Biofuels
Sustainable developmentProf. Melania Muñoz
• fuels derived from biomass (organic materials). • In order to be considered a biofuel the fuel must contain over
80% renewable materials• The term covers solid biomass, liquid fuels and
various biogases.
Sustainable development Prof. Melania Muñoz G.
What is a biofuel?
Biofuels are gaining increased public and scientific attention.
Factors:
• Need for increase energy security
• Concern over greenhouse gas emission from fossil fuels
• Are portable and clean burning
Sustainable development
Prof. Melania Muñoz G.
Biofuels
Sustainable development
Prof. Melania Muñoz G.
Bioethanol production
Sustainable development
Prof. Melania Muñoz G.
Biodiesel production
• Made from:– Sugar– Starch– Vegetable oil– Animal fat
• Basic feedstocks:– Seeds and grains
Sustainable development
Prof. Melania Muñoz G.
First-generation biofuels
Why is it controversial?
Sustainable development
Prof. Melania Muñoz G.
First-generation biofuels
The use of this feedstocksin producing biofuels has been criticised
for diverting food away from the human food chain, leading to food shortages and price risesSustainable development
Prof. Melania Muñoz G.
First-generation biofuels
Major feedstockSustainable development
Prof. Melania Muñoz G.
• Produced by the action of microorganisms and enzymes through the fermentation of sugars or starches
• Sugars are obtained from wheat, corn, sugar beets, sugar cane
• Most common: ethanol• Also: propanol and butanol
Sustainable development
Prof. Melania Muñoz G.
First-generation biofuels
Bioalcohols
Sustainable development
Prof. Melania Muñoz G.
Sustainable development 2012 Prof. Melania Muñoz G.
Taboga
• Edible oil is generally not used as a fuel
• Lower quality oil is used
• It is processed into biodiesel or (more rarely) used directly as a fuel
Sustainable development
Prof. Melania Muñoz G.
First-generation biofuels
Vegetable oil
• Biodiesel is typically made by a chemical reaction(transesterification) : lipids + alcohol = fatty acid esters(e.g., vegetable oil, animal fat)
Biodiesel
Feedstock:Oils: e.g. canola, algae, jatropha and salicornia
• Use traditional fractional distillation to process the oils
• Do not confuse it with biodiesel
(chemical reaction)
First-generation biofuels
Green diesel
It is methane produced by the process of anaerobic digestion of organic material:
• biodegradable waste materials• energy crops
– feed anaerobic digesters
• The solid (or liquid) byproduct, digestate, can be used as a fertilizer
• Farmers can produce biogas from manure from their cows by getting a anaerobic digester (AD)Sustainable development
Prof. Melania Muñoz G.
First-generation biofuels
Biogas
Sustainable development 2012 Prof. Melania Muñoz G.
First-generation biofuels
Biogas
Organic fertilizer
Gas. E.g. kitchen
Turbine and generator:electricity
• Examples:– Wood– Sawdust– grass trimmings– domestic refuse– Charcoal– agricultural waste– non-food energy crops– dry manure.
• When raw biomass is already in a suitable form (such as firewood), it can burn directly in a stove or furnace to provide heat or raise steam
Sustainable development
Prof. Melania Muñoz G.
First-generation biofuels
Solid biofuel
Fisrt generation biofuels
Made from sugar and vegetable oils
Easily extracted using
conventional technology
Sustainable development
Prof. Melania Muñoz G.
Second generation biofuels
Second generation
biofuels
Made from lignocellulosic biomas or woody crops, agricultural residues or
waste
Makes it harder to extract the requiered fuel
FOOD
NO FOOD
Sustainable development Prof. Melania Muñoz G.
Use modern and proven green chemical technologies
including pyrolysis, Fisher Tropsch, and other catalytic processes, in order to produce biofuels
Second generation biofuels
Some microoganism in
some insects species
Gliocladium roseum
• Production of myco-diesel from cellulose.
• Was discovered in Patagonia
• Has the unique capability of converting cellulose into medium length hydrocarbons typically found in diesel fuel.
Sustainable development
Prof. Melania Muñoz G.
Second generation biofuels
RESEARCH!
It is fuel from algae
• Algae are low-input, high-yield feedstocks to produce biofuels.
• Algae can produces up to 30 times more energy per acre than land crops such as soybeans
• But these yields have yet to be produced commercially.
Sustainable development
Prof. Melania Muñoz G.
Third generation biofuels
GMOs
• GM Saccharomycescerevisiae (yeast)
• farnesene synthase from the plant Artemisia annua
• Commercial production of hydrocarbon farnesene (C15H24)
Sustainable development
Prof. Melania Muñoz G.
GMOs
GM Algae
• Oil Production• Biofuels• Food• Cosmetics
Sustainable development
Prof. Melania Muñoz G.
GMOs
Confined areasSustainable development
Prof. Melania Muñoz G.
• Good option to produce cleaner energy
• Controversy still exist
• More research and technology is needed to produce second and third generation biofuels
Sustainable development
Prof. Melania Muñoz G.
Biofuels
Sustainable development 2012 Prof. Melania Muñoz G.
• http://tedxtalks.ted.com/video/TEDxAtlanta-Harrison-Dillon-Res;search%3Abiotechnology
• http://tedxtalks.ted.com/video/TEDxNASASiliconValley-Bilal-Bom;search%3Aalgae%20fuel
Third generation biofuels