GP1 Final Report Template Ss09.10

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    United Arab Emirates University

    College ofEngineering

    Urea Production Plant Design

    Graduation Project I Course

    Graduation Project Code: XXXX(e.g. CEM1-1)

    Submitted for Partial Fulfillment of the

    B.Sc. Degree in Chemical EngineeringBy

    Student 1 Name Student 1 IDStudent 2 Name Student 2 IDStudent 3 Name Student 3 ID

    Project Advisor(s): Name of Advisor

    Examination Committee:

    Examiner 1 Name

    Examiner 2 Name

    Examiner 3 Name

    Second Semester 2009/2010

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    UAE University

    College of Engineering

    Industrial Training and Graduation Projects Unit

    Contribution of Team Members*

    Project Title-----------------------------------------------------------------------------------------

    Semester / Academic Year----------------------------------- Date -----------------

    Tasks

    Student #1 Student #2 Student #3 Student #4 Student #5

    Student

    signature

    1. Example 20% 30% 10% 0 40%

    2.

    3.

    4.

    5.

    6.

    7.

    8.

    * The total percentage for each task should be 100.

    Project Advisor Name and Signature: _______________________________________________________________

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    Acknowledgments

    (Example [1])

    We would like to express our deepest gratitude and appreciation to our project

    advisor Dr. Eesa Bastaki for his guidance, continuous encouragement and

    support to complete this work. Also, we would like to thank Dr. Mohamed Abdul-

    Hafez, Dr. Khalifa Harib and Dr. Mohammed Younis Selim for serving as members

    of our final examination committee. Our thanks go also to the Training and

    Graduation Projects Unit, represented by the administration staff and our project

    coordinator Dr. Mohamed Shakeel for his helpful comments, guidance and

    suggestions. Finally, we wish to express our appreciation to our family members

    for their unlimited help and support during our study.

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    Executive Summary

    Executive Summary is a summary of the project presented by the student. It,

    briefly, explains the objective of the project and its results. This sample

    document is a complete example of the way and method of writing graduation

    projects. (300 words maximum). The entire report, excluding appendices, should

    not exceed 60 pages. All material used from other sources must be included in

    the References section and all sources should be cross-referenced in the main

    text. A text that is an exact copy of information taken from another source

    should be enclosed in a pair of double quotes. Regardless of whether a text is an

    exact copy or not, you must cross-reference the source at the end of the

    paragraph that includes the text. Page 2 of this document contains an example

    of cross-referencing [1].

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    TABLE OF CONTENTS

    PRELIMINARY MATERIAL Cover Page

    Contribution of Team Members

    Acknowledgements

    Executive Summary

    Table of Contents

    List of Tables

    List of Figures

    Nomenclature

    The following chapter titles and subheadings are provided as a template which you

    should base your report on. Where relevant, you should stick to the same format and

    wording below. Some flexibility will be accepted as long as the project report requires

    this modification to better communicate your work. However, similar content will be

    expected and the grading rubric will remain unchanged*. Please make sure you read

    the files "GP contents guidelines.doc"[2] and "GP report format.doc"[3]

    1. INTRODUCTION

    Should include:

    Problem Statement and Purpose

    Project and Design Objectives

    Intended Outcomes and Deliverables

    Summary of Design Process used (NOT required for CHME & PETE)

    Summary of Report Structure

    2. BACKGROUND LITERATURE AND MARKET SURVEY

    Should include (for CEE, MAYinclude)

    Relevant Literature Search

    Target Market and their needs (NOT required for CHME & PETE)

    Prioritized Needs / Requirements

    Potential Ethical and/or Environmental Issues

    *prepared by: Dr. Tamer Shaheen and modified/revised by ADHOC committee represented by members from alldepartments.

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    Intended application to UAE (Required for CHME & PETE ONLY)

    3. CONCEPTUAL DESIGN (for AE, CE, EE & ME ONLY)

    Should include (for CEE, May include):

    Problem Review

    Design Specifications

    Generation of Conceptual Alternatives

    Selected Alternatives and Reasoning

    Formal Decision-Making Process and Final Concept Selection

    Discussion and Perceived problems

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    3. CONCEPTUAL DESIGN (for PETE ONLY)

    Should include:

    Problem Review

    Possible alternatives and their advantages/disadvantages

    Generation of Conceptual Alternatives

    Selected Alternatives and Reasoning

    Formal Decision Making Process

    Discussion and Perceived problems

    3. PROCESS SELECTION (for CHME ONLY)

    Should include:

    Problem Review

    Possible alternatives and their advantages/disadvantages

    Process selection

    Flowsheet preparation

    Required information from literature

    Discussion and Perceived problems

    4. PRELIMINARY DESIGN

    Area-Specific Preliminary Design. Chapter should include the following where

    relevant:

    Schematics and flow sheets defining the preliminary design and its

    relationships

    Mass, momentum, force, energy, species, particle, current, etc. balances

    (Relevant Standards. e.g. ASTM, IEEE, etc)

    Other relevant engineering application(s) required for the preliminary design

    Safety Considerations (NOT required for CHME & PETE)

    Use of software packages for design (Required for CHME & PETE ONLY)

    5. ECONOMICAL, ETHIC, AND CONTEMPORARY ISSUES (for AE, CE, EE & ME ONLY)

    Preliminary Cost Estimation and Justification

    Relevant Codes of Ethics and Moral Frameworks

    Relevant Environmental Considerations

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    Relevance to UAE and Region (Social, Cultural, and Political)

    Other Issues and Constraints (where relevant)

    Ethical Dilemmas and Justification of Proposed Solution

    5. SAFETY, ECONOMICAL, ETHIC, AND CONTEMPORARY ISSUES (for CHME ONLY)

    Relevant Codes of Ethics and Moral Frameworks

    Ethical Dilemmas and Justification of Proposed Solution

    Relevant Environmental Considerations

    Safety and HAZOP Considerations

    5. SAFETY, ECONOMICAL, ETHIC, AND CONTEMPORARY ISSUES (for PETE ONLY)

    Relevant Codes of Ethics and Moral Frameworks

    Relevant Environmental Considerations

    Safety and Economical Considerations

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    6. PROJECT MANAGEMENT

    Tasks and Schedule

    Problems faced and solutions

    Resources

    Each Students Responsibilities

    7. CONCLUSION AND PLAN FOR GP2

    Restatement of Purpose of Report and Objectives

    Restatement of Proposed Deliverables

    Summary of how each O bjective and Deliverable has been met

    Summary of Final Design Solution

    New skills learnt

    Plan for GP2

    REFERENCES

    [1] Dr. Eesa Bastaki & Dr. Abdulla Al-Amiri, "GP_Final Report Kit" V2.0. 2003

    [2] Dr. Nabil Bastaki, "GP Content Guidelines" V1.1 Feb. 2010.

    [3] Eng. Hanan Al-Harmoudi, "GP Report Format.doc" V1.0 March 2010.

    APPENDICES

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    List of Tables

    (Example [1])

    Table Page

    Table 1.1 Shampoo chemical analysis 5

    Table 1.2 Water samples analysis of EMARAT petrol filling station 9

    Table 1.3 Water samples analysis of EPPCO petrol filling station 2

    Table 1.4 Summary of water samples results. 24

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    List of Figures

    (Example [1])

    Figure Page

    Fig. 2.1 Schematic drawing of water recycling system for a car wash 12

    Fig. 2.2 Used Water Recycling System for a car wash at EMARAT 17

    Fig. 2.3 Suspended solids removal versus overflow rate 40

    Fig. 3.1 Sedimentation tank dimensions 45

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    Nomenclature

    (Example [1])

    fluid dynamic viscosity, m2/s

    Z height from datum to liquid overflow, m

    dimensionless cost constant

    e purchased equipment cost, $

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    1. INTRODUCTION

    Urea is anorganic compound with the chemical formulaCO(NH2)2, also known as

    carbamide. Urea is essentially the waste produced when the body metabolizes protein. It is

    not only produced by humans, but also by many other mammals, as well as amphibians and

    some fish.

    history

    Urea widely used in the agriculture sector both as a fertilizer and animal feed additive.

    Fertilizer is generally defined as "material that is added to the soil to supply one or more

    elements required for plant growth and productiveness as well as animal feed additive"[1].

    The main role of fertilizers is supply the essential nutrients required for the plant growth.

    On the world basis , urea is the most popular solid nitrogen fertilizer because of its high

    nitrogen concentration , equal to 46 % which is highest concentration dry nitrogen fertilizer

    available and for it's favorable production cost[2]. It is used in solid fertilizer, liquid

    fertilizer, formaldehyde resins and adhesives.

    Urea is the major fertilizer traded internationally. In the dry fertilizer category, urea has

    captured more than 65% of world trade and it use grow rapidly more than other materials .

    In 2000, a total of 55 countries produced 107.4 M.t. of urea . Most of the biggest producers

    are located in the highly populous rice growing areas in Asia or where natural gas is readily

    available.For the last decade, the greatest growth took place in China in which nearly20

    M.t, while the rest of Asia produced about 11 M.t . The Middle East region together with

    Latin America are planning to accelerate their production over the next 5 years while West

    Europe is the only region that is cutting back on capacities [3].

    [1] http://en.wikipedia.org/wiki/Fertilizer.

    [2] http://www.ehow.com/about_5380766_urea-fertilizer.html

    [3] Global Supply and Demand for Urea, K.G. Soh, International Fertilizer

    Industry Association , Paris

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    http://en.wikipedia.org/wiki/Organic_compoundhttp://en.wikipedia.org/wiki/Organic_compoundhttp://en.wikipedia.org/wiki/Chemical_formulahttp://en.wikipedia.org/wiki/Carbonhttp://en.wikipedia.org/wiki/Oxygenhttp://en.wikipedia.org/wiki/Nitrogenhttp://en.wikipedia.org/wiki/Hydrogenhttp://en.wikipedia.org/wiki/Chemical_formulahttp://en.wikipedia.org/wiki/Carbonhttp://en.wikipedia.org/wiki/Oxygenhttp://en.wikipedia.org/wiki/Nitrogenhttp://en.wikipedia.org/wiki/Hydrogenhttp://en.wikipedia.org/wiki/Organic_compound
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    In Table() shows the urea production capacities at different companies .

    Company Name Technology Used Annual production capacity

    SAFCO(Saudi ArabianFertilizer Company )

    Over 2.6 million ton of urea

    QAFCO (Qatar Fertilizer

    Company )

    3 Million tons of urea

    (OMIFCO) Oman India

    Fertilizer Company SAOC

    Snamprogetti

    Technology

    9 Million tons of urea

    (FERTIL) 8.4 Million tons of urea

    SAFCO(Saudi Arabian Fertilizer Company,) is one of the largest producer of urea in the

    world. Our annual production capacity is over 2.6 million ton of urea. Around 13% of total

    urea production is consumed in the local market and remaining 87% is exported to the

    International market

    QAFCO (Qatar Fertilizer Company) operates 4 trains of Anhydrous ammonia as liquid and 4

    trains of urea , with a total production capacity of 2.2 million \

    NOT DONE

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    1.2 PROPERTIES OF UREA

    1.2.1 Physical properties

    Urea appears to be a light brown or light yellow, odorless and hygroscopic solid. It is non-

    corrosive. The smell of urea is almost non-existent [4].

    1.2.2 Chemical properties

    Some of Chemical properties of Urea that are interest for fertilizer use are shown in Table 2

    [5] :

    Table 2: Chemical Properties of urea

    Molecular weight 60.06

    Nitrogen content,% 46.6

    Specific gravity 1.335

    Melting poi.nt ,c 132.7

    Flash Point ,c 72.7 22.6 (3)

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    Solubility in water parts per 100 parts ofwater by weight at

    0 66.7

    20 108.0

    40 167.0

    60 251.0

    80 400.0

    100 733.0

    Critical relative humidity at

    20 81%

    30 73%

    Specific heat 20 C, cal/g C 0.320

    Heat of Solution in water (endothermic )cal/g

    0.320

    -57.8

    PH 7.2 (10 % aqueous solution )

    The specific heat capacity of urea at different temperate is shown in Table (3)[5].

    Table 3: Specific heat capacity of urea

    Temperature, Specific heat, kj/kg

    0 1.398

    50 1.66

    100 1.89

    150 2.11

    1.2.3 Stability and reactivity

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    Urea is stable under ordinary conditions of use and storage. When urea reacts with calcium

    hypochlorite or sodium hypochlorite it form the explosive nitrogen trichloride. Urea is

    incompatible with several compounds such as sodium nitrite, gallium perchlorate, strong

    oxidizing agents (permanganate, dichromate, nitrate, chlorine), phosphorus pentachloride,

    nitrosyl perchlorate, titanium tetrachloride and chromyl chloride [6] .

    [5] http://www.epa.gov/iris/toxreviews/1022tr.pdf

    [6]http://www.hvchemical.com/msds/urea.htm

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