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Materials Sci ence & Technolog y1
Processing Materials by High Power Laser M. Roth
Empa Duebendorf
Lecture «Advanced Materials and Structures» Institute of Metals Research, Shenyang, October 21-23, 2013
Materials Sci ence & Technolog y2
Laser Material Processing
Introduction - application of lasers - principle of laser - laser-processing parameters Surface treatment by laser - martensitic hardening - remelting/alloying/cladding - amorphous metals Laser welding Laser cutting Laser drilling Repair of turbine blades
Materials Sci ence & Technolog y3
Laser-principle - active medium - pumping source - resonator
Light beam - equal wave length - coherent - high density of radiation
Laser Principle
mirror partial mirror
active medium
pumping source
Laser light beam
Resonator
Materials Sci ence & Technolog y4
Induced emission
Laser Principle
Events in a laser resonator
Materials Sci ence & Technolog y5
Laser process: CO2- gas
Laser Principle
Gas-mixture: 5% CO2 15% N2 80% He
Materials Sci ence & Technolog y6
CO2- cross flow laser
Laser Principle
Gas-mixture: 5% CO2 15% N2 80% He
Materials Sci ence & Technolog y7
Laser beam: Transversale Electromagnetic Mode (TEM)
Laser Principle
Materials Sci ence & Technolog y8
CO2-Gaslaser - power: 0.5 – 18 kW - wave-length: 10.6 µm - continuous / pulsed - axial / transverse flow - beam diameter: 15 – 60 mm - TEM – mode: Gauss, multi-mode - focus-diameter: 0.2 – 0.85 mm - power density: 106-108 W/cm2
Laser Material Processing
Materials Sci ence & Technolog y9
Laser processing parameters: interaction time and power density
Laser Material Processing
Hardening
Welding
Cutting
Cladding
Glazing
Interaction time
Pow
er d
ensi
ty
Materials Sci ence & Technolog y10
Heating up: Martensitic hardening Remelting: Remelt hardening Alloying/Cladding Welding Evaporating: Drilling / Cutting Material removal
Laser Material Processing
Hardening
Welding
Cutting
Cladding
Glazing
Interaction time
Pow
er d
ensi
ty
Materials Sci ence & Technolog y11
Surface martensitic hardening by laser
Goal: high surface hardness against wear and erosion high toughness in the base material Materials: carbon steels, low alloy steels and tool steels, cast iron Process: - heating above austenite forming temperature - „holding-time“ long enough: diffusion of carbon - quenching to form martensite: critical cooling rate Advantage of laser hardening: - control of hardening depth - localized hardening - low distortion - fine grained microstructure, small tempering zone Martensitic hardening: typical laser processing parameters: - power: 0.5 – 3 kW - laser track: 4 – 10 mm - rate: 0.5 – 1 m/min - interaction time: 0.3 – 1 s - power density: 2 x 103 – 104 W/cm2
Materials Sci ence & Technolog y12
Surface martensitic hardening by laser
Hardening of low-pressure steam turbine blades Leading edge is subjected to water drop erosion due to first condensation of steam
Materials Sci ence & Technolog y13
Surface martensitic hardening by laser
Hardening of low-pressure steam turbine blades Optical system for constant energy distribution of the laser beam
Materials Sci ence & Technolog y14
Surface martensitic hardening by laser
Hardening of low-pressure steam turbine blades Microsection through laser track Material: X22CrMoV 12 1
Distance from Surface
Har
dnes
s H
V0.1
Materials Sci ence & Technolog y15
Surface martensitic hardening by laser Hardening of low-pressure steam turbine blades Microsection through laser track: SEM-images
Distance from surface
Har
dnes
s H
V0.1
Materials Sci ence & Technolog y16
Surface martensitic hardening by laser Hardening of low-pressure steam turbine blades Microsection through laser track: TEM-images
Distance from surface
Har
dnes
s H
V0.1
Materials Sci ence & Technolog y17
Surface martensitic hardening by laser
Hardening of low-pressure steam turbine blades Microsection through overlapping laser tracks
Materials Sci ence & Technolog y18
Surface martensitic hardening by laser
Examples for industrial applications Cylinder liners of Diesel engines
Materials Sci ence & Technolog y19
Surface martensitic hardening by laser
Examples for industrial applications Steering rack
Materials Sci ence & Technolog y20
Surface martensitic hardening by laser
Examples for industrial applications Ring groove in grey iron piston Crankshaft
Materials Sci ence & Technolog y21
Laser- surface remelting Goal: Increase resistance against: - wear - friction - erosion - fretting corrosion / wet corrosion / hot gas corrosion Materials: steels, cast steels, Ni-base alloys, Ti-, Al-alloys, …… Process: - remelting of the surface - high density of power - high cooling rates Properties of surface layer: - fine grain zone, fine dendrites - supersaturated solid solutioned crystal - metastable phases - suppression of transformations
Materials Sci ence & Technolog y22
Laser- surface remelting
Surface remelting of Ni-base superalloy:
Materials Sci ence & Technolog y23
Laser- surface remelting
Surface remelting of 12%-Cr-steel:
Materials Sci ence & Technolog y24
Laser-alloying / Laser-cladding
Materials: steels, cast iron, Ni-, Ti-, Al-alloys….. Alloying elements: Cr, WC, TiC, … gas alloying: C, N,… Coatings: MeCrAlY (Me = Ni, Co), stellite, ….. Process: - application of alloying elements - remelting of the surface - injection of powder in the laser beam Properties: - good adhesion - low porosity - dissolution of oxide particles - small interdiffusion zone
Materials Sci ence & Technolog y25
Laser-alloying / Laser-cladding Process: - application of alloying elements - remelting of the surface - Cladding: injection of powder into the laser beam
Source: IWS Dresden/Germany
Materials Sci ence & Technolog y26
Laser-cladding Cladding: injection of powder in the laser beam Stellite on carbon steel
Source: Sulzer/Switzerland
Materials Sci ence & Technolog y27
Laser-cladding Cladding: injection of powder in the laser beam Stellite on carbon steel
Source: Sulzer/Switzerland
Materials Sci ence & Technolog y28
Laser-cladding
Cladding: injection of powder in the laser beam Stellite on carbon steel (austenitic steel) EPMA: line-scan for Co, Cr
Source: Sulzer/Switzerland
Materials Sci ence & Technolog y29
Laser-welding
Deep-penetration mode Key hole: vapor channel inside molten pool
Materials Sci ence & Technolog y30
Laser-welding
Deep-penetration mode Key hole: vapor channel inside molten pool Welding of Ni-base superalloy
Materials Sci ence & Technolog y31
Laser-welding
Deep-penetration mode Welding of pressure sensor Ferrite-Austenite weld Exact positioning!
Materials Sci ence & Technolog y32
Removal of material by horizontal gas flow necessary!
Laser Cutting
Hardening
Welding
Cutting
Cladding
Glazing
Interaction time
Pow
er d
ensi
ty
Materials Sci ence & Technolog y33
Laser-cutting
High-speed cutting of sheets from ferritic steel
Processing time: 40 sec Source: Bystronic/Switzerland
Materials Sci ence & Technolog y34
Laser-cutting
High-speed cutting of sheets from ferritic steel
Processing time: 50 sec Source: Bystronic/Switzerland
Materials Sci ence & Technolog y35
Laser-cutting
Combination of stamping and laser cutting
Materials Sci ence & Technolog y36
Laser-drilling
Laser drilling of cooling holes in turbine blades Nd-YAG Laser is applied
Materials Sci ence & Technolog y37
Repair of turbine blades Blade tip restoration by laser cladding
Source: Sulzer/Switzerland
Materials Sci ence & Technolog y38
Repair of turbine blades Contour scan of blade tip geometry
Source: Sulzer/Switzerland
Precise restoration by laser cladding
Materials Sci ence & Technolog y39
Repair of turbine blades
Source: Sulzer/Switzerland
Laser cladding for abrasive blade tip protection with chromised SiC-particles