NORTHEAST ANALYTICAL - DATA SUMMARY PACKAGE - … · DATA SUMMARY PACKAGE CHECKLIST SDG #: 08120164 Sample IDs: AL20796-815 Date: Jan 8, 2009 Analytical Method: EPA SW 846 8082 Number

DATA SUMMARY PACKAGE CHECKLIST

SDG #: 08120164 Sample IDs: AL20796-815 Date: Jan 8, 2009 Analytical Method: EPA SW 846 8082

Number of Samples: 20 Matrix: Soil/Plainwell TCRA 12/10.,.11/08

Present Package Attestation Documentation

Present Package Narrative

Present- Field Chain-of-Custody Record

GC sheet 8082- Re-extracted sample AL20797 exceeded extraction holding time GC Extraction Log by two days-see qualification explanation for holding times. Present Compound Identification

(FORMI)

Present Compound Quantitation

Present-Two performed in control. Laboratory Control Spike Summary

Present- Both surrogates were flagged as diluted out in 3 samples and the Surrogate Recovery MS/MSD in this batch due to high PCB concentrations in the samples or added

Summary to the samples. Present- One MS/MSD was analyzed with this batch and the recoveries were MS/MSD Summary within QC limits. The RPD was 20. 7% and the control limit for MS/MSD RPDs is 20% so it was slightly out of control. The surrogates were flagged as diluted for the MS and MSD due to the high concentration of PCB added to the samples. The surrogate recoveries were within the QC limits but due to dilution the concentrations were below the calibration limits. No qualification is necessary. Present-NA Duplicate Summary

Present-NA Standards Summary Tables (FORM VII)

Present-Form 6F-1 Initial Instrument Calibration (FORM VI)

Present- Form 7E-1 and 7E-2 Continuing Calibration Check Standard Summary

Present-NA Check Standards

Present- one performed in control-all Aroclors < PQL Laboratory Blanks/Method Blank

Present Sample Chromatograms

Present QC Raw Data

Present Sample GC Injection Log

Comments: In all samples when detected, Aroclors 1242, 1254 and 1260 were flagged to denote an altered chromatographic pattern and were reported as best Aroclor matches. Sample AL20797 was re-extracted due to low surrogate recovery and the re-extraction was two days out of holding time. Both surrogates were flagged as diluted out for samples AL20797RE, 811, 814 and the MS/MSD (AL20805M, K) due to high concentrations of PCB in or added to the samples. No qualification necessary. The field duplicate and sample both had no Aroclors detected above the PQL indicating~greemeCen the two. G ( REVIEWER1 ::J DATE: ( ( \ \\?

DATA SUMMARY PACKAGE FOR

CAMP DRESSER & McKEE 1 WOODWARD AVENUE

DETROIT, MICHIGAN 48226

ANALYTICAL METHOD:

SW-846 METHOD 8082 (PCB)

DATE: January 8, 2009-C

LRF: 08120164

PROVIDED BY NORTHEAST ANALYTICAL, INC. 2190 TECHNOLOGY DRIVE SCHENECTADY, NEW YORK 12308 518-346-4592

Table Of Contents

Attestations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . . . .. .. . . . . . . . . 2

Case Narrative................................................................................... 4

Sample Chain Of Custody .. ... . .. ........ ......... ............... ........... ... .......... 7

Internal Sample Tracking Record..................................................... 10

Surrogate % Recovery Summary...................................................... 15

Matrix Spike/Matrix Spike Duplicate Summary .. .. .. . .. . .. . .. . .. .. .. ... .. .. . 17

Laboratory Control Spike Summary................................................. 19

M~thod Blank Summary................................................................... 22

Sample Analysis Data....................................................................... 25

Analytical Sequence.......................................................................... 98

Initial Calibration Data . .. .. .. .. .. .. .. .. .. .. .. .. .. .. . .. .. .. .. .. .. .. .. .. .. .. .. .. .. . .. .. .. .. .. 101

Initial/Continuing Calibration Data .. .. .. .. .. .. .. . .. .. .. . .. .. . .. . .. . .. .. . .. .. . .. .. .. . 165

QC Sample Raw Data....................................................................... 182

Certificates of Analysis..................................................................... 203 ·

Northeast Analytical, Inc. 08120164.PDF Page 1

Attestations


Attestations:

The following have been directly involved in the preparation of the sample data contained herein and in the preparation of the associated data summary report.

SAMPLE CUSTODIAN: Adam Moore

SAMPLE PREPARATION CHEMIST: Carrie Barss

GC ANALYST: Anthony Maiello

QA/QC.OFFICER: Christina Braidwood

LAB DIRECTOR: Robert E. Wagner


Case Narrative

Northeast Analytical, Inc. 08120164.PDF Page4

January 12, 2009

CASE NARRATIVE

This data summary package is comprised of sediment and soil samples received for analysis on December 18, 2008 (Assigned Sample Delivery Group: 08120164). The samples are from Project Name: Plainwell Dam #2 Investigation. The samples were collected by Camp, Dresser & McKee (CDM) on December 10 & 11, 2008. Samples were delivered to Northeast Analytical, Inc. (NEA) by FedEx courier service. All samples were received at the laboratory intact and within holding times.

This sample delivery group consists of the following samples:

NEA Sample ID: AL20796 AL20797 AL20798 AL20799 AL20800 AL20801 AL20802 AL20803 AL20804 AL20805 AL20806 AL20807 AL20808 AL20809 AL20810 AL20811 AL20812 AL20813 AL20814 AL20815

f)IJ

Client Sample ID: P2SD-12B-01 P2SL-13A-01 P2SL-14A-01 P2SD-15A-01 P2SD-15B-01 P2SD-15C-Ol P2SD-16A-01 P2SD-17A-01 P2SD-17A-03 P2SL-18A-01 P2SL-18B-01 P2SD-19A-01 P2SD-20A-01 P2SD-21A-01 P2SD-22A-01 P2SL-23A-01 P2SL-23B-01 P2SL-23C-01 P2SL-24A-01 P2SL-25A-01

PCB Aroclor Analysis

Analysis for PCB Aroclors was performed by EPA Method 8082 single column GC analysis. The Accelerated Solvent Extraction Method (EPA Method 3545) was employed for the sediment and soil samples. The following technical and administrative items were noted for the analysis:

1. The concentration results for Aroclor 1242 was flagged to denote that an altered Aroclor pattern was observed for several samples. Please see Form 1 for details.



4. The percent recoveries for the TCMX and DCBP surrogates were diluted out for the Matrix Spike and the Matrix Spike Duplicate samples (NEA ID: AL20805M and AL20805K) due to the high PCB concentration in the samples. Please see Form 2 for details.

Northeast Analytical, Inc. . 08120164.PDF Page 5

5. The percent recovery for the TCMX and DCBP surrogates was diluted out for several samples (NEA ID: AL20797RE1, AL20811, and AL20814) due to the high PCB concentration in the samples. Please see Form 2 for details.

6. The sample P2SL-13A-01 (NEA ID: AL20797) was re-extracted/analyzed due to low surrogate recovery. The sample is included in this data package with a suffix ofREl added to the file ID. Please see Form 1 for details. The re-extraction exceeded the extraction hold time by two days.

7. The relative percent difference for the Matrix Spike and the Matrix Spike Duplicate (NEA ID: AL20805M, AL20805K) samples was above quality acceptance limits. Please see form 3 for details.

Form -1 Qualifier Summary PCB Analysis:

J-Denotes concentration result greater than the MDL but less than the PQL B-Denotes analyte observed in associated method blank at a concentration exceeding the PQL U-Denotes analyte not observed at a concentration greater than the PQL

Respectfully submitted,

~J::JX.,.11-.:J.~ Christina L. Braidwood Quality Assumace Officer S:\LabData\DataPackages\CASEN\CASEN2008108120164A.doc


Sample Chain Of Custody


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Internal Sample Tracking Record

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I Prep Date: 12/22/08 I Batch ID: 6988

Prep NEA Alt Analysis Extract ID Sample ID Sample ID Matrix pH Required Type/Unit

1 70561 PBLK-32 AL20805B Soil EPCBS ASEJASE2.

2 70562 LCS-32 AL20805L Soil EPCBS ASEJASE2.

3 70542 08120164--02 AL20797 Soil EPCBS ASEJASE2.

4 70543 08120164-03 AL20798 Soil EPCBS ASEJASE2.


6 70563 08120164-10MS AL20805M Soil EPCBS ASEJASE2.

7 70565 08120164-10MSD AL20805K Soil EPCBS ASEJASE2.







14 70541 08120164--01 AL20796 Sediment EPCBS ASEJASE2.

15 70544 08120164-04 AL20799 Sediment EPCBS ASEJASE2.




19 70548 08120164--08 AL20803 Sediment EPCBS ASEIASE2.






Solvent, Surrogate, Spike, and Acid Information

Item Lot Number Amount(ul)

TBA 060308MLB1P148A NA Sulfuric Acid (Main Lab) E49039 NA Acetone (Dewar) Current CW981 NA 0.5ppm TCMX I 5.0ppm DCBP in Hexan 102108B26P65A1-10 500 10% Florisil (Main Lab) 110308MLB1P164A NA Hexane (Dewar) [CURRENl] CY047 NA Aroclor 1242@ 12.5PPM SPIKE 1216088026P101A 1000 Aroclor 1242@ 100 PPM in Hexane 121908B26P104A 500

SPIKED BY: Timothy Holton

SIGNATURE: r~

PCB SOLID EXTRACTION LOG

Sample Extract Extract Extract Extract Cell Amount Time Time . Time Time Num

(g ormL) On-1 Off-1 On-2 Off-2

AO 9.473 NA NA NA NA

AM 9.568 NA NA NA NA

108 10.325 NA NA NA NA

39 10.988 NA NA NA NA

62 10.448 NA NA NA NA

32 10.103 NA NA NA NA

29 10.905 NA NA NA NA

51 10.138 NA NA NA NA

40 10.195 NA NA NA NA

23 10.377 NA NA NA NA

AY 10.645 NA NA NA NA

34 10.435 NA NA NA NA

BO 10.136 NA NA NA NA

1 10.140 NA NA NA NA

103 10.129 NA NA NA NA

CE 10.851 NA NA NA NA

11 10.905 NA NA NA NA

CL 10.120 NA NA NA NA

BF 10.147 NA NA NA NA

BT 10.666 NA NA NA NA

c 10.689 NA NA NA NA

CG 10.680 NA NA NA NA



Cone (ug/mL) B L LD s NA It! 0 D 0 NA b11 b11 D I b11

0 0 D 0 0.515.0 0 0 D 0

0 0 D 0 0 0 D 0

12.5 D b11 D D 100 D D D D

WITNESSED BY: _Ji_H_G_ry~g;;.,a_s _____ _

SIGNATURE: ~d. ~

Initial for reauired Clean Up Steps

CAP CAP CAP

uate uate uate uate Acid TBA Floris ii Hg

Cleaned Cleaned Shake Shake KMM/DD) (MM/DD) (MM/DD) MM/DD)

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

12123 12123 12123 NA

D M K D 0 0 D W'I W'I D It! 0 D It! 0 D ~ 0 D 0 0 D D D D It! 0

Final Ext. Vol (ml)

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

25

Date

Cone (MM/DD)

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

12123

NEA NORTHEAST ANALYT~CA L. LASS:

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Comments

Print Date: 01112/2009 Nea Lims Version 4.4.2.2

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Batch ID: 6988 Prepared by: Jill Grygas

Prep Wet Percent Dry Set Screen Screen NEA Alt

Matrix Weight Weight Volume Dilution Result Dilution Sequence Final Multiplier

Sample ID Sample ID Date (g or ml) Solids (g or ml) (ml)

PBlK-32 Al20805B Soil 12/22/08 9.473 N/A 9.4730 25 25 0.01343946 NA 25x

lCS-32 Al20805l Soil 12/22/08 9.568 N/A 9.5680 25 25 0.74768062 NA 25x

08120164-02 Al20797 Soil 12/22108 10.325 43.4 .

4.4810 25 250 RE-EXTRACTED

08120164-03 Al20798 Soil 12/22/08 10.988 52.1 5.7247 25 250 0.11611545 2>4 50x

08120164-10 Al20805 Soil 12/22/08 10.448 60.0 6.2688 25 250 0.02525577 NA 25x

08120164-10MS Al20805M Soil 12/22/08 10.103 60.0 6.0618 25 250 0.35992119 1>7 175x

08120164-10MSD Al20805K Soil 12/22/08 10.905 60.0 6.5430 25 250 0.45854303 1>7 175x

08120164-11 Al20806 Soil 12/22/08 10.138 56.5 5.7280 25 250 0.02064287 NA 25x

08120164-16 Al20811 Soil 12/22/08 10.195 42.2 4.3023 25 250 0.86974532 1>10 2>4 SOOx

08120164-17 Al20812 Soil 12/22/08 10.377 41.1 4.2649 25 250 0.14581435 1>3 75x

08120164-18 Al20813 Soil 12/22/08 10.645 37.8 4.0238 25 250 0.01358522 NA 25x

08120164-19 Al20814 Soil 12/22/08 10.435 36.7 3.8296 25 250 1.02035856 1>10 2>4 500x

08120164-20 Al20815 Soil 12/22/08 10.136 47.0 4.7639 25 250 0.02717904 NA 25x

08120164-01 Al207~6 Sediment 12/22/08 10.140 49.5 5.0193 25 250 0.03143190 NA 25x

08120164-04 Al20799 Sediment 12/22/08 10.129 41.4 4.1934 25 250 0.04650315 NA 25x

08120164-05 Al20800 Sediment 12/22/08 10.851 42.4 4.6008 25 250 0.03221097 NA 25x

08120164-06 Al20801 Sediment 12/22/08 10.905 46.7 5.0926 25 250 0.02611128 NA 25x

08120164-07 Al20802 Sediment 12/22/08 10.120 61.0 6.1732 25 250 0.01132618 NA 25x

08120164-08 Al20803 Sediment 12/22/08 10.147 63.5 6.4433 25 250 0.03302336 NA 25x 08120164-09 Al20804 Sediment 12/22/08 10.666 62.5 6.6662 25 250 0.01764742 NA 25x

08120164-12 Al20807 Sediment 12/22/08 10.689 69.4 7.4182 25 250 0.02853918 NA 25x

08120164-13 Al20808 Sediment 12/22/08 10.680 45.5 4.8594 25 250 0.01415156 NA 25x

08120164-14 Al20809 Sediment 12/22/08 10.425 44.4 4.6287 25 250 0.02738826 NA 25x

08120164-15 Al20810 Sediment 12/22/08 10.518 53.3 5.6061 25 250 0.04295672 NA 25x

Solvent, Surrogate. Spike, and Acid Information B = Blank, L = Lab Control Spike, LO= Lab Control Spike Duplicate, S = Sample, D = Duplicate, M = Matrix Spike, K = Matrix Spike Duplicate

Item Lot Number Amount{uL) Cone {ug/mL) B L LD s D M K 1BA 060308MLB1P148A NA NA 0 0 D 0 D ~ 0 Sulfuric Acid (Main Lab) E49039 NA NA 0 0 D 0 D 0 0 Acetone {Dewar) Current CW981 NA 0 0 D 0 D 0 0 0.5ppm TCMX I 5.0ppm DCBP in Hexan 102108B26P65A 1·10 :.1111 0.5/5.0 0 0 D 0 D 0 0 10% Florisil {Main Lab) 110308MLB1P164A NA 0 0 D 0 D W'I ~ Hexane {Dewar) [CURRENT] CY047 NA 0 0 D 0 D 0 0 Aroclor 1242@ 12.5PPM SPIKE 121608B026P101A 1000 12.5 D 0 D D D D D Aroclor 1242@ 100 PPM in Hexane 121908B26P104A 500 100 D D D D D 0 W'I

·~ COMMENTS:=============-~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

-N Page 1 of 1 Print Date: 01112/2009 Nea Lims Version : 4.4.2.2

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Prep Date: 12/26/2008 I Batch ID: 7019

Prep NEA Alt Analysis Extract Matrix pH ID Sample ID Sample ID Required Type/Unit

1 70868 PBLK-53 AL20797B Soi EPCBS ASE/ASE2

2 70869 LCS-53 AL20797L Soil EPCBS ASE/ASE2

3 70867 08120164-02RE1 AL20797RE1 Soil EPCBS ASE/ASE2

Solvent, Surrogate, Spike, and Acid Information

Item Lot Number Amount(ul)

Hydro Matrix 706150·AB NA TBA 060308MLB1P148A NA Sulfuric Acid (Main Lab) E49039 NA Acetone (Dewar) Current CW981 NA O.Sppm TCMX I 5.0ppm DCBP In Hexane 102108B26P65A1-10 500 10% Florisil (Main Lab) 110308MLB1P164A NA Hexane (Dewar) [CURRENT] CY047 NA Aroclor 1242@ 12.5PPM SPIKE 121608B026P101A 1000

SPIKED BY: Timothy Holton

SIGNATURE: r~

SOLID EXTRACTION LOG

Initial for reauired Clean Uo Steps

MTH MTH MTH

Date Date Date Date Sample Extract Extract Extract Extract Final Date Cell Amount Time Time Time Time

Acid TBA Floris ii Hg Ext. Cone I ICleaned Cleaned Shake Shake Comments Num Vol (gorml) On-1 Off·1 On-2 Off ·2 (MM/DD) (MM/DD) (MM/DD) (MM/DD) (ml) (MM/DD)

au 9.113 NA NA NA NA 12129 12129 12129 NA 25 12129

62 9.497 NA NA NA NA 12129 12129 12129 NA 25 12/29

68 10.007 NA NA NA NA 12129 12129 12/29 NA 25 12/29

Cone (ug/ml) B L LO s D M K na li2I 0 0 0 0 0 0 NA li2I 0 0 li2I 0 0 0 NA li2I 0 0 0 0 0 0

0 0 0 0 0 0 D 0.5/5.0 li2I li2I 0 0 0 0 0

li2I 0 0 0 0 D 0 0 0 0 0 D D 0

12.5 0 li2I D D D D D

WITNESSED BY: _J_ill_G_ry.;.;g.._a_s ______ _

SIGNATURE: ~ d. ~ Pnnt Date: 1212912008 t..Jos-3 L>nr::- ·.;o::;,-51on ·~A 2.(;

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PCB SOLID SCREEN SHEET

Batch ID: 7019 Prepared by: Jill Grygas

NEA Alt Prep Wet Percent , Dry Set

Screen Screen Sample ID Sample ID Matrix Weight Weight Volume

Dilution Result Dilution Sequence Final Multiplier Date (g ormL) Solids (g or ml) (ml)

PBLK-53 AL20797B Soil 12126108 9.113 NIA 9.1130 25 NA 0.02877383 NA 25x

LCS-53 AL20797L Soll 12126108 9.497 NIA 9.4970 25 NA 0.70778471 NA 25x

08120164-02 AL20797RE1 Soll 12126108 10.007 43.4 4.3430 25 250 0.64514081 1>10 250x

Solvent, Surrogate, Spike, and Acid Information B = Blank, L = Lab Control Spike, LO= Lab Control Spike Duplicate, S = Sample, D = Duplicate, M = Matrix Spike, K = Matrix Spike Duplicate

Item Lot Number Amount(ul) Cone (uglml) B L LO s D M K Hydro Matrix 706150-AB NA na 0 0 D 0 D D D TBA 060308MLB1P148A NA NA 0 0 D 0 D D D Sulfuric Acid (Main Lab) E49039 NA NA 0 0 D 0 D D D Acetone (Dewar) Current CW981 NA 0 0 D 0 D D D 0.Sppm TCMX / 5.0ppm DCBP In Hexane 102108B26P65A1-10 500 0.515.0 0 0 D 0 D D D 10% FlorisU (Main Lab) 110308MLB1P164A NA 0 0 D 0 D D D Hexane (Dewar) [CURRENl] CY047 NA 0 0 D 0 D D D Aroclor 1242@ 12.SPPM SPIKE 121608B026P101A 1000 12.5 D 0 D D D D D

COMMENTS:~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

Page1 of 1 Print Dale: 12129/2008 Ne!J Urn~'> \l•:r::.ion 4A.?.:.O

Surrogate % Recovery Summary


2F-1 PCB SURROGATE RECOVERY

Laboratory Name: Northeast Analytical, Inc.

ELAP ID No: 11078 --------GC Column ( 1 ): J&W, NARROWBORE CAPILLARY, DB-1, 30M; ID: 0.25 mm

GC Column (2): NA -------------------~

LAB LAB SURR1 (Col 1)

LRFID SAMPLE ID FILEID %REC# PBLK-53 AL20797B

PBLK-32 AL20805B

LCS-53 AL20797L

LCS-32 AL20805L

08120164-01 AL20796

08120164-02RE 1 AL20797RE1

08120164-03 AL20798

08120164-04 AL20799

08120164-05 AL20800

08120164-06 AL20801

08120164-07 AL20802

08120164-08 AL20803

08120164-09 AL20804

08120164-10 AL20805

08120164-11 AL20806

08120164-12 AL20807

08120164-13 AL20808

08120164-14 AL20809

08120164-15 AL20810

08120164-16 AL20811

08120164-17 AL20812

08120164-18 AL20813

08120164-19 AL20814

08120164-20 AL20815

08120164-10MS AL20805M

08120164-10MSD AL20805K

# Column to be used to flag recovery values

SURR1 = TETRACHLORO-MET A-XYLENE SURR2 = DECACHLOROBIPHENYL

Northeast Analytical, Inc.

GC20F-327-12

GC20F-326-11

GC20F-327-13

GC20F-326-12

GC20F-326-13

GC20F-327-14

GC20F-326-14

GC20F-326-15

GC20F-326-16

GC20F-326-17

GC20F-326-18

GC20F-326-19

GC20F-326-21

GC20F-326-22

GC20F-326-25

GC20F-326-26

GC20F-326-27

GC20F-326-28

GC20F-326-29

GC20F-326-31

GC20F-326-32

GC20F-326-33

GC20F-326-34

GC20F-326-35

GC20F-326-23

GC20F-326-24

Adyjsorv QC Umjts

(60-140) (60-140)

67.8

85.5

86.7

91.5

86.6

79.4 D

82.7

90.6

86.7

88.6

90.3

91.2

97.0

93.6

84.7

90.6

92.5

91.5

90.0

63.4 D

88.3

89.9

69.3 D

92.0

69.3 D

75.8 D

Form 11-CLP-PCB(NEA)

08120164.PDF

SDG: 08120164

SURR2 OTHER (Col 1)

%REC# (1)

71.9

83.8

103

92.5

88.8

100 D

89.2

93.2

90.3

93.7

93.8

93.7

98.5

91.7

85.2

92.4

92.4

94.5

91.9

67.5 D

94.1

92.3

33.5 D

99.4

68.1 D

78.1 D

OTHER (2)

TOTAL OUT

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Print Date: 01/07/2009 Nea Urns Version : 4.4.2.2

Page 16

Matrix Spike/Matrix Spike Duplicate Summary


3F-1 MATRIX SPIKE (MS) I MATRIX SPIKE DUPLICATE (MSD) RECOVERY

Laboratory Name: Northeast Analytical, Inc.

ELAP ID No: 11078 SDG No: 08120164

MS LRF ID: 08120164-10MS MSD LRF ID: 08120164-10MSD

MS Lab File ID: GC20F-326-23 MSD Lab File ID: GC20F-326-24

MS Sample lnj Date: 12/26/2008 22:34:14 MSD Sample lnj Date: 12/26/2008 23:06:50

MS Lab Sample ID: AL20805M MSD Lab Sample ID: AL20805K -------

SPIKE SAMPLE COMPOUND ADDED CONCENTRATION

(ug/g) (ug/g)

Aroclor 1242 8.25 0

SPIKE MSD

COMPOUND ADDED CONCENTRATION (ug/g) (ug/g)

Aroclor 1242 7.64 7.42

# Column to be used to flag recovery values

* Values outside of QC limits

1 QC Limits based upon laboratory defaults.

MS

CONCENTRATION (ug/g)

6.51

MSD PERCENT

RECOVERY

97.1

Spike Recovery: 0 out of 2 outside limits.

RPD: 1 out of outside limits.

COMMENTS:

Form Ill-CLP

Northeast Analytical, Inc. 08120164.PDF

#

Sample LRF ID: 08120164-10 -------Sample File ID: __ G_C_2_0_F-_3_26_-_22 __

Sample lnj Date: 12/26/2008 22:01 :38

Sample ID: AL20805 · -------

MS QCLIMITS1

PERCENT PERCENT

RECOVERY # RECOVERY

78.9 (70.0-130)

QC LIMITS 1

RPD # RPD REC

20.7 . 20 (70.0-130)

Nea Urns Version : 4.4.2.2

Page 18

Documents

NORTHEAST ANALYTICAL - DATA SUMMARY PACKAGE - … · DATA SUMMARY PACKAGE CHECKLIST SDG #: 08120164 Sample IDs: AL20796-815 Date: Jan 8, 2009 Analytical Method: EPA SW 846 8082 Number