i. EIA report uploaded on the website was finalized in

To, 11/05/2020

Member Secretory,

Expert Appraisal Committee (Industry-II),

Ministry of Environment, Forest & Climate Change,

New Delhi

Sub: Observation of Committee during presentation and undertaking/

Commitment from PP.

Ref: Proposal No: Proposal Number: IA/GJ/IND2/98969/2019, TORs

letter No. IA-J-11011/81/2019-IA-II(I)

MoM: Minutes of 18th EAC (Industry-2) meeting held during April 13-15,

2020

Respected Sir,

This is regarding Presentation made before Expert Appraisal Committee

(Industry-II) on 13th April 2020. During the presentation, Honorable committee

has suggested some point for compliances and commitments and same was

communicated by above MoM which we are accepting herewith with and submit

following commitment.

i. EIA report uploaded on the website was finalized in March, 2019 as

per title of the Report. PP needs to upload the correct EIA/EMP

Report. The Committee suggested that the Consultant/PP has to read

all the documents before uploading on the Parivesh Portal.

It was mistake in change of Date in title page of uploaded EIA report in Form

2. Otherwise entire report is updated and finalized after PH. Chapter 7 and

CER is also updated in the submitted report. In the revised submitted report

we have included revision history summary in tabular form on the title page.

We have uploaded Final EIA report with above correction and modification in

ADS reply.

ii. PP mentioned that instant site is not located at CPA, the Committee

suggested that PP needs to submit a letter from CPCB or SPCB about

the location of project side in CPA or not.

Our project location does not fall in Critically Polluted Area (CPA) or Severely

Polluted Area (SPA) as per the MoEFCC Office Memorandum dated

31.10.2019. Gujarat Pollution Control Board (GPCB) has issue Office Order for

mechanism of environmental management of CPAs/SPAs of Gujarat State

including Map of respective areas with 10 km radius from the CPA boundary.

The map was prepared by BISAG (Bhaskaracharya Institute for Space

Applications and Geo-Informatics). BISAG is a State level agency by

Government of Gujarat to facilitate to provide services and solutions in

implementing map-based Geo Spatial Information Systems. Copy of same is

enclosed herewith for your ready reference.

Nandesari and PCCI Estate are identified CEPI areas nearest from our project

location, which are around 21 km & 20 km away from the site. Pls. refer Pg.

no. 6 & 7 of Annexure-I. It is self-explanatory that, our industrial area does

not fall in CEPI area or not in close vicinity of boundary of CEPI areas.

iii. PP has not carried out alternate site analysis. Committee is of the

view that as PP shall conduct the alternate site analysis study and

prepare the Report as per Appendix III of the EIA Notification, 2006.

Before finalization of this land for Pharma project, we have carried out

alternate site analysis and finalized land of Site-2 based on maximum criteria

fulfilled by this location. We have covered this detail in chapter 5, section 5.2

of EIA report.

iv. PP in slide number 49 mentioned that there is no schedule-I species

reported, However as per EIA/EMP Report Schedule I species were

reported. The PP needs to prepare the Conservation plan for

protection of schedule-1 species and submit to the CWLW for

approval.

Conservation plan with budgetary allocation for schedule-I spices of the study

area enclosed as Annexure-II with Acknowledgement from Office of Deputy

Conservator of Forest, Wildlife Division, Vadodara.

v. Status of TSDF membership.

We have approach to Bharuch Enviro Projects Pvt. Ltd. Dahej, Bharuch

district) a GPCB approved TSDF site and he informed that they have spare

capacity to accommodate our waste. They inform that after obtain EC from

MoEFCC New Delhi & CTE from GPCB, applied for membership with granted

quantity of waste and deposit respective amount for required membership. We

will immediately obtained TSDF membership after grant of CTE based on EC

grant by MoEFCC.

vi. Land conversion details for industrial purpose needs to be submitted.

Copy of NA order is enclosed as Annexure-III

vii. Revised detailed CER plan @ 5% of project cost and needs to be

submitted.

Please refer Annexure-IV for quick reference for increase the CER amount

from 2.5 % to 5% as suggested by Honorable EAC committee. We have

increase the CER amount from 2.5 % to 5% Modified amount is incorporated

in modified EIA report on section- E: Social Impact Assessment (Page no-7-

45), table no Table 7.12(Page no-7-50)

viii. Details technology/mitigation measure to achieve the Volatile organic

compounds (VOCs)/Fugitive emissions @ 99.997%.

Please refer Annexure-V for quick reference for mitigation measure to

achieve the Volatile organic compounds (VOCs)/Fugitive emissions @

99.997%. We have modified section 10.1.1.1: Measures for Solvent Recovery

in modified EIA report on page no-10.4.

ix. Details of fly ash brick making unit inside the plant for fly ash

disposal.

Unit committed to install and operate fly ash brick making unit inside the

plant for fly ash disposal with capacity of 2000 bricks per hour hydraulic

pressure machine for operate once in a week to utilize fly ash to be

generated from burning of Ago briquette in boiler, HAG and TFH. The criteria

of selection of fly ash brick unit is summarized below.

About 80% fly ash will be used for the production of fly ash bricks. The ratio

of Fly Ash (80%) Gypsum (15%) and sand (5%). Based on the maximum fly

ash generation (4.0 TPD), around 2000 per day *26 =52000 nos /month will

be produce. To considering 4 day production per month (Only Sunday), unit

will require 13000 brick per day capacity of machine. To considering this

aspect unit will purchase semi-automatic machine with capacity of 2000

bricks per hour hydraulic pressure machine.

Above details incorporated in modified EIA report on section 2.9.3 Fly Ash

management, page 2-41.

What is stated/committed above is bounded to comply by us. We humbly

request to process our application and issue us an Environmental Clearance at

your earliest. Our project being Pharma units please take positively.

Thanking You,

For, Reynish Pharmachem Pvt. Ltd.

Director

o

Gujarat Pollution Control BoardParyavaran Bhavan, Sector-1 0-A

Gandhinagar

Office Order

Sub: Mechanism for environmenta! management of critically and severallyPolluted Area and considerations of activities/Projects in such areasin compliance to Hon'ble NGT order dated 2310812019 in the matter ofO.A. No. 1038/2018-reg.

With reference to CPCB letter no. CPCB/IPC-VI|/CEPI/NGT/2019 dated2511012019 mechanism prepared by MoEF&CC for grant Consent toEstablishmenUConsent to Operate to those projects / activities of Red /Orange categories located in CPAsi SPAs which are not covered under theprovisions of the EIA notification,2006 are delineated.

Accordingly, it is required to prescribe the additional conditions deemedfit in the CTE / CTO of the projects / activities of Red/ Orange categories in theCPAs / SPAs of Gujarat.

After detailed discussion with industries associations of the CPA / SPAsof Gujarat and consultation with other stakeholders, it is decided to prescribefollowing additional conditions (deemed fit on case to case basis) consideringthe framework given in the letter of CPCB daled 2511012019.

These additional conditions will be applicable to the following CPAs/ SPAs ofthe Gujarat. Considering the mechanism, the 5 km from the boundary of eachCPA/ SPA should be considered as the area of influence and the additionalconditions stipulated for the new / expansion project will be made applicable toall such projects in this area. Map of the respective areas obtained fromBISAG is enclosed herewith as Annexure-1.

1. Vapi GIDC Estate

2. Sachin & Pandesara GIDC Estate (Considering monitoring carriedout by CPCB in these areas)

3. Ankleshwar Cluster (Ankleshwar and Panoli GIDC estate)

4. Nandesari GIDC & PCC Area (Considering monitoring carried out byCPCB in these areas)

5. Vatva- Narol

Page 1 of 5

a

Admin

Text Box

Annexure-I

6. AjiG|DC estate (Rajkot)

7. Chitra GIDC estate (Bhavnagar)

Specific Conditions sti ulated in Criticallv Poll uted Areas CPA)/D (

a

a

Severelv Polluted Areas (SPA).

Additional conditions under Air Act:

a) Unit shall adhere to stringent air pollutants standards i.e. 80 % of existing

flue gas and process emission standards in the CPA.

b) Unit shall adhere to stringent air pollutants standards i.e. 90 % of existing

flue gas and process emission standards in the SPA.

c) Following air pollution control measures shall be provided for the flue gas

emission sources like Boiler, Thermic Fluid Heaters etc. (As Applicable)

Stipulated APCM in Red / Orange category industrialunits of CPA/ SPA

Steam generationcapacity (in TPH)

Type of APCM

Less than 1 Multi Cyclone1to<3 Multi Cyclone

Scrubber+ Water

3to<6 Bag filter + Water Scrubber>6 ESP+ Water Scrubber

d) Unit shall provide at least two stage scrubbing system of appropriate

media for the control of the process gas emission.e) Unit shall install and commission Continuous Emission Monitoring

System- CEMS (as per CPCB guidelines for relevant parameters) which

shall be connected with GPCB/CPCB server (ln case of large and

medium red category industries)f) All common facilities shall install CEMS (as per CPCB guidelines for

relevant parameters) which shall be connected with GPCB/CPCB server

to the Stacks provided with Common Multiple Effect Evaporator (CMEE),

Common Spray Dryer, Common incinerator etc.g) The unit shall adhere to Sector specific guidelines/ SOP published by

GPCB / CPCB from time to time for effective fugitive emission control.(like guidelines for: Stone crushing units, Coal handling units, spent

spent acid management,

Page 2 of 5

solvent handling and management,Decontamination of drums, containers etc.)

h) Unit shall take adequate measures to control odour nuisance from the

industrial activities which may include measures like- use of masking

agent with atomizer System (water curtain), closed / automatic material

handling system, containment of the odour vulnerable areas etc'

Unit shall not use Pet-coke, furnace oil, LSHS as a fuel'

Unit shall adopt sectoral Best Available Technology-BAT (Like Use of

lnduction Furnace, Electric Arc Furnace instead of cupola furnace in

foundry industry, Caustic Recovery System in Cotton Textile units etc')

Unit shall provide green belt ol 40o/o of the plot area, using concept of the

social forestry and development of green belt outside project premises in

adjacent areas.

Unit shall provide wall to wall carpeting in vehicle movement areas

within premises to avoid dusting.

i)

i)

k)

r)

e Add itional conditions under the Water Act:

1 unit shall only use treated effluent for preparation of lime and other slurry

in ETP. No fresh water shall be utilized in ETP.

ln the case, if the lndustry is not a member of CETP and domestic waste

water generation is more than 10 KLPD, industry shall install STP of

adequatecapacityandtreatedSewageshallbereused/recycledtothemaximum extent.

2

3 ln case of Large and Medium Red category industry, the unit shall install

system for continuous monitoring of effluent quality / quantity as per

CPCB guidelines for relevant parameters (like pH, Flow, Temperature'

TOC/COD, NHo-N etc.) and shall be connected to GPCB server' ln case'

if the industry is a member of CETP, unit shall install flow meter'

lf the water consumption of the unit is more than 50 KLPD' Unit shall

submit detailed water harvesting plan (off site).

The unit shall explore Techno-Economic feasibility of Zero Liquid

a.

4

5

Discharge (ZLD) and if feasible, ZLD should be adopted

Page 3 of 5

Rules:

I

2

3

Unit shall strictly carry out handling, storage and disposal of fly-ash' slag'

red-mud, de-inking sludge etc (Uign Volume- Low Effect Wastes) as per

prevailing guidelinls and its disposal at designated locations approved by

L

lndustry shall dispose its hazardous wastes through co-processlng' pre.-

processing to the extent possible prior its disposal to incineration/ landfill

as per provisions of Hazardous and Other Wastes (Management and

Transboundary Movement) Rules, 20'l 6'

lndustry shall strictly comply with all the measures specified in guidelines

for spent solvent management, spent acid m.anagement' and other

g;ioetineslOirections puntLneo from time to time by GPCB and/or CPCB'

the Board.

etc.

Unit shall carry out transportation of hazardous wastes through GPS

mounted vehicles onlY

Other General Conditions:

located in CPAs/ SPAs'

.M ab a

Member Secretary

4

1 Unit shall submit report of compliance of the conditions of EC every year

to the Board prepared by third party'

Unit shall enhance CER fundallocation to at least 1 5 times the slabs

gir"n in the OM dated 01 05 2O18 for SPA and 2 times for CPA in case

of Environmental Clearance'

You are required to prescribe relevant additional conditions as

above henceforth while granting cTE / cTo of Red / orange categories

2

i)

No. GPCB/P- ltcEPt'1zt s-L6 g-s-2'-.--)

To, I

Date: { 1.1{.20{9

1. All Unit HeadsZ. nif n"gional Officers...For necessary action please'

Page 4 of 5

Additional conditions under the Hazardous Waste Management

r-

Copy to:

1. Chairman Office2. Member Secretary Office3. All Vigilance Officers... for necessary action

4. Respective File5. lT Cell-for display on Board Website'

e

a

Page 5 of 5

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Admin

Text Box

Annexure-II

Conservation Plan for Peacock or Indian Peafowl (Pavo Cristatus)

Schedule – I Bird Species

Protection Status:

As per IUCN: Classified as Least Concern (LC) on the IUCN Red List (1) and listed

on Appendix II of CITES 3.

Population Trend: Stable

Habitat: Terrestrial

Habitat Type: Forest, Scrubland, Artificial/Terrestrial

Generation Length in Year: 6.1

Movement Patterns: Non Migrant

Indian Peafowl (Pavocristatus)

Scientific classification

Kingdom: Animalia

Phylum: Chordata

Class: Aves

Order: Galliformes

Family: Phasianidae

Genus: Pavo

Species: Pavocristatus

Common Name: Indian Peafowl

Vernacular Name: Mor

Introduction: The Indian Peafowl (Pavo Cristatus) is a resident breeder in the

Indian subcontinent. The bird was declared as the National Bird of and its

widespread distribution in the country. The species is found in dry semi-desert

grasslands, shrub and deciduous forests. It forges and nests on the ground but

roots on top of trees. It eats seeds, insects, fruits, small mammals and reptiles. The

Indian Peafowl is a ground nesting bird and it lays a clutch of 4-8 eggs which take

28 days to hatch. The eggs are light brown and are laid every other day usually in

the afternoon. The male does not assist with the rearing, and is polygamous.

Poaching of Peacock for their feathers and poisoning by feeding on pesticide treated

seeds are known threats to wild birds. Under the law, collection of tail feather is

allowed only when bird sheds them. The Indian peafowl is under various threats

that include the demand for feathers and wild meat, conflict with farmers during

cropping season, increased use of chemical fertilizer and pesticide and habitat

degradation.

Habitat:

The Indian Peafowl is found mainly on the ground in open scrub forest or on land

under cultivation where they forage for berries, grains but will also prey on snakes,

lizards, and small rodents. Their loud calls make them easy to detect, and in forest

areas often indicate the presence of a predator such as a tiger. They forage on the

ground in small groups and will usually try to escape on foot through undergrowth

and avoid flying, though they will fly into tall trees to roost. The bird has a

celebrated status in Indian mythology, and hence protected culturally in India

especially in Gujarat. The Indian Peafowl is listed as Least Concern by IUCN (2014)

Red data.

Photographs of Peafowl

Appearance: The male, known as a peacock, is a large bird with a length from bill

to tail of 100 to 115 cm (40 to 46 inches) and to the end of a fully grown train as

much as 195 to 225 cm (78 to 90 inches) and weigh 4–6 kg. The females, or

peahens, are smaller at around 95 cm (38 inches) in length and weigh 2.75– 4 kg.

Indian Peafowl are among the largest and heaviest representatives of the

Phasianidae family. Their size, colour and shape of crest make them unmistakable

within their native distribution range. The male is metallic blue on the crown, the

feathers of the head being short and curled. The fan shaped crest on the head is

made of feathers with bare black shafts and tipped with blush-green webbing. A

white stripe above the eye and a crescent shaped white patch below the eye are

formed by bare white skin. The sides of the head have iridescent greenish blue

feathers. The back has scaly bronze-green feathers with black and copper

markings. The scapular and the wings are buff and barred in black, the primaries

are chestnut and the secondaries are black. The tail is dark brown and the "train" is

made up of elongated upper tail coverts (more than 200 feathers, the actual tail

has only 20 feathers) and nearly all of these feathers end with an elaborate eye-

spot. A few of the outer feathers lack the spot and end in a crescent shaped black

tip. The underside is dark glossy green shading into blackish under the tail. The

thighs are buff coloured. The male has a spur on the leg above the hind toe.

Peacocks are polygamous, and the breeding season is spread out but appears to be

dependent on the rains. Several males may congregate at a lek site and these

males are often closely related. Males at lek appear to maintain small territories

next to each other and they allow females to visit them and make no attempt to

guard harems. Females do not appear to favour specific males. Peafowl are

omnivorous and eat seeds, insects, fruits, and reptiles. A large percentage of their

food is made up of the fallen berries. Around cultivated areas; peafowl feed on a

wide range of crops such as groundnut, tomato, paddy, etc. Around human

habitations, they feed on a variety of food scraps. In the countryside, it is

particularly partial to crops and garden plants.

Status & impact in the Study Area:

No peacock was sighted in the project site. All the direct sightings of the peacock

were located near the human habitats, villages and agriculture field, of study area.

This species is well adapted to natural village environment setting. Day time they

temporarily move towards the surrounding agriculture areas for feeding while

during night time they roost on the trees present in the village and in the

agriculture hedges.

Since Indian Peafowl is a ground nester, several project activities can have adverse

Impact on their nesting grounds such as pollution, degradation of soil and

vegetation from surrounding area and in the forest areas. Direct disturbance by

presence of people, vehicle their noise, vibration, light etc. can potentially disturb

most of the bird species.

Threats in the Study Area:

No perceptible threats were identified in the study region, as

Village residents are against hunting or poaching of the peafowl, due to

culture and mythology reasons.

Majority villagers follow Hinduism in the region, thus they have high respect

towards peacocks due to mythological reasons, and

Literacy levels are greater than 80% in the study region and people are

aware with the significance of the peacock as the national bird.

Conservation: Following actions for the conservation and protection are suggested

in wildlife conservation action plan to reduce impacts of project related activities on

the species. Based on our field observation on the distribution, behavioural ecology,

conservation need, and envisaged impacts of proposed project.

Conservation through Habitat Improvement and Awareness

Habitat improvement programme can be undertaken through plantation of suitable

tree species in the surrounding villages. While selecting the tree/ shrub species care

shall be provided for beery plants which attract these birds. During summer period,

villagers will be encouraged to use the old earthen pots to fill with water for

drinking these birds.

Seed Distribution among the Villagers:

Summer is the time when these birds are facing shortage of feeds, there by

supplying the feed like Bajri, Juwar, Maize to the surrounding villages with good

population of Indian peafowls will suffix the problem of food shortage.

Conservation Measures with fund allocation:

In consultation of the forest department, following conservation measures will be

adapted for peacock conservation:

1. Increasing the tree cover in the study area which will provide shelter and

roosting to the peacocks. This can be achieved by planting of local tree species

like Neem, Shirish, Khakhro, Haldu, Amli, Banyan, Peepal and Peeper or other

Ficus sp. Vacant places such as edges of agricultural fields, village Gauchar,

Panchayat’s common land, neighbourhood of people inhibiting, road side avenue

tree plantation, open scrubs, ravines, school compounds can be selected for

practicing the plantation activity.

2. School level awareness programmes will be conducted for conservation of

peacocks in the study area by organizing competitions during “Wildlife Week”

and “Van Mahotsav” celebrations by active involvement of local community.

3. Some provision of rewards to informers for the control of poaching and illegal

trade in wildlife.

4. Carrying out census and research projects to know the potential threats and

population status of the species in collaboration of local schools, colleges,

panchayats and forest department.

5. Suggest strategies to minimize negative impacts of changing environment in

nearby area of peacock populations and to promote conservation of peacock

habitats.

6. Another way to help preserve the endangered species is to create society

dedicated to ecological ethics. All the conservation measures will be

implemented with the help of and in the consultation of the district forest

department.

The proponent has proposed a sum of Rs. 220000/- for the “Peacock”

conservation plan under the following heads:

Sr.

No.

Work or Activity Approximate

Cost. Rs.

Village

1 Plantation-350 tree plants (5 feet height

as per the plant species-Cost of sapling

will be changed per year)

70,000/-(@

200/-per

plant)

Dabhasa, Ranu,

Dhobikuwa and

Mahuvad

2 Small water tank–10 nos. @ 10000/-per

tank

1,00,000/-

3 One awareness programme for “Peacock”

conservation

20,000/- Study area

4 3 cash prizes @ 10000 in a year will be

awarded to the informer of poachers.

30,000/-

Total 2,20,000/-

Scanned by CamScanner

Admin

Text Box

Annexure-III

Annexure-IV

Revised CER based on local needs

Need Analysis of the Target Beneficiaries in the Project Area

Various needs were identified during the baseline survey within the study

area. Major problems they are facing are given below.

Poor availability of water for irrigation and drinking purpose

Lack of good medical facilities

Unemployment

Health and sanitation program

Poor educational facilities

In the assessment of socio-economic conditions, few indicators were

identified for further attention and strategic planning as given below:

Target Project Area

Total 53 villages fall within the study area; Out of which unit will give

priorities to 4 villages namely 4 villages (Dabhasa, Ranu, Dhobikuwa

and Mahuvad) for CER activities according to the below mentioned criteria.

Largely affected by industrial growth

Vicinity to the project site

Sourcing of employees from these areas

Low level socio-economic status of the people

Lack of adequate intervention of voluntary organization in the

area

The focus area of comprehensive program includes: health, education,

sanitation, sustainable livelihood & infrastructure development.

Details of expenditure for ESR activities(Revised):

Cost of the proposed project : Rs. 40 Crores

Expenditure earmarked towards ESR : Rs. 2.0 Crore

(5.0 % of the total project cost)

Detailed expenditure break-up for CER activities*

Sr.

No.

Activities Years (Rs. in lakhs) Total

Budget

(Rs. in

Lakhs)

1st 2nd 3rd

1 Educational activities

Computers 6.08 6.08 -- 12.16

Scholarship 12.8 12.8 12.8 38.4

2 Drinking water facilities 12 sets of RO and

water cooler at

Primary school and

village Panchayat of 4

villages

14.0 14.0 14.0 42.0

Operating and

maintenance cost

2.0 2.0 2.0 6.0

3 Public Health and family

welfare

Around 10 camp with

cluster of 5 to 6

villages

4.0 4.0 4.0 12.0

Free Medicines 6.0 6.0 6.0 18.0

4 Provide Sawing and

embroidery machine to

women coming from

BPL family and widow

women.

All 53 villages in the

study area

Onetime 100 nos

Sawing machine

5.0 5.0 5.0 15.0

Onetime 50 no

embroidery Machine

5.0 5.0 2.5 12.5

5 Widening and digging of

four village pond

namely

Dabhasa, Bhoj Ranu

Pond and Dabka and

other as per the

suggestion by local

authorities.

8 village pond 22.0 22.0 -- 44.0

Total 76.88 76.8

8

46.3 200.06

*Increase the CER budget from 2.5% to 5.0% as suggested by EAC

committee (Industry-II). Reduce the estimated utilization fund

within 5 years to 3 years. However, project will completed earlier

then the estimated time then utilize CER fund accordingly.

Quantify CER activities in details

Proposed Activities Selected areas or

villages

Frequency Financial provision

in Lakhs

Educational

Provide the

Computer

Secondary School

and Higher

Secondary school of

4 villages

One time

8 Computer x 4

32 x 38000

Total Rs. 12.16

Scholarship to poor

children around 160

students

(40 on merit basis of

each 4 village

student of Secondary

& Higher secondary

school

Every year up to 3

years

Rs.8000 x 160 x 3

Years

Total Rs.38.4

Drinking water facility

Water Cooler, RO

4 sets of RO and

water cooler at

Primary school of 4

villages

Onetime

350000 x 10

Total Rs.42.0

8 sets of RO and

water cooler at

Village Panchayat of

8 villages

Operating and

maintenance cost

-- Three Years 12 x 0.5

Total Rs.6.0

Public Health and family welfare

Medical camp and

free medicine

Around 10 camp with

cluster of 5 to 6

villages

10 camp up to three

Years during rainy

days

10 x 0.4 x 3 years

Total Rs.12.0

Free Medicines 10 x 0.6 x 3 years

Total Rs.18.0

Women Empowerment & children Development activities

Provide Sawing and

embroidery machine

to women coming

from BPL family and

widow women.


study area

Onetime

100 nos Sawing

machine

100 x 15000

Total Rs.15.0

Onetime

50 no embroidery

Machine

50 x 25000

Total Rs.12.5

Environment Sustainability - Ground water recharging

Widening and digging

of four village pond

namely

Dabhasa, Bhoj Ranu

Pond and Dabka and

other as per the

suggestion of local

authorities.

8 village pond One time

(550000

x 8 =

Total 44.0

Total Rs. 200.06 Lakhs

Annexure-V

Details technology/mitigation measure to achieve the Volatile

organic compounds (VOCs)/Fugitive emissions @ 99.997%.

Unit will use Methanol, Dichloromethane, Isopropyl Alcohol, Ethyl Acetate,

Acetone, Toluene, Chloroform, Hexane and Dimethyl Formamide (DMF) etc.

These are mostly transferred to reactors by means of pumps and their

related pipelines. Pumps are provided with proper mechanical seal, and

pipeline is connected with each other by flanges and gaskets. There will be

practically no emission of solvents in form of VOCs. The leak detector and

emission will be checked by digital transmitter with smart sensor. If the

detection level exceed in the work area of half level of TLV/TWA value,

immediate action will be taken by operator to shut down valve/pump to

prevent the leak and emission of gas. Periodically preventive maintenance

schedule shall also be conducted by team.

Unit will handle following solvent having following physical properties namely

BP oC and FP oC.

Solvent to be used with B.P. and F.P. Sr. No. Name of solvent BP oC FP oC

1 Methanol 64.5 12

2 Dichloromethane 39.75 NA

3 Isopropyl Alcohol 82.5 18.3

4 Ethyl Acetate 77.0 -4.4

5 Acetone 56.2 -20

6 Toluene 110.6 4.44

7 Chloroform 61 NA

8 Hexane 69 -22

9 Dimethyl Formamide (DMF) 153 57.7

Unit will follow following LDAR (Leak Detection and Repair)

Programme.

1. Unit will prepare summary of possible Sources of equipment leaks like;

Pumps, Valves, Joints/ Connectors, Pressure relief devices, Open-

ended lines etc.

2. Regular monitoring to check and repair leaking components, including

valves, pumps, connectors, compressors, and agitators, in order to

minimize the emission of fugitive volatile organic compounds (VOCs).

3. Unit will use VOC meter to detect the VOCs and its source to repairing

any leakages

4. Find the Sources of leakages, its Causes and Control the Leaks by way

of modifying/replacing leaking equipment with “leakless” components.

5. Develop awareness of the benefits of leak detection and repair into the

company’s operating and maintenance program in terms of cost

savings, environmental protection, and worker and community safety.

6. Reducing Product Losses, Increasing Safety for Facility Workers and

Operators, Decreasing Exposure for the Surrounding Community,

Avoiding Enforcement Actions.

7. Install Brine chiller (-10 to -200C chiller) for secondary condenser of

solvent recovery system to achieve VOCs loss practically zero.

8. Use Double seal/mechanical seal for control of VOC.

9. Closed handling system shall be provided for chemicals.

10. Reflux condenser shall be provided over reactor.

11. System of leak detection and repair of pump/pipeline based on

preventive maintenance.

12. The acids shall be taken from storage tanks to reactors through closed

pipeline.

13. Storage tanks shall be. vented through trap receiver and condenser

operated on chilled water

14. The condensers shall be providing with sufficient HTA and residence

time to achieve maximum recovery.

15. Solvents shall be stored in a separate space specified with all safety

measures

16. Proper Earthing shall be providing in all the electrical equipment

wherever solvent handling is done.

17. Entire plant shall be flameproof. The solvent storage tanks shall be

providing with breather valve to prevent losses.

Final Environmental Impact

Assessment Report &

Environment Management Plan

of

Reynish Pharmachem Pvt. Ltd.

Survey No. 504, 505, 507, Village: Dabhasa,

Tehsil: Padra, Dist. Vadodara, Gujarat

Proposed Project for Manufacturing of

Bulk Drugs - 50 MTPM

Project Activity: 5(f), Category: A

[ToR Letter No. F. No. J-11011/194/2018-IA-II(I), dated 13.07.2018]

[Study Period: October, 2018 to December, 2018]

Prepared by

San Envirotech Pvt. Ltd.

(NABET Accreditation No. NABET/EIA/1619/RA0084; Valid till 15.06.2020)

424, Medicine Market, Paldi Cross Road, Ahmedabad-380006, Gujarat

Email: [email protected]

Version History

SAN-EIA-REY-V1 March 2019 Submitted for PH

SAN-EIA-REY-V2 August 2019 Modified after PH, submitted to MOEF&CC for

appraisal

SAN-EIA-REY-V3 May 2020 Modified after 18th EAC (Industry-2)

meeting

mailto:[email protected]

San Envirotech Pvt. Ltd., Ahmedabad

Final EIA Report of Reynish Pharmachem Pvt. Ltd. I

Contents Particulars Page No.

Index I

List of Tables X

List of Figures XIII

List of Annexures XIV

Index Chapter 1 Introduction Page No.

1.1 Preface 1-1

1.2 Purpose of the Report 1-1

1.3 Identification of Project & Project Proponent 1-2

1.4 Importance of the project 1-2

1.5 Brief description of project 1-3

1.6 Applicable environmental regulatory framework 1-4

1.7 Scope of the study 1-5

1.8 Compliance to Terms of Reference 1-5

1.9 Objective of EIA 1-18

1.10 Methodology for EIA 1-18

1.11 List of Industries surrounding project site 1-19

1.12 Structure of report 1-21

Chapter 2 Project Description

2.1 Introduction 2-1

2.2 Location of the Project 2-1

2.3 Size or magnitude of operation 2-4

2.3.1 Land breakup & project site layout 2-4

2.3.2 Project Magnitude 2-5

2.4 Infrastructure Facilities 2-6

2.5 Description of manufacturing process 2-7

2.6 Project Components 2-28

2.7 Input Requirements 2-28

2.8 Generation of pollutants 2-34

2.8.1 Wastewater generation 2-34

2.8.2 Gaseous emission 2-34

2.8.3 Hazardous/ solid waste generation 2-36


Final EIA Report of Reynish Pharmachem Pvt. Ltd. II

2.8.4 Noise Generation 2-37

2.9 Pollution control strategy 2-37

2.9.1 Effluent management 2-37

2.9.2 Air pollution control measures 2-40

2.9.3 Hazardous/solid waste management 2-41

2.9.4 Noise pollution control measures 2-42

2.10 Rain water harvesting 2-42

2.11 Green Belt Development 2-42

2.12 Occupational health & safety 2-42

Chapter 3 Description of Environment

3.1 General 3-1

3.2 Study area 3-1

3.3 Study Period 3-2

3.4 Source of environmental data generation 3-2

3.5 Methodology 3-3

3.6 Land Environment 3-3

3.6.1 Land use pattern of the Study Area 3-3

3.6.2 Objective of Land Use Studies 3-5

3.6.3 Topography 3-5

3.6.4 Seismicity of the area 3-5

3.7 Meteorology 3-6

3.7.1 Site specific micro-meteorological data 3-6

3.7.2 Wind Rose 3-7

3.8 Ambient air quality 3-7

3.8.1 Introduction 3-7

3.8.2 Design of Network for Ambient Air Quality

Monitoring Stations

3-7

3.8.3 Reconnaissance 3-8

3.8.4 Parameters, Frequency and monitoring

Methodology

3-8

3.8.5 Interpretation of result 3-9

3.9 Water Environment 3-10

3.9.1 Geology 3-10

3.9.2 Hydrogeology 3-11

3.10 Water quality 3-12


Final EIA Report of Reynish Pharmachem Pvt. Ltd. III

3.10.1 Introduction 3-12

3.10.2 Sampling Frequency, Techniques & Methodology 3-13

3.10.3 Surface Water Quality (Primary data) 3-14

3.10.4 Ground Water Quality 3-14

3.10.5 Interpretation 3-14

3.10.6 Conclusion 3-15

3.11 Noise Environment 3-15

3.11.1 Instrument used for Sampling and Monitoring 3-15

3.11.2 Noise Quality Monitoring Locations 3-16

3.11.3 Ambient Noise Standards 3-16

3.11.4 Results 3-16


3.12 Soil Environment 3-17

3.12.1 Soil sampling locations 3-17

3.12.2 Methodology 3-18

3.12.3 Corollaries 3-19


3.13 Biological Environment 3-20

3.13.1 Period of the study 3-20

3.13.2 Study methodology 3-20

3.13.3 Floral species in the study area 3-21

3.13.4 Fauna in the study area 3-21

3.14 Socio Economic Environment 3-23

3.14.1 Objective of the study 3-23

3.14.2 Land use pattern and infrastructure 3-23

3.14.3 Demographic and Socio-Economic Environment 3-24

3.14.4 Living Standard and Infrastructure 3-24

Chapter 4 Anticipated Environmental Impacts &

Mitigation Measures

4.1 General 4-1

4.2 Identification of Impact 4-2

4.2.1 Identification of Impacting Activities 4-2

4.2.2 Identification of Environment Attributes 4-3

4.3 Impact on Topography 4-3

4.4 Impact on Air Environment 4-3

4.4.1 Air Pollution Dispersion modeling of stack 4-4


Final EIA Report of Reynish Pharmachem Pvt. Ltd. IV

4.4.2 Micrometeorology 4-5

4.4.3 Input data 4-6

4.4.4 Receptor Network 4-6

4.4.5 Output of Model (24-hourly GLCs) 4-7

4.4.6 Incremental & cumulative concentration of

pollutants

4-7


4.5 Impact on Water Environment 4-7

4.6 Impact on Noise Environment 4-9

4.7 Impact on Land Environment 4-10

4.8 Impact on Biological Environment 4-11

4.9 Impact on Socio-Economic Environment 4-14

4.10 Impact on Occupational Health & Safety 4-15

4.11 Impact on Traffic Movement 4-16

Chapter 5 Analysis of Alternatives

5.1 Prologue 5-1

5.2 Site Alternative 5-1

5.3 Process Alternative 5-4

Chapter 6 Environmental Monitoring Program

6.1 Prelude 6-1

6.2 Environment Monitoring Program 6-1

6.3 Objective of Monitoring Plan 6-1

6.4 Schedule for Environment Monitoring 6-2

6.5 Ambient Air Quality Monitoring 6-2

6.6 Water Environment Monitoring 6-3

6.7 Noise Environment Monitoring 6-3

Chapter 7 Additional Studies

(A) HAZARD ANALYSIS & RISK ASSESSMENT 7-1


7.2 Risk Assessment- Identification of Hazards 7-1

7.3 Hazardous Materials Storage 7-3

7.4 Risk Screening Approach 7-4

7.4.1 Acute Exposure Guideline Levels (AEGLs) 7-7

7.4.2 Emergency Response Planning Guidelines (ERPGs) 7-9

7.5 QRA Approach 7-10

7.6 Thermal Hazards 7-10


Final EIA Report of Reynish Pharmachem Pvt. Ltd. V

7.7 Damage due to explosion 7-12

7.8 Toxic release 7-12

7.9 Acid/Alkali Hazards 7-13

7.10 Likely Failure Scenarios 7-14

(B) Quantitative Risk Assessment & Consequence

Analysis

7-15

7.11 Preamble 7-15

7.11.1 Weather Effect 7-15

7.12 Incidents Impacts 7-15

7.13 Consequential Impacts 7-18

7.13.1 Thermal and Explosion Hazards 7-18

7.13.2 Toxic Hazards 7-18

7.13.3 Other Hazards 7-19

7.13.4 Other Toxic Hazards 7-19

7.14 Occupational Health 7-19

7.15 Conclusion & Recommendations 7-22

7.16 Action plan for handling & safety system of

chemical

7-23

7.16.1 Safety measures for transportation and unloading

of hazardous chemicals

7-23

7.16.2 Safety measures for storage/handling of hazardous

chemicals

7-23

7.16.3 Safety measures for process units 7-24

7.16.4 Safety measures for preventive maintenance 7-25

7.16.5 Safety measures to prevent spillage/leakage of

toxic chemicals

7-25

7.17 Arrangements for ensuring health & safety of

workers engaged in handling of toxic materials

7-25

(D) Disaster management plan 7-27

7.18 Onsite Emergency plan 7-29

7.18.1 Incident controller 7-29

7.18.1.1 Duties of Incident controller 7-29

7.18.2 Site main controller 7-30

7.18.2.1 Duties of site main controller 7-30

7.18.3 Other key personnel 7-31

7.18.3.1 Emergency response team 7-31

7.18.3.2 Emergency personnel’s responsibilities outside

normal working hours of the factory

7-31


Final EIA Report of Reynish Pharmachem Pvt. Ltd. VI

7.18.3.3 Assembly points 7-32

7.18.4 Emergency control centre 7-32

7.18.4.1 Role of emergency control centre 7-32

7.18.5 Fire & Toxicity control arrangements 7-33

7.18.6 Medical arrangements 7-33

7.18.7 Transport & evacuation, mutual aid arrangements 7-33

7.19 Communication system 7-33

7.19.1 Declaring the emergency 7-33

7.19.1.1 Type of sirens 7-33

7.19.1.2 Location of siren 7-34

7.19.1.3 Raising alarm 7-34

7.19.2 Internal communication 7-35

7.19.2.1 Availability of key personnel outside normal

working hours

7-35

7.19.3 Communication to the authorities 7-35

7.20 Pre emergency activities 7-36

7.21 Post-emergency activities 7-36

7.21.1 Evacuation and transportation 7-36

7.21.2 Safe close down 7-37

7.21.3 Use of mutual aid 7-37

7.21.4 Use of external authorities 7-37

7.21.5 Medical treatment 7-37

7.21.6 Accounting for personnel 7-37

7.21.7 Access to records 7-37

7.21.8 Public relations 7-37

7.21.9 Rehabilitation 7-37

7.22 Causes of emergency 7-38

7.22.1 Risk 7-38

7.22.1.1 Nature 7-38

7.22.1.2 Various emergency actions 7-38

7.22.1.3 Response time-minutes 7-39

7.23 Offsite emergency plan 7-39

7.23.1 Need of the site emergency plan 7-39

7.23.2 Structure of the off-site emergency plan 7-40

7.23.3 Role of the factory management 7-40

7.23.4 Role of emergency co-ordination office (ECO) 7-40


Final EIA Report of Reynish Pharmachem Pvt. Ltd. VII

7.23.5 Role of local authority 7-40

7.23.6 Role of fire authorities 7-40

7.23.7 Role of the police and evacuation authorities 7-40

7.23.8 Role of health authorities 7-41

7.23.9 Role of mutual aid agencies 7-41

7.23.10 Role of factory inspectorate 7-41

7.24 Mock drills and records 7-41

7.24.1 Need of rehearsal & training 7-41

7.24.2 Some check points 7-41

7.24.3 Records and updating the plan 7-41

(D) PUBLIC CONSULTATION 7-42

(E) Social Impact Assessment 7-45

Chapter 8 Project Benefits


8.2 Improvement in Physical Infrastructure 8-1

8.3 Improvement in Social Infrastructure 8-1

8.4 Employment Potential 8-2

8.5 Other Tangible Benefits 8-2

Chapter 9 Environmental Cost Benefit Analysis 9-1

Chapter 10 Environment Management Plan


10.2 Environmental Management During Construction

Phase

10-2

10.2.1 Air & Noise Environment 10-2

10.2.2 Water Environment 10-2

10.2.3 Socio-Economic Environment 10-2

10.2.4 Health & Safety 10-2

10.3 Environmental Management during the Operational

Phase

10-3

10.3.1 Air Pollution Management 10-3

10.3.1.1 Source of Air Pollution & Control Measures 10-3

10.3.1.2 Measures for Solvent Recovery 10-4

10.3.1.3 Odour Control Plan 10-6


10.3.3 Hazardous/Solid waste management 10-7

10.3.4 Noise Control 10-8


Final EIA Report of Reynish Pharmachem Pvt. Ltd. VIII

10.3.5 Green Belt Development 10-9

10.3.6 Occupational Health & Safety Plan 10-11

10.3.7 Details of the separate isolated storage area 10-13

10.4 Post Project Environmental Monitoring 10-13

10.4.1 Details of Work Place Air Quality Monitoring Plan 10-15

10.5 Environment Management Budget Allocation 10-15

10.6 Environmental Management Cell 10-15

10.6.1 Hierarchical Structure of Environmental

Management Cell

10-16

10.6.2 Environment Policy 10-16

10.6.3 Reporting System of Non-Compliances/Violations

of Environmental Norms

10-17

10.6.4 Framework for Continual Improvement of

Environmental Performance of Organization

10-18

10.7 Resource Conservation and Cleaner Production 10-18

10.8 Energy conservation programme 10-19

10.9 Socio Economic Activities 10-19

Chapter 11 Summary & Conclusion

11.1 Project Description 11-1

11.1.1 General Introduction 11-1

11.1.2 Brief project description 11-1

11.1.3 Investment of the Project 11-2

11.1.4 List of Products 11-2

11.2 Description of Environment 11-2

11.2.1 Baseline Environmental Study 11-2

11.2.2 Air Environment 11-3


11.2.4 Noise Environment 11-5

11.2.5 Soil Quality 11-6

11.2.6 Biological Environment 11-6

11.2.7 Socio-Economic Environment 11-6

11.3 Anticipated Environmental Impacts and Mitigation

Measures

11-6

11.3.1 Summary of Impacts on Air Environment 11-6

11.3.2 Summary of Impacts on Water Environment 11-7

11.3.3 Impacts on Noise quality & Mitigation measures 11-8

11.3.4 Summary of Impacts on Land Environment 11-8


Final EIA Report of Reynish Pharmachem Pvt. Ltd. IX

11.3.5 Summary of Impact on Socio Economy 11-9

11.3.6 Summary on Impact on Ecology 11-9

11.4 Environment Monitoring Programme 11-9

11.5 Additional Studies 11-10

11.5.1 Risk Assessment 11-10

11.6 Project Benefits 11-10

11.7 Environmental Management Plan 11-10

11.8 Conclusion 11-12

Chapter-12 Disclosure of Consultant engaged

12.1 Preface 12-1

12.2 Details of EIA Consultant Organization 12-1


Final EIA Report of Reynish Pharmachem Pvt. Ltd. X

List of Tables

Table No.

Name Page No.

1.1 Salient features of the project 1-3

1.2 Product details 1-4

2.1 Boundary coordinates of the site 2-3

2.2 Land breakup 2-4

2.3 List of products with its capacity 2-5

2.4 List of machineries/equipment 2-6

2.5 Raw Materials Requirement, Availability & of Transport

Mode

2-28

2.6 Breakup of water consumption & w/w generation 2-32

2.7 Details of utilities and fuel consumption 2-34

2.8 Details of stacks 2-35

2.9 Estimated Emission quality of stack 2-35

2.10 Details of solid/Hazardous waste 2-36

2.11 Name and size of ETP units 2-38

2.12 Technical specification of RO 2-39

2.13 Technical Details of MEE 2-40

2.14 Estimated characteristic of untreated and treated effluent 2-40

3.1 Environmental setting of the study area 3-2

3.2 Land use statistics work out based on satellite imaginary 3-5

3.3 Monitoring Methodology of Meteorological Data 3-6

3.4 Meteorological Data for the Monitoring Period 3-7

3.5 Methodology of Ambient Air Monitoring 3-8

3.6 Monitored Parameters and Frequency of Sampling 3-9

3.7 Sampling locations with source & date of sampling 3-13

3.8 Monitoring Methodology of Noise 3-16

3.9 Location of soil sampling 3-18

3.10 Methodology of Soil Sample analysis 3-18

3.11 Ambient Air Quality Monitoring Locations 3-26

3.12 Ambient Air Quality Status 3-27

3.13 Ambient Air Quality Status (PM10) 3-28

3.14 Ambient Air Quality Status (PM2.5) 3-29

3.15 Ambient Air Quality Status (SO2) 3-30

3.16 Ambient Air Quality Status (NOx) 3-31


Final EIA Report of Reynish Pharmachem Pvt. Ltd. XI

3.17 Ambient Air Quality Status (CO, HC (Methane & non-

Methane), VOC, HCl)

3-32

3.18 National Ambient Air Quality Standards 3-33

3.19 Results of Groundwater Quality in the Study Area 3-34

3.20 Surface water analysis of Study Area 3-35

3.21 Indian Standard Specification for Drinking Water 3-36

3.22 Ambient Noise Levels in the Study Area 3-37

3.23 Ambient Air Quality Standards with respect to Noise 3-37

3.24 Soil Analysis of Study area 3-38

3.25 Floral Diversity 3-39

3.26 Faunal Biodiversity 3-41

3.27 Traffic Survey 3-42

3.28 Land Use Pattern 3-43

3.29 Summary of Socio-Economic Status of Study area

(Demography)

3-45

3.30 Summary of Socio-Economic Status of Study area

(Amenities)

3-47

4.1 Input data for air quality modeling 4-17

4.2 Cumulative Concentrations at various locations 4-18

4.3 The 24-hourly average GLC Concentration Values for SPM 4-19

4.4 The 24-hourly average GLC Concentration Values for SO2 4-20

4.5 The 24-hourly average GLC Concentration Values for NOx 4-21

4.6 The 24-hourly average GLC Concentration Values for HCl 4-22

6.1 Environment Monitoring Plan 6-4

7.1 Bulk storage of Hazardous Chemicals 7-3

7.2 Hazard Analysis- Raw materials (stored in bulk) 7-5

7.3 Properties of Hazardous Materials 7-7

7.4 Risk Classification 7-10

7.5 Effects due to Incident Radiation intensity 7-11

7.6 Thermal Radiation Impact to human 7-11

7.7 Tolerable Intensities for various objects 7-11

7.8 Damage due to overpressure 7-12

7.9 Different failure scenarios 7-14

7.10 Hazards scenario impact 7-18

7.11 Points raised during public hearing 7-42

7.12a Detailed expenditure break-up for CER activities 7-50

7.12b Quantify CER activities in details 7-51


Final EIA Report of Reynish Pharmachem Pvt. Ltd. XII

10.1 Details of solvent to be used 10-4

10.2 Environment Monitoring Plan 10-14

10.3 Budget Allocation for Environment Management 10-15

10.4 Budgetary provisions for the social upliftment 10-21


Final EIA Report of Reynish Pharmachem Pvt. Ltd. XIII

List of Figures

Figure No.

Name Page No.

2.1 Location of the project site 2-2

2.2 Location of Google map 2-3

2.3 Image showing all boundary coordinates of the site 2-3

2.4 Plant layout 2-5

2.5 Water Balance Diagram 2-33

2.6 Process flow chart of wastewater treatment 2-39

3.1 Land use map 3-4

3.2 Graphical representation of ambient air quality 3-27

3.3 Graphical representation for PM10 3-28

3.4 Graphical representation for PM2.5 3-29

3.5 Graphical representation for SO2 3-30

3.6 Graphical representation for NOx 3-31

3.7 Location of AAQM station 3-54

3.8 Wind Rose Diagram 3-55

3.9 Water sampling Locations 3-56

3.10 Noise monitoring Locations 3-57

3.11 Soil Sampling Locations 3-58

3.12 Topo sheet of location with site location map of 10 km radius (1:50,000 scale)

3-59

4.1 Isopleths for Ground Level Concentration for SPM 4-23

4.2 Isopleths for Ground Level Concentration for SO2 4-24

4.3 Isopleths for Ground Level Concentration for NOx 4-25

4.4 Isopleths for Ground Level Concentration for HCl 4-26

7.1 Methanol Tank BLEVE — Thermal Impact Zone 7-16

7.2 Dichloromethane Tank Leakage — Toxic Impact Zone 7-16

7.3 Ethyl Acetate Tank Leakage Pool Fire —Thermal Impact

Zone

7-17

7.4 Acetone Tank Leakage — Toxic Impact Zone 7-17

7.5 Hydrochloric Acid Tank Leakage – Toxic Impact Zone 7-17

10.1 Environment Management Cell 10-16


Final EIA Report of Reynish Pharmachem Pvt. Ltd. XIV

List of Annexures

Sr. No. Annexures Page no.

I. NABET-QCI Certificate A–1

II. Photographs of the Site A–3

III. Land Possession Documents A–4

IV. Material Safety Data Sheet of Chemicals A-9

V. Undertaking from Consultant A–111

VI. Undertaking from Project Proponent A–112

VII. Copy of Terms of Reference (TOR) A–114

VIII. Minutes of Public hearing A–122

IX. Hourly Meteorological data A–153

X. Detailed AAQM, Ground Water, Surface Water, Soil,

Noise Result Tables

A–199

XI. Wildlife Conservation Plan submitted for Schedule I

species Pavo Cristatus

A–215


Final EIA Report of Reynish Pharmachem Pvt. Ltd. 1-1

Chapter-1

Introduction

1.1 PREFACE

An Environmental Impact Assessment (EIA) is an assessment of the

possible impacts that a proposed project may have on the environment -

consisting of the environmental, social and economic aspects. It is an

assessment and management tool that evaluates the possible impacts,

positive or negative, that a proposed project may have on the

environment. EIA systematically examines both beneficial and adverse

consequences of the project and ensures that these effects are taken into

account during project design. The purpose of the assessment is to

ensure that decision makers consider the ensuing environmental impacts

when deciding to proceed with a project. In India, Ministry of

Environment and Forests has defined elaborated “Environmental

Clearance (EC)” framework along with requirements for preparing

Environmental Impact Assessment (EIA) under the Environmental

(Protection) Act, 1986 (Environmental Impact Assessment Notification,

2006) for establishing/expanding and industry/development projects.

1.2 PURPOSE OF THE REPORT

Industrialization and infrastructure development have increased economic

growth and improved living standards of people in India. However,

development has led to rapid consumption of natural resources and

increased emissions of waste. To control the pollutions from industrial

activity, government has framed regulations which are governed by

Ministry of Environment, Forest & Climate Change in India. Environment

Impact analysis is mandatory as per the Environment Impact Assessment

(EIA) Notification issued by Ministry of Environment, Forest & Climate

Change (MoEF&CC), New Delhi dated 14th September, 2006 and its

subsequent amendment; for setting up a new projects or activities, or

expansion or modernization of existing projects or activities based on

their potential environmental impacts as indicated in the Schedule to the

notification, being undertaken in any part of India, unless prior

environmental clearance has been accorded.



Proposed activity of M/s. Reynish Pharmachem Pvt. Ltd. falls under

the schedule of 5(f) category- Synthetic organic chemicals industry

(dyes & dye intermediates; bulk drugs and intermediates excluding drug

formulations; synthetic rubbers; basic organic chemicals, other synthetic

organic chemicals and chemical intermediates) and categorized under

“A”. Therefore, unit requires prior Environmental Clearance for proposed

project.

EIA Consultant

In view of the above, legal aspect and monitoring work has been carried

out for all the environmental attributes by M/s. San Envirotech Pvt.

Ltd. (SEPL), Ahmedabad. SEPL is accredited as Category-A organization

under the QCI-NABET Scheme for accreditation of EIA consultant

Organizations: Version 3 for preparing EIA-EMP reports in 10 sectors.

Final Environment Impact Assessment (EIA) and Environmental

Management Plan (EMP) have been prepared after obtaining Terms of

References (TORs) from Ministry of Environment, Forests & Climate

Change (MoEF&CC), New Delhi. The public hearing will be conducted by

SPCB based on draft EIA/EMP submitted by project proponent. Final

EIA/EMP report is prepared incorporating to comments of Public hearing

and compliance of the Terms of References.

1.3 IDENTIFICATION OF PROJECT & PROJECT PROPONENT

Project is promoted by young entrepreneur Nishant P. Patel. Reynish

Pharmachem Pvt. Ltd. proposes to set up bulk drugs manufacturing

unit at Survey no. 504, 505, 507, Village: Dabhasa, Ta: Padra, District:

Vadodara, Gujarat. Required facilities like infrastructure, communication,

medical facilities, fuel, water, power, unskilled & skilled manpower, raw

materials, road network etc. are readily available, therefore, no other

optional site or area was considered. There is no Rehabilitation and

Resettlement involved. Nearest city Vadodara is about 20 km away from

the site, which is having connectivity with other parts of the country by

road, rail & air.

1.4 IMPORTANCE OF THE PROJECT

The Indian pharmaceuticals market is the 3rd largest in terms of volume

and 13th largest in terms of value. It accounts for 20% in the volume



terms and 1.4% in value terms of the Global Pharmaceutical Industry as

per a report by Equity Master. India is the largest provider of generic

drugs globally with the Indian generics accounting for 20% of global

exports in terms of volume. The Indian pharmaceutical market size is

expected to grow to US$ 100 billion by 2025, driven by increasing

consumer spending, rapid urbanization, and raising healthcare insurance

among others. Pharma sector‟s revenues are expected to grow by 9 per

cent year-on-year through fiscal 2020. India having unique blend of low-

cost manufacturing, R&D infrastructure, skilled workforce, as well as

gigantic domestic market and world dominance in generics production,

needs to increase its production capacity of pharmaceuticals.

1.5 BRIEF DESCRIPTION OF PROJECT

Salient features of the project and list of products are given in Table 1.1

and Table 1.2, respectively.

Table 1.1 Salient Features of the Project

Name of the Project Reynish Pharmachem Pvt. Ltd.

Proposed production capacity 50 MTPM

Proposed project cost Rs. 40 Crores

Manpower requirement About 65 persons

Location

Survey No. 504, 505, 507

Village Dabhasa

Tehsil Padra

District Vadodara

State Gujarat

Area 36958 m2

Coordinates Latitude: 22°13'32.76"N

Longitude: 73° 1'13.01"E

Nearest

Railway Station Vadodara Railway Station - 19 km,

Padra Railway station - 7.0 km

Air Port Vadodara Airport, about 24 km

Town Padra, about 7.0 km

City, District Headquarters Vadodara, about 20 km

National Park/Wildlife Sanctuary None, within 10 km radius



Table 1.2 Product details

Sr.

No.

Name of Products Qty.

(MTPM)

1. Telmisartan 48.0

2. Ondansetron HCl

3. Benfotiamine

4. Albendazole

5. 4-Hexyl resorcinol

6. Zopiclone

7. Tamoxifen citrate

8. Bupropion HCl

9. Anstrozole

10. Theophylline

11. Allantoin

12. Terbinafine Hydrochloride

13. Pregabalin Hydrochloride

14. Rebamipide

15. Valsartan

16. R & D Drugs 2.0

Total 50.0

1.6 APPLICABLE ENVIRONMENTAL REGULATORY FRAMEWORK

The proposed project will abide and function under the purview of the

following Rules, Acts & Regulations which are formulated by the Govt. of

India to protect the environment and development in a sustainable way.

The Water (Prevention & Control of Pollution) Act, 1974

The Air (Prevention & Control of Pollution) Act, 1981

The Environmental (Protection) Act, 1986

Environmental Impact Assessment Notification dated 14th September

2006 and subsequent amendments

The Hazardous & Other Waste (Management and Transboundary

Movement) Rules, 2016

Noise Pollution (Regulation and Control) Rules, 2000 and its

amendments

The Public Liability Insurance Act, 1991



1.7 SCOPE OF THE STUDY

The scope of the EIA study is based on the guideline provided by Ministry

of Environment, Forests & Climate Change, and Government of India. The

scope of the study broadly includes:

Field sampling of environmental attributes at various representative

locations in the study area to establish the baseline status;

Collect & compile secondary data including socio-economic data;

Identification, assessment and evaluation of the beneficial and

adverse impacts on surrounding environment due to proposed

project activities considering the existing baseline status along with

compilation of other information.

Analysis of project proposal and data analysis.

Assessment of pollution potential due to proposed project.

Predict the incremental levels of pollutants in the study area due to

the proposed project;

Evaluate the predicted impacts on the various environmental

attributes by using scientifically developed and widely accepted

models.

Identification and assessment of risks associated with the proposed

project and their appropriate management through proper Risk

Assessment (RA) and Disaster Management Plan (DMP).

Prepare an Environmental Management Plan (EMP) to mitigate the

predicted impacts; and

Identify critical environmental attributes required to be monitored

during the project execution and to suggest post project monitoring.

The scope also includes all the conditions outlined in the TOR issued by

MoEF&CC and the compliance to the TOR is given below.

1.8 COMPLIANCE TO TERMS OF REFERENCE

The Ministry of Environment, Forest and Climate Change to prescribed

the Standard Terms of Reference (TOR) “IA-J-11011/194/2018-

IA-II(I)” dated 13 July 2018 for undertaking detailed EIA study for

the purpose of obtaining Environmental Clearance in accordance with the

provisions of the EIA Notification, 2006.



Compliance of TORs is as below:

Sr.

No.

Condition Compliance

A. Specific TOR

i Public consultation for obtaining

prior environmental clearance is

prescribed.

The public hearing was conducted

by GPCB on 21.06.2019. Public

hearing proceeding is enclosed as

Annexure-VIII.

5(F) STANDARD TERMS OF REFERENCE FOR CONDUCTING ENVIRONMENT

IMPACT ASSESSMENT STUDY FOR SYNTHETIC ORGANIC CHEMICALS

INDUSTRY (DYES & DYE INTERMEDIATES; BULK DRUGS AND

INTERMEDIATES EXCLUDING DRUG FORMULATIONS; SYNTHETIC

RUBBERS; BASIC ORGANIC CHEMICALS, OTHER SYNTHETIC ORGANIC

CHEMICALS AND CHEMICAL INTERMEDIATES) AND INFORMATION TO BE

INCLUDED IN EIA/EMP REPORT

A STANDARD TERMS OF REFERENCE

1. Executive Summary Enclosed as Chapter-11.

2. Introduction

i. Details of the EIA Consultant

including NABET accreditation.

Details of EIA consultant is given in

Chapter-12 „Disclosure of

Consultant engaged‟.

NABET accreditation certificate is

enclosed as Annexure-I.

ii. Information about the project

proponent.

It is described in Chapter-1,

Section 1.3 (Page no. 1-2).

iii. Importance and benefits of the

project.

Importance of the project is

described in Chapter-1, Section 1.4

(Page no. 1-2).

Benefits of the project are

described in Chapter-8 of EIA

report.

3. Project Description

i. Cost of project and time of

completion.


Section 2.1 (Paragraph 2; Page no.

2-1).

ii. Products with capacities for the

proposed project.


Section 2.3.2 (Page no. 2-5).

iii. If expansion project, details of

existing products with capacities

and whether adequate land is

available for expansion, reference

of earlier EC if any.

Not applicable

(New project proposal).

iv. List of raw materials required and

their source along with mode of

List of raw materials required and

their source along with mode of



transportation. transportation is given in Table No.

2.5, Page no. 2-28 of Chapter-2.

v. Other chemicals and materials

required with quantities and

storage capacities.

Storage capacity of materials is

mentioned in Chapter 7, Table 7.1

(Page no. 7-3).

vi. Details of Emission, effluents,

hazardous waste generation and

their management.



vii. Requirement of water, power, with

source of supply, status of

approval, water balance diagram,

man-power requirement (regular

and contract).


Section 2.7(b, c, d & e) (Page no.

2-32 to 2-34).

viii. Process description along with

major equipments and

machineries, process flow sheet

(quantities) from raw material to

products to be provided.


Section 2.4 (Page no. 2-6) & 2.5

(Page no. 2-7).

ix. Hazard identification and details of

proposed safety systems.

Hazard identification is described in

Chapter-7, Section 7.2 (Page no. 7-

1); risk screening approach is

covered in Section 7.4 (Page no. 7-

4); details of proposed safety

system are covered in Section 7.16

(Page no. 7-23).

x. Expansion/modernization

proposals:

Not applicable


a. Copy of all the Environmental

Clearance(s) including

Amendments thereto obtained for

the project from MOEF/SEIAA shall

be attached as an Annexure. A

certified copy of the latest

Monitoring Report of the Regional

Office of the Ministry of

Environment and Forests as per

circular dated 30th May, 2012 on

the status of compliance of

conditions stipulated in all the

existing environmental clearances

including Amendments shall be

provided. In addition, status of

compliance of Consent to Operate

for the ongoing / existing operation

of the project from SPCB shall be

attached with the EIA-EMP report.

Not applicable




b. In case the existing project has not

obtained environmental clearance,

reasons for not taking EC under the

provisions of the EIA Notification

1994 and/or EIA Notification 2006

shall be provided. Copies of

Consent to Establish/No Objection

Certificate and (Consent to Operate

(in case of units operating prior to

EIA Notification '2006, CTE and

CTO of FY 2005-2006) obtained

from the SPCB shall be submitted.

Further, compliance report to the

conditions of consents from the

SPCB shall be submitted.

Not applicable


4. Site Details:

i. Location of the project site

covering village, Taluka/Tehsil,

District and State, Justification for

selecting the site, whether other

sites were considered.

Location of the project site covering

village, Taluka/Tehsil, District and

State is provided in Chapter 1,

Table 1.1 (Page no. 1-3); also

shown in Figure 2.1 to 2.3 (Page

no. 2-2).

Justification for selecting the site is

covered in Chapter 5, Section 5.2

(Page no. 5-1).

ii. A toposheet of the study area of

radius of 10km and site location on

1:50,000/1:25,000 scale on an

A3/A2 sheet. (Including all eco-

sensitive areas and

environmentally sensitive places).

Included in Chapter 3, Figure 3.12

(Page no. 3-59).

iii. Details w.r.t. option analysis for

selection of site.

Justification for site selection is

covered Chapter 5, Section 5.2

(Page no. 5-1).

iv. Co-ordinates (lat-long) of all four

corners of the site.

Included in Chapter 2, Table 2.1

(Page no. 2-3).

v. Google map-Earth downloaded of

the project site.

Included in Chapter 2, as Figure

2.2 and Figure 2.3 (Page no. 2-3).

vi. Layout maps indicating existing

unit as well as proposed unit

indicating storage area, plant area,

greenbelt area, utilities etc. If

located within an Industrial area/

Estate/Complex, layout of

Industrial Area indicating location

of unit within the Industrial area/

Estate.

Included in Chapter 2, Figure 2.4

(Page no. 2-5).



vii. Photographs of the proposed and

existing (if applicable) plant site. If

existing, show photographs of

plantation/greenbelt, in particular.

Attached as Annexure-II.

viii. Land use break-up of total land of

the project site (identified and

acquired), government/private -

agricultural, forest, wasteland,

water bodies, settlements, etc.

shall be included. (Not required for

industrial area).

Land use breakup is included in

Chapter 2, Table no. 2.2 (Page no.

2-4).

ix. A list of major industries with name

and type within study area (10 km

radius) shall be Incorporated. Land

use details of the study area.

A list of major industries with name

and type within study area is

provided in Chapter 1, Section 1.11

(Page no. 1-19).

Land use details of the study area

are included in Chapter 3, Section

3.6 (Page no. 3-3).

x. Geological features and Geo-

hydrological status of the study

area shall be included.

Geological features and Geo-

hydrological status of the study

area is included in Chapter 3,


xi. Details of Drainage of the project

up to 5 km radius of study area. If

the site is within 1 km radius of

any major river, peak and lean

season river discharge as well as

flood. Occurrence frequency based

on peak rainfall data of the past 30

years. Details of Flood Level of the

project site and maximum Flood

Level of the river shall also be

provided. (mega green field

projects)

Site is not within 1 km of any

major river.

xii. Status of acquisition of land. If

acquisition is not complete, stage

of the acquisition process and

expected time of complete

possession of the land.

Attached as Annexure-III.

xiii. R&R details in respect of land in

line with state Government policy.

No, R & R is involved.

5. Forest and wildlife related issues (if applicable):

i. Permission and approval for the

use of forest land (forestry

clearance), if any, and

recommendations of the State

Not applicable.

(Project does not involve forest

land; and

Site is not located within 10 km of



Forest Department. (if applicable) the National Parks, Sanctuaries,

Biosphere reserves, Migratory

Corridors of Wild Animals)

ii. Land use map based on High

resolution satellite imagery (GPS)

of the proposed site delineating the

forestland (in case of projects

involving forest land more than 40

ha).

iii. Status of Application submitted for

obtaining the stage I forestry

clearance along with latest status

shall be submitted.

iv. The projects to be located within

10 km of the National Parks,

Sanctuaries, Biosphere Reserves,

Migratory Corridors of Wild

Animals, the project proponent

shall submit the map duly

authenticated by Chief Wildlife

Warden showing these features

vis-à-vis the project location and

the recommendations or comments

of the Chief Wildlife Warden-

thereon.

v. Wildlife Conservation Plan duly

authenticated by the Chief Wildlife

Warden of the State Government

for conservation of Schedule I

fauna, if any exists in the study

area.

Wildlife Conservation Plan

submitted for Schedule I species

Pavo Cristatus is included in

Annexure-XI (Page no. A-215).

vi. Copy of application submitted for

clearance under the Wildlife

(Protection) Act, 1972, to the

Standing Committee of the

National Board for Wildlife.

6. Environmental Status

i. Determination of atmospheric

inversion level at the project site

and site-specific micro-

meteorological data using

temperature, relative humidity,

hourly wind speed and direction

and rainfall.

Briefly covered in Chapter 3,


Hourly meteorological data

including temperature, relative

humidity, hourly wind speed and

direction and rainfall is attached as

Annexure-IX.

ii. AAQ data (except monsoon) at 8

locations for PM10, PM2.5, SO2, NOX,

CO and other parameters relevant

to the project shall be collected.


Section 3.8 (Page no. 3-7) and

monitoring locations, period of

monitoring & address are given in



The monitoring stations shall be

based CPCB guidelines and take

into account the pre-dominant wind

direction, population zone and

sensitive receptors including

reserved forests.

Chapter-3, Table 3.11 (page no. 3-

26).

iii. Raw data of all AAQ measurement

for 12 weeks of all stations as per

frequency given in the NAQQM

Notification of Nov. 2009 along

with -min., max., average and

98% values for each of the AAQ

parameters from data of all AAQ

stations should be provided as an

annexure to the EIA Report.

Briefly covered in Chapter 3, Table

3.11 to 3.17 (Page no. 3-26).

Detailed AAQM table is attached as

Annexure-X.

iv. Surface water quality of nearby

River (100m upstream and

downstream of discharge point)

and other surface drains at eight

locations as per CPCB/ MoEF&CC

guidelines.

Unit will not discharge in surface

water.

Results of surface water monitoring

at eight locations are covered in

Chapter 3, Table 3.20 (Page no. 3-

35).

v. Whether the site falls near to

polluted stretch of river identified

by the CPCB/ MoEF&CC, if yes give

details.

No, the site doesn‟t falls near to

polluted stretch of the river

identified by CPCB/MoEF&CC.

vi. Ground water monitoring at

minimum at 8 locations shall be

included.


3.19 (Page no. 3-34).

vii. Noise levels monitoring at 8

locations within the study area.


3.22 (Page no. 3-37).

viii. Soil Characteristic as per CPCB

guidelines.


3.24 (Page no. 3-38).

ix. Traffic study of the area, type of

vehicles, frequency of vehicles for

transportation of materials,

additional traffic due to proposed

project, parking arrangement etc.


3.27 (Page no. 3-42).

x. Detailed description of flora and

fauna (terrestrial and aquatic)

existing in the study area shall be

given with special reference to

rare, endemic and endangered

species. If Schedule-I fauna are

found within the study area, a

Wildlife Conservation Plan shall be

prepared and furnished.


3.25 (Page no. 3-39) & 3.26 (Page

no. 3-41). No endangered floral or

faunal species has been recorded

within the study area.

Wildlife Conservation Plan

submitted for Schedule I species

Pavo Cristatus is included in

Annexure-XI (Page no. A-215).



xi. Socio-economic status of the study

area.


Section 3.14 (Page no. 3-29); and

Table 3.29 (Page no. 3-45) & 3.30

(Page no. 3-47).

7. Impact and Environment Management Plan

i. Assessment of ground level

concentration of pollutants from

the stack emission based on site-

specific meteorological features. In

case the project is located on a

hilly terrain, the AQIP Modeling

shall be done using inputs of the

specific terrain characteristics for

determining the potential impacts

of the project on the AAQ.

Cumulative impact of all sources of

emissions (including

transportation) on the AAQ of the

area shall be assessed. Details of

the model used and the input data

used for modeling shall also be

provided. The air quality contours

shall be plotted on a location map

showing the location of project site,

habitation nearby, sensitive

receptors, if any.

Assessment of ground level

concentration of pollutant from the

stack emission superimposed on

geographical area map based on

the site specific meteorological

features is covered in Chapter 4,

Figure 4.1 to 4.4 (Page no. 4-23).

The modeling approach is briefly

covered in Chapter 4, Section 4.4.1

(Page no. 4-4).

Input parameters used for

modeling are provided in Table 4.1

(Page no. 4-17), additional inputs -

maximum 50 (24-hr) average

concentration values for SPM, SO2,

NOx & HCl, are given in Table 4.3

to 4.6 (Page no. 4-19).

Cumulative impact of all sources of

emissions on AAQ of the area is

given in Table 4.2 (Page no. 4-18).

ii. Water Quality modeling -in case of

discharge in water body.

Not applicable, as unit will not

discharge in water body.

iii. Impact of the transport of the raw

materials and end products on the

surrounding environment shall be

assessed and provided. In this

regard, options for transport of raw

materials and finished products and

wastes (large quantities) by rail or

rail-cum road transport or

conveyor-cum-rail transport shall

be examined.

Traffic study is provided in Chapter

3, Table 3.27 (Page no. 3-42). The

impact of the transport of raw

material and the end products on

the surrounding environment will

be insignificant, so rail or rail-cum

road transport of conveyor-cum-

rail transport is not required at this

point.

iv. A note on treatment of wastewater

from different plant operations,

extent recycled and reused for

different purposes shall be

included. Complete scheme of

effluent treatment. Characteristics

of untreated and treated effluent to

meet the prescribed standards of

discharge under E(P) Rules.

Treatment on wastewater from

different plant operations, extent

recycled and reuse for different

purposes is briefly described in

Chapter 2, Section 2.9.1 (Page no.

2-37).

Characteristic of untreated and

treated effluent is given in Table

2.14 (Page no. 2-40).



v. Details of stack emission and

action plan for control of emissions

to meet standards.

Details of stack emission and action

plan for control of emissions to

meet standards are covered in

Chapter 2, Section 2.8.2 (Page no.

2-34) & 2.9.2 (Page no. 2-40).

vi. Measures for fugitive emission

control.

Measures for fugitive emission

control are covered in Chapter 2,


vii. Details of hazardous waste

generation and their storage,

utilization and management.

Copies of MOU regarding utilization

of solid and hazardous waste in

cement plant shall also be

included. EMP shall include the

concept of waste-minimization,

recycle/reuse/recover techniques,

Energy conservation, and natural

resource conservation.

Details of hazardous waste

generation and their storage,

utilization and management are

covered in Chapter 2, Section 2.8.3

(Page no. 2-36) & 2.9.3 (Page no.

2-41).

Proponent will explore the

possibility of utilization of solid and

hazardous waste in cement plant.

Concepts of resource & energy

conservation and cleaner

production are covered in Chapter

10, Section 10.7 & 10.8 (Page no.

10-17).

viii. Proper utilization of fly ash shall be

ensured as per Fly Ash Notification,

2009. A detailed plan of action

shall be provided.

A detailed plan of fly ash

management is covered in Chapter

2, Section 2.9.3 (Page no. 2-41).

ix. Action plan for the green belt

development plan in 33 % area i.e.

land with not less than 1500 trees

per ha. Giving details of species,

width of plantation; planning

schedule etc. shall be included. The

green belt shall be around the

project boundary and a scheme for

greening of the roads used for the

project shall also be incorporated.

Layout plan earmarking space for

development of green belt is

provided in Chapter 2, Figure 2.4

(Page no. 2-5). Greenbelt

development plan is provided in

Chapter 10, Section 10.3.5 (Page

no. 10-8).

x. Action plan for rainwater

harvesting measures at plant site

shall be submitted to harvest

rainwater from the roof tops and

storm water drains to recharge the

ground water and also to use for

the various activities at the project

site to conserve fresh water and

reduce the water requirement from

other sources.

Action plan for rainwater harvesting

is provided in Chapter 2, Section

2.10 (Page no. 2-42).



xi. Total capital cost and recurring

cost/annum for environmental pollution control measures shall be

included.

Total capital cost and recurring

cost/annum for environmental

pollution control measures is

included in Chapter 10, Section

10.5 (Page no. 10-15).

xii. Action plan for post-project

environmental monitoring shall be

submitted.

Action plan for post-project

environmental monitoring is

included in Chapter 10, Section

10.4 (Page no. 10-13).

xiii. Onsite and Offsite Disaster (natural

and Man-made) Preparedness and

Emergency Management Plan

including Risk Assessment and

damage control. Disaster

management plan should be linked

with District Disaster Management

Plan.

Onsite and offsite Disaster (natural

and man-made) Preparedness and

Emergency Management Plan is

included in Chapter 7, Section 7.18

(Page no. 7-29) & Section 7.23

(Page no. 7-39).

8. Occupational health:

i. Plan and fund allocation to ensure

the occupational health & safety of

all contract and casual workers.

Occupational health & safety plan is

given in Chapter 10, Section 10.3.6

(Page no. 10-10); and Chapter 7,


Fund allocation is mentioned in

Chapter 10, Section 10.5 (Page no.

10-14).

ii. Details of exposure specific health

status evaluation of worker. If the

workers‟ health is being evaluated

by pre designed format, chest x

rays, Audiometry, Spirometry,

Vision testing (Far & Near vision,

color vision and any other ocular

defect) ECG, during pre-placement

and periodical examinations give

the details of the same. Details

regarding last month analyzed data

of above mentioned parameters as

per age, sex, duration of exposure

and department wise.

Occupational health & safety

programme is covered in Chapter

7, Section 7.14 (Page no. 7-19);

and Chapter 10, Section 10.3.6

(Page no. 10-10).

iii. Details of existing Occupational &

Safety Hazards. What are the

exposure levels of hazards and

whether they are within Permissible

Exposure Level (PEL)? If these are

not within PEL, what measures the

company has adopted to keep

them within PEL so that health of

No existing Occupational & Safety

Hazards (as this is a new project

proposal).

Hazard analysis of materials is

provided in Chapter 7, Table 7.2

(Page no. 7-5) & Table 7.3 (Page

no. 7-7). Acute Exposure Guideline

Levels (AEGLS) provided in Section



the workers can be preserved. 7.4.1 (Page no. 7-7); Emergency

Response Planning Guidelines

(ERPGs) provided in Section 7.4.2

(Page no. 7-9); Immediately

dangerous to life or health air

concentration values (IDLH values)

provided in Section 7.8 (Page no.

7-12).

iv. Annual report of health status of

workers with special reference to

Occupational Health and Safety.

Not applicable


9. Corporate Environment Policy

i. Does the company have a well laid

down Environment Policy approved

by its Board of Directors? If so, it

may be detailed in the EIA report.

Yes, It is discussed in Chapter 10,


Additionally, company will set up a

separate Environment Management

Cell and the objectives and duties

of it are discussed in Chapter 10,


ii. Does the Environment Policy

prescribe for standard operating

process / procedures to bring into

focus any infringement / deviation

/ violation of the environmental or

forest norms / conditions? If so, it

may be detailed in the EIA.



iii. What is the hierarchical system or

Administrative order of the

company to deal with the

environmental issues and for

ensuring compliance with the

environmental clearance

conditions? Details of this system

may be given.

It is discussed in Chapter 10,


iv. Does the company have system of

reporting of non-compliances /

violations of environmental norms

to the Board of Directors of the

company and / or shareholders or

stakeholders at large? This

reporting mechanism shall be

detailed in the EIA report.



10. Details regarding infrastructure

facilities such as sanitation, fuel,

restroom etc. to be provided to the

labor force during construction as

well as to the casual workers

It is discussed in Chapter 10,

Section 10.2.2 (Page no. 10-2) and

10.2.4 (Page no. 10-2).



including truck drivers during

operation phase.

11. Enterprise Social Commitment (ESC)

i. Adequate funds (at least 2.5 % of

the project cost) shall be

earmarked towards the Enterprise

Social Commitment based on Public

Hearing issues and item-wise

details along with time bound

action plan shall be included.

Socio-economic development

activities need to be elaborated

upon.

ESR plan for 3 years @ 5.0% of the

project cost is included in Chapter

10, Section 10.9 (Page no. 10-19).

Elaborated Socio-economic

development activities & year wise

break up of budget is discussed in

Chapter 7, Section (E) (Page no. 7-

45) & Table 7.12, Page no. 7-50.

12. Any litigation pending against the

project and/or any direction/order

passed by any Court of Law against

the project, if so, details thereof

shall also be included. Has the unit

received any notice under the

Section 5 of Environment

(Protection) Act, 1986 or relevant

Sections of Air and Water Acts? If

so, details thereof and compliance/

ATR to the notice(s) and present

status of the case.

No pending litigation against the

project and/or any direction/order

passed by any Court of Law against

the project.

13. A tabular chart with index for point

wise compliance of above TORs.

Done.

B SPECIFIC TERMS OF REFERENCE

1 Details on solvent to be used,

measures for solvent recovery and

for emission control.

Covered in Chapter 10, Section

10.3.1.2 (Page no. 10-6).

2 Details of process emission from

the unit and its arrangement to

control.

It is briefly described in Chapter 2,

Section 2.8.2 (Page no. 2-34) &

2.9.2 (Page no. 2-40).

3 Ambient air quality data should

include VOC, other-process-specific

pollutants* like NH3*, chlorine*,

HCl*, HBr*, H2S*, HF*, etc. (*-as

applicable).

Ambient air quality data includes

VOC, and process-specific

pollutants HCl; Included in Table

3.17 (Page no. 3-32).

4 Work zone monitoring

arrangements for hazardous

chemicals.

It is described in Chapter 10,


5 Detailed effluent treatment scheme

including segregation of effluent

streams for units adopting „Zero‟

Liquid Discharge.

It is described in Chapter 2, Section

2.9.1 (Page no. 2-37).



6 Action plan for odour control to be

submitted.

It is described in Chapter 10,

Section 10.3.1.3 (Page no. 10-6).

7 A copy of the Memorandum of

Understanding signed with cement

manufactures indicating clearly

that they co-process organic

solid/Hazardous waste in TSDF if

any.

Unit will consider obtaining such

Memorandum of Understanding

signed with cement manufacturers.

8 Authorization/Membership for the

disposal of liquid effluent in CETP

and solid/hazardous waste in TSDF,

if any.

Unit will perform ZLD with in-house

ETP, RO, MEE setup; hence

membership of CETP is not

required.

Unit will obtain membership of

TSDF before establishment.

9 Action plan for utilization of

MEE/dryers salts.

Being a Pharma unit, no possibility

to utilize utilization of MEE/dryers

salts. Unit will send MEE salts to

TSDF.

It is covered in Chapter 2, Section

2.9.3 (Page no. 2-41).

10 Material Safety Data Sheet for all

the Chemicals are being used/will

be used.

Attached as Annexure-IV.

11 Authorization/Membership for the

disposal of solid/hazardous waste

in TSDF.

Unit will obtain membership of TSDF before establishment.

12 Details of incinerator if to be

installed.

Not applicable

13 Risk assessment for storage and

handling of hazardous chemicals/

solvents. Action plan for handling &

safety system to be incorporated.

Risk assessment for storage and

handling of hazardous chemicals is

covered in Chapter 7, Section 7.3

(Page no. 7-3), Section 7.4 (Page

no. 7-4). Hazard analysis of

materials is provided in Table 7.2

(Page no. 7-5) & Table 7.3 (Page

no. 7-7). Acute Exposure Guideline

Levels (AEGLS) provided in Section

7.4.1 (Page no. 7-7); Emergency

Response Planning Guidelines

(ERPGs) provided in Section 7.4.2

(Page no. 7-9); Immediately

dangerous to life or health air

concentration values (IDLH values)

provided in Section 7.8 (Page no.

7-12).

Quantitative risk assessment &

consequence analysis is covered in



Section 7.12 (Page no. 7-15) and


Action plan for handling & safety

system is covered in Section 7.16-

7.17 (Page no. 7-23).

14 Arrangements for ensuring health

and safety of workers engaged in

handling of toxic materials.

It is briefly covered in Section 7.17

(Page no. 7-25).

1.9 OBJECTIVE OF EIA

The objectives of the present EIA study are to identify potential source of

pollution, assess the impacts on various environmental components due

to the proposed project activity, and recommend appropriate

environmental management system and environment management plan

for the unit to ensure that the adverse impacts, if any, will be minimized.

1.10 METHODOLOGY FOR EIA

Considering the nature and magnitude of the project, surrounding area

and various guidelines available, an area of 10-km radius from the center

of proposed plant site was considered for the purpose of environmental

impact assessment study. The methodology is briefly reported below,

Baseline data collection:

The baseline data for the impact zone have been generated for the

following environmental parameters.

Ambient Air Quality

Micrometeorology

Noise Level

Surface &Ground Water Quality

Soil Quality

Ecology &Biodiversity

Land use pattern

Socio-Economics

The baseline status of the above environmental parameters has been

worked out based on the rapid monitoring/analysis carried out during the

study period of October, 2018 to December, 2018 supplemented by

data collected from various Govt. Dept., census publications etc. The data

is collected and analyzed as per the standard methods for establishing



the baseline data and so determine the impact of proposed activity on the

same.

Evaluation of Impact from Project Activities

The Environmental Impact resulting from the various project activities,

have been identified, predicted and evaluated based on the study of

manufacturing process and other project related activities as well as

correlating the same with existing baseline status.

Preparation of Environmental Management Plan

Environmental Management Plan has been prepared covering pollution

prevention measures at source in terms of air and water pollution control

measures, solid waste/hazardous waste management, safety

management, greenbelt development, environmental surveillance and

environmental surveillance and environmental management team.

Finally, the detailed assessment of the resultant environmental impacts

have been made based on the impacts identification and evaluated from

the activities over the baseline status of various environmental

components to reduce the pollution and to delineate a comprehensive

environment management plan along with recommendations and

suggestions to improve environment management system.

1.11 LIST OF INDUSTRIES SURROUNDING PROJECT SITE

List of industries in the study area are shown below.

Sr.

No.

Name of Industry Address Type of Industry

1 Ipca Laboratories At Village: Ranu, Tal. Padra,

Dist: Vadodara

Pharmaceutical

Company

2 Admark Poly Coat

Pvt. Ltd.

Survey No. 207, Vill: Luna,

Taluka: Padra, Dist Vadodara

Resin Manufacturer

3 Ami Life Sciences

Pvt. Ltd.

Block No 82/B , VECL Road,

At & Po - Karakhadi, Padra

Pharmaceutical

Company

4 Amoli Organics Ltd. Block No. 422 to 425, VECL

Road, Vill: Luna

Pharmaceutical

Company

5 Apicore Parma Pvt.

Ltd.

Block No. 252/253,

Vill: Dhobikuwa, Tal: Padra

Pharmaceutical

Company

6 BDR Life Sciences

Pvt. Ltd.

R.S. No. 578, Near VECL

Road, Vill: Luna, Tal: Padra

Pharmaceutical

Company

7 Cadila Healthcare

Ltd.

Plot No. 31, Vill: Dabhasa,

Tal. Padra

Pharmaceutical

Company

8 Gulbrandsen Coastal Highway, Vill.: Fine Chemicals



Chemical Pvt. Ltd. Mujpur, Tal: Padra

9 Kaival Chemicals

Pvt. Ltd.

Block No. 489, Umraya Road,

Vill: Umraya, Tal. Padra

Pharmaceutical

Intermediates

10 Kronox Lab

Sciences Pvt. Ltd.

Block No 284 Vill: Dabhasa,

Tal. Padra

Fine chemicals

11 Kumar Organics

Ltd.

Plot No. 379, Canal Road,

Vill: Luna, Taluka: Padra

Fine chemicals

12 Lupin Limited Block No. 2100, Vill.

Dabhasa, Tal. Padra

Pharmaceutical

Company

13 Paragon Organics Plot No. 582, VECL Road,

Luna, Padra

Pharmaceutical

Company

14 Philoden Agrochem

Pvt. Ltd.

Block No. 73, B/H, Geb Sub

Station, Karkhadi, Tal. Padra

Dyestuff

15 Piramal Glass Ltd Gajera Road, Uchhad Village,

Jambusar, Dist, Bharuch

Glass manufactures

16 Cadila Healthcare

Ltd.

Block No 162, Vill. Dabhasa,

Tal, Padra

Pharmaceutical

Company

17 Shimmer Chemicals

Pvt. Ltd.

Block No. 338, Coastal

Highway, Vill: Mujpur, Tal.

Padra

Fine Chemicals

18 Shiva Pharmachem

Ltd.

Block No. 528, Vill, Luna, Tal.

Padra

Fine Chemicals

19 Solaris Chemtech

Industries

Karakhadi, Taluka: Padra Fine Chemicals

20 Sun

Pharmaceuticals

Indu Ltd.

Plot No. 817 A, VECL Road,

Vill. Karakhdi, Tal, Padra

Pharmaceutical

Company

21 Synbiotics Ltd. Block No. 570,571, & 576/A,

Vill, Luna, Taluka: Padra

Pharmaceutical

Company

22 Transpek Silox

Industry Ltd.

Survey No. 325/1, Ekalbara,

Tal. Padra

Fine Chemicals

23 Exemed

Pharmaceuticals

Block No. 628 VECL Canal

Road, Vill: Luna, Tal: Padra

Pharmaceutical

Company

24 Parad Chem

Corporation

Plot No. 145, Dabhasa,

Dabhasa- Ekalbara Road, Tal. Padra, Dist Vadodara

Fine Chemicals

25 Zydex Industries

Pvt. Ltd.

Village Gavasad, Tal Padra,

Dist Vadodara

Fine Chemicals

26 Prasad International Pvt.

Ltd.

Plot No. 313/P, Village: Luna

Taluka: Padra, Dist Vadodara

Dyestuff & Pigments

27 Alembic Pharmaceuticals Ltd.

Survey No. 843, Karakhadi

Village, Padra Taluka

Pharmaceutical

Company

28 Sterling Biotech

Ltd.

Village: Masar, Taluka:

Padra, Dist: Vadodara

Pharmaceutical

Company



29 Colorband Dyestuff

Pvt. Ltd.

Village: Ekalbara, Taluka:

Padra, Dist: Vadodara

Dyestuff

1.12 STRUCTURE OF REPORT

The overall contents of the EIA report is in line with generic structure of

EIA report as per the Appendix III of the EIA Notification, 2006. The

report consists of twelve chapters and the content is briefly described in

this section.

Chapter 1: Introduction

The chapter gives brief outline of the project and its proponent, brief

description nature, size and location of the project, purpose of the EIA

study including the scope of the study, TORs compliance etc. and work

to be covered under each Environmental component.

Chapter 2: Project Description

This chapter includes project details and Infrastructure facilities

including all industrial & environmental aspects of the unit as well as

manufacturing process details. It also gives information about utilities,

raw material, water & wastewater quantitative details, stack details,

hazardous waste generation, storage & disposal facility.

Chapter 3: Description of the Environment

This chapter covers data of existing condition of Valued Environmental

Components like air, water, noise, soil, biological environment and

socio-economic aspects, basic amenities land use pattern. It also gives

details of study area, period of study, component of environment & its

methodology. Various sections of the chapter discuss the existing land

use and drainage pattern, climate and meteorological parameters.

Both primary and secondary data collected for the study are depicted

in this chapter.

Chapter 4: Anticipated Environmental Impacts and Mitigation

Measures

This chapter describes the overall impacts of the project activities on

various environmental components. It predicts the overall impact of

the project activities on different components of the environment viz.

Air, Water, Land, Noise, Biological and Socio-Economic and its

mitigation measures.



Chapter 5: Analysis of Alternatives

This chapter gives details of analysis of alternatives in terms of

technology & site.

Chapter 6: Environmental Monitoring Programme

This chapter describes technical aspects of monitoring (including

measurement methodologies, frequency, location and data analysis,

reporting schedules, emergency procedures, detailed budget and

procurement schedules.

Chapter 7: Additional Studies

This chapter describes Risk assessment and on-site, off-site

emergency plan and occupational health & safety programme.

Chapter 8: Project Benefits

This chapter focuses on benefits of project on improvement in physical

infrastructure, social infrastructure & other tangible benefits.

Chapter 9: Environmental Cost Benefit Analysis

Chapter 10: Environmental Management Plan

This chapter describes Environment Management Plan (EMP) to be

adopted for mitigation of anticipated adverse impacts if any and to

ensure acceptable impacts.

Chapter 11: Summary & Conclusion

It gives brief of the EIA Report and chapters there in. It also describes

about overall justification for implementation of the project and

explanation on various mitigation measures.

Chapter 12: Disclosure of Consultants engaged

This chapter describes the name of the consultant engaged with their

brief nature of consultancy activities.



Chapter 2

Project Description

2.1 INTRODUCTION

M/s. Reynish Pharmachem Pvt. Ltd. is a green field project, proposes

to set up bulk drugs manufacturing unit at Survey no. 504, 505, 507,

Village: Dabhasa, Ta.: Padra, District: Vadodara, Gujarat. Total

production capacity of all the products will be tune around 50 MT/month.

The estimated cost for the proposed project is estimated around Rs. 40.0

Crores. Out of this around Rs. 2.5 Crores will be invested for pollution

control measures as capital cost and Rs. 1.5 Crores as recurring cost per

annum. Time of project completion will be about 1.0 - 1.5 years after

accordance of the EC.

As per the EIA Notification - 2006, Industry falls under the Project or

Activity - 5(f) - Synthetic organic chemicals industry (dyes & dye

intermediates; bulk drugs and intermediates excluding drug formulations;

synthetic rubbers; basic organic chemicals, other synthetic organic

chemicals and chemical intermediates).

Based on the type of project, following are the expected aspects:

Air Emissions,

Waste water generation,

Noise generation,

Hazardous waste generation, and

Occupational health, hazards & safety risk

2.2 LOCATION OF THE PROJECT

The project site is located at Survey no. 504, 505, 507, Village: Dabhasa,

Ta: Padra, District: Vadodara, Gujarat. Locations of the project, Google

map and boundary coordinates of the site are shown in Figure 2.1,

Figure 2.2, and Figure 2.3, respectively. The project site is

approachable by Road via Vadodara-Jambusar Hwy. Nearest railway

station and airport is Vadodara Railway Station at about 19 km, Padra

Railway station at about 7.0 km and Vadodara Airport at about 24 km,

respectively.



Figure 2.1 Location of the project site



Figure 2.2 Location on Google map

Figure 2.3 Image showing all boundary coordinates of the site

Table 2.1 Boundary coordinates of the site

A 22° 13'34.14"N 73°01'09.11"E

B 22° 13'37.03"N 73°01'14.93"E

C 22° 13'29.17"N 73°01'09.37"E

D 22° 13'31.79"N 73°01'18.09"E



2.3 SIZE OR MAGNITUDE OF OPERATION

2.3.1 Land Breakup & Project Site Layout

Proposed land area is 36958 m2. Greenbelt will be developed in around

12175 m2 area which is more than 33% of the total project area. The

detailed proposed land break up is given below in Table 2.2, whereas the

site layout map is given in the Figure 2.4.

Table 2.2 Land breakup

Sr. No.

Particular Area (m2)

1. Admin Building & Lab 525

2. Water storage area 800

3. Raw Water treatment area 100

4. Tank farm/solvent storage area 680

5. Raw Materials & Finished goods storage area 1200

6. Manufacturing area 5930

7. Manufacturing plant-2 1200

8. Boiler Shed and utilities area 665

9. ETP, MEE and RO Area 650

10. Parking 900

11. Electrical and Security cabin 310

12. Staff Canteen 225

13. Greenbelt 12175

14. Internal Roads & Margin 4615

15. Open Space for future expansion 6983

Total 36958



Figure 2.4 Plant Layout

2.3.2 Project Magnitude

Proposed production capacity is given below:

Table 2.3 List of products with its capacity

Sr.

No.

Name of Products Qty.

MTPM

1. Telmisartan 48

2. Ondansetron HCl

3. Benfotiamine

4. Albendazole


6. Zopiclone


8. Bupropion HCl

9. Anstrozole

10. Theophylline



11. Allantoin



14. Rebamipide

15. Valsartan

16. R & D Drugs 2.0

Total 50.0

2.4 INFRASTRUCTURE FACILITIES

The list of proposed plant equipments/machineries is given below in

Table 2.4.

Table 2.4 List of major machineries/equipment

Sr.

No.

Name of the

Equipment/Machinery

Capacity Nos.

1. SSR (Reactor) 2000 Lit. 4

3000 Lit. 2

4000 Lit. 4

2. GLR (Reactor) 2000 Lit. 4

3000 Lit. 2

4000 Lit. 4

3. CF (Centrifuge) 36” 5

48” 5

4. SF (Sparkler Filter) 18” 3

24” 3

5. Spin Flash Dryer (SFD)/

Fluid Based Dryer (FBD)

1000 Lit. 3

6. Nauta Dryer 1000 Lit. 3

7. Rotary Vacuum Dryer (RVD) 500 Lit. 2

8. Blender 3500 Lit. 1

9. Hydrogenator (SS 316) 2000 Lit. 1

10. Hydrogenator (SS 316) 4000 Lit. 1

11. DG Set 500 kVA 1

12. Steam Boiler 3.0 TPH 1

13. Thermic Fluid Heater 20 lac Kcal/hr. 1

14. Hot Air Generator 30 lac Kcal/hr. 1

15. RO (Raw Water Treatment) 5.0 Kl/hr. 2

16. RO (Effluent Treatment Plant) 7.5 Kl/hr. 2

17. Cooling tower 250 TR 1

500 TR 1

18. Multiple Effect Evaporator 2500 Lit/hr. 1



2.5 DESCRIPTION OF MANUFACTURING PROCESS

The company will use the Best Available Process Technology (BAT) for the

production. Manufacturing process of all products, with chemical reactions

& mass balance are summarized below.

1. Telmisartan

Manufacturing Process:

2‐n‐Propyl‐4‐methyl‐6‐(1‐methyl benzimidazole‐2‐yl) benzimidazole is

treated with methyl‐4’‐(bromomethyl)‐biphenyl‐2‐carboxylate in acetone

in the presence of sodium hydroxide to form 4‐[4’‐methyl‐6‐

(1‐methyl‐1H‐benzimidazole‐2‐yl‐2‐propyl‐1H‐benzimidazole‐1‐ylmethyl]

biphenyl‐2‐carboxylic acid methyl ester which is hydrolyzed with sodium

hydroxide in aqueous methanol to give telmisartan which is purified in

dichloromethane and methanol.

Chemical Reaction:



Mass Balance:

INPUT KG OUTPUT KG

2‐n‐Propyl‐4‐methyl

‐6‐(1‐methyl

benzimidazole‐2‐yl)

benzimidazole

68

methyl‐4’‐

(bromomethyl)‐biphenyl‐2

‐carboxylate

58

Acetone 500 Acetone recovery 490

Water 1600 Wastewater 950

Sodium hydroxide 15 Distillation residue 10

Methanol 750 Methanol recovery 650

Sodium hydroxide 25


HCl 70

Methanol 450 Methanol recovery 560

Dichloromethane 500 Dichloromethane recovery 490

Distillation residue 34

Charcoal 1.5 Spent carbon 1.5

Hyflo 1 Wastewater 903

Drying loss 25

TELMISARTAN 100

Total 4564 4564

Drying

MASS BALANCE OF TELMISARTAN

Reactor

Reactor

Filteration



2. Ondansetron HCl:


1, 3 CHD reacts with phenyl hydrazine in presence of catalyst and water.

Acetic acid is added along with zinc chloride and methanol. And then add

concentrated HCl and stir it for 1 hour to maintain the temperature

between 20-25oC. Then mass is methylized with the help of Di-methyl

sulphate and acetone. Acetone is recovered at the end. Then add DMA

HCl with paraformaldehyde to complete the alkylation. Add 2 methyl-

Imidazole to condensate the mass. Then add concentrated HCl in vessel

under stirring. Salt of Ondensetron Dihydrate HCl is generated. Product

and wastewater are separated through centrifugation and wastewater is

sent to the ETP.

Mass Balance:

INPUT KG OUTPUT KG

1,3-CHD 120

Phenyl hydrazine 181

Water 2120

Acetic acid 72 Methanol Recovery 465

Zinc chloride 252 Solvent residue 12

Methanol 477 Wastewater 2000

Con HCl 53

Dimethyl sulphate 70 Acetone Recovery 420

Acetone 435 Solvent residue 15

Potassium Carbonate 40 Wastewater 165

Acetic acid 450

DMA HCl 72

Paraformaldehyde 27

Water 318

2-Methyl Imidazole 95 Wastewater 1200

Water 530

Con HCl 40


Drying loss 21

Ondansetron Dihydrate HCl 100

Total 5882 5882

Centrifuge

Drying

HCl salt formation

MASS BALANCE OF ONDANSETRON HCl

Condensation

reaction

cyclization

Methylation

Reductive

alkylation

Condensation



3. Benfotiamine:

Manufacturing process:

In a clean and dry Reactor, take Thiamine Monophosphate Chloride (TMP)

at room temperature. Add water and stir well at room temperature. Cool

the reaction mass to 10‐15 oC. Add to reaction mass the first lot of 47%

NaOH solution. Then add to reaction mass the Benzoyl Chloride 20‐25 oC

in 30 min. Then Stir the reaction mass a 1h. After completion of reaction,

add to reaction mixture Conc. HCl. Here pH of reaction mixture should be

4.0 ‐ 4.5. Stir reaction mixture at room temperature for 2 h. Cooled and

chilled the product to 10‐15 oC and stirred at same temperature for 30

min. Centrifuged the product. Dry the weight cake. The Dried white solid

product is obtained.

Chemical Reaction:

Mass Balance:

INPUT KG OUTPUT KG

TMP 122

Caustic 27 Methanol recovery 385

Benzoyl chloride 60 Solvent residue 15

HCl 80

Water 200

Methanol 400

Wastewater 362

Drying loss 27

BENFOTIAMINE 100

Total 889 889

MASS BALANCE OF BENFOTIAMINE

Condensation

reaction

Centrifuge

Drying



4. Albendazole:


Charge 3 Chloro 6 nitro acetanilide and add NaOH lye in the reactor. Add

Methanol in the vessel then it is distilled in the chamber. In the residue

add hexane along with Di-isopropyl ether. Then heat up to 50-55oC. Then

the mass is dried. The solid mass is obtained. Then add NaOH in solution

to complete the hydrogenation. Add acetone, methyl chloroform ate and

water in the reactor. Centrifuged the product. The aqueous layer is sent

into ETP and product is obtained at the end.

Mass Balance:

INPUT KG OUTPUT KG

3-Chloro-6-

nitroacetanilide91 Wastewater 1471

Propylmercaptan 44

NaOH lye 77

Water 1370

Methanol 274 Methanol Recovery 260

Hexane 137 Hexane + Ether Recovery 220

Di-isopropylether 137 Distillation Residue 7

Water 822

NASH solution (30%) 274 Wastewater 1182

Con HCl 137

Sodium Hydroxide 343

Cyanamide 26

Acetone 40

Methyl chloroformate 30


Drying loss 27

Albendazole 100

Total 4076 4076

Centrifuge

Drying

MASS BALANCE OF ALBENDAZOLE

Condensation

reaction

cyclization

Hydrogenation

Reductive

alkylation



5. 4-Hexyl resorcinol:


Add Zinc chloride, Caproic acid, resorcinol and water in the reactor. Mass

is condensed. During layer separation Caproic acid is recovered and

aqueous filtrate goes into ETP. Then methanol is added during

crystallization process. Also nickel catalyst and toluene is added with

water. Maintain the right temperature. Stir for 1 hour. At the end catalyst

is recovered and the mass is Centrifuged and 4-Hexyl resorcinol is

obtained.

Mass Balance:

INPUT KG OUTPUT KG

Zinc chloride 77

Caproic acid 190 Wastewater 1400

Resorcinol 110

Water 1400

Ni-catalyst 8 Catalyst 8


Toluene 605 Toluene Recovery 590

Distillation residue 50


Drying loss 31

4-Hexyl resorcinol 100

Total 4925 4925

MASS BALANCE OF 4-Hexyl Resorcinol

Condensation

reaction

Crystalization

Centrifuge

Drying



6. Zopiclone:


2-Amino-5-chloropyridine and pyrazine-2-carboxylic acid was suspended

in dichloromethane. The suspension was refluxed azeotropically for 60

min. The mixture was cooled to 25-30° C and dimethyl formamide was

added followed by addition of thionyl chloride in 45-60 min at 25-30° C.

The resulting mixture was refluxed till completion of reaction. The

reaction mixture was concentrated to dryness at atmospheric pressure.

Cooled the solid to 25-35° C. and water is added to cooled the slurry to

20-25° C. and stirred for 30 min. Slurry was filtered and washed with

water. The solid was dried at 60-70° C. to obtain the mass. Add aqueous

sodium borohydride solution and water is added in under vigorous

stirring. Reaction mixture was stirred at 0-5° C. for 4 to 5 hrs. After

completion of reaction solid was filtered and washed with water. The

filtered solid was refluxed in dichloromethane for 30 min and cooled to

25-30° C. The solid was filtered and dried at 50-60° C to obtain of title

compound. Mixture of N-methyl piperazine carbomoyl chloride

hydrochloride was cooled to 10-15° C. Calcium oxide and dimethyl amino

pyridine were added to the mixture. Reaction mixture was warmed to 25-

30° C. and stirred till completion of reaction. After completion of reaction,

mixture was filtered and washed with dichloromethane. The

dichloromethane layer was concentrated at atmospheric pressure till

dryness. Methanol was added to residual solid and stirred for 60 min at

25-30° C. Slurry was cooled to 0-5° C. and stirred for 60 min at same

temperature. Solid was filtered, and dried at 50-60° C. to obtain

Zopiclone.



Mass Balance:

INPUT KG OUTPUT KG

2-Amino-5-

chloropyridine111

Toluene 580 Toluene Recovered 550

Con.HCl 65 Distillation Residue 30

Pyrazine-2,3-

dicarboxylic acid anhy65 Wastewater 1220

Water 968

Dichloromethane 548 Dichloromethane Recovery 535

Dimethylformamide 33 Distillation Residue 13


Thionyl chloride 79 SO2, HCl to scrubber 65

Sodium hydroxide 58

Water 1410 Dichloromethane Recovery 295

Sodiumborohydride 7 Distillation Residue 10

Dichloromethane 305 Wastewater 1418

N-me-piperazine

carbamoyl chloride HCl84

Calcium oxide 35

Dimethylaminopyridine 2

Dimethylformamide 80Dichloromethane + DMF

Recovery700

Dichloromethane 635 Methanol Recovery 345

Methanol 355 Residue 25

Drying loss 25

ZOPICLONE 100

Total 6188 6188

Centrifuge

Drying

MASS BALANCE OF Zopiclone

Condensation

reaction

Chroniation

Reduction

Condensation



7. Temoxifen Citrate:


In a Reactor charge POCl3 at cool it for 5-10oC. Then charge 2-

phenylbutanoic acid at 5-10 o C. Stir the reaction mass for 1 h at 5-10oC.

Then charge Phenol and chloride at 5-10o C and maintain temp. 5-10oC

for 30 min. Then rise the temp and stir the reaction mass at 48 hrs. Add

water and soda ash. Maintain the temperature 10-15oC during quenching.

Charge Water, NaOH solution, and Toluene in a Reactor with dean stark

and condenser and start heating for reflux 110o C. Then stop the heating

and cool the reaction mass to 50-55o C. Then Charge TBAB and DMCA

HCl and heat the reaction mass for reflux. Then stop heating and stirring.

Charge water to the reaction mass and stir well. Separate the organic and

aqueous layer. The Organic layer (Toluene layer) take for distillation and

distilled out toluene under vacuum below 70o C. Oily compound observed.

Charge Mg-turning and bromo benzene. Exotherm observed, apply water

bath. Take bromo-benzene, Me-THF and make solution with stirring.

After addition complete maintain the temperature (80-85oC) for 1 h. Then

cool the reaction mass to 10-15o C. Then take NH4Cl and water. Then add

this solution in reaction mass drop wise at 5-10oC. Charge IPA and clear

it on heating. Then cooled it up to 0-5oC and stir it well for 20 min at

same temp. The solid obtained was filter of charge Conc. HCl and heat it

up to 55oC. Maintain this temperature to complete hydrolysis for 18 hrs.

After complete hydrolysis, Charge Chloroform to reaction mass and

separate out it. Take Organic layer and distilled out the solvent Charge

Citric acid and Acetone in a reactor and Stir well. Heat it and clear it at

45o C. Then pass the mass to the centrifuge and waste water sent to the

ETP and then wet cake is formed which is dried and product is recovered.



Chemical Reaction:



Mass Balance:

INPUT KG OUTPUT KG

Phenol 236

2-Phenyl butanoic acid 144

Phosphorus oxychloride 80

Zinc chloride 45

Water 500

Sodium hydroxide 106

HCL Conc. 120

Dimethylamine HCL 85

Sodium methoxide 105 Toluene Recovery 735

Tetrabutly ammonium

bromide9 Distillation Residue 15

Toluene 750 Waste water 600

Water 200

Soda ash 102

2-Methyl

tetrahydrofuran220

2-Methyl tetra hydrofuran

Recovery215

Bromo benzene 102 Isopropyl alcohol Recovery 282

Magnesium turning 70 Distillation Residue 13

Ammonium chloride 55 Wastewater 650

Iso propyl alcohol 290

Water 800

Conc. HCl 650 Wastewater 2066

Chloroform 600 Chloroform Recovery 590

Citric acid 37 Distillation Residue 10

Acetone 300 Acetone Recovery 290

Distillation Residue 10

Drying loss 30

Temoxifen Citrate 100

Total 5606 5606

Centrifuge

Drying

MASS BALANCE OF Tamoxifen Citrate

Condensation

reaction

Ammination

Reduction

Condensation



8. Bupropion HCl:


Take of 3‐Chloropropiophenone in Reactor Charge PTSA (P-Toluene

sulfonic acid) in reaction mass. The reaction mass is Stirred for 10‐15

min. Charge NBS (N-Bromo succinamide) and Di-chloro methane in

reaction mass at 50‐55oC. The reaction mass is cooled up to 30 min.

During Ammination process Tert. butyl amine and Di-chloro methane.

Aqueous filter is sent into ETP and Di-chloro methane is recovered. Add

IPA and IPA HCl to form the Salt of Bupropion HCl. Charge tert. Butyl

amine in reaction mass. Heating started up to reflux for completion of the

reaction. Charge DM water. Separate out layer and aqueous layer is

extracted with MDC Both Organic layers are distilled out under vacuum

below at 50-55oC. The reaction mass is cooled up to 10-15oC. Feed 16%

IPA. HCl drop wise in the reaction mass at 10-15oC up to pH 2-3. Hold

the reaction mass for 30 min at 10-15oC. Filter the material and washed

with chilled IPA then centrifuge the mass. Dry the wet cake and product

is obtained at last.

Chemical Reaction:



Mass Balance:

INPUT KG OUTPUT KG

3-Chloropropiophenone 57

P-Toluene sulfonic acid 7 Wastewater 1094

N-Bromo succinamide 67

Water 1026

Dichloro methane 171

Tert. Butyl amine 74 Wastewater 1061

Dichloro methane 57 Dichloro methane Recovery 220

Water 993 Distillation Residue 8

Isopropyl alcohol HCl 63

Isopropyl alcohol Recovery 220

Isopropyl alcohol 228 Distillation Residue 8

Drying loss 32

Bupropion HCl 100

Total 2743 2743

Drying

Centrifuge

MASS BALANCE OF Bupropion HCl

Condensation

reaction

Ammination

HCL Salt

Formation



9. Anastrazole:


Add 3,5-Bis(bromo methyl) toluene, sodium cynide and ethyle acetate

was added drop wise with vigorous stirring over 1 h. The reaction mixture

was stirred for a further 4 h at room temperature. The organic layer

taken and solvent is recovered in distillation column. Then add sodium

hydride, methyl iodide in reactor to complete the methylation and waste

water is sent into ETP. Add Acetonitrile in the solution along with water

and ethyl acetate. Wastewater is sent into treatment. From organic layer

separation solvents are recovered. Then add Dimethyl Formamide, ethyl

acetate and cyclohexane. After that centrifuge the mass and at the end of

process Anstrazole is generated.

Mass Balance:

INPUT KG OUTPUT KG

3,5-Bis(bromo methyl)

toluene

180

Sodium cynide 55 Methanol Recovery 635

Methanol 650 Ethylacetate Recovery 343

Ethyl acetate 350 Isopropanol Recovery 440

Isopropanol 450 Distillation residue 32

Sodium Hypochlorite solution 150

Sodium hydride 150Dimethylformamide

Recovery245

Methyl iodide 338 Ethylacetate Recovery 441

Dimethyl formamide 250 Distillation residue 14

Ethyl acetate 450 Waste water 380

Water 520

Acetonitrile 450 Acetonitrile Recovery 445

NBS 100 Ethyl acetate Recovery 635

AIBN 20 Distilation Residue 20


Ethylaceatate 650

Dimethyl formamide 400 Dimethyl formamide 390

1,2,4-trazole Na salt 27 Ethyl acetate Recovery 540

AIBN 20 Cyclohexane Recovery 440

Ethylaceatate 550 Distilation Residue 30

Cyclohexane 450


Drying loss 29

Anastrazole 100

Total 7860 7860

Centrifuge

Drying

MASS BALANCE OF Anastrozole

Cyanation

Reaction

Methylation

Ditillation

Traizole

Reaction



10. Theophylline:


Add Uracil, Methanol and potassium hydroxide in the reactor. Add methyl

iodide in the reactor. Keep the temperature between 55-60oC. Methanol

is recovered at the end. Waste water is goes into the ETP. Add nitric acid

and sulphuric acid to complete the nitration process. Add HCl, Iron

powder and Methylene chloride. Tetrahydro furan and Methylene chloride

is recovered at the end. Add Nitric acid, sulphuric acid and formic acid for

purification process. For reflux add ethyl acetate and Dichloromethane.

Solvents are recovered in distillation. Centrifuge the mass and aqueous

layer goes into ETP, dried the mass and product is recovered.

Mass Balance:

INPUT KG OUTPUT KG

Uracil 95


Potassium hydroxide 80 Distillation residue 11

Methyl iodide 55

Nitric acid 87

Sulphuric acid 125 Waste water 1500

Water 2097

Tetrahydro furan 710 Iron Sludge 75

HCL solution 90 Tetrahydro furan

Recovery

700

Iron powder 80 Methylene chloride

Recovery

500

Bicarbonate 115 Distillation residue 26

Methylene chloride 516

Nitric acid 85

Sulphuric acid 95 Wastewater 900

Water 450

Formic acid 25

Glacial acetic acid 3

Ethyl acetate 645 Ethyl acetate Recovery 630

Dichloromethane 645 Dichloromethane

Recovery

630

Bicarbonate 90 Distillation residue 30


Drying loss 33

Theophylline 100

Total 7562 7562

Centrifuge

Drying

Purification

MASS BALANCE OF Theophylline

Codentasation

reaction

Nitration

Reaction

Reduction

reaction

Purification



11. Allantoin


Add urea, Glyoxylic acid, sodium hydroxide in reactor. Mass is condensed

with water. Catalyst is recovered at the end. Mass is dried and then it is

goes for crystallization. In crystallization add water and NaOH. Then mass

is transfer for centrifugation and waste water is sent into ETP. Then mass

is dried and product is received at the end.

Mass Balance:

INPUT KG OUTPUT KG

Urea 38

Glyoxylic acid 47 Waste water 2090

Catalyst 8 Catalyst 8

Water 2205

Sodium hydroxide 23

NaOH 20

Water 500

Water 1995 Waste water 2605

Drying loss 33

Allantoin 100

Total 4836 4836

MASS BALANCE OF Allantoin

Condensation

reaction

Crystallization/

Purification

Centrifuge

Drying





Add 6,6-Dimethyl-1-Heptene-4-yene-3-ol and Phosphorous oxy chloride.

Mass is condensed with Conc. HCl. Keep it stir for 3 hours. Diisopropyl

ether and Acetonitrile is added in the vessel, which are recovered at the

end of condensation. Add N-Methyl-1-Naphthalene methylamine in the

above dried mass. Add Dimethyl formamide, Di-isopropyl Ether,

Methylene chloride and Sodium carbonate. Solvents are recovered at the

end of distillation process. Then mass is dried and Terbinafine Base is

obtained. In Terbinafine Base acetone and Methylene chloride is added

along with water and centrifuge it. Then mass is dried. Terbinafine

Hydrochloride is obtained at the end.

Mass Balance:

INPUT KG OUTPUT KG

6,6-Dimethyl-1-Heptene-

4-yene-3-ol150 Acetonitrile Recovery

515

Phosphorous oxy chloride 625 Diisopropyl ether Recovery 1470

Acetonitrile 525 Distillation Residue 40

Conc. HCl 125 Waste Water 1310

Diisopropyl ether 1500

Water 725

N-Methyl-1-Naphthalene

methylamine

100 Methylene chloride Recovery 735

Dimethyl formamide 50 Diisopropyl Ether Recovery 860

Sodium carbonate 55 Distillation Residue 30

Methylene chloride 750 Wastewater 535

Diisopropyl Ether 875

Water 225

Methylene chloride 500 Methylene chloride Recovery 480

Acetone 300 Acetone Recovery 290

Distillation Residue 30

Water 200 Waste Water 280

Drying loss 30

TERBINAFINE HCl 100

Total 6705 6705

Drying

MASS BALANCE OF TERBINAFINE HYDROCHLORIDE

Codentasation

reaction

Preperation of

Terbinafine

Purification

Centrifuge





In the reactor charge Isoveraldehyde, ethyl Cyano acetate, Diethyle

malonate and water. Maintain the temperature between 27-32oC. Add HCl

in the vessel and stir it for 1 hour. Then mass is further condensed with

urea and sodium hydroxide solution. Waste water goes into ETP and mass

is dried. Then dried mass is collected in that Phenyl ethylamine and PTSA

is added. Add Concentrated HCl in vessel. Stir it for 3 hrs. Cool it for 1

hour. Then mass is crystallized with IPA. IPA is recovered at the end. Add

HCl in the mass and after that centrifuge the mass. Then dried the mass.

At the end Pregabalin Hydrochloride is obtained.

Mass Balance:

INPUT KG OUTPUT KG

Isoveraldehyde 65

Ethyl cyano acetate 78

Diethyl malonate 93 Heptane Recovery 82

Di-N-Propylamine 8 Distillation residue 5

Water 155

Heptane 87

Conc HCl 543

Urea 47

Sodium Hydroxide 1 Wastewater 350

Conc HCl solution 8

Water 250

Chloroform 543 Chloroform Recovery 525

Ethanol 5 Phenyl ethylamine Recovery 72

Phenyl ethylamine 76 Distillation residue 22

PTSA 4 Wastewater 112

Sodium hydroxide 26

Conc HCl 70

DM Water 101

Sodium Hydroxide 146 Isopropyl alcohol

Recovery

78

Isopropyl alcohol 80 Distillation residue 2

Conc HCl 147


Drying loss 30

Pregabaline HCl 100

Total 3231 3231

Centrifuge

Drying

MASS BALANCE OF PREGABALIN HYDROCHLORIDE

Codentasation

reaction

Condensation

reaction

Recimization

Crystallization/

Purification



14. Rebamipide


Nitration: Charge Diethyl Malonate in nitric acid and warm reaction and

add water in the reaction. After completion of nitration, Reduction take

place.

Reduction: Charge Dichloromethane along with Catalyst and heat up to

45 to 60oC. At the end of reduction catalyst is recovered.

Condensation: charge 4-Chlorobenzoic acid chloride and Dimethyl

formamide. Add water in it. Methylene Dichloride Filtrate is obtained at

the end. Further mass is condensed with 4 Bromo methyl quinoline and

sodium ethoxide. Add Concentrated HCl in vessel and stir for 1 hr. then

add Ethanol.

Centrifugation: The mass is transfer for centrifugation, waste water

goes into ETP and Ethanol is recovered by distillation process. Mass is

dried and Rebapimide is obtained at the end.

Mass Balance:

INPUT KG OUTPUT KG

Diethyl Malonate 44

Nitric acid 42 Wastewater 153

Water 139

Dichloromethane 278 Catalyst Recovery 7

Catalyst Pd/C 7

4-Chlorobenzoic acid 49 Wastewater 31

Dimethyl formamide 1 Dichloromethane Recovery 270

DM water 28 Distillation residue 8

4-Bromo methyl quinoline 63

Sodium Ethoxide 21 Ethanol Recovery 400

Ethanol 416 Residue 16

Sodium Hydroxide 13

Conc HCl 42


Drying loss 30

REBAMIPIDE 100

Total 1213 1213

Centrifuge

Drying

MASS BALANCE OF REBAMIPIDE

Nitration

Reduction

Condensation

Condensation



15. Valsartan


L‐ Valine is treated with methanol in presence of Thionyl chloride to get L‐

Valine methyl ester which was then neutralized with alkali solution to get

L‐methyl valinate. L‐Methyl valinate is condensed with 4‐bromo methyl

‐2‐cyano biphenyl in presence of potassium carbonate which was then

treated with oxalic acid to isolate the Valsartan oxalate. Valsartan oxalate

is condensed with Valeroyl chloride in presence of potassium, Carbonate

in o‐xylene to get Valeroyl Valsartan. The cyano group of Valeroyl

Valsartan is cyclized in presence of tri butyl tin chloride & sodium azide in

o‐xylene at reflux to get methyl Valsartan. The methyl Valsartan is then

hydrolyzed with sodium hydroxide and isolated with dichloromethane and

cyclohexane to get crude Valsartan. The crude Valsartan is treated with

calcium hydroxide in acetone and D I water and filtered to obtained

calcium salt of Valsartan. Valsartan calcium salt is treated with

hydrochloric acid in ethyl acetate and water. The ethyl acetate layer is

treated with di-isopropyl ether to obtain the pure Valsartan.

Chemical Reaction:



Mass Balance:

INPUT KG OUTPUT KG

L‐ Valine 45

Methanol 450

Thionyl chloride 35 SO2, HCl to scrubber 28

Water 200 Methanol recovery 440

Toluene 650 Toluene recovery 635

DCM 350 DCM recovery 345


NaCl 15 Wastewater 120

4‐ bromo methyl ‐2 ‐

cyano biphenyl

70

Potassium carbonate 45

Acetonitrile 450 Acetonitrile recovery 442

O-xylene 625 O-xylene recovery 615

Oxalic acid 1 Distillation residue 18


Valeroyl Chloride 40

Potassium carbonate 25

Water 900

Sodium bicarbonate 28

O-xylene 300

HCl 65

Tri butyl tin chloride 20

Tetra butyl

ammonium bromide

15

Sodium azide 22

Hexane 550 Hexane recovery 540

DCM 300 DCM recovery 295

O-xylene 300 O-xylene recovery 295


Calcium hydroxide 25


Acetone 450 Acetone recovery 445

Ethyl acetate 400 Ethyl acetate recovery 390

Di isopropyl ether500 Di isopropyl ether

recovery490

Water 100 Distillation residue 20

HCl 10 Wastewater 1873

Drying loss 25

VALSARTAN 100

Total 8416 8416

MASS BALANCE OF VALSARTAN

Reactor

Reactor

Reactor

Drying

Reactor

Reactor

Centrifuge



2.6 PROJECT COMPONENTS

Components of the project include all facilities required for the operation,

which is summarized below:

a) Input Requirement: Raw materials, Water, Fuel, Power, Manpower

b) Utility requirement: Boilers, D.G. set, Cooling tower, Chilling Plant

and RO/DM Plant.

c) Treatment Facilities:

Water treatment facilities: ETP, RO, & MEE

Air Pollution Control Facilities: Multi Cyclone, Bag filter & water

scrubber for flue gas stacks; and water scrubbers & alkali scrubbers

for process gas stacks.

Hazardous/solid waste disposal facilities: Hazardous waste storage

facility.

d) Other: Greenbelt and rain water harvesting.

2.7 INPUT REQUIREMENTS

a) Raw material requirement:

The details of the raw material requirement with availability and mode of

transport are given in Table 2.5 below. The raw materials will be stored/

inventory will be maintained as per market requirement of the products

and production schedule.

Table 2.5 Raw Materials Requirement, Availability & Mode of Transport

Sr. no.

Name of Products

Name of Raw Material Quantity MT/MT

Availability Mode of Transport

1 Telmisartan 2‐n‐Propyl‐4‐methyl ‐6‐(1‐methyl

benzimidazole‐2‐yl)

benzimidazole

0.68 Indigenous/ Imported

By Road/ Sea

methyl‐4’‐(bromomethyl)‐biphen

yl‐2‐carboxylate

0.58 Indigenous/

Imported

By Road/

Sea

Acetone 0.10 Indigenous By Road

Sodium hydroxide 0.40 Indigenous By Road

Methanol 0.10 Indigenous/ Imported

By Road/ Sea

HCl 0.70 Indigenous By Road

Dichloromethane 0.10 Indigenous By Road

Hyflo 0.01 Indigenous By Road

2 Ondensetron

HCl

1,3-CHD 1.20 Indigenous/ Imported

By Road/ Sea

Phenyl hydrazine 1.81 Indigenous/ Imported

By Road/ Sea

Acetic acid 5.22 Indigenous By Road

Zinc chloride 2.52 Indigenous By Road

Methanol 0.12 Indigenous By Road

Con HCl 0.93 Indigenous By Road

Dimethyl sulphate 0.70 Indigenous By Road




Potassium Carbonate 0.40 Indigenous By Road

DMA HCl 0.72 Indigenous By Road

Paraformaldehyde 0.27 Indigenous/ Imported

By Road/ Sea

2-Methyl Imidazole 0.95 Indigenous By Road

3 Benfotanamine TMP 1.22 Indigenous/

Imported

By Road/

Sea

Caustic 0.27 Indigenous By Road

Benzoyl chloride 0.60 Indigenous By Road



4 Albendazole 3-Chloro-6-nitroacetanilide 0.91 Indigenous/ Imported

By Road/ Sea

Propylmercaptan 0.44 Indigenous/

Imported

By Road/

Sea

NaOH lye 0.77 Indigenous By Road


Hexane 0.03 Indigenous By Road

Di-isopropylether 0.03 Indigenous By Road

NASH solution (30%) 2.74 Indigenous By Road

Con HCl 1.37 Indigenous By Road

Sodium Hydroxide 3.43 Indigenous By Road

Cyanamide 0.26 Indigenous By Road


Methyl chloroformate 0.30 Indigenous By Road

5 4-Hexyl

resorcinol


Caproic acid 1.90 Indigenous By Road

Resorcinol 1.10 Indigenous By Road


Toluene 0.15 Indigenous By Road

6 Zopiclone 2-Amino-5-chloropyridine 1.11 Indigenous/ Imported

By Road/ Sea


Con.HCl 0.65 Indigenous By Road

Pyrazine-2,3-dicarboxylic acid

anhy

0.65 Indigenous By Road


Dimethylformamide 0.35 Indigenous By Road

Thionyl chloride 0.79 Indigenous By Road


Sodiumborohydride 0.07 Indigenous By Road

N-me-piperazine carbamoyl chloride HCl


By Road/ Sea

Calcium oxide 0.35 Indigenous By Road

Dimethylaminopyridine 0.02 Indigenous/ Imported

By Road/ Sea


7 Tamoxifen

Citrate

Phenol 2.36 Indigenous By Road

2-Phenyl butanoic acid 1.44 Indigenous/ Imported

By Road/ Sea

Phosphorus oxychloride 0.80 Indigenous/

Imported

By Road/

Sea



Conc. HCl 7.70 Indigenous By Road



Dimethylamine HCl 0.85 Indigenous By Road

Sodium methoxide 1.05 Indigenous By Road

Tetrabutly ammonium bromide 0.09 Indigenous By Road


Soda ash 1.02 Indigenous By Road

2-Methyl tetrahydrofuran 0.05 Indigenous By Road

Bromo benzene 1.02 Indigenous By Road

Magnesium turning 0.70 Indigenous By Road

Ammonium chloride 0.55 Indigenous By Road

Iso propyl alcohol 0.08 Indigenous By Road

Chloroform 0.10 Indigenous By Road

Citric acid 0.37 Indigenous By Road


8

Bupropion HCl 3-Chloropropiophenone 0.57 Indigenous/

Imported

By Road/

Sea

P-Toluene sulfonic acid 0.07 Indigenous/ Imported

By Road/ Sea

N-Bromo Succinamide 0.67 Indigenous/ Imported

By Road/ Sea

Dichloro methane 0.08 Indigenous By Road

Tert. Butyl amine 0.74 Indigenous By Road

Isopropyl alcohol HCl 0.63 Indigenous By Road

Isopropyl alcohol 0.08 Indigenous By Road

9 Anastrazole 3,5-Bis (bromo methyl) toluene 1.80 Indigenous/ Imported

By Road/ Sea

Sodium cynide 0.55 Indigenous By Road


Ethyl acetate 0.07 Indigenous By Road

Isopropanol 0.10 Indigenous By Road

Sodium Hypochlorite solution 1.50 Indigenous By Road

Sodium hydride 1.50 Indigenous By Road

Methyl iodide 3.38 Indigenous By Road

Dimethyl formamide 0.05 Indigenous/ Imported

By Road/ Sea


Acetonitrile 0.05 Indigenous By Road

NBS 1.00 Indigenous By Road

AIBN 0.40 Indigenous By Road

Ethylaceatate 0.25 Indigenous By Road

Dimethyl formamide 0.10 Indigenous By Road

1,2,4-trazole Na salt 0.27 Indigenous By Road

Cyclohexane 0.10 Indigenous By Road

10 Theophylline Uracil 0.95 Indigenous By Road


Potassium hydroxide 0.80 Indigenous By Road

Methyl iodide 0.55 Indigenous By Road

Nitric acid 0.87 Indigenous By Road

Sulphuric acid 1.25 Indigenous By Road

Tetrahydro furan 0.10 Indigenous By Road

HCl solution 0.90 Indigenous By Road

Iron powder 0.80 Indigenous By Road

Bicarbonate 1.15 Indigenous By Road

Methylene chloride 0.16 Indigenous By Road




Sulphuric acid 0.95 Indigenous By Road

Formic acid 0.25 Indigenous By Road

Glacial acetic acid 0.03 Indigenous By Road



Bicarbonate 0.90 Indigenous By Road

11 Allantoin Urea 0.38 Indigenous By Road

Glyoxylic acid 0.47 Indigenous By Road


NaOH 0.20 Indigenous By Road

12 Terbinafine

Hydrochloride

6,6-Dimethyl-1-Heptene-4-yene-3-ol


By Road/ Sea

Phosphorous oxy chloride 6.25 Indigenous By Road


Conc. HCl 1.25 Indigenous By Road

Diisopropyl ether 0.30 Indigenous By Road

N-Methyl-1-Naphthalene methylamine


By Road/ Sea


Sodium carbonate 0.55 Indigenous By Road


Diisopropyl Ether 0.15 Indigenous By Road



13 Pregabalin

Hydrochloride

Isoveraldehyde 0.65 Indigenous/

Imported

By Road/

Sea

Ethyl cyano acetate 0.78 Indigenous/

Imported

By Road/

Sea

Diethyl malonate 0.93 Indigenous/ Imported

By Road/ Sea

Di-N-Propylamine 0.08 Indigenous By Road

Heptane 0.05 Indigenous By Road

Conc HCl 7.68 Indigenous By Road

Urea 0.47 Indigenous By Road


Chloroform 0.18 Indigenous By Road

Ethanol 0.05 Indigenous By Road

Phenyl ethylamine 0.76 Indigenous By Road

PTSA 0.04 Indigenous By Road

Isopropyl alcohol 0.02 Indigenous By Road

14 Rebapimide Diethyl Malonate 0.44 Indigenous By Road



4-Chlorobenzoic acid chloride 0.49 Indigenous By Road


4-Bromo methyl quinoline 0.63 Indigenous/ Imported

By Road/ Sea

Sodium Ethoxide 0.21 Indigenous By Road

Ethanol 0.16 Indigenous By Road


Conc HCl 0.42 Indigenous By Road

15 Valsartan L‐ Valine 0.45 Indigenous/ Imported

By Road/ Sea


Thionyl chloride 0.35 Indigenous By Road




DCM 0.05 Indigenous By Road


NaCl 0.15 Indigenous By Road

4‐ bromo methyl ‐2 ‐ cyano

biphenyl


By Road/ Sea

Potassium carbonate 0.45 Indigenous By Road


O-xylene 0.20 Indigenous By Road

Oxalic acid 0.01 Indigenous By Road

Valeroyl Chloride 0.40 Indigenous By Road

Potassium carbonate 0.25 Indigenous By Road

Sodium bicarbonate 0.28 Indigenous By Road


Tri butyl tin chloride 0.20 Indigenous By Road

Tetra butyl ammonium bromide 0.15 Indigenous/ Imported

By Road/ Sea

Sodium azide 0.22 Indigenous By Road

Hexane 0.10 Indigenous By Road

DCM 0.05 Indigenous By Road

Calcium hydroxide 0.25 Indigenous By Road



Di isopropyl ether 0.10 Indigenous By Road

b) Water requirement:

Total water requirement (Industrial + Domestic + Greenbelt) will be 253

KLD; out of which 118 KLD will be fresh water requirement & 135 KLD

will be recycle/treated water (RO permeate & MEE condensate). Unit will

satisfy its fresh water requirement from Bore well water supply. Major

water demand will be industrial – mainly process (115 KLD), cooling (30

KLD), boiler (35 KLD), and washing (10 KLD). Detailed break up of each

water consumption and Water balance diagram is given in Table 2.6 and

Figure 2.5, respectively.

Table 2.6 Breakup of water consumption & w/w generation

Sr. No.

Source Water Consumption (KL/day)

W/w Generation (KL/day)

1. Domestic 5.0 4.0

2. Green Belt 50 --

3. Industrial

A Water treatment 22 22

B Process 93 96

C Lab 2.0 2.0

D Scrubber 6.0 1.0

E Cooling 30 6.0

F Boiler 35 4.0



G Washing 10 10

Total Industrial 198 141

Total (1 +2 + 3) 253 145

Recycle Water 135 --

Fresh water

requirement

118 --

Figure 2.5 Water Balance Diagram

Total Water consumption = 253 KLD (118 fresh KLD + 135 recycle* KLD)

Domestic 5

Lab 2

Washing 10

Greenbelt 50

Cooling 30

2 96

Scrubber 6.0

6.0 Bleed off

Boiler 35

Drying loss 1.0

1.0

Soak-pit 4

ETP 22+96+2.0+1.0+10+4+6 = 141

Permeate 95*

4.0 Blow down

RO 141

Reject

MEE 46

Condensate 40*

Salt 2.0

Loss 4.0

Process 115

W. treatment 115

Process 93

Utilities 65

Water

with RM 4.0

10

HCl 3.0

NaHSO3 2.0

22



c) Power:

Total power requirement of 1000 kVA will be sourced from MGVCL

(Madhya Gujarat Vij Company Limited). Unit will also install a stand by D.

G. Set of capacity 500 kVA, which will be used only in case of emergency/

power failure from the grid.

d) Fuel:

Unit proposes to use Agro briquette as fuel in proposed boiler, TFH & HAG

at the rate of 37 TPD, respectively. Details of fuel consumption are given

below in Table 2.7.

Table 2.7 Details of Utilities and fuel consumption

Sr.

No.

Name of utility Name of fuel Quantity

of fuel

1 Steam Boiler (3.0 TPH) Agro briquette 12 TPD

2 Thermic fluid heater

(20 lac Kcal/hr.)

Agro briquette 10 TPD

3 Hot air generator

(30 lac Kcal/hr.)

Agro briquette 15 TPD

4 DG Set (500 kVA) Diesel 125 lit/hr

e) Manpower:

Total manpower for proposed project will be 65 nos., which include

manpower at all levels.

2.8 GENERATION OF POLLUTANTS

The sources of generation of pollutants are given below;

2.8.1 Wastewater Generation

Total industrial wastewater generation will be 141 KLD. The main source

of the industrial wastewater generation will be from process including lab

and scrubber (99 KLD), washing (10 KLD), utilities (Water treatment,

Boiler & cooling - 10 KLD), and water treatment (22 KLD). Domestic

wastewater generation will be 4.0 KLD. The details of the wastewater

generation are depicted in Table 2.6. Water balance diagram is given in

Figure 2.5.

2.8.2 Gaseous Emission

Flue gas emission will be from stack attached with boilers, Thermic fluid

heater and Hot air generator where Agro briquette will be used as a fuel;

and standby D.G. Set. Most probable pollutants will be SPM, SO2 and



NOx. Process emission will be from the reaction vessels and

corresponding pollutants will be HCl and SO2. The details of the flue gas

stacks & process gas stacks and emission quality of Stacks are given in

Table 2.8 and Table 2.9, respectively.

Table 2.8 Details of stacks

Sr.

No.

Stack

attached to

Stack

Height

(m)

Fuel

Used

Fuel

consu-

mption

APC

measure

Pollutants

Flue gas Stack

1 Steam Boiler

(3.0 TPH)

30 Agro

briquette

12 TPD Multi

Cyclone, bag filter &

water scrubber

PM<150

mg/Nm3

SO2<100 ppm

NOx<50 ppm 2 Thermic fluid

heater (20 lac Kcal/hr.)

30 Agro

briquette

10 TPD

3 Hot air

generator (30 lac Kcal/hr.)

30 Agro

briquette

15 TPD

4 DG Set

(500 kVA)

11 Diesel 125

lit/hr.

--

Process Gas Emission

1 Process vessel 11 -- -- Water

scrubber followed by

Alkali

Scrubber

SO2<40

mg/Nm3

HCl<20

mg/Nm3

2 SFD/FBD/RVD

(5 nos.)

11 -- -- Inbuilt Cyclone and

Bag filter

PM<40

mg/Nm3

Table 2.9 Estimated Emission Quality of Stack

Sr.

No.

Stack attached

to

Stack

Height

(m)

Temp.

(K)

Velocity

(m/s)

Dia.

(m)

Concentration

SPM

mg/Nm3

SO2

mg/Nm3

NOx

mg/Nm3

1 Steam Boiler

(3.0 TPH)

30 455 6.0 0.45 80 40 35

2 Thermic fluid

heater

(20 lac Kcal/hr.)

30 455 6.5 0.45 80 40 35

3 Hot air

generator

(30 lac Kcal/hr.)

30 455 6.5 0.45 80 40 35

4 D. G. Set

(500 kVA)

11 485 15.0 0.3 65 30 35

5 Process vessel

stack

11 335 5.0 0.3 SO2 - 30 mg/Nm3

HCl - 18 mg/Nm3

6 SFD/ FBD/ RVD

(5 nos.)

11 335 5.0 0.3 PM - 30 mg/Nm3



Sources of fugitive emission:

In proposed activities, there will be chances of generation of acid fumes

and VOCs from material handling area, process area, and solvent storage

area. There will be also changes of generation of PM (Dust) from packing/

finishing area.

2.8.3 Hazardous/Solid waste generation

Main source of hazardous waste generation will be ETP sludge (25

MT/month) and MEE salt (50 MT/month) from wastewater treatment.

Other wastes will be distillation residue (15 MT/month), Process sludge

(12 MT/month), spent carbon (0.75 MT/month), spent catalyst (1.0

MT/month), used lubricating oil (40 Lit/month), discarded drums (700

nos./month), containers/liners and liners (0.5 MT/month), whatsoever

generated off-specific product and date expired products. HCl (20-25%) -

75 MT/month and Sodium bisulfite (NaHSO3) - 50 MT/month.

Fly ash generation will be around 4.0 MT/day. The details of

solid/hazardous waste generation with its category and quantity are given

in Table 2.10.

Table 2.10 Details of Hazardous waste

Sr.

No.

Type of Solid

Waste

Schedule Quantity Disposal method

Hazardous waste

1 ETP Sludge

&

MEE Salt

35.3 25

MT/month

50

MT/month

Collection, storage & disposal at

TSDF site approved by GPCB.

2 Distillation

residue

20.3 15

MT/month


CHWIF or Co-processing.

3 Process Waste 28.1 12

MT/month


TSDF site approved by GPCB.

4 Used

Lubricating Oil

5.1 40

liter/month

Collection, storage & use within premises as lubricant/sell to

registered recycler.

5 Discarded

containers/

barrels/

Liners

33.1 700

Nos./month

0.5

MT/month

Collection, storage and reuse

for packing of products or

disposal by selling to approved

recyclers.

6 Spent catalyst 28.2 1.0 MT/month

Collection, storage & return back to supplier for

regeneration.



7 Spent carbon 28.3 0.75 MT/month

Collection, storage & return back to supplier for regeneration

8 Off Specific

Products

28.4 Whatever

generated


CHWIF.

9 Date expired

product

28.5 Whatsoever generated


CHWIF.

10 HCl (20-25%) B(15) 75 MT/month

Collection, Storage,

Transportation, sell to actual

user under Rule-9 of HAZ Rule.

11 Sodium

bisulfite

(NaHSO3)

B(15) 50 MT/month

Collection, Storage,

Transportation, sell to actual

user under Rule-9 of HAZ Rule.

Solid waste

1 Fly ash -- 100 MT/month

Collection, Storage, sell to brick

manufacturers.

2.8.4 Noise generation

Main source of noise generation will be boilers, D.G. set, process plant,

vehicular transportation & other machineries.

2.9 POLLUTION CONTROL STRATEGY

The unit is equally conscious about the pollution control strategy. The

details of pollution control strategy for various parameters are given here

under,

2.9.1 Effluent Management

The main source of the industrial wastewater generation will be from

process, water treatment, washing & utilities. The details of the

wastewater generation are shown in Table 2.6. Unit will built full-fledged

ETP to treat w/w generated from proposed project.

Process effluent (Concentrated stream) along with wastewater of

scrubber, washing and utility will be passed through to RO after primary

and secondary treatment. RO reject will be sent to MEE; RO permeate

and condensate of MEE will be reused. Domestic wastewater will be

disposed to soak pit. Thus, achieving Zero Liquid Discharge (ZLD). ETP

sludge and MEE salt will be disposed to approve TSDF site. Domestic

effluent of 4.0 KLD will be disposed to soak pit.

Effluent treatment scheme:

Wastewater from process, washing Scrubbers etc. will be collected in

equalization/neutralization tank, where it is neutralized, depending upon



the acidity/alkalinity of influent. Later it will be pumped into primary

settling tank to settle down suspended solid. Later it will be pumped into

aeration tanks for biological treatment, where microorganisms will be

reduced organic load in effluent. Then effluent is allowed to secondary

settling tank. This activated effluent is passed to settling tanks for

settling purpose. Here sludge formed is settled and removed from the

bottom hopper. Then water will be transferred to the pressure sand filter

followed by RO. RO permeate will be reused, and RO reject will be sent to

MEE. Sludge will be transferred to the sludge drying bed. After drying,

the dried sludge will be collected, packed in HDPE bags and stored in

separate storage area and disposed at approved TSDF site. Salt from MEE

will be sent to TSDF site, too.

Specifications of ETP, RO, and MEE are provided in Table 2.11, 2.12,

and 2.13, respectively. Characteristic of untreated and treated effluent is

provided in Table 2.14. Process flowchart of ETP is given in Figure 2.6.

Table 2.11 Name and size of ETP units, Design Capacity-200 KLD

Sr. No. Name of units Size of Unit Capacity (m3)

1 Equalization tank 6.0 m x 6.0 m x 4.0

(3.5 WD)

126

2 Neutralization tank 6.0 m x 6.0 m x 4.0

(3.5 WD)

126

3 Primary Settling tank 8.0 m x 6.0 m x 2.5

(1.5 SWD)

48 m2

Surface area

4 Aeration tank 7.5 m x 7.5 m x 4.5

(4.0 WD)

225

5 Secondary Settling tank 8.0 m x 6.0 m x 2.5

(1.5 SWD)

48 m2

Surface area

6 Sludge sump 3.0 m x 3.0 m x 3.0

(2.5 WD)

22.5

7 Filter press 1 No. 42 plates with

36”x 36” size

--

8 Sludge drying beds-

4 Nos.

5.0 m x 5.0 m x 1.5 25 m2 x 4

Surface area

9 Intermediate sump 5.0 m x 5.0 m x 4.5

(4.0 WD)

100

10 Pressure sand Filter Standard Supply 10 Kl/Hr

filtration rate

11 Treated water collection

sump

5.0 m x 5.0 m x 4.5

(4.0 WD)

100



12 RO, 2 Nos. (One

standby)

Standard Supply 10 Kl/Hr

filtration rate

13 RO Treated water sump 5.0 m x 5.0 m x 4.5

(4.0 WD)

100

14 Reject Effluent sump 3.5 m x 3.5 m x 4.5

(4.0 WD)

49

15 MEE & ATFD Standard Supply 2.5 Kl/Hr

Figure 2.6 Process flow chart of wastewater treatment (ETP-200 m3/day)

Table 2.12 Technical specification of RO (Capacity: 10 KL/hr.)

Particulars Specification

Type of membrane Thin film composite spiral wound

MOC of membrane Polyamide

MOC of membrane housing FRP

Make of membrane housing Matrix/Equiv

High pressure piping from SS 316

No. of housings Two

No. of membranes 6 nos.

RO feed flow rate 10000 LPH

RO permeate flow rate ~7000LPH

Operating pressure 12-14 kg/cm2

Filter Press & Sludge drying bed

ETP Sludge to TSDF

Equalization/ Neutralization

Tank

Primary Settling

Tank

Pressure sand filter

RO Permeate to reuse

Reject

MEE/ ATFD

Condensate reuse

Reject

Salt to TSDF

Equalization/

Neutralization Tank

Aeration

Tank

Secondary

Settling Tank

Intermediate

sump

Effluent from Plant



Table 2.13 Technical Details of MEE (Capacity: 2.5 KL/hr)

Description Unit Value

Water Evaporation capacity Kgs/hr ~2125-2050

Feed rate Kgs/hr 2500

Concentrate outlet rate Kgs/hr ~250-300

Total solids in product feed TDS% 3%

Total solids in Concentrate outlet TDS% 30%

Inlet/outlet temp ˚C 185-200

Concentrate outlet temp ˚C 60-65

Cooling water inlet/outlet temp ˚C 32-40

Operating hours Hrs/day 20

Table 2.14 Estimated characteristic of untreated and treated effluent

Parameters Unit Untreated

effluent-

Process

Treated

effluent

RO

Permeate

MEE

Condensate

pH pH Unit 2.0-4.5 7.0-7.5 7.0-7.5 7.0-7.5

Color Co-Pt Unit 25-45 <15.0 -- --

SS mg/L 450-600 75-100 -- --

TDS mg/L 12750-

13500

8750-9500 450-500 50-100

COD mg/L 3500-4500 1500-2000 <50 <150

BOD mg/L 1200-1500 1000-1250 -- --

Oil & Grease mg/L 15-20 5-10 -- --

Ammonical

Nitrogen

mg/L 35-45 10-15 -- --

2.9.2 Air Pollution Control Measures

Flue gas emission is due to the combustion of fuel Agro briquette in

boiler, Thermic Fluid Heater and Hot Air Generator. Multi Cyclone, bag

filter & water scrubber will be installed as APCM for each flue gas

emission source. To control the process emission, water and alkali

scrubber will be provided. Spin flash dryers (SFD)/Fluid Based Dryer

(FBD)/Rotary Vacuum Dryer (RVD) will be equipped with in-built cyclone

and bag filter. Furthermore, adequate stack height and facility for

sampling such as ladder and sampling point will be provided as per the

GPCB guidelines. The details of stacks with their APC measures are given

in Table 2.8.

Operating hours 20 Hrs/day

Recovery 70 % (approx.)

High pressure piping from SS 316



Fugitive Emission Control

To control fugitive emission, following steps will be implemented:

Entire process will be carried out in closed reactors.

Pneumatically transfer of liquid raw material in rector.

Raw material will be stored in the covered structure.

Regular maintenance of valves, pipes etc.

PPEs will be provided to the workers.

Frequent work area monitoring will be done ensure fugitive

emissions level.

Greenbelt will be developed around the plant to arrest the fugitive

emission.

2.9.3 Hazardous/Solid Waste Management

Entire quantity of hazardous waste will be handled & disposed as per

Hazardous & Other waste (Management & Transboundary Movement)

Rules, 2016. ETP sludge and MEE salt from wastewater treatment and

Process sludge will be disposed of at approved TSDF site. Spent carbon

and spent catalyst will be returned back to supplier for regeneration.

Distillation residue, off specification products and date expired products

will be sent for co-processing or at CHWIF. Used lubricating oil will be

sold to registered recycler. Discarded Drums & containers/Liners will be

sold to actual users. HCl (20-25%) and Sodium bisulfite (NaHSO3) will be

sold to actual user under Rule-9 of HAZ Rule.

The unit will provide isolated area with impervious flooring & roof cover

for the storage of hazardous waste. Details of hazardous waste disposal

methods are given in Table 2.10.

Fly Ash management




generated from burning of Ago briquette in boiler, HAG and TFH. The

criteria of selection of fly ash brick unit is summarized below.

About 80% fly ash will be used for the production of fly ash bricks. The

ratio of Fly Ash (80%) Gypsum (15%) and sand (5%). Based on the

maximum fly ash generation (4.0 TPD), around 2000 per day *26



=52000 nos /month will be produce. To considering 4 day production per

month (Only Sunday), unit will require 13000 brick per day capacity of

machine. To considering this aspect unit will purchase semi-automatic

machine with capacity of 2000 bricks per hour hydraulic pressure

machine.

2.9.4 Noise Pollution Control Measures

The main noise generating sources in the plant will be boiler, D.G. set,

process plant, vehicular transportation & other machineries. All these

sources will generate continuous noise. However, the noise transmitted

outside the plant boundary will be low because most of the noise

generating equipments will be in closed structures provided with acoustic

enclosure. Equipments will be statically and dynamically balanced. Ear

muff, ear plug will be provided to all workers working at noisy area.

Additionally, extensive oiling, lubrication, periodic monitoring and regular

maintenance will be carried out for the machineries and equipments to

reduce noise generation. Moreover, adequate greenbelt will be developed

within premises and around the periphery to prevent the noise pollution.

By taking measures as mentioned, it is anticipated that noise levels in the

plant will be maintained below the permissible limit.

2.10 RAIN WATER HARVESTING

The rain water from the building roofs will be directed through the

drainage to the covered storm water drainage line. All drainage system

will be concreted lined and located along the roads up to rain water

harvesting pit. Roof top rain water will be collected in tanks and reused

after filtration as per requirements. Additional rain water will be recharge

into water recharging well.

2.11 GREEN BELT DEVELOPMENT

Total land area is 36958 m2. The unit will develop greenbelt in area of

12175 m2. Overall greenbelt area will be tuned around 33% of the total

area of the project.

2.12 OCCUPATIONAL HEALTH & SAFETY

The company is concerned with the health, safety and environment

protection. Following key safety measures shall be a part of the Health &

Safety policy and shall be followed after the project implementation:



Safety Training shall be provided to the employees.

Safety Sirens with Alarm System in case of emergency shall be

provided.

Fire Hydrant System shall be installed.

Fire Extinguishers shall be provided.

Mock drills shall be periodically conducted.

First Aid Facility and training shall be provided.

Personnel protective Equipment shall be provided to the employees.

Health check-ups shall be organized at regular intervals.

Safety/Health records and MSDS shall be maintained.



Chapter-3

Description of Environment

3.1 GENERAL

To assess environmental impacts from proposed project at a specific

location, it is essential to monitor the existing environmental quality

prevailing in the surrounding area prior to implementation of the project.

The environmental status within the impact zone could be used for

identification of significant environmental issues to be addressed in the

impact assessment study. Baseline data generation is a part of the

Environmental Impact Assessment (EIA) study and helps to evaluate the

predicted impacts on the various environmental attributes in the study

area by using scientifically developed and widely accepted impact

assessment methodologies. This section contains the description of

baseline studies of 10 km radius surrounding the project site. The

baseline study was carried out to understand following environmental

parameters.

Land Environment

Meteorology

Air Environment

Water Environment

Soil Environment

Noise Environment

Biological Environment

Socio-economic Environment

The data collected has been used to understand the existing environment

scenario around the project site against which the potential impacts of

the proposed project can be assessed.

3.2 STUDY AREA

The unit is located at Survey no. 504, 505, 507, Village: Dabhasa, Ta.:

Padra, District: Vadodara, Gujarat. An area of 10 km radius from the

boundary of the project site is considered as study area for the EIA study

as per the TOR issued by MoEF&CC.



Table 3.1 Environmental setting of the study area





Location

Survey No. 504, 505, 507

Village Dabhasa

Tehsil Padra

District Vadodara

State Gujarat

Area 36958 m2



Nearest

Railway Station Vadodara Railway Station – 19.0 km,




City, District Headquarters Vadodara, about 20 km


3.3 STUDY PERIOD

Baseline environmental quality represents the background scenario of

various environmental components. As part of EIA study, baseline

environmental monitoring was done over a radial distance of 10 km

around the project site during the period of October, 2018 to

December, 2018.

3.4 SOURCE OF ENVIRONMENTAL DATA GENERATION

Baseline information on micrometeorology, ambient air quality, water

quality, noise level, soil quality and ecology (flora-fauna) are generated

by M/s. San Envirotech Pvt. Ltd., Ahmedabad. Apart from these,

secondary data have been collected from census book, revenue records,

soil survey and forest department, meteorological department etc. The

generation of primary as well as collection of secondary data &

information from the site and surrounding was carried out during the

period of October, 2018 to December, 2018.



3.5 METHODOLOGY

The process & methodology adopted for various environmental attributes

in the study is as follows:

To assess the Air environment in the study area, monitoring of the Air

quality was done by setting up reconnaissance. The samples were

collected by installation of combined sampler (with gaseous

attachment) at different locations for monitoring of primary air

pollutants to work out the existing status of air quality.

Ground water samples & surface water samples were analyzed for the

parameters necessary to determine water quality (based on IS:

10500-2012 criteria) and those which are relevant from the point of

view of environmental impacts of the project site.

Soil samples were collected using an Auger and analyzed for relevant

physico-chemical characteristics in order to assess the impact on soil.

The noise level monitoring was done at various locations at different

intervals of time with the help of sound level meter.

Socio-economic data was collected from field studies and secondary

sources like Census of India 2011, Revenue record, etc.

3.6 LAND ENVIRONMENT

Land Cover is the physical material at the surface of the earth (includes

grass, trees, bare ground, water etc.); whereas Land use is the human

use of land. Studies on land use aspects of eco-system play an important

role in identifying susceptible issues and to take appropriate action to

uphold ecological equilibrium in the region. Main objective is to provide a

baseline status of the study area so that temporal changes due to the

proposed activities on the surroundings can be assessed in future.

3.6.1 Land use pattern of the Study Area

The study area of 10-km around the project site is considered in the land

use pattern study. The term land-use indicates the way in which the land

is utilized for different purposes. The land-use distribution of the study

area is given in Table 3.2. Land-use map is given in Figure 3.1.



Figure 3.1 Land use Map



Table 3.2 Land use statistics work out based on satellite imaginary

Level 1 Level 2 Area (Sq. km.) Area (%)

Agricultural Crop Land 238.3 75.83

Fallow Land 21.37 6.8

Marsh Land 11.96 3.81

Marsh Vegetation 6.98 2.22

Built-up land

Industrial & Commercial 2.69 0.86

Residential 11.47 3.65

Transportation 5.63 1.79

Waste land Barren land 7.29 2.32

Scrub land 3.92 1.25

Water body Canal 1.08 0.34

Reservoirs /Ponds 2.46 0.77

River 1.12 0.36

Total 314.27 100

3.6.2 Objective of Land Use Studies

The objectives of land use studies are (i) to develop land use & land cover

map using land coordinates of the project area, (ii) to identify and mark

important basic features according primary and secondary data, and (iii)

to suggest measures for conservation and sustainable use of land.

3.6.3 Topography

The site area is plain with little undulating at few places. Agriculture and

allied activities are most predominant in this area. Fallow land and barren

lands were less observed near project site. There was no Eco Fragile Zone

or Natural Forest near project site in study area. Toposheet of location

with site location map of 10 km radius at 1:50,000 scale is shown in

Figure 3.12.

3.6.4 Seismicity of the area

The project site falls under seismic zone III. The Seismic Zone Map of

Gujarat is given below.



3.7 METEOROLOGY

Meteorology is the key to understand the air quality. Wind fluctuations

over a very wide range of time, accomplish dispersion and strongly

influence other processes associated with them. The micrometeorological

conditions at the project site will be regulating the transport and diffusion

of air pollutants released into the atmosphere.

3.7.1 Site specific micro-meteorological data

The data on surface meteorological parameters in the study area were

collected from October, 2018 to December, 2018, by setting up

portable weather monitoring station placed at project site. The sensor of

the equipment was kept at sufficient height (about 10 m) from ground

level with free exposure to the atmosphere. The monitoring methodology

is given in Table 3.3 & data collected are presented in Table 3.4.

The following parameters were recorded at hourly intervals during

monitoring period:

• Wind speed & Wind direction

• Temperature

• Relative humidity

• Rainfall

Table 3.3: Monitoring Methodology of Meteorological Data

Sr.

No.

Sampling

Parameters

Sample Collection Total

Sampling

Period

Sampling

Frequency

Methodology

Sampling

Equipment

Sensitivity/

Detection

Limit

1 Wind Speed Anemometer

cup counter

(0 to 65 m/s)

0.25 m/s October,

2018 to

December,

2018

Hourly As per

manufacturer‟s

manual,

Instruments

are

Calibrated

2 Wind

Direction

Wind vane

(0° to 357°)

10

3 Temperature Thermometer

(-40° to 60°)

0.10C

4 Humidity Hygrometer 3%

5 Rainfall Rain gauge 0.5 mm

6 Cloud Cover -- -- 4 Hourly Visual

Inspection by

the observer



Table 3.4: Meteorological Data for the Monitoring Period

(October, 2018 to December, 2018)

Month Wind

speed

(km/hr.)

Pre

dominant

wind

direction

Temp. (0C) Relative

Humidity

(%)

Rain fall (mm)

Max Min Max Min Max Min 24 hrs.

highest

No. of

rainy days

Oct‟18 21.4 0.0 E 39 26 87 20 No rainfall during

the study period Nov‟18 17.5 0.0 NE 38 20 40 16

Dec‟18 25.1 0.0 E 37 17 53 14

3.7.2 Wind Rose

Wind rose is the diagrammatic representation of wind speed in a specified

direction with its arms representing sixteen directions, each arms give a

clear frequency distribution of wind speed in a particular direction for a

given period of time. It is one of the most important meteorological

parameters and governs dispersion; diffusion & transportation of

pollutants. The % frequencies of wind in 16 directions have been

computed from the recorded data during the study period for 24-hourly

intervals to plot wind rose. The predominant wind directions – NNE, NE,

ENE, E; implying that winds come from these directions for most of the

time during the period. The wind speed class 1-5 kmph occurred for

3.99%, 6-10 kmph about 25.18%, 11-15 kmph 48.1% and above 15

kmph and below 40 kmph occurred for 10.05 % of the study period. Calm

wind during this period is 12.68 %.Wind rose diagram is shown as Figure

3.8.

3.8 AMBIENT AIR QUALITY

3.8.1 Introduction

To quantify the impact of the proposed project on the ambient air quality,

it is necessary to evaluate the existing ambient air quality of the area.

The ambient air quality monitoring with respect to the study area of 10

km radius around the project site was done for the baseline information.

3.8.2 Design Network for Ambient Air Quality Monitoring Stations

The baseline status of the ambient air quality has been assessed through

a scientifically designed ambient air quality monitoring network. The

design of monitoring network is based on the following considerations:

Topography/Terrain of the study area

Populated areas within the region



Prediction of maximum concentrations and distances of their likely

occurrence under prevailing meteorological conditions

Representation of regional background

Representatives of likely impact areas

Ambient Air Quality Monitoring (AAQM) stations were placed at eight

locations with due consideration to the above mentioned points.

3.8.3 Reconnaissance

Reconnaissance was undertaken to establish the baseline status of air

environment in the study region. The prime objective of the NAAQ

survey, within 10 km radial study area around the proposed project, was

to establish the existing ambient air quality levels. The monitoring

locations (relative directions and distances) are given in Table 3.11 &

shown in Figure 3.7 and results are given in Table 3.12 to 3.17.

3.8.4 Parameters, Frequency and monitoring Methodology

The existing ambient air quality, in terms of Particulate Matter-10 (PM10),

Particulate Matter-2.5 (PM2.5), Sulphur Dioxide (SO2), Oxides of Nitrogen

(NOx), Carbon Monoxide (CO), Hydrocarbons (HC), Volatile Organic

Compounds (VOCs), Hydrochloric acid (HCl) has been measured. It was

ensured that, the equipment was placed at open space free from any

obstacles at a height of at least 3 to 4 m above the ground level at each

monitoring station to avoid the effects of wind-blown ground dust.

Monitoring has been carried out as per the latest CPCB and MoEF & CC

guidelines and notifications. Details of methodology are given in Table

3.5.

Table 3.5 Methodology of Ambient Air Monitoring

Sampling

Parameters

Instrument used Analytical

equipment

Detection

Limit

Test method

PM10 Combined Sampler

(GTI-241)

Electronic Balance 1 μg/m3 Gravimetric IS: 5182

(Part 23) 2006

PM2.5 Combined Sampler

(GTI-241)

Electronic Balance 1 μg/m3 Gravimetric CPCB

Guidelines for Ambient

Air Monitoring

SO2 Gaseous flow

attachment with

Combined sampler

Spectro Photometer 2.5 μg/m3 Colorimetric IS: 5182:

(Part II) 2001

NOx Gaseous flow

attachment with

combined sampler

Spectro Photometer 6.0 μg/m3 Colorimetric IS: 5182:

(Part VI) 2006

HCl Gaseous flow

attachment with

Titrimetric 1 μg/m3 Titrimetric



combined sampler

CO Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography

HC Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography

VOC Bladder & Pump Gas Chromatograph 1 ppm Gas Chromatography

The duration of sampling of PM2.5, PM10, SO2 & NOx was 24-hourly

continuous sampling per day and CO, HC (Methane & non-Methane), VOCs

(benzene, Toluene & Xylene) & HCl were sampled for 8-hours duration. The

monitoring was done for twice a week for three months. Parameters and

frequency of sampling is given in Table 3.6.

Table 3.6 Monitored Parameters and Frequency of Sampling

Parameters Sampling frequency

Fine Particulate Matter (PM2.5) 24 hourly sample twice a week for three months

Respirable Particulate Matter

(PM10)

24 hourly sample twice a week for three months

Sulphur dioxide (SO2) 24 hourly sample twice a week for three months

Oxides of Nitrogen (NOx) 24 hourly sample twice a week for three months

Hydrochloric acid (HCl) 8 hourly sampling

Carbon Monoxide (CO) 8 hourly sampling

Hydro Carbon (HC) 8 hourly sampling

Volatile Organic Compounds

(VOCs)

8 hourly sampling

3.8.5 Interpretation of result

The existing baseline levels with respect to PM10, PM2.5, SO2, NOX, HCl,

CO, VOCs and HC are tabulated in Tables 3.13 to 3.17 & chart is given

as Figure 3.2 to 3.6.

Particulate Matter (PM10)

An average and 98th percentile value of 24-hourly PM10 values at all the

locations are found from 63.7-71.0 g/m3 and 63.7-68.8 g/m3. The

results were found well within the National Ambient Air Quality Standards

(NAAQS-CPCB) of 100 g/m3.

Particulate Matter (PM2.5)

An average and 98th percentile value of 24-hourly PM2.5 values at all the

locations ranges from 37.0– 48.0 g/m3 and 41.4-50.0 g/m3. The values

are well within National Ambient Air Quality Standards (NAAQS-CPCB) of

60 g/m3.



Sulphur Dioxide (SO2)

An average and 98th percentile value of 24-hourly SO2 value of arithmetic

mean at all the locations ranged from 13.0 – 16.3 g/m3 and 15.8 – 20.8

g/m3 respectively, which are well below National Ambient Air Quality

Standards (NAAQS-CPCB) of 80 g/m3.

Oxides of Nitrogen (NOx)

An average and 98th percentile value of 24 hourly NOx value of arithmetic

mean at all the locations ranged from 15.8-18.1 g/m3 and 19.7-23.6

g/m3 respectively, which are well below the National Ambient Air Quality


Hydrochloric acid (HCl)

HCl found below detectable limit at all the locations.

Carbon Monoxide (CO)

Minimum & Maximum value of CO at all the locations ranged from 1024 –

1182 g/m3.

Hydro Carbon (HC)

Minimum & Maximum value of Methane HC at all the locations ranged

from 32.2-41.1 g/m3 & non-methane HC ranged from 1028-1185 g/m3.

Volatile Organic Compounds (VOCs)

Minimum & Maximum value of VOC at all the locations ranged from 0.27

g/m3 – 3.41 g/m3.

3.9 WATER ENVIRONMENT

3.9.1 Geology

The rocks of the Vadodara district shows an age from Proterozoic to

Recent but a striking features of the district stratigraphy is the total

absence of Paleozoic, and the development of only the uppermost

Mesozoic rocks. The south westerly extended Precambrian basement of

Peninsular India, the oldest rocks of Proterozoic age, are exposed in

eastern and north eastern part of the district. Post Cretaceous sediments

& major volcanic rocks rest over this south westerly extended

Precambrian basement. Post Cretaceous sediments, Infratrappean and

Intratrappean are exposed as scattered inliers while younger volcanic

rocks unit as Deccan trap is well represented and so are the Tertiary and



Quaternary, though the Tertiary records are not complete and fully

exposed.

3.9.2 Hydrogeology

In Vadodara district area, groundwater occurs both as unconfined and

confined conditions. Saturated zones of unconsolidated shallow alluvium

and weathered zones, shallow depth jointed and fractured rocks forms

unconfined aquifers, whereas multilayered aquifer below impervious clay

horizons in alluvium formation and interflow zones of basalts, inter-

trappean beds, deep seated fracture zones, shear zones in basalts,

granites and gneisses give rise to semi confined to confined conditions.

Generally the water table follows topographic configuration. The depth to

water is greater in upland areas whereas in valley portion and shallow

grounds, the levels are very close to surface. In hilly terrain of eastern,

north- east and south-east part of the district, spring zones are seen in

stream river section; also along the section of the Mahi, the Narmada and

the Orsang rivers. The piezometric surface, mainly in alluvium areas of

western half the district also follows the gentle gradient corresponding to

subsurface configuration of deep aquifer zones.

In major part of the district, in north and almost in eastern half of the

district, the hard rocks, such as phyllite, schist, granite, gneiss, basalt

and other sediments such as sandstone, limestone etc., form aquifers,

whereas multilayered alluvium deposits form aquifer system in remaining

central, south-central and western half of the district. The weathered

basalts, granite, gneiss etc., covered by soil and the valley fill & piedmont

deposits forms potential aquifer in the vicinity of rivers and on vast

undulating plains adjacent to hilly terrain but their regional continuity and

extent are limited due to heterogeneous nature of deposits with limited

thickness and as such rarely exceed a few square kilometers. Map

showing general hydrogeology of the district is given as figure below.



Groundwater Condition

As per the GWRDC ground water estimation the Padra Taluka falls in Safe

(White) category.

3.10 WATER QUALITY

3.10.1 Introduction

Water quality assessment is one of the essential components of EIA

study. Such assessment helps in evaluating the existing health of water

body and suggesting appropriate mitigation measures to minimize the

potential impact from development projects. The water quality at the site

and other locations within the 10-km impact zone was monitored during

the study period. The purpose of the study is to:

Assess the water quality characteristics for critical parameters;

Evaluate the impact on agricultural productivity, habitat conditions

recreational resources and aesthetics in the vicinity; and

Predict the likely impacts on water quality due to the project and

related activities.

Reconnaissance survey was undertaken and monitoring locations were

finalized based on:

Location of residential areas representing different activities/likely

impact areas; and

Likely areas, which can represent baseline conditions.



3.10.2 Sampling Frequency, Techniques & Methodology

Eight surface water and eight groundwater samples were collected during

the study period. Ground water samples were collected from the existing

bore wells, while surface water was collected from ponds by surface

water sampler. These samples were taken as grab samples. Necessary

precautions were taken for preservation of samples. Sampling locations

with source & date of sampling is given in Table 3.7.

The samples collection procedure was adopted from „Standard Methods‟

for the examination of Water and Wastewater published by American

Public Health Association (APHA) and IS 10500-2012.The samples were

analyzed for Physico-chemical parameters to assess the existing water

quality of the area (based on IS: 10500-2012 & APHA/AWWA, 23rd

edition). The water sampling locations marked within the study area and

the result of the analysis (ground water and surface water) is presented

in the Figure 3.9 & Table 3.19 & 3.20 respectively.

Table 3.7 Sampling locations with source & date of sampling

Ground Water Sampling Locations

Sample

Code

Location Coordinates Date of

Sampling

Taluka District

GW1 Project Site 22°13'32.76"N

73° 1'13.01"E

18/12/2018 Padra Vadodara

GW2 Dabhasa 22° 14' 19.54" N

73° 1' 31.97" E


GW3 Padra 22° 15' 12.83" N

73° 4' 30.43" E


GW4 Umaraya 22° 15' 42.29" N

73° 1' 50.55" E


GW5 Dhobikuwa 22° 13' 13.63" N

72° 59' 29.52" E


GW6 Ranu 22° 13' 19.73" N

73° 1' 8.66" E


GW7 Bhoj 22° 11' 47.11" N

72° 59' 56.27" E


GW8 Vishrampura 22° 11' 47.11" N

72° 58' 22.85" E




Surface Water Sampling Locations

Sample Code

Location Coordinates Date of Sampling

SW1 Dabhasa Pond 22°14'52.50"N, 73° 2'12.87"E 18/12/2018

SW2 Padra Pond 22°14'29.47"N, 73° 4'59.38"E 18/12/2018

SW3 Bhoj Pond 22°11'57.70"N, 73° 0'16.22"E 19/12/2018

SW4 Ranu Pond 22°12'36.72"N, 73° 1'19.35"E 19/12/2018

SW5 Luna Pond 22°15'47.48"N, 73° 2'50.25"E 19/12/2018

SW6 Dabka Pond 22°14'50.41"N, 72°57'34.74"E 18/12/2018

SW7 Tajpura Pond 22°15'32.56"N, 73° 4'14.73"E 18/12/2018

SW8 Mahi River 22°15'35.19"N, 72°59'38.49"E 19/12/2018

3.10.3 Surface Water Quality (Primary data)

Surface water samples were collected from ponds of Dabhasa, Padra,

Bhoj, Ranu, Luna, Dabka, Tajpur village, and Mahi River. Analysis of the

same is given in Table 3.20. The results have been compared with the

drinking water quality standards specified in IS: 10500-2012. It was

observed that all the physico-chemical parameters and heavy metals

from surface water samples except turbidity are below stipulated drinking

water standards and are suitable for domestic purposes.

3.10.4 Ground Water Quality

The results of the ground water quality monitored during the study period

are given in Table 3.19.

3.10.5 Interpretation

The samples were taken as grab samples and analyzed for various

parameters of ground water. Sampling location is shown in Figure 3.9.

Color: All the samples were found color less meeting desirable norms.

pH: All the samples meet the desirable standards (pH ranges from 7.3-

7.9).

Total Dissolved Solids (TDS): TDS in samples ranges from 1092 mg/L

(Nr. Project Site) to 1923 mg/L (Umaraya). The entire samples meet the

permissible limit of 2000 mg/L TDS.

Calcium: Calcium contents in the water ranges from 44 mg/L

(Dhobikuwa) to 92 mg/L (Umaraya), all the samples meet the permissible

limit of 200 mg/L, (Permissible Limit in the Absence of Alternate Source).

Magnesium: Magnesium content in the water ranges from 40 mg/L

(Bhoj) to 59 mg/L (Dhobikuwa). All the samples meet the permissible

limit of 100 mg/L (Permissible Limit in the Absence of Alternate Source).



Sulfate: Sulfate content in the water ranges from 58 mg/L (Nr. Project

Site) to 116 mg/L (Dabhasa). All the samples meet the permissible limit

of 400 mg/L(Permissible Limit in the Absence of Alternate Source).

Fluoride: Fluoride content in the water ranges from 0.56 mg/L

(Vishrampura) to 0.70 mg/L (Dhobikuwa). All the samples meet the

permissible limit of 1.5 mg/L (Permissible Limit in the Absence of

Alternate Source).

Total Alkalinity: Total alkalinity in the water samples ranges from 308

mg/L (Dabhasa) to 346 mg/L (Padra). All the samples are within the

permissible limit of 600 mg/L (Permissible Limit in the Absence of

Alternate Source).

Other Parameters: Potassium (ranges from 43 mg/L to 68 mg/L),

Sodium (ranges from 323 mg/L to 592 mg/L) and Chloride (ranges from

512 mg/L to 935 mg/L). All the samples meet permissible limit in the

absence of alternate source.

Heavy metals like cadmium, copper, lead, chromium, iron and zinc are

well below the limit in all samples.

3.10.6 Conclusion

The results have been compared with the drinking water quality

standards specified in IS: 10500-2012 & all parameters meet the

permissible limit set by the authority (BIS). Indian Standard specification

for drinking water is given in Table 3.21.

3.11 NOISE ENVIRONMENT

Noise can be defined as an unwanted sound. The definition of noise as

unwanted sound implies that it has an adverse effect on human beings

and their environment. The noise level variation can be temporal, spatial.

It interferes with speech and hearing and is intense enough to damage

hearing or is otherwise annoying. Noise can also disturb natural wildlife

and ecological system. It is therefore, necessary to measure both the

quality as well as the quantity of noise in and around the proposed site.

3.11.1 Instrument used for Sampling and Monitoring

The intensity of sound energy in the environment is measured in a

logarithmic scale and is expressed in a decibel, dB(A) scale. Sound Level

Meter (SLM) is used for the collection of data at an interval of one hour.



The day noise levels have been monitored during 6:00 am to 10:00 pm

and night noise levels during 10:00 pm to 6:00 am at all locations. Noise

levels recorded at each station are computed for equivalent noise levels.

Noise monitoring methodology is given in below Table 3.8.

Table 3.8 Monitoring Methodology of Noise

Environment Component

Sampling Location

Test method Instrument used

Make

Ambient Noise level

09 Locations

As per manufacturers Manual

Sound Level Meter

Mextech-SL-4012

3.11.2 Noise Quality Monitoring Locations

The noise survey was conducted to assess the background noise levels in

different zones. Based on the Gazettes Notification (S.O. 123(E)) of MoEF

dated February 14, 2000 on ambient air quality standards, 9 monitoring

locations were selected. Noise level measurements have been made using

Sound Level Meter. The noise monitoring locations & its results are given

in Figure 3.10 & Table 3.22 respectively.

3.11.3 Ambient Noise Standards

Ministry of Environment & Forests (MoEF) has notified the noise

standards vide Gazette Notification dated February 14, 2000 for different

zones viz. industrial, commercial, residential and silence zones under the

Environment Protection Act (1986). These standards are given in Table-

3.23.

3.11.4 Results

The noise levels of various locations are given in Table 3.22. The

monitored noise level in the day time Leq (Ld) varies from 50.7 to 53.7

dB(A) and the night time Leq (Ln) varies from 39.2 to 43.4 dB(A) within

the study area. Higher noise value of 53.7 dB(A) was recorded during day

time at Village 1000 m East from the site & lower noise value of 40.1

dB(A) was recorded during night time at 500 m North from the site.

3.11.5 Conclusion

Based on the observations made during the studies, it is concluded that;

the noise levels recorded at various locations in the study area show

considerable fluctuations because of changes in traffic movement,

commercial and other domestic activities in the study area. Overall the

ambient noise level in the monitored locations was found to be within the



permissible limits stipulated for residential, industrial areas, silence and

commercial zone.

3.12 SOIL ENVIRONMENT

Soils may be defined as a thin layer of earth‟s crust that serves as a

natural medium for the growth of plants. It is the unconsolidated mineral

matter that has been subjected to and influenced by genetic and

environmental factors. Soils serve as a reservoir of nutrients for plants

and crops and also provide mechanical anchorage and favorable tilth.

The objective of the soil sampling is:

To determine the baseline soil characteristics;

To monitor the impact on soil (pollutant deposition/other) in long

run.

The soils of Vadodara district can be broadly classified into three groups.

They are black soils, alluvial soils and hilly soils. Soil map of the district is

given below.

The above mentioned data has been sourced from District Groundwater

Brochure Vadodara District Gujarat

3.12.1 Soil sampling locations

Soil quality of the study area is one of the important components for

environment impact assessment. The composite soil samples were

collected from the study area from eight locations (Project site, Dabhasa,

Padra, Umaraya, Dhobikuwa, Ranu, Bhoj and Vishrampura) and were

analyzed for different parameters. The location of the monitoring is given



below in Table 3.9. Results are given in Table 3.24 and depicted in

Figure 3.11.

Table 3.9 Location of soil sampling

Sample

Code

Locations Coordinates Date of

sampling

Tehsil District

S1 Project Site

22°13'35.86"N 73° 1'14.67"E


S2 Dabhasa 22°14'26.55"N 73° 1'28.67"E


S3 Padra

22°15'9.75"N

73° 4'19.69"E


S4 Umaraya 22° 15' 43.56" N 73° 1' 49.41" E


S5 Dhobikuwa 22° 13' 16.24" N 72° 59' 26.19" E


S6 Ranu 22° 13' 20.09" N

73° 1' 8.91" E


S7 Bhoj

22° 12' 2.67" N 72° 59' 56.13" E


S8 Vishrampura 22° 11' 47.01" N 72° 58' 22.26" E


3.12.2 Methodology

To understand the soil quality of the study area, analysis of all eight

locations including the project site was conducted by making suspension

of soil sample. The samples were examined for various physical and

chemical characteristics in order to assess the impact on soil. Analysis

was done by using following methodology.

Table 3.10 Methodology of Soil Sample analysis

Sampling

Parameters

Sample

collection

Analytical

Equipment

Methodology Remarks

Porosity

Manual

sample

Collection in

polyethylene

bags using

an Auger

- IS: 2720 Part 7 Trial pit

method

for topsoil

sample

collection;

disturbed

samples

Water holding

capacity

- -

Permeability - IS: 2720 Part 17

Moisture content Electronic Balance IS: 2720 Part 2

Texture - IS: 2720 Part 4

Particle size

Distribution

Glass wares IS: 2720 Part 4 5% Leachate

to

be made and

analyzed as

per

APHA,

“Standard

Methods”

All method

numbers are

as

Cation Exchange

Capacity

Centrifuge IS: 2720 Part 24

(1976)

SAR F. Photometer

(Na, K)

Titration (Ca & Mg)

Calculation

pH pH Meter 4500 H+B

Electrical

Conductivity

Conductivity Meter As per IS 14767 -

2000



Calcium Glass wares 3500 Ca B per APHA

“Standard

Methods”

(23rdedition)

Magnesium Glass wares 3500 Mg B

Sodium (Na) Flame Photometer 3500 Na B

Potassium Flame Photometer 3500 K B

3.12.3 Corollaries

Physical Parameters

Particle Size: A Particle size of the different constituents (clay, silt, sand

and gravel) controls the porosity and water holding characteristic of the

soil. Clay (size<0.002 mm) amount in the soil samples ranges from 16 %

to 24 %; Silt (size 0.002 to 0.075 mm) in the soil samples is 21 % to 32

% and Sand (size 0.075 to 0.475 mm) in the soil samples is 24 % to 33

%, while Gravel (size>4.75 mm) in the soil samples is 20% to 26%.

Analysis shows that the soil has moderate water holding capacity.

Porosity: Porosity is a measure of space in between soil particles caused

by structural conditions and determined under identical conditions.

Porosity of soil samples of the study area ranges from 40.3 % to 43.7%.

Water Holding Capacity (WHC): Water Holding Capacity (WHC) of soil

samples of the study area ranges from 40.3% to 42.1%.

Bulk Density: Bulk Density of soils in the study area is found to be in the

range from 1.39 to 1.46 g/cm3.

Chemical Parameters

pH: pH of soils in the study area is found to be in the range of 7.2 to 7.9.

Chloride: Chloride content in soils of the study area is found to be in the

range of 622 to 898 mg/kg.

Soluble Calcium: The soluble calcium as CaCO3 in soil samples is found

to be in the range of 363 to 797 mg/kg.

Magnesium: Magnesium content in soil samples of the study area ranges

from 202 to 720 mg/kg.

Total Phosphorus: Available Phosphorus content in soil samples of the

study area ranges from 36 to 188 mg/kg.

Total Nitrogen: Available nitrogen content in soil samples of the study

area is found to be in the range from 9 to 282 mg/kg.

Potassium: Potassium content in soil samples of the study area is found

to be in the range from 126 to 185 mg/kg.



Sodium: Sodium content in soil samples of the study area is found to be

in the range from 510 to 692 mg/kg.

Total Organic Matter (TOM): Total organic matter content in soil

samples of the study area is found to be in the range of 1.85 to 4.95

mg/kg.

3.12.4 Conclusion

In the study area, variations in the pH value ranging from 7.2 to 7.9

which shows that the soil is slightly alkaline in nature. Organic Matter

ranges from 1.85 to 4.95 mg/kg in the soil samples. Soil of the study

area is known to be good for cultivation. Generally, soils with low bulk

density have favorable physical conditions (porosity and permeability)

whereas those with high bulk density exhibit poor physical conditions for

agriculture crops.

3.13 BIOLOGICAL ENVIRONMENT

An ecological study of the ecosystem is essential to understand the

impact of industrialization and urbanization on existing flora and fauna of

the study area. The biological study was undertaken as a part of the EIA

study report to:

Understand the present status of ecosystem prevailing in the study

area.

Compare it with past condition with the help of available data.

Predict changes in the biological environment as a result of present

activities and to suggest measures for maintaining its health.

The survey was conducted to study the flora & fauna in 10 km radius.

Some of the information was gathered from the local habitants. All the

collected data were classified to interpret the impact of pollution.

3.13.1 Period of the study

The baseline study, for the assessment of the floral and faunal

biodiversity of the terrestrial environment, within 10 km radius from the

site was conducted during October, 2018 to December, 2018.

3.13.2 Study methodology

Survey methodology was based on the flora & fauna species identification

in person, recently recorded and found in the region by the localities.



Sampling of grass species was carried out by quadrat sampling method to

examine the species distribution and its frequency in the region.

Quadrate Sampling Method:

A quadrat (or plot-based) survey is a quantitative examination of species

distribution & abundance. Quadrats are more likely to detect

inconspicuous species because a smaller area is sampled in a

concentrated search. The survey was carried out for the vegetation

ground cover found in the road edges by 1 m2 quadrat and study on the

edge effect due to rapid industrialization and urbanization.

3.13.3 Floral species in the study area

Flora is basically the plant life that is present in a particular region or

habitat at a particular time. List of flora found in the study area is

tabulated in Table 3.25.

3.13.4 Fauna in the study area

Fauna is the animal life that is present in a particular region or habitat at

a particular time. Irrespective of its unfriendly terrain, Gujarat gives

shelter to a variety of animals and birds. They live in smaller herds and

thrive mainly on wild grasses and various types of shrubs. Faunal

biodiversity with their scientific names and common names is presented

in Table 3.26.


Protection Status:

As per IUCN: Pavo cristatus is Classified as Least Concern (LC) on the

IUCN Red List (1) and listed on Appendix II of CITES 3.








Indian Peafowl (Pavo cristatus)


Kingdom: Animalia

Phylum: Chordata

Class: Aves

Order: Galliformes

Family: Phasianidae

Genus: Pavo




No peacock was sighted in the project site. All the direct sightings of the

peacock were located near the human habitats, villages and agriculture

field, of study area. This species is well adapted to natural village

environment setting. Day time they temporarily move towards the

surrounding agriculture areas for feeding while during night time they

roost on the trees present in the village and in the agriculture hedges.

Since Indian Peafowl is a ground nester, several project activities can

have adverse Impact on their nesting grounds such as pollution,

degradation of soil and vegetation from surrounding area and in the

forest areas. Direct disturbance by presence of people, vehicle their

noise, vibration, light etc. can potentially disturb most of the bird species.



Village residents are against hunting or poaching of the peafowl, due

to culture and mythology reasons.

Majority villagers follow Hinduism in the region, thus they have high

respect towards peacocks due to mythological reasons, and

Literacy levels are greater than 80% in the study region and people

are aware with the significance of the peacock as the national bird.



3.14 SOCIO-ECONOMIC ENVIRONMENT

An essential part of environmental study is socio-economic environment

incorporating various facts related to socio-economic conditions in the

area, which deals with the total environment. Socio economic study

includes demographic structure of the area, provision of basic amenities

viz., housing, education, health and medical services, occupation, water

supply, sanitation, communication, transportation as well as feature of

aesthetic significance such as temples, historical monuments etc. at the

baseline level. This would help in visualizing and predicting the possible

impact depending upon the nature and magnitude of the project. Socio-

economic study of an area provides a good opportunity to assess the

socio-economic conditions of an area. This study will possibly make a

change in living and social standards of the particular area benefitted due

to the project. It can undoubtedly be said that this unit will provide direct

and indirect employment and improve the infrastructural facilities and

standards of living of the area.

3.14.1 Objective of the study

The objectives of this socio-economic report consist of:

To conduct socio-economic assessment study in lease Area

To help in providing better living standards.

To know the current socio-economic situation in the region to cover

the sub sectors of education, health, sanitation, water and food.

To provide employment opportunities.

3.14.2 Land use pattern and infrastructure

The land use pattern indicates the manner in which different parts of land

in an area is being utilized or non-utilized. It is an important indicator of

environmental health; human activity and a degree of inter play between

these two. Even though the soil quality, water availability and climate

have strong influence on agriculture and vegetation, the human activity

may alter the natural environment to a large extent to suit human needs.

Unnatural land use often triggers rapid environmental deterioration and

disturbs ecological balance. In census records, major land use

classifications are; Forests, Culturable land, Culturable wasteland and

area not available for cultivation. Culturable land is further classified as:



irrigated and unirrigated. Area not available for cultivation includes lands

put to non-agriculture uses as well as barren and uncultivable lands.

The main land use in area is for dwellings, infrastructure and related

activities. However, the land use pattern for rural areas is discussed

below. The information is preliminary based on 2011 Census as depicting

in Table 3.28. Total land area is 32540.2 ha, out of that Irrigated area is

16487.3 ha. It constitutes 50.66% of the total land area. 8613.9 ha are

un-irrigated by source and it constitutes 26.47% of total land area. The

study area consist of Cultivable wasteland is 757 ha (2.32%). Area not

available for cultivation is 1549.4 ha & it constitute 4.76%.

3.14.3 Demographic and Socio-Economic Environment

The demographic and Socio-economic details of the study area are

discussed below. These are primarily based on census data of 2011. Data

on number of households, population as well as literacy and employment

pattern in the study area have been presented in Table 3.29. The

employment pattern in the area is indicator of number of persons

employed in various sectors. It also indicates the various categories of

employment flourishing in the area. The Study area in 10 km radius has

53 villages including project site. The total no. of household in the

villages are 37970 and the total population is 185899 (52.16% men &

47.84% women). 70.41% of are literate while literacy rate among women

& men is 62.90% & 77.31% respectively. 54.30% of male population is

part of main worker, while only 12.25% of female population is a part of

main workers. 4.37% of male workers are marginal workers, while 9.55%

of female workers are engaged in such type of activities. 41.33% of male

population and 78.19% of female population are non-workers.

3.14.4 Living Standard and Infrastructure

In India it is not possible to setup a primary standard of living because of

wide variations in terms of income, economic conditions, social custom,

employment opportunity, pattern of spending, etc. However, availability

of amenities like education, medical, water supply, communication, road

network, electricity, etc. significantly reflects the level of development of

the area. Information on available amenities in the study area has been

extracted from census record of 2011. Total numbers of village in study



area are 53. On the basis of data presented in the Table 3.30, the status

of available amenities is discussed in following sub-sections:

Educational Facilities

As per 2011 census, there are primary school in all 53 villages, 31 Pre-

primary school, 50 Secondary schools, 34 Senior Secondary schools, and

27 Arts, Science and Commerce College.

Medical Facilities

53 villages in the study area have 46 primary health centers, 50 primary

health sub centers, 44 Maternity & Child Welfare Centre, 28 T.B Clinic, 42

Dispensaries, 45 Veterinary hospital, and 40 Family welfare center in

study area of 10 km.

Drinking Water Supply

All the 53 villages in the study area have two or more sources of drinking

water. Most of the villages in study area have tube well water supply in

addition to Tap water (almost all). Moreover all villages have facility of

well water and some villages have hand pump, river and tank water, tube

well or other facilities for water.

Communication and Transport

The main mode of public transport available in the study area is by bus

service. 35 villages have approach to railway station as western railway

meter gauge line is passing through nearby. All of villages in the study

area are connected with pucca road & kutccha road. 47 villages have

water bound macadam facilities, 44 villages are connected with the State

highways and 29 villages are connected with the national highways.

Post and Telegraph

As per 2011 census record out of 53 villages in study area, almost all the

villages have phone facility at doorstep & post office facility. Villages have

facility of Public Call Office service at door step.

Power Supply

As per 2011 census record almost all the villages are getting power

supply for all purposes.



Table 3.11: Ambient Air Quality Monitoring Locations

(Monitoring Period: 1st October, 2018 to 29th December, 2018)

Sr.

No.

Sampling

Location

Direction

w.r.t project

site

Address &

Geographical location

Distance

in km

Type of

Area

1 Project Site

(A1)

-- 22°13'35.86"N

73° 1'14.67"E

0.0 Industrial

2 Dabhasa

(A2)

NNE(UW) Tarak Patel

22°14'26.55"N

73° 1'28.67"E

1.57 Residential

3 Padra (A3) ENE(UW) Parul Patel,

Ujambag, Padra-

Tajpura Road

22°15'9.75"N

73° 4'19.69"E

6.11 Residential

4 Umaraya

(A4)

NNE(UW) Pyarelal Virubhai

22°15'43.56"N

73°1'49.41"E

4.16 Residential

5 Dhobikuwa

(A5)

WSW(DW) Sagabhai Parmar

22°13'16.24"N

72°59'26.19"E

3.10 Residential

6 Ranu (A6) SSW(DW) Jivanbhai Patel

22°13'20.09"N

73°1'8.91"E

0.45 Residential

7 Bhoj (A7) SW(DW) Narshinhbhai

Valand

22°12'2.67"N

72°59'56.13"E

3.56 Residential

8 Vishrampura

(A8)

SW(DW) Ashokbhai Patel

22°11'47.01"N

72°58'22.26"E

5.88 Residential



Table 3.12: Ambient Air Quality Status


Sr.

No.

Sampling

Station

PM10

(g/m3)

PM2.5

(g/m3)

SO2

(g/m3)

NOx

(g/m3)

Average (Min-Max)

1 Project Site (A1) 67.9

(59.9-74.0)

39.9

(35.0-44.5)

15.5

(12.5-18.0)

18.1

(14.4-21.4)

2 Dabhasa (A2) 70.7

(63.7-82.2)

39.8

(28.9-45.8)

15.1

(13.0-17.6)

17.8

(13.5-21.0)

3 Padra (A3) 67.2

(54.3-74.8)

37.0

(29.4-42.7)

13.7

(10.8-15.8)

16.9

(13.3-20.7)

4 Umaraya (A4) 67.1

(59.0-76.3)

41.8

(34.6-51.2)

16.3

(12.9-19.2)

17.4

(14.4-22.2)

5 Dhobikuwa (A5) 71.0

(64.3-76.2)

37.3

(29.4-44.0)

13.6

(11.2-15.9)

16.0

(12.4-20.5)

6 Ranu (A6) 68.9

(61.3-76.0)

37.6

(31.7-47.1)

13.0

(10.2-18.3)

15.8

(11.6-23.1)

7 Bhoj (A7) 69.6

(61.9-77.7)

41.1

(35.2-49.3)

13.8

(11.4-16.9)

15.8

(13.7-20.8)

8 Vishrampura (A8)

70.7

(66.2-76.6)

39.5

(34.3-45.4)

14.9

(11.5-24.2)

16.7

(13.1-26.5)

Figure 3.2 Graphical representation of Ambient Air Quality



Table 3.13: Ambient Air Quality Status (PM10)


Average-24 Hours Unit-g/m3

Station Name Max Min 98th

Percentile

75th

Percentile

50th

Percentile

25th

percentile

Avg. SD

Project Site(A1) 74.0 59.9 73.3 70.9 68.3 66.0 67.9 3.9

Dabhasa(A2) 82.2 63.7 81.2 75.4 71.1 65.3 70.7 5.6

Padra (A3) 74.8 54.3 74.7 71.8 68.1 63.7 67.2 5.6

Umaraya (A4) 76.3 59.0 75.6 69.2 66.9 64.0 67.1 4.4

Dhobikuwa(A5) 76.2 64.3 76.1 73.7 71.6 68.8 71.0 3.7

Ranu (A6) 76.0 61.3 75.7 72.5 68.9 65.6 68.9 4.2

Bhoj (A7) 77.7 61.9 76.4 72.1 69.7 67.0 69.6 3.7

Vishrampura (A8) 76.6 66.2 76.5 72.8 70.6 68.3 70.7 3.0

Figure 3.3 Graphical representation for PM10



Table 3.14: Ambient Air Quality Status (PM2.5)




Percentile

75th

Percentile

50th

Percentile

25th

percentile

Avg. SD

Project Site (A1) 44.5 35.0 44.5 41.8 39.6 38.0 39.9 2.7

Dabhasa (A2) 45.8 28.9 45.8 41.5 40.2 37.2 39.8 3.9

Padra (A3) 42.7 29.4 41.4 38.8 37.6 35.9 37.0 2.8

Umaraya (A4) 51.2 34.6 50.0 44.0 41.9 38.9 41.8 4.2

Dhobikuwa (A5) 44.0 29.4 42.6 38.9 37.8 35.9 37.3 3.1

Ranu (A6) 47.1 31.7 46.3 40.0 37.6 33.7 37.6 4.4

Bhoj (A7) 49.3 35.2 47.0 42.6 41.3 39.6 41.1 2.9

Vishrampura (A8) 45.4 34.3 45.0 42.9 38.5 36.2 39.5 3.6

Figure 3.4 Graphical representation for PM2.5



Table 3.15: Ambient Air Quality Status (SO2)




Percentile

75th

Percentile

50th

Percentile

25th

percentile

Avg. SD

Project Site(A1) 18.0 12.5 18.0 16.8 15.3 14.7 15.5 1.6

Dabhasa(A2) 17.6 13.0 17.2 15.8 15.3 14.3 15.1 1.2

Padra (A3) 15.8 10.8 15.8 14.8 13.9 12.8 13.7 1.5

Umaraya (A4) 19.2 12.9 19.1 17.6 16.5 14.8 16.3 1.8

Dhobikuwa(A5) 15.9 11.2 15.8 14.9 13.6 12.7 13.6 1.4

Ranu (A6) 18.3 10.2 17.4 13.4 12.6 11.4 13.0 2.0

Bhoj (A7) 16.9 11.4 16.4 14.5 13.7 13.2 13.8 1.2

Vishrampura (A8) 24.2 11.5 20.8 16.1 14.6 13.5 14.9 2.5

Figure 3.5 Graphical representations for SO2



Table 3.16: Ambient Air Quality Status (NOx)




Percentile

75th

Percentile

50th

Percentile

25th

percentile

Avg. SD

Project Site(A1) 21.4 14.4 21.1 19.7 18.1 16.8 18.1 1.9

Dabhasa(A2) 21.0 13.5 21.0 19.1 17.7 16.6 17.8 2.0

Padra (A3) 20.7 13.3 20.2 18.3 16.8 16.0 16.9 2.0

Umaraya (A4) 22.2 14.4 21.9 17.8 16.9 16.0 17.4 2.2

Dhobikuwa(A5) 20.5 12.4 20.2 18.2 13.9 14.0 16.0 2.3

Ranu (A6) 23.1 11.6 22.0 16.7 15.3 14.0 15.8 2.7

Bhoj (A7) 20.8 13.7 19.7 16.8 15.3 14.4 15.8 1.8

Vishrampura

(A8)

26.5 13.1 23.6 17.8 16.0 15.1 16.7 2.8

Figure 3.6 Graphical representations for NOx



Table 3.17: Ambient Air Quality Status

(CO, HC (Methane & non-Methane), VOC, HCl)


Station Name CO

(g/m3)

Hydro Carbon

(g/m3)

VOC

(g/m3)

HCl

(g/m3)

Methane Non-

Methane

Benzene Toluene Xylene

Project Site(A1) 1024 32.2 1028 0.42 0.59 0.37 BDL

Dabhasa(A2) 1062 37.6 1123 0.89 0.21 0.29 BDL

Padra (A3) 1131 36.1 1141 1.42 1.63 0.26 BDL

Umaraya (A4) 1087 39.3 1092 0.49 0.36 BDL BDL

Dhobikuwa(A5) 1054 39.5 1063 0.63 0.29 BDL BDL

Ranu (A6) 1075 34.0 1039 0.35 0.21 BDL BDL

Bhoj (A7) 1182 34.9 1109 0.28 0.27 BDL BDL

Vishrampura

(A8)

1073 41.1 1185 0.27 BDL BDL BDL



Table 3.18: National Ambient Air Quality Standards

(EP, 7th amendment rules-2009)

Pollutants Time-weighted average

Concentration in ambient air

Industrial, Residential, Rural and

others area

Ecologically Sensitive area (Notified by

Central Government)

Method of Measurement

Sulphur Dioxide (SO2), µg/m3

Annual Average*

50 20 Improved west and Gaekemethod

Ultraviolet fluorescence

24 hours** 80 80

Oxides of Nitrogen as (NO2), µg/m3

Annual Average*

40 30 Modified Jacob &Hochheiser

(Na-Arsenate) Chemiluminescence

24 hours** 80 80

Particulate Matter (Size less than 10 µm or PM10, µg/m3

Annual Average*

60 60 Gravimetric TOEM Beta attenuation 24 hours** 100 100

Particulate Matter (Size less than 2.5 µm or PM2.5, µg/m3

Annual Average*

40 40 Gravimetric TOEM Beta attenuation 24 hours** 60 60

Ozone (O3) µg/m3

8 hours ** 100 100 UV photometric Chemiluminescence Chemical Method

1hours** 180 180

Lead (Pb) µg/m3

Annual Average*

0.50 0.50 AAS/ICP method after sampling on EPM 2000 or equivalent filter paper

ED-XRF using Teflon filter

24 hours** 1.0 1.0

CarbonMonoxide

(CO) mg/m3

8 hours** 02 02 Non Dispersive Infra

Red (NDIR) spectroscopy

1 hour** 04 04

Ammonia (NH3) µg/m3

Annual Average*

100 100 Chemiluminescence Indophenol Blue

Method 24 hours** 400 400

Benzene (C6H6) µg/m3

Annual* 05 05 Gas chromatography based continuous analyzer

Adsorption and desorption followed

by GC analysis

Benzo(a) Pyrine (BaP)-particulate

phase only, ng/m3

Annual* 01 01 Solvent extraction followed by HPLC/GC

analysis

Arsenic (As), ng/m3

Annual* 06 06 AAS/ICP method after sampling on EPM 2000 or equivalent

filter paper

Nickel (Ni) ng/m3

Annual* 20 20 AAS/ICP method after sampling on EPM

2000 or equivalent filter paper

* Annual Arithmetic mean of minimum 104 measurements in a year taken twice a week 24 hourly at uniform interval.

** 24 hourly/8 hourly or 01 hourly values, as applicable, shall be complied with 98% of the time in a year. 2% of the time, they may exceed the limits but not two consecutive days of monitoring.



Table 3.19: Results of Groundwater Quality in the Study Area

(Date of Sampling: 18 to 19 December, 2018)

Parameters Unit CONCENTRATION

Nr. Project

Site

(GW1)

Dabhasa

(GW2)

Padra

(GW3)

Umaraya

(GW4)

Dhobikuwa

(GW5)

Ranu

(GW6)

Bhoj

(GW7)

Vishrampura

(GW8)

pH pH Unit 7.6 7.3 7.5 7.7 7.4 7.1 7.3 7.8

Color Co-Pt Unit Color

less

Color

less

Color

less

Color

less

Color

less

Color

less

Color

less

Color

less

Conductivity Micro

mhos/cm

1580 2450 1735 2770 1963 1670 1825 1930

Turbidity NTU 7.2 5.9 6.1 11.9 8.5 10.3 6.9 7.8

TDS mg/L 1092 1690 1209 1923 1372 1156 1270 1342

Total Hardness as CaCO3 mg/L 265 362 313 460 353 393 297 387

Total Alkalinity mg/L 310 308 346 319 328 332 309 314

Sodium as Na+ mg/L 397 528 330 592 449 323 391 403

Potassium as K+ mg/L 68 62 53 66 43 50 68 50

Calcium as Ca+2 mg/L 48 56 51 92 44 85 53 84

Magnesium as Mg+2 mg/L 59 54 45 56 59 44 40 43

Chlorides as Cl- mg/L 516 818 512 935 643 561 567 634

Sulfates as SO4-2 mg/L 58 116 85 112 92 87 72 81

Fluoride as F- mg/L 0.66 0.61 0.59 0.67 0.7 0.64 0.66 0.56

Nitrates as NO3-3 mg/L 17 21 21 18 16 25 18 15

Phenol mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001

Cyanide as CN- mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001

Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Manganese as Mn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

Iron as Fe mg/L 0.23 0.26 0.19 0.29 0.25 0.23 0.21 0.23

Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

% Sodium -- 65.6 72.08 65.2 70.1 70.3 60.4 68.7 65.9



Table 3.20: Surface Water analysis of study area


Parameters Unit CONCENTRATION Method of Test

(Ref. to IS) Dabhasa

Pond

(SW1)

Padra

Pond

(SW2)

Bhoj

Pond

(SW3)

Ranu

Pond

(SW4)

Luna

Pond

(SW5)

Dabka

Pond

(SW6)

Tajpura

Pond

(SW7)

Mahi

River

(SW8)

pH pH Unit 7.3 7.6 7.5 7.2 7.7 7.1 7.4 7.8 3025(Part 11)

Conductivity Micro

mhos/cm

755 502 508 630 560 830 610 1225 ---

Turbidity NTU 15.3 10.9 9.6 11.7 12.5 10.7 7.9 15.6 3025(Part 10)

TDS mg/L 518 342 406 435 385 572 418 842 3025(Part 16)

Dissolved Oxygen mg/L 5.1 6.2 7.5 4.9 6.3 8.4 5.8 6.3 ---

Total Hardness as

CaCO3

mg/L 171 152 196 171 129 170 122 205 3025(Part 21)

Total Alkalinity mg/L 258 286 310 295 276 278 265 338 3025(Part 23)

Sodium as Na+ mg/L 186 123 142 159 141 185 160 295 3025(Part 45)

Potassium K+ mg/L 25 28 21 27 30 28 25 39 3025(Part 45)

Calcium Ca+2 mg/L 29 31 39 32 27 35 21 36 3025(Part 40)

Magnesium Mg+2 mg/L 24 18 24 22 15 20 17 28 3025(Part 46)

Chlorides as Cl- mg/L 203 108 137 155 109 225 152 382 3025(Part 32)

Sulfates as SO4-2 mg/L 28 18 29 32 24 27 31 46 3025(Part 24)

Nitrates as NO3-3 mg/L 9.5 10 11.3 7.8 9.5 10.2 11.3 12.7 3025(Part 34)

Phenol as CH3OH mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 3025(Part 43)

Cyanide as CN- mg/L <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 <0.001 3025(Part 27)

Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 37)

Cadmium as Cd mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 41)

Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 42)

Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 47)

Manganese as Mn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 59)

Iron as Fe mg/L 0.19 0.23 0.17 0.15 0.13 0.21 0.18 0.15 3025(Part 53)

Total Chromium mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 52)

Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 3025(Part 49)

Total Coliform MPN/ml 142 152 172 98 110 152 148 198 IS: 5401(P-I)



Table 3.21: Indian Standard Specification for Drinking Water

Sr. No.

Parameters Desirable Limit

Permissible Limit in the

Absence of Alternate

Source

I Essential Characteristics

1. Colour, Hazen Units, Max. 5 25

2. Odour Unobjectionable -

3. Taste Agreeable -

4. Turbidity, NTU, Max. 5 10

5. pH 6.5-8.5 No Relaxation

6. Total Hardness (as CaCO3) mg/l, Max. 300 600

7. Iron (as Fe) mg/l, Max. 0.3 1.0

8. Chlorides (as Cl) mg/l, Max. 250 1000

9. Residual Free Chlorine, mg/l, Min. 0.20* -

II Desirable Characteristics

10. Dissolved Solids, mg/l, Max. 500 2000

11. Alkalinity (as CaCO3), mg/l, Max. 200 600

12. Sulphate (as SO4) mg/l, Max. 200 400

13. Nitrate (as NO3) 45 100

14. Fluoride (as F) mg/l, Max. 1.0 1.5

15. Calcium (as Ca) mg/l, Max. 75 200

16. Magnesium (as Mg) mg/l, Max. 30 100

17. Copper (as Cu) mg/l, Max. 0.05 1.5

18. Manganese (as Mn) mg/l, Max. 0.1 0.3

19. Mercury (as Hg) mg/l, Max. 0.001 No Relaxation

20. Cadmium (as Cd) mg/l, Max. 0.01 No Relaxation

21. Selenium (as Se) mg/l, Max. 0.01 No Relaxation

22. Arsenic (As As) mg/l, Max. 0.05 No Relaxation

23. Cyanide (as CN) mg/l, Max. 0.05 No Relaxation

24. Lead (as Pb) mg/l, Max. 0.05 No Relaxation

25. Zinc (as Zn) mg/l, Max. 5 15

26. Aluminium (as Al) mg/l, Max. 0.03 0.2

27. Boron (as B) mg/l, Max. 1 5

28. Chromium (as Cr) mg/l, Max. 0.05 No Relaxation

29. Phenolic Compounds (as C6H5OH) mg/l,

Max.

0.001 0.002

30. Anionic Detergents (as MBAS) mg/l, Max. mg/l, Max.

0.2 1.0

31. Mineral Oil mg/l, Max. 0.01 0.03

32. Pesticides Absent 0.001

33. Radioactive Materials a. Alpha Emitters, Bq/I, Max.

b. Beta Emitters, Pci/I, Max

-

-

0.1

0.037

Note: * Applicable only when water is chlorinated

Source: IS: 10500, 2012



Table 3.22: Ambient Noise Levels in the Study Area


Sr.

No.

Locations Coordinates Ld/Ln Noise

Level

dB(A)

1 Project site (N1) 22°13'32.76"N

73° 1'13.01"E Ld 52.7

Ln 41.9

2 100 m West from the

site (N2)

22°13'30.48"N

73° 1'5.74"E

Ld 52.7

Ln 43.1

3 250 m South from the

site (N3)

22°13'22.58"N

73° 1'15.97"E

Ld 51.7

Ln 40.8

4 500 m North from the

site (N4)

22°13'51.53"N

73° 1'10.05"E

Ld 50.9

Ln 39.2

5 1000 m East from the

site (N5)

22°13'36.56"N

73° 1'51.78"E

Ld 53.7

Ln 43.4

6 Village Dabhasa (N6) 22°14'38.53"N

73° 2'11.02"E

Ld 52.7

Ln 41.2

7 Nr Bus stop Padra(N7) 22°14'30.19"N

73° 5'7.73"E

Ld 52.9

Ln 41.0

8 Village Ranu (N8) 22°12'30.40"N

73° 1'28.74"E

Ld 50.7

Ln 40.2

9 Village Bhoj (N9) 22°12'1.19"N

73° 0'9.68"E

Ld 51.8

Ln 40.3

Table 3.23

Ambient Air Quality Standards with respect to Noise

Zone Limits Leq, dB(A)

Day Time Night Time

Industrial 75 70

Commercial 65 55

Residential 55 45

Silence 50 40



Table 3.24: Soil Analysis of Study area


Sr.

No.

Parameters Unit Concentration

Project Site

(S1)

Dabhasa

(S2)

Padra

(S3)

Umaraya

(S4)

Dhobi

Kuwa (S5)

Ranu

(S6)

Bhoj

(S7)

Vishrampura

(S8)

1. pH (5%) Solution --- 7.8 7.2 7.9 7.5 7.3 7.5 7.4 7.8

3. Loss of Ignition % 7.5 6.3 6.8 8.9 10.2 9.2 8.5 7.3

4. Particle Size

Clay (<0.002 mm) % 16 20 18 18 20 20 19 24

Silt (0.002 to 0.075 mm) % 32 31 26 30 21 28 32 28

Sand (0.075 - 0.475 mm) % 29 28 32 32 33 27 24 25

Gravel (size > 4.75 mm) % 23 21 24 20 26 25 25 23

5. Water Holding Capacity % 42.1 40.9 40.8 40.3 41.1 40.4 40.6 41.9

6. Permeability cm/hr 2.96 3.12 1.98 3.05 3.14 3.15 3.12 3.15

7. Bulk Density g/cm3 1.43 1.41 1.42 1.43 1.42 1.39 1.44 1.46

8. Porosity % 42.1 42.9 42.5 42.1 42.5 43.7 41.7 40.8

9. Sodium Absorption Ratio Meq/

100 gm

5.99 3.97 4.55 4.2 3.67 5.52 4.95 5.37

10. Sodium mg/kg 629 578 559 510 573 692 589 626

11. Potassium mg/kg 156 163 173 175 142 185 163 126

12. Calcium mg/kg 497 406 615 556 797 629 559 363

13. Magnesium mg/kg 202 720 316 335 629 336 307 398

14. Chlorides mg/kg 678 622 679 689 850 888 795 727

15. Sulphates mg/kg 494S 480 466 428 421 437 494 429

16. Organic Matter mg/kg 4.95 2.07 2.91 2.65 2.33 1.85 2.02 2.42

17. Total Nitrogen mg/kg 282 230 49 214 83 198 193 207

18. Total Phosphorus mg/kg 146 132 36 188 98 134 185 171

19. Iron mg/kg 2.57 2.24 2.38 2.34 2.38 2.16 2.4 2.35

20. Manganese mg/kg 7.42 5.54 7.42 8.12 3.76 5.86 5.86 5.54

21. Cation Exchange Capacity meq/

100 gm

7.3 10.96 8.58 8.24 12.08 9.43 8.33 8.18



Table 3.25

Floral Diversity

(A) Trees

Scientific Name Family Vernacular Name

Acacia Nilotica Fabaceae Bawal

Acacia Tortilis Fabaceae Israeli Bawal

Ailanthus Excelsa Simaroubiaceae Mahanimb

AlangiumSalvifolium Alangiaceae Ankol

AlbiziaLebbeck Fabaceae Siras

Azadirachtaindica Meliaceae Neem

Borassusflabellifer Arecaceae Tad

Calotropisprocera Asclepiadaceae Akauwa

CommiphoraMukul Burseraceae Guggal

CordiaDichotoma Ehretiaceae Gundi

Delonixelata Caesalpiniaceae Gulmohar

Emblicaofficinalis Euphorbiaceae Amla

Eucalyptus Tereticornis Myrtaceae Nilgiri

Ficusbengalesis Moraceae Vad

Ficusmicrocarpa Moraceae Banyan

Ficusreligiosa Moraceae Pipal

MangiferaIndica Anacardiaceae Ambo

ManilkaraZapota Sapotaceae Chikoo

Moringaoleifera Moringaceae Sargvo

Phoenix Sylvestris Arecaceae Khajoor

Pithecellobiumdulce Fabaceae Gorasamli

Sapindusemarginatus Sapindaceae Aritha

Syzygiumcumini Myrtaceae Jamun

TamarindusIndica Fabaceae Amli

Tectonagrandis Verbenaceae Sagwan

TerminaliaCatappa Combretaceae Almond

ZiziphusMauritiana Rhamnaceae Bor

(B) Shrubs


Acacia Caesia Fabaceae Palinja

Acacia Catechu Mimosoideae Khair

Adhatodavasica Acanthaceae Adusa

Annonasquamosa Annonaceae Sitafal

AzimaTetracantha Salvadoraceae Piludi

Calotropisprocera Asclepiadaceae Aak

Carica Papaya Caricaceae Papaya

Cassia Auriculata Caesalpiniaceae Anwal

DaturaStramonium Solanaceae Datura

Euphorbia Neriifolia Euphorbiaceae Thor



LawsoniaInermis Lythraceae Hina

Nariumindicum Apocynaceae Karne

Ocimum Sanctum Lamiaceae Tulsi

Ricinuscommunis Euphorbiaceae Arandi

Rosa Chinensis Rosaceae Rose

SennaAuriculata Fabaceae Avaram

ZizyphusMauritiana Rhamnaceae Bordi

(C) Herbs


Adhatodavasica Acanthaceae Adusa

AlysicarpusRugosus Fabaceae Chainpea

AmaranthusViridis Amaranthaceae Amaranth

AnisomelesIndica Lamiaceae Indian Catmint

Annonasquamosa Annonaceae Sitafal

BiophytumReinwardii Oxalidaceae Lajwanti

Carica Papaya Caricaceae Papaya

Croton Bonplandianum Euphorbiaceae Tulsi

Daturametel Solanaceae Datura

DesmostachyaBipinnata Poaceae Daabh

EchinopsEchinatus Asteraceae Shuliyo

Euphorbia Tirucalli Euphorbiaceae Saptala

Jatrophagossypifolia Euphorbiaceae Ratanjyot

Lantana Camara Verbenaceae Raimunia

Nariumindicum Apocynaceae Karne

Ocimum Sanctum Lamiaceae Tulsi

Pedalium Murex Pedaliacae KadvaGokhru

PhyllanthusAmarus Euphorbiaceae Jar-Amla

Punicagranatum Puniacaceae Dadam

Ricinuscommunis Euphorbiaceae Arandi



Table 3.26

Faunal Biodiversity

(A) List of Terrestrial & Aquatic Birds in the Study Area

Scientific Name Common Name

AcridotheresGinginianus Bank Myna

AcridotheresTristis Common Myna

AlcedoAtthis Kingfisher

AnasPoecilorhyncha Duck

CetntropusSinensis Coucal

Columba Livia Rock Pigeon

CorvusCorax Common Raven

CorvusSplendens House Crow

DendrocittaVagabunda Rufoustreepie

DicrurusMacrocercus Black Drongo

EremoptrixGrisea Sparrow-Lark

EudynamysScolopacea Asian Koel

MotacillaMaderaspatensis White-Browed Wagtail

Nectarinia Minima Sunbird

Passer Domesticus Sparrow

PavoCristatus Peafowl

PsittaculaKrameri Parakeet

PycnonotusCafer Bulbul

SaxicoloidesFulicata Indian Robin

SpilopeliaSenegalensis Dove

StreptopeLiachinensis Spotted Dove

TurdoidesCaudatus Babbler

(B) List of Mammals and Reptiles in the Study Area

Scientific Name Common Name

AhaetullaNasuta Green Vine Snake

BungarusCaeruleus Common Krait

CalotesVersicolor Garden Lizard

Canis Lupus Familiaris Indian Pariah Dog

FelisChaus Jungle Cat

FunambulusPennantii Palm Squirrel

HerpestesEdwardsii Mongoose

MusBooduga Field Mouse

NajaNaja Cobra

Presbytis Entellus Monkey

RattusRattus Rat

Semnopithecus Entellus Langur

VulpesBengalensis Fox



Table 3.27

Traffic Survey

TRAFFIC SHEET

LOCATION Padra-Jambusar Road

TIME 09.00 to 10.00 DATE 21/12/18

TOTAL PCU calculation Total PCU/hr

BUSES/TRUCKS* 52 PCU x 3 156

CARS/VANS 270 PCU x 1 270

MOTORCYCLES / BICYCLES 318 PCU x0.5 159

Total 585

TIME 18.00 to 19.00 DATE 21/12/18

TOTAL PCU calculation Total PCU/hr

BUSES/TRUCKS* 61 PCU x 3 183

CARS/VANS 249 PCU x 1 249

MOTORCYCLES / BICYCLES 342 PCU x0.5 171

Total 603

Note: *Mini-bus, Chartered Bus, School Bus, have been collectively

classified as Buses. Trucks and Tankers have been collectively classified as

Trucks.

Existing Traffic Scenario and Level of Services

The road from Padra to Jambusar Road is two track lane with divider, all types of

vehicles move on the road.

Capacity of road = 1500 PCU‟s/hr

Total Volume during Peak Hours = 603

Existing Volume/Capacity ratio = 603/1500= 0.402

The level of service is “C” that is Good

LEVEL OF SERVICE

Sr. No.

Existing Volume/Capacity Ratio

Level of Services

1. 0.0 to 0.2 “A” (Excellent)

2. 0.2 to 0.4 “B” (Very Good)

3. 0.4 to 0.6 “C” (Good)

4. 0.6 to 0.8 “D” (Fair)

5. 0.8 to 1.0 “E” (Poor)



Table 3.28 Land Use Pattern

Name of Village

Total Area of the

Village (ha)

Irrigated by

source (ha)

Un-irrigated

(ha)

Cultivable waste

(ha)

Area not available for

cultivation (ha)

Jhilod 290.2 140 51 8.2 31

Narpura 191 147.1 0 0 30.2

Sankhyad 409.5 288.4 0 0 96.8

Chamara 940.5 350 42 299 28.4

Jaspur 1575 442.2 533 0 130.4

Raypura 449 80 220 67.2 50

Bamangam 1474.2 1221.5 0 0.6 112.3

Devapura 234 181.1 0 0 27

Gambhira 1567.1 583 712 0 127

Umaraya 539.2 300 20 2 45

Tajpura 332.7 200.4 98 0 2.1

Luna 447.5 200 108.4 1.8 3.2

Ekalbara 593 250 115 0 56

Mujpur 888.8 345 300 0 65

Sultanpura 299 65.3 66.2 0 8.7

Dabka 1906.3 650.8 363.3 150.3 100

Pavda 563.2 250.2 180.4 21.4 5.8

Chokari 1380.1 380.1 98.9 10.3 0

Narsipura 266.9 195 26 2 28

Mahuvad 482.5 390.2 31.1 0 6.4

Dabhasa 1199.1 765.8 216.6 0 39.3

Sangma 329.2 215 68 0 20

Sokhdakhurd 446.8 210.1 220.6 4.1 1.9

Darapura 407.6 300 29.9 0 1.7

Ghayaj 737.5 540 104 10 11

Latipura 350.4 248.2 67.8 0 1.5

Ranu 858 568 194 0 40

Dhobikuwa 196.9 129 50 0 0.2

Vadu 874 480 330.7 2.1 9.2

Somjipura 252.2 197.1 24.1 1.8 1.3

Majatan 456.6 77.8 336.7 0 5.3

Sandha 336.7 280 34 16.6 2.1

Chitral 371.7 229 98 0 3

Lola 119.7 74 24 0 13

Muval 781.1 375 296 9 2

Vishrampura 234.9 170 40 1 0

Karnakuva 152.8 105 33.8 0 10.4

Bhoj 1153 710 306.4 123.2 0

Pipli 399.9 190 163 0 41.9

Sejakuva 369.8 15 171.7 0 40.7

Goriyad 614.4 414.4 92.9 4.2 44.2

Sareja 190.4 40 144.6 0.2 0.6

Saras vani 1089.6 591 356.2 20 7

Amla 1021.6 565.5 375 0 53



Name of

Village

Total Area

of the Village

(ha)

Irrigated

by source

(ha)

Un-

irrigated (ha)

cultivable

waste (ha)

Area not

available for cultivation

(ha)

Sadhi 1400.1 775 511 0 72

Vadadla 263.6 150 61 0 3

Anti 863.1 453.1 315.6 0 9.8

Rajupura 258.1 132 88 0 28

Jalalpur 426.2 255 110 0 45

Kalyankui 213.8 95 93 0 12

Ambada 761.6 367 302 0 50

Bhadara 384.8 70 260 0 17

Gayapura 195.3 40 130 2 10



Table: 3.29 Summary of Socio-economic status of Study area (Demography)

Name of

the Village/

Town/Ward

No. of

Occupied

Residential

House

Total Population

(Including

institutional and

houseless

population)

Literates Total main

Workers

Marginal

Workers

Cultivators Agricultur

al Laborer

Non-Worker

P M F M F M F M F M F M F M F

Jhilod 406 2061 1101 960 834 598 562 348 42 166 165 7 292 168 497 446

Narpura 323 1563 830 733 630 406 381 314 17 70 151 3 136 193 432 349

Sankhyad 664 3181 1661 1520 1275 862 821 341 134 379 569 26 170 255 706 800

Chamara 1020 5005 2620 2385 2047 1352 1487 436 108 449 528 20 746 191 1025 1500

Jaspur 1530 7658 3996 3662 3145 2425 2213 522 103 83 546 50 1080 402 1680 3057

Raypura 1085 5619 2879 2740 2380 2126 1530 392 179 75 484 23 416 306 1170 2273

Bamangam 1636 8201 4288 3913 3399 2366 2267 595 276 475 971 34 890 335 1745 2843

Devapura 142 631 335 296 255 177 134 35 73 124 102 4 17 1 128 137

Gambhira 1595 7939 4202 3737 3460 2461 2233 807 273 544 723 26 1111 232 1696 2386

Umaraya 775 4115 2146 1969 1621 1111 1072 45 151 85 237 4 304 25 923 1839

Tajpura 360 1720 897 823 733 597 545 121 25 37 177 2 246 114 327 665

Luna 521 2739 1430 1309 1087 833 849 269 17 42 248 10 261 132 564 998

Ekalbara 917 4435 2308 2127 1770 1386 1160 123 89 106 497 31 396 48 1059 1898

Mujpur 1923 9410 4887 4523 3759 2559 2259 445 538 1571 583 13 1154 347 2090 2507

Sultanpura 167 892 462 430 307 258 175 9 11 5 31 1 134 6 276 416

Dabka 1545 7345 3963 3382 2883 1984 2108 414 141 309 165 18 1528 354 1714 2659

Pavda 453 2113 1130 983 852 609 576 141 107 236 188 5 315 126 447 606

Chokari 1811 8884 4706 4178 3336 2170 2738 239 253 1417 535 25 1776 116 1715 2522

Narsipura 729 3447 1747 1700 1410 1090 1066 481 5 2 233 12 595 451 676 1217

Mahuvad 534 2564 1336 1228 1024 759 635 60 109 32 126 5 198 23 592 1136

Dabhasa 1708 8337 4322 4015 3319 2570 2381 243 163 155 586 13 983 144 1778 3617

Sangma 664 3096 1587 1509 1228 979 879 172 83 54 199 14 413 115 625 1283

Sokhdakhurd 462 2139 1099 1040 955 760 713 127 19 6 207 7 248 90 367 907

Darapura 666 3032 1589 1443 1255 1026 836 163 106 21 93 8 384 128 647 1259

Ghayaj 594 2667 1399 1268 1126 888 878 344 10 5 140 3 425 319 511 919



Latipura 592 2702 1427 1275 1207 920 855 139 32 81 258 12 372 108 540 1055

Ranu 1188 6092 3208 2884 2365 1792 1809 283 103 383 307 8 1032 240 1296 2218

Dhobikuwa 710 3392 1739 1653 1395 1108 713 76 218 133 232 12 310 45 808 1444

Vadu 1916 9626 5027 4599 3887 3024 2702 335 169 213 1040 36 1073 277 2156 4051

Somjipura 518 2480 1292 1188 1020 742 748 180 4 2 109 9 322 158 540 1006

Majatan 629 3288 1704 1584 1301 972 847 251 91 102 230 28 417 144 766 1231

Sandha 531 2600 1349 1251 1024 740 785 156 10 237 287 2 464 152 554 858

Chitral 351 1728 885 843 683 512 455 59 58 66 128 4 231 49 372 718

Lola 270 1535 805 730 637 471 502 41 8 5 238 10 166 26 295 684

Muval 903 4164 2177 1987 1685 1271 1265 207 8 18 344 18 418 149 904 1762

Vishrampura 606 2997 1538 1459 1242 975 859 375 37 147 238 20 375 199 642 937

Karnakuva 283 1289 667 622 516 372 389 185 7 99 88 2 271 179 271 338

Bhoj 1403 7072 3658 3414 2641 1888 2035 394 90 60 622 9 1198 323 1533 2960

Pipli 406 2046 1051 995 837 659 582 73 2 4 87 4 440 66 467 918

Sejakuva 512 2343 1212 1131 892 653 669 135 16 11 71 6 377 112 527 985

Goriyad 429 1943 1003 940 791 620 601 29 11 256 143 0 205 10 391 655

Sareja 2 10 6 4 2 0 3 0 0 0 0 0 3 0 3 4

Saras vani 511 2305 1195 1110 841 622 748 182 11 7 161 10 401 149 436 921

Amla 449 2129 1063 1066 861 811 570 39 14 2 190 9 281 23 479 1025

Sadhi 819 3794 2007 1787 1601 1190 1086 87 85 30 336 4 503 64 836 1670

Vadadla 503 2303 1194 1109 943 729 674 67 41 8 123 18 177 32 479 1034

Anti 837 5055 2602 2453 2004 1648 1266 139 89 18 415 15 673 106 1247 2296

Rajupura 277 1185 612 573 404 310 405 30 2 1 103 6 240 15 205 542

Jalalpur 434 2069 1064 1005 852 706 668 40 19 40 230 6 294 24 377 925

Kalyankui 141 627 326 301 273 219 132 9 70 42 78 4 2 1 124 250

Ambada 244 1021 561 460 453 263 364 157 4 3 95 1 234 150 193 300

Bhadara 137 730 365 365 286 217 223 21 1 1 80 2 59 13 141 343

Gayapura 139 581 308 273 227 153 199 23 7 85 55 2 113 15 102 165



Table 3.30: Summary of Socio-economic status of Study area (Amenities)

Name of

Village

Educational

Facility

Medical

Facility

Drinking

Water

Facility

Communication

(Post

or Telegraph)

Transportation

Facility

(Bus etc.)

Approach to

Village

Nearest

town

Power

Supply

Jhilod P None of within 10

Km

T,HP,TW,

TK

PO(5-10),SPO(5-

10),PH,PCO

BS,RS(5-10) PR,KR,FP Anklav EA

Narpura PP(5-

10),P(2),S(5-

10),SS(<5)

PHC(5-10),PHS(5-

10), MCW(5-10),

TBC(5-10),D(5-10),

VH(5-10),FWC(5-10)

T,HP,TW PO(5-10),

SPO(5-

10),PH,PCO

BS,RS(5-10) SH(5-

10),PR,KR(5-

10),WBM(5-

10),FP

Anklav EA

Sankhyad P(3),S(<5) PHS T,HP,TW,

R/C

PO(<5),SPO(<5)

,PH,PCO(5-10)

BS,RS(5-10) PR,KR,FP Anklav EA

Chamara PP(5-

10),P(2),S,SS

(<5),ASC(5-

10)

PHC(5-10), PHS,

MCW(5-10), TBC(5-

10), D(5-10), VH(5-

10), FWC(5-10)

T,W,HP,TW PO(<5),SPO,PH,

PCO

BS,RS(<5) SH(5-

10),PR,KR,W

BM(5-10),FP

Anklav EA

Jaspur PP(5-

10),P,S,SS,A

SC(5-10)

PHC(5-10),PHS,

MCW(5-10),TBC(5-

10),D(5-10),VH(5-

10),FWC(5-10)

T,W,HP,

TW,R/C

PO(5-

10),SPO,PH,PCO

BS,RS(5-10) NH(5-

10),SH(5-

10),PR,KR,W

BM(5-10),FP

Padra EA

Raypur PP(5-

10),P,S(<5),

SS(<5),ASC(

5-10)

PHC(<5),PHS,

MCW(<5),TBC(5-

10), D(5-10), VH(5-

10), FWC(<5)

T,HP,TW PO(<5),SPO,PH(

<5),PCO(<5)

BS,RS(<5) NH(<5),SH(

<5),PR,KR(<

5),WBM(5-

10),FP

Vadodara EA

Bamangam P(6),S,SS PHC,PHS(2) T,HP,TW PO,PH,PCO BS PR,KR,FP Anklav EA

Devapura PP(5-

10),P,S(5-

10),SS(<5)

PHC(5-10), PHS(5-

10), MCW(5-10),

TBC(5-10), D(5-10),

VH(5-10), FWC(5-

10)

T,HP,TW PO(<5),SPO(<5)

,PH,PCO(5-10)

BS,RS(<5) SH,PR,KR(5-

10),WBM(5-

10),FP

Anklav EA

Gambhira P(4),S,SS(2) PHS T,HP,TW PO(<5),SPO,PH,

PCO

BS SH,PR,FP Anklav EA

Umaraya PP(5-

10),P,S(<5),

ASC(5-10)

PHC(5-10),PHS,

MCW(5-10),TBC(5-

10),D(<5),VH(5-10),

FWC(5-10)

T,W,HP,TW

,R/C

PO(5-

10),SPO,PH,PCO

(5-10)

BS PR,KR,

WBM(5-10),

FP

Padra EA

Tajpur PP(<5),P,ASC

(<5)

PHC(<5),PHS,MCW(

<5),TBC(<5),D(<5),

T,TW,TK PO(<5),SPO,PH,

PCO(<5)

BS,RS(<5) NH(5-10),

SH(5-10),

Padra EA



Name of

Village

Educational

Facility

Medical

Facility

Drinking

Water

Facility

Communication

(Post

or Telegraph)

Transportation

Facility

(Bus etc.)

Approach to

Village

Nearest

town

Power

Supply

VH(<5),FWC(<5) PR,KR(<5),W

BM(<5),FP

Luna PP(<5),P,S(5

-10),SS(5-

10),ASC(<5)

PHC(<5),PHS(<5),M

CW(<5),TBC(<5),

D(<5),VH(<5),

FWC(<5)

T,W,TW,TK PO(<5),SPO,PH,

PCO(<5)

BS NH(5-

10),SH(5-

10),PR,KR(<

5),WBM(<5),

FP

Padra EA

Ekalbara PP(5-

10),P(2),S(<

5),SS(5-

10),ASC(5-

10)

PHC(5-10), PHS(5-

10), MCW(5-10),

TBC(5-10), D,

VH(<5), FWC(<5)

T,HP,R/S,

TK

PO(5-

10),SPO,PH,

PCO(<5)

BS,RS(5-10) SH,PR,KR,W

BM(5-10),FP

Padra EA

Mujpur PP(5-

10),P(2),S(<

5),ASC(5-10)

PHC,PHS, MCW(5-

10), TBC(5-10), D(5-

10), VH(5-10),

FWC(5-10)

T,W,HP,

TW,R/C,TK

PO(5-10),

SPO,PH, PCO

BS SH,PR,

KR(<5),

WBM(<5), FP

Padra EA

Sultanpura P,S(<5),SS(5

-10)

PHC(5-

10),PHS(<5),MCW(5

-10),VH(5-10)

T,W,HP,TW

,R/C,TK

PO(<5),

SPO(<5), PH,

PCO

BS,RS(5-10) SH(5-

10),PR,KR,W

BM(5-10),FP

Padra EA

Dabka P(2),S PHC(5-

10),PHS,MCW(5-

10),VH(5-10)

T,W,HP,

TW,R/C,

SPO,PH,PCO BS SH(5-

10),PR,KR,FP

Padra EA

Pavda P,S(5-10) PHC W,HP,TW,

R/C,TK

PO(<5),SPO(<5)

,PH,PCO

BS,RS(5-10) NH(5-10),

SH(5-10),

PR,KR,WBM,

FP

Padra EA

Chokari PP(5-

10),P(3),S(5-

10)

PHC(5-

10),PHS,MCW(5-

10),D,VH(5-10)

T,W,HP,

TW,R/C,TK

PO(<5),SPO,PH,

PCO

BS PR,KR(5-10),

WBM(5-10),

FP

Padra EA

Narsipura P,S(<5) PHC(<5),PHS(<5),M

CW(<5),D(<5),VH(<

5),FWC(<5)

T,HP,TK SPO BS,RS(5-10) NH(5-10),

SH(5-10),

PR,KR,WBM,

FP

Padra EA

Mahuvad PP,P,S,SS(5-

10),ASC(5-

PHC(<5),PHS,MCW,

TBC(5-10), D(5-

T,W,HP,

TW,R/C

PO(5-10), SPO,

PH,PCO

BS,RS(<5) SH,PR,KR,W

BM(5-10),FP

Padra EA



Name of

Village

Educational

Facility

Medical

Facility

Drinking

Water

Facility

Communication

(Post

or Telegraph)

Transportation

Facility

(Bus etc.)

Approach to

Village

Nearest

town

Power

Supply

10) 10),VH(<5), FWC(5-

10)

Dabhasa PP(<5),P(2),

S,SS(5-

10),ASC(<5)

PHC(<5)PHS,MCW,T

BC(<5),D(<5),VH(<

5),FWC(<5)

T,W,HP,

TW,TK

PO(<5),SPO,PH,

PCO

BS NH(5-10),

SH,PR,KR,W

BM (<5),FP

Padra EA

Sangma PP(<5),P,S(<

5),SS(<5),AS

C(<5)

PHC(<5),PHS,MCW(

<5),TBC(<5),D(<5),

VH(<5), FWC(<5)

T,W,HP,

TW,R/C,TK

PO(<5),SPO,PH,

PCO

BS,RS(<5) NH(5-10),

SH,PR,

KR(<5),

WBM(<5), FP

Padra EA

Sokhdakhurd PP,P,S(<5),S

S(<5),ASC(<

5)

PHC(<5),PHS,

MCW(<5),TBC(<5),

D(<5),VH(<5), FWC

(<5)

T,W,HP,

TW,TK

PO(<5),SPO(<5)

,PH,PCO

BS NH(<5),SH(

<5),PR,KR(<

5),WBM(<5),

FP

Padra EA

Darapura PP(<5),P(2),

S(2),SS(<5),

ASC(<5)

PHC(<5),PHS(<5),

MCW(<5),TBC(<5),

D(<5),VH(<5),

FWC(<5)

T,W,HP,

TW,TK

PO(<5),SPO,PH,

PCO

BS,RS(<5) NH(<5),SH(

<5),PR,KR,W

BM(<5),FP

Padra EA

Ghayaj PP(<5),P,S(<

5),SS(<5),AS

C(<5)

PHC(<5),PHS(<5),

MCW(<5),TBC(<5),

D(<5),VH(<5),

FWC(<5)

T,W,HP,

TW,R/C,TK

PO(<5),SPO,PH,

PCO

BS,RS(<5) SH,PR,KR,W

BM(<5),FP

Padra EA

Latipura PP(<5),P,S,S

S(<5),ASC(<

5)

PHC(<5),PHS(<5),

MCW(<5),TBC(<5),

D(<5),VH(<5),

FWC(<5)

T,W,HP,TW PO(<5),SPO,PH,

PCO(<5)

BS,RS(<5) SH(<5),PR,K

R,WBM,FP

Padra EA

Ranu PP(5-10),

P(3), S,

SS(5-10),

ASC(5-10)

PHC(5-10),PHS,

MCW(<5), TBC(5-

10), D(5-10),VH(5-

10),FWC(5-10)

T,W,HP,TW PO,SPO(<5),PH,

PCO

BS,RS NH(5-10),

SH(5-10),

PR,KR(<5),W

BM(<5),FP

Padra EA

Dhobikuwa P,S(<5) PHC(<5),PHS(<5),

MCW(<5),

TBC(5-10), D(5-10),

VH(<5),FWC(5-10)

T,W,HP,

TW,R/C

PO(5-

10),SPO(<5),PH,

PCO

BS SH,PR,KR,W

BM(5-10),FP

Padra EA

Vadu PP,P(3),S PHC,PHS,MCW,

D(<5),VH

T,HP,TW SPO,PH,PCO BS,RS(<5) NH(<5), SH,

PR,KR,

Padra EA



Name of

Village

Educational

Facility

Medical

Facility

Drinking

Water

Facility

Communication

(Post

or Telegraph)

Transportation

Facility

(Bus etc.)

Approach to

Village

Nearest

town

Power

Supply

WBM(<5), FP

Somjipura P,S(<5) PHC(<5),PHS(<5),

MCW(<5),VH(<5)

T,HP,TW,

TK

PH,PCO(5-10) BS NH(5-

10),PR,KR,W

BM(<5),FP

Padra EA

Majatan P,S(<5) PHC(<5),PHS(<5),M

CW(<5),D(<5),

VH(5-10),FWC(5-10)

T,W,HP,

TW,TK

PO(<5),SPO,PH,

PCO(<5)

BS,RS(5-10) NH(5-10),

SH(5-10),

PR, KR(5-

10),WBM(5-

10), FP

Padra EA

Sandha PP(<5),P,S(<

5),SS(<5),AS

C(<5)

PHC(<5),PHS(<5),M

CW(<5),D(5-10),

VH(5-10),FWC(5-10)

T,W,TK PO(5-10),

SPO,PH,PCO

BS,RS(5-10) NH(5-

10),SH(<5),

PR,KR,WBM,

FP

Padra EA

Chitral P(2),S(<5),S

S(<5)

PHC(5-10), PHS,

MCW(<5)

T,HP,TW SPO,PH,PCO(<5) BS,RS(5-10) NH(<5),

SH(<5),PR(<

5),KR(<5),W

BM(<5),FP

Padra EA

Lola P,S(<5) PHC(5-10),PHS(5-

10),MCW(5-10),

D(5-10), VH(5-

10),FWC(5-10)

T,HP,TW,

TK

PO(<5),PH BS,RS(5-10) NH(<5),SH,P

R(<5),KR,WB

M(<5),FP

Padra EA

Muval P(3),S PHC(<5),PHS(<5),D,

VH(5-10),FWC(5-10)

T,W,HP,TW

,TK

PO(<5),SPO,PH,

PCO

BS,RS(<5) PR,KR,FP Padra EA

Vishrampura P,S(<5),SS(5

-10)

PHS, MCW(5-

10),D(5-10),VH(5-

10)

T,TW,TK PO(5-10), SPO,

PH,PCO(5-10)

BS,RS(5-10) SH,PR(5-

10),KR(5-

10),WBM(5-

10),FP

Padra EA

Karnakuva P,S(<5) PHS,MCW(<5),

D(<5),VH(<5),

FWC(<5)

T,HP,TW PO(<5),

SPO(<5), PH,

PCO

BS SH,PR,KR,W

BM,FP

Padra EA

Bhoj P(3),S,SS(5-

10)

PHC(5-10), PHS,

MCW(<5), D(<5),

VH(<5), FWC(<5)

T,HP,TW,

R/C

SPO,PH,PCO BS,RS SH(<5),PR,

KR(<5),

WBM(<5),FP

Padra EA

Pipli PP(5-10), P,

S(<5),

PHC(<5),PHS(<5),

MCW(<5),TBC(5-

T,W,HP,

TW,TK

PO(5-

10),SPO,PH,PCO

BS,RS(<5) NH(5-10),

SH(5-10),

Padra EA



Name of

Village

Educational

Facility

Medical

Facility

Drinking

Water

Facility

Communication

(Post

or Telegraph)

Transportation

Facility

(Bus etc.)

Approach to

Village

Nearest

town

Power

Supply

SS(<5),

ASC(5-10)

10), D(5-10),

VH(<5), FWC(5-10)

PR,KR(<5),W

BM(5-10),FP

Sejakuva PP(5-

10),P(2),S,

SS, ASC(5-

10)

PHC(<5),PHS,

MCW(<5),TBC(5-

10),D(5-10),VH(5-

10),FWC(5-10)

T,W,TW,TK PO(5-

10),SPO,PH,PCO

BS SH(5-

10),PR,KR,W

BM(5-10),FP

Padra EA

Goriyad PP(<5),P,S(5

-10),SS(5-

10),ASC(<5)

PHC(<5),PHS,MCW(

<5),TBC(<5),D(<5),

VH(<5),FWC(<5)

W,TW,TK PO(<5),SPO,PH,

PCO

BS SH,PR,KR,W

BM(<5),FP

Padra EA

Sareja PP(<5),P(<5)

,ASC(<5)

PHC(<5),PHS(<5),

MCW(<5),TBC(<5),

D(<5),VH(<5),

FWC(<5)

T,W,HP,TW PO(<5),SPO(<5)

,PH,PCO

BS NH(5-10),

SH(5-10),PR,

KR(<5),WBM

(5-10),FP

Padra EA

Saras vani PP(5-

10),P,S,SS(<

5),ASC(5-10)

PHC(<5),PHS,MCW,

TBC(<5),D(<5),

VH(<5),FWC(<5)

T,TW,TK PO(<5),SPO,PH,

PCO(<5)

BS,RS(<5) NH(5-10),

SH,PR,

KR(<5),

WBM(<5),FP

Padra EA

Amla PP(5-

10),P,S(<5),

SS(<5),ASC(

5-10)

PHC(<5),PHS,

MCW(5-10),TBC(5-

10),D(<5),

VH(<5),FWC(5-10)

T,W,HP,

TW,TK

PO(5-

10),SPO,PH,PCO

BS,RS(5-10) PR,KR(5-

10),WBM(5-

10),FP

Padra EA

Sadhi PP(5-

10),P(5),S,SS

,ASC(5-10)

PHC,PHS,MCW,

TBC(5-10),D,VH(5-

10),FWC(5-10)

T,W,HP,

TW,TK

PO(5-

10),SPO,PH,PCO

BS NH(5-

10),SH(5-

10),PR,KR,W

BM(<5),FP

Padra EA

Vadadla PP(5-

10),P,S(5-10)

,SS(5-10),

ASC(5-10)

PHC(5-10),PHS(5-

10),MCW(5-10),

D(5-10),VH(5-

10),FWC(5-10)

T,W,HP,

TW,R/C,TK

PO(5-

10),SPO,PH,PCO

BS,RS(<5) NH(5-

10),SH(5-

10),PR,KR,W

BM(<5),FP

Padra EA

Anti PP(5-10),

P(2), S(<5)

, SS(<5),

ASC(5-10)

PHC(<5),PHS(<5),M

CW(<5),TBC(5-

10),D(5-10),VH(5-

10),FWC(5-10)

T,TK PO(<5),SPO,PH,

PCO

BS,RS(5-10) NH(5-10),

SH(5-10),

PR, KR,

WBM(<5), FP

Padra EA

Rajupura P,S(5-10) D(5-10),VH(5-

10),FWC(5-10)

T,W,HP,

TW,TK

PO(<5),SPO,PH,

PCO

BS,RS(<5) NH(5-10),

SH(5-10),

Padra EA



Name of

Village

Educational

Facility

Medical

Facility

Drinking

Water

Facility

Communication

(Post

or Telegraph)

Transportation

Facility

(Bus etc.)

Approach to

Village

Nearest

town

Power

Supply

PR(5-10),

KR,

WBM(<5), FP

Jalalpura P,S(5-

10),SS(5-10)

PHC(<5),PHS,MCW(

<5),D(<5),VH(5-

10),FWC(5-10)

T,R/C,TK PO(<5),SPO,PH BS,RS(<5) NH(<5),

SH(<5), PR,

KR,

WBM(<5), FP

Padra EA

Kalyankui P PHS(<5),MCW(<5) T,W,HP,

TW,R/C,TK

PO(<5),SPO(5-

10),PH(<5),

PCO(<5)

BS,RS(<5) NH(5-10),

SH(5-10),

PR, KR,

WBM(<5),FP

Padra EA

Ambada P,S PHC(5-10),PHS,D(5-

10),FWC(5-10)

T,W,HP,

TW,TK

PO(5-

10),SPO,PH,

PCO(<5)

BS,RS(<5) NH(5-10),

SH(5-10),

PR,KR,WBM(

5-10),FP

Padra EA

Bhadara P,S(<5),SS(<

5)

PHC(<5),PHS(<5),D(

5-10),VH(5-

10),FWC(5-10)

T,W,HP,

TW,TK

SPO,PH,PCO BS PR,KR, WBM

(5-10),FP

Padra EA

Gayapura PP(5-10), P,

S(5-10),

SS(5-10),

ASC(5-10)

PHC(5-10), PHS(5-

10), MCW(5-

10),TBC(5-10), D(5-

10),VH(<5), FWC(5-

10)

T,W,HP,TW PO(5-10),

SPO(5-10),PH,

PCO(5-10)

BS,RS(<5) NH(5-10),

SH(5-10),

PR,KR,

WBM(<5),FP

Padra EA



Abbreviations: Educational

PP - Preprimary School

P - Primary School S - Secondary School

SS - Senior Secondary School ASC - College of Arts, Science & Commerce

Medical Facility PHC - Primary Health Centre PHS - Primary Health Sub-Centre

MCW - Maternity & Child Welfare Centre TBC - T.B Clinic

FWC - Family Welfare Centre

D - Dispensary

VH - Veterinary Hospital Drinking Water

T - Tap Water HP - Hand Pump

TW - Tube well Water W - Well Water

TK - Tank water R/C - River/Canal

Post and Telegraph

PO - Post Office

PH - Telephone Connection SPO - Sub Post Office

PCO - Public Call Office

Transportation BS - Bus

RS - Railway Station

Approach to Village NH - National Highway

SH - State Highway PR - Pucca Road

KR - Kutccha Road WBM - Water bound macadam

FP - Footpath

Power Supply

EA - Electricity for all Purposes



Figure 3.7

Location of AAQM station

Indicating AAQM stations

Project site



Figure 3.8

Wind Rose diagram



Figure 3.9

Water sampling Locations

Indicating Ground Water sampling location

Indicating Surface Water Sampling location

Project site



Figure 3.10

Noise monitoring locations

Indicating Noise Monitoring location

Project site



Figure 3.11

Soil Sampling Locations

Indicating locations of Soil sampling

Project site



Figure 3.12 Toposheet of location with site location map of 10 km

radius (1:50,000 scale)



Chapter-4

Anticipated Environmental Impacts &

Mitigation Measures

4.1 GENERAL

Environmental Impact can be defined as any change in environmental

conditions which may be adverse or beneficial; occurred due to action or

set of actions under consideration. It can be assessed by identifying the

sources of the impact and predicting the same. The identification of

environmental impacts has been made by co-relating the relationship

between project activity and environmental parameters. As a part of

present EIA study, anticipated environmental impacts associated with the

project activity of the unit have been identified. The project activities are

usually divided into two phases: Construction Phase and Operation Phase.

For evaluation of impacts due to proposed activities, baseline data has

been utilized. Changes in the environmental parameters & their impact in

terms of short term or long term, positive or negative, reversible &

irreversible are identified & predicted.

The next step is prediction of impacts, which is an important component

in environmental impact assessment process. Several techniques and

methodologies are in vogue for predicting the impacts due to proposed

industrial development on physical, chemical, biological and socio-

economic components of environment. Such predictions delineate

contribution in existing baseline condition for the proposed project. The

additional impacts due to proposed activities are analyzed by keeping in

mind the baseline status. This helps to assess the assimilative capacity of

the environment and in turn the gravity of the impacts. Based on the

identification & prediction of the nature of impact, it can be evaluated

qualitatively and quantitatively.

In this chapter, the effect due to construction & operational activity of the

proposed project is explained.



4.2 IDENTIFICATION OF IMPACT

This chapter deals with the assessment of project impacts on

environment. Mitigation measures are suggested to minimize the likely

negative impacts. The network method (Cause - effect) was adopted to

identify potential impact of the proposed activity. It includes stepwise

study of relationship between an activity and its environmental

parameters. This method involves in the “Road Map” type of approach to

the identification of second & third order effect. The basic idea is to

account for the project activity & identify the type of impact that could

initially occur followed by the identification of secondary and tertiary

impact.

The project will have impacts of varying magnitude on different

environmental components. These impacts could be categorized as -

Primary impacts, i.e. impacts which occur as a direct result of the

project activities.

Secondary and tertiary impacts, i.e. impacts that occur as a result

of primary impacts.

4.2.1 Identification of Impacting Activities

Various activities involved in the project are divided viz.:

A. Construction phase activities: impacts are immediate, in the vicinity

and sporadic

B. Operation phase activities: impacts are long term, in wide area and

continuous

The activities identified for the project under each phase are:

Construction phase

Excavation

Foundation & Civil work

Transportation of construction materials, equipments & machineries

Installation of equipments & machineries

Operation phase

Plant operation

Material storage & handling

Utilities and services

Green belt development



4.2.2 Identification of Environment Attributes

There are various types of impacts arise due to the proposed activities

which will be evaluated considering the following environment parameters

in construction and operational phase,

Impact on Topography

Impact on Air Environment

Impact on Water Environment

Impact on Noise Environment

Impact on Land Environment (Hazardous/solid waste generation)

Impact on Biological Environment

Impact on Socio-Economic Environment

Impact on Occupational Health & Safety

4.3 IMPACT ON TOPOGRAPHY

Proposed activities at Reynish Pharmachem Pvt. Ltd. will be carried out in

the new premises at Survey no. 504, 505, 507, Village: Dabhasa, Ta.:

Padra, District: Vadodara, Gujarat. Proposed land is already converted

from agriculture to non-agriculture for industrial purpose. During the

construction, excavated soil will be restored to its original shape. Thus,

the impact during the construction is reversible, for short terms and

insignificant. Construction of plant & building will be carried out for

proposed project. During the operational phase of the project, no major

impact is envisaged on the topography.

4.4 IMPACT ON AIR ENVIRONMENT

a. Construction Phase impact & mitigation measures

During construction phase, there will be chances of dust generation due

to the construction activities to be carried out as per the plant design. It

will be limited up to working area only and not likely to spread in wider

area. To mitigate the impact, regular sprinkling of the water will be done.

Vehicular traffic may lead to increased concentration pollutants through

exhaust gases, affecting the ambient air quality of surrounding areas;

vehicles only with PUC certificates will be allowed. However, this effect

remains localized near to the plant site and during the time of vehicular

movement only. Thus, overall impact is envisaged as short-term negative

& reversible in nature. Hence, looking to the overall facts described



above, it can be concluded that, the impacts on air due to the

construction & erection activities will be minimum or negligible.

b. Operational phase impact & mitigation measures

Long term impacts on the air quality are anticipated due to operational

activities. It depends on various factors like process technology,

operation & maintenance, raw material, fuel, air pollution control

measures. For the study of impact assessment for air environment, all

probable emissions are studied including fugitive emission. The sources

and expected emission level are described in below section.

Emission from the project

Flue gas emission will be from stack attached with Boiler (3.0 TPH),

Thermic Fluid Heater (20 lac Kcal/hr.) and Hot Air Generator (30 lac

Kcal/hr.) where Agro briquette will be used as a fuel; and standby D.G.

Set. Most probable pollutants will be SPM, SO2 and NOx. Process emission

will be from the stack attached with reaction vessels and vent of Spin

flash dryers (SFD)/Fluid Based Dryer (FBD)/Rotary Vacuum Dryer (RVD).

Pollutants from reaction vessels will be SO2 & HCl and PM will be

generated from SFD/FBD/RVD.

Mitigation measures

Multi Cyclone, bag filter & water scrubber will be installed as APCM for

boiler, Thermic fluid heater and Hot air generator. To control the process

emission, water and alkali scrubber will be provided. SFD/FBD/RVD will

be equipped with in-built cyclone and bag filter. Furthermore, adequate

stack height and facility for sampling such as ladder and sampling point

will be provided as per the GPCB guidelines. The details of all stacks with

their APC measures & height are given in Table 2.8.

4.4.1 Air Pollution Dispersion Modeling of stack

Following sub-section give air dispersion modeling details for prediction of

changes in GLC of pollutants emitted from the above stacks.

Objective: The objective of dispersion modeling is to predict the ground

level concentration during the operation of the project and its impact on

ambient air quality of the area concentrations and compare with

applicable NAAQS.



Model used: The impact on air quality due to emissions from single

source or group of sources is evaluated by use of mathematical models.

The impacts of air pollutants were predicted using Gaussian air dispersion

model, which is selected on the basis of existence of multiple point

sources within the industrial complex and the plain terrain at the project

site. In order to predict the impact of air pollutants on ambient air

quality, ISCST3 model (Industrial Source Complex – Short Term

(ISCST3) dispersion model) of United State Environmental Protection

Agency (USEPA) was used by considering guidelines stipulated by CPCB

for air pollution dispersion modeling. The Gaussian model provides

estimates of pollutant concentrations at various receptor locations.

It is an hour-by-hour steady state Gaussian model which takes into

account the following:

Terrain adjustments

Stack-tip downwash

Gradual plume rise

Buoyancy-induced dispersion, and

Complex terrain treatment and consideration of partial reflection

Plume reflection off elevated terrain

Building down wash

Partial penetration of elevated inversions is accounted for Hourly

source emission rates, exit velocity and stack gas temperature

Only two stability conditions based on the meteorology aspects were used

to calculate the theoretical maximum ground level concentration is

comparing the actual data and data generated from mathematical

modeling, it highlights that the stability condition E & A-B were

predominant in the region.

Following are the assumptions made while using the model:

- No dry and wet depletion of pollutants

- Receptors are on flat terrain

The key emitted pollutants will be SPM, SO2, NOx and HCl.

4.4.2 Micrometeorology

Hourly micrometeorological data collected during the study period

(October, 18 to December, 2018) have been used for modeling. The



hourly wind speed, solar insolation & total cloudiness during day time and

wind speed & total cloudiness during night time were used to determine

the hourly atmospheric stability classes (defined by Pasquill and Gifford

as A to F, A being most unstable and F being most stable). The hourly

stability classes were determined based on the technique suggested by

Turner.

Turner’s system used for determining the stability classes is as follows:

- For day or night: If total cloud cover (TC) = 10/10 and ceiling

<7000 ft (2134 m), NR=0

- For night-time (defined as period from one hour before sunset to

one hour after sunrise):

a) If TC<4/10, use NR = -2

b) If TC>4/10, use NR = -1

- For daytime: determine isolation class number (IN)

a) If TC<5/10, use NR=IN

b) If TC>5/10, modify IN by the sum of the following applicable

criteria

If ceiling<7000 ft (2134 m), modification = -2

If ceiling>7000 ft but <16000 ft (4877 m), modification = -1

- If TC=10/10 and ceiling>7000 ft, modification = -1 and let modified

value of IN=NR, except for day-time NR cannot be <+1.

During the study period, stability calculated based on above-mentioned

Turner method gives average stability as A-B class during Day time and E

class during Night time.

4.4.3 Input data

Stack emissions data have been used for prediction of incremental GLC

values of SPM, SO2, NOx and HCl using one season meteorological data

during October, 18 to December, 2018. Input data includes

quantitative expected emission levels, temperature, and mixing height

from the stack. Input data is given in Table 4.1.

4.4.4 Receptor Network

Uniform polar grid and ambient air monitoring locations are considered as

discrete Cartesian receptor network for entire study area of 10 km radius.



4.4.5 Output of model (24-hourly GLCs)

The 24-hourly average Ground Level Concentration (GLC) values from

proposed project have been computed for SPM, SO2, NOx and HCl

considering topographical features around the plant & applicable stability

classes. The maximum 50 (24-hr) average concentration values for SPM,

SO2, NOx and HCl are given in Table 4.3 to 4.6. Corresponding Isopleths

for 24-hourly predicted value is generated which is shown in Figure 4.1

to 4.4.

It may be noted from the computed result for the proposed scenario that,

the highest 24-hourly average GLCs values for SPM, SO2, NOx and HCl

from the proposed activity are 3.603 g/m3, 1.902 g/m3, 1.628 g/m3,

and 0.287 g/m3 respectively. These GLCs are expected to occur at a

distance of 1.0 km from the source in W direction. With this, marginal

contribution due to the proposal of the project, the levels of PM10, SO2 &

NOx will remain well below the 24-hourly ambient air quality standards

for SO2 & NOx (80 g/m3), PM10 (100 g/m3), PM2.5 (60 g/m3) prescribed

by CPCB.

4.4.6 Incremental & cumulative concentration of pollutants

The maximum incremental GLCs due to project for SPM, SO2, NOx and

HCl is superimposed on the baseline concentrations recorded during the

study period to arrive at the likely resultant concentrations after

implementation of the proposed plant. The cumulative concentrations

(baseline + incremental) of the project is tabulated at Table 4.2.

4.4.7 Conclusion

The modeling study proved that, the air emissions from the proposed

activities would not likely to cause any significant impact on the ambient

air quality of the study area. The ambient air quality around project site

will remain within the National Ambient Air Quality Standards (NAAQS)

prescribed for residential area.

4.5 IMPACT ON WATER ENVIRONMENT

The main sources of impact on water environment will be due to

withdrawal of fresh water from the ground during construction and

operation phase. These are discussed below.



a. Construction Phase impacts & mitigation measures

The water requirement for various purposes will be met from bore well.

During construction work, water requirement is estimated to be about 10-

25 KLD depending upon nature of construction work. In addition to this,

about 3-5 KLD fresh water will be required for domestic activities of the

construction staff which will also be met through the same source. There

will be no major wastewater generation from the construction work.

Hence, it can be concluded that there will be no adverse impact during

construction phase.

b. Operational Phase impacts & mitigation measures



will be recycle/treated water (RO permeate & MEE condensate). Unit will

satisfy its fresh water requirement from Bore well water supply. Major

water demand will be industrial – mainly process (115 KLD), cooling (30

KLD), boiler (35 KLD), and washing (10 KLD).


of the industrial wastewater generation will be from process, lab &

scrubber (99 KLD), washing (10 KLD), utilities (Boiler & cooling - 10

KLD), and water treatment (22 KLD). Domestic wastewater generation

will be 4.0 KLD. Unit will built full-fledged ETP to treat w/w generated

from proposed project.

Process effluent along with wastewater of scrubber, washing and utility

will be taken to RO after primary and secondary treatment. RO reject will

be sent to MEE; RO permeate and condensate of MEE will be reused.

Domestic wastewater will be disposed to soak pit. Thus, achieving Zero

Liquid Discharge (ZLD). ETP sludge and MEE salt will be disposed to

approve TSDF site. Domestic effluent of will be disposed to soak pit.

c. Impact Assessment

As fresh water will be met from Bore well water supply, minor impact

envisage on ground water. However, unit will balance it by recharging

ground water during the monsoon season. For that, industry will develop

rain water harvesting structures nearby project area. So, there will not be

any major impact on the water environment due to proposed activities.



Mitigation Measures:

Minimum use of water will be done for construction phase.

Maximum use of treated water from MEE and RO during operational

phase.

Regular maintenance of rain water harvesting structures shall be

undertaken to have effective recharge.

4.6 IMPACT ON NOISE ENVIRONMENT

Any unwanted sound that creates disturbance in hearing is termed as

Noise. Hence, it is important to assess the present noise quality of the

area in order to predict the potential impact of future noise levels due to

the project.

a. Construction Phase Impact & mitigation measures

During the construction phase at Reynish Pharmachem Pvt. Ltd.,

impacts on noise level will occur due to the noise generation from new

equipments/machineries as well as some impact due to transportation.

Mainly the impacts of increased noise levels during construction are likely

to occur due to increase movement of trucks & other diesel-powered

material handling equipment. The impacts of noise during the

construction would be restricted to the site only and will be temporary.

PPEs like ear muff/ear plug will be provided to the workers. Regular

maintenance & lubrication of machineries will be undertaken to reduce

the noise generation. Thus, it is envisaged that the impacts on noise

during the construction phase would be insignificant after mitigation

measure.

b. Operational Phase Impact & mitigation measures

During operation, noise levels will increase due to operation of boiler, Hot

air generation, D.G. sets, process plant, vehicular transportation & other

machineries. The noise anticipated from the project will be confined only

within plant boundary. Adequate greenbelt will be developed for

prevention of noise propagation outside plant premises. Oiling/lubrication

& preventive maintenance will be done to reduce noise generation at

source to the permissible limit. However, at places where noise levels

may exceed the limit, PPEs will be provided to workers. Adequate noise

control measures such as silencers, anti-vibration pad etc. will be



provided. All the equipment will be designed/operated in such a way that

the noise level in work place shall not exceed 85 dB(A) as per the OSHA

Standard. During operation, the protective measures like PPEs (ear muff,

ear plug) will be provided & the exposure duration of workers/other

personnel to noise will be managed as per OSHA standard. The results of

baseline monitoring carried out in the region are presented in Chapter-3.

The results are below the standards prescribed for Industrial

environment. It can be concluded that, the impact on noise environment

will be long term but insignificant.

4.7 IMPACT ON LAND ENVIRONMENT

The main source of impact on land and soil environment results due to

construction activities and hazardous waste disposal.

a. Construction Phase Impact & mitigation measures

The construction activities at Reynish Pharmachem like excavation,

clearing, leveling & vehicular movements will entail change in the

landscape, which are expected to be of short duration and insignificant.

Unit will provide sanitation facilities for the staff engaged in construction

work which will prevent the impacts on land. Thus, there will not be any

issue of impacts on land during the construction phase.

b. Operational Phase impact (Solid/Hazardous Waste)

The hazardous wastes are the major source of impacts on land.

Hazardous waste generation from project must be considered to identify

the potential impacts. At Reynish Pharmachem Pvt. Ltd., entire quantity

of the hazardous waste will be stored in the isolated hazardous waste

storage area within premises having impervious platform having RCC

floor, leachate collection system & roof cover and disposed as per the

scientific method. Entire quantity of hazardous waste will be handled &

disposed as per Hazardous & Other waste (Management & Transboundary

Movement) Rules, 2016.

Main source of hazardous waste generation will be ETP sludge (25

MT/month), MEE salt (50 MT/month) from wastewater treatment and

Process waste (12 MT/month) will be disposed of at approved TSDF site.

Spent carbon (0.75 MT/month), and spent catalyst (1.0 MT/month) will

be returned back to supplier for regeneration. Distillation residue (15



MT/month), off specification products and date expired products will be

sent for co-processing or at CHWIF for incineration. Used lubricating oil

(40 Lit/month) will be sold to registered recycler. Discarded Drums (700

Nos./month) & containers/Liners (0.5 MT/month) will be sold to actual

users. Whatsoever generated off-specific product and date expired

products will be sent to CHWIF for Incineration. HCl (20-25%) - 75

MT/month and Sodium bisulfite (NaHSO3) - 50 MT/month will be sold to

actual user under Rule-9 of HAZ Rule.

Fly ash generation from the unit will be around 4.0 MT/day. Fly ash will

be utilized for brick manufacturing in plant premises. Details of

hazardous waste disposal methods are given in Table 2.10. Hence, no

adverse impact on the land environment is likely to occur, and no

significant negative impact is envisaged on the surrounding soil quality.

4.8 IMPACT ON BIOLOGICAL ENVIRONMENT

a. Construction phase impact & mitigation measures

This is a Greenfield project; hence minor cutting of trees/shrubs will be

done to clean the area. However, it will be balanced by developing

greenbelt within premises and along the roads. Various trees, shrubs and

herbs are found in and around it, a list of which is given in baseline. None

of the plants are in the list of endangered plant species. Also, the trees

are identified for their sensitivity & pollution tolerance capacity. This

concept helps to plan the greenbelt of the area making it less polluted

and a pollution absorber. Thus, it is envisaged that there will not be any

adverse impacts on the ecology/biological environment in construction

phase.

b. Operational phase impact & mitigation measures

There are no protected areas like national park/wildlife sanctuary within

the 10 km radial of the project site, so there will not be any significant

impact on ecology. No endangered floral or faunal species has been

recorded within the study area. Further, unit will develop greenbelt to

enhance the biological feature of the site. Also, the trees are identified for

their sensitivity & pollution tolerance capacity.



Conservation of Schedule-I fauna Pavo Cristatus through Habitat

Improvement and Awareness

No peacock was sighted in the project site. All the direct sightings of the

peacock were located near the human habitats, villages and agriculture

field, of study area. This species is well adapted to natural village

environment setting. Day time they temporarily move towards the

surrounding agriculture areas for feeding while during night time they

roost on the trees present in the village and in the agriculture hedges.

Habitat improvement programme can be undertaken through plantation

of suitable tree species in the surrounding villages. While selecting the

tree/ shrub species care shall be provided for beery plants which attract

these birds. During summer period, villagers will be encouraged to use

the old earthen pots to fill with water for drinking these birds.

(Wildlife Conservation Plan submitted for Schedule I species Pavo

Cristatus is attached as Annexure-XI of the EIA report.)


Summer is the time when these birds are facing shortage of feeds, there

by supplying the feed like Bajri, Juwar, Maize to the surrounding villages

with good population of Indian peafowls will suffix the problem of food

shortage.


In consultation of the forest department, following conservation measures

will be adapted for peacock conservation:

1. Increasing the tree cover in the study area which will provide shelter

and roosting to the peacocks. This can be achieved by planting of local

tree species like Neem, Shirish, Khakhro, Haldu, Amli, Banyan, Peepal

and Peeper or other Ficus sp. Vacant places such as edges of

agricultural fields, village Gauchar, Panchayat’s common land,

neighbourhood of people inhibiting, road side avenue tree plantation,

open scrubs, ravines, school compounds can be selected for practicing

the plantation activity.

2. School level awareness programmes will be conducted for

conservation of peacocks in the study area by organizing competitions



during “Wildlife Week” and “Van Mahotsav” celebrations by active

involvement of local community.

3. Some provision of rewards to informers for the control of poaching and

illegal trade in wildlife.

4. Carrying out census and research projects to know the potential

threats and population status of the species in collaboration of local

schools, colleges, panchayats and forest department.

5. Suggest strategies to minimize negative impacts of changing

environment in nearby area of peacock populations and to promote

conservation of peacock habitats.

6. Another way to help preserve the endangered species is to create

society dedicated to ecological ethics. All the conservation measures

will be implemented with the help of and in the consultation of the

district forest department.



Sr.

No.


Cost. Rs.

Village

1 Plantation-350 tree plants (5 feet height as

per the plant species-Cost of sapling will be

changed per year)

70,000/-(@

200/-per plant)

Dabhasa, Ranu,

Dhobikuwa and

Mahuvad


tank

1,00,000/-


conservation

20,000/- Study area



30,000/-

Total 2,20,000/-

Following is the list of trees which are helpful as pollution absorber and at

the same time pollution sensitive.

Family

Name

Botanical Name Common

Name

Sensitive Tolerant

Anacardiaceae Mangiferaindica Mango Cement dust, Coal dust, SO2

Dust collector

Anonaceae Polyalthialongifolia Asopalav SO2 Dust collector



Family Name

Botanical Name Common Name

Sensitive Tolerant

Caesalpini-aceae

Cassia fistula Garmalo Cement dust, Poor Dust

collector, SO2

N.A

Delonixregia Gulmohar SO2, Fly ash, Cement dust

N.A

Meliaceae Azadirachtaindica Neem Cement dust SO2

Mimosaceae Pithecellobiumdulce Gorasamli N.A Better Dust collector, SO2

There will not be discharge of effluent from Reynish Pharmachem Pvt.

Ltd. and entire quantity of hazardous waste will be handled & disposed as

per Hazardous & Other waste (Management & Transboundary Movement)

Rules, 2016. Hence there will not be any impact on aquatic ecology of the

surrounding area. GLCs of air pollutants will remain low and hence no

significant impact on terrestrial ecology is expected. Thus, there will not

be any significant impact on ecological environment due to proposed

activities.

4.9 IMPACT ON SOCIO-ECONOMIC ENVIRONMENT

a. Construction Phase Impacts & mitigation measures

During the peak construction phase, construction manpower including

construction workers will be employed. However, to the maximum extent

possible, construction workers will be employed from within the study

area. Since the construction phase of this project will be for short time

period, the socio-economic impact due to construction of this project is

going to be temporary. Around 25 to 75 workers will be employed in the

construction work (upon nature of work). This will increase construction

employment in the study area. As the construction phase for the

proposed project will be few months, the impact would be temporary.

b. Operation Phase Impacts & mitigation measures

The proposed unit will be located in private land, so no displacement of

person is envisaged. Unit will provide employment opportunity to locally

available skilled and un-skilled labors at different level as per the

requirement, which in turn result into a positive impact on prevailing

socio-economic environment. For the proposed activities, 65 nos. of

workers will be employed. In addition, employment will be generated by

the secondary supporting activities e.g. transportation, communication,



daily utility services. Surrounding area has got good educational facilities

and most of employees will come from the surrounding area. Thus,

overall impacts on socio-economic environment are long term and

positive in nature.

4.10 IMPACT ON OCCUPATIONAL HEALTH & SAFETY

a. Construction Phase Impacts & mitigation measures

In the Construction phase, some effects on occupational health & safety

of the employees working in the site are envisaged. Major health issues

encountered will be physical hazards & accidental Hazard. All plans and

construction schedule will be followed as per relevant laws approved by

competent authority, so as to minimize the occupational health hazards.

Mitigation Measures

Necessary PPEs like helmets, ear plug/ear muff, safety shoes,

goggles etc. will be provided to workers.

Incident/accident reporting system will be developed and all the

employees will be made aware for the same.

Periodic inspection & testing of equipments & machineries will be

done.

b. Operational Phase Impacts & mitigation measures

In operational phase, various effects on occupational health and safety of

the employees working in the plant are envisaged. Major health and

safety issues encountered will be physical hazards, respiratory hazards,

electrical hazards, noise, fire hazards associated while working within the

plant. Preventive safety measures shall be taken to minimize the risk of

accident with respect to chemical handling.

Mitigation Measures

Emergency preparedness plan should be implemented.

First aid/other emergency treatment should be provided.

Workers shall be well equipped with personal protective

equipments. Only authorized persons will be allowed inside the

plant.

A health monitoring program shall be in place to monitor the health

of the persons working on the site to ensure the health status of all

concerned.



Fire hydrant system, fire extinguishers will be installed at different

locations within premises.

Sign boards will be displayed at designated locations indicating

appropriate hazard warnings.

Good house-keeping will be ensured within the factory premises.

4.11 IMPACT ON TRAFFIC MOVEMENT

Raw materials, products & wastes will be transported in covered trucks by

road. The traffic load is to be increased due to proposed project for the

transportation of finished goods and raw materials.

Baseline/ Existing Traffic Scenario & Level of Services

The road from Padra to Jambusar Road is two track lane with divider, all

types of vehicles move on the road.

Capacity of road = 1500 PCU’s/hr

Total Volume during Peak Hours = 603

Existing Volume/Capacity ratio = 603/1500= 0.402

The level of service is “C” that is Good

Traffic Scenario & Level of Services: During Construction

Additional traffic from proposed project construction will be,

(i) Estimated 1 trucks/tanker per hour or 3 PCU/hr and

(ii) One to two cars estimated per hour or 2 PCU/hr.

Traffic Scenario & Level of Services: During operational level

Additional traffic from our project will be estimated 30 PCU/day [10

trucks/tankers (in & out) x 3] and 60 PCU/day from car and motorcycle,

which have insignificant impact on existing traffic load.

Conclusion: Traffic load due to proposed project is negligible compare

with existing traffic, hence insignificant impact on existing traffic

condition.



Table 4.1

Input data for air quality modeling

Sr.

No.

Stack attached to Stack

Height

(m)

Temp.

(K)

Velocity

(m/s)

Dia.

(m)

Concentration

SPM

g/s

SO2

g/s

NOx

g/s

1 Steam Boiler

(3.0 TPH)

30 455 6.0 0.45 0.076 0.038 0.033

2 Thermic fluid heater

(20 lac Kcal/hr.)

30 455 6.5 0.45 0.083 0.041 0.036

3 Hot air generator

(30 lac Kcal/hr.)

30 455 6.5 0.45 0.083 0.041 0.036

4 D. G. Set

(500 kVA)

11 485 15.0 0.3 0.069 0.032 0.037

5 Process vessel stack 11 335 5.0 0.3 SO2 – 0.011 g/s

HCl- 0.006 g/s

6 SFD/FBD/RVD

(5 nos.)

11 335 5.0 0.3 PM-0.011 g/s



Table 4.2

Cumulative Concentrations at various locations

Station Direction Dist.

(Km)

Baseline

Concentration

(g/m3)

Predicted GLC

(g/m3)

Cumulative

Concentration

(g/m3)

PM SO2 NOx PM SO2 NOx PM SO2 NOx

Project Site (A1) -- 0.0 67.9 15.5 18.1 0.2 0.1 0.1 68.1 15.6 18.2

Dabhasa (A2) NNE(UW) 1.57 70.7 15.1 17.8 0.6 0.2 0.4 71.3 15.3 18.2

Padra (A3) ENE(UW) 6.11 67.2 13.7 16.9 0.2 0.0 0.1 67.4 13.7 17.0

Umaraya (A4) NNE(UW) 4.16 67.1 16.3 17.4 0.2 0.0 0.2 67.3 16.3 17.6

Dhobikuwa (A5) WSW(DW) 3.10 71.0 13.6 16.0 1.4 1.2 1.2 72.4 14.8 17.2

Ranu (A6) SSW(DW) 0.45 68.9 13.0 15.8 0.8 0.3 0.3 69.7 13.3 16.1

Bhoj (A7) SW(DW) 3.56 69.6 13.8 15.8 0.6 0.3 0.3 70.2 14.1 16.1

Vishrampura (A8) SW(DW) 5.88 70.7 14.9 16.7 0.2 0.1 0.1 70.9 15.0 16.8



Table 4.3 The 24-hourly average GLC Concentration Values for SPM

RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE

1 3.603 ( -1000.00, .00) GC 26 1.821 ( -1000.00, -1000.00) GC

2 3.001 ( -2000.00, .00) GC 27 1.810 ( -2000.00, .00) GC

3 2.880 ( -1000.00, .00) GC 28 1.790 ( -1000.00, -1000.00) GC

4 2.492 ( -1000.00, .00) GC 29 1.750 ( -2000.00, .00) GC

5 2.389 ( -1000.00, -1000.00) GC 30 1.737 ( -1000.00, -1000.00) GC

6 2.360 ( -1000.00, .00) GC 31 1.730 ( -2000.00, .00) GC

7 2.335 ( 1000.00, 1000.00) GC 32 1.720 ( .00, 2000.00) GC

8 2.322 ( -1000.00, .00) GC 33 1.699 ( -1000.00, .00) GC

9 2.269 ( 1000.00, .00) GC 34 1.669 ( -1000.00, -1000.00) GC

10 2.260 ( -1000.00, .00) GC 35 1.664 ( -1000.00, -1000.00) GC

11 2.258 ( .00, 1000.00) GC 36 1.656 ( -2000.00, .00) GC

12 2.202 ( -1000.00, .00) GC 37 1.654 ( -1000.00, .00) GC

13 2.189 ( -3000.00, .00) GC 38 1.652 ( -4000.00, .00) GC

14 2.185 ( -1000.00, .00) GC 39 1.636 ( -1000.00, -1000.00) GC

15 2.176 ( -1000.00, -1000.00) GC 40 1.615 ( -1000.00, .00) GC

16 2.052 ( 2000.00, .00) GC 41 1.605 ( -1000.00, -1000.00) GC

17 2.010 ( -1000.00, .00) GC 42 1.592 ( -1000.00, -1000.00) GC

18 1.994 ( -1000.00, .00) GC 43 1.586 ( -2000.00, .00) GC

19 1.990 ( -2000.00, .00) GC 44 1.561 ( -1000.00, .00) GC

20 1.978 ( -1000.00, -1000.00) GC 45 1.558 ( -2000.00, .00) GC

21 1.958 ( -1000.00, .00) GC 46 1.536 ( 3000.00, .00) GC

22 1.927 ( -1000.00, .00) GC 47 1.535 ( -2000.00, .00) GC

23 1.909 ( -1000.00, .00) GC 48 1.526 ( 1000.00, 1000.00) GC

24 1.888 ( .00, -1000.00) GC 49 1.505 ( -1000.00, .00) GC

25 1.883 ( -1000.00, .00) GC 50 1.499 ( -1000.00, -1000.00) GC

Note: Receptor Types: GC = Grid cart, Concentration in µg/m3



Table 4.4 The 24-hourly average GLC Concentration Values for SO2


1 1.902 ( -1000.00, .00) GC 26 0.946 ( -1000.00, -1000.00) GC

2 1.552 ( -2000.00, .00) GC 27 0.936 ( -2000.00, .00) GC

3 1.506 ( -1000.00, .00) GC 28 0.927 ( -1000.00, -1000.00) GC

4 1.304 ( -1000.00, .00) GC 29 0.904 ( -2000.00, .00) GC

5 1.244 ( -1000.00, -1000.00) GC 30 0.903 ( -1000.00, -1000.00) GC

6 1.227 ( -1000.00, .00) GC 31 0.892 ( -2000.00, .00) GC

7 1.213 ( 1000.00, 1000.00) GC 32 0.891 ( .00, 2000.00) GC

8 1.211 ( -1000.00, .00) GC 33 0.889 ( -1000.00, .00) GC

9 1.202 ( 1000.00, .00) GC 34 0.868 ( -1000.00, .00) GC

10 1.186 ( .00, 1000.00) GC 35 0.867 ( -1000.00, -1000.00) GC

11 1.185 ( -1000.00, .00) GC 36 0.865 ( -1000.00, -1000.00) GC

12 1.153 ( -1000.00, .00) GC 37 0.855 ( -2000.00, .00) GC

13 1.151 ( -1000.00, .00) GC 38 0.852 ( -1000.00, -1000.00) GC

14 1.133 ( -1000.00, -1000.00) GC 39 0.847 ( -4000.00, .00) GC

15 1.126 ( -3000.00, .00) GC 40 0.836 ( -1000.00, .00) GC

16 1.064 ( 2000.00, .00) GC 41 0.835 ( -1000.00, -1000.00) GC

17 1.058 ( -1000.00, .00) GC 42 0.828 ( -1000.00, -1000.00) GC

18 1.048 ( -1000.00, .00) GC 43 0.819 ( -2000.00, .00) GC

19 1.029 ( -1000.00, -1000.00) GC 44 0.819 ( -1000.00, .00) GC

20 1.028 ( -1000.00, .00) GC 45 0.804 ( -2000.00, .00) GC

21 1.026 ( -2000.00, .00) GC 46 0.802 ( 1000.00, 1000.00) GC

22 1.011 ( -1000.00, .00) GC 47 0.793 ( -2000.00, .00) GC

23 0.999 ( -1000.00, .00) GC 48 0.791 ( -1000.00, .00) GC

24 0.989 ( -1000.00, .00) GC 49 0.791 ( 3000.00, .00) GC

25 0.969 ( .00, -1000.00) GC 50 0.777 ( -1000.00, -1000.00) GC




Table 4.5 The 24-hourly average GLC Concentration Values for NOx


1 1.628 ( -1000.00, .00) GC 26 0.817 ( -1000.00, -1000.00) GC

2 1.342 ( -2000.00, .00) GC 27 0.809 ( -2000.00, .00) GC

3 1.296 ( -1000.00, .00) GC 28 0.801 ( -1000.00, -1000.00) GC

4 1.122 ( -1000.00, .00) GC 29 0.781 ( -2000.00, .00) GC

5 1.072 ( -1000.00, -1000.00) GC 30 0.779 ( -1000.00, -1000.00) GC

6 1.058 ( -1000.00, .00) GC 31 0.773 ( -2000.00, .00) GC

7 1.046 ( 1000.00, 1000.00) GC 32 0.769 ( .00, 2000.00) GC

8 1.042 ( -1000.00, .00) GC 33 0.764 ( -1000.00, .00) GC

9 1.025 ( 1000.00, .00) GC 34 0.748 ( -1000.00, -1000.00) GC

10 1.019 ( -1000.00, .00) GC 35 0.747 ( -1000.00, -1000.00) GC

11 1.014 ( .00, 1000.00) GC 36 0.746 ( -1000.00, .00) GC

12 0.989 ( -1000.00, .00) GC 37 0.740 ( -2000.00, .00) GC

13 0.987 ( -1000.00, .00) GC 38 0.735 ( -4000.00, .00) GC

14 0.977 ( -1000.00, -1000.00) GC 39 0.734 ( -1000.00, -1000.00) GC

15 0.976 ( -3000.00, .00) GC 40 0.722 ( -1000.00, .00) GC

16 0.918 ( 2000.00, .00) GC 41 0.720 ( -1000.00, -1000.00) GC

17 0.908 ( -1000.00, .00) GC 42 0.715 ( -1000.00, -1000.00) GC

18 0.895 ( -1000.00, .00) GC 43 0.709 ( -2000.00, .00) GC

19 0.889 ( -2000.00, .00) GC 44 0.703 ( -1000.00, .00) GC

20 0.888 ( -1000.00, -1000.00) GC 45 0.696 ( -2000.00, .00) GC

21 0.883 ( -1000.00, .00) GC 46 0.686 ( 1000.00, 1000.00) GC

22 0.869 ( -1000.00, .00) GC 47 0.686 ( -2000.00, .00) GC

23 0.860 ( -1000.00, .00) GC 48 0.685 ( 3000.00, .00) GC

24 0.847 ( -1000.00, .00) GC 49 0.679 ( -1000.00, .00) GC

25 0.840 ( .00, -1000.00) GC 50 0.672 ( -1000.00, -1000.00) GC




Table 4.6 The 24-hourly average GLC Concentration Values for HCl


1 0.287 ( -1000.00, .00) GC 26 0.097 ( -1000.00, -1000.00) GC

2 0.198 ( 1000.00, .00) GC 27 0.095 ( .00, 1000.00) GC

3 0.185 ( -1000.00, .00) GC 28 0.095 ( 2000.00, .00) GC

4 0.174 ( -1000.00, .00) GC 29 0.092 ( .00, 1000.00) GC

5 0.162 ( .00, 1000.00) GC 30 0.090 ( .00, -1000.00) GC

6 0.162 ( -1000.00, .00) GC 31 0.090 ( .00, -1000.00) GC

7 0.160 ( -1000.00, .00) GC 32 0.088 ( -1000.00, -1000.00) GC

8 0.154 ( -1000.00, .00) GC 33 0.087 ( .00, -1000.00) GC

9 0.147 ( -1000.00, .00) GC 34 0.086 ( -1000.00, -1000.00) GC

10 0.146 ( -1000.00, .00) GC 35 0.086 ( -1000.00, -1000.00) GC

11 0.146 ( -1000.00, .00) GC 36 0.085 ( 1000.00, .00) GC

12 0.140 ( -1000.00, .00) GC 37 0.084 ( 1000.00, .00) GC

13 0.136 ( -1000.00, .00) GC 38 0.083 ( -1000.00, .00) GC

14 0.135 ( -1000.00, .00) GC 39 0.082 ( -1000.00, -1000.00) GC

15 0.132 ( -1000.00, .00) GC 40 0.082 ( -1000.00, .00) GC

16 0.132 ( -2000.00, .00) GC 41 0.080 ( .00, 1000.00) GC

17 0.126 ( -1000.00, -1000.00) GC 42 0.080 ( -2000.00, .00) GC

18 0.120 ( -1000.00, .00) GC 43 0.080 ( .00, -1000.00) GC

19 0.114 ( -1000.00, .00) GC 44 0.080 ( -2000.00, .00) GC

20 0.113 ( -1000.00, .00) GC 45 0.080 ( -1000.00, -1000.00) GC

21 0.109 ( -1000.00, .00) GC 46 0.079 ( -1000.00, .00) GC

22 0.109 ( -1000.00, -1000.00) GC 47 0.079 ( -1000.00, -1000.00) GC

23 0.109 ( -1000.00, .00) GC 48 0.079 ( -1000.00, -1000.00) GC

24 0.109 ( 1000.00, 1000.00) GC 49 0.079 ( -1000.00, -1000.00) GC

25 0.097 ( 1000.00, 1000.00) GC 50 0.079 ( -1000.00, -1000.00) GC




Figure 4.1: Isopleths for Ground Level Concentrations for SPM

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Figure 4.2: Isopleths for Ground Level Concentrations for SO2

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Figure 4.3: Isopleths for Ground Level Concentrations for NOx

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Figure 4.4: Isopleths for Ground Level Concentrations for HCl

-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

-10000

-8000

-6000

-4000

-2000

0

2000

4000

6000

8000

10000



Chapter-5

Analysis of Alternatives

5.1 PROLOGUE

Alternative analysis is the process of analyzing the proposed locating for

suitability for basic necessities to operate the plant safely, this analysis

also covers the environmental aspect of pollution prevention and

improvement in quality of life nearby the project vicinity. The project

alternative is the course of action in pace of another, that would meet the

same purpose and need, but which would avoid or minimize negative

impacts and enhance project benefits. Such projects may result in

specific impacts which can be avoided or mitigated by adherence to

certain predetermined performance standards, guidelines or design

criteria. Alternative approaches may therefore be more effective in

integrating environmental and social concerns into the project planning

process.

5.2 SITE ALTERNATIVE

M/s. Reynish Pharmachem Pvt. Ltd. is a Greenfield project, proposes

to set up bulk drugs manufacturing unit. Total production capacity of all

products will be tune around 50 MT/month. Before finalization of project

land, unit as carried out following three alternate site study.

Alternative sites examined for the proposed project before

finalization of project location:

The following three alternative sites have been considered for the

proposed Pharma Plant before finalize the site.

Description Site-1 Site-2 Site-3

Location (Village) Survey no 206, 207/2

Village Waghodia, Tal: Waghodia

Dist: Vadodara

Survey no. 504,

505, 507, Village:

Dabhasa, Tal:

Padra, Vadodara

Block No.: 391&

392 Village:

Umaraya, Tal:

Padra, Vadodara

Land Area Insufficient

16692 m2

Sufficient

36958 m2

Considerable

20581 m2

Geographical Coordinates

22°19'6.66"N 73°23'42.91"E

22°13'32.76"N 73° 1'13.01"E

22°15'37.7"N 73°01'34.1"E

Areas falling under the critically polluted areas

No critically polluted areas





(within 10 Kms.

Radius)

Within 10 Kms

Radius

Within 10 Kms

Radius

Within 10 Kms

Radius

National Parks/Wildlife

Sanctuaries/Bird Sanctuaries/Tiger

reserve/Elephant corridors/Migratory routes for Birds/Forest

(within 10 Kms. of the project site)

No National

Parks /Wildlife Sanctuaries /Bird

Sanctuaries Migratory routes for Birds/Forest

within 10 Kms. of the project

site

No National Parks

/Wildlife Sanctuaries /Bird


within 10 Kms. of the project site

No National

Parks /Wildlife Sanctuaries /Bird


within 10 Kms. of the project

site

Sensitive Areas with

10 Kms. radius of the site

Outside the ESZ Outside the ESZ Outside the ESZ

Land use pattern Rich agriculture land with surrounding

Agriculture farm

Agriculture non-irrigated land converted for

non-agricultural usage

Agriculture irrigated land

Residential structures within 1 km radius

from the project boundary

Waghodia town

around 0.9 km

No Residential

structures within

1 km

Umraya village

around 0.75 km

Number of schools

within 1 km of site

Waghodia

primary School around 1.1 km

None One primary

school

Major water bodies

within 2.5 km radius

from the project

boundary

Waghodia Pond

around 1.4 km

Ajwa Lake 6.0km

Ranu village Pond

around 1.5 km

Mahi river within

1.7 km

Numbers village within 2.5 km radius from the project boundary

4 villages – [email protected] km

Nava [email protected] km

[email protected] km [email protected] km

2 villages – Ranu@ 1.42km, [email protected] km

[email protected]

[email protected]

4 villages – [email protected] km,

[email protected] km, Luna@ 1.9

km, [email protected] km

Transport – Ranked on the ease of

accessibility and networking of Roads,

Rail, Air, Waterways along with logistic centers and

connectivity to port

Easy accessibility of Road network,

but traffic have to pass through

town of Waghodia. Around 20.0 km

from Vadodara city with national

and international connectivity for business by

Road, Rail Air cargo etc.

[email protected] km

Easy accessibility of road network,

Around 19.0 km from Vadodara

city with national and international connectivity for

business by Rail, Air etc.


four lane [email protected] km

six lane Railway station-

Easy accessibility of road network,

Around 19.0 km from Vadodara

city with national and international connectivity for

business by Rail, Air etc.


four lane [email protected] km

six lane Railway station-








Two lane road

[email protected] km six lane

Railway station-Vadodara@22 km

Vadodara Airport@ 18.0

km Dahej port

Waterways connectivity for

import/export of raw materials and products.

Vadodara@19 km

Vadodara Airport@ 24.0

Dahej port Waterways

connectivity for import/export of

raw materials and products.

Vadodara@19

km Vadodara

Airport@ 23.0 Dahej port

Waterways connectivity for

import/export of raw materials and products.

Proximity to from raw material source and

market)

Easy available from Vadodara,

Ahmedabad and Ankleshwar





Infrastructure – Ranked on basis of

safe ground water blocks

Area falls under the safe zone as

per the CGWA classification.

Area falls under the safe Zone as


Area falls under the safe Zone as


Nearby unit No major highly polluting Chemical

industries in vicinity

No major highly polluting Chemical industries in

vicinity

Pigment Color, Dyes and Dye Intermediates

units nearby, may create FDA

approval issues for chances of contamination by

neighboring unit

Water Quality Saline with TDS

level (Around 1550 mg/L) and

Electric Conductivities (2250 Micro

mhos/cm)

Compare to less

saline with TDS level (1092 mg/L)

and Electric Conductivities (1580 Micro

mhos/cm)

Saline with TDS

level (1925 mg/L) and

Electric Conductivities (2770 Micro

mhos/cm )

Major criteria for selection of this site are:

No forest land involved and land is converted into non-agriculture

activity

No Religious and Historic Places or Archaeological Monuments within

10 km radius from the project site.

Other required facilities like infrastructure, communication, medical

facilities, unskilled & skilled manpower, fuel, water, power, and raw

materials, are readily available, too.



No prime agricultural land converted into industrial site (Proposed

Land yields poor agriculture productivities due to non-irrigated land

Land area is sufficiently large to provide space for appropriate EMS.

The site boundary is approachable at about 1.0 km from Vadodara to

Jambusar Highway (SH-16).

Required facilities like infrastructure, communication, medical facilities,

fuel, water, power, unskilled & skilled manpower, raw materials, road

network etc. are easily available at this location.

There is no Rehabilitation and Resettlement involved.

Nearest city Vadodara is about 19 km away from the site, which is

having connectivity with other parts of the country by road, rail & air.

Therefore, project proponent has considered this site/location.

Considering above all aspect, location Site # 2 is better than the

Site-1 & Site-3.

5.3 PROCESS ALTERNATIVE

Production Technology

Reynish will have a team of scientists engaged in R&D activities, work on

differentiated medicines for the future. Proposed technology of production

is result of R & D and no alteration is currently with the proponent.

Wastewater Treatment Technology


scrubber, washing and utility will be taken to RO after primary and

secondary treatment. RO reject will be sent to MEE; RO permeate and

condensate of MEE will be reused. Domestic wastewater will be disposed

to soak pit. Thus, achieving Zero Liquid Discharge (ZLD). Thus proven,

most feasible and best available technology will be used for wastewater

management and no other alternatives are with the proponent.

Air Pollution Control Technology

Flue gas emission is due to the combustion of fuel Agro briquette in

boiler, Thermic Fluid Heater and Hot Air Generator. Multi Cyclone, bag

filter & water scrubber will be installed as APCM for each flue gas

emission source. Process gas emission will be from the stack attached to

process reactors and vent of Spin flash dryers (SFD)/ Fluid Based Dryer

(FBD)/Rotary Vacuum Dryer (RVD). To control the process emission,



water and alkali scrubber will be provided. Spin flash dryers will be

equipped with in-built cyclone and bag filter. Thus proven, most feasible

and best available technology will be used for Air Pollution Control and no

other alternatives are currently with the proponent.



Chapter-6

Environmental Monitoring Programme

6.1 PRELUDE

Environment monitoring is the sampling and analysis tool to know the

environment conditions at particular time. The record of environmental

monitoring is most important as the environmental changes are slow in

nature and impact appears after many years. Environmental Monitoring is

the technical heart of assessment of environmental and social impacts

arising due to implementation of the proposed project. An equally

essential element of this process is to develop measures to eliminate,

offset or reduce impacts to acceptable levels during implementation and

operation of projects. The integration of such measures into project

implementation and operation is supported by clearly defining the

environmental requirements within an Environmental Management Plan.

Reynish Pharmachem Pvt. Ltd. proposed to manufacture bulk drugs

with production capacity of 50 MT/month. The environmental monitoring

programme is developed as below.

6.2 ENVIRONMENT MONITORING PROGRAM

The periodically monitoring of Environmental parameters like air, water,

noise, soil and performance of pollution control facilities and safety

measures in the plant are vital for proper Environmental management of

any industrial project. Therefore, the company shall create environmental

monitoring facilities by the environmental and safety department to

monitor air and water pollutants as per the guideline of GPCB & CPCB.

Moreover, air and water quality shall be monitored by outside agencies

authorized by GPCB at regular frequencies. This department shall also

carry out periodical checkup of fire and safety equipments.

6.3 OBJECTIVE OF MONITORING PLAN

The basic objective of implementing a monitoring plan on a regular basis

is as follows:

To know the pollution status within the plant and its vicinity.

Generate data for corrective action in respect of pollution.



Correlate the production operations with emission & control

mechanism.

Examine the performance of pollution control system.

Assess the Environmental impacts.

Remedial measures and environment management plant to reverse

the impacts.

6.4 SCHEDULE FOR ENVIRONMENT MONITORING

The environmental monitoring will be scheduled on regular interval to

assess the conditions. The record of these monitoring will be compared

with the baseline study to know the changes in environmental conditions.

The post-project environmental monitoring suggested herewith should be

as per the following guideline.

The highlights of the integrated environmental monitoring plan are:

The stack monitoring facilities like ladder, platform and porthole at all

the stacks will be maintained in good condition.

Regular monitoring of all gaseous emissions from stacks/vents.

The performance of air pollution control equipment evaluated based

on these monitoring results.

Water consumption will be recorded daily.

As far as possible, noise curbed at its source, with the help of

acoustic hoods and other such noise reducing equipment. Regular

noise level monitoring will be carried out.

Greenbelt will be properly maintained and new plantation

programmes will be undertaken frequently.

Continuous environmental awareness programmes will be carried out

for the employees and also in the surrounding villages.

6.5 AMBIENT AIR QUALITY MONITORING

At Reynish Pharmachem Pvt. Ltd., Flue gas emission is due to the

combustion of fuel Agro briquette in boiler, Thermic fluid heater and Hot

air generator. Multi Cyclone, bag filter & water scrubber will be installed

as APCM for each flue gas stack. Process gas emission will be from the

stack attached to process reactors and vents of Spin flash dryers

(SFD)/Fluid Based Dryer (FBD)/Rotary Vacuum Dryer (RVD). To control



the process emission, water and alkali scrubber will be provided.

SFD/FBD/RVD will be equipped with in-built cyclone and bag filter.

Scheme for monitoring ambient air quality, stack emissions and fugitive

emissions are proposed. The ambient air quality monitoring systems are

recommended for monitoring the ground level concentrations and fugitive

emissions around the plant. Unit should install three monitoring stations

around its battery limit (at 1200 as per guideline) for monitoring PM, SO2

and NOx. The combined data will provide overall characteristic and

emission from the industry. Besides this, stack emissions monitoring as

per SPCB guidelines shall be carried out. Proposed monitoring schemes

are mentioned in Table 6.1.

6.6 WATER ENVIRONMENT MONITORING


of the industrial wastewater generation will be from process including lab

and scrubber (99 KLD), washing (10 KLD), utilities (Boiler & cooling - 10

KLD), and water treatment (22 KLD). Domestic wastewater generation

will be 4.0 KLD.


scrubber, washing and utility will be taken to RO after primary and

secondary treatment. RO reject will be sent to MEE; RO permeate and

condensate of MEE will be reused. Domestic wastewater will be disposed

to soak pit. Thus, achieving Zero Liquid Discharge (ZLD). ETP sludge

and MEE salt will be disposed to approve TSDF site. Domestic effluent of

4.0 KLD will be disposed to soak pit. The detail of water usage and

wastewater generation is provided comprehensively in Chapter 2.

Proposed monitoring schemes are mentioned in Table 6.1.

6.7 NOISE ENVIRONMENT MONITORING

Main source of noise generation at Reynish Pharmachem Pvt. Ltd. will be

boilers, D.G. set, process plant, vehicular transportation & other

machineries. Monitoring of noise levels is essential to assess the efficacy

of maintenance schedules undertaken to reduce noise levels and noise

protection measures. A good quality digital sound pressure level meter is

essential for this purpose. Proposed monitoring schemes are mentioned

in Table 6.1.



Table: 6.1 Environment Monitoring Plan

Nature of

Analysis

Frequency of

analysis with its analyzer

Parameters No. of

samples

Method of

Monitoring

Wastewater analysis

Monthly by external agency

pH, TDS, SS, COD, BOD, Oil

& Grease, etc.

2-3 samples APHA-AWWA 23rd edition

Stack Monitoring of

each stack


PM, SO2, NOX, HCl

All stacks Stack monitoring kit

Ambient Air

Quality Monitoring

Monthly for 24

hours or as per the statutory

conditions by external agency

PM10, PM2.5,

SO2, NOX, HCl

3-5 locations RDS, Fine

particulate sampler

Noise level Monthly as per the statutory


Noise level 6-8 locations (Nr. Main gate,

Nr. boiler, Nr. D.

G. Set, Process

area etc.)

Sound Level Meter

Work zone fugitive

monitoring


RPM, VOCs, acid mist

2-3 locations Personal sampler, VOC

sampler

Health check-up of

workers

As per the statutory

guideline

All workers ---

**Rs. 3.0 Lakhs per annum are allocated for Environment Monitoring.



Chapter-7

Additional Studies (A) HAZARD ANALYSIS & RISK ASSESSMENT

7.1 INTRODUCTION

Industrial plants deal with materials, which are generally hazardous in

nature by virtue of their intrinsic chemical properties or their operating

temperatures or pressures or a combination of these. Fire, explosion,

toxic release or combinations of these are the hazards associated with

industrial plants using hazardous chemicals. More comprehensive,

systematic and sophisticated methods of Safety Engineering, such as,

Hazard Analysis and Quantitative Risk Assessment have now been

developed to improve upon the integrity, reliability and safety of

industrial plants.

The primary emphasis in safety engineering is to reduce risk to human

life, property and environment. Some of the more important methods

used to achieve this are:

Quantitative Risk Analysis: Provides a relative measure of the

likelihood and severity of various possible hazardous events by

critically examining the plant process and design.

Work Safety Analysis: The technique discerns whether the plant

layout and operating procedures in practice have any inherent

infirmities.

Safety Audit: Takes a careful look at plant operating conditions, work

practices and work environments to detect unsafe conditions.

Together, these three broad tools attempt to minimize the chances of

accidents occurring. Yet, there always exists, no matter how remote,

probability of occurrence of a major accident. If the accident involves

highly hazardous chemicals in sufficiently large quantities, the

consequences may be serious to the plant, to surrounding areas and the

populations residing therein.

7.2 RISK ASSESSMENT-Identification of Hazards

A three „levels‟ risk assessment approach has been adopted for the M/s.

Reynish Pharmachem Pvt. Ltd. for their greenfield project at 504, 505,



507, Village: Dabhasa, Ta.: Padra, District: Vadodara, Gujarat. The risk

assessment levels are generally consistent with the practices encountered

through various assignments for medium and large chemical complexes.

The brief outline of the three tier approach is given below:

Level 1 – Risk Screening

This is top-down review of worst-case potential hazards/risks, aimed

primarily at identifying plant sites or areas within plant, which pose the

highest risk. Various screening factors considered include:

Inventory of hazardous materials;

Hazardous Materials properties;

Storage conditions (e.g. temperature and pressure);

Location sensitivity (distance to residential areas/populace).

The data/information is obtained from plant. The results provide a

relative indication of the extent of hazards and potential for risk

exposure.

Level 2 – Major Risk Survey (Semi - Quantitative)

The survey approach combines the site inspection with established risk

assessment techniques applied both qualitative as well quantitative

mode. The primary objective is to identify and select major risks at a

specific location in the plant considering possible soft spots/weak links

during operation/maintenance. Aspects covered in the risk usually

include:

Process Hazards;

Process Safety Management Systems;

Fire Protection and Emergency response equipment and programs.

Security Vulnerability;

Impact of hazards consequences (equipment damage, business

interruption, injury, fatalities);

Qualitative risk identification of scenarios involving hazardous

materials;

Risk reduction measures.

Selection of critical scenarios and their potential of damage provide

means of prioritising mitigative measures and allocate the resources to

the areas with highest risks.



Level 3 – Quantitative Risk Assessment (Deterministic)

This is the stage of assessment of risks associated with all credible

hazards (scenarios) with potential to cause an undesirable outcome such

as human injury, fatality or destruction of property. The four basic

elements include:

Hazards identification utilizing formal approach (Level 2, HAZOP etc.);

Frequency Analysis. Based on past safety data (incidents/accidents);

Identifying likely pathway of failures and quantifying the toxic /

inflammable material release;

Hazards analysis to quantify the consequences of various hazards

scenarios (fire, explosion, BLEVE, toxic vapour release etc.).Establish

minimum value for damage (e.g. IDLH, over pressure, radiation flux)

to assess the impact on environment.

Risk Quantification: Quantitative techniques are used considering

effect/impact due to weather data, population data, and frequency of

occurrences and likely hood of ignition/toxic release. Data are

analyzed considering likely damage (in terms of injury/fatality,

property damage) each scenarios is likely to cause.

QRA provides a means to determine the relative significance of a number

of undesired events, allowing analyst and the team to focus their risk

reduction efforts where they will be beneficial most.

Reynish Pharmachem Pvt. Ltd. project is hazardous in nature. The

QRA for this plant is based on Level 1 and Level 2. Table 2.3 in Chapter

2 gives the list of products (and their monthly production capacity) to be

manufactured in the proposed project.

7.3 HAZARDOUS MATERIALS STORAGE

The solid raw materials will be received in bags or drums and will be

stored in chemicals godowns. The bulk storages of hazardous materials

are given in the Table 7.1 below.

Table 7.1: Bulk Storage of Hazardous Chemicals

Sr.

No.

Name of solvent Maximum storage capacity

(KL)

1 Methanol 10 KL tank

2 Dichlo Methane 10 KL tank

3 Iso propyl alcohol 5 KL tank



4 Ethyl Acetate 5 KL tank

5 Sodium Hydroxide Lye 5 KL tank

6 HCl (30-32%) 10 KL tank

7 Sulphuric Acid 5 KL tank

8 Acetone 5 KL tank

9 Toluene 0.2 KL x 5 Drum=1.0 KL

10 Chloroform 0.2 KL x 5 Drum=1.0 KL

11 Benzoyl chloride 0.2 KL x 5 Drum=1.0 KL

12 Hexane 0.2 KL x 5 Drum=1.0 KL

13 Nitric acid 0.08 KL x 20 Carboys =1.6 KL

14 Dimethyl formamide 0.2 KL x 5 Drum=1.0 KL

7.4 RISK SCREENING APPROACH

Proposed Plant: Risk screening of Reynish plant was undertaken

through process study and study of data/information provided by

Reynish. Data of major/bulk storages of raw materials, intermediates and

other chemicals were collected. MSDS of hazardous chemicals were

studied vis a vis their inventories and mode of storage. Unit will be used

numbers of hazardous chemicals and also producing organic chemicals –

hazardous in nature. The chemicals stored in bulk (liquid or gaseous) and

defined under MSHIC Rule will be considered for detailed analysis.

The solid materials will be kept in bags or drums and will be stored in

chemicals godowns. The products (liquid or solid) will be packed in drums

and stored in product godowns as per market demand. The bulk storages

of hazardous materials are given in the Table 7.1 above. In addition,

Reynish will store fuels mainly Agro briquette for boiler, TFH & HAG and

HSD (in limited quantity) for DG Set (during power failure only). The solid

material-powder or granules spillage can results in polluting small area

only. The damage to personnel can be through ingress-dermal (if

individual come in contact), oral (if individual food gets infected through

fugitive dust) or inhalation (fugitive dust). The main route is fugitive dust

which in covered area will move to short distance only. The risk is

through liquid/gaseous materials which are volatile material. The toxic

vapours due to spillage of such material can travel to some distance (as

they are stored in covered godowns) and cause damage.

Reynish will be producing 15 Bulk Drug products. All Reynish products are

solid (Either simple Solid or crystalline solid or powder). Many of the



Reynish raw materials are hazardous in nature. However, hazards

potential (for damage) of materials/chemicals to plant personnel,

environment and off-site area is different for different materials. Reynish

will be using a number of raw materials but only 14 are stored in bulk.

The raw materials coming under hazardous category as specified by

MSIHC Rules, 1989 (including subsequent amendments) is given in Table

7.2 below:

Table: 7.2 Hazards Analysis – Raw materials (stored in Bulk)

Sr.

No.

Raw material Sr. No & Threshold

Quantity (TQ in MT) as

per MSHIC Rules

Chemicals Hazards Potential

Sch-1,

Part-II

Sch-2,

Part-I

Sch-3,

Part-I

1. Methanol

CAS No: 67-56-1

UN No: 1230

377 --- --- Highly flammable, Exposure to

excessive vapor causes eye

irritation, headache, fatigue and

drowsiness. High concentrations

can produce central nervous

system depression and optic

nerve damage.

2. Dichloromethane

CAS No.: 75-09-2

UN No.: 1593

-- --- --- Very hazardous in case of eye

contact (irritant), of ingestion, of

inhalation. Hazardous in case of

skin contact (irritant, permeator).

Inflammation of the eye is

characterized by redness,

watering, and itching.

3. Iso Propyl alcohol

CAS No: 67-63-0

UN No: 1219

334 --- --- Highly flammable, Vapors cause

mild irritation of eyes and upper

respiratory tract; high

concentrations may be anesthetic.

4. Ethyl acetate

CAS No: 141-78-6

UN No: 1173

247 --- --- Hazardous in case of ingestion, of

inhalation. Slightly hazardous in

case of skin contact (irritant,

permeator), of eye contact

(irritant).

5. Sodium Hydroxide

CAS No: 1310-730-2

UN No: 1823

571 --- --- Not flammable; Corrosive to

metals and tissue. Hazardous.

6. Caustic Lye

CAS No.: 1310-73-2

UN No.: 1824

--- --- --- Very hazardous in case of skin

contact (corrosive, irritant,


(irritant, corrosive), of ingestion.

Slightly hazardous in case of

inhalation (lung sensitizer).

7. Hydrochloric acid

CAS No: 7647-01-0

UN No: 1789

313 --- --- Inhalation of fumes results in

coughing and choking sensation,

and irritation of nose and lungs.

Liquid causes burns

8. Sulphuric acid

CAS No: 7664-93-9

UN No: 1830

591 --- --- Corrosive to all body tissues.

Inhalation of vapor may cause

serious lung damage. Contact

with eyes may result in total loss



Sr.

No.

Raw material Sr. No & Threshold

Quantity (TQ in MT) as

per MSHIC Rules

Chemicals Hazards Potential

Sch-1,

Part-II

Sch-2,

Part-I

Sch-3,

Part-I

of vision. Skin contact may

produce severe necrosis.

9. Acetone

CAS No. 67-64-1

UN No: 109

4 --- --- Hazardous in case of skin contact

(irritant), of eye contact (irritant),

of ingestion, of inhalation. Slightly

hazardous in case of skin contact

(permeator).

10. Toluene

CAS No: 108-88-3

UN No: 1294

628 -- --- The substance may be toxic to

blood, kidneys, the nervous

system, liver, brain, central

nervous system (CNS). Repeated

or prolonged exposure to the

substance can produce target

organs damage.

11. Chloroform

CAS No: 67-66-3

UN No: 1888

130 --- --- Toxic by inhalation. Irritating to

respiratory system. Exposure to

decomposition products may

cause a health hazard. Serious

effects may be delayed following

exposure. Toxic if swallowed.

Aspiration hazard if swallowed.

Can enter lungs and cause

damage. Irritating to skin.

12. Benzoyl chloride

CAS No: 98-88-4

UN No: 1736

65 --- --- A colorless fuming liquid with a

pungent odor. Irritating to skin

and eyes. Corrosive to metals and

tissue.

13. Hexane

CAS No: 110-54-3

UN No: 1208

306 --- --- Inhalation causes irritation of

respiratory tract, cough, mild

depression, cardiac arrhythmias.

Aspiration causes severe lung

irritation, coughing, pulmonary

edema; excitement followed by

depression. Ingestion causes

nausea, vomiting, swelling of

abdomen, headache, depression.

14. Nitric Acid

CAS No.: 7697-37-2

UN No.: 2031

423 --- -- Very hazardous in case of skin

contact (corrosive, irritant,


(irritant, corrosive), of ingestion,

Slightly hazardous in case of

inhalation (lung sensitizer). Liquid

or spray mist may produce tissue

damage particularly on mucous

membranes of eyes, mouth and

respiratory tract.

15. Dimethyl formamide

CAS No.: 68-12-2

UN No.: 2265

--- --- --- Irritation of eyes, skin and nose.

May cause nausea

Note: TQ-I: Threshold quantity (for application of rules 4,5,7 to 9 and 13 to 15)

TQ-II: Threshold quantity (for application of rules 10 to 12)



Table: 7.3 Properties of Hazardous materials

Chemicals Physical form

BP oC

FP oC

LEL %

UEL %

TLV ppm

LD50 mg/Kg or LC50 mg/l

Vapour Density

Specific Gravity

Methanol Liquid 64.5 12 6 36.5 250 LD50: 5628 LC50:64000

1.11 0.7915

Dichloro methane

Liquid 39.75 NA 12 19 50 LD50: 1600 LC50: --

2.93 1.32

Iso Propyl

alcohol

Liquid 82.5 18.3 2 12.7 400 LD50: 5045

LC50: --

2.07 0.84

Ethyl acetate Liquid 77 -4.4 2.2 9 400 LD50: 5620 LC50:16000

3.04 0.902

Sodium hydroxide

Solid 1388 NA NA NA 2 NA NA 2.13

Caustic Lye Liquid 140 NA NA NA 2 mg/m3

NA 0.62 (Water)

1.53

Hydrochloric acid

Liquid 108.58 NA NA NA 5 LD50: 900 LC50: 3124

1.267 1.1

Sulphuric acid Liquid 270 NA NA NA 3 LD50: 2140

LC50: 510

3.4 1.84

Acetone Liquid 56.2 -20 2.6 12.8 750 LD50: 5800 LC50: 50100

2 0.79

Toluene Liquid 110.6 4.44 1.1 7.1 300 LD50: 636 LC50: 440

3.1 0.8636

Chloroform Liquid 61 NA NA NA 10 LD50: 695 LC50: 47702

4.36 1.484

Benzoyl chloride

Liquid 198 72 1.2 4.9 1 LD50: 1900 LC50: 1870

4.88 1.211

Hexane Liquid 69 -26 1.2 7.5 50 LD50: 25000

LC50: 48000

2.97 0.659

Nitric acid Liquid 121 NA NA NA 4 NA 2.5 1.408

Dimethyl formamide

Liquid 153 58 2.2 15.2 10 LD50: 2800 LC50: 15

0.95 2.51

NA= Not Available

Note:

1. Oral Toxicity (OT) in LD50 (mg/kg)

2. Dermal Toxicity (DT) in LD50 (mg/kg)

3. Inhalation Toxicity in LC50 (mg/l) [4 hrs.]

Sr.

No.

Toxicity Oral toxicity

LD50 (mg/kg)

Dermal

toxicity LD50 (mg/kg)

Inhalation

toxicity LC50(mg/l)

1. Extremely toxic >5 <40 <0.5

2. Highly toxic >5-50 >40-200 <0.5-2.0

3. Toxic >50-200 >200-1000 >2-10

As detailed in the above table out of 14 raw materials stored in bulk,

none are listed in Schedule 2 and 3 of MSIHC Rules. None of the raw

materials are extremely toxic.

7.4.1 Acute Exposure Guideline Levels (AEGLS)

AEGLs estimate the concentrations at which most people - including

sensitive individuals such as old, sick, or very young people - will begin to

experience health effects if they are exposed to a hazardous chemical for



a specific length of time (duration). For a given exposure duration, a

chemical may have up to three AEGL values, each of which corresponds

to a specific tier of health effects. AEGLs of the materials at Reynish are

as below.

AEGL-3 is “the airborne concentration of a substance above which it is

predicted that the general population, including susceptible individuals,

could experience life-threatening adverse health effects or death.”

10 min 30 min 60 min 4 hr 8 hr Unit

Methanol (67-56-1)

AEGL 1 670 670 530 340 270 ppm

AEGL 2 11000* 4000 2100 730 520 ppm

AEGL 3 40000** 14000* 7200* 2400 1600 ppm

Dichloromethane (75-09-2)

AEGL 1 290 230 200 NR NR ppm

AEGL 2 1700 1200 560 100 60 ppm

AEGL 3 12000 8500 6900 4900 2100 ppm

Hydrogen Chloride (7647-01-0)

AEGL 1 1.8 1.8 1.8 1.8 1.8 ppm

AEGL 2 100 43 22 11 11 ppm

AEGL 3 620 210 100 26 26 ppm

Sulphuric acid (7664-93-9)

AEGL 1 0.20 0.20 0.20 0.20 0.20 mg/m3

AEGL 2 8.7 8.7 8.7 8.7 8.7 mg/m3

AEGL 3 270 200 160 110 93 mg/m3

Acetone (67-64-1)

AEGL 1 200 200 200 200 200 ppm

AEGL 2 9300* 4900* 3200* 1400 950 ppm

AEGL 3 ** 8600* 5700* 2500 1700 ppm

Toluene(108-88-3)

AEGL 1 67 67 67 67 67 ppm

AEGL 2 1400 760 560 310 250 ppm

AEGL 3 10000 5200 3700 1800 1400 ppm

Chloroform (67-66-3)

AEGL 1 NR NR NR NR NR ppm

AEGL 2 120 80 64 40 29 ppm

AEGL 3 4000 4000 3200 2000 1600 ppm

Hexane (110-54-3)

AEGL 1 NR NR NR NR NR ppm

AEGL 2 4000 2900 2900 2900 2900 ppm

AEGL 3 12000 8600 8600 8600 8600 ppm

Nitric acid (7697-37-2)

AEGL 1 0.16 0.16 0.16 0.16 0.16 ppm

AEGL 2 43 30 24 6 3 ppm

AEGL 3 170 120 92 23 11 ppm

NR = Not recommended due to insufficient data * indicates value is 10-49% of LEL. Safety consideration against explosions must be taken into account. ** indicates value is 50-99% of LEL. Extreme safety consideration against explosions

must be taken into account.





could experience irreversible or other serious, long-lasting adverse

health effects or an impaired ability to escape.”



could experience notable discomfort, irritation, or certain asymptomatic

no sensory effects.”

7.4.2 Emergency Response Planning Guidelines (ERPGs)

ERPGs estimate the concentrations at which most people will begin to

experience health effects if they are exposed to a hazardous airborne

chemical for 1 hour. (Sensitive members of the public - such as old, sick,

or very young people - aren't covered by these guidelines and they may

experience adverse effects at concentrations below the ERPG values).

ERPGs of the materials at Reynish are as below.

ERPG-1 ERPG-2 ERPG-3 Unit

Acetic acid 5* 35 250 ppm

Chloroform NA 50 5000 ppm

Dimethylamine 0.6* 100 350 ppm

Hydrogen Chloride 3* 20 150 ppm

Methanol 200 1000 5000 ppm

Sodium Hydroxide 0.5 5.0 50 mg/m3

Sulphuric Acid 2 10 120 mg/m3

Dichloromethane 300 750 4000 ppm

Toluene 50* 300 1000 ppm

*indicates that odor should be detectable near ERPG-1;NA=Not Appropriate

The 3 ERPG tiers are defined as follows:

ERPG-3 is "the maximum airborne concentration below which it is

believed that nearly all individuals could be exposed for up to 1 hour

without experiencing or developing life-threatening health effects."



without experiencing or developing irreversible or other serious health

effects or symptoms which could impair an individual's ability to take

protective action."



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without experiencing other than mild transient health effects or

perceiving a clearly defined, objectionable odor."

7.5 QRA APPROACH

Identification of hazards and likely scenarios (based on Level-1 and

Level-2 activities) calls for detailed analysis of each scenario for potential

of damage, impact area (may vary with weather conditions/wind

direction) and safety system in place. Subsequently each incident is

classified according to relative risk classifications provided in Table 7.4.

Table 7.4: Risk Classification

Stage Description

High

(> 10-2/yr.)

A failure which could reasonably be expected to occur within

the expected life time of the plant. Examples of high failure likelihood are process leaks or single

instrument or valve failures or a human error which could result in releases of hazardous materials.

Moderate (10-2 --10-4/yr.)

A failure or sequence of failures which has a low probability of occurrence within the expected lifetime of the plant.

Examples of moderate likelihood are dual instrument or valve failures, combination of instrument failures and human errors,

or single failures of small process lines or fittings.

Low

(<10-4)

A failure or series of failures which have a very low probability

of occurrence within the expected lifetime of plant. Examples of „low‟ likelihood are multiple instruments or valve

failures or multiple human errors, or single spontaneous failures of tanks or process vessels.

Minor Incidents Impact limited to the local area of the event with potent for

„knock – on- events‟

Serious Incident

One that could cause: Any serious injury or fatality on/off site;

Property damage of $ 1 million offsite or $ 5 million onsite.

Extensive

Incident

One that is five or more times worse than a serious incident.

Assigning a relative risk to each scenario provides a means of prioritising

associated risk mitigation measures and planned actions.

7.6 THERMAL HAZARDS

In order to understand the damages produced by various scenarios, it is

appropriate to understand the physiological/physical effects of thermal

radiation intensities. The thermal radiation due to tank fire usually results

in burn on the human body. Furthermore, inanimate objects like

equipment, piping, cables, etc. may also be affected and also need to be

evaluated for damages. Table 7.5, Table 7.6 and Table 7.7,



respectively give tolerable intensities of various objects and desirable

escape time for thermal radiation. Thermal hazards could be from fires or

explosion. Fire releases energy slowly while explosion release energy very

rapidly (typically in micro seconds). Explosion is rapid expansion of gases

resulting in rapidly moving shock wave. Explosion can be confined (within

a vessel or building) or unconfined (due to release of flammable gases).

BLEVE (boiling liquid expanding vapour explosion) occurs if a vessel

containing a liquid at a temperature above its atmospheric boiling point

ruptures. The subsequent BLEVE is the explosive vaporization of large

fraction of its vapour contents; possibly followed by combustion or

explosion of the vaporized cloud if it is combustible. Thermal hazards

have been considered for various scenarios including- Fire in inflammable

chemicals storage tanks.

Table 7.5: Effects due to Incident Radiation Intensity

Incident Radiation

kW/m2

Damage Type

0.7 Equivalent to Solar Radiation

1.6 No discomfort on long duration

4.0 Sufficient to cause pain within 20 sec. Blistering of

skin (first degree burn are likely).

9.5 Pain threshold reached after 8 sec. Second degree burn after 20 sec.

12.5 Minimum energy required for piloted ignition of wood, melting of plastic tubing etc.

25

Minimum Energy required for piloted ignition of

wood, melting, plastic tubing etc.

37.5 Sufficient to cause damage to process equipment.

62.0 Spontaneous ignition of wood.

Table 7.6: Thermal Radiation Impact to Human

Exposure

Duration

Radiation Energy

{1% lethality;

kW/m2}

Radiation Energy

for 2nd degree

burns; kW/m2

Radiation Energy

for 1st degree

burns; kW/m2

10 sec 21.2 16 12.5

30 9.3 7.0 4.0

Table 7.7: Tolerable Intensities for Various Objects

Sl.

No.

Objects Tolerable Intensities

(kw/m2)

1 Drenched Tank 38

2 Special Buildings (No window, fire proof doors)

25

3 Normal Buildings 14

4 Vegetation 10-12

5 Escape Route 6 (up to 30 secs.)



6 Personnel in Emergencies 3 (up to 30 secs.)

7 Plastic Cables 2

8 Stationary Personnel 1.5

7.7 DAMAGE DUE TO EXPLOSION

The explosion of a dust or gas (either as a deflagration or detonation)

results in a reaction front moving outwards from the ignition source

preceded by a shock wave or pressure front. After the combustible

material is consumed the reaction front terminates but the pressure wave

continues its outward movement. Blast damage is based on the

determination of the peak overpressure resulting from the pressure wave

impacting on the object or structure. Damage estimates based on

overpressure are given in Table 7.8 below:

Table 7.8: Damage due to Overpressure

Sr.

No.

Overpressure

(psig/bar)

Damage

1. 0.04 Loud Noise/sonic boom glass failure

2. 0.15 Typical pressure for glass failure

3. 0.5 - 1 Large and small windows usually shattered

4. 0.7 Minor damage to house structure

5. 1 Partial demolition of houses, made uninhabitable

6. 2.3 Lower limit of serious structure damage

7. 5 - 7 Nearly complete destruction of houses

8. 9 Loaded train box wagons completely demolished

9. 10 Probable total destruction of houses

10. 200 Limits of crater lip

In Reynish case explosion probability is remote.

7.8 TOXIC RELEASE

Hazardous materials handled and stored in bulk in Reynish complex are

hazardous materials (as detailed in Table 7.1) as defined in MSHIC rules

and indicated in Table 7.2. Some of these chemicals are stored in bulk

(in tank farm). For toxic release the damage criteria considered is IDLH

concentration (if data are available). The Immediately dangerous to life

or health air concentration values (IDLH values) developed by the

National Institute for Occupational Safety and Health (NIOSH)

characterize these high-risk exposure concentrations and conditions and

are used as a component of respirator selection criteria first developed in

the mid-1970s. IDLH values are established (1) to ensure that the worker



can escape from a given contaminated environment in the event of failure

of the respiratory protection equipment and (2) to indicate a maximum

level above which only a highly reliable breathing apparatus, providing

maximum worker protection, is permitted. IDLH of all the materials

stored in bulk at Reynish are as below.

IDLH Value Unit

Acetic acid 50 ppm

Acetone 2500 ppm

Chloroform 500 ppm

Dichloromethane 2300 ppm

Dimethylamine 500 ppm

Ethyl Acetate 2000 ppm

Hexane 1100 ppm

Hydrochloric acid 50 ppm

Methanol 6000 ppm

Sodium Hydroxide 10 mg/m3

Nitric acid 25 ppm

Sulfuric Acid 15 mg/m3

Isopropyl Alcohol 2000 ppm

7.9 ACID/ALKALI HAZARDS

Various hazards that can occur due to the acid and alkali incidents are-

Skin irritation and corrosive effects after spillage

Spill pool evaporation of sulphuric/hydrochloric acid or Caustic lye

storage tanks catastrophic failure are limited only

Catastrophic failure giving rise to spill pool evaporation dispersion

up to LC50, IDLH and TLV level

The more hazardous scenario likely is if spilled acid comes in contact with

metal and hydrogen is generated resulting in fire/explosion hazards.

Based on the outcome of the risk assessment, following recommendation

has been made to avoid any risk associated with the storage and use of

acids in the plant:

Double drain valve will be provided to sulphuric acid storage tank.

Full body protection will be provided to operator.

Caution note and emergency first aid will be displayed

All employees will be trained for use of emergency first aid.

Safety shower and eye wash will be provided in storage tank area

and plant area.

Total close process will be adopted for Sulphuric acid handling.



Dyke wall will be provided to storage tank

Tanker unloading procedure will be prepared.

SOP will be prepared for Hydrochloric acid handling.

Training programme will be conducted for safe handling and

emergency handling of Acids.

In storage tank area, reaction with water generating fumes should

be displayed and avoided.

Suitable extinguishing media-Extinguish with dry powder/sand. DO

NOT USE WATER.

7.10 LIKELY FAILURE SCENARIOS

Few likely failure scenarios have been selected after critical appraisal of

raw materials and storage inventories. Failure scenarios selected are as

given in Table 7.9 below:

Table 7.9: Different Failure Scenarios

S. No. Scenario Remark

RM-1 Methanol tank BLEVE Thermal

RM-2 Dichloromethane tank leakage Toxic

RM-3 Ethyl Acetate tank leakage pool fire Thermal

RM-4 Acetone tank leakage Toxic

RM-5 Hydrochloric Acid tank leakage Toxic



(B) QUANTITATIVE RISK ASSESSMENT & CONSEQUENCE ANALYSIS

7.11 PREAMBLE

In the previous Chapter we have carried out the hazards analysis of the

Reynish complex considering various aspects including bulk storages of

hazardous chemicals, plant process system, plant incidents/accidents

records, critical appraisal and discussion at site for soft spots in the plant

etc. Based on the hazards analysis few critical scenarios have been

selected for QRA and consequence analysis. QRA quantifies vulnerable

zones for a conceived incident with various levels of severity.

Consequence calculations for risk assessment are invariably in terms of

percentage of fatalities but for emergency handling, fatalities are of no

interest saving lives is the main objectives then. The injury criteria have

to be agreed in terms of thermal load or toxic concentration versus

exposure duration in the first instance.

In consequence calculation, use is made of a number of calculation

models to estimate the physical effects of an accident (spill of hazardous

material) and to predict the damage (lethality, injury, material

destruction and other property damage). The risk assessment modelling

can be roughly divided into three groups:

Determination of source strength parameters;

Determination of consequential effects;

Determination of damage or damage distances (with specific severity

rates)

7.11.1 Weather Effect

The effect of ambient conditions on the impact of fire/heat radiation and

GLC of hazardous/toxic material can be beneficial as well as harmful. A

high wind (turbulence) can dilute the toxic material while stable

environment can extend the reach of IDLH or IT (inhalation LC50 rats for

products) concentration to long distance. Any inflammable gas/vapour

release in turbulent weather will soon dilute the hazardous gases below

LEL and thus prevent the disaster.

7.12 INCIDENTS IMPACTS

The identified failure scenarios (Table 7.9) have been analyzed (Using

ALOHA and EFFECT Modules) for the impact zones considering damage



due to thermal and toxic impacts. Each incident will have Impact on the

surrounding environment which in extreme case may cross plant

boundary. The impact zones for various scenarios are given in Table

7.10.

Figure-7.1 Methanol Tank BLEVE — Thermal Impact Zone

Figure-7.2 Dichloromethane Tank Leakage — Toxic Impact Zone



Figure-7.3 Ethyl Acetate Tank Leakage Pool Fire —Thermal Impact Zone

Figure-7.4 Acetone Tank Leakage — Toxic Impact Zone

Figure-7.5 Hydrochloric Acid Tank Leakage – Toxic Impact Zone



Table 7.10: Hazards Scenario Impact

Scenario Impact Zone (m)

Methanol tank

BLEVE

Red : 161 meters --- (10.0 kW/(sq m) = potentially lethal within 60 sec)

Orange: 234 meters --- (5.0 kW/(sq m) = 2nd degree burns within 60 sec)

Yellow: 369 meters --- (2.0 kW/(sq m) = pain within 60 sec)

Dichloromethane

tank leakage

Red : 79 meters --- (6900 ppm = AEGL-3 [60 min])

Orange: 378 meters --- (560 ppm = AEGL-2 [60 min])

Yellow: 739 meters --- (200 ppm = AEGL-1 [60 min])

Ethyl Acetate tank

leakage pool fire

Red : 29 meters --- (10.0 kW/(sq m) = potentially lethal within 60 sec)

Orange: 37 meters --- (5.0 kW/(sq m) = 2nd degree burns within 60 sec)

Yellow: 51 meters --- (2.0 kW/(sq m) = pain within 60 sec)

Acetone tank

leakage



Yellow: 536 meters --- (200 ppm = AEGL-1 [60 min])

Hydrochloric Acid

tank leakage


Note: Threat zone was not drawn because effects of near-field patchiness

make dispersion predictions less reliable for short distances.


Note: Threat zone was not drawn because effects of near-field patchiness

make dispersion predictions less reliable for short distances.

Yellow: 116 meters --- (1.8 ppm = AEGL-1 [60 min])

7.13 CONSEQUENTIAL IMPACTS

The consequential impacts from each incident scenarios can be though

thermal, over pressure wave and toxic route. The damage can be on

plant personnel (and neighbouring residents in case incident crosses

boundary), property and also loss in production.

7.13.1 Thermal and Explosion Hazards

Incidents involving thermal hazards are mainly due to BLEVE and fire (in

tank farms). The impact (1st degree burn due to Methanol tank BLEVE) is

limited to ~161 m (i.e. within plant boundary and adjoining premises).

However the consequences can go to worse if the incidents lead to

domino effect to other tanks.

7.13.2 Toxic Hazards

Toxic hazards are mainly due to Dichloromethane, Acetone, and

Hydrochloric Acid tank leakage/spillage. The impact (AEGL-3) is limited to

~79 m (i.e. within plant boundary and adjoining premises). However,

their impact can cross the plant boundary and adjoining premises (if not

controlled in time).



7.13.3 Other Hazards

The other hazards in the plant include (but not limited to):

Other toxic hazards due to acids/other toxic spillages (mainly limited

to spillage area only).

Mechanical hazards due to machines/equipment.

Hazards due to individual soft spots like walking casually and noticing

a pit and falling or colliding/stumbling or slipping (not noticing a wet

place etc.).

7.13.4 Other Toxic Hazards

Acid spillage-its impact will be limited to spillage area. The spillage if

comes in contact with metal parts will produce hydrogen which is highly

flammable gas. Any person moving in area and getting splash will get the

injury. In addition the spillage will cause pollution problem. The spillage is

to be collected and neutralized for toxic contents before disposal.

7.14 OCCUPATIONAL HEALTH

Reynish will have a well-equipped first aid post. It will also have staff

personnel trained in first aid. Injured personnel will be immediately

rushed to hospital after giving first aid. All employees will have regular

medical checkup as per norms. An emergency vehicle/ambulance will

always (round the clock) available for meeting any eventuality.

Treatment of workers affected by accidental spillage of chemicals

There is wide range of chemicals present in the Chemical plants. The safe

cleanup of a chemical spill requires some knowledge of the properties and

hazards posed by the chemical & any added dangers posed by the

location of the spill. Employees must notify their immediate supervisor of

injury by spillage of chemicals or exposure to hazardous materials. All

injuries must be reported. Supervisor is responsible for reporting any

injuries or occupational illnesses to the management.

Following steps will be immediate taken by the Supervisor.

Identify spillage/leakages of hazardous chemicals

Chemical Exposure to Skin:

Immediately flush with cool water for at least 15 minutes. If there are no

visible burns, remove the cloth from burning part of body. Seek medical

attention if exposure/spillages occur major possible problems.



Chemical Exposure to Skin – Serious:

Remove all contaminated clothing. Locate the nearest emergency shower

and soak for at least 15 minutes. Have someone contact the Hospital for

immediate medical attention.

Chemicals in Eyes:

Irrigate eyes for at least 15 minutes with tempered water from

emergency eyewash station. Remove contact lenses if there is. Notify the

management and immediate medical attention.

Acid Fumes:

Anyone overcome by fumes should be removed to fresh air. Never

attempt to enter a location where potentially dangerous fumes might

place you at risk. If someone is down, contact emergency personnel and

let them enter. Self-breathing apparatus is required for persons entering

the affected area. Seek medical attention for exposure as soon as

possible.

Chemical Spills:

The safe clean-up of an acid spill requires some knowledge of the

properties and hazards posed by the acid and any added dangers posed

by the location of the spill. If you believe a spill is beyond your capacity

to clean up, do not attempt to do so by your own, immediately contact to

nearest fire/emergency station. Spill kits with instructions, absorbents,

neutralizing agents if applicable, protective equipment, and sealable

waste buckets should be present in plant area.

Following Steps to be taken for ensuring health and safety of

workers engaged in handling of Hazardous materials

Identify chemicals to be used, amounts required, condition followed as

per the MSDS guideline.

Evaluate the hazards posed by the chemicals and the process

conditions. The evaluation should cover toxic, physical, reactive,

flammable, explosive as well as any other potential hazards posed by

the respective chemicals.

Select appropriate controls to minimize risk, including use of

engineering controls, administrative controls, and personal protective

equipment (PPE) to protect workers from hazards. The controls must



ensure that OSHA‟s Permissible Exposure Limits (PELs) are not

exceeded.

Avoid Underestimation of Risk of handling and its reaction.

Before working with chemicals, know the facility‟s policies and

procedures for how to handle an accidental spill or fire. Emergency

telephone numbers should be posted in a prominent area. Know the

location of all safety equipment and the nearest fire alarm and

telephone.

Provide popper Ventilation in the plant/process area.

Corrosive chemicals that require vented storage should be stored in

vented cabinets instead of in a chemical hood.

Local exhaust ventilation devices should be appropriate to the

operations in the plant.

Chemicals should be separated and stored according to hazard

category and compatibility.

Antidotes

Antidotes are used to reduce morbidity and mortality in certain

intoxications, but they are unavailable for most toxic agents. Antidotes

may reverse or reduce poisonous effects by a variety of means. They

may prevent absorption, bind and neutralize poisons directly, antagonize

end‐organ effects, or inhibit conversion to more toxic metabolites. The

antidotes considered to be stored at Reynish and/or supplied to nearest

hospital are shown below.

Name of Antidote Usage

Inj. Avil/ Inj. Dexona Allergic/Anaphylaxis Reaction

Inj. Bal Heavy Metal, Mercury, Lead, Arsenic

Inj. Sneak Venom Sneak Bites

Inj. Adrenalin/ Inj. Atropine Poisoning

Inj. Deriphyllin Abnormal Breathing

Inj. Voveran Pain Relief

Milk of Magnesia Gastric Problems

T.T For Tetanus

Calmpose (Diazepam) Convulsion



7.15 CONCLUSION & RECOMMENDATIONS

The hazard analysis and risk assessment of few possible selected incident

scenarios indicates that such incidents mostly are not limited to plant

battery limits and have impact on adjoining plants. There are possibilities

of domino effect and the secondary scenario not predictable can be worse

than the primary one.

Incidents involving thermal hazards are mainly due to BLEVE and fire (in

tank farms). The impact (1st degree burn due to Methanol tank BLEVE) is

limited to ~161 m (i.e. within plant boundary and adjoining premises).

Toxic hazards are mainly due to Dichloromethane, Acetone, and

Hydrochloric Acid tank leakage/spillage. The impact (AEGL-3) is limited to

~79 m (i.e. within plant boundary and adjoining premises). The direction

of impact will be in down wind direction (wind direction and speed varies

with season).

Some of the recommendations for Tank farm storage system are as given

below:

Provision of flame detectors/ thermal sensors at strategic locations in

the tank farm area.

Auto water deluge system on each bulk storage tank for inflammable

liquids. The system should automatically start taking signal from flame

detectors or thermal relay.

Fixed foam system with adequate capacity.

Regular „Hazard Survey‟ ensures the detection of leakage in the plant. In

house „capability building‟ to attend hazardous scenarios is to be taken up

through mock drills. Train staff in attending such scenarios.

Human Factors: Reynish should have well equipped Toxic and fire

handling system and also safety department – safety practices. Human

factors role in safety cannot be ignored. Odd hours working and over/long

hours work can drain out individual. It shows in lack of efficiency and also

the lack of apt attention the modern chemical complex demand.

„Safety‟ has unique features:

If no accident has happened so far probability of incident/accident

occurring increases.



„No accident‟/good safety record develops complacency inertia/over

confidence in the team. This attitude gives rise to gaps/soft spots in

the system giving chances to incidents/accidents.

Safety requires novelty. Routine training practices get stale with no

positive results. Look for novel scheme of training/ safety practices

to build up fresh impetus in safety. Involvement of employees with

refreshed outlook for safety is to be achieved.

7.16 ACTION PLAN FOR HANDLING & SAFETY SYSTEM OF CHEMICAL

Flammable chemicals will be stored in open area outside the process

plant with all the safety measures. Hazardous chemicals will be stored

and handle in dispensing room for taking out sample from the container

for quality check-up purpose or for the partial use. This activity for

Hazardous material handling will be carried out by using all PPEs with

proper ventilation & under supervision.

7.16.1 Safety Measures for Transportation and Unloading of Hazardous

Chemicals

Solvent unloading standard procedure will in place and will be

implemented for safe unloading of road tanker.

Static earthing provision will be made for tanker unloading.

Drum handling trolleys will be used for transportation of drums up to

plant and internal handling from storage to process area.

Display Boards will be provided on all storage tanks which include the

name of the chemicals and its major hazardous characteristics.

Fire extinguishers will be provided as required.

First aids boxes will also be provided at different places wherever

required.

Water showering system will be provided to the flammable chemicals

storage area.

Area will be declared as “NO SMOKE ZONE”.

7.16.2 Safety Measures for Storage/Handling of Hazardous Chemicals

All Hazardous and flammable chemicals will store separately and away

from the strong oxidant & kept it in well ventilated room. Adequate

firefighting system will be installed. Safety shower and eye washer will be

installed near storage area. Flame proof light fitting will be provided at



storage area. Sprinkler system will be installed near storage area. Safety

permit system will be followed for loading and unloading. Isolate storage

will be provided with wire fencing under lock and key. Caution note,

hazardous identification board will be provided. Only authorized person

will be permitted in storage area and register will be maintained. “NO

SMOKING” board will be displayed and Wind Indicator and siren will be

provided.

7.16.3 Safety Measures for Process Units

Safety measures are the most important aspect of selection of process

technology to ensure safety in production unit. For the safety in

production area some important critical safety measures will be provided

within the process technology/equipment itself & will put continue efforts

for developing new technology/equipment. Company will ensure such

provision in the technology/equipment/machineries at time of purchase.

The details of the critical safety measures for process unit are as below;

any reaction upsets will be confined to the reaction vessel itself as

defined quantity of raw materials will be issued to the reaction vessel by

metering pumps/load cells. Process parameters control will be provided

as per SOP- Standard Operating Procedures. Materials will be transferred

by pumping through pipeline or by vacuum from drums. All reaction vents

will be connected to vapor condensers system. Hazardous materials will

be transferred by pipelines and in controlled manners. Trained person will

be engaged for handling of hazardous materials. Proper safety

precautions will be taken during handling of hazardous materials. All

solvents and flammable material with required quantity will be charge in

reactor by pump or by gravity. All the vessels will be examined

periodically by a recognized competent person. All the vessels and

equipments will be well earthed appropriately and well protected against

Static Electricity. Temperature indicators will be provided near all reactor

and distillation systems. Flame proof light fittings will be installed in the

plant. All the Plant Personnel will be provided with Personal Protection

Equipments to protect against any adverse health effect during

operations, leakage, spillages or splash. PPE like Helmets, Safety Shoes

and Safety Glasses will be provided to the employees.



7.16.4 Safety Measures for Preventive Maintenance

The safety measures in the form of the general Do's & Don'ts for safety in

process & other plant area are as below:

Do not work on equipments without permission from plant head and

maintenance head.

Make sure equipment is empty and flushed with nitrogen and air.

Check VOC content for flammable and make sure that no flammable

vapour contents.

Keep proper and adequate fire extinguisher near work area.

Use proper PPE.

Do not allow any employment without pre-medical check-up or without

checking fitness.

Work in any equipment must be conducted in presence of supervisor.

Additional safety measures in form of the checklist covering Do's &

Don'ts of preventive maintenance, strengthening of HSE,

manufacturing utility staff for safety related measures will be updated

timely and will be made available to all concern department &

personnel.

7.16.5 Safety measures to prevent spillage/leakage of toxic chemicals

The preventive maintenance will be planned and carried out as per plan

to avoid the failure of valve, pipelines and other component of

transferring line. The spillage will be confined to the dyke area

underneath the vessel. The resultant splash of such chemicals will result

in exposure of toxic chemicals to employees. Decontamination facilities

(Safety shower and eye wash fountains) will be provided in the plant

area, which can be used to decontaminate the affected employees.

Suitable decontamination procedure will be used to decontaminate the

spilled or leaked material. The SOP for decontamination will be available

with all related department.

7.17 ARRANGEMENTS FOR ENSURING HEALTH AND SAFETY OF

WORKERS ENGAGED IN HANDLING OF TOXIC MATERIALS

The significance of Safety & Health in plant has been a vital issue in

achieving productivity and quality standard. Following is an effort for

safety & health of workers working in the plant. Numbers of chemicals



are used in plant have specific health hazards in nature. Following are

basic fundamental principles properly underlie all the workers working in

the plant. Occupational health and safety is about preventing people from

being harmed by work or becoming ill from work by taking adequate

precautions and providing a safe and healthy work environment.

Consideration of each should be encouraged before beginning work as

part of the culture of safety within the plant.

Plan ahead. Determine the potential hazards associated with

production.

Minimize exposure to chemicals. Do not allow toxic chemicals to

come in contact with skin. Provide proper ventilation devices to

prevent/minimize airborne.

Do not underestimate hazards or risks. Assume that any mixture

of chemicals will be more toxic than its most toxic component. Treat

all the chemicals as toxic substances.

Be prepared for accidents. Before beginning of any batch reaction,

know what specific steps to take which cause to accident if any

hazardous substance release accidently. Proper follow SOP- Standard

Operating procedure to take batch reaction.

Unit will assess is careful examination of what, at work, could cause harm

to workers, accidents and ill health. All risks in the workplace must be

identified and assessed for control measures to be put in place.

Follow the five steps of hazard identification will be taken by unit namely;

Identify the hazards

Decide who might be harmed and how

Evaluate the risks and decide on precaution

Record your findings and implement them

Review your assessment and update if necessary

Following Information workers should know regarding hazardous

chemicals

Unit shall ensure that the employee is adequately trained with regard to:

The contents of the hazardous chemical substances

Potential source exposure to chemicals



Measures taken by the employer to protect employees against any risk

from exposure

Precautions to be taken by an employee to protect himself against the

health risks associated exposure

Correct use, maintenance of safety equipment, facilities and

engineering controls

Importance of good housekeeping at the workplace & personal hygiene

Safe working procedures

Procedures to be followed in the event of spillages or leakages.

(C) DISASTER MANAGEMENT PLAN (DMP)

Disaster/Emergency Management Plan is essential for a chemical plant as

the processes adopted for manufacturing are classified under Factory Act

as Hazardous due to handling and storage of toxic, flammable and

explosive hazardous materials. DMP is proposed here is to meet the

extremely adverse situations caused by the various hazardous accident

scenarios. Mock drills are to be carried out in association with district

authorities. Any weak points observed during the mock drills are to be

strengthened.

Primarily, DMP is prepared to furnish details which may require at the

time of the emergency, to delegate responsibility, to estimate the

consequences in advance and to prepare ourselves to control any type of

emergency. The plan explains basic requirements as follows:

Definition,

Objectives,

Organization set up,

Communication System,

Action on site,

Link with Off-site Emergency Plan,

Training rehearsal and record aspect.

Definitions

Various definitions on different analogy used on On-site & Off-site

Emergency Plan are as follows:



Accident: An accident may be defined as “an undesirable and unplanned

event with or without or major damage consequence of life and /or

property.

Major Accident: It is a sudden, unexpected, unplanned event resulting

from uncontrolled developments during an industrial activity, which

causes or has the potential to cause, death or hospitalization to a number

of people, damage to environment, evacuation of local population or any

combination of above effects.

Emergency: This can be defined as any situation, which presents a

threat to safety of person's or/and property. It may require outside help

also.

Major Emergency: Occurring at a work is one that may affect several

departments within and/or may cause serious injuries, loss of life,

extensive damage to properly or serious disruption outside the works. It

will require the use of outside resources to handle it effectively.

Disaster: Disaster is a sudden calamitous event, bringing great damage,

loss or destruction.

Hazards: Hazard may be defined as “the potential of an accident”.

Hazard exists in man and the system of materials and machines.

Chemical Hazards: It is a hazard due to chemical(s) (including its

storage, process, handling, etc.) and it is realized by fire, explosion,

toxicity, corrosively, radiation, etc.

Risk: Risk may be defined as the combination of consequence and

probability or likelihood of an accident being caused in a given man-

material – machine system.

On-Site Emergency plan: It deals with measures to prevent and control

emergencies within the factory and not affecting outside public or

environment.

Off-Site Emergency plan: It deals with measures to prevent and

control emergencies affecting public and the environment outside the

premises.

Objective of the Disaster Management Plan

The DMP document is prepared keeping in view and to confirm the

requirements of the provisions of The Factories Act, 1948, Guidelines



issued by the MoEF&CC and MSIHC, 1989 amended in 2000, Schedule 11

under Environmental Protection Act, 1986.

Following are the main objectives of the plan to:

Defined and assess emergencies, including hazards and risk

Control and contain incidents.

Safeguard employees and people in vicinity.

Minimize damage to property and/or the environment.

Minimization of risk and impact of event accident.

Preparation of action plan to handle disasters and to contain damage.

Inform employees, the general public and the authority about the

hazards/risk assessed, & role to be played in the event of emergency.

Be ready for 'mutual aid' if need arises to help neighbouring unit.

Inform authorities and mutual aid centres to come for help.

Effect rescue and treatment of casualties.

Effective rehabilitation of the affected persons and prevention of

damage to the property.

Secure the safe rehabilitation of affected areas & to restore normalcy.

Provide authoritative information to the news media.

7.18 ONSITE EMERGENCY PLAN

7.18.1 Incident Controller

Incident Controller‟s role is to control the emergency at the incident site.

7.18.1.1 Duties of Incident Controller

Incident Controller will proceed to the place of emergency after hearing

siren/announcement. He will:

Assess the scale of emergency and decide if a major emergency exists

or is likely, accordingly activate emergency procedure.

Immediately give his feedback to Emergency Control Centre (ECC)

regarding emergency.

Direct all operations within the area with following priorities.

o Secure the safety of personnel

o Minimize damage to plant property and environment.

o Minimize loss of material.

Direct rescue and firefighting operations till the arrival of the outside

Fire Brigade; he will relinquish control to Sr. Officer of Fire Brigade.



Ensure that the affected area is searched for causalities.

Ensure that all non-essential workers in the affected area evacuate to

the appropriate assembly point.

Set up communication point to establish Radio/Telephone/Messenger

contact as with emergency control centre.

Pending arrival of works site controller, assume the duties of the post

in particular to:

o Direct the shutting down and evacuation of plant and areas likely to

be threatened by emergency.

o Ensure that the outside emergency services have been called in.

Ensure that the key personnel have been called in.

Report all significant development to the Site Main Controller.

Provide advice and information, as required to the Senior Officer of the

Fire Brigade.

Preserve evidence that would facilitate any subsequent inquiry into the

cause and circumstances of emergency.

Dy. Incident Controller will carry out above said duties in absence of

Incident Controller.

7.18.2 Site Main Controller

Site Main Controller will be overall in-charge of emergency organization.

7.18.2.1 Duties of Site Main Controller:

Relieve the Incident Controller of responsibility of overall main control.

Co-ordinate ECC or if required, security for raising evacuation siren

and also all clear siren, in case emergency is over.

Declaration of major emergency ensures that outside emergency

services will be called and when required nearby firms will be

informed.

Ensure that key personnel will be called in.

Exercise direct operational control on parts of the works outside the

affected area.

Maintain a speculative continuous review of possible development and

assess these to determine most possible cause of events.

Direct the shutting down and evacuation of plants in consultation with

key personnel.



Ensure causalities are receiving adequate attention; arrange for

additional help if required. Ensure relatives are advised.

Ensure the accounting of personnel.

Control traffic movement within the work.

Arrange for a chronological record of the emergency to be maintained.

During prolonged emergency, arrange for the relief of the personnel

and provision of catering facilities.

Contact the local office to receive early notification of impending

changes in weather conditions, in case of prolonged emergency.

Issue authorized statements to the news media and informs H.O.

Ensure that proper consideration is given to the preservation of

evidence.

Control rehabilitation of affected areas after control of the emergency.

7.18.3 Other Key Personnel

The key personnel required for taking decision about further action for

shutting down the plant, evacuate the personnel, and carry out

emergency engineering works in consultation with Site Main Controller in

light of the information received. HOD‟s /Senior Managers/ Section Heads

will be responsible for safety, security, fire, gas and pollution control,

spillage control, communication system including telephone, wireless etc.

Also medical services, transport, engineering, production, technical

services, will form part of advising team.

7.18.3.1 Emergency Response Team

The role of Emergency Response Team members is to actually combat

the emergency at the site and control the emergency situation and carry

out rescue operations. All team members will be thoroughly trained to

deal with fires, explosions, chemical spills and atmospheric releases, first

aid. As per priority list during emergency, the activities will be carried

out as per emergency control plan.

7.18.3.2 Emergency Personnel’s Responsibilities outside Normal

Working Hours of the Factory.

The duties of Shift In-charge & team members have been brought out

in emergency control plan. All team members after evacuating the area

shall report to ECC/Incident Place. The non-essential workers shall be



evacuated from the plants if need arises and this will be determined with

the forcible rate with which incident may escalate. Non-essential workers

shall assemble at the earmarked/specified point of assembly.

7.18.3.3 Assembly Points

At the proposed plant, at least 2 assembly points will be identified and

marked properly.

7.18.4 Emergency Control Centre

It will be headed by Site Main Controller, HOD – PD, HOD- P&A and it is

sited in Office of Site Main Controller in Admin Building & New

security office (after office hours), which is readily accessible & with

minimum risk, equipped with telephone facilities and other

announcements extra communications facilities needed. It has enough

means to receive and transmit information and directions from site main

controller to incident controller and other areas. In emergency control

centre due to its safer location and advantage of easier accessibility, all

necessary personnel protective equipment‟s fire-fighting extinguishers

will be stocked in sufficient quantity.

7.18.4.1 Role of Emergency Control Centre

In case of mishap or accident like fire, toxic gas leakage, explosion in the

factory, The Emergency Control Centre will be Office of Head-Operations.

The plot plan indicating all the activities in the factory premises

including storage‟s utility services, production area, administration, will

be kept for ready reference, showing the location of fire hydrant and

fire-fighting aids.

Normal role of employees, work permits, gate entries and documents

for head count, employees blood group, other information and

addresses will be available.

Stationery required is available in the Control Centre (ECC) and HOD

(P & A) looks after it.

The requirement of personnel protective equipment and other

material, like torches, have been worked out and the quantity required

during emergency will be kept in the Control Room (ECC). The

responsible person for maintaining the said requirement/inventory will

be HOD-HSE.



7.18.5 Fire & Toxicity Control Arrangements

The plant will be well equipped with suitable numbers of fire-fighting and

personnel protective equipment. The staff will be trained regularly to

handle the various emergency situations.

7.18.6 Medical Arrangements

Availability of first aid facilities in sufficient quantity will be always

ensured. In case of emergency arrangements will be made to avail

outside medical help immediately.

7.18.7 Transport & Evacuation, Mutual Aid Arrangements

Emergency Transport & Evacuation and Mutual Aid arrangements will be

available in the factory.

7.19 COMMUNICATION SYSTEM

7.19.1 Declaring the Emergency

In case of any emergency in the plant, speedy and effective

communication of the same to all concerned in least possible time is the

most important aspect of any emergency-handling plan. An early

communication increases the chances of control of emergency in the bud

stage. Blowing siren will be adopted as method of communication of

emergency, to all employees in the plant.

7.19.1.1 Type of Sirens

Three different types of sirens have been identified for communication of

emergency.

Alert Siren: Single Continuous Siren for One Minute. This indicates

that there is some accidental happening in the plant. All have to become

alert. Incident controller will be rush to the site of emergency. Plant area

people have to start safe shut down. Rescue team and other emergency

control teams have to reach at the site of emergency.

Siren for evacuation: wailing & waning siren for three minutes.

This siren indicates that emergency is of serious proportion and

everybody has to leave his work place. All people having their role in

emergency control have to assume their assigned role. All non-essential

workers have to proceed immediately to assembly area and wait for

further instruction.



All clear siren: Long continuous siren for two minutes. This is a sign

of return of normalcy. On hearing this siren everybody should go back to

his or her respective workplace.

7.19.1.2 Location of Siren

Siren will be located in centre of the pant for wide coverage of the whole

campus. Switch for siren will be provided at security gate. The switch at

Security gate should be operated only as a general rule.

Emergency manual call bell will be installed which will be used in case of

total failure of electricity. It is responsibility of HOD (HSE) to maintain the

upkeep of electric call bell and HOD- Security and administration to

maintain manual and Hand operated siren.

7.19.1.3 Raising Alarm

Any person noticing any emergency situation in the plant should

immediately call security gate with following information:

Identify oneself

State briefly the type of emergency i.e. whether fire, explosion, toxic

gas release etc.

Give the location of the incident

Estimated severity of the incident

Security personnel after ensuring genuineness of the call shall raise the

ALERT SIREN. At the same time, he will also contact the incident

controller and ECC in order and inform about the incident. He will keep

the gate open and rush his two security personnel at the site of

emergency with appropriate PPEs. ECC will be located at the office of

Head-Operations on normal working hours and at Security gate after

normal working hours (during night). ECC shall be immediately manned

on hearing alert siren. If the authorized people to handle ECC are not

available, any senior most people out of the available person nearby shall

occupy ECC till authorized person comes. Incident controller, on hearing

alert siren or by any other way of information of the emergency, will

immediately reach at the site of incident and assess the situation. He will

immediately give his feed back to ECC. ECC shall direct security gate to

raise evacuation siren, if the need arise. SIREN FOR EVACUATION shall

be raised on instruction from Site Main Controller or any Manager of the



plant in the ECC. Security gate person will be authorized to raise ALL

CLEAR SIREN on instruction from Site Main Controller or ECC, after the

emergency is over.

7.19.2 Internal Communication

It shall be responsibility of ECC to communicate to all employees in the

plant. They may take help of telephone operator for such communication.

However, telephone operator can directly communicate information about

emergency to all internal departments, if such message comes from

incident controller or site main controller. Telephone operator will

continue to operate the switchboard advising the callers that staffs are

not available and pass all calls connected with the incident to ECC.

7.19.2.1 Availability of Key Personnel outside Normal Working Hours

The details of key personnel availability after working hours will be made

available at Security Gate, ECC, telephone operator as well as production

units. Security personnel shall call required key personnel from their

residence in case emergency occurs outside normal working hours.

Availability of emergency vehicle/Ambulance will be ensured to fetch the

key personnel residing outside. It will be the responsibility of HOD (P & A)

to maintain it.

To the Outside Emergency Services

Decision to call outside help to deal with emergency like fire brigade,

ambulance, police, etc., shall be taken by Site Main Controller. However,

in absence of Site Main Controller, if the incident controller realizes the

situation going out of control, he may ask for immediate help from

outside. ECC will be responsible for calling help from outside. A list of

emergency services available in the area with their telephone numbers

will be provided at ECC, at Security gate and with telephone operator.

Facilities such as phones, emergency vehicle, and security personnel will

be available to help calling outside emergency services and authorities.

7.19.3 Communication to the Authorities

The emergency will be immediately communicated to the government

officers and other authorities such as SPCB, police, district emergency

authority, Factory Inspectorate, hospital etc. by Emergency Control

Centre.



Communication to Neighboring Firms & the General Public

In case of emergency having its outside impact, public will be cautioned

regarding the same. Co-ordination of police will be sought for speedy

action. This is to be ensured by ECC.

7.20 Pre-emergency activities

Internal Safety survey with regard to identification of hazards, availability

of protective equipment‟s, checking for proper installation of safety

devices will be carried out periodically.

Periodic pressure testing of equipment

Periodic pressure testing of lines

Periodic safety/relief valve testing

Periodic fire hydrant system testing

Mock drill to check up level of confidence, extent of preparedness of

personnel to face emergency is being contemplated

Regular training is being imparted to all personnel to create awareness

Adequate safety equipment will be made available

Periodic check-up of emergency lights

Safer assembly points will be identified

Storage of adequate first aid treatment facilities

7.21 POST-EMERGENCY ACTIVITIES

Following post emergency actions will be carried out to study in detail and

preventive measures to be taken

Collection of records

Inquiries

Insurance claims

Preparation of reports comprising suggestion and modification

Rehabilitation of affected personnel

Normalization of plant

7.21.1 Evacuation and Transportation

In case of emergency, evacuation and transportation of non-essential

workers will be carried out immediately. The affected personnel will be

transported for medical aid.



7.21.2 Safe Close Down

During emergency plant shut down will be carried out if situation

warrants. This will be as per the instruction of site main controller under

guidance of incident controller.

7.21.3 Use of Mutual Aid

Mutual aid agreement with nearby industries will be ensures to provide

help to each other in the emergency,

7.21.4 Use of External Authorities

As and when necessary, statutory authorities, police, pollution control

personnel, medical aid/center, ambulance etc. will be contacted.

7.21.5 Medical Treatment

The affected personnel will be brought to safer place immediately to give

them first aid. Immediate medical attention will be sought.

7.21.6 Accounting for Personnel

Proper accounting for personnel will be laid down in all the shifts. The

number of persons present inside the plant premises, their duty etc. will

be available with the P & A. This record will be regularly updated.

7.21.7 Access to Records

The relatives of affected personnel will be informed. The details regarding

all employees will be made available to Administration building.

7.21.8 Public Relations

In case of emergency, Manager P & A will be available for official release

of information pertaining to the incident.

7.21.9 Rehabilitation

The affected area will be cleared from emergency activities only after

positive ascertaining of the system in all respects. The entry to affected

area will have to be restricted until statutory authorities visit and inspect

the spot of incident. The site main controller will be in charge of the

activities to be undertaken. The plan will cover emergencies, which can

be brought under control by the works with the help of emergency

team/fire services. The DISASTER CONTROL PLAN for gas leak and fire

will be prepared for entire factory.



7.22 CAUSES OF EMERGENCY

7.22.1 Risk

7.22.1.1 Nature

In the plant, the nature of dangerous events could be of the following:

Fire : Chemical/Electrical

Toxic Release : From chemicals

Leakages : Equipment, pipelines, valves, etc.

Improper handling of products (raw materials/finished products)

Large spillage to ground floors resulting in pollution & fire.

Failures of Equipment/Instruments.

Release of safety valves or ruptures of vessels due to excessive

pressures.

7.22.1.2 Various Emergency Actions

a) Onsite

Safe shut down of the plant and utilities

Emergency control measures.

To attempt with the help of trained crew in firefighting to contain the

fire spread up/gas emission and limit within limited space.

To cut off source of oxygen by use of firefighting appliances.

Cut off fall sources of ignition like electrical gadgets.

To protect fire prone area from the fire.

To remove material which can catch fire.

Evacuation of non-essential persons.

b) Medical Facilities/Treatment

The Plant will have a Health centre which is manned with trained male

nurse on continuous basis who can render medical first aid. Doctor will

visit two times a week for two hour each time.

Depending on seriousness the injured person shall be shifted to any

other hospital.

Vehicle will be available round the clock for transportation. Ambulance

will be also made available in the campus on regular basis.

c) In the event of Fatal Accidents

The information shall be given to following authorities:

Inspector of Police



Inspector of Factories

Mamlatdar

Corporate Office

Regd. Office

Insurance the plant

Regional Officer, SPCB

d) Emergency Siren

Emergency siren shall be blown for announcing the emergency which

shall have different sound for identification/differentiation than the

normally used for commencement of factory working etc.

Location of Siren Above Plant

Type of Siren Industrial Siren

Position of siren switch Located at Main Gate

e) Seeking help from neighboring industries/sources for fire engine

f) Advise for vacation of other areas

Since the effect of fire/gas emission shall be contained within the area

of the plant advice of vacation of other areas is not necessary.

7.22.1.3 Response Time-Minutes

Hazard Fire Fighting Police Medical Services

Fire &

Explosion

Immediate with whatever

facilities available with the plant

10

min.

10 minutes

External Help within 15 minutes

7.23 OFF-SITE EMERGENCY PLAN

7.23.1 Need of the Site Emergency Plan

Depending upon the wind direction and velocity of the effects of accident

in factory may spread to outside its premises. To avert major disaster it

is essential to seek guidance/assistance of statutory authorities, police

and health department. The movement of traffic may have to be

restricted. Required information will be given to the authority and

consultation will be sought for remedial measures.

A purpose of the off-site emergency plan is:

To provide the local/district authorities, police, fire, brigade, doctors,

surrounding industries and public the basic information of risk and

environmental impact assessment and appraise them of the



consequences and the protection/prevention measures and to seek

their help to communicate with public in case of major emergency.

To assist district authorities for preparing the off-site emergency plan

for district or particular area and to organize rehearsals from time to

time and initiate corrective actions on experience.

7.23.2 Structure of the Off-Site Emergency Plan

Available with concerned authorities.

7.23.3 Role of the Factory Management

The site main controller will provide a copy of action plan to the statutory

authorities in order to facilitate preparedness of district/area off-site

emergency plan.

7.23.4 Role of Emergency Co-ordination Office (ECO)

He will be a senior police or fire officer co-ordination with site main

controller. He will utilize emergency control centre.

7.23.5 Role of Local Authority

Preparation of Off Site Plan lies with local authorities. An Emergency

Planning Officer (EPO) works to obtain relevant information for preparing

basis for the plan and ensures that all those organization involved in

offsite emergency and to know their role and responsibilities.

7.23.6 Role of Fire Authorities

The fire authorities will take over the site responsibility from incident

controller after arrival. They will be familiarized with site of flammable

materials, water and foam applies points, fire-fighting equipment.

7.23.7 Role of the Police and Evacuation Authorities

Senior Police Officer designated, as emergency co-ordination officer shall

take over all control of an emergency. The duties include protection of

life, property and control of traffic movement. Their functions include

controlling standards, evacuating public and identifying dead and dealing

with casualties and informing relatives of dead or injured. There may be

separate authorities/agencies to carry out evacuation and transportation

work. Evacuation depends upon the nature of accident, in case of fire

only neighboring localities shall be alerted. Whole areas have to be

evacuated in case of toxic release.



7.23.8 Role of Health Authorities

After assessing the extent of effect caused to a person the health

authorities will treat them.

7.23.9 Role of Mutual Aid Agencies

Various types of mutual aid available from the surrounding factories and

other agencies will be utilized.

7.23.10 Role of Factory Inspectorate

In the event of an accident, the Factory Inspector will assist the District

Emergency Authority for information and helping in getting Neighbouring

Industries/mutual aid from surrounding factories. Factory Inspector may

wish to ensure that the affected areas are rehabilitated safely.

7.24 MOCK DRILLS AND RECORDS

7.24.1 Need of Rehearsal & Training

Regular training and rehearsal program of emergency procedures shall be

conducted with elaborate discussions & testing of action plan with mock

drill. If needed, the guidance of outside agencies will be sought.

7.24.2 Some Check Points

The extent of realistic nature of incidents.

Adequate assessment of consequences of various incidents.

Availability of sufficient resources such as water, fire-fighting aids,

personnel.

Logical sequences of actions.

The involvement of key personnel in the preparation of plan.

At least 24 hours covers to take account of absences due to sickness

and holiday, minimum shift manning.

Satisfactory co-operation with local emergency services and district or

regional emergency planning offices.

7.24.3 Records and Updating the Plan

All records of various on-site and off-site emergency plans of the factory

will be useful alone with those of the factors by which statutory

authorities draw a detailed plan for the whole area/district. The records of

the activity will be updated regularly.



(D) PUBLIC CONSULTATION

The public hearing was conducted by GPCB on 18.10.2019 on the basis of

the draft EIA/EMP incorporating the Terms of References. Point raised

during the public hearing by participants is summarized below with

reply/action taken by project proponent.

Table 7.11 Points raised during public hearing

Statement of issues raised by the public and response of the project proponent with

action plan is as follows.

Sr.

No.

Name and

Address

Point Represented Reply from

Project

Proponent

Time Bound

Action Plan

proposed

Budgetary

provision

1. Shri Chauhan

Javed

Vill. Dabhasa

Ta. Padra

It was informed that

local people of an

area are poor and

are in dire need of

employment and

therefore

establishment of an

industry in an area is

welcome. He

subsequently,

inquired to know

about the

employment

creation.

Representative of

project proponent,

Dr. Mahendrabhai

Sadaria informed

that local residents

of village :

Dabhasa would be

given preference

and then to an

area covered

within 10 km.

Total manpower

requirements

would be 65. He

further informed

that only in case

of non-availability

of the requisite

qualified persons;

outsider would be

considered over

local people.

Appointment

office staff/

skill/unskilled

employs

start during

construction

and

operational

phase

--

2. Shri Deval

Patel

Vill. Padra

Ta. Padra

He inquired to know

the expected

benefits to the

society due to social

activities by

industry.

Representative of

project proponent,

Dr. Mahendrabhai

Sadaria briefed

about the various

six activities that

would be

considered under

their CER activities

over the five years

with a budgetary

provisions of Rs.

100 Lakhs. He

further informed

that any

suggestions from

the local people or

from the local

district

administration

would be

positively

considered and

CER activities

Immediately

start before

starting of

construction

activities of

project

Rs.100

Lakh

earmark for

CER

activities



will be

accommodated.

3 Shri Ketal

Patel

Vill. Dabhasa

Ta. Padra

He inquired to know

the management

plan for the air

pollution control.

Representative of

project proponent,

Dr. Mahendrabhai

Sadaria informed

that coal is

proposed to be

used as a fuel and

therefore cyclone

and bag filter with

the adequate

stack height is

proposed to be

provided for the

air pollution

control whereas

water and alkali

scrubber is

proposed to be

provided for the

process gas

emission and

exhausted

scrubbing media

will be reused /

sold to the

authorized actual

users. He further

informed that

APCMs would be

operated

judiciously without

any flexibility.

Immediately

with Plant

operation

Rs. 32 Lakh

as capital

investment

and Rs.5.0

Lakh/Year

as recurring

cost for

installation

and

operating

APCM for

Air Pollution

Control

4 Shri Bhupendrasinh Mohansinh

Mahida

Vill. Chokari –

Sarpanch,

Ta. Padra

He quoted that

industry is to spend

about 2% as per the

legal requirements

for the CSR and

demanded that such

amount shall be

spent in an area

where industries are

not located.

He also demanded to

give preference to

local people for the

employment who are

residing within 10

km radius.

Representative of

project proponent,

Dr. Mahendrabhai

Sadaria welcomed

the suggestion

about the amount

of CSR to be spent

as well as that of

employment to the

local people. He

further added that

adequate care

would be taken

while

implementation.

CER activities

Immediately

start before

starting of

construction

activities of

project

Rs.100

Lakh

earmark for

CER

activities

5 Shri

Manojbhai

Patel,

Vill. Abhor –

Sarpanch,

Ta. Padra.

He opined that

industry shall strive

to use agro based

fuel being generated

from the local

farmers in lieu of

proposed fuel of coal

which may not only

reduce the air

pollution but would

Representative of

project proponent,

Dr. Mahendrabhai

Sadaria welcomed

the suggestion and

recommended to

plan a briquette

manufacturing

plant for their agro

waste being

CER activities

Immediately

start before

starting of

construction

activities of

project

Rs.100

Lakh

earmark for

CER

activities



in turn also support

the local farmers in

revenue generation

and will result into

building up of inter

relationship. He

informed that sister

concern unit Lakshya

Group is carrying out

good CSR activities

and opined that such

action will further

support the farmers

of an area where

there are no

industries.

generated from an

area. He further

informed that final

EIA report would

be submitted with

agro briquette as

an alternate fuel

to proposed fuel of

coal.

6 Shri

Dhanajibhai

Ratanabhai

Padhiyar

Vill. Ekalbara,

Member –

Gram

Panchayat

Ta. Padra

He inquired to know

the waste water

management plan

and also demanded

to provide

preference to local

for employment.

Representative of

project proponent,

Dr. Mahendrabhai

Sadaria once again

explained the

waste water

treatment scheme

that was already

shown during

presentation and

informed that

industry will aim

at resource

conservation, will

reuse the treated

waste water and

will maintain ZLD.

It was further

informed that

deserving local

people will be

given preference

for the

employment based

on the

requirements.

Immediately

with Plant

operation

Rs.141

Lakh as

capital

investment

and Rs.95

Lakh/Year

as recurring

cost for

installation

and

operating

wastewater

treatment

7 Shri

Jhahirkhan

Pathan

Vill. Ranu

Ta. Padra

He quoted that he

has provided

employment to

around 10 – 12 local

people even though

running a very small

business and

therefore the

estimated

employment of 65

persons seems very

less for an industry

and therefore has an

objection.

He further inquired

to know about the

steps proposed to be

taken by the

Representative of

project proponent,

Dr. Mahendrabhai

Sadaria informed

that requirements

of manpower are a

proprietary

decision of an

industry based on

their requirements

and cannot be

compared.

With regard to foul

smell, he further

informed that it is

proposed to

provide alkali

Immediately

with Plant

operation

Rs. 32 Lakh

as capital

investment

and Rs.5.0

Lakh/Year

as recurring

cost for

installation

and

operating

APCM for

Air Pollution

Control



industry for the

control of foul smell

being

pharmaceutical

industry.

scrubber for the

scrubbing of the

process emission.

Further opined

that, though

industry is

committed for the

control of pollution

Additionally,

general awareness

would also not

allow industry to

be non-compliant.

(E) Social Impact Assessment

Reynish Pharmachem Pvt. Ltd. is a green field project, proposes to set

up bulk drugs manufacturing unit. Total production capacity of all

products will be tune around 50 MT/month. There will be no

Rehabilitation & Resettlement (R&R) involved. However, preference will

be given to local people for employment and contribute to improve the

physical infrastructure in vicinity of plant. Detailed Social Impact

Assessment (SIA) study is given below:

Introduction

Corporate Environmental Responsibility (CER) refers to a company‟s

duties to withdraw from damaging natural environments. The term

derives from Corporate Social Responsibility (CSR). Also can be referred

as corporate initiative to assess and take responsibility for the company's

effects on the environment and impact on social welfare. The term

generally applies to companies efforts that go beyond what may be

required by regulators or environmental protection groups.

CSR is a way of conducting business, by which corporate entities visibly

contribute to the social good. Socially responsible companies do not limit

themselves to using resources to engage in activities that increase only

their profits. They use CSR to integrate economic, environmental and

social objectives with the company's operations and growth.

Corporate Social Responsibility is not a new concept in India, however,

the Ministry of Corporate Affairs, Government of India has recently

notified the Section 135 of the Companies Act, 2013 along with

Companies (Corporate Social Responsibility Policy) Rules, 2014

"hereinafter CSR Rules" and other notifications related thereto which



makes it mandatory (with effect from 1st April, 2014) for certain

companies who fulfill the criteria as mentioned under Sub Section 1 of

Section 135 to comply with the provisions relevant to Corporate Social

Responsibility. CSR is generally understood as being the way through

which a company achieves a balance of economic, environmental and

social imperatives ("Triple-Bottom-Line- Approach"), while at the same

time addressing the expectations of shareholders and stakeholders. The

term "Corporate Social Responsibility (CSR)" can be referred as corporate

initiative to assess and take responsibility for the company's effects on

the environment and impact on social welfare. The term generally applies

to companies efforts that go beyond what may be required by regulators

or environmental protection groups.

Purpose of the CER/CSR

Corporate Environment/ social responsibility (CSR) is a broad term used

to describe a company's efforts to improve society in some way. These

efforts can range from donating money to non-profits to implementing

environmentally-friendly policies in the workplace. The group's CSR

activities are rooted in the knowledge that businesses have a duty to

enable all living beings to get a fair share of the planet's resources.

Businesses are powerful constituents of society and the most successful,

respected, and desirable businesses exist to do much more than make

money; they exist to use the power of business to solve social and

environmental problems. Unit will involve in a community development

and environment preservation projects. Social activities relate to health,

primary education, skills training and entrepreneurship, livelihoods and

women empowerment.

Objective of the study

The main objectives are as follows:

1. To assess the impact of the project on agricultural situation;

2. To examine the impact of the project on pattern of demand;

3. To assess the in impact of the project on consumption pattern;

4. To examine employment and income effects of the project;

5. To explore the possibility of local industrialization as an offshoot of the

Project;



6. To examine the effect of the project on education status of the people

in the study area; and

7. To judge peoples' perception regarding the project

Survey Methodology

The survey aims to document the living conditions, level of socio-

economic development of the region and the socioeconomic profile of

people in the core and buffer zones of the proposed project area. The

survey was organized to collect information on socio-economic variables

at the village level as well as household level. The village level data are

collected from revenue offices, Panchayat office; Censuses while the

household level data are collected through questionnaire method. The

agreed methodology has been followed with the tools of SIA. The

following strategies were adopted for undertaking the study.

Consultation with Representatives of focus area

Close coordination was maintained with concerned Public Representative‟s

Offices, Local representatives and common village people. Assessment of

the area was made by industry representative along with Team of M/s

San Envirotech Pvt. Ltd.

Assessment of studied area

Pre-contract field visit was conducted with assessment of the area and

people interacting with concerned employees and few opinion leaders of

the area. This visit facilitated the strategic plan to complete the study in

stipulated time.

Focus Group Discussion:

A guiding principle was developed to conduct focused group discussion

with different categories of people of the studied villages.

Study of Village Profile

This study includes village level survey of Population, Economics, Land

use Pattern, Employment pattern, Healthcare Facilities, Amenities for

Livelihood. This primary data is statistically validated and the statistical

differences and is interpreted in the light of economic impacts.

Sources of Information

As per the scope of present study, the information on the sociological

aspects like demography, human settlements, social aspects like SC & ST



population, literacy levels and economic aspects like occupational

structure of workers has been gathered and complied from secondary

sources viz. the District Census Statistical Handbook, 2011 for Vadodara

District as these documents being comprehensive and authentic.

Socio Economic Survey within study area:

1) Educational facility

Literacy is an important indicator for understanding the socio-economic

development of any area. Many villages of the study area have no proper

education facility and literacy rate is very low especially women. Overall

literacy ratio in the study area is 70.41%. The male literacy in the study

area is found to be 52.16% and the female literacy in the study area is

found to be 47.84%. However, the difference in literacy rate between

male and female is found be much wider. The overall study indicates that

the literacy rate in female population is low which can be attributed to the

social structure prevailing in the villages and traditional family trends.

The educational facilities in the study area are good due to the presence

of good infrastructure for basic education like primary schools and high

schools for higher education.

As per 2011 census, there are primary school in all 53 villages, 31 Pre-

primary school, 50 Secondary schools, 34 Senior Secondary schools, and

27 Arts, Science and Commerce College.

Area is an industrial zone and skilled manpower is essential. Unit will

contribute to start give contribution in terms of stipend to unskilled

employs for vocational training or join hands with other industrial group

to start training institute.

2) Drinking water and Sanitation Facilities

All the 53 villages in the study area have two or more sources of drinking

water. Most of the villages have tube well water supply in addition to Tap

water. Moreover, all villages have facility of well water and some villages

have hand pump, river & tank water, tube well or other facilities for

water. Unit proposed to provide drinking water facility in nearby 2 villages

where quality of potable water is poor. Unit will contribute fund towards

storage of drinking water facility at selected villages.



3) Health & Family welfare

In the study area, there are 7 primary health centers, 17 primary health

sub-centers. There is no any Employees' State Insurance (ESI) Hospital

within the study area. Based on above study, it is concluded that heath

and family welfare facility found good in the study area. However unit will

arrange 2-3 health checkup camp during monsoon and provide fee

medicines.

4) Women Empowerment activities

In some cases, women bear larger losses in terms of educational

attainment, employment and wages. In terms of employment, which is a

major determinant of livelihood, Vadodara rural talukas shows lower than

state average in Worker Participation Rates (WPR). There is distinct

Gender disparity in WPR across all talukas, with women substantially

under-represented in main workers category. Thus, unit proposes to

provide education and training to engage more women in employment

opportunities.

Need Analysis of the Target Beneficiaries in the Project Area

Various needs were identified during the baseline survey within the study

area. Major problems they are facing are given below.

Poor availability of water for irrigation and drinking purpose

Lack of good medical facilities

Unemployment

Health and sanitation program

Poor educational facilities

In the assessment of socio-economic conditions, few indicators were

identified for further attention and strategic planning as given below:

Target Project Area

Target Project Area

Total 53 villages fall within the study area; Out of which unit will give

priorities to 4 villages namely 4 villages (Dabhasa, Ranu, Dhobikuwa

and Mahuvad) for CER activities according to the below mentioned

criteria.

Largely affected by industrial growth

Vicinity to the project site



Sourcing of employees from these areas

Low level socio-economic status of the people

Lack of adequate intervention of voluntary organization in the area

The focus area of comprehensive program includes: health, education,

sanitation, sustainable livelihood & infrastructure development.

Details of expenditure for ESR activities(Revised):

Cost of the proposed project : Rs. 40 Crores

Expenditure earmarked towards ESR : Rs. 2.0 Crore

(5.0 % of the total project cost)

Table 7.12a Detailed expenditure break-up for CER activities*

Sr.

No.


Budget

(Rs. in

Lakhs)

1st 2nd 3rd


Computers 6.08 6.08 -- 12.16

Scholarship 12.8 12.8 12.8 38.4


water cooler at

Primary school and


villages

14.0 14.0 14.0 42.0

Operating and

maintenance cost

2.0 2.0 2.0 6.0


welfare

Around 10 camp with

cluster of 5 to 6

villages

4.0 4.0 4.0 12.0




women coming from BPL

family and widow

women.


study area

Onetime 100 nos

Sawing machine

5.0 5.0 5.0 15.0

Onetime 50 no

embroidery Machine

5.0 5.0 2.5 12.5


four village pond namely

Dabhasa, Bhoj Ranu

Pond and Dabka and

other as per the

suggestion by local

authorities.

8 village pond 22.0 22.0 -- 44.0

Total 76.88 76.8

8

46.3 200.06

*Increase the CER budget from 2.5% to 5.0% as suggested by EAC

committee (Industry-II). Reduce the estimated utilization fund within 5 years to 3 years. However, project will completed earlier then the

estimated time then utilize CER fund accordingly.



Table 7.12b: Quantify CER activities in details

Proposed Activities Selected areas or

villages

Frequency Financial provision

in Lakhs

Educational

Provide the

Computer

Secondary School

and Higher

Secondary school of

4 villages

One time

8 Computer x 4

32 x 38000

Total Rs. 12.16

Scholarship to poor

children around 160

students

(40 on merit basis of

each 4 village

student of Secondary

& Higher secondary

school

Every year up to 3

years

Rs.8000 x 160 x 3

Years

Total Rs.38.4

Drinking water facility

Water Cooler, RO

4 sets of RO and

water cooler at

Primary school of 4

villages

Onetime

350000 x 10

Total Rs.42.0

8 sets of RO and

water cooler at

Village Panchayat of

8 villages

Operating and

maintenance cost

-- Three Years 12 x 0.5

Total Rs.6.0

Public Health and family welfare

Medical camp and

free medicine

Around 10 camp with

cluster of 5 to 6

villages

10 camp up to three

Years during rainy

days

10 x 0.4 x 3 years

Total Rs.12.0

Free Medicines 10 x 0.6 x 3 years

Total Rs.18.0

Women Empowerment & children Development activities

Provide Sawing and

embroidery machine

to women coming

from BPL family and

widow women.


study area

Onetime

100 nos Sawing

machine

100 x 15000

Total Rs.15.0

Onetime

50 no embroidery

Machine

50 x 25000

Total Rs.12.5

Environment Sustainability - Ground water recharging

Widening and digging

of four village pond

namely

Dabhasa, Bhoj Ranu

Pond and Dabka and

other as per the

suggestion of local

authorities.

8 village pond One time

(550000

x 8 =

Total 44.0

Total Rs. 200.06 Lakhs



Chapter-8

Project Benefits

8.1 INTRODUCTION

Project benefit focus on those points which will become beneficial to the

surrounding area or community in terms of infrastructural development,

social development, employment and other tangible benefits due to

project. Proposed project of Reynish Pharmachem Pvt. Ltd. has a

potential for employment of skilled, semi-skilled and unskilled employees

during construction phase as well as operational phase.

8.2 IMPROVEMENT IN PHYSICAL INFRASTRUCTURE

Reynish Pharmachem Pvt. Ltd. has proposed to manufacture bulk drugs

with quantity of 50 MT/month. The project will have requirement of an

infrastructure, so direct benefits of infrastructure development is

anticipated. The project proposes to employ local people which will help

to increase the income of local people & improve their standard of living.

The construction and commissioning phase will require a substantial

manpower and resources. Hence, with the growth in the economic

conditions, the project may lead to growth in the social stature &

improvement of the quality of life in the surrounding area. It will also help

in improvement in local amenities. Thus, the project will have

considerable indirect benefits to the public physical infrastructures.

8.3 IMPROVEMENT IN SOCIAL INFRASTRUCTURE

The company will conduct social welfare activities which include the

funding & contribution for public infrastructure/facilities development,

maintenance & improvement on basis of as & when required. Due to

proposed project activity at Reynish Pharmachem Pvt. Ltd., social

infrastructure will improve by means of civilization, vocational training

and basic amenities.

Civilization: Due to the project, employment and other infrastructural

facilities will boost up income of surrounding people and improve quality

of life. This will indirectly boost up the civilization of the surrounding

people.



Vocational Training: Unit will provide vocational training opportunity to

the surrounding people and motivate the education activities that will

lead the change in life style of the surrounding, hence, improving social

infrastructure.

Basic Amenities: Unit will consider providing or improving education

facilities, healthcare, and drinking water facilities in the area, which will

help in uplifting the living standards of local communities.

8.4 EMPLOYMENT POTENTIAL

In the construction phase, direct and indirect manpower will be involved.

Thus temporary and permanent employment will be generated during

construction phase. The proposed manpower requirement during

construction will be 25-75 nos. During the operation phase, 65 nos. of

skilled and unskilled manpower will be required. Moreover, Reynish

Pharmachem Pvt. Ltd. will provide first priority to local workers for the

employment. Further, the indirect employment via increased

transportation, ancillary units & local economic activities will also add in

the employment potential of the project. Thus, the Reynish Pharmachem

will result in considerable benefits in terms of employment.

8.5 OTHER TANGIBLE BENEFITS

In addition to mentioned above, the project will have many employment

& trade opportunities, which will eventually result in appreciable

economic benefits to the local people & businesses/contractors.

Indirectly, the project will help the Government by paying different taxes

from time to time, which is a part of revenue and thus, will help in

developing the area. Additionally, unit will motivate and support to

provide technology to local farmers and small entrepreneurs for

manufacturing of agro waste based briquettes.



Chapter-9

Environmental Cost Benefit Analysis

As per EIA Notification 2006, this Chapter of the ‘Environmental Cost Benefit

Analysis’ is applicable only if it is recommended at the Scoping stage. As per

the standard ToR issued by MoEF&CC, New Delhi vide File No. IA-J-

11011/194/2018-IA-II(I)dated 13th July 2018, the Environmental Cost

Benefit Analysis is not applicable and hence has not been prepared.



Chapter-10

Environment Management Plan

10.1 INTRODUCTION

Assessment of environmental and social impacts arising due to

implementation of the project activities is the technical heart of EIA

process. An equally essential element of this process is to develop

measures to eliminate, offset or reduce impacts to acceptable levels

during implementation and operation of projects. The integration of such

measures into project implementation and operation is supported by

clearly defining the environmental requirements within an Environment

Management Plan (EMP).

The EMP of Reynish Pharmachem Pvt. Ltd. has been formulated

considering all necessary mitigation measures to prevent/ minimize/

eliminate environmental impacts associated with the proposed activities.

Reynish Pharmachem will develop an Environment Management Cell to

keep a close watch on the performance of the pollution control

equipments, emissions from the sources and the quality of surrounding

environment in accordance with the monitoring program.

OBJECTIVE OF ENVIRONMENT MANAGEMENT PLAN

The EMP is prepared with the main objective of enlisting all the

requirements to ensure effective mitigation of adverse impacts for all the

components of the proposed project. The key objectives of the

Environment Management Plan are,

To limit/reduce the degree, extent, magnitude or duration of adverse

impacts,

To treat all the pollutants i.e. liquid effluent, air emissions and

hazardous waste with adoption of adequate and efficient technology,

To reduce risk/hazards and design the disaster management plan,

To make budgetary provision and allocation of funds for environment

management system and for timely revision of budgetary provisions.



10.2 ENVIRONMENTAL MANAGEMENT DURING CONSTRUCTION PHASE

Construction phase results in temporary environmental pollution except

for the permanent change in local land use pattern & aesthetics in certain

cases. Such pollution is mainly due to site preparation, civil works,

transportation, storage & handling of construction materials, construction

worker’s sanitation etc. These are usually short-term impacts.

10.2.1 Air and Noise Environment

During construction work at Reynish Pharmachem, air pollution is

expected in the form of increased suspended particulate matter

concentration. Installation work will generate noise and dust, but it will

be within working areas. To mitigate the adverse environment impact due

to the construction phase, following measures will be taken:

Regular sprinkling of the water will be carried out at least twice a day

along with the construction activities to reduce dust emissions,

Regular preventing maintenance of machinery and transportation

vehicles will be carried out to reduce vehicular emissions and noise

pollution,

Provision of silencer to modulate the noise generated by the machine,

if required, and

Provision of personal protective equipment such as earmuffs/earplugs

to workers working in noisy area.

10.2.2 Water Environment

During construction phase, water supply from bore well and/or tankers

and portable sanitation facilities will be provided. Rest room will be

provided for workers as well as truck drivers during operation phase.

Domestic wastewater will be discharged into soak pit.

10.2.3 Socio-Economic Environment

The proposed man power requirement during construction will be 30-50

nos. Reynish Pharmachem gives preference to local people through both

direct and indirect employment.

10.2.4 Health and Safety

Adequate rest area will be provided to the construction workers, casual

workers, and truck drivers. Unit will also supply potable water and

portable sanitation facilities for the construction workers, casual workers,



and truck drivers. The safety department will supervise the safe working

of the contractor and their employees. Work spots will be maintained

clean, provided with optimum lighting and enough ventilation to eliminate

dust/fumes.

10.3 ENVIRONMENTAL MANAGEMENT DURING THE OPERATIONAL

PHASE

EMP proposed for implementation is detailed under the following heads:

Air Pollution Management

Wastewater Management

Solid/Hazardous Waste Management

Noise Management

Greenbelt Development

Occupational Safety and Health

Implementation of EMP and monitoring programme

10.3.1 Air Pollution Management

10.3.1.1 Source of Air Pollution and Control Measures

Flue gas emission is due to the combustion of fuel Agro Briquettes in

boiler, Thermic Fluid Heater and Hot Air Generator. Most probable

pollutants will be SPM, SO2 and NOx. Multi Cyclone, bag filter & water

scrubber will be installed as APCM for each flue gas emission source.

Process emission will be from the stack attached with reaction vessels

and corresponding pollutants will be HCl and SO2. To control the process

emission, water and alkali scrubber will be provided. Spin flash dryers

(SFD)/Fluid Based Dryer (FBD)/Rotary Vacuum Dryer (RVD) will be

equipped with in-built cyclone and bag filter. Furthermore, adequate

stack height and facility for sampling such as ladder and sampling point

will be provided as per the GPCB guidelines. The details of stacks with

their APC measures are given in Table 2.8 of Chapter-2.

Measures to control fugitive emission

The fugitive pollutants of PM, VOCs & Acid mists are likely to emit from

process area. Unit will adopt following measures,

Adequate scrubbing system to absorb the process gas and

condensing systems,

Entire process will be carried out in closed reactors,



Pneumatically transfer of liquid raw material in rector,

Raw material will be stored in the covered structure,

Regular maintenance of valves, pipes, etc.,

Greenbelt will be developed around the plant to arrest the fugitive

emission.

PPEs will be provided to the workers, and

Frequent work area monitoring will be done to ensure fugitive

emissions level.

10.3.1.2 Measures for Solvent Recovery

Details technology/mitigation measure to achieve the Volatile

organic compounds (VOCs)/Fugitive emissions @ 99.997%.

Unit will use Methanol, Dichloromethane, Isopropyl Alcohol, Ethyl Acetate,

Acetone, Toluene, Chloroform, Hexane and Dimethyl Formamide (DMF)

etc.

These are mostly transferred to reactors by means of pumps and their

related pipelines. Pumps are provided with proper mechanical seal, and

pipeline is connected with each other by flanges and gaskets. There will

be practically no emission of solvents in form of VOCs. The leak detector

and emission will be checked by digital transmitter with smart sensor. If

the detection level exceed in the work area of half level of TLV/TWA

value, immediate action will be taken by operator to shut down

valve/pump to prevent the leak and emission of gas. Periodically

preventive maintenance schedule shall also be conducted by team.

Unit will handle following solvent having following physical properties

namely BP oC and FP oC.

Solvent to be used with B.P. and F.P. Sr. No. Name of solvent BP oC FP oC

1 Methanol 64.5 12

2 Dichloromethane 39.75 NA

3 Isopropyl Alcohol 82.5 18.3

4 Ethyl Acetate 77.0 -4.4

5 Acetone 56.2 -20

6 Toluene 110.6 4.44

7 Chloroform 61 NA

8 Hexane 69 -22

9 Dimethyl Formamide (DMF) 153 57.7



Unit will follow following LDAR (Leak Detection and Repair)

Programme.

1. Unit will prepare summary of possible Sources of equipment leaks

like; Pumps, Valves, Joints/ Connectors, Pressure relief devices,

Open-ended lines etc.

2. Regular monitoring to check and repair leaking components, including

valves, pumps, connectors, compressors, and agitators, in order to

minimize the emission of fugitive volatile organic compounds (VOCs).

3. Unit will use VOC meter to detect the VOCs and its source to

repairing any leakages

4. Find the Sources of leakages, its Causes and Control the Leaks by

way of modifying/replacing leaking equipment with “leakless”

components.

5. Develop awareness of the benefits of leak detection and repair into

the company’s operating and maintenance program in terms of cost

savings, environmental protection, and worker and community safety.

6. Reducing Product Losses, Increasing Safety for Facility Workers and

Operators, Decreasing Exposure for the Surrounding Community,

Avoiding Enforcement Actions.

7. Install Brine chiller (-10 to -200C chiller) for secondary condenser of

solvent recovery system to achieve VOCs loss practically zero.

8. Use Double seal/mechanical seal for control of VOC.

9. Closed handling system shall be provided for chemicals.

10. Reflux condenser shall be provided over reactor.

11. System of leak detection and repair of pump/pipeline based on

preventive maintenance.

12. The acids shall be taken from storage tanks to reactors through

closed pipeline.

13. Storage tanks shall be. vented through trap receiver and condenser

operated on chilled water

14. The condensers shall be providing with sufficient HTA and residence

time to achieve maximum recovery.

15. Solvents shall be stored in a separate space specified with all safety

measures



16. Proper Earthing shall be providing in all the electrical equipment

wherever solvent handling is done.

17. Entire plant shall be flameproof. The solvent storage tanks shall be

providing with breather valve to prevent losses.

10.3.1.3 Odour Control Plan

All solid raw materials shall be charged directly to reactor through special

air lock hopper against slight negative pressure (in water column) so that

no odour is emitted to the environment. Solid charging nozzle in reactor

shall be projected inside so that it directly falls in to the solvent media,

thereby eliminating carrying over of solid to vapour nozzle. Powder

transfer system shall also be used wherever applicable to have zero loss

of powder into the atmosphere. All liquid raw material handled in drum

shall be cooled down before charging so as to minimize its vapour

pressure and control of odour. Alternatively vacuum lock could also be

used in day tank for transfer of liquid from drum (pumping under

vacuum). Proper Personal Protective Equipment (PPEs) will be provided to

the workers who are involved in handling odorous materials.


Unit will satisfy its fresh water requirement from Bore well water supply.



will be recycle/treated water (RO permeate & MEE condensate). Total

industrial wastewater generation will be 141 KLD. The main source of the

industrial wastewater generation will be from process including lab and

scrubber (99 KLD), washing (10 KLD), utilities (Boiler & cooling - 10

KLD), and water treatment (22 KLD).

Process effluent along with wastewater of scrubber, washing and utility

will be taken to RO after primary and secondary treatment. RO reject will

be sent to MEE; RO permeate and condensate of MEE will be reused.

Domestic wastewater will be disposed to soak pit. Thus, achieving Zero

Liquid Discharge (ZLD). ETP sludge and MEE salt will be disposed to

approve TSDF site. Domestic effluent of 4.0 KLD will be disposed to soak

pit.



Effluent treatment scheme:

Wastewater from process, washing Scrubbers etc. will be collected in

equalization/neutralization tank, where it is neutralized, depending upon

the acidity/alkalinity of influent. Later it will be pumped into primary

settling tank to settle down suspended solid. Later it will be pumped into

aeration tanks for biological treatment, where microorganisms will be

reduced organic load in effluent. Then effluent is allowed to secondary

settling tank. This activated effluent is passed to settling tanks for

settling purpose. Here sludge formed is settled and removed from the

bottom hopper. Then water will be transferred to the pressure sand filter

followed by RO.

RO permeate will be reused, and RO reject will be sent to MEE/ATFD.

Sludge will be transferred to the sludge drying bed. After drying, the

dried sludge will be collected, packed in HDPE bags and stored in

separate storage area and disposed at approved TSDF site. Salt from

MEE/ATFD will be sent to TSDF site, too.

10.3.3 Hazardous/Solid Waste Management


Hazardous & Other waste (Management & Transboundary Movement)

Rules, 2016. ETP sludge (25 MTPM) and MEE salt (50 MTPM) from

wastewater treatment and Process sludge (12 MTPM) will be disposed of at

approved TSDF site. Spent carbon (0.75 MTPM), and spent catalyst (1.0

MT/Month) will be returned back to supplier for regeneration. Distillation

residue (15 MTPM), off specification products and date expired products

will be sent for co-processing or at CHWIF. Used lubricating oil (40

Lit/month) will be sold to registered recycler. Discarded Drums (700

Nos./month) & containers/ Liners (0.5 MT/month) will be sold to actual

users. HCl (20-25%) - 75 MT/month and Sodium bisulfite (NaHSO3) - 50

MT/month will be sold to actual user under Rule-9 of HAZ Rule.

The unit will provide isolated area with impervious flooring & roof cover for

the storage of hazardous waste. Details of hazardous waste disposal

methods are given in Chapter 2 (Table 2.10).



Fly Ash management




generated from burning of Ago briquette in boiler, HAG and TFH. The

criteria of selection of fly ash brick unit is summarized below.

About 80% fly ash will be used for the production of fly ash bricks. The

ratio of Fly Ash (80%) Gypsum (15%) and sand (5%). Based on the

maximum fly ash generation (4.0 TPD), around 2000 per day *26 =52000

nos /month will be produce. To considering 4 day production per month

(Only Sunday), unit will require 13000 brick per day capacity of machine.

To considering this aspect unit will purchase semi-automatic machine with

capacity of 2000 bricks per hour hydraulic pressure machine.

Above details incorporated in modified EIA report on section 2.9.3 Fly Ash

management, page 2-41.

Storage and Transportation of Solid/Hazardous Waste:

Proper Hazardous waste storage area with impervious flooring and

covered shed is provided for storage of solid/hazardous waste.

Entire quantity of the hazardous waste is stored in the isolated

hazardous waste storage area within premises having leachate

collection system and roof cover. The storage yard shall be properly

labeled for identification of wastes.

Hazardous waste shall not be stored for a period more than 90 days.

Records of the same shall be maintained and make them available for

inspection.

Properly packed & labeled waste shall be transported through

dedicated vehicle to authorized TSDF facility.

10.3.4 Noise Control

Reynish Pharmachem proposes following measures to minimize the

impact of noise on the environment during the operational phase,

Noise suppression measures such as enclosures, buffers and/or

protective measures should be provided, if required (wherever noise

level is more than 90 dB (A)).



Extensive oiling, lubrication and preventive maintenance will be carried

out for the machineries and equipments to reduce noise generation.

Use of PPE like ear plugs and ear muffs is made compulsory near the

high noise generating machines.

Moreover, the personnel shall be provided breaks in their working

hours, with the continuous exposure not increasing three hours.

The transportation contractor shall be informed to avoid unnecessary

speeding of the vehicles inside the premises.

Acoustic enclosure shall be provided for D.G. set and similar provisions

like noise attenuator wherever suitable/possible.

Areas with high noise levels will be identified and segregated where

possible and will include prominently displayed caution boards.

Adequate greenbelt will be developed within industrial premises and

around the periphery to prevent the noise pollution.

Periodic monitoring of noise levels as per post-project monitoring plan

shall be done on regular basis.

By taking measures as mentioned above, it is anticipated that noise

levels in the plant will be maintained below the permissible limit.

10.3.5 Green Belt Development

Tree plantation is one of the effective remedial measures to control the

air pollution and noise pollution. It also causes aesthetics improvement of

the area as well as sustains and supports the biosphere. Reynish

Pharmachem proposes to do extensive plantation in 12175 m2.Overall

greenbelt area will be more than 33% of the total area of the project.

Design of Green Belt

As far as possible, following guidelines will be considered in greenbelt

development.

The spacing between the trees will be maintained as per SPCB

guideline i.e. 1 tree/4 sqm.

Spaces, so that the trees may grow vertically and slightly increase

the effective height of the greenbelt.

Planting of trees in each row will be in staggered orientation.



The short trees (< 10 m height) will be planted in the first two rows

(towards plant side) of the green belt. The tall trees (> 10 m height)

will be planted in the outer three rows (away from plant side).

Planting methodology

The plantation shall be done in pits. The pit shall be refilled with soil after

the planting. The sampling of healthy, nursery raised, seedlings in

polythene containers shall be transported in baskets. Planting shall be

done after first monsoon showers. The level of soil is about 10 cm above

of ground level. The soil around the plant shall be pressed to form a low

through. About 25 gm chemical fertilizers shall be added. Watering shall

be continued after plantation if any dry spells follows. Planted area shall

be inspected and mortality rate ensured for each species. The dead and

drying plant shall be replaced by fresh seedlings.

Selection of species for greenbelt

For the development of greenbelt, plants having simple big leaves and

native species are preferred to the plants. The plants are suitable for

greenbelt development based on gaseous exchange capacity of foliage

which is ascertained by the following characteristics:

The plant should be fast growing.

It should have thick canopy cover.

It should be perennial and evergreen.

It should have large leaf area index.

It should be indigenous.

It should be efficient in absorbing pollutants without significant effects

on plant growth.

The objectives of the industrial greenbelt are to improve the micro-

environment. The success depends on the type of land available and

selection of suitable tree species for pollution control. Selection of tree

species for industrial areas is influenced by the nature of industry. The

objective should be to ensure a green cover tolerating pollutant gases

and solid particulates present in the atmosphere. It is also advisable to

select suitable tree species and adopt simple techniques which require

minimum investment and care.



Floral species recommended for greenbelt

Azadirachtaindica (Neem), Albizialebbeck (Siris), Pongamiapinnata

(Karanj), Ficusreligiosa (Peepal) are suggested for the greenbelt

development with respect to this particular area. They are mostly

deciduous and evergreen tree types suitable to be grown in the area.

Survival rate of trees and post plantation care

Considering the availability of water and general survey of surrounding

area, the survival rate is expected to be around 70-75%. Moreover, the

wire net guards will be provided to protect the saplings. The same will be

properly manured and watered so that it can grow well.

Protection of plantation site:

Protection from grazing will be done by erecting tree guards around

planted sapling.

Though the tree suggested for plantation will require very less water,

however during the first year watering will be done twice in a day.

There after watering will be done twice in a week.

The manuring will be done when plantation take up. For this purpose,

cow dung will be dump in the pit. No other manuring will require for

plantation. Cow dung is easily available in the study area.

Damaged plants will be replaced with new plants.

Strict surveillance will be made to increase the survival rate of the

trees.

10.3.6 Occupational Health & Safety Plan

To maintain high standard in Health, Safety and Environment, necessary

key mitigation measures & action plan as EMP has been suggested as

described below.

Post-employment health check-up programs will be carried out on

annually and all records & documents related with employee health

check-up program will be maintained.

As per RA report, all risk control & prevention measures in the unit will

be implemented.

Necessary PPEs, safety equipments/materials to ensure healthy & safe

work conditions will be provided to employees.



All employees will be provided with required set of PPEs like ear plug,

ear muff etc. where noise levels in excess of 80 dB(A) are regularly

generated.

It is recommend that Pre-employment health check-up programs shall

be carried out for every new employee and all records & documents

related with employee health check-up program shall be maintained

by the proponent.

Safety documents, procedures, guidelines along with MSDS shall be

provided to the associated/concerned personnel engaged in respective

operational activities.

Training programs & safety audit shall be done on regular basis to

prevent impacts of the operational activities on occupational health as

well as to improve workplace condition & safe work system.

The proponent shall ensure implementation of emergency

management plan with provision of fire-fighting equipment/facilities,

first aid & medical facilities, evacuation procedures etc.

Proponent shall also ensure proper implementation & functioning as

well as assess effectiveness of this safety & emergency system on

regular basis throughout the project operation phase.

Plans for Periodic Medical Checkup

Part time doctor is periodically visited the plant for health check-up of

each employee.

Pre-employment health check-up will be followed by periodical health

check-up with special attention to occupational health.

Medical records of each employee will be maintained in prescribed

format as per Factory Act.

The health check-up will be conducted as per the pre-designed format

which will include chest X-rays, Audiometry, Spirometry, Vision

Testing, ECG, Blood and urine test etc.

The work zone monitoring will be conducted on regular basis.

Monitoring of the Occupational Injury & It’s Impact on workers

The action plan will be prepared to monitor the injury to workers:

Each workplace will be evaluated for the existing work conditions.

Unsafe Act &unsafe Practices will be identified.



Unsafe equipment, unsafe areas, etc., will be identified.

Area will be checked for proper Ventilation and Illumination.

Air-borne concentration of toxic chemicals will be measured and

records will be kept.

Evaluation of training & on the job work.

Impact of the above mentioned unsafe conditions on workers will be

studied and remedial measures for the same will be adopted.

10.3.7 Details of the separate isolated storage area:

Unit will provide isolated storage area for solvent and corrosive

chemicals. Details of storage are given in Table 7.1 of Chapter-7 of EIA

report. All the raw materials are stored in isolated storage area and

containers are tightly closed.The following precautions shall be taken to

avoid foreseeable accident like spillage, fire and explosion hazards and to

minimize the effect of any such accident and to combat the emergency at

site level in case of emergency.

Various emergency spots in plant area will be identified and kept in

sharp and alert watch.

Protective equipment will be regularly checked and will be kept easily

accessible and easily workable during emergency.

Safety installations like available quantity of running water will be

regularly watched.

Fire bucket and hose reels will be provided to withstand the fire or

explosion conditions.

Various types of fire extinguishers such as (Foam type, water CO2

type, CO2 type) will be provided inside the factory premises.

Every pressure vessel will be provided with minimum one or more

pressure relief devices. The design of the valve is made in such a way

that the breakage of any part will not obstruct force discharge of the

liquid under pressure. Moreover, relief valves are tested and a periodic

schedule for their testing shall be maintained. The defective valves will

be removed if found unsafe for the operation.

10.4 POST-PROJECT ENVIRONMENTAL MONITORING

The highlights of the integrated environmental monitoring plan are:



The stack monitoring facilities like ladder, platform and port-hole of all

the stacks maintained in good condition.

Regular monitoring of all gaseous emissions from stacks &fugitive

emissions in the process areas.

The performance of air pollution control equipment such as cyclones

and scrubbers will be evaluated based on these monitoring results.

Water consumption in the unit recorded daily.

Analysis of untreated and treated effluent will be carried out regularly.

Performance of effluent treatment plant units, RO, and MEE evaluated

based on above analysis results.

As far as possible, noise curbed at its source, with the help of acoustic

hoods and other such noise reducing equipment. Regular noise level

monitoring carried out.

Green belt properly maintained and new plantation programmes

undertaken frequently.

Continued environmental awareness programmes carried out within

the employees and also in the surrounding villages.

Rain water harvesting ponds will be developed within the industrial

premises and encouraged in the surrounding villages too.

Table: 10.2 Environment Monitoring Plan

Nature of

Analysis

Frequency of analysis

with its analyzer

Parameters No. of samples

Wastewater analysis



& Grease, etc.

4-6 samples

Stack Monitoring of each stack


PM, SO2, NOX, HCl

All stacks

Ambient Air Quality

Monitoring

Monthly for 24 hours or as per the statutory


PM10, PM2.5, SO2, NOX, HCl

3-5 locations

Noise level Monthly as per the statutory conditions by

external agency

Noise level 6-8 locations (Nr. Main gate, Nr.

boiler, Nr. D. G. Set,

Process area etc.)

Work zone fugitive monitoring



2-3 locations

Health check-up

of workers

As per the statutory

guideline

All workers



10.4.1 Details of Work Place Air Quality Monitoring Plan

Work zone monitoring will be carried out by independent competent third

party every month. Records will be kept in Form No. 37 as per Gujarat

Factories Rules. Location for samplings will be identified. Following

information will be incorporated in the format for maintaining records of

work zone monitoring:

Location/Operation monitored

Identified contaminant

Sampling instrument used

Number of Samples

Range of contaminant concentration as measured in sample

Average concentration

TWA concentration of contaminant

Reference method used for analysis

Number of workers exposed at the location being monitored

Signature of the person taking samples

10.5 ENVIRONMENT MANAGEMENT BUDGET ALLOCATION

Total capital cost and recurring cost/annum earmarked for environment

pollution control measures by Reynish Pharmachem Pvt. Ltd. will be as

under.

Table 10.3: Budget Allocation for Environment Management

Sr.

No.

Particulars Capital Cost (Rs. in

Lakhs)

Recurring Cost per annum

(Rs. in Lakh)

1 Air Pollution Control 32 5.0

2 Water Pollution Control 141 95

3 Noise Pollution Control 1.0 2.0

4 Solid/Hazardous Waste Management

5.5 28

5 Environment Monitoring

and Management

2.5 3.0

6 Occupational Health 15 10

7 Green Belt Development Plan 35 5.0

8 Rain Water Harvesting

System

18 2.0

Total 250 150

10.6 ENVIRONMENTAL MANAGEMENT CELL



Reynish Pharmachem will set up separate Environment Management Cell.

The major duties & responsibilities of EMC will be as follows:

To implement the Environmental Management Plan,

To ensure regular operation &maintenance of pollution control devices,

To assure regulatory compliance with all relevant rules and

regulations,

To minimize environmental impacts by strict adherence to the EMP,

To initiate environmental monitoring as per approved schedule,

Review & interpretation of monitored results and corrective measures

in case monitored results are above the specified limit,

Maintain documentation of good environmental practices and

applicable environmental laws as ready reference,

Maintain environmental related records,

Coordination with regulatory agencies, external consultants and

monitoring laboratories, and

Maintaining log of public complaints and the action taken

10.6.1 Hierarchical Structure of Environmental Management Cell

The hierarchical structure of Reynish Pharmachem is given below

Figure 10.1: Environment Management Cell

10.6.2 ENVIRONMENT POLICY

Unit will develop Environment Policy. They commit themselves to:

EHS Head

ETP in-charge Safety officer

General Manager

(Operation)

ETP

Operator

ETP

Chemist



Ensure continuous improvement in environmental performance of our

works through protective Environmental management system.

Comply with applicable legal and other requirements related to

environmental aspects.

Conserve the resources particularly water, power by fixing and

improving consumption norms.

Concept of cleaner production will be adopted.

Ensure involvement of all employees and contractors in effective

implementation of Environment Management System through

training and awareness.

Promote awareness among local surrounding community for

preservation and maintaining clean environment.

10.6.3 Reporting System of Non-Compliances/Violations of

Environmental Norms

Record keeping and reporting of performance is an important

management tool for ensuring sustainable operation of the unit. Records

are maintained for regulatory, monitoring and operational issues. Reynish

Pharmachem Pvt. Ltd. will develop reporting systems of non-

compliances/violations of environmental norms to the Board of Directors.

The mechanism is summarized below:

1. Identify deviation/non-compliance/violation of environmental norms

as lay down in consent to operate and letter of Environmental

clearance. Record to communication/complain received from

plausible stake holder.

2. The EHS manager will identify deviation/non-compliance/violation

from failure to comply with statutory requirements.

3. Respond from EHS manager within reasonable time limit to concern

authorities with c/c mark to Technical head.

4. Technical head will take it in action and give necessary guideline to

comply this deviation/non-compliance/violation of environmental

norms. Parallel arrange budget for necessary action to comply the

condition.



5. Communication received from the EHS manager will be discussed in

technical management meeting.

6. Board discussion, Decision and Action

The chairperson will review the information available and take a

decision depending on the seriousness of the violation.

The decision will be taken to ensure the compliance of non-

compliance/violation of environmental norms and it’s safeguarded.

The decision will be taken by consensus and if no consensus is

arrived at, voting will be conducted.

Enlist measures that would undertake to ensure that deviations/

non-compliance/violations of Environmental norms and take care

not to occur same violation in future.

10.6.4 Framework for Continual Improvement of Environmental

Performance of Organization

10.7 RESOURCE CONSERVATION AND CLEANER PRODUCTION

Steps that are undertaken by the industry are given below:

RO permeate and MEE condensate will be reused to reduce fresh

water demand.

Housekeeping will be regularly maintained. Dedicated staff for the

purpose will be employed.

Solid wastes e.g. powders, spills, etc. in process and packaging are

to be separately collected and disposed of instead of allowing these

EMP

Implementation

Monitoring as

per EMP

requirement

Internal and

External Audits Corrective and

Preventive Actions

Review and revision of EMP

based on Environmental

Performance Evaluation Improvement

Mitigation

measures



to effluent streams. This will reduce load to treatment and increase

the efficiency of treatment system.

Mechanical seals will be provided to the process vessels having

agitator for reduction of fugitive emissions and leakages.

Rain water harvesting system will be adopted to compensate the

fresh water withdrawal.

10.8 ENERGY CONSERVATION PROGRAMME

Energy conservation measures are often the easiest, quickest and

cheapest way to reduce costs and be environmentally pro-active. The

conservation efforts would consist of the following:

Ensure proper selection fuel-firing equipments - Burners, mechanical

stokers, etc.

Reduce radiation losses from boilers, furnaces and auxiliary equip-

meant by improved thermal insulation. This will also improve the

working conditions within the building and eliminate unnecessary

ventilation,

Schedule process operations to avoid fluctuations in boiler loads,

Keep the heat transfer surfaces clean by preventing excessive scale

formation,

Pressure vessels should be designed with a length to diameter ratio

of roughly three as they are the most economical,

Maximize the use of natural lighting through design,

CFLs or LED lights are used in administration building and plant

premises,

Constant monitoring of energy consumption and defining targets for

energy conservation,

Maximize the use of laptop computers over desktop computers as

Laptops use less energy than desktop and leave a smaller

environmental footprint at end of life,

Adjusting the settings and illumination levels to ensure minimum

energy used for desired comfort levels,

Recycling of water will be done, and



10.9 SOCIO-ECONOMIC ACTIVITIES

Enterprise Social Commitment (ESC) refers to voluntary actions

undertaken by company/organization to either improve the living

conditions (economically, socially, environmentally) of local communities

or to reduce the negative effects of the project. By definition, voluntary

actions are those that go beyond legal obligations, contracts, and license

agreements. Socio-economic development activities is a concept of

organization whereby organizations serve the interests of society by

taking responsibility for the impact of their activities on customers,

employees, shareholders, communities and the environment in all aspects

of their operations.

Following activities will be under taken as a part of CSR under

different heads:

A. Education

Awarding meritorious school students in SSC & HSC

Science Lab - Equipment & books in libraries for schools

Supports for sport & cultural competitions in schools

B. Health and family welfare

Malaria eradication camps (collection of blood sample & detection of

virus & free medicine distribution, blood donation camp)

Contribution towards primary Health Services depending on local

needs.

Dental & Eye checkup camp

C. Preservation of Environment and Sustainable Development

Water harvesting systems in nearby villages.

Landscaping and greenbelt development in & around the project

site.

Provide sanitation facilities to villagers.

D. Women Empowerment & children Development activities

Providing training and basic facility for self-sustainability of women.

Scholarship for education to children coming from Low Income

family.

Reynish Pharmachem Pvt. Ltd. proposes to allocate Rs. 2.0 Crores

(Increase the CER budget from 2.5% to 5.0% as suggested by EAC



committee (Industry-II) of total project cost i.e. Rs. 40.0 Crores) towards

the Enterprise Social Commitment. Proposed activities with budgetary

allocation are given below.

Table: 10.4 Budgetary Provisions for the Social Upliftment

Sr.

No.


Budget

(Rs. in

Lakhs)

1st 2nd 3rd


Computers 6.08 6.08 -- 12.16

Scholarship 12.8 12.8 12.8 38.4


water cooler at

Primary school and


villages

14.0 14.0 14.0 42.0

Operating and

maintenance cost

2.0 2.0 2.0 6.0


welfare

Around 10 camp with

cluster of 5 to 6

villages

4.0 4.0 4.0 12.0




women coming from BPL

family and widow

women.


study area

Onetime 100 nos

Sawing machine

5.0 5.0 5.0 15.0

Onetime 50 no

embroidery Machine

5.0 5.0 2.5 12.5


four village pond namely

Dabhasa, Bhoj Ranu

Pond and Dabka and

other as per the

suggestion by local

authorities.

8 village pond 22.0 22.0 -- 44.0

Total 76.88 76.8

8

46.3 200.06



Chapter-11

Summary & Conclusion

11.1 PROJECT DESCRIPTION

11.1.1 General Introduction

M/s. Reynish Pharmachem Pvt. Ltd. is a green field project, proposes

to set up bulk drugs manufacturing unit at Survey no. 504, 505, 507,

Village: Dabhasa, Ta.: Padra, District: Vadodara, Gujarat. Total

production capacity of all products will be tune around 50 MT/month.

Project activity falls under item 5(f) of the Schedule of EIA Notification,

2006 and its subsequent amendments.

11.1.2 Brief project description





Location

Survey No. 504, 505, 507

Village Dabhasa

Tehsil Padra

District Vadodara

State Gujarat

Area 36958 m2



Nearest

Railway Station Vadodara Railway Station – 19.0 km,




City Vadodara, about 20 km


Proposed

Power Requirement 1000 kVA, Source: MGVCL (Madhya Gujarat Vij Company Limited)

Water Requirement Total: 253 KLD;

Fresh water: 118 KLD; Recycle: 135 KLD

Source of raw water: Bore well

Wastewater Generation Industrial: 141 KLD, ZLD

Domestic: 4 KLD



Fuel Requirement Agro Briquettes: 37 TPD Diesel for D.G. Set: 125 lit/hr.

Source of Air Emission Boiler (1 no.), Thermic fluid heater (1 no), Hot air generator (1 no.), D. G. set

(1 no.), process vent (1 no.), SFD/FBD/RVD (5 nos.).

Details of Haz. Waste ETP sludge, MEE Salt, Distillation residue,

spent carbon, spent catalyst, off specific

product, date expired product, Used Oil,

Discarded drums/containers & Liners,

HCl, Sodium bisulfite

11.1.3 Investment of the project

Estimated cost of the proposed project will be around Rs. 40.0 Crores.

Out of this, Rs. 2.5 Crores will be earmarked as capital investment for

EMS and Rs. 1.5 Crores will be recurring/operating cost per annum.

11.1.4 List of products

Product details with its capacity are given in table below.

Sr. No.

Name of Products Qty. MTPM

1. Telmisartan 48.0

2. Ondansetron HCl

3. Benfotiamine

4. Albendazole


6. Zopiclone


8. Bupropion HCl

9. Anstrozole

10. Theophylline

11. Allantoin



14. Rebamipide

15. Valsartan

16. R & D Drugs 2.0

Total 50.0

11.2 DESCRIPTION OF ENVIRONMENT

11.2.1 Baseline Environmental Study

To predict the impact of the project on the surrounding environment, the

current baseline environmental status was studied by collecting the data

and carrying out monitoring during October, 2018 to December, 2018

in the study area of 10 km radius from project site as per the TOR.



11.2.2 Air Environment

The ambient air quality monitoring was carried out at 8 AAQM locations,

to assess the existing sub-regional air quality status during the period of

October, 2018 to December, 2018.

Combined Sampler along with the analytical methods, prescribed by

CPCB was used for carrying out air quality monitoring. At all these

sampling locations; PM10, PM2.5, SO2 and NOx were monitored on 24-

hourly and HCl, CO, HC and VOCs were monitored on 8-hourly basis to

enable the comparison with ambient air quality standards prescribed by

the CPCB. The data on concentrations of various pollutants were

processed for different statistical parameters like arithmetic mean,

standard deviation, minimum and maximum concentration and various

percentile values. The results are summarized below:

Particulate Matter (PM10)

An average and 98th percentile value of 24-hourly PM10 values at all the

locations are found from 63.7 – 71.0 g/m3 and 63.7 – 68.8 g/m3. The

results were found well within the National Ambient Air Quality Standards

(NAAQS-CPCB) of 100 g/m3.

Particulate Matter (PM2.5)

An average and 98th percentile value of 24-hourly PM2.5 values at all the

locations ranges from 37.0 – 48.0 g/m3 and 41.4 – 50.0 g/m3. The

values are well within National Ambient Air Quality Standards (NAAQS-

CPCB) of 60 g/m3.

Sulphur Dioxide (SO2)

An average and 98th percentile value of 24-hourly SO2 value of arithmetic

mean at all the locations ranged from 13.0 – 16.3 g/m3 and 15.8 – 20.8

g/m3 respectively, which are well below National Ambient Air Quality


Oxides of Nitrogen (NOx)

An average and 98th percentile value of 24 hourly NOx value of arithmetic

mean at all the locations ranged from 15.8-18.1 g/m3 and 19.7-23.6

g/m3 respectively, which are well below the National Ambient Air Quality


Hydrochloric acid (HCl)

HCl found below detectable limit at all the locations.



Carbon Monoxide (CO)

Minimum & Maximum value of CO at all the locations ranged from 1024 –

1182 g/m3.

Hydro Carbon (HC)

Minimum & Maximum value of Methane HC at all the locations ranged

from 32.2 – 41.1 g/m3 and non-methane HC ranged from 1028 – 1185

g/m3.

Volatile Organic Compounds (VOCs)

Minimum & Maximum value of VOC at all the locations ranged from 0.27

g/m3 – 3.41 g/m3.

Conclusion:

The quality of ambient air in the study area is compared with AAQM

Standards prescribed by CPCB & found below the prescribed standards.


Eight surface water & eight ground water samples were collected during

the study period.

Surface Water Quality

Surface water samples were collected from pond of village Dabhasa,

Padra, Bhoj, Ranu, Luna, Dabka, Tajpur and Mahi River. Results of the

same are given in Chapter-3 of EIA report.

Conclusion:

It was observed that all the physico-chemical parameters and heavy

metals from surface water samples except turbidity are below stipulated

drinking water standards and are suitable for domestic purposes.

Ground Water Quality

Ground water samples have been collected Project site, Dabhasa, Padra,

Umaraya, Dhobikuwa, Ranu, Bhoj and Vishrampura villages.

The summary of the analysis is as below:

Color: All the samples were found color less meeting desirable norms.

pH: All the samples meet the desirable standards (pH ranges from 7.3-

7.9).

Total Dissolved Solids (TDS): TDS in samples ranges from 1092 mg/L

(Nr. Project Site) to 1923 mg/L (Umaraya). The entire samples meet the

permissible limit of 2000 mg/L TDS.



Calcium: Calcium contents in the water ranges from 44 mg/L

(Dhobikuwa) to 92 mg/L (Umaraya), all the samples meet the permissible

limit of 200 mg/L, (Permissible Limit in the Absence of Alternate Source).

Magnesium: Magnesium content in the water ranges from 40 mg/L

(Bhoj) to 59 mg/L (Dhobikuwa). All the samples meet the permissible

limit of 100 mg/L (Permissible Limit in the Absence of Alternate Source).

Sulfate: Sulfate content in the water ranges from 58 mg/L (Nr. Project

Site) to 116 mg/L (Dabhasa). All the samples meet the permissible limit

of 400 mg/L (Permissible Limit in the Absence of Alternate Source).

Fluoride: Fluoride content in the water ranges from 0.56 mg/L

(Vishrampura) to 0.70 mg/L (Dhobikuwa). All the samples meet the

permissible limit of 1.5 mg/L (Permissible Limit in the Absence of

Alternate Source).

Total Alkalinity: Total alkalinity in the water samples ranges from 308

mg/L (Dabhasa) to 346 mg/L (Padra). All the samples are within the

permissible limit of 600 mg/L (Permissible Limit in the Absence of

Alternate Source).

Other Parameters: Potassium (ranges from 43 mg/L to 68 mg/L),

Sodium (ranges from 323 mg/L to 592 mg/L) and Chloride (ranges from

512 mg/L to 935 mg/L). All the samples meet permissible limit in the

absence of alternate source.

Heavy metals like cadmium, copper, lead, chromium, iron and zinc are

well below the limit in all samples.

Conclusion:

The results have been compared with the drinking water quality

standards specified in IS: 10500-2012 & all parameters meet the

permissible limit set by the authority (BIS).

11.2.4 Noise Environment

Noise monitoring has been conducted at nine locations in the study area.

The monitored noise level in the day time Leq (Ld) varies from 50.7 to

53.7 dB(A) and the night time Leq (Ln) varies from 39.2 to 43.4 dB(A)

within the study area. Higher noise value of 53.7 dB(A) was recorded

during day time at Village 1000 m East from the site & lower noise value



of 40.1 dB(A) was recorded during night time at 500 m North from the

site.

11.2.5 Soil Quality

Soil samples were collected from 8 different locations and analyzed to

assess the soil quality prevailing in the study area. Physical

characteristics of soil have been delineated through specific parameters,

viz. particle size distribution (grain size analysis), porosity, water holding

capacity and permeability whereas data for chemical characterization of

soil, viz. pH, electrical conductivity, cation exchange capacity and sodium

absorption ratio have been analyzed.

11.2.6 Biological Environment

Baseline data for flora & fauna has been collected with its family. It was

found that, none of the species of conservation importance exists in the

study area and no endangered species found in the study area.

11.2.7 Socio-Economic Environment

Socio-economic study includes description of demography, available basic

amenities like housing, health care services, transportation, education

facilities. Information on the above said parameters has been collected to

define the socio-economic profile of the study area (10-km radius).

11.3 ANTICIPATED ENVIRONMENTAL IMPACTS AND MITIGATION

MEASURES

Impact identification has been carried out for various activities involved in

construction as well as operational phase of the project and prediction

has been done for significant impacts. The summary of anticipated

adverse environmental impacts due to proposed project and mitigation

measures is given below.

11.3.1 Summary of impacts on Air Environment:

(a) During construction phase & Mitigation measures

Main sources of impact during construction phase are due to movement

of vehicles & construction equipment at site, foundation works,

transportation of construction material etc. Water sprinkling in the vicinity

of the construction area will be done to control dust. PUC certified

vehicles will be used. Temporary barricades will be provided to reduce

spreading of particulates from construction area.



(b) During operation phase & Mitigation measures

Flue gas emission will be from stack attached with boiler where Agro

Briquettes will be used as a fuel; and standby D.G. Set. Most probable

pollutants will be SPM, SO2 and NOx. Multi Cyclone, bag filter & water

scrubber will be installed as APCM for flue gas stacks. Process emission

will be from the reaction vessels and vent of Spin flash dryers (SFD)/Fluid

Based Dryer (FBD)/Rotary Vacuum Dryer (RVD). Pollutants from reaction

vessels will be SO2 & HCl and PM will be generated from SFD/FBD/RVD.

To control the process emission, water and alkali scrubber will be

provided. SFD/FBD/RVD will be equipped with in-built cyclone and bag

filter.

Prediction of impacts on air environment is quantified using ISCST3

model. Maximum Ground level concentrations of 24-hr average for SPM,

SO2, NOx and HCl from the proposed activity are 3.603 g/m3, 1.902

g/m3, 1.628 g/m3 and 0.287 g/m3 respectively. These GLCs are

expected to occur at a distance of 1.0 km from the source in W direction.

The obtained GLCs are well within the 24-hourly ambient air quality

standards stipulated by CPCB. However, to mitigate the impact due to the

proposed, unit will provide adequate stack height for proper atmospheric

dispersion as per the norms.

11.3.2 Summary of impacts on Water Environment

(a) Impacts during construction phase & Mitigation measures:

Temporary impacts are likely to occur due to water consumption &

sewage generation. It will not be significant as water requirement would

be temporary during construction phase. Proper sanitation facilities with

adequate disposal system will be provided within the operational plant.

(b) Impacts during operation phase & Mitigation measures:

Fresh water requirement of the unit will be satisfied from bore well. Total

water requirement (Industrial + Domestic + Greenbelt) will be 253 KLD;

out of which 118 KLD will be fresh water requirement & 135 KLD will be

recycle/treated water (RO permeate & MEE condensate).

Total industrial w/w generation will be 141 KLD. Process effluent along

with wastewater of scrubber, washing and utility will be taken to RO after

primary and secondary treatment. RO reject will be sent to MEE; RO



permeate and condensate of MEE will be reused. Domestic wastewater

4.0 KLD will be disposed to soak pit. Thus, achieving Zero Liquid

Discharge (ZLD). ETP sludge and MEE salt will be disposed to approve

TSDF site.

11.3.3 Impacts on Noise quality & Mitigation measures


During construction phase, major sources of noise are vehicle’s

movement & construction activities. High noise producing activities will be

restricted to daytime only. Well maintained equipments will be used to

prevent noise. Usage of PPE by workers will be made compulsory.


During the operation phase, the noise levels may increase due to the

operation of boilers, reactors, D.G. sets and other machineries. The

impact is found to be insignificant outside the premises. Unit will provide

necessary PPEs like earplugs or earmuffs to all workers where exposure is

85 dB(A) or more. Selection of any new plant equipment will be made

with specification of low noise levels.

11.3.4 Summary of Impacts on Land Environment


The construction activities like excavation, leveling & vehicular

movements will change the landscape, which are expected to be of short

duration & insignificant. Preliminary activities like proper storage of

construction materials & proper management will be done within the

project area. Therefore, impact will be negligible. Unit will provide

sanitation facilities for the staff engaged in construction work which will

prevent the impacts on land.


Hazardous wastes will have significant negative impacts if disposed

unsystematically. Unit has provided all required structural facilities like

separate hazardous waste storage room with RCC floor, leachate

collection system, and concrete floors within premises. Hence, no

significant negative impact is envisaged on the land environment.



11.3.5 Summary of impact on Socio Economy


As this is a Greenfield project, workers for the construction work will be

required. Local contractors to be employed for construction, so no other

issues like social conflict are envisaged. Temporary employment

generated during construction of project will have beneficial impacts on

economic environment.


Project will require about 65 persons for its operation, which result into a

positive impact on prevailing socio-economic environment. Project will

also have potential of indirect employment due to the increase

transportation activities, contractual works as well as opportunity of

trade. Thus, overall impacts on socio-economic environment are long

term and positive in nature.

11.3.6 Summary of impact on Ecology

There are no protected areas like National Park/Wildlife Sanctuary within

the 10 km radial periphery of the project site so there will not be any

significant impact on ecology.

11.4 ENVIRONMENT MONITORING PROGRAMME

The unit will have dedicated Environment Management Cell to monitor

and evaluate the environmental performance and to supervise the EMS.

Below Post-project monitoring programme will be followed.

Environment Monitoring Program

Nature of Analysis

Frequency of analysis with its analyzer

Parameters No. of samples

Wastewater analysis



& Grease, etc.

2-3 samples

Stack Monitoring

of each stack

Monthly by external

agency

PM, SO2, NOX,

HCl

All stacks

Ambient Air

Quality Monitoring

Monthly for 24 hours or

as per the statutory conditions by external

agency

PM10, PM2.5,

SO2, NOX, HCl

3-5 locations

Noise level Monthly as per the statutory conditions by external agency

Noise level 6-8 locations (Nr. Main gate, Nr.

boiler, Nr. D. G. Set,

Process area etc.)



Work zone fugitive

monitoring



2-3 locations

Health check-up of workers

As per the statutory guideline

All workers

11.5 ADDITIONAL STUDIES

11.5.1 Risk Assessment

Risk analysis and study have been carried out for identification of

accident hazards, selection of credible scenarios, Risk Mitigation

measures etc. All the hazardous chemicals will be stored and handled as

per MSDS guidelines. The detail study is prescribed in Chapter-7.

11.6 PROJECT BENEFITS

Proposed project has a potential for employment of skilled, semi-skilled &

unskilled employees. The direct employment potential is estimated as 65

persons and many others will be indirectly employed. Indirectly, the

proposed project will help the Government by paying different taxes from

time to time, which is a part of revenue and thus, will help in developing

the area. The company has allocated a budget of Rs. 2.0 Crore for CER

activities, which can lead to improve social infrastructure.

11.7 ENVIRONMENTAL MANAGEMENT PLAN

EMP includes the protection & mitigation measures to be implemented to

reduce the adverse impact on the environment. Management plan of

impacts identified is detailed below:

Air Pollution Management

Multi Cyclone, bag filter & water scrubber will be installed as APCM to

control flue gas emission. To control the process emission, water and

alkali scrubber will be provided. SFD/FBD/RVD will be equipped with in-

built cyclone and bag filter.

Appropriate stack height and SMF will also be provided as per the

guideline. To control the fugitive emissions, unit will adopt following

mitigation measures. • Regular maintenance of valves, pumps and other equipment will be

done to prevent leakages.



• Regular maintenance of air pollution control equipments like scrubber

and bag filters keeping its efficiency utmost.

• Mechanical seals will be provided to all the reactors.

• Regular periodic monitoring of work area to check the fugitive

emission.

Water Pollution Management

• Industrial wastewater will be treated in ETP followed by RO & MEE to

achieve ZLD.

• RO permeate & condensate of MEE will be reused within the premises.

• Domestic sewage will be disposed off into soak pit though septic tank.

• Unit will maintain the records for the total water consumption.

• Regular monitoring of working of ETP, RO & MEE.

• Rain water harvesting will be done.

Hazardous Waste Management


Hazardous & Other wastes (Management & Transboundary Movement)

Rules, 2016. ETP sludge (25 MT/month), MEE salt (50 MT/month) from

wastewater treatment and Process waste (12 MT/month) will be disposed

of at approved TSDF site. Spent carbon (0.75 MT/month), and spent

catalyst (1.0 MT/month) will be returned back to supplier for

regeneration. Distillation residue (15 MT/month), off specific products and

date expired products will be sent for co-processing or at CHWIF for

incineration. Used lubricating oil (40 Lit/month) will be sold to registered

recycler. Discarded Drums (700 Nos./month) & containers/ Liners (0.5

MT/month) will be sold to actual users. HCl (20-25%) - 75 MT/month and

Sodium bisulfite (NaHSO3) - 50 MT/month will be sold to actual user

under Rule-9 of HAZ Rule. The unit will provide isolated area with

impervious flooring & roof cover for the storage of hazardous waste.

There will not be any major impact on the environment due to hazardous

waste management. Fly ash generation will be around 4.0 MT/day. Fly

ash will be sold to brick manufacturers.

Noise Pollution Management

• Extensive oiling, lubrication and regular maintenance will be carried

out for the machineries and equipments to reduce noise generation.

• PPEs will be provided to the workers working in high noise area.



• Acoustic enclosure will be provided to D.G. set.

• Greenbelt will be developed within industrial premises to prevent the

noise pollution.

• Periodic monitoring of noise levels will be done.

Green Belt Development

Total land area is 36958 m2. The unit will develop greenbelt in an area of

12175 m2. Overall greenbelt area will be more than 33% of the total area

of the project.

11.8 CONCLUSION

Based on the study it is concluded that-

There will be no major impact on water environment as entire process

wastewater along with other stream of wastewater will be treated into

ETP and will be taken to RO. RO reject will be sent to MEE and unit will

achieve Zero Liquid Discharge (ZLD).

Condensate of MEE and RO permeate will be reused/recycled within

plant premises. Thus, reducing fresh water consumption.

Domestic effluent will be disposed to soak pit though septic tank.

Multi Cyclone, bag filter & water scrubber will be used as pollution

control equipments for control of flue gas emission.

Water scrubber and Alkali scrubber will be installed as pollution control

equipments for process emission from the unit.

SFD/FBD/RVD will be equipped with in-built cyclone and bag filter.

Fugitive emission will be controlled by close material handling system

and proper storage of materials.

For noise control, unit will provide necessary PPEs like earplugs or

earmuffs to all workers and selection of any new plant equipment will

be made with specification of low noise levels.

Entire quantity of hazardous waste will be handled and disposed as per

Hazardous & Other Waste (Management & Transboundary Movement)

Rules, 2016.

Greenbelt will be developed in more than 33% of the total area.

Fire protection and safety measures will be provided.

Direct and indirect employment opportunities will have positive

impact.



Chapter-12

Disclosure of Consultant engaged

12.1 PREFACE

San Envirotech Pvt. Ltd. (SEPL) has been appointed by Reynish

Pharmachem Pvt. Ltd. to carry out this Environmental Impact

Assessment Study as per the EIA notification, 2006 as amended till date.

SEPL is accredited as Category-A organization under the QCI-NABET

Scheme for accreditation of EIA consultant Organizations: Version 3 for

preparing EIA-EMP reports in 10 sectors (Certificate No. NABET/EIA/

1619/RA0084; Valid till 15.06.2020).

12.2 DETAILS OF EIA CONSULTANT ORGANIZATION

San Envirotech Pvt. Ltd. has started its work in 1990 to serve the

environment as a trustee of next generation with a small infrastructure

under the dynamic leadership of Dr. Mahendra Sadaria. SEPL has wide

spectrum of national and multinational clients covering the industries -

Bulk Drugs and Pharmaceuticals, Dyes and Dye Intermediates, Pesticides,

Fertilizers, Chemicals, Cement, Mining, and Infrastructure. During last

two decades, SEPL has been taking care of client’s unique problems and

concerns in order to develop cost effective strategies to meet their

regulatory obligations. SEPL focuses on strategic planning and

comprehensive solutions to address both short and long term needs of

the clients.

SEPL has in-house multi-disciplinary analytical testing laboratory that is

MoEFCC approved under EP Act. SEPL is also a recognized schedule-II

Environmental Auditor appointed by Gujarat Pollution Control Board as

per the directives of the Honorable High Court of Gujarat. SEPL is also an

ISO 9001:2008, 14001:2008 and OHSAS 18001 certified company. SEPL

team consists of qualified & experienced personnel. Experts involved in

the preparation of this EIA/EMP report are given in EIA report as

‘declaration by experts’.

Annexure-I NABET-QCI Certificate

A-1

A-2

Annexure-II Photographs of the Site

Photographs of the proposed site

The project site is located at Survey no. 504, 505, 507, Village: Dabhasa, Ta.:

Padra, District: Vadodara, Gujarat.

A-3

Annexure-III Land Possession Documents

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Annexure-IV Material Safety Data Sheet of Chemicals

Product: Acetone Revision Date: 12/03/2012 1/8

Acetone MSDS Effective Date: December 03, 2012 24 Hour Emergency Contact: ChemTel: (800)255-3924 www.pioneerforensics.com

1. PRODUCT AND COMPANY IDENTIFICATION Product: Acetone Product Number(s): PF003 CAS#: 67-64-1 Synonyms: Dimethylketal; 2-Propanone; Dimethyl ketone Manufacturer: Pioneer Forensics, LLC

804 E. Eisenhauer Blvd. Loveland, CO 80537 Ph: (970) 292-8487

Emergency Number: (800) 255-3924 (CHEM-TEL) Customer Service: (970) 292-8487

2. HAZARDS IDENTIFICATION Emergency Overview: DANGER! Extremely flammable liquid and vapor. Vapor may cause flash fire. Easily

ignited by heat, spark or flames. Causes eye irritation. Harmful if swallowed. May enter lungs if swallowed or vomited. Prolonged or repeated skin contact may cause drying, cracking, or irritation. High vapor concentrations may cause drowsiness and irritation of the eyes or respiratory tract.

Safety Ratings: Health: 2, Moderate Reactivity: 0, None

Flammability: 3, Severe Contact: 2, Moderate OSHA Regulatory Status: This product is considered a "Hazardous Chemical" as defined by the OSHA Hazard

Communication Standard, 29 CFR 1910.1200. Potential Acute Health Effects:

Routes of Exposure: Inhalation, ingestion, skin contact, eye contact Inhalation: May cause irritation to the mucous membranes and upper respiratory tract. In high

concentrations, vapors and aerosol mists have a narcotic effect and may cause headache, fatigue, dizziness and nausea.

Ingestion: Irritating. May cause nausea, stomach pain and vomiting. Aspiration (breathing) of vomitus

into lungs must be avoided as even small quantities may result in aspiration pneumonitis. Skin Contact: Prolonged or repeated contact with skin may cause redness, itching, irritation and

eczema/chapping. Eye Contact: Causes irritation. High vapor/aerosol concentrations may cause eye irritation.

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Target Organs: Skin, respiratory system, eyes, central nervous system Chronic Health Effects: Frequent or prolonged contact may defat and dry the skin, leading to discomfort and

dermatitis. Aggravation of Repeated or prolonged exposure to the substance can produce target organs damage. Medical Conditions: Persons with pre-existing skin disorders or eye problems may be more susceptible to the

effects of the substance. Potential Environmental Not classified as environmentally hazardous, however, this does not exclude the possibility Effects: that large or frequent spills can have harmful or damaging effects on the environment. 3. COMPOSITION AND INFORMATION ON INGREDIENTS Chemical Formula % by Components CAS# Formula Weight Hazardous Weight Acetone 67-64-1 C3H6O 58.08 Yes >99.5

4. FIRST AID MEASURES First Aid Procedures:

Inhalation: Remove to fresh air. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Get medical attention if symptoms persist.

Ingestion: Do not induce vomiting. If vomiting occurs, keep head low so that vomit does not enter

lungs. Never give anything by mouth to an unconscious person. GET MEDICAL ATTENTION IMMEDIATELY.

Skin Contact: Wash affected area with soap and water. Remove contaminated clothing and shoes. Wash

clothing before reuse. Get medical attention if symptoms occur.

Eye Contact: Check for and remove contact lenses. Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention.

General Advice: In the case of accident or if you feel unwell, seek medical advice immediately (show the

label where possible). Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.

Notes to Physician: Treat symptomatically. Keep victim under observation.

5. FIRE FIGHTING MEASURES NFPA Ratings: Health: 2 Flammability: 3 Reactivity: 0 Flammable Properties: HIGHLY FLAMMABLE! Vapors may cause a flash fire or ignite explosively. Vapors may

travel considerable distance to a source of ignition and flash back. Heat may cause sealed containers to explode.

Flash Point: -20° C (-4° F) Closed Cup

Auto-ignition Temp: 465° C (869° F)

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Flammable Limits in Lower Explosion Limit: 2.6% Air (% by volume): Upper Explosion Limit: 12.8%

Suitable Extinguishing Media: Water spray, dry powder, alcohol resistant foam, carbon dioxide Unsuitable Extinguishing Media: Do not use a solid (straight) water stream as it may scatter and spread fire. Hazardous Combustion Carbon monoxide, carbon dioxide Products: Specific Hazards: Can be ignited easily by heat, sparks, or flame and burns vigorously. Above flash point,

vapor-air mixtures are explosive within flammable limits noted above. Sealed containers may explode when heated or involved in fire. Vapor may accumulate in container headspace resulting in flammability hazard. Material is sensitive to static discharge.

Special Protective Equipment As in any fire, wear MSHA/NIOSH approved (or equivalent) self-contained positive pressure For Firefighters: or pressure-demand breathing apparatus and full protective gear. Specific Methods: Use water spray to cool unopened containers. Cool containers exposed to flames with

flooding quantities of water until well after the fire is out. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. Move containers from fire area if you can do so without risk. Some of these materials, if spilled, may evaporate leaving a flammable residue. In the event of fire and/or explosion do not breathe fumes.

6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Ventilate area of leak or spill. Isolate hazard area and keep unnecessary and unprotected

personnel away from the area of the leak or spill. Keep upwind. Keep out of low areas. Wear appropriate personal protective equipment as specified in the Exposure Control and Personal Protection Section 8. Avoid contact with eyes, skin, and clothing. Pay attention to flashback. Take precautionary measures against static discharges.

Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid

discharge into drains, water courses or onto the ground. In case of large spill, dike if needed.

Methods for Containment: Remove all sources of ignition. Stop the flow of material, if this is without risk. Prevent

entry into waterways, sewer, basements or confined areas. Dike the spilled material, where this is possible.

Methods for Cleaning Up: Use spark-proof tools and explosion-proof equipment. All equipment used when handling

the product must be grounded. Absorb spill with an inert material (e.g. vermiculite, dry sand, earth, cloth, fleece), and place in a suitable non-combustible container for reclamation or disposal. Do not use combustible materials, such as sawdust. Clean contaminated surface thoroughly. Never return spills in original containers for re-use. Clean up in accordance with all applicable regulations.

7. HANDLING AND STORAGE Handling: Do not handle or open near flame, sources of heat, or sources of ignition. Protect material

from direct sunlight. Wear personal protective equipment (see section 8). Use only in well-ventilated areas. Provide sufficient air exchange and/or exhaust in work rooms. Avoid contact with skin, eyes and clothing. Do not breathe vapors or spray mist. Do not ingest. When using, do not eat, smoke, or drink. Take precautionary measures against static discharge. Keep away from incompatible materials. Handle in accordance with good

A-11


industrial hygiene and safety practice. Wash thoroughly after handling. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquids). Observe all warnings and precautions listed for the product

Storage: Store in a cool, dry, ventilated area. Store away from flame, sources of ignition, heat, and

incompatible materials. Store in original container. Keep containers tightly closed and upright. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. Ground container and transfer equipment to eliminate static electric sparks. Comply with all national, state, and local codes pertaining to the storage, handling, dispensing, and disposal of flammable liquids.

8. EXPOSURE CONTROL AND PERSONAL PROTECTION Exposure Limits: ACGIH: TWA: 500 ppm

STEL: 750 ppm BEL: 50mg/L

OSHA: PEL: 1000 ppm 2400 mg/m3

Engineering Controls: Ensure adequate ventilation. Ventilation rates should be matched to conditions. If

applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Explosion proof exhaust ventilation should be used.

Personal Protective Equipment: Eye/Face Protection: Wear safety glasses with side shields or goggles and a face shield.

Skin Protection: Wear appropriate chemical resistant clothing (with long sleeves) and appropriate chemical resistant gloves.

Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended

exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respirator type: Chemical respirator with organic vapor cartridge. Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection.

General Hygiene Avoid contact with skin, eyes and clothing. When using, do not eat, drink or smoke. Always Considerations: observe good personal hygiene measures, such as washing after handling the material and

before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Provide eyewash station and safety shower.

9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Appearance: Transparent Color: Colorless Odor: Sweet, mint-like Molecular Formula: C3H6O

Molecular Weight: 58.08 pH: No information found Specific Gravity: 0.79 Freezing/Melting Point: -94.7 °C (-139 °F)

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Boiling Point: 56.1 °C (132.8 °F) Flash Point: -20° C (-4° F) Closed Cup Auto Ignition Temperature: 465° C (869° F) Flammable Limits in Air (% by Volume): Upper: 12.8% Lower: 2.6% Solubility: Miscible with water Vapor Pressure: 30.93 kPa at 25°C Vapor Density: 2 Odor threshold (ppm): 62-140 ppm Evaporation Rate: 5.6 BuAc Partition Coefficient (n-octanol/water): -0.24

10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: Heat, flames, sparks, ignition sources, incompatibles Incompatible Materials: Oxidizing agents, acids, alkalis, peroxides Hazardous Decomposition Carbon dioxide and carbon monoxide may form when heated to decomposition. Products: Possibility of Hazardous Can react vigorously, violently or explosively with incompatible materials listed above. Reactions: Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Toxicological Data: Oral Rat LD50: 5800 mg/kg Skin Rabbit LD50: 20000 mg/kg Inhalation Rat LC50: 76 mg/L 4H Acute Effects: Harmful if swallowed. May enter lungs if swallowed or vomited. Local Effects: Causes eye irritation. Prolonged or repeated skin contact may cause drying, cracking, or

irritation. High vapor concentrations may cause drowsiness and irritation of the eyes or respiratory tract.

Sensitization: Not a skin sensitizer. Chronic Effects: Frequent or prolonged contact may defat and dry the skin, leading to discomfort and

dermatitis. Carcinogenic Effects: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. ACGIH: A4 – Not classifiable as a human carcinogen Skin Corrosion/Irritation: Defatting, drying, and cracking of the skin. Epidemiology: No epidemiological data is available for this product.

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Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Neurological Effects: High vapor/aerosol concentrations (attainable only at elevated temperatures) may cause

central nervous system effects such as dizziness, drowsiness or headaches. Reproductive Effects: Contains no ingredient listed as toxic to reproduction. Teratogenic Effects: No data available to indicate product or any components present at greater than 0.1% may

cause birth defects. Target Organs and Symptoms: Moderate eye and/or upper respiratory tract irritation. Drowsiness and dizziness.

12. ECOLOGICAL INFORMATION Ecotoxicological Data: EC50 Water flea (Daphnia magna): 10294 mg/L 48 H

LC50 Fathead minnow (Pimephales promelas): > 100 mg/L 96 H Ecotoxicity: The product components are not classified as environmentally hazardous, however, this

does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Environmental Effects: Ecological injuries are not known or expected under normal use. Persistence and Degradability: Expected to be readily biodegradable. Partition Coefficient -0.24 (n-octanol/water): 13. DISPOSAL INFORMATION Disposal Instructions: Dispose of this material and its container to hazardous or special waste collection point.

Incinerate the material under controlled conditions in an approved incinerator. All wastes must be handled in accordance with local, state and federal regulations.

Contaminated Packaging: Since emptied containers retain product residue, follow label warnings even after container

is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near this container. Offer rinsed packaging material to local recycling facilities.

Waste Codes: US RCRA Hazardous Waste U List: Acetone: U002

14. TRANSPORT INFORMATION DOT: UN Number: UN1090 Proper Shipping Name: Acetone Hazard Class: 3 Packaging Group: II ERG Number: 127

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15. REGULATORY INFORMATION U.S. Federal Regulations:

OSHA: This product is considered a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

TSCA Inventory: Acetone

U.S. EPCRA (SARA Title III):

Sections 311/312: Hazard Categories List (Yes/No)____ Section 311 – Hazardous Chemical Yes

Immediate Hazard Yes Delayed Hazard No Fire Hazard Yes Pressure Hazard No Reactivity Hazard No CERCLA: Acetone: 5000 lbs

International Inventories: Country(s) or Region Inventory Name On Inventory (Yes/No)*

Australia Australian Inventory of Chemical Yes Substances (AICS)

Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No

China Inventory of Existing Chemical Yes Substances in China (IECSC)

Europe European Inventory of Existing Commercial Yes Chemical Substances (EINECS)

Europe European List of Notified Chemical No Substances (ELINCS)

Japan Inventory of Existing and New Chemical Yes Substances (ENCS)

Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Yes

Chemical Substances (PICCS) *A "Yes" indicates that the listed component(s) of this product comply with the inventory requirements administered by the governing country(s)

16. OTHER INFORMATION Product Use: Laboratory and/or field reagent Disclaimer: Pioneer Forensics LLC provides the information in this Material Safety Data Sheet in the

belief that it is reliable but assumes no responsibility for its completeness or accuracy. The physical properties reported in this MSDS are obtained from the literature and do not constitute product specifications. Pioneer Forensics LLC makes and gives no representations or warranties with respect to the information contained herein or the product to which it refers, whether express, implied, or statutory, including without limitation, warranties of accuracy, completeness, merchantability, non-infringement, performance, safety, suitability, stability, and fitness for a particular purpose. No warranty against

A-15


infringement of any patent, copyright or trademark is made or implied. This MSDS is intended only as a guide to the appropriate handling of the material by a properly trained person. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. Accordingly, Pioneer Forensics LLC assumes no liability whatsoever for the use of or reliance upon this information including results obtained, incidental or consequential damages, or lost profits.

Issue Date: 12/03/2012 Reason for Revision: Not applicable

A-16

SAFETY DATA SHEET

Revision Date 18-Jan-2018 Revision Number 3

1. IdentificationProduct Name 3-Nitrobenzoyl chloride

Cat No. : AC155840000; AC155840050; AC155841000; AC155845000

CAS-No 121-90-4

Synonyms m-Nitrobenzoyl chloride.

Recommended Use Laboratory chemicals.

Uses advised against Not for food, drug, pesticide or biocidal product use

Details of the supplier of the safety data sheet

Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11

Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99

CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887

2. Hazard(s) identificationClassification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Label Elements

Signal WordDanger

Hazard StatementsToxic in contact with skinCauses severe skin burns and eye damageMay cause respiratory irritation

Company Fisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100

Acros OrganicsOne Reagent LaneFair Lawn, NJ 07410

Acute dermal toxicity Category 3Skin Corrosion/irritation Category 1Serious Eye Damage/Eye Irritation Category 1Specific target organ toxicity (single exposure) Category 3Target Organs - Respiratory system.

______________________________________________________________________________________________

Page 1 / 7

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______________________________________________________________________________________________3-Nitrobenzoyl chloride Revision Date 18-Jan-2018

Precautionary StatementsPreventionWear protective gloves/protective clothing/eye protection/face protectionDo not breathe dust/fume/gas/mist/vapors/sprayWash face, hands and any exposed skin thoroughly after handlingUse only outdoors or in a well-ventilated area

ResponseImmediately call a POISON CENTER or doctor/physician

InhalationIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

SkinWash contaminated clothing before reuseIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower

EyesIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

IngestionIF SWALLOWED: Rinse mouth. DO NOT induce vomiting

StorageStore locked upStore in a well-ventilated place. Keep container tightly closed

DisposalDispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) None identified

3. Composition/Information on Ingredients

Component CAS-No Weight %

Benzoyl chloride, 3-nitro- 121-90-4 98

4. First-aid measures

Eye Contact Immediate medical attention is required. Rinse immediately with plenty of water, also underthe eyelids, for at least 15 minutes.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Immediate medical attention is required.

Inhalation Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. Ifnot breathing, give artificial respiration. Obtain medical attention.

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Drinkplenty of water. Call a physician immediately. If possible drink milk afterwards.

Most important symptoms andeffects

Causes burns by all exposure routes. Product is a corrosive material. Use of gastriclavage or emesis is contraindicated. Possible perforation of stomach or esophagus shouldbe investigated: Ingestion causes severe swelling, severe damage to the delicate tissueand danger of perforation

Notes to Physician Treat symptomatically

______________________________________________________________________________________________

Page 2 / 7

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5. Fire-fighting measuresSuitable Extinguishing Media Carbon dioxide (CO 2). Dry chemical. Chemical foam.

Unsuitable Extinguishing Media No information available

Flash Point > 112 °C / > 233.6 °F

Method - No information available

Autoignition Temperature No information available

Explosion LimitsUpper No data available

Lower No data available

Sensitivity to Mechanical Impact No information available

Sensitivity to Static Discharge No information available

Specific Hazards Arising from the ChemicalKeep product and empty container away from heat and sources of ignition.

Hazardous Combustion ProductsHydrogen chloride gas Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Phosgene

Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.

NFPA

6. Accidental release measuresPersonal Precautions Ensure adequate ventilation. Use personal protective equipment.

Environmental Precautions See Section 12 for additional ecological information.

Methods for Containment and CleanUp

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder,sawdust). Keep in suitable, closed containers for disposal.

7. Handling and storageHandling Avoid contact with skin and eyes. Do not breathe dust. Do not breathe vapors or spray mist.

Use only in area provided with appropriate exhaust ventilation.

Storage Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Corrosivesarea.

8. Exposure controls / personal protectionExposure Guidelines This product does not contain any hazardous materials with occupational exposure

limitsestablished by the region specific regulatory bodies.

Health3

Flammability1

Instability0

Physical hazardsN/A

Engineering Measures Ensure adequate ventilation, especially in confined areas.

Personal Protective Equipment

Eye/face Protection

______________________________________________________________________________________________

Page 3 / 7

Wear appropriate protective eyeglasses or chemical safety goggles as described byOSHA's eye and face protection regulations in 29 CFR 1910.133 or European StandardEN166.

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9. Physical and chemical propertiesPhysical State Solid

Appearance Brown

Odor pungent

Odor Threshold No information available

pH No information available

Melting Point/Range 30 - 35 °C / 86 - 95 °F

Boiling Point/Range 275 - 278 °C / 527 - 532.4 °F @ 760 mmHg

Flash Point > 112 °C / > 233.6 °F

Evaporation Rate No information available

Flammability (solid,gas) No information available

Flammability or explosive limitsUpper No data available

Lower No data available

Vapor Pressure No information available

Vapor Density No information available

Specific Gravity 1.420

Solubility No information available

Partition coefficient; n-octanol/water No data available

Autoignition Temperature No information available

Decomposition Temperature No information available

Viscosity No information available

Molecular Formula C7 H4 Cl N O3

Molecular Weight 185.57

10. Stability and reactivity

Reactive Hazard None known, based on information available

Stability Stable under normal conditions. Moisture sensitive.

Conditions to Avoid Incompatible products.

Incompatible Materials Water, Strong bases, Alcohols

Hazardous Decomposition Products Hydrogen chloride gas, Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide(CO2), Phosgene

Hazardous Polymerization No information available.

Hazardous Reactions None under normal processing.

11. Toxicological informationAcute Toxicity

Product Information No acute toxicity information is available for this product

Component InformationComponent LD50 Oral LD50 Dermal LC50 Inhalation

Benzoyl chloride, 3-nitro- LD50 = 2460 µL/kg ( Rat ) LD50 = 790 µL/kg ( Rabbit ) Not listed

Toxicologically Synergistic No information available

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airlinerespirator in the positive pressure mode with emergency escape provisions.

Hygiene Measures

______________________________________________________________________________________________

Page 4 / 7

Handle in accordance with good industrial hygiene and safety practice.

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ProductsDelayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation No information available

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS-No IARC NTP ACGIH OSHA Mexico

Benzoyl chloride,3-nitro-

121-90-4 Not listed Not listed Not listed Not listed Not listed

Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

STOT - single exposure Respiratory system

STOT - repeated exposure None known

Aspiration hazard No information available

Symptoms / effects,both acute anddelayed

Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.Possible perforation of stomach or esophagus should be investigated: Ingestion causessevere swelling, severe damage to the delicate tissue and danger of perforation

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological informationEcotoxicity Do not empty into drains.

Persistence and Degradability No information available

Bioaccumulation/ Accumulation No information available.

Mobility No information available.

13. Disposal considerationsWaste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a

hazardous waste. Chemical waste generators must also consult local, regional, andnational hazardous waste regulations to ensure complete and accurate classification.

14. Transport informationDOT

UN-No UN3261

Hazard Class 8

Packing Group II

TDG UN-No UN3261

Hazard Class 8

Packing Group II

IATA UN-No 1759

______________________________________________________________________________________________

Page 5 / 7

A-21


Proper Shipping Name CORROSIVE SOLID, N.O.S.*

Hazard Class 8

Packing Group II

IMDG/IMO UN-No 1759

Proper Shipping Name CORROSIVE SOLID, N.O.S.

Hazard Class 8

Packing Group II

15. Regulatory information

International Inventories

Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL

Benzoyl chloride, 3-nitro- X X - 204-505-9 - X X - X -Legend:X - ListedE - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designatedpolymer made with any free-radical initiator regardless of the amount used.P - Indicates a commenced PMN substanceR - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.S - Indicates a substance that is identified in a proposed or final Significant New Use RuleT - Indicates a substance that is the subject of a Section 4 test rule under TSCA.XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data BaseProduction and Site Reports (40 CFR 710(B).Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactantsthat comprises one of the eligibility criteria for the exemption rule.

U.S. Federal Regulations

TSCA 12(b) Not applicable

SARA 313 Not applicable

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act) Not applicable

Clean Air Act Not applicable

OSHA Occupational Safety and Health AdministrationNot applicable

CERCLA Not applicable

California Proposition 65 This product does not contain any Proposition 65 chemicals

U.S. State Right-to-KnowRegulations

Not applicable

U.S. Department of Transportation

Reportable Quantity (RQ): NDOT Marine Pollutant NDOT Severe Marine Pollutant N

U.S. Department of Homeland SecurityThis product does not contain any DHS chemicals.

Other International Regulations

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A-22


Mexico - Grade No information available

16. Other informationPrepared By Regulatory Affairs

Thermo Fisher ScientificEmail: [email protected]

Revision Date 18-Jan-2018

Print Date 18-Jan-2018

Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standardreplacing the current legislation under 29 CFR 1910.1200 to align with the GloballyHarmonized System of Classification and Labeling of Chemicals (GHS).

DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text

End of SDS

______________________________________________________________________________________________

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A-23

Chloroform

Trichloromethane

CX1050

Other non-specified industry: Analytical reagent.

EMD Chemicals Inc.480 S. Democrat Rd.Gibbstown, NJ 08027856-423-6300 Technical ServiceMonday-Friday: 8:00 -5:00 PM

800-424-9300 CHEMTREC (USA)613-996-6666 CANUTEC (Canada)24 Hours/Day: 7 Days/Week

Material Safety Data Sheet

Product name

Supplier

Synonym

Material uses

Product code

Validation date

In case of emergency

Product and company identification

Chloroform

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1 .

4/2/2009.

Dermal contact. Eye contact. Inhalation. Ingestion.

Emergency overview

Hazards identification

Routes of entry

Potential acute health effects

Toxic by inhalation. Irritating to respiratory system. Exposure to decomposition productsmay cause a health hazard. Serious effects may be delayed following exposure.

Irritating to eyes.

Toxic if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.Irritating to skin.

Eyes

Skin

Inhalation

Ingestion

Physical state Liquid. [Colorless.]

See toxicological information (section 11)

Do not breathe vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing.Use only with adequate ventilation. Keep container tightly closed and sealed until readyfor use. Wash thoroughly after handling.

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Medical conditionsaggravated by over-exposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.

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OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).

2 .

Potential chronic health effects

Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.No known significant effects or critical hazards.:Mutagenicity

Teratogenicity : No known significant effects or critical hazards.No known significant effects or critical hazards.:Developmental effects

Fertility effects : No known significant effects or critical hazards.May cause damage to the following organs: kidneys, liver, heart, skin, eyes, centralnervous system (CNS).

:Target organs

WARNING: This product contains a chemical known to the State of California to causecancer.

HARMFUL IF INHALED OR SWALLOWED.CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION.SUSPECT CANCER HAZARD - MAY CAUSE CANCER.MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: KIDNEYS, LIVER, HEART,SKIN, EYES, CENTRAL NERVOUS SYSTEM.

WARNING!

Continued on next page A-24

2/8CX1050Chloroform

Composition/information on ingredients

Name CAS number % by weight

3 .

Chloroform 67-66-3 100

Wash out mouth with water. Do not induce vomiting unless directed to do so by medicalpersonnel. Never give anything by mouth to an unconscious person. Get medicalattention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty of waterfor at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention immediately.In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash clothing before reuse. Cleanshoes thoroughly before reuse. Get medical attention immediately.Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.

First aid measuresEye contact

Skin contact

Inhalation

Ingestion

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4 .

Use an extinguishing agent suitable for the surrounding fire.

Emits very toxic fumes when heated to decomposition.

Fire-fighting measures

Extinguishing media

Special remarks on firehazards

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.

In a fire or if heated, a pressure increase will occur and the container may burst.

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

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5 .

Special exposure hazards :

None known.:

Hazardous thermaldecomposition products

: Decomposition products may include the following materials:carbon dioxidecarbon monoxidehalogenated compoundscarbonyl halides

Flammability of the product :

Not suitable :

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Do not breathe vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment (see section 8).

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).

Personal precautions :

6 .

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,vermiculite or diatomaceous earth and place in container for disposal according to localregulations (see section 13). Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilled product.Note: see section 1 for emergency contact information and section 13 for wastedisposal. Dilute with water and mop up if water-soluble or absorb with an inert drymaterial and place in an appropriate waste disposal container.

Spill :

Methods for cleaning up


3/8CX1050Chloroform

Store in accordance with local regulations. Store in original container, protected fromdirect sunlight. Keep container tightly closed and sealed until ready for use. Containersthat have been opened must be carefully resealed and kept upright to prevent leakage.

Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.Use only with adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Empty containers retainproduct residue and can be hazardous. Do not reuse container.

Handling and storage

Handling

Storage

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Chloroform ACGIH (United States, 1996). TWA: 49 mg/m³OSHA (United States, 1989). TWA: 9.78 mg/m³ACGIH TLV (United States, 1/2008). TWA: 10 ppm 8 hour(s). TWA: 49 mg/m³ 8 hour(s).OSHA PEL 1989 (United States, 3/1989). TWA: 2 ppm 8 hour(s). TWA: 9.78 mg/m³ 8 hour(s).NIOSH REL (United States, 6/2008). STEL: 2 ppm 60 minute(s). STEL: 9.78 mg/m³ 60 minute(s).OSHA PEL (United States, 11/2006). CEIL: 50 ppm CEIL: 240 mg/m³

Exposure controls/personal protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash gogglesPersonal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.Recommended: lab coat

Personal protection

Eyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

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Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary. Recommended: Viton

Hands :

8 .

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.

Ingredient Exposure limits


4/8CX1050Chloroform

60.5°C (140.9°F)

Liquid. [Colorless.]

100% (v/v)

Not available.

-63°C (-81.4°F)

1.49

4.1 [Air = 1]22.3 kPa (167 mm Hg)

Partially soluble in the following materials: water

205 ppm

263.3°C (505.9°F)

119.37 g/molePleasant. Ethereal.Colorless.

Boiling/condensation point

Melting/freezing point

10.2 (Butyl acetate. = 1)

Physical and chemical properties

Physical state

Molecular weight

pH

Critical temperature

Relative density

Vapor pressure

Vapor density

Volatility

Odor threshold

Evaporation rate

Solubility

Odor

Color

CHCl3Molecular formula

100 (%)VOC

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9 .

The product is stable.

Reactive or incompatible with the following materials: oxidizing materials, metals andalkalis.

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

Avoid exposure - obtain special instructions before use. Do not swallow.

Stability and reactivity

Chemical stability

Conditions to avoid

Materials to avoid

Hazardous decompositionproducts

Hazardous polymerization

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10 .

Emits very toxic fumes when heated to decomposition.Conditions of reactivity :

Possibility of hazardousreactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Toxicological information11 .

Acute toxicity

Chloroform LD50Intraperitoneal

Rat 894 mg/kg

LD50 Oral Rat 695 mg/kgLD50 Oral Rat 300 mg/kgLD50 Oral Mouse 36 mg/kgLD50 Dermal Rabbit >20 g/kgLD50 Oral Rat 1250 mg/kgLDLo Oral Man 2514 mg/kgLDLo Oral Rabbit 500 mg/kgTDLo Oral Rat 0.5 mL/kgTDLo Oral Rat 14.9 mg/kgTDLo Oral Rat 119.37 mg/kgTDLoIntraperitoneal

Rat 0.5 mL/kg

TDLoIntraperitoneal

Rat 180 mg/kg

LC50 InhalationVapor

Rat 6000 mg/m3

LC50 Inhalation Rat 47702 mg/m3

Product/ingredient name Test Route Species Result


5/8CX1050Chloroform

Toxicological information11 .VaporLC50 InhalationVapor

Rat 47702 mg/m³

Carcinogenicity

Mutagenicity

Teratogenicity

Classification

Chloroform A3 2B - + Possible -Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA

No known significant effects or critical hazards.

No known significant effects or critical hazards.

May cause cancer. Risk of cancer depends on duration and level of exposure.

Ecological information12 .

Aquatic ecotoxicity

Chloroform Acute EC50 950 mg/L Algae 48 hoursAcute EC50 560 mg/L Algae 48 hoursAcute LC50 81.5 to 106mg/L Marine water

Crustaceans - Northern pinkshrimp - Penaeus duorarum- 35 to 50 mm

48 hours

Acute LC50 65.7 mg/LFresh water

Daphnia - Water flea -Daphnia magna

48 hours

Acute LC50 17.1 mg/L Fish 96 hoursAcute LC50 16.2 mg/L Fish 96 hoursAcute LC50 15.1 mg/L Fish 96 hoursAcute LC50 13.3 mg/L Fish 96 hoursAcute LC50 17.1 ppmFresh water

Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss

96 hours

Acute LC50 16.2 ppmFresh water

Fish - Bluegill - Lepomismacrochirus

96 hours



96 hours



96 hours

Acute LC50 13300 ug/LFresh water

Fish - Bluegill - Lepomismacrochirus - 17.1 cm -126.4 g

96 hours

Acute LC50 758000 to850000 ug/L Fresh water

Daphnia - Water flea -Daphnia magna - Young -<=24 hours

48 hours


Daphnia - Water flea -Daphnia magna - Neonate -<12 hours

48 hours


Daphnia - Water flea -Ceriodaphnia dubia -Neonate - <12 hours

48 hours


Daphnia - Water flea -Daphnia magna - Neonate

48 hours


Daphnia - Water flea -Daphnia magna - Neonate

48 hours


Fish - Bluegill - Lepomismacrochirus - 16.9 cm -129.9 g

96 hours

Acute LC50 63800 to Daphnia - Water flea - 48 hours

Product/ingredient name SpeciesResult Exposure


6/8CX1050Chloroform

Ecological information12 .

Environmental effects : No known significant effects or critical hazards.

78000 ug/L Fresh water Daphnia magna - NeonateAcute LC50 15100 to22100 ug/L Fresh water


96 hours


Daphnia - Water flea -Daphnia magna - <24 hours

48 hours


Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss -Juvenile (Fledgling,Hatchling, Weanling) - 11.5cm - 16.8 g

96 hours


Fish - Rainbowtrout,donaldson trout -Oncorhynchus mykiss -Juvenile (Fledgling,Hatchling, Weanling) - 8.8cm - 7.6 g

96 hours



96 hours

Other adverse effects : No known significant effects or critical hazards.

The information presented only applies to the material as supplied. The identification based on characteristic(s) or listingmay not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator todetermine the toxicity and physical properties of the material generated to determine the proper waste identification anddisposal methods in compliance with applicable regulations. Disposal should be in accordance with applicable regional,national and local laws and regulations.

Disposal considerations13 .

Transport information

6.1

6

POISON

DOT Classification CHLOROFORM III

Regulatoryinformation

UN number Proper shippingname

Classes PG* Label Additionalinformation

UN1888

14 .

PG* : Packing group

Reportable quantity10 lbs. (4.54 kg)

Toxic materialIrritating materialCarcinogenTarget organ effects

HCS Classification

Regulatory information

U.S. Federal regulations United States inventory (TSCA 8b): This material is listed or exempted.TSCA 8(d) H and S data reporting: Chloroform : 1987

Clean Water Act (CWA) 307: ChloroformClean Water Act (CWA) 311: Chloroform

SARA 302/304/311/312 extremely hazardous substances: ChloroformSARA 302/304 emergency planning and notification: ChloroformSARA 302/304/311/312 hazardous chemicals: ChloroformSARA 311/312 MSDS distribution - chemical inventory - hazard identification:Chloroform : Immediate (acute) health hazard, Delayed (chronic) health hazard

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United States

15 .

TSCA (Toxic Substance Control Act): This product is listed on the TSCA Inventory.


7/8CX1050Chloroform

Regulatory information15 .

WARNING: This product contains a chemical known to the State of California to cause cancer.

Clean Air Act (CAA) 112 accidental release prevention: ChloroformClean Air Act (CAA) 112 regulated flammable substances: No products were found.Clean Air Act (CAA) 112 regulated toxic substances: Chloroform

CEPA Toxic substances: This material is not listed.Canadian ARET: This material is not listed.Canadian NPRI: This material is listed.Alberta Designated Substances: This material is not listed.Ontario Designated Substances: This material is not listed.Quebec Designated Substances: This material is not listed.

WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).

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SARA 313

Canada

Product name CAS number Concentration

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.

Chloroform Yes. No. 20 μg/day (ingestion)40 μg/day (inhalation)

No.

Ingredient name Cancer Reproductive No significant risklevel

Maximumacceptable dosagelevel

R40- Limited evidence of a carcinogenic effect.R22- Harmful if swallowed.R48/20/22- Harmful: danger of serious damage to health by prolonged exposure throughinhalation and if swallowed.R38- Irritating to skin.

Risk phrases

EU regulations

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Hazard symbol or symbols :

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and theMSDS contains all the information required by the Controlled Products Regulations.



Form R - Reportingrequirements

Supplier notification

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Canadian lists :

California Prop. 65

CEPA DSL / CEPA NDSL : This material is listed or exempted.

DEA List I Chemicals(Precursor Chemicals)

: Not listed

DEA List II Chemicals(Essential Chemicals)

: Not listed

Massachusetts Substances : This material is listed.

New Jersey HazardousSubstances

: This material is listed.

New York AcutelyHazardous Substances


Pennsylvania RTKHazardous Substances



8/8CX1050Chloroform

Regulatory information15 .

Australia inventory (AICS): This material is listed or exempted.China inventory (IECSC): This material is listed or exempted.Japan inventory (ENCS): This material is listed or exempted.Japan inventory (ISHL): Not determined.Korea inventory (KECI): This material is listed or exempted.New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.Philippines inventory (PICCS): This material is listed or exempted.

International regulations

International lists :

S2- Keep out of the reach of children.S36/37- Wear suitable protective clothing and gloves.

Safety phrases :

Contains stabilizer. (<1% wt/wt)

Other information

Other specialconsiderations

00

2

National Fire ProtectionAssociation (U.S.A.)

Health

Special

Instability

Flammability

Notice to reader

The statements contained herein are based upon technical data that EMD Chemicals Inc. believes to be reliable,are offered for information purposes only and as a guide to the appropriate precautionary and emergency handlingof the material by a properly trained person having the necessary technical skills. Users should consider thesedata only as a supplement to other information gathered by them and must make independent determinations ofsuitability and completeness of information from all sources to assure proper use, storage and disposal of thesematerials and the safety and health of employees and customers and the protection of the environment. EMDCHEMICALS INC. MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED,INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATIONHEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.

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A-31

SAFETY DATA SHEET

Creation Date 27-Jan-2010 Revision Date 17-Jan-2018 Revision Number 6

1. IdentificationProduct Name Methylene chloride

Cat No. : D37-1; D37-4; D37-20; D37-200; D37-200LC; D37-500; D37FB-19;D37FB-50; D37FB-115; D37FB-200; D37POP-19; D37POPB-50;D37POPB-200; D37RB-19; D37RB-50; D37RB-115; D37RB-200;D37RS-19; D37RS-28; D37RS-50; D37RS-115; D37RS-200; D37SK-4;D37SK-4LC; D37SS-28; D37SS-50; D37SS-115; D37SS-200;D37SS-1350; D37RS1000ASME; NC1485726; D37RE200ASME;NC1568702

CAS-No 75-09-2

Synonyms Dichloromethane; DCM


Uses advised against Food, drug, pesticide or biocidal product use


Emergency Telephone Number

CHEMTRECÒ, Inside the USA: 800-424-9300

CHEMTRECÒ, Outside the USA: 001-703-527-3887

2. Hazard(s) identificationClassification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Label Elements

Company Fisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100

Skin Corrosion/irritation Category 2Serious Eye Damage/Eye Irritation Category 2Carcinogenicity Category 1BSpecific target organ toxicity (single exposure) Category 3Target Organs - Central nervous system (CNS).Specific target organ toxicity - (repeated exposure) Category 2Target Organs - Liver, Kidney, Blood.

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A-32

______________________________________________________________________________________________Methylene chloride Revision Date 17-Jan-2018

Signal WordDanger

Hazard StatementsCauses skin irritationCauses serious eye irritationMay cause drowsiness or dizzinessMay cause cancerMay cause damage to organs through prolonged or repeated exposure

Precautionary StatementsPreventionObtain special instructions before useDo not handle until all safety precautions have been read and understoodUse personal protective equipment as requiredWash face, hands and any exposed skin thoroughly after handlingWear eye/face protectionDo not breathe dust/fume/gas/mist/vapors/sprayUse only outdoors or in a well-ventilated area

ResponseIF exposed or concerned: Get medical attention/advice

InhalationIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

SkinIF ON SKIN: Wash with plenty of soap and waterIf skin irritation occurs: Get medical advice/attentionTake off contaminated clothing and wash before reuse

EyesIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attention

StorageStore locked upStore in a well-ventilated place. Keep container tightly closed


Hazards not otherwise classified (HNOC)

WARNING. Cancer - https://www.p65warnings.ca.gov/.



Methylene chloride 75-09-2 >99.5


General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention.

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A-33


Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,call a physician.

Inhalation Move to fresh air. If not breathing, give artificial respiration. Get medical attention ifsymptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Most important symptoms andeffects

None reasonably foreseeable. Inhalation of high vapor concentrations may causesymptoms like headache, dizziness, tiredness, nausea and vomiting


5. Fire-fighting measuresSuitable Extinguishing Media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable Extinguishing Media No information available

Flash Point No information available

Method - No information available

Autoignition Temperature 556 °C / 1032.8 °F

Explosion LimitsUpper 23 vol %

Lower 13 vol %



Specific Hazards Arising from the ChemicalThermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat andsources of ignition.

Hazardous Combustion ProductsCarbon monoxide (CO) Carbon dioxide (CO2) Hydrogen chloride gas Phosgene


NFPA

6. Accidental release measuresPersonal Precautions Use personal protective equipment. Ensure adequate ventilation.

Environmental Precautions Should not be released into the environment.


Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

7. Handling and storageHandling Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Avoid

ingestion and inhalation. Ensure adequate ventilation.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place.

8. Exposure controls / personal protectionExposure Guidelines

Health2

Flammability1

Instability0

Physical hazardsN/A

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A-34


9. Physical and chemical propertiesPhysical State Liquid

Appearance Colorless

Odor sweet

Odor Threshold No information available


Melting Point/Range -97 °C / -142.6 °F

Boiling Point/Range 39 °C / 102.2 °F

Flash Point No information available

Evaporation Rate No information available

Flammability (solid,gas) Not applicable

Flammability or explosive limitsUpper 23 vol %

Lower 13 vol %

Vapor Pressure 350 mbar @ 20°C

Vapor Density 2.93 (Air = 1.0)


Solubility No information available




Viscosity No information available

Molecular Formula C H2 Cl2




Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA)

Methylene chloride TWA: 50 ppm (Vacated) TWA: 500 ppm(Vacated) STEL: 2000 ppm

(Vacated) Ceiling: 1000 ppmTWA: 25 ppm

STEL: 125 ppm

IDLH: 2300 ppm TWA: 100 ppmTWA: 330 mg/m3

STEL: 500 ppmSTEL: 1740 mg/m3

Legend

ACGIH - American Conference of Governmental Industrial HygienistsOSHA - Occupational Safety and Health AdministrationNIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health

Engineering Measures Use only under a chemical fume hood. Ensure that eyewash stations and safety showersare close to the workstation location.

Personal Protective Equipment

Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described byOSHA's eye and face protection regulations in 29 CFR 1910.133 or European StandardEN166.

Skin and body protection Long sleeved clothing.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European StandardEN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator ifexposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

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A-35


Stability Stable under normal conditions.

Conditions to Avoid Incompatible products. Excess heat.

Incompatible Materials Strong oxidizing agents, Strong acids, Amines

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Hydrogen chloride gas, Phosgene

Hazardous Polymerization Hazardous polymerization does not occur.



Product InformationComponent Information

Component LD50 Oral LD50 Dermal LC50 Inhalation

Methylene chloride > 2000 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) 53 mg/L ( Rat ) 6 h76000 mg/m3 ( Rat ) 4 h

Toxicologically SynergisticProducts

No information available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Irritating to eyes and skin




Methylene chloride 75-09-2 Group 2A ReasonablyAnticipated

A3 X A3

IARC: (International Agency for Research on Cancer) IARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansGroup 2A - Probably Carcinogenic to HumansGroup 2B - Possibly Carcinogenic to Humans

NTP: (National Toxicity Program) NTP: (National Toxicity Program)Known - Known CarcinogenReasonably Anticipated - Reasonably Anticipated to be a HumanCarcinogen

ACGIH: (American Conference of Governmental IndustrialHygienists)

A1 - Known Human CarcinogenA2 - Suspected Human CarcinogenA3 - Animal CarcinogenACGIH: (American Conference of Governmental Industrial Hygienists)

Mexico - Occupational Exposure Limits - Carcinogens Mexico - Occupational Exposure Limits - CarcinogensA1 - Confirmed Human CarcinogenA2 - Suspected Human CarcinogenA3 - Confirmed Animal CarcinogenA4 - Not Classifiable as a Human CarcinogenA5 - Not Suspected as a Human Carcinogen

Mutagenic Effects Mutagenic effects have occured in microorganisms.




STOT - single exposure Central nervous system (CNS)

STOT - repeated exposure Liver Kidney Blood

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A-36




Inhalation of high vapor concentrations may cause symptoms like headache, dizziness,tiredness, nausea and vomiting


Other Adverse Effects Tumorigenic effects have been reported in experimental animals.

12. Ecological informationEcotoxicity .

Component Freshwater Algae Freshwater Fish Microtox Water Flea

Methylene chloride EC50:>660 mg/L/96h Pimephales promelas:LC50:193 mg/L/96h

EC50: 1 mg/L/24 hEC50: 2.88 mg/L/15 min

EC50: 140 mg/L/48h

Persistence and Degradability Persistence is unlikely based on information available.


Mobility Will likely be mobile in the environment due to its volatility.

Component log Pow

Methylene chloride 1.25



Component RCRA - U Series Wastes RCRA - P Series Wastes

Methylene chloride - 75-09-2 U080 -


UN-No UN1593

Proper Shipping Name DICHLOROMETHANE

Hazard Class 6.1

Packing Group III

TDG UN-No UN1593

Proper Shipping Name DICHLOROMETHANE

Hazard Class 6.1

Packing Group III

IATA UN-No UN1593

Proper Shipping Name Dichloromethane

Hazard Class 6.1

Packing Group III

IMDG/IMO UN-No UN1593

Proper Shipping Name Dichloromethane

Hazard Class 6.1

Packing Group III


All of the components in the product are on the following Inventory lists: X = listed

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Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL

Methylene chloride X X - 200-838-9 - X X X X XLegend:X - ListedE - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designatedpolymer made with any free-radical initiator regardless of the amount used.P - Indicates a commenced PMN substanceR - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.S - Indicates a substance that is identified in a proposed or final Significant New Use RuleT - Indicates a substance that is the subject of a Section 4 test rule under TSCA.XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data BaseProduction and Site Reports (40 CFR 710(B).Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactantsthat comprises one of the eligibility criteria for the exemption rule.


TSCA 12(b)

SARA 313

Component CAS-No Weight % SARA 313 - ThresholdValues %

Methylene chloride 75-09-2 >99.5 0.1

SARA 311/312 Hazard Categories See section 2 for more information

CWA (Clean Water Act)

Component CWA - HazardousSubstances

CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - Priority Pollutants

Methylene chloride - - X X

Clean Air Act

Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors

Methylene chloride X -

OSHA Occupational Safety and Health Administration

Component Specifically Regulated Chemicals Highly Hazardous Chemicals

Methylene chloride 125 ppm STEL12.5 ppm Action Level

25 ppm TWA

-

CERCLA This material, as supplied, contains one or more substances regulated as a hazardoussubstance under the Comprehensive Environmental Response Compensation and LiabilityAct (CERCLA) (40 CFR 302)

Component Hazardous Substances RQs CERCLA EHS RQs

Methylene chloride 1000 lb 1 lb -

California Proposition 65 This product contains the following proposition 65 chemicals

Component CAS-No California Prop. 65 Prop 65 NSRL Category

Methylene chloride 75-09-2 Carcinogen 200 µg/day50 µg/day

Carcinogen

U.S. State Right-to-KnowRegulations

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Methylene chloride X X X X X

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U.S. Department of Transportation

Reportable Quantity (RQ): YDOT Marine Pollutant NDOT Severe Marine Pollutant N

U.S. Department of Homeland SecurityThis product does not contain any DHS chemicals.


Mexico - Grade No information available



Creation Date 27-Jan-2010

Revision Date 17-Jan-2018

Print Date 17-Jan-2018

Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standardreplacing the current legislation under 29 CFR 1910.1200 to align with the GloballyHarmonized System of Classification and Labeling of Chemicals (GHS).


End of SDS

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Material Safety Data SheetN,N-Dimethylformamide MSDS

Section 1: Chemical Product and Company Identification

Product Name: N,N-Dimethylformamide

Catalog Codes: SLD4261, SLD3331

CAS#: 68-12-2

RTECS: LQ2100000

TSCA: TSCA 8(b) inventory: N,N-Dimethylformamide

CI#: Not applicable.

Synonym: DMF; Dimethyl Formamide

Chemical Name: N,N-Dimethylformamide

Chemical Formula: HCON(CH3)2

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

{N,N-}Dimethylformamide 68-12-2 100

Toxicological Data on Ingredients: N,N-Dimethylformamide: ORAL (LD50): Acute: 2800 mg/kg [Rat]. 2900 mg/kg [Mouse].5000 mg/kg [Rabbit]. DERMAL (LD50): Acute: 4720 mg/kg [Rabbit].

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion,of inhalation.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for mammaliansomatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Classified POSSIBLE for human.DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE].The substance is toxic to kidneys, liver, central nervous system (CNS). The substance may be toxic to blood, the nervoussystem. Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

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Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Get medical attention.

Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek medical attention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 445°C (833°F)

Flash Points: CLOSED CUP: 57.778°C (136°F). (Tagliabue.) OPEN CUP: 67°C (152.6°F).

Flammable Limits: LOWER: 2.2% UPPER: 15.2%

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).

Fire Hazards in Presence of Various Substances:Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.

Fire Fighting Media and Instructions:Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards:A mixture of triethylaluminum and DMF explodes when heated. DMF + potassium permanganate may explode.

Section 6: Accidental Release Measures

Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.

Large Spill:

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Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confinedareas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDSand with local authorities.

Section 7: Handling and Storage

Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Donot ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wearsuitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids.

Storage:Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed andsealed until ready for use. Avoid all possible sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:TWA: 10 (ppm) from ACGIH (TLV) [United States] TWA: 30 (mg/m3) from ACGIH (TLV) [United States] Consult localauthorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Amine like. (Slight.)

Taste: Not available.

Molecular Weight: 73.09 g/mole

Color: Colorless to light yellow.

pH (1% soln/water): Not available.

Boiling Point: 153°C (307.4°F)

Melting Point: -61°C (-77.8°F)

Critical Temperature: 374°C (705.2°F)

Specific Gravity: 0.949 (Water = 1)

Vapor Pressure: 0.3 kPa (@ 20°C)

Vapor Density: 2.51 (Air = 1)

Volatility: Not available.

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Odor Threshold: 100 ppm

Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -1

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water, diethyl ether, acetone.

Solubility:Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone. Miscible organic solvents. Soluble in benzene, andchloroform.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Heat, ignition sources (sparks, flames), incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, acids.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:Can react vigorously with oxidizing agents, halogenated hydrocarbons, and inorganic nitrates. Incompatible with carbontetrachloride, alkyl aluminums, sodium tetrahydroborate, nitrates, chromic acid, diisocyanatomethane, triethylaluminum,sodium hydride, lithium azide, metallic sodium, bromine, magnesium nitrate, potassium permanganate, nitric acid, chromiumtrioxide, borohydrides, phosphorus trioxide, diborane, octafluoroisobutyrate, sodium nitrite, perchloryl fluoride, postassiummethyl 4,4'-dinitrobutyrate. Reaction with inorganic acid chlorides, such as phosphorous oxychloride and thionyl chloride, mayform dimethylcarbamoyl, a suspect carcinogen. May release dimethylamine and carbon monoixde if heated above 350 C (662F).

Special Remarks on Corrosivity:Pure dimethylformamide is essentially non-corrosive to metals. However copper, tin and their alloys should be avoided.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2800 mg/kg [Rat]. Acute dermal toxicity (LD50): 4720 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 94001 hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for mammaliansomatic cells. Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Classified POSSIBLE for human.DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE].Causes damage to the following organs: kidneys, liver, central nervous system (CNS). May cause damage to the followingorgans: blood, the nervous system.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LCL[Rat] - Route: Inhalation; Dose: 5000 ppm/6H

Special Remarks on Chronic Effects on Humans:May affect genetic material. May cause adverse reproductive effects(paternal and maternal) and birth defects. Embryotoxicand/or foetotoxic in animal. Passes through the placental barrier in animal. May cause cancer although IARC evidence forcancer in humans shows inadequate data.

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Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation with itching, burning, redness, swelling, or rash. It may be absorbedthrough the skin in toxic amounts and cause systemic effects similar to that of ingestion. It may facilitate the absorptionof other chemical substances through the skin. If there is significant potential for skin contact, monitoring should be doneto measure the level of DMF metabolites in urine specimans at the end of the shift. It is common practice to limit end-of-shift metabolites at or below 40 ppm expressed as n-monomethylformamide or a single individual or at or below 20 ppmMMF for several workers doing the same job. Eyes: Causes eye irritation (possibly severe) with tearing pain or blurredvision. Inhalation: May cause respiratory tract irritation. Short-term overexposure by inhalation may affect behavior/centralnervous system (convulsions, muscle weakness and other symptoms similar to that of acute ingestion), respiration (dyspnea).Ingestion: It can cause gastrointestinal tract irritation with heartburn, abdominal pain, nausea, vomiting or diarrhea. It may alsoaffect the cardiovascular system (hypertension, tachycardia, ECG abnormalities), blood (elevated white blood cell counts), andliver damage (hepatomegaly, jaundice, altered liver enzymes, fatty liver

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.

Identification: : N,N-Dimethylformamide UNNA: 2265 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:Illinois toxic substances disclosure to employee act: N,N-Dimethylformamide Illinois chemical safety act: N,N-Dimethylformamide New York release reporting list: N,N-Dimethylformamide Rhode Island RTK hazardous substances: N,N-Dimethylformamide Pennsylvania RTK: N,N-Dimethylformamide Minnesota: N,N-Dimethylformamide Massachusetts RTK:N,N-Dimethylformamide Massachusetts spill list: N,N-Dimethylformamide New Jersey: N,N-Dimethylformamide New Jerseyspill list: N,N-Dimethylformamide Louisiana spill reporting: N,N-Dimethylformamide California Director's List of HazardousSubstances: N,N-Dimethylformamide TSCA 8(b) inventory: N,N-Dimethylformamide TSCA 8(d) H and S data reporting: N,N-Dimethylformamide: 12/19/95 SARA 313 toxic chemical notification and release reporting: N,N-Dimethylformamide CERCLA:Hazardous substances.: N,N-Dimethylformamide: 100 lbs. (45.36 kg)

Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.

Other Classifications:

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WHMIS (Canada):CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS D-2A: Material causingother toxic effects (VERY TOXIC).

DSCL (EEC):R20/21- Harmful by inhalation and in contact with skin. R36- Irritating to eyes. R61- May cause harm to the unborn child.S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53- Avoidexposure - obtain special instructions before use.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 1

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 05:12 PM

Last Updated: 11/01/2010 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

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SAFETY DATA SHEET

Creation Date 13-October-2009 Revision Date 18-January-2018 Revision Number 5

1. IdentificationProduct Name Ethyl acetate

Cat No. : BP1125-1; BP1125-4

CAS-No 141-78-6

Synonyms Acetic acid ethyl ester


Uses advised against Not for food, drug, pesticide or biocidal product use


Emergency Telephone Number

CHEMTRECÒ, Inside the USA: 800-424-9300

CHEMTRECÒ, Outside the USA: 001-703-527-3887

2. Hazard(s) identificationClassification

WHMIS 2015 Classification Classified as hazardous under the Hazardous Products Regulations (SOR/2015-17)

Label Elements

Signal WordDanger

Hazard StatementsHighly flammable liquid and vaporCauses serious eye irritationMay cause drowsiness and dizzinessProlonged or repeated contact may dry skin and cause irritation or cracking

Company Importer/DistributorFisher Scientific112 Colonnade Road,Ottawa, ON K2E 7L6,CanadaTel: 1-800-234-7437

ManufacturerFisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100

Serious Eye Damage/Eye Irritation Category 2

Specific target organ toxicity (single exposure) Category 3Target Organs - Central nervous system (CNS).

Health Hazards Not Otherwise Classified Category 1Prolonged or repeated contact may dry skin and cause irritation or cracking

Flammable liquids

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______________________________________________________________________________________________Ethyl acetate Revision Date 18-January-2018

Precautionary StatementsPreventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smokingKeep container tightly closedGround/bond container and receiving equipmentUse explosion-proof electrical/ventilating/lighting/equipmentUse only non-sparking toolsTake precautionary measures against static dischargesDo not breathe dust/fumes/gas/mist/vapours/sprayWash face, hands and any exposed skin thoroughly after handlingUse only outdoors or in a well-ventilated areaWear protective gloves/protective clothing/eye protection/face protection

ResponseIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ showerIF INHALED: Remove person to fresh air and keep comfortable for breathingIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingCall a POISON CENTER/ doctor if you feel unwellIn case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish

StorageStore in a well-ventilated place. Keep container tightly closedStore locked up




Ethyl acetate 141-78-6 >95


General Advice If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Getmedical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists,call a physician.

Inhalation Move to fresh air. If not breathing, give artificial respiration. Get medical attention ifsymptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water.

Most important symptoms/effects Breathing difficulties. May cause central nervous system depression: Inhalation of highvapor concentrations may cause symptoms like headache, dizziness, tiredness, nauseaand vomiting


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5. Fire-fighting measuresSuitable Extinguishing Media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable Extinguishing Media Water may be ineffective, Do not use a solid water stream as it may scatter and spread fire

Flash Point -4 °C / 24.8 °F

Method - Closed cup


Explosion LimitsUpper 11.5 vol %

Lower 2.0 vol %

Oxidizing Properties Not oxidising



Specific Hazards Arising from the ChemicalFlammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back.Containers may explode when heated.

Hazardous Combustion ProductsCarbon monoxide (CO) Carbon dioxide (CO2)


NFPA

6. Accidental release measuresPersonal Precautions Use personal protective equipment. Ensure adequate ventilation.

Environmental Precautions Should not be released into the environment. See Section 12 for additional ecologicalinformation.


Soak up with inert absorbent material. Keep in suitable, closed containers for disposal.

7. Handling and storageHandling Ensure adequate ventilation. Wear personal protective equipment. Do not get in eyes, on

skin, or on clothing. Avoid ingestion and inhalation.

Storage Flammables area. Keep away from heat and sources of ignition. Keep container tightlyclosed in a dry and well-ventilated place.

8. Exposure controls / personal protectionExposure Guidelines

Component Alberta BritishColumbia

Ontario TWAEV Quebec ACGIH TLV OSHA PEL NIOSH IDLH

Ethyl acetate TWA: 400 ppmTWA: 1440

mg/m3

TWA: 150 ppm TWA: 400 ppm TWA: 400 ppmTWA: 1440

mg/m3

TWA: 400 ppm (Vacated) TWA:400 ppm

(Vacated) TWA:1400 mg/m3

TWA: 400 ppm

IDLH: 2000 ppmTWA: 400 ppm

TWA: 1400mg/m3

Health2

Flammability3

Instability0

Physical hazardsN/A

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TWA: 1400mg/m3

Legend

ACGIH - American Conference of Governmental Industrial Hygienists

OSHA - Occupational Safety and Health Administration

NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health

Engineering MeasuresEnsure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment. Ensure thateyewash stations and safety showers are close to the workstation location.Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process orequipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted tocontrol hazardous materials at source

Personal protective equipment

Eye Protection Goggles

Hand Protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by thesupplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatability,Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific localconditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination.

Respiratory ProtectionNo protective equipment is needed under normal use conditions.

Environmental exposure controlsNo information available.

Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Donot eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Wash hands beforebreaks and at the end of workday.

9. Physical and chemical propertiesPhysical State Liquid


Odor sweet

Odor Threshold 50 ppm


Melting Point/Range -83.5 °C / -118.3 °F

Boiling Point/Range 75 - 78 °C / 167 - 172.4 °F

Flash Point -4 °C / 24.8 °F

Method - Closed cup

Evaporation Rate 6.2

Flammability (solid,gas) Not applicable

Flammability or explosive limitsUpper 11.5 vol %

Lower 2.0 vol %

Glove material Breakthrough time Glove thickness Glove comments

Butyl rubberNitrile rubber

> 120 minutes< 200 minutes

0.5 - 0.7 mm

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Permeation rate 8 µg/cm2/minAs tested under EN374-3

Determination of Resistance toPermeation by Chemicals

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Vapor Pressure 103 mbar @ 20°C

Vapor Density 3.04


Solubility Slightly soluble in water




Viscosity 0.45 cP @ 20 °C

Molecular Formula C4 H8 O2


Surface tension 24 mN/m @ 20°C




Conditions to Avoid Incompatible products. Keep away from open flames, hot surfaces and sources of ignition.

Incompatible Materials Strong oxidizing agents, Strong acids, Amines, Peroxides

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)

Hazardous Polymerization Hazardous polymerization does not occur.



Product InformationComponent Information


Ethyl acetate 10,200 mg/kg ( Rat ) > 20 mL/kg ( Rabbit )> 18000 mg/kg ( Rabbit )

58 mg/l (rat; 8 h)

Toxicologically SynergisticProducts

No information available

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Irritating to eyes




Ethyl acetate 141-78-6 Not listed Not listed Not listed Not listed Not listed

Mutagenic Effects No information available




STOT - single exposure Central nervous system (CNS)

STOT - repeated exposure None known

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May cause central nervous system depression: Inhalation of high vapor concentrations maycause symptoms like headache, dizziness, tiredness, nausea and vomiting


Other Adverse Effects The toxicological properties have not been fully investigated.

12. Ecological informationEcotoxicity Do not empty into drains.


Ethyl acetate EC50 = 3300 mg/L/48h Fathead minnow: LC50: 230mg/l/ 96h

Gold orfe: LC50: 270mg/L/48h

EC50 = 1180 mg/L 5 minEC50 = 1500 mg/L 15 minEC50 = 5870 mg/L 15 min

EC50 = 7400 mg/L 2 h

EC50 = 717 mg/L/48h

Persistence and Degradability Persistence is unlikely based on information available.


Mobility Will likely be mobile in the environment due to its volatility.

Component log Pow

Ethyl acetate 0.6



Component RCRA - U Series Wastes RCRA - P Series Wastes

Ethyl acetate - 141-78-6 U112 -


UN-No UN1173

Proper Shipping Name ETHYL ACETATE

Hazard Class 3

Packing Group II

TDG UN-No UN1173


Hazard Class 3

Packing Group II

IATA UN-No UN1173


Hazard Class 3

Packing Group II

IMDG/IMO UN-No UN1173


Hazard Class 3

Packing Group II


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All of the components in the product are on the following Inventory lists: X = listed


Component DSL NDSL TSCA EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL

Ethyl acetate X - X 205-500-4 - X X X X X

Canada

SDS in compliance with provisions of information as set out in Canadian Standard - Part 4, Schedule 1 and 2 of the HazardousProducts Regulations (HPR) and meets the requirements of the HPR (Paragraph 13(1)(a) of the Hazardous Products Act (HPA)).

Component Canada - National PollutantRelease Inventory (NPRI)

Canadian EnvironmentalProtection Agency (CEPA)- List of Toxic Substances

Canada's Chemicals ManagementPlan (CEPA)

Ethyl acetate Part 5, Individual Substances



Creation Date 13-October-2009

Revision Date 18-January-2018

Print Date 18-January-2018

Revision Summary This document has been updated to comply with the requirements of WHMIS 2015 to alignwith the Globally Harmonised System (GHS) for the Classification and Labelling ofChemicals.


End of SDS

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MATERIAL SAFETY DATA SHEET

HYDROCHLORIC ACID 33%

SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT IDENTIFIER: HYDROCHLORIC ACID 33% SOLUTION RECOMMENDED USAGE:

Steel pickling and Scale Removal Ore Refining Hydrolyzing Agent Food Processing Activation of Petroleum Wells Catalyst in Organic Process Removal of Heavy metal from Carbon Black and Activated Carbon Leaching alumina from Crystalline Zeolities Manufacturing of Chlorine Dioxide Water Treatment

MANUFACTURER:

PT ASAHIMAS CHEMICAL Ds Gunung Sugih, Jalan Raya Anyer Km-122 Cilegon 42447 Banten - Indonesia Tel: +62 254 601252 Fax: +62 254 602027 Contact Department: CVT Department

EMERGENCY PHONE NUMBER: +62 254 601252 SECTION 2 HAZARDS IDENTIFICATION GHS Classification: Health Environmental Physical Acute Toxicity - Category 3 Eye Corrosion - Category 1A Skin Corrosion - Category 1A Skin Sensitization - Category 1 Mutagenicity - Category 1A Carcinogenicity - Category 1B Reproductive/Developmental - Category 1A Target Organ Toxicity (Repeated) - Category 1

Aquatic Toxicity: Acute 1 Chronic 1

Substance which in contact with water emit flammable gasses - Category 1

GHS Label: Symbols: skull and crossbones, corrosion, health hazard Hazard Statements DANGER! EXTREMELY CORROSIVE Fatal if inhaled.

Precautionary Statements Causes eye and skin burns Keep container tightly closed. Wear protective gloves and eye/face protection.

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Avoid to swallowed. Causes severe skin burns and eye damage. Can cause blindness, permanent scarring and death. Toxic if swallowed and in contact with skin Suspected of damaging the unborn child. Suspected of causing genetic defects. May cause damage to cardiovascular, respiratory, nervous, and gastrointestinal systems and liver and blood through prolonged or repeated exposure. Harmful to aquatic life. Possible sensitizer. Hygroscopic

Store container tightly closed in cool/ well-ventilated place. Wash thoroughly after handling.

SECTION 3 COMPOSITION, INFORMATION ON INGREDIENTS

CAS# Chemical Name Percent EINECS/ELINCS

7647-01-0 Hydrogen chloride 33 231-595-7 7732-18-5 Water 67 231-791-2

Synonyms: Muriatic acid; Chlorohydric acid; Hydrogen chloride; Spirits of salt Hazard Symbols: C Risk Phrases: 34 SECTION 4 FIRST AID MEASURES INHALATION: Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. SKIN CONTACT: Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. EYE CONTACT: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). SPEEDY ACTION IS CRITICAL! INGESTION: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. NOTES TO PHYSICIAN: Do NOT use sodium bicarbonate in an attempt to neutralize the acid. ANTIDOTE: Do NOT use oils or ointments in eye. SECTION 5 FIRE FIGHTING MEASURES - GENERAL INFORMATION: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated. - SUITABLE EXTINGUISTING MEDIA: For large fires, use water spray, fog, or alcohol-resistant foam. Substance is non combustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water

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inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam. SECTION 6 ACCIDENTAL RELEASE MEASURES - PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT & EMERGENCY PROCEDURES: Use proper personal protective equipment as indicated in Section 8. - METHODS & MATERIALS FOR CONTAINMENT & CLEANING UP SPILLS / LEAKS: Large spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water. SECTION 7 HANDLING AND STORAGE - PRECAUTIONS FOR SAFE HANDLING: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Contents may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam. - PRECAUTIONS FOR SAFE STORAGE (including any incompatibilities): Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Store protected from moisture. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates). SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION - CONTROL PARAMETERS: OCCUPATIONAL EXPOSURE LIMIT or BIOLOGICAL LIMIT VALUE: NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 1 Explosion Limits Value: Lower: Not available. Upper: Not available.

Chemical Name ACGIH NIOSH OSHA - Final PELs Hydrogen chloride C 5 ppm 50 ppm IDLH C 5 ppm; C 7 mg/m3

Water none listed none listed none listed OSHA Vacated PELs: Hydrogen chloride: C 5 ppm; C 7 mg/m3 Water: No OSHA Vacated PELs are listed for this chemical. - APPROPRIATE ENGINEERING CONTROLS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible

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exposure limits. PERSONAL PROTECTIVE EQIPMENT Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear neoprene or polyvinyl chloride gloves to prevent exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE:

PHYSICAL STATE: Clear liquid COLOR: colorless to slight yellow CHANGE IN APPEARANCE: Not available

ODOR: strong, pungent ODOR THRESHOLD: Not available Molecular Formula: HCl Molecular Weight: 36.46 pH: 0.01 FREEZING/MELTING POINT: -74 deg C BOILING POINT: 81.5-110 deg C @ 760 mmHg FLASH POINT: Not applicable. EVAPORATION RATE: > 1.00 (N-butyl acetate) FLAMMABILITY (solid, gas): Not available VAPOR PRESSURE: 5.7 mm Hg @ 0 deg C VAPOR DENSITY: 1.26 SPECIFIC GRAVITY/DENSITY: 1.0-1.2 VISCOSITY: Not available. SOLUBILITY IN WATER: VERY soluble SOLVENT SOLUBILITY:

Soluble: Miscible Insoluble: Not available

PARTITION COEFICIENT n-octanol / water: Not available AUTO IGNITION TEMPERATURE: Not applicable. DECOMPOSITION TEMPERATURE: Not available. SECTION 10 STABILITY AND REACTIVITY - CHEMICAL STABILITY: Stable under normal temperatures and pressures. - CONDITIONS TO AVOID: Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.

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- INCOMPATIBILITIES WITH OTHER MATERIALS: Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide. - HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas. - HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION RTECS#: CAS# 7647-01-0: MW4025000 CAS# 7732-18-5: ZC0110000 LD50/LC50: CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation, rat: LC50 = 3124 ppm/1H; Oral, rabbit: LD50 = 900 mg/kg;<BR. CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg;<BR. Carcinogenicity: CAS# 7647-01-0: IARC: Group 3 carcinogen CAS# 7732-18-5: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Epidemiology: Experimental reproductive effects have been reported. Teratogenicity: Embryo or Fetus: Stunted fetus, Inhalation, rat TCL0=450 mg/m3/1H Specific Developmental Abnormalities: homeostatis, Inhalation, rat TCL0=450 mg/m3/1H (female 1 days pre-mating). Reproductive Effects: No information available. Neurotoxicity: No information available. Mutagenicity: Cytogenetic analysis: Hamster, lung = 30 mmol/L.; Cytogenetic analysis: Hamster, ovary = 8 mmol/L. Target Organs: Teeth, circulatory system. POTENTIAL HEALTH EFFECTS Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes. Ingestion: May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed. Skin: May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration. Eye: May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light. Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects. Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.

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SECTION 12 ECOLOGICAL INFORMATION ECOTOXICITY: Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified) Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5 No data available. ENVIRONMENTAL: Rapidly hydrolyzes when exposed to water. Will exhibit extensive evaporation from soil surfaces. Upon transport through the soil, hydrochloric acid will dissolve some of the soil materials (especially those with carbonate bases) and the acid will neutralize to some degree. PHYSICAL: No information available. SECTION 13 DISPOSAL CONSIDERATIONS

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed.

SECTION 14 TRANSPORT INFORMATION

US DOT IATA RID/ADR IMO Canada TDG

Shipping Name: HYDROCHLORIC ACID HYDROCHLORIC

ACID Hazard Class: 8 8(9.2) UN Number: UN1789 UN1789

Packing Group: II II SECTION 15 REGULATORY INFORMATION US FEDERAL TSCA CAS# 7647-01-0 is listed on the TSCA inventory. CAS# 7732-18-5 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA Section 302 (RQ)

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CAS# 7647-01-0: final RQ = 5000 pounds (2270 kg) Section 302 (TPQ) CAS# 7647-01-0: TPQ = 500 pounds; RQ = 5000 pounds (does not meet toxicity criteria but because of high production volume and recognized toxicity is considered a chemical of concern) SARA Codes CAS # 7647-01-0: acute. Section 313 This material contains Hydrogen chloride (CAS# 7647-01-0, 36 38%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act: CAS# 7647-01-0 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletory. This material does not contain any Class 2 Ozone depletory. Clean Water Act: CAS# 7647-01-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: CAS# 7647-01-0 is considered highly hazardous by OSHA. STATE CAS# 7647-01-0 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 7647-01-0: 1 CAS# 7732-18-5: No information available. Canada CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7647-01-0 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. This product has a WHMIS classification of D2A, E. CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List. CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List. Exposure Limits CAS# 7647-01-0: OEL-AUSTRALIA:TWA 5 ppm (7 mg/m3) OEL-AUSTRIA:TWA 5 ppm (7 mg/m3) OEL-BELGIUM:STEL 5 ppm (7.7 mg/m3) OEL-DENMARK:STEL 5 ppm (7 mg/m3) OEL-FINLAND:STEL 5 ppm (7 mg/m3);Skin OEL-FRANCE:STEL 5 ppm (7.5 mg/m3) OEL-GERMANY:TWA 5 ppm (7 mg/m3) OEL-HUNGARY:STEL 5 mg/m3 OEL-JAPAN:STEL 5 ppm (7.5 mg/m3) OEL-THE NETHERLANDS:TWA 5 ppm (7 mg/m3) OEL-THE PHILIPPINES:TWA 5 ppm (7 mg/m3) OEL-POLAND:TWA 5 mg/m3 OEL-RUSSIA:STEL 5

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ppm (5 mg/m3) OEL-SWEDEN:STEL 5 ppm (8 mg/m3) OEL-SWITZERLAND:TWA 5 ppm (7.5 mg/m3);STEL 10 ppm (15 mg/m3) OEL-THAILAND:TWA 5 ppm (7 mg/m3) OEL-TURKEY:TWA 5 ppm (7 mg/m3) OEL-UNI TED KINGDOM:TWA 5 ppm (7 mg/m3);STEL 5 ppm (7 mg/m3) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV SECTION 16 OTHER INFORMATION Revise: 4 Date: August 20, 2009 MSDS SUMMARY OF CHANGES Change of ASC LOGO Licensed to: Supplier to make unlimited paper copies for ASC customer only.

The information in this MSDS was believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall PT ASC be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if PT ASC has been advised of the possibility of such damages.

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1. PRODUCT AND COMPANY IDENTIFICATION

Product Name Hexane

Cat No. BP2615-100; H291-4; H291-20; H291-200; H291-500; H291FB-19; H291FB-50; H291FB-200; H291RB-19; H291RB-50; H291RB-115; H291RB-200; H291RS-19; H291RS-28; H291RS-50; H291RS-115; H291RS-200; H291S-4; H291SS-28; H291SS-50; H291SS-115; H291SS-200; H300-4; H302-1; H302-4; H302-4LC; H302N-119; H302N-119LC; H302N-219; H302POP-19; H302POP-50; H302RS-19; H302RS-28; H302RS-50; H302RS-115; H302RS-200; H302SK-1; H302SK-4; H302SS-19; H302SS-28; H302SS-50; H302SS-115; H302SS-200; H303-1; H303-4; H303-4LC; H303RS-19; H303RS-28; H303RS-50; H303RS-115; H303RS-200; H303SK-4; H303SS-19; H303SS-28; H303SS-50; H303SS-115; H303SS-200; H307-4; H334-1; H334-4; N3-20; N3-200; O3386-20

Synonyms n-Hexane with < 5% various methyl pentanes; Ligroine; Naphtha Solvent (Anhydrous/Certified ACS/Pesticide/HPLC/OPTIMA/GC Resolv/Spectranalyzed/Technical/Laboratory)

Recommended Use Laboratory chemicals

2. HAZARDS IDENTIFICATION

Target Organs Skin, Respiratory system, Eyes, Central nervous system (CNS), Heart, Blood, Liver,

Reproductive System

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Emergency Telephone NumberCHEMTREC®, Inside the USA: 800-424-9300CHEMTREC®, Outside the USA: 703-527-3887

DANGER!

Revision Number 1

Emergency Overview

Creation Date 26-Oct-2009 Revision Date 26-Oct-2009

Extremely flammable liquid and vapor. Inhalation may cause central nervous system effects. Irritating to eyes and skin. May cause irritation of respiratory tract. Aspiration hazard if swallowed - can enter lungs and cause damage. Danger of

serious damage to health by prolonged exposure. Possible risk of impaired fertility. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

CompanyFisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100

Appearance Colorless Physical State Liquid odor Petroleum distillates

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Potential Health Effects

Acute Effects Principle Routes of Exposure

Eyes Irritating to eyes.

Skin Irritating to skin. May be harmful in contact with skin.

Inhalation Inhalation may cause central nervous system effects. May cause irritation of respiratory tract. May be harmful if inhaled.

Ingestion Aspiration hazard. May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Chronic Effects Tumorigenic effects have been reported in experimental animals.. Experiments have shown reproductive toxicity effects on laboratory animals. Possible risk of impaired fertility. Danger of serious damage to health by prolonged exposure. May cause adverse liver effects.

See Section 11 for additional Toxicological information.

Aggravated Medical Conditions Central nervous system disorders. Preexisting eye disorders. Skin disorders.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Haz/Non-haz


Hexane 110-54-3 >95

4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain

medical attention.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a respiratory medical device. Obtain medical attention.

Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately.

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Flash Point -22°C / -7.6°F

Method No information available.

Autoignition Temperature 223°C / 433.4°F

Explosion Limits Upper 7.5 vol %

Lower 1.1 vol %

Suitable Extinguishing Media CO2, dry chemical, dry sand, alcohol-resistant foam. Cool closed containers exposed to fire with water spray.

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Revision Date 26-Oct-2009Thermo Fisher Scientific - Hexane

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Unsuitable Extinguishing Media Water may be ineffective. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained..

Hazardous Combustion Products No information available.

Sensitivity to mechanical impact No information available.

Sensitivity to static discharge No information available.

Specific Hazards Arising from the ChemicalFlammable. Risk of ignition. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Containers may explode when heated.

Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment. Remove all sources of ignition. Take precautionary

measures against static discharges.

Environmental Precautions Should not be released into the environment.

Methods for Containment and Clean Up

Soak up with inert absorbent material. Keep in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

7. HANDLING AND STORAGE

Handling Use only under a chemical fume hood. Wear personal protective equipment. Do not get in

eyes, on skin, or on clothing. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Use explosion-proof equipment. Take precautionary measures against static discharges.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Flammables area.

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Instability 0 Physical hazards N/A NFPA

Thermo Fisher Scientific - Hexane

Health 1 Flammability 3

Revision Date 26-Oct-2009

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Measures Use only under a chemical fume hood. Use explosion-proof

electrical/ventilating/lighting/equipment. Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Exposure Guidelines

Component ACGIH TLV OSHA PEL NIOSH IDLH

Hexane TWA: 50 ppm Skin

(Vacated) TWA: 180 mg/m3 (Vacated) TWA: 50 ppm

TWA: 500 ppm TWA: 1800 mg/m3

IDLH: 1100 ppm TWA: 180 mg/m3

TWA: 50 ppm

Component Quebec Mexico OEL (TWA) Ontario TWAEV

Hexane TWA: 176 mg/m3 TWA: 50 ppm

Skin

TWA: 176 mg/m3 TWA: 50 ppm

TWA: 176 mg/m3 TWA: 50 ppm

NIOSH IDLH: Immediately Dangerous to Life or Health

Personal Protective Equipment Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's

eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid


odor Petroleum distillates

Odor Threshold No information available.

pH No information available. Vapor Pressure 160 mbar @ 20 °C

Vapor Density 2.97 (Air = 1.0)

Viscosity 0.31 mPa s at 20 °C

Boiling Point/Range 69°C / 156.2°F@ 760 mmHg

Melting Point/Range -95°C / -139°F

Decomposition temperature No information available.

Flash Point -22°C / -7.6°F

Evaporation Rate No information available.


Solubility Insoluble in water

log Pow No data available


Molecular Formula C6 H14

10. STABILITY AND REACTIVITY


Conditions to Avoid Incompatible products. Heat, flames and sparks. Exposure to light.

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Thermo Fisher Scientific - Hexane Revision Date 26-Oct-2009

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Incompatible Materials Strong oxidizing agents, Halogens

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)

Hazardous Polymerization Hazardous polymerization does not occur

Hazardous Reactions . None under normal processing.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Component Information


Hexane 25 g/kg ( Rat ) 3000 mg/kg ( Rabbit ) 48000 ppm ( Rat ) 4 h

Irritation Irritating to eyes and skin

Toxicologically Synergistic Products

No information available.

Chronic Toxicity

Carcinogenicity There are no known carcinogenic chemicals in this product

Sensitization No information available.

Mutagenic Effects Mutagenic effects have occurred in experimental animals.

Reproductive Effects Experiments have shown reproductive toxicity effects on laboratory animals.

Developmental Effects Developmental effects have occurred in experimental animals.

Teratogenicity Teratogenic effects have occurred in experimental animals..

Other Adverse Effects Tumorigenic effects have been reported in experimental animals.. See actual entry in RTECS for complete information.


12. ECOLOGICAL INFORMATION

Ecotoxicity

. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.


Hexane Not listed Not listed Not listed EC50: 3.87 mg/L/48h

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Revision Date 26-Oct-2009Thermo Fisher Scientific - Hexane

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Persistence and Degradability No information available

Bioaccumulation/ Accumulation No information available

Mobility .

Component log Pow

Hexane 4.11

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a

hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

14. TRANSPORT INFORMATION

DOT

UN-No UN1208

Proper Shipping Name Hexanes

Hazard Class 3

Packing Group II

TDG

UN-No UN1208

Proper Shipping Name HEXANES

Hazard Class 3

Packing Group II

IATA

UN-No UN1208


Hazard Class 3

Packing Group II

IMDG/IMO

UN-No UN1208


Hazard Class 3

Packing Group II

15. REGULATORY INFORMATION

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15. REGULATORY INFORMATIONInternational Inventories

Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS CHINA KECL

Hexane X X - 203-777-6

- X X X X KE-18626

X

Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule.


TSCA 12(b) Not applicable

SARA 313

Component CAS-No Weight % SARA 313 - Threshold

Values %

Hexane 110-54-3 >95 1.0

SARA 311/312 Hazardous Categorization Acute Health Hazard No

Chronic Health Hazard No

Fire Hazard Yes

Sudden Release of Pressure Hazard No

Reactive Hazard No

Clean Water Act Not applicable

Clean Air Act

Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors Hexane X -

OSHA Not applicable

CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)


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Hexane 5000 lb -

California Proposition 65 This product does not contain any Proposition 65 chemicals.

State Right-to-Know

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Hexane X X X X X

U.S. Department of Transportation Reportable Quantity (RQ): YDOT Marine Pollutant NDOT Severe Marine Pollutant N

U.S. Department of Homeland Security This product does not contain any DHS chemicals.


Mexico - Grade Serious risk, Grade 3

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard ClassB2 Flammable liquidD2A Very toxic materials D2B Toxic materials

16. OTHER INFORMATION

Prepared By Regulatory Affairs

Thermo Fisher ScientificTel: (412) 490-8929

Creation Date 26-Oct-2009

Print Date 26-Oct-2009

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Revision Summary "***", and red text indicates revision

Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.

End of MSDS

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Isopropyl Alcohol (2-Propanol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/14/2013 Revision date: 01/26/2018 Supersedes: 09/29/2015 Version: 1.2

01/26/2018 EN (English US) Page 1

SECTION 1: Identification

1.1. Identification Product form : Substance Substance name : Isopropyl Alcohol (2-Propanol) CAS-No. : 67-63-0 Product code : LC15750 Formula : C3H8O Synonyms : 1-methylethanol / 1-methylethyl alcohol / 2-hydroxypropane / dimethyl carbinol / ethyl carbinol /

hydroxypropane / IPA / i-propanol / isoethylcarbinol / propan-2-ol / sec-propanol

1.2. Recommended use and restrictions on use Use of the substance/mixture : Disinfectant

Solvent

1.3. Supplier LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 [email protected] - www.labchem.com

1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

GHS-US classification Flammable liquids Category 2

H225 Highly flammable liquid and vapour

Serious eye damage/eye irritation Category 2A

H319 Causes serious eye irritation

Specific target organ toxicity (single exposure) Category 3

H335 May cause respiratory irritation

Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) :

GHS02

GHS07

Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapour

H319 - Causes serious eye irritation H335 - May cause respiratory irritation

Precautionary statements (GHS-US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P261 - Avoid breathing mist, vapors, spray. P264 - Wash exposed skin thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact

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Isopropyl Alcohol (2-Propanol) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

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lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P337+P313 - If eye irritation persists: Get medical advice/attention. P370+P378 - In case of fire: Use dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2) to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to comply with local, state and federal regulations P235 - Keep cool. If inhaled: Remove person to fresh air and keep comfortable for breathing

2.3. Other hazards which do not result in classification Other hazards not contributing to the classification

: None.

2.4. Unknown acute toxicity (GHS US) Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances Substance type : Mono-constituent

Name Product identifier % GHS-US classification Isopropyl Alcohol (2-Propanol) (Main constituent)

(CAS-No.) 67-63-0 100 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H335

Full text of hazard classes and H-statements : see section 16

3.2. Mixtures Not applicable

SECTION 4: First-aid measures

4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory

arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. Never give alcohol to drink.

First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Rinse with water. Soap may be used. Do not apply (chemical) neutralizing agents. Take victim

to a doctor if irritation persists. First-aid measures after eye contact : Rinse immediately with plenty of water. Do not apply neutralizing agents. Take victim to an

ophthalmologist if irritation persists. First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce

vomiting. Give activated charcoal. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital. Doctor: gastric lavage.

4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Dry/sore throat. Central nervous

system depression. Dizziness. Headache. Narcosis. Symptoms/effects after skin contact : Dry skin. Symptoms/effects after eye contact : Irritation of the eye tissue. Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Central nervous system depression.

Headache. Dilation of the blood vessels. Low arterial pressure. Nausea. Vomiting. Abdominal pain. Disturbed motor response. Disturbances of consciousness. FOLLOWING SYMPTOMS MAY APPEAR LATER: Body temperature fall. Slowing respiration.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Itching. Cracking of the skin. Skin rash/inflammation. Impaired memory.

4.3. Immediate medical attention and special treatment, if necessary No additional information available

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SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Water spray. Polyvalent foam. Alcohol-resistant foam. BC powder. Carbon dioxide. Unsuitable extinguishing media : Solid water jet ineffective as extinguishing medium.

5.2. Specific hazards arising from the chemical Fire hazard : DIRECT FIRE HAZARD. Highly flammable. Gas/vapor flammable with air within explosion

limits. INDIRECT FIRE HAZARD. May be ignited by sparks. Gas/vapor spreads at floor level: ignition hazard.

Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD. may be ignited by sparks. Reactions with explosion hazards: see "Reactivity Hazard".

Reactivity : Upon combustion: CO and CO2 are formed. Violent to explosive reaction with (strong) oxidizers. Prolonged storage/in large quantities: may form peroxides.

5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to

heat. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Large spills/in enclosed spaces: compressed

air apparatus. See "Material-Handling" to select protective clothing. Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close

doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and explosion-proof appliances and lighting equipment. Keep containers closed. Wash contaminated clothes.

6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Do not breathe gas, fumes, vapor or spray. Emergency procedures : Stop leak if safe to do so. Ventilate area. If a major spill occurs, all personnel should be

immediately evacuated and the area ventilated.

6.2. Environmental precautions Prevent spreading in sewers.

6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to

select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to reduce evaporation. Measure the concentration of the explosive gas-air mixture. Dilute/disperse combustible gas/vapour with water curtain. Provide equipment/receptacles with earthing. Do not use compressed air for pumping over spills.

Methods for cleaning up : Take up liquid spill into absorbent material, e.g.: dry sand/earth/vermiculite or powdered limestone. Scoop absorbed substance into closing containers. See "Material-handling" for suitable container materials. Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

6.4. Reference to other sections No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean

contaminated clothing. Handle uncleaned empty containers as full ones. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Do not use compressed air for pumping over. Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Observe normal hygiene standards. Keep container tightly closed. Measure the concentration in the air regularly. Work under local exhaust/ventilation.

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Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.

7.2. Conditions for safe storage, including any incompatibilities Incompatible products : Ammonia. Strong acids. Strong oxidizers. Incompatible materials : Direct sunlight. Heat sources. Sources of ignition. Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. strong acids. (strong) bases. amines.

halogens. Storage area : Store in a cool area. Store in a dry area. Ventilation at floor level. Fireproof storeroom. Provide

for an automatic sprinkler system. Provide for a tub to collect spills. Provide the tank with earthing. May be stored under nitrogen. Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: closing. with pressure relief valve. dry. clean. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.

Packaging materials : SUITABLE MATERIAL: stainless steel. monel steel. carbon steel. copper. nickel. bronze. glass. Teflon. polyethylene. polypropylene. zinc. MATERIAL TO AVOID: steel with rubber inner lining. aluminium.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Isopropyl Alcohol (2-Propanol) (67-63-0) ACGIH ACGIH TWA (ppm) 200 ppm (2-propanol; USA; Time-weighted average

exposure limit 8 h; TLV - Adopted Value) ACGIH ACGIH STEL (ppm) 400 ppm (2-propanol; USA; Short time value; TLV -

Adopted Value) OSHA OSHA PEL (TWA) (mg/m³) 980 mg/m³

OSHA OSHA PEL (TWA) (ppm) 400 ppm

IDLH US IDLH (ppm) 2000 ppm

NIOSH NIOSH REL (TWA) (mg/m³) 980 mg/m³

NIOSH NIOSH REL (TWA) (ppm) 400 ppm

NIOSH NIOSH REL (STEL) (mg/m³) 1225 mg/m³

NIOSH NIOSH REL (STEL) (ppm) 500 ppm

8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate

vicinity of any potential exposure. Provide adequate general and local exhaust ventilation.

8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:

Safety glasses. Gloves. Protective clothing. Face shield. High gas/vapor concentration: gas mask with filter type A.

Materials for protective clothing:

GIVE EXCELLENT RESISTANCE: butyl rubber. nitrile rubber. viton. polyethylene/ethylenevinylalcohol. GIVE GOOD RESISTANCE: neoprene. GIVE LESS RESISTANCE: PVC. neoprene/natural rubber. GIVE POOR RESISTANCE: natural rubber. polyethylene. PVA

Hand protection:

Gloves

Eye protection:

Safety glasses

Skin and body protection:

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Protective clothing

Respiratory protection:

Wear gas mask with filter type A if conc. in air > exposure limit

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Physical state : Liquid

Appearance : Liquid. Color : Colourless

Odor : Alcohol odour Stuffy odour Mild odour

Odor threshold : 3 - 610 ppm 8 - 1499 mg/m³

pH : No data available

Melting point : -88 °C

Freezing point : No data available

Boiling point : 82 °C (1013 hPa)

Critical temperature : 235 °C Critical pressure : 47600 hPa Flash point : 12 °C

Relative evaporation rate (butyl acetate=1) : 2.3

Relative evaporation rate (ether=1) : 21 Flammability (solid, gas) : No data available

Vapor pressure : 44 hPa (20 °C)

Vapor pressure at 50 °C : 60.2 hPa (25 °C) Relative vapor density at 20 °C : 2.1

Relative density : 0.79

Relative density of saturated gas/air mixture : 1.05 Specific gravity / density : 785 kg/m³ Molecular mass : 60.1 g/mol Solubility : Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in acetone. Soluble in oils/fats.

Soluble in chloroform. Water: Complete Ethanol: Complete Ether: Complete Acetone: soluble

Log Pow : 0.05 (Weight of evidence approach; Other; 25 °C)

Auto-ignition temperature : 399 °C

Decomposition temperature : No data available

Viscosity, kinematic : 2.5316 mm²/s (25 °C)

Viscosity, dynamic : 0.002 Pa.s (25 °C)

Explosion limits : 2 - 13 vol % 50 - 335 g/m³

Explosive properties : No data available

Oxidizing properties : No data available

9.2. Other information Minimum ignition energy : 0.65 mJ Specific conductivity : 5.8 µS/m Saturation concentration : 106 g/m³ VOC content : 100 % Other properties : Gas/vapour heavier than air at 20°C. Clear. Volatile.

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SECTION 10: Stability and reactivity

10.1. Reactivity Upon combustion: CO and CO2 are formed. Violent to explosive reaction with (strong) oxidizers. Prolonged storage/in large quantities: may form peroxides.

10.2. Chemical stability Stable under normal conditions.

10.3. Possibility of hazardous reactions May react violently with oxidants.

10.4. Conditions to avoid Direct sunlight. High temperature. Incompatible materials. Open flame. Sparks.

10.5. Incompatible materials Ammonia. Strong acids. Strong oxidizers.

10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified

Isopropyl Alcohol (2-Propanol) (67-63-0) LD50 dermal rabbit 12870 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; 16.4; Rabbit) LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat) ATE US (oral) 5045 mg/kg body weight ATE US (dermal) 12870 mg/kg body weight ATE US (vapors) 73 mg/l/4h ATE US (dust, mist) 73 mg/l/4h

Skin corrosion/irritation : Not classified Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified

Isopropyl Alcohol (2-Propanol) (67-63-0) IARC group 3 - Not classifiable

Reproductive toxicity : Not classified Specific target organ toxicity – single exposure : May cause respiratory irritation.

Specific target organ toxicity – repeated exposure

: Not classified

Aspiration hazard : Not classified

Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Coughing. Dry/sore throat. Central nervous system depression. Dizziness. Headache. Narcosis.

Symptoms/effects after skin contact : Dry skin. Symptoms/effects after eye contact : Irritation of the eye tissue. Symptoms/effects after ingestion : AFTER ABSORPTION OF LARGE QUANTITIES: Central nervous system depression.

Headache. Dilation of the blood vessels. Low arterial pressure. Nausea. Vomiting. Abdominal pain. Disturbed motor response. Disturbances of consciousness. FOLLOWING SYMPTOMS MAY APPEAR LATER: Body temperature fall. Slowing respiration.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Dry skin. Itching. Cracking of the skin. Skin rash/inflammation. Impaired memory.

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SECTION 12: Ecological information

12.1. Toxicity Ecology - general : Not classified as dangerous for the environment according to the criteria of Directive

67/548/EEC. Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008.

Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Not included in the list of substances which may contribute to the greenhouse effect (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.5.

Ecology - water : Ground water pollutant. Not harmful to fishes (LC50(96h) >1000 mg/l). Not harmful to invertebrates (Daphnia). Not harmful to algae (EC50 (72h) >1000 mg/l). Inhibition of activated sludge.

Isopropyl Alcohol (2-Propanol) (67-63-0) LC50 fish 2 9640 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-

through system; Fresh water; Experimental value) EC50 Daphnia 2 13299 mg/l (EC50; Other; 48 h; Daphnia magna) Threshold limit algae 1 > 1000 mg/l (EC50; UBA; 72 h; Scenedesmus subspicatus)

12.2. Persistence and degradability Isopropyl Alcohol (2-Propanol) (67-63-0) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under

anaerobic conditions. No test data on mobility of the substance available. Biochemical oxygen demand (BOD) 1.19 g O₂/g substance Chemical oxygen demand (COD) 2.23 g O₂/g substance ThOD 2.4 g O₂/g substance

12.3. Bioaccumulative potential Isopropyl Alcohol (2-Propanol) (67-63-0) Log Pow 0.05 (Weight of evidence approach; Other; 25 °C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

12.4. Mobility in soil Isopropyl Alcohol (2-Propanol) (67-63-0) Surface tension 0.021 N/m (25 °C)

12.5. Other adverse effects No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not

be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Recycle by distillation. Remove to an authorized waste incinerator for solvents with energy recovery. Do not discharge into surface water. Obtain the consent of pollution control authorities before discharging to wastewater treatment plants.

Additional information : LWCA (the Netherlands): KGA category 03. Hazardous waste according to Directive 2008/98/EC.

SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1219 Isopropyl alcohol, 3, II

UN-No.(DOT) : UN1219 Proper Shipping Name (DOT) : Isopropyl alcohol Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120

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Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 3 - Flammable liquid

DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite

(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling.

DOT Packaging Exceptions (49 CFR 173.xxx) : 4b;150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27)

: 5 L

DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75)

: 60 L

DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Other information : No supplementary information available.

SECTION 15: Regulatory information

15.1. US Federal regulations Isopropyl Alcohol (2-Propanol) (67-63-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 SARA Section 311/312 Hazard Classes Physical hazard - Flammable (gases, aerosols, liquids, or solids)

Health hazard - Serious eye damage or eye irritation Health hazard - Specific target organ toxicity (single or repeated exposure)

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory

Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Isopropyl Alcohol (2-Propanol) CAS-No. 67-63-0 100%

15.2. International regulations CANADA No additional information available

EU-Regulations No additional information available

National regulations No additional information available

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Revision date : 01/26/2018

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Full text of H-phrases: see section 16: ------

H225 Highly flammable liquid and vapour

------

H319 Causes serious eye irritation

------

H335 May cause respiratory irritation

NFPA health hazard : 1 - Materials that, under emergency conditions, can cause significant irritation.

NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions.

NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions.

Hazard Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature

conditions. Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)

Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives.

Personal protection : H H - Splash goggles, Gloves, Synthetic apron, Vapor respirator

SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application.

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Product: Methyl Alcohol Revision Date: 02/27/2015 1/8

Product Identifier: Methyl Alcohol

Product Code(s): NC-6832, NC-3495, M1008, M1025, M1027, M1036

Synonyms: Methanol; Carbinol; Wood Alcohol

Recommended Use: For manufacturing, industrial, and laboratory use only. For use as a solvent or as a cleaning agent.

Uses Advised Against: Not for food, drug, or household use.

Supplier: The Science Company

7625 W Hampden Ave #14, Lakewood, CO 80227 Phone: (303) 777-3777 Fax: (303) 777-3331

Emergency Phone Number: (800) 255-3924 (CHEM-TEL)

Hazard Classifications: Acute Toxicity – Oral: Category 3 Acute Toxicity – Dermal: Category 3 Acute Toxicity – Inhalation: Category 3 Specific Target Organ Toxicity (Single Exposure): Category 1 Flammable Liquids: Category 2

Signal Word: DANGER

Hazard Statements: Toxic if swallowed.

Toxic in contact with skin. Toxic if inhaled. Causes damage to organs. Highly flammable liquid and vapor.

Pictograms:

Precautionary Statements:

SDS

Safety Data Sheet

1. IDENTIFICATION

2. HAZARDS IDENTIFICATION

The Science Company SDS 7625 W Hampden Ave, #14 Lakewood CO 80227 Ph: 303-777-3777

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Prevention: Wash thoroughly after handling. Do not eat, drink, or smoke when using this product. Wear protective gloves, protective clothing, eye protection, and face protection. Do not breathe fumes, mists, vapors, or spray. Use only outdoors or in a well-ventilated area. Keep away from heat, sparks, open flames, and hot surfaces. – No smoking. Keep container tightly closed. Ground container and receiving equipment. Use explosion-proof electrical, ventilating, lighting, and transportation equipment. Use only non-sparking tools. Take precautionary measures against static discharge.

Response: If swallowed: Immediately call a poison center or doctor. Rinse mouth.

If on skin (or hair): Wash with plenty of water. Call a poison center or doctor if you feel unwell. Take off immediately all contaminated clothing and wash it before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor. If exposed: Call a poison center or doctor. In case of fire, use water spray, dry powder, alcohol resistant foam, or carbon dioxide to extinguish.

Storage: Store locked up.

Store in a well-ventilated place. Keep container tightly closed. Keep cool.

Disposal: Dispose of contents and container in accordance with local, regional, national, and international regulations.

Hazards Not Otherwise This product is toxic to humans. Primates are especially susceptible to the toxic effects of Classified: methanol, which are not reflected through toxicity data (see Section 11).

May cause adverse reproductive effects.

Toxicity Statement: Not applicable.

Component Common Name / Synonyms CAS# Chemical Formula % by Weight Methyl Alcohol Methanol 67-56-1 CH3 OH ≥ 99.8

Trade Secret Statement: Not applicable.

First Aid Procedures:

Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. WARNING! It may be hazardous to the person providing aid to give mouth-to- mouth resuscitation when the inhaled or ingested material is toxic, infectious, or corrosive. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a poison center or doctor.

Ingestion: Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs,

keep head low so that vomit does not enter lungs. Never give anything by mouth to an unconscious person. Immediate medical attention is required. Call a physician or poison control center immediately.

3. COMPOSITION AND INFORMATION ON INGREDIENTS

4. FIRST AID MEASURES

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Skin Contact: Remove contaminated clothing and shoes. Wash skin with plenty of water for at least 15 minutes. Wash clothing before reuse. Get medical attention if symptoms occur.

Eye Contact: Check for and remove contact lenses if present and easy to do. Immediately flush eyes with

gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention if irritation persists.

General Advice: Poison information centers in each state can provide additional assistance for scheduled

poisons. Ensure that medical personnel and those providing first aid are aware of the material(s) involved and take precautions to protect themselves.

Symptoms and Effects: May cause irritation to eyes, skin, respiratory tract, and gastrointestinal tract. Absorption

through skin may cause visual disturbances and metabolic acidosis. Inhalation of vapors may cause dizziness, suffocation, nervous system effects, and cardiovascular effects. May affect the blood, brain, urinary system, liver, spleen, and eyes. Ingestion may cause nausea, vomiting, diarrhea, abdominal pain, constipation, nervous system effects, blindness, and respiration effects. May affect the blood, liver, kidneys, cardiovascular system, brain, pancreas, and eyes.

Immediate Medical Care/ If you feel unwell or are concerned, call a physician or poison control center immediately. Special Treatment: Treat symptomatically.

Suitable Extinguishing Media: Water spray, dry powder, alcohol resistant foam, carbon dioxide.

Unsuitable Extinguishing Media: Do not use a solid (straight) water stream as it may scatter and spread fire.

Hazardous Combustion Carbon oxides. Products:

Specific Hazards: Highly flammable. Vapors may case flash fire or ignite explosively. Can be ignited easily by

heat, sparks, or flames and burns vigorously. Material may burn with an invisible flame. Sealed containers may explode when heated or involved in fire. Material is sensitive to static discharge. Vapors may travel considerable distance to source of ignition and flash back. Vapor from the solvent may accumulate in container headspace resulting in flammability hazard. High vapor concentration in air may cause an explosion hazard.

Special Protective Equipment/ As in any fire, wear MSHA/NIOSH-approved (or equivalent), self-contained, positive- Precautions for Firefighters: pressure or pressure-demand breathing apparatus and full protective gear. Use water spray

to cool unopened containers. Move containers from fire area, if you can do so without risk. This material may evaporate if spilled and leave a flammable residue. In the event of fire and/or explosion, do not breathe fumes.

Personal Precautions and Ventilate area of leak or spill. Isolate hazard area and keep unnecessary and unprotected Protective Equipment: personnel away from the area of the leak or spill. Keep upwind. Keep out of low areas.

Wear appropriate personal protective equipment (see Section 8). Remove all sources of ignition. Pay attention to flashback. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use spark-proof tools and explosion-proof equipment. Avoid contact with eyes, skin, and clothing.

Emergency Procedures: In case of chemical emergency, or if unsure how to address an accidental release, consult a

professional (see Section 1).

5. FIREFIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

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Methods for Containment: Eliminate all sources of ignition. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements, or confined areas. Dike the spilled material, where this is possible. Product should not be released to the environment. Contain and recover liquid when possible.

Methods for Cleanup: Absorb spill with an inert material (e.g. vermiculite, dry sand, earth, cloth, or fleece) and

place in a noncombustible container for reclamation or disposal. Do not flush to sewer. Clean contaminated surface thoroughly. Never return spills in original containers for reuse. Clean up in accordance with all applicable regulations.

Handling: Do not handle, store, or open near an open flame, sources of heat, or sources of ignition. Wear personal protective equipment (see Section 8). Use only in well-ventilated areas. Provide sufficient air exchange and/or exhaust in work areas. Avoid contact with skin, eyes, and clothing. Do not breathe vapors or spray mist. Do not ingest. When using, do not eat, drink, or smoke. Take precautionary measures against static discharge. To avoid ignition of vapors by static electricity discharge, all metal parts of equipment must be grounded. Keep away from incompatible materials (see Section 10). Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Containers of this material may be hazardous when empty, as they retain product residues (vapors, liquids). Observe all warnings and precautions listed for this product.

Storage: Store in a cool, dry, ventilated area. Store in a segregated and approved area away from

incompatible materials (see Section 10). Store in original container. Keep containers tightly closed and upright. Keep away from food, drink, and animal foodstuffs. Keep out of the reach of children. Ground container and transfer equipment. Comply with all national, state, and local codes pertaining to the storage, handling, dispensing, and disposal of this product.

Exposure Limits: ACGIH: TWA: 200 ppm STEL: 250 ppm BEL: 15 mg/L

OSHA: PEL: 200 ppm 260 mg/m3

Engineering Controls: Ensure adequate ventilation. Ventilation rates should be matched to conditions. If

applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.

Personal Protective Measures:

Eye/Face Protection: Wear safety glasses with side shields or goggles and a face shield. Maintain approved

eyewash station and accessible rinse facilities in work area.

Skin Protection: Wear appropriate chemical resistant clothing (with long sleeves) and appropriate chemical resistant gloves.

Respiratory Protection: An air-purifying, NIOSH-approved respirator with appropriate cartridge or canister may be

permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Use a positive-pressure, air-supplied respirator if there is any potential for an uncontrolled release, if exposure levels are unknown, or if any other circumstances exist where air-purifying respirators may not provide adequate protection.

7. HANDLING AND STORAGE

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

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Specific Requirements Ensure that glove material is compatible with this product. This information is available from for Personal Protective glove manufacturers. Equipment:

Appearance: Colorless, transparent liquid.

Odor: Pungent, alcoholic.

Odor Threshold: 100 ppm

Formula Weight: 32.04

pH: No information found.

Melting/Freezing Point: -97.8 °C

Boiling Point/Range: 64.7 °C

Decomposition Temperature: No information found.

Flash Point: 9.7 °C

Auto-ignition Temperature: 455 °C

Flammability: Explosive as vapor; flammable as liquid.

Flammability/Explosive Limits: Lower: 6% by volume Upper: 36% by volume

Solubility: Miscible with water, alcohol, ether, benzene, chloroform.

Vapor Pressure: 97.7 mmHg at 20 °C; 410 mmHg at 50 °C

Vapor Density: 1.11 (Air = 1)

Specific Gravity: 0.791 (Water = 1)

Evaporation Rate: 5.2 (Ether = 1)

Viscosity: No information found.

Partition Coefficient -0.77 (n-octanol/water):

Reactivity Data: Highly flammable. See Section 9.

Chemical Stability: Stable under normal conditions.

Conditions to Avoid: Heat, flames, sparks, sources of ignition, incompatible materials.

Incompatible Materials: Oxidizing agents, metals, reducing agents, acids.

Hazardous Decomposition Carbon oxides. Products:

Possibility of Hazardous May react vigorously, violently, or explosively if exposed to extreme thermal conditions or in Reactions: contact with the incompatible materials listed above.

Hazardous Polymerization: Will not occur.

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

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Routes of Exposure: Inhalation, ingestion, skin contact, eye contact.

Acute Effects: Harmful or fatal if swallowed, inhaled, or absorbed through the skin or eyes. Causes irritation to the eyes, skin, respiratory tract, and gastrointestinal tract. May cause visual disturbances or blindness if absorbed into the blood stream. May affect the blood, brain, urinary system, liver, spleen, eyes, kidneys, cardiovascular system, and pancreas.

Chronic Effects: May cause central nervous system effects. May cause damage to eyesight. Prolonged or

repeated exposure may cause liver, kidney, brain, cardiovascular system, blood, spleen, and heart damage as well as adverse reproductive effects, birth defects, mutagenic effects, and dermatitis.

Toxicological Data: LD50 Oral, Rat: 5628 mg/kg

LC50 Inhalation, Rat: 87.6 mg/L 6 h LD50 Dermal, Rabbit: 15,800 mg/kg LDL Oral, Human: 143 mg/kg Toxic to reproduction based on animal data.

Symptoms of Exposure: Irritation, unconsciousness, visual disturbances, metabolic acidosis, drowsiness, dizziness,

suffocation, shortness of breath, nervous system effects, cardiovascular effects, cough, nausea, vomiting, diarrhea, abdominal pain, constipation, blindness, and respiration effects.

Carcinogenic Effects: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

Ecotoxicological Data: EC50 Water Flea (Daphnia magna): > 10,000 mg/L 48 h LC50 Fathead Minnow (Pimephales promelas): > 100 mg/L 96 h

Persistence and Degradability: Expected to be readily biodegradable.

Bioconcentration Factor: 1.0

Environmental Effects: Not expected to be hazardous to the environment. However, the possibility of an environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Partition Coefficient (n-octanol/water): -0.77

Disposal Instructions: All wastes must be handled in accordance with local, state, and federal regulations. Minimize exposure to product waste (see Section 8). Do not dispose unused waste down drains or into sewers.

Contaminated Packaging: Because emptied containers retain product residue, follow label warnings even after

container is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near product container. Offer rinsed packaging material to local recycling facilities.

Waste Codes: U154 (US RCRA Hazardous Waste U List – Ignitable waste)

11. TOXICOLOGICAL INFORMATION

12. ECOLOGICAL INFORMATION

13. DISPOSAL INFORMATION

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DOT:

UN Number: UN1230

Proper Shipping Name: Methanol

Hazard Class: 3

Packing Group: II

ERG Number: 127

Other Transport Precautions: Reportable Quantity: 5000 lb

U.S. Federal Regulations:

OSHA: This product is considered a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

TSCA Inventory: All components of this product are on the U.S. TSCA Inventory.

U.S. EPCRA (SARA Title III):

Section 302: No information found.

Sections 311/312:

Section 313: Methanol

CERCLA Reportable Quantities: Methanol: 5000 lb

14. TRANSPORT INFORMATION

15. REGULATORY INFORMATION

Hazard Category List (Yes/No) Section 311 – Hazardous Chemical Yes Immediate Hazard Yes Delayed Hazard Yes Fire Hazard Yes Pressure Hazard No Reactivity Hazard No

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International Inventories:

Country or Region Inventory Name On Inventory (Yes/No)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Yes Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes

*A "Yes" indicates that the listed component(s) of this product comply with the inventory requirements administered by the governing country(s)

Disclaimer: The Science Company provides the information in this Safety Data Sheet in the belief that it is reliable but assumes no responsibility for its completeness or accuracy. The physical properties reported in this SDS are obtained from literature and do not constitute product specifications. The Science Company makes and gives no representations or warranties with respect to the information contained herein or the product to which it refers, whether express, implied, or statutory, including without limitation, warranties of accuracy, completeness, merchantability, non-infringement, performance, safety, suitability, stability, and fitness for a particular purpose. No warranty against infringement of any patent, copyright or trademark is made or implied. This SDS is intended only as a guide to the appropriate handling of the material by a properly trained person. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. Accordingly, The Science Company assumes no liability whatsoever for the use of or reliance upon this information including results obtained, incidental or consequential damages, or lost profits.

Issue Date: February 27, 2015

Reason for Revision: Update of Section 2 over 01/29/2014 version.

16. OTHER INFORMATION

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Concentrated Nitric Acid, 98% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date: November 2017

Version: 1.0

November 2017 EN (English US) 1/10

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY Product Identifier Product Name: Concentrated Nitric Acid, 98% Synonyms: Hydrogen Nitrate, Aqua Fortis, White Fuming Nitric Acid Intended Use of the Product Not available Name, Address, and Telephone of the Responsible Party

Company El Dorado Chemical Company 4500 North West Ave. P.O. Box 231 El Dorado, AR 71731 T (870) 863-1400 - F (870)-863-1126

Emergency Telephone Number Emergency number : (870) 863-1400, (800) 424-9300 (CHEMTREC, 24 hours)

SECTION 2: HAZARDS IDENTIFICATION

Classification of the Substance or Mixture Classification (GHS-US) Ox. Liq. 3 H272 Met. Corr. 1 H290 Skin Corr. 1A H314 Eye Dam. 1 H318

Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) :

GHS03

GHS05

Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H272 - May intensify fire; oxidizer

H290 - May be corrosive to metals H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage

Precautionary Statements (GHS-US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking. P220 - Keep/Store away from extremely high or low temperatures, ignition sources, combustible materials, incompatible materials. P221 - Take any precaution to avoid mixing with incompatible materials, ignition sources, combustible materials. P234 - Keep only in original container. P260 - Do not breathe vapors, mist, spray. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P280 - Wear protective gloves, protective clothing, eye protection, face protection, respiratory protection. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER or doctor/physician.

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Concentrated Nitric Acid, 98% Safety Data Sheet According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations


P321 - Specific treatment (see section 4). P363 - Wash contaminated clothing before reuse. P370+P378 - In case of fire: Use appropriate media for extinction. P390 - Absorb spillage to prevent material damage. P405 - Store locked up. P406 - Store in corrosive resistant container with a resistant inner liner. P501 - Dispose of contents/container to local, regional, national, territorial, provincial, and international regulations.

Other Hazards Other Hazards Not Contributing to the Classification: Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. May cause or intensify fire; oxidizer. When heated to decomposition, emits toxic fumes. Contact with metals may evolve flammable hydrogen gas. Unknown Acute Toxicity (GHS-US) Not available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Mixture

Name Product identifier % (w/w) Classification (GHS-US)

Nitric acid (CAS No) 7697-37-2 97.5 - 100 Ox. Liq. 3, H272 Met. Corr. 1, H290 Skin Corr. 1A, H314 Eye Dam. 1, H318

Full text of H-phrases: see section 16 SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

Inhalation: When symptoms occur: go into open air and ventilate suspected area. Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call for medical assistance.

Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Immediately call for medical assistance. Wash contaminated clothing before reuse.

Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call for medical assistance.

Ingestion: Rinse mouth. Do NOT induce vomiting. Immediately call for medical assistance.

Most Important Symptoms and Effects Both Acute and Delayed General: Causes severe skin burns and eye damage. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.

Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.

Skin Contact: Causes severe irritation which will progress to chemical burns.

Eye Contact: Causes serious eye damage.

Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms: May cause erosion of the teeth, or chronic bronchitis.

Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention.

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SECTION 5: FIREFIGHTING MEASURES

Extinguishing Media

Special Hazards Arising From the Substance or Mixture

Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Nitrogen oxides. Acrid vapors. Corrosive vapors. Other information: Do not allow run-off from fire fighting to enter drains or water courses. Contact with metals may evolve flammable hydrogen gas. Use water spray to disperse vapors. Reference to Other Sections Refer to section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do NOT breathe (vapors, mist, spray). Avoid all contact with skin, eyes, or clothing. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area.

Environmental Precautions Prevent entry to sewers and public waters.

Methods and Material for Containment and Cleaning Up For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Cautiously neutralize spilled liquid with crushed limestone, soda ash or lime. CAUTION : Neutralization can produce vigorous reaction, boiling and fumes. Use extreme caution in clean-up procedure. As an immediate precautionary measure, isolate spill or leak area in all directions. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Absorb spillage to prevent material damage. Cautiously neutralize spilled liquid with crushed limestone, soda ash or lime. CAUTION : Neutralization can produce vigorous reaction, boiling and fumes. Use extreme caution in clean-up procedure. Contact competent authorities after a spill.

Reference to Other Sections See section 8, Exposure Controls and Personal Protection.

SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed: May be corrosive to metals. When heated to decomposition, emits toxic fumes. Corrosive vapors are released. Contact with metals may evolve flammable hydrogen gas. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do no eat, drink or smoke when using this product. Wash hands and forearms thoroughly after handling.

Suitable Extinguishing Media: Water spray, fog, carbon dioxide, foam, dry chemical. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.

Fire Hazard: May intensify fire; oxidizer. Will burn if exposed to heat, and in addition, will accelerate the burning of other combustibles, resulting in more rapid spread of fire. Explosion Hazard: Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. In contact with metals, emits flammable/explosive gas. May cause fire or explosion; strong oxidizer. Reactivity: Thermal decomposition generates : toxic/corrosive vapors. Can react explosively with reducing agents, metal powders, Hydrogen sulfide, nitrate, and organic materials. Contact with metals may evolve flammable hydrogen gas.

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Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof electrical, ventilating, and lighting equipment. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place. Keep/Store away from extremely high or low temperatures, direct sunlight, heat, ignition sources, combustible materials, incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Finely divided metals. Hydrogen sulfide. Reducing agents. Organic materials. Specific End Use(s) Not available SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters


Mexico OEL TWA (mg/m³) 5 mg/m³ Mexico OEL TWA (ppm) 2 ppm Mexico OEL STEL (mg/m³) 10 mg/m³ Mexico OEL STEL (ppm) 4 ppm USA ACGIH ACGIH TWA (ppm) 2 ppm USA ACGIH ACGIH STEL (ppm) 4 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 2 ppm USA NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ USA NIOSH NIOSH REL (TWA) (ppm) 2 ppm USA NIOSH NIOSH REL (STEL) (mg/m³) 10 mg/m³ USA NIOSH NIOSH REL (STEL) (ppm) 4 ppm USA IDLH US IDLH (ppm) 25 ppm Alberta OEL STEL (mg/m³) 10 mg/m³ Alberta OEL STEL (ppm) 4 ppm Alberta OEL TWA (mg/m³) 5.2 mg/m³ Alberta OEL TWA (ppm) 2 ppm

British Columbia OEL STEL (ppm) 4 ppm British Columbia OEL TWA (ppm) 2 ppm Manitoba OEL STEL (ppm) 4 ppm Manitoba OEL TWA (ppm) 2 ppm New Brunswick OEL STEL (mg/m³) 10 mg/m³ New Brunswick OEL STEL (ppm) 4 ppm New Brunswick OEL TWA (mg/m³) 5.2 mg/m³ New Brunswick OEL TWA (ppm) 2 ppm Newfoundland & Labrador OEL STEL (ppm) 4 ppm Newfoundland & Labrador OEL TWA (ppm) 2 ppm Nova Scotia OEL STEL (ppm) 4 ppm Nova Scotia OEL TWA (ppm) 2 ppm Nunavut OEL STEL (mg/m³) 10 mg/m³ Nunavut OEL STEL (ppm) 4 ppm Nunavut OEL TWA (mg/m³) 5.2 mg/m³ Nunavut OEL TWA (ppm) 2 ppm Northwest Territories OEL STEL (mg/m³) 10 mg/m³ Northwest Territories OEL STEL (ppm) 4 ppm Northwest Territories OEL TWA (mg/m³) 5.2 mg/m³ Northwest Territories OEL TWA (ppm) 2 ppm Ontario OEL STEL (ppm) 4 ppm

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Ontario OEL TWA (ppm) 2 ppm Prince Edward Island OEL STEL (ppm) 4 ppm Prince Edward Island OEL TWA (ppm) 2 ppm Québec VECD (mg/m³) 10 mg/m³ Québec VECD (ppm) 4 ppm Québec VEMP (mg/m³) 5.2 mg/m³ Québec VEMP (ppm) 2 ppm Saskatchewan OEL STEL (ppm) 4 ppm Saskatchewan OEL TWA (ppm) 2 ppm Yukon OEL STEL (mg/m³) 10 mg/m³ Yukon OEL STEL (ppm) 4 ppm Yukon OEL TWA (mg/m³) 5 mg/m³ Yukon OEL TWA (ppm) 2 ppm

Exposure Controls Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Use explosion-proof equipment. Ensure all national/local regulations are observed. Alarm detectors should be used when toxic gases may be released. Gas detectors should be used when flammable gases/vapors may be released.

Personal Protective Equipment: Gloves. Respiratory protection of the dependent type. Protective goggles. Protective clothing.

Materials for Protective Clothing: Chemically resistant materials and fabrics. Corrosion-proof clothing. Wear fire/flame resistant/retardant clothing.

Hand Protection: Wear chemically resistant protective gloves. Acid-resistant protective gloves.

Eye Protection: Chemical goggles or face shield.

Skin and Body Protection: Wear suitable protective clothing.

Respiratory Protection: Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of vapor or mist are expected to exceed exposure limits.

Other Information: When using, do not eat, drink or smoke.

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties Physical State : Liquid

Appearance : Colorless,light brown

Odor : Acrid

Odor Threshold : Not available

pH : < 1

Relative Evaporation Rate (butylacetate=1) : > 1

Melting Point : Not available

Freezing Point : -41.1 °C (-42°F)

Boiling Point : 83.9 °C (183°F)

Flash Point : Not available

Auto-ignition Temperature : Not available

Decomposition Temperature : Not available

Flammability (solid, gas) : Not available

Lower Flammable Limit : Not available

Upper Flammable Limit : Not available

Vapor Pressure : 51 mm Hg @25°C (77°F)

Relative Vapor Density at 20 °C : >1

Relative Density : Not available

Specific Gravity : 1.51

Solubility : Miscible.

Viscosity : 1 cp @20°C (68°F)

Volatility : 100% Explosion Data – Sensitivity to Mechanical Impact : Not available

Explosion Data – Sensitivity to Static Discharge : Not available

SECTION 10: STABILITY AND REACTIVITY

Reactivity: Thermal decomposition generates : toxic/corrosive vapors. Can react explosively with reducing agents, metal powders, Hydrogen sulfide, nitrate, and organic materials. Contact with metals may evolve flammable hydrogen gas.

Chemical Stability: May intensify fire; oxidizer.

Possibility of Hazardous Reactions: Hazardous polymerization will not occur.

Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Heat. Sparks. Overheating. Open flame. Incompatible materials. Adding water to acid should be avoided.

Incompatible Materials: Strong acids. Strong bases. Strong oxidizers. Metals. May be corrosive to metals. Reducing agents. Amines.

Hazardous Decomposition Products: Thermal decomposition generates : Corrosive vapors. Nitrogen oxides. Explosive hydrogen gas. Toxic vapors.

SECTION 11: TOXICOLOGICAL INFORMATION

Information on Toxicological Effects - Product

LD50 and LC50 Data: Not available

Skin Corrosion/Irritation: Causes severe skin burns and eye damage. pH: < 1

Serious Eye Damage/Irritation: Causes serious eye damage. pH: < 1

Respiratory or Skin Sensitization: Not classified

Germ Cell Mutagenicity: Not classified

Teratogenicity: Not available

Carcinogenicity: Not classified

Specific Target Organ Toxicity (Repeated Exposure): Not classified

Reproductive Toxicity: Not classified

Acute Toxicity: Not classified.

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Specific Target Organ Toxicity (Single Exposure): Not classified

Aspiration Hazard: Not classified

Symptoms/Injuries After Inhalation: Inhalation may cause immediate severe irritation progressing quickly to chemical burns.

Symptoms/Injuries After Skin Contact: Causes severe irritation which will progress to chemical burns.

Symptoms/Injuries After Eye Contact: Causes serious eye damage.

Symptoms/Injuries After Ingestion: Contact may cause immediate severe irritation progressing quickly to chemical burns. Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms: May cause erosion of the teeth, or chronic bronchitis. Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data:


LC50 Inhalation Rat (mg/l) 0.13 mg/l (Exposure time: 4 h)

LC50 Inhalation Rat (ppm) 67 ppm/4h

SECTION 12: ECOLOGICAL INFORMATION Toxicity Not classified Persistence and Degradability Concentrated Nitric Acid

Persistence and Degradability Not established. Bioaccumulative Potential

Concentrated Nitric Acid

Bioaccumulative Potential Not established.


Log Pow -2.3 (at 25 °C)

Mobility in Soil Not available Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations.

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SECTION 14: TRANSPORT INFORMATION

14.1 In Accordance with DOT Proper Shipping Name : NITRIC ACID other than red fuming, with more than 70% nitric acid Hazard Class : 8

Identification Number : UN2031 Label Codes : 8,5.1 Packing Group : I

ERG Number : 157 14.2 In Accordance with IMDG Proper Shipping Name : NITRIC ACID Hazard Class : 8 Identification Number : UN2031 Packing Group : I Label Codes : 8,5.1

EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-Q 14.3 In Accordance with IATA Proper Shipping Name : NITRIC ACID Packing Group : I Identification Number : UN2031

Hazard Class : 8 Label Codes : 8,5.1 ERG Code (IATA) : 8X 14.4 In Accordance with TDG Proper Shipping Name : NITRIC ACID Packing Group : I Hazard Class : 8

Identification Number : UN2031 Label Codes : 8,5.1 SECTION 15: REGULATORY INFORMATION US Federal Regulations


Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 302 Threshold Planning Quantity (TPQ) 1000 SARA Section 313 - Emission Reporting 1.0 %

US State Regulations


U.S. - California - SCAQMD - Toxic Air Contaminants - Non-Cancer Acute U.S. - California - SCAQMD - Toxic Air Contaminants With Proposed Risk Values U.S. - California - Toxic Air Contaminant List (AB 1807, AB 2728) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (30 min) U.S. - Connecticut - Hazardous Air Pollutants - HLVs (8 hr)


SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard

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U.S. - Delaware - Accidental Release Prevention Regulations - Sufficient Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Threshold Quantities U.S. - Delaware - Accidental Release Prevention Regulations - Toxic Endpoints U.S. - Delaware - Pollutant Discharge Requirements - Reportable Quantities U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Acceptable Ambient Concentrations U.S. - Idaho - Non-Carcinogenic Toxic Air Pollutants - Emission Levels (ELs) U.S. - Idaho - Occupational Exposure Limits - TWAs U.S. - Illinois - Toxic Air Contaminants U.S. - Louisiana - Reportable Quantity List for Pollutants U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Groundwater Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Oil & Hazardous Material List - Reportable Quantity U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 1 U.S. - Massachusetts - Oil & Hazardous Material List - Soil Reportable Concentration - Reporting Category 2 U.S. - Massachusetts - Right To Know List U.S. - Massachusetts - Toxics Use Reduction Act U.S. - Michigan - Occupational Exposure Limits - STELs U.S. - Michigan - Occupational Exposure Limits - TWAs U.S. - Michigan - Polluting Materials List U.S. - Michigan - Process Safety Management Highly Hazardous Chemicals U.S. - Minnesota - Chemicals of High Concern U.S. - Minnesota - Hazardous Substance List U.S. - Minnesota - Permissible Exposure Limits - STELs U.S. - Minnesota - Permissible Exposure Limits - TWAs U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - 24-Hour U.S. - New Hampshire - Regulated Toxic Air Pollutants - Ambient Air Levels (AALs) - Annual U.S. - New Jersey - Discharge Prevention - List of Hazardous Substances U.S. - New Jersey - Environmental Hazardous Substances List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Special Health Hazards Substances List U.S. - New Jersey - TCPA - Extraordinarily Hazardous Substances (EHS) U.S. - New York - Occupational Exposure Limits - TWAs U.S. - New York - Reporting of Releases Part 597 - List of Hazardous Substances U.S. - North Carolina - Control of Toxic Air Pollutants U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 1-Hour U.S. - North Dakota - Air Pollutants - Guideline Concentrations - 8-Hour U.S. - Ohio - Accidental Release Prevention - Threshold Quantities U.S. - Ohio - Extremely Hazardous Substances - Threshold Quantities U.S. - Oregon - Permissible Exposure Limits - TWAs U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Rhode Island - Air Toxics - Acceptable Ambient Levels - 1-Hour U.S. - South Carolina - Toxic Air Pollutants - Maximum Allowable Concentrations U.S. - South Carolina - Toxic Air Pollutants - Pollutant Categories U.S. - Tennessee - Occupational Exposure Limits - STELs U.S. - Tennessee - Occupational Exposure Limits - TWAs U.S. - Texas - Effects Screening Levels - Long Term U.S. - Texas - Effects Screening Levels - Short Term U.S. - Vermont - Permissible Exposure Limits - STELs U.S. - Vermont - Permissible Exposure Limits - TWAs U.S. - Washington - Permissible Exposure Limits - STELs U.S. - Washington - Permissible Exposure Limits - TWAs U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 25 Feet to Less Than 40 Feet

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U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 40 Feet to Less Than 75 Feet U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights 75 Feet or Greater U.S. - Wisconsin - Hazardous Air Contaminants - All Sources - Emissions From Stack Heights Less Than 25 Feet U.S. - Wyoming - Process Safety Management - Highly Hazardous Chemicals

Canadian Regulations


Listed on the Canadian DSL (Domestic Substances List) inventory. Listed on the Canadian Ingredient Disclosure List WHMIS Classification Class C - Oxidizing Material

Class E - Corrosive Material

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.

SECTION 16: OTHER INFORMATION

Revision date : November 2017 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA

Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Met. Corr. 1 Corrosive to metals Category 1 ------ Ox. Liq. 3 Oxidizing liquids Category 3 ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ H272 May intensify fire; oxidizer ------ H290 May be corrosive to metals ------ H314 Causes severe skin burns and eye damage ------ H318 Causes serious eye damage

NFPA Health Hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given.

NFPA Fire Hazard : 0 - Materials that will not burn. NFPA Reactivity : 0 - Normally stable, even under fire exposure conditions,

and are not reactive with water. NFPA Specific Hazard : OX - This denotes an oxidizer, a chemical which can greatly

increase the rate of combustion/fire. Party Responsible for the Preparation of This Document El Dorado Chemical Company P.O. Box 231 El Dorado, AR 71731 (870) 863-1400 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.


WHMIS Classification Class E - Corrosive Material Class C - Oxidizing Material

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Sulfuric Acid 1 August 2009

MATERIAL SAFETY DATA SHEET - MSDS

Sulfuric Acid (Concentrated)

Martin Product Sales, LLC Emergency Assistance P.O. Box 191 Chemtrec: (800)424-9300 Kilgore, Texas 75663 1-800-256-6644 Section 1: Product Identification Synonyms: Sulphuric Acid, Hydrogen Sulphate, Oil of Vitriol, Battery Acid Chemical Name: Sulfuric Acid Chemical Family: Inorganic Acid Chemical Formula: H2SO4 CAS Reg. No.: 7664-93-9 Martin can not guarantee the technical analysis and exact chemical composition as it may vary depending on the chemical components of the raw material and are not reflected in this document. Consult analysis sheets for exact chemical composition. Section 2: Hazard Identification PHYSICAL STATE AND APPEARANCE: Odorless, clear to amber, heavy, oily liquid. A pungent odor may exist if certain impurities are present in the acid. EMERGENCY OVERVIEW: Danger! Extremely corrosive. Causes severe burns and / or eye damage. Mist: Causes respiratory irritation. Harmful if inhaled. Harmful or fatal if swallowed. Reacts violently with water. Concentrated Sulfuric Acid will react with many organic materials and may cause fire due to the heat of the reaction. Not flammable, but reacts with most metals to form explosive/flammable hydrogen gas. This product contains ingredients that are considered to be hazardous as defined by the OSHA Hazard Communication Standard 29 CFR 1910.1200, and is listed in the Toxic Substances Control Act (TSCA). Routes of entry: Skin contact. Eye contact. Ingestion. Inhalation. Potential acute health effects EYE CONTACT: Immediate pain, severe burns and corneal damage, which may result in permanent blindness. SKIN CONTACT: Causes burns, and brownish or yellow stains. Concentrated solutions may cause second or third degree burns with severe necrosis. Prolonged and repeated exposure to dilute solutions may cause irritation, redness, pain and drying and cracking of the skin. INHALATION: Causes respiratory irritation and at high concentrations may cause severe injury, burns, or death. Effects of exposure may be delayed. INGESTION: Causes severe irritation or burns of the mouth, throat, and esophagus.

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EXISTING MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE: Skin irritation may be aggravated in individuals with existing skin lesions. Breathing of vapors or sprays (mists) may aggravate acute or chronic asthma and chronic pulmonary disease such as emphysema and bronchitis. See Section 11 for Toxicological Data Section 3: Composition / Information on Ingredients Name CAS # % by weight Sulfuric Acid 7664-93-9 70 – 100% Water 7732-18-5 0-30% Section 4: First Aid Measures Corrosive effects on the skin and eyes may be delayed, and damage may occur without the sensation or onset of pain.

SPEED IS ESSENTIAL. OBTAIN IMMEDIATE MEDICAL ATTENTION. Have emergency eyewash station / safety shower available in work area.

SKIN CONTACT: Immediately flush skin with running water for a minimum of 20 minutes. Start flushing while removing contaminated clothing. If irritation persists, repeat flushing. Obtain medical attention immediately. Do not transport victim unless the recommended flushing period is completed or flushing can be continued during transport. Discard heavily contaminated clothing and shoes in a manner that limits further exposure. EYE CONTACT: Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY. Do not transport victim until the recommended flushing period is completed unless flushing can be continued during transport. INHALATION: Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Do not use mouth-to-mouth method if victim ingested or inhaled the substance: induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Give Cardiopulmonary Resuscitation (CPR) if there is no pulse AND no breathing. Obtain medical attention IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING. If victim is alert and not convulsing, rinse mouth and give ½ to 1 glass of water to dilute material. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water. IMMEDIATELY contact local poison control center. Vomiting may need to be induced but should be directed by a physician or a poison control centre. IMMEDIATELY transport victim to an emergency facility. While the patient is being transported to a medical facility apply compresses of iced water. If medical treatment must be delayed, immerse the affected area in iced water or apply compresses of iced water to affected areas. Do not freeze tissue. Continued washing of the affected area with cold or iced water will be helpful in removing the last traces of sulfuric acid. Creams or ointments should not be applied before or during the washing phase of treatment.

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NOTE TO PHYSICIANS: This product contains materials that may cause severe pneumonitis if aspirated. If ingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, to prevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation and appropriate chemotherapy if respiration is depressed. Following exposure the patient should be kept under medical review for at least 48 hours as delayed pneumonitis may occur. DO NOT attempt to neutralize the acid with weak bases since the reaction will produce heat that may extend the corrosive injury

Section 5: Fire Fighting Measures

Flammability of the product: Non-flammable

Flash points: Not applicable

Auto-ignition temperature: Not applicable

Flammable limits: Not applicable

Products of thermal decomposition: Oxides of Sulfur

EXPLOSION HAZARDS:

Not flammable but highly reactive. Reacts violently with water with evolution of heat can react with organic materials explosively (See Section 10). Reacts with many metals to liberate hydrogen gas which can form explosive mixtures with air. Hydrogen can accumulate to explosive concentrations. May ignite other combustible materials. HAZARDOUS REACTIVITY Instability: Stable, but reacts violently with water and organic materials with evolution of heat. Decomposition: Releases sulfur dioxide at extremely high temperatures. Polymerization: Polymerization will not occur. Materials to Avoid: Vigorous reactions with water; alkaline solutions; metals, metal powder; carbides; chlorates; fuminates; nitrates; picrates; strong oxidizing, reducing, or combustible organic materials. Hazardous gases are evolved on contact with chemicals such as cyanides, sulfides, and carbides. FIRE-FIGHTING MEDIA AND INSTRUCTIONS: Wear a NIOSH/MSHA approved self-contained breathing apparatus if vapors or mists are present and full protective clothing. For fighting fires in close proximity to spill or vapors, use acid-resistant personal protective equipment. Evacuate personnel to a safe area. Prevent unauthorized entry to fire area. Dike area to contain runoff and prevent contamination of water sources. Neutralize runoff with lime, soda ash or other suitable neutralizing agents (see Deactivating Chemicals, Section 6). Cool containers that are exposed to flame with streams of water until fire is out.

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Section 6: Accidental Release Measures Small Spill: Cover with DRY earth, sand or other non-combustible material or absorb with an inert dry material and place in a loosely covered plastic or other appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate, lime, or other suitable neutralizing agent. Large Spill: Stop leak if possible without risk. Dike with DRY earth, sand or other non-combustible inert material. Prevent entry into sewers or waterways. Consider neutralizing the residue with sodium carbonate, lime, or other suitable neutralizing agent. Ensure adequate decontamination of tools and equipment following clean up. Comply with Federal, Provincial/State and local regulations on reporting releases. Dispose of waste material at an approved waste treatment/disposal facility, in accordance with applicable regulations. Do not dispose of waste with normal garbage or to sewer systems. Section 7: Handling and Storage Good general ventilation should be provided to keep vapor and mist concentrations below the exposure limits. Have available and wear as appropriate: Chemical splash goggles; full-length faceshield/chemical splash goggle combination; acid-proof gauntlet gloves, apron, and boots; acid proof suit and hood; and appropriate NIOSH/MSHA respiratory protection. In case of emergency or where there is a strong possibility of considerable exposure, wear a complete acid suit with hood, boots and gloves. If acid vapor or mist are present and exposure limits may be exceeded, wear appropriate NOISH/MSHA respiratory protection. HANDLING: Wear appropriate Personal Protection Equipment. Do not breathe sprays or mists. Do not ingest. Do not get in eyes, on skin or on clothing. Keep ignition sources away from sulfuric acid storage, handling and transportation equipment. Locate safety shower and eyewash station close to chemical handling area. Use EXTREME care when diluting with water. Always add acid to water never the reverse. CAUTION: Hydrogen, a highly flammable gas, can accumulate to explosive concentrations inside drums, or any types of steel containers or tanks upon storage. Carbon steel storage tanks must be vented. People working with this chemical should be properly trained regarding its hazards and its safe use. STORAGE: If stored in non-reactive container, keep container tightly closed. Metal and, specifically carbon steel, storage tanks must be vented due to hydrogen release as noted above. Section 8: Exposure Control / Personal Protection Engineering controls Use process enclosures, local exhaust ventilation or other engineering controls to keep airborne levels below recommended exposure limits. The most effective measures are the total enclosure of processes and the mechanization of handling procedures to prevent all personal contact with sulfuric acid. Safety showers and eyewash stations should be installed in storage and handling areas.

Personal protection Eyes: Chemical goggles and face shield. Skin: Where there is a danger of spilling or splashing, acid resistant aprons or suits should be worn. Trouser legs should be worn outside (not tucked in) rubber boots.

Hands: Chemical-resistant, impervious gloves (i.e. neoprene) should be worn when handling sulfuric acid.

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Respiratory: Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mist cartridges for concentrations up to 10 mg/m

3. An air-

supplied respirator if concentrations are higher or unknown. NOTE: Personal protection information shown in Section 8 is based upon general information as to normal uses and conditions. Where special or unusual uses or conditions exist, it is suggested that the expert assistance of an industrial hygienist or other qualified professional be sought. Component Exposure limits Sulfuric Acid: ACGIH TLV 1 mg/m

3 (TWA) 8 hours

ACGIH STEL 3 mg/m3 15 minutes

OSHA PEL 1 mg/m3 (TWA) 8 hours

NIOSH REL 1 mg/m3 (TWA) 10 hours


Appearance and Odor: Odorless, clear to amber, heavy, oily liquid. A pungent odor may exist if certain impurities are present in the acid. Physical State: Liquid

Molecular Weight: 98.08

Odor Threshold: Not applicable

Boiling Point: 78%: 193°C (380°F) 93%: 276°C (529°F) 98%:330°C (626°F)

Melting/Freezing Point: 78%: -11.2°C (+11.6°F) 93%: -29.5°C (-21.1°F) 98%: -1.1°C (30°F)

Vapor Pressure at 40°C (102°F): 78%: 1.2 mmHg 93%: 0.0016 mmHg 98%: 0.002 mmHg

Specific Gravity at 15°C (60°F): 78%: 1.7059 93%: 1.8354 98%: 1.8437

Vapor Density: (Air=1): 3.4

Evaporation Rate: Not applicable

Solubility: Easily soluble in cold water (with liberation of much heat.) Soluble in ethyl alcohol.

pH: 0.3 (1N solution at 25°C/78°F)

Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Keep away from heat and sources of ignition. Avoid temperatures, which may have a negative effect on the materials of construction used in equipment. Materials to Avoid: Contact with organic materials (such as alcohol, acrylonitrile, chlorates, carbides, epichlorohydrin, fulminates, isoprene, nitrates and picrates) may cause fire and explosions. Contact with metals may produce flammable hydrogen gas. When diluting, add acid to water. Do NOT add water to the acid.

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Hazardous Decomposition or Combustion Products: Toxic gases and vapors (e.g. sulfur dioxide, sulfuric acid vapors/mists and sulfur trioxide) may be released when sulfuric acid decomposes. Hazardous Polymerization: Will Not Occur. Corrosivity: Extremely corrosive in presence of aluminum, copper, and stainless steel. Highly corrosive in presence of stainless steel (304). Non-corrosive in presence of glass. Section 11: Toxicological Information Toxicity Data LD

50 (oral, rat) = 2140 mg/kg LC

50 (inhalation, rat) = 510 mg/m

3 for 2 hrs

Carcinogenicity Data: The IARC has concluded that occupational exposure to strong inorganic acid mists containing sulfuric acid is carcinogenic to man, causing cancer of the larynx (the voice box). Although no direct link has been established between exposure to sulfuric acid and cancer in man, exposure to any mist or aerosol during the use of this product should be avoided. Reproductive Effects: Slightly embryotoxic in rabbits (a minor, rare skeletal variation). The animals were exposed to 5 and 20 mg/m

3 for 7 hrs/day throughout pregnancy. Slight maternal toxicity was present at the

highest dose in both species. Mutagenicity Data: Cytogenic analysis (hamster) ovaries 4 mmol/L Teratogenicity Data: Not teratogenic in mice and rabbits. Synergistic Materials: None known Special Remarks on other Toxic Effects on Humans: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis. Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May cause permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the stomach, GI bleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse (similar to acute inhalation). It may also cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucous membranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. May also affect teeth (changes in teeth and supporting structures - erosion, discoloration).

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Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalation may affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart (ischemic heart lesions), and respiratory system/lungs (pulmonary edema, lung damage), teeth (dental discoloration, erosion). Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.

Section 12: Ecological Information Ecotoxic Effects: Harmful to aquatic life in very low concentrations. May be dangerous if it enters water intake; Fish toxicity; 2.8 μg/L 96 hrs LC50 Rainbow trout. Products of Degradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. These products are sulphur oxides (SO2, SO3) Toxicity of the Products of Degradation: The products of degradation are more toxic than the original product.


Waste disposal: The generation of waste should be avoided or minimized wherever possible. Cleaned up material may be a hazardous waste as defined by Resource Conservation and Recovery Act (RCRA) on disposal due to the corrosivity characteristic. Disposal of this product and any by-products must comply with all local, state, and federal requirements. Consult your local and/or regional authorities. Section 14: Transport Information Shipping Description: Sulfuric Acid Shipping Description: UN 1830, Sulfuric Acid, 8, PG II Packaging References: 49CFR, Sections 172.504, 173.213, 173.247, 172.325 / SP 30 Section 15: Regulatory Information U.S. Federal regulations: TSCA 8(b) inventory: Sulfuric acid SARA 302/304/311/312 extremely hazardous substances: Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous Substances: Sulfuric acid: 1000 lbs. (453.6 kg) Reportable Quantity (RQ) under U.S. EPA CERCLA: RQ=1000 lb / 454 kg TSCA Inventory Status: Reported/Included Other Regulations/Legislation which apply to this product: New Jersey Special Health Hazard Substance List and Environmental Hazardous Substance; Minnesota, Florida, Rhode Island Hazardous Substance ; California Director's List of Hazardous Substances; Massachusetts Extraordinarily Hazardous Substance List

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Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA)

References: 29 CFR Part 1910.1200 OSHA MSDS Requirements.

49 CFR 172.101 Table of Hazardous Materials ANSI Z400.1, MSDS Standard, 2004. Hawley’s Condensed Chemical Dictionary, 14th Edition The Merck Index, 12th Edition Supplier Material Safety Data Sheets

LEGAL DISCLAIMER While the information contained in the MSDS is believed to be reliable, no guarantee is made as to its accuracy or completeness. The conditions of use, handling, storage, and disposal, and the suitability of the product for particular uses are beyond our control. Consequently, all risks involving the use of the product are assumed by the user. We expressly disclaim all warranties of every kind and nature, express or implied, including the warranties of merchantability and fitness for a particular purpose.

Health 3

Fire hazard 0

Physical Hazard 2

Personal protection C

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Toluene (MSDS)

Section 1: Chemical Product and Company Identification

Product Name: Toluene

CAS#: 108-88-3

Synonym: Synonyms: Methacide;

Methylbenzene; Phenylmethane; Antisal la;

Benzene, methyl-; Methane, phenyl-;

Methylbenzol; Tolu-Sol; Tolueen; Toluen;

Toluene; Tolueno; Toluol; Toluolo.

Chemical Formula: C6H5CH3

Contact Information:

Research and Production Enterprise “Zarya”, Ltd. Zavodskaya Street, 1g/36, Rubezhnoye, Lugansk reg., Ukraine, 93001 Phone: +380 (6453) 95085, 95026, 95035 Fax: +380 (6453) 95042, 95026, 95035

www.zaryachem.com

Section 2: Composition and Information on Ingredients

Composition:

Name % by Weight

Toluene wt, % min 99,2

Benzene wt, % max 0,02

Sulphur wt, % 0,25

Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Slightly hazardous in case of skin contact (permeator).

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not

classifiable for human.) by IARC.

MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to blood, kidneys, the

nervous system, liver, brain, central nervous system (CNS).

Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of

water for at least 15 minutes. Get medical attention.

Skin Contact:

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an

emollient. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean

shoes before reuse. Get medical attention.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek

immediate medical attention.

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Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give

oxygen. Get medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt

or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform

mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give

mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek medical

attention.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by

mouth to an unconscious person. If large quantities of this material are swallowed, call a physician

immediately. Loosen tight clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 552°C

Flammable Limits: LOWER: 1.17% UPPER: 7.1%

Flash Points: 4.4°C

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:

Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of

explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions:

Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE:

Use water spray or fog.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards:

Toluene forms explosive reaction with 1,3-dichloro-5,5-dimethyl-2,4-imidazolididione; dinitrogen

tetraoxide; concentrated nitric acid, sulfuric acid + nitric acid; N2O4; AgClO4; BrF3; Uranium

hexafluoride; sulfur dichloride. Also forms an explosive mixture with tetranitromethane.

Section 6: Accidental Release Measures

Small Spill:

Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:

Toxic flammable liquid, insoluble or very slightly soluble in water. Keep away from heat. Keep

away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-

combustible material. Do not get water inside container. Do not touch spilled material. Prevent entry

into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful

that the product is not present at a concentration level above TLV. Check TLV on the MSDS and

with local authorities.

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Section 7: Handling and Storage

Precautions:

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing

material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In

case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice

immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from

incompatibles such as oxidizing agents.

Storage:

Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep

container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark

or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of

vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers

are proximal to the work-station location.

Personal Protection:

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or

equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus

should be used to avoid inhalation of the product. Suggested protective clothing might not be

sufficient; consult a specialist BEFORE handling this product.

Exposure Limits:

TWA: 200 STEL: 500 CEIL: 300 (ppm) from OSHA (PEL) [United States] TWA: 50 (ppm) from

ACGIH (TLV) [United States] SKIN TWA: 100 STEL: 150 from NIOSH [United States] TWA: 375

STEL: 560 (mg/m3) from NIOSH [United States] Consult local authorities for acceptable exposure

limits.


Physical State: Liquid

Appearance: colorless

Odor: sweetish odor - pleasant odor - benzene-like

Molecular Weight: 92.14 g/mol

Boiling Point: 110.62 °C

Freezing/Melting Point:-94,99 °C

Vapor Pressure: 36.7 mm Hg @ 30 deg C

Vapor Density: 3.1 (Air=1)

Density (20 ºC): 0,8669 g/cm3

Volatility: Moderate

Water/Oil Dist. Coeff.: The product is more soluble in oil; log(oil/water) = 2.69

Solubility: Soluble in diethyl ether, acetone. Practically insoluble in cold water. Soluble in ethanol,

benzene, chloroform, glacial acetic acid, carbon disulfide.

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Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Heat, ignition sources (flames, sparks, static), incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:

Incompatible with strong oxidizers, silver perchlorate, sodium difluoride, Tetranitromethane,

Uranium Hexafluoride. Frozen Bromine Trifluoride reacts violently with Toluene at -80 deg. C.

Reacts chemically with nitrogen oxides, or halogens to form nitrotoluene, nitrobenzene, and

nitrophenol and halogenated products, respectively.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:

Acute oral toxicity (LD50): 7530 mg/kg [Rat]. Acute dermal toxicity (LD50): 12400 mg/kg

[Rabbit]. Acute toxicity of the vapor (LC50): 440 24 hours [Mouse].

Chronic Effects on Humans:

CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not

classifiable for human.) by IARC.

May cause damage to the following organs: blood, kidneys, the nervous system, liver, brain,

central nervous system (CNS).

Other Toxic Effects on Humans:

Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case

of skin contact (permeator).

Special Remarks on Toxicity to Animals:

Lowest Published Lethal Dose: LDL [Human] - Route: Oral; Dose: 50 mg/kg LCL [Rabbit] -

Route: Inhalation; Dose: 55000 ppm/40min

Special Remarks on Chronic Effects on Humans:

Detected in maternal milk in human. Passes through the placental barrier in human. Embryotoxic

and/or foetotoxic in animal.

May cause adverse reproductive effects and birth defects (teratogenic). May affect genetic material

(mutagenic)

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects: Skin: Causes mild to moderate skin irritation. It can be absorbed to

some extent through the skin. Eyes: Causes mild to moderate eye irritation with a burning

sensation. Splash contact with eyes also causes conjunctivitis, blepharospasm, corneal edema,

corneal abraisons. This usually resolves in 2 days. Inhalation: Inhalation of vapor may cause

respiratory tract irritation causing coughing and wheezing, and nasal discharge. Inhalation of high

concentrations may affect behavior and cause central nervous system effects characterized by

nausea, headache, dizziness, tremors, restlessness, lightheadedness, exhilaration, memory loss,

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insomnia, impaired reaction time, drowsiness, ataxia, hallucinations, somnolence, muscle

contraction or spasticity, unconsciousness and coma. Inhalation of high concentration of vapor may

also affect the cardiovascular system (rapid heart beat, heart palpitations, increased or decreased

blood pressure, dysrhythmia), respiration (acute pulmonary edema, respiratory depression, apnea,

asphyxia), cause vision disturbances and dilated pupils, and cause loss of appetite. Ingestion:

Aspiration hazard. Aspiration of Toluene into the lungs may cause chemical pneumonitis. May

cause irritation of the digestive tract with nausea, vomiting, pain. May have effects similar to that

of acute inhalation. Chronic Potential Health Effects: Inhalation and Ingestion: Prolonged or

repeated exposure via inhalation may cause central nervous system and cardiovascular symptoms

similar to that of acute inhalation and ingestion as well liver damage/failure, kidney damage/failure

(with hematuria, proteinuria, oliguria, renal tubular acidosis), brain damage, weight loss, blood

(pigmented or nucleated red blood cells, changes in white blood cell count), bone marrow changes,

electrolyte imbalances (Hypokalemia, Hypophostatemia), severe, muscle weakness and

Rhabdomyolysis. Skin: Repeated or prolonged skin contact may cause defatting dermatitis.

Section 12: Ecological Information

Ecotoxicity:

Ecotoxicity in water (LC50): 313 mg/l 48 hours [Daphnia (daphnia)]. 17 mg/l 24 hours [Fish (Blue

Gill)]. 13 mg/l 96 hours [Fish (Blue Gill)]. 56 mg/l 24 hours [Fish (Fathead minnow)]. 34 mg/l 96

hours [Fish (Fathead minnow)]. 56.8 ppm any hours [Fish (Goldfish)].

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation

products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the

product itself.

Special Remarks on the Products of Biodegradation: Not available.


Waste Disposal:

Waste must be disposed of in accordance with state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 3: Flammable liquid.

Identification: : Toluene UNNA: 1294 PG: II

Special Provisions for Transport: Not available.

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References: Not available.

Other Special Considerations: Not available.

Created: 15/08/2011 11:00 AM

Last Updated: 14/07/2012 12:00 PM

Futher Information: The information contained in this Material Safety Data Sheet is based upon

available data and believed to be correct; however, as such has been obtained from various

sources, including the manufacturer and independent laboratories, it is given without warranty or

representation that it is complete, accurate, and can be relied upon. Research and Production

Enterpise “Zarya”, Ltd. has not attempted to conceal in any manner the deleterious aspects of

the product listed herein, but makes no warranty as to such. Further, Research and Production

Enterpise “Zarya”, Ltd. cannot anticipate nor control the many situations in which the product or

this information may be used; there is no guarantee that the health and safety precautions suggested

will be proper under all conditions. It is the sole responsibility of each user of the product to

determine and comply with the requirements of all applicable laws and regulations regarding its

use. This information is given solely for the purposes of safety to persons and property. Any other

use of this information is expressly prohibited.

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Annexure-V Undertaking from Consultant

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Annexure-VI Undertaking from Project Proponent

UNDERTAKING

I], Nishant Patel, Director of Reynish Pharmachem Pvt. Ltd. to be located a t

urvey. no.: 504, 505 and 507, Village: Dabhasa, Ta.: Padra, District:

adodara , Gujarat, do hereby undertake as under:

1 I hereby give an undertaking that, the data & information given in the

application and enclosures are true and we will be responsible for any

1 factual discrepancy in EIA report. The ownership of EIA report remain

with us.

I

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I undertake that, content including information & data of EIA report is

own by us and data or information are not taken from any other EIA

report.

I hereby declare that, what is stated herein above is true to the best of

my knowledge and same I believed to be true.

For Reynish Pharmachem I F y t . - Ltd

= i P*P* D;.rietor

(Stamp & Signature here)

Date: 12.02.2019

Place: Vadodara

For, Reynish Pharmachem Pvt. Ltd.

Nishant Patel

Director

~ W C A N T J. PATEL NOTARY

-.DIST.VADOMM (GOVT. OF INDIA)

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Annexure-VII Copy of Terms of Reference (TOR)

No.IA-J-11011/194/2018-IA-II(I)

Goverment of India

Minister of Enviroment,Forest and Climate Change

Impact Assessment Division

***

Indira Paryavaran Bhavan,

Vayu Wing,3rd Floor,Aliganj,

Jor Bagh Road,New Delhi-110003

13 Jul 2018

To,

M/s REYNISH PHARMACHEM PVT. LTD.

2, Capriana Appartment, 27 Rajnagar Soc., Near Akota Stadium, Vadodara,

Vadodara-391150

Gujarat

Tel.No.079-26583077; Email:[email protected]

Sir/Madam,

This has reference to the proposal submitted in the Ministry of Environment, Forest

and Climate Change to prescribe the Terms of Reference (TOR) for undertaking detailed EIA

study for the purpose of obtaining Environmental Clearance in accordance with the provisions of

the EIA Notification, 2006. For this purpose, the proponent had submitted online information in the

prescribed format (Form-1 ) along with a Pre-feasibility Report. The details of the proposal are

given below:

1. Proposal No.: IA/GJ/IND2/75368/2018

2. Name of the Proposal: REYNISH PHARMACHEM PVT. LTD.

3. Category of the Proposal: Industrial Projects - 2

4. Project/Activity applied for: 5(f) Synthetic organic chemicals industry (dyes

& dye intermediates; bulk

5. Date of submission for TOR: 11 Jun 2018

In this regard, under the provisions of the EIA Notification 2006 as amended, the Standard TOR

for the purpose of preparing environment impact assessment report and environment

management plan for obtaining prior environment clearance is prescribed with public consultation

as follows:

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STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FOR PROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE

5(f):STANDARD TERMS OF REFERENCE FOR CONDUCTINGENVIRONMENT IMPACT ASSESSMENT STUDY FOR SYNTHETICORGANIC CHEMICALS INDUSTRY (DYES & DYEINTERMEDIATES; BULK DRUGS AND INTERMEDIATESEXCLUDING DRUG FORMULATIONS; SYNTHETIC RUBBERS;BASIC ORGANIC CHEMICALS, OTHER SYNTHETIC ORGANICCHEMICALS AND CHEMICAL INTERMEDIATES) ANDINFORMATION TO BE INCLUDED IN EIA/EMP REPORT

A. STANDARD TERMS OF REFERENCE

1) Executive Summary

2) Introduction

i. Details of the EIA Consultant including NABET accreditation

ii. Information about the project proponent

iii. Importance and benefits of the project

3) Project Description

i. Cost of project and time of completion.

ii. Products with capacities for the proposed project.

iii. If expansion project, details of existing products with capacities and whether adequate landis available for expansion, reference of earlier EC if any.

iv. List of raw materials required and their source along with mode of transportation.

v. Other chemicals and materials required with quantities and storage capacities

vi. Details of Emission, effluents, hazardous waste generation and their management.

vii. Requirement of water, power, with source of supply, status of approval, water balance diagram,man-power requirement (regular and contract)

viii. Process description along with major equipments and machineries, process flow sheet(quantative) from raw material to products to be provided

ix. Hazard identification and details of proposed safety systems.

x. Expansion/modernization proposals:

c. Copy of all the Environmental Clearance(s) including Amendments thereto obtained forthe project from MOEF/SEIAA shall be attached as an Annexure. A certified copy of thelatest Monitoring Report of the Regional Office of the Ministry of Environment and Forestsas per circular dated 30th May, 2012 on the status of compliance of conditions stipulatedin all the existing environmental clearances including Amendments shall be provided. In

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STANDARD TERMS OF REFERENCE (TOR) FOR EIA/EMP REPORT FORPROJECTS/ACTIVITIES REQUIRING ENVIRONMENT CLEARANCE

addition, status of compliance of Consent to Operate for the ongoing Iexisting operationof the project from SPCB shall be attached with the EIA-EMP report.

d. In case the existing project has not obtained environmental clearance, reasons for nottaking EC under the provisions of the EIA Notification 1994 and/or EIA Notification2006 shall be provided. Copies of Consent to Establish/No Objection Certificate andConsent to Operate (in case of units operating prior to EIA Notification 2006, CTE andCTO of FY 2005-2006) obtained from the SPCB shall be submitted. Further, compliancereport to the conditions of consents from the SPCB shall be submitted.

4) Site Details

i. Location of the project site covering village, Taluka/Tehsil, District and State, Justificationfor selecting the site, whether other sites were considered.

ii. A toposheet of the study area of radius of 10km and site location on 1:50,000/1:25,000 scaleon an A3/A2 sheet. (including all eco-sensitive areas and environmentally sensitive places)

iii. Details w.r.t. option analysis for selection of site

iv. Co-ordinates (lat-long) of all four corners of the site.

v. Google map-Earth downloaded of the project site.

vi. Layout maps indicating existing unit as well as proposed unit indicating storage area, plantarea, greenbelt area, utilities etc. If located within an Industrial area/Estate/Complex, layoutof Industrial Area indicating location of unit within the Industrial area/Estate.

vii. Photographs of the proposed and existing (if applicable) plant site. If existing, showphotographs of plantation/greenbelt, in particular.

viii. Landuse break-up of total land of the project site (identified and acquired), government/private - agricultural, forest, wasteland, water bodies, settlements, etc shall be included. (notrequired for industrial area)

ix. A list of major industries with name and type within study area (10km radius) shall beincorporated. Land use details of the study area

x. Geological features and Geo-hydrological status of the study area shall be included.

xi. Details of Drainage of the project upto 5km radius of study area. If the site is within 1 kmradius of any major river, peak and lean season river discharge as well as flood occurrencefrequency based on peak rainfall data of the past 30 years. Details of Flood Level of theproject site and maximum Flood Level of the river shall also be provided. (mega green fieldprojects)

xii. Status of acquisition of land. If acquisition is not complete, stage of the acquisition processand expected time of complete possession of the land.

xiii. R&R details in respect of land in line with state Government policy.

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5) Forest and wildlife related issues (if applicable):

i. Permission and approval for the use of forest land (forestry clearance), if any, andrecommendations of the State Forest Department. (if applicable)

ii. Landuse map based on High resolution satellite imagery (GPS) of the proposed site delineatingthe forestland (in case of projects involving forest land more than 40 ha)

iii. Status of Application submitted for obtaining the stage I forestry clearance along with lateststatus shall be submitted.

iv. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere Reserves,Migratory Corridors of Wild Animals, the project proponent shall submit the map dulyauthenticated by Chief Wildlife Warden showing these features vis-à-vis the project locationand the recommendations or comments of the Chief Wildlife Warden-thereon.

v. Wildlife Conservation Plan duly authenticated by the Chief Wildlife Warden of the StateGovernment for conservation of Schedule I fauna, if any exists in the study area.

vi. Copy of application submitted for clearance under the Wildlife (Protection) Act, 1972, to theStanding Committee of the National Board for Wildlife.

6) Environmental Status

i. Determination of atmospheric inversion level at the project site and site-specific micro-meteorological data using temperature, relative humidity, hourly wind speed and directionand rainfall.

ii. AAQ data (except monsoon) at 8 locations for PM10, PM2.5, SO2, NOX, CO and otherparameters relevant to the project shall be collected. The monitoring stations shall be basedCPCB guidelines and take into account the pre-dominant wind direction, population zoneand sensitive receptors including reserved forests.

iii. Raw data of all AAQ measurement for 12 weeks of all stations as per frequency given in theNAQQM Notification of Nov. 2009 along with - min., max., average and 98% values foreach of the AAQ parameters from data of all AAQ stations should be provided as an annexureto the EIA Report.

iv. Surface water quality of nearby River (100m upstream and downstream of discharge point)and other surface drains at eight locations as per CPCB/MoEF&CC guidelines.

v. Whether the site falls near to polluted stretch of river identified by the CPCB/MoEF&CC, ifyes give details.

vi. Ground water monitoring at minimum at 8 locations shall be included.

vii. Noise levels monitoring at 8 locations within the study area.

viii. Soil Characteristic as per CPCB guidelines.

ix. Traffic study of the area, type of vehicles, frequency of vehicles for transportation of materials,additional traffic due to proposed project, parking arrangement etc.

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x. Detailed description of flora and fauna (terrestrial and aquatic) existing in the study areashall be given with special reference to rare, endemic and endangered species. If Schedule-I fauna are found within the study area, a Wildlife Conservation Plan shall be prepared andfurnished.

xi. Socio-economic status of the study area.

7) Impact and Environment Management Plan

i. Assessment of ground level concentration of pollutants from the stack emission based onsite-specific meteorological features. In case the project is located on a hilly terrain, theAQIP Modelling shall be done using inputs of the specific terrain characteristics fordetermining the potential impacts of the project on the AAQ. Cumulative impact of all sourcesof emissions (including transportation) on the AAQ of the area shall be assessed. Details ofthe model used and the input data used for modelling shall also be provided. The air qualitycontours shall be plotted on a location map showing the location of project site, habitationnearby, sensitive receptors, if any.

ii. Water Quality modelling - in case of discharge in water body

iii. Impact of the transport of the raw materials and end products on the surrounding environmenthall be assessed and provided. In this regard, options for transport of raw materials andfinished products and wastes (large quantities) by rail or rail-cum road transport or conveyor-cum-rail transport shall be examined.

iv. A note on treatment of wastewater from different plant operations, extent recycled and reusedfor different purposes shall be included. Complete scheme of effluent treatment. Characteristicsof untreated and treated effluent to meet the prescribed standards of discharge under E(P)Rules.

v. Details of stack emission and action plan for control of emissions to meet standards.

vi. Measures for fugitive emission control

vii. Details of hazardous waste generation and their storage, utilization and management. Copiesof MOU regarding utilization of solid and hazardous waste in cement plant shall also beincluded. EMP shall include the concept of waste-minimization, recycle/reuse/recovertechniques, Energy conservation, and natural resource conservation.

viii. Proper utilization of fly ash shall be ensured as per Fly Ash Notification, 2009. A detailedplan of action shall be provided.

ix. Action plan for the green belt development plan in 33 % area i.e. land with not less than1,500 trees per ha. Giving details of species, width of plantation, planning schedule etc. shallbe included. The green belt shall be around the project boundary and a scheme for greeningof the roads used for the project shall also be incorporated.

x. Action plan for rainwater harvesting measures at plant site shall be submitted to harvestrainwater from the roof tops and storm water drains to recharge the ground water and also to

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use for the various activities at the project site to conserve fresh water and reduce the waterrequirement from other sources.

xi. Total capital cost and recurring cost/annum for environmental pollution control measuresshall be included.

xii. Action plan for post-project environmental monitoring shall be submitted.

xiii. Onsite and Offsite Disaster (natural and Man-made) Preparedness and Emergency ManagementPlan including Risk Assessment and damage control. Disaster management plan should belinked with District Disaster Management Plan.

8) Occupational health

i. Plan and fund allocation to ensure the occupational health & safety of all contract and casualworkers

ii. Details of exposure specific health status evaluation of worker. If the workers' health is beingevaluated by pre designed format, chest x rays, Audiometry, Spirometry, Vision testing (Far& Near vision, colour vision and any other ocular defect) ECG, during pre placement andperiodical examinations give the details of the same. Details regarding last month analyzeddata of above mentioned parameters as per age, sex, duration of exposure and departmentwise.

iii. Details of existing Occupational & Safety Hazards. What are the exposure levels of hazardsand whether they are within Permissible Exposure level (PEL). If these are not within PEL,what measures the company has adopted to keep them within PEL so that health of the workerscan be preserved,

iv. Annual report of heath status of workers with special reference to Occupational Health andSafety.

9) Corporate Environment Policy

i. Does the company have a well laid down Environment Policy approved by its Board ofDirectors? If so, it may be detailed in the EIA report.

ii. Does the Environment Policy prescribe for standard operating process / procedures to bringinto focus any infringement / deviation / violation of the environmental or forest norms /conditions? If so, it may be detailed in the EIA.

iii. What is the hierarchical system or Administrative order of the company to deal with theenvironmental issues and for ensuring compliance with the environmental clearanceconditions? Details of this system may be given.

iv. Does the company have system of reporting of non compliances / violations of environmentalnorms to the Board of Directors of the company and / or shareholders or stakeholders atlarge? This reporting mechanism shall be detailed in the EIA report

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10) Details regarding infrastructure facilities such as sanitation, fuel, restroom etc. to be provided to thelabour force during construction as well as to the casual workers including truck drivers duringoperation phase.

11) Enterprise Social Commitment (ESC)

i. Adequate funds (at least 2.5 % of the project cost) shall be earmarked towards the EnterpriseSocial Commitment based on Public Hearing issues and item-wise details along with timebound action plan shall be included. Socio-economic development activities need to beelaborated upon.

12) Any litigation pending against the project and/or any direction/order passed by any Court of Lawagainst the project, if so, details thereof shall also be included. Has the unit received any noticeunder the Section 5 of Environment (Protection) Act, 1986 or relevant Sections of Air and WaterActs? If so, details thereof and compliance/ATR to the notice(s) and present status of the case.

13) 'A tabular chart with index for point wise compliance of above TOR.

B. SPECIFIC TERMS OF REFERENCEFOREIASTUDIES FOR SYNTHETICORGANIC CHEMICALS INDUSTRY (DYES & DYE INTERMEDIATES;BULK DRUGS AND INTERMEDIATES EXCLUDING DRUGFORMULATIONS; SYNTHETIC RUBBERS; BASIC ORGANICCHEMICALS, OTHER SYNTHETIC ORGANIC CHEMICALS ANDCHEMICAL INTERMEDIATES)

1. Detailsonsolvents to be used,measuresfor solventrecovery and for emissions control.

2. Details of process emissions from the proposed unit and its arrangement to control.

3. Ambient air quality data should include VOC, otherprocess-specificpollutants* like NH3*, chlorine*,HCl*, HBr*, H2S*, HF*,etc.,(*-asapplicable)

4. Work zone monitoring arrangements for hazardous chemicals.

5. Detailed effluent treatment scheme including ssegregation of effluent streams for units adopting'Zero' liquid discharge.

6. Action plan for odour control to be submitted.

7. A copy of the Memorandum of Understanding signed with cement manufacturers indicating clearlythat they co-process organic solid/hazardous waste generated.

8. Authorization/Membership for the disposal of liquid effluent in CETP and solid/hazardous waste inTSDF, if any.

9. Action plan for utilization of MEE/dryers salts.

10. Material Safety Data Sheet for all the Chemicals are being used/will be used.

11. Authorization/Membership for the disposal of solid/hazardous waste in TSDF.

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12. Details of incinerator if to be installed.

13. Risk assessment for storage and handling of hazardous chemicals/solvents. Action plan for handling& safety system to be incorporated.

14. Arrangements for ensuring health and safety of workers engaged in handling of toxic materials.

***

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Annexure-VIII Minutes of Public Hearing

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Annexure-IX Hourly Meteorological data

Hourly Meteorological data

Year Date Time Temp.

(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 01.10.18 0:00 31.0 80.0 180 9.7 0

2018 01.10.18 1:00 32.6 76.0 171 10.2 0

2018 01.10.18 2:00 34.1 72.0 162 10.7 0

2018 01.10.18 3:00 28.0 80.0 45 0.0 0

2018 01.10.18 4:00 29.4 76.0 43 0.0 0

2018 01.10.18 5:00 30.8 72.0 41 0.0 0

2018 01.10.18 6:00 28.0 77.0 90 3.9 0

2018 01.10.18 7:00 29.4 73.2 86 4.1 0

2018 01.10.18 8:00 30.8 69.3 81 4.3 0

2018 01.10.18 9:00 31.0 70.0 113 15.5 0

2018 01.10.18 10:00 32.6 66.5 107 16.3 0

2018 01.10.18 11:00 34.1 63.0 101 17.1 0

2018 01.10.18 12:00 33.0 59.0 113 21.4 0

2018 01.10.18 13:00 34.7 62.0 118 22.5 0

2018 01.10.18 14:00 36.3 64.9 124 23.5 0

2018 01.10.18 15:00 36.0 51.0 113 19.4 0

2018 01.10.18 16:00 34.2 53.6 118 18.4 0

2018 01.10.18 17:00 32.4 56.1 124 17.5 0

2018 01.10.18 18:00 34.0 58.0 90 15.5 0

2018 01.10.18 19:00 32.3 60.9 95 14.7 0

2018 01.10.18 20:00 30.6 63.8 99 14.0 0

2018 01.10.18 21:00 31.0 65.0 68 11.7 0

2018 01.10.18 22:00 29.5 68.3 71 11.1 0

2018 01.10.18 23:00 27.9 71.5 74 10.5 0

2018 02.10.18 0:00 29.0 72.0 45 3.9 0

2018 02.10.18 1:00 30.5 68.4 43 4.1 0

2018 02.10.18 2:00 31.9 64.8 41 4.3 0

2018 02.10.18 3:00 27.0 80.0 180 9.7 0

2018 02.10.18 4:00 28.4 76.0 171 10.2 0

2018 02.10.18 5:00 29.7 72.0 162 10.7 0

2018 02.10.18 6:00 29.0 78.0 180 9.7 0

2018 02.10.18 7:00 30.5 74.1 171 10.2 0

2018 02.10.18 8:00 31.9 70.2 162 10.7 0

2018 02.10.18 9:00 33.0 64.0 68 9.7 0

2018 02.10.18 10:00 34.7 67.2 64 10.2 0

2018 02.10.18 11:00 36.3 70.4 61 10.7 0

2018 02.10.18 12:00 37.0 50.0 158 3.9 0

2018 02.10.18 13:00 35.2 52.5 165 4.1 0

2018 02.10.18 14:00 33.3 55.0 173 4.3 0

2018 02.10.18 15:00 38.0 46.0 68 0.0 0

2018 02.10.18 16:00 36.1 48.3 71 0.0 0

2018 02.10.18 17:00 34.2 50.6 74 0.0 0

2018 02.10.18 18:00 36.0 53.0 248 0.0 0

2018 02.10.18 19:00 34.2 55.7 260 0.0 0

2018 02.10.18 20:00 32.4 58.3 272 0.0 0

2018 02.10.18 21:00 32.0 66.0 360 13.7 0

2018 02.10.18 22:00 33.6 62.7 378 13.0 0

A-153


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 02.10.18 23:00 35.2 59.4 396 12.3 0

2018 03.10.18 0:00 30.0 76.0 360 13.7 0

2018 03.10.18 1:00 31.5 72.2 342 14.4 0

2018 03.10.18 2:00 33.0 68.4 324 15.1 0

2018 03.10.18 3:00 29.0 80.0 180 9.7 0

2018 03.10.18 4:00 30.5 76.0 171 10.2 0

2018 03.10.18 5:00 31.9 72.0 162 10.7 0

2018 03.10.18 6:00 30.0 79.0 180 9.7 0

2018 03.10.18 7:00 31.5 83.0 171 10.2 0

2018 03.10.18 8:00 33.0 86.9 162 10.7 0

2018 03.10.18 9:00 34.0 67.0 68 3.9 0

2018 03.10.18 10:00 32.3 70.4 64 4.1 0

2018 03.10.18 11:00 30.6 73.7 61 4.3 0

2018 03.10.18 12:00 37.0 51.0 135 0.0 0

2018 03.10.18 13:00 35.2 53.6 142 0.0 0

2018 03.10.18 14:00 33.3 56.1 149 0.0 0

2018 03.10.18 15:00 38.0 49.0 135 0.0 0

2018 03.10.18 16:00 36.1 51.5 142 0.0 0

2018 03.10.18 17:00 34.2 53.9 149 0.0 0

2018 03.10.18 18:00 36.0 62.0 45 13.7 0

2018 03.10.18 19:00 37.8 58.9 47 13.0 0

2018 03.10.18 20:00 39.6 55.8 50 12.3 0

2018 03.10.18 21:00 32.0 76.0 45 13.7 0

2018 03.10.18 22:00 33.6 72.2 47 13.0 0

2018 03.10.18 23:00 35.2 68.4 50 12.3 0

2018 04.10.18 0:00 30.0 77.0 45 11.7 0

2018 04.10.18 1:00 31.5 73.2 43 12.3 0

2018 04.10.18 2:00 33.0 69.3 41 12.9 0

2018 04.10.18 3:00 29.0 77.0 45 9.7 0

2018 04.10.18 4:00 30.5 73.2 43 10.2 0

2018 04.10.18 5:00 31.9 69.3 41 10.7 0

2018 04.10.18 6:00 30.0 79.0 360 11.7 0

2018 04.10.18 7:00 28.5 83.0 342 12.3 0

2018 04.10.18 8:00 27.0 86.9 324 12.9 0

2018 04.10.18 9:00 32.0 73.0 360 11.7 0

2018 04.10.18 10:00 30.4 76.7 342 12.3 0

2018 04.10.18 11:00 28.8 80.3 324 12.9 0

2018 04.10.18 12:00 35.0 61.0 45 3.9 0

2018 04.10.18 13:00 33.3 64.1 47 4.1 0

2018 04.10.18 14:00 31.5 67.1 50 4.3 0

2018 04.10.18 15:00 35.0 60.0 45 9.7 0

2018 04.10.18 16:00 36.8 63.0 47 9.2 0

2018 04.10.18 17:00 38.5 66.0 50 8.7 0

2018 04.10.18 18:00 32.0 71.0 45 11.7 0

2018 04.10.18 19:00 33.6 67.5 47 11.1 0

2018 04.10.18 20:00 35.2 63.9 50 10.5 0

2018 04.10.18 21:00 30.0 78.0 180 9.7 0

2018 04.10.18 22:00 31.5 74.1 189 9.2 0

2018 04.10.18 23:00 33.0 70.2 198 8.7 0

A-154


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 05.10.18 0:00 28.0 82.0 180 9.7 0

2018 05.10.18 1:00 29.4 77.9 171 10.2 0

2018 05.10.18 2:00 30.8 73.8 162 10.7 0

2018 05.10.18 3:00 27.0 84.0 338 13.7 0

2018 05.10.18 4:00 25.7 88.2 321 14.4 0

2018 05.10.18 5:00 24.3 92.4 304 15.1 0

2018 05.10.18 6:00 27.0 84.0 338 15.5 0

2018 05.10.18 7:00 25.7 88.2 321 16.3 0

2018 05.10.18 8:00 24.3 92.4 304 17.1 0

2018 05.10.18 9:00 31.0 71.0 338 17.5 0

2018 05.10.18 10:00 29.5 74.6 321 18.4 0

2018 05.10.18 11:00 27.9 78.1 304 19.3 0

2018 05.10.18 12:00 35.0 55.0 360 19.4 0

2018 05.10.18 13:00 36.8 57.8 378 20.4 0

2018 05.10.18 14:00 38.5 60.5 396 21.3 0

2018 05.10.18 15:00 35.0 57.0 180 21.4 0

2018 05.10.18 16:00 36.8 54.2 189 20.3 0

2018 05.10.18 17:00 38.5 51.3 198 19.3 0

2018 05.10.18 18:00 31.0 72.0 180 17.5 0

2018 05.10.18 19:00 32.6 68.4 189 16.6 0

2018 05.10.18 20:00 34.1 64.8 198 15.8 0

2018 05.10.18 21:00 28.0 83.0 360 11.7 0

2018 05.10.18 22:00 29.4 78.9 378 11.1 0

2018 05.10.18 23:00 30.8 74.7 396 10.5 0

2018 06.10.18 0:00 28.0 83.0 338 11.7 0

2018 06.10.18 1:00 26.6 87.2 321 12.3 0

2018 06.10.18 2:00 25.2 91.3 304 12.9 0

2018 06.10.18 3:00 28.0 81.0 360 3.9 0

2018 06.10.18 4:00 26.6 85.1 342 4.1 0

2018 06.10.18 5:00 25.2 89.1 324 4.3 0

2018 06.10.18 6:00 29.0 80.0 360 3.9 0

2018 06.10.18 7:00 27.6 84.0 342 4.1 0

2018 06.10.18 8:00 26.1 88.0 324 6.4 0

2018 06.10.18 9:00 33.0 68.0 360 11.7 0

2018 06.10.18 10:00 34.7 71.4 342 12.3 0

2018 06.10.18 11:00 36.3 74.8 324 12.9 0

2018 06.10.18 12:00 35.0 57.0 180 17.5 0

2018 06.10.18 13:00 36.8 54.2 189 18.4 0

2018 06.10.18 14:00 38.5 51.3 198 19.3 0

2018 06.10.18 15:00 34.0 60.0 45 21.4 0

2018 06.10.18 16:00 35.7 57.0 47 20.3 0

2018 06.10.18 17:00 37.4 54.0 50 19.3 0

2018 06.10.18 18:00 31.0 72.0 180 17.5 0

2018 06.10.18 19:00 32.6 68.4 189 16.6 0

2018 06.10.18 20:00 34.1 64.8 198 15.8 0

2018 06.10.18 21:00 28.0 80.0 360 17.5 0

2018 06.10.18 22:00 26.6 76.0 378 16.6 0

2018 06.10.18 23:00 25.2 72.0 297 15.8 0

2018 07.10.18 0:00 28.0 81.0 338 15.5 0

A-155


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 07.10.18 1:00 26.6 85.1 321 16.3 0

2018 07.10.18 2:00 25.2 89.1 304 17.1 0

2018 07.10.18 3:00 27.0 84.0 338 15.5 0

2018 07.10.18 4:00 25.7 88.2 321 16.3 0

2018 07.10.18 5:00 24.3 92.4 304 17.1 0

2018 07.10.18 6:00 28.0 84.0 338 17.5 0

2018 07.10.18 7:00 29.4 88.2 321 18.4 0

2018 07.10.18 8:00 30.8 92.4 304 19.3 0

2018 07.10.18 9:00 32.0 73.0 338 15.5 0

2018 07.10.18 10:00 33.6 76.7 321 16.3 0

2018 07.10.18 11:00 35.2 80.3 304 17.1 0

2018 07.10.18 12:00 35.0 59.0 270 9.7 0

2018 07.10.18 13:00 36.8 56.1 284 10.2 0

2018 07.10.18 14:00 38.5 53.1 297 10.7 0

2018 07.10.18 15:00 35.0 60.0 45 9.7 0

2018 07.10.18 16:00 36.8 57.0 47 9.2 0

2018 07.10.18 17:00 38.5 54.0 50 8.7 0

2018 07.10.18 18:00 32.0 73.0 45 11.7 0

2018 07.10.18 19:00 30.4 69.4 47 11.1 0

2018 07.10.18 20:00 28.8 65.7 50 10.5 0

2018 07.10.18 21:00 29.0 82.0 180 13.7 0

2018 07.10.18 22:00 27.6 86.1 189 13.0 0

2018 07.10.18 23:00 26.1 90.2 198 12.3 0

2018 08.10.18 0:00 28.0 84.0 270 13.7 0

2018 08.10.18 1:00 26.6 88.2 257 14.4 0

2018 08.10.18 2:00 25.2 92.4 243 15.1 0

2018 08.10.18 3:00 27.0 84.0 338 11.7 0

2018 08.10.18 4:00 28.4 88.2 321 12.3 0

2018 08.10.18 5:00 29.7 92.4 304 12.9 0

2018 08.10.18 6:00 28.0 84.0 270 11.7 0

2018 08.10.18 7:00 29.4 88.2 257 12.3 0

2018 08.10.18 8:00 30.8 92.4 243 12.9 0

2018 08.10.18 9:00 32.0 71.0 270 9.7 0

2018 08.10.18 10:00 33.6 67.5 257 10.2 0

2018 08.10.18 11:00 35.2 63.9 243 10.7 0

2018 08.10.18 12:00 36.0 53.0 338 0.0 0

2018 08.10.18 13:00 37.8 50.4 354 0.0 0

2018 08.10.18 14:00 39.6 47.7 371 0.0 0

2018 08.10.18 15:00 37.0 47.0 293 0.0 0

2018 08.10.18 16:00 35.2 44.7 307 0.0 0

2018 08.10.18 17:00 33.3 42.3 322 0.0 0

2018 08.10.18 18:00 34.0 61.0 270 9.7 0

2018 08.10.18 19:00 32.3 64.1 284 9.2 0

2018 08.10.18 20:00 30.6 67.1 297 8.7 0

2018 08.10.18 21:00 29.0 79.0 270 15.5 0

2018 08.10.18 22:00 27.6 83.0 284 14.7 0

2018 08.10.18 23:00 26.1 86.9 297 14.0 0

2018 09.10.18 0:00 29.0 82.0 270 13.7 0

2018 09.10.18 1:00 30.5 86.1 257 14.4 0

A-156


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 09.10.18 2:00 31.9 90.2 243 15.1 0

2018 09.10.18 3:00 28.0 84.0 270 13.7 0

2018 09.10.18 4:00 29.4 88.2 257 14.4 0

2018 09.10.18 5:00 30.8 92.4 243 15.1 0

2018 09.10.18 6:00 29.0 84.0 270 11.7 0

2018 09.10.18 7:00 30.5 79.8 257 12.3 0

2018 09.10.18 8:00 31.9 75.6 243 12.9 0

2018 09.10.18 9:00 34.0 68.0 45 11.7 0

2018 09.10.18 10:00 35.7 64.6 43 12.3 0

2018 09.10.18 11:00 37.4 61.2 41 12.9 0

2018 09.10.18 12:00 37.0 50.0 68 11.7 0

2018 09.10.18 13:00 35.2 47.5 71 12.3 0

2018 09.10.18 14:00 33.3 45.0 74 12.9 0

2018 09.10.18 15:00 38.0 49.0 68 13.7 0

2018 09.10.18 16:00 36.1 46.6 71 13.0 0

2018 09.10.18 17:00 34.2 44.1 74 12.3 0

2018 09.10.18 18:00 35.0 64.0 270 15.5 0

2018 09.10.18 19:00 33.3 67.2 284 14.7 0

2018 09.10.18 20:00 31.5 70.4 297 14.0 0

2018 09.10.18 21:00 31.0 80.0 270 15.5 0

2018 09.10.18 22:00 32.6 84.0 284 14.7 0

2018 09.10.18 23:00 34.1 88.0 297 14.0 0

2018 10.10.18 0:00 29.0 81.0 270 15.5 0

2018 10.10.18 1:00 30.5 85.1 257 16.3 0

2018 10.10.18 2:00 31.9 89.1 243 17.1 0

2018 10.10.18 3:00 29.0 83.0 270 9.7 0

2018 10.10.18 4:00 30.5 87.2 257 10.2 0

2018 10.10.18 5:00 31.9 91.3 243 10.7 0

2018 10.10.18 6:00 31.0 77.0 45 5.8 0

2018 10.10.18 7:00 32.6 73.2 257 6.1 0

2018 10.10.18 8:00 34.1 69.3 243 6.4 0

2018 10.10.18 9:00 35.0 60.0 68 9.7 0

2018 10.10.18 10:00 33.3 57.0 64 10.2 0

2018 10.10.18 11:00 31.5 54.0 61 10.7 0

2018 10.10.18 12:00 37.0 45.0 68 15.5 0

2018 10.10.18 13:00 35.2 42.8 71 16.3 0

2018 10.10.18 14:00 33.3 40.5 74 17.1 0

2018 10.10.18 15:00 37.0 46.0 270 17.5 0

2018 10.10.18 16:00 35.2 48.3 284 16.6 0

2018 10.10.18 17:00 33.3 50.6 297 15.8 0

2018 10.10.18 18:00 34.0 62.0 270 15.5 0

2018 10.10.18 19:00 35.7 65.1 284 14.7 0

2018 10.10.18 20:00 37.4 68.2 297 14.0 0

2018 10.10.18 21:00 29.0 77.0 270 17.5 0

2018 10.10.18 22:00 30.5 80.9 284 16.6 0

2018 10.10.18 23:00 31.9 84.7 297 15.8 0

2018 11.10.18 0:00 29.0 81.0 360 13.7 0

2018 11.10.18 1:00 30.5 85.1 342 14.4 0

2018 11.10.18 2:00 31.9 89.1 324 15.1 0

A-157


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 11.10.18 3:00 30.0 84.0 270 5.8 0

2018 11.10.18 4:00 31.5 79.8 257 6.1 0

2018 11.10.18 5:00 33.0 75.6 243 6.4 0

2018 11.10.18 6:00 30.0 81.0 68 0.0 0

2018 11.10.18 7:00 28.5 77.0 64 0.0 0

2018 11.10.18 8:00 27.0 72.9 61 0.0 0

2018 11.10.18 9:00 34.0 62.0 90 5.8 0

2018 11.10.18 10:00 32.3 58.9 86 6.1 0

2018 11.10.18 11:00 30.6 55.8 81 6.4 0

2018 11.10.18 12:00 37.0 45.0 90 11.7 0

2018 11.10.18 13:00 35.2 47.3 95 12.3 0

2018 11.10.18 14:00 33.3 49.5 99 12.9 0

2018 11.10.18 15:00 38.0 41.0 68 11.7 0

2018 11.10.18 16:00 39.9 43.1 71 11.1 0

2018 11.10.18 17:00 41.8 45.1 74 10.5 0

2018 11.10.18 18:00 37.0 52.0 270 11.7 0

2018 11.10.18 19:00 38.9 54.6 284 11.1 0

2018 11.10.18 20:00 40.7 57.2 297 10.5 0

2018 11.10.18 21:00 32.0 65.0 270 13.7 0

2018 11.10.18 22:00 33.6 68.3 284 13.0 0

2018 11.10.18 23:00 35.2 71.5 297 12.3 0

2018 12.10.18 0:00 28.0 77.0 360 11.7 0

2018 12.10.18 1:00 29.4 73.2 342 12.3 0

2018 12.10.18 2:00 30.8 69.3 324 12.9 0

2018 12.10.18 3:00 26.0 87.0 360 11.7 0

2018 12.10.18 4:00 24.7 82.7 342 12.3 0

2018 12.10.18 5:00 23.4 78.3 324 12.9 0

2018 12.10.18 6:00 28.0 84.0 270 5.8 0

2018 12.10.18 7:00 26.6 79.8 257 6.1 0

2018 12.10.18 8:00 25.2 75.6 243 6.4 0

2018 12.10.18 9:00 33.0 65.0 270 5.8 0

2018 12.10.18 10:00 31.4 61.8 257 6.1 0

2018 12.10.18 11:00 29.7 58.5 243 6.4 0

2018 12.10.18 12:00 36.0 46.0 68 9.7 0

2018 12.10.18 13:00 37.8 48.3 71 10.2 0

2018 12.10.18 14:00 39.6 50.6 74 10.7 0

2018 12.10.18 15:00 37.0 42.0 270 13.7 0

2018 12.10.18 16:00 38.9 44.1 284 13.0 0

2018 12.10.18 17:00 40.7 46.2 297 12.3 0

2018 12.10.18 18:00 35.0 55.0 270 11.7 0

2018 12.10.18 19:00 36.8 57.8 284 11.1 0

2018 12.10.18 20:00 38.5 60.5 297 10.5 0

2018 12.10.18 21:00 31.0 68.0 270 11.7 0

2018 12.10.18 22:00 32.6 71.4 284 11.1 0

2018 12.10.18 23:00 34.1 74.8 297 10.5 0

2018 13.10.18 0:00 28.0 76.0 360 13.7 0

2018 13.10.18 1:00 26.6 72.2 342 14.4 0

2018 13.10.18 2:00 25.2 68.4 324 15.1 0

2018 13.10.18 3:00 27.0 84.0 360 13.7 0

A-158


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 13.10.18 4:00 25.7 79.8 342 14.4 0

2018 13.10.18 5:00 24.3 75.6 324 15.1 0

2018 13.10.18 6:00 28.0 82.0 270 5.8 0

2018 13.10.18 7:00 26.6 77.9 257 6.1 0

2018 13.10.18 8:00 25.2 73.8 243 6.4 0

2018 13.10.18 9:00 33.0 64.0 68 0.0 0

2018 13.10.18 10:00 34.7 67.2 64 0.0 0

2018 13.10.18 11:00 36.3 70.4 61 0.0 0

2018 13.10.18 12:00 36.0 44.0 90 0.0 0

2018 13.10.18 13:00 37.8 46.2 95 0.0 0

2018 13.10.18 14:00 39.6 48.4 99 0.0 0

2018 13.10.18 15:00 37.0 40.0 68 0.0 0

2018 13.10.18 16:00 38.9 42.0 71 0.0 0

2018 13.10.18 17:00 40.7 44.0 74 0.0 0

2018 13.10.18 18:00 34.0 51.0 360 0.0 0

2018 13.10.18 19:00 35.7 53.6 378 0.0 0

2018 13.10.18 20:00 37.4 56.1 396 0.0 0

2018 13.10.18 21:00 31.0 58.0 270 5.8 0

2018 13.10.18 22:00 32.6 55.1 284 5.5 0

2018 13.10.18 23:00 34.1 52.2 297 5.2 0

2018 14.10.18 0:00 28.0 60.0 270 9.7 0

2018 14.10.18 1:00 26.6 57.0 257 10.2 0

2018 14.10.18 2:00 25.2 54.0 243 10.7 0

2018 14.10.18 3:00 27.0 65.0 68 9.7 0

2018 14.10.18 4:00 25.7 61.8 64 10.2 0

2018 14.10.18 5:00 24.3 58.5 61 10.7 0

2018 14.10.18 6:00 28.0 70.0 270 5.8 0

2018 14.10.18 7:00 26.6 73.5 257 6.1 0

2018 14.10.18 8:00 25.2 77.0 243 6.4 0

2018 14.10.18 9:00 33.0 54.0 203 0.0 0

2018 14.10.18 10:00 34.7 56.7 192 0.0 0

2018 14.10.18 11:00 36.3 59.4 182 0.0 0

2018 14.10.18 12:00 37.0 38.0 180 0.0 0

2018 14.10.18 13:00 38.9 39.9 189 0.0 0

2018 14.10.18 14:00 40.7 41.8 198 0.0 0

2018 14.10.18 15:00 37.0 36.0 270 5.8 0

2018 14.10.18 16:00 38.9 37.8 284 5.5 0

2018 14.10.18 17:00 40.7 39.6 297 5.2 0

2018 14.10.18 18:00 35.0 46.0 315 0.0 0

2018 14.10.18 19:00 36.8 43.7 331 0.0 0

2018 14.10.18 20:00 38.5 41.4 347 0.0 0

2018 14.10.18 21:00 32.0 52.0 270 0.0 0

2018 14.10.18 22:00 30.4 49.4 284 0.0 0

2018 14.10.18 23:00 28.8 46.8 297 0.0 0

2018 15.10.18 0:00 28.0 54.0 90 5.8 0

2018 15.10.18 1:00 26.6 51.3 86 6.1 0

2018 15.10.18 2:00 25.2 48.6 81 6.4 0

2018 15.10.18 3:00 27.0 62.0 90 0.0 0

2018 15.10.18 4:00 25.7 58.9 86 0.0 0

A-159


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 15.10.18 5:00 24.3 55.8 81 0.0 0

2018 15.10.18 6:00 28.0 59.0 315 0.0 0

2018 15.10.18 7:00 29.4 62.0 299 0.0 0

2018 15.10.18 8:00 30.8 64.9 284 0.0 0

2018 15.10.18 9:00 34.0 44.0 203 0.0 0

2018 15.10.18 10:00 35.7 46.2 192 0.0 0

2018 15.10.18 11:00 37.4 48.4 182 0.0 0

2018 15.10.18 12:00 37.0 34.0 248 0.0 0

2018 15.10.18 13:00 38.9 35.7 260 0.0 0

2018 15.10.18 14:00 40.7 37.4 272 0.0 0

2018 15.10.18 15:00 37.0 34.0 293 0.0 0

2018 15.10.18 16:00 38.9 35.7 307 0.0 0

2018 15.10.18 17:00 40.7 37.4 322 0.0 0

2018 15.10.18 18:00 36.0 44.0 360 0.0 0

2018 15.10.18 19:00 34.2 41.8 378 0.0 0

2018 15.10.18 20:00 32.4 39.6 396 0.0 0

2018 15.10.18 21:00 32.0 44.0 90 5.8 0

2018 15.10.18 22:00 30.4 41.8 95 5.5 0

2018 15.10.18 23:00 28.8 39.6 99 5.2 0

2018 16.10.18 0:00 29.0 42.0 360 5.8 0

2018 16.10.18 1:00 27.6 39.9 342 6.1 0

2018 16.10.18 2:00 26.1 37.8 324 8.5 0

2018 16.10.18 3:00 28.0 41.0 293 0.0 0

2018 16.10.18 4:00 29.4 43.1 278 0.0 0

2018 16.10.18 5:00 30.8 45.1 263 0.0 0

2018 16.10.18 6:00 29.0 41.0 158 0.0 0

2018 16.10.18 7:00 30.5 43.1 150 0.0 0

2018 16.10.18 8:00 31.9 45.1 142 0.0 0

2018 16.10.18 9:00 34.0 35.0 135 0.0 0

2018 16.10.18 10:00 35.7 36.8 128 0.0 0

2018 16.10.18 11:00 37.4 38.5 122 0.0 0

2018 16.10.18 12:00 38.0 28.0 68 0.0 0

2018 16.10.18 13:00 39.9 29.4 71 0.0 0

2018 16.10.18 14:00 41.8 30.8 74 0.0 0

2018 16.10.18 15:00 38.0 31.0 315 0.0 0

2018 16.10.18 16:00 36.1 29.5 331 0.0 0

2018 16.10.18 17:00 34.2 27.9 347 0.0 0

2018 16.10.18 18:00 36.0 41.0 270 0.0 0

2018 16.10.18 19:00 34.2 39.0 284 0.0 0

2018 16.10.18 20:00 32.4 36.9 297 0.0 0

2018 16.10.18 21:00 32.0 36.0 90 9.7 0

2018 16.10.18 22:00 30.4 34.2 95 9.2 0

2018 16.10.18 23:00 28.8 32.4 99 8.7 0

2018 17.10.18 0:00 29.0 37.0 113 9.7 0

2018 17.10.18 1:00 30.5 38.9 107 10.2 0

2018 17.10.18 2:00 31.9 40.7 101 10.7 0

2018 17.10.18 3:00 28.0 44.0 158 7.7 0

2018 17.10.18 4:00 29.4 46.2 150 8.1 0

2018 17.10.18 5:00 30.8 48.4 142 8.5 0

A-160


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 17.10.18 6:00 28.0 44.0 68 7.7 0

2018 17.10.18 7:00 29.4 46.2 64 8.1 0

2018 17.10.18 8:00 30.8 48.4 61 8.5 0

2018 17.10.18 9:00 34.0 38.0 203 7.7 0

2018 17.10.18 10:00 35.7 39.9 192 8.1 0

2018 17.10.18 11:00 37.4 41.8 182 8.5 0

2018 17.10.18 12:00 37.0 30.0 180 11.7 0

2018 17.10.18 13:00 35.2 28.5 189 12.3 0

2018 17.10.18 14:00 33.3 27.0 198 12.9 0

2018 17.10.18 15:00 38.0 30.0 180 9.7 0

2018 17.10.18 16:00 36.1 28.5 189 9.2 0

2018 17.10.18 17:00 34.2 27.0 198 8.7 0

2018 17.10.18 18:00 36.0 39.0 203 7.7 0

2018 17.10.18 19:00 34.2 37.1 213 7.3 0

2018 17.10.18 20:00 32.4 35.1 223 6.9 0

2018 17.10.18 21:00 34.0 43.0 293 0.0 0

2018 17.10.18 22:00 35.7 40.9 307 0.0 0

2018 17.10.18 23:00 37.4 38.7 322 0.0 0

2018 18.10.18 0:00 30.0 47.0 113 0.0 0

2018 18.10.18 1:00 31.5 49.4 107 0.0 0

2018 18.10.18 2:00 33.0 51.7 101 0.0 0

2018 18.10.18 3:00 27.0 46.0 270 9.7 0

2018 18.10.18 4:00 28.4 48.3 257 10.2 0

2018 18.10.18 5:00 29.7 50.6 243 10.7 0

2018 18.10.18 6:00 28.0 47.0 68 0.0 0

2018 18.10.18 7:00 29.4 49.4 64 0.0 0

2018 18.10.18 8:00 30.8 51.7 61 0.0 0

2018 18.10.18 9:00 34.0 36.0 338 0.0 0

2018 18.10.18 10:00 32.3 37.8 321 0.0 0

2018 18.10.18 11:00 30.6 39.6 304 0.0 0

2018 18.10.18 12:00 37.0 29.0 158 7.7 0

2018 18.10.18 13:00 35.2 27.6 165 8.1 0

2018 18.10.18 14:00 33.3 26.1 173 8.5 0

2018 18.10.18 15:00 37.0 31.0 135 7.7 0

2018 18.10.18 16:00 35.2 29.5 142 7.3 0

2018 18.10.18 17:00 33.3 27.9 149 6.9 0

2018 18.10.18 18:00 35.0 42.0 90 0.0 0

2018 18.10.18 19:00 36.8 39.9 95 0.0 0

2018 18.10.18 20:00 38.5 37.8 99 0.0 0

2018 18.10.18 21:00 31.0 44.0 68 0.0 0

2018 18.10.18 22:00 32.6 46.2 71 0.0 0

2018 18.10.18 23:00 34.1 48.4 74 0.0 0

2018 19.10.18 0:00 28.0 42.0 270 7.7 0

2018 19.10.18 1:00 29.4 44.1 257 8.1 0

2018 19.10.18 2:00 30.8 46.2 243 8.5 0

2018 19.10.18 3:00 26.0 42.0 315 7.7 0

2018 19.10.18 4:00 27.3 44.1 299 8.1 0

2018 19.10.18 5:00 28.6 46.2 284 8.5 0

2018 19.10.18 6:00 28.0 42.0 270 0.0 0.5

A-161


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 19.10.18 7:00 26.6 44.1 257 0.0 0.5

2018 19.10.18 8:00 25.2 46.2 243 0.0 0.5

2018 19.10.18 9:00 34.0 33.0 293 0.0 1.6

2018 19.10.18 10:00 32.3 31.4 278 0.0 1.6

2018 19.10.18 11:00 30.6 29.7 263 0.0 1.6

2018 19.10.18 12:00 36.0 28.0 158 9.7 1.1

2018 19.10.18 13:00 34.2 26.6 165 10.2 1.1

2018 19.10.18 14:00 32.4 25.2 173 10.7 1.1

2018 19.10.18 15:00 37.0 32.0 135 7.7 0

2018 19.10.18 16:00 38.9 30.4 142 7.3 0

2018 19.10.18 17:00 40.7 28.8 149 6.9 0

2018 19.10.18 18:00 36.0 44.0 113 0.0 0

2018 19.10.18 19:00 37.8 46.2 118 0.0 0

2018 19.10.18 20:00 39.6 48.4 124 0.0 0

2018 19.10.18 21:00 32.0 45.0 113 0.0 0

2018 19.10.18 22:00 33.6 47.3 118 0.0 0

2018 19.10.18 23:00 35.2 49.5 124 0.0 0

2018 20.10.18 0:00 29.0 45.0 158 0.0 0

2018 20.10.18 1:00 30.5 47.3 150 0.0 0

2018 20.10.18 2:00 31.9 49.5 142 0.0 0

2018 20.10.18 3:00 27.0 49.0 113 0.0 0

2018 20.10.18 4:00 25.7 51.5 107 0.0 0

2018 20.10.18 5:00 24.3 53.9 101 0.0 0

2018 20.10.18 6:00 28.0 49.0 270 0.0 0

2018 20.10.18 7:00 26.6 46.6 257 0.0 0

2018 20.10.18 8:00 25.2 44.1 243 0.0 0

2018 20.10.18 9:00 33.0 36.0 293 0.0 0

2018 20.10.18 10:00 31.4 34.2 278 0.0 0

2018 20.10.18 11:00 29.7 32.4 263 0.0 0

2018 20.10.18 12:00 36.0 28.0 203 7.7 0

2018 20.10.18 13:00 37.8 26.6 213 8.1 0

2018 20.10.18 14:00 39.6 25.2 223 8.5 0

2018 20.10.18 15:00 37.0 31.0 113 0.0 0

2018 20.10.18 16:00 38.9 29.5 118 0.0 0

2018 20.10.18 17:00 40.7 27.9 124 0.0 0

2018 20.10.18 18:00 35.0 42.0 270 0.0 0

2018 20.10.18 19:00 36.8 44.1 284 0.0 0

2018 20.10.18 20:00 38.5 46.2 297 0.0 0

2018 20.10.18 21:00 30.0 45.0 315 0.0 0

2018 20.10.18 22:00 31.5 47.3 331 0.0 0

2018 20.10.18 23:00 33.0 49.5 347 0.0 0

2018 21.10.18 0:00 27.0 50.0 270 0.0 0

2018 21.10.18 1:00 25.7 52.5 257 0.0 0

2018 21.10.18 2:00 24.3 55.0 243 0.0 0

2018 21.10.18 3:00 27.0 55.0 113 9.7 0

2018 21.10.18 4:00 25.7 57.8 107 10.2 0

2018 21.10.18 5:00 24.3 60.5 101 10.7 0

2018 21.10.18 6:00 28.0 54.0 158 7.7 0

2018 21.10.18 7:00 26.6 51.3 150 8.1 0

A-162


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 21.10.18 8:00 25.2 48.6 142 8.5 0

2018 21.10.18 9:00 33.0 45.0 68 7.7 0

2018 21.10.18 10:00 34.7 42.8 64 8.1 0

2018 21.10.18 11:00 36.3 40.5 243 8.5 0

2018 21.10.18 12:00 36.0 34.0 270 0.0 0

2018 21.10.18 13:00 37.8 32.3 284 0.0 0

2018 21.10.18 14:00 39.6 30.6 297 0.0 0

2018 21.10.18 15:00 36.0 34.0 90 0.0 0

2018 21.10.18 16:00 37.8 35.7 95 0.0 0

2018 21.10.18 17:00 39.6 37.4 99 0.0 0

2018 21.10.18 18:00 34.0 44.0 270 0.0 0

2018 21.10.18 19:00 35.7 46.2 284 0.0 0

2018 21.10.18 20:00 37.4 48.4 297 0.0 0

2018 21.10.18 21:00 31.0 49.0 270 0.0 0

2018 21.10.18 22:00 29.5 51.5 284 0.0 0

2018 21.10.18 23:00 27.9 53.9 297 0.0 0

2018 22.10.18 0:00 29.0 53.0 270 0.0 0

2018 22.10.18 1:00 27.6 55.7 257 0.0 0

2018 22.10.18 2:00 26.1 58.3 243 0.0 0

2018 22.10.18 3:00 26.0 58.0 113 7.7 0

2018 22.10.18 4:00 24.7 55.1 107 8.1 0

2018 22.10.18 5:00 23.4 52.2 101 8.5 0

2018 22.10.18 6:00 28.0 60.0 135 7.7 0

2018 22.10.18 7:00 29.4 57.0 128 8.1 0

2018 22.10.18 8:00 30.8 54.0 122 8.5 0

2018 22.10.18 9:00 34.0 50.0 158 0.0 0

2018 22.10.18 10:00 35.7 47.5 150 0.0 0

2018 22.10.18 11:00 37.4 45.0 142 0.0 0

2018 22.10.18 12:00 37.0 36.0 135 0.0 0

2018 22.10.18 13:00 38.9 37.8 142 0.0 0

2018 22.10.18 14:00 40.7 39.6 149 0.0 0

2018 22.10.18 15:00 36.0 35.0 90 0.0 0

2018 22.10.18 16:00 37.8 36.8 95 0.0 0

2018 22.10.18 17:00 39.6 38.5 99 0.0 0

2018 22.10.18 18:00 34.0 45.0 270 0.0 0

2018 22.10.18 19:00 32.3 47.3 284 0.0 0

2018 22.10.18 20:00 30.6 49.5 297 0.0 0

2018 22.10.18 21:00 30.0 49.0 270 7.7 0

2018 22.10.18 22:00 28.5 51.5 284 7.3 0

2018 22.10.18 23:00 27.0 53.9 297 6.9 0

2018 23.10.18 0:00 27.0 57.0 270 7.7 0

2018 23.10.18 1:00 25.7 54.2 257 8.1 0

2018 23.10.18 2:00 24.3 51.3 243 8.5 0

2018 23.10.18 3:00 26.0 64.0 270 9.7 0

2018 23.10.18 4:00 27.3 60.8 257 10.2 0

2018 23.10.18 5:00 28.6 57.6 243 10.7 0

2018 23.10.18 6:00 27.0 66.0 113 7.7 0

2018 23.10.18 7:00 28.4 62.7 107 8.1 0

2018 23.10.18 8:00 29.7 59.4 101 8.5 0

A-163


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 23.10.18 9:00 32.0 53.0 135 9.7 0

2018 23.10.18 10:00 33.6 50.4 128 10.2 0

2018 23.10.18 11:00 35.2 47.7 122 10.7 0

2018 23.10.18 12:00 36.0 38.0 135 0.0 0

2018 23.10.18 13:00 37.8 39.9 142 0.0 0

2018 23.10.18 14:00 39.6 41.8 149 0.0 0

2018 23.10.18 15:00 36.0 36.0 90 0.0 0

2018 23.10.18 16:00 34.2 37.8 95 0.0 0

2018 23.10.18 17:00 32.4 39.6 99 0.0 0

2018 23.10.18 18:00 34.0 46.0 270 7.7 0

2018 23.10.18 19:00 32.3 48.3 284 7.3 0

2018 23.10.18 20:00 30.6 50.6 297 6.9 0

2018 23.10.18 21:00 32.0 51.0 270 9.7 0

2018 23.10.18 22:00 30.4 53.6 284 9.2 0

2018 23.10.18 23:00 28.8 56.1 297 8.7 0

2018 24.10.18 0:00 29.0 59.0 270 11.7 0

2018 24.10.18 1:00 30.5 56.1 257 12.3 0

2018 24.10.18 2:00 31.9 53.1 243 12.9 0

2018 24.10.18 3:00 26.0 67.0 270 11.7 0

2018 24.10.18 4:00 27.3 63.7 257 12.3 0

2018 24.10.18 5:00 28.6 60.3 243 12.9 0

2018 24.10.18 6:00 27.0 65.0 90 9.7 0

2018 24.10.18 7:00 28.4 61.8 86 10.2 0

2018 24.10.18 8:00 29.7 58.5 81 10.7 0

2018 24.10.18 9:00 31.0 54.0 135 9.7 0

2018 24.10.18 10:00 32.6 56.7 128 10.2 0

2018 24.10.18 11:00 34.1 59.4 122 10.7 0

2018 24.10.18 12:00 34.0 39.0 113 9.7 0

2018 24.10.18 13:00 32.3 41.0 118 10.2 0

2018 24.10.18 14:00 30.6 42.9 124 10.7 0

2018 24.10.18 15:00 35.0 36.0 270 9.7 0

2018 24.10.18 16:00 33.3 37.8 284 9.2 0

2018 24.10.18 17:00 31.5 39.6 297 8.7 0

2018 24.10.18 18:00 32.0 48.0 270 11.7 0

2018 24.10.18 19:00 30.4 50.4 24 11.1 0

2018 24.10.18 20:00 28.8 52.8 25 10.5 0

2018 24.10.18 21:00 28.0 61.0 23 13.7 0

2018 24.10.18 22:00 29.4 58.0 24 13.0 0

2018 24.10.18 23:00 30.8 54.9 25 12.3 0

2018 25.10.18 0:00 26.0 69.0 23 9.7 0

2018 25.10.18 1:00 27.3 65.6 21 10.2 0

2018 25.10.18 2:00 28.6 62.1 20 10.7 0

2018 25.10.18 3:00 26.0 72.0 23 7.7 0

2018 25.10.18 4:00 27.3 68.4 21 8.1 0

2018 25.10.18 5:00 28.6 64.8 20 8.5 0

2018 25.10.18 6:00 28.0 71.0 270 0.0 0

2018 25.10.18 7:00 29.4 74.6 257 0.0 0

2018 25.10.18 8:00 30.8 78.1 243 0.0 0

2018 25.10.18 9:00 32.0 58.0 135 7.7 0

A-164


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 25.10.18 10:00 30.4 60.9 128 8.1 0

2018 25.10.18 11:00 28.8 63.8 122 8.5 0

2018 25.10.18 12:00 35.0 43.0 135 7.7 0

2018 25.10.18 13:00 33.3 45.2 142 8.1 0

2018 25.10.18 14:00 31.5 47.3 149 8.5 0

2018 25.10.18 15:00 35.0 40.0 113 0.0 0

2018 25.10.18 16:00 33.3 42.0 118 0.0 0

2018 25.10.18 17:00 31.5 44.0 124 0.0 0

2018 25.10.18 18:00 33.0 52.0 270 0.0 0

2018 25.10.18 19:00 34.7 49.4 284 0.0 0

2018 25.10.18 20:00 36.3 46.8 297 0.0 0

2018 25.10.18 21:00 29.0 58.0 23 9.7 0

2018 25.10.18 22:00 30.5 55.1 24 9.2 0

2018 25.10.18 23:00 31.9 52.2 25 8.7 0

2018 26.10.18 0:00 27.0 62.0 270 7.7 0

2018 26.10.18 1:00 28.4 58.9 257 8.1 0

2018 26.10.18 2:00 29.7 55.8 243 8.5 0

2018 26.10.18 3:00 26.0 64.0 90 0.0 0

2018 26.10.18 4:00 27.3 60.8 86 0.0 0

2018 26.10.18 5:00 28.6 57.6 81 0.0 0

2018 26.10.18 6:00 27.0 63.0 158 0.0 0

2018 26.10.18 7:00 28.4 66.2 150 0.0 0

2018 26.10.18 8:00 29.7 69.3 142 0.0 0

2018 26.10.18 9:00 32.0 48.0 270 0.0 0

2018 26.10.18 10:00 30.4 50.4 257 0.0 0

2018 26.10.18 11:00 28.8 52.8 243 0.0 0

2018 26.10.18 12:00 35.0 36.0 180 9.7 0

2018 26.10.18 13:00 33.3 37.8 189 10.2 0

2018 26.10.18 14:00 31.5 39.6 198 10.7 0

2018 26.10.18 15:00 36.0 36.0 248 9.7 0

2018 26.10.18 16:00 34.2 37.8 260 9.2 0

2018 26.10.18 17:00 32.4 39.6 272 8.7 0

2018 26.10.18 18:00 34.0 47.0 315 0.0 0

2018 26.10.18 19:00 35.7 44.7 331 0.0 0

2018 26.10.18 20:00 37.4 42.3 347 0.0 0

2018 26.10.18 21:00 30.0 52.0 113 0.0 0

2018 26.10.18 22:00 31.5 49.4 118 0.0 0

2018 26.10.18 23:00 33.0 46.8 124 0.0 0

2018 27.10.18 0:00 27.0 52.0 158 0.0 0

2018 27.10.18 1:00 28.4 49.4 150 0.0 0

2018 27.10.18 2:00 29.7 46.8 142 0.0 0

2018 27.10.18 3:00 26.0 52.0 270 9.7 0

2018 27.10.18 4:00 27.3 54.6 257 10.2 0

2018 27.10.18 5:00 28.6 57.2 243 10.7 0

2018 27.10.18 6:00 28.0 51.0 203 13.7 0

2018 27.10.18 7:00 26.6 53.6 192 14.4 0

2018 27.10.18 8:00 25.2 56.1 182 15.1 0

2018 27.10.18 9:00 34.0 42.0 203 13.7 0

2018 27.10.18 10:00 32.3 44.1 192 14.4 0

A-165


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 27.10.18 11:00 30.6 46.2 182 15.1 0

2018 27.10.18 12:00 37.0 28.0 180 15.5 0

2018 27.10.18 13:00 35.2 29.4 189 16.3 0

2018 27.10.18 14:00 33.3 30.8 198 17.1 0

2018 27.10.18 15:00 37.0 28.0 180 13.7 0

2018 27.10.18 16:00 38.9 26.6 189 13.0 0

2018 27.10.18 17:00 40.7 25.2 198 12.3 0

2018 27.10.18 18:00 35.0 37.0 315 0.0 0

2018 27.10.18 19:00 36.8 35.2 331 0.0 0

2018 27.10.18 20:00 38.5 33.3 347 0.0 0

2018 27.10.18 21:00 33.0 36.0 135 0.0 0

2018 27.10.18 22:00 34.7 34.2 142 0.0 0

2018 27.10.18 23:00 36.3 32.4 149 0.0 0

2018 28.10.18 0:00 30.0 36.0 270 9.7 0

2018 28.10.18 1:00 31.5 37.8 257 10.2 0

2018 28.10.18 2:00 33.0 39.6 243 10.7 0

2018 28.10.18 3:00 27.0 40.0 203 11.7 0

2018 28.10.18 4:00 25.7 42.0 192 12.3 0

2018 28.10.18 5:00 24.3 44.0 182 12.9 0

2018 28.10.18 6:00 28.0 41.0 180 11.7 0

2018 28.10.18 7:00 26.6 43.1 171 12.3 0

2018 28.10.18 8:00 25.2 45.1 162 12.9 0

2018 28.10.18 9:00 33.0 36.0 180 7.7 0

2018 28.10.18 10:00 31.4 37.8 171 8.1 0

2018 28.10.18 11:00 29.7 39.6 162 8.5 0

2018 28.10.18 12:00 38.0 25.0 180 7.7 0

2018 28.10.18 13:00 39.9 23.8 189 8.1 0

2018 28.10.18 14:00 41.8 22.5 198 8.5 0

2018 28.10.18 15:00 39.0 23.0 180 7.7 0

2018 28.10.18 16:00 41.0 21.9 189 7.3 0

2018 28.10.18 17:00 42.9 20.7 198 6.9 0

2018 28.10.18 18:00 36.0 32.0 180 0.0 0

2018 28.10.18 19:00 37.8 30.4 189 0.0 0

2018 28.10.18 20:00 39.6 28.8 198 0.0 0

2018 28.10.18 21:00 32.0 31.0 203 0.0 0

2018 28.10.18 22:00 33.6 29.5 213 0.0 0

2018 28.10.18 23:00 35.2 27.9 223 0.0 0

2018 29.10.18 0:00 29.0 33.0 248 0.0 0

2018 29.10.18 1:00 27.6 34.7 235 0.0 0

2018 29.10.18 2:00 26.1 36.3 223 0.0 0

2018 29.10.18 3:00 27.0 34.0 270 0.0 0

2018 29.10.18 4:00 25.7 35.7 257 0.0 0

2018 29.10.18 5:00 24.3 37.4 243 0.0 0

2018 29.10.18 6:00 29.0 31.0 360 0.0 0

2018 29.10.18 7:00 27.6 32.6 342 0.0 0

2018 29.10.18 8:00 26.1 34.1 324 0.0 0

2018 29.10.18 9:00 35.0 25.0 270 0.0 0

2018 29.10.18 10:00 36.8 26.3 257 0.0 0

2018 29.10.18 11:00 38.5 27.5 243 0.0 0

A-166


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 29.10.18 12:00 38.0 20.0 180 0.0 0

2018 29.10.18 13:00 39.9 19.0 189 0.0 0

2018 29.10.18 14:00 41.8 18.0 198 0.0 0

2018 29.10.18 15:00 38.0 24.0 180 0.0 0

2018 29.10.18 16:00 39.9 22.8 189 0.0 0

2018 29.10.18 17:00 41.8 21.6 198 0.0 0

2018 29.10.18 18:00 36.0 36.0 180 0.0 0

2018 29.10.18 19:00 37.8 34.2 189 0.0 0

2018 29.10.18 20:00 39.6 32.4 198 0.0 0

2018 29.10.18 21:00 34.0 37.0 248 0.0 0

2018 29.10.18 22:00 32.3 38.9 260 0.0 0

2018 29.10.18 23:00 30.6 40.7 272 0.0 0

2018 30.10.18 0:00 30.0 38.0 293 0.0 0

2018 30.10.18 1:00 28.5 39.9 278 0.0 0

2018 30.10.18 2:00 27.0 41.8 263 0.0 0

2018 30.10.18 3:00 27.0 32.0 248 11.7 0

2018 30.10.18 4:00 25.7 33.6 235 12.3 0

2018 30.10.18 5:00 24.3 35.2 223 12.9 0

2018 30.10.18 6:00 27.0 32.0 248 11.7 0

2018 30.10.18 7:00 28.4 33.6 235 12.3 0

2018 30.10.18 8:00 29.7 35.2 223 12.9 0

2018 30.10.18 9:00 32.0 29.0 248 11.7 0

2018 30.10.18 10:00 33.6 27.6 235 12.3 0

2018 30.10.18 11:00 35.2 26.1 223 12.9 0

2018 30.10.18 12:00 36.0 21.0 270 13.7 0

2018 30.10.18 13:00 37.8 20.0 284 14.4 0

2018 30.10.18 14:00 39.6 18.9 297 15.1 0

2018 30.10.18 15:00 37.0 25.0 248 11.7 0

2018 30.10.18 16:00 38.9 23.8 260 11.1 0

2018 30.10.18 17:00 40.7 22.5 272 10.5 0

2018 30.10.18 18:00 34.0 34.0 180 0.0 0

2018 30.10.18 19:00 32.3 35.7 189 0.0 0

2018 30.10.18 20:00 30.6 37.4 198 0.0 0

2018 30.10.18 21:00 31.0 32.0 180 7.7 0

2018 30.10.18 22:00 29.5 33.6 189 7.3 0

2018 30.10.18 23:00 27.9 35.2 198 6.9 0

2018 31.10.18 0:00 28.0 30.0 248 11.7 0

2018 31.10.18 1:00 26.6 31.5 235 12.3 0

2018 31.10.18 2:00 25.2 33.0 223 12.9 0

2018 31.10.18 3:00 26.0 31.0 248 13.7 0

2018 31.10.18 4:00 27.3 32.6 235 14.4 0

2018 31.10.18 5:00 28.6 34.1 223 15.1 0

2018 31.10.18 6:00 26.0 34.0 248 15.5 0

2018 31.10.18 7:00 27.3 32.3 235 16.3 0

2018 31.10.18 8:00 28.6 30.6 223 17.1 0

2018 31.10.18 9:00 31.0 31.0 270 15.5 0

2018 31.10.18 10:00 32.6 29.5 257 16.3 0

2018 31.10.18 11:00 34.1 27.9 243 17.1 0

2018 31.10.18 12:00 35.0 20.0 270 17.5 0

A-167


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 31.10.18 13:00 36.8 19.0 284 18.4 0

2018 31.10.18 14:00 38.5 18.0 297 19.3 0

2018 31.10.18 15:00 36.0 23.0 270 13.7 0

2018 31.10.18 16:00 34.2 21.9 284 13.0 0

2018 31.10.18 17:00 32.4 20.7 297 12.3 0

2018 31.10.18 18:00 35.0 34.0 270 0.0 0

2018 31.10.18 19:00 33.3 35.7 284 0.0 0

2018 31.10.18 20:00 31.5 37.4 297 0.0 0

2018 31.10.18 21:00 32.0 33.0 248 7.7 0

2018 31.10.18 22:00 30.4 34.7 260 7.3 0

2018 31.10.18 23:00 28.8 36.3 272 6.9 0

2018 01.11.18 0:00 28.0 29.0 248 11.7 0

2018 01.11.18 1:00 29.4 30.5 235 12.3 0

2018 01.11.18 2:00 30.8 31.9 223 12.9 0

2018 01.11.18 3:00 26.0 29.0 248 13.7 0

2018 01.11.18 4:00 27.3 30.5 235 14.4 0

2018 01.11.18 5:00 28.6 31.9 223 15.1 0

2018 01.11.18 6:00 26.0 33.0 248 15.5 0

2018 01.11.18 7:00 27.3 31.4 235 16.3 0

2018 01.11.18 8:00 28.6 29.7 223 17.1 0

2018 01.11.18 9:00 31.0 32.0 248 15.5 0

2018 01.11.18 10:00 32.6 30.4 235 16.3 0

2018 01.11.18 11:00 34.1 28.8 223 17.1 0

2018 01.11.18 12:00 35.0 22.0 270 17.5 0

2018 01.11.18 13:00 33.3 20.9 284 18.4 0

2018 01.11.18 14:00 31.5 19.8 297 19.3 0

2018 01.11.18 15:00 35.0 24.0 248 15.5 0

2018 01.11.18 16:00 33.3 25.2 260 14.7 0

2018 01.11.18 17:00 31.5 26.4 272 14.0 0

2018 01.11.18 18:00 33.0 32.0 180 9.7 0

2018 01.11.18 19:00 31.4 33.6 189 9.2 0

2018 01.11.18 20:00 29.7 35.2 198 8.7 0

2018 01.11.18 21:00 29.0 31.0 248 11.7 0

2018 01.11.18 22:00 30.5 32.6 260 11.1 0

2018 01.11.18 23:00 31.9 34.1 272 10.5 0

2018 02.11.18 0:00 27.0 32.0 270 13.7 0

2018 02.11.18 1:00 28.4 33.6 257 14.4 0

2018 02.11.18 2:00 29.7 35.2 243 15.1 0

2018 02.11.18 3:00 24.0 34.0 248 11.7 0

2018 02.11.18 4:00 25.2 32.3 235 12.3 0

2018 02.11.18 5:00 26.4 30.6 223 12.9 0

2018 02.11.18 6:00 26.0 35.0 180 13.7 0

2018 02.11.18 7:00 27.3 33.3 171 14.4 0

2018 02.11.18 8:00 28.6 31.5 162 15.1 0

2018 02.11.18 9:00 31.0 31.0 248 13.7 0

2018 02.11.18 10:00 29.5 29.5 235 14.4 0

2018 02.11.18 11:00 27.9 27.9 223 15.1 0

2018 02.11.18 12:00 35.0 21.0 248 17.5 0

2018 02.11.18 13:00 33.3 22.1 260 18.4 0

A-168


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 02.11.18 14:00 31.5 23.1 272 19.3 0

2018 02.11.18 15:00 35.0 21.0 180 17.5 0

2018 02.11.18 16:00 33.3 22.1 189 16.6 0

2018 02.11.18 17:00 31.5 23.1 198 15.8 0

2018 02.11.18 18:00 31.0 28.0 203 11.7 0

2018 02.11.18 19:00 32.6 29.4 213 11.1 0

2018 02.11.18 20:00 34.1 30.8 223 10.5 0

2018 02.11.18 21:00 27.0 26.0 180 13.7 0

2018 02.11.18 22:00 28.4 27.3 189 13.0 0

2018 02.11.18 23:00 29.7 28.6 198 12.3 0

2018 03.11.18 0:00 24.0 29.0 248 15.5 0

2018 03.11.18 1:00 25.2 27.6 235 16.3 0

2018 03.11.18 2:00 26.4 26.1 223 17.1 0

2018 03.11.18 3:00 23.0 35.0 248 15.5 0

2018 03.11.18 4:00 24.2 33.3 235 16.3 0

2018 03.11.18 5:00 25.3 31.5 223 17.1 0

2018 03.11.18 6:00 23.0 39.0 248 17.5 0

2018 03.11.18 7:00 21.9 37.1 235 18.4 0

2018 03.11.18 8:00 20.7 35.1 223 19.3 0

2018 03.11.18 9:00 29.0 36.0 248 17.5 0

2018 03.11.18 10:00 27.6 34.2 235 18.4 0

2018 03.11.18 11:00 26.1 32.4 223 19.3 0

2018 03.11.18 12:00 35.0 26.0 248 17.5 0

2018 03.11.18 13:00 33.3 27.3 260 18.4 0

2018 03.11.18 14:00 31.5 28.6 272 19.3 0

2018 03.11.18 15:00 36.0 27.0 180 15.5 0

2018 03.11.18 16:00 37.8 28.4 189 14.7 0

2018 03.11.18 17:00 39.6 29.7 198 14.0 0

2018 03.11.18 18:00 33.0 34.0 203 11.7 0

2018 03.11.18 19:00 34.7 35.7 213 11.1 0

2018 03.11.18 20:00 36.3 37.4 223 10.5 0

2018 03.11.18 21:00 29.0 34.0 180 13.7 0

2018 03.11.18 22:00 30.5 35.7 189 13.0 0

2018 03.11.18 23:00 31.9 37.4 198 12.3 0

2018 04.11.18 0:00 26.0 35.0 248 15.5 0

2018 04.11.18 1:00 27.3 33.3 235 16.3 0

2018 04.11.18 2:00 28.6 31.5 223 17.1 0

2018 04.11.18 3:00 24.0 37.0 248 15.5 0

2018 04.11.18 4:00 22.8 35.2 235 16.3 0

2018 04.11.18 5:00 21.6 33.3 223 17.1 0

2018 04.11.18 6:00 24.0 40.0 248 13.7 0

2018 04.11.18 7:00 22.8 38.0 235 14.4 0

2018 04.11.18 8:00 21.6 36.0 223 15.1 0

2018 04.11.18 9:00 30.0 36.0 248 13.7 0

2018 04.11.18 10:00 28.5 37.8 235 14.4 0

2018 04.11.18 11:00 27.0 39.6 223 15.1 0

2018 04.11.18 12:00 35.0 25.0 180 13.7 0

2018 04.11.18 13:00 36.8 26.3 189 14.4 0

2018 04.11.18 14:00 38.5 27.5 198 15.1 0

A-169


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 04.11.18 15:00 35.0 25.0 203 13.7 0

2018 04.11.18 16:00 36.8 26.3 213 13.0 0

2018 04.11.18 17:00 38.5 27.5 223 12.3 0

2018 04.11.18 18:00 32.0 34.0 315 7.7 0

2018 04.11.18 19:00 33.6 35.7 331 7.3 0

2018 04.11.18 20:00 35.2 37.4 347 6.9 0

2018 04.11.18 21:00 28.0 36.0 180 0.0 0

2018 04.11.18 22:00 29.4 34.2 189 0.0 0

2018 04.11.18 23:00 30.8 32.4 198 0.0 0

2018 05.11.18 0:00 26.0 34.0 270 7.7 0

2018 05.11.18 1:00 24.7 32.3 257 8.1 0

2018 05.11.18 2:00 23.4 30.6 243 8.5 0

2018 05.11.18 3:00 24.0 34.0 203 11.7 0

2018 05.11.18 4:00 22.8 32.3 192 12.3 0

2018 05.11.18 5:00 21.6 30.6 182 12.9 0

2018 05.11.18 6:00 26.0 36.0 180 11.7 0

2018 05.11.18 7:00 24.7 37.8 171 12.3 0

2018 05.11.18 8:00 23.4 39.6 243 12.9 0

2018 05.11.18 9:00 32.0 31.0 270 9.7 0

2018 05.11.18 10:00 33.6 32.6 257 10.2 0

2018 05.11.18 11:00 35.2 34.1 243 10.7 0

2018 05.11.18 12:00 36.0 22.0 203 11.7 0

2018 05.11.18 13:00 37.8 23.1 213 12.3 0

2018 05.11.18 14:00 39.6 24.2 223 12.9 0

2018 05.11.18 15:00 36.0 24.0 203 11.7 0

2018 05.11.18 16:00 37.8 25.2 213 11.1 0

2018 05.11.18 17:00 39.6 26.4 223 10.5 0

2018 05.11.18 18:00 33.0 33.0 248 7.7 0

2018 05.11.18 19:00 34.7 31.4 260 7.3 0

2018 05.11.18 20:00 36.3 29.7 272 6.9 0

2018 05.11.18 21:00 29.0 35.0 270 0.0 0

2018 05.11.18 22:00 27.6 33.3 284 0.0 0

2018 05.11.18 23:00 26.1 31.5 297 0.0 0

2018 06.11.18 0:00 27.0 34.0 338 0.0 0

2018 06.11.18 1:00 25.7 32.3 321 0.0 0

2018 06.11.18 2:00 24.3 30.6 304 0.0 0

2018 06.11.18 3:00 26.0 33.0 90 7.7 0

2018 06.11.18 4:00 24.7 31.4 86 8.1 0

2018 06.11.18 5:00 23.4 29.7 81 8.5 0

2018 06.11.18 6:00 28.0 33.0 270 7.7 0

2018 06.11.18 7:00 29.4 34.7 257 8.1 0

2018 06.11.18 8:00 30.8 36.3 243 8.5 0

2018 06.11.18 9:00 34.0 26.0 248 0.0 0

2018 06.11.18 10:00 35.7 27.3 235 0.0 0

2018 06.11.18 11:00 37.4 28.6 223 0.0 0

2018 06.11.18 12:00 37.0 20.0 293 0.0 0

2018 06.11.18 13:00 38.9 21.0 307 2.1 0

2018 06.11.18 14:00 40.7 22.0 322 2.2 0

2018 06.11.18 15:00 37.0 23.0 270 7.7 0

A-170


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 06.11.18 16:00 38.9 24.2 284 7.3 0

2018 06.11.18 17:00 40.7 25.3 297 6.9 0

2018 06.11.18 18:00 34.0 31.0 203 7.7 0

2018 06.11.18 19:00 32.3 29.5 213 7.3 0

2018 06.11.18 20:00 30.6 27.9 223 6.9 0

2018 06.11.18 21:00 32.0 32.0 270 7.7 0

2018 06.11.18 22:00 30.4 30.4 284 7.3 0

2018 06.11.18 23:00 28.8 28.8 297 6.9 0

2018 07.11.18 0:00 29.0 35.0 203 0.0 0

2018 07.11.18 1:00 27.6 33.3 192 0.0 0

2018 07.11.18 2:00 26.1 31.5 182 0.0 0

2018 07.11.18 3:00 26.0 35.0 270 7.7 0

2018 07.11.18 4:00 27.3 36.8 257 8.1 0

2018 07.11.18 5:00 28.6 38.5 243 8.5 0

2018 07.11.18 6:00 27.0 35.0 248 7.7 0

2018 07.11.18 7:00 28.4 36.8 235 8.1 0

2018 07.11.18 8:00 29.7 38.5 223 8.5 0

2018 07.11.18 9:00 34.0 27.0 360 2.0 0

2018 07.11.18 10:00 35.7 28.4 342 2.1 0

2018 07.11.18 11:00 37.4 29.7 324 2.2 0

2018 07.11.18 12:00 37.0 19.0 270 2.0 0

2018 07.11.18 13:00 38.9 20.0 284 2.1 0

2018 07.11.18 14:00 40.7 20.9 297 2.2 0

2018 07.11.18 15:00 37.0 21.0 180 9.7 0

2018 07.11.18 16:00 38.9 20.0 189 9.2 0

2018 07.11.18 17:00 40.7 18.9 198 8.7 0

2018 07.11.18 18:00 33.0 29.0 203 9.7 0

2018 07.11.18 19:00 31.4 27.6 213 9.2 0

2018 07.11.18 20:00 29.7 26.1 223 6.9 0

2018 07.11.18 21:00 30.0 29.0 338 7.7 0

2018 07.11.18 22:00 28.5 27.6 354 7.3 0

2018 07.11.18 23:00 27.0 26.1 371 6.9 0

2018 08.11.18 0:00 26.0 30.0 270 13.7 0

2018 08.11.18 1:00 24.7 31.5 257 14.4 0

2018 08.11.18 2:00 23.4 33.0 243 15.1 0

2018 08.11.18 3:00 23.0 34.0 203 15.5 0

2018 08.11.18 4:00 24.2 35.7 192 16.3 0

2018 08.11.18 5:00 25.3 37.4 182 17.1 0

2018 08.11.18 6:00 24.0 31.0 270 13.7 0

2018 08.11.18 7:00 25.2 32.6 257 14.4 0

2018 08.11.18 8:00 26.4 34.1 243 15.1 0

2018 08.11.18 9:00 30.0 25.0 248 13.7 0

2018 08.11.18 10:00 31.5 26.3 235 14.4 0

2018 08.11.18 11:00 33.0 27.5 223 15.1 0

2018 08.11.18 12:00 36.0 16.0 270 13.7 0

2018 08.11.18 13:00 37.8 15.2 284 14.4 0

2018 08.11.18 14:00 39.6 14.4 297 15.1 0

2018 08.11.18 15:00 36.0 17.0 203 11.7 0

2018 08.11.18 16:00 34.2 16.2 213 11.1 0

A-171


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 08.11.18 17:00 32.4 15.3 223 10.5 0

2018 08.11.18 18:00 32.0 24.0 315 7.7 0

2018 08.11.18 19:00 30.4 22.8 331 7.3 0

2018 08.11.18 20:00 28.8 21.6 347 6.9 0

2018 08.11.18 21:00 29.0 22.0 270 7.7 0

2018 08.11.18 22:00 27.6 20.9 284 7.3 0

2018 08.11.18 23:00 26.1 19.8 297 6.9 0

2018 09.11.18 0:00 26.0 23.0 180 11.7 0

2018 09.11.18 1:00 27.3 24.2 171 12.3 0

2018 09.11.18 2:00 28.6 25.3 162 12.9 0

2018 09.11.18 3:00 23.0 29.0 203 13.7 0

2018 09.11.18 4:00 24.2 30.5 192 14.4 0

2018 09.11.18 5:00 25.3 31.9 182 15.1 0

2018 09.11.18 6:00 24.0 33.0 248 11.7 0

2018 09.11.18 7:00 25.2 34.7 235 12.3 0

2018 09.11.18 8:00 26.4 36.3 223 12.9 0

2018 09.11.18 9:00 31.0 28.0 248 7.7 0

2018 09.11.18 10:00 32.6 29.4 235 8.1 0

2018 09.11.18 11:00 34.1 30.8 223 8.5 0

2018 09.11.18 12:00 37.0 19.0 248 7.7 0

2018 09.11.18 13:00 35.2 18.1 260 8.1 0

2018 09.11.18 14:00 33.3 17.1 272 8.5 0

2018 09.11.18 15:00 37.0 21.0 270 2.0 0

2018 09.11.18 16:00 35.2 20.0 284 1.9 0

2018 09.11.18 17:00 33.3 18.9 297 1.8 0

2018 09.11.18 18:00 34.0 30.0 270 2.0 0

2018 09.11.18 19:00 32.3 28.5 284 1.9 0

2018 09.11.18 20:00 30.6 27.0 297 1.8 0

2018 09.11.18 21:00 32.0 30.0 203 2.0 0

2018 09.11.18 22:00 33.6 31.5 213 1.9 0

2018 09.11.18 23:00 35.2 33.0 223 1.8 0

2018 10.11.18 0:00 29.0 31.0 203 7.7 0

2018 10.11.18 1:00 30.5 32.6 192 8.1 0

2018 10.11.18 2:00 31.9 34.1 182 8.5 0

2018 10.11.18 3:00 23.0 31.0 203 11.7 0

2018 10.11.18 4:00 24.2 32.6 192 12.3 0

2018 10.11.18 5:00 25.3 34.1 182 12.9 0

2018 10.11.18 6:00 24.0 32.0 270 7.7 0

2018 10.11.18 7:00 25.2 33.6 257 8.1 0

2018 10.11.18 8:00 26.4 35.2 243 8.5 0

2018 10.11.18 9:00 31.0 29.0 248 7.7 0

2018 10.11.18 10:00 29.5 27.6 235 8.1 0

2018 10.11.18 11:00 27.9 26.1 223 8.5 0

2018 10.11.18 12:00 37.0 20.0 248 2.0 0

2018 10.11.18 13:00 35.2 19.0 260 4.1 0

2018 10.11.18 14:00 33.3 18.0 272 4.3 0

2018 10.11.18 15:00 38.0 24.0 338 0.0 0

2018 10.11.18 16:00 36.1 22.8 354 0.0 0

2018 10.11.18 17:00 34.2 21.6 371 0.0 0

A-172


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 10.11.18 18:00 34.0 36.0 113 0.0 0

2018 10.11.18 19:00 35.7 37.8 118 0.0 0

2018 10.11.18 20:00 37.4 39.6 124 0.0 0

2018 10.11.18 21:00 32.0 33.0 113 3.9 0

2018 10.11.18 22:00 33.6 34.7 118 3.7 0

2018 10.11.18 23:00 35.2 36.3 124 3.5 0

2018 11.11.18 0:00 28.0 33.0 270 7.7 0

2018 11.11.18 1:00 29.4 34.7 257 8.1 0

2018 11.11.18 2:00 30.8 36.3 243 8.5 0

2018 11.11.18 3:00 23.0 33.0 203 13.7 0

2018 11.11.18 4:00 24.2 34.7 192 14.4 0

2018 11.11.18 5:00 25.3 36.3 182 15.1 0

2018 11.11.18 6:00 24.0 34.0 270 11.7 0

2018 11.11.18 7:00 22.8 32.3 257 12.3 0

2018 11.11.18 8:00 21.6 30.6 243 12.9 0

2018 11.11.18 9:00 31.0 28.0 270 7.7 0

2018 11.11.18 10:00 29.5 26.6 257 8.1 0

2018 11.11.18 11:00 27.9 25.2 243 8.5 0

2018 11.11.18 12:00 36.0 20.0 203 7.7 0

2018 11.11.18 13:00 34.2 19.0 213 8.1 0

2018 11.11.18 14:00 32.4 18.0 223 8.5 0

2018 11.11.18 15:00 37.0 23.0 203 3.9 0

2018 11.11.18 16:00 38.9 21.9 213 3.7 0

2018 11.11.18 17:00 40.7 20.7 223 3.5 0

2018 11.11.18 18:00 32.0 32.0 203 3.9 0

2018 11.11.18 19:00 33.6 33.6 213 3.7 0

2018 11.11.18 20:00 35.2 35.2 223 3.5 0

2018 11.11.18 21:00 29.0 28.0 203 7.7 0

2018 11.11.18 22:00 30.5 29.4 213 7.3 0

2018 11.11.18 23:00 31.9 30.8 223 6.9 0

2018 12.11.18 0:00 26.0 28.0 203 11.7 0

2018 12.11.18 1:00 27.3 29.4 192 12.3 0

2018 12.11.18 2:00 28.6 30.8 182 12.9 0

2018 12.11.18 3:00 23.0 34.0 270 13.7 0

2018 12.11.18 4:00 21.9 35.7 257 14.4 0

2018 12.11.18 5:00 20.7 37.4 243 15.1 0

2018 12.11.18 6:00 23.0 36.0 270 11.7 0

2018 12.11.18 7:00 21.9 34.2 257 12.3 0

2018 12.11.18 8:00 20.7 32.4 243 12.9 0

2018 12.11.18 9:00 30.0 32.0 270 11.7 0

2018 12.11.18 10:00 28.5 30.4 257 12.3 0

2018 12.11.18 11:00 27.0 28.8 243 12.9 0

2018 12.11.18 12:00 36.0 22.0 203 7.7 0

2018 12.11.18 13:00 37.8 20.9 213 8.1 0

2018 12.11.18 14:00 39.6 19.8 223 8.5 0

2018 12.11.18 15:00 36.0 24.0 203 7.7 0

2018 12.11.18 16:00 37.8 25.2 213 7.3 0

2018 12.11.18 17:00 39.6 26.4 223 6.9 0

2018 12.11.18 18:00 32.0 33.0 203 7.7 0

A-173


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 12.11.18 19:00 33.6 34.7 213 7.3 0

2018 12.11.18 20:00 35.2 36.3 223 6.9 0

2018 12.11.18 21:00 29.0 32.0 203 11.7 0

2018 12.11.18 22:00 30.5 33.6 213 11.1 0

2018 12.11.18 23:00 31.9 35.2 223 10.5 0

2018 13.11.18 0:00 24.0 33.0 180 13.7 0

2018 13.11.18 1:00 22.8 34.7 171 14.4 0

2018 13.11.18 2:00 21.6 36.3 162 15.1 0

2018 13.11.18 3:00 23.0 37.0 270 13.7 0

2018 13.11.18 4:00 21.9 35.2 257 14.4 0

2018 13.11.18 5:00 20.7 33.3 243 15.1 0

2018 13.11.18 6:00 24.0 39.0 270 13.7 0

2018 13.11.18 7:00 22.8 37.1 257 14.4 0

2018 13.11.18 8:00 21.6 35.1 243 15.1 0

2018 13.11.18 9:00 30.0 34.0 270 13.7 0

2018 13.11.18 10:00 31.5 32.3 257 14.4 0

2018 13.11.18 11:00 33.0 30.6 243 15.1 0

2018 13.11.18 12:00 35.0 24.0 270 15.5 0

2018 13.11.18 13:00 36.8 25.2 284 16.3 0

2018 13.11.18 14:00 38.5 26.4 297 17.1 0

2018 13.11.18 15:00 35.0 24.0 270 11.7 0

2018 13.11.18 16:00 36.8 25.2 284 11.1 0

2018 13.11.18 17:00 38.5 26.4 297 10.5 0

2018 13.11.18 18:00 31.0 31.0 203 7.7 0

2018 13.11.18 19:00 32.6 32.6 213 7.3 0

2018 13.11.18 20:00 34.1 34.1 223 6.9 0

2018 13.11.18 21:00 27.0 31.0 203 7.7 0

2018 13.11.18 22:00 25.7 32.6 213 7.3 0

2018 13.11.18 23:00 24.3 34.1 223 6.9 0

2018 14.11.18 0:00 26.0 32.0 203 7.7 0

2018 14.11.18 1:00 24.7 30.4 192 8.1 0

2018 14.11.18 2:00 23.4 28.8 182 8.5 0

2018 14.11.18 3:00 23.0 32.0 270 13.7 0

2018 14.11.18 4:00 21.9 30.4 257 14.4 0

2018 14.11.18 5:00 20.7 28.8 243 15.1 0

2018 14.11.18 6:00 23.0 35.0 270 15.5 0

2018 14.11.18 7:00 24.2 33.3 257 16.3 0

2018 14.11.18 8:00 25.3 31.5 243 17.1 0

2018 14.11.18 9:00 29.0 33.0 270 13.7 0

2018 14.11.18 10:00 30.5 31.4 257 14.4 0

2018 14.11.18 11:00 31.9 29.7 243 15.1 0

2018 14.11.18 12:00 35.0 23.0 248 13.7 0

2018 14.11.18 13:00 36.8 24.2 260 14.4 0

2018 14.11.18 14:00 38.5 25.3 272 15.1 0

2018 14.11.18 15:00 35.0 24.0 270 11.7 0

2018 14.11.18 16:00 36.8 25.2 284 11.1 0

2018 14.11.18 17:00 38.5 26.4 297 10.5 0

2018 14.11.18 18:00 32.0 30.0 203 11.7 0

2018 14.11.18 19:00 30.4 31.5 213 11.1 0

A-174


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 14.11.18 20:00 28.8 33.0 223 10.5 0

2018 14.11.18 21:00 28.0 28.0 203 13.7 0

2018 14.11.18 22:00 26.6 29.4 213 13.0 0

2018 14.11.18 23:00 25.2 30.8 223 12.3 0

2018 15.11.18 0:00 24.0 28.0 203 13.7 0

2018 15.11.18 1:00 22.8 26.6 192 14.4 0

2018 15.11.18 2:00 21.6 25.2 182 15.1 0

2018 15.11.18 3:00 22.0 30.0 203 15.5 0

2018 15.11.18 4:00 23.1 28.5 192 16.3 0

2018 15.11.18 5:00 24.2 27.0 182 17.1 0

2018 15.11.18 6:00 22.0 34.0 270 17.5 0

2018 15.11.18 7:00 23.1 32.3 257 18.4 0

2018 15.11.18 8:00 24.2 30.6 243 19.3 0

2018 15.11.18 9:00 28.0 34.0 270 15.5 0

2018 15.11.18 10:00 29.4 35.7 257 16.3 0

2018 15.11.18 11:00 30.8 37.4 243 17.1 0

2018 15.11.18 12:00 34.0 23.0 248 15.5 0

2018 15.11.18 13:00 35.7 24.2 260 16.3 0

2018 15.11.18 14:00 37.4 25.3 272 17.1 0

2018 15.11.18 15:00 35.0 23.0 270 11.7 0

2018 15.11.18 16:00 33.3 24.2 284 11.1 0

2018 15.11.18 17:00 31.5 25.3 297 10.5 0

2018 15.11.18 18:00 32.0 30.0 203 11.7 0

2018 15.11.18 19:00 30.4 31.5 213 11.1 0

2018 15.11.18 20:00 28.8 33.0 223 10.5 0

2018 15.11.18 21:00 29.0 28.0 270 15.5 0

2018 15.11.18 22:00 27.6 26.6 284 14.7 0

2018 15.11.18 23:00 26.1 25.2 297 14.0 0

2018 16.11.18 0:00 26.0 28.0 270 15.5 0

2018 16.11.18 1:00 27.3 26.6 257 16.3 0

2018 16.11.18 2:00 28.6 25.2 243 17.1 0

2018 16.11.18 3:00 22.0 28.0 270 15.5 0

2018 16.11.18 4:00 23.1 26.6 257 16.3 0

2018 16.11.18 5:00 24.2 25.2 243 17.1 0

2018 16.11.18 6:00 22.0 32.0 270 15.5 0

2018 16.11.18 7:00 23.1 33.6 257 16.3 0

2018 16.11.18 8:00 24.2 35.2 243 17.1 0

2018 16.11.18 9:00 28.0 33.0 248 17.5 0

2018 16.11.18 10:00 29.4 34.7 235 18.4 0

2018 16.11.18 11:00 30.8 36.3 223 19.3 0

2018 16.11.18 12:00 34.0 24.0 248 17.5 0

2018 16.11.18 13:00 32.3 25.2 260 18.4 0

2018 16.11.18 14:00 30.6 26.4 223 19.3 0

2018 16.11.18 15:00 35.0 25.0 270 13.7 0

2018 16.11.18 16:00 33.3 26.3 284 13.0 0

2018 16.11.18 17:00 31.5 27.5 297 12.3 0

2018 16.11.18 18:00 31.0 31.0 203 13.7 0

2018 16.11.18 19:00 29.5 29.5 213 13.0 0

2018 16.11.18 20:00 27.9 27.9 223 12.3 0

A-175


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 16.11.18 21:00 29.0 28.0 270 17.5 0

2018 16.11.18 22:00 30.5 26.6 284 16.6 0

2018 16.11.18 23:00 31.9 25.2 297 15.8 0

2018 17.11.18 0:00 24.0 29.0 270 17.5 0

2018 17.11.18 1:00 25.2 27.6 257 18.4 0

2018 17.11.18 2:00 26.4 26.1 243 19.3 0

2018 17.11.18 3:00 22.0 33.0 203 17.5 0

2018 17.11.18 4:00 23.1 31.4 192 18.4 0

2018 17.11.18 5:00 24.2 29.7 182 19.3 0

2018 17.11.18 6:00 22.0 36.0 203 17.5 0

2018 17.11.18 7:00 23.1 37.8 192 18.4 0

2018 17.11.18 8:00 24.2 39.6 182 19.3 0

2018 17.11.18 9:00 28.0 35.0 270 17.5 0

2018 17.11.18 10:00 26.6 36.8 257 18.4 0

2018 17.11.18 11:00 25.2 38.5 243 19.3 0

2018 17.11.18 12:00 34.0 23.0 270 17.5 0

2018 17.11.18 13:00 32.3 24.2 284 18.4 0

2018 17.11.18 14:00 30.6 25.3 297 19.3 0

2018 17.11.18 15:00 34.0 23.0 270 15.5 0

2018 17.11.18 16:00 32.3 24.2 284 14.7 0

2018 17.11.18 17:00 30.6 25.3 297 14.0 0

2018 17.11.18 18:00 32.0 30.0 203 13.7 0

2018 17.11.18 19:00 33.6 28.5 213 13.0 0

2018 17.11.18 20:00 35.2 27.0 223 12.3 0

2018 17.11.18 21:00 28.0 29.0 270 13.7 0

2018 17.11.18 22:00 29.4 27.6 189 13.0 0

2018 17.11.18 23:00 30.8 26.1 198 12.3 0

2018 18.11.18 0:00 23.0 29.0 203 15.5 0

2018 18.11.18 1:00 24.2 27.6 192 16.3 0

2018 18.11.18 2:00 25.3 26.1 182 17.1 0

2018 18.11.18 3:00 22.0 32.0 203 15.5 0

2018 18.11.18 4:00 23.1 33.6 192 16.3 0

2018 18.11.18 5:00 24.2 35.2 182 17.1 0

2018 18.11.18 6:00 22.0 34.0 203 13.7 0

2018 18.11.18 7:00 20.9 35.7 192 14.4 0

2018 18.11.18 8:00 19.8 37.4 182 15.1 0

2018 18.11.18 9:00 29.0 31.0 270 11.7 0

2018 18.11.18 10:00 27.6 32.6 257 12.3 0

2018 18.11.18 11:00 26.1 34.1 243 12.9 0

2018 18.11.18 12:00 35.0 21.0 203 13.7 0

2018 18.11.18 13:00 33.3 22.1 213 14.4 0

2018 18.11.18 14:00 31.5 23.1 223 15.1 0

2018 18.11.18 15:00 35.0 22.0 180 11.7 0

2018 18.11.18 16:00 36.8 20.9 189 11.1 0

2018 18.11.18 17:00 38.5 19.8 198 10.5 0

2018 18.11.18 18:00 32.0 30.0 203 11.7 0

2018 18.11.18 19:00 33.6 28.5 213 11.1 0

2018 18.11.18 20:00 35.2 27.0 223 10.5 0

2018 18.11.18 21:00 29.0 30.0 180 11.7 0

A-176


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 18.11.18 22:00 30.5 28.5 189 11.1 0

2018 18.11.18 23:00 31.9 27.0 198 10.5 0

2018 19.11.18 0:00 26.0 31.0 203 11.7 0

2018 19.11.18 1:00 27.3 32.6 192 12.3 0

2018 19.11.18 2:00 28.6 34.1 182 12.9 0

2018 19.11.18 3:00 20.0 31.0 203 11.7 0

2018 19.11.18 4:00 19.0 32.6 192 12.3 0

2018 19.11.18 5:00 18.0 34.1 182 12.9 0

2018 19.11.18 6:00 21.0 32.0 203 7.7 0

2018 19.11.18 7:00 20.0 33.6 192 8.1 0

2018 19.11.18 8:00 18.9 35.2 182 8.5 0

2018 19.11.18 9:00 29.0 29.0 203 7.7 0

2018 19.11.18 10:00 27.6 30.5 192 8.1 0

2018 19.11.18 11:00 26.1 31.9 182 8.5 0

2018 19.11.18 12:00 35.0 20.0 203 7.7 0

2018 19.11.18 13:00 36.8 19.0 213 8.1 0

2018 19.11.18 14:00 38.5 18.0 223 8.5 0

2018 19.11.18 15:00 36.0 21.0 225 7.7 0

2018 19.11.18 16:00 37.8 20.0 236 7.3 0

2018 19.11.18 17:00 39.6 18.9 248 6.9 0

2018 19.11.18 18:00 32.0 29.0 225 7.7 0

2018 19.11.18 19:00 33.6 27.6 236 7.3 0

2018 19.11.18 20:00 35.2 26.1 248 6.9 0

2018 19.11.18 21:00 29.0 28.0 225 11.7 0

2018 19.11.18 22:00 30.5 26.6 236 11.1 0

2018 19.11.18 23:00 31.9 25.2 248 10.5 0

2018 20.11.18 0:00 24.0 28.0 203 11.7 0

2018 20.11.18 1:00 25.2 29.4 192 12.3 0

2018 20.11.18 2:00 26.4 30.8 182 12.9 0

2018 20.11.18 3:00 22.0 29.0 203 11.7 0

2018 20.11.18 4:00 20.9 30.5 192 12.3 0

2018 20.11.18 5:00 19.8 31.9 182 12.9 0

2018 20.11.18 6:00 26.0 30.0 203 7.7 0

2018 20.11.18 7:00 24.7 31.5 192 8.1 0

2018 20.11.18 8:00 23.4 33.0 182 8.5 0

2018 20.11.18 9:00 32.0 26.0 225 3.9 0

2018 20.11.18 10:00 30.4 27.3 214 4.1 0

2018 20.11.18 11:00 28.8 28.6 203 4.3 0

2018 20.11.18 12:00 36.0 18.0 225 3.9 0

2018 20.11.18 13:00 37.8 17.1 236 4.1 0

2018 20.11.18 14:00 39.6 16.2 248 4.3 0

2018 20.11.18 15:00 35.0 22.0 225 3.9 0

2018 20.11.18 16:00 36.8 20.9 236 3.7 0

2018 20.11.18 17:00 38.5 19.8 248 3.5 0

2018 20.11.18 18:00 29.0 33.0 203 3.9 0

2018 20.11.18 19:00 30.5 31.4 213 3.7 0

2018 20.11.18 20:00 31.9 29.7 223 3.5 0

2018 20.11.18 21:00 26.0 29.0 203 7.7 0

2018 20.11.18 22:00 27.3 30.5 213 7.3 0

A-177


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 20.11.18 23:00 28.6 31.9 223 6.9 0

2018 21.11.18 0:00 22.0 28.0 225 11.7 0

2018 21.11.18 1:00 20.9 29.4 214 12.3 0

2018 21.11.18 2:00 19.8 30.8 203 12.9 0

2018 21.11.18 3:00 22.0 28.0 225 11.7 0

2018 21.11.18 4:00 20.9 29.4 214 12.3 0

2018 21.11.18 5:00 19.8 30.8 203 12.9 0

2018 21.11.18 6:00 23.0 30.0 225 11.7 0

2018 21.11.18 7:00 21.9 31.5 214 12.3 0

2018 21.11.18 8:00 20.7 33.0 203 12.9 0

2018 21.11.18 9:00 31.0 29.0 203 7.7 0

2018 21.11.18 10:00 32.6 27.6 192 8.1 0

2018 21.11.18 11:00 34.1 26.1 182 8.5 0

2018 21.11.18 12:00 35.0 20.0 203 7.7 0

2018 21.11.18 13:00 36.8 19.0 213 8.1 0

2018 21.11.18 14:00 38.5 18.0 223 8.5 0

2018 21.11.18 15:00 35.0 22.0 225 7.7 0

2018 21.11.18 16:00 36.8 20.9 236 7.3 0

2018 21.11.18 17:00 38.5 19.8 248 6.9 0

2018 21.11.18 18:00 30.0 31.0 203 7.7 0

2018 21.11.18 19:00 31.5 32.6 213 7.3 0

2018 21.11.18 20:00 33.0 34.1 223 6.9 0

2018 21.11.18 21:00 27.0 29.0 203 7.7 0

2018 21.11.18 22:00 25.7 30.5 213 7.3 0

2018 21.11.18 23:00 24.3 31.9 223 6.9 0

2018 22.11.18 0:00 26.0 29.0 225 11.7 0

2018 22.11.18 1:00 24.7 30.5 214 12.3 0

2018 22.11.18 2:00 23.4 31.9 203 12.9 0

2018 22.11.18 3:00 23.0 29.0 203 15.5 0

2018 22.11.18 4:00 21.9 30.5 192 16.3 0

2018 22.11.18 5:00 20.7 31.9 182 17.1 0

2018 22.11.18 6:00 24.0 31.0 225 13.7 0

2018 22.11.18 7:00 25.2 29.5 214 14.4 0

2018 22.11.18 8:00 26.4 27.9 203 15.1 0

2018 22.11.18 9:00 30.0 30.0 225 11.7 0

2018 22.11.18 10:00 31.5 28.5 214 12.3 0

2018 22.11.18 11:00 33.0 27.0 203 12.9 0

2018 22.11.18 12:00 36.0 20.0 225 7.7 0

2018 22.11.18 13:00 37.8 19.0 236 8.1 0

2018 22.11.18 14:00 39.6 18.0 248 8.5 0

2018 22.11.18 15:00 36.0 22.0 225 7.7 0

2018 22.11.18 16:00 37.8 20.9 236 7.3 0

2018 22.11.18 17:00 39.6 19.8 248 6.9 0

2018 22.11.18 18:00 32.0 31.0 203 7.7 0

2018 22.11.18 19:00 30.4 32.6 213 7.3 0

2018 22.11.18 20:00 28.8 34.1 223 6.9 0

2018 22.11.18 21:00 29.0 30.0 203 7.7 0

2018 22.11.18 22:00 27.6 31.5 213 7.3 0

2018 22.11.18 23:00 26.1 33.0 223 6.9 0

A-178


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 23.11.18 0:00 26.0 29.0 203 7.7 0

2018 23.11.18 1:00 24.7 30.5 192 10.2 0

2018 23.11.18 2:00 23.4 31.9 182 10.7 0

2018 23.11.18 3:00 23.0 28.0 225 13.7 0

2018 23.11.18 4:00 24.2 29.4 214 14.4 0

2018 23.11.18 5:00 25.3 30.8 203 15.1 0

2018 23.11.18 6:00 23.0 29.0 225 11.7 0

2018 23.11.18 7:00 24.2 27.6 214 12.3 0

2018 23.11.18 8:00 25.3 26.1 203 12.9 0

2018 23.11.18 9:00 30.0 28.0 203 7.7 0

2018 23.11.18 10:00 31.5 26.6 192 8.1 0

2018 23.11.18 11:00 33.0 25.2 182 8.5 0

2018 23.11.18 12:00 35.0 19.0 203 7.7 0

2018 23.11.18 13:00 36.8 18.1 260 8.1 0

2018 23.11.18 14:00 38.5 17.1 272 8.5 0

2018 23.11.18 15:00 35.0 22.0 248 7.7 0

2018 23.11.18 16:00 33.3 23.1 260 7.3 0

2018 23.11.18 17:00 31.5 24.2 272 6.9 0

2018 23.11.18 18:00 30.0 31.0 203 3.9 0

2018 23.11.18 19:00 28.5 32.6 213 3.7 0

2018 23.11.18 20:00 27.0 34.1 223 3.5 0

2018 23.11.18 21:00 27.0 27.0 203 11.7 0

2018 23.11.18 22:00 25.7 28.4 213 11.1 0

2018 23.11.18 23:00 24.3 29.7 223 10.5 0

2018 24.11.18 0:00 26.0 26.0 225 13.7 0

2018 24.11.18 1:00 27.3 27.3 214 14.4 0

2018 24.11.18 2:00 28.6 28.6 203 15.1 0

2018 24.11.18 3:00 23.0 26.0 225 13.7 0

2018 24.11.18 4:00 24.2 24.7 214 14.4 0

2018 24.11.18 5:00 25.3 23.4 203 15.1 0

2018 24.11.18 6:00 23.0 29.0 248 13.7 0

2018 24.11.18 7:00 24.2 27.6 235 14.4 0

2018 24.11.18 8:00 25.3 26.1 223 15.1 0

2018 24.11.18 9:00 29.0 29.0 248 13.7 0

2018 24.11.18 10:00 30.5 27.6 235 14.4 0

2018 24.11.18 11:00 31.9 26.1 223 15.1 0

2018 24.11.18 12:00 34.0 20.0 248 15.5 0

2018 24.11.18 13:00 32.3 21.0 260 16.3 0

2018 24.11.18 14:00 30.6 22.0 272 17.1 0

2018 24.11.18 15:00 34.0 21.0 225 15.5 0

2018 24.11.18 16:00 32.3 22.1 236 14.7 0

2018 24.11.18 17:00 30.6 23.1 248 14.0 0

2018 24.11.18 18:00 30.0 27.0 203 13.7 0

2018 24.11.18 19:00 28.5 28.4 213 13.0 0

2018 24.11.18 20:00 27.0 29.7 223 12.3 0

2018 24.11.18 21:00 28.0 25.0 225 15.5 0

2018 24.11.18 22:00 29.4 26.3 236 14.7 0

2018 24.11.18 23:00 30.8 27.5 248 14.0 0

2018 25.11.18 0:00 24.0 24.0 248 17.5 0

A-179


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 25.11.18 1:00 25.2 22.8 235 18.4 0

2018 25.11.18 2:00 26.4 21.6 223 19.3 0

2018 25.11.18 3:00 21.0 25.0 248 17.5 0

2018 25.11.18 4:00 22.1 23.8 235 18.4 0

2018 25.11.18 5:00 23.1 22.5 223 19.3 0

2018 25.11.18 6:00 22.0 28.0 248 15.5 0

2018 25.11.18 7:00 23.1 26.6 235 16.3 0

2018 25.11.18 8:00 24.2 25.2 223 17.1 0

2018 25.11.18 9:00 29.0 29.0 248 13.7 0

2018 25.11.18 10:00 27.6 27.6 235 14.4 0

2018 25.11.18 11:00 26.1 26.1 223 15.1 0

2018 25.11.18 12:00 35.0 19.0 248 15.5 0

2018 25.11.18 13:00 33.3 20.0 260 16.3 0

2018 25.11.18 14:00 31.5 20.9 272 17.1 0

2018 25.11.18 15:00 36.0 19.0 225 13.7 0

2018 25.11.18 16:00 34.2 20.0 236 13.0 0

2018 25.11.18 17:00 32.4 20.9 248 12.3 0

2018 25.11.18 18:00 31.0 25.0 203 11.7 0

2018 25.11.18 19:00 32.6 26.3 213 11.1 0

2018 25.11.18 20:00 34.1 27.5 223 10.5 0

2018 25.11.18 21:00 28.0 22.0 225 15.5 0

2018 25.11.18 22:00 29.4 23.1 236 14.7 0

2018 25.11.18 23:00 30.8 24.2 248 14.0 0

2018 26.11.18 0:00 24.0 22.0 248 13.7 0

2018 26.11.18 1:00 25.2 20.9 235 14.4 0

2018 26.11.18 2:00 26.4 19.8 223 15.1 0

2018 26.11.18 3:00 23.0 23.0 248 15.5 0

2018 26.11.18 4:00 24.2 21.9 235 16.3 0

2018 26.11.18 5:00 25.3 20.7 223 17.1 0

2018 26.11.18 6:00 23.0 27.0 248 13.7 0

2018 26.11.18 7:00 21.9 25.7 235 14.4 0

2018 26.11.18 8:00 20.7 24.3 223 15.1 0

2018 26.11.18 9:00 30.0 27.0 248 11.7 0

2018 26.11.18 10:00 28.5 28.4 235 12.3 0

2018 26.11.18 11:00 27.0 29.7 223 12.9 0

2018 26.11.18 12:00 35.0 18.0 248 13.7 0

2018 26.11.18 13:00 33.3 18.9 260 14.4 0

2018 26.11.18 14:00 31.5 19.8 272 15.1 0

2018 26.11.18 15:00 35.0 20.0 225 13.7 0

2018 26.11.18 16:00 36.8 21.0 236 13.0 0

2018 26.11.18 17:00 38.5 22.0 248 12.3 0

2018 26.11.18 18:00 32.0 27.0 203 13.7 0

2018 26.11.18 19:00 33.6 28.4 213 13.0 0

2018 26.11.18 20:00 35.2 29.7 223 12.3 0

2018 26.11.18 21:00 29.0 25.0 225 13.7 0

2018 26.11.18 22:00 30.5 23.8 236 13.0 0

2018 26.11.18 23:00 31.9 22.5 248 12.3 0

2018 27.11.18 0:00 24.0 25.0 225 13.7 0

2018 27.11.18 1:00 25.2 23.8 214 14.4 0

A-180


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 27.11.18 2:00 26.4 22.5 203 15.1 0

2018 27.11.18 3:00 23.0 28.0 225 13.7 0

2018 27.11.18 4:00 21.9 26.6 214 14.4 0

2018 27.11.18 5:00 20.7 25.2 203 15.1 0

2018 27.11.18 6:00 23.0 31.0 225 13.7 0

2018 27.11.18 7:00 21.9 32.6 214 14.4 0

2018 27.11.18 8:00 20.7 34.1 203 15.1 0

2018 27.11.18 9:00 30.0 29.0 248 11.7 0

2018 27.11.18 10:00 28.5 30.5 235 12.3 0

2018 27.11.18 11:00 27.0 31.9 223 12.9 0

2018 27.11.18 12:00 36.0 19.0 248 11.7 0

2018 27.11.18 13:00 37.8 20.0 260 12.3 0

2018 27.11.18 14:00 39.6 20.9 272 12.9 0

2018 27.11.18 15:00 37.0 20.0 225 11.7 0

2018 27.11.18 16:00 38.9 21.0 236 11.1 0

2018 27.11.18 17:00 40.7 22.0 248 10.5 0

2018 27.11.18 18:00 33.0 26.0 203 11.7 0

2018 27.11.18 19:00 34.7 24.7 213 11.1 0

2018 27.11.18 20:00 36.3 23.4 223 10.5 0

2018 27.11.18 21:00 31.0 24.0 203 11.7 0

2018 27.11.18 22:00 32.6 22.8 213 11.1 0

2018 27.11.18 23:00 34.1 21.6 223 10.5 0

2018 28.11.18 0:00 28.0 23.0 225 11.7 0

2018 28.11.18 1:00 26.6 21.9 214 12.3 0

2018 28.11.18 2:00 25.2 20.7 203 12.9 0

2018 28.11.18 3:00 24.0 24.0 225 13.7 0

2018 28.11.18 4:00 22.8 22.8 214 14.4 0

2018 28.11.18 5:00 21.6 21.6 203 15.1 0

2018 28.11.18 6:00 24.0 26.0 225 13.7 0

2018 28.11.18 7:00 22.8 27.3 214 14.4 0

2018 28.11.18 8:00 21.6 28.6 203 15.1 0

2018 28.11.18 9:00 30.0 24.0 248 11.7 0

2018 28.11.18 10:00 31.5 25.2 235 12.3 0

2018 28.11.18 11:00 33.0 26.4 223 12.9 0

2018 28.11.18 12:00 37.0 17.0 225 11.7 0

2018 28.11.18 13:00 38.9 17.9 236 12.3 0

2018 28.11.18 14:00 40.7 18.7 248 12.9 0

2018 28.11.18 15:00 37.0 19.0 203 11.7 0

2018 28.11.18 16:00 38.9 20.0 213 11.1 0

2018 28.11.18 17:00 40.7 20.9 223 10.5 0

2018 28.11.18 18:00 33.0 26.0 203 11.7 0

2018 28.11.18 19:00 34.7 24.7 213 11.1 0

2018 28.11.18 20:00 36.3 23.4 223 10.5 0

2018 28.11.18 21:00 29.0 26.0 203 11.7 0

2018 28.11.18 22:00 27.6 24.7 213 11.1 0

2018 28.11.18 23:00 26.1 23.4 223 10.5 0

2018 29.11.18 0:00 26.0 28.0 203 9.7 0

2018 29.11.18 1:00 24.7 26.6 192 10.2 0

2018 29.11.18 2:00 23.4 25.2 182 10.7 0

A-181


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 29.11.18 3:00 23.0 29.0 203 9.7 0

2018 29.11.18 4:00 21.9 30.5 192 10.2 0

2018 29.11.18 5:00 20.7 31.9 182 10.7 0

2018 29.11.18 6:00 24.0 29.0 225 9.7 0

2018 29.11.18 7:00 25.2 30.5 214 10.2 0

2018 29.11.18 8:00 26.4 31.9 203 10.7 0

2018 29.11.18 9:00 31.0 24.0 248 9.7 0

2018 29.11.18 10:00 32.6 25.2 235 10.2 0

2018 29.11.18 11:00 34.1 26.4 223 10.7 0

2018 29.11.18 12:00 37.0 17.0 248 7.7 0

2018 29.11.18 13:00 38.9 17.9 260 8.1 0

2018 29.11.18 14:00 40.7 18.7 272 8.5 0

2018 29.11.18 15:00 37.0 19.0 225 7.7 0

2018 29.11.18 16:00 38.9 18.1 236 7.3 0

2018 29.11.18 17:00 40.7 17.1 248 6.9 0

2018 29.11.18 18:00 33.0 26.0 203 9.7 0

2018 29.11.18 19:00 31.4 24.7 213 9.2 0

2018 29.11.18 20:00 29.7 23.4 223 8.7 0

2018 29.11.18 21:00 31.0 25.0 203 11.7 0

2018 29.11.18 22:00 29.5 23.8 213 11.1 0

2018 29.11.18 23:00 27.9 22.5 223 10.5 0

2018 30.11.18 0:00 28.0 26.0 225 11.7 0

2018 30.11.18 1:00 26.6 27.3 214 12.3 0

2018 30.11.18 2:00 25.2 28.6 203 12.9 0

2018 30.11.18 3:00 24.0 27.0 225 13.7 0

2018 30.11.18 4:00 25.2 28.4 214 14.4 0

2018 30.11.18 5:00 26.4 29.7 203 15.1 0

2018 30.11.18 6:00 24.0 29.0 225 11.7 0

2018 30.11.18 7:00 25.2 30.5 214 12.3 0

2018 30.11.18 8:00 26.4 31.9 203 12.9 0

2018 30.11.18 9:00 31.0 28.0 225 3.9 0

2018 30.11.18 10:00 32.6 29.4 214 4.1 0

2018 30.11.18 11:00 34.1 30.8 203 4.3 0

2018 30.11.18 12:00 37.0 18.0 293 0.0 0

2018 30.11.18 13:00 38.9 17.1 307 0.0 0

2018 30.11.18 14:00 40.7 16.2 322 0.0 0

2018 30.11.18 15:00 37.0 20.0 135 3.9 0

2018 30.11.18 16:00 35.2 19.0 142 3.7 0

2018 30.11.18 17:00 33.3 18.0 149 3.5 0

2018 30.11.18 18:00 32.0 28.0 270 7.7 0

2018 30.11.18 19:00 30.4 26.6 284 7.3 0

2018 30.11.18 20:00 28.8 25.2 297 6.9 0

2018 30.11.18 21:00 28.0 27.0 180 11.7 0

2018 30.11.18 22:00 26.6 25.7 189 11.1 0

2018 30.11.18 23:00 25.2 24.3 198 10.5 0

2018 01.12.18 0:00 24.0 28.0 180 13.7 0

2018 01.12.18 1:00 25.2 29.4 171 14.4 0

2018 01.12.18 2:00 26.4 30.8 162 15.1 0

2018 01.12.18 3:00 23.0 32.0 203 13.7 0

A-182


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 01.12.18 4:00 24.2 33.6 192 14.4 0

2018 01.12.18 5:00 25.3 35.2 182 15.1 0

2018 01.12.18 6:00 23.0 34.0 225 11.7 0

2018 01.12.18 7:00 24.2 35.7 214 12.3 0

2018 01.12.18 8:00 25.3 37.4 203 12.9 0

2018 01.12.18 9:00 29.0 28.0 225 11.7 0

2018 01.12.18 10:00 30.5 29.4 214 12.3 0

2018 01.12.18 11:00 31.9 30.8 203 12.9 0

2018 01.12.18 12:00 36.0 19.0 225 7.7 0

2018 01.12.18 13:00 34.2 18.1 236 8.1 0

2018 01.12.18 14:00 32.4 17.1 248 8.5 0

2018 01.12.18 15:00 36.0 20.0 203 7.7 0

2018 01.12.18 16:00 34.2 19.0 213 7.3 0

2018 01.12.18 17:00 32.4 18.0 223 6.9 0

2018 01.12.18 18:00 31.0 26.0 180 11.7 0

2018 01.12.18 19:00 29.5 24.7 189 11.1 0

2018 01.12.18 20:00 27.9 23.4 198 10.5 0

2018 01.12.18 21:00 37.0 26.0 203 13.7 0

2018 01.12.18 22:00 38.9 27.3 213 13.0 0

2018 01.12.18 23:00 40.7 28.6 223 12.3 0

2018 02.12.18 0:00 24.0 28.0 225 13.7 0

2018 02.12.18 1:00 25.2 29.4 214 14.4 0

2018 02.12.18 2:00 26.4 30.8 203 15.1 0

2018 02.12.18 3:00 23.0 32.0 225 15.5 0

2018 02.12.18 4:00 24.2 33.6 214 16.3 0

2018 02.12.18 5:00 25.3 35.2 203 17.1 0

2018 02.12.18 6:00 22.0 35.0 225 17.5 0

2018 02.12.18 7:00 23.1 36.8 214 18.4 0

2018 02.12.18 8:00 24.2 38.5 203 19.3 0

2018 02.12.18 9:00 27.0 34.0 248 19.4 0

2018 02.12.18 10:00 28.4 32.3 235 20.4 0

2018 02.12.18 11:00 29.7 30.6 223 21.3 0

2018 02.12.18 12:00 33.0 24.0 248 21.4 0

2018 02.12.18 13:00 31.4 22.8 260 22.5 0

2018 02.12.18 14:00 29.7 21.6 272 23.5 0

2018 02.12.18 15:00 34.0 25.0 225 19.4 0

2018 02.12.18 16:00 32.3 23.8 236 18.4 0

2018 02.12.18 17:00 30.6 22.5 248 17.5 0

2018 02.12.18 18:00 31.0 32.0 203 15.5 0

2018 02.12.18 19:00 29.5 33.6 213 14.7 0

2018 02.12.18 20:00 27.9 35.2 223 14.0 0

2018 02.12.18 21:00 27.0 33.0 225 17.5 0

2018 02.12.18 22:00 28.4 34.7 236 16.6 0

2018 02.12.18 23:00 29.7 36.3 248 15.8 0

2018 03.12.18 0:00 23.0 36.0 248 19.4 0

2018 03.12.18 1:00 24.2 37.8 235 20.4 0

2018 03.12.18 2:00 25.3 39.6 223 21.3 0

2018 03.12.18 3:00 22.0 38.0 248 17.5 0

2018 03.12.18 4:00 23.1 39.9 235 18.4 0

A-183


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 03.12.18 5:00 24.2 41.8 223 19.3 0

2018 03.12.18 6:00 22.0 41.0 248 19.4 0

2018 03.12.18 7:00 23.1 39.0 235 20.4 0

2018 03.12.18 8:00 24.2 36.9 223 21.3 0

2018 03.12.18 9:00 26.0 39.0 248 21.4 0

2018 03.12.18 10:00 24.7 37.1 235 22.5 0

2018 03.12.18 11:00 23.4 35.1 223 23.5 0

2018 03.12.18 12:00 33.0 28.0 270 21.4 0

2018 03.12.18 13:00 31.4 26.6 284 22.5 0

2018 03.12.18 14:00 29.7 25.2 297 23.5 0

2018 03.12.18 15:00 35.0 27.0 248 15.5 0

2018 03.12.18 16:00 33.3 25.7 260 14.7 0

2018 03.12.18 17:00 31.5 24.3 272 14.0 0

2018 03.12.18 18:00 32.0 34.0 225 13.7 0

2018 03.12.18 19:00 33.6 35.7 236 13.0 0

2018 03.12.18 20:00 35.2 37.4 248 12.3 0

2018 03.12.18 21:00 29.0 35.0 225 17.5 0

2018 03.12.18 22:00 30.5 36.8 236 16.6 0

2018 03.12.18 23:00 31.9 38.5 248 15.8 0

2018 04.12.18 0:00 24.0 37.0 248 19.4 0

2018 04.12.18 1:00 25.2 38.9 235 20.4 0

2018 04.12.18 2:00 26.4 40.7 223 21.3 0

2018 04.12.18 3:00 21.0 41.0 248 19.4 0

2018 04.12.18 4:00 22.1 43.1 235 20.4 0

2018 04.12.18 5:00 23.1 45.1 223 21.3 0

2018 04.12.18 6:00 21.0 46.0 248 19.4 0

2018 04.12.18 7:00 20.0 43.7 235 20.4 0

2018 04.12.18 8:00 18.9 41.4 223 21.3 0

2018 04.12.18 9:00 26.0 46.0 248 19.4 0

2018 04.12.18 10:00 24.7 43.7 235 20.4 0

2018 04.12.18 11:00 23.4 41.4 223 21.3 0

2018 04.12.18 12:00 34.0 32.0 248 15.5 0

2018 04.12.18 13:00 32.3 30.4 260 16.3 0

2018 04.12.18 14:00 30.6 28.8 272 17.1 0

2018 04.12.18 15:00 36.0 30.0 225 11.7 0

2018 04.12.18 16:00 37.8 31.5 236 11.1 0

2018 04.12.18 17:00 39.6 33.0 248 10.5 0

2018 04.12.18 18:00 32.0 36.0 203 13.7 0

2018 04.12.18 19:00 33.6 37.8 213 13.0 0

2018 04.12.18 20:00 35.2 39.6 223 12.3 0

2018 04.12.18 21:00 29.0 36.0 225 17.5 0

2018 04.12.18 22:00 30.5 37.8 236 16.6 0

2018 04.12.18 23:00 31.9 39.6 248 15.8 0

2018 05.12.18 0:00 24.0 38.0 225 17.5 0

2018 05.12.18 1:00 25.2 39.9 214 18.4 0

2018 05.12.18 2:00 26.4 41.8 203 19.3 0

2018 05.12.18 3:00 21.0 42.0 248 17.5 0

2018 05.12.18 4:00 20.0 39.9 235 18.4 0

2018 05.12.18 5:00 18.9 37.8 223 19.3 0

A-184


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 05.12.18 6:00 22.0 45.0 248 17.5 0

2018 05.12.18 7:00 20.9 42.8 235 18.4 0

2018 05.12.18 8:00 19.8 40.5 223 19.3 0

2018 05.12.18 9:00 27.0 41.0 248 13.7 0

2018 05.12.18 10:00 25.7 39.0 235 14.4 0

2018 05.12.18 11:00 24.3 36.9 223 15.1 0

2018 05.12.18 12:00 34.0 28.0 248 11.7 0

2018 05.12.18 13:00 35.7 29.4 260 12.3 0

2018 05.12.18 14:00 37.4 30.8 272 12.9 0

2018 05.12.18 15:00 35.0 25.0 203 9.7 0

2018 05.12.18 16:00 36.8 26.3 213 9.2 0

2018 05.12.18 17:00 38.5 27.5 223 8.7 0

2018 05.12.18 18:00 31.0 32.0 203 13.7 0

2018 05.12.18 19:00 32.6 33.6 213 13.0 0

2018 05.12.18 20:00 34.1 35.2 223 12.3 0

2018 05.12.18 21:00 28.0 29.0 225 15.5 0

2018 05.12.18 22:00 29.4 30.5 236 14.7 0

2018 05.12.18 23:00 30.8 31.9 248 14.0 0

2018 06.12.18 0:00 24.0 25.0 225 13.7 0

2018 06.12.18 1:00 22.8 23.8 214 14.4 0

2018 06.12.18 2:00 21.6 22.5 203 15.1 0

2018 06.12.18 3:00 21.0 25.0 225 13.7 0

2018 06.12.18 4:00 20.0 23.8 214 14.4 0

2018 06.12.18 5:00 18.9 22.5 203 15.1 0

2018 06.12.18 6:00 21.0 30.0 225 15.5 0

2018 06.12.18 7:00 20.0 28.5 214 16.3 0

2018 06.12.18 8:00 18.9 27.0 203 17.1 0

2018 06.12.18 9:00 26.0 30.0 248 17.5 0

2018 06.12.18 10:00 27.3 28.5 235 18.4 0

2018 06.12.18 11:00 28.6 27.0 223 19.3 0

2018 06.12.18 12:00 33.0 19.0 248 17.5 0

2018 06.12.18 13:00 34.7 20.0 260 18.4 0

2018 06.12.18 14:00 36.3 20.9 272 19.3 0

2018 06.12.18 15:00 35.0 20.0 248 13.7 0

2018 06.12.18 16:00 36.8 21.0 260 13.0 0

2018 06.12.18 17:00 38.5 22.0 272 12.3 0

2018 06.12.18 18:00 31.0 27.0 225 11.7 0

2018 06.12.18 19:00 32.6 28.4 236 11.1 0

2018 06.12.18 20:00 34.1 29.7 248 10.5 0

2018 06.12.18 21:00 29.0 26.0 225 13.7 0

2018 06.12.18 22:00 27.6 27.3 236 13.0 0

2018 06.12.18 23:00 26.1 28.6 248 12.3 0

2018 07.12.18 0:00 24.0 27.0 248 15.5 0

2018 07.12.18 1:00 22.8 25.7 235 16.3 0

2018 07.12.18 2:00 21.6 24.3 223 17.1 0

2018 07.12.18 3:00 21.0 29.0 248 17.5 0

2018 07.12.18 4:00 20.0 27.6 235 18.4 0

2018 07.12.18 5:00 18.9 26.1 223 19.3 0

2018 07.12.18 6:00 21.0 33.0 248 17.5 0

A-185


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 07.12.18 7:00 22.1 31.4 235 18.4 0

2018 07.12.18 8:00 23.1 29.7 223 19.3 0

2018 07.12.18 9:00 27.0 31.0 248 15.5 0

2018 07.12.18 10:00 28.4 32.6 235 16.3 0

2018 07.12.18 11:00 29.7 34.1 223 17.1 0

2018 07.12.18 12:00 34.0 21.0 270 15.5 0

2018 07.12.18 13:00 35.7 22.1 284 16.3 0

2018 07.12.18 14:00 37.4 23.1 297 17.1 0

2018 07.12.18 15:00 35.0 22.0 248 11.7 0

2018 07.12.18 16:00 36.8 23.1 260 11.1 0

2018 07.12.18 17:00 38.5 24.2 272 10.5 0

2018 07.12.18 18:00 31.0 30.0 225 9.7 0

2018 07.12.18 19:00 29.5 31.5 236 9.2 0

2018 07.12.18 20:00 27.9 33.0 248 8.7 0

2018 07.12.18 21:00 28.0 29.0 225 13.7 0

2018 07.12.18 22:00 26.6 27.6 236 13.0 0

2018 07.12.18 23:00 25.2 26.1 248 12.3 0

2018 08.12.18 0:00 23.0 29.0 248 13.7 0

2018 08.12.18 1:00 21.9 27.6 235 14.4 0

2018 08.12.18 2:00 20.7 26.1 223 15.1 0

2018 08.12.18 3:00 22.0 31.0 248 13.7 0

2018 08.12.18 4:00 23.1 29.5 235 14.4 0

2018 08.12.18 5:00 24.2 27.9 223 15.1 0

2018 08.12.18 6:00 22.0 33.0 248 13.7 0

2018 08.12.18 7:00 23.1 34.7 235 14.4 0

2018 08.12.18 8:00 24.2 36.3 223 15.1 0

2018 08.12.18 9:00 28.0 30.0 248 11.7 0

2018 08.12.18 10:00 29.4 31.5 235 12.3 0

2018 08.12.18 11:00 30.8 33.0 223 12.9 0

2018 08.12.18 12:00 34.0 20.0 248 11.7 0

2018 08.12.18 13:00 35.7 21.0 260 12.3 0

2018 08.12.18 14:00 37.4 22.0 272 12.9 0

2018 08.12.18 15:00 35.0 21.0 225 11.7 0

2018 08.12.18 16:00 33.3 22.1 236 11.1 0

2018 08.12.18 17:00 31.5 23.1 248 10.5 0

2018 08.12.18 18:00 30.0 28.0 203 11.7 0

2018 08.12.18 19:00 28.5 26.6 213 11.1 0

2018 08.12.18 20:00 27.0 25.2 223 10.5 0

2018 08.12.18 21:00 26.0 28.0 203 11.7 0

2018 08.12.18 22:00 24.7 26.6 213 11.1 0

2018 08.12.18 23:00 23.4 25.2 223 10.5 0

2018 09.12.18 0:00 23.0 29.0 225 11.7 0

2018 09.12.18 1:00 24.2 27.6 214 12.3 0

2018 09.12.18 2:00 25.3 26.1 203 12.9 0

2018 09.12.18 3:00 22.0 30.0 225 11.7 0

2018 09.12.18 4:00 23.1 28.5 214 12.3 0

2018 09.12.18 5:00 24.2 27.0 203 12.9 0

2018 09.12.18 6:00 22.0 31.0 248 11.7 0

2018 09.12.18 7:00 23.1 32.6 235 12.3 0

A-186


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 09.12.18 8:00 24.2 34.1 223 12.9 0

2018 09.12.18 9:00 29.0 27.0 248 9.7 0

2018 09.12.18 10:00 30.5 28.4 235 10.2 0

2018 09.12.18 11:00 31.9 29.7 223 10.7 0

2018 09.12.18 12:00 35.0 18.0 248 7.7 0

2018 09.12.18 13:00 33.3 18.9 260 8.1 0

2018 09.12.18 14:00 31.5 19.8 272 8.5 0

2018 09.12.18 15:00 36.0 21.0 225 3.9 0

2018 09.12.18 16:00 34.2 22.1 236 3.7 0

2018 09.12.18 17:00 32.4 23.1 248 3.5 0

2018 09.12.18 18:00 32.0 30.0 203 7.7 0

2018 09.12.18 19:00 30.4 28.5 213 7.3 0

2018 09.12.18 20:00 28.8 27.0 223 6.9 0

2018 09.12.18 21:00 30.0 34.0 225 7.7 0

2018 09.12.18 22:00 31.5 32.3 236 7.3 0

2018 09.12.18 23:00 33.0 30.6 248 6.9 0

2018 10.12.18 0:00 27.0 37.0 225 7.7 0

2018 10.12.18 1:00 28.4 35.2 214 8.1 0

2018 10.12.18 2:00 29.7 33.3 203 8.5 0

2018 10.12.18 3:00 22.0 34.0 225 11.7 0

2018 10.12.18 4:00 23.1 35.7 214 12.3 0

2018 10.12.18 5:00 24.2 37.4 203 12.9 0

2018 10.12.18 6:00 22.0 35.0 248 11.7 0

2018 10.12.18 7:00 23.1 36.8 235 12.3 0

2018 10.12.18 8:00 24.2 38.5 223 12.9 0

2018 10.12.18 9:00 29.0 31.0 248 3.9 0

2018 10.12.18 10:00 27.6 32.6 235 4.1 0

2018 10.12.18 11:00 26.1 34.1 223 4.3 0

2018 10.12.18 12:00 35.0 20.0 315 0.0 0

2018 10.12.18 13:00 33.3 21.0 331 0.0 0

2018 10.12.18 14:00 31.5 22.0 347 0.0 0

2018 10.12.18 15:00 35.0 22.0 203 3.9 0

2018 10.12.18 16:00 33.3 20.9 213 3.7 0

2018 10.12.18 17:00 31.5 19.8 223 3.5 0

2018 10.12.18 18:00 31.0 32.0 270 7.7 0

2018 10.12.18 19:00 32.6 30.4 284 7.3 0

2018 10.12.18 20:00 34.1 28.8 297 6.9 0

2018 10.12.18 21:00 29.0 34.0 203 9.7 0

2018 10.12.18 22:00 30.5 32.3 213 9.2 0

2018 10.12.18 23:00 31.9 30.6 223 8.7 0

2018 11.12.18 0:00 23.0 36.0 203 11.7 0

2018 11.12.18 1:00 24.2 37.8 192 12.3 0

2018 11.12.18 2:00 25.3 39.6 182 12.9 0

2018 11.12.18 3:00 21.0 39.0 225 13.7 0

2018 11.12.18 4:00 22.1 41.0 214 14.4 0

2018 11.12.18 5:00 23.1 42.9 203 15.1 0

2018 11.12.18 6:00 22.0 40.0 270 11.7 0

2018 11.12.18 7:00 20.9 42.0 257 12.3 0

2018 11.12.18 8:00 19.8 44.0 243 12.9 0

A-187


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 11.12.18 9:00 28.0 31.0 248 11.7 0

2018 11.12.18 10:00 26.6 32.6 235 12.3 0

2018 11.12.18 11:00 25.2 34.1 223 12.9 0

2018 11.12.18 12:00 34.0 19.0 225 11.7 0

2018 11.12.18 13:00 32.3 18.1 236 12.3 0

2018 11.12.18 14:00 30.6 17.1 248 12.9 0

2018 11.12.18 15:00 35.0 21.0 203 11.7 0

2018 11.12.18 16:00 36.8 20.0 213 11.1 0

2018 11.12.18 17:00 38.5 18.9 223 10.5 0

2018 11.12.18 18:00 31.0 32.0 203 11.7 0

2018 11.12.18 19:00 32.6 30.4 213 11.1 0

2018 11.12.18 20:00 34.1 28.8 223 10.5 0

2018 11.12.18 21:00 27.0 37.0 180 11.7 0

2018 11.12.18 22:00 28.4 35.2 189 11.1 0

2018 11.12.18 23:00 29.7 33.3 198 10.5 0

2018 12.12.18 0:00 23.0 44.0 203 13.7 0

2018 12.12.18 1:00 24.2 46.2 192 14.4 0

2018 12.12.18 2:00 25.3 48.4 182 15.1 0

2018 12.12.18 3:00 22.0 51.0 203 15.5 0

2018 12.12.18 4:00 20.9 53.6 192 16.3 0

2018 12.12.18 5:00 19.8 56.1 182 17.1 0

2018 12.12.18 6:00 22.0 53.0 203 13.7 0

2018 12.12.18 7:00 20.9 55.7 192 14.4 0

2018 12.12.18 8:00 19.8 58.3 182 15.1 0

2018 12.12.18 9:00 28.0 45.0 225 13.7 0

2018 12.12.18 10:00 26.6 47.3 214 14.4 0

2018 12.12.18 11:00 25.2 49.5 203 15.1 0

2018 12.12.18 12:00 34.0 30.0 203 13.7 0

2018 12.12.18 13:00 35.7 28.5 213 14.4 0

2018 12.12.18 14:00 37.4 27.0 223 15.1 0

2018 12.12.18 15:00 35.0 28.0 293 11.7 0

2018 12.12.18 16:00 36.8 26.6 307 11.1 0

2018 12.12.18 17:00 38.5 25.2 322 10.5 0

2018 12.12.18 18:00 32.0 35.0 270 11.7 0

2018 12.12.18 19:00 33.6 33.3 284 11.1 0

2018 12.12.18 20:00 35.2 31.5 297 10.5 0

2018 12.12.18 21:00 29.0 36.0 315 13.7 0

2018 12.12.18 22:00 30.5 37.8 331 13.0 0

2018 12.12.18 23:00 31.9 39.6 347 12.3 0

2018 13.12.18 0:00 26.0 37.0 270 13.7 0

2018 13.12.18 1:00 24.7 38.9 257 14.4 0

2018 13.12.18 2:00 23.4 40.7 243 15.1 0

2018 13.12.18 3:00 21.0 37.0 203 13.7 0

2018 13.12.18 4:00 20.0 38.9 192 14.4 0

2018 13.12.18 5:00 18.9 40.7 182 15.1 0

2018 13.12.18 6:00 21.0 39.0 225 13.7 0

2018 13.12.18 7:00 20.0 41.0 214 14.4 0

2018 13.12.18 8:00 18.9 42.9 203 15.1 0

2018 13.12.18 9:00 27.0 35.0 203 13.7 0

A-188


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 13.12.18 10:00 28.4 33.3 192 14.4 0

2018 13.12.18 11:00 29.7 31.5 182 15.1 0

2018 13.12.18 12:00 33.0 24.0 203 13.7 0

2018 13.12.18 13:00 34.7 22.8 213 14.4 0

2018 13.12.18 14:00 36.3 21.6 223 15.1 0

2018 13.12.18 15:00 34.0 24.0 203 11.7 0

2018 13.12.18 16:00 35.7 22.8 213 11.1 0

2018 13.12.18 17:00 37.4 21.6 223 10.5 0

2018 13.12.18 18:00 30.0 31.0 180 11.7 0

2018 13.12.18 19:00 31.5 32.6 189 11.1 0

2018 13.12.18 20:00 33.0 34.1 198 10.5 0

2018 13.12.18 21:00 26.0 31.0 180 13.7 0

2018 13.12.18 22:00 24.7 32.6 189 13.0 0

2018 13.12.18 23:00 23.4 34.1 198 12.3 0

2018 14.12.18 0:00 22.0 31.0 203 15.5 0

2018 14.12.18 1:00 20.9 32.6 192 16.3 0

2018 14.12.18 2:00 19.8 34.1 182 17.1 0

2018 14.12.18 3:00 21.0 32.0 225 15.5 0

2018 14.12.18 4:00 20.0 33.6 214 16.3 0

2018 14.12.18 5:00 18.9 35.2 203 17.1 0

2018 14.12.18 6:00 21.0 36.0 225 17.5 0

2018 14.12.18 7:00 22.1 34.2 214 18.4 0

2018 14.12.18 8:00 23.1 32.4 203 19.3 0

2018 14.12.18 9:00 27.0 36.0 248 15.5 0

2018 14.12.18 10:00 28.4 34.2 235 16.3 0

2018 14.12.18 11:00 29.7 32.4 223 17.1 0

2018 14.12.18 12:00 34.0 23.0 270 15.5 0

2018 14.12.18 13:00 35.7 21.9 284 16.3 0

2018 14.12.18 14:00 37.4 20.7 297 17.1 0

2018 14.12.18 15:00 35.0 23.0 248 11.7 0

2018 14.12.18 16:00 36.8 21.9 260 11.1 0

2018 14.12.18 17:00 38.5 20.7 272 10.5 0

2018 14.12.18 18:00 31.0 30.0 225 11.7 0

2018 14.12.18 19:00 32.6 31.5 236 11.1 0

2018 14.12.18 20:00 34.1 33.0 248 10.5 0

2018 14.12.18 21:00 27.0 29.0 225 15.5 0

2018 14.12.18 22:00 25.7 30.5 236 14.7 0

2018 14.12.18 23:00 24.3 31.9 248 14.0 0

2018 15.12.18 0:00 23.0 32.0 225 17.5 0

2018 15.12.18 1:00 21.9 33.6 214 18.4 0

2018 15.12.18 2:00 20.7 35.2 203 19.3 0

2018 15.12.18 3:00 21.0 34.0 248 17.5 0

2018 15.12.18 4:00 20.0 35.7 235 18.4 0

2018 15.12.18 5:00 18.9 37.4 223 19.3 0

2018 15.12.18 6:00 22.0 36.0 248 15.5 0

2018 15.12.18 7:00 23.1 34.2 235 16.3 0

2018 15.12.18 8:00 24.2 32.4 223 17.1 0

2018 15.12.18 9:00 28.0 34.0 270 11.7 0

2018 15.12.18 10:00 29.4 32.3 257 12.3 0

A-189


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 15.12.18 11:00 30.8 30.6 243 12.9 0

2018 15.12.18 12:00 34.0 23.0 248 7.7 0

2018 15.12.18 13:00 35.7 21.9 260 8.1 0

2018 15.12.18 14:00 37.4 20.7 272 8.5 0

2018 15.12.18 15:00 35.0 24.0 225 7.7 0

2018 15.12.18 16:00 36.8 25.2 236 7.3 0

2018 15.12.18 17:00 38.5 26.4 248 6.9 0

2018 15.12.18 18:00 32.0 31.0 203 9.7 0

2018 15.12.18 19:00 30.4 32.6 213 9.2 0

2018 15.12.18 20:00 28.8 34.1 223 8.7 0

2018 15.12.18 21:00 29.0 30.0 203 13.7 0

2018 15.12.18 22:00 27.6 31.5 213 13.0 0

2018 15.12.18 23:00 26.1 33.0 297 12.3 0

2018 16.12.18 0:00 26.0 30.0 225 15.5 0

2018 16.12.18 1:00 24.7 31.5 214 16.3 0

2018 16.12.18 2:00 23.4 33.0 203 17.1 0

2018 16.12.18 3:00 22.0 32.0 225 13.7 0

2018 16.12.18 4:00 23.1 30.4 214 14.4 0

2018 16.12.18 5:00 24.2 28.8 203 15.1 0

2018 16.12.18 6:00 22.0 36.0 248 13.7 0

2018 16.12.18 7:00 23.1 34.2 235 14.4 0

2018 16.12.18 8:00 24.2 32.4 223 15.1 0

2018 16.12.18 9:00 28.0 35.0 248 11.7 0

2018 16.12.18 10:00 29.4 33.3 235 12.3 0

2018 16.12.18 11:00 30.8 31.5 223 12.9 0

2018 16.12.18 12:00 35.0 25.0 248 7.7 0

2018 16.12.18 13:00 36.8 26.3 260 8.1 0

2018 16.12.18 14:00 38.5 27.5 272 8.5 0

2018 16.12.18 15:00 36.0 27.0 315 3.9 0

2018 16.12.18 16:00 34.2 28.4 331 3.7 0

2018 16.12.18 17:00 32.4 29.7 347 3.5 0

2018 16.12.18 18:00 32.0 33.0 270 11.7 0

2018 16.12.18 19:00 30.4 34.7 284 11.1 0

2018 16.12.18 20:00 28.8 36.3 297 10.5 0

2018 16.12.18 21:00 29.0 31.0 270 13.7 0

2018 16.12.18 22:00 27.6 32.6 284 13.0 0

2018 16.12.18 23:00 26.1 34.1 297 12.3 0

2018 17.12.18 0:00 26.0 31.0 225 13.7 0

2018 17.12.18 1:00 27.3 29.5 214 14.4 0

2018 17.12.18 2:00 28.6 27.9 203 15.1 0

2018 17.12.18 3:00 22.0 33.0 225 13.7 0

2018 17.12.18 4:00 23.1 31.4 214 14.4 0

2018 17.12.18 5:00 24.2 29.7 203 15.1 0

2018 17.12.18 6:00 21.0 36.0 225 13.7 0

2018 17.12.18 7:00 22.1 34.2 214 14.4 0

2018 17.12.18 8:00 23.1 32.4 203 15.1 0

2018 17.12.18 9:00 27.0 33.0 225 15.5 0

2018 17.12.18 10:00 28.4 31.4 214 16.3 0

2018 17.12.18 11:00 29.7 29.7 203 17.1 0

A-190


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 17.12.18 12:00 33.0 23.0 225 17.5 0

2018 17.12.18 13:00 31.4 24.2 236 18.4 0

2018 17.12.18 14:00 29.7 25.3 248 19.3 0

2018 17.12.18 15:00 34.0 25.0 270 15.5 0

2018 17.12.18 16:00 32.3 26.3 284 14.7 0

2018 17.12.18 17:00 30.6 27.5 297 14.0 0

2018 17.12.18 18:00 31.0 35.0 270 9.7 0

2018 17.12.18 19:00 29.5 36.8 284 9.2 0

2018 17.12.18 20:00 27.9 38.5 297 8.7 0

2018 17.12.18 21:00 28.0 37.0 270 9.7 0

2018 17.12.18 22:00 29.4 38.9 284 9.2 0

2018 17.12.18 23:00 30.8 40.7 297 8.7 0

2018 18.12.18 0:00 23.0 39.0 270 11.7 0

2018 18.12.18 1:00 24.2 37.1 257 12.3 0

2018 18.12.18 2:00 25.3 35.1 243 12.9 0

2018 18.12.18 3:00 21.0 42.0 270 13.7 0

2018 18.12.18 4:00 22.1 39.9 257 14.4 0

2018 18.12.18 5:00 23.1 37.8 243 15.1 0

2018 18.12.18 6:00 22.0 44.0 225 11.7 0

2018 18.12.18 7:00 23.1 41.8 214 12.3 0

2018 18.12.18 8:00 24.2 39.6 203 12.9 0

2018 18.12.18 9:00 28.0 37.0 225 9.7 0

2018 18.12.18 10:00 26.6 38.9 214 10.2 0

2018 18.12.18 11:00 25.2 40.7 203 10.7 0

2018 18.12.18 12:00 34.0 26.0 315 7.7 0

2018 18.12.18 13:00 32.3 27.3 331 8.1 0

2018 18.12.18 14:00 30.6 28.6 347 8.5 0

2018 18.12.18 15:00 35.0 27.0 180 7.7 0

2018 18.12.18 16:00 33.3 28.4 189 7.3 0

2018 18.12.18 17:00 31.5 29.7 198 6.9 0

2018 18.12.18 18:00 31.0 36.0 270 9.7 0

2018 18.12.18 19:00 32.6 37.8 284 9.2 0

2018 18.12.18 20:00 34.1 39.6 74 8.7 0

2018 18.12.18 21:00 27.0 37.0 270 11.7 0

2018 18.12.18 22:00 28.4 35.2 284 11.1 0

2018 18.12.18 23:00 29.7 33.3 297 10.5 0

2018 19.12.18 0:00 23.0 38.0 270 11.7 0

2018 19.12.18 1:00 24.2 36.1 257 12.3 0

2018 19.12.18 2:00 25.3 34.2 243 12.9 0

2018 19.12.18 3:00 21.0 39.0 225 11.7 0

2018 19.12.18 4:00 22.1 37.1 214 12.3 0

2018 19.12.18 5:00 23.1 35.1 203 12.9 0

2018 19.12.18 6:00 21.0 42.0 225 11.7 0

2018 19.12.18 7:00 20.0 44.1 214 12.3 0

2018 19.12.18 8:00 18.9 46.2 203 12.9 0

2018 19.12.18 9:00 27.0 36.0 248 9.7 0

2018 19.12.18 10:00 25.7 37.8 235 10.2 0

2018 19.12.18 11:00 24.3 39.6 223 10.7 0

2018 19.12.18 12:00 33.0 25.0 225 9.7 0

A-191


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 19.12.18 13:00 31.4 26.3 236 10.2 0

2018 19.12.18 14:00 29.7 27.5 248 10.7 0

2018 19.12.18 15:00 33.0 25.0 270 11.7 0

2018 19.12.18 16:00 34.7 26.3 284 11.1 0

2018 19.12.18 17:00 36.3 27.5 297 10.5 0

2018 19.12.18 18:00 29.0 33.0 270 11.7 0

2018 19.12.18 19:00 30.5 31.4 284 11.1 0

2018 19.12.18 20:00 31.9 29.7 297 10.5 0

2018 19.12.18 21:00 26.0 36.0 270 13.7 0

2018 19.12.18 22:00 27.3 34.2 284 13.0 0

2018 19.12.18 23:00 28.6 32.4 297 12.3 0

2018 20.12.18 0:00 22.0 38.0 225 13.7 0

2018 20.12.18 1:00 23.1 36.1 214 14.4 0

2018 20.12.18 2:00 24.2 34.2 203 15.1 0

2018 20.12.18 3:00 21.0 38.0 225 13.7 0

2018 20.12.18 4:00 20.0 36.1 214 14.4 0

2018 20.12.18 5:00 18.9 34.2 203 15.1 0

2018 20.12.18 6:00 20.0 38.0 225 13.7 0

2018 20.12.18 7:00 19.0 39.9 214 14.4 0

2018 20.12.18 8:00 18.0 41.8 203 15.1 0

2018 20.12.18 9:00 24.0 33.0 248 15.5 0

2018 20.12.18 10:00 22.8 34.7 235 16.3 0

2018 20.12.18 11:00 21.6 36.3 223 17.1 0

2018 20.12.18 12:00 32.0 21.0 248 17.5 0

2018 20.12.18 13:00 33.6 22.1 260 18.4 0

2018 20.12.18 14:00 35.2 23.1 272 19.3 0

2018 20.12.18 15:00 33.0 20.0 225 15.5 0

2018 20.12.18 16:00 34.7 21.0 236 14.7 0

2018 20.12.18 17:00 36.3 22.0 248 14.0 0

2018 20.12.18 18:00 29.0 27.0 270 13.7 0

2018 20.12.18 19:00 30.5 25.7 284 13.0 0

2018 20.12.18 20:00 31.9 24.3 297 12.3 0

2018 20.12.18 21:00 27.0 27.0 225 15.5 0

2018 20.12.18 22:00 28.4 25.7 236 14.7 0

2018 20.12.18 23:00 29.7 24.3 248 14.0 0

2018 21.12.18 0:00 23.0 28.0 248 15.5 0

2018 21.12.18 1:00 21.9 26.6 235 16.3 0

2018 21.12.18 2:00 20.7 25.2 223 17.1 0

2018 21.12.18 3:00 20.0 30.0 248 13.7 0

2018 21.12.18 4:00 19.0 31.5 235 14.4 0

2018 21.12.18 5:00 18.0 33.0 223 15.1 0

2018 21.12.18 6:00 20.0 35.0 248 11.7 0

2018 21.12.18 7:00 19.0 36.8 235 12.3 0

2018 21.12.18 8:00 18.0 38.5 223 12.9 0

2018 21.12.18 9:00 26.0 32.0 248 9.7 0

2018 21.12.18 10:00 27.3 33.6 235 10.2 0

2018 21.12.18 11:00 28.6 35.2 223 10.7 0

2018 21.12.18 12:00 34.0 20.0 225 9.7 0

2018 21.12.18 13:00 35.7 21.0 236 10.2 0

A-192


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 21.12.18 14:00 37.4 22.0 248 10.7 0

2018 21.12.18 15:00 35.0 20.0 270 9.7 0

2018 21.12.18 16:00 36.8 19.0 284 9.2 0

2018 21.12.18 17:00 38.5 18.0 297 8.7 0

2018 21.12.18 18:00 31.0 28.0 270 9.7 0

2018 21.12.18 19:00 32.6 26.6 284 9.2 0

2018 21.12.18 20:00 34.1 25.2 297 8.7 0

2018 21.12.18 21:00 27.0 29.0 270 11.7 0

2018 21.12.18 22:00 25.7 27.6 284 11.1 0

2018 21.12.18 23:00 24.3 26.1 297 10.5 0

2018 22.12.18 0:00 22.0 30.0 270 11.7 0

2018 22.12.18 1:00 20.9 31.5 257 12.3 0

2018 22.12.18 2:00 19.8 33.0 243 12.9 0

2018 22.12.18 3:00 21.0 33.0 270 11.7 0

2018 22.12.18 4:00 20.0 34.7 257 12.3 0

2018 22.12.18 5:00 18.9 36.3 243 12.9 0

2018 22.12.18 6:00 21.0 34.0 225 11.7 0

2018 22.12.18 7:00 22.1 35.7 214 12.3 0

2018 22.12.18 8:00 23.1 37.4 203 12.9 0

2018 22.12.18 9:00 27.0 25.0 225 11.7 0

2018 22.12.18 10:00 28.4 26.3 214 12.3 0

2018 22.12.18 11:00 29.7 27.5 203 12.9 0

2018 22.12.18 12:00 34.0 16.0 225 11.7 0

2018 22.12.18 13:00 35.7 15.2 236 12.3 0

2018 22.12.18 14:00 37.4 14.4 248 12.9 0

2018 22.12.18 15:00 34.0 17.0 270 11.7 0

2018 22.12.18 16:00 35.7 16.2 284 11.1 0

2018 22.12.18 17:00 37.4 15.3 297 10.5 0

2018 22.12.18 18:00 29.0 23.0 180 11.7 0

2018 22.12.18 19:00 27.6 21.9 189 11.1 0

2018 22.12.18 20:00 26.1 20.7 198 10.5 0

2018 22.12.18 21:00 26.0 24.0 270 11.7 0

2018 22.12.18 22:00 24.7 22.8 284 11.1 0

2018 22.12.18 23:00 23.4 21.6 297 10.5 0

2018 23.12.18 0:00 23.0 25.0 270 11.7 0

2018 23.12.18 1:00 21.9 26.3 257 12.3 0

2018 23.12.18 2:00 20.7 27.5 243 12.9 0

2018 23.12.18 3:00 21.0 26.0 225 11.7 0

2018 23.12.18 4:00 22.1 27.3 214 12.3 0

2018 23.12.18 5:00 23.1 28.6 203 12.9 0

2018 23.12.18 6:00 22.0 27.0 225 9.7 0

2018 23.12.18 7:00 23.1 28.4 214 10.2 0

2018 23.12.18 8:00 24.2 29.7 203 10.7 0

2018 23.12.18 9:00 28.0 24.0 225 7.7 0

2018 23.12.18 10:00 29.4 25.2 214 8.1 0

2018 23.12.18 11:00 30.8 26.4 203 8.5 0

2018 23.12.18 12:00 35.0 15.0 315 3.9 0

2018 23.12.18 13:00 36.8 14.3 331 4.1 0

2018 23.12.18 14:00 38.5 13.5 347 4.3 0

A-193


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 23.12.18 15:00 36.0 17.0 158 7.7 0

2018 23.12.18 16:00 34.2 16.2 165 7.3 0

2018 23.12.18 17:00 32.4 15.3 173 6.9 0

2018 23.12.18 18:00 31.0 25.0 158 9.7 0

2018 23.12.18 19:00 29.5 23.8 165 9.2 0

2018 23.12.18 20:00 27.9 22.5 173 8.7 0

2018 23.12.18 21:00 27.0 26.0 180 11.7 0

2018 23.12.18 22:00 25.7 27.3 189 11.1 0

2018 23.12.18 23:00 24.3 28.6 198 10.5 0

2018 24.12.18 0:00 22.0 27.0 68 13.7 0

2018 24.12.18 1:00 23.1 28.4 64 14.4 0

2018 24.12.18 2:00 24.2 29.7 61 15.1 0

2018 24.12.18 3:00 20.0 29.0 270 11.7 0

2018 24.12.18 4:00 21.0 30.5 257 12.3 0

2018 24.12.18 5:00 22.0 31.9 243 12.9 0

2018 24.12.18 6:00 21.0 31.0 270 9.7 0

2018 24.12.18 7:00 22.1 32.6 257 10.2 0

2018 24.12.18 8:00 23.1 34.1 243 10.7 0

2018 24.12.18 9:00 28.0 27.0 293 7.7 0

2018 24.12.18 10:00 29.4 25.7 278 8.1 0

2018 24.12.18 11:00 30.8 24.3 263 8.5 0

2018 24.12.18 12:00 33.0 16.0 158 9.7 0

2018 24.12.18 13:00 31.4 15.2 165 10.2 0

2018 24.12.18 14:00 29.7 14.4 173 10.7 0

2018 24.12.18 15:00 35.0 18.0 158 7.7 0

2018 24.12.18 16:00 33.3 17.1 165 7.3 0

2018 24.12.18 17:00 31.5 16.2 173 6.9 0

2018 24.12.18 18:00 31.0 27.0 158 7.7 0

2018 24.12.18 19:00 29.5 28.4 165 7.3 0

2018 24.12.18 20:00 27.9 29.7 173 6.9 0

2018 24.12.18 21:00 26.0 34.0 158 9.7 0

2018 24.12.18 22:00 27.3 35.7 165 9.2 0

2018 24.12.18 23:00 28.6 37.4 173 8.7 0

2018 25.12.18 0:00 22.0 47.0 45 11.7 0

2018 25.12.18 1:00 23.1 49.4 43 12.3 0

2018 25.12.18 2:00 24.2 51.7 41 12.9 0

2018 25.12.18 3:00 21.0 53.0 180 11.7 0

2018 25.12.18 4:00 22.1 55.7 171 12.3 0

2018 25.12.18 5:00 23.1 58.3 162 12.9 0

2018 25.12.18 6:00 21.0 50.0 270 11.7 0

2018 25.12.18 7:00 22.1 47.5 257 12.3 0

2018 25.12.18 8:00 23.1 45.0 182 12.9 0

2018 25.12.18 9:00 26.0 44.0 203 13.7 0

2018 25.12.18 10:00 24.7 41.8 192 14.4 0

2018 25.12.18 11:00 23.4 39.6 182 15.1 0

2018 25.12.18 12:00 32.0 23.0 225 21.4 0

2018 25.12.18 13:00 30.4 21.9 236 22.5 0

2018 25.12.18 14:00 28.8 20.7 248 23.5 0

2018 25.12.18 15:00 32.0 18.0 225 21.4 0

A-194


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 25.12.18 16:00 30.4 17.1 236 20.3 0

2018 25.12.18 17:00 28.8 16.2 248 19.3 0

2018 25.12.18 18:00 30.0 20.0 225 15.5 0

2018 25.12.18 19:00 31.5 21.0 236 14.7 0

2018 25.12.18 20:00 33.0 22.0 248 14.0 0

2018 25.12.18 21:00 28.0 16.0 225 17.5 0

2018 25.12.18 22:00 29.4 16.8 236 16.6 0

2018 25.12.18 23:00 30.8 17.6 248 15.8 0

2018 26.12.18 0:00 23.0 16.0 225 21.4 0

2018 26.12.18 1:00 24.2 16.8 214 22.5 0

2018 26.12.18 2:00 25.3 17.6 203 23.5 0

2018 26.12.18 3:00 17.0 19.0 225 21.4 0

2018 26.12.18 4:00 17.9 20.0 214 22.5 0

2018 26.12.18 5:00 18.7 20.9 203 23.5 0

2018 26.12.18 6:00 17.0 20.0 225 23.4 0

2018 26.12.18 7:00 16.2 19.0 214 24.6 0

2018 26.12.18 8:00 15.3 18.0 203 25.7 0

2018 26.12.18 9:00 21.0 21.0 225 25.1 0

2018 26.12.18 10:00 20.0 20.0 214 26.4 0

2018 26.12.18 11:00 18.9 18.9 203 27.6 0

2018 26.12.18 12:00 29.0 14.0 248 25.1 0

2018 26.12.18 13:00 27.6 13.3 260 26.4 0

2018 26.12.18 14:00 26.1 12.6 272 27.6 0

2018 26.12.18 15:00 31.0 15.0 225 17.5 0

2018 26.12.18 16:00 32.6 15.8 236 16.6 0

2018 26.12.18 17:00 34.1 16.5 248 15.8 0

2018 26.12.18 18:00 28.0 21.0 203 15.5 0

2018 26.12.18 19:00 29.4 22.1 213 14.7 0

2018 26.12.18 20:00 30.8 23.1 223 14.0 0

2018 26.12.18 21:00 26.0 23.0 225 15.5 0

2018 26.12.18 22:00 27.3 24.2 236 14.7 0

2018 26.12.18 23:00 28.6 25.3 248 14.0 0

2018 27.12.18 0:00 22.0 28.0 225 15.5 0

2018 27.12.18 1:00 23.1 29.4 214 16.3 0

2018 27.12.18 2:00 24.2 30.8 203 17.1 0

2018 27.12.18 3:00 19.0 34.0 225 15.5 0

2018 27.12.18 4:00 20.0 32.3 214 16.3 0

2018 27.12.18 5:00 20.9 30.6 203 17.1 0

2018 27.12.18 6:00 18.0 38.0 225 17.5 0

2018 27.12.18 7:00 17.1 36.1 214 18.4 0

2018 27.12.18 8:00 16.2 34.2 203 19.3 0

2018 27.12.18 9:00 21.0 35.0 248 21.4 0

2018 27.12.18 10:00 20.0 33.3 235 22.5 0

2018 27.12.18 11:00 18.9 31.5 223 23.5 0

2018 27.12.18 12:00 30.0 20.0 248 21.4 0

2018 27.12.18 13:00 28.5 21.0 260 22.5 0

2018 27.12.18 14:00 27.0 22.0 272 23.5 0

2018 27.12.18 15:00 32.0 20.0 248 17.5 0

2018 27.12.18 16:00 33.6 21.0 260 16.6 0

A-195


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 27.12.18 17:00 35.2 22.0 272 15.8 0

2018 27.12.18 18:00 30.0 27.0 225 13.7 0

2018 27.12.18 19:00 31.5 28.4 236 13.0 0

2018 27.12.18 20:00 33.0 29.7 248 12.3 0

2018 27.12.18 21:00 27.0 29.0 225 15.5 0

2018 27.12.18 22:00 28.4 30.5 236 14.7 0

2018 27.12.18 23:00 29.7 31.9 248 14.0 0

2018 28.12.18 0:00 22.0 31.0 248 17.5 0

2018 28.12.18 1:00 23.1 29.5 235 18.4 0

2018 28.12.18 2:00 24.2 27.9 223 19.3 0

2018 28.12.18 3:00 19.0 36.0 248 17.5 0

2018 28.12.18 4:00 18.1 34.2 235 18.4 0

2018 28.12.18 5:00 17.1 32.4 223 19.3 0

2018 28.12.18 6:00 19.0 43.0 248 15.5 0

2018 28.12.18 7:00 18.1 40.9 235 16.3 0

2018 28.12.18 8:00 17.1 38.7 223 17.1 0

2018 28.12.18 9:00 24.0 41.0 248 15.5 0

2018 28.12.18 10:00 22.8 39.0 235 16.3 0

2018 28.12.18 11:00 21.6 36.9 223 17.1 0

2018 28.12.18 12:00 33.0 24.0 270 15.5 0

2018 28.12.18 13:00 34.7 25.2 284 16.3 0

2018 28.12.18 14:00 36.3 26.4 297 17.1 0

2018 28.12.18 15:00 35.0 22.0 248 11.7 0

2018 28.12.18 16:00 36.8 23.1 260 11.1 0

2018 28.12.18 17:00 38.5 24.2 272 10.5 0

2018 28.12.18 18:00 32.0 29.0 225 11.7 0

2018 28.12.18 19:00 33.6 30.5 236 11.1 0

2018 28.12.18 20:00 35.2 31.9 248 10.5 0

2018 28.12.18 21:00 29.0 30.0 225 15.5 0

2018 28.12.18 22:00 30.5 31.5 236 14.7 0

2018 28.12.18 23:00 31.9 33.0 248 14.0 0

2018 29.12.18 0:00 26.0 31.0 248 13.7 0

2018 29.12.18 1:00 24.7 29.5 235 14.4 0

2018 29.12.18 2:00 23.4 27.9 223 15.1 0

2018 29.12.18 3:00 21.0 34.0 248 11.7 0

2018 29.12.18 4:00 20.0 32.3 235 12.3 0

2018 29.12.18 5:00 18.9 30.6 223 12.9 0

2018 29.12.18 6:00 21.0 37.0 225 9.7 0

2018 29.12.18 7:00 20.0 35.2 214 10.2 0

2018 29.12.18 8:00 18.9 33.3 203 10.7 0

2018 29.12.18 9:00 28.0 33.0 225 9.7 0

2018 29.12.18 10:00 29.4 34.7 214 10.2 0

2018 29.12.18 11:00 30.8 36.3 203 10.7 0

2018 29.12.18 12:00 35.0 21.0 225 9.7 0

2018 29.12.18 13:00 36.8 22.1 236 10.2 0

2018 29.12.18 14:00 38.5 23.1 248 10.7 0

2018 29.12.18 15:00 36.0 20.0 225 7.7 0

2018 29.12.18 16:00 37.8 21.0 236 7.3 0

2018 29.12.18 17:00 39.6 22.0 248 6.9 0

A-196


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 29.12.18 18:00 33.0 28.0 203 9.7 0

2018 29.12.18 19:00 34.7 29.4 213 9.2 0

2018 29.12.18 20:00 36.3 30.8 223 8.7 0

2018 29.12.18 21:00 30.0 28.0 203 13.7 0

2018 29.12.18 22:00 28.5 26.6 213 13.0 0

2018 29.12.18 23:00 27.0 25.2 223 12.3 0

2018 30.12.18 0:00 27.0 29.0 225 13.7 0

2018 30.12.18 1:00 25.7 27.6 214 14.4 0

2018 30.12.18 2:00 24.3 26.1 203 15.1 0

2018 30.12.18 3:00 22.0 30.0 225 11.7 0

2018 30.12.18 4:00 20.9 28.5 214 12.3 0

2018 30.12.18 5:00 19.8 27.0 203 12.9 0

2018 30.12.18 6:00 22.0 33.0 225 9.7 0

2018 30.12.18 7:00 23.1 34.7 214 10.2 0

2018 30.12.18 8:00 24.2 36.3 203 10.7 0

2018 30.12.18 9:00 29.0 32.0 248 7.7 0

2018 30.12.18 10:00 30.5 33.6 235 8.1 0

2018 30.12.18 11:00 31.9 35.2 223 8.5 0

2018 30.12.18 12:00 36.0 19.0 248 0.0 0

2018 30.12.18 13:00 37.8 20.0 260 0.0 0

2018 30.12.18 14:00 39.6 20.9 272 0.0 0

2018 30.12.18 15:00 37.0 21.0 315 0.0 0

2018 30.12.18 16:00 38.9 22.1 331 0.0 0

2018 30.12.18 17:00 40.7 23.1 347 0.0 0

2018 30.12.18 18:00 33.0 31.0 135 7.7 0

2018 30.12.18 19:00 31.4 29.5 142 7.3 0

2018 30.12.18 20:00 29.7 27.9 149 6.9 0

2018 30.12.18 21:00 31.0 30.0 45 11.7 0

2018 30.12.18 22:00 29.5 28.5 47 11.1 0

2018 30.12.18 23:00 27.9 27.0 50 10.5 0

2018 31.12.18 0:00 26.0 31.0 203 13.7 0

2018 31.12.18 1:00 24.7 29.5 192 14.4 0

2018 31.12.18 2:00 23.4 27.9 182 15.1 0

2018 31.12.18 3:00 22.0 33.0 225 13.7 0

2018 31.12.18 4:00 23.1 31.4 214 14.4 0

2018 31.12.18 5:00 24.2 29.7 203 15.1 0

2018 31.12.18 6:00 23.0 36.0 225 11.7 0

2018 31.12.18 7:00 24.2 37.8 214 12.3 0

2018 31.12.18 8:00 25.3 39.6 203 12.9 0

2018 31.12.18 9:00 30.0 34.0 225 3.9 0

2018 31.12.18 10:00 31.5 35.7 214 4.1 0

2018 31.12.18 11:00 33.0 37.4 203 4.3 0

2018 31.12.18 12:00 37.0 21.0 293 0.0 0

2018 31.12.18 13:00 38.9 22.1 307 0.0 0

2018 31.12.18 14:00 40.7 23.1 322 0.0 0

2018 31.12.18 15:00 36.0 22.0 90 7.7 0

2018 31.12.18 16:00 34.2 23.1 95 7.3 0

2018 31.12.18 17:00 32.4 24.2 99 6.9 0

2018 31.12.18 18:00 32.0 31.0 90 9.7 0

A-197


(0C)

Humidity

(%)

Wind Direction

(Degree)

Wind Speed

(Km/hr.)

Rainfall

(mm)

2018 31.12.18 19:00 30.4 29.5 95 9.2 0

2018 31.12.18 20:00 28.8 27.9 99 8.7 0

2018 31.12.18 21:00 28.0 36.0 113 9.7 0

2018 31.12.18 22:00 26.6 34.2 118 9.2 0

2018 31.12.18 23:00 25.2 32.4 124 8.7 0

A-198

Annexure-X Detailed AAQM, Ground Water, Surface

Water, Soil, Noise Result Tables

SAN ENVIROTECH PVT, LTD, Acclred3xed QCI-NABET Consultant

MoEF Recogneed Envkronrnentai taborarory Uodcr EP J k t , 1986 GPCB Recognized Schedule43 Auditors

I S 0 900%. 14CK$1& QkjSAS 18002 Certified Company GSTlN: 24AASCS5415CXZR

AMBIENT AIR QUALITY

Analyzed By : B& J

Max . Min

98 Percentile - 75 Percentile

50 Percentile 25 Percentile Average

PM-10 (pg/m3)

74.0 59.9

Phone No. 079-26583O77 Cell: 9825007201/9723766007 4011402{423/424/324* Medicine Market* Opp. Shefali Center, Paldi Cross Road, Ahmdabad.

73.3 70.9 68.3 66.0 67.9 *

PM-2.5 (pg/m3)

44.5 35.0 44.5 41.8 39.6 38.0 39.9

(pg/m3)

18.0 12.5

No2 (p9/m3)

21.4 14.4

18.0 16.8 15.3 14.7 15.5

21.1 19.7 18.1 16.8 18.1

A-199

A-200

ENVPROTECH PVT- LTD- A c c ~ d i r e d QCI-NABET Consulant

M o E F Recognized E n w i r o a m e n t a k Labaratory UnUer E P Act. 19S6 GPCB Recognized Schedule-il Auditors

#SO 9001,14<H)1& OHSAS 18001 Cemfied Company GSTIN: 24MGCS5415CZZR

AMBIENT AIR QUALITY

Samplinq Location A3 : Padra Villaqe

Monitorinq 02.10.18 05.10.18 09.10.18

CLOCK HOURS ~ ~ - l O ( p g / r n ~ )

24 HOURS (pg/m3)

67.3 61.6 70.4

Analyzed By : ad Max

CO Date of 1 00-08 1 08-16 ' 1 16-24 1 00-08 1 08-16 1 16-24 / 00-08 1 08-16 1 16-24 / 00-08 1 08-16 1 16-24 ~~-2 . ! i (pg / rn~)

H C

77.4 68.3 76.5

Min 98 Percentile 75 Percentile 50 Percentile 25 Percentile Average

PM-10 (pg/rn3)

74.8

s02(pg/rn3) I ~ 0 2 ( p g / r n ~ )

71.6 65.6 72.4

Phone No. 039-26583077 Cell: 98250~?201/9?23766007 ml/4a2/;123/424/324, Medicine Market, Opp. Shefaii Center, Pal& Cross Rmd, A h m d a b d .

54.3 74.7 71.8 68.1 63.7 67.2

PM-2.5 (pg/m3)

42.7

30.6 27.7 35.1

29.4 41.4 38.8 37.6 35.9 37.0

SO2 (pg/m3)

15.8

NO2 (pg/m3)

20.7

46.1 49.6 43.4

10.8 15.8 14.8 13.9 12.8 13.7

13.3 20.2 18.3 16.8 15.3 16.9

40.8 35.2 37.7

10.7 11.1 8.8

15.4 17.8 14.2

12.8 14.6 10.9

11.8 12.8 10.3

17.7 18.1 16.2

15.0 13.3 14.3

1154 1188 1199

1201 1236 1248

A-201

SAN ENVBROTECH P W T - L T D - Accredited QCI-NABET Consultant

MoEF Recognized Envaronmentaf L a b o r a P o s y Under EP Act, 1986 GPCS Recognized Sched ule-31 Aud itorr

IS0 SOOH, 14009 & OlHSrFIS 18002 Cebtineu Company GSTIM: 2 4 M G CSS15CXZR

AMBIENT AIR QUALITY

I PM-10 (ug/m3) I PM-2.5 (ug/m3) 1 102 (ug/m3) I NO2 (ug/m31

Min 59.0 34.6 12.9 14.4 98 Percentile 75.6 50.0 19.1 21.9 75 Percentile 69.2 44.0 17.6 17.8 50 Percentile 66.9 41.9 16.5 16.9 25 Percentile 64.0 . 38.9 14.8 16.0 Average 67.1 41.8 16.3 17.4

I -. -. - -. - - - - -. -- - -

401/402/423/424/324, Medicine Market. Opp. Shefali Center. Paldi Uoss Road, ~ h k d a b a d .

Max Analyzed By: ,&$a 76.3 51 .? 19.3 3 3 3

A-202

ENVEROTECH PVT, LTD- Accredited QCI-NABET Consultant

MaEF Recognized Enviroslrnental Laboratory Under EP AcZ,

GPCS Recognized Schedulell Auditors I S 8 W O B . 14001 & OHSAS 18001 cCemned Company

GST1N: 24AAGCS5415CXZR

AMBIENT AIR QUALITY

PM-10 (pg/m3) PM-2.5 (pg/m3) (pg/m3) NO2 (v9/m3)

Max 76.2 44.0 15.9 20.5 Analyzed By : r

Mln 64.3 29.4 11.2 12.4 98 Percentile 76.1 42.6 15.8 20.2 75 Percent~le 73.7 38.9 14.9 18.2 50 Percentile 71.6 37.8 13.6 15.7 Authorized by:

25 Percentile 68.8 - 35.9 12.7 i4.0 Averaqe 71.0 37.3 13.6 16.0

Phone No. 079-2fiS83077 Cdl: 98250072~3/97237~07 Ernail: - M3[4Q2f42364241324, Medicine Market, Opp. Shefali Cente~, Pa%& O m s Rwd, Ahanedabad-

A-203

ENVIROTECH PVTl. L T D S Accredfted QCI-MABET Cz;pnsultant

M o E F Recognized Environmental tatxxatory Under EP Act, 1986 GPCS Recognize& Schedule41 Awdirars

I S 0 9001.14001 & OHSAS 1&00P Certified Company CSTIM: 24AAGCS5415C1ZR

AMBIENT AIR QUALITY

Sampling Location A6 : Ranu Village

Analyzed By : C

Authorized by: v,

Phone No. 079-2f583077 - CeU: 98~d1720d~972376W)87 Ernaill: .48%1402/423/424/324, Medicine Market, Cdpp. Shefati Center-, Paldi Cams Road, Ahmdabad.

Max

Min 98 Percentile 75 Percentile 50 Percentile 25 Percentile Average

SO1 (pg/m3)

18.3 10.2 17.4 13.4 12.6 11.4 13.0

NO1 (pg/m3)

23.1 11.6 22.0 16.7 15.3 14.0 15.8

PM-10 (pg/m3)

76.0 61.3 75.7 72.5 68.9 65.6 .

68.9

PM-2.5 (pg/m3)

47.1 31.7 46.3 40.0 37.6 33.7 37.6

A-204

SAN ENVIROTECH PVTill TTD, Accredited QCI-MABET Ca4nsulranZ

MoEF Recognized Environmental LaEwxafckry Under EP Act, 19&6 GPCB Recognized Schedule-ll Auditors

IS0 9009,14001 & Q H S M 1&004. CertifkqZ Company GSTIN: 24AAGCS5rl.15CPZR

AMBIENT AIR QUALITY

Sampling Location A7 : Bhsj Village.

Monitoring 1

Phone Wo. 079-26583077 CeH: 9825007203 /9?23766007

CLOCK HOURS

03.10.18 1 64.4 1 73.3 1 67.1 1 31.5 1 47.9 1 39.6 ( 11.8 1 14.7 1 12.7 1 10.3 / 17.0 1 14.4

Max Min 98 Percentile 75 Percentile 50 Percentile 25 Percentile Average

Analyzed By :,$Ab*

~ ~ - 1 0 ( p g / m ~ ) 24 HOURS

(vg/m3)

1206 1 1167

- 401/402/423/424#32r1. Medicine Market, Opp. Shefali Center. Paldi Crou Road, ~hmedabad.

CO

77.7 61.9 76.4 72.1 69.7 67.0 *

69.6

' Date of 1 00-08 1 08-16 1 16-24 1 00-08 1 08-16 1 '16-24 1 00-08 1 08-16 1 '16-24 1 00-08 1 08-16 1 ' 16-24 PM-2.5(pg/m3)

H C

49.3 35.2 47.0 42.6 41.3 39.6 41.1

S02(pgJm3) N02@gJm3)

16.9 11.4 16.4 14.5 13.7 13.2 13.8

20.8 13.7 19.7 16.8

. 15.3 14.4 15.8

A-205

SAN ENVlROTECH PVT, LTD, Accredixed El--BET Consulrant

MoEF Wecognized Environmental Laboratory Uncfer E P Act, 19&6 GPC5 Recognized Schedule-ll Audttors

158 9a01.140018r OD-ISAS 18001 Certrfcecd Company GSTIN: 24AAGCS5415C1ZR

AMBIENT AIR QUALITY

Sampling Location A8 : Vishrampura Villeqe CLOCK HOURS

~ ~ - l O ( p g / m ~ ) 24 HOURS

(pg/m3)

Analyzed By : &'* J -

Authorized by:

Max

Min 98 Percentile 75 Percent~le 50 Percent~le 25 Percent~le Average

CO

Phne No. 079-26583077 ~ e t f ! : Emaif: &32/4~21423/424f 324, Medicine Market, Opp. Shefali Center' PaMi Crass Rwd, Ahmedabad.

Date of 1 00-08 1 08-16' 1 16-24 1 00-08 1 08-16 1 16-24 1 00-08 1 08-16 1 '16-24 1 00-08 1 08-16 1 ' 16-24 'HC

PM-10 (pg/m3)

76.6 66.2 76.5 72.8 70.6 68.3 - 70.7

N01(pq/m3) ~ ~ - 2 . 5 ( p q / m ~ ) S0z(pq/m3)

NO2 (IJg/m3)

26.5 13.1 23.6 17.8 16.0 15.1 16.7

PM-2.5 (pg/m3)

45.4 34.3 45.0 42.9 38.5 36.2 39.5

So2 (pg/m3)

24.2 11.5 20.8 16.1 14.6 13.5 14.9

A-206

S A M EMVIROTECH PVT- LTD, Accredircd QCI-NASET Consultant

MoEF R e c o g n i z e d EnwironrnentaE Laboratory U n d e r E P Act, 19843 GPC8 R e c o g n i z e d Schedule41 Auditem

IS0 9001,14001 & OHSAS 18001 CertjRa3 Company GSnN: 24AAGCS5Q15CZZR

ANALYSIS REPORT OF GROUND WATER SAMPLE

Description of sample

Sample Collected by

Quantity /No. of Sample

:

:

:

Ground Water

San Envirotech Pvt.Ltd.

3 Lit x 08 Nos.

Lab I D Code Report Issue Date PackingISeal

Test Parameters & Method

: : :

:

SEPL/RPP/GWS (1 t o 8)-201812 26.12.2018 Sealed wi th Proper Identif ication

As per result Table, Method of Test : I S 3025

A-207

S A N ENVIROTECH PVTL LTDI Accredited QGI-MABET Consultant

1 WOEF RecognPzed Environrnesltaf L a h r a t o r y Under EP Pwrt, 19&S

@PCB R e c o g n i z e d Schedule-9i Auditors IS0 900a. 1400P & OHSAS 1 W O E Ce-f ied C o m p a n y

GWEN: 24AAGCS5415tlZR

ANALYSIS REPORT OF SURFACE WATER SAMPLE


Sample Collected by _ Quantity /No. o f Sample

:

: :

Surface Water

San Envirotech Pvt.Ltd. 3 Lit x 08 Nos.

19.12.18 Mahi River

7.8 1225

Lab I D Code Report Issue Date PackingISeal Test Parameters & Method

18.12.18 Dabka Pond 7.1 830

Date of Monitoring 18.12.18 Tajpura

Pond 7.4 '

6 10

18.12.18 Dabhasa

Pond 7.3 755

Parameters

pH Conductivity

: : : :

Unit

pH Unit Micro

SEPL/RPP/GWS (1 to 8)-201812 26.12.2018 Sealed with Proper Identification As per result Table, Method of Test : I S 3025

18.12.18 Padra Pond 7.6 502

19.12.18 Bhoj Pond 7.5 508

19.12.18 Ranu Pond 7.2 630

19.12.18 Luna Pond 7.7 560

A-208

SAN ENVIROTECH PVT, LTDp Accsedircd QCI-NMET Consultant

MoEF Recognized E n v i r o n m e n t a l Labonatow U n d e r E P Act, 19236 GPCB Recognized Schedule-31 Auditors

ISO ~ O Z , 14001 & OHSM 18001 ~ e m ~ e d Company GSTIN: 24AAGCS5415CIZR

: 2 Kg - 8 Nos. Test Parameters & Method : As per result Table, Method of Test : After water and acid leachate preparation followed by the analysis method of APHA AWWA WEF 23'* Edition

ANALYSIS REPORT OF SOIL SAMPLE


Sample Collected by

:

:

Soil Sample

San Envirotech Pvt.Ltd.

Lab I D Code Report Issue Date PackingISeal

: : :

SEPL/RPP/SOI(l to 8)-201812 26.12.2018 Sealed with Proper Identification

A-209

SAN ENVfROTECN PVT. LTD. Accredited QCI-NABET Consultant

MoEF Recognized Envlmnmental Laboratow Under EP Act. 1986 GPCB Recognized ScReduleil Auditors

ISO 9001,1~01& OHSAS ISW)~ ~crhflcd Company emff: 2 4 U G C S 5 4 1 5 C l Z R

Ambient Noise Levels in the Study Area (Date of Sampling: 18 to 19 December, 2018)

Location: Project site (N 1) Unit: dB(A)

5 11:OO AM 3:00 AM 40.1 44.8 - 6 ' 12:OO AM 56.4 57.7 22 4:00 AM 44.7 46.6

Pbne No. 079-26583077 072a1/972376fiMt7 Email: mahendra.sep~~i l .con 401/402/423/424/324, Medicine Market, Opp. Shefali Center, Paldi Cross Road, Ahmedabad

Min

44.7 44.3 41.2 45.9

Reading during Night time

11:OO PM 12:OO PM 1:00 AM 2:00 AM

Max

48.1 45.2 44.7 47.7

Sr. No.

17 18 19 20

Sr. No.

1 2 3 4

Max

50.3 51.8 53.3 54.6

Reading during daytime

7.00 am 8:00 AM 9: 00 AM 10:OO AM

Min

49.2 50.2 52.2 53.6

A-210

EMVkROTECH PVT. ZTD. Accrcd~ted QCI-NAB= Consulrant

MOEF Reerognued Envrronmental Laboratory Under EP Act. 1986 GPCB Recognued Scheduleil Audttors

150 5001,14001 &OH= lLUtO1 CeRtlbed Company GmN: 24AACiCSYIlSClZR

Location: 250 m South from the site (IV3) Unit: dB(A)

13 14 15 16

Max

Location: 500 m North from the site (IV4) Unit: dB(A)

Min

7:00 PM 8:00 PM 9:00 PM 10:OO PM

Sr. No.

11 12 13


Sr. No.

14 15 16

46.3 53.8 45.9 43.4

5:00 PM 6:00 PM 7:00 PM 8:00 PM 9:00 PM 40:00 PM

Sr. No.


48 56.9 48.7 48.9


Sr. No.


46.6 52.5 49.9 47.5 44.2 47.5

Min

Leq Night Leq Day & Night

Min Min

54.1 56 53.6

Max

Ln - 40.8 Ldn- 49.9

Max Max

54.8 49.3 50.8

Leq Day Leq Niqht

Ld - 50.9 Ln - 39.2

Leq Day & Night Ldn- 49.0

A-211

SAN ENVIROTECW PVT. LTD. Accred~ted QCI-NAB- Consultant

MoEF Recognrzed Envtronmenml Laboratow Under EPAct. 1986 GPCB RecognuEd Schedule-ll Audrtors

150 9~)1,14a31 &OHSAS lBOO1 Cemlted Cn-mpany GSTIM: 24AAGCS5415ClZR

Location: 1000 m East from the site (NS) Unit: dB(A)

11 12

Phone Mo. 079-2W3077 Cell: 9825007201/9723766007 Email: [email protected] 401/402/423/424/324, Medicine Market, Opp. Shefali Center, Paidi Cross R d , Ahmedabad.

Location: Village Dabhasa (IV6) Unit: dB(A)

Min Reading during Night time

5:00 PM 6:00 PM

Max Sr. No.

Sr. No.

13 7:00 PM 49.2 50.4

Sr. No.

52.6 54.9

14 15

Max Reading during daytime

Max Reading during daytime

53.2 56.8

8:00 PM 9:00 PM


Sr. No.

Min

Min

Leq Day

51.8 47.6

Min

Ld - 53.7

Max

52.5 49.8

Leq Day & Night Ldn- 51.9

A-212

SAN ENVBIROTECH PVT. LTD, Accredited QCI-NABET Consultant

MoEF Recognized Environmental Laboratory Under EP,.9cf, 1986 GPCB Recognized Schedule-ll Auditors

ISO 9001,14001 & OHSAS l m l certifies Company GSlfN: 24AACSCS5415ClZR

"

Location: Nr BUS stop Padra (N7) Unit: dB(A) 1 Sr. Reading during 1 Min I Max Sr. Reading during I Min I Max I

P h m No. 079-26583077 Cell: 9825007281/9?2376f3007 Email: [email protected] 4011402/423/424/324, Medicine Market, Opp. Shetali Center, Paldi Crws Road, Ahmedabad.

Location: Village Ranu (N8) Unit: dB(A) Max Sr.

No. Reading during

Night time Sr. No.


Min Min Max

A-213

Accredited QCI-NABET Consulrant MOEF Recognized EnvimnmenKal Laboratory Under EP Act. 1986

GPCB Recogn~zed Schedule-11 Auditors I S 0 9001.14001. & OHSAS 18001 CcrMfed Uomoanv

Location: Village Bhoj (N9) Unit: dB(A) Min Max Sr. Reading during

No. Night time

10 11 12

P b n e No. 079-2€i%Ew77 Cell: 9&Z5007201/97237664H177 Emair: [email protected] 4M/402#'423/424/324, Wdicine Market, Opp. SheQli Center, Pal& 005s Road, Ahmedabad.

13

4:00 PM 5:00 PM 6:00 PM

-

7:00 PM

42.1 44.3 43.6 42.8

14

53.0 56.3 59.4

41.7 8:00 PM 56.7

Leq Day I Leq Night I Ln - 40.3

54.8

Ld - 51.8

I Leq Day & Night I Ldn - 49.9

A-214

Annexure-XI Wildlife Conservation Plan submitted for

Schedule I species Pavo Cristatus

A-215

Conservation Plan for Peacock or Indian Peafowl (Pavo Cristatus)


Protection Status:

As per IUCN: Classified as Least Concern (LC) on the IUCN Red List (1) and listed

on Appendix II of CITES 3.






Indian Peafowl (Pavocristatus)


Kingdom: Animalia

Phylum: Chordata

Class: Aves

Order: Galliformes

Family: Phasianidae

Genus: Pavo




A-216

Introduction: The Indian Peafowl (Pavo Cristatus) is a resident breeder in the

Indian subcontinent. The bird was declared as the National Bird of and its

widespread distribution in the country. The species is found in dry semi-desert

grasslands, shrub and deciduous forests. It forges and nests on the ground but

roots on top of trees. It eats seeds, insects, fruits, small mammals and reptiles. The

Indian Peafowl is a ground nesting bird and it lays a clutch of 4-8 eggs which take

28 days to hatch. The eggs are light brown and are laid every other day usually in

the afternoon. The male does not assist with the rearing, and is polygamous.

Poaching of Peacock for their feathers and poisoning by feeding on pesticide treated

seeds are known threats to wild birds. Under the law, collection of tail feather is

allowed only when bird sheds them. The Indian peafowl is under various threats

that include the demand for feathers and wild meat, conflict with farmers during

cropping season, increased use of chemical fertilizer and pesticide and habitat

degradation.

Habitat:

The Indian Peafowl is found mainly on the ground in open scrub forest or on land

under cultivation where they forage for berries, grains but will also prey on snakes,

lizards, and small rodents. Their loud calls make them easy to detect, and in forest

areas often indicate the presence of a predator such as a tiger. They forage on the

ground in small groups and will usually try to escape on foot through undergrowth

and avoid flying, though they will fly into tall trees to roost. The bird has a

celebrated status in Indian mythology, and hence protected culturally in India

especially in Gujarat. The Indian Peafowl is listed as Least Concern by IUCN (2014)

Red data.

Photographs of Peafowl

A-217

Appearance: The male, known as a peacock, is a large bird with a length from bill

to tail of 100 to 115 cm (40 to 46 inches) and to the end of a fully grown train as

much as 195 to 225 cm (78 to 90 inches) and weigh 4–6 kg. The females, or

peahens, are smaller at around 95 cm (38 inches) in length and weigh 2.75– 4 kg.

Indian Peafowl are among the largest and heaviest representatives of the

Phasianidae family. Their size, colour and shape of crest make them unmistakable

within their native distribution range. The male is metallic blue on the crown, the

feathers of the head being short and curled. The fan shaped crest on the head is

made of feathers with bare black shafts and tipped with blush-green webbing. A

white stripe above the eye and a crescent shaped white patch below the eye are

formed by bare white skin. The sides of the head have iridescent greenish blue

feathers. The back has scaly bronze-green feathers with black and copper

markings. The scapular and the wings are buff and barred in black, the primaries

are chestnut and the secondaries are black. The tail is dark brown and the "train" is

made up of elongated upper tail coverts (more than 200 feathers, the actual tail

has only 20 feathers) and nearly all of these feathers end with an elaborate eye-

spot. A few of the outer feathers lack the spot and end in a crescent shaped black

tip. The underside is dark glossy green shading into blackish under the tail. The

thighs are buff coloured. The male has a spur on the leg above the hind toe.

Peacocks are polygamous, and the breeding season is spread out but appears to be

dependent on the rains. Several males may congregate at a lek site and these

males are often closely related. Males at lek appear to maintain small territories

next to each other and they allow females to visit them and make no attempt to

guard harems. Females do not appear to favour specific males. Peafowl are

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omnivorous and eat seeds, insects, fruits, and reptiles. A large percentage of their

food is made up of the fallen berries. Around cultivated areas; peafowl feed on a

wide range of crops such as groundnut, tomato, paddy, etc. Around human

habitations, they feed on a variety of food scraps. In the countryside, it is

particularly partial to crops and garden plants.

Status & impact in the Study Area:

No peacock was sighted in the project site. All the direct sightings of the peacock

were located near the human habitats, villages and agriculture field, of study area.

This species is well adapted to natural village environment setting. Day time they

temporarily move towards the surrounding agriculture areas for feeding while

during night time they roost on the trees present in the village and in the

agriculture hedges.

Since Indian Peafowl is a ground nester, several project activities can have adverse

Impact on their nesting grounds such as pollution, degradation of soil and

vegetation from surrounding area and in the forest areas. Direct disturbance by

presence of people, vehicle their noise, vibration, light etc. can potentially disturb

most of the bird species.



Village residents are against hunting or poaching of the peafowl, due to

culture and mythology reasons.

Majority villagers follow Hinduism in the region, thus they have high respect

towards peacocks due to mythological reasons, and

Literacy levels are greater than 80% in the study region and people are

aware with the significance of the peacock as the national bird.

Conservation: Following actions for the conservation and protection are suggested

in wildlife conservation action plan to reduce impacts of project related activities on

the species. Based on our field observation on the distribution, behavioural ecology,

conservation need, and envisaged impacts of proposed project.

Conservation through Habitat Improvement and Awareness

Habitat improvement programme can be undertaken through plantation of suitable

tree species in the surrounding villages. While selecting the tree/ shrub species care

shall be provided for beery plants which attract these birds. During summer period,

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villagers will be encouraged to use the old earthen pots to fill with water for

drinking these birds.


Summer is the time when these birds are facing shortage of feeds, there by

supplying the feed like Bajri, Juwar, Maize to the surrounding villages with good

population of Indian peafowls will suffix the problem of food shortage.


In consultation of the forest department, following conservation measures will be

adapted for peacock conservation:

1. Increasing the tree cover in the study area which will provide shelter and

roosting to the peacocks. This can be achieved by planting of local tree species

like Neem, Shirish, Khakhro, Haldu, Amli, Banyan, Peepal and Peeper or other

Ficus sp. Vacant places such as edges of agricultural fields, village Gauchar,

Panchayat’s common land, neighbourhood of people inhibiting, road side avenue

tree plantation, open scrubs, ravines, school compounds can be selected for

practicing the plantation activity.

2. School level awareness programmes will be conducted for conservation of

peacocks in the study area by organizing competitions during “Wildlife Week”

and “Van Mahotsav” celebrations by active involvement of local community.

3. Some provision of rewards to informers for the control of poaching and illegal

trade in wildlife.

4. Carrying out census and research projects to know the potential threats and

population status of the species in collaboration of local schools, colleges,

panchayats and forest department.

5. Suggest strategies to minimize negative impacts of changing environment in

nearby area of peacock populations and to promote conservation of peacock

habitats.

6. Another way to help preserve the endangered species is to create society

dedicated to ecological ethics. All the conservation measures will be

implemented with the help of and in the consultation of the district forest

department.

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Sr.

No.


Cost. Rs.

Village

1 Plantation-350 tree plants (5 feet height

as per the plant species-Cost of sapling

will be changed per year)

70,000/-(@

200/-per

plant)

Dabhasa, Ranu,

Dhobikuwa and

Mahuvad


tank

1,00,000/-


conservation

20,000/- Study area



30,000/-

Total 2,20,000/-

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