WILLIAM BAKER TOLMAN

Department of Chemistry and Tel.: 612-625-4061 Center for Metals in Biocatalysis FAX: 612-626-8659 University of Minnesota E-mail: wtolman@umn.edu 207 Pleasant St. S.E. http://www.chem.umn.edu/groups/tolman/ Minneapolis, MN 55455-0431 Birthdate: May 20, 1961

8/09-present University of Minnesota, Minneapolis, MN. Chair, Department of Chemistry.

7/05-7/10 University of Minnesota, Minneapolis, MN. Lee Irvin Smith Professor, Department of Chemistry.

7/00-present University of Minnesota, Minneapolis, MN. Distinguished McKnight University Professor, Department of Chemistry, Center for Metals in Biocatalysis, Center for Sustainable Polymers.

7/97-7/00 University of Minnesota, Minneapolis, MN. Professor, Department of Chemistry and Center for Metals in Biocatalysis.

8/96-6/97 University of California, Berkeley, CA. Visiting Professor, Department of Chemsitry and Miller Institute for Basic Sciences Research. Sponsor: Professor Judith Klinman.

7/94-7/97 University of Minnesota, Minneapolis, MN. Associate Professor, Department of Chemistry and Center for Metals in Biocatalysis.

8/90-7/94 University of Minnesota, Minneapolis, MN. Assistant Professor, Department of Chemistry.

10/87 - 7/90 Massachusetts Institute of Technology, Cambridge, MA. Postdoctoral Fellow in the laboratory of Professor Stephen J. Lippard.

8/83 - 9/87 University of California, Berkeley, CA. Ph.D. in Chemistry (1987). Advisor: Professor K. Peter C. Vollhardt.

9/79 - 6/83 Wesleyan University, Middletown, CT. B.A. in Chemistry (1983). Undergraduate research in the laboratory of Professor Alan Cutler.

AWARDS 2017 ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry 4/12 Charles E. Bowers Teaching Award, College of Science & Engineering, University of

Minnesota 7/10 Fellow of the American Chemical Society 11/06 Fellow of the American Association for the Advancement of Science 8/05 Lee Irvin Smith Professorship (University of Minnesota) 8/04-8/05 Alexander von Humboldt Foundation Research Award (@Technical University of Munich) 9/01 Buck-Whitney Medal (ACS Eastern New York Section) 7/00 Distinguished McKnight University Professorship (University of Minnesota) 6/98 George W. Taylor Award for Excellence in Research (University of Minnesota) 6/94-5/99 Camille & Henry Dreyfus Teacher-Scholar Award 6/93-6/98 National Young Investigator Award (National Science Foundation) 9/96-6/97 Bush Sabbatical Supplement Award (University of Minnesota). 1/97-5/97 Visiting Professorship, Miller Institute for Research (University of California, Berkeley). 9/94-10/96 Alfred P. Sloan Foundation Research Fellowship 7/92-6/95 Searle Scholar Award (Chicago Community Trust) 7/92-6/94 McKnight-Land Grant Professorship (University of Minnesota)

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5/94 George W. Taylor Career Development Award (University of Minnesota) 1/88-7/90 Postdoctoral Fellowship (American Cancer Society) 10/87-1/88 Postdoctoral Fellowship (National Institutes of Health) 1984-85 W.R. Grace Fellowship (University of California, Berkeley) 1983-84 University Fellowship (University of California, Berkeley) 1983 University Honors (Wesleyan University) 1983 Phi Beta Kappa (Wesleyan University) 1983 Sigma Xi (Wesleyan University) 1982 Analytical Chemistry Award, American Chemical Society (Wesleyan University) TEACHING

Classes Taught

Undergraduate Elementry Organic Chemistry I (Chem 3301, W'96, F’97; Chem 2301 F’02, F’06, F’07(x2),

F’08 (x2), F’14, S’15, F’15) Elementary Organic Chemistry II (Chem 3302, F'90, S'92, W'93, S’96, S’98; Chem 2302

S’03, S’04, F’05, S’07). Honors General Chemistry I (Chem 1051H, W’99; Chem 1031, F'99, F'00) Honors General Chemistry II (Chem 1052H, S’99; Chem 1032, S'00) Green Chemistry (Chem 4601, S’11, S’12) Honors Elementary Organic Chemistry I (Chem 2331, F’ 12) Graduate Physical Inorganic Chemistry II (Chem 8752, W'92) Bioinorganic Chemistry (Chem 5765, W'91, Chem 8752, W‘95, Chem 8765, S‘95, W’98,

F’01, S’06) Mechanisms of Chemical Reactions (Chem 8002/8011, F’92, F'93, F'94, F'95, F’03).

Undergraduate Students (1990-present); total = 48

Brooke Benson 6/16-8/16 Nathaniel Larson 6/16-8/16 Paremesh Ramaraj 1/15-present Alex Benson 9/15-present Devon Urness 9/15-present Janaya Sachs (Lando) 6/15 – 8/15 Hillis Johns 6/15 – 8/15 Levi Hogan 1/14 – present Luis Torrealba 9/13 – 8/14 Yvonne Deporrey 6/12 – 8/12 Joy Zhou 6/10 – 6/11 Eric Hermes 6/10 – 8/11 Erinn Brigham (Lando) 6/10 – 8/10 Justine Olsen 9/09 – 8/10 Spencer Knight 6/09 – 6/12 Bridget Ulrich 1/08 – 9/09 Benjamin Naab 7/08 – 8/08 Christopher McGuirk 7/08 – 6/09 Joseph Kumka 10/07- 6/09 David Pearson 6/07 – 8/07 Lisa Wang 6/07 – 8/07 Leslie O’Leary 5/06 – 8/07 David Heppner 1/06 – 5/07 Elizabeth Devine 1/05 – 12/05 Nicole Holm (Lando) 6/04 – 8/04

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Loren Greenman 9/03 – 6/05 Thomas Fillman 9/03 – 6/04 Scott Eastman (Lando) 6/03 - 8/03 Brandon Johnson 5/03 – 6/05 Phil Jensen 9/02 – 9/03 Dejan Petrovic (Lando) 6/02 - 8/02 James Kong 12/01 - 7/03 Theresa Zahn (Kückmann) 9/99 - 6/02 Susanne Monnier (Lando) 6/00 - 8/00 Adam Westman (Lando) 6/00 - 8/00 Karen Chang (Lando) 6/99 - 8/99 Eric Hemmesch 9/98 - 6/00 Paul Boucher 9/98 - 5/00 Justin Weaver (Lando) 6/98 - 8/98 Melanie Nicholson 9/96 - 6/97 Michael Kavana 1996 John Cahoy 5/96 - 6/00 Alan Gengenbach 9/93 - 8/95 Colleen Havlin 1995 Bernice Lam (Lando) 6/95 - 8/95 Candyce Kroenke 1993 Jeanette Stallons 1992 Daniel LeCloux (Dupont) 1990-92

Graduate Students (1990-present); total = 45 (20 Ph.D.s granted)

Christy Ruggiero (Ph.D., 1995), pdoc fellow, Los Alamos National Laboratory, NM. Susan Carrier (Ph.D., 1995), research scientist, Dupont Central Research, DE. Veronical Reynolds (M.S., 1994), Environmental Lab Tech., Photocircuits Inc. NY. David Christenson (M.S., 1995), scientist/technician, 3M Company, MN. Jason Halfen (Ph.D., 1996), Professor, U. Wisconsin, Eau Claire, WI. Robert Houser (Ph.D., 1996), Professor, University of Oklahoma, Norman, OK. Christopher Tokar (Ph.D., 1997), postdoc with M. Johnson (U. Minn.). Michael Keyes (Ph.D., 1997), Director of Knowledge Management, Ciceron Interactive,

Minneapolis, MN. Bradley Chamberlain (Ph.D., 1999), Associate Professor, Luther College, IA. Jamie Schneider (Ph.D., 1999), Lecturer, Winona State University, MN. Brian Jazdzewski (Ph.D., 2000), research scientist, Dow Chemical Co., SC. Bernice Lam (M.S., 1998), staff scientist, Advanced Medicine, Inc., CA. Scott Caltagirone (1997-99), graduate student, University of Washington. Lynneice Bowen (1999-2000). Kevin Bechtold (M.S., 2001), staff scientist, Cargill-Dow LLC, MN. Anne Reynolds (Ph.D., 2005), patent agent, Michael Best and Friedrich, Madison, WI.

Clarke Price (2000-2001) Nermeen Aboelella (Ph.D. 2005), Scientist, Dow Research, Houston, TX. Laurie Breyfogle (Ph.D., 2005), staff scientist, Proctor & Gamble, Cincinnati. Jianyan Xu (2001) John York (2002-2007, Ph.D. 2007), Associate Professor, Stetson College, FL. Erin Hilton (M.S., 2005) Carolyn Gamble/Wanamaker (2004-2008, Ph.D. 2008), Instructor, Normandale Community College Sungjun Hong (2004-2010, Ph.D. 2010) Scientist, Korea Research Institute of Chemical Technology Jennifer Lowe (2005-2010, Ph.D. 2010), Scientist, Dow, PA.

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Jessica Hilborn (2005-2007, M.S. 2007, lab coordinator/lecturer, Gustavus Adolphus) Sara Palavicini (visitor from U. Pavia, 2006) Erin Arndt (2006-2008, M.S. 2008) Aalo Gupta (2006-2011, Ph.D. 2011), Team Lead, Biofuels - Novel Processes, Phillips 66. Jacqui Tehranchi (Ph.D. 2013), Scientist, Beckman Coulter. David Boyce (Ph.D. 2014), postdoctoral associate U. Delaware. Maria Miranda (2009-2014, Ph.D. 2014), Scientist, 3M Stephanie Roe (2010-2013) Elizabeth Korsmo (2011-12) Gereon Yee (2011-present) Benjamin Neisen (2011-present) Hongtu Zhang (2012-2014, M.S. 2014) Dabanjan Dhar (2012-present) Nicole Gagnon (2012-present) Che (Tom) Wu (2013-2014) Hanna Macaranas (2013-present) Leon Lillie (2014-present) Courtney Ellwell (2014-present) Anna Luke (2015-present) Husnain Sajjad (2015-present)

Postdoctoral Associates (1990-present); total = 49

Dr. Peter Kettler (pdoc, 1992), Director of Research and Development, Colonial Metals, Inc. Dr. Masahisa Osawa (pdoc, 1993), Staff Scientist, RIKEN, Japan Dr. Samiran Mahapatra (pdoc, 1993-1996), Senior Scientist, Unilever, India. Dr. Christopher Schaller (pdoc, 1995-96), Associate Professor, St. John University Dr. Lisa Berreau (NIH postdoctoral fellow, 1995-1998), Associate Professor, Utah State

University Dr. Yongping Sun (pdoc, 1997-1999) Dr. Patrick Holland (NIH postdoctoral fellow, 1997-2000), Professor, University of

Rochester Dr. John Hagadorn (NIH postdoctoral fellow, joint w/L. Que, Jr., 1998-2000), Scientist,

Exxon, Texas. Dr. Carole Toia (now Duboq) (pdoc, 1998-1999), scientist, CNRS, Grenoble, France Dr. Katherine Aubrecht (pdoc, 1998-2001), Assistant Professor, St. Anselm College, NH Dr. Ferman Chavez (pdoc, joint w/L. Que, Jr., 1999-2002) Dr. Brendan O’Keefe (pdoc, 1999-2001), Scientist, GE Silicones, WVA. Dr. Douglas Spencer (pdoc, 2000-2002), Scientist, Avecia Ltd., Grangemouth, Scotland. Dr. Wayzen Lee (pdoc, 2001-2003), Professor, National Taiwan Normal University, Taipei,

Taiwan. Dr. Pamela Lord (pdoc, joint w/L. Que, Jr., 2001-2002), Assistant Professor, University of

St. Francis, Fort Wayne, IA. Dr. Luis Alcazar-Roman (pdoc, joint w/M. Hillmyer, 2001-2003) Dr. Charlotte Williams (pdoc, joint w/M. Hillmyer, 2001-2002), Lecturer in Inorganic

Chemistry at Imperial College, London, UK). Dr. Elizabeth Lewis (pdoc, 2002-2003), University of Hull, UK Dr. Eric Brown (pdoc, 2002-2006, Associate Professor, Boise State University) Dr. Tryg Jensen (pdoc. joint w/M. Hillmyer, 2003-2005) Dr. Catherine (Donghui) Zhang (pdoc. joint w/M. Hillmyer, 2003-2005), Associate

Professor, LSU Dr. Benjamin Gherman (NIH postdoctoral fellow, joint w/C. Cramer, 2003-2006, Associate

Professor, California State University, Sacramento) Dr. Jaeho Lee (pdoc, 2004).

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Dr. Lyndal Hill (pdoc, 2004-2007). Dr. David Klein (pdoc joint w/L. Que, 2004-2006) Dr. Seth Friese (pdoc joint w/L. Que, 2005-2007, Associate Professor, Salisbury University) Dr. Carter Silvernail (pdoc joint w/M. Hillmyer, 2005-2007, Principal Scientist, EcoLabs) Dr. Itsik Bar-Nahum (2005-2007), Scientist, Agan Aroma & Fine Chemicals, Israel Dr. Xi Zhang (pdoc joint w/L. Que, 2007) Dr. Stefan Huber (pdoc joint w/C. Cramer, 2007-2008, Professor, Ruhr-Universität

Bochum) Dr. Paul Vecchi (pdoc joing w/L. Que, 2007-2008) Dr. Lei Yang (pdoc, 2008-2011, Assistant Professor, University of Central Arkansas) Dr. Patrick Donoghue (pdoc, 2008-2012; Lecturer, Appalachian State University) Dr. Agostino Pietrangelo (pdoc, 2008-2011, Assistant Professor, Rutgers University) Dr. Jihoon Shin (pdoc, 2009-2012; Senior Research Scientist, Korea Research Institute for

Chemical Technology) Dr. Dorian Nelson (pdoc, 2009-2010); Scientist, Ecolab, Minneapolis. Dr. Noureddine Ajellal (pdoc, 2009-2010); Catalyst Researcher, Borealis Polymers, Finland Dr. Senthil A Gurusamy-Thangavelu (pdoc, 2010-2012); Scientist, Polymer Division, CSIR-

CLRI, Adyar, Chennai, India Dr. Beth Moscato-Goodpaster (pdoc, 2010-2011, pdoc with J.P. Loria, Yale) Dr. Mohammad Reza Halvagar (pdoc, 11/10-4/14); Manager of Single-Crystal X-ray

Diffraction Laboratory. Chemistry & Chemical Engineering Research Center of Iran (CCERCI)

Dr. Debra J. Salmon (pdoc, 2011-2013, lecturer, University of Minnesota) Dr. Keying Ding (pdoc, 9/11-8/13; Assistant Professor, Middle Tennessee State University) Dr. Pavlo Solntsev (pdoc, 9/12-6/15; scientist, Cortec Corporation) Dr. William Shearouse (pdoc, 11/12-5/14; scientist, HB Fuller) Dr. Alex John (pdoc, 9/13-9/16; Assistant Professor, Cal Poly Pomona) Dr. Anthony Ostlund (pdoc, 9/13-2/14, joint with T. Hoye; scientist, HB Fuller) Dr. Andrew Spaeth (pdoc, 6/14-present) Dr. Elodie Marlier (pdoc, 9/14-7/15; Assistant Professor, UW River Falls) Dr. Daniel Stasiw (pdoc, 7/15-present) Dr. Megan Fieser (pdoc, 8/15-present) Dr. Lauren Mitchell (pdoc, 2/16-present) Pedagogical and Curriculum Development. Participant in the University of Minnesota Bush Faculty Development Program for Excellence and Diversity in Teaching. Co-developed new graduate core curriculum course "Mechanisms of Chemical Reactions" with Professor Thomas Hoye. Co-developed new advanced undergraduate course "Green Chemistry" with Professor Marc Hillmyer (CHEM 4061). Developed new undergraduate course "Honors Elementary Organic Chemistry I" (CHEM 2331).

PROFESSIONAL ORGANIZATIONS, SERVICE, AND OUTREACH

Editor in Chief, Inorganic Chemistry (2013-present).

Chair, ACS Publications Peer Review Advisory Group (2015-present)

Member, Advisory Board, Chemical & Engineering News (2015-present)

Member, Task Force on Laboratory Safety, Council for Research, Association of Public and Land-Grant Universities (2015-16).

Member, Executive Committee, Center for Sustainable Polymers (2014-present)

Member, Faculty Advisory Board, The Green Chemistry Commitment (2011-present).

Associate Fellow, University of Minnesota Institute on the Environment (2008-present).

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Member, ACS Petroleum Research Fund Advisory Board (2011-2016).

Councilor, Inorganic Division of the ACS (2013-2015).

Member, Governing Board, Council for Chemical Research (2012-2015).

Member, International Advisory Committee, 6th International Conference on Metals in Genetics, Chemical Biology, and Therapeutics (February 17-20, 2016)

Member, Electorate Nominating Committee, American Association for the Advancement of Science (2012-2014)

Associate Editor, Inorganic Chemistry (2007-2012).

Member, Board of Directors, Minnesota Academy of Science (2008-2010).

Fellow of the Royal Society of Chemistry (2005).

Chair-Elect, Chair, Bioinorganic Subdivision, Division of Inorganic Chemistry of the ACS (2002-2004)

Member, Editorial Advisory Board, Dalton Transactions (2004-2006).

Member, Editorial Advisory Board, Journal of Biological Inorganic Chemistry (2000-2002).

Member, Reviewer Panel, Dalton Transactions (2003-2007).

Member, NIH Metallobiochemistry Study Section (2001-2005)

Webmaster, Division of Inorganic Chemistry of the ACS (2000-2003)

Member of the American Chemical Society (ACS), the Society for Biological Inorganic Chemistry (SBIC), and the American Association for the Advancement of Science (AAAS). Meeting Organization

2016 Co-organizer, Telluride Conference on Small Molecule Activation, June 2016.

2013-present Co-organizer, Inorganic Chemistry Lectureship Symposium, National ACS Meeting, Indianapolis, IN (September, 2013); San Francisco (August, 2014); Boston (August, 2015).

2011 Chair, Gordon Research Conference “Metals in Biology”

2010 Co-organizer, Symposium on Dioxygen Activation Chemistry and Catalytic Oxidation Reactions (#108), Pacifichem 2010, Dec 15-20.

2005 Chair, Gordon Research Conference “Inorganic Reaction Mechanisms” (February, 2005).

2002 Program Chair, "2002 Great Lakes Regional American Chemical Society Meeting," Minnapolis, MN (June 2002)

1999 Member, Organizing Committee, “9th International Conference on Biological Inorganic Chemistry,” Minneapolis, MN (July 11-16, 1999).

1998 Co-organizer and session chair, Symposium on “Multinuclear Enzymes in Oxygen Metabolism,” sponsored by the Inorganic and Physical Divisions of the ACS, National ACS Meeting, Boston, MA (August 1998).

1997 Co-organizer, “Conference on Oxygen Intermediates in Nonheme Metallobiochemistry,” University of Minnesota.

1996 Co-organizer and session chair, Symposium on the “Bioinorganic Chemistry of Nitrogen Oxides,” sponsored by the Inorganic Division of the ACS, National ACS Meeting, New Orleans, LA (March).

University Committees

2012-2014 Member, UM Twin-Cities Sustainability Committee

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2012-2016 Member, University Naming Committee 2010-2012 Member, Electronic Financial System Reporting Work Group 2010-2016 Member, All-University Senate Honors Committee (Chair, 2012-2016) 2012-2016 Chair, Selection Committee for President’s Award for Outstanding Service 2007-8 Member, Teaching Classroom and Student Services Building Faculty Advisory Committee 2006-8 Member, Graduate School Review Committee for Camille Dreyfus Teacher-Scholar Awards

Program 2008-09 Reviewer for Graduate School of Preproposals for Searle Scholars Award 2006-8 Member and Chair (2008), Promotions and Tenure Committee, Institute of Technology 2002-3 Chair, Faculty Search Committee 2000 Member, Faculty Search Committee 2000 Member, Departmental NMR Committee 1999-2005 Member, Departmental Awards Committee 1998 Chair, Search Committee for Department of Chemistry Chair 1998 Member, Organic Senior Faculty Search Committee 1996-present Chair, Departmental X-ray Crystallographic Facility Committee. 1998-00 Chair, Planning, Staffing, and Resources Committee, University of Minnesota 1997-00 Coordinator, Inorganic Specialty Area, University of Minnesota 1997-00 Member, Graduate Admissions Committee, University of Minnesota 1996 Member, Departmental Senior Faculty Search Committee 1990-93 Co-chair, Lando-NSF Program for Undergraduate Research, Department of Chemistry. 1990-94 Chair, Inorganic Seminar Program, Department of Chemistry. 1990-92 Member, Undergraduate Curriculum Committee, Department of Chemistry. 1990-93 Undergraduate advisor, Department of Chemistry. Outreach

2010-present Staff, Center for Sustainable Polymers Exhibit, EcoExperience, Minnesota State Fair 2/2010 Moderator, Minnesota State Regional Middle School Science Bowl, St. Paul 1/2010 Moderator, Minnesota State Regional High School Science Bowl, St. Paul 2/2009 Presenter, Southwest High School Career Fair 2/2009 “Taste of Science and Engineering” presentation to URM high school students 1/2009 Judge, Minnesota State High School Science Bowl, St. Paul 9/2008 Participant, Kick Off Event of the North Star STEM Alliance, Science Museum of Minnesota INVITED LECTURES 1992 Symposium: Copper Coordination Chemistry: Bioinorganic Perspectives, Johns Hopkins

University, Baltimore, MD Carlton College, Northfield, MN Marquette University, Milwaukee, WI. 1993 3M Corporate Research Laboratories, St. Paul, MN Symposium: Mechanistic Bioinorganic Chemistry, National ACS Meeting, Denver, CO 17th NSF Organometallic Workshop, New Orleans, LA Sixth International Conference in Bioinorganic Chemistry, San Diego, CA Augustana College, Sioux Falls, SD University of South Dakota, Vermillion, SD University of Wisconsin, Oshkosh, WI Swiss Federal Institute of Technology (ETH), Zürich, Switzerland. 1994 California Institute of Technology, Pasadena, CA University of California at Los Angeles, Los Angeles, CA University of California at San Diego, San Diego, CA

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Symposium in Recognition of ACS Inorganic Chemistry Award Winners, National ACS Meeting, San Diego, CA

University of California at Santa Cruz, Santa Cruz, CA Stanford University, Stanford, CA University of California at Berkeley, Berkeley, CA University of Wisconsin at Madison, Madison, WI Northwestern University, Evanston, IL Wesleyan University, Middletown, CT Yale University, New Haven, CT Massachusetts Institute of Technology, Cambridge, MA Cell and Molecular Biology Training Grant Symposium, University of Minnesota, St. Paul,

MN Macalester College, St. Paul, MN Johns Hopkins University, Baltimore, MD Iowa State University, Ames, IA. 1995 University of North Dakota, Grand Forks, ND Indiana University, Bloomington, IN Great Lakes ACS Regional Meeting, LaCrosse, WI University of Amsterdam, Amsterdam, Netherlands University of Alberta, Edmonton, Canada University of Calgary, Calgary, Canada Harvard University, Cambridge, MA University of Illinois, Champaign-Urbana, IL North Dakota State University, Fargo, ND Symposia on Bioinorganic Chemistry and Metal-Promoted Reactions in Organic Chemistry,

International Chemical Congress of Pacific Basin Societies, Honolulu, HA. 1996 Gordon Research Conference on Metal Ions in Biology, Ventura, CA University of Chicago, Chicago, IL Hatfield Symposium, University of North Carolina, Chapel Hill, NC. Conference on Oxygen Intermediates in Nonheme Metallobiochemistry, University of

Minnesota, Minneapolis, MN. International Conference on Coordination Chemistry, Vancouver, BC, Canada. International Conference on Reaction Field and Mechanics of Respiratory Terminal

Oxidases, Okazaki National Research Institutes, Okazaki, Japan. Tokyo Insititute of Technology, Yokohama, Japan.¨ Dupont Central Research, Wilmington, DE. University of Delaware, Newark, DE. Oregon Graduate Institute, Portland, OR. 1997 University of California, Santa Cruz, CA. Zeneca Pharmaceuticals, Newark, DE. University of Washington, Seattle, WA. Case Western Reserve University, Cleveland, OH. University of Utah, Salt Lake City, UT. University of California, Berkeley, CA. III Winter Research Conference on “Proteins and Free Radicals, From Radical Enzymes to

Damages”, Les Arcs, France. Texas A&M University, College Station, TX. University of California, Davis, CA. Yale University, New Haven, CT. Gordon Conference: Quinones, Radicals, and Redox-Active Amino Acid Cofactors, Pisa,

Italy.

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Gordon Conference: Enzymes, Coenzymes, and Metabolic Pathways, Meriden, NH. Okazaki Conference: Roles of Metal Ions in Biological Activities, Okazaki, Japan. International Conference on Bioinorganic Chemistry (ICBIC8), Yokohama, Japan. Princeton University, Princeton, NJ. Northwestern University, Evanston, IL. College of St. Benedict/St. Johns University, St. Joseph, MN. 1998 University of Colorado, Boulder, CO. Colorado State University, Fort Collins, CO. University of Rochester, Rochester, NY. Florida Catalysis Conference, Palm Coast, FL. International Conference on Coordination Chemistry, Florence, Italy. University of Virginia, Charlottesville, VA. University of Louisville, Louisville, KY.

Harvard University, Cambridge, MA. 1999 Plenary Lecture, Joint meeting of the Inorganic Division of Royal Australian Chemical

Institute and Inorganic Specialist Group of The New Zealand Institute of Chemistry (IC ‘99), Wellington, New Zealand. University of Otago, Dunedin, New Zealand University of Canterbury, Christchurch, New Zealand

37th IUPAC Congress on “Frontiers in Chemistry: Molecular Basis of the Life Sciences”, Berlin, Germany.

Carleton College, Northfield, MN. University of Illinois, Chicago, IL. University of California, Irvine, CA. University of California, San Diego, CA. Symposium on "Bioinspired Catalysis", ACS National Meeting, New Orleans. Scripps Research Institute, La Jolla, CA. California Institute of Technology, Pasadena, CA. University of Wisconsin, River Falls, WI. University of Pittsburgh, Pittsburgh, PA. 2000 Gordon Conference on Metals in Biology, Ventura, CA. Michigan State University, Lansing, MI. University of Chicago, Chicago, IL. NSF Physical Organic Workshop, San Diego, CA. Hope College, Holland, MI. Calvin College, Grand Rapids, MI. Lippard2000: Inorganic Chemistry for the New Millenium, Cambridge, MA. Boston College, Boston, MA. Pacifichem Meeting: Symposium on "Oxygen Activation by Metalloproteins and Their

Models", Honolulu, HI. Pacfichem Meeting: Symposium on "Chemistry and Application of Metal Complexes of

Mixed-Donor Multidentate Ligands", Honolulu, HI. 2001 University of Michigan, Ann Arbor, MI. Gordon Conference on Inorganic Reaction Mechanisms, Ventura, CA. Marquette University, Milwaukee, WI. Symposium in Honor of E. I. Solomon (Inorganic Award), National ACS Meeting, San

Diego, CA. University of Kentucky, Lexington, KY.

Western Washington University, Bellingham, WA. University of Minnesota, Duluth, MN.

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International Conference on Biological Inorganic Chemistry, Florence, Italy. Iowa State University, Ames, IA. University of Maryland, College Park, MD.

2002 Dalton Discussion 4: Inorganic Reaction Mechanisms, Kloster Banz, Germany. (1/11, “Sterically Hindered Benzoates: A Synthetic Strategy for Modeling Dioxygen Activation at Diiron Sites in Proteins”)

University of Nurnberg-Erlangen, Erlangen, Germany. (1/14, "Catalyst Development and Mechanistic Insights into the Synthesis of Biodegradable Polyesters")

Princeton University, Princeton, NJ. (2/27, “Ligand Structural Effects on Biologically Relevant Copper(I)/Dioxygen Reactivity”)

Columbia University, New York, NY. (2/28, “Ligand Structural Effects on Biologically Relevant Copper(I)/Dioxygen Reactivity”)

Boston University, Boston, MA. (3/18, "Using Synthetic Chemistry to Understand Copper and Iron Sites in Proteins")

Wake Forest University, Winston-Salem, NC (5/1, Oakley R. Vail Lecture, “Ligand Structural Effects on Biologically Relevant Copper(I)/Dioxygen Reactivity”)

University of Georgia, Athens, GA. (4/30, “Ligand Structural Effects on Biologically Relevant Copper(I)/Dioxygen Reactivity”)

8th International Conference on Dioxygen Activation and Homogeneous Catalytic Oxidation, Emory University, Atlanta, GA. (6/6, "Characterization of Novel Intermediates Along the Pathway of Dioxygen Activation by Copper")

Conference on Reaction Mechanisms, Ohio State University, Columbus, OH. (7/1, “Which Happens First? O-O Bond Breaking vs. Hydrocarbon Oxidation in Reactions of Metalloenzyme Model Complexes”)

Pennsylvania State University, University Park, PA (10/24, “Ligand Structural Effects on Biologically Relevant Copper(I)/Dioxygen Reactivity”)

University of Oklahoma, Norman, OK. (11/21, J. Clarence Karcher Lecture, “Ligand Structural Effects on Biologically Relevant Copper(I)/Dioxygen Reactivity”)

5th Japanese-American Frontiers of Science Symposium, Beckman Center, Irvine, CA (12/6-8, plenary lecture, “Using Synthetic Chemistry to Understand Molecular Oxygen Production and Utilization in Biology”)

2003 Eastman Corporation, Kingsport, NC (1/14, “Ligand Structural Effects on Biologically

Relevant Copper(I)/Dioxygen Reactivity”) University of Wisconsin, Madison, WI (1/29, student “Samuel M. McElvain Seminar”,

“Ligand Structural Effects on Biologically Relevant Copper(I)/Dioxygen Reactivity”). Gordon Conference on Inorganic Reaction Mechanisms, Ventura, CA. (2/18, “Mechanistic

Insights into the Catalytic Synthesis of Polymers from Renewable Resources”) Duquesne University, Pittsburgh, PA. (3/21, “Ligand Structural Effects on Biologically

Relevant Copper(I)/Dioxygen Reactivity”) Symposium in Honor of S. Trofimenko, National ACS Meeting, New Orleans, LA. (3/23,

“Ligand structural effects on copper-dioxygen reactivity: Novel 1:1 Cu/O2 Complexes”) Indiana University, Bloomington, IN. (4/24, “Characterization of Novel Intermediates Along

the Pathway of Dioxygen Activation by Copper”) University of New South Wales, Sydney, Australia, (5/19-24, 2003 Jeffrey Lectures

Provisional titles “I. Using Synthetic Chemistry to Understand Copper and Iron Sites in Proteins: Ligand Structural Effects on Copper(I)/Dioxygen Reactivity. II. Using Synthetic Chemistry to Understand Copper and Iron Sites in Proteins: Sterically Hindered Benzoates for Modeling Dioxygen Activation at Diiron Centers. III. Mechanistic Insights into the Catalytic Synthesis of Biodegradable Polymers from Renewable Resources.”)

University of Melbourne, Melbourne, Australia (5/26, “Using Synthetic Chemistry to Understand Copper Sites in Proteins: Ligand Structural Effects on Copper(I)/Dioxygen Reactivity.”).

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Massachusetts Institute of Technology, Cambridge, MA (5/28, “Characterization of Novel Intermediates Along the Pathway of Dioxygen Activation by Copper”).

Ohio State University, Columbus, OH (6/4, “Characterization of Novel Intermediates Along the Pathway of Dioxygen Activation by Copper”).

Kaioshiung Medical University, Kaioshiung, Taiwan (9/30, “Sterically Hindered Benzolates for Modeling Dioxygen Activation at Diiron Protein Active Sites”).

Tankang University, Tapei, Taiwan (10/1, “Sterically Hindered Benzolates for Modeling Dioxygen Activation at Diiron Protein Active Sites”).

Taiwan Bioinorganic Symposium (in honor of Sunney Chan), Hsin-Chu, Taiwan (10/3, “Ligand Structural Effects on Copper(I)/Dioxygen Reactivity”).

Macalester College, St. Paul, MN (12/10, “Structures, Bonding, and Reactivity of Monocopper Dioxygen Complexes Relevant to Monocopper Oxygenase Enzyme Active Sites”).

2004 Osaka City University, Osaka, Japan (1/6, “Mechanistic Studies on the Formation and

Reactivity of Dioxygen Adducts of Diiron Complexes Supported by Sterically Hindered Carboxylates”)

International Symposium on the Activation of Oxygen, Awaji Island, Japan (1/7, “Ligand Strutural Effects on Cu(I)/O2 Chemistry: Monocopper Complexes”).

Chinese University of Hong Kong, Hong Kong, China (1/12, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper and Iron Sites in Proteins”; 1/13, “Monocopper Dioxygen Complexes: Structure, Bonding, and Reactivity”).

Georgia Institute of Technology, Atlanta, GA (1/26, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Sites in Proteins”)

Dartmouth College, Hanover, NH (6/3/04, “Dioxygen Activation at a Single Copper Site: Structure, Bonding, and Mechanism of Formation of 1:1 Cu/O2 Adducts”)

7th European Biological Inorganic Chemistry Conference (Eurobic 7), Garmisch-Partenkirchen, Germany (8/29-9/2/04, “Dioxygen Activation at a Single Copper Site: Structure, Bonding, and Mechanism of Formation of 1:1 Cu/O2 Adducts”)

Universität Heidelberg, Hedelberg, Germany (11/12/04, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Sites in Proteins”)

Georg-August-Universität Göttingen, Göttingen, Germany (11/23/04, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Sites in Proteins”)

Universität Freiburg, Freiburg, Germany (11/24/04, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Sites in Proteins”)

Imperial College, London, England (12/8/04, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Sites in Proteins”)

2005 Max Planck Institute for Bioanorganische Chemie, Mülheim, Germany (1/13/05, “Insights into Dioxygen Activation at Single Copper Sites”)

Christian-Albrechts-Universität, Kiel, Germany (1/27/05, “Insights into Dioxygen Activation at Single Copper Sites”)

Workshop on Metal Mediated Oxidative Transformations, Giessen, Germany (1/29/05, “Structure, Bonding, Reactivity, and Mechanism of Formation of Unique Monocopper-Dioxygen Adducts”)

Phillips-Universität Marburg, Marburg, Germany (1/31/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”)

University of Basel, Basel, Switzerland (2/26/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Pavia, Pavia, Italy (4/13/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Padova, Padova, Italy (4/14/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

Technical University of Munich, Munich, Germany (4/19/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

William B. Tolman

- 12 -

University of Utrecht, Utrecht, Netherlands (4/22/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Leiden, Leiden, Netherlands (4/25/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Konstanz, Konstanz, Germany (4/28/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Zurich, Zurich, Switzerland (4/29/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Dresden, Dresden, Germany (5/10/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

Humboldt University, Berlin, Germany (5/11/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Girona, Girona, Spain (5/30/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Barcelona, Barcelona, Spain (5/31/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

Friedrich-Schiller-Universität Jena, Jena, Germany (6/22/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

University of Leipzig, Leipzig, Germany (6/23/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

11th International Conference on Biological Inorganic Chemistry, Ann Arbor, MI (8/5/05, Using Synthetic Chemistry to Understand Copper Protein Active Sites”, Plenary Lecture).

ACS National Meeting, Washington D.C., Symposium “Beta-diketiminates: A Renaissance of Reaction Chemistries” (8/28/05, “Using beta-diketiminates and analogs for synthetic modeling of copper protein active sites”).

Wayne State University, Detroit, MI (9/19/05, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites”).

Winona State University, Winona, MN (9/29/05, "Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Protein Active Sites“).

2006 Gordon Conference on Metals in Biology, Ventura, CA (1/28-2/3/06, “Using Synthetic

Models to Understand Reactive Intermediates and Unusual Structures in Copper Proteins”) Symposium in Honor of Karl Wieghardt for ACS Award in Inorganic Chemistry, National

ACS Meeting, Atlanta, GA (3/26-3/30/05, “Using N-donor ligands for synthetic modeling of copper protein active sites: from tacn to nacnac and beyond”).

Symposium on Radical Metal Complex Chemistry, National ACS Meeting, San Francisco, CA (9/10-9/14/06, “Synthetic modeling of mono- and multicopper protein active sites: Dioxygen activation and Cu-S chemistry”)

University of Minnesota, Duluth (10/20/06, “Using Synthetic Chemistry to Understand Copper Protein Active Sites: Cu(I)/O2 Reactivity”)

2007 Reilly Lectures, University of Notre Dame, South Bend, IN (4/10-4/12/07, “Using Synthetic

Chemistry to Understand Copper and Iron Sites in Proteins: (I) Copper(I)/Dioxygen Reactivity. II. Copper-Sulfur Interactions. III. Carboxylate-Rich Nonheme Iron Centers.”).

University of Oregon, Eugene, OR (5/18/07, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

University of Minnesota IPRIME (Industrial Partnership for Research in Interfacial and Materials Engineering) Annual Meeting (5/30/07, “Mechanistic Insights into Cyclic Ester Polymerizations”)

Symposium on Polymers from Renewable Resources, National ACS Meeting, Boston (8/20/07, “Mechanistic Insights into Ring Opening Polymerization of Cyclic Esters”)

Gordon Conference on Inorganic Chemistry, Newport, RI (7/15-7/20/07, “Probing the Details of Dioxygen and Sulfur Activation by Copper Complexes”)

William B. Tolman

- 13 -

University of Wisconsin, Eau Claire, WI (11/1/07, “Using Synthetic Chemistry to Understand Dioxygen Activation by Copper Proteins”)

2008 Symposium on Systems Chemistry, Max Planck Society, Berlin (1/7/08, “Using Synthetic

Chemistry to Understand Cu and Fe Sites in Proteins”) Montana State University, Bozeman, MT (2/27/08, “Using Synthetic Chemistry to

Understand Copper and Iron Protein Active Sites”) Northern Illinois University, Dekalb, IL (3/3/08, “Using Synthetic Chemistry to Understand

Dioxygen Activation by Copper Proteins”) Ewha Womans University, Seoul, Korea (3/17/08, “Using Synthetic Chemistry to

Understand Dioxygen Activation by Monocopper Sites in Proteins”) Symposium on Oxygen Activation, Nagoya, Japan (3/19/08, “Mononuclear Cu-O2

Complexes: Geometries, Spectroscopic Properties, Electronic Structures, and Reactivity”) International Symposium on Advanced Science and Biotechnology 2008, Osaka, Japan

(3/24/08, “Copper-Sulfur Chemistry From A to Z: Towards Models of the Nitrous Oxide Reductase Active Sites”)

Symposium in Honor of Bader Award to Larry Que, ACS National Meeting, New Orleans, LA (4/6/08, “TITLE”)

University of Washington, Seattle, WA (4/15/08, “Using Synthetic Chemistry to Understand Dioxygen Activation at Monocopper Sites in Proteins”)

Simon Fraser University, Vancouver, BC (4/16/08, “Using Synthetic Chemistry to Understand Dioxygen Activation at Monocopper Sites in Proteins”)

Victoria University, Victoria, BC (4/17/08, “Using Synthetic Chemistry to Understand Dioxygen Activation at Monocopper Sites in Proteins”)

Massachusets Institute of Technology, Cambridge, MA (9/23/08, “Biomimetic Reduction of Dioxygen and Nitrous Oxide by Copper”)

University of Pennsylvania, Philadelphia, PA (10/28/08, “Biomimetic Reduction of Dioxygen and Nitrous Oxide by Copper”)

2009 Gordon Conference on Metals in Biology, Ventura, CA (1/29/09, “Biomimetic Reduction of

Dioxygen and Nitrous Oxide by Copper”) University of Northern Iowa, Cedar Falls, IA (3/12/09, "Catalytic Syntheses of Biorenewable

Polymers") Symposium in Honor of Kenneth Karlin (Cotton Award for Synthetic Inorganic Chemistry),

ACS National Meeting, Salt Lake City (3/22/09, “Copper-oxygen and –sulfur complexes for modeling active site intermediates in copper enzymes”)

Fudan University, Shanghai, PRC (4/20/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

Jiaotong University, Shanghai, PRC (4/21/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

Shanghai Institute of Organic Chemistry, Shanghai, PRC (4/21/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

Nanjing University, Nanjing, PRC (4/22/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

Wuhan University, Wuhan, PRC (4/24/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

Peking University, Beijing, PRC (4/27/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

Tsinghua University, Beijing, PRC (4/28/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

Chinese Academy of Sciences, Beijing, PRC (4/28/09, “Using Synthetic Chemistry to Understand Copper Sites in Enzymes”)

University of British Columbia, Vancouver, CA (11/10/09, “Using Synthetic Chemistry to Understand Dioxygen Activation at Copper Protein Active Sites”)

William B. Tolman

- 14 -

2010 Symposium on Biomimetic Chemistry, ACS Meeting, CA (3/23/10, “Modeling Active Site Intermediates in Copper Enzymes”)

Symposium on "Frontiers in Metallobiochemistry", Penn State University (6/2/10, “Synthetic Approaches to Understanding Small Molecule Activation at Copper Enzyme Active Sites”)

DOE/BES Catalysis Meeting, Bethesda, MD (6/1/10, “Mechanistic Insights into O2 and N2O Activation by Copper Complexes”)

Symposium on Ligand Design and Metal Behavior, ACS National Meeting, Boston MA (8/23/10, “Ligand Effects on Copper-Oxygen Reactivity”)

Symposium on Metals in Biology, ACS National Meeting, Boston, MA (8/23/10, “Modeling the CuZ site in nitrous oxide reductase: synthesis and properties of copper-sulfur complexes”)

Symposium on "Chemistry at Spin Centers" in Bonn, Sept. 22-24, 2010 (“Copper-Oxygen and –Sulfur Complexes as Models of Metalloenzyme Active Sites: Unusual Structures, Bonding and Reactivity”).

University of Delaware, Newark, DE (10/20/10, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

Dupont Corporation, Wilmington, DE (10/21/10, “Research in the Department of Chemistry and Center for Sustainable Polymers at the University of Minnesota”)

Pre-Symposium for ASBIC-V, Kaohsiung Medical University, Taiwan (11/1/10, “Copper-–Sulfur Complexes as Models of Metalloenzyme Active Sites: Unusual Structures, Bonding and Reactivity”)

5th Asian Biological Inorganic Chemistry Conference, Kaohsiung, Taiwan (11/2/10, “Modeling Copper Oxygenases”).

E3 2010 Conference, Panel on Next Generation Biofuels and Products, St. Paul (11/30/10) Symposium on “Dioxygen Activation Chemistry and Catalytic Oxidation Reactions”,

Pacifichem, Hawaii (12/10, “Supporting Ligand Effects on Dioxygen Activation by Copper Centers”)

2011 Northwestern University, Evanston, IL (4/22, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

California Institute of Technology, Pasadena, CA (5/23, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

University of Southern California, Los Angeles, CA (5/24, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

University of California, Los Angeles, CA (5/25, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

University of California, Santa Barbara (5/27, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

Encuentro de Quimica Inorganica 2011, Guadalajara, Mexico (EQI 2011, 6/29, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”) Plenary Lecture

ACS National Meeting, Symposium Celebrating 50 Years of Inorganic Chemistry, Denver, CO (8/29, “Rapid C-H Bond Activation form a New Type of Monocopper-Oxygen Species”)

University of Rochester, NY (10/12, “Using Synthetic Chemistry to Understand Copper Protein Active Sites”)

Symposium on Proton Coupled Electron Transfer, Bordeaux, France (10/9-13, “Rapid C-H Bond Activation by a Cu(III)-OH Complex”)

2011 Wisconsin Chemistry Faculties Meeting, UW-Stout (10/21, “Teaching Green Chemistry at the University of Minnesota”)

University of New Hampshire, Harold A. Iddles Lectures (10/24-25, "Plastics from Plants: Making Useful, Sustainable Polymers" and “Synthetic Models of Copper Protein Active Sites”)

2011 Conference of the Inorganic Division of the Royal Australian Chemical Institute (IC11), University of Western Australia (12/6, “Understanding Copper Oxygen Intermediates Involved in Oxidation Catalysis”) Plenary Lecture

William B. Tolman

- 15 -

2012 Berkeley Green Chemistry Conference (4/3/12, “Green Chemistry Education at the University of Minnesota”).

George H. Cady Lecture and Inorganic Seminar, University of Washington (5/29-30, “Plastics from Plants: Using Metal Catalysts to Make Sustainable Polymers” and “Copper-Oxygen Intermediates Relevant to Biocatalysis”)

DARPA Workshop on “"Low-temperature Electrochemical Oxidation of Hydrocarbon Fuels", Denver, CO (7/10-12, “Understanding Copper-Oxygen Intermediates Involved in Oxidation Catalysis”)

Symposium on Sustainable Materials and Light Induced Processes, Fargo, North Dakota (9/29/12, “Plastics from Plants: Using Metal Catalysts to Make Sustainable Polymers”)

University of Wisconsin, Madison, WI (10/22/12, “From the Bioinorganic Chemistry of Copper to Metal-Catalyzed Cyclic Ester Polymerizations: Insights from Mechanistic Studies”)

University of Missouri, Columbia, MO (11/2/12, “Using Synthetic Chemistry to Understand Copper Catalyzed Oxidations by Enzymes”)

2013 Zing Conference on Bioinorganic Chemistry, Lanzarote, Spain (2/20/13, “Understanding Copper-Oxygen Intermediates Involved in Oxidation Catalysis”).

Symposium on Natural and Renewable Polymers, ACS National Meeting, New Orleans, LA (4/10/13, “Plastics from plants: Using metal catalysts to make sustainable polymers”)

International Conference in Biological Inorganic Chemistry, Grenoble, France (7/28/13, “Advances in the Bioinorganic Chemistry of Copper”).

Meeting of the National Academy of Sciences Committee on Safety Culture in Academic Laboratories, Boston, MA (8/28, “Student Involvement in Improving the Safety Culture of Academic Laboratories”)

Symposium in Honor of Coordination Chemistry and Alfred Werner, ACS National Meeting, Indianopolis, IN (9/9/13, “Advances in the Bioinorganic Chemistry of Copper”)

University of California, Berkeley, CA (9/20/13, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

4th Asian Coordination Chemistry Conference, Jeju Island, South Korea (Plenary Lecture, 11/7/13, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Korean Advanced Institute for Science and Technology (KAIST), Daejon, South Korea (11/8/13, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Zing Conference on Coordination Chemistry, Cancun, Mexico (12/8/13, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

2014 Animesh Chakrovorty Lecturer, Annual Meeting of the Chemical Research Society of India, Bombay (2/8/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Indian Institute of Technology, Bangalore (2/11/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Unilever Hindustan, Bangalore (2/12/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Indian Association for the Cultivation of Science, Calcutta (2/14/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

University of California, Irvine (3/3/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

University of Illinois, Urbana-Champaign (5/6/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

University of Tel-Aviv, Israel (5/29/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Hebrew University of Jerusalem, Israel (6/1/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

William B. Tolman

- 16 -

Weizmann Institute, Israel (6/2/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Gordon Conference on Inorganic Chemistry, New England University, Biddeford, ME (6/8/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Institute of Chemical Research of Catalonia (ICIQ), Tarragona, Spain (6/23/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

VII International School on Organometallic Chemistry Marcial Moreno-Mañas, Universitat Autònoma de Barcelona, Spain (6/25/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”) PLENARY

FUSION Conference on Small Molecule Activation, Chicago (7/16/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Eurobic-12, Zurich, Switzerland (8/25/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

Middle Tennessee State University (10/24/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts” and “Plastics from Plants”)

University of Miami, Miami (11/21/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

National University of Singapore (12/11/14, “Inorganic Chemistry and Ten Tips to Publishing”)

Nanyang Technological University (NTU), Singapore (12/12/14, “Inorganic Chemistry and Ten Tips to Publishing”)

8th Singapore International Chemical Conference (SICC-8), Singapore (12/16/14, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

2015 University of Iowa, Iowa City (2/6/15, “Copper-Oxygen Intermediates Relevant to Metalloenzymes and Other Oxidation Catalysts”)

University of Texas, Austin (2/14/15, “Promoting a Culture of Safety in Research”) Yale University, New Haven (3/18/15, “Copper-Oxygen Intermediates Relevant to

Metalloenzymes and Other Oxidation Catalysts”) Yale University (3/18/15, “Promoting a Culture of Safety in Research”) Stonybrook University, Long Island, NY (3/19/15, “Copper-Oxygen Intermediates Relevant

to Metalloenzymes and Other Oxidation Catalysts”) Stonybrook University, Long Island, NY (3/20/15, “Promoting a Culture of Safety in

Research”) Council for Chemical Research Annual Meeting, Workshop on Safety, Alexandria, VA

(5/4/2015, “Promoting a Culture of Safety in Research”) Summer School in Green Chemistry and Sustainable Energy, Golden, CO (6/19/15, “From

Renewable Plastics to Improving the Culture of Safety: Applying the Principles of Green Chemistry”).

5th Asian Conference on Coordination Chemistry, Hong Kong (7/12/15, “Thermodynamics and Mechanistic Insights into C-H Bond Activation by the Cu(III)-OH Core” and “Inorganic Chemistry and Tips for Publishing”)

Final Symposium, International Research Training Group: Metal Sites in Biomolecules: Structures, Regulation, and Mechanisms, Georg-August-Universität, Göttingen, Germany (8/28/15, “Copper Oxygen Intermediates Relevant to Metalloenzyme Catalysis”)

Summer School on Methods in Molecular Energy Research: Theory and Spectroscopy, Max Planck Institute for Energy Conversion, Gelsenkirchen, Germany (8/30/15, “Copper Oxygen Intermediates Relevant to Metalloenzyme Catalysis”)

University of Münster, Münster, Germany (8/31/15, “Which is better, the book or the movie? Advice for scientists.”)

Gustavus Adolfus, St. Peter, MN (11/5/15, “Plastics from Plants: Catalytic Synthesis of Sustainable Polymers”)

William B. Tolman

- 17 -

Pacifichem, Hawaii. Symposium on The Evolving Nature of Scholarly Communication: Connecting Scholars with Each Other and with Society (12/15/15, “Social media and Inorganic Chemistry: successes and challenge”)

Pacifichem, Hawaii. Symposium on Dioxygen Activation Chemistry of Metalloenzymes and Models (12/16/15, “Copper-oxygen intermediates in oxidation catalysis”)

2016 ACS On-Campus, IIT Bombay (1/25/16, “Communicating Your Research”) ACS On-Campus, IISc Bangalore (1/27/16, “Controlling the Burn: Understanding C-H Bond

Activation by Copper-Oxygen Species”) ACS On-Campus, U. Hyderabad (1/29/16, “Controlling the Burn: Understanding C-H Bond

Activation by Copper-Oxygen Species”) University of Utah, Salt Lake City (2/16/16, “Controlling the Burn: Understanding C-H Bond

Activation by Copper-Oxygen Species” and “Which is better, the book or the movie? Advice for scientists.”)

Olsen Lecture, Utah State University, Logan, UT (2/17/16, “Controlling the Burn: Understanding C-H Bond Activation by Copper-Oxygen Species” and “Which is better, the book or the movie? Advice for scientists.”)

University of Nevada, Reno (4/4/16, “Promoting a Culture of Safety in Research”; 4/5/16, “Controlling the Burn: Understanding C-H Bond Activation by Copper-Oxygen Species”)

University of Connecticut, Storrs (4/12/16, “Promoting a Culture of Safety in Research”) National Taiwan University, Taiwan (4/27/16, “Which is better, the book or the movie?

Advice for scientists.”) Academia Sinica, Taiwan (4/28/16, “Controlling the Burn: Understanding C-H Bond

Activation by Copper-Oxygen Species”) National Chung Hsing University, Taiwan (4/29/16, “Plastics from Plants: Catalytic

Synthesis of Renewable Polymers”) Telluride Conference on Small Molecule Activation, Telluride CO (6/21/16, “Adventures in

influencing the reactivity of the [CuOH]2+ Core”) Summer School in Green Chemistry and Sustainable Energy, Golden, CO (6/26/16, “From

Renewable Plastics to Improving the Culture of Safety: Applying the Principles of Green Chemistry”).

GRANT SUPPORT

Previous (expired) 11/91-10/92 Exxon Education Foundation (14043), "Modeling Copper-Nitrogen Oxide Interactions in

Nitrogen Cycle Proteins," $10,000.

1/91-8/93 American Chemical Society Petroleum Research Fund Grant-in-Aid (23776-G1), "Chiral Tris(pyrazolyl)hydroborate Ligands for Use in Synthetic and Biomimetic Metal-Mediated Enantioselective Recognition," $18,000.

7/92-12/95 National Science Foundation (CHE-9207152), "Novel C3-Symmetric Polypyrazole Ligands for Use in Enantioselective Metal-Mediated Transformations," $192,000.

7/92-6/95 Searle Scholar Award (Chicago Community Trust, 92-C-113), "The Chemistry of Biological Denitrification," $180,000.

7/92-6/94 McKnight-Land Grant Professorship (University of Minnesota), $33,000.

6/93-9/93 Supplement for Undergraduate Research Experience (National Institutes of Health), $3,200.

8/92-7/96 National Institutes of Health (GM47365), "Modeling Copper Protein-Nitrogen Oxide Interactions," $447,460.

9/94-10/96 Alfred P. Sloan Foundation Research Fellowship, $30,000.

William B. Tolman

- 18 -

10/95-9/97 Comedicus Corporation, $3,500.

9/96-6/97 Bush Sabbatical Supplement Award (University of Minnesota).

1/97-5/97 Miller Institute Visiting Research Professorship (University of California, Berkeley).

6/93-6/98 National Science Foundation (National Young Investigator Award), $277,570.

5/94 George W. Taylor Career Development Award (University of Minnesota), $10,000.

6/94-5/99 Camille & Henry Dreyfus Teacher-Scholar Award, $65,000.

6/98 George W. Taylor Award for Excellence in Research (University of Minnesota), $1,500.

8/96-7/99 National Science Foundation, “Enantioselective Reactivity Studies of Transition Metal Complexes of Optically Active Polypyrazole Ligands,” $270,000.

8/96-7/00 National Instiutues of Health, “Synthetic Modeling of Copper Protein Active Sites,” $621,372.

8/99-7/02 National Science Foundation, “Discrete Lanthanide Complexes for Biodegradable Polymer Synthesis,” $360,000 (co-PI with Prof. Marc Hillmyer).

8/00-8/04 National Instiutues of Health, “Synthetic Modeling of Copper Protein Active Sites,” $1,002,997 ($700,000 direct costs).

2/04-12/04 University of Minnesota Initiative for Renewable Energy and the Environment (IREE) and Cargill Corporation, “Synthesis And Properties Of Polyesters Using 3-Hydroxy Propionic Acid (3HP) As The Primary Building Block,” $30,000 (co-PI Prof. Marc Hillmyer).

7/00-7/05 University of Minnesota, "Distinguished McKnight University Professorship," $100,000.

1/03-12/05 National Science Foundation, “New Approaches to the Ring Opening Polymerization of Cyclic Esters,” $414,000 (co-PI Prof. Marc Hillmyer).

9/06-8/07 University of Minnesota Materials Research Science and Engineering Center (UMN MRSEC), Seed Grant, “New Routes to Biorenewable Plastics: Converting Natural Resources to Environmentally Friendly Materials,” $62,000 (co-PIs Profs. Marc Hillmyer and Thomas Hoye).

11/06-11/07 Cargill, Inc., Gift for research on “Synthesis and Subsequent Polymerization of Acrylate Terminated poly3HP Oligomers,” $25,500 (co-PI Prof. Marc Hillmyer).

8/04-7/08 National Institutes of Health, “Synthetic Modeling of Copper Protein Active Sites,” $1,281,593 ($863,025 direct costs). GM047365-(13-16)

9/05-12/08 National Science Foundation, “Sterically Hindered Carboxylates for Modeling Nonheme Iron Proteins,” $405,000 (co-PI Prof. Lawrence Que, Jr.).

1/07-12/09 ACS Petroleum Research Fund, “Controlled Polymerization of Renewable Cyclic Esters: Catalyst Design and Polymerization Mechanisms,” $90,000.

2/09-6/12 National Science Foundation, “Renewable Resource Polymers: Catalyst Design and Materials Development”, $402,000 (co-PI Prof. Marc Hillmyer). CHE-0842654.

2009-11 IREE-large grant, “Sustainable polymers: Tomorrow’s advanced materials,” $800,000 (Marc Hillmyer, PI; co-PI with five others).

8/08-7/09 National Science Foundation, Center for Enabling New Technologies Through Catalysis (subcontract to the University of Washington), $17,214. U WA/565206---NSF/CHE-0650456

1/13-7/13 DARPA, “Dicopper Catalysts for Hydrocarbon Oxidations,” $50,000.

1/13-2/14 BASF Corporation, “Bioderived Oligomeric Isocyanates,” $105,321 (T. Hoye, co-PI).

William B. Tolman

- 19 -

1/13-1/14 Bridgestone Corporation, “High-Activity Catalysts for Dehydrocarbonylation of Carboxylic Acids,” $101,524 (M. Hillmyer, co-PI).

9/11-8/14 National Science Foundation, Center for Chemical Innovation Phase I “Center for Sustainable Polymers” $1.5M (Marc Hillmyer, PI; co-PI with five others).

8/14-7/15 National Science Foundation, Center for Chemical Innovation Phase II “Center for Sustainable Polymers” $4M (total, Marc Hillmyer, PI); $300,000 (Tolman projects).

Current 8/08-7/18 National Institutes of Health, “Synthetic Modeling of Copper Protein Active Sites,”

$1,617,595 ($1,100,000 direct costs). MERIT award 2R37GM047365.

8/15-7/16 National Science Foundation, Center for Chemical Innovation Phase II “Center for Sustainable Polymers” $4M (total, Marc Hillmyer, PI); $293,000 (Tolman projects).

9/13-8/17 United States-Israel Binational Science Foundation, “Zinc, Magnesium, and Calcium Complexes of Pyrrolidine-based Chiral Ligands in Catalysis,” $244,000 total (joint with M. Kol, University of Tel-Aviv; WBT portion $122,000).

William B. Tolman

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PATENTS Polymer Synthesis from Macrocycles, U.S. Patent Number 7,714,097 issued on May 11, 2010. Catalytic Ester Decarbonylation, U.S. Patent Number 14/990,308 filed January 7, 2016. PUBLICATIONS (edited books/editorials/special issues/popular media) Editorial: Upcoming Changes for Inorganic Chemistry: Adding Titles to References and Adjusting Communication Length Requirements, Tolman, W. B. Inorganic Chemistry, 2016, 55, 6351. Editorial: The Year 2015 in Inorganic Chemistry, Tolman, W. B. Inorganic Chemistry, 2016, 55, 1. Editorial: Forums on Small Molecule Activation: from Biological Principles to Energy Applications. Meyer, F. and Tolman, W. B. Inorganic Chemistry, 2015, 54, 5039. Editorial: @InorgChem. Tolman, W. B. Inorganic Chemistry, 2015, 54, 1. Editorial: Reading the Instructions. Tolman, W. B. Inorganic Chemistry, 2014, 53, 7799-7799. Webinar: Student Involvement in Improving the Culture of Safety in Academic Laboratories, BioRaft, January 29, 2014. http://www.bioraft.com/blog/recorded-webinar-students-and-safety-culture-laboratories Webinar: Top 10 Tips to Publish Your Research Work in English Language Journals, ACS Office of International Activities, January 23, 2014. http://acswebinars.org/tips-to-publish Promotional video: http://www.youtube.com/watch?v=OoyzSsnxpyE Editorial: Reflections on Year One. Tolman, W. B. Inorganic Chemistry, 2014, 53, 1-2. Editorial: Virtual Issue on Models of Metalloenzymes. Tolman, W. B., Inorganic Chemistry Virtual Issue, 2013, 52, 7307–7310. Editorial: A Change of the Guard. Tolman, W. B., Inorganic Chemistry 2013, 52, 1-2. Sustainable plastics: the world’s future materials. Laura Seifert, Marc Hillmyer, William Tolman, and Tom Hoye, Blue & Green Tomorrow, June 7, 2012, URL: bit.ly/KW1BAk. Edward I. Solomon and William B. Tolman (Eds.), Inorg. Chem. 2010, 49, 3555-3675. (Forum on Dioxygen Activation and Reduction). Introduction: pp. 3555-3958. Cathleen Drennan and William B. Tolman (Eds.), Current Opinion in Chemical Biology, 2007, 11, 113-240 (issue on Bioinorganic Chemistry). Editorial: pp. 113-171. William B. Tolman (Ed.), Activation of Small Molecules: Organometallic and Bioinorganic Perspectives, Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, Germany, 2006. ISBN: 3-527-31312-5. Lawrence Que, Jr., and William B. Tolman (Volume Eds.), Comprehensive Coordination Chemistry II: From Biology to Nanotechnology, J. McCleverty, T.J. Meyer, Eds., Elsevier: Oxford, UK, Volume 8, 2004. PUBLICATIONS (peer-reviewed journal articles or book chapters) Total = 197, ~16,200 citations, h index = 72 (Google Scholar).

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198. Reactivity of the Copper(III)-Hydroxide Unit with Phenols. Debanjan Dhar, Gereon M. Yee, Todd F. Markle, James M. Mayer*, and William B. Tolman*, submitted to Chemical Science, 7/10/16.

197. Nickel Catalysts for the Dehydrative Decarbonylation of Carboxylic Acids to Alkenes. Alex

John, Maria O. Miranda, Keying Ding, Büsra Dereli, Manuel A. Ortuño, Anne M. LaPointe,* Geoffrey W. Coates,* Christopher J. Cramer,* and William B. Tolman*, Organometallics, 2016, ASAP. DOI: 10.1021/acs.organomet.6b00415

196. Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a

Predictive Model for Cyclic Ester Polymerizations. Elodie E. Marlier, Joahanna A. Macaranas, Daniel J. Marell, Christine R. Dunbar, Michelle A. Johnson, Yvonne DePorre, Maria O. Miranda, Benjamin D. Neisen, Christopher J. Cramer,* Marc A. Hillmyer,* and William B. Tolman*, ACS Catalysis, 2016, 6, 1215–1224 (DOI: 10.1021/acscatal.5b02607). PMCID# PMC4749094

195. Perturbing the Copper(III)-Hydroxide Unit Through Ligand Structural Variation. Debanjan

Dhar, Gereon M. Yee, Andrew D. Spaeth, David W. Boyce, Hongtu Zhang, Büsra Dereli, Christopher J. Cramer,* and William B. Tolman,* J. Am. Chem. Soc. 2016, 138, 356–368 (DOI: 10.1021/jacs.5b10985).

194. Secondary Sphere Hydrogen Bonding in Monocopper Complexes of Potentially Dinucleating

Bis(carboxamide) Ligands. Benjamin D. Neisen, Pavlo Solntsev, Mohammad R. Halvagar, and William B. Tolman, European Journal of Inorganic Chemistry, 2015, 36, 5856-5863 (DOI: 10.1002/ejic.201501060).

193. High performance pressure sensitive adhesives from renewable triblock copolymers. Keying

Ding, Alex John, Jihoon Shin, Youngmin Lee, Tom Quinn, William B. Tolman, and Marc A. Hillmyer, Biomacromolecules, 2015, 16, 2537–2539. (DOI: 10.1021/acs.biomac.5b00754)

192. Pushing the limits of delta bonding in metal-chromium complexes with redox changes and

metal swapping. Reed J. Eisenhart, P. Alex Rudd, Nora Planas, David W. Boyce, Rebecca K. Carlson, William B. Tolman, Eckhard Bill, Laura Gagliardi, and Connie C. Lu, Inorg. Chem., 2015, 54, 7579–7592. (DOI: 10.1021/acs.inorgchem.5b01163)

191. [CuO]+ and [CuOH]2+ Complexes: Intermediates in Oxidation Catalysis?. Nicole Gagnon and

William B. Tolman, Acc. Chem. Res., 2015, 48, 2126–2131. (DOI: 10.1021/acs.accounts.5b00169) 190. Sustainable polyesters derived from glucose and castor oil: Building block structure

impacts properties. William C. Shearouse, Theresa M. Reineke, and William B. Tolman, ACS Macro Letters, 2015, 4, 284–288 (DOI: 10.1021/acsmacrolett.5b00099).

189. Olefins from Biomass Feedstocks: Catalytic Ester Decarbonylation and Tandem Heck-type

Coupling. Alex John, Levi T. Hogan, Marc A. Hillmyer and William B. Tolman, Chemical Communications, 2015, 51, 2731 - 2733 (DOI: 10.1039/c4cc09003a).

188. Hydrogen Atom Abstraction from Hydrocarbons by a Copper(III)-Hydroxide Complex.

Debanjan Dhar and William B. Tolman, J. Am. Chem. Soc. 2015, 137, 1322–1329 (DOI: 10.1021/ja512014z).

187. Transition Metal Complexes and the Activation of Dioxygen. Gereon M. Yee and William B.

Tolman, in Sustaining Life on Planet Earth: Metalloenzymes Mastering Dioxygen and Other Chewy Gases, Eds P.M.H. Kroneck, M.E. Sosa Torres; Vol. 15 of Metal Ions in Life Sciences; Eds A. Sigel,

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H. Sigel, R.K.O. Sigel; Springer International Publishing AG, Cham, Switzerland, 2015, Chapter 5, pp. 131-204.

186. Exploring the Potential of Fulvalene Dimetals as Platforms for Molecular Solar Thermal

Energy Storage: Computations, Syntheses, Structures, Kinetics, and Catalysis. Karl Börjesson, Dušan Ćoso, Victor Gray, Jeffrey C. Grossman, Jingqi Guan, Charles B. Harris, Norbert Hertkorn, Zongrui Hou, Yosuke Kanai, Donghwa Lee, Justin P. Lomont, Arun Majumdar, Steven K. Meier, Kasper Moth-Poulsen, Randy L. Myrabo, Son C. Nguyen, Rachel A. Segalman, Varadharajan Srinivasan, Willam B. Tolman, Nikolai Vinokurov, K. Peter C. Vollhardt, and Timothy W. Weidman, Chem. Eur. J. 2014, 20, 15587-15604.

185. Oxygen-Bridged Dicopper(II,III) and (III,III) Complexes: Models for Putative Intermediates in

Oxidation Catalysis. Mohammad Reza Halvagar, Pavlo V. Solntsev, Hyeongtaek Lim, Britt Hedman, Keith O. Hodgson, Edward I. Solomon, Christopher J. Cramer, and William B. Tolman, J. Am. Chem. Soc. 2014, 136, 7269-7272.

184. Linkage Isomerism in Transition Metal Complexes of Mixed

(Arylcarboxamido)(arylimino)pyridine Ligands. David W. Boyce, Debra J. Salmon, and William B. Tolman, Inorg. Chem. 2014, 53, 5788–5796.

183. Aliphatic polyester block polymers: renewable, degradable, sustainable. Marc A. Hillmyer and

William B. Tolman, Acc. Chem. Res. 2014, 47, 2390–2396. DOI: 10.1021/ar500121d 182. Oxygen-Promoted C-H Bond Activation at Pd. Margaret L. Scheuermann, David W. Boyce, Kyle

A. Grice, Werner Kaminsky, Stefan Stoll, William B. Tolman, Ole Swang, Karen I. Goldberg Angew. Chem. Int. Ed. 2014, 53, 6492-6495.

181. Synthetic Models of Copper-Nitrosyl Species Proposed as Intermediates in Biological

Denitrification. Debra J. Salmon and William B. Tolman, Struct. Bond. 2014, 154, 137-154. 180. Understanding the Mechanism of Polymerization of ε-Caprolactone Catalyzed by Aluminum

Salen Complexes. Maria O. Miranda, Yvonne DePorre, Hugo Vazquez-Lima, Michelle Johnson, Daniel J. Marell, Christopher J. Cramer, and William B. Tolman, Inorganic Chemistry, 2013, 52, 13692–13701.

179. Renewable carvone-based polyols for use in polurethane thermosets. Spencer C. Knight,

Chris P. Schaller, William B. Tolman and Marc A. Hillmyer, RSC Advances 2013, 3, 20399-20404. 178. Isolation of a 2-Hydroxytetrahydrofuran Complex from Copper-Promoted Hydroxylation of

THF. Mohammad Reza Halvagar and William B. Tolman, Inorganic Chemistry, 2013, 52, 8306-8308.

177. Student Involvement in Improving the Culture of Safety in Academic Laboratories. Kathryn A.

McGarry, Katie R. Hurley, Kelly A. Volp, Ian M. Hill, Brian A. Merritt, Katie L. Peterson, P. Alex Rudd, Nicholas C. Erickson, Lori A. Seiler, Pankaj Gupta, Frank S. Bates, and William B. Tolman, J. Chem. Educ. 2013,90, 1414–1417.

176. Reactivity of (Dicarboxamide)M(II)-OH (M = Cu, Ni) Complexes: Reaction with Acetonitrile to

Yield M(II)-Cyanomethides. Jacqui Tehranchi, Patrick J. Donoghue, Christopher J. Cramer, and William B. Tolman, Eur. J. Inorg. Chem. 2013, 4077-4084.

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175. Copper, Palladium, and Platinum-Containing Complexes of an Asymmetric Dinucleating Ligand. Mohammad Reza Halvagar, Benjamin Neisen, and William B. Tolman, Inorganic Chemistry 2013, 52, 793-799.

174. “Small Molecule Models: Cu, Ni, Co” Debra J. Salmon, Mohammed Reza Halvagar, and William

B. Tolman, In: Comprehensive Inorganic Chemistry II, Vol 3, Jan Reedijk and Kenneth Poeppelmeier, editors. Oxford: Elsevier; 2013. p. 455-486.

173. Thermoplastic Elastomers Derived from Menthide and Tulipalin A. Jihoon Shin, Youngmin

Lee, William B. Tolman, and Marc A. Hillmyer, Biomacromolecules 2012, 13, 3833–3840. 172. Polyurethanes based on renewable polyols from bioderived lactones. Senthil A. Gurusamy-

Thangavelu, Susanna Emond, Aman Kulshrestha, Marc A. Hillmyer, Christopher W. Macosko, William B. Tolman and Thomas R. Hoye, Polymer Chemistry, 2012, 3, 2941 - 2948.

171. The Roles of Monomer Binding and Alkoxide Nucleophilicity in Aluminum-Catalyzed

Polymerization of ε-Caprolactone. Keying Ding, Maria O. Miranda, Beth Moscato-Goodpaster, Noureddine Ajellal, Laurie E. Breyfogle, Eric D. Hermes, Chris P. Schaller, Stephanie E. Roe, Christopher J. Cramer, Marc A. Hillmyer and William B. Tolman, Macromolecules, 2012, 45, 5387-5396.

170. “Preparation and Properties of a Monomeric High-Spin MnV–Oxo Complex” Taketo Taguchi,

Rupal Gupta, Benedikt Lassalle-Kaiser, David W. Boyce, Vittal K. Yachandra, William B. Tolman, Junko Yano, Michael P. Hendrich, and Andrew S. Borovik, J. Am. Chem. Soc. 2012, 134, 1996–1999.

169. “Cu(I)/O2 Chemistry Using a β-Diketiminate Supporting Ligand Derived from N,N-

Dimethylhydrazine: Identification of a [Cu3O2]3+ Complex with Novel Reactivity” Aalo K. Gupta and William B. Tolman, Inorg. Chem. 2012, 50, 1881–1888.

168. “Catalytic decarbonylation of biomass-derived carboxylic acids as an efficient route to

commodity monomers” Maria O. Miranda, Agostino Pietrangelo, Marc A. Hillmyer and William B. Tolman, Green Chemistry, 2012, 14, 490-494.

167. “Type 1 Copper Site Synthetic Model Complexes with Increased Redox Potentials” Lei Yang

and William B. Tolman, J. Biol. Inorg. Chem. 2012, 17, 285-291. 166. “Rapid C-H Bond Activation by a Monocopper(III)-Hydroxide Complex” Patrick J. Donoghue,

Jacqui Tehranchi, Christopher J. Cramer, Ritimukta Sarangi, Edward I. Solomon, and William B. Tolman, J. Am. Chem. Soc. 2011, 133, 17602–17605.

165. “X-ray Absorption Spectroscopic and Computational Investigation of a Possible S…S

Interaction in the [Cu3S2]3+ Core” Ritimukta Sarangi, Lei Yang, Stuart G. Kohl, Laura Gagliardi, Christopher J. Cramer, William B. Tolman, and Edward I. Solomon, J. Am. Chem. Soc., 2011, 133, 17180–17191.

164. “Reactions of Ph3Sb=S with Copper(I) Complexes Supported by N-Donor Ligands:

Formation of Stable Adducts and S-Transfer Reactivity” Lei Yang, Jacqui Tehranchi, and William B. Tolman, Inorg. Chem., 2011, 50, 2606-2612.

163. “Pressure-Sensitive Adhesives from Renewable Block Copolymers” Jihoon Shin, Mark T.

Martello, Mona Shrestha, Jane E. Wissinger, William B. Tolman, and Marc A. Hillmyer, Macromolecules, 2011, 44, 87-94.

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162. “Functional Biorenewable Polyesters from Carvone-derived Lactones” Jennifer R. Lowe, Mark

Martello, William B. Tolman, and Marc A. Hillmyer, Polymer Chemistry, 2011, 2, 702-708. 161. “An Anionic, Tetragonal Copper(II) Superoxide Complex” Patrick J. Donoghue, Aalo K. Gupta,

David W. Boyce, Christopher J. Cramer, and William B. Tolman, J. Am. Chem. Soc. 2010, 132, 15869-15871.

160. “Mechanistic Study of the Stereoselective Polymerization of D,L-Lactide using Indium(III)

Halides” Agostino Pietrangelo, Spencer C. Knight, Aalo K. Gupta, Letitia J. Yao, Marc A. Hillmyer, and William B. Tolman, J. Am. Chem. Soc., 2010, 132, 11649–11657.

159. “Copper/α-Ketocarboxylate Chemistry With Supporting Peralkyated Diamines: Reactivity of

Copper(I) Complexes and Dicopper-Oxygen Intermediates” Aalo K. Gupta and William B. Tolman, Inorg. Chem. 2010, 49, 3531-3539.

158. “Binding and Activation of N2O at Transition Metal Centers: Recent Mechanistic Insights“

William B. Tolman, Angew. Chem. Int. Ed., 2010, 49, 1018-1024. 157. “Consequences of Polylactide Stereochemistry on the Properties of Polylactide-

Polymenthide-Polylactide Thermoplastic Elastomers” Carolyn L. Wanamaker, Michael J. Bluemle, Louis M. Pitet, Leslie E. O’Leary, William B. Tolman, and Marc A. Hillmyer, Biomacromolecules, 2009, 10, 2904-2911.

156. “Oxidized Dihydrocarvone as a Renewable Multifunctional Monomer for the Synthesis of

Shape Memory Polyesters” Jennifer R. Lowe, William B. Tolman, and Marc A. Hillmyer, Biomacromolecules, 2009, 10, 2003-2008.

155. “Intermediates in Reactions of Copper(I) Complexes with N-Oxides: From Formation of

Stable Adducts to Oxo Transfer” Sungjun Hong, Aalo K. Gupta, and William B. Tolman, Inorg. Chem., 2009, 48, 6323–6325.

154. “Stereoselective and Controlled Polymerization of rac-Lactide Using Indium(III) Trichloride”

Agostino Pietrangelo, Marc A. Hillmyer, and William B. Tolman, Chem. Commun., 2009, 2736-2737.

153. “Effects of Electron Deficient β-Diketiminate and Formazan Supporting Ligands on

Copper(I)-Mediated Dioxygen Activation” Sungjun Hong, Lyndal M. R. Hill, Aalo K. Gupta, Benjamin D. Naab, Joe B. Gilroy, Robin G. Hicks, Christopher J. Cramer, and William B. Tolman, Inorg. Chem., 2009, 48, 4514-4523.

152. “Poly(d-lactide)–Poly(menthide)–Poly(d-lactide) Triblock Copolymers as Crystal Nucleating

Agents for Poly(l-lactide)” Carolyn L. Wanamaker, William B. Tolman, and Marc A. Hillmyer, Macromol. Symp. 2009, 283–284, 130–138. (Also to published in "New Trends in Polymer Science" Krzysztof Matyjaszewski, Rigoberto Advincula, Enrique Saldívar-Guerra, Gabriel Luna-Bárcenas (Editors), Wiley-VCH, Weinheim, 2009. ISBN: 3-527-32735-5.)

151. “Reduction of Nitrous Oxide to Dinitrogen by a Mixed Valent Tricopper-Disulfido Cluster”

Itsik Bar-Nahum, Aalo K. Gupta, Stefan M. Huber, Mehmed Z. Ertem, Christopher J. Cramer, and William B. Tolman, J. Am. Chem. Soc., 2009, 131, 2812-2814.

150. “Hydrolytic Degradation Behavior of a Renewable Thermoplastic Elastomer” Carolyn L.

Wanamaker, William B. Tolman, and Marc A. Hillmyer, Biomacromolecules, 2009, 10, 443-448.

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149. “Generating Cu(II)-Oxyl / Cu(III)-Oxo Species from Cu(I)-α-Ketocarboxylate Complexes and

O2: In silico studies on ligand effects and C-H-activation reactivity” S. M. Huber, M. Z. Ertem, F. Aquilante, L. Gagliardi, W. B. Tolman, and C. J. Cramer, Chem. Eur. J., 2009, 15, 4886-4895. PMC2878202. NIHMS146788.

148. “Biologically Inspired Oxidation Catalysis” Lawrence Que, Jr., and William B. Tolman, Nature,

2008, 455, 333-340. 147. “Iron(II) Complexes of Sterically Bulky α-Ketocarboxylates. Structural Models for α-

Ketoacid-Dependent Nonheme Iron Halogenases” Seth J. Friese, Benjamin E. Kucera, Victor G. Young, Jr., Lawrence Que, Jr., and William B. Tolman, Inorg. Chem., 2008, 47, 1324-1331.

146. “Novel Reactivity of Side-On (Disulfido)Dicopper Complexes Supported by Bi- and

Tridentate N-Donors: Impact of Axial Coordination” Itsik Bar-Nahum, John T. York, Victor G. Young, Jr., and William B. Tolman, Angew. Chem. Int. Ed., 2008, 47, 533-536.

145. “Synthesis and Reactivity of Copper(I) Complexes with an Ethylene-bridged Bis(imidazolin-

2-imine) Ligand” Dejan Petrovic, Lyndal M. R. Hill, Peter G. Jones, William B. Tolman, and Matthias Tamm, Dalton

Transactions, 2008, 887-894. 144. “X-ray Absorption Spectroscopic and Theoretical Studies on (L)2[Cu2Sn]2+ Complexes:

Disulfide Versus Disulfide (�1−) Bonding” Ritimukta Sarangi, John T. York, Matthew E. Helton, Kiyoshi Fujisawa, Kenneth D. Karlin, William

B. Tolman, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon, J. Am. Chem. Soc., 2008, 130, 676-686.

143. “Copper-Sulfur Complexes Supported by N-Donor Ligands: Towards Models of the CuZ Site

in Nitrous Oxide Reductase” John T. York, Itsik Bar-Nahum, and William B. Tolman, Inorg. Chim. Acta (special issue in honor of E. Solomon), 2008, 361, 885–893.

142. “Copper(I)-α-Ketocarboxylate Complexes: Characterization and O2 Reactions That Yield

Copper-Oxygen Intermediates Capable of Hydroxylating Arenes” Sungjun Hong, Stefan Huber, Laura Gagliardi, Christopher J. Cramer, and William B. Tolman, J. Am. Chem. Soc., 2007, 129, 14190-14192.

141. “Structural Diversity in Copper-Sulfur Chemistry: Synthesis of Novel Cu/S Clusters through

Metathesis Reactions” John T. York, Itsik Bar-Nahum and William B. Tolman, Inorg. Chem., 2007, 46, 8105-8107. 140. “Modular Syntheses of Multidentate Ligands with Variable N-Donors: Applications to Tri-

and Tetracopper(I) Complexes” Eric C. Brown, Brandon Johnson, Sara Palavicini, Benjamin Kucera, Luigi Casella and William B.

Tolman Dalton Trans., 2007, 3035-3042. 139. “Renewable Resource Thermoplastic Elastomers based on Polylactide and Polymenthide”

Carolyn L. Wanamaker, Leslie E. O’Leary, Nathaniel A. Lynd, Marc A. Hillmyer, and William B. Tolman, Biomacromolecules, 2007, 8, 3634-3640.

138. “Structural and Mechanistic Studies of Bis(phenolato)amine Zinc(II) Catalysts for the

Polymerization of ε-Caprolactone”

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Carter M. Silvernail, Letitia J. Yao, Lyndal M.R. Hill, Marc A. Hillmyer, and William B. Tolman, Inorg. Chem., 2007, 46, 6565-6574.

137. “Heterobimetallic Dioxygen Activation: Synthesis and Reactivity of Mixed Cu-Pd and Cu-Pt

Bis(µ-oxo) Complexes” John T. York, Antoni Llobet, Christopher J. Cramer and William B. Tolman, J. Am. Chem. Soc. 2007, 129, 7990-7999.

136. “Mononuclear Cu/O2 Complexes: Geometries, Spectroscopic Properties, Electronic

Structures, and Reactivity” Christopher J. Cramer and William B. Tolman, Acc. Chem. Res., 2007, 40, 601-608.

135. “Ligand Structural Effects on Cu2S2 Bonding and Reactivity in Side-On Disulfido-Bridged

Dicopper Complexes” Eric C. Brown, Itsik Bar-Nahum , John T. York, Nermeen W. Aboelella and William B. Tolman,

Inorganic Chemistry, 2007, 46, 486-496. 134. “Electronic Tuning of β-Diketiminate Ligands with Fluorinated Substituents: Effects on the

O2-Reactivity of Mononuclear Cu(I) Complexes” Lyndal M. R. Hill, Benjamin F. Gherman, Nermeen W. Aboelella, Christopher J. Cramer and William

B. Tolman, Dalton Trans. 2006, 4944 - 4953. 133. “Can an Ancillary Ligand Lead to a Thermodynamically Stable End-On 1:1 Cu-O2 Adduct

Supported by a β-Diketiminate Ligand?” David E. Heppner, Benjamin F. Gherman, William B. Tolman, and Christopher J. Cramer, Dalton

Trans., 2006, 4773 - 4782. 132. “Self-Assembly of Mononuclear Iron(II) and Zinc(II) Models of Metalloenzyme Active Sites

With the 2-His-1-Carboxylate Facial Triad” Seth J. Friese, Benjamin E. Kucera, Lawrence Que, Jr., and William B. Tolman, Inorg. Chem.,

2006, 45, 8003-8005. 131. “Mononitrosyl Iron Complexes Supported by Sterically Hindered Carboxylate Ligands” David P. Klein, Victor G. Young, Jr., William B. Tolman, and Lawrence Que, Jr., Inorganic

Chemistry, 2006, 45, 8006-8008. 130. “Characterization and Reactivity of Monocopper-Oxygen Complexes Supported by β-

Diketiminate and Anilido-Imine Ligands” Benjamin F. Gherman, William B. Tolman, Christopher J. Cramer, Journal of Computational

Chemistry, 2006, 27, 1950-1961. 129. “X-ray Absorption Edge Spectroscopy and Computational Studies on LCuO2 Species:

Superoxide-CuII versus Peroxide-CuIII Bonding” Ritimukta Saragi, Nermeen Aboelella, Kiyoshi Fujisawa, William B. Tolman, Britt Hedman, Keith O.

Hodgson, and Edward I. Solomon, Journal of the American Chemical Society, 2006, 128, 8286-8296.

128. “Heterobimetallic Activation of Dioxygen: Characterization and Reactivity of Novel Cu(I)-

Ge(II) Complexes” John T. York, Victor G. Young, Jr., and William B. Tolman, Inorganic Chemistry, 2006, 45, 4191-

4198.

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127. “Using Synthetic Chemistry to Understand Copper Protein Active Sites: A Personal Perspective”

William B. Tolman, Journal of Biological Inorganic Chemistry, 2006, 11, 261-271. 126. “Effects of Thioether Substituents on the O2 Reactivity of β-Diketiminate-Cu(I) Complexes:

Probing the Role of the Methionine Ligand in Copper Monooxygenases” Nermeen W. Aboelella, Benjamin F. Gherman, Lyndal M. R. Hill, John T. York, Nicole Holm, Victor

G. Young, Jr., Christopher J. Cramer, and William B. Tolman, Journal of the American Chemical Society, 2006, 128, 3445-3458.

125. “Comparison of Structurally Analogous Zn2, Co2, and Mg2 Catalysts for the Polymerization of

Cyclic Esters” Laurie E. Breyfogle, Charlotte K. Williams, Victor G. Young, Jr., Marc A. Hillmyer, and William B. Tolman, Dalton Transactions, 2006, 928-936.

124. “Models for Dioxygen Activation by the CuB Site of DβM and PHM”

Benjamin F. Gherman, David E. Heppner, William B. Tolman, and Christopher J. Cramer, Journal of Biological Inorganic Chemistry, 2006, 11, 197-205.

123. “Zinc N-Heterocyclic Carbene Complexes and their Polymerization of D,L-Lactide” Tryg R. Jensen, Chris P. Schaller, Marc A. Hillmyer, and William B. Tolman, Journal of

Organometallic Chemistry, 2005, 690, 5881-5891. 122. “[Cu3(µ-S)2]3+ Clusters Supported by N-Donor Ligands: Progress Towards a Synthetic Model

of the Catalytic Site of Nitrous Oxide Reductase” Eric C. Brown, John T. York, William E. Antholine, Eliseo Ruiz, Santiago Alvarez, and William B.

Tolman, Journal of the American Chemical Society, 2005, 127, 13752-13753. 121. “Characterization of a Complex Comprising a [Cu2(S2)2]2+ Core: Bis(µ-S2

2-)dicopper(III) or Bis(µ- S2

�−)dicopper(II)?”

John T. York, Eric C. Brown, and William B. Tolman, Angewandte Chemie International Edition, 2005, 44, 7745-7748.

120. “Characterization of a 1:1 Cu/O2 Adduct Supported by an Anilido-Imine Ligand” Anne M. Reynolds, Benjamin F. Gherman, Christopher J. Cramer, and William B. Tolman,

Inorganic Chemistry, 2005, 44, 6989-6997. 119. “Catalytic Polymerization of a Cyclic Ester Derived from a “Cool” Natural Precursor” Donghui Zhang, Marc A. Hillmyer, and William B. Tolman, Biomacromolecules, 2005, 6, 2091-2095. 118. “Reactivity of a 1:1 Copper-Oxygen Complex: Isolation of a Cu(II)-o-Iminosemiquinonato

Species” Anne M. Reynolds, Elizabeth A. Lewis, Nermeen W. Aboelella, and William B. Tolman, Chemical Communications, 2005, 2014-2016.

117. “Dioxygen Activation at a Single Copper Site: Structure, Bonding, and Mechanism of

Formation of 1:1 Cu/O2 Adducts” Nermeen W. Aboelella, Sergey V. Kryatov, Benjamin F. Gherman, William W. Brennessel, Victor G.

Young, Jr., Ritimukta Sarangi, Elena V. Rybak-Akimova, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, Christopher J. Cramer, and William B. Tolman, Journal of the American Chemical Society, 2004, 126, 16896-16911.

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116. “A New Synthetic Route to Poly[3-hydroxypropionic acid] (P[3-HP]): Ring-opening Polymerization of 3-HP Macrocyclic Esters”

Donghui Zhang, Marc A. Hillmyer, and William B. Tolman, Macromolecules, 2004, 37, 8198-8200. 115. “Stereoelective Polymerization of D,L-Lactide Using N-Heterocyclic Carbene Based

Compounds” Tryg R. Jensen, Laurie E. Breyfogle, Marc A. Hillmyer, and William B. Tolman, Chemical Communications, 2004, 2504-2505.

114. “Catching Copper in the Act” (Perspective) Nermeen W. Aboelella, Anne M. Reynolds, and William B. Tolman, Science, 2004, 304, 836-837. 113. “Isotactic Polymers with Alternating Lactic Acid and Oxetane Subunits from the

Endoentropic Polymerization of a 14-membered Ring” Donghui Zhang, Jianyan Xu, Luis Alcazar-Roman, Loren Greenman, Christopher J. Cramer, Marc

A. Hillmyer, and William B. Tolman, Macromolecules, 2004, 37, 5274-5281. 112. “A New Class of (µ-η2:η2-Disulfido)dicopper Complexes: Synthesis, Characterization, and

Disulfide Exchange” Eric C. Brown, Nermeen W. Aboelella, Anne M. Reynolds, Gabriel Aullón, Santiago Alvarez, and William B. Tolman, Inorganic Chemistry, 2004, 43, 3335-3337.

111. “Mixed Metal Bis(µ-oxo) Complexes with [CuM(µ-O)2]n+ (M = Ni(III) or Pd(II)) Cores”

Nermeen W. Aboelella, John T. York, Anne M. Reynolds, Koyu Fujita, Christopher R. Kinsinger, Christopher J. Cramer, Charles G. Riordan, and William B. Tolman, Chemical Communications, 2004, 1716-1717.

110. “Mechanistic Studies on the Formation and Reactivity of Dioxygen Adducts of Diiron

Complexes Supported by Sterically Hindered Carboxylates” Sergey V. Kryatov, Ferman A. Chavez, Anne M. Reynolds, Elena V. Rybak-Akimova, Lawrence

Que, Jr., and William B. Tolman, Inorganic Chemistry, 2004, 43, 2140-2150. 109. “Reactivity of Dioxygen-Copper Systems” Elizabeth A. Lewis and William B. Tolman, Chemical

Reviews, 2004, 104, 1047-1076. 110. “A Highly Active Zinc Catalyst for the Controlled Polymerization of Lactide” Charlotte K.

Williams, Laurie E. Breyfogle, Sun Kyung Choi, WonWoo Nam, Victor G. Young, Jr., Marc A. Hillmyer, and William B. Tolman, Journal of the American Chemical Society, 2003, 125, 11350-11359.

107. “Recurring Structural Motifs.” Lawrence Que, Jr., and William B. Tolman, In Comprehensive Coordination Chemistry II: From

Biology to Nanotechnology, J. McCleverty, T.J. Meyer, Eds., Elsevier: Oxford, UK, Volume 8, 2004, 1-15.

106. “Metal-Radical Arrays.” William B. Tolman, In Comprehensive Coordination Chemistry II: From Biology to Nanotechnology,

J. McCleverty, T.J. Meyer, Eds., Elsevier: Oxford, UK, Volume 8, 2004, 715-737. 105. “Electronic Influence of Ligand Substituents on the Rate of Polymerization of ε-

Caprolactone by Single-Site Aluminum Alkoxide Catalysts” Luis M. Alcazar-Roman, Brendan J. O'Keefe, Marc A. Hillmyer, and William B. Tolman, Dalton

Transactions, 2003, 3082-3087.

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104. “Dicopper(I,I) and Delocalized Mixed-Valent Dicopper(I,II) Complexes of a Sterically Hindered

Carboxylate Ligand” John R. Hagadorn, Theresa I. Zahn, Lawrence Que, Jr., and William B. Tolman, Dalton

Transactions, 2003, 1790-1794. 103. “Variable Character of O-O and M-O Bonding in Side-on (η2) 1:1 Metal Complexes of O2” Christopher J. Cramer, William B. Tolman, Klaus H. Theopold, and Arnold L. Rheingold,

Proceedings of the National Academy of Sciences, USA 2003, 100, 3635-3640. 102. “Copper(I)-Phenolate Complexes as Models of the Reduced Site of Galactose Oxidase:

Synthesis, Characterization, and O2 Reactivity” Brian A. Jazdzewski, Anne M. Reynolds, Patrick L. Holland, Victor G. Young, Jr., Susan Kaderli, Andreas D. Zuberbühler, and William B. Tolman, Journal of Biological Inorganic Chemistry, 2003, 8, 381-393.

101. “Metalloenzyme Inspired Dizinc Catalyst for the Polymerization of Lactide”

Charlotte K. Williams, Neil R. Brooks, Marc A. Hillmyer, and William B. Tolman, Chemical Communications, 2002, 2132-2133.

100. “Toward Synthetic Analogs of Linked Redox and Catalytic Multimetal Sites in Proteins: A

Model of the Histidine-Cysteine Bridged Dicopper Array" Way-Zen Lee and William B. Tolman, Inorganic Chemistry, 2002, 41, 5656-5658.

99. “Snapshots of Dioxygen Activation by Copper: The Structure of a 1:1 Cu/O2 Adduct and Its

Use in Syntheses of Asymmetric Bis(µ-oxo) Complexes" Nermeen W. Aboelella, Elizabeth A. Lewis, Anne M. Reynolds, William W. Brennessel, Christopher J. Cramer, and William B. Tolman, Journal of the American Chemical Society, 2002, 124, 10660-10661.

98. “Copper Chemistry of β-Diketiminate Ligands: Monomer/Dimer Equilibria and a New Class

of Bis(µ-oxo)dicopper Compounds” Douglas J. E. Spencer, Anne M. Reynolds, Patrick L. Holland, Brian A. Jadzewski, Carole Duboq-Toia, Laurent Le Pape, Seiji Yokota, Yoshimitsu Tachi, Shinobu Itoh, and William B. Tolman, Inorganic Chemistry, 2002, 41, 6307-6321.

97. “The Electronic Properties of a Model Active Site for Blue Copper Proteins as Probed by

Stark Spectroscopy” Arindam Chowdhury, Linda A. Penteanu, Patrick L. Holland, and William B. Tolman, Journal of Physical Chemistry B, 2002, 106, 3007-3012.

96. “Calix[4]arenes Linked to Multiple Bidentate N-Donors: Potential Ligands for Synthetic

Modeling of Multinuclear Metalloenzymes" Douglas J.E. Spencer, Bryan J. Johnson, Brian J. Johnson, and William B. Tolman, Organic Letters, 2002, 4, 1391-1393.

95. “Mechanistic Comparison of Cyclic Ester Polymerizations by Novel Iron(III)-Alkoxide

Complexes: Single vs. Multiple Site Catalysis” Brendan J. O’Keefe, Laurie E. Breyfogle, Marc A. Hillmyer, and William B. Tolman, Journal of the

American Chemical Society, 2002, 124, 4384-4393.

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94. "β-Diketiminate Ligand Backbone Structural Effects on Cu(I)/O2 Reactivity: Unique Copper-

Superoxo and Bis(µ-oxo) Complexes” Douglas J.E. Spencer, Nermeen W. Aboelella, Anne M. Reynolds, Patrick L. Holland, and William B. Tolman, Journal of the American Chemical Society, 2002, 124, 2108-2809.

93. “Sterically Hindered Benzoates: A Synthetic Strategy for Modeling Dioxygen Activation at

Metalloprotein Active Sites” William B. Tolman and Lawrence Que, Jr., Journal of the Chemical Society, Dalton Transactions, 2002, 653-660.

92. “Polymerization of Lactide by Monomeric Sn(II) Alkoxide Complexes”.

Katherine B. Aubrecht, Marc A. Hillmyer, and William B. Tolman, Macromolecules, 2002, 35, 644-650.

91. “Bis(µ-oxo)dimetal ‘Diamond’ Cores in Copper and Iron Complexes Relevant to

Biocatalysis" Lawrence Que, Jr., and William B. Tolman, Angewandte Chemie, International Edition, 2002, 41, 1114-1137.

90. “Unusual Peroxo Intermediates in the Reaction of Dioxygen with Carboxylate-Bridged Diiron(II,II) Paddlewheel Complexes.” Ferman A. Chavez, Raymond Y. N. Ho, Maren Pink, Victor G. Young, Jr., Sergei V. Kryatov, Elena V. Rybak-Akimova, Hanspeter P. Andres, Eckard Münck, Lawrence Que, Jr., and William B. Tolman, Angewandte Chemie, Internation Edition, 2002, 41, 149-152.

89. “The Perfectly Alternating Copolymer of Lactic Acid and Ethylene Oxide as a Plasticizing

Agent for Polylactide” Kevin Bechtold, Marc A. Hillmyer, and William B. Tolman, Macromolecules, 2001, 34, 8641-8648.

88. ”Three-Coordinate Copper(II)-Phenolate Complexes”. Brian A. Jazdzewski, Patrick L. Holland, Maren Pink, Victor G. Young, Jr., Douglas J. E. Spencer, and William B. Tolman, Inorganic Chemistry, 2001, 40, 6097-6107.

87. “Polymerization of Lactide and Related Cyclic Esters by Discrete Metal Complexes.”

Brendan J. O’Keefe, Marc A. Hillmyer, and William B. Tolman, Journal of the Chemical Society, Dalton Transactions, 2001, 2215-2224.

86. “A Quantitative Description of the Ground-State Wave Function of CuA by X-ray Absorption

Spectroscopy: Comparison to Plastocyanin and Relevance to Electron Transfer.” Serena DeBeer George, Markus Metz, Robert K. Szilagyi, Hongxin Wang, Stephen P. Cramer, Yi Lu, William B. Tolman, Britt Hedman, Keith O. Hodgson, and Edward I. Solomon, Journal of the American Chemical Society, 2001, 123, 5757-5767.

85. "New Advances in Ligand Design for Synthetic Modeling of Metalloprotein Active Sites."

William B. Tolman and Douglas J.E. Spencer, Current Opinion in Chemical Biology, 2001, 5, 188-195.

84. "Rapid and Controlled Polymerization of Lactide by Structurally Characterized Ferric

Alkoxides." Brendan J. O'Keefe, Susanne M. Monnier, Marc A. Hillmyer, and William B. Tolman, Journal of the American Chemical Society, 2001, 123, 339-340.

William B. Tolman

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83. "Metal Ion Complexation by a New, Highly Sterically Hindered, Bowl-Shaped Carboxylate

Ligand." Ferman A. Chavez, Lawrence Que, Jr., and William B. Tolman, Chemical Communications, 2001,

111-112. 82. "Lactide Polymerization Activity of Alkoxide, Phenoxide, and Amide Derivatives of Yttrium

(III) Arylamidinates." Katherine B. Aubrecht, Karen Chang, Marc A. Hillmyer, and William B. Tolman, Journal of Polymer

Science Part A: Polymer Chemistry, 2001, 39, 284-293. 81. "A Novel Copper-Mediated DNA Base Pair." Eric Meggers, Patrick L. Holland, William B. Tolman, Floyd E. Romesberg, and Peter G. Schultz,

Journal of the American Chemical Society, 2000, 122, 10714-10715. 80. "Copper(I) Chemistry of Bis(pyrazolyl)diphenylborate Ligands: Formation of a Heterocycle

by Cu-Mediated Acetonitrile Addition." Jamie L. Schneider, Victor G. Young, Jr., and William B. Tolman, Inorganic Chemistry, 2001, 40,

165-168. 79. "N-Donor Effects on Carboxylate Binding in Mononuclear Iron(II) Complexes of a Sterically

Hindered Benzoate Ligand." John R. Hagadorn, Lawrence Que, Jr., and William B. Tolman, Inorganic Chemistry, 2000, 39,

6086-6090. 78. "Spectroscopic and Electronic Structural Studies of Blue Copper Model Complexes. 2:

Comparison of 3- and 4-Coordinate Cu(II) Thiolate Complexes and Fungal Laccase." David W. Randall, Serena DeBeer, Patrick L. Holland, Britt Hedman, Keith O. Hodgson, William B.

Tolman, and Edward I. Solomon, Journal of the American Chemical Society, 2000, 122, 11632-11648.

77. "Ligand Macrocycle Structural Effects on Copper-Dioxygen Reactivity" Bernice M. T. Lam, Jason A. Halfen, Victor G. Young, Jr., John R. Hagadorn, Patrick L. Holland,

Agustí Lledós, Lourdes Cucurull-Sánchez, Juan J. Novoa, Santiago Alvarez, and William B. Tolman, Inorganic Chemistry, 2000, 39, 4059-4072.

76. "A Structural Model of the Type 1 Copper Protein Active Site: N2S(thiolate)S(thioether)

Ligation in a Cu(II) Complex." Patrick L. Holland and William B. Tolman, Journal of the American Chemical Society, 2000, 122,

6331-6332. 75. "Controlled Polymerization of D,L-Lactide and ε-Caprolactone by Structurally Well-Defined

Alkoxo-Bridged Di- and Triyttrium(III) Complexes." Bradley M. Chamberlain, Brian A. Jazdzewski, Maren Pink, Marc A. Hillmyer, and William B.

Tolman, Macromolecules, 2000, 33, 3970-3977. 74. "Understanding the Copper-Phenoxyl Radical Array in Galactose Oxidase: Contributions

From Synthetic Modeling Studies." Brian A. Jazdzewski and William B. Tolman, Coordination Chemistry Reviews, 2000, 200-202,

633-685. 73. “Resonance Raman Spectroscopy as a Probe of the Bis(µ-oxo)dicopper Core.” Patrick L.

Holland, Christopher J. Cramer, Elizabeth C. Wilkinson, Samiran Mahapatra, Kenton R. Rodgers,

William B. Tolman

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Shinobu Itoh, Masayasu Taki, Shunichi Fukuzumi, Lawrence Que, Jr., and William B. Tolman, Journal of the American Chemical Society, 2000, 122, 792-802.

72. “Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and

Oxidases.” Allan G. Blackman and William B. Tolman, in Metal-Oxo and Metal-Peroxo Species in Catalytic

Oxidations; Meunier, B., Ed.; Structure & Bonding, Vol. 97; Springer-Verlag: Berlin, 2000; Vol. 97, pp 179-211.

71. “Heterocyclic Donor Influences on the Binding and Activation of CO, NO, and O2 by Copper

Complexes of Hybrid Triazacyclononane-Pyridyl Ligands.” Lisa M. Berreau, Jason A. Halfen, Victor G. Young, Jr., and William B. Tolman, Inorganica Chimica Acta (Special Lippard 60th Birthday Issue), 2000, 297, 115-128.

70. “Aliphatic Hydroxylation by a Bis(µ-oxo)dicopper(III) Complex.” Shinobu Itoh, Masayasu Taki, Hajime Nakao, Patrick L. Holland, William B. Tolman, Lawrence

Que, Jr., and Shunichi Fukuzumi, Angewandte Chemie, International Edition in English, 2000, 39, 398-400.

69. "Conformational Tuning of Valence Delocalization in Carboxylate-Rich Diiron Complexes." John R. Hagadorn, Lawrence Que, Jr., William B. Tolman, Ion Prisecaru, and Eckard Münck,

Journal of the American Chemical Society, 1999, 121, 9760-9761. 68. “Three-Coordinate Cu(II) Complexes: Structural Models of Trigonal-Planar Type 1 Copper

Protein Active Sites.” Patrick L. Holland and William B. Tolman, Journal of the American Chemical Society, 1999, 121,

7270-7271.

67. “Reactivity of Peroxo- and Bis(µ-oxo)dicopper Complexes with Catechols.” Lisa M. Berreau, Samiran Mahapatra, Jason A. Halfen, Robert P. Houser, Victor G. Young, Jr., and William B. Tolman, Angewandte Chemie, International Edition in English, 1999, 38, 207-210.

66. “Discrete Yttrium(III) Complexes as Lactide Polymerization Catalysts.” Bradley M. Chamberlain, Yongping Sun, John R. Hagadorn, Eric W. Hemmesch, Victor G. Young, Jr., Maren Pink, Marc A. Hillmyer, and William B. Tolman, Macromolecules, 1999, 38, 2400-2402.

65. “Dioxygen Activation by Copper Sites: Relative Stability and Reactivity of (µ-η2:η2-Peroxo)-

and Bis(µ-oxo)dicopper Cores.” Patrick L. Holland and William B. Tolman, Coordination Chemistry Reviews, 1999, 190-192, 855-869.

64. “Is the Bis(µ-oxo)dicopper Core Capable of Hydroxylating an Arene?”

Patrick L. Holland, Kenton R. Rodgers, and William B. Tolman, Angewandte Chemie, International Edition in English, 1999, 38, 1139-1142.

63. “Experimental Studies of the Interconversion of µ-η2:η2-Peroxo- and Bis(µ-oxo)dicopper

Complexes.” John Cahoy, Patrick L. Holland, and William B. Tolman, Inorganic Chemistry, 1999, 38, 2161-2168.

62. “A Bulky Benzoate Ligand for Modeling the Carboxylate-Rich Active Sites of Non-Heme

Diiron Enzymes.” John R. Hagadorn, Lawrence Que, Jr., and William B. Tolman, Journal of the American Chemical Society, 1998, 120, 13531-13532.

William B. Tolman

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61. “A Three-Coordinate Copper(I)-Phenoxide Complex that Models the Reduced Form of

Galactose Oxidase” Brian A. Jazdzewski, Victor G. Young, Jr., and William B. Tolman, Journal of the Chemical

Society, Chemical Communications, 1998, 2521-2522. 60. “Influences of Ligand Environment on the Spectroscopic Properties and Disproportionation

Reactivity of Copper-Nitrosyl Complexes.” Jamie L. Schneider, Susan M. Carrier, Christy E. Ruggiero, Victor G. Young, Jr., and William B. Tolman, Journal of the American Chemical Society, 1998, 120, 11408-11418.

59. “Mono- versus Bidentate Coordination of the NONOate [Et2N(N2O2)]- to Copper(II)

Complexes of Tetradentate Ligands.” Jamie L. Schneider, Jason A. Halfen, Victor Young, Jr., and William B. Tolman, New Journal of

Chemistry, 1998, 459-466. 58. Condensation/Commentary on “Thermodynamic Viability of Hydrogen Atom Transfer from

Water Coordinated to the Oxygen-Evolving Complex of Photosystem II” (M.T. Caudle and V.L. Pecoraro)

William B. Tolman, Chemtracts--Inorganic Chemistry, 1998, 11, 339-345. 57. “An Unusual Ligand Oxidation By a (µ-η2:η2-Peroxo)dicopper Compound: 1° > 3° C-H Bond

Selectivity and a Novel Bis(µ-alkylperoxo)dicopper Intermediate” Jason A. Halfen, Victor G. Young, Jr., and William B. Tolman, Inorganic Chemistry, 1998, 37, 2102-

2103. 56. “Spectroscopy of Mixed-Valence CuA-Type Centers: Ligand-Field Control of Ground-State

Properties Related to Electron Transfer.” Daniel R. Gamelin, David W. Randall, Michael T. Hay, Robert P. Houser, Ton C. Mulder, Gerard

W. Canters, Simon de Vries, William B. Tolman, Yi Lu, and Edward I. Solomon, Journal of the American Chemical Society, 1998, 120, 5246-5263.

55. “A New Set of Structurally Related Enantiopure Polypyrazolyl Ligands of Varying Rotational

Symmetry. Synthesis, Metal Complexation, and Comparison of Asymmetric Induction.” Michael C. Keyes, Bradley M. Chamberlain, Scott A. Caltagirone, Jason A. Halfen, and William B.

Tolman, Organometallics, 1998, 17, 1984-1992. 54. “C2-Symmetric 1,4-Diisopropyl-7-R-1,4,7-Triazacyclononanes.” Jason A. Halfen and William B. Tolman, Inorganic Synthesis, 1998, 34, 75-81. 53. “Synthesis and Copper Coordination Chemistry of Hindered 1,4,7-Triazacyclononane

Ligands with Amide Appendages.” Lisa M. Berreau, Jason A. Halfen, Victor G. Young, Jr., and William B. Tolman, Inorganic

Chemistry, 1998, 37, 1091-1098. 52. “Chiral C3-Symmetric Ligands and Their Transition Metal Complexes: Syntheses,

Structures, and Enantioselective Reactivity.” Michael C. Keyes and William B. Tolman, In Advances in Catalytic Processes, Doyle, M. P., Ed.;

JAI Press: Greenwich, CT, 1997; Vol. 2, 189-219. 51. “Binucleating Ligand Structural Effects on µ-Peroxo- and Bis(µ-oxo)dicopper Complex

Formation and Decay: Competition Between Arene Hydroxylation and Aliphatic C-H Bond Activation.”

William B. Tolman

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Samiran Mahapatra, Susan Kaderli, Antoni Llobet, Yorck-Michael Neuhold, Tania Palanché, Jason A. Halfen, Victor G. Young, Jr., Thomas A. Kaden, Lawrence Que, Jr., Andreas D. Zuberbühler, and William B. Tolman, Inorganic Chemistry, 1997, 36, 6343-6356.

50. “The Photochemistry of (Fulvalene)diruthenium(tetracarbonyl) and Its Derivatives: Efficient

Light Energy Storage Devices.” Roland Boese, J. Kevin Cammack, Adam J. Matzger, Kai Pflug, William B. Tolman, K. Peter C.

Vollhardt, Timothy W. Weidman, Journal of the American Chemical Society, 1997, 119, 6757-6773. 49. “X-ray Absorption Studies on the Mixed-Valence and Fully Reduced Forms of the Soluble

CuA Domains of Cytochrome c Oxidase.” Ninian J. Blackburn, Simon de Vries, Mary E. Barr, Robert P. Houser, William B. Tolman, Donita

Sanders, and James A. Fee, Journal of the American Chemical Society, 1997, 119, 6135-6143. 48. “Making and Breaking the Dioxygen O-O Bond: New Insights From Studies of Synthetic

Copper Complexes.” William B. Tolman, Accounts of Chemical Research, 1997, 30, 227-237. 47. “Synthetic Models of the Inactive Copper(II)-Tyrosinate and Active Copper(II)-Tyrosyl

Radical Forms of Galactose and Glyoxal Oxidases.” Jason A. Halfen, Brian A. Jazdzewski, Samiran Mahapatra, Lisa M. Berreau, Elizabeth C.

Wilkinson, Lawrence Que, Jr., and William B. Tolman, Journal of the American Chemical Society, 1997, 119, 8217-8227.

46. “Influence of Copper-Sulfur Covalency and Copper-Copper Bonding on Valence

Delocalization and Electron Transfer in the CuA Site of Cytochrome c Oxidase.” Kendra R. Williams, Daniel R. Gamelin, Louis B. LaCroix, Britt Hedman, Keith O. Hodgson, Edward

I. Solomon, Robert P. Houser, William B. Tolman, Ton C.M. Mulder, and Simon de Vries, Journal of the American Chemical Society, 1997, 119, 613-614.

45. “Tuning the Structure and Reactivity of the [Cu2(µ-O)2]2+ Core: Characterization of a New

Bis(µ-oxo)dicopper Complex Stabilized by a Sterically Hindered Dinucleating Bis(triazacyclononane) Ligand.”

Samiran Mahapatra, Victor G. Young, Jr., Susan Kaderli, Andreas Zuberbühler, and William B. Tolman, Angewandte Chemie, International Edition in English, 1997, 36, 130-133. (german:1997, 109, 125-127)

44. “Kinetic and Thermodynamic Parameters of Copper-Dioxygen Interactions with Different

Oxygen Binding Modes.” Kenneth D. Karlin, William B. Tolman, Susan Kaderli, and Andreas D. Zuberbühler, Journal of

Molecular Catalysis A: Chemical, 1997, 117, 215-222. 43. “Ab Initio Characterization of the Isomerism Between the µ-η2:η2-Peroxo- and Bis(µ-

oxo)dicopper Cores.” Christopher J. Cramer, Bradley A. Smith, and William B. Tolman, Journal of the American

Chemical Society, 1996, 118, 11283-11287. 42. “Dioxygen Activation by a Copper(I) Complex of a New Tetradentate Tripodal Ligand:

Mechanistic Insights into Peroxodicopper Core Reactivity.” Jason A. Halfen, Victor G. Young, Jr., and William B. Tolman, Journal of the American Chemical

Society, 1996, 118, 10920-10921. 41. “Mechanistic Study of the Oxidative N-Dealkylation Reactions of Bis(µ-oxo)dicopper

Complexes.”

William B. Tolman

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Samiran Mahapatra, Jason A. Halfen, and William B. Tolman, Journal of the American Chemical Society, 1996, 118, 11575-11586.

40. “Structural, Spectroscopic, and Theoretical Characterization of Bis(µ-oxo)dicopper

Complexes, Novel Intermediates in Copper-Mediated Dioxygen Activation.” Samiran Mahapatra, Jason A. Halfen, Elizabeth C. Wilkinson, Gaofeng Pan, Xuedong Wang, Victor

G. Young, Jr., Christopher J. Cramer, Lawrence Que, Jr., and William B. Tolman, Journal of the American Chemical Society, 1996, 118, 11555-11574.

39. “Independent Synthesis and Structural Characterization of a Mononuclear Copper-

Hydroxide Complex Previously Assigned as a Copper-Superoxide Adduct.” Lisa M. Berreau, Samiran Mahapatra, Jason A. Halfen, Victor G. Young, Jr., and William B.

Tolman, Inorganic Chemistry, 1996, 35, 6339-6342. 38. “Synthesis and Characterization of a Copper Complex of [Et2N(N2O2)]- Stabilized with

Respect to NO Release in Aqueous Solution.” Jamie L. Schneider, Victor G. Young, Jr., and William B. Tolman, Inorganic Chemistry, 1996, 35,

5410-5411. 37. “Diastereoselective Intramolecular C-H Bond Activation by Optically Active

Tris(pyrazolyl)hydroborate Complexes of Rhodium.” Michael C. Keyes, Victor G. Young, Jr., and William B. Tolman, Organometallics, 1996, 15, 4133-

4140. 36. “Modeling of the Chemistry of the Active Site of Galactose Oxidase.” Jason A. Halfen, Victor G. Young, Jr., and William B. Tolman, Angewandte Chemie, International

Edition English, 1996, 35, 1687-1690. 35. “A Thiolate-Bridged, Fully Delocalized Mixed-Valence Dicopper(I,II) Complex that Models the

CuA Biological Electron-Transfer Site.” Robert P. Houser, Victor G. Young, Jr., William B. Tolman, Journal of the American Chemical

Society, 1996, 118, 2101-2102. 34. "Reversible Cleavage and Formation of the Dioxygen O-O Bond Within a Dicopper

Complex.” Jason A. Halfen, Samiran Mahapatra, Elizabeth C. Wilkinson, Susan Kaderli, Victor J. Young, Jr.,

Lawrence Que, Jr., Andreas D. Zuberbühler, and William B. Tolman, Science, 1996, 271, 1397-1400.

33. “Synthetic Modeling of Nitrite Binding and Activation by Reduced Copper Proteins.

Characterization of Copper(I)-Nitrite Complexes That Evolve Nitric Oxide.” Jason A. Halfen, Samiran Mahapatra, Elizabeth C. Wilkinson, Alan J. Gengenbach, Victor G.

Young, Jr., Lawrence Que, Jr., William B. Tolman, Journal of the American Chemical Society, 1996, 118, 763-776.

32. "Structural Characterization of the First Example of a Bis(µ-thiolato)dicopper(II) Complex.

Relevance to Proposals for the Electron Transfer Sites in Cytochrome c Oxidase and Nitrous Oxide Reductase.”

Robert P. Houser, Jason A. Halfen, Victor G. Young, Jr., Ninian J. Blackburn, and William B. Tolman, Journal of the American Chemical Society, 1995, 117, 10745-10746.

31. "A New Intermediate in Copper Dioxygen Chemistry: Breaking the O-O Bond to Form a

{Cu2(µ-O)2}2+ Core.”

William B. Tolman

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Samiran Mahapatra, Jason A. Halfen, Elizabeth C. Wilkinson, Gaofeng Pan, Christopher J. Cramer, Lawrence Que, Jr., and William B. Tolman, Journal of the American Chemical Society, 1995, 117, 8865-8866.

30. "New Copper and Rhodium Cyclopropanation Catalysts Supported by Chiral

Bis(pyrazolyl)pyridines. A Metal-Dependent Enantioselectivity Switch.” David L. Christenson, Christopher J. Tokar, and William B. Tolman, Organometallics, 1995, 14,

2148-2150. 29. "Mixed Valence Tricopper (I,II,I) Complexes with Thiolate Bridges. Progress Towards

Synthetic Models of the Putative {Cu2}3+ Sites in Nitrous Oxide Reductase and Cytochrome c Oxidase.”

Robert P. Houser and William B. Tolman, Inorganic Chemistry, 1995, 34, 1632-1633. 28. "Coordination Chemistry with Sterically Hindered Hyrdotris(pyrazolyl)borate Ligands:

Organometallic and Bioinorganic Perspectives.” Nobumasa Kitajima and William B. Tolman, Progress in Inorganic Chemistry, 1995, 43, 419-531. 27. "(Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(η2-NO2-O,O').” Jason A. Halfen and William B. Tolman, Acta Crystallographica, 1995, C51, 215-217. 26. "Synthetic Modeling of the Interactions of Nitrogen Oxides with Copper Proteins: Copper-

Nitrosyl Complexes Relevant to Putative Denitrification Intermediates.” William B. Tolman In Mechanistic Bioinorganic Chemistry, V. Pecoraro, H. Thorp, Eds.; American

Chemical Society (Advances in Chemistry Series), Washington, D.C., 1995; 195-217. 25. "Modeling Copper-Dioxygen Reactivity in Proteins: Aliphatic C-H Bond Activation by a New

Dicopper(II)-Peroxo Complex.” Samiran Mahapatra, Jason A. Halfen, Elizabeth C. Wilkinson, Lawrence Que, Jr., and William B.

Tolman, Journal of the American Chemical Society, 1994, 116, 9785-9786. 24. "Catalytic Reduction of Nitric Oxide (NO) to Nitrous Oxide (N2O) by Alcohols Mediated by

Copper(I) Complexes.” Samiran Mahapatra, Jason A. Halfen, and William B. Tolman, Journal of the Chemical Society,

Chemical Communications, 1994, 1625-1626. 23. "Optically Active and C3-Symmetric Tris(pyrazolyl)hydroborate and

Tris(pyrazolyl)phosphine Oxide Ligands: Synthesis and Structural Characterization.” Daniel D. LeCloux, Christopher J. Tokar, Masahisa Osawa, Robert P. Houser, Michael C. Keyes,

and William B. Tolman, Organometallics, 1994, 13, 2855-2866. 22. "Synthetic Model for the Substrate Adduct to the Reduced Active Site of Copper Nitrite

Reductase.” Jason A. Halfen and William B. Tolman, Journal of the American Chemical Society, 1994, 116,

5475-5476. 21. "Synthetic Analogues of Nitrite Adducts of Copper Proteins: Characterization and

Interconversion of Dicopper(I,I) and -(I,II) Complexes Bridged Only by NO2-.”

Jason A. Halfen, Samiran Mahapatra, Marilyn M. Olmstead, and William B. Tolman, Journal of the American Chemical Society, 1994, 116, 2173-2174.

20. "Reductive Disproportionation of NO Mediated by Copper Complexes: Modeling N2O

Generation by Copper Proteins and Heterogeneous Catalysts."

William B. Tolman

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Christy E. Ruggiero, Susan M. Carrier, and William B. Tolman, Angewandte Chemie, International Edition in English, 1994, 33, 895-897.

19. "Transition Metal Complexes of Optically Active Tris(pyrazolyl)hydroborates.” Daniel D. LeCloux, Michael C. Keyes, Masahisa Osawa, Veronica Reynolds, and William B.

Tolman, Inorganic Chemistry, 1994, 33, 6361-6368. 18. "Synthesis, Structural Characterization, and Electrochemical Behavior of Cu(I) Complexes

of Sterically Hindered Tris(3-t-butyl- and 3,5-diphenylpyrazolyl)hydroborate Ligands.” Susan M. Carrier, Christy E. Ruggiero, Robert P. Houser, and William B. Tolman, Inorganic

Chemistry, 1993, 32, 4889-4899. 17. "Synthesis and Structural and Spectroscopic Characterization of Mononuclear Copper

Nitrosyl Complexes: Models for Nitric Oxide Adducts of Copper Proteins and Copper-Exchanged Zeolites.”

Christy E. Ruggiero, Susan M. Carrier, William E. Antholine, James W. Whittaker, Christopher J. Cramer, and William B. Tolman, Journal of the American Chemical Society, 1993, 115, 11285-11298.

16. "Synthesis and Transition Metal Complexation of an Enantiomerically Pure

Tris(pyrazolyl)hydroborate Ligand.” Daniel D. LeCloux and William B. Tolman, Journal of the American Chemical Society, 1993, 115,

1153-1154. 15. "Characterization of Mononuclear Copper-Nitrogen Oxide Complexes: Models of NOx

Binding to Isolated Active Sites in Copper Proteins.” William B. Tolman, Susan M. Carrier, Christy E. Ruggiero, William E. Antholine, and James W.

Whittaker In Bioinorganic Chemistry of Copper; K. D. Karlin and Z. Tyeklár, Eds.; Chapman & Hall, Inc.: New York, 1993; 406-418.

14. "Enantiomerically Pure Copper(I) and Zinc(II) Complexes of a Novel C3-Symmetric

Polypyrazole Ligand.” Christopher J. Tokar, Peter B. Kettler, and William B. Tolman, Organometallics, 1992, 11, 2737-

2739. 13. "Synthesis and Structural Characterization of a Mononuclear Copper Nitrosyl Complex.” Susan M. Carrier, Christy E. Ruggiero, William B. Tolman, and Geoffrey B. Jameson, Journal of the

American Chemical Society, 1992, 114, 4407-4408. 12. "A Model for the Substrate Adduct of Copper Nitrite Reductase and its Conversion to a

Novel Tetrahedral Cu(II) Triflate Complex.” William B. Tolman, Inorganic Chemistry, 1991, 30, 4877-4880. Publications from postdoctoral, graduate, and undergraduate research: 11. "Synthesis and Characterization of Novel Trinuclear Iron(II) and Manganese(II) Carboxylate

Complexes: Structural Trends in Low Valent Iron and Manganese Carboxylates.” R. Lynn Rardin, Peter Poganiuch, Avi Bino, David P. Goldberg, William B. Tolman, Shuncheng Liu,

and Stephen J. Lippard, Journal of the American Chemical Society, 1992, 114, 5240-5249. 10. "Monodentate Carboxylate Complexes and the Carboxylate Shift: Implications for

Polymetalloprotein Structure and Function.”

William B. Tolman

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R. Lynn Rardin, William B. Tolman, and Stephen J. Lippard, New Journal of Chemistry 1991, 15, 417-430.

9. "The Effects of a Bridging Dicarboxylate Ligand on the Synthesis and Physical Properties of

(µ-Oxo)bis(µ-carboxylato)diiron(III) Complexes.” Robert H. Beer, William B. Tolman, Simon G. Bott, and Stephen J. Lippard, Inorganic Chemistry

1991, 30, 2082. 8. "Models of the Reduced Forms of Polyiron Oxo Proteins: An Asymmetric, Triply

Carboxylate Bridged Diiron(II) complex and its Reaction with Dioxygen.” William B. Tolman, Shuncheng Liu, James G. Bentsen, and Stephen J. Lippard, Journal of the

American Chemical Society 1991, 113, 152. 7. "Synthesis and Characterization of the Linear Trinuclear Complexes [M3(O2CCH3)6(BIPhMe)2]

[M= Mn(II) or Fe(II)].” R. Lynn Rardin, Avi Bino, Peter Poganiuch, William B. Tolman, Shuncheng Liu, and Stephen J.

Lippard, Angewandte Chemie, International Edition in English 1990, 29, 812. 6. "A General Method for Assembling (µ-Oxo)bis(µ-carboxylato)diiron(III) Complexes with

Labile Terminal Sites Using a Bridging Dicarboxylate Ligand.” Robert Beer, William B. Tolman, Simon G. Bott, and Stephen J. Lippard, Inorganic Chemistry

1989, 28, 4557. 5. "Self Assembly and Dioxygen Reactivity of an Asymmetric Triply Bridged Diiron(II) Complex

with Imidazole Ligands and an Open Coordination Site.” William B. Tolman, Avi Bino, Stephen J. Lippard, Journal of the American Chemical Society 1989,

111, 8522. 4. "A Dinucleating Hexaimidazole Ligand and Its Dicopper(II) Methanol Inclusion Complex.” William B. Tolman, R. Lynn Rardin, and Stephen J. Lippard, Journal of the American Chemical

Society 1989, 111, 4532. 3. "Designed Synthesis of Heterobimetallic Fulvalene Complexes.” Mark A. Huffman, David A. Newman, Mats Tilset, William B. Tolman, and K. Peter C. Vollhardt,

Organometallics 1986, 5, 1926. 2. "Carbonyl Substitution and Ring Slippage upon Reaction of Trialkylphosphines with

(Fulvalene)diruthenium Tetracarbonyl. X-ray Structural Analysis of (η0:η4-C10H8)Ru(PMe3)2CO and Fluxional Behavior of (η5:η5-C10H8)Ru2(CO)3L (L = Phosphine).”

Roland Boese, William B. Tolman, and K. Peter C. Vollhardt, Organometallics 1986, 5, 582. 1. "Bimetallic Activation of Coordinated Ligands. Reactions of the Lewis Acid (η-

C5H5)(CO)3Mo+ PF6- with Organo-Iron and -Molybdenum η1-Methoxymethyl and Ethyl

Complexes.” James Markham, William Tolman, Kevin Menard, and Alan Cutler, Journal of Organometallic

Chemistry 1985, 294, 45-58.