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Cypress Sandstone Background Nathan D. Webb, Nathan P. Grigsby, Scott M. Frailey Illinois State Geological Survey, Prairie Research Institute, University of Illinois at Urbana-Champaign, [email protected] Identifying indicators of residual oil zone formation in the Illinois Basin Acknowledgments This research is funded by the U.S. Department of Energy through the National Energy Technology Laboratory (NETL) contract number DE- FE0024431. Project Description The thick Cypress Sandstone is being investigated in the Illinois Basin to determine if a basin-wide residual oil zone (ROZ) exists. To form a ROZ, oil must be emplaced throughout the formation and then be displaced by natural brine migration over geologic time. Studies have focused on the mechanisms of ROZ formation and localized ROZ indicators, but, by understanding the regional consequences of ROZ formation, additional criteria emerge for ROZ identification. For example, if the Cypress Sandstone contains a ROZ, the thickness and areal extent of the sandstone across the Basin implies huge fluid flux. Thus, a regional ROZ has broad implications for the Basin, raising questions as to where the displaced oil went and from where the invading water was sourced. The Cypress Sandstone is truncated in the subsurface along its northern and western termini by younger Pennsylvanian strata along an angular unconformity, whereas the southern and eastern boundaries are exposed in outcrop. Depending on the timing of oil emplacement and basinal hydrodynamic regime, three possible ROZ indicators are postulated: (1) oil was trapped below the unconformity to the north or west or passed into overlying Pennsylvanian sandstones, (2) migrated to the south or east where oil seeps and tar mats might be expected in the outcrop belt, or (3) migrated into updip Cypress strata that were subsequently eroded in the geologic past. Integrating studies of fluid properties with broader regional indicators via basin analysis increases confidence in the mechanisms of ROZ formation and aids in identifying ROZs. References Bristol, H. M., & Treworgy, J. D. (1979). The Wabash Valley Fault System in Southeastern Illinois (C 509). Urbana, IL: Illinois State Geological Survey. Lewan, M. D., Henry, M. E., Higley, D. K., & Pitman, J. K. (2002). Material-balance assessment of the New Albany-Chesterian petroleum system of the Illinois basin. AAPG Bulletin, 86(5), 745 777. Mariño, J., Marshak, S., & Mastalerz, M. (2015). Evidence for stratigraphically controlled paleogeotherms in the Illinois Basin based on vitrinite-reflectance analysis: Implications for interpreting coal-rank anomalies. AAPG Bulletin, 99(10), 18031825 May, M. T. (2013). Oil-saturated MississippianPennsylvanian Sandstones of South-central Kentucky. In F. J. Hein, D. Leckie, S. Larter, & J. R. Suter (Eds.), Heavy-oil and oil-sand petroleum systems in Alberta and beyond (AAPG Studi., pp. 373406). Melzer, L. S. (2006). Stranded Oil in the Residual Oil Zone. Stueber, A. M., Walter, L. M., Huston, T. J., & Pushkar, P. (1993). Formation waters from Mississippian-Pennsylvanian reservoirs, Illinois basin, USA: Chemical and isotopic constraints on evolution and migration. Geochimica et Cosmochimica Acta, 57, 763784. Indicators to Look For Residual oil saturation in outcrops; tar seeps How ROZs Form Potential ROZ Forming Mechanisms in the Illinois Basin Petroleum Migration/Emplacement in the Cypress Thick sandstones are Nonconventional CO 2 - EOR target and have potential for residual oil zones (ROZ) If a ROZ exists, how did it form and what are the geologic consequences of its formation? Oil escaped Cypress into Pennsylvanian sands along faults in drape folded strata along the La Salle Anticline (Type 2 ROZ)? Pennsylvanian producing areas in Illinois Basal Pennsylvanian channels incise almost to the level of the Cypress Sandstone? Heavy oil sands near outcrop belt Tar Springs Sandstone, Kentucky Tar seep, Kentucky (May 2013) Maps of heavy oil deposits in sandstones above the Cypress Ss, Kentucky (May 2013) Geochemical and compositional evidence of biodegradation of Cypress Sandstone oils Decrease in API Gravity and n-alkanes Sterane and hopane biomarkers absent Evidence of compositional changes resulting from secondary migration through the Cypress Sandstone into overlying formations Evidence of petroleum trapped in fault sealing mineral cements Evidence that magnitude of tilt of oil-water contacts reflects tectonic or isostatic movements Steuber et al 1993 Oil migrated to northwest and was trapped in Loudon Anticline and/or trapped under Penn/Miss unconformity or migrated into Pennsylvanian sands (Type 3 ROZ)? Oil migrated to west and was trapped in fields along the DuQuoin Monocline (Type 3 ROZ)? Bristol and Treworgy 1979 Secondary migration from mature source (orange) driven by buoyancy and hydrodynamic flow followed catchments emplaced in the Cypress Ss over much of the basin Tectonic forces or isostatic rebound causes Cypress Sandstone oil reservoirs to re-equilibrate (Type 1 ROZ)? Map of Cypress Sandstone depositional facies and productive areas May 2013 Modified from Melzer 2006 Mariño et al 2015 Mod from Lewan et al. 2002 Right: Diagram of events in the Illinois Basin petroleum system (from Lewan 2002) Oil escaped Cypress Sandstone into shallower Chesterian and Pennsylvanian sands along WVFS (Type 2 ROZ)?

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Cypress Sandstone Background

Nathan D. Webb, Nathan P. Grigsby, Scott M. FraileyIllinois State Geological Survey, Prairie Research Institute, University of Illinois at Urbana-Champaign, [email protected]

Identifying indicators of residual oil zone formation in the Illinois Basin

AcknowledgmentsThis research is funded by the U.S. Department of Energy through the

National Energy Technology Laboratory (NETL) contract number DE-

FE0024431.

Project DescriptionThe thick Cypress Sandstone is being investigated in

the Illinois Basin to determine if a basin-wide residual oil

zone (ROZ) exists. To form a ROZ, oil must be

emplaced throughout the formation and then be

displaced by natural brine migration over geologic time.

Studies have focused on the mechanisms of ROZ

formation and localized ROZ indicators, but, by

understanding the regional consequences of ROZ

formation, additional criteria emerge for ROZ

identification. For example, if the Cypress Sandstone

contains a ROZ, the thickness and areal extent of the

sandstone across the Basin implies huge fluid flux.

Thus, a regional ROZ has broad implications for the

Basin, raising questions as to where the displaced oil

went and from where the invading water was sourced.

The Cypress Sandstone is truncated in the

subsurface along its northern and western termini by

younger Pennsylvanian strata along an angular

unconformity, whereas the southern and eastern

boundaries are exposed in outcrop. Depending on the

timing of oil emplacement and basinal hydrodynamic

regime, three possible ROZ indicators are postulated:

(1) oil was trapped below the unconformity to the north

or west or passed into overlying Pennsylvanian

sandstones, (2) migrated to the south or east where oil

seeps and tar mats might be expected in the outcrop

belt, or (3) migrated into updip Cypress strata that were

subsequently eroded in the geologic past. Integrating

studies of fluid properties with broader regional

indicators via basin analysis increases confidence in the

mechanisms of ROZ formation and aids in identifying

ROZs.

References

Bristol, H. M., & Treworgy, J. D. (1979). The Wabash Valley Fault System in Southeastern Illinois

(C 509). Urbana, IL: Illinois State Geological Survey.

Lewan, M. D., Henry, M. E., Higley, D. K., & Pitman, J. K. (2002). Material-balance assessment of

the New Albany-Chesterian petroleum system of the Illinois basin. AAPG Bulletin, 86(5), 745–

777.

Mariño, J., Marshak, S., & Mastalerz, M. (2015). Evidence for stratigraphically controlled

paleogeotherms in the Illinois Basin based on vitrinite-reflectance analysis: Implications for

interpreting coal-rank anomalies. AAPG Bulletin, 99(10), 1803–1825

May, M. T. (2013). Oil-saturated Mississippian–Pennsylvanian Sandstones of South-central

Kentucky. In F. J. Hein, D. Leckie, S. Larter, & J. R. Suter (Eds.), Heavy-oil and oil-sand

petroleum systems in Alberta and beyond (AAPG Studi., pp. 373–406).

Melzer, L. S. (2006). Stranded Oil in the Residual Oil Zone.

Stueber, A. M., Walter, L. M., Huston, T. J., & Pushkar, P. (1993). Formation waters from

Mississippian-Pennsylvanian reservoirs, Illinois basin, USA: Chemical and isotopic constraints on

evolution and migration. Geochimica et Cosmochimica Acta, 57, 763–784.

Indicators to Look For• Residual oil saturation in outcrops; tar seeps

How ROZs Form

Potential ROZ Forming Mechanisms in the Illinois Basin

Petroleum Migration/Emplacement in the Cypress

• Thick sandstones are

Nonconventional CO2-

EOR target and have

potential for residual oil

zones (ROZ)

• If a ROZ exists, how

did it form and what

are the geologic

consequences of its

formation?

Oil escaped Cypress into Pennsylvanian

sands along faults in drape folded strata

along the La Salle Anticline (Type 2 ROZ)?

Pennsylvanian producing areas in Illinois

Basal Pennsylvanian

channels incise almost

to the level of the

Cypress Sandstone?

• Heavy oil sands near outcrop belt

Tar Springs Sandstone, Kentucky Tar seep, Kentucky (May 2013)

Maps of heavy oil deposits in sandstones above the Cypress Ss, Kentucky (May 2013)

• Geochemical and compositional evidence of

biodegradation of Cypress Sandstone oils

• Decrease in API Gravity and n-alkanes

• Sterane and hopane biomarkers absent

• Evidence of compositional changes resulting from

secondary migration through the Cypress Sandstone

into overlying formations

• Evidence of petroleum trapped in fault sealing mineral

cements

• Evidence that magnitude of tilt of oil-water contacts

reflects tectonic or isostatic movements

Steuber et al 1993

Oil migrated to

northwest and was

trapped in Loudon

Anticline and/or

trapped under

Penn/Miss

unconformity or

migrated into

Pennsylvanian sands

(Type 3 ROZ)?

Oil migrated to west

and was trapped in

fields along the

DuQuoin Monocline

(Type 3 ROZ)?

Bristol and Treworgy 1979

• Secondary migration from

mature source (orange)

• driven by buoyancy and

hydrodynamic flow

• followed catchments

• emplaced in the Cypress Ss over

much of the basin

Tectonic forces or isostatic rebound causes Cypress

Sandstone oil reservoirs to re-equilibrate (Type 1 ROZ)?

Map of Cypress Sandstone depositional

facies and productive areas

May 2013

Modified from Melzer 2006 Mariño et al 2015

Mod from Lewan et al. 2002

Right: Diagram of events in the Illinois

Basin petroleum system (from Lewan

2002)

Oil escaped Cypress Sandstone into

shallower Chesterian and Pennsylvanian

sands along WVFS (Type 2 ROZ)?