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Materials Sci ence & Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf Lecture «Advanced Materials and Structures» Institute of Metals Research, Shenyang, October 21-23, 2013

Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

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Page 1: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y1

Processing Materials by High Power Laser M. Roth

Empa Duebendorf

Lecture «Advanced Materials and Structures» Institute of Metals Research, Shenyang, October 21-23, 2013

Page 2: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y2

Laser Material Processing

Introduction - application of lasers - principle of laser - laser-processing parameters Surface treatment by laser - martensitic hardening - remelting/alloying/cladding - amorphous metals Laser welding Laser cutting Laser drilling Repair of turbine blades

Page 3: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y3

Laser-principle - active medium - pumping source - resonator

Light beam - equal wave length - coherent - high density of radiation

Laser Principle

mirror partial mirror

active medium

pumping source

Laser light beam

Resonator

Page 4: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y4

Induced emission

Laser Principle

Events in a laser resonator

Page 5: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y5

Laser process: CO2- gas

Laser Principle

Gas-mixture: 5% CO2 15% N2 80% He

Page 6: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y6

CO2- cross flow laser

Laser Principle

Gas-mixture: 5% CO2 15% N2 80% He

Page 7: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y7

Laser beam: Transversale Electromagnetic Mode (TEM)

Laser Principle

Page 8: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y8

CO2-Gaslaser - power: 0.5 – 18 kW - wave-length: 10.6 µm - continuous / pulsed - axial / transverse flow - beam diameter: 15 – 60 mm - TEM – mode: Gauss, multi-mode - focus-diameter: 0.2 – 0.85 mm - power density: 106-108 W/cm2

Laser Material Processing

Page 9: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y9

Laser processing parameters: interaction time and power density

Laser Material Processing

Hardening

Welding

Cutting

Cladding

Glazing

Interaction time

Pow

er d

ensi

ty

Page 10: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y10

Heating up: Martensitic hardening Remelting: Remelt hardening Alloying/Cladding Welding Evaporating: Drilling / Cutting Material removal

Laser Material Processing

Hardening

Welding

Cutting

Cladding

Glazing

Interaction time

Pow

er d

ensi

ty

Page 11: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y11

Surface martensitic hardening by laser

Goal: high surface hardness against wear and erosion high toughness in the base material Materials: carbon steels, low alloy steels and tool steels, cast iron Process: - heating above austenite forming temperature - „holding-time“ long enough: diffusion of carbon - quenching to form martensite: critical cooling rate Advantage of laser hardening: - control of hardening depth - localized hardening - low distortion - fine grained microstructure, small tempering zone Martensitic hardening: typical laser processing parameters: - power: 0.5 – 3 kW - laser track: 4 – 10 mm - rate: 0.5 – 1 m/min - interaction time: 0.3 – 1 s - power density: 2 x 103 – 104 W/cm2

Page 12: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y12

Surface martensitic hardening by laser

Hardening of low-pressure steam turbine blades Leading edge is subjected to water drop erosion due to first condensation of steam

Page 13: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y13

Surface martensitic hardening by laser

Hardening of low-pressure steam turbine blades Optical system for constant energy distribution of the laser beam

Page 14: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y14

Surface martensitic hardening by laser

Hardening of low-pressure steam turbine blades Microsection through laser track Material: X22CrMoV 12 1

Distance from Surface

Har

dnes

s H

V0.1

Page 15: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y15

Surface martensitic hardening by laser Hardening of low-pressure steam turbine blades Microsection through laser track: SEM-images

Distance from surface

Har

dnes

s H

V0.1

Page 16: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y16

Surface martensitic hardening by laser Hardening of low-pressure steam turbine blades Microsection through laser track: TEM-images

Distance from surface

Har

dnes

s H

V0.1

Page 17: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y17

Surface martensitic hardening by laser

Hardening of low-pressure steam turbine blades Microsection through overlapping laser tracks

Page 18: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y18

Surface martensitic hardening by laser

Examples for industrial applications Cylinder liners of Diesel engines

Page 19: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y19

Surface martensitic hardening by laser

Examples for industrial applications Steering rack

Page 20: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y20

Surface martensitic hardening by laser

Examples for industrial applications Ring groove in grey iron piston Crankshaft

Page 21: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y21

Laser- surface remelting Goal: Increase resistance against: - wear - friction - erosion - fretting corrosion / wet corrosion / hot gas corrosion Materials: steels, cast steels, Ni-base alloys, Ti-, Al-alloys, …… Process: - remelting of the surface - high density of power - high cooling rates Properties of surface layer: - fine grain zone, fine dendrites - supersaturated solid solutioned crystal - metastable phases - suppression of transformations

Page 22: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y22

Laser- surface remelting

Surface remelting of Ni-base superalloy:

Page 23: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y23

Laser- surface remelting

Surface remelting of 12%-Cr-steel:

Page 24: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y24

Laser-alloying / Laser-cladding

Materials: steels, cast iron, Ni-, Ti-, Al-alloys….. Alloying elements: Cr, WC, TiC, … gas alloying: C, N,… Coatings: MeCrAlY (Me = Ni, Co), stellite, ….. Process: - application of alloying elements - remelting of the surface - injection of powder in the laser beam Properties: - good adhesion - low porosity - dissolution of oxide particles - small interdiffusion zone

Page 25: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y25

Laser-alloying / Laser-cladding Process: - application of alloying elements - remelting of the surface - Cladding: injection of powder into the laser beam

Source: IWS Dresden/Germany

Page 26: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y26

Laser-cladding Cladding: injection of powder in the laser beam Stellite on carbon steel

Source: Sulzer/Switzerland

Page 27: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y27

Laser-cladding Cladding: injection of powder in the laser beam Stellite on carbon steel

Source: Sulzer/Switzerland

Page 28: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y28

Laser-cladding

Cladding: injection of powder in the laser beam Stellite on carbon steel (austenitic steel) EPMA: line-scan for Co, Cr

Source: Sulzer/Switzerland

Page 29: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y29

Laser-welding

Deep-penetration mode Key hole: vapor channel inside molten pool

Page 30: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y30

Laser-welding

Deep-penetration mode Key hole: vapor channel inside molten pool Welding of Ni-base superalloy

Page 31: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y31

Laser-welding

Deep-penetration mode Welding of pressure sensor Ferrite-Austenite weld Exact positioning!

Page 32: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y32

Removal of material by horizontal gas flow necessary!

Laser Cutting

Hardening

Welding

Cutting

Cladding

Glazing

Interaction time

Pow

er d

ensi

ty

Page 33: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y33

Laser-cutting

High-speed cutting of sheets from ferritic steel

Processing time: 40 sec Source: Bystronic/Switzerland

Page 34: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y34

Laser-cutting

High-speed cutting of sheets from ferritic steel

Processing time: 50 sec Source: Bystronic/Switzerland

Page 35: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y35

Laser-cutting

Combination of stamping and laser cutting

Page 36: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y36

Laser-drilling

Laser drilling of cooling holes in turbine blades Nd-YAG Laser is applied

Page 37: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y37

Repair of turbine blades Blade tip restoration by laser cladding

Source: Sulzer/Switzerland

Page 38: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y38

Repair of turbine blades Contour scan of blade tip geometry

Source: Sulzer/Switzerland

Precise restoration by laser cladding

Page 39: Processing Materials by High Power Laser M. Roth Empa ... · Materials Science &Technolog y 1 Processing Materials by High Power Laser M. Roth Empa Duebendorf . Lecture «Advanced

Materials Sci ence & Technolog y39

Repair of turbine blades

Source: Sulzer/Switzerland

Laser cladding for abrasive blade tip protection with chromised SiC-particles