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研 究 業 績 リ ス ト

‒ 査 読 論 文 ‒ (1) The First Example of Asymmetric Selenoxide Elimination: Application to the

Synthesis of Chiral Allenes N. Komatsu, Y. Nishibayashi, T. Sugita, S. Uemura J. Chem. Soc., Chem. Commun., 46-47 (1992).

(2) Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides Using R-(+)-Binaphthol N. Komatsu, Y. Nishibayashi, T. Sugita, S. Uemura Tetrahedron Lett., 33, 5391-5394 (1992).

(3) Asymmetric [2,3]Sigmatropic Rearrangement via Chiral Selenoxide with Sharpless Oxidants N. Komatsu, Y. Nishibayashi, S. Uemura Tetrahedron Lett., 34, 2339-2342 (1993).

(4) Telluroxide Elimination by Oxidation of Alkyl Aryl Tellurides: Remarkable Effect of Added Triethylamine Y. Nishibayashi, N. Komatsu, K. Ohe, S. Uemura J. Chem. Soc., Perkin Trans. 1, 1133-1138 (1993).

(5) Asymmetric Selenoxide Elimination Leading to Chiral Allenic Sulfones N. Komatsu, T. Murakami, Y. Nishibayashi, T. Sugita, S. Uemura J. Org. Chem., 58, 3697-3702 (1993).

(6) Dinuclear (η5-C5Me5)Ru Complexes Triply Bridged by Tellurium or Selenium Ligands - Syntheses and Characterisation of (η5-C5Me5)Ru(µ2-RTeTeR)(µ2-TeR)2Ru(η5-C5Me5) and [(η5-C5Me5)Ru(µ2-SeR)3Ru(η5-C5Me5)]Cl (R = Tol, Ph) H. Matsuzaka, T. Ogino, M. Nishio, M. Hidai, Y. Nishibayashi, S. Uemura J. Chem. Soc., Chem. Commun., 223-224 (1994).

(7) Synthesis of Chiral Diferrocenyl Diselenides and Their Application to Asymmetric Reactions Y. Nishibayashi, J. D. Singh, S. Uemura, S. Fukuzawa Tetrahedron Lett., 35, 3115-3118 (1994).

(8) Syntheses and Reactivities of Ferrocenyl Organyl Tellurides Y. Nishibayashi, T. Chiba, J. D. Singh, S. Uemura, S. Fukuzawa J. Organomet. Chem., 473, 205-213 (1994).

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(9) Rhodium(I)-catalysed Asymmetric Hydrosilylation of Ketones using New

Diferrocenyl Dichalcogenides (R,S)-{[EC5H3CHMe(NMe2)]Fe(C5H5)}2 (E=S, Se, Te) as Chiral Ligands Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, S. Uemura J. Chem. Soc., Chem. Commun., 1375-1376 (1994).

(10) Asymmetric Synthesis and Highly Diastereoselective ortho-Lithiation of Oxazolinylferrocenes Y. Nishibayashi, S. Uemura Synlett, 79-81 (1995).

(11) Stereo- and Chemo-Selectivity in Reduction of α-[Phenyl(or Methyl)seleno]- alkyl Aryl Ketones with Metal Hydrides I. Aoki, Y. Nishibayashi, S. Uemura Bull. Chem. Soc. Jpn., 68, 337-340 (1995).

(12) The First Example of Chirality Transfer in Allylic Telluroxides – Possible [2,3]-Sigmatropic Rearrangement T. Chiba, Y. Nishibayashi, J. D. Singh, K. Ohe, S. Uemura Tetrahedron Lett., 36, 1519-1522 (1995).

(13) Synthesis of [R,S;R,S]- and [S,R;S,R]-Bis[2-[1-(dimethylamino)ethyl]-ferrocenyl] Diselenides and Their Application to Asymmetric Selenoxide Elimination and [2,3]Sigmatropic Rearrangement Y. Nishibayashi, J. D. Singh, S. Fukuzawa, S. Uemura J. Org. Chem., 60, 4114-4120 (1995).

(14) High Chirality Transfer in Chiral Selenimides via [2,3]Sigmatropic Rearrangement Y. Nishibayashi, T. Chiba, K. Ohe, S. Uemura J. Chem. Soc., Chem. Commun., 1243-1244 (1995).

(15) The First Example of Enantioselective Carbenoid Addition to Organochalcogen Atoms : Application to [2,3]Sigmatropic Rearrangement of Allylic Chalcogen Ylides Y. Nishibayashi, K. Ohe, S. Uemura J. Chem. Soc., Chem. Commun., 1245-1246 (1995).

(16) Highly Selective Asymmetric Intramolecular Selenocyclisation Y. Nishibayashi, S. K. Srivastava, H. Takada, S. Fukuzawa, S. Uemura J. Chem. Soc., Chem. Commun., 2321-2322 (1995).

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(17) Allylic Amine Formation by Imination of Allylic Tellurides Y. Nishibayashi, S. K. Srivastava, K. Ohe, S. Uemura Tetrahedron Lett., 36, 6725-6728 (1995).

(18) Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand for the Asymmetric Hydrosilylation of Ketones Y. Nishibayashi, K. Segawa, K. Ohe, S. Uemura Organometallics, 14, 5486-5487 (1995).

(19) Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Nucleophilic Ring-Opening of meso-Epoxides Y. Nishibayashi, J. D. Singh, S. Fukuzawa, S. Uemura J. Chem. Soc., Perkin Trans. 1, 2871-2876 (1995).

(20) Palladium-catalyzed Cross-coupling Reactions between Organic Tellurides and Alkenes Y. Nishibayashi, C. S. Cho, S. Uemura J. Organomet. Chem., 507, 197-200 (1996).

(21) Novel Chiral Ligands, Diferrocenyl Dichalcogenides and Their Derivatives, for the Rh(I)- and Ir(I)-Catalyzed Asymmetric Hydrosilylation Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, K. Ohe, S. Uemura Organometallics, 15, 370-379 (1996).

(22) Enantioselective ortho-Lithiation of Substituted Ferrocenes Y. Nishibayashi, Y. Arikawa, K. Ohe, S. Uemura J. Org. Chem., 61, 1172-1174 (1996).

(23) Iridium(I)-Catalysed Asymmetric Hydrosilylation of Ketones using Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand Y. Nishibayashi, K. Segawa, H. Takada, K. Ohe, S. Uemura Chem. Commun., 847-848 (1996).

(24) Novel Asymmetric Catalytic Synthesis of Sulfimides H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura Chem. Commun., 931-932 (1996).

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(25) Oxidative Addition of Diferrocenyl Dichalcogenides to [(η5-C5Me5)Ru(µ3-Cl)]4. Syntheses, Crystal Structures and Some Reactivities of Ferrocenylchalcogenolate-Bridged Diruthenium Complexes [(η5-C5Me5)RuCl(µ2-EFc)]2 (E=S, Se, Te; Fc=ferrocenyl) H. Matsuzaka, J.-P. Qü, T. Ogino, M. Nishio, Y. Nishibayashi, Y. Ishii, S. Uemura, M. Hidai J. Chem. Soc., Dalton Trans., 4307-4312 (1996).

(26) Palladium-catalyzed Homocoupling Reactions of Organic Tellurides Y. Nishibayashi, C. S. Cho, K. Ohe, S. Uemura J. Organomet. Chem., 526, 335-339 (1996).

(27) Rhodium(I)-, Iridium(I)-, and Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones using Diferrocenyl Dichalcogenides as Chiral Ligands Y. Nishibayashi, J. D. Singh, Y. Arikawa, S. Uemura, M. Hidai J. Organomet. Chem., 531, 13-18 (1997).

(28) Allylation of Arenes Catalysed by Thiolate-Bridged Diruthenium Complexes Y. Nishibayashi, M. Yamanashi, Y. Takagi, M. Hidai Chem. Commun., 859-860 (1997).

(29) Synthesis, Structures and Reactivities of Rhodium and Ruthenium Complexes with Novel Chiral Cyclopentadienyl-ferrocenyldiphenylphosphine Bidentate Ligand Y. Nishibayashi, I. Takei, M. Hidai Organometallics, 16, 3091-3093 (1997).

(30) Synthesis and Structure of Novel Chiral Oxazolinylferrocenes and Oxazolinylferrocenylphosphines, and Their Rhodium(I)-Complexes Y. Nishibayashi, K. Segawa, Y. Arikawa, K. Ohe, M. Hidai, S. Uemura J. Organomet. Chem., 545 & 546, 381-398 (1997).

(31) Catalytic Asymmetric Sulfimidation H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura, C. P. Baird, T. J. Sparey, P. C. Taylor J. Org. Chem., 62, 6512-6518 (1997).

(32) Bimetallic System for Nitrogen Fixation: Ruthenium-assisted Protonation of Coordinated N2 on Tungsten with H2 Y. Nishibayashi, S. Iwai, M. Hidai Science, 279, 540-542 (1998).

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(33) A Model for Protonation of Dinitrogen by Nitrogenase: Protonation of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Dinuclear Complexes Y. Nishibayashi, S. Iwai, M. Hidai J. Am. Chem. Soc., 120, 10559-10560 (1998).

(34) Ruthenium-catalyzed Asymmetric Hydrosilylation of Ketones and Imine Y. Nishibayashi, I. Takei, S. Uemura, M. Hidai Organometallics, 17, 3420-3422 (1998).

(35) Synthesis of Heterobimetallic Fe-M (M=Ni, Pd, Pt) Complexes Containing 1,1'-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes S. Takemoto, S. Kuwata, Y. Nishibayashi, M. Hidai Inorg. Chem., 37, 6428-6434 (1998).

(36) Ruthenium(II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones using Chiral Oxazolinylferrocenylphosphines and its Ru(II) Complex Y. Arikawa, M. Ueoka, K. Matoba, Y. Nishibayashi, M. Hidai, S. Uemura J. Organomet. Chem., 572, 163-168 (1999).

(37) The Use of Chiral Diferrocenyl Diselenides for Highly Selective Asymmetric Intramolecular Selenocyclization H. Takada, Y. Nishibayashi, S. Uemura J. Chem. Soc., Perkin Trans. 1, 1511-1516 (1999).

(38) Iridium-Catalyzed Asymmetric Hydrosilylation of Imines by Chiral Oxazolinyl-Phosphine Ligands I. Takei, Y. Nishibayashi, Y. Arikawa, S. Uemura, M. Hidai Organometallics, 18, 2271-2274 (1999).

(39) Extremely High-Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl2(PPh3)(oxazolinylferrocenylphosphine) Y. Nishibayashi, I. Takei, S. Uemura, M. Hidai Organometallics, 18, 2291-2293 (1999).

(40) Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by the Use of an Acidic Ruthenium Dihydrogen Complex Y. Nishibayashi, I. Takei, M. Hidai Angew. Chem., Int. Ed. Engl., 38, 3047-3050 (1999).

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(41) Cyclization of Terminal Diynes Catalyzed by Thiolate-bridged Diruthenium Complexes: A Simple Synthetic Route to Endo-Macrocyclic (Z)-1-En-3-ynes Y. Nishibayashi, M. Yamanashi, I. Wakiji, M. Hidai Angew. Chem., Int. Ed. Engl., 39, 2909-2911 (2000).

(42) Synthesis and Structures of 1,1'-Ferrocenedithiolato-Bridged Di- and Trinuclear Ruthenium Complexes S. Takemoto, S. Kuwata, Y. Nishibayashi, M. Hidai Organometallics, 19, 3249-3252 (2000).

(43) Formation of Ammonia in the Reactions of a Tungsten Dinitrogen with Ruthenium Dihydrogen Complexes under Mild Reaction Conditions Y. Nishibayashi, S. Takemoto, S. Iwai, M. Hidai Inorg. Chem., 39, 5946-5957 (2000).

(44) Novel Propargylic Substitution Reactions Catalyzed by Thiolate-Bridged Diruthenium Complexes via Allenylidene Intermediates Y. Nishibayashi, I Wakiji, M. Hidai J. Am. Chem. Soc., 122, 11019-11020 (2000).

(45) Protonation of Coordinated N2 on Tungsten with H2 Mediated by Sulfido-bridged Dinuclear Molybdenum Complexes Y. Nishibayashi, I. Wakiji, K. Hirata, M. Rakowski DuBois, M. Hidai Inorg. Chem., 40, 578-590 (2001).

(46) Ruthenium-Catalyzed Propargylic Alkylation of Propargylic Alcohols with Ketones: Straightforward Synthesis of γ-Keto Acetylenes Y. Nishibayashi, I. Wakiji, Y. Ishiii, S. Uemura, M. Hidai J. Am. Chem. Soc., 123, 3393-3394 (2001).

(47) Ruthenium-Catalysed Asymmetric Hydrosilylation of Ketoximes Using Chiral Oxazolinylferrocenylphosphines, I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura, M. Hidai Chem. Commun., 2360-2361 (2001).

(48) Kinetic Resolution of Secondary Alcohols via Chiral Pd(II)-Complex-Catalysed Enantioselective Benzoylation Using CO and Organobismuth(V) Compound Y. Miyake, T. Iwata, K.-G. Chung, Y. Nishibayashi, S. Uemura Chem. Commun., 2584-2585 (2001).

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(49) Asymmetric Synthesis of Epoxides from Aromatic Aldehydes and Benzyl Halides Catalyzed by C2 Symmetric Optically Active Sulfides Having Binaphthyl Skeleton Y. Miyake, A. Oyamada, Y. Nishibayashi, S. Uemura Heteroatom Chemistry, 13, 270–275 (2002).

(50) Ruthenium-Catalyzed Cycloaddition of Propargylic Alcohols with Phenol

Derivatives via Allenylidene Intermediates: Catalytic Use of the Allenylidene Ligand as C3 Unit Y. Nishibayashi, Y. Inada, M. Hidai, S. Uemura J. Am. Chem. Soc., 124, 7900–7901 (2002).

(51) Palladium(II) Complex-Catalysed Enantioselective Benzoylation of Alcohols Using Carbon Monoxide and Organobismuth(V) Compound T. Iwata, Y. Miyake, Y. Nishibayashi, S. Uemura J. Chem. Soc., Perkin Trans. 1, 1548-1554 (2002).

(52) Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, S. Uemura J. Am. Chem. Soc., 124, 11846–11847 (2002).

(53) Asymmetric Baeyer-Villiger Oxidation of Cyclic Ketones Using Chiral Organoselenium Catalysts Y. Miyake, Y. Nishibayashi, S. Uemura Bull. Chem. Soc. Jpn., 75, 2233–2237 (2002).

(54) Ruthenium-Catalyzed Propargylic Substitution Reaction of Propargylic Alcohols with Thiols: A General Synthetic Route to Propargylic Sulfides Y. Inada, Y. Nishibayashi, M. Hidai, S. Uemura J. Am. Chem. Soc., 124, 15172–15173 (2002).

(55) Kinetic Resolution of Racemic Ferrocenylphosphine Compounds by Enantioselective Oxidation Using Cyclic Selenoxides as Having a Chiral Ligand Y. Miyake, A. Yamauchi, Y. Nishibayashi, S. Uemura Bull. Chem. Soc. Jpn., 76, 381–387 (2003).

(56) Synthesis of Diruthenium Complexes Containing Chiral Thiolate-bridged Ligands and Their Application to Catalytic Propargylic Alkylation of Propargylic Alcohols with Acetone Y. Nishibayashi, G. Onodera, Y. Inada, M. Hidai, S. Uemura Organometallics, 22, 873–876 (2003).

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(57) Propargylation of Aromatic Compounds with Propargylic Alcohols Catalyzed

by Cationic Diruthenium Complex Y. Nishibayashi, Y. Inada, M. Yoshikawa, M. Hidai, S. Uemura Angew. Chem., Int. Ed., 42, 1495–1498 (2003).

(58) Ruthenium-Catalyzed Carbon–Carbon Bond Formation between Propargylic Alcohols and Alkenes via the Allenylidene –Ene Reaction Y. Nishibayashi, Y. Inada, M. Hidai, S. Uemura J. Am. Chem. Soc., 125, 6060–6061 (2003).

(59) Novel Ruthenium- and Platinum-Catalyzed Sequential Reactions: Synthesis of Tri- and Tetra-Substituted Furans and Pyrroles from Propargylic Alcohols and Ketones Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. D. Milton, M. Hidai, S. Uemura Angew. Chem., Int. Ed., 42, 2681–2684 (2003).

(60) Oxidative Kinetic Resolution of Racemic Alcohols Catalyzed by Chiral Ferrocenyloxazolinylphosphine–Ruthenium Complexes Y. Nishibayashi, A. Yamauchi, G. Onodera, S. Uemura J. Org. Chem., 68, 5875 (2003).

(61) Novel Catalytic Hydrogenolysis of Silyl Enol Ethers by the Use of Acidic Ruthenium Dihydrogen Complexes I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura, M. Hidai J. Organomet. Chem., 679, 32–42 (2003).

(62) Preparation of a Series of Chalcogenolate-Bridged Diruthenium Complexes and their Catalytic Activities toward the Propargylic Substitution Reactions Y. Nishibayashi, H. Imajima, G. Onodera, M. Hidai, S. Uemura Organometallics, 23, 26–30 (2004).

(63) Ruthenium-Catalyzed Cycloaddition between Propargylic Alcohols and Cyclic 1,3-Dicarbonyl Compounds via Allenylidene Intermediates Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, S. Uemura J. Org. Chem., 69, 3408–3412 (2004).

(64) Synthesis of Dinuclear Complexes Bearing Metalloporphyrin-Phosphine Hybrid Ligand and Their Catalytic Activity toward Hydrosilylation of Ketones M. Saito, Y. Nishibayashi, S. Uemura Organometallics, 23, 4012–4017 (2004).

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(65) A Non-metal System for Nitrogen Fixation Y. Nishibayashi, M. Saito, S. Uemura, S. Takekuma, H. Takekuma, Z. Yoshida Nature, 428, 279-280 (2004).

(66) Stereospecific Carbon–Carbon Bond Formation by the Reaction of a Chiral Episelenonium Ion with Aromatic Compounds K. Okamoto, Y. Nishibayashi, S. Uemura, A. Toshimitsu Tetrahedron Lett., 45, 6137–6139 (2004).

(67) Preparation of Alkanechalcogenolate- and Benzenechalcogenolate-Bridged Diruthenium Complexes and Their Catalytic Activities toward Propargylation of Acetone with Propargylic Alcohols Y. Nishibayashi, H. Imajima, G. Onodera, Y. Inada, M. Hidai, S. Uemura Organometallics, 23, 5100–5103 (2004).

(68) Ruthenium- and Gold-Catalysed Sequential Reactions: a Straightforward

Synthesis of Substituted Oxazoles from Propargylic Alcohols and Amides M. D. Milton, Y. Inada, Y. Nishibayashi, S. Uemura Chem. Commun., 2712–2713 (2004).

(69) Double Phosphinylation of Propargylic Alcohols: a Novel Synthetic Route to 1,2-Bis(diphenylphosphino)ethane Derivatives M. D. Milton, G. Onodera, Y. Nishibayashi, S. Uemura Org. Lett., 6, 3993–3995 (2004).

(70) Ruthenium-Catalyzed Allylation of Aromatic Compounds and Allylic Ether Formation G. Onodera, H. Imajima, M. Yamanashi, Y. Nishibayashi, M. Hidai, S. Uemura Organometallics, 23, 5841–5848 (2004).

(71) Ruthenium-Catalyzed Propargylic Substitution Reactions of Propargylic Alcohols with Oxygen-, Nitrogen-, and Phosphorus-Centered Nucleophiles Y. Nishibayashi, M. D. Milton, Y. Inada, M. Yoshikawa, I. Wakiji, M. Hidai, S. Uemura Chemistry-A European Journal, 11, 1433–1451 (2005).

(72) Ruthenium- and Platinum-Catalyzed Sequential Reactions: Selective Synthesis of Fused Polycyclic Compounds from Propargylic Alcohols and Alkenes Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, S. Uemura J. Am. Chem. Soc., 126, 16066–16072 (2004).

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(73) Synergistic Dimetallic Effects in Propargylic Substitution Reaction Catalyzed by Thiolate-bridged Diruthenium Complex S. C. Ammal, N. Yoshikai, Y. Inada, Y. Nishibayashi, E. Nakamura J. Am. Chem. Soc., 127, 9428-9438 (2005).

(74) Asymmetric Carboselenenylation Reaction of Alkenes with Aromatic Compounds K. Okamoto, Y. Nishibayashi, S. Uemura, A. Toshimitsu Angew. Chem., Int. Ed., 44, 3588-3591 (2005).

(75) A Novel Method for the Preparation of Enantiomerically Pure Propargylic Substituted Compounds Y. Nishibayashi, H. Imajima, G. Onodera, S. Uemura Organometallics, 24, 4106-4109 (2005).

(76) Ruthenium-Catalyzed Reductive Coupling Reaction of Propargylic Alcohols via Hydroboration of Allenylidene Intermediates G. Onodera, Y. Nishibayashi, S. Uemura Organometallics, 25, 35-37 (2006).

(77) Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reaction of Propargylic Alcohols with Acetone Y. Inada, Y. Nishibayashi, S. Uemura Angew. Chem., Int. Ed., 44, 7715-7717 (2005).

(78) Ruthenium-Catalyzed Formation of Aryl(diphenyl)phosphine Oxides by Reactions of Propargylic Alcohols with Diphenylphosphine Oxide G. Onodera, H. Matsumoto, M. D. Milton, Y. Nishibayashi, S. Uemura Org. Lett., 7, 4029-4032 (2005).

(79) Preparation of Dicationic Chalcogenolate-Bridged Diruthenium Complexes and Their Dual Catalytic Activity toward Reactions between Propargylic Alcohols and Acetone G. Onodera, H. Matsumoto, Y. Nishibayashi, S. Uemura Organometallics, 24, 5799-5801 (2005).

(80) Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols Y. Inada, M. Yoshikawa, M. D. Milton, Y. Nishibayashi, S. Uemura Eur. J. Org. Chem., 881-890 (2006).

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(81) Iridum- and Ruthenium-Catalyzed Sequential Reactions: Asymmetric α-Alkylative Reduction of Ketones with Alcohols G. Onodera, Y. Nishibayashi, S. Uemura Angew. Chem. Int. Ed., 45, 3819-3822 (2006).

(82) Ruthenium-Catalyzed Propargylic Reduction of Propargylic Alcohols with Silanes Y. Nishibayashi, A. Shinoda, Y. Miyake, H. Matsuzawa, M. Sato Angew. Chem. Int. Ed., 45, 4835-4839 (2006).

(83) Ruthenium-Catalyzed Sequential Reactions: Deracemization of Secondary Benzylic Alcohols Y. Shimada, Y. Miyake, H. Matsuzawa, Y. Nishibayashi Chemistry–An Asian Journal, 2, 393-396 (2007).

(84) Ruthenium-Catalyzed Reactions of 1-Cyclopropyl-2-propyn-1-ols with Anilines and Water via Allenylidene Intermediates: Preparation of Tri- and Tetrasubstituted Conjugated Enynes Y. Yamauchi, G. Onodera, K. Sakata, M. Yuki, Y. Miyake, S. Uemura, Y. Nishibayashi J. Am. Chem. Soc., 129, 5175-5179 (2007).

(85) Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes ���Y. Miyake, Y. Nomaguchi, M. Yuki, Y. Nishibayashi ���Organometallics, 26, 3611-3613 (2007).

(86) Ruthenium-Catalyzed Enantioselective Propargylation of Aromatic Compounds with Propargylic Alcohols via Allenylidene Intermediates ��� H. Matsuzawa, Y. Miyake, Y. Nishibayashi ��� Angew. Chem. Int. Ed., 46, 6488-6491 (2007).

(87) Design and Preparation of a Chiral Ligand Based on a Pseudorotaxane Skeleton: Application to Rhodium-Catalyzed Enantioselective Hydrogenation of Enamides G. Hattori, T. Hori, Y. Miyake, Y. Nishibayashi J. Am. Chem. Soc., 129, 12930-12931 (2007).

(88) Remarkable Effect of N-Substituent on Enantioselective Ruthenium-Catalyzed Propargylation of Indoles with Propargylic Alcohols H. Matsuzawa, K. Kanao, Y. Miyake, Y. Nishibayashi Org. Lett., 9, 5561-5564 (2007).

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(89) Ruthenium-Catalyzed Vinylic Substitution Reactions with Nucleophiles via

Butatrienylidene Intermediates Y. Yamauchi, M. Yuki, Y. Tanabe, Y. Miyake, Y. Inada, S. Uemura, Y. Nishibayashi J. Am. Chem. Soc., 130, 2908-2909 (2008).

(90) Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines G. Hattori, H. Matsuzawa, Y. Miyake, Y. Nishibayashi Angew. Chem. Int. Ed., 47, 3781-3783 (2008).

(91) Ruthenium-Catalyzed Dienyne Formation from Propargylic Alcohols and 1,3-Conjugated Dienes M. Daini, M. Yoshikawa, Y. Inada, S. Uemura, K. Sakata, K. Kanao, Y. Miyake, Y. Nishibayashi Organometallics, 27, 2046-2051 (2008).

(92) A DFT study on the Reaction Pathways for Carbon-Carbon Bond Forming Reactions between Propargylic Alcohols and Alkenes or Ketones Catalyzed by Thiolate-Bridged Diruthenium Complexes K. Sakata, Y. Miyake, Y. Nishibayashi Chemistry–An Asian Journal, 4, 81-88 (2009).

(93) Ruthenium-Catalyzed Intramolecular Cyclization of 3-Butyne-1,2-diols into Furans Y. Yada, Y. Miyake, Y. Nishibayashi Organometallics, 27, 3614-3617 (2008).

(94) Synthesis and Reactivity of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis M. Yuki, Y. Miyake, Y. Nishibayashi, I. Wakiji, M. Hidai Organometallics, 27, 3947-3953 (2008).

(95) Novel Monophosphido-Bridged Diruthenium Complexes: Efficient Preparative Method and Catalytic Activity toward Reactions of Propargylic Alcohols with Aromatic Compounds Y. Miyake, S. Endo, Y. Nomaguchi, M. Yuki, Y. Nishibayashi Organometallics, 27, 4017-4020 (2008).

(96) Ruthenium-Catalyzed Enantioselective Carbon-Carbon Bond Formation via Allenylidene-Ene Process: A Novel Synthetic Approach to Chiral Heterocycles such as Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives K. Fukamizu, Y. Miyake, Y. Nishibayashi J. Am. Chem. Soc., 130, 10498-10499 (2008).

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(97) Synthesis of Optically Active N,N,N’,N’-Tetraphenyl-1,1’-binaphthyl-2,2’-

diamine Derivatives as Analogues of BINAP H. Matsuzawa, Y. Tanabe, M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 27, 4021-4024 (2008).

(98) Ruthenium-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Alcohols K. Kanao, H. Matsuzawa, Y. Miyake, Y. Nishibayashi Synthesis (PSP, invitation), 3869-3873 (2008).

(99) Synthesis and Reactivities of Hybrid Phosphido– and Thiolato–Bridged Diruthenium Complexes Y. Miyake, S. Endo, M. Yuki, Y. Tanabe, Y. Nishibayashi Organometallics, 27, 6039-6042 (2008).

(100) Ruthenium-Catalyzed Oxypropargylation of Alkenes Y. Yamauchi, Y. Miyake, Y. Nishibayashi Organometallics, 28, 48-50 (2009).

(101) Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions Y. Tanabe, K. Kanao, Y. Miyake, Y. Nishibayashi Organometallics, 28, 1138-1142 (2009).

(102) Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper-Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols G. Hattori, A. Yoshida, Y. Miyake, Y. Nishibayashi J. Org. Chem., 74, 7603-7607 (2009).

(103) Catalytic Cycloisomerization of 1,5-Enynes to 1,3-Cyclohexadienes via Ruthenium-Vinylidene Intermediates K. Fukamizu, Y. Miyake, Y. Nishibayashi Angew. Chem. Int. Ed., 48, 2534-2537 (2009).

(104) Design and Synthesis of Diphosphine Ligands Bearing Osmium(II) Bis(terpyridyl) Moiety as a Light Harvesting Unit: Application to Photocatalytic Production of Dihydrogen Y. Miyake, K. Nakajima, K. Sasaki, R. Saito, H. Nakanishi, Y. Nishibayashi Organometallics, 28, 5240-5243 (2009).

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(105) Ruthenium-Catalyzed Enantioselective Intramolecular Propargylation of

Thiophenes with Propargylic Alcohols K. Kanao, Y. Miyake, Y. Nishibayashi Organometallics, 28, 2920-2926 (2009).

(106) Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ruthenocenyldiphosphines M. Yuki, T. Midorikawa, Y. Miyake, Y. Nishibayashi Organometallics, 28, 4741-4746 (2009).

(107) Preparation and Protonation of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Bis(dialkylphosphinobenzene)chromiums as Auxiliary Ligands M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 28, 5821-5827 (2009).

(108) Copper-Catalyzed Enantioselective Sequential Reactions of Propargylic Alcohols with (E)-2,4-Pentadienylamine G. Hattori, Y. Miyake, Y. Nishibayashi ChemCatChem, 2, 155-158 (2010).

(109) Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper-Allenylidene Complexes as Key Intermediates G. Hattori, K. Sakata, H. Matsuzawa, Y. Tanabe, Y. Miyake, Y. Nishibayashi J. Am. Chem. Soc., 132, 10592-10608 (2010).

(110) Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols K. Kanao, Y. Miyake, Y. Nishibayashi Organometallics, 29, 2126-2131 (2010).

(111) Intramolecular Edge-to-Face Aromatic π–π Interaction in Optically Active Ruthenium–Allenylidene Complexes for Enantioselective Propargylic Substitution Reactions K. Kanao, Y. Tanabe, Y. Miyake, Y. Nishibayashi Organometallics, 29, 2381-2384 (2010).

(112) Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes M. Ikeda, Y. Miyake, Y. Nishibayashi Angew. Chem. Int. Ed., 49, 7289-7293 (2010).

15

(113) A Molybdenum Complex Bearing PNP-type Pincer Ligands Leads to the Catalytic Reduction of Dinitrogen into Ammonia K. Arashiba, Y. Miyake, Y. Nishibayashi Nature Chemistry, 3, 120-125 (2011).

(114) Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 29, 4148-4153 (2010).

(115) Preparation of Thiolate-Bridged Dinuclear Ruthenium Complexes Bearing a Phosphine Ligand and Application to Propargylic Reduction of Propargylic Alcohols with 2-Propanol M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 29, 5994-6001 (2010).

(116) Synthesis of Group IV (Zr, Hf)-Group VIII (Fe, Ru) Heterobimetallic Complexes Bearing Metallocenyl Diphosphine Moieties and their Application to Catalytic Dehydrogenation of Amine-Boranes T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 30, 2394-2404 (2011).

(117) Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands H. Tanaka, A. Sasada, T. Kouno, M. Yuki, Y. Miyake, H. Nakanishi, Y. Nishibayashi, K. Yoshizawa J. Am. Chem. Soc., 133, 3498-3506 (2011).

(118) Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes A. Yoshida, M. Ikeda, G. Hattori, Y. Miyake, Y. Nishibayashi Org. Lett., 13, 592-595 (2011).

(119) Cooperative Catalytic Reactions Using Organocatalysts and Lewis Acid Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes K. Motoyama, M. Ikeda, Y. Miyake, Y. Nishibayashi Eur. J. Org. Chem., 2239-2246 (2011).

16

(120) Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines A. Yoshida, G. Hattori, Y. Miyake, Y. Nishibayashi Org. Lett., 13, 2460-2463 (2011).

(121) Propargylic Substitution Reaction Catalyzed by Group IV (Ti, Zr, Hf)-Ru Heterobimetallic Complexes T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 30, 3194-3199 (2011).

(122) Remarkable Effect of Valence Electrons in Thiolato-Bridged Diruthenium Complexes toward Catalytic Dimerization of α-Methylstyrenes Y. Miyake, T. Moriyama, Y. Tanabe, G. Onodera, Y. Nishibayashi Organometallics, 30, 5972-5977 (2011).

(123) Cooperative Catalytic Reactions Using Distinct Transition Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation M. Ikeda, Y. Miyake, Y. Nishibayashi Chemistry-A European Journal, 18, 3321-3328 (2012).

(124) Visible Light Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron Deficient Alkenes Using Photoredox Catalysts Y. Miyake, K. Nakajima, Y. Nishibayashi J. Am. Chem. Soc., 134, 3338-3341 (2012).

(125) Synthesis and Catalytic Behavior of Sulfur- and Nitrogen-Bridged Diiron Complexes: Model Complexes for Function of Nitrogenase M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 31, 2953-2956 (2012).

(126) Synthesis and Protonation of Molybdenum- and Tungsten-Dinitrogen Complexes Bearing PNP-Type Pincer Ligands K. Arashiba, K. Sasaki, S. Kuriyama, Y. Miyake, H. Nakanishi, Y. Nishibayashi Organometallics, 31, 2035-2041 (2012).

(127) Synthesis and Reactivity of Hybrid Phosphido– and Hydrosulfido–Bridged Diruthenium Complex: Transformations into Diruthenium and Tetraruthenium Complexes Bridged by Phosphido and Sulfido Ligands Y. Miyake, T. Moriyama, Y. Tanabe, S. Endo, Y. Nishibayashi Organometallics, 31, 3292-3299 (2012).

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(128) Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation of

Propargylic Alcohols with β-Keto Phosphonates K. Motoyama, M. Ikeda, Y. Miyake, Y. Nishibayashi Organometallics, 31, 3426-3430 (2012).

(129) Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Allylation of Propargylic Alcohols with α,β-Unsaturated Aldehydes M. Ikeda, Y. Miyake, Y. Nishibayashi Organometallics, 31, 3810-3813 (2012).

(130) Visible-Light-Mediated Addition of α-Aminoalkyl Radicals Generated from α-Silylamines to α,β-Unsaturated Carbonyl Compounds Y. Miyake, Y. Ashida, K. Nakajima, Y. Nishibayashi Chem. Commun., 48, 6966-6968 (2012).

(131) Enantioseletive Alkylation of β-Keto Phosphonates by Direct Use of Diaryl Methanols as Electrophiles M. Shibata, M. Ikeda, K. Motoyama, Y. Miyake, Y. Nishibayashi Chem. Commun., 48, 9528-9530 (2012).

(132) Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: Simple Approach to Allylic Trifluoromethylation Y. Miyake, S. Ota, Y. Nishibayashi Chemistry-A European Journal, 18, 13255-13258 (2012).

(133) Direct sp3 C-H Amination of Nitrogen-Containing Benzoheterocycles Mediated by Visible-Light-Photoredox Catalysts Y. Miyake, K. Nakajima, Y. Nishibayashi Chemistry-A European Journal, 18, 16473-16477 (2012).

(134) Ruthenium–Triggered Ring-Opening of Ethynylcyclopropanes Leading to [3+2] Cycloaddition with Aldehydes and Aldimines via Metal–Allenylidene Intermediates Y. Miyake, S. Endo, T. Moriyama, K. Sakata, Y. Nishibayashi Angew. Chem. Int. Ed., 52, 1758-1762 (2013).

(135) Iron-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Conditions M. Yuki, H. Tanaka, K. Sasaki, Y. Miyake, K. Yoshizawa, Y. Nishibayashi Nature Communications, 3, 1254 (2012).

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(136) Synthesis and Catalytic Activity of Molybdenum-Dinitrogen Complexes

Bearing Unsymmetric PNP-Type Pincer Ligands E. Kinoshita, K. Arashiba, S. Kuriyama, Y. Miyake, R. Shimazaki, H. Nakanishi, Y. Nishibayashi Organometallics, 31, 8437-8443 (2012).

(137) Synthesis, Structure, and Reactivity of Group VI Metal Complexes Bearing Group IV Metallocenyldiphosphine Moieties and Pentamethylcyclopentadienyl Ligand T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, Y. Nishibayashi Organometallics, 32, 2007-2013 (2013).

(138) Visible Light-Mediated Oxidative Decarboxylation of Arylacetic Acids into Benzyl Radicals: Addition to Electron-Deficient Alkenes by Using Photoredox Catalysts Y. Miyake, K. Nakajima, Y. Nishibayashi Chem. Commun., 49, 7854-7856 (2013).

(139) Copper-Catalyzed Nucleophilic Trifluoromethylation of Propargylic Halides Y. Miyake, S. Ota, M. Shibata, K. Nakajima, Y. Nishibayashi Chem. Commun., 49, 7809-7811 (2013).

(140) Design and Preparation of Molybdenum-Dinitrogen Complexes Bearing Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, K. Nakajima, Y. Nishibayashi Chemistry-A European Journal, 19, 11874-11877 (2013).

(141) Preparation and Reactivity of Molybdenum–Dinitrogen Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand Y. Tanabe, S. Kuriyama, K. Arashiba, Y. Miyake, K. Nakajima, Y. Nishibayashi Chem. Commun., 49, 9290-9292 (2013).

(142) Preparation and Reactivity of Dinitrogen-Bridged Dimolybdenum-Tetrachloride Complex Kazuya Arashiba, Shogo Kuriyama, Kazunari Nakajima, Yoshiaki Nishibayashi Chem. Commun., 49, 11215-11217 (2013).

19

(143) Visible-Light-Mediated Addition of α-Aminoalkyl Radicals to [60]Fullerene

Using Photoredox Catalysts Y. Miyake, Y. Ashida, K. Nakajima, Y. Nishibayashi Chemistry-A European Journal, 20, 6120-6125 (2014).

(144) Unique Behavior of Dinitrogen-Bridged Dimolybdenum Complexes Bearing Pincer Ligand towards Catalytic Formation of Ammonia H. Tanaka, K. Arashiba, S. Kuriyama, A. Sasada, K. Nakajima, K. Yoshizawa, Y. Nishibayashi Nature Communications, 5, 3737 (2014).

(145) Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine T. Miyazaki, H. Tanaka, Y. Tanabe, M. Yuki, K. Nakajima, K. Yoshizawa, Y. Nishibayashi Angew. Chem. Int. Ed., in press.

(146) Enantioselective Intramolecular Propargylic Amination Using Chiral Copper-Pybox Complexes as Catalyst M. Shibata, K. Nakajima, Y. Nishibayashi Chem. Commun., 50, 7874-7877.

(147) Copper-Catalyzed Nucleophilic Trifluoromethylation of Benzylic Chlorides Y. Miyake, S. Ota, M. Shibata, K. Nakajima, Y. Nishibayashi Org. Biomol. Chem., 12, 5594-5596 (2014).

(148) Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand K. Arashiba, K. Nakajima, Y. Nishibayashi ZAAC (special issue “reactive nitrogen-containing species: generation, characterization and functionalization”, invitation), in press.

(149) Synthesis and Redox Properties of PNP Pincer Complexes Based on N-Methyl-4,4'-Bipyridinium Y. Miyake, K. Nakajima, Y. Higuchi, Y. Nishibayashi Eur. Inorg. Chem., in press.

(150) Synthesis of Nitrogen Heterocycles via α-Aminoalkyl Radicals Generated from α-Silyl Secondary-Amines under Visible Light Irradiation K. Nakajima, M. Kitagawa, Y. Ashida, Y. Miyake, Y. Nishibayashi Chem. Commun., 50, 8900-8903 (2014).

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(151) Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of

Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, N. Kamaru, K. Yoshizawa, Y. Nishibayashi J. Am. Chem. Soc., 136, 9719-9731 (2014).

(152) Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand Y. Tanabe, S. Kuriyama, K. Nakajima, K. Nakajima, Y. Nishibayashi submitted.

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‒ 総 説・解 説 ‒

(1) Novel Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application

to Asymmetric Reactions Y. Nishibayashi, S. Uemura Rev. Heteroatom Chem., MYU, Tokyo, Vol. 14, 83-118 (1996).

(2) Chiral Bis(oxazoline)-copper Catalyzed Enantioselective Imination of Sulfides H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura Phosphorus, Sulfur, and Silicon, 120 & 121, 363-364 (1997).

(3) ジルコニウムに配位する窒素分子の新しい反応

西林仁昭

Organometallic News, 95-96 (1997).

(4) Highly Selective Asymmetric Intramolecular Selenocyclization H. Takada, Y. Nishibayashi, S. K. Srivastava, K. Ohe, S. Uemura Phosphorus, Sulfur, and Silicon, 136–138, 629-632 (1998).

(5) 夢の常温での空中窒素固定法の開発に向けて，－ 窒素錯体と水素錯体と

の反応によるアンモニア合成－

干鯛眞信，西林仁昭

化学と工業，51 1897-1899 (1998).

(6) 分子状水素錯体を用いた新規な水素化反応の開発 干鯛眞信，西林仁昭 Organometallic News, 121-124 (1998).

(7) ４級ホスホニウム塩のセレンディピティー的な効果 － 不活性な塩化ア

リールの活性化と触媒活性の向上－

西林仁昭

化学，53 (12) 63-64 (1998).

(8) Sigmatropic Rearrangements of Organoselenium Compounds Y. Nishibayashi, S. Uemura Organoselenium Chemistry: A Practical Approach; Ed. T. G. Back, Oxford University Press, Oxford, 207-221 (1999).

22

(9) Selenoxide Elimination and [2,3]Sigmatropic Rearrangement Y. Nishibayashi, S. Uemura Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 201-233 (2000).

(10) Selenium Compounds as Ligands and Catalysts Y. Nishibayashi, S. Uemura Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 235-255 (2000).

(11) 「化学のフロンティア２０００」 ２１世紀を担う次世代の空中窒素固定法の開発 － 温和な条件下での窒

素と水素からのアンモニア合成－

西林仁昭

化学と工業，53, 131-135 (2000).

(12) Heterolytic Cleavage of Dihydrogen by Ruthenium and Molybdenum Complexes to Protonate Coordinated Dinitrogen and Cleave Si–O Bond M. Hidai, Y. Nishibayashi Recent Advances in Hydrides Chemistry; Ed. R. Poli, Elsevier Science, 117-138 (2001).

(13) Kinetic Resolution of Racemic Ferrocenylphosphine Compounds Using Optically Active Cyclic Selenoxides as Oxidants Y. Miyake, A. Yamauchi, Y. Nishibayashi, S. Uemura Phosphorus, Sulfur, and Silicon, 177, 2107–2108 (2002).

(14) オレフィンメタセシスによる大環状高分子化合物の合成 西林仁昭

Organometallic News, 110 (2003).

(15) 新規 N,P-不斉配位子(FOXAP)の開発と不斉合成反応への応用 西林仁昭，植村 榮

Organic Square, 11, 1-3 (2003).

(16) カルコゲン元素架橋二核ルテニウム錯体を触媒とする有機合成反応 西林仁昭，植村 榮，干鯛眞信

Organic Square, 13, 1-3 (2004).

23

(17) 次世代の窒素固定法の開発に向けて：フラーレンを用いた窒素固定法の開発

西林仁昭

触媒, 47, 233-238 (2005).

(18) A Non-Metal System for Nitrogen Fixation Utilizing Buckminsterfullerene Y. Nishibayashi, S. Uemura, S. Takekuma, Z. Yoshida Biological Nitrogen Fixation, Sustainable Agriculture and the Environment; Eds. Y.-P. Wang, M. Lin, Z.-X. Tian, C. Elmerich, W. E. Newton, Springer, 39-40 (2005).

(19) Ruthenium-Catalyzed Novel Carbon-Carbon Bond Forming Reactions via Ruthenium-Allenylidene Complexes Y. Nishibayashi, S. Uemura Current Organic Chemistry, 10, 135-150 (2006).

(20) C-C Bond Formation by Substitution Reaction: Substitution at Propargylic and Benzylic Positions Y. Nishibayashi, S. Uemura Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 123-150 (2007).

(21) C-C Bond Formation by Substitution Reaction: Allylic Alkylation Y. Nishibayashi, S. Uemura Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 75-122 (2007).

(22) 光学活性フェロセニルオキサゾリニルホスフィン(FOXAP)配位子の開発と触媒的不斉合成反応への応用

西林仁昭，三宅由寛，植村 榮

有機合成化学協会誌, 65, 761-771 (2007).

(23) 二核ルテニウム錯体の特性を用いた新規触媒反応の開発̶ セレンディピティー的発見から阿吽の呼吸による協奏作用まで

西林仁昭

化学と工業, 60, 1088-1091 (2007).

(24) Allenylidene Complexes in Catalysis Y. Nishibayashi, S. Uemura Metal Vinylidenes and Allenylidenes in Catalysis; Eds. P. H. Dixneuf and C. Bruneau, WILEY-VCH, 217-250 (2008).

24

(25) Development of Optically Active Chiral Ligands Ferrocenyloxazolinylphosphines (FOXAPs) and Their Application to Catalytic Asymmetric Reactions Y. Miyake, Y. Nishibayashi, S. Uemura Synlett, 1747-1758 (2008).

(26) ルテニウム-アレニリデン錯体を鍵中間体として経由する新規触媒反応の開発

西林仁昭，三宅由寛，植村 榮

有機合成化学協会誌, 67, 437-450 (2009).

(27) 硫黄架橋二核ルテニウム錯体を用いた触媒的プロパルギル位置換反応の開発

西林仁昭，三宅由寛

触媒, 51, 594-600 (2009).

(28) アンモニアによるエネルギー問題の解決 ハーバー・ボッシュ法に代わる新しい窒素固定法の開発を目指して

田邊資明，三宅由寛，西林仁昭

配管技術(11 月号), 7-13 (2009).

(29) Catalytic Propargylic Substitution Reactions Y. Miyake, S. Uemura, Y. Nishibayashi ChemCatChem, 1, 342-356 (2009).

(30) 未来を拓く次世代型窒素固定法の開発 エネルギー及び環境問題を解決するアンモニア社会の実現に向けて

西林仁昭

現代化学(10 月号), 28-34 (2009).

(31) 銅触媒による不斉プロパルギル位置換反応の開発 服部 岳，三宅由寛，西林仁昭

化学工業(9月号), 46-54 [702-710] (2010).

(32) 窒素分子の活性化に基づく窒素固定法の開発 西林仁昭

不活性結合・不活性分子の活性化(日本化学会 Current Review), 125-137 (2011).

25

(33) Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement

Y. Nishibayashi, S. Uemura Organoselenium Chemistry–Synthesis and Reactions; Ed. T. Wirth, WILEY-VCH, 287-320 (2012).

(34) 特集：化学未踏のテーマ Haber-Bosch 法を超えるアンモニア合成

西林仁昭

化学(7月号), 18-22 (2011).

(35) Nitrogen Fixation: Nitrido Complexes Step up Y. Nishibayashi Nature Chemistry, 3, 502-504 (2011).

(36) 銅-アセチリド錯体を鍵中間体として経由する触媒反応の最近の展開 服部 岳，三宅由寛，西林仁昭

有機合成化学協会誌, 69, 1086-1098 (2011).

(37) (S,S)-FOXAP; Ferrocene, 1-[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl]-2-(diphenylphosphino)-, (2R)- Y. Nishibayashi Electronic Encyclopedia of Reagents for Organic Synthesis, RN01404 (2012).

(38) Transition Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles Y. Nishibayashi Synthesis, 44, 489-503 (2012).

(39) Molybdenum-Catalyzed Reduction of Molecular Dinitrogen under Mild Reaction Conditions Y. Nishibayashi Dalton Transactions (Dalton Perspective), 41, 7447-7453 (2012).

(40) Cycloaromatization via Transition Metal-Cumulenylidenes Y. Nishibayashi Transition-Metal-Mediated Aromatic Ring Construction; Ed. K. Tanaka, WILEY-VCH, 547-567 (2013).

26

(41) Developing More Sustainable Processes for Ammonia Synthesis

Y. Tanabe, Y. Nishibayashi Coord. Chem. Rev., 257, 2551-2564 (2013).

(42) 解説：鉄触媒は｢窒素固定能｣を秘めていた！ 常温常圧の窒素ガスからのアンモニア変換に光明

西林仁昭

化学(6月号), 37-42 (2013).

(43) 穏和な条件下での触媒的アンモニア合成法の開拓を目指して 田邊資明，西林仁昭

ファインケミカル(7月号), 42, 42-48 (2013).

(44) 遷移金属窒素錯体を用いた触媒的アンモニア合成反応の最近の進展と今後の展望

西林仁昭

錯体化学会誌 (Bull. Jpn. Soc. Coord. Chem.), 62, 21-25 (2013).

(45) 常温常圧下の触媒的アンモニア合成反応の開発と将来展望 田邊資明，西林仁昭

日本エネルギー学会誌(5月号),93, 386-392 (2014).

(46) 遷移金属窒素錯体を用いた触媒的窒素固定法反応に関する最近の進展 西林仁昭，荒芝和也，結城雅弘

有機合成化学協会誌, 72, 529-537 (2014).

(47) Wade著 Organic Chemistry (Seventh Edition) 日本語版 西林仁昭 共著（10、11、14章担当） 丸善出版株式会社 (2014).

(48)