1
Geology and MetalogeneƟc features of La Bodega Concesion, California Mining District, Santander, Colombia A. Rodriguez Madrid*¹’², T. Bissig¹, C. Hart¹ ¹ Mineral Deposits Research Unit, University of BriƟsh Columbia, Canada ² Ventana Gold Corp. , AUX, CVS ExploraƟons Ltda. * Corresponding Author: [email protected] NE main mineralized trend La Bodega Project mineralization targets map (Altman et al., 2010), and geological map of La Bodega North-east zone (Right, small) (Bernasconi et al., 2009) INTRODUCTION La Bodega project has a total of infered resources of 3 milion ounces (Moz) of gold, 19.2 Moz of Silver and 84.4 pounds of Copper, with 2.0 g/ton of gold cut o. La Bodega project is located in the Eastern Cordillerain the Santander department within the Califor- nia mining district, 60 Km to the North-east of Bucaramanga in Colombia. The main lithologies in the concesion are metamorphic rocks of the Bucaramanga Gneiss FormaƟon (Middle Proterozoic) and felsic intrusives of Mesozoic age (Ward et al., 1973; Evans, 1977; Mendoza & Jaramillo, 1979; Royero & Clavijo, 2001). MineralizaƟon age is not well dened yet:a Re-Os radiometric age of 57 +/- 10 of the mineralizaƟon was determined by means of pyrite concentrates (Mathur et al., 2002), while K-Ar data of hydrothermal alteraƟon minerals in the intrusives showed ages between 60 and 66 Ma (Nippon Mining Company, 1967 in Mathur et al., 2002). Nevertheless, porphyriƟc rocks outcropping at less than 7 km of the project have been dated giving ages between 9 and 8 Ma. (ManƟlla et al, 2009). Most mineralized bodies show a strong structural control on the NE trend steeply dipping to the NW (Bernasconi, 2006) speccially in the zones of main interest La Bodega and La Mascota which are the main objecƟve in this study. MAIN ROCK TYPES AT LA BODEGA PROJECT Gneiss: Bucaramanga Gneiss FormaƟon (Middle proterozoic) LB178 278.50m. LM (9950) Amphibolite, epi- dote veinlets LB260 206.60 m. LR (0100) BioƟte Augen Gneiss Felsic Intrusives (Triassic to Jurassic?) LB260 108.80 m LR (0100) Feldspar-Quartz Gneiss (graniƟc gneiss) LB112 347.70 m. LM (9350) Felsic Intrusive (monzogranite dike?) LB267 280.90 m. EC (8700-2) Felsic Intrusive. Minor Illite altered phenocrysts LB V9 185.70 m. Banded gneiss with mesosomes and leucosomes LB001 94.80 m. LB (0425) Felsic Intrusive (monzogranite?) LB280 228.0m. Aser- radero (0075-1) Fine grained felsic in- trusive with gneiss xenolith LB282 131.30 m. EC (8400) Quartz monzonite porphyry (Post Jurassic?) HYDROTHERMAL ALTERATION LB112 281.55 m. Quartz-silica lling- cemenƟng, replac- ing matrix of HyBx. LB187 554.60 m. (EC) Vuggy Silica (?) LB262 444.18 m chlorite+epidote+pyr ite+ chalcopyrite1 LB112 336.70 m quartz+Illite-(or sericite?)+ pyrite LB112 295.60 m. Alunite,+Quartz+Py rite (?) Hydrothermal systems alteraƟon assemblages are typical in the area: 1. PropyliƟc alteraƟon: epidote+ chlorite+pyrite+chalcopyrite1; 2. Illite-sericite alteraƟon: Quartz+illite(o sericita)+pyrita; 3. SilicicaƟon: found mainly in the core of main mineralized zones: Quartz occurs mainly as cement of breccias, replacing matriz, altera- Ɵon halos in the host rock and re- placing clasts in brecias. 4. Alunite alteraƟon is minor and is manily accompanied by quartz al- teraƟon. MINERALIZATION STYLES LA BODEGA ZONE: Predominantly vein dissemi- nated systems. Minor disconƟnuous Hydrothermal breccias LA MASCOTA ZONE: Hydrothermal breccias with mulƟple phases of brecciaƟon. Complex paragenesis. Strong structural control. EL CUATRO ZONE: Black hydrothermal brec- cias. More Zn and U rich. Breccias delopped in Int. Vuggy or pseudo-vuggy silica. TECTONIC BRECCIAS DURING MINERALIZATION EVENTS: cataclasƟtes with tectonic foliaƟon. Si- licied. POST MINERALIZATION EVENTS FAULT BRECCIAS: Clay supported brec- cias. PolimicƟc. Subrounded subangu- lar clasts. After Di Prisco, 2009 References and Bibliography Altmann, K., Sim, R., Davis, B., Prenn, N., Elfen, S., Fisher, B. 2010. Canadian NaƟonal Instrument 43-101 Technical Report Preliminary Assesment La Bodega Project Department of Santander, Colombia. Prepared by Samuel Enge- neering, Inc. for Ventana Gold Corp. Bernasconi, A. 2006. La Bodega Gold Project CVS ExploraƟons Ltda.- Colombia. Progress Report on the Geology and MineralizaƟon of the Mine Property and Adjacent Areas. Unpublished report from Gondwanaland ExploraƟon to CVS ExploraƟons Ltda. Bernasconi, A. 2010. The Geology and Gold MineralizaƟon of La Bodega Property, Santander Department, Colombia. PresentaƟon. Unpublished. For Ventana Gold Corp. Di Prisco, G., 2009. CharacterizaƟon Of Gold Ore From La Mascota Deposit, California District, Colombia. Unpublished. Internal report for Ventana Gold Corp. by Terra Mineralogical Services. Di Prisco, G., 2010. CharacterizaƟon Of Gold And Silver MineralizaƟon From El Cuatro Deposit, California-Santander District, Colombia. Unpublished. Internal report for Ventana Gold Corp. by Terra Mineralogical Services. Evans, J. 1977. Geological and Geochemical reconnaissance in the Central Santander Massif, Deparments of Santander and Norte de Santander, Colombia. U. S. Geological Survey (edits). 43 p. Hedenquist, J. W. 2010. Comments on the La Bodega Project, California District, Colombia. Unpublished report for Ventana Gold Corp. by Hedenquist ConsulƟng, Inc. Mathur, R., Ruiz, J., Herb, P., Hahn, L., Burgath, P. 2003. Re-Os isotopes applied to epithermal gold deposits near Bucaramanga, northeastern Colombia. Journal of South American Earth Sciences, 15: 815-821. Mendoza, H.; Jaramillo, L. 1979. Geología y geoquímica del área de California, Santander. Boleơn Geológico Ingeominas, 22: 3-52. Nippon Mining Company, 1967. Report in Mathur, R., Ruiz, J., Herb, P., Hahn, L., Burgath, P. 2003. Re-Os isotopes applied to epithermal gold deposits near Bucaramanga, northeastern Colombia. Journal of South American Earth Sciences, 15: 815-821. PraƩ, W. 2009. La Mascota and La Bodega Gold Project, Santander, Colombia. Unpublished. Unpublished Internal report for Ventana Gold Corp. by Specialized Geological Mapping. Royero G. J. M.; Clavijo J. 2001. Mapa Geológico generalizado departamento de Santander. Escala 1: 400.000.Informe Ingeominas. 92 p. Sillitoe, R. 2008. Major Gold Deposits and Belts of the North and South American Cordillera: DistribuƟon, TectonomagmaƟc Seƫngs, and Metallogenic ConsideraƟons. Economic Geology, v. 103, pp. 663–687. Ward, D., Goldsmith, R., Cruz, B., Jaramillo, C., y Restrepo, H. 1973. Geología de los Cuadrángulos H-12, Bucaramanga y H-13, Pamplona, Departamento de Santander. U.S. Geological Survey e Ingeominas. Boleơn Geológico XXI (1-3), 1-132. OUTLINE, OBJECTIVES AND AIMS OF THE PROJECT The project aims to make a characterizaƟon of the geology and the hydrothermal fea- tures of the La Mascota and La Bodega zones, determining similitudes and dierences among classic hydrothermal deposits, as well as dening the parageneƟc sequences of these two zones. Microscopy, SEM, electron microprobe analysis will be necessary for dening the paragenesis and elements distribuƟon in sulphide phases and wolframite. X-ray diracƟon and Terraspeck analysis will be done in order to characterize properly the alteraƟon in the zones as well as to properly choose alunite samples for stable iso- tope analysis and daƟng. Mineralizing uids ngerprint, oxidaƟon state of the uids and paleotemperature of mineralizing uids precipitaƟon are to be determined by means of the use of stable isotopes of Sulfur, Oxygen and Hydrogen mainly in alunites and pyrite . This may give clues for possible source and paths for the mineralizing uids, which will probably help to develop an exploraƟon tool for the project. In order to properly constraint the ages of the mineralizaƟon, K-Ar daƟng on alunites will be done, as well as U-Pb daƟng of the intrusives within the concession. Sampling within at least two secƟons in La Mascota and two secƟons in La Bodega will be necessary in order to achieve these objecƟves. Ackknowledgments This project is developed by the MDRU at the University of BriƟsh Columbia. The project is funded by Ventana Gold Corp. which has been undertaken by AUX. CVS ExplotaƟons Ltda has given support and logisƟcs. Society of Economic Geologist SEG has given further funding for daƟng. Preliminar parageneƟc sequence at La Mascota based on DDH09LB112 log. The preliminar parageneƟc sequence was determined based on hand sample descripƟon of vein cross-cuƫng relaƟonships. PremineralizaƟon stages are related to propyliƟc alteraƟon assemblages (epidote, chlorite, pyrite and in this case chalcopyrite1. Pyrite and quartz occur throughout almost the whole sequence of events and is related to gold deposiƟon in the mineralizaƟon stages. Quartz and alunite alteraƟon (alunite1) characterize the alteraƟon assemblage of mineralizaƟon stage 1. Quartz (difuse light gray silica) with ne pyrite (and visible gold) cuƫng quartz+coarse Pyrite was noƟced but whether or not is part of stage 1 is not clear yet. MineralizaƟon stage 2 is dened mainly by hypogene (or specular?) hemaƟte, pyrite and quartz deposiƟon. Evi- dence for this is that a quartz+pyrite+hypogene hemaƟte (specular?) vein was found cuƫng aluniƟzied-silicied clast. Mineral- izaƟon stage 3a is characterized by the occurrence of sphalerite and alunite2, which was noƟced below 326 m depth of the drill hole. Unambiguous cross cuƫng relaƟonships between stage 3 sphalerite and stage 3b are sƟll elusive. The laƩer contains chalcopyrite2+chalcocite+covellite+bornite with quartz as dening characterisƟc. MineralizaƟon stage 4 is characterized by the rst occurrence of wolframite (and/or huebnerite) and the rst occurrence of enargite, which seems to represent the last events of ore deposiƟon. Veins that contain wolframite and enargite are cuƫng features (veins, cement of breccias and clasts) that contain the copper sulphides or sphalerite. Visible gold was also documented in this mineralizaƟon stage. LB112. 294.45 m. quartz+pyrite+enargite +minor wolframite (mineralizaƟon stage 4) and visible gold vein, hosted in silicied gneiss. LB112. 264.15m. BX5. PolimicƟtc clasts supported breccia with clast of cataclasite. Coarse pyrite (Py) with quartz cuts cataclasite and it is cut by quartz+wolframite+enargite+bornite? Vein (MineralizaƟon stage 4) . This vein is cut by quartz-enargite (possibly luzonite) vein (end of mineraliza- Ɵon stage 4). Banded silica precipitates in open space (part of mineraliza- Ɵon stage 4). It is also cut by quartz-enargite vein.

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Page 1: Geology and Metalogene c features of La Bodega Concesion ... · Geology and Metalogene c features of La Bodega Concesion, California Mining District, Santander, Colombia A. Rodriguez

Geology and Metalogene c features of La BodegaConcesion, California Mining District, Santander, Colombia

A. Rodriguez Madrid*¹’², T. Bissig¹, C. Hart¹¹ Mineral Deposits Research Unit, University of Bri sh Columbia, Canada

² Ventana Gold Corp. , AUX, CVS Explora ons Ltda.* Corresponding Author: [email protected]

NE main mineralized trend

La Bodega Project mineralization targets map (Altman et al., 2010), and geological map of La Bodega North-east zone (Right, small) (Bernasconi et al., 2009)

INTRODUCTIONLa Bodega project has a total of infered resources of 3 milion ounces (Moz) of gold, 19.2 Moz of Silver and 84.4 pounds of Copper, with 2.0 g/ton of gold cut off. La Bodega project is located in the Eastern Cordillerain the Santander department within the Califor-nia mining district, 60 Km to the North-east of Bucaramanga in Colombia. The main lithologies in the concesion are metamorphic rocks of the Bucaramanga Gneiss Forma on (Middle Proterozoic) and felsic intrusives of Mesozoic age (Ward et al., 1973; Evans, 1977; Mendoza & Jaramillo, 1979; Royero & Clavijo, 2001).

Mineraliza on age is not well defined yet:a Re-Os radiometric age of 57 +/- 10 of the mineraliza on was determined by means of pyrite concentrates (Mathur et al., 2002), while K-Ar data of hydrothermal altera on minerals in the intrusives showed ages between 60 and 66 Ma (Nippon Mining Company, 1967 in Mathur et al., 2002). Nevertheless, porphyri c rocks outcropping at less than 7 km of the project have been dated giving ages between 9 and 8 Ma. (Man lla et al, 2009).

Most mineralized bodies show a strong structural control on the NE trend steeply dipping to the NW (Bernasconi, 2006) speccially in the zones of main interest La Bodega and La Mascota which are the main objec ve in this study.

MAIN ROCK TYPES AT LA BODEGA PROJECTGneiss: Bucaramanga Gneiss Forma on(Middle proterozoic)

LB178 278.50m. LM (9950)Amphibolite, epi-dote veinlets

LB260 206.60 m. LR (0100)Bio te Augen Gneiss

Felsic Intrusives (Triassic to Jurassic?)

LB260 108.80 m LR (0100)Feldspar-Quartz Gneiss (grani c gneiss)

LB112 347.70 m. LM (9350)Felsic Intrusive (monzogranite dike?)

LB267 280.90 m. EC (8700-2)Felsic Intrusive. Minor Illite altered phenocrysts

LB V9 185.70 m.Banded gneiss with mesosomes and leucosomes

LB001 94.80 m. LB (0425)Felsic Intrusive (monzogranite?)

LB280 228.0m. Aser-radero (0075-1)Fine grained felsic in-trusive with gneiss xenolith

LB282 131.30 m. EC (8400)Quartz monzonite porphyry (Post Jurassic?)

HYDROTHERMAL ALTERATION

LB112 281.55 m. Quartz-silica filling-cemen ng, replac-ing matrix of HyBx.

LB187 554.60 m. (EC)Vuggy Silica (?)

LB262 444.18 mchlorite+epidote+pyrite+ chalcopyrite1

LB112 336.70 mquartz+Illite-(or sericite?)+ pyrite

LB112 295.60 m. Alunite,+Quartz+Pyrite (?)

Hydrothermal systems altera on assemblages are typical in the area:1. Propyli c altera on: epidote+ chlorite+pyrite+chalcopyrite1;2. Illite-sericite altera on: Quartz+illite(o sericita)+pyrita;3. Silicifica on: found mainly in the core of main mineralized zones: Quartz occurs mainly as cement of breccias, replacing matriz, altera-

on halos in the host rock and re-placing clasts in brecias.4. Alunite altera on is minor and is manily accompanied by quartz al-tera on.

MINERALIZATION STYLES

LA BODEGA ZONE: Predominantly vein dissemi-nated systems. Minor discon nuous Hydrothermal breccias

LA MASCOTA ZONE: Hydrothermal breccias with mul ple phases of breccia on. Complex paragenesis. Strong structural control.

EL CUATRO ZONE: Black hydrothermal brec-cias. More Zn and U rich. Breccias delopped in Int. Vuggy or pseudo-vuggy silica.

TECTONIC BRECCIAS DURING MINERALIZATION EVENTS: cataclas tes with tectonic folia on. Si-licified.

POST MINERALIZATION EVENTSFAULT BRECCIAS: Clay supported brec-cias. Polimic c. Subrounded subangu-lar clasts.

After Di Prisco, 2009

References and BibliographyAltmann, K., Sim, R., Davis, B., Prenn, N., Elfen, S., Fisher, B. 2010. Canadian Na onal Instrument 43-101 Technical Report Preliminary Assesment La Bodega Project Department of Santander, Colombia. Prepared by Samuel Enge-neering, Inc. for Ventana Gold Corp.Bernasconi, A. 2006. La Bodega Gold Project CVS Explora ons Ltda.- Colombia. Progress Report on the Geology and Mineraliza on of the Mine Property and Adjacent Areas. Unpublished report from Gondwanaland Explora on to CVS Explora ons Ltda.Bernasconi, A. 2010. The Geology and Gold Mineraliza on of La Bodega Property, Santander Department, Colombia. Presenta on. Unpublished. For Ventana Gold Corp.Di Prisco, G., 2009. Characteriza on Of Gold Ore From La Mascota Deposit, California District, Colombia. Unpublished. Internal report for Ventana Gold Corp. by Terra Mineralogical Services.Di Prisco, G., 2010. Characteriza on Of Gold And Silver Mineraliza on From El Cuatro Deposit, California-Santander District, Colombia. Unpublished. Internal report for Ventana Gold Corp. by Terra Mineralogical Services.Evans, J. 1977. Geological and Geochemical reconnaissance in the Central Santander Massif, Deparments of Santander and Norte de Santander, Colombia. U. S. Geological Survey (edits). 43 p.Hedenquist, J. W. 2010. Comments on the La Bodega Project, California District, Colombia. Unpublished report for Ventana Gold Corp. by Hedenquist Consul ng, Inc.Mathur, R., Ruiz, J., Herb, P., Hahn, L., Burgath, P. 2003. Re-Os isotopes applied to epithermal gold deposits near Bucaramanga, northeastern Colombia. Journal of South American Earth Sciences, 15: 815-821.Mendoza, H.; Jaramillo, L. 1979. Geología y geoquímica del área de California, Santander. Bole n Geológico Ingeominas, 22: 3-52.Nippon Mining Company, 1967. Report in Mathur, R., Ruiz, J., Herb, P., Hahn, L., Burgath, P. 2003. Re-Os isotopes applied to epithermal gold deposits near Bucaramanga, northeastern Colombia. Journal of South American Earth Sciences, 15: 815-821.Pra , W. 2009. La Mascota and La Bodega Gold Project, Santander, Colombia. Unpublished. Unpublished Internal report for Ventana Gold Corp. by Specialized Geological Mapping.Royero G. J. M.; Clavijo J. 2001. Mapa Geológico generalizado departamento de Santander. Escala 1: 400.000.Informe Ingeominas. 92 p.Sillitoe, R. 2008. Major Gold Deposits and Belts of the North and South American Cordillera: Distribu on, Tectonomagma c Se ngs, and Metallogenic Considera ons. Economic Geology, v. 103, pp. 663–687.Ward, D., Goldsmith, R., Cruz, B., Jaramillo, C., y Restrepo, H. 1973. Geología de los Cuadrángulos H-12, Bucaramanga y H-13, Pamplona, Departamento de Santander. U.S. Geological Survey e Ingeominas. Bole n Geológico XXI (1-3), 1-132.

OUTLINE, OBJECTIVES AND AIMS OF THE PROJECT

The project aims to make a characteriza on of the geology and the hydrothermal fea-tures of the La Mascota and La Bodega zones, determining similitudes and differences among classic hydrothermal deposits, as well as defining the paragene c sequences of these two zones. Microscopy, SEM, electron microprobe analysis will be necessary for defining the paragenesis and elements distribu on in sulphide phases and wolframite. X-ray diffrac on and Terraspeck analysis will be done in order to characterize properly the altera on in the zones as well as to properly choose alunite samples for stable iso-tope analysis and da ng. Mineralizing fluids fingerprint, oxida on state of the fluids and paleotemperature of mineralizing fluids precipita on are to be determined by means of the use of stable isotopes of Sulfur, Oxygen and Hydrogen mainly in alunites and pyrite . This may give clues for possible source and paths for the mineralizing fluids, which will probably help to develop an explora on tool for the project. In order to properly constraint the ages of the mineraliza on, K-Ar da ng on alunites will be done, as well as U-Pb da ng of the intrusives within the concession. Sampling within at least two sec ons in La Mascota and two sec ons in La Bodega will be necessary in order to achieve these objec ves.

Ackknowledgments

This project is developed by the MDRU at the University of Bri sh Columbia. The project is funded by Ventana Gold Corp. which has been undertaken by AUX. CVS Explota ons Ltda has given support and logis cs. Society of Economic Geologist SEG has given further funding for da ng.

Preliminar paragene c sequence at La Mascota based on DDH09LB112 log. The preliminar paragene c sequence was determined based on hand sample descrip on of vein cross-cu ng rela onships.Premineraliza on stages are related to propyli c altera on assemblages (epidote, chlorite, pyrite and in this case chalcopyrite1. Pyrite and quartz occur throughout almost the whole sequence of events and is related to gold deposi on in the mineraliza on stages. Quartz and alunite altera on (alunite1) characterize the altera on assemblage of mineraliza on stage 1. Quartz (difuse light gray silica) with fine pyrite (and visible gold) cu ng quartz+coarse Pyrite was no ced but whether or not is part of stage 1 is not clear yet. Mineraliza on stage 2 is defined mainly by hypogene (or specular?) hema te, pyrite and quartz deposi on. Evi-dence for this is that a quartz+pyrite+hypogene hema te (specular?) vein was found cu ng aluni zied-silicified clast. Mineral-iza on stage 3a is characterized by the occurrence of sphalerite and alunite2, which was no ced below 326 m depth of the drill hole. Unambiguous cross cu ng rela onships between stage 3 sphalerite and stage 3b are s ll elusive. The la er contains chalcopyrite2+chalcocite+covellite+bornite with quartz as defining characteris c. Mineraliza on stage 4 is characterized by the first occurrence of wolframite (and/or huebnerite) and the first occurrence of enargite, which seems to represent the last events of ore deposi on. Veins that contain wolframite and enargite are cu ng features (veins, cement of breccias and clasts) that contain the copper sulphides or sphalerite. Visible gold was also documented in this mineraliza on stage. LB112. 294.45 m.

quartz+pyrite+enargite+minor wolframite (mineraliza on stage 4) and visible gold vein, hosted in silicified gneiss.

LB112. 264.15m. BX5. Polimic tc clasts supported breccia with clast of cataclasite. Coarse pyrite (Py) with quartz cuts cataclasite and it is cut by quartz+wolframite+enargite+bornite? Vein (Mineraliza on stage 4) . This vein is cut by quartz-enargite (possibly luzonite) vein (end of mineraliza-

on stage 4). Banded silica precipitates in open space (part of mineraliza-on stage 4). It is also cut by quartz-enargite vein.