell Tank 241-BY-107 Using the Vapor Sampling System, WHC-SD-WM-RPT-120, Westinghouse Hanford Company, Richland, Washington.

14

THIS PAGE ~ N T I O N A L L Y LEFTBLANK


Table 3-1 Tank BY-I07 Inorganic Gas and Vapor Concentrations -

Analyses by Pacific Northwest Laboratory

CAS’ Sample Number Average Standard RSD’ Compound Type of (ppmv) Deviation (”/)

( P P W Number

samples

6 972 6 0.6 Ammonia, NH3 7664-41-7 Sorbent Trap

Carbon Dioxide, CO, 124-38-9 SUMMATM 3 94 26 28 Carbon Monoxide, CO

Hydrogen, H,

Nitric Oxide, NO

630-08-0 SUMMATM

1333-74-0 SUMMATM

10102-43-9 Sorbent Trap

< 20

267

0.13

- 36

0.03

- 14

23

Nitrogen Dioxide, NO, 101024-0 Sorbent Trap 6 < 0.02 - -

7732-18-5 Sorbent Trap 6 18,700 600 3

Nitrous Oxide, N,O 10024-97-2 SUMMATM 3 621 36 6 Water Vapor, H,O

(13.0 mglL) (0.4 mglL)

1 CAS = Chemical Abstracts Service.

2 RSD = relative standard deviation. Burnum (1995) specifies the RSD should be less than 25 %.

16


Table 3-2

Tank: BY-I07 BY-108'

Date sampled, (mo/day/yr) 10/26/94 10/27/94

Headspace temperature, ("C) 33.1 25.7

Hydrogen, (ppmv) 267 399

Ammonia, (ppmv) 972 1040

Carbon dioxide, (ppmv) 94 224 Carbon monoxide, (ppmv)

Nitric oxide, (ppmv)

Nitrogen dioxide, (ppmv)

Nitrous oxide, (ppmv)

Water vapor, (mg/m3)

< 20

0.13

i 0.02

621

13.0

<76

i 0.03

i 0.02

641

13.4

Water vapor, (% relative humidity) 36 56

Ethanenitrile (acetonitrile), (ppmv) (2.2) 0.94

Propanone (acetone), (ppmv)

I-Butanol, (ppmv)

n-Dodecane, (ppmv)

(3.9)

(7.9) 0.21

n-Tridecane, (ppmv) (0.26) 0.73

Total organic compounds ', (mg/m3) 149.4 510

1 Inorganic gas or vapor results are from PNL; organic vapor results are from ORNL, with semiquantitative values in parentheses and quantitative values not in parentheses.

2 Data are from Huckaby and Brahel 1995.

3 Total organic compound concentration was estimated from TST sample results.

17


Table 4-1 Tank BY-I07 Quantitatively Measured Organic Compounds in SUMMATY Samples -

Anaiyaes by Pacific Northwest Laboratory

Cmpd Compound #

CAS' Average2 Standard RSD' Number (PPmv) Deviation (%)

1 Trichlorofluoromethane 75-69-4 0.030 0.002 7

2 Propanone (acetone) 67-64-1 6.5 0.7 10

3 I-Propanol 71-23-8 1.8 0.2 14

4 2-Butanone 78-93-3 1.1 0.03 3

5 n-Hexane 11 0-54-3 0.79 0.07 9

6 Benzene 7143-2 0.0048 0.0003 6

7 4-Methyl-2-pentanone 108-10-1 0.028 0.003 12

9 n-Heptane 142-82-5 0.19 0.01 5

10 Tetrahydrofuran 109-99-9 0.56 0.01 1

11 Toluene 108-88-3 0.036 0.002 7

12 Cyclohexanone 108-94-1 0.0059 0.0022 38

13 n-Decane 124-18-5 0.033 0.003 9

14 Methane 74-82-8 C20 - __

8 Cyclohexane 11 0-82-7 0.078 0.048 62

---- I CAS = Chemical Abstract Service.

2 Average of 3 samples.


18


Table 4-2 Tank BY-I07 Quantitatively Measured Oganlc Compound Average Concentrations -

Cmpd Compound CAS' Average' Standard RSD4 # Number (PPmv) Deviation (%)

(ppmv) 1 n-Butanenitrile 109-74-0 0.12 0.08 68

2 Toluene

3 n-Pentanenitrile

4 2-Hexanone

5 n-Octane

6 2-Heptanone

7 n-Nonane

8 2-Octanone

9 n-Decane

10 n-Undecane

100-88-3

110-59-8

591-78-6

11 1-65-9

1 10-43-0

111-84-2

11 1-13-7

124-18-5

1120-21-4

0.067

0.028

0.15

0.12

0.12

0.066

0.035

0.068

0.14

0.007

0.002

0.03

0.02

0.02

0.005

0.005

0.010

0.004

11

6

17

13

19

8

13

14

3

11 n-Dodecane 1 12-40-3 0.21 0.001 0.5

1 Results in this table are quantitative (as defined in Section 4.1).

2 CAS = Chemical Abstract Service.

3 Average of 3,250 ml TST samples

4 RSD = relative standard deviation. Burnum (1995) specifies the RSD should be less than 25 %

19


Table 4 4 Tank BY-I07 Positively Identified Organic Compounds in TST Samples

for which Practical Holding Times we18 Exceeded - [ -

Cmpd Compound CAS2 Average3 Standard RSD' Number (PPmv) Deviation (Oh/.) #

1 Butana15 123-72-8 0.13 0.20 153

2 I-Butanol5 71-36-3 7.9 5.0 63

3 2-Pentanones 107-87-9 0.23 0.12 53

1 Practical holding times are defined and discussed in Section 4.1.

2 CAS = Chemical Abstract Service

3 Average of 3,250 ml TST samples.


5 The concentration of this analyte was not quantitatively measured (as defined in Section 4.1), because the measured concentration was outside of the instrumental calibration limits.

6 The concentration of this analyte is quantitatively measured (as defined in Section 4.1).

21


Table 4-6 Tank BY-107 Tentatively Identified Organic Compounds in SUMMA” Samples -

Analyses by Paclflc Northwest Laboratory

Cmpd Compound CAS’ Average2 Standard # Number (mglm3) Deviation

(mglm3)

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

Propane

Propene

Cyclopropane

lsobutane

1 -Butene

n-Butane

1-Propene, 2-methyl-

Isopropyl Alcohol

n-Pentane

2-methyl penhe

3-Methylpentane

2-Butanol

Methylcyclopentane

3-methyl-2-Butanone

1-Butanol

2-Pentanone

Hexane, 3-methyl-

2-Pentanol

1-Heptene

C7 AlkenelCycloalkane

2-Methyl-2-Pentanol

Methylcyclohexane

1-Pentanol

2-Methylheptane

2-Hexanone

n-Octane

74-986

11 5-07-1

75-1 9-4

75-28-5

106-98-9

106-97-8

11 5-1 1-7

67-630

10966-0

107-83-5

96-14-0

78-92-2

96-37-7

563-80-4

71-36-3

107-87-9

589-34-4

6032-29-7

592-76-7

590-36-3

108-87-2

71-41-0

592-27-8

591-78-6

11 1-65-9

0.81

1.01

0.19

0.34

0.36

0.85

0.17

0.30

0.55

0.76

0.15

0.13

0.09

0.12

2.66

0.91

0.53

0.09

0.08

0.07

0.10

0.17

0.08

0.30

0.31

0.29

0.33

0.22

0.01

0.02

0.02

0.04

0.01

0.01

0.00

0.01

0.00

0.00

0.00

0.00

0.27

0.07

0.01

0.00

0.00

0.00

0.00

0.00

0.00

0.01

0.01

0.01

23


Cmpd Compound #

CAS' Average' Standard Number (mg/m3) Deviation

54

55

56

57

58

59

60

61

62

Alkene/Cycloalkane

AlkenelCycloalkane

Alkane

Alkene/Cycloalkane

2-methyltridecane

3-Methyltridecane

C15 Alkane

n-Tetradecane

Alkene/Cycloalkane

1560-96-9

641 8-41 -3

629-594

0.08

0.26

0.30

0.32

0.20

0.11

1.20

1.12

0.13

0.01

0.02

0.02

0.03

0.02

0.01

0.10

0.07

0.01

Sum of tentatively identified compounds: 25.57

1 CAS = Chemical Abstract Service.

2 Average of 3 samples, values listed are estimates.

25


Cmpd Compound CAS' Average2 Standard # Number (mglm3) Deviation

(mg/m3) 137

138

139

140

141

142

143

144

145

146

147

148

149

150

151

152

153

154

155

156

157

158

159

160

161

162

163

164

decane, 2,3,5-trimethyl- and others

2-undecene. 7-methyl-. cis=trans

cyclopentane, 1 -pentyl-Z-propyl-

cyclohexane, 2-butyl-I ,I ,3-trimethyl-

undecane. 5-ethyl-

naphthalene, decahydro-I ,6-dimethyl-

dimethyldeca'hydronaphthalene

cyclohexane, hexyl-

undecane, 2,6:dimethyl-

dodecane, 5-methyl-

dodecane. 4-methyl-

dodecane, 2-methyl-

undecane, 2.1 O-dimethyl-

dodecane, 4.6dimethyl

trimethyl-decahydronaphthalene

decane, 2,6,7-trimethyl-

dodecane, 4.6-dimethyl

trimethyldecahydronaphthalene

cyclopentane. I-butyl9-ethyl-

6-tridecene, 7-methyl-

5-undecene, 7-methyL. (2)-

3-tetradecene, (E)-

c8-cyclopentane

cl4-alkane

cl4-alkane

tetradecane

cl4-alkane

3.3,4,4-tetraethylhexane

621 99-51-3

54676-39-0

17453-94-0

1750-51-2

4292-75-5

17301-23-4

17453-93-9

6117-97-1

1560-97-0

17301-27-8

61 141 -72-8

62108-25-2

61 141-72-8

72993-32-9

24949428

74630-62-9

41446-68-8

629-59-4

0.23

0.055

0.023

0.80

0.098

0.10

0.076

0.67

0.21

0.21

0.58

0.72

0.34

1.2

0.14

1.2

1.1

0.12

0.073

0.48

0.037

0.24

0.13

0.14

0.23

0.84

0.029

0.027

0.06

0.048

0.040

0.01

0.013

0.04

0.068

0.06

0.04

0.03

0.02

0.63

0.59

2.1

0.01

2.0

2.0

0.11

0.069

0.41

0.064

0.41

0.11

0.12

0.20

0.55

0.050

0.047

31

WHC-SD-WM-ER421 REV. 2

Cmpd Compound CAS' Average2 Standard # Number (mg/m3) Deviation - (mg/m3)

165

166

167

168

169

170

171

172

173

1 74

175

176

177

178

179

180

181

182

183

184

185

186

187

188

189

190

191

192

undecane, 2,gdimethyl-

tridecane. 6-methyl

cyclohexane, 2.4diethyl-I -methyl-

tridecanenitrile

butane, 2qclohexyl-3-methyl-

tridecane, 3-methyl-

1 H-pyrrole, I-pentyl and others

c5-octyne


c7-cyclohexane



undecane. 3,8dimethyl-

cl4-alkene and others

dodecane, 3-methyl-

undecane, 2,8dimethyl-

mixture

tridecane. 3-methyl-

dodecane, 2,6,1 l-trimethyl-

mixture

decane, 2-methyl-

tetradecane

pentadecane

dodecane, 2,7,1 O-trimethyl-


cl5-alkane

dodecane. 2.6,l l-trimethyl-

alkane

17301-26-7

13287-21-3

61 142-70-9

629-60-7

641841-3

13287-21-3

26730-12-1

1560-96-9

17301-30-3

17312-57-1

17301-254

641 8-41 -3

31295-56-4

6975-98-0

629-59-4

629-62-9

74645-98-0

31295-56-4

0.24

0.38

0.19

0.030

0.055

0.079

0.032

0.046

0.59

1.1

0.91

1.3

0.021

0.068

0.63

0.021

0.071

0.24

3.3

0.041

0.043

4.1

1.2

0.48

0.40,

0.22

0.34

0.10

0.11

0.66

0.16

0.052

0.095

0.137

0.056

0.079

0.10

0.1

0.02

0.04

0.037

0.118

0.59

0.037

0.122

0.41

0.3

0.070

0.074

0.2

0.1

0.02

0.01

0.20

0.30

0.17

32


~

Standard CAS’ Average’ Cmpd Compound # Number Deviation

219

220

22 1

222

223

224

225

226

227

228

229

230

231

232

233

234

235

236

237

238

239

240

241

242

dodecane, 5.8-diethyl

hexadecane

pentadecane, 2,6,1 O-trimethyl- (non-pristan)

ester of alkenoic acid

1 -hexadecene


hexadecanoic acid

alkene and others

tetradecanoic acid

I-hexandecanol, acetate

benzenamine, N-phenyl-

pentadecane

pentadecane. 2.6.10,14-tetramethyl-

tetradecanoic acid

benzenesulfonamide, n-butyl-

Soctadecenoic acid (2)-

9-octadecenoic acid (2)-

14-pentadecenoic acid

tetradecanoic acid

9-hexadecenoic acid

hexadecanoic acid

eicosane

hexadecanoic acid, l-methylethyl ester

cyclohexadecane

24251-86-3

544-76-3

3892-00-0

629-73-2

17301-28-9

57-10-3

544-63-8

629-70-9

122-39-4

629-62-9

1921-70-6

544-63-8

3622-84-2

112-80-1

112-80-1

17351-34-7

544-63-8

2091-294

57-1 0-3

112-95-8

142-91-6

295-65-8

0.025

0.48

0.063

0.017

0.017

0.034

0.020

0.018

0.27

0.018

0.015

0.019

0.019

0.11

0.38

0.030

0.016

0.014

0.23

0.52

1.1

0.028

0.077

0.024

0.044

0.05

0.055

0.029

0.029

0.058

0.035

0.032

0.23

0.031

0.026

0.033

0.033

0.19

0.04

0.026

0.028

0.024

0.08

0.14

0.3

0.049

0.022

0.041

243 1 -hexadecanol 36653-82-4 0.039 0.067


I CAS = Chemical Abstract Service.

34


2 Average of 3, 250 ml TST samples, values listed are estimates.

35


Cmpd Compound #

CAS’ AveragG Standard Number (mglm’) Deviation

24

26

27

15

16

6

125

58

138

34

61

36

65

107

39

106

103

97

93

69

31

35

32

48

70

76

118

84

2-pentanol

2-pentano1, 2-methyl-

2-pentanone, 4-methyl-

2-butanone

2-butanol

2-propanol

2-undecene. 6-methyL. (E)-

2-heptanol

2-undecene, 7-methyl-. cis=trans

2-pentene. (E)-

2-heptanone, 4-methyl-

2-0ctanol


2-undecene, 2,5-dimethyC

2-heptanol

2-decene, 4-methyL. (2)-

2-nonanone

2-furanacetaldehyde, .alpha.-propyl-


2-octanol

2(3H)-furanone, dihydro-3.5dimethyl-

3-hexanone

3-pentano1, 2-methyl-

3-octanone

3-butene-2-01

3-hexene. 3-ethyl-2.5dimethyl-

3-undecene. 2-methyl-, (2)-

3-nonyne and others

6032-29-7

590-36-3

108-1 0-1

78-93-3

78-92-2

67-63-0

74630-61-0

543-49-7

646-04-8

61 37-06-0

123-96-6

928-68-7

49622-16-4

543-49-7

74630-30-1

821-556

31681 -26-2

108-10-1

123-96-6

51 45-01 -7

589-38-8

565-67-3

106-68-3

598-32-3

62338-08-3

74630-48-1

0.55

0.078

0.31

1.0

0.45

2.1

0.060

0.18

0.055

0.24

0.033

0.14

1 .o 0.030

0.092

0.043

0.29

0.14

0.23

0.27

0.17

0.30

0.051

0.052

0.67

0.093

0.065

0.024

0.28

0.135

0.11

1.7

0.45

1.9

0.105

0.01

0.048

0.41

0.058

0.24

0.2

0.053

0.159

0.074

0.05

0.12

0.39

0.07

0.30

0.06

0.089

0.090

0.37

0.160

0.061

0.041

37


Cmpd Compound #

CAS’ AverageZ Standard Number (mdm’) Deviation

233

59

4

169

189

161

163

178

160

190

203

115

172

174

159

3

18

128

242

25

44

45

85

89

104

114

132

140

benzenesulfonamide. n-butyl-

bicyclo[2.2. llheptane

butane, 2-methyl-

butane, 2-cyclohexyl-3-methyl-


cl4-alkane

cl4-alkane


cl4-alkane

cl5-alkane

cl6-alkane

c4-heptadiene

c5-octyne

c7cyclohexane

c8-cyclopentane

cyclobutane

cyclobutane, ethyl-

cyclododecane

cyclohexadecane

cyclohexane, methyl-

cyclohexahe, ethyl-

cyclohexane, 1.1.3-trimethyl-

cyclohexane, butyl-

cyclohexane, cyclopropyl-

cyclohexane, 1 -ethyl-Z-propyl-

cyclohexane, pentyl-

cyclohexane, 1 -methyl-.l-(l-methylbutyl)-

cyclohexane, 2-butyI-1,l .btrimethyl-

3622-84-2

279-23-2

78-784

287-23-0

4806-61-5

294-62-2

2 9 5 -6 5 - 8

108-87-2

1678-91-7

3073-66-3

1678-93-9

32669-86-6

62238-33-9

4292-92-6

5441 1-00-6

54676-39-0

0.38

0.19

3.1

0.055

0.40

0.23

0.029

0.068

0.14

0.22

0.11

0.29

0.046

1.1

0.13

0.15

0.19

0.14

0.024

0.51

0.24

0.67

0.23

0.061

0.11

0.14

0.13

0.80

0.04

0.03

0.8

0.095

0.01

0.20

0.050

0.118

0.12

0.20

0.18

0.50

0.079

0.1

0.11

0.26

0.33

0.24

0.041

0.24

0.09

0.46

0.07

0.053

0.03

0.23

0.02

0.01

39


Cmpd Compound #

CAS’ AveragG Standard (mslm3) Deviation Number

144

167

210

116

9

72

73

75

77

78

86

87

113

139

155

2

5

7

17

130

71

91

92

96

123

126

cyclohexane, hexyl-

cyclohexane, 2,4diethyl-I-methyl-

cyclohexane, 1 -(cyclohexylmethyl)-2-methyl-, cis-

cyclooctane, ethenyl-

cyclopentane

Cyclopentane, 1 ,2-dimethyl-3-(1 -methylethyl)-

cyclopentane, 1 -methyl-3-(2-methylpropyl)-

Cyclopentane, 1.2-dimethyl-3-( I-methylethyl)-

cyclopentane, 2-isopropyl-I .3dimethyl-

cyclopentane, (I-methylbuty1)-

cyclopentane, 2-isopropyl-I ,3-dimethyl-

cyclopentane, 2-isopropyl-I ,3-dimethyC

cyclopentane, I-butyl-2-propyl-

cyclopentane, I-pentyl-2-propyl-

cyclopentane, I-butyl-2-ethyl-

cyclopropane, 1 ,l-dimethyl

cyclopropane, ethyl-


cyclopropane, propyl-

cyclotetradecane

decadienal

decane, 5-methyl-

decane, 4-methyl-

decane, 3-methyl-

decane, 2.3,8-trimethyC

decane, 2,6.7-trimethyl-

4292-75-5

61 142-70-9

54824-04-3

61 142-41 -4

287-92-3

489-20-3

29053-04-1

489-20-3

32281-85-9

4737-43-3

32281-85-9

32281-85-9

621 99-50-2

62199-51 -3

72993-32-9

1630-94-0

1 191 -96-4

1191-964

2415-72-7

295-17-0

131 51-354

2847-72-5

13151-34-3

62238-14-6

62108-25-2

0.67

0.19

0.037

0.096

0.43

0.13

0.037

0.20

0.092

0.079

0.061

0.030

0.052

0.023

0.073

0.17

4.0

0.67

0.53

0.27

0.099

0.25

0.22

0.43

0.26

0.18

0.06

0.16

0.064

0.017

0.38

0.11

0.064

0.17

0.102

0.137

0.105

0.051

0.091

0.040

0.069

0.29

4.9

0.15

0.28

0.23

0.006

0.03

0.04

0.22

0.08

0.17

40


Cmpd Compound #

CAS’ Average’ Standard Number (m!a/m3) Deviation

127

137

1 52

185

129

143

146

147

148

150

153

179

183

188

191

198

201

213

219

212

240

222

99

20

30

21 1

43

49


decane, 2,3,5-trimethyl- and others


decane, 2-methyl-

dimethyldecahydronaphthalene

dimethyldecahydronaphthalene

dodecane. 5-methyl-

dodecane, 4-methyl-

dodecane. 2-methyl-

dodecane, 4,6dimethyl-

dodecane, 4,6-dimethyl-

dodecane, 3-methyl-

dodecane, 2.6.1 l-trimethyl-

dodecane, 2.7,l O-trimethyl-

dodecane, 2,6,1 l-trimethyl-

dodecane, 3-methyl-

dodecane. 2-methyl-8-propyl

dodecane. 2-methyl-8-propyl-

dodecane, 5,Ediethyl-

eicosane

eicosane

ester of alkenoic acid

formic acid, 2,6-dimethyI-5-hepten-2-01 ester

furan, tetrahydro-

furan, 2,5-dihydro-

heptadecane, 2,6,10,14-tetramethyl-

heptane, 2.6-dimethyl-

heptane, 2,3-dimethyl-

62238-12-4

62108-25-2

6975-98-0

17453-93-9

61 17-97-1

1560-97-0

61141-72-8

61 141 -72-8

17312-57-1

31295-56-4

74645-98-0

31295-56-4

1731 2-57-1

55045-07-3

55045-07-3

24251-86-3

1 12-95-8

11 2-95-8

109-99-9

1708-29-8

18344-37-1

1072-05-5

3074-71-3

0.18

0.23

1.2

0.043

0.10

0.076

0.21

0.58

0.72

1.2

1.1

0.63

3.3

0.48

0.34

0.15

1.7

0.14

0.025

0.11

0.028

0.017

0.10

2.0

0.75

0.015

0.29

0.040

0.03

0.06

2.0

0.074

0.18

0.068

0.03

0.02

0.63

2.1

2.0

0.59

0.3

0.02

0.30

0.26

1.5

0.12

0.044

0.19

0.049

0.029

0.02

0.4

1.30

0.026

0.09

0.070

41


Cmpd Compound CAS’ Averagez Standard # Number (mg/m3) Deviation

(mglm3)

62

204

217

220

225

239

241

33

22

29

47

53

109

38

181

184

216

95

111

119

131

142

66

68

79

80

81

200

heptane, 4-(l-methylethyl)-

hexadecane, 3-methyl-

hexadecane. 2-methyl-

hexadecane

hexadecanoic acid

hexadecanoic acid

hexadecanoic acid, I-methylethyl ester

hexanal, 3-methyl-

hexane, 2-methyl-

hexane, 2,3dimethyl-

hexane, 3-methoxy-

hexane, 2,2,3-trimethyl and d-benzene

methyldecahydronaphthalene

methylamine, N-(I-methylbutylidene)-

mixture

mixture

mixture

naphthalene, decahydro-, trans-

naphthalene, decahydro-2-methyl-


naphthalene, decahydro-I ,6dimethyl-


nonane, 4-methyl-

nonane. 2-methyl-

nonane, 2.6dimethyl-

nonane, 3,7-dimethyl-

nonane. 3.7-dimethyl-

nonane, 5-butyl-

52896-87-4

6418-436

1560-92-5

544-76-3

57-1 0-3

57-1 0-3

142-91 -6

19269-28-4

591-76-4

584-94-1

54658-01-4

22431-09-0

493-02-7

2958-76-1

2958-76-1

1750-51 -2

1750-51-2

17301-94-9

871-83-0

17302-28-2

17302-32-8

17302-32-8

17312-63-9

0.028

0.15

0.044

0.48

0.020

1.1

0.077

0.18

0.61

0.70

0.24

0.54

0.10

0.39

0.071

0.041

0.087

0.18

0.35

0.99

0.10

0.10

0.11

0.042

0.75

0.028

0.048

0.1 1

0.048

0.25

0.039

0.05

0.035

0.3

0.022

0.30

0.20

0.67

0.14

0.54

0.01

0.41

0.122

0.070

0.112

0.17

0.32

0.91

0.18

0.04

0.10

0.072

0.04

0.049

0.082

0.19

42


Cmpd Compound #

CAS‘ Average2 Standard Number (malm3) Deviation

50

51

60

94

187

193

208

215

22 1

230

231

10

12

74

37

40

162

186

199

214

227

232

237

166

170

173

175

176

octane, 2-methyl- and &-benzene

octane, 3-methyl- and c2-benzene

octane, 2.6dimethyl-

octane, 2,3.3-trimethyl-

pentadecane

pentadecane

pentadecane

pentadecane. 8-hexyl-

pentadecane, 2,6,1 O-trimethyl- (non-pristan)

pentadecane

pentadecane. 2,6,10,14-tetramethyl-

pentane, 2-methyl-

pentane, 3-methyl-

phenol

propane, 2,Z-oxybis-

tetrachloroethene

tetradecane

tetradecane

tetradecane

tetradecane. 2,6,1 O-trimethyl-

tetradecanoic acid

tetradecanoic acid

tetradecanoic acid






3221-61-2

2216-33-3

2051-30-1

62016-30-2

629-62-9

629-62-9

629-62-9

13475-75-7

3892-00-0

629-62-9

192 1-70-6

107-83-5

96-14-0

108-95-2

108-20-3

127-184

629-594

629-59-4

629-59-4

14905-56-7

544-63-8

544-63-8

544-63-8

13287-21-3

641 8-41 -3

13287-21-3

26730-12-1

1560-96-9

0.17

0.17

0.11

0.47

1.2

0.33

2.5

0.024

0.063

0.019

0.019

6.9

1.2

0.029

0.15

0.26

0.84

4.1

0.11

0.14

0.27

0.11

0.23

0.38

0.079

0.59

0.91

1.3

0.18

0.29

0.19

0.42

0.1

0.57

0.2

0.041

0.055

0.033

0.033

1.6

0.3

0.050

0.25

0.45

0.55

0.2

0.19

0.11

0.23

0.19

0.08

0.66

0.137

0.10

0.02

0.04

43


Average2 Standard # Number (mg/m3) Deviation

Cmpd Compound CAS’

(mslmL 182

195

197

168

151

154

88

108

110

112

121

122

124

134

135

136

141

145

149

165

177

180

205

224


tridecane, 3ethyl-

tridecane, 5-propyl-

tridecanenitrile


trimethyl-decahydronaphthalene

UndecaW, 5-mthyl-

undecane. 5-methyl-

undecane, 2,8-dimethyC


undecane, 4-methyl-

undecane. 2-methyl-

undecane, 3-methyl-

undecane, 2,4-dimethyl-



undecane, 5-ethyl-


undecane, 2,lOdimethyl-



undecane, 2.8-dimethyl-


undecane, 3,6-dimethyC

641841-3

13286-73-2

55045-1 1-9

629-60-7

1632-70-8

1632-70-8

17301-25-6

17301-25-6

2980-69-0

7045-71-8

100243-3

17312-80-0

17301-23-4

17301-29-0

17453-94-0

17301-234

17301 -27-8

17301-26-7

17301-30-3

17301-254

17312-83-3

17301-28-9

0.24

0.35

1.2

0.030

0.14

0.12

0.047

0.67

0.40

0.43

0.52

1.1

0.60

0.048

2.0

0.20

0.098

0.21

0.34

0.24

0.021

0.021

0.11

0.034

0.41

0.61

1.4

0.052

0.01

0.11

0.081

0.24

0.49

0.39

0.11

0.3

0.13

0.042

0.03

0.02

0.013

0.04

0.59

0.11

0.037

0.037

0.19

0.058

55 unknown 0.042 0.073


1 CAS = Chemical Abstract Service. 2 Average of 3, 250 ml TST samples, values listed are estimates.

44


Table 4-9 Tank BY407 Tentatively Identified Organic Compounds in TST Samples

Sorted by Estimated Concentration - Analyses by Oak Ridge National Laboratory

4

Cmpd Compound CAS’ Average’ Standard # Number (mglm3) Deviation

(mglm3)

10

186

5

183

4

208

6

20

135

201

176

12

197

187

150

152

174

153

239

122

15

11

1

65

119

120

pentane, 2-methyl-

tetradecane


dodecane. 2,6,1 l-trimethyl-

butane, 2-methyl-

pentadecane

2-propanol

furan, tetrahydro-

undecane. 2.6dimethyl-

dodecane. 2-methyl-8-propyl-


pentane, 3-methyl-

tridecane, 5-propyl-

pentadecane

dodecane, 4,64imethyl-


c7-cyclohexane

dodecane, 4,6-dimethyl-

hexadecanoic acid

undecane. 2-methyl-

2-butanone

I-propene, 2duoro-

I-propene, 2-methyl-

2-heptanone. 6-methyl-


6methylundecane

107-83-5

629-59-4

1191-96-4

31295-56-4

78-78-4

629-62-9

67-63-0

109-99-9

17301-23-4

55045-07-3

1560-96-9

96-14-0

55045-1 1-9

629-62-9

61141-72-8

62108-25-2

61 141-72-8

57-1 0-3

7045-71-8

70-93-3

1184-60-7

115-1 1-7

928-68-7

2958-76-1

17302-33-9

6.9

4.1

4.0

3.3

3.1

2.5

2.1

2.0

2.0

1.7

1.3

1.2

1.2

1.2

1.2

1.2

1.1

1.1

1.1

1.1

1.0

1 .o 1 .o 1.0

0.99

0.97

1.6

0.2

4.9

0.3

0.8

0.2

1.9

0.4

0.03

1.5

0.04

0.3

1.4

0.1

2.1

2.0

0.1

2.0

0.3

0.3

1.7

0.3

0.1

0.2

0.91

0.27

45

WHCSD-WM-ER421 REV. 2

Cmpd Compound CAS‘ Average2 Standard # Number (mglm’) Deviation

(mg/m3) - ~ ~

175

162

140

30

79

148

29

8

7

144

45

108

70

179

22

14

124

173

147

56

24

53

17

121

238

25

188

156

tridecane, 4lnethyl-

tetradecane

cyclohexane, 2-butyl-I ,I ,3-trimethyl-

furan, 2,5dihydro

nonane. 2.6dimethyl-

dodecane, 2-methyl-

hexane, 2.3dimethyC

I-hexene


cyclohexane, hexyl-

cyclohexane, 1 .I ,3-trimethyl-

undecane, 5-methyl-

3-butene-2-01

dodecane, 3-methyl-

hexane, 2-methyl-

I-hexene

undecane, 3-methyl-


dodecane, 4-methyl-

3 -he p t a n o n e

2-pentanol

hexane, 2.2,3-trimethyl- and d-benzene

cyclopropane, propyl-

undecane, 4-methyl-

9-hexadecenoic acid

cyclohexane, methyl-

dodecane, 2.7,l O-trimethyl-

6-tridecene, 7-methyl-

26730-12-1

629-594

54676-39-0

1708-29-8

17302-28-2

1560-97-0

584-94-1

59241-6

1191-964

4292-75-5

3073-66-3

1632-70-8

598-32-3

17312-57-1

591-764

59241-6

100243-3

13287-21-3

6117-97-1

106-35-4

6032-29-7

2415-72-7

2 9 8 0 -6 9 - 0

2091-294

108-87-2

74645-98-0

24949-42-6

0.91

0.84

0.80

0.75

0.75

0.72

0.70

0.69

0.67

0.67

0.67

0.67

0.67

0.63

0.61

0.61

0.60

0.59

0.58

0.57

0.55

0.54

0.53

0.52

0.52

0.51

0.48

0.48

0.02

0.55

0.01

1.30

0.04

0.63

0.67

0.21

0.15

0.06

0.46

0.24

0.37

0.59

0.20

0.16

0.13

0.10

0.02

0.07

0.28

0.54

0.28

0.11

0.14

0.24

0.02

0.41

46


Cmpd Compound #

CAS’ Average2 Standard Number (mglm’) Deviation

220

94

16

96

112

9

189

110

38

233

166

102

195

111

46

149

191

193

57

27

35

103

19

115

43

69

227

130

hexadecane

octane, 2,3,3-trimethyl-

2-butanol

decane, 3-methyl-


cyclopentane


undecane. 2.8dimethyl-

methylamine, N-(I-methylbutylidene)-

benzenesulfonamide, n-butyl-


5-undecene

tridecane. 3-ethyl-


1 -hexene. 3.4dimethyl-

undecane. 2, l O-dimethyl-

dodecane. 2,6,1 l-trimethyl-

pentadecane

3-heptanol


3-hexanone

2-nonanone

1 -pentene-2-methyl-

c4-heptadiene

heptane, 2,bdimethyl-

Z-octanol

tetradecanoic acid

cyclotetradecane

544-76-3

6201 6-30-2

78-92-2

13151-34-3

17301-25-6

287-92-3

17301-25-6

22431-09-0

3622-84-2

13287-21-3

4941-53-1

13286-73-2

2958-76-1

16745-94-1

17301 -27-8

31295-56-4

629-62-9

589-82-2

108-10-1

589-38-8

821-55-6

763-29-1

1072-05-5

123-96-6

544-63-8

295-17-0

0.48

0.47

0.45

0.43

0.43

0.43

0.40

0.40

0.39

0.38

0.38

0.36

0.35

0.35

0.34

0.34

0.34

0.33

0.31

0.31

0.30

0.29

0.29

0.29

0.29

0.27

0.27

0.27

0.05

0.42

0.45

0.22

0.39

0.38

0.01

0.49

0.41

0.04

0.66

0.15

0.61

0.32

0.27

0.59

0.30

0.57

0.22

0.11

0.06

0.05

0.50

0.50

0.09

0.07

0.23

0.23

47


Cmpd Compound #

CAS’ AverageZ Standard Number (malm3) Deviation

18

126

95

127

58

33

2

31

50

51

101

3

204

37

198

21

114

202

151

128

36

160

97

214

213

209

132

cyclobutane, ethyl-

decane, 2,6.7-trimethyl-

naphthalene, decahydro-, trans-


2-heptanol

hexanal, 3-methyl-

cyclopropane, 1 .I-dimethyl-

2(3H)-furanone, dihydro-3,5-dimethyl-

octane, 2-methyl- and &benzene

octane, 3-methyl- and &benzene

4-hepten-3-one. 5-ethyl-2,4-dimethyl-

cyclobutane


propane, 2,T-oxybis-

dodecane, 3-methyl-

1,3-pentadiene, 2-methyl-

cyclohexane, pentyl-

alkane


cyclododecane

2octanol

cl4-alkane

2-furanacetaldehyde, .alpha.-propyl-

tetradecane, 2.6.1 O-trimethyl-

dodecane, 2-methyl-8-propyl-

1 h-l.2,4-triazole, l-ethyl-

cyclohexane, l-methyl-4-(1 -methylbutyl)-

4806-61-5

62108-25-2

493-02-7

62238-12-4

543-49-7

19269-28-4

1630-94-0

5145-01 -7

3221-61-2

2216-33-3

22319-29-5

287-23-0

6418-43-5

108-20-3

1731 2-57-1

1 1 18-58-7

4292-92-6

294-62-2

123-96-6

31681-26-2

14905-56-7

55045-07-3

16778-70-4

5441 1-00-6

0.19

0.18

0.18

0.18

0.18

0.18

0.17

0.17

0.17

0.17

0.16

0.15

0.15

0.15

0.15

0.14

0.14

0.14

0.14

0.14

0.14

0.14

0.14

0.14

0.14

0.13

0.13

0.33

0.17

0.17

0.03

0.01

0.30

0.29

0.30

0.18

0.29

0.15

0.26

0.25

0.25

0.26

0.24

0.23

0.24

0.01

0.24

0.24

0.12

0.12

0.11

0.12

0.09

0.02

49


Cmpd Compound #

CAS’ AverageZ Standard Number (mglm’) Deviation

72

54

159

105

13

154

203

60

66

199

200

104

205

232

196

194

212

192

142

129

131

109

71

141

116

76

39

77

Cyclopentane, 1 ,Z-dimethyld-( I-methylethyl)-

4-heptanone

c8qclopentane

5-undecene

I-pentene. 2-methyl-


cl6-alkane

octane, 2,6-dimethyl-

nonane, 4-methyl-

tetradecane

nonane, 5-butyl-

cyclohexane, I-ethyl-2-propyl-


tetradecanoic acid

l-octanol, 2-butyl-

1 -pentadecene

eicosane

alkane


dimethyl-decahydronaphthalene

naphthalene, decahydro-l,6-dimethyl-

rnethyldecahydronaphthalene

decadienal

undecane, 5ethyl-

cyclooctane, ethenyl-

3-hexene, 3ethyl-2.5-dimethyl-

2-heptanol

cyclopentane, 2-isopropyl-l,3-dimethyl-

50

489-20-3

123-19-3

4941-53-1

763-29-1

2051-30-1

17301-94-9

629-594

17312-63-9

62238-33-9

17312-83-3

544-63-8

3913-02-8

13360-61-7

112-95-8

1750-51-2

1750-51-2

17453-94-0

61142-41-4

62338-08-3

543-49-7

32281-85-9

0.13

0.13

0.13

0.12

0.12

0.12

0.11

0.11

0.11

0.1 1

0.11

0.11

0.11

0.11

0.11

0.11

0.11

0.10

0.10

0.10

0.10

0.10

0.099

0.098

0.096

0.093

0.092

0.092

0.11

0.01

0.11

0.03

0.21

0.11

0.18

0.19

0.10

0.19

0.19

0.03

0.19

0.19

0.18

0.19

0.19

0.17

0.04

0.18

0.18

0.01

0.006

0.013

0.017

0.160

0.159

0.102

WHC-SD-WM-ER-421 RW. 2

~

Cmpd Compound CAS' Average2 Standard # Number (mg/m3) Deviation

88

1 72

217

185

106

55

68

184

67

49

243

157

210

73

82

224

61

87

107

168

234

163

74

218

80

240

62

undecane, Smethyl-

c5-octyne


decane, 2-methyl-

2-decene, 4-methyl-, (2)-

unknown

nonane, 2-methyl-

mixture

1,1,2.3-tetramethylcyclohexane

heptane, 2,3dimethyl-

1 -hexadecanol

5-undecene, 7-methyl-, (Z)-

cyclohexane, 1 -(cyclohexylmethyl)-2-methyl-, cis-

cyclopentane, 1 -methyC3-(2-methylpropyl)-

I-hexanol, 2-ethyl

undecane. 3.6dimethyC


cyclopentane. 2-isopropyl-I ,3-dimethyC

2-undecene, 2,5-dimethyl-

tridecanenitrile

9-octadecenoic acid (Z)-

cl4-alkane

phenol

alkane

nonane, 3,7dimethyl-

eicosane

heptane, 44 1 -methylethyl)-

1632-70-8

1560-92-5

6975-98-0

74630-30-1

871-83-0

6783-92-2

3074-71-3

36653-82-4

74630-62-9

54824-04-3

29053-04-1

104-76-7

17301-28-9

61 37-06-0

32281-85-9

49622-16-4

629-60-7

112-80-1

108-95-2

17302-32-8

112-95-8

52896-87-4

0.047

0.046

0.044

0.043

0.043

0.042

0.042

0.041

0.27

0.040

0.039

0.037

0.037

0.037

0.035

0.034

0.033

0.030

0.030

0.030

0.030

0.029

0.029

0.029

0.028

0.028

0.028

0.081

0.079

0.039

0.074

0.074

0.073

0.072

0.070

0.04

0.070

0.067

0.064

0.064

0.064

0.061

0.058

0.058

0.051

0.053

0.052

0.026

0.050

0.050

0.050

0.049

0.049

0.048

52

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