DAC Center at NSLS H. K. Mao (spokesperson) R. J. Hemley (co-spokesperson) Q. Z. Guo (X17B3)

DAC Center at NSLS H. K. Mao (spokesperson)R. J. Hemley (co-spokesperson)Q. Z. Guo (X17B3)Jingzhu Hu (X17C)Z. X. Liu (U2A)

Geophysical Laboratory, Carnegie Institution of Washington COnsortium for Materials Properties Research in Earth Sciences

IRX-RAYDAC Center at NSLS U2AX17BX17C

X17 Superconducting Wiggler White Beam FluxIR BrillianceX-RayBrillianceXray Spectroscopy Time Resolved XRD Xray Diffraction Amorphous Single-crystal XRD NSLS has a very bright future in the next decade

CapabilitiesX17B3 beam lineOn-line laser-heatingCryogenic conditionsEDXDADXDMicrobeam < 10 microns100 days/year beam time

X17C beam lineEDXDADXD

Dedicated high-pressure XRD beamlineDedicated high-pressure IR beamlineIntegration of XRD and laser-heating high P-T Double-sided laser heatingResistive heating and XRD above 100 GPa-1000 KIntegration of HP XRD, IR, on-line Raman at cryogenic TSide diffraction for HP elasticity tensor and rheologySingle crystal diffraction above 20 GPa (to 60 GPa)XRD of nanometer-size single crystalXRD of amorphous structure at high PPressure calibration based on volume and elasticity

Firsts

Hydrogen clathrate, H2-2H2O220 MPa234 KX-ray DiffractionExamples of Current Research: Clathrates Xe-SilicatesSanloup et al, GRL 2002Sanloup et al, PNAS 2002Xe ClathratesIR Absorption SpectroscopyW Mao et al, Science 2002

Chart2

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-0.1201877422-0.1090423622-0.0913184022-0.0625795922-0.0456380722

-0.1215115275-0.1096382675-0.0919108575-0.0633030275-0.0461460875

-0.1226045728-0.1107430428-0.0926116728-0.0642542328-0.0472190128

-0.1235028781-0.1120664781-0.0936432381-0.0651103281-0.0482566281

-0.1243252535-0.1136628635-0.0950469335-0.0658651435-0.0493259435

-0.1253019388-0.1143481488-0.0956351088-0.0660696888-0.0495829288

-0.1268760541-0.1147956941-0.0958633741-0.0662377441-0.0498403741

-0.1283795594-0.1161100094-0.0968230594-0.0670103294-0.0508193094

-0.1289149347-0.1171502647-0.0975705247-0.0677433247-0.0510765147

-0.12981651-0.11740736-0.09862665-0.0684355-0.05152633

-0.1318592653-0.1184564653-0.0999830953-0.0698879953-0.0531442653

-0.1335249806-0.1195563806-0.1005538606-0.0710553106-0.0538841306

-0.1342982559-0.1199270759-0.1008223759-0.0715224059-0.0544791959

-0.1350767212-0.1211574812-0.1017771112-0.0721889912-0.0557516112

-0.1362475965-0.1222513365-0.1035032365-0.0735074065-0.0568130265

-0.1378632719-0.1233857619-0.1051288119-0.0747406319-0.0578194319

-0.1396066772-0.1250423172-0.1061008472-0.0759797972-0.0590197072

-0.1407151925-0.1258227725-0.1065038625-0.0765634225-0.0596536225

-0.1420145378-0.1274170078-0.1079736678-0.0774207178-0.0607626078

-0.1434626631-0.1289062631-0.1097171831-0.0783935831-0.0616748731

-0.1445329484-0.1294615784-0.1105639784-0.0792281184-0.0622341784

-0.1457421237-0.1300287737-0.1114157537-0.0799658337-0.0631877637

-0.146917709-0.131098419-0.112146769-0.080573989-0.064035559

-0.1475953943-0.1316005843-0.1120267143-0.0809297943-0.0642199643

-0.1479417496-0.1317471696-0.1124273096-0.0811565696-0.0642747596

-0.1487246449-0.1328087049-0.1135559549-0.0824306449-0.0652762349

-0.1497232602-0.1336018602-0.1141540002-0.0832110202-0.0661380202

-0.1513430756-0.1345504556-0.1146601756-0.0839035656-0.0668240756

-0.1533483809-0.1369563109-0.1165542609-0.0861565809-0.0689866809

-0.1539024662-0.1383965862-0.1179179762-0.0870011962-0.0698854762

-0.1539463015-0.1389211315-0.1186659515-0.0869162315-0.0695495615

-0.1555377268-0.1400924968-0.1202137368-0.0879374668-0.0705816568

-0.1579416221-0.1420522421-0.1217522121-0.0894176221-0.0721154721

-0.1595990274-0.1442203674-0.1232422574-0.0908358574-0.0735032974

-0.1601504327-0.1457608227-0.1250142127-0.0921616827-0.0739457927

-0.161568708-0.147077178-0.126708858-0.093119308-0.074424348

-0.1633915933-0.1485220633-0.1279106633-0.0940430733-0.0758458033

-0.1647682086-0.1500862886-0.1290723986-0.0948634886-0.0772169586

-0.164794424-0.151440894-0.129995024-0.094801924-0.077214194

-0.1652462793-0.1531129793-0.1315775493-0.0959254993-0.0776879293

-0.1669612546-0.1546634846-0.1338400646-0.0979457746-0.0794319146

-0.1688390399-0.1557612399-0.1347780999-0.0988109999-0.0806657299

-0.1706233952-0.1573287452-0.1358114952-0.0997814252-0.0817387952

-0.1713368005-0.1581090505-0.1367829005-0.1006052105-0.0819867405

-0.1712798858-0.1584920858-0.1375022358-0.1008147958-0.0816211158

-0.1716902011-0.1594433811-0.1385598611-0.1011401911-0.0819900011

-0.1723392164-0.1598008264-0.1383635064-0.1012377364-0.0826012764

-0.1728705517-0.1604967117-0.1386930617-0.1020730517-0.0835079917

-0.173355307-0.161288807-0.139853267-0.103283767-0.084328987

-0.1741667423-0.1624992123-0.1414653323-0.1045182423-0.0851441123

-0.1745048377-0.1632394977-0.1425021977-0.1048440377-0.0855614177

-0.175033783-0.163591633-0.142659243-0.104943083-0.086160843

-0.1757283483-0.1641635183-0.1428173383-0.1054571083-0.0866230183

-0.1767133036-0.1653993236-0.1439113836-0.1065968236-0.0874269736

-0.1772181589-0.1668607689-0.1451432789-0.1079245989-0.0880803389

-0.1772001242-0.1673481142-0.1460285342-0.1082591642-0.0885684542

-0.1774704995-0.1673836395-0.1464070295-0.1081075395-0.0891252095

-0.1782521048-0.1680461348-0.1466201748-0.1085097448-0.0896162448

-0.1793278301-0.1693657101-0.1476650501-0.1098307301-0.0902103201

-0.1796921254-0.1703142054-0.1488595254-0.1110384054-0.0908431654

-0.1794682507-0.1707590307-0.1496128407-0.1115113407-0.0915233107

-0.180360716-0.171644356-0.150483636-0.112484066-0.092511006

-0.1812359814-0.1722989214-0.1513165414-0.1130883714-0.0932666514

-0.1816287967-0.1731187867-0.1523588167-0.1137824667-0.0941906067

-0.181696812-0.173664152-0.153155972-0.114397622-0.094430382

-0.1808267473-0.1733238773-0.1529847173-0.1142171673-0.0937717573

-0.1804375126-0.1737030126-0.1531673626-0.1144862726-0.0943294626

-0.1812523679-0.1755547979-0.1543177479-0.1154266479-0.0954922079

-0.1816828432-0.1766444132-0.1552098932-0.1160469332-0.0959291932

-0.1811682285-0.1765507885-0.1553026485-0.1161868285-0.0961045285

-0.1806458538-0.1768795138-0.1556068238-0.1161069238-0.0965537938

-0.1801027291-0.1769243791-0.1556485291-0.1163022691-0.0971225191

-0.1806885244-0.1768133944-0.1557365744-0.1169610144-0.0976081744

-0.1812042998-0.1765701198-0.1562278398-0.1175519798-0.0978707898

-0.1806152451-0.1772471151-0.1573254351-0.1179858851-0.0985980351

-0.1796729404-0.1774827304-0.1573980004-0.1182223804-0.0988604304

-0.1787343857-0.1775134657-0.1563815157-0.1179742657-0.0986356357

-0.178697331-0.178307841-0.156437511-0.118817811-0.099536501

-0.1788673463-0.1788260763-0.1572903463-0.1198378163-0.1008446263

-0.1785964516-0.1789393316-0.1579796016-0.1199976416-0.1013178116

0.05

500 MPa, 80 K

100 kPa, 80 K

100 kPa, 140 K

100 kPa, 126 K

100 kPa, 107 K

clo3

clo6

clo7

clo8

clo9

Wavenumber (cm-1)

Absorbance

Sheet1

wavenumberclo3clo4clo5clo6clo7clo8clo9clo10

3997.99-0.43-4.26E-012.38E-03-4.19E-01-3.83E-01-3.20E-019.63E-03-3.63E-013.23E-02-3.66E-015.15E-02-3.87E-017.12E-02-5.97E-02

3999.92-0.43-4.27E-01-3.64E-04-4.21E-01-3.86E-01-3.21E-017.74E-03-3.64E-013.05E-02-3.67E-014.96E-02-3.89E-016.83E-02-5.83E-02

4001.85-0.43-4.28E-01-1.85E-03-4.21E-01-3.86E-01-3.20E-018.17E-03-3.64E-012.94E-02-3.66E-015.00E-02-3.88E-016.82E-02-5.66E-02

4003.78-0.43-4.27E-01-2.02E-03-4.20E-01-3.85E-01-3.19E-018.24E-03-3.64E-012.85E-02-3.65E-015.01E-02-3.87E-016.82E-02-5.53E-02

4005.70-0.42-4.25E-01-2.14E-04-4.18E-01-3.82E-01-3.17E-019.41E-03-3.61E-013.02E-02-3.62E-015.19E-02-3.85E-016.94E-02-5.16E-02

4007.63-0.42-4.24E-01-5.02E-04-4.16E-01-3.81E-01-3.14E-011.16E-02-3.58E-013.20E-02-3.61E-015.28E-02-3.82E-017.11E-02-4.82E-02

4009.56-0.42-4.25E-01-2.53E-03-4.16E-01-3.82E-01-3.14E-011.07E-02-3.57E-013.23E-02-3.61E-015.18E-02-3.82E-017.03E-02-5.01E-02

4011.49-0.42-4.25E-01-3.11E-03-4.17E-01-3.82E-01-3.14E-019.25E-03-3.57E-013.18E-02-3.60E-015.15E-02-3.82E-016.96E-02-5.05E-02

4013.42-0.42-4.23E-01-2.19E-03-4.17E-01-3.81E-01-3.13E-019.57E-03-3.55E-013.24E-02-3.59E-015.19E-02-3.80E-017.02E-02-4.74E-02

4015.35-0.42-4.24E-01-4.12E-03-4.18E-01-3.82E-01-3.15E-016.98E-03-3.56E-013.08E-02-3.60E-014.96E-02-3.81E-016.87E-02-4.80E-02

4017.28-0.42-4.25E-01-6.24E-03-4.18E-01-3.83E-01-3.16E-015.37E-03-3.57E-012.93E-02-3.60E-014.92E-02-3.82E-016.72E-02-4.75E-02

4019.20-0.42-4.27E-01-8.56E-03-4.19E-01-3.83E-01-3.16E-014.43E-03-3.57E-012.78E-02-3.60E-014.85E-02-3.82E-016.61E-02-4.79E-02

4021.13-0.42-4.24E-01-6.81E-03-4.16E-01-3.81E-01-3.13E-016.28E-03-3.55E-012.88E-02-3.58E-014.87E-02-3.78E-016.86E-02-4.67E-02

4023.06-0.42-4.20E-01-3.38E-03-4.13E-01-3.78E-01-3.10E-018.60E-03-3.52E-013.09E-02-3.55E-015.10E-02-3.75E-017.11E-02-4.35E-02

4024.99-0.42-4.16E-01-8.60E-04-4.09E-01-3.73E-01-3.05E-011.19E-02-3.47E-013.49E-02-3.50E-015.53E-02-3.72E-017.29E-02-3.98E-02

4026.92-0.41-4.13E-011.87E-03-4.06E-01-3.70E-01-3.03E-011.36E-02-3.45E-013.64E-02-3.47E-015.70E-02-3.70E-017.41E-02-3.68E-02

4028.85-0.41-4.10E-013.36E-03-4.04E-01-3.68E-01-3.01E-011.47E-02-3.44E-013.65E-02-3.46E-015.73E-02-3.68E-017.53E-02-3.37E-02

4030.78-0.41-4.08E-014.42E-03-4.02E-01-3.65E-01-2.99E-011.59E-02-3.42E-013.72E-02-3.44E-015.88E-02-3.66E-017.61E-02-3.13E-02

4032.70-0.41-4.08E-013.29E-03-4.02E-01-3.66E-01-2.98E-011.52E-02-3.43E-013.60E-02-3.44E-015.75E-02-3.67E-017.45E-02-3.35E-02

4034.63-0.41-4.07E-013.61E-03-4.01E-01-3.65E-01-2.96E-011.69E-02-3.41E-013.70E-02-3.44E-015.70E-02-3.66E-017.44E-02-3.25E-02

4036.56-0.41-4.04E-016.09E-03-3.98E-01-3.61E-01-2.93E-011.92E-02-3.37E-013.98E-02-3.41E-015.89E-02-3.65E-017.53E-02-2.83E-02

4038.49-0.41-4.03E-016.44E-03-3.97E-01-3.60E-01-2.92E-011.93E-02-3.37E-013.93E-02-3.40E-015.91E-02-3.64E-017.52E-02-2.66E-02

4040.42-0.41-4.02E-016.32E-03-3.97E-01-3.59E-01-2.91E-011.94E-02-3.36E-013.95E-02-3.39E-015.91E-02-3.62E-017.60E-02-2.48E-02

4042.35-0.41-4.01E-016.07E-03-3.96E-01-3.58E-01-2.89E-012.02E-02-3.34E-014.01E-02-3.39E-015.86E-02-3.61E-017.61E-02-2.27E-02

4044.28-0.41-4.01E-014.89E-03-3.96E-01-3.57E-01-2.87E-012.12E-02-3.32E-014.08E-02-3.37E-015.92E-02-3.60E-017.58E-02-2.00E-02

4046.20-0.41-4.02E-013.25E-03-3.97E-01-3.58E-01-2.88E-011.93E-02-3.34E-013.88E-02-3.38E-015.73E-02-3.61E-017.40E-02-2.07E-02

4048.13-0.40-4.03E-011.83E-03-3.98E-01-3.61E-01-2.89E-011.70E-02-3.36E-013.58E-02-3.40E-015.41E-02-3.63E-017.10E-02-2.35E-02

4050.06-0.40-4.02E-011.57E-03-3.98E-01-3.61E-01-2.88E-011.75E-02-3.35E-013.59E-02-3.40E-015.40E-02-3.63E-017.01E-02-2.33E-02

4051.99-0.40-4.03E-01-5.39E-05-3.97E-01-3.60E-01-2.88E-011.65E-02-3.34E-013.53E-02-3.40E-015.26E-02-3.64E-016.91E-02-2.22E-02

4053.92-0.40-4.03E-01-1.27E-03-3.97E-01-3.60E-01-2.88E-011.53E-02-3.34E-013.50E-02-3.40E-015.19E-02-3.62E-016.97E-02-2.10E-02

4055.85-0.40-4.00E-017.45E-04-3.95E-01-3.58E-01-2.86E-011.73E-02-3.31E-013.66E-02-3.37E-015.41E-02-3.59E-017.15E-02-1.76E-02

4057.78-0.40-3.97E-012.76E-03-3.93E-01-3.56E-01-2.83E-011.94E-02-3.30E-013.73E-02-3.34E-015.60E-02-3.58E-017.23E-02-1.59E-02

4059.70-0.40-3.97E-012.03E-03-3.94E-01-3.55E-01-2.82E-011.92E-02-3.28E-013.75E-02-3.34E-015.51E-02-3.57E-017.19E-02-1.66E-02

4061.63-0.40-3.97E-011.28E-03-3.93E-01-3.54E-01-2.81E-011.91E-02-3.27E-013.83E-02-3.33E-015.47E-02-3.56E-017.23E-02-1.38E-02

4063.56-0.40-3.95E-011.89E-03-3.90E-01-3.52E-01-2.79E-012.00E-02-3.25E-013.96E-02-3.31E-015.62E-02-3.54E-017.36E-02-1.05E-02

4065.49-0.40-3.96E-016.82E-04-3.90E-01-3.53E-01-2.79E-011.92E-02-3.25E-013.88E-02-3.31E-015.54E-02-3.53E-017.36E-02-9.71E-03

4067.42-0.40-3.95E-013.65E-04-3.90E-01-3.54E-01-2.79E-011.80E-02-3.25E-013.71E-02-3.31E-015.44E-02-3.53E-017.25E-02-8.26E-03

4069.35-0.39-3.92E-012.06E-03-3.89E-01-3.51E-01-2.79E-011.79E-02-3.23E-013.82E-02-3.29E-015.59E-02-3.51E-017.32E-02-4.95E-03

4071.28-0.39-3.92E-011.19E-03-3.89E-01-3.51E-01-2.78E-011.79E-02-3.22E-013.82E-02-3.28E-015.52E-02-3.50E-017.31E-02-3.21E-03

4073.21-0.39-3.91E-011.67E-03-3.87E-01-3.48E-01-2.75E-011.98E-02-3.20E-013.99E-02-3.27E-015.59E-02-3.48E-017.45E-021.72E-04

4075.13-0.39-3.89E-012.75E-03-3.86E-01-3.47E-01-2.74E-012.01E-02-3.18E-014.10E-02-3.25E-015.70E-02-3.47E-017.52E-022.53E-03

4077.06-0.39-3.90E-011.25E-03-3.86E-01-3.48E-01-2.74E-011.85E-02-3.19E-013.93E-02-3.25E-015.62E-02-3.48E-017.31E-029.92E-04

4078.99-0.39-3.91E-01-1.30E-03-3.87E-01-3.48E-01-2.74E-011.84E-02-3.19E-013.78E-02-3.26E-015.39E-02-3.48E-017.17E-02-1.03E-03

4080.92-0.39-3.90E-01-5.15E-04-3.86E-01-3.46E-01-2.71E-011.98E-02-3.17E-013.87E-02-3.25E-015.44E-02-3.46E-017.29E-021.80E-03

4082.85-0.39-3.87E-017.59E-04-3.84E-01-3.45E-01-2.70E-012.02E-02-3.15E-013.98E-02-3.22E-015.65E-02-3.45E-017.36E-023.58E-03

4084.78-0.39-3.87E-011.13E-04-3.83E-01-3.45E-01-2.68E-012.10E-02-3.15E-013.94E-02-3.21E-015.63E-02-3.43E-017.40E-022.11E-03

4086.71-0.39-3.87E-01-7.80E-04-3.82E-01-3.45E-01-2.67E-012.15E-02-3.14E-013.90E-02-3.21E-015.57E-02-3.42E-017.40E-021.28E-03

4088.63-0.39-3.84E-019.68E-04-3.79E-01-3.42E-01-2.65E-012.23E-02-3.11E-014.12E-02-3.18E-015.78E-02-3.39E-017.68E-023.02E-03

4090.56-0.38-3.84E-011.81E-04-3.80E-01-3.42E-01-2.66E-012.08E-02-3.12E-013.94E-02-3.17E-015.74E-02-3.39E-017.58E-023.87E-03

4092.49-0.38-3.84E-01-4.35E-04-3.80E-01-3.43E-01-2.66E-012.00E-02-3.13E-013.80E-02-3.18E-015.59E-02-3.40E-017.33E-024.92E-03

4094.42-0.38-3.83E-01-2.57E-04-3.78E-01-3.41E-01-2.64E-012.09E-02-3.11E-013.90E-02-3.17E-015.62E-02-3.39E-017.38E-026.70E-03

4096.35-0.38-3.82E-01-6.40E-04-3.77E-01-3.40E-01-2.63E-012.11E-02-3.09E-013.96E-02-3.14E-015.74E-02-3.37E-017.49E-027.15E-03

4098.28-0.38-3.82E-01-6.30E-04-3.77E-01-3.38E-01-2.63E-012.02E-02-3.09E-013.92E-02-3.14E-015.71E-02-3.36E-017.50E-028.87E-03

4100.21-0.38-0.3802-2.12E-04-3.76E-01-3.37E-01-2.62E-012.04E-02-3.07E-013.97E-02-3.13E-015.67E-02-3.36E-017.43E-021.18E-02

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4210.14-0.33-3.11E-011.78E-02-3.08E-01-2.65E-01-1.96E-013.40E-02-2.53E-014.29E-02-2.58E-016.01E-02-2.84E-017.41E-026.14E-02

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4217.85-0.32-3.05E-011.97E-02-3.00E-01-2.55E-01-1.90E-013.71E-02-2.44E-014.83E-02-2.51E-016.36E-02-2.78E-017.68E-026.66E-02

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4235.21-0.32-3.15E-012.08E-03-3.12E-01-2.68E-01-1.95E-012.38E-02-2.44E-013.99E-02-2.48E-015.82E-02-2.75E-017.21E-026.21E-02

4237.14-0.32-3.15E-013.72E-04-3.13E-01-2.67E-01-1.95E-012.25E-02-2.44E-013.89E-02-2.48E-015.74E-02-2.74E-017.20E-026.24E-02

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4240.99-0.31-3.20E-01-5.86E-03-3.16E-01-2.72E-01-1.98E-011.77E-02-2.47E-013.43E-02-2.51E-015.34E-02-2.75E-016.90E-026.30E-02

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4254.49-0.31-3.40E-01-3.21E-02-3.35E-01-2.91E-01-2.17E-01-7.59E-03-2.60E-011.46E-02-2.62E-013.53E-02-2.86E-015.16E-025.26E-02

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4260.28-0.30-3.44E-01-3.93E-02-3.40E-01-2.96E-01-2.24E-01-1.67E-02-2.65E-017.06E-03-2.65E-012.98E-02-2.88E-014.68E-025.28E-02

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4264.14-0.30-3.48E-01-4.49E-02-3.44E-01-3.01E-01-2.28E-01-2.33E-02-2.68E-011.78E-03-2.68E-012.49E-02-2.91E-014.25E-024.97E-02

4266.07-0.30-3.49E-01-4.67E-02-3.45E-01-3.01E-01-2.29E-01-2.47E-02-2.70E-01-5.50E-04-2.69E-012.37E-02-2.91E-014.12E-025.13E-02

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4426.14-0.23-3.36E-01-1.09E-01-3.32E-01-2.82E-01-2.29E-01-9.97E-02-2.76E-01-8.15E-02-2.69E-01-5.23E-02-2.94E-01-3.69E-026.56E-02

4428.07-0.23-3.36E-01-1.10E-01-3.32E-01-2.81E-01-2.28E-01-1.00E-01-2.75E-01-8.22E-02-2.69E-01-5.30E-02-2.94E-01-3.76E-026.60E-02

4430.00-0.23-3.36E-01-1.11E-01-3.32E-01-2.81E-01-2.29E-01-1.01E-01-2.75E-01-8.30E-02-2.69E-01-5.40E-02-2.94E-01-3.83E-026.61E-02

4431.92-0.22-3.37E-01-1.12E-01-3.33E-01-2.82E-01-2.29E-01-1.03E-01-2.76E-01-8.42E-02-2.70E-01-5.59E-02-2.94E-01-3.93E-026.58E-02

4433.85-0.22-3.36E-01-1.13E-01-3.33E-01-2.82E-01-2.28E-01-1.03E-01-2.75E-01-8.47E-02-2.70E-01-5.62E-02-2.93E-01-3.98E-026.62E-02

4435.78-0.22-3.37E-01-1.15E-01-3.33E-01-2.83E-01-2.29E-01-1.04E-01-2.76E-01-8.66E-02-2.70E-01-5.72E-02-2.94E-01-4.12E-026.63E-02

4437.71-0.22-3.39E-01-1.17E-01-3.34E-01-2.83E-01-2.29E-01-1.06E-01-2.77E-01-8.81E-02-2.70E-01-5.85E-02-2.94E-01-4.26E-026.62E-02

4439.64-0.22-3.38E-01-1.17E-01-3.34E-01-2.83E-01-2.29E-01-1.06E-01-2.76E-01-8.85E-02-2.70E-01-5.90E-02-2.94E-01-4.30E-026.69E-02

4441.57-0.22-3.37E-01-1.17E-01-3.34E-01-2.82E-01-2.29E-01-1.07E-01-2.76E-01-8.90E-02-2.69E-01-5.95E-02-2.93E-01-4.33E-026.71E-02

4443.50-0.22-3.38E-01-1.19E-01-3.34E-01-2.83E-01-2.29E-01-1.08E-01-2.76E-01-9.03E-02-2.70E-01-6.11E-02-2.93E-01-4.44E-026.67E-02

4445.42-0.22-3.38E-01-1.20E-01-3.34E-01-2.83E-01-2.29E-01-1.09E-01-2.76E-01-9.13E-02-2.71E-01-6.26E-02-2.94E-01-4.56E-026.70E-02

4447.35-0.22-3.39E-01-1.22E-01-3.34E-01-2.83E-01-2.29E-01-1.10E-01-2.76E-01-9.19E-02-2.70E-01-6.33E-02-2.93E-01-4.61E-026.70E-02

4449.28-0.22-3.39E-01-1.23E-01-3.34E-01-2.83E-01-2.29E-01-1.11E-01-2.76E-01-9.26E-02-2.70E-01-6.43E-02-2.93E-01-4.72E-026.66E-02

4451.21-0.22-3.39E-01-1.24E-01-3.35E-01-2.83E-01-2.29E-01-1.12E-01-2.76E-01-9.36E-02-2.70E-01-6.51E-02-2.94E-01-4.83E-026.65E-02

4453.14-0.21-3.39E-01-1.24E-01-3.35E-01-2.83E-01-2.30E-01-1.14E-01-2.76E-01-9.50E-02-2.70E-01-6.59E-02-2.94E-01-4.93E-026.72E-02

4455.07-0.21-3.39E-01-1.25E-01-3.34E-01-2.82E-01-2.30E-01-1.14E-01-2.76E-01-9.56E-02-2.70E-01-6.61E-02-2.93E-01-4.96E-026.80E-02

4457.00-0.21-3.39E-01-1.27E-01-3.34E-01-2.82E-01-2.29E-01-1.15E-01-2.75E-01-9.59E-02-2.69E-01-6.62E-02-2.92E-01-4.98E-026.84E-02

4458.93-0.21-3.40E-01-1.28E-01-3.35E-01-2.82E-01-2.30E-01-1.16E-01-2.76E-01-9.68E-02-2.69E-01-6.70E-02-2.93E-01-5.08E-026.96E-02

4460.85-0.21-3.40E-01-1.29E-01-3.35E-01-2.82E-01-2.30E-01-1.17E-01-2.75E-01-9.76E-02-2.69E-01-6.77E-02-2.92E-01-5.11E-027.14E-02

4462.78-0.21-3.40E-01-1.30E-01-3.35E-01-2.82E-01-2.29E-01-1.17E-01-2.76E-01-9.86E-02-2.68E-01-6.84E-02-2.91E-01-5.15E-027.19E-02

4464.71-0.21-3.41E-01-1.32E-01-3.36E-01-2.83E-01-2.29E-01-1.18E-01-2.76E-01-1.00E-01-2.69E-01-6.99E-02-2.92E-01-5.31E-027.08E-02

4466.64-0.21-3.42E-01-1.34E-01-3.36E-01-2.83E-01-2.30E-01-1.20E-01-2.76E-01-1.01E-01-2.69E-01-7.11E-02-2.92E-01-5.39E-027.08E-02

4468.57-0.21-3.41E-01-1.34E-01-3.36E-01-2.82E-01-2.29E-01-1.20E-01-2.75E-01-1.01E-01-2.69E-01-7.15E-02-2.92E-01-5.45E-027.15E-02

4470.50-0.21-3.41E-01-1.35E-01-3.37E-01-2.83E-01-2.29E-01-1.21E-01-2.75E-01-1.02E-01-2.68E-01-7.22E-02-2.92E-01-5.58E-027.21E-02

4472.43-0.21-3.42E-01-1.36E-01-3.38E-01-2.84E-01-2.30E-01-1.22E-01-2.76E-01-1.04E-01-2.69E-01-7.35E-02-2.92E-01-5.68E-027.24E-02

4474.35-0.20-3.42E-01-1.38E-01-3.38E-01-2.84E-01-2.30E-01-1.23E-01-2.77E-01-1.05E-01-2.69E-01-7.47E-02-2.92E-01-5.78E-027.17E-02

4476.28-0.20-3.43E-01-1.40E-01-3.38E-01-2.84E-01-2.31E-01-1.25E-01-2.77E-01-1.06E-01-2.70E-01-7.60E-02-2.93E-01-5.90E-027.11E-02

4478.21-0.20-3.43E-01-1.41E-01-3.38E-01-2.84E-01-2.30E-01-1.26E-01-2.76E-01-1.07E-01-2.69E-01-7.66E-02-2.92E-01-5.97E-027.23E-02

4480.14-0.20-3.44E-01-1.42E-01-3.40E-01-2.84E-01-2.31E-01-1.27E-01-2.77E-01-1.08E-01-2.69E-01-7.74E-02-2.93E-01-6.08E-027.30E-02

4482.07-0.20-3.44E-01-1.43E-01-3.40E-01-2.85E-01-2.32E-01-1.29E-01-2.78E-01-1.10E-01-2.69E-01-7.84E-02-2.93E-01-6.17E-027.28E-02

4484.00-0.20-3.44E-01-1.45E-01-3.40E-01-2.85E-01-2.31E-01-1.29E-01-2.78E-01-1.11E-01-2.69E-01-7.92E-02-2.92E-01-6.22E-027.32E-02

4485.93-0.20-3.45E-01-1.46E-01-3.40E-01-2.85E-01-2.31E-01-1.30E-01-2.77E-01-1.11E-01-2.69E-01-8.00E-02-2.92E-01-6.32E-027.36E-02

4487.85-0.20-3.45E-01-1.47E-01-3.40E-01-2.86E-01-2.31E-01-1.31E-01-2.77E-01-1.12E-01-2.69E-01-8.06E-02-2.92E-01-6.40E-027.38E-02

4489.78-0.20-3.45E-01-1.48E-01-3.41E-01-2.85E-01-2.31E-01-1.32E-01-2.76E-01-1.12E-01-2.68E-01-8.09E-02-2.91E-01-6.42E-027.46E-02

4491.71-0.20-3.44E-01-1.48E-01-3.40E-01-2.84E-01-2.30E-01-1.32E-01-2.76E-01-1.12E-01-2.67E-01-8.12E-02-2.91E-01-6.43E-027.54E-02

4493.64-0.20-3.44E-01-1.49E-01-3.40E-01-2.84E-01-2.30E-01-1.33E-01-2.76E-01-1.14E-01-2.68E-01-8.24E-02-2.91E-01-6.53E-027.57E-02

4495.57-0.19-3.44E-01-1.50E-01-3.40E-01-2.84E-01-2.30E-01-1.34E-01-2.76E-01-1.14E-01-2.68E-01-8.32E-02-2.91E-01-6.61E-027.58E-02

4497.50-0.19-3.45E-01-1.51E-01-3.40E-01-2.84E-01-2.30E-01-1.35E-01-2.75E-01-1.15E-01-2.68E-01-8.39E-02-2.90E-01-6.68E-027.59E-02

4499.43-0.19-3.46E-01-1.53E-01-3.41E-01-2.85E-01-2.32E-01-1.37E-01-2.76E-01-1.17E-01-2.69E-01-8.62E-02-2.92E-01-6.90E-027.55E-02

4501.35-0.19-3.46E-01-1.54E-01-3.41E-01-2.85E-01-2.32E-01-1.38E-01-2.77E-01-1.18E-01-2.69E-01-8.70E-02-2.92E-01-6.99E-027.70E-02

4503.28-0.19-3.45E-01-1.54E-01-3.40E-01-2.85E-01-2.32E-01-1.39E-01-2.77E-01-1.19E-01-2.68E-01-8.69E-02-2.90E-01-6.95E-027.80E-02

4505.21-0.19-3.46E-01-1.56E-01-3.41E-01-2.85E-01-2.32E-01-1.40E-01-2.77E-01-1.20E-01-2.68E-01-8.79E-02-2.91E-01-7.06E-027.86E-02

4507.14-0.19-3.47E-01-1.58E-01-3.42E-01-2.86E-01-2.33E-01-1.42E-01-2.78E-01-1.22E-01-2.69E-01-8.94E-02-2.91E-01-7.21E-027.89E-02

4509.07-0.19-3.48E-01-1.60E-01-3.42E-01-2.86E-01-2.34E-01-1.44E-01-2.78E-01-1.23E-01-2.69E-01-9.08E-02-2.92E-01-7.35E-027.85E-02

4511.00-0.19-3.47E-01-1.60E-01-3.43E-01-2.87E-01-2.35E-01-1.46E-01-2.79E-01-1.25E-01-2.69E-01-9.22E-02-2.91E-01-7.39E-027.94E-02

4512.93-0.19-3.48E-01-1.62E-01-3.42E-01-2.88E-01-2.35E-01-1.47E-01-2.80E-01-1.27E-01-2.69E-01-9.31E-02-2.91E-01-7.44E-027.99E-02

4514.85-0.19-3.49E-01-1.63E-01-3.43E-01-2.88E-01-2.36E-01-1.49E-01-2.80E-01-1.28E-01-2.70E-01-9.40E-02-2.91E-01-7.58E-027.97E-02

4516.78-0.18-3.49E-01-1.65E-01-3.43E-01-2.88E-01-2.37E-01-1.50E-01-2.81E-01-1.29E-01-2.69E-01-9.49E-02-2.92E-01-7.72E-028.03E-02

4518.71-0.18-3.48E-01-1.65E-01-3.43E-01-2.88E-01-2.37E-01-1.51E-01-2.81E-01-1.30E-01-2.68E-01-9.48E-02-2.91E-01-7.72E-028.14E-02

4520.64-0.18-3.48E-01-1.65E-01-3.43E-01-2.88E-01-2.38E-01-1.53E-01-2.81E-01-1.32E-01-2.69E-01-9.59E-02-2.90E-01-7.77E-028.21E-02

4522.57-0.18-3.49E-01-1.67E-01-3.44E-01-2.90E-01-2.39E-01-1.55E-01-2.83E-01-1.34E-01-2.70E-01-9.79E-02-2.91E-01-7.94E-028.13E-02

4524.50-0.18-3.50E-01-1.69E-01-3.45E-01-2.90E-01-2.39E-01-1.56E-01-2.83E-01-1.35E-01-2.70E-01-9.88E-02-2.92E-01-8.07E-028.01E-02

4526.43-0.18-3.51E-01-1.71E-01-3.45E-01-2.90E-01-2.39E-01-1.57E-01-2.83E-01-1.36E-01-2.70E-01-9.98E-02-2.92E-01-8.17E-028.06E-02

4528.35-0.18-3.50E-01-1.71E-01-3.45E-01-2.90E-01-2.39E-01-1.58E-01-2.83E-01-1.37E-01-2.70E-01-1.01E-01-2.91E-01-8.20E-028.17E-02

4530.28-0.18-3.50E-01-1.71E-01-3.44E-01-2.89E-01-2.39E-01-1.58E-01-2.83E-01-1.38E-01-2.69E-01-1.01E-01-2.90E-01-8.16E-028.22E-02

4532.21-0.18-3.49E-01-1.72E-01-3.44E-01-2.89E-01-2.39E-01-1.59E-01-2.83E-01-1.39E-01-2.68E-01-1.01E-01-2.89E-01-8.20E-028.22E-02

4534.14-0.18-3.49E-01-1.72E-01-3.43E-01-2.88E-01-2.38E-01-1.60E-01-2.82E-01-1.38E-01-2.68E-01-1.01E-01-2.89E-01-8.26E-028.31E-02

4536.07-0.18-3.48E-01-1.73E-01-3.42E-01-2.87E-01-2.38E-01-1.60E-01-2.81E-01-1.39E-01-2.68E-01-1.02E-01-2.89E-01-8.35E-028.45E-02

4538.00-0.17-3.48E-01-1.73E-01-3.42E-01-2.87E-01-2.38E-01-1.61E-01-2.81E-01-1.40E-01-2.68E-01-1.03E-01-2.89E-01-8.43E-028.52E-02

4539.93-0.17-3.48E-01-1.74E-01-3.42E-01-2.86E-01-2.38E-01-1.62E-01-2.82E-01-1.41E-01-2.68E-01-1.05E-01-2.89E-01-8.51E-028.58E-02

4541.85-0.17-3.47E-01-1.75E-01-3.41E-01-2.86E-01-2.38E-01-1.63E-01-2.82E-01-1.43E-01-2.68E-01-1.05E-01-2.88E-01-8.56E-028.67E-02

4543.78-0.17-3.47E-01-1.75E-01-3.40E-01-2.85E-01-2.37E-01-1.64E-01-2.82E-01-1.43E-01-2.67E-01-1.05E-01-2.88E-01-8.62E-028.73E-02

4545.71-0.17-3.47E-01-1.76E-01-3.40E-01-2.84E-01-2.37E-01-1.64E-01-2.81E-01-1.43E-01-2.66E-01-1.05E-01-2.88E-01-8.66E-028.86E-02

4547.64-0.17-3.47E-01-1.77E-01-3.39E-01-2.84E-01-2.37E-01-1.65E-01-2.81E-01-1.44E-01-2.67E-01-1.07E-01-2.88E-01-8.74E-028.84E-02

4549.57-0.17-3.46E-01-1.77E-01-3.40E-01-2.84E-01-2.38E-01-1.67E-01-2.81E-01-1.45E-01-2.67E-01-1.08E-01-2.87E-01-8.81E-028.75E-02

4551.50-0.17-3.45E-01-1.77E-01-3.39E-01-2.83E-01-2.38E-01-1.67E-01-2.81E-01-1.46E-01-2.67E-01-1.08E-01-2.87E-01-8.86E-028.79E-02

4553.43-0.17-3.45E-01-1.77E-01-3.37E-01-2.81E-01-2.37E-01-1.67E-01-2.81E-01-1.46E-01-2.65E-01-1.08E-01-2.87E-01-8.91E-028.94E-02

4555.36-0.17-3.45E-01-1.78E-01-3.36E-01-2.80E-01-2.37E-01-1.68E-01-2.80E-01-1.47E-01-2.65E-01-1.09E-01-2.86E-01-8.96E-028.99E-02

4557.28-0.17-3.45E-01-1.79E-01-3.36E-01-2.80E-01-2.37E-01-1.69E-01-2.80E-01-1.48E-01-2.65E-01-1.10E-01-2.86E-01-9.02E-028.92E-02

4559.21-0.16-3.44E-01-1.80E-01-3.36E-01-2.79E-01-2.37E-01-1.70E-01-2.81E-01-1.49E-01-2.66E-01-1.11E-01-2.86E-01-9.08E-028.91E-02

4561.14-0.16-3.43E-01-1.79E-01-3.35E-01-2.78E-01-2.37E-01-1.71E-01-2.80E-01-1.50E-01-2.65E-01-1.12E-01-2.85E-01-9.15E-028.86E-02

4563.07-0.16-3.43E-01-1.80E-01-3.34E-01-2.78E-01-2.37E-01-1.72E-01-2.80E-01-1.50E-01-2.65E-01-1.12E-01-2.85E-01-9.25E-028.82E-02

4565.00-0.16-3.43E-01-1.81E-01-3.33E-01-2.77E-01-2.36E-01-1.72E-01-2.80E-01-1.51E-01-2.65E-01-1.13E-01-2.85E-01-9.33E-028.89E-02

4566.93-0.16-3.43E-01-1.82E-01-3.33E-01-2.76E-01-2.36E-01-1.73E-01-2.80E-01-1.52E-01-2.65E-01-1.14E-01-2.85E-01-9.42E-028.94E-02

4568.86-0.16-3.42E-01-1.82E-01-3.32E-01-2.75E-01-2.36E-01-1.74E-01-2.80E-01-1.53E-01-2.65E-01-1.14E-01-2.85E-01-9.44E-029.04E-02

4570.78-0.16-3.40E-01-1.81E-01-3.30E-01-2.73E-01-2.35E-01-1.73E-01-2.79E-01-1.53E-01-2.63E-01-1.14E-01-2.83E-01-9.38E-029.22E-02

4572.71-0.16-3.39E-01-1.80E-01-3.29E-01-2.72E-01-2.34E-01-1.74E-01-2.78E-01-1.53E-01-2.63E-01-1.14E-01-2.83E-01-9.43E-029.31E-02

4574.64-0.16-3.39E-01-1.81E-01-3.28E-01-2.71E-01-2.35E-01-1.76E-01-2.79E-01-1.54E-01-2.63E-01-1.15E-01-2.83E-01-9.55E-029.36E-02

4576.57-0.16-3.38E-01-1.82E-01-3.26E-01-2.70E-01-2.35E-01-1.77E-01-2.79E-01-1.55E-01-2.63E-01-1.16E-01-2.82E-01-9.59E-029.34E-02

4578.50-0.16-3.37E-01-1.81E-01-3.25E-01-2.68E-01-2.34E-01-1.77E-01-2.78E-01-1.55E-01-2.62E-01-1.16E-01-2.82E-01-9.61E-029.39E-02

4580.43-0.15-3.35E-01-1.81E-01-3.24E-01-2.66E-01-2.34E-01-1.77E-01-2.77E-01-1.56E-01-2.61E-01-1.16E-01-2.81E-01-9.66E-029.46E-02

4582.36-0.15-3.34E-01-1.80E-01-3.23E-01-2.64E-01-2.33E-01-1.77E-01-2.76E-01-1.56E-01-2.60E-01-1.16E-01-2.81E-01-9.71E-029.47E-02

4584.28-0.15-3.34E-01-1.81E-01-3.20E-01-2.63E-01-2.32E-01-1.77E-01-2.76E-01-1.56E-01-2.60E-01-1.17E-01-2.81E-01-9.76E-029.58E-02

4586.21-0.15-3.33E-01-1.81E-01-3.19E-01-2.61E-01-2.31E-01-1.77E-01-2.75E-01-1.56E-01-2.60E-01-1.18E-01-2.80E-01-9.79E-029.61E-02

4588.14-0.15-3.32E-01-1.81E-01-3.18E-01-2.59E-01-2.30E-01-1.77E-01-2.75E-01-1.57E-01-2.59E-01-1.18E-01-2.80E-01-9.86E-029.55E-02

4590.07-0.15-3.30E-01-1.80E-01-3.16E-01-2.57E-01-2.30E-01-1.77E-01-2.75E-01-1.57E-01-2.58E-01-1.18E-01-2.79E-01-9.89E-029.64E-02

4592.00-0.15-3.28E-01-1.79E-01-3.13E-01-2.55E-01-2.29E-01-1.78E-01-2.73E-01-1.56E-01-2.57E-01-1.18E-01-2.78E-01-9.86E-029.83E-02

4593.93-0.15-3.27E-01-1.79E-01-3.12E-01-2.53E-01-2.29E-01-1.78E-01-2.72E-01-1.56E-01-2.57E-01-1.19E-01-2.78E-01-9.95E-029.90E-02

4595.86-0.15-3.26E-01-1.79E-01-3.10E-01-2.52E-01-2.28E-01-1.79E-01-2.72E-01-1.57E-01-2.57E-01-1.20E-01-2.78E-01-1.01E-019.89E-02

4597.78-0.15-3.25E-01-1.79E-01-3.08E-01-2.49E-01-2.28E-01-1.79E-01-2.72E-01-1.58E-01-2.57E-01-1.20E-01-2.78E-01-1.01E-019.90E-02

Sheet2

Sheet3

Ultrahigh-pressure metamorphism and meteorite impact metamorphismXie et al, GCA 2002Sobolev et al, PNAS 2000Chen et al, in pressNew Mineral, Tuite, in shocked meteoriteTwo New Minerals, high pressure phases of chromite, in DAC and in shocked meteorite

High Resolution Diffraction in Helium Medium Mg0.1Fe0.9O K0=15510 GPa K0=3.60.8Mao et al, JPCM 2002

Chart1

11.6571720940.016410848810.502104333310.10860.02007666670.02007666670.01641084880.1264830.12648311.48790.0301150.03011511.772411.7641683020.02476667420.024766674210.52699940.00421610.0042161

11.55898398440.032637140910.556311333310.14070.0240920.0240920.03263714090.11845233330.118452333311.7710.64582722350.02317109110.023171091110.49507750.01144370.0114437

11.46946397260.040585524710.4800210.15880.01565980.01565980.04058552470.1144370.11443711.763310.61496231720.0308350490.03083504910.46576556670.00421610.0042161

11.4208302680.040470714310.435851333310.65470.0240920.0240920.04047071430.02609966670.026099666711.7610.59185282830.03079027950.030790279510.43404443330.00622376670.0062237667

11.40464963720.032345978810.40172110.69080.0240920.0240920.03234597880.09235266670.092352666711.7410.56109238430.01536531510.015365315110.41858540.01084140.0108414

11.32397568850.032193259610.34149110.76310.02609966670.02609966670.03219325960.07428366670.074283666711.7210.37782976670.01023910.0102391

11.29181293660.024099201710.279253333310.81130.02609966670.02609966670.02409920170.05621466670.056214666711.710.28266636670.01003833330.0100383333

11.23567476510.016012839310.273230333310.84940.02810733330.02810733330.01601283930.05019166670.050191666711.6810.18569606670.01967513330.0196751333

11.16377092640.023916675910.100610.93580.13451366670.13451366670.02391667590.06826066670.068260666711.6610.16039946670.0180.018

11.10805829430.039728410411.17270.03972841040.06424533330.064245333311.6410.11382160.01887206670.0188720667

11.06837724720.03170698670.03170698670.0301150.03011511.6210.08651733330.01646286670.0164628667

11.0287908140.03953918280.039539182811.610.05881153330.00662530.0066253

10.94203314480.03146523790.031465237911.58

10.90274871680.0156949370.01569493711.56

10.84790864670.0234633970.02346339711.54

10.78545981810.02337326160.023373261611.52

10.73101409030.01552968870.015529688711.5

10.69998467120.00774986830.007749868311.48

10.66901512550.01546981530.015469815311.46

10.63810539550.00771996050.007719960511.44

0.01543245310.015432453111.42

11.4

11.38

11.36

11.34

11.32

11.3

11.28

11.26

11.24

11.22

11.2

11.18

11.16

11.14

11.12

11.1

11.08

11.06

11.04

11.02

11

10.98

10.96

10.94

10.92

10.9

10.88

10.86

10.84

10.82

10.8

10.78

10.76

10.74

10.72

10.7

10.68

10.66

10.64

10.62

10.6

10.58

10.56

10.54

10.52

10.5

10.48

10.46

10.44

10.42

10.4

10.38

10.36

10.34

10.32

10.3

10.28

10.26

10.24

10.22

10.2

10.18

10.16

10.14

10.12

10.1

10.08

10.06

10.04

10.02

10

9.98

9.96

9.94

9.92

9.9

9.88

9.86

9.84

9.82

9.8

9.78

HydroCubic1

nonhydroCompRhomb1

nonhydro-release1

9.0GPa rhomb1

Birch-Murnaghan EOS

HydroCubic2

HydroRhomb2

Pressure (GPa)

Volume, cm3/mol

Sheet1

P(GPa)latt conststand devlatt const3 reflectV (A^3)V,cm^3/molV stan devcommentsEOSPP(f)VP(f)V

1.64.2620.0024.2644.26277.417711.65720.0164011.7724011.7724

2.94.250.0044.2524.2576.765611.55900.03260.031621663311.770.031621663311.7700

4.24.2390.0054.2414.23976.171111.46950.04060.120056811511.76330.120056811511.7633

4.94.2330.0054.2364.23475.848111.42080.0405did not use 3110.163700087311.760.163700087311.76

5.24.2310.0044.2314.23275.740711.40460.0323pressure +0.10.429419474111.740.296298643211.75

6.64.2210.0044.2214.21975.204911.32400.03220.697236584311.720.429419474111.74

6.74.2170.0034.224.21774.991311.29180.02410.967168765211.70.563064733411.73

8.04.210.0024.2134.21174.618511.23570.0160used 3 ref1.239233528511.680.697236584311.72

8.94.2010.0034.2034.274.140911.16380.02391.513448551111.660.831937200311.71

10.04.1940.0054.1944.19273.770911.10810.03971.789831677411.640.967168765211.70

10.84.1890.0044.1894.18873.507411.06840.03172.068400921111.621.102933473211.69

11.54.1840.0054.1844.18273.244511.02880.03952.34917446711.61.239233528511.68

12.74.1730.0044.1734.17472.668310.94200.03152.632170672611.581.37607114611.67

13.74.1680.0024.1684.16972.407410.90270.01572.917408070411.561.513448551111.66

14.74.1610.0034.1614.1672.043210.84790.02353.204905369611.541.651367979411.65

16.04.1530.0034.1564.15471.628510.78550.0234used 3 ref3.49468145811.521.789831677411.64

17.04.1460.0024.1484.14871.266910.73100.01553.786755403911.51.928841902111.63

17.64.1420.0014.1434.14271.060810.70000.00774.081146458311.482.068400921111.62

18.34.1380.0024.1394.13970.855210.66900.01554.377874056811.462.20851101311.61

18.84.1340.0014.1354.13570.649910.63810.00774.676957821511.442.34917446711.60

19.34.1330.0024.1334.13370.598610.63040.01544.978417563211.422.490393583211.59

12.24.18673.349611.0428V (calc)5.282273283411.42.632170672611.58

24.351.827328573810.40520.02010.50215.588545176611.382.774508057311.57

24.651.756599701110.39100.02410.55635.897253632111.362.917408070411.56

25.451.59920305510.35940.01610.48006.208419236411.343.060873056111.55

27.151.239083513210.28710.02410.43596.522062775311.323.204905369611.54

28.450.997509546710.23860.02410.40176.838205236111.33.349507377611.53

29.550.789805744610.19690.02610.34157.1568678111.283.49468145811.52

30.650.581603851910.15510.02610.27937.478071894111.263.640429999911.51

31.350.452598372910.12920.02810.27327.801839093811.243.786755403911.50

35.149.76398804589.99100.13510.10068.128191225311.223.933660082211.49

34.349.902208201910.01870.12610.10868.457150317811.24.081146458311.48

33.550.054623941610.04930.11810.14078.788738615811.184.229216967611.47

32.550.229453760610.08440.11410.15889.122978581711.164.377874056811.46

22.052.314261995710.50300.026110.65479.459892898211.144.527120184611.45

21.052.53660966310.54760.092410.69089.799504470611.124.676957821511.44

19.952.786900215810.59790.074310.763110.141836429511.14.827389449611.43

18.753.067076207910.65410.056210.811310.486912133511.084.978417563211.42

18.153.209530134510.68270.050210.849410.834755171211.065.130044668411.41

15.953.749958492410.79120.068310.935811.185389364611.045.282273283411.40

13.554.372073717410.91610.064211.172711.538838770811.025.435105938711.39

9.0rhomb55.645691515911.17180.030111.487911.8951276858115.588545176611.38

9.04.2660.0134.2664.26277.635911.69000.106946.694412.25428064610.985.742593552111.37

12.616322431910.965.897253632111.36

MgFeO212.981278070510.946.052527996311.35

P(GPa)latt conststand devV (A^3)V,cm^3/molV stan devcomments13.349172838110.926.208419236411.34

0.04.2750.00378.128311.76420.024813.72003226310.96.364929957111.33

18.74.1350.00370.701210.64580.023214.093882128810.886.522062775311.32

19.34.1310.00470.496210.61500.03083 reflect14.470748477110.866.679820320911.31

20.04.1280.00470.342710.59190.030814.850657610310.846.838205236111.30

20.54.1240.00270.138410.56110.015415.23363609510.826.997220176511.29

21.052.43410.52699940.00420.021015.619710764510.87.1568678111.28

21.852.27510.49507750.01140.057016.008908722510.787.317150817811.27

22.352.12910.46576556670.00420.021016.401257345710.767.478071894111.26

22.951.97110.43404443330.00620.031016.796784287310.747.639633745911.25

23.351.89410.41858540.01080.054017.195517480110.727.801839093811.24

23.851.69110.37782976670.01020.051017.597485139510.77.964690671311.23

25.751.217010.28266636670.01000.050018.002715767210.688.128191225311.22

27.150.734010.18569606670.01970.098018.411238154510.668.292343516211.21

28.050.608010.16039946670.01800.100018.823081385210.648.457150317811.20

28.950.376010.11382160.01890.094019.238274839510.628.622614417411.19

29.750.240010.08651733330.01650.082019.656848197410.68.788738615811.18

30.550.10210.05881153330.00660.033020.07883144210.588.955525727811.17

20.504254863210.569.122978581711.16

21.04.1210.00269.985510.53810.015320.933149061410.549.291100019811.15

21.84.1150.00569.680210.49210.038221.365544950810.529.459892898211.14

22.34.1090.00569.375910.44630.038121.801473763710.59.62936008711.13

22.94.1040.00469.122910.40820.030422.240967053510.489.799504470611.12

23.34.1020.00469.021910.39300.030422.684056699410.469.970328947211.11

23.130774909310.4410.141836429511.10

23.581154224510.4210.314029844511.09

24.035227523110.410.486912133511.08

24.493028024310.3810.660486252311.07

24.954589292610.3610.834755171211.06

25.419945241410.3411.009721875411.05

25.889130137810.3211.185389364611.04

26.362178606310.311.361760653211.03

26.839125633610.2811.538838770811.02

27.320006572510.2611.716626761911.01

27.804857146510.2411.895127685811.00

28.293713454310.2212.074344617210.99

28.786611974410.212.25428064610.98

29.283589569310.1812.434938877410.97

29.784683490810.1612.616322431910.96

30.289931384110.1412.798434445810.95

30.79937129310.1212.981278070510.94

31.313041664410.113.164856473610.93

31.830981353710.0813.349172838110.92

32.353229629410.0613.534230362910.91

32.87982617810.0413.72003226310.90

33.410811109910.0213.906581769310.89

33.94622496361014.093882128810.88

34.48610871179.9814.281936604910.87

35.03050376599.9614.470748477110.86

35.57945198269.9414.660321041410.85

36.13299566839.9214.850657610310.84

36.6911775859.915.041761512910.83

37.25404095639.8815.23363609510.82

37.82162947269.8615.42628471910.81

38.39398729729.8415.619710764510.80

38.97115907239.8215.813917627810.79

39.55318992489.816.008908722510.78

40.14012547229.7816.204687479110.77

40.73201182919.7616.401257345710.76

41.32889561319.7416.598621787510.75

41.93082395159.7216.796784287310.74

42.53784448739.716.995748345510.73

43.15000538599.6817.195517480110.72

43.76735534189.6617.396095226810.71

44.3899435859.6417.597485139510.70

17.799690789710.69

18.002715767210.68

18.206563680110.67

18.411238154510.66

18.616742835110.65

18.823081385210.64

19.030257486510.63

19.238274839510.62

19.447137163710.61

19.656848197410.60

19.86741169810.59

20.07883144210.58

20.291111225310.57

20.504254863210.56

20.718266190410.55

20.933149061410.54

21.148907350210.53

21.365544950810.52

21.583065777310.51

21.801473763610.50

22.020772864210.49

22.240967053510.48

22.462060326710.47

22.684056699410.46

22.906960207910.45

23.130774909310.44

23.355504881810.43

23.581154224510.42

23.807727057710.41

24.035227523110.40

24.263659783710.39

24.493028024310.38

24.723336451210.37

24.954589292610.36

25.186790798510.35

25.419945241410.34

25.654056915510.33

25.889130137810.32

26.125169247410.31

26.362178606310.30

26.600162599210.29

26.839125633610.28

27.079072140110.27

27.320006572510.26

27.561933407810.25

27.804857146510.24

28.048782312810.23

28.293713454310.22

28.53965514310.21

28.786611974410.20

29.034588568410.19

29.283589569310.18

29.533619645710.17

29.784683490810.16

30.036785822610.15

30.289931384110.14

30.544124943210.13

30.79937129310.12

31.05567525210.11

31.313041664410.10

31.571475399810.09

31.830981353710.08

32.091564447710.07

32.353229629410.06

32.615981872710.05

32.87982617810.04

33.144767572510.03

33.410811109910.02

33.67796187110.01

33.946224963610.00

34.2156055239.99

34.48610871179.98

34.757739729.97

35.03050376599.96

35.30440609549.95

35.57945198269.94

35.855646739.93

36.13299566839.92

36.41150415729.91

36.6911775859.90

36.97202136929.89

37.25404095639.88

37.53724182229.87

37.82162947259.86

38.10720944259.85

38.39398729729.84

38.6819686329.83

38.97115907239.82

39.26156427449.81

39.55318992489.80

39.84604174129.79

40.14012547229.78

40.43544689779.77

40.73201182919.76

41.02982610939.75

41.32889561319.74

41.62922624759.73

41.93082395159.72

42.23369469679.71

42.53784448739.70

42.84327936039.69

43.15000538599.68

43.45802866749.67

43.76735534189.66

44.07799157959.65

44.3899435859.64

44.70321759699.63

45.01781988819.62

45.33375676619.61

45.65103457319.60

45.96965968639.59

46.28963851819.58

46.61097751649.57

46.93368316479.56

47.25776198259.55

47.58322052529.54

47.91006538479.53

48.23830318959.52

48.56794060499.51

48.89898433329.50

49.23144111399.49

49.56531772429.48

49.90062097899.47

50.2373577319.46

50.57553487169.45

50.91515933049.44

51.25623807569.43

51.59877811479.42

51.94278649439.41

52.28827030049.40

52.6352366599.39

52.98369273599.38

53.33364573739.37

53.68510290979.36

54.03807154079.35

54.39255895879.34

54.74857253369.33

55.10611967679.32

55.46520784139.31

55.82584452299.30

56.18803725919.29

56.55179363059.28

56.91712126059.27

57.28402781589.26

57.65252100659.25

58.02260858679.24

58.39429835449.23

58.76759815219.22

59.14251586699.21

59.5190594319.20

59.89723682169.19

60.27705606179.18

60.65852522019.17

61.04165241179.16

61.42644579799.15

61.81291358679.14

62.20106403369.13

62.59090544099.12

62.98244615929.11

63.37569458669.10

63.77065916999.09

64.16734840439.08

64.56577083439.07

64.96593505329.06

65.36784970459.05

65.77152348119.04

66.17696512679.03

66.58418343539.02

66.9931872529.01

67.4039854739.00

67.81658704658.99

68.23100097248.98

68.64723630318.97

69.06530214368.96

69.48520765198.95

69.90696203958.94

70.33057457178.93

70.75605456778.92

71.18341140158.91

71.61265450168.90

72.0437933528.89

72.47683749228.88

72.91179651758.87

73.34868007988.86

73.78749788778.85

74.22825970668.84

74.67097535988.83

75.11565472838.82

75.56230775138.81

76.01094442688.80

76.46157481188.79

76.91420902288.78

77.36885723638.77

77.82552968898.76

78.2842366788.75

78.7449885628.74

79.20779576098.73

79.67266875698.72

80.13961809418.71

80.60865437988.70

81.07978828438.69

81.55303054178.68

82.02839195018.67

82.50588337238.66

82.9855157368.65

83.46730003428.64

83.95124732618.63

84.4373687378.62

84.92567545918.61

85.41617875198.60

85.90888994248.59

86.40382042618.58

86.90098166718.57

87.40038519858.56

87.90204262328.55

Chart3

11.6571720940.016410848810.526999410.10860.00421610.00421610.01641084880.1264830.12648310.50210433330.02007666670.020076666711.772410.53

11.55898398440.032637140910.495077510.14070.01144370.01144370.03263714090.11845233330.118452333310.55631133330.0240920.02409211.7710.52

11.46946397260.040585524710.465765566710.15880.00421610.00421610.04058552470.1144370.11443710.480020.01565980.015659811.763310.51

11.4208302680.040470714310.434044433310.65470.00622376670.00622376670.04047071430.02609966670.026099666710.43585133330.0240920.02409211.7610.5

11.40464963720.032345978810.418585410.69080.01084140.01084140.03234597880.09235266670.092352666710.4017210.0240920.02409211.7510.49

11.32397568850.032193259610.377829766710.76310.01023910.01023910.03219325960.07428366670.074283666710.3414910.02609966670.026099666711.7410.48

11.29181293660.024099201710.282666366710.81130.01003833330.01003833330.02409920170.05621466670.056214666710.27925333330.02609966670.026099666711.7310.47

11.23567476510.016012839310.185696066710.84940.01967513330.01967513330.01601283930.05019166670.050191666710.27323033330.02810733330.028107333311.7210.46

11.16377092640.023916675910.160399466710.93580.0180.0180.02391667590.06826066670.068260666710.10060.13451366670.134513666711.7110.45

11.10805829430.039728410410.113821611.17270.01887206670.01887206670.03972841040.06424533330.064245333311.710.44

11.06837724720.031706986710.086517333311.48790.01646286670.01646286670.03170698670.0301150.03011511.6910.43

11.0287908140.039539182810.05881153330.00662530.00662530.039539182811.6810.42

10.94203314480.03146523790.031465237911.6710.41

10.90274871680.0156949370.01569493711.6610.4

10.84790864670.0234633970.02346339711.6510.39

10.78545981810.02337326160.023373261611.6410.38

10.73101409030.01552968870.015529688711.6310.37

10.69998467120.00774986830.007749868311.6210.36

10.66901512550.01546981530.015469815311.6110.35

10.63810539550.00771996050.007719960511.610.34

11.7641683020.02476667420.024766674211.5910.33

10.64582722350.02317109110.023171091111.5810.32

10.61496231720.0308350490.03083504911.5710.31

10.59185282830.03079027950.030790279511.5610.3

10.56109238430.01536531510.015365315111.5510.29

11.5410.28

11.5310.27

11.5210.26

11.5110.25

11.510.24

11.4910.23

11.4810.22

11.4710.21

11.4610.2

11.4510.19

11.4410.18

11.4310.17

11.4210.16

11.4110.15

11.410.14

11.3910.13

11.3810.12

11.3710.11

11.36

11.35

11.34

11.33

11.32

11.31

11.3

11.29

11.28

11.27

11.26

11.25

11.24

11.23

11.22

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11.2

11.19

11.18

11.17

11.16

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11.13

11.12

11.11

11.1

11.09

11.08

11.07

11.06

11.05

11.04

11.03

11.02

11.01

11

10.99

10.98

10.97

10.96

10.95

10.94

10.93

10.92

10.91

10.9

10.89

10.88

10.87

10.86

10.85

10.84

10.83

10.82

10.81

10.8

10.79

10.78

10.77

10.76

10.75

10.74

10.73

10.72

10.71

10.7

10.69

10.68

10.67

10.66

10.65

10.64

10.63

10.62

10.61

10.6

10.59

10.58

10.57

10.56

10.55

10.54

Cubic, hydrostatic compression

Rhombohedral, hydrostatic compression

Rhombohedral, quasihydrostatic release

Rhombohedral, quasihydrostatic compression

Birch-Murnaghan EOS

B-M High Pressure

Pressure,GPa

Volume, cm3/mol

Sheet2

Sheet3

Rheology of Core & Mantle MineralsMerkel et al, EPSL 2003Merkel et al, JGR 2002

Plasticity of Iron and the Earths Inner Core[Wenk et al. Nature 405, 1044 (2000)] 54 GPa 220 GPaEXP.THEORY Basal slip is dominant deformation mechanism Aggregate VP anisotropy is 4-18% in core Earth:

Laser-Heating[Shen et al., Geophys. Res. Lett. 25, 373 (1998);Ma et al., to be published]Williams et al. (1987)Boehler (1993)

Large Volume DAC & Big MACRapid Growth of Single-Crystal Diamond by Homoepitaxial CVD[Yan, et al, PNAS 2002]XRD with CVD DAC to 230 GPa[Manuscript in prep.]XRD, Raman, IR and laser -heating with 10 carat moissanite anvil cell

[Xu et al, JPCM 2002]

Planetary Gases and IcesGoncharov et al, PNAS 2002HYDROGENStructure/bonding/dynamics of of hydrogen and H2O from XRD, IR, and Raman

Volume (cm3/mol)

Pressure (GPa)

Compression of H2O(300 K)

200

0

50

100

150

6

8

10

12

14

16

18

Ice VI

Water

Ice X

Ice VII

[Hemley and Mao, J. Phys. Condens, Matter 49, 11157 (1998)]

bcc-like oxygen for ice VII and X No other major phase transitions to at least 210 GPa

Beamtime and UsersUsers write proposals to NSLSTwo tracks:NSLS review committee gives ratings and assigns 25% of the beam timeIf a COMPRES member does not receive beamt ime from NSLS, it will be reviewed for consideration for PRT beam timeSo far, 100% of COMPRES member proposals have been awarded beam time through one of the above two tracks. We could still do much better because many times more people in the COMPRES community could be greatly benefited from this state-of-the-art facility but have not learned about the capabilities and do not know how to get started.

Future Goals with COMPRESDAC/NSLS focuses on SR development and operation. We rely on COMPRES to reach out the greater user community and coordinate user needs to appropriate facilities. COMPRES handles 100% of the DAC/NSLS PRT beam time and financial responsibilities to satisfy the needs of the greater community.Improving COMPRES and DAC/NSLS communication

DAC/NSLS Budget and Resources

Yearly operation budget (including beamline staff salaries, maintenance, and upgrade) : $600 K ($300 K from COMPRES)Total beam time from 3 beamlines: 500 days/yearCost of beam time : $1200/day

This is among the most cost-efficient and most productive high-pressure beamline in the world. In comparison:Multi-anvil at NSLS: > $5000/dayGSECARS beam time: $5000/day

AcknowledgmentsOriginal PRT MembersEarl Skelton- -- NRLDave Schiferl -- LANLJagan Akella -- LLNLPaul McMillan -- ASUFunding SourcesNSF-EARNSF-DMRDOE-DPDOE-BESNASANavyCarnegieBeamline DevelopmentTom DuffyGuoyin ShenYanzhang MaMaddury SomayazuluMichael HanflandMing LiTechnical HelpLarry CarrPeter EngLarry FingerAlexander GoncharovGwyn Williams Yan WuMark RiversUsers

Today my talk title is high pressure research at X17C using diamond anvil cell.

Documents

DAC Center at NSLS H. K. Mao (spokesperson) R. J. Hemley (co-spokesperson) Q. Z. Guo (X17B3)