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Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets Nano Lett. 2011, 11, 5227-5233

Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

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Page 1: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Nano Lett. 2011, 11, 5227-5233

Page 2: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Graphene Oxide (GO)

1) 10% w/w Eu2O3

2) heated 8000C at 100C/min, 2h

3) Treated with conc. HNO3

4) Filtered and washed with DI water

5) Heated in an air oven at 1000C for 12 h

Luminescent graphene (LG)

Synthesis of Luminescent Graphene

Page 3: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Structural and Chemical Characterization

Page 4: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Structural and Chemical Characterization

Page 5: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Electron Microscopic Characterization

Page 6: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Electron Microscopic Characterization

Page 7: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Spectroscopic Characterization

Page 8: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Spectroscopic Characterization

Page 9: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Optical Bifunctionality

Page 10: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

Conclusions

Luminescent graphene was synthesized using easily available starting materials and simple technique.

A shift in the photoluminescence from 611 nm (Eu2O3) to 618 nm is due the complexation of Eu3+ with graphene was established.

Optical bifunctionality of the luminescent graphene was studied.

Page 11: Optical Bifunctionality of Europium-Complexed Luminescent Graphene Nanosheets

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