MCR Solutions Inc PFDs

V-101

Natural Gas Knock-Out Drum

1.22m D X 1.22m H

V-102

1st

Stage Air Knock-Out Drum

2.74m D X 2.74m H

V-103

2nd


1.83m D X 1.83m H

V-104

3rd


2.13m D X 2.13m H

C-103 C-104 C-105 C-106

C-101 C-102

R-102

880.3°C

R-103

450.2°C

R-104

159.1°C

Cooling

Water

Cooling

Water

Cooling

Water

Cooling

Water

Cooling

Water

C-101

1st

Stage Natural Gas Compressor

Power = 2,070.82 kW

C-102

2nd

Stage Natural Gas Compressor

Power = 2113.57 kW

C-103

1st

Stage Air Compressor

Power = 5,012.78 kW

C-104

2nd


Power =5,893.63 kW

C-105

3rd


Power = 5,554.90 kW

C-106

4th


Power = 4,533.60 kW

E-101

Natural Gas Compressor Intercooler

Duty = 7.52 GJ/hr

E-102

1st

Stage Air Compressor Intercooler

Duty = 15.12 GJ/hr

E-103

2nd


Duty = 21.33 GJ/hr

E-104

3rd


Duty = 20.29 GJ/hr

E-105

Steam Generation Exchanger

Duty = 356.20 GJ/hr

E-106

Shift Reactors Intercooler

Duty = 238.45 GJ/hr

E-107

2nd

Stage Air-Flue Gas Exchanger

Duty = 33.42 GJ/hr

E-108

Process Steam-Flue Gas Exchanger

Duty = 16.25 GJ/hr

E-109

2nd

Stage Natural Gas-Flue Gas Exchanger

Duty =27.28 GJ/hr

E-110

1st

Stage Air-Flue Gas Exchanger

Duty = 23.85 GJ/hr

E-111

1st

Stage Natural Gas-Flue Gas Exchanger

Duty = 20.20 GJ/hr

E-112

Exiting Flue Gas Cooler

Duty = 39.98 GJ/hr

R-101

Primary Reformer

1.76m D X 8m H

R-102

Secondary Reformer

3.15m D X 5m H

R-103

High Temperature Shift Reactor

4.89m D X 8m H

R-104

Low Temperature Shift Reactor

1.14m D X 3m H

R-106

Desulfurization Swing Reactor 1

4.35m D X 5m H

R-107

Desulfurization Swing Reactor 2

4.35m D X 5m H

R-106

R-107

S-1016

S-1017

S-1018S-1020

S-1021

S-1022

S-1023 S-1024

S-1025

S-1026

S-1027 S-1028

S-1001

S-1002

S-1003

S-1004

S-1005

S-1006

S-1007

S-1008 S-1009

S-1029

S-1032

S-1033

S-1034 S-1035 S-1036 S-1037 S-1038

S-1047

S-1049

S-1050

S-1051

S-1052

S-1053

S-1054

S-1055

S-1061

S-1062

387.8°C 160.0°C

E-102 E-103V-102 V-104

E-101

E-104

V-101

V-103

R-101

760.0°C

Cooling

Water

S-1013

113.4°C

34.0 atmS-1011

S-1012S-1010

426.7°C

S-1014

426.7°C

S-1039

S-1040

S-1015

S-1029

145.5°C

34.0 atm

S-1030

S-1031

482.2°C

S-1059

S-1060

E-107

E-108

E-109

E-110

E-111

E-112

TIC

Natural Gas

42°C

8 atm

Process Air

26.7°C

1.0 atm

Process Steam

373.3°C

40.8 atmBFW

90.5°C

95.3 atm

Steam (Utilities)

507.8°C

95.3 atm

To Section 2

159.1°C

32.8 atm

Fuel Gas

42.0°C

40.8 atm

Furnace Air

26.7°C

1atm

TIC TIC TIC

TIC

V-15

TIC

TIC

Flue Gas

93.3°C

0.272 atm

S-1041

S-1019

S-1042

S-1043

S-1044

S-1045

S-1046

S-1048

S-1056

S-1057

S-1058

S-1063

E-106E-105

AMMONIA PROCESSING PLANT

FEED PREPARATION

REFORMING

SHIFT REACTION

PROCESS FLOW DIAGRAM

SECTION 1 – FEED PREP AND REFORMING

APPROVED BY: CRYSTAL LIN, PM

PLANT LOCATION – REPUBLIC OF TATARSTAN, RUSSIA

MY CHEMICAL ROMANCE SOLUTION INC.

LOS ANGELES, CALIFORNIA

SCALE PROJECT NUMBER DRAWING NUMBER REV

NONE 01-2012 108A-PANG-108B 7

DATE 06-06-2012 CLIENT – HP CHEMICAL SHEET 1 OF 1

D 201D 202

V 201

E 201

E 202

P 201

S-2000

From Shift Reaction

230.56 °C

31 atm

S-2001

S-2002

Cooling Water

S-2013

S-2014

S-2004

S-2003

S-2006

To Section 3

23.8°C

27.2 atm

S-2005

Recycled MDEA Solution

23.88 °C

1 atm

S-2007

S-2008

S-2010

S-2011

S-2012

T 201

S-2009

1

50

1

50

30

49

2

49

2

LC

LP

STEAM

HP

STEAM

Cooling Water

LC

TC

TC

TC

TC

E 204

E 205

E 203

Removed

CO2

64.5 °C

2 atm

97.11°C

27.7 atm

83.7 °C

2 atm

82.2 °C

27.4 atm

LC

V 202

LC

D 201

CO2 Absorption

Column

D=4.82 m,

H=48.5m

D 202

CO2 Stripping

Column

V201

H2O Removal

Flash Drum

D = 1.01 m ,

H= 3.02 m

V202

MDEA Stripper

Condenser Accumulator

E 201

Second Stage

Intercooler

7.27 GJ/hr

E 202

First Stage

Intercooler

256.71 GJ/hr

E 203

CO2 Stripper

Condenser

46.23 GJ/hr

E 204

CO2 Stripper

High Pressure Reboiler

335.63 GJ/hr

E205

CO2 Stripper

Low Pressure Reboiler

51.79 GJ/hr

T 201

CO2 Stripper

Feed Expander

13,386.25 kW

P201

MDEA Recycle

Pump

1,637.46 kW


CO2 REMOVAL


SECTION 2 – REMOVAL AND RECOVERY






NONE 01-2012 108A-PANG-108B 3


D 203D 204

E 206

P 202

S-2100

From Purge Stream

2 °C

166 atm

Cooling Water

S-2101

Waste Gas

112 °C

166 atm

S-2102

Recycled H2O

123 °C

166 atm

S-2103

S-2104

27°C

166 atm

S-2105

S-2106

1

10

1

8

4

9

2

7

2

LC

HP

STEAM

Cooling Water

LC

TC

TC

E 207

Recovered

NH3

98 °C

2 atm

80 °C

2 atm2 °C

166 atm

LC

V 203

D 203

NH3 Absorption

Column

D 204

NH3 Stripping

Column

V203

NH3 Stripper

Condenser Accumulator

E 206

Ammonia Recovery Fisrt Heat Exchanger

0.383 GJ/hr

E 203

NH3 Stripper Condenser

4.47 GJ/hr

E 204

NH3 Stripper

Reboiler

7.22 GJ/hr

P201

H2O Recycle

Pump

25.31 kW

E 208

S-2107

S-2108

S-2109


NH3 RECOVERY


SECTION 2 – REMOVAL AND RECOVERY






NONE 01-2012 108A-PANG-108B 3


65.6 C

27 atm

315.6 C

26.9 atm

E305E306

E307

D301

E304

V302-2

R301

E301

E303

R301

MethanatIon

Reactor

V301

Water

Knockout

Drum

V302-1

Molecular

Sieve Dryer

No.1

D301

Cryogenic Distillation

Column

E301

Methanator Pre-heat

Exchanger

Duty= 99.7 GJ/hr

E302

Methanation Effluent

Water Cooler

Duty= 9.84 GJ/hr

E306

Second Cold Box

Heat Exchanger

Duty= 73.3 GJ/hr

E307

Cryogenic Distillation

Condenser

Duty=9.15 GJ/hr

E308

Methanator Effluent

Air Cooler

Duty= 15.5 GJ/hr

352.2 C

25.8 atm

N2, Argon, CH4

N2,H2, Argon

E308

E303

MethanatIon Effluent

1st

Level Refrigerant

Cooler

Duty= 9.56 GJ/hr

V302-1

V302-2

Molecular

Sieve Dryer

No.2

V303

V303

Distillation Column

Condensate Tank

Air

19.0 C

1 atm

Water

20 C

1 atm

102.4 C

25.6 atm

H2O

E302

1st

Level Liq. NH3

10.0 C

6.1 atm

2nd

Level Liq. NH3

-4.0 C

4.1 atm 6.0 C

24.1 atm

-181.6 C

23.3 atm

-182.1 C

1.1 atm

-173.3 C

23.4 atm

-174.7 C

23.5 atm

E304

MethanatIon Effluent

2nd

Level Refrigerant

Cooler

Duty=3.71 GJ/hr

E305

First Cold Box

Heat Exchanger

Duty= 0.26 GJ/hr

V301

P301

Bottoms Pump

Power= 664.5 kW

CH4, H2,

N2, Argon

H2, N2,

Argon

P301

5.5 C

25.1 atm

-195.6 C

1 atm

3.7 C

1.1 atm

3.7 C

23.3 atm

Process StreamS3001

TIC TICTIC

S3002

S3003

PIC

LIC

Syngas To Compressor

Waste Gas

S3004

S3005 S3006 S3007

37.8 C

25.4 atm

15.0 C

25.2 atm

S3008

5.5 C

25.1 atm

S3011

S3014

S3015

S3016

S3018

S3020

S3029

S3024


CRYOGENIC PURIFICATION


SECTION 3 – CRYOGENIC PURIFICATION



MY CHEMICAL ROMANCE SOLUTIONS INC.



NONE 01-2012 108A-PANG-108B 6


E-4001 E-4002 E-4003

S4001

S4002 S4003

S4004

C-4001C-4002

S4005

FIC-4001 LIC-4001 LIC-4002

V-18 V-16V-21

4.2C° 23.5atm

2°C, 45.5atm76.3°C, 86.1atm

E-4004 E-4005 E-4006

S4006

S4007

C-4003

S4008

C-4004

FIC-4002 LIC-4003

LIC

-40

04

V-24 V-23 V-22

2°C, 86.1atm

S4009

R-4001 R-4002

E-4009

E-4008

E-4010 E-4007

S4010

S4011

S4012

S4013

S4015

S4014

V-30I-31

287.7°C.98.7atm

310.3°C,98.3atm

385.0°C,179.6atm 476.7°C,178.9atm 418.3°C,178.8atm

E-4011

S4018

E-4012

S4019

E-4013

S4020

E-4014

S4025

S4023

S4022

V-34

V-33 V-32

S4021

V-31

S4024V-35

FIC-4003 LIC-4005 LIC-4006

FIC-4004

FIC-4005

Coolant waterRefrigerant NH3 Level 1

Refrigerant NH3 Level 2

191.2°C, 178.5atm

23.8°C,1atm

33.8°C,0.80atm

-9.0°C, 4.0atm

37.8°C,178.4atm 10.0°C,178.2atm

-33.3°C,1atm

-37.8°C,0.8atm

2°C,178.1atm

2°C,166.1atm

2°C, 166.1atm

S4016

246.1°C,179.8atm

S4009

S4017

-2.3°C,3.8atm

67.2°C, 180.0atm

2°C, 166.1atm

271.1°C,178.6atm

421.6°C,179.2atm

385°C,179.6atm531.7°C,179.4atm

67.2°C, 180atm

287.7°C, 98.7atm

81.7C°, 45.5atm

V-4001

Flash Drum

V-4001

Flash Drum for

Seperation

Compressor

ID C-4001 C-4002 C-4003 C-4004

Description 1st Compresser 2nd Comrpessor 3rd Compressor 4th Compressor

for synthesis gas for synthesis gas for synthesis gas for synthesis gas

KW 12845.81 12523.96 13001.23 8201.36

Heat Exchanger

ID E-4001 E-4002 E-4003 E-4004 E-4005 E-4006 E-4007

Description first Second Third first Second Third HX for

Intercooler Intercooler Intercooler Intercooler Intercooler Intercooler feed stream

C-4001 C-4001 C-4001 C-4002 C-4002 C-4002

Duty [GJ/hr] 16.0 6.6 2.6 14.5 5.3 5.3 223.1

ID E-4008 E4009 E-4010 E-4011 E-4012 E-4013 E-4014

Description 1st HX 2nd HX HX for HX for

for mixed gas for mixed gas Steam heat Recycle HX HX for Refrigerent Refrigerent

before 1st reactor after 1st reactor Exchanger Coolant water Level 1 Level 2

Duty [GJ/hr] 170.938462 6.693264 70.708466 45.594416 224.73113 80.245074 18.53569

Reactor

ID R-4001 R-4002

Description First reactor for Second reactor for

synthesis gas synthesis gas

Height[m] 12 7

Diameter[m] 3.5 3.5

Ammonia Production

Coolant water

Coolant water





From Section 3


COMPRESSION AND SYNTHESIS


SECTION 4 – COMPRESSION & SYNTHESIS






NONE 01-2012 108A-PANG-108B 5


T-521

T-528

T-529

T-522

T-523

T-524

T-525

T-526

T-527

E-521

E-522

E-523

P-521

E-527

E-528

E-529

E-526

E-525

E-524

E-521

Removal Reboiler

Duty: 218 kJ/hr

E-522

1st

Recovery Reboiler

Duty: 247 kJ/hr

E-523

2nd

Recovery Reboiler

Duty: 105 kJ/hr

E-524

Flue Gas Heater

Duty: 525 kJ/hr

E-525

1st

Synthesis Heater

Duty: 45 kJ/hr

E-526

2nd

Synthesis Heater

Duty: 227 kJ/hr

E-527

3rd

Synthesis Heater

Duty: 58 kJ/hr

E-528

4th

Synthesis Heater

Duty: 44 kJ/hr

E-529

5th

Synthesis Heater

Duty: 171 kJ/hr

T-521

1st

Pre-Cryo Comp Turbine

Work: 15853 kW

T-522

2nd

Pre-Cryo Comp Turbine

Work: 5132 kW

T-523

4th

Syn Comp Turbine

Work: 60 kW

T-524

Recovery Pump Turbine

Work: 25 kW

T-525

1st

Syn Comp Turbine

Work: 9.21 kW

T-526

2nd

Syn Comp Turbine

Work: 9.47 kW

T-527

3rd

Syn Comp Turbine

Work: 10 kW

T-528

Removal Pump Turbine

Work: 1673 kW

T-529

Steam System Pump Turbine

Work: 1257 kW

P-521

Steam System Pump

Work: 1257 kW

S-5201

T: 482 C

P: 95 ATM

S-5202

T: 374 C

P: 41 ATM

S-5204

T: 152 C

P: 3.7 ATM

S-5203

T: 374 C

P: 41 ATM

S-5205

T: 152 C

P: 95 ATM

S-5206

T: 10 C

P: 1 ATM

To Section 1


STEAM SYSTEM


SECTION 5 - UTILITIES






NONE 01-2012 108A-PANG-108B 6


E-501

V-501

V-502

C-502 C-501

C-503

E-502 E-503

S-5001

S-5002 S-5003 S-5004 S-5005

S-5006

S-5007

S-5008

S-5009

S-5010

S-5011

S-5012

S-5013

S-5015

S-5016

TIC

I-1

Cold Water

Used Cold Water

17 atm

93.3 C

17 atm

65.5 C

41 atm

166 C

41 atm

87.8 C

40 atm

78.8 C

6 atm

10 C

6 atm

10 C

3.4 atm

-5.6 C

3.4 atm

-5.6 C

S-5021

3.4 atm

-5.6 C

6 atm

35.6 C

6 atm

13.3 C

C-501

Primary Compressor

8292 kW

C-502

Compressor 2

6432 kW

C-503

Compressor 3

234.5 kW

E-501

Condensor

144 GJ/hr

E-502

Interstage Cooler

1785 m2

11.4 GJ/hr

E-503

Precooler

1011 m2

33.6 GJ/hr

V-501

Primary Knockout Drum

1.2 m-D x 6.7 m-H

V-502

Secondary Knockout Drum

0.6 m-D x 6.7 m-H

E-303b

E-408

E-409b

E-410b

E-303a

E-407

E-409a

E-410a

S-5025

6 atm

10 C

6 atm

10 C

E-303a

9.5 GJ/hr

E-407

68.8 GJ/hr

E-409a

7.9 GJ/hr

E-409b

3.9 GJ/hr

E-408

27.4 GJ/hr

E-410a

7.9 GJ/hr

E-303b

3.8 GJ/hr

E-410b

4.0 GJ/hr

437 kg-mol/hr

3162 kg-mol/hr

370 kg-mol/hr

370 kg-mol/hr

1835 kg-mol/hr

6169 kg-mol/hr

8900 kg-mol/hr

2731 kg-mol/hr

108 kg-mol/hr

1727 kg-mol/hr

168 kg-mol/hr

176 kg-mol/hr

174 kg-mol/hr

1209 kg-mol/hr

1727 kg-mol/hr


REFRIGERATION SYSTEM








NONE 01-2012 108A-PANG-108B 5


E-511

P-511

P-512

S-5103

S-5101

S-5104

Makeup Water

S-5105

P-513

S-5102

T-511

Quality

I-1

S-5109

W-511

W-511

Cooling Water Filter

20247 kg-mol/hr

E-511

Cooling Tower

90-W x 14.6-L x 10-H (m)

T-511

Chemical Additive Tank

3-D x 3-H (m)

P-511

Cooling Tower Feed Pump

450 kW

848927 kg-mol/hr

P-513

Filtration Pump

7.5 kW

20247 kg-mol/hr

P-512

Cooling Water Pump

1050 kW

848927 kg-mol/hr

S-5107

S-5108

E-101

E-102

E-103

E-104

E-106

E-112

E-204c

E-203

E-202c

E-201

E-302

E-501

E-409

E-409a

E-410a

E-411

E-406

S-5111

S-5106

S-5115S-5114

S-5113

S-5112

12053 kg-mol/hr

16996 kg-mol/hr

16162 kg-mol/hr

5990 kg-mol/hr

190011 kg-mol/hr

31838 kg-mol/hr273050 kg-mol/hr

3554 kg-mol/hr

346 kg-mol/hr

223453 kg-mol/hr

6588 kg-mol/hr

233941

kg-mol/hr

8308 kg-mol/hr

109306 kg-mol/hr

19580 kg-mol/hr

11616 kg-mol/hr

10334 kg-mol/hr

4529 kg-mol/hr

178262 kg-mol/hr

E-101

15.1 GJ/hr

E-102

21.2 GJ/hr

E-103

20.2 GJ/hr

E-104

7.6 GJ/hr

E-106

240 GJ/hr

E-112

40 GJ/hr

E-204C

4.5 GJ/hr

E-203

0.4 GJ/hr

E-202C

280 GJ/hr

E-201

8.3 GJ/hr

E-302

10.4 GJ/hr

E-409

24.5 GJ/hr

E-409a

14.4 GJ/hr

E-410a

13 GJ/hr

E-411

5.8 GJ/hr

E-406

224 GJ/hr

E-501

137 GJ/hr

224321 kg-mol/hr

848927 kg-mol/hr

3.4 atm

27 C

848927 kg-mol/hr

20247 kg-mol/hr

1 atm

27 C

1 atm

27 C

848927 kg-mol/hr

1 atm

43.3 C

848927 kg-mol/hr

1.5 atm

43.3 C

20247 kg-mol/hr

1.5 atm

27 C


COOLING WATER SYSTEM








NONE 01-2012 108A-PANG-108B 5


Documents

MCR Solutions Inc PFDs