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Izvestaj o Stanju Zivotne Sredine 2003-2004
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2003. 2004.
, 2005.
:
1
3
3
- 4
5
7
8 10
11
12
12
13
- 16
20
21
24
25
31 35
37
39
43 44
48
48
50
54
55
57
60
(SO2) 61
64
67 71
73
75
84
85
87
() 88
93
95
98
108 109
110
115
152
163
164
165 166
168
169
176
177
180
182 183
184 187
190
192
196
197
- 200
201
202
205
207
208
208
209
211
( ) 211 212
213
2003 - 2004. 215
224
227 233
235
236
237
240 242
243
246
248
249
253 254
255
258
259 262
262
269
274
278
281 284 In situ 286
Ex situ 294
295
296 297
298
299
-Brucellosis 299
301 -Trichinellosis 301
302
304
(AIDS) 305 308
309
310
312 315
1
, , - . (, , , ) , ( , ), ( ) ( , , , ). (, , ). 2002 11 80 , 15 (Mc Glade, 2004). .
(, 1992) , , e e . :
(
) ()
, , . , .
,
2
- . . ( , )
( )
, .
, . ( ), ( , , ). . . , .
, j , - , , , , , , , , , , , , ". ", , , , , , , , - , , , , , , , , , , , , , , , , , , - , , , , , - , ,
3
2003. 2004.
,
- -
-
, , , , . ( ). . ( , , , , ) ( , ). , (, , , ), ( ) (- ) . , , . . , , . ( , , ) . - ( , , , ) ( , ). , . , .
4
-
(European Environment Agency, 2001.) - :
(
, , , , , , ).
- (
, , , , , , ) .
( , , ) , .
, , , , , .
,
- .
, , .
5
. , , . -, 41 52' 46 11' 18 06' 23 01' , 88.361 2. . , : (21 506 2) (10 887 2). 1999. , (). , , .
1. .
, - . , - (, - ). (2 656m ..), (2 168m ..).
6
2.
7
o . , , , . , . (, , ).
(1992) . - , (, , , ), ( , , , , , ), - (, Je) - ( ).
. - , . , (- ), - - ( ).
. , , , , , ( ). . , , , , , (-).
, . , , , , , , , , . , , , , .
, , . : (); , , , , ( ); ( ).
8
:
3.
, , . (,
9
, ) . , , .
Anti et al.1982, , .
4.
5,113.307 ha 66% . (3,343.916 ha 65,4%). 3,321.148 ha, 1,762.094 ha , 53,1%, 1,792.159 ha , 1,581.822 ha 88,3%.
10
( 2003. 1,204.000 ha), (612.000 ha), (200.000 ha), (131.000 ha).
27%
66%
7%
5.
27% . 64,3% (59,6% 4,7% ), (30,5%) (6%). . 235 m3, 6,2 m3.
. () . , . , .
( ) . , , .
( 41 50` 42 12`). . , .
11
(ppen, 1923), : ( C ) ( D) , . , . . ( ) . a , . (, , , ) .
(Thornthwaite, 1948), ( ) , () .
, - , , , .
, , 1000 . ( ) , () .
. . . . , , , . 1000 . .
, 1961-1990., 10.1 C. , 3.0 C (1710), 11.9 C (132).
, , , . .
12
-1.3 C; -6.0 C 0.4 C . , 19.9 C; 11.6 C, 22.2 C. 22 C; . -38 C () 44 C ().
, , 1961-1990. 734 .
, 535 550 2. , 600. , , , , 650 . , . , , 800 850. , 2000 1000 . . 800 .
. . 1, , 85. , 120 130, , .
, . , , . . ( ) , , . 60 100 , 6,5 3. 350 , 60 48 . (2021. .) 107.563 l/s.
13
6.
, . - .
Koji, Popovi, Karadi (1997) . ( , ) . Salicion albae Populion albae . - Aceri tatarici-Quercion.
14
7.
Quercion pubescenti-petraeae Quercion frainetto. Quercion petraeae-cerris.
( 500 1000 ...). Carpinion betuli Fagion. j e, .
, Vaccinion uliginosi, Bruckenthalion spiculifoliae Pinion mugi.
. Festcion rupicolae, Festucion vaginatae. , Puccinellion limosae, Juncion gerardi, Puccinellion peisonis Festucion pseudovinae. Molinietalia coerulae Hordeetalia .
15
( ),
, ( Festucetalia valesiacae, Astragalo-Potentilletalia, Halascyetalia sendtneri), Cynosurion, Arrhenatherion elatioris Bromion erecti. Pancicion, Nardion strictae, Potentillo ternatae-Nardion Deschampsion caespitosae. , ( Festuco-Seslerietea) ( Juncetea trifidi).
16
-
, - . (2003), . , .
- . 2004. , , ; , ; , . ( , 2004.). (2004.) . , - .
2000. , . , . (2005.), () , 20% 2000. 14% 2002. .
, . , , , , , , .
17
. , , .
91,8% 2001. 10,1% 2004. . , . . , , .
- , , , . (2005.), 9,3% 2001. 15,8% 2004. . 1,5% 2001. 3,7% 2004. . . 2004. 2000. , 2,4 .
0
5000
10000
15000
20000
2000 2001 2002 2003 2004
.
8.
, , . . , , , 117,6% 2000. 34,6% 2004. .
2002. 2,4 . (2003), 2288 . , 2002.
18
10,6% . , 7,8% , 14,2%. 2003. 10,5%. , . , .
7,68,1
23,1
5,64,88,4
42,4
,
9.
( 15%). , 2000. ( ). 2003. 31,8%, 20,2%. 2004. 31,8%. . 75% , 33% , 42% . ( , 17 , 2004.). 15-24 ( ).
( ) , 20,0% 2000. , 29,3% 2002. .
19
0,0
10,0
20,0
30,0
40,0
2000 2001 2002 2003 2004
%
%
10.
2000-2002. , , . 0,762 2000. , 70. . 2001. , 0,768, 75 , 2000. . HDI 2002, 0,775. (Human Development Index - HDI, : , )
0.755
0.76
0.765
0.77
0.775
0.78
2000 2001 2002
11.
20
, . , 2002. 7,498.001 ( ). 1991. , 7,576.837, 1,1%. 12 .
0
50
100
150
1991 1997 1998 1999 2000 2001 2002
12.
, . , 2002. 40,2 . 69,7 , 75,0 .
, , 51,4% (2002.). , , , , .
21
0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0
1986 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002
13.
, , 1999. 2000. . (2005.), , . .
, , , , , , 24,2% , , (, , ). 2002. 2,521.190, 1991. . . ( 4,2 1948. ., 3,1 2002. .) . 4.706 . 2002. , 169, 3,6 % . 57% , . , (56,8% 1991., 56.4% 2002.).
, , , . , ( ), , . , , .
22
, , , ( , 2005.)
, , -, , - - , , , , , , , . , , 1991-2002. . , , , , .
, .
, , , ( ), 2002. 1991. . ( , 2005.)
80
90
100
110
120
130
140
1991 2002
.
e
15.
90-, () .
2003. 376.392 , . , , .
23
, . ( , 2005.).
, . , . , , 2002. , ( ) 593 ( 285 ), 250.000 . 100 5.000 . : 43,5% (); 34,3% ; 34,1% 51,5% .
( , , , , ). ( , , )
, - - , ( , ).
, : ( 2003.) , . , . , . , (1996.) . (2004.) , , , , . : (2004) (2004).
, : ; ;
24
; ; ; , ; '''' ; ; , . ( , 2005.).
. ( ) . - , .
, . , . . . ( , 2005.)
25
14. ()
, , , , . '' 2015. '', ( - 4,62%/.)
26
.
02468
101214161820
1990 1994 1998 2002 2003 2006 2009 2012 2015
mil. kg.en
0
0.2
0.4
0.6
0.8
1
1.2kg.en/$, 1994
(109 kg. ) (kg./$,1994)
16.
(kg.en - kg )
: , , , , . , , , . 2003. 37,49%, 2004. 45,79% .
0
2
4
6
8
10
12
1990 1994 1998 2002 2003 2006 2009 2012 2015
M. t
en
17. .
(ten - )
,
. , . ,
27
2,58 mil.toe ( ). , . 0,4 mil.toe. , 0,18 mil. Toe (Naumov, 2005).
, , , , , .
. : , , , , , , . 19% ( ). () , . ( 0,9 kg./$), .
. (TE TE ), 3.160 W, 160.000-190.000 S2, 38.280 Nx 50.000 . , 1007 W, 150.000-165.000 S2, 8.000 Nx 13.000 .
( ). '''' (96,3 99,0 %), '''' (99,6 99,8%), '''' (98,32-98,50%). 2004. 5 , EU . - 2 1 2 .
( ) . , 2003. 3 2 .
28
18. (Naumov, 2005).
6 8 . 1100 ha .
, . , , . 2004. - , 2006. .
29
, 47% , 16%, 10%. , 56% , 24% () 20% . , 2002. 32% . , ( ) 40 % ( ).
, S2, S Nx, . 43 6600 W. 55%. 1200 , (, S2, N2) . , . , ( ). .
, , S2, Nx C2 ; C2; ; ;
; ; ;
3C. .
: , .
, , . , ... I II, 9 .
30
, , , ., . , , ( ) . , . , , , . , . , , , . , . . , de facto , . :
;
, ;
, - - .
31
, , , , . , , , , , ( ). , , : . , . , , , , . , , . , . , , , ( 60% 1990 2000.), .
1990-2003.( 1990 =100)
0
10
20
30
40
50
60
70
80
90
1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
19. .
2001. , : , , . , 2003. , 3,0% 2002. . , 0,8%, , 2,3%, 4,5%,
32
76,23% ( ). 2003., 2002. , 4 , 38%, : , , e , .
2004. 7,1%, 2003. , (9,6%), 80,7% , , 2003. ( , 2005.)
6,4
80,7
12,9
.,
20. .
. , , , . ( , ). (, , .) , . , 90% .
(2005),
: (Lafarge, ), -Holcim () Titan ();
; : (
), US Steel (), (), ( ), ( ), (), (), (), , , , ;
33
: (), (), ( ) ();
: ( ) ().
:
21.
. , :
S2, Nx, , , , , , .;
, , , , , , .;
;
, .
34
22. ( , 2004.)
14001 - 1995. . 14001, 30 . - 14001, 20 .
35
, , , . , . , 2004. , .
. , . 3%, . 20 . ( , 2005.)
. 0,35% 0,7% . , , , . , .
. , , ( ) , , ( ) , , , , , ., (, , .) , , , . , , .
, 2004., .
36
( =100)
40
60
80
100
120
140
160
2000. 2001. 2002. 2003.
%
,
23. .
. . .
, , . . . :
170 , 1,4 1,7 700 .
10 . ( ) 20% . 1991. 1.700 . 1992. .
: , .
. 100 .
37
,
( , , 2) ;
; ; ; ;
.
( , ).
, . , .
( ), , . , , , 50% , ( 40 /h). 2000. , , , .
60
70
80
90
100
110
120
2000 2001 2002 2003
2002
.=10
0
..
23. .
, . , 40.845 , 1,8%
38
. 383 . . , .
2003. 3.809 . 32% . . .
959 . (588 ), (207 ) (164 ) (, 2005). , -- . , , , . . : . 75% 90% . . 1999., 1.237.045 . , . S2, C, Nx, 3, . (- ). 90% C, 80% , 50% Nx, 50% , 10% N2, 40% 15% C2 . - ( ). .
() (
C, Nx, , , 3);
;
; , ,
; (, , );
.
, . . , . ,
39
, , .
" , " 1982. . . , , , . ( , 2005.) . , - ( , , , .).
, , , , ( , , , ), , ( ), . . ( , , 2005.)
, , . , :
, , ,
, (
, . ).
, , ( , , , , .)
, .
40
, . . ( , , 2005.)
24. . ( , )
, 2003. 1,997.947 1,658.664 339.283 . 6,684.592 , 5,892.890 791.702 . , 2002. , 9% 7% . 2004. 1,971.683 , 1,579.857 391.826 , 15% 2003. . O 6,642.623 , 5,791.564 851.059 , 5% 2003. .
41
0
1000
2000
3000
4000
5000
6000
7000
2003
2004
25. 2003. 2004.
2003. , 85.634, 34.661 39.241. 2004. 85.867, 36.088 39.799, :
0
10
20
30
40
2003 2004
26.
2003. 158,423 USD, a u 2004. 220,781 USD. ( ) , . , . , , .
42
, , .
, : , / ; ; ; ; ; . . : , , , , , .
, , . :
- ( , , ).
, .
- ( ),
( , ).
43
44
. ( 1).
N2 78.08 %
O2 20.94 %
Ar 0.93 %
CO2 0.0360 %
Ne 0.0018 %
He 0.0005 %
CH4 0.00017 %
H2 0.00005 %
N2O 0.00003 %
3 0.000004 %
1
, ,
( 27). . 16 , 8 . 80% . - . ( 20 C). ( 6.5 C 1000 ). -56.5 C.
45
11 50 . 19.9% . 20 5 , . , , .
27 . . .
, . , , (CO2), (CH4), (N2O), (O3). , . , , .
46
, .
, 15 C , , -18 C. , 33C .
, , .
1750.
1995.
280 ppm 360 ppm 29 % ,
,
,
0.70 ppm 1.70 ppm 143 % , ,
,
280 ppb 310 ppb 11 %
-
0 900 ppt
.
( )
.
2. 1750. .
47
,
, . . 240 nm. .
, : , , , (Morrison, 1989, UNEP, 1991, IARC, 1992, Stiling, 1996).
, (--, - , , , , ), (SF6) (Fisher, 1990, Prather and Watson, 1990, US EPA, 1990, WMO, 1991). Kurylo and Rodriguez, 1999; Prinn and Zander, 1999, Butler et al., 1999 . 1928. , General Motors Corporation, . ( , 12,5C), , ( ), , (, , ) . , , .
Cl + O3 >>>> ClO + O2
ClO + O >>>> Cl + O2
100 000 .
1987 ( ) 1996. 2010. . ( , - , 6-96),
48
( , 2/2004).
. . CFCl3, CF2Cl2, CF2ClCFCl2 CH3CCl3 .
(CFC) , 1986. 2.250-2.800 . , , CFC 1986-1990. . . , 1994. 900 . CFC. .
0100200300400500600700800900
1000
1996 1997 1998 1999 2000 2001 2002 2003
27 .
. ( ) .
49
. (Popovi et al., 1994, Jovanovi and Popovi, 1994, Popovi and Jovanovi, 1994, Popovi, 2002) .
1951 2004. 27.
-3
-2
-1
0
1
2
3
4
5
1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005
GODINA
NO
RM
ALI
ZOVA
NO
OD
STU
PAN
JE
27 , 1951-2004.
19 ( 1985. ), 14 , 9 , 3 , 2000, .
, 1951-2004 0.66 oC/100 () +1.76 oC/100 (). , , , . +0.6 oC/100 . . , , . 54 1.4 oC/100 .
50
1951-2004. 1991-2004
28. . o C/100
, 1991-2004 . 1991-2004 1951-2004.
2003. ( 29), 2003. . -1, 2003 . 2003. . 2004. , 2004. .
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0
-0.8 -0.2 0.0 0.2 0.6 1.0 1.4 1.8
TIPO_05
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0
2.0 4.5 5.5 6.5 8.0
TIPO_05
51
29. ,
1951-2004.
23 ( 1981. ), 12 , 8 , 3 , 2000, . 11 , 3 .
, . , , .
, 1951-2004 1991-2004, 30.
-5
-4
-3
-2
-1
0
1
2
3
1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005GODINA
NO
RM
ALI
ZOVA
NO
OD
STU
PAN
JEE
52
1951-2004. 1991-2004
30. %
. , . , , , . , 1951 , , .
, 1991-2004, . 30 . % 1961-1990 10 . , -3.9 % 23.8 %. 1991-2004, , .
(, ), , . - . ( - , . 1-90)
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0 PALIC
KIKINDASOMBOR
ZRENJANINN.SAD
VRSAC
S.MITROVICABEOGRAD V.GRADISTE
LOZNICA
S.PALANKAVALJEVO NEGOTIN
C.VRHKragujevac
CUPRIJA ZAJECARPOZEGAZLATIBOR KRALJEVO
KRUSEVACIvanjica
NISKOPAONIKSJENICAN.PAZAR KURSUMLIJA
DIMITROV.LESKOVAC
PEC PRISTINAVRANJE
PRIZREN
.
.
-30 -15 -5 0 5 10 17
TIPO_05
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0
-5 0 5 15 25 35
PALIC
KIKINDASOMBOR
ZRENJANINN.SAD
VRSAC
S.MITROVICABEOGRAD V.GRADISTE
LOZNICA
S.PALANKAVALJEVO NEGOTIN
C.VRHKragujevac
CUPRIJA ZAJECARPOZEGAZLATIBOR KRALJEVO
KRUSEVACIvanjica
NISKOPAONIKSJENICAN.PAZARKURSUMLIJA
DIMITROV.LESKOVAC
PEC PRISTINAVRANJE
PRIZREN
.
.
TIPO_05
53
( - , . 16-90), . , ( - , . 2/90). 1997. .
CO2, - ( ) .
. . , . , . , .
27% , . , .
54
55
. . , (USEPA, 2003, , 2002). , , (WHO, 1992, USEPA, 2003, Environment Canada, 2005, , 2003).
. , , ( ) .
. . , . , , .
(Persistent Organic Pollutants) , , e e . . , . , () , .
. , . , , . , , .
() (, , , , , , ), , , , , , .
56
( , , , ) ( , , , , , , , , , ). .
: ( ), , , , , , , , . , , . . . , , , , , , , , , .
: , ( ), .
( . 135/04), , , ( . 54/92), , ( . 30/97) ( . 5/2002).
, 2004. 2005. ( 48/2004), :
; ; ;
;
; ,
; , .
() ,
57
, , , , ,
- . .
, . , , . 50 50 , . 31 SO2 , 1999-2003.
58
SO2, 1999-2003. ( Gg )
SO2 2003. (: 1999-2003.)
. .
32 NO2 , 1999-2003. , , , .
PALIC
KIKINDASOMBOR
ZRENJANINN.SAD
B.KarlovacVRSAC
SR.MITR.
BEOGRAD V.GRADISTE
LOZNICA
S.PALANKAVALJEVO NEGOTIN
C.VRHKragujevac
CUPRIJA ZAJECARPOZEGAZLATIBOR KRALJEVO
KRUSEVAC
NISKOPAONIKSJENICA
DIMITR.LESKOVAC
PEC PRISTINA
VRANJE
PRIZREN
.
.
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0
0 20 40 60 80 100 120 140 160
PALIC
KIKINDASOMBOR
ZRENJANINN.SAD
B.KarlovacVRSAC
SR.MITR.BEOGRAD V.GRADISTE
LOZNICA
S.PALANKAVALJEVO NEGOTIN
C.VRHKragujevac
CUPRIJA ZAJECARPOZEGAZLATIBOR KRALJEVO
KRUSEVAC
NISKOPAONIKSJENICA
DIMITR.LESKOVAC
PEC PRISTINAVRANJE
PRIZREN
.
.
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0
-80 -50 -20 0 20 50 100 150 200
59
, NO2, 1999-2003. ( Gg)
, NO2, 2003. (: 1999-2003.)
PALIC
KIKINDASOMBOR
ZRENJANINN.SAD
B.KarlovacVRSAC
SR.MITR.BEOGRAD V.GRADISTE
LOZNICA
S.PALANKAVALJEVO NEGOTIN
C.VRHKragujevac
CUPRIJA ZAJECARPOZEGAZLATIBOR KRALJEVO
KRUSEVAC
NISKOPAONIKSJENICA
DIMITR.LESKOVAC
PEC PRISTINAVRANJE
PRIZREN
.
.
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0
0 2 4 6 8 10 12 14 16 18 20 22
PALIC
KIKINDASOMBOR
ZRENJANINN.SAD
B.KarlovacVRSAC
SR.MITR.BEOGRAD V.GRADISTE
LOZNICA
S.PALANKAVALJEVO NEGOTIN
C.VRHKragujevac
CUPRIJA ZAJECARPOZEGAZLATIBOR KRALJEVO
KRUSEVAC
NISKOPAONIKSJENICA
DIMITR.LESKOVAC
PEC PRISTINAVRANJE
PRIZREN
.
.
19.0 19.5 20.0 20.5 21.0 21.5 22.0 22.5 23.0
42.0
42.5
43.0
43.5
44.0
44.5
45.0
45.5
46.0
-80 -50 -20 0 20 50 100 150 200
60
( ) , . .
31. 2004. 2005.
( 48/2004)
, ,
61
( , 54/92 30/99).
. , ; . , ; ( ), ( ), - .
, , , , , , , , , , , (, , , , , ) (, , , .).
(S2)
,
. , . . , . , (Fleischer et al., 1993). - 1.
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 17 28 21 27 26 15 20 21 21 23 .. 78 95 91 89 102 60* 88 94 94 111
1. - 1995 - 2004.
2003. - (43,98 mg/m3) (41,54 mg/m3), 2004. - (47.6 mg/m3) (26.23 mg/m3). 150,0 mg/m3 .
62
2003. - (3.53 mg/m3) (6.30 mg/m3), 2004. (0.0 mg/m3) (2.68 mg/m3).
2003. - () (150mg/m3) 0,0 % . , , , , , 5.87 6.57 . 2004. - () (150mg/m3) 0,0 % , , , , , , 13.15 % .
- (S2) 1995-2004. . (mg/m3) 32 (,).
0
50
100
150
200
250
300
350
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
mg/m3
0102030405060708090
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
mg/m3
38. S2 ( mg/m3 ) 1995 2004,
63
, . 33 (,) SO2 () , 1995. 2004. , .
0
10
20
30
40
50
60
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
% a
0
2
4
6
8
10
12
14
16
18
20
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
% a
39. (,) S2
64
, . : -- , -- , , , . -- . .
1995. 1996. 1997. 1998. 1999. 2000. 2001. 2002. 2003. 2004.
17 28 21 27 26 15 20 21 20 26
.. 78 95 91 89 102 60* 88 96 93 104
2. .
2003. 20 93
, 2004. 26 104 ( ). , , 15 (2000.) 28 (1996), 60 (2000.) 104 (2004).
2003. (58.64 mg/m3) (55.55 mg/m3), 50,0 mg/m3 2004. (31.3mg/m3) (29.88mg/m3), 50,0 mg/m3.
2003. (6.70 mg/m3). (7.00 mg/m3) , 2004. (5.00 mg/m3) (6.7 mg/m3).
6. 2003. () (50,0 mg/m3) 0,0 % 41.1% .
6. 2004. () (50,0 mg/m3) 0,0 % 18% .
65
34 (,) 1995-2004. . (mg/m3)
0
10
20
30
40
50
60
70
80
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
mg/m3
0
10
20
30
40
50
60
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
mg/m3
40. (,) (mg/m3)
66
1995. 2004. 35(,)
0
5
10
15
20
25
30
35
40
45
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
% a
0
5
10
15
20
25
30
35
40
45
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
% a
41. (,)
67
, 10 m, . . 10 m - , , : , , , .
1995. 1996. 1997. 1998. 1999. 2000. 2001. 2002. 2003 2004.
23 28 22 34 27 25 27 22 23 27
.. 145 175 127 172 151 105 148 141 132 124
3. 1995-2004.
2003. 23 132 , 2004 27 124 ( 3). 22 (1997 2002.) 34 (1998.), 105 (2000.) 172 (1998)
2003. (355.8 mg/m2/) (312.7 mg/m2/). 9 200,0 mg/m2/. 2004. (336.5 mg/m2/) (333.16 mg/m2/). 11 200,0 mg/m2/. 2003. (6.08 mg/m2/) (112 mg/m2/), 2004. (10.17 mg/m2/) 83.93 (mg/m2/).
1995-2004. (mg/m2/) 36(,).
68
0
100
200
300
400
500
600
700
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
mg/m2/
g/m2/ g/m2/g/m2/ g/m2/ g/m2/ g/m2/ g/m2/ g/m2/ g/m2/
g/m2/
0
200
400
600
800
1000
1200
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
g/ m 2/
mg/m2/
36 (,) (mg/m2/) .
2002-2004. 4.
69
2003.-2002.
2004. 2003.
4 2002.2004. .
2002 2004.
,
70
- (, , , , , , ) - (, , --, ,, ) - (, , , , , , , )
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
10 11 14 14 17 8 12 10 10 11
.. 40 46 75 80 88 43 44 36 46 49
5. 1995-2004. .
2003. 10 46 , 2004. 11 49 . (15), 30,6% .
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
. - - - - 6 - -
2
8 8 14 15 15 20 15 15 15 15
1 1 1 - - 1 1 1 1 1
1 1 1 1
- - - - 3 - - - - -
. 3
- - 2 10 3 - - - - -
2 2 2 2 5 - 4 4 4 2
1 1 - - - - -
- - - - 4 4 - -
1 1 1 1 - 1 1 1 1
6 4 6 6 6 - 2 2 2 2
12 12 20 18 18 - 12 12 12 12
1 1 1
2 2 2 2 2 - 2 2 2
1 2 2 1 2 - - -
- 6 6 7 7 7 1 6 6 6
- - - - 3 - - -
2 2 2 2 2 2 2 3 3 3
6. 1995-2004. ( )
71
2003. 2004. :
(, , , , , ) (, , , , ) () (, ) (, ) (, , , .
)
2003.
23.0 mg/m3 283.4 mg/m3 2004. 19.00 mg/m3 449.9 mg/m3 . 200,0 mg/m3 .
0
50
100
150
200
250
300
350
400
450
500
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
NH4 (mg/m3)
37
2003.
11.4 mg/m3 43.5 mg/m3 , 2004. 4.0 mg/m3 45.75 mg/m3 . 60,0 mg/m3 .
72
0
10
20
30
40
50
60
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
NO2 (mg/m3)
38
2003. 7.87 mg/m3 43.2 mg/m3 , 2004. 8.75 mg/m3 50.8 mg/m3 ( 7). 2004. 50,0 mg/m3.
1995. 1996. 1997. 1998. 1999. 2000. 2001. 2002. 2003. 2004.
31.0 31.0 - 54.3 37.5 34.8 - 31.2 43.2 50.8
2.0 6.4 6.5 3.3 3.3 -
73
a, ( ), , , ( ). , : 10 m (P 10) 2.5 m (P 2.5). .
( , , , ). 2003. 126.9 mg/m3 196.7 mg/m3 2004. 34.24 mg/m3 467.4 mg/m3 . 70,0 mg/m3 .
0
100
200
300
400
500
600
700
800
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
(mg/m3 )
39.
2003. 2004. :
(, , ) () () (, , ) 1,2- () ()
74
() (, , , ) (, , )
.
1995. 1996. 1997. 1998. 1999. 2000. 2001. 2002. 2003. 2004.
43.0 16.0 - 2.4
75
2003. 2004.
:
, , , , ,
, , , , , , . , , , , ,
, , , , (6+) . . , , , , ,
, , , ,
21.85 mg/m2/ ,
76
0
5
10
15
20
25
30
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
(mg/m3/)
41. 1995.-2004.
(mg/m2/ )
2003.
0.003mg/m2/ 10.94 mg/m2/ 2004
77
0
50
100
150
200
250
300
1998 1999 2000 2001 2002 2003 2004
(mg/m3/)
42.
1995.-2004. (mg/m2/ )
0
100
200
300
400
500
600
700
800
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
PM10
43. 1995-2004. PM10 1999. .
78
(6+) 2003. < 1.0 mg/m2/ 65.9 mg/m2/ 2004.
79
2003
80
(6+) 2003. 2004. < 0,01 mg/m3 . 2003. 2004.
81
0
1
2
3
4
5
6
2001 2002 2003 2004
45. (mg/m3).
, 2003. 0,0 mg/m3 18.0 mg/m3 . 2004. 2003. 0,0 mg/m3 9.0 mg/m3 .
0
5
10
15
20
25
2001 2002 2003 2004
46. (mg/m3).
, 2003.
43.0 mg/m3 113.0 mg/m3 2004. 0.08 mg/m3 90.3 mg/m3 .
82
1000 mg/m3.
0
20
40
60
80
100
120
140
2001 2002 2003 2004
47. (mg/m3).
2003. , 4.0 mg/m3 58.0 mg/m3 2004 2.7 mg/m3 19.3 mg/m3 . 2.5 mg/m3.
0
10
20
30
40
50
60
70
2001 2002 2003 2004
47. (mg/m3).
83
2003 2.0 mg/m3 293.0 mg/m3 2004.
84
2003. 2004. , , , , ( 12).
1995. 1996. 1997. 1998. 1999. 2000. 2001. 2002. 2003. 2004.
(mg/m3)
7.20 8.50 7.90 8.32 8.85 - - 6.65
3.20 3.70 1.35 - - 3.12 3.40 2.39
20.70 - 0.50 - 1.00 1.00 0.50 0.0
- (mg/m3)
0.12 0.13 0.124 0.128 0.134 - - 152.91
45.75
11.40 0.095 0.098 - - 11.92 12.57 30.79
1.20 - 0.20 - 0.018 23.70 34.00 34.0
(mg/m3)
0.010 0.006 0.011 0.024 0.018 - - 0.0074
4.67
3.90 0.004 0.012 - - - -
- - - - - - -
(mg/m3)
1.32 1.70 2.00 1.20 2.50 - - 1.555
0.17
9.53
0.20 0.050 0.20 0.0 0.1 0.10
(mg/m3)
0.014 0.023 0.035 0.030 - - 0.026
290.0
12. 1997-2004. .
85
2003. 0.50 mg/m3 3.40 mg/m3 2004 0.0 mg/m3 6.65 mg/m3 . 3,0 mg/m3.
2003. 12.57 mg/m3 34.00 mg/m3 2004. 30.79 mg/m3 152.91.91 mg/m3 . 60.00 mg/m3.
2003 2004. 0.0074 4.67 mg/m3 , 0,100 mg/m3.
2003. 0.1 mg/m3 2004 0.1 mg/m3 9.53 mg/m3 , 1,0 mg/m3
2004 0.026 mg/m3 290.0 mg/m3 .
:
2004.
5 : - , - , ( ), ( ). 6 38 -, 13 45 -, 15 49 , 4 11 8 10 .
14 49 (417 g/m3 50 g/m3). - 673,5 g/m3, - 650,9 g/m3 200 g/m3, 2002. .
. 2002.- .
86
Nissal . 6 (H2S) Nissal.
- . , .
2002. .
. , . , . , .
2004. , , ( ), , , , . . , , , (26-50 .).
. .
5 365 . , , 3 . 115 , 106 , 114 109 .
.
, .
87
, . , .
758 5, 4 4 .
760 , 10 , 4 , .
, 320 .
( ). , .
0 162 g/m3 .
(Pb, Cd, Zn) .
, , ( ), , .
, . 2002. , . , , .
, , , , - , , , .
88
2003. 3004. , , . - (, , ). . , , . , .
()
, , . ( ) . . .
(www.ec.gc.ca)
89
, , . . , ( ) , , , . .
. , . 1- 2%, 40 80 g/m3.
, . : 200 g/m3 , , , 250 g/m3
, , (GAWWMO) . ( ) , .
, 150 g/m3 .
UNECE ( ) 150 g/m3 50 g/m3 (9-16 ) (-).
, 110 g/m3 . , 180 g/m3, , 360 g/m3. 200 g/m3 65 g/m3 .
, , , , , . 54/92
, , . EMEP
90
(Programme for Monitoring and Evaluation of the Long-range Transmission of Air Pollutants in Europe).
, , .
- 2003 , 8. 9. 2003. 85 g/m3 ( , , , , . 54/92).
14. 2003. . 120, 150, 200 240 g/m3 . - 120 g/m3 . 22.04.2003. 128 g/m3 .
h d
>120
h d
>150
h d
>200
h d
>240
h d
.
g/m3
7 5
7 5
0 0
0 0
0 0
128 22.02.2003. 14. (h) (d) 120, 150, 200 240g/m3 2003. -
, 15. . . : , , NOx . .
* 48.9 50.7 36.9 40.7 21.7 15. (g/m3 ) - 2003. -
, , .
2003. - 59. , . ( 7h), ( 14 h). . ,
91
, .
59. -
2003. -
g/m3 , 60. , 2003. .
0
10
20
30
40
50
60
g/m
3
2003
60. 2003.
92
, 2003. 2004. , 61. . , , , Nx.
0
10
20
30
40
50
60
70
g/m
3
2004 2003
61. 2003.
2004.
2003. . .
, , , .
. , , . , , .
93
, , , , .
, a- ( ), b- ( ) g . ( ) () . . 105 ). ( 104 ). ( 103 ), . (, , X-) , - (UNSCEAR, 1993). ( ) . .
- 2003. - : , -, , , ( , . . 46/96 - , . 45/97). 1m 24 . - - (0,1 mGy/h 15 mGy/h). ( ), (), , 24 , 300 m3 , 1m .
94
( ) ( ) . 90Sr ( ). Bq/m3 .
( , , , ), (), , -, , , 24 1m . , 90Sr. Bq/m2 . Jaa aooae oe aa aea a a 1m a oe a eea je oao eoa (ooa a) ao (ooa Oooo a). Jaa aooae oe aa aea a eaa e oo 2003. oe ea o 0.078 o 0.142 Gy/h a eo oo eo o 0.0847 Gy/h eoa ea o 0.079 o 0.144 Gy/h a eo oo eo o 0.0896 Gy/h ao. aaeoeja aaa oo ee oaa aa eoa, , a ajea oaje o aoa oo oea oa. Ao 137Cs je 2003. o a o ae eeje. Ao 7Be, ooeo aoa, eaa e o 0.5 mBq/m3 a o 1.68 mBq/m3 a . 90Sr 7.7 17.1 Bq/m3 , 6.1 54.6 Bq/m3 , 11.3 65.6 Bq/m3 4 84 Bq/m3 .
Bg_av Bg_max Kla_av Kla_max
Jan 0.0838 0.098 0.088 0.1
Feb 0.0829 0.096 0.089 0.098
r 0.0841 0.091 0.089 0.095
pr 0.085 0.094 0.09 0.128
y 0.0857 0.111 0.089 0.137
un 0.0853 0.107 0.09 0.099
Jul 0.085 0.142 0.091 0.119
ug 0.0856 0.103 0.092 0.129
Sep 0.0844 0.127 0.09 0.144
kt 0.084 0.122 0.09 0.14
Nov 0.0827 0.097 0.089 0.119
Dec 0.0875 0.13 0.089 0.113
13. ( )
95
aaeoeja aaa ee oaa eoa, , , , , a oaje o aoa oo oea oa. Ao 137Cs . 7Be < 4 Bq/m2 208 Bq/m2 , . 90Sr < 0.11 Bq/m2 3.49 Bq/m2 .
0.070.080.09
0.10.110.120.130.140.15
Jan Feb r pr y un Jul ug Sep kt Nov Dec
2003
uG
y/
h
Bg_av Bg_max Kla_av Kla_max
54. 2003.
2003. , ( - ), .
2003. 2004. , , ELF (Extremely Low Frequency) RF (Radio Frequency) , 43 . , (29 ), (3), (2), , , , , , , , .
96
: , , GSM , TV .
. ( ) (, , ). (. ) , , 1. , .
ELF (30 Hz do 2kHz)
Emax [V/m] Bmax [mT]
FON 1 2 0,02 0,2
10 50 0,4 18
18 mT , TS
(400kV) 3000 6000 0,4 4 6 kV/m DV 1,7 m
VN
TV 75 100 50 70 70 mT 30cm
RF (100kHz do 3GHz)
Emax [V/m] Smax=(Emax)2/ 3770
[mW/cm2]
FON 0,6 0,0001
GSM
8 - 11 0,017 0,032
i TV 8 30 0,017 0,240
14. 2003. 2004. ( : http://www.who.int/peh-emf/standards/en/) . RF , (
97
) ( ).
15 16
E
(kV/m)
B
(mT)
E
(kV/m)
B
(mT)
NRPB 1993. (.) 12 1600 12 1600
CENELEC 1995. ( ) 12
640
30 1600
DIN/VDE 1995.
() - - 21 1400
ICNIRP 1998.
( ) 5 100 10 500
15. ELF ( 50 Hz)
NRPB (1993.) IEEE (1999.) ICNIRP (1998.)
E (V/m) E (V/m) E (V/m) 600kHz 12MHz 600/f (MHz) 0,1-1,34MHz 614 0,15 1MHz 87
12 200MHz 50 1,34 - 3MHz 823,8 / f 1 10MHz 87/f 1/2
200 400MHz 250 f(GHz) 3 30MHz 823,8 / f 10 400MHz 28
400 800MHz 100 30 100MHz 27,5 400MHz-2GHz 1,375 f 1/2
800MHz 1,55GHz 125 f(GHz) 100 300MHz 27,5 2 300 GHz 61
1,55 300GHz 194 - - - -
MHz MHz
16. (RF )
98
E2 [V/m]2
. E [V/m]
S [mW/cm2] 30 MHz 300 GHz
3770: 5 =754 27,45
0,2
17. 30 MHz 300 GHz JUS N.N0.205 1990.
15 16 14, (ICNIR), , .
,
. (, , ) . , 20 25% . , , .
. 24 48 . .
. . . .
.
. ,
99
, (IAA).
01. ( ) ( ). 24 (, , , , , , , , , , , , , , , , , , , , , , ).
( ). (Taxaceae / Cupresaceae) , (Betula sp..).
63 2003 2004. . ). .
100
63. ( Betula sp.)
2003. 2004.
( 64) .
101
64. 2003. 2004.
( Plantago sp.), (
Rumex sp..), (Urticaceae). , . .
102
65. .
Ambrosia artemisiifolia.
, . , , , , , , , (, , 2004, 2005). , .
103
. . Ambrosia artemisiifolia , , . :
,
.(Koji,1986)
66
AMBROZIJA
50%
BREZA30%
TRAVE20%
66. .
2003. 2004.
, . , . 21 22.
104
1. 2003.
3
.
/3 12 23 15 44 496 520 11 118 230 14 26 25 42 1056 666 10 225 163 ,
68 75 71 1203 4483 2983 124 462 758
25 24 23 153 409 351 19 111 121 18 43 33 663 13494 1245 359 2401 210 31 47 54 388 3147 760 49 486 141 64 65 57 1062 7887 1550 143 1216 87 54 67 56 1461 1943 1530 220 177 123 57 63 53 3795 5990 10108 334 1340 1349 50 42 53 830 573 2841 89 58 477 16 28 21 498 1671 881 126 327 240 27 20 30 340 383 410 68 88 60 39 51 41 1159 1302 2175 150 169 416 78 71 63 997 681 1078 168 55 135
87 87 89 595 983 932 40 66 39 156 176 163 1109 2633 3386 60 66 125 64 51 93 212 217 1975 17 24 181
104 119 102 466 468 440 43 19 28 50 65 77 149 288 248 16 33 13 152 155 149 6099 9580 12195 183 300 385 ,
125
127 126 954 1440 2219 43 52 79
82 84 75 785 1017 1165 51 80 86 118 113 118 4500 12090 16162 287 755 1654
25 23 27 2045 4105 1276 681 837 270
21. 2003.
105
1. 2004..
3
. /3
36 39 28 271 559 172 40 256 24 44 42 35 969 1614 1477 285 546 512 ,
86 78 89
3285 1831 4467
395 279 934
18 34 21 216 223 250 58 67 50 30 35 29 2349 5335 537 1360 1291 89 39 30 33 688 604 272 53 250 64 51 49 52 501 1439 593 91 215 48 28 52 65 660 524 785 146 52 159 51 56 58 2556 1438 1707 269 201 162 47 39 54 516 203 662 65 23 85 31 27 28 262 719 1662 33 195 428 42 34 45 2514 422 1126 387 84 180 33 37 42 623 415 581 78 51 50 73 65 69 298 321 522 15 21 110 56 66 58 355 387 229 25 31 18 166 171 171 2261 1892 2022 84 99 67 50 51 87 192 298 1189 19 36 100 96 115 81 215 441 133 10 19 6 38 56 53 95 89 113 8 7 7 144 149 150 8104 8345 7816 273 229 262 ,
114 93 92
531 429 448
22 17 15
85 81 61 632 588 437 58 35 37 99 87 83 3343 5866 4616 319 472 462 25 34 30 1668 2288 2738 240 355 642 22. 2004.
67, 68 69 ( 2003, 2003 2004). ( 30 m3 ).
106
9 1 0 11 12 13 1 5 16 17 1 8 1 9 2 0 2 1 22 23 2 4 2 5 2 6 28 2 9 3 0 3 1 3 2 33 34 3 6 3 7 38 39 4 1 4 2 43 4 4 1 3 4
3 1 7 3 2 3 5 2 3 7 5 4 5 1 5 1 3 2 7 6 2 3 2 1
3 6 1 2 5 3 2
1 2 4 4 3 4 4 7 4 5 2 1 2 1 1 1 1
2 1 1 2 2 4 6 2 3 6 7 7 6 7 7 7 1
,
3 7 5 3 7 7 7 6 6 7 4 2
6 6 1
:
4
1 1 6
7 3
2 12 5 6 22
5 4
12
51
77
26 2 4 2
2
14 2 7 35 40
VII V III IX XII I IV V VI
67. , 2003
8 9 1 0 11 1 2 13 1 4 15 1 6 17 1 8 1 9 2 0 2 1 22 2 3 24 2 5 26 2 7 28 2 9 30 3 1 32 3 3 34 3 5 36 3 7 38 3 9 40 4 1 42 4 3 44
, 3 2 3 3 2 1 6 3 2 6 1 2 1 2 3 1 3 4 2 3 4 6 7 5 1 3 3 3
1 2 4 3 1 1 5 5 2 4 5
1 2 3 1
1 2
1 1 5 7 2 3 5 7 7 7 7 7 6 7 4 , 1 4
1 5 2 1 7 6 7 6 3 5 1
4 7
:
4
68. , 2003
107
8 9 1 0 11 1 2 13 1 4 15 1 6 17 1 8 19 2 0 21 2 2 23 2 4 25 2 6 27 2 8 29 3 0 3 1 3 2 3 3 3 4 3 5 3 6 3 7 3 8 3 9 4 0 4 1 42 4 3 44
2
1 5
, 1 7 3 4 2 3 1
2
3 4
4 4 1
2 1 5 3 2
3 3 1
5 5 5 4
2
2 1
2 5 6 3
2 2 3 1
2 4 3 2 3 5 1 2
3 6 7 5 7 7 7 7 2 6 6 5 6 7 2
,
1 3 1
3 3 7 7 6 2
2 6 3
:
4
69. , 2004
( , , , ) . , , . () , ( Radii et al., 2001).
. :
,
(, , ).
,
-
( ) ,
108
109
. - , . , , .
, . - . .
() ( , ), ( ). , (Baumgartner and Reichel, 1975, UNESCO, 1978). , ,
( , , , ). , , , , . , , (, , ) (Cresser and Edwards, 1987, Borg, 1987, Chevreuil, Chesterikoff and Letolle, 1987, Boesten and van der Linden, 1991 , 1999, 2003). / ( , , ). . ( )
110
() . . , . () (OECD, 1982).
, ( ), . . ( ), . .
( ), ( ) (, ). ( 176 m3 93%). 2 m3, 0.5 m3 . 162,5 m3, 178,5 m3 . 16 m3 .
a 62.
111
(2002), ( 63, 23).
63. . (Isailovi, Srna 2002),
. ( 23).
112
F Pb Qb Qn Pn Pi q h
(km2) (mm) (m3/s) (m3/s) (mm) (mm) (l/skm2) (%) 1 4609 565 83 4.33 30 535 0.94 5.2
2 4545 621 89 5.93 41 580 1.30 6.6
3 4235 575 77 4.04 30 545 0.95 5.2
4 4570 650 94 5.96 41 609 1.30 6.3
5 3894 657 81 8.55 69 588 2.20 10.5
6 3623 858 99 29.42 256 602 8.12 29.8
7 5445 746 129 24.92 144 602 4.58 19.3
8 3608 790 90 22.46 196 594 6.23 24.8
9 4751 737 111 33.5 222 515 7.05 30.1
10 3119 810 80 39.25 396 414 12.58 48.9
11 4746 856 129 41.9 278 578 8.83 32.5
12 5342 768 130 37.44 221 547 7.01 28.7
13 5915 768 144 47.34 252 516 8.00 32.8
14 1561 709 35 8.24 166 543 5.28 23.5
15 3136 750 75 24.41 245 505 7.78 32.7
16 3642 753 87 24.46 212 541 6.72 28.1
17 7413 711 167 45.04 191 520 6.08 26.9
18 4529 710 102 19.45 135 575 4.29 19.1
19 4820 704 108 16.69 109 595 3.46 15.5
20 4858 919 142 65.44 424 495 13.47 46.2
88361 732 2051 508.8 182 551 5.76 25.0
23 (Isailovi, Srna 2002),
23 :
- 732 mm. ( , , , ),
113
800 900 mm/., 550 650 mm/.
- 25%, 75% .
- , - 10% , , 45%.
- , 1 2 l/skm2 , 12 13 l/skm2 . , 40 l/skm2 (, ), 60 l/skm2 ().
( ) 8%, ( ) 92% . .
37.320 km2. : 16,7% , 15.850 km2 15.400 km2. 64-67 (Q min), (Q ) (Q max) (), (), () ( ).
0
2000
4000
6000
8000
10000
1950-2000 2001 2002 2003 2004
Q(m3/s)
Q.Q.Qa.
64:
(: )
114
0500
100015002000250030003500
1950-2000 2001 2002 2003 2004
Q(m3/s)
Q.Q.Qa.
65:
(: )
0
2000
4000
6000
1950-2000 2001 2002 2003 2004
Q(m3/s)Q.Q.Qa.
66:
(: )
0
500
1000
1500
2000
2500
1950-2000 2001 2002 2003 2004
Q(m3/s)
Q.Q.Qa.
67: (: )
0,26. 0,2 0,7 .
115
E
2003. 2004. . . , .
, . .
116
68.
, , , , . , -
117
. .
, :
( mg C/l H2O), (
), (
, , 5 20C),
KMnO4 ( 1 .
Liebman-u pH
0102030405060708090
I II III IV
2003
2003
2004
2004
69. 2003. 2004. (:
)
2003. . 2003. 2002. . o 2003. . .
118
( , , ) . . 2004. .
69 a 97 2003. 94 2004. .
: ( ), , , , , , , , , , , , , , .
, 2003. II ( . .5/68).
2 ( 70). () (III-III/IV) (5, , , ). : (III/IV), (III/IV), F (III/IV) n. 2004. , , , a II . , -, ( , IV III ), 5 (III ). 7.7-8.8, III/IV . III . , ( ) II , , III/IV . - II III , 5 (III ). - III . : NO2-N (III/IV ), (III/IV ), Fe (III/IV ), S2-, r+6 Mn.
, , , .
119
2003. , III () . . III/IV . .
405060708090
100110120130140150160
%(2)
2003
2003
2003
2003
405060708090
100110120130140150160
%(2)
2004
2004
2004
2004
70. 2003. 2004. (: )
2004. , III . III (), III . (NH4-N) (N02-N) II . Mn.
2003. , III . 2 III, IV , IV . 5 III .
120
: (III/IV ), S2- (III/IV ) n.
0.0
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0
TOC (mg/l)
(g/l)
(g/l)
71. , 2003. (: .. )
2004. , ,
, . 2 III, IV (), III . , , Mn, S2-.
2003. , III . 2 IV , IV . : (III/IV ), S2- (III/IV ) F (III/IV ) n.
121
-5
-
pH-
I III I II III III I I I I III/IV II
I III I II III III I I I I III/IV II
I III I II III III I I I I III/IV II
II III I II IV III I I I I III/IV II
II III III I II III II I I I I III II
II III III I II II III I I I I III II
II III II I II III II I I I I II/III II
II III II I II II II I I I I III II
III III III I II III III I I I I III II
II III II I II II II I I I I III II
III III II I II II III I I I I III II
II III III I II III III I I I I III II
III III III I II IV II I I I I III II
III III III I II III I I I I I III II
III III III I II II I I I I I III II
III III II I II III I I I I I III II
I II II I II IV III II I I III III IIA
I III II I II IV II I I III III/IV III
II III I II - III II I I I III/IV III
I III II I II IV I II I III III/IV II
24. 2003.
2004. 2 IV , III . : S2- Mn.
122
-5
-
pH-
I III I II IV III I III I I III/IV II
I III I II II III I IV I I III/IV II
I IV II I II III III I III I I III II
I III III I II - III I III I I III II
I IV III I II III III I II I I III II
I III I II II III I III I I III II
II III I II II III I III I I III II
I III II I II II III I I I III III II
II III III I II II IV I I I I III II
II III II I II II III I I I I III II
II II II I II IV III I I I I III II
II III II I II II II I I I I III II
II III III I II II III I II I I III II
II II II I II II II I I I I II II
II III II I II II II I I I I II/III II
II III II I II II II I I I I II/III II
I III II I II II I II I III III II
I III II I II II II II II I I III III
I II I II I III II I I I III III
I IV III I II II III II II I I III II
25. 2004.
: ( ), , , .
2003. 2 . 5 III . ( III, III/IV ) 72. (III/IV ). ,
123
: F (III/IV ), (III/IV ), (III/IV ) n.
2004. , , II . -, (III ). 5 III . , III IV . (III/IV ) Mn.
04080
120160200240280320
(mg/l) 2003
2003
2003
2003
2003
04080
120160200240280320
(mg/l) 2004
2004
2004
2004
2004
72. 2003. 2004. (: )
, .
2003. , , . 2, 2 Mn III, IV , 5 III IV . (III/IV ), (III/IV ) (III/IV ). : (III/IV ) (III/IV ).
124
0,0
5,0
10,0
15,0
20,0
25,0
TOC (mg/l) (g/l) (g/l)
73. , 2003.
(: .. )
-5
-
pH-
III III III I II IV IV II I I I III/IV II
IV IV II I II IV II I I I III/IV II
IV IV III I II IV II I I I IV II
III III II I II III III II I I I III II
III III II I II IV III II I I I III/IV II
26. 2003.
2004. 2 2 III, IV , 5 Mn III IV . (III ), - NH4-N (IIMV ) - N02-N (III/IV ). : (III/IV ) Mn.
125
-5
-
pH-
II II III I II IV I I I I III/IV II II III III I II IV I I I I III/IV II
III III II I II IV I I I I III/IV II
III III II I II II I I I I III II
II III II I II IV II I I I III/IV II
27. 2004.
, -- () .
2003. IV . - (%2, 5, Mn ) III IV . : (III/IV ), (III/IV ), g ( ) n.
2004. . 2 2 III, IV ( ), -5 Mn III IV , III . , (NO2-N) III/IV . : Fe (III/IV), (III/IV ), (III/IV ), Hg ( ), ( ) Mn.
: ( ), ( ) .
2003. 2, 5 III IV , (III, IV ). : (III/IV ), F (III/IV ), (III/IV ) n.
126
2004. 2. 5 III IV , III IV . - NH4-N - NO2-N (III/IV ). : Fe (III/IV ), Hg ( ), (III/IV ), (IIMV ) Mn.
: ( ), .
2003. 2, 2 5 - III , III . (III/IV ). : (III/IV ) n.
2004. 2, 2, Mn 5 - III , III . - NH4-N - NO2-N (III/IV ). : Fe (III/IV), (III/IV ) Mn.
( ).
203. (III ). III/IV . (III/IV ), (III/IV ) n.
2004. IV . , 2 5 III . (III IV ). (NH4-N) (NO2-N) III/IV . : Fe (III/IV ) (III/IV ), r+6 Mn .
.
2003. , , . (III ), 2 (III ), 5 (III IV ) n (III, IV ). : (III/IV ) (III/IV ). , , , .
2004. IV .
127
2 (III ), 5 Mn (III IV ) (III ). a (NH4-N) III/IV . : Fe (III/IV ), (III/IV ) Mn.
. 2003.
( III/IV ). , , (III/IV ).
2004. III . (III IV ). , , Fe (III/IV ) (III/IV ).
. 2003. II/III .
- III . (III/IV ).
2004. II/III . 2, , , III . (III/IV ).
0.010.020.030.040.050.060.070.080.090.0
100.0
TOC (mg/l)
(g/l)
(g/l)
74. ,
2003. (: .. )
128
--
2003. () , :
-, , , I ( ) II ( )
-, - , -, I - , ,
, II II , , - , ( 1968. ). , 2 , . , .
-5
-
pH-
II III I II III I II I I I III/IV II
III IV IV II II II III I I III
III III IV IV III II III II III I I IV III
IV III II IV III I I I I III
III IV III I II IV II I I I I IV II
IV I II IV III I I I I II
III III II I II III IV I I I I III/IV II
III III III I II IV III I I I I III/IV II
II III III I II II III I I I I III/IV II
II II II I II II III I I I I III IIA
II II II I II III III I I I I III II
I III II I II II II I I I I II/III II
129
IV III IV II I I I II
III IV II III III II I I II
III II I II III II II I I I III/IV IIA
III IV II I II II II II I I I III II
1 III III I II II I II I I I III/IV II
2 IV III IV IV II I I I II
III III I II III II II I I I III/IV IIA
IV II II III II III I I II
1 IV II II IV III I I I I IIA
1 II III IV III II III III II III I I III/IV II
.. IV IV IV I II III III II I I I IV II
III III III I II II III II I I I III II
III III III I II III III I I I I III II
III III I II II III I I I I III/IV II
28. 2003. .
2003. 2, 2, 5 . (Mn II ), . : (III/IV ), S2- II ( ) ( III ), (III/IV ) n.
-5
-
pH-
III III III I II II II I II I I III/IV
IV III II II III II III I I III
III IV II II III II III I I
IV III III IV III I I I I III
IV IV III III II IV III I I I I IIA
IV IV III II IV II I I I II
II II II I II IV I I I I III/IV II
II II II III II III I I I I III II
III III III I II III III I I I I III II
I IV III I II IV I I I I IV II
II II II I II IV I I I I III II
I III II I II II III I I I I II/III II
130
IV III II IV II II I I I II
II IV IV III III IV II IV I I II
IV IV II II III II IV I I II
II IV II I II III I II I I I III/IV II
IV IV III I II II II II I I I III/IV II
1 III IV III III II III II II II I I III/IV II
2 II IV II III I I II
II III I II III III II II I I III/IV II
III II II II I I II
1 III IV III I II III II II II I I III/IV II
IV III I II II II II I I I III/IV II
III III I II III II I I I I III/IV II
1 III III III III II III III II III I I IV II
IV IV III II III IV II I I I
29. 2004. .
2004. 2 2. 2, 5 III, IV . (Mn II ), . ( , , , , , , , ) : (III/IV ), S2-, Fe(III/IV ), Hg ( ), r+6 Mn.
.
2003. 2 III-III/IV , 5 III . (III/IV ).
2004. 2 III, IV , 2 5 III . (NO2-N) y III/IV . (III/IV ) Mn.
131
0.05.0
10.015.020.025.030.035.040.045.050.0
I
II
TOC (mg/l)
(g/l)
(g/l)
75. ,
2003. (: .. )
.
2003. , . 2 2 , 5 n III . (III ). , : (III/IV ) , (III/IV ) Mn.
2004. 2 2 . 5 IV , Mn III IV . (III ) . , (III/IV ).
0200400600800
1 0001 2001 4001 6001 8002 000
-
-
-
-
-
-
-
-
-
-
-
1
-
2
-
(g/kg)
132
76. 2003.
(: .. )
: ( ) .
2003. , . n, 5 III, IV . (III/IV ). : (III/IV ), (III/IV ), Mn -.
2004. . 2 III IV . Mn III , 5 III IV . , - NH4-N (III/IV), - NO2-N (III/IV ). : Fe (III/IV ), Hg (III/IV ), (III/IV ) Mn.
. 2003. :
2, 2, n , 5 ( III ), ( III ), (III/IV ). (III/IV ). : F (III/IV ), Mn (III/IV ).
2004. : 2, 2, 5 ( III ). Mn III IV . -NH4-N, -N3-N -N2-N (III/IV ). : Hg (III/IV ), (III/IV ), r+6 Mn.
: ( ), , .
2003. 2 ( 77) III, IV , 5 III .
133
(III/IV ). : Fe (III/IV ), S2- (III/IV ), (III/IV ) Mn.
2004. . 2 III ( 77), (III ) . : (III/IV ) S2-.
60708090
100110120130140
%(2) 2003
2003
2003
2003
2003
.2003
60708090
100110120130140
%(2) 2004
2004
2004
2004
2004
.2004
77. 2003. 2004.
(: )
134
-5
-
pH-
II III III I II II II I I I I III II
II II III I II II II I I I I II/III II
II III II I II II III I I I I III II
II IV II I II II II I I I I III II
III IV III II II II II IV I I IV II
II IV III II II II II I I III
. III III I III II III II I IV
30. 2003.
-5
-
pH-
II III II I II II III I I I I II II
II II I I II II III I I I I III II
II II II I II II III I I I I II II
II III II I II II III I I I III II/III II
II IV III II II II II III I III IV III
III IV III II II III II III I III IV
. III IV III III III II II I
31. 2004.
, ( ). 2003. 2, 2, ,
5 n III, III/IV . .
135
2004. , III . 2 IV , 5 III IV , Mn III . III . .
( ).
2003. 2, 2, , 5, n III, III/IV . .
2004. , III . 2 III , 2 III, IV , 5 III IV , Mn III , III . III . .
.
2003. . , , . 2, 5 III , 2 . III , III/IV . Fe (III/IV ) Mn.
2004. . , , . 2, 5 Mn III , 2 IV , III . NO2-N NH4-N III/IV . (III/IV), (III/IV), Cr+6 (III/IV) Mn, S2-.
: ,
, .
2003. 2 III . .
136
2004. 2, , III IV . .
2003. III . .
2004. II/III . 2 III , III . .
: . 2003.
(III ). S2- (III / IV ).
2004. , III . , , III . , , (III/IV ), , S2-.
-5
-
pH-
I II I II II I I I I I II/III II
I II I II II I I I I I II/III II
I III II I II II III I I I I II/III II
I IV II I II II II I I I I II/III II
II III III I II II I I I I III II
I I I I II II III I I I I II II
32. 2003. .
. 2003. ,
, . III . .
137
2004. II . , , , III . 2 III . .
-5
-
pH-
I III - I II II II I II I I II II
I IV - I II II II I I I I II/III II
I III I I II II II I I I I II II
I II I I II II II I I I I II II
I III II I II II I I I I II/III II
I II I I II - I I I III II/III II
I II I I II II II I I I I II II
I III I I II II I I II I I II II
33. 2004. .
: ,
.
2003. 2 III , III . III . : (III IV ), Fe (III/IV ), S2- (III/IV ), (III/IV ) Mn.
2004. , III . , III . (III/IV ) r+6, S2-.
138
.
2003. 2, 2 III . Fe (III/IV ) Mn.
2004. III . Mn.
-5
-
pH-
III III II I II II III I I I I II/III IIA
II III II I II II III I I I I III IIA
III III II I II II II I I III III IIA
III III II I II II III II I I I II/III IIA
III III II I II II IV II I I III III IV
34. 2003. .
-5
-
pH-
II II II I II II IV I I I III III II
II II II I II II III I I I III III II
II II II I II II I I I III III II
II II II I II II III II I I III III II
II II II I II II III II I I III III IV
35. 2004. .
139
. 2003. 2
2 III , III . Fe (III/IV ) Mn.
2004. , III . 2 2, , III , III IV . Mn.
: , , , , , .
020406080
100120140160180
(mg/l)
2003
2003
2003
2003
0
40
80
120
160
200
240
280
(mg/l)
2004
2004
2004
2004
78. a
2003. 2004. (: )
140
2003. , , , III , . 2, 2, 5 ( 78) , III . (III/IV ) . S2- (III/IV ), (III/IV ), (III/IV ), Hg ( ) Mn.
2004. , III . 2 III IV , ( 78) III IV . S2-, (III/IV ), r+6 Mn.
.
2003. 2 2 III . Fe (III/IV ) Mn.
2004. 2 III , III IV . .
. 2003. 2
IV . (III/IV ) Mn.
2004. 2 III IV , III . (III/IV ) Mn.
. 2003. III , IV , III/IV . : Fe (III/IV ), (III/IV ) Mn.
2004. . , . , 2 III IV . III , NH4-N, III/IV , aa (N2-N) III/IV .
141
: (III/IV ) Mn.
. 2003. ,
, III . 2 2 IV , 5 IV , III . , III/IV . , , Fe (III/IV ), (III/IV ) Mn.
2004. . , , III . 2 2 III , 5 III IV , III . NH4-N aa N2-N III/IV . Mn.
. 2003. 2 IV
, 5 III . : Fe (III/IV ), Mn S2- (III/IV ).
2004. . , . 2 , , III , III . aa N2-N, , III/IV . .
. 2003. 2 2
III IV , . III/IV . : Fe (III/IV ), Mn, (III/IV ) S2- (III/IV ).
142
-5
-
pH-
I III III I II IV III I I I III III/IV IIA
II II III I II IV II I III I I III/IV IIA
II III III I II III III I I I III III/IV IIA
II II III I II III III I I I III III IIA
I III III I II II IV I I I III III IIA
I II III I II III III I I I III III/IV IIA
III IV II I II IV II I I I I III/IV IIA
II III II I II IV II I I I III/IV IV
IV IV IV II III IV III II I I III IV
I IV III I II IV III I I I I III/IV III
IV IV III I II IV II I I I IV IIA
36. 2003. .
2004. . 2 2 III IV , 5 III , , , IV . Mn.
. 2003. ,
, . III . , III . (III/IV ) Mn.
2004. , , . 5 III , , Mn III IV . NH4-N , NO2-N III/IV .
143
(III/IV ), r+6 Mn.
-5
-
pH-
I II II I II III I II I I III II
II II - I II IV III I - I III - II
I IV III I II - III I I I III III/IV II
I IV - I II II IV I I I III III/IV II
I III - I II II III I II I III III/IV II
I IV - I II II III I I I III III/IV II
II III - I II II III I - I I - II
I III - I II III I - I I - IV
- - - IV - II II - I - II
III III - I III II II - III - IV
I III - I II II II - I I - III
37. 2004. .
: , , , , .
2003. 2 III , 5 III . III . Fe (III/IV ) Mn.
2004. 2 III IV , III . , III . (III/IV ), S2- Mn.
.
144
2003. 2 III , 5 III . S2- (IV ) Mn.
2004. 2 III . NO2-N III/IV . S2- Mn.
. 2003. ,
( ). 2 5 III . .
2004. . , . 2 III . Mn.
. 2003. 2 III
. .
2004. . , III . III . Mn.
. 2003. 2
III, IV , n 5 III IV . III, IV , III/IV , . Fe (III/IV ) Mn.
2004. , . III . 2 , III . Mn.
. 2003. 2
III, IV , 5 III . .
2004. , . , , III . 2 , ,
145
III , III . , , Mn.
. 2003. 2
III, IV , 5 III . . Mn.
-5
-
pH-
I III II I II IV III I I I I III II
I III III I II IV II I I I I III II
I IV III I II III I I I I I III II
I II II I II III III I I I I II/III IIA
I II I II - III I I I III III IIA
I IV III I II IV I I I I I III/IV IIA
I III III I II IV II I I I III/IV IIA
I III II I II II II I I I I II/III IIA
II IV III III IV II I I IIA
I III I III III II II I I I III/IV II
II III I II III II II I I I IV IV
38. 2003.
2004. , , , , . , 2 III . Mn.
. 2003. 2
, III . .
2004. , .
146
2 III , III . .
-5
-
pH-
I II - I II IV III I I I I III II
I III - I II IV III I I I I III II
I II - I II II III I II I I II/III II
I II - I II IV III II II I III III II
I IV - I II - I II I III - II
I IV - I II - I II I III - II
I III - I II - II I I I I - IV
I III - I II - III I I I III - II
I II - I II - III I III I I - II
II III - I - - II I I I III - II
I III - I II IV II III I III III/IV II
III III - I II IV III II I I III III/IV IV
39 2004.
,
.
2003. 2 III , 5 III IV . - III , III . : Fe (III/IV ), S2- (III/IV ), (III/IV ) Mn.
2004. III . 2 III IV , , , III . - III .
147
, , : (III/IV ) S2- Mn.
-5
-
pH-
I II III I II - III I I I I III IIA
I III II I II III III I I I I III IIA
I II II I II IV IV I I I III III IIA
I III - I - - III I I I I - II
I II II I II II III I III I I II/III I
40. 2003. .
-5
-
pH-
I III - I II - I I I III - II
I III - I II IV I II I III III/IV II
I II - I II IV IV I III I III III/IV II
I II - I - - I I I - II
I II II I II - IV I III I I II/III I
41. 2004. .
. 2003. III ,
2 IV . Fe (III/IV ) Mn.
2004. , .
148
III .
Mn.
. 2003. III
, - III/IV . .
2004. . , , III , - IV , III . Mn.
,
, , , . 2003.
. , III . 2 ( III ), 5 (III IV ), ( III ) (III /IV ). Mn.
2004. , III . : 2 (III ), 5 (III ), ( III ) (III /IV ). : Fe (III/IV ).
. 2003. 2 III
. 5 III . .
2004. 2 III . .
. 2003. , , ,
2, 5 III .
149
2004. II . III . Fe (III/IV).
. 2003. , ,
III , 5 IV , 2 .
2004. , , . 2, , III IV . (III ), , , III . .
. 2003. , , , 5
III , 2 .
2004. , , . 2 , , IV, III . .
: , .
2003. , - III , 2, III IV . n IV , 5 III . III . Fe (III/IV ) Mn.
2004. , - , , . III ( ), 2 III . - 5 III IV , III .
. 2003. , , ,
. 2 III , 2 III IV . n IV , 5 III . (III/IV ). (III/IV ).
150
2004. III . III IV . 2 , , III ( ), 5 III IV . Mn . III . (III/IV ).
( ), , .
2003. , , . 2 . 5 III , III IV . Mn.
2004. 2 - III, IV (). , , III, IV . .
. 2003. , 2 5
III . .
2004. , II . .
.
2003. II . .
2004. III . , , III . .
. 2003.
I . .
151
2004. II/III . , , III (). , , (III/IV ).
. 2003. ,
III . 2004. III ,
III . III . Fe(III/IV ) Mn.
. 2003.
IV . 2004. .
. III . Fe (III/IV ) Mn.
. 2003. 2, ,
III . .
2004. , III . 2 , , (), , , III . .
. 2003. 2
III . .
2004. III . III , 2 III . .
.
152
2003. II .
2004. , 2, , III .
, (- ,- ,- ) (1- ,2- ,3- ).
2003. , : -1, -
2, -3, -1, -2, -3, -1, -2 -3 ( ). (III/IV ) . 2 2 -2, -3, -3. Mn -3 -3 III , III/IV . : S2- (III/IV ) Mn.
2004. . , III/IV . , 2 -2, -3, -2, -3 -3 (III IV ), (III ). 5 A-1, -1 B-1 III , aa (N2-N) -3 -3 III/IV . , , S2- Mn.
2003. . 2 ( I ), 2 . 5 III , -1, -2, -3 -3 III/IV . S2- , (III/IV ) Mn.
2004. . , III/IV
153
. 2 -2, -3, -2, -3 -3 (III IV ), A-1, -1 -1 (III ). aa (N2-N) -2, -3, -2, -3, B-1 -3 III/IV , . , , S2-, -3 (III/IV ), II -2, -3, -1, -2, B-1, -2 -3.
2003. . 2 2 . -1, -2 -3 III . S2- (III/IV ).
2004. . A-1, -1, B-1, -2 -3 , IV . 2 -3, -3 (IV III ),