Test Paper - 25 Questions

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  • 8/18/2019 Test Paper - 25 Questions

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    umber of H involved in the conversion of nitrobenzene to hydrazobenzene are

    A 6

    B 10

    C 4

    D 8

    Which of the following vitamins are water soluble?

    A A

    B C

    C B

    D D

    wo students use same stock solution of and a solution of . The emf of one cell is 0.03 V higher than the other. The concentration of in the cell w

    igher emf value is 0.5 M. Find out the concentration of in the other cell. Given .

    A 0.1 M

    B 0.2 M

    C 0.05M

    D 0.025 M

    Which of the following statement (s) is (are) correct, when a mixture of NaCl and is gently warmed with conc. ?

    A A deep red vapours is evolved.

    B The vapours when passed into NaOH solution gives a yellow solution of

    C Chlorine gas is evolved.

    D

    Chromyl chloride is formed.

    he complexes and can be identified by

    A

    B

    C

    D

    Z S O        

    4   

    C S O        

    4   

    C S O        

    4   

    C S O        

    4   

    (  = 0 . 0 6      

      

    2 . 3 0 3      R T    

    F     

    C     K     

    2   

       

    2   

    O    

    7   

    S    H     

    2   

    O    

    4   

    N C    a   

    2   

    O    

    4   

    [  C    

    (  N B    

    ]  S    H     

    3   

    )  

    5   

    O    

    4   

    [  C    

    (  N S    

    ] B    

    H     

    3   

    )  

    5   

    O    

    4   

    B a C    

    2   

    A N O        

    3   

    P b C    

    2   

    C S O        

    4   

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    A

    List 2

    1 Saytzeff rule

    2 Hofmann rule

    wo isomeric compounds A and B have the formula . With aq KOH solution A gives propionaldehyde and B gives acetone. Then A and B are

    A  and

    B  and

    C  and

    D  and

    he internal energy change in the conversation of 2.0 moles of calcite form of to the aragonite form is 0.4 kJ. The enthalpy change when the pressure is 1 bar give

    hat the densities of solids are and respectively is approximately

    A 0.2kJ

    B 2.0kJ

    C 1.0kJ

    D 10kJ

    he oxidation state of metal M in the complex given above is

    he ratio of angular node of a 3s orbital and the spherical node of a 4p orbital is

    Which of the following statements are correct?

    A If for a reaction is - Ve, is + ve, the reverse reaction is always non spontaneous at all temperatures.

    B If is + ve, is - ve, the forward reaction is non spontaneous at all temperatures.

    C If both are - ve, the reverse reaction is spontaneous at high temperatures.

    D If both are + ve, the reverse reaction is spontaneous at all temperatures

    Match List-I with List-II.

    C     C     

    3   

    H     

    6   

      

    2   

    C      −    C C     

    −     C     H     

    3   

      

    2   

    H     

    3   

    C      −     C      −    C H C     

    H     

    3   

    H     

    2   

      

    2   

    C      −     C H C    −    C H C     

    H     

    3   

      

    2   

    C      −     C      −    C H C     

    H     

    3   

    H     

    2   

      

    2   

    C     −    

    C     −    

    C H C     H     

    3   

    H     

    2   

      

    2   

    C     −    

    C C     

    −    C     H     

    3   

      

    2   

    H     

    3   

    C      −     C H C    −    C H C     

    H     

    3   

      

    2   

    C      −    C C     

    −     C     H     

    3   

      

    2   

    H     

    3   

    C a C O        

    3   

    2 . 7    c      

    − 3   

    2 . 9    c      

    − 3   

    Δ     H      Δ     S    

    Δ     H      Δ     S    

    −     C      −     C      −    B    

    C     

    6   

    H     

    5   

    H     

    2   

    H     

    2   

    →     

    C     

    2   

    H     

    5   

    O    

    −    

  • 8/18/2019 Test Paper - 25 Questions

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    B

    C

    D

    3 Anti-elimination

    4 Cis-elimination

    5 First order

    A

    B

    C

    D

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    A

    B

    C

    D

    List 2

    1 Dimeric halide formation

    2 Dioxygen formation

    3 Cyclic compound formation at room temperature

    4 Acidic oxide formation

    -Bromobutane is subjected to the following sequence of reactions. The difference between molar mass of C and D is

    umber of different type of structures of carbonyl compounds which can be obtained by reductive ozonolysis of the above given figure is

    n fcc structure, the number of tetrahedral voids present along the edges of fcc unit cell is ________ .

    eactions are listed in List-I. Match the result of the respective reactions with the appropriate options listed in List-II.

    substance A has green hydroxide but blue ferricyanide. Another substance B has blue hydroxide but

    rown ferrocyanide A & B could be

    A

    B

    C

    +    S O C     

    →     P     

    4   

      

    2   

    K   +     O    

    + →     H     

    2   

    O    

    3   

    S     +    O    

    2   

    O    

    2   

    →     

    V     

    2   

    O    

    5   

    P      +     B     H     

    3   

    O    

    3   

       

    2   

    ⟶               

    a a a b      

    F S    , 

    N S    O    

    4   

    O    

    4   

    F    (   S     )  O    

    4   

    3   

    F S    , 

    Z S    O    

    4   

    O    

    3   

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    D

    he number of alkenes (consider the stereochemistry of the alkene too) that can be hydrogenated to form methyl cyclohexene is

    What is the correct order of acidity of the given compounds?

    A

    B

    C

    D

    uffer solution A of a weak monoprotic acid and its sodium salt in the concentration ratio x : y has . Buffer solution B of the same acid and its sodium salt in th

    oncentration ratio y : x has . If unit and , then-

    A

    B

    C

    D

    00 ml of 0.1 M solution of a weak acid HA has molar conductivity 5 . The osmotic pressure of resulting solution obtained after dilution of original solution upto

    t 500 K assuming ideal solution is

    eport your answer as X, where X Osmotic pressure (in atm) 10. Give your answer in nearest intiger.

    When a graph is plotted between log x/m and log p, it is a straight line with an angle which intercept at 0.3010 on the y-axis. If the initial pressure is 0.3 atm, the amoun

    as which will be adsorbed per gram of adsorbent is . The value of is

    he number of moles of acetic anhydride is needed to react completely with sucrose are

    F S    , 

    C S    O    

    4   

    O    

    4   

    I   

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