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GM 50432 BIOCHEMICAL SAMPLING, LAMOTHE OPTION

BIOCHEMICAL SAMPLING, LAMOTHE OPTION

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dmntstite de retool* at eSlios mosiortecummesomasbotirkome

20 JUIN 1991

1,3)- DATE

G.M.

WESTMINER CANADA LIMITED EXPLORATION DIVISION

BIOGEOCHEMICAL SAMPLING AT LAMOTHE OPTION, LEMOINE TOWNSHIP

cry) 32) y3

Chibougamau, Québec CANADA

February 4th, 1991 Malcolm A. Ward Senior Geologist/Geochemist

ABSTRACT

Orientation biochemical sampling using humus and the outer bark of black spruce has been carried out over strike extensions of moderately copper-gold mineralised shears at the Lamothe property, Chibougamau. The purpose was to determine if biological media could be sampled to detect mineralised shears which are concealed by 2 to 4 metres of glacial deposits.

Of 35 elements analysed by instrumental neutron activation (Cu by AA), Au, As, Br, Cr, Cu, Fe, La, Na, Sc and. U proved useful for humus and the same, except for Cu, Sc and U, for spruce bark.

Modelling using the PROBPLOT program revealed that most elements' populations could be best modelled by assuming 2 or 3 sub-populations. The anomalous thresholds calculated were applied to line profiles, enabling 4 major and 4 minor multielement, bark + humus anomalies to be defined and ranked using scores assigned by the assemblage of anomalous elements.

Excavation to remove the overburden beneath the 4 best anomalies has been recommended to reveal if the anomalies are sourced by mineralised shears.

TABLE OF CONTENTS

PAGE:

-' ABSTRACT

TABLE OF CONTENTS

LIST OF FIGURES iii

LIST OF TABLES

LIST OF APPENDICES

--

--

1.0 INTRODUCTION 1

1.1 PURPOSE 1 1.2 LOCATION AND ACCESS 1 1.3 CLAIMS 1 1.4 PREVIOUS WORK AND GEOLOGY 1 1.5 LITERATURE ON BIOGEOCHEMISTRY 6

2.0 BIOGEOCHEMICAL SAMPLING PROGRAMME 8

2.1 LIMITATIONS 8 2.2 SITE INSPECTION - BOTANICAL AND SURFICIAL

ENVIRONMENT 8 2.3 SAMPLING 9

2.3.1 HUMUS SAMPLING 9 2.3.2 BARK 10 2.3.3 LEAVES 10

2.4 ANALYSES 11

2.4.1 HUMUS 11 2.4.2 BARK 12

3.0 DISCUSSION 13

3.1 THRESHOLD DEFINITION 13 3.2 ANOMALIES GENERATED 13

3.2.1 ANOMALY 1 19 3.2.2 ANOMALY 2 19 3.2.3 ANOMALY 3 19 3.2.4 ANOMALY 4 19 3.2.5 ANOMALY 5 20 3.2.6 ANOMALIES 6 - 8 20

4.0 CONCLUSIONS AND RECOMMENDATIONS 21

4.1 CONCLUSIONS 21 4.2 RECOMMENDATIONS 22

5.0 REFERENCES AND BIBLIOGRAPHY 23

LIST OF FIGURES:

PAGE:

Lamothe Property Location 2

Lamothe Property Claims 3

Simplified Geological Map of the Chibougamau District 4

Generalised Lay-out of Sampling 5

Sample Numbers and Net Anomalies, Showing 2 (in pocket)

Sample Numbers and Net Anomalies, Showing 5 (in pocket)

FIGURE 1 :

FIGURE 2 :

FIGURE 3 :

FIGURE 4 :

FIGURE 5 :

FIGURE 6 :

LIST OF TABLES:

TABLE 1 Lamothe Humus Population Summary 14

TABLE 2 Lamothe Bark Population Summary 15

TABLE 3 Lamothe Humus Anomalous Line Intervals 16

TABLE 4 Lamothe Bark Anomalous Line Intervals 17

TABLE 5 Major Net Anomalies 18

LIST OF APPENDICES:

APPENDIX 1: Analytical Data for Humus

APPENDIX 2: Analytical Data for Bark

APPENDIX 3: Histograms and Threshold Calculations for Au, As, Br, Cr, Cu, Fe, Na, Sc, La and U for Humus

-- APPENDIX 4: Histograms and Threshold Calculations for Au, As, Br, Cr, Cu, Fe, Na, Sc, La and U for Bark

APPENDIX 5: Profiles for Selected Elements, by Lines Showing

APPENDIX 6: Profiles for Selected Elements, by Lines Showing 5

1.0 INTRODUCTION

1.1 PURPOSE:

This report summarises the methodology and results of an orientation biochemical sampling programme conducted on 2 areas of the Lamothe Option. The Lamothe Option lies in Lemoine Township, in the Mining District of Chibougamau.

The programme was undertaken to assess the effectiveness of several biochemical sampling techniques to detect gold-copper mineralised shears concealed by several metres of overburden.

1.2 LOCATION AND ACCESS:

The Lamothe property is situated about 8 kilometres SSE of the town of Chibougamau, east of Lac Chibougamau (Figure 1). The two areas sampled, named Showing 2 and Showing 5, are accessible via gravel road L-210 and thereafter by 4WD logging tracks.

1.3 CLAIMS:

The sampling occurred specifically on claims 5032965 and 458734-2 (Figure 2). The Lamothe property in general has been under option to Westminer from Fancamp Resources since November 1988.

1.4 PREVIOUS WORK AND GEOLOGY:

Both the previous work undertaken by W.C.L. and others on the Lamothe property and the geology of the property have been summarised by Champagne (1990). The "Previous Work" portion will not be repeated here.

A simplified geological map of the Chibougamau District is given as Figure 3. Most of the property is occupied by meta-leucotonalite of the Chibougamau Pluton, with rare gabbro (dykes) and gabbroic anorthosite. Occasional enclaves of chloritic mafic rocks are sometimes highly magnetic (2 to 20=x. magnetite). The Chibougamau Pluton contains a 56° to 65°F foliation, sub-parallel to its contacts.

Generally, mineralised shears within the pluton strike 310°-330° and dip 70-75° SN and have maximum thicknesses of several metres. Mineralogically the shears contain quartz, magnetite, pyrite, chalcopyrite and hematite within an alteration halo of sericite, chlorite and silica. Both gold

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WESTMINER CANADA LTD Div. EXPLORATION

PROJECT: L A M OT H E

FIGURE *1 Lamothe Property Location

Drawn by MA. Plan no

Work by M.W.

Date: Jan ._1991__ Scale . 1:167 000 NT.S.: 32 G

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WESTMINER CANADA LTD Div. EXPLORATION

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GÉOLOGIE DE LA REGION DE

CHIBOUGAMAU, QUEBEC

SYMBOLES DES GiTES SÉLECTIONNES

• Au A9

S Cu • Fe

A Zn y Amiante

• V.11

Note: Les numerus ae Bites apparaissent sur la carte sans le numero de feuillet lopograpnibue oui est 32 par defaut

MINES

1 - Icon (Cu) 32 ira - 4

2- Gw4iin (Au) 32 G/I6 - 4

3-Nomeau (Au) 32 G/16- 1a

4 - Bruneau (Cul 32 G/16 - 56

5-Janvier (Cu. Out 32 G/16 - 55

6 - Graridroy (Cu) 32 6116 - 25

2- Copper Cira (Cul 32 Gr16 - Si

6-Baleman Bay 32 6116-52

9 -Cedar Bay (Cu. Au) 32 G/16- 50

10 - Copper Rand (Cu. nu) 32 6/16 - 54

Zone anorthosibglre

Formation de Bordeleau. norcanoclastile lelsique

Formation de Blondeau volcanoclashte felsrque. lave viatique

▪ Sommet slratrgraphrque

Zone de cisaillement

Contour 900109ique

Faille système NNE

Faille sysleme NE

— 1 - - Trace axiale d'un anticlinal

—~- Trace axiale d'un synclinal

?t Puits de mine

f

—.Ga IÎ

LÉGENDE

1111

4L733

Dyke de drabase

Roche proterozorque. conglomérat. gres argrlrle. dolomie

Pluton post-leclonrque. granodiorrle

Pluton syn-leclOnrque. tonalite. diorrle

Complexe tonalnrque. folie a gneissique

Intrusion gehbrolque non-différenciée

Formation de Chebistuane, conglomérat. gres. argilite

Formation de Matin. conglomérat. grés. 41911110. lave andésrbque

Formation de Stella. conglomeral. grès, argilite

Complexe de Cummrngs, gabbro. pyroxenile. peridolile

Complexe do lac Dore

-

Zone de bordure. gabbro. anorlhosite

Granophyre

Zone Iité, gabbro. magnetrlite

11 - nerlderson I ICu. Oui 32 6116-62 '

12 - Henderson lI(Cu Au) 32G/16-62

13 - Portage (Cu Au) 32 6116 - 63

la - Ouebec Chrbouganiau (Cu. Au) 32 G116- 46

15 - Koko Creek (Cui 32 G/16 - 44

16 - Campbell Mine Prrnpq le (Girl 32 6116 - 65

17 - Menia (Cul 32 G116 - 06

18 - Chib Kayrand (Cul 32 6116 - 64

19 - ObaLski (Cu. Aul 32 G/16 - 61

20 - Lemolne 12n, Cu. Ag. Au) 32 G/16 - 97

21 - CNlbex IAuI 32 G16 - 06

Compilation et interprétation.

Réal Daigneault, Gilles O. Allard

19 Gouvernement du Québec. 1987

WESTMINER CANADA LTD Div. EXPLORATION

PROJECT: LAMOTHE

FIGURE *3 Chibougamau Geological Map

Oslo :~$n._19Q1_ _ Plan no.

Scala : 1_ 455 000 N.T.S.: 32 G

Formalron de Gilman lave malique. filon-couche gabbroique

Formation de WaconrChr pyrnclastite lelsrque a inlermedlaire. porphyre a quartz. lave myolnique

Formation d'Obalogamau lave malique porphyrique a plagioclase. filon-couche gabbroique

Drawn by : M.A

Work by : M.W-

5m spacings on projection of SHEAR

(including 1 duplicate) 10m spacings away from SHEAR (including 1 duplicate)

Projection of /--SHEAR

TILL COVERED

TILL COVERED

5m ~

10m

WESTMINER CANADA LTD M

Div. EXPLORATION

PROJECT : L g M O T H E

FIGURE *4 Generalised Lay-out of Sampling

Drawn by Data : _s18 n ._1991_ _ Plan no.

Scala

-5- Worthy: M.W. N.TS.: 32 G

and copper grades are erratic within the shears sampled. Although spot grades of +10 g/t where obtained in rock chips, "average" grade could not be considered to exceed several grams/tonne.

Of most significance to the biogeochemical sampling were:

I) the narrowness of the target (< 5 m),

II) mineralogy of the shears-magnetite, pyrite, chalcopyrite, (gold),

III) alteration halo.

1.5 LITERATURE ON BIOGEOCHEMISTRY:

Prior to any field work, an extensive literature review was made to assist in the choice of sample media and sample preparation/analytical techniques. A bibliography of literature is included at the end of this report.

Numerous papers dealing with biogeochemical applications (especially to gold exploration) have appeared in recent years. Three good reviews are Brooks (1982), Cohen et al. (1987) and Erdman and Olson (1985). An M.Sc. thesis by Cohen (1986) thoroughly reviewed and tested many biogeochemical exploration methodologies for gold in the Canadian Shield. Both Reading et al. (1987) and Rencz and Watson (1989) discussed gold biogeochemistry, but not in Chibougamau-type environments.

Literature concerning humus geochemistry is a little more sparse, although several good papers have recently appeared. Gleeson and Sheehan (1987) discussed a combined humus and till survey over the Doyon, Bousquet and Williams (Hemlo) gold deposits in the Canadian Shield. The Williams property was also subject to humus geochemistry in a study by the O.G.S. (Ontario Geological Survey, 1985). Gleeson et a1. (1986) canvassed the relevance of gold in "peat" to mineral exploration in the Shield.

Bill Baker of the Tasmanian Department of Mines has published his work on gold and other metals in "humic substances" and has developed a procedure known as "Huminex" for exploration using humic substances (Baker, 1978, 1986 a,b, and 1990).

The usefulness of vegetation in exploring for gold has been actively persued by Colin Dunn of the Geological Survey of Canada since the early 1980s. Some of his published work appears in the bibliography of this report. Although many of Dunn's investigations have been in Saskatchewan and Nova

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Scotia, his works on gold in vegetation in Shield areas of Ontario and Québec undoubtedly contain the best relevant hard data available relating to plant species found in the Chibougamau area.

Discussions with Colin Dunn greatly influenced the choice of sample media and the sample preparation/analytical techniques for this study. The laboratory used by us, Activation Laboratories of Ancaster, Ontario is the one used by Dunn. Although Dunn recommends analysing ashed vegetation, unashed preparation was chosen initially in this study as part of the "orientation" process. Some bark samples were later ashed and analysed for comparison; these results will be discussed in a later report.

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2.0 BIOGEOCHEMICAL SAMPLING PROGRAMME

2.1 LIMITATIONS:

Although this exercise was designated an orientation study, a major limitation was the known generally low and erratic grade of the shears chosen for study (these were the best available in an undisturbed environment). It was also known that the shears were fault offset where exposed and may be also offset where concealed.

Biogeochemical sampling is known to be subject to many limitations imposed by the nature of the media. Live vegetation is subject to sometimes extreme seasonal variations in mineral content; media such as humus is extremely variable in composition and the exact "nutrient uptake area" (spread of tree roots etc) for most plants is poorly known.

In spite of these limitations, biogeochemical sampling can be an effective and relatively cheap geochemical sampling technique in certain environments which are concealed by overburden.

2.2 SITE INSPECTION - BOTANICAL AND SURFICIAL ENVIRONMENT:

An initial visit to both showings 2 and 5 revealed that both prospects had been cleared of one to three metres of overburden and the bedrock hosed down. The resulting effluent however had drained into several nearby creeks without contaminating the surrounding forest. Thus it was deemed possible to step off only 10 metres into the forest, along strike from the shears to conduct the sampling with reasonably good geological control.

The forest consisted mainly of mature Black Spruce ("épinette noire" in French) Picea mariana with occasional birch ("bouleau") Betula sp., Balsam Fir ("sapin") Abies balsamea, Tamarak ("mélèze") Larix laricina and, in boggy areas, cedar ("cèdre") Thuja occidentalis. Understory is dominated by sparse shrub Labrador Tea, Ledumgroenlandicum, in better drained areas and small alders ("aulne") A1nus ?rugosa in boggy areas. The ground is fairly uniformly carpeted with variable thicknesses of moss (Sphagnum sp. and others).

Beneath the moss, the A horizon is extremely variable. Working downwards, beneath the surface live moss is a horizon of browned live moss and dead moss, followed by a 1 to 10 centimetre layer of variably decaying brown leaves, needles, moss and twigs, usually penetrated by rootlets of shrubs. A major variable in this horizon and also the humus

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horizon (where present) is the proportion of variably decayed wood and charcoal. These components have the potential to greatly influence the sample both volumetrically and chemically.

Beneath the decaying brown organic horizon in poorly drained areas may be a black humus horizon 1 to 30 centimetres thick. Humus is mostly likely to be developed where the brown organic horizon is thick (to 10 centimetres). In well drained areas, the humus horizon is often absent or very thin ( < 1 centimetre). For a discussion of the nature of "humus", see Bree (1990).

A sharp contact exists between the brown organic or black humus horizon and the underlying B horizon developed on ablation till. The top few centimetres of B horizon was usually a leached, clay rich grey horizon (with rock cobbles) beneath which was formed a light brown Fe enriched horizon. This graded downwards over about 5 centimetres to an indistinct C horizon (till). The till itself is a sandy-cobble-boulder ablation till. In nearby stripping, the till is 1 - 3 metres thick and appears to be a single horizon. No lodgement till was obvious although it was not specifically sought out.

2.3 SAMPLING:

As a result of the site inspection and following in part advice given by Colin Dunn of the Geological Survey of Canada (and others) it was decided to sample humus, the outer bark of the Black Spruce and the leaves of Labrador Tea.

At both Showings 2 and 5 two sampling traverses 10 metres apart were made at each end of the exposed shears a short way into the forest. Traverses were between 90 and 120 metres long, centred on the strike projection of the shears. Sample points were 5 metres apart in the vicinity on the centre of the traverses and 10 metres apart elsewhere (Figure 4). Duplicate samples were collected on every second traverse; one over the projected strike extent of the shear ("mineralisation") and one elsewhere on the traverse ("barren").

2.3.1 Humus Sampling:

At each location a small hole was dug with a mattock (grub-hoe) until overburden was exposed. The hole was then enlarged by hand to clearly expose the black humus layer, or in the absence of this, the lowermost organic horizon. The humus or

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lowermost organic layer was hand picked into Kraft sample envelopes. As much of the adhering mineral grains, rootlets, charcoal and wood as practicable was excluded from the sample. About 250 g (wet weight) was collected at each site.

Duplicate samples consisted of material from a second hole dug within one metre of the original sample hole.

Details of the sample and its environment were recorded onto a custom sample data sheet.

2.3.2 Bark:

At each sample site usually 2 or 3 individual adjacent Black Spruce trunks were sampled. Occasionally tree density was such that only one specimen or several trees up to 5 metres away (perpendicular to the traverse direction) were available for sampling.

Bark was collected by scraping the entire circumference of the tree trunk from head to foot height with the back of a pair of secateurs. The loose dry, outermost scales of bark were collected into an open plastic bag. Scraping ceased when the yellow-orange inner bark was encountered. About 100 g of bark was collected at each site.

Data concerning the sample and its environment was collected onto a customised data form.

Duplicate samples consisted of sampling a different group of trees in the same location.

2.3.3 Leaves:

As soon as sampling began, it become apparent that sampling of the leaves of the Labrador Tea would not be feasible at the scale of the orientation programme (5 or 10 metres spacing). The shrub does not grow in poorly drained areas, which often includes the strike extent of shears (usually a creek). In these areas the Labrador Tea is replaced by the Swamp Alder.

Although samples were collected over two lines, processing was not persevered with due to the incompleteness of the sampling.

2.4 ANALYSES:

Sampling preparation and analysis was done by Activation Laboratories of Ancaster, Ontario mainly by Instrumental Neutron Activation Analysis (INAA).

2.4.1 Humus`1':

Humus samples were dried at 80°C overnight. Samples were macerated in a Wyllie mill. Up to 30 grams of material was compressed into a briquette under 15 tons of pressure. Samples were packaged for irradiation together with a reference standard and flux wires at the top, middle and bottom of the bundle. Samples were irradiated for 90 minutes at the University of Michigan reactor using a thermal neutron flux of 7 x 1011 n.cm-2s-1

in a rotating irradiation facility. After a decay of 7 days the samples were measured on a high resolution (better than 1.8 KeV for the 1332 Co-60 peak) germanium detector for 500 seconds for the long lived induced radioisotopes. This procedure allowed the determination of 35 elements simultaneously and nondestructively. Subsequently the collected gamma spectrum was sorted using a multichannel analyzer which is linked and controlled by a MICROVAX II computer. All values were computed automatically using the flux wire to compare neutron exposure to an internal calibration based on multiple synthetic and international reference materials. The internal standard present is used solely as a check on the procedure. All data was automatically placed in the customer report with little if any manual data entry to ensure virtual freedom from data entry errors. Beside the samples chosen for complete repetition, approximately 30 - 50% of samples were recounted to ensure data reliability and minimize chance of sample mix-up. Virtually all samples with anomalous gold values were chosen for the counting repetition.

Copper is not available by the INNA and was analysed separately by AA.

Appendix 1 contains all analytical data and sample data for humus.

12' "Humus", unless otherwise stated includes samples of the basal organic horizon where true humus had not been present.

-11-

2.4.2 Bark:

As above but irradiation times increased to 4 hours and decay cut to perhaps 6 days if samples are low in sodium. The much better detection limits are primarily a function of sample being composed of H, C, N, O which does not activate, (hence does not cause a high Compton background), combined with increased irradiation time.

Appendix 2 contains all analytical and sample data for bark.

At a subsequent stage, a split of the bark samples was ashed and the ash re-analysed. This data, and the results of it will be discussed in a subsequent report.

3.0 DISCUSSION

3.1 THRESHOLD DEFINITION:

The PROBPLOT program version 1.0 was used to divide the analyses of Au, As, Cu, Cr, Br, La, Na, Sc and U for bark and humus (Cu not analysed and U not possible for bark) into populations. Analyses less than the detection limit for a particular element were set to 50% of the detection limit. In most cases this did not skew the statistics significantly.

In most cases both 2 and 3 populations were modelled for each data set (element) and the Maximum Likelihood Function for logged class interval data chosen. Thresholds calculated by the program for the 2 and 3 population models were critically assessed and the most geologically reasonable model accepted.

In general, the geological interpretation placed on populations defined by statistics is open to debate, most of all when dealing with biological systems. In this study, in cases where the entire population consisted of a main,approximately log normal group of data and a much smaller somewhat or completely separate higher (or lower) group of data, then the threshold of "anomalism due to mineralisation" was taken as the upper threshold of the majority (or "background") population. This technique will include some data of the "background" population in the "anomalous" population (as opposed to the converse technique which would omit some truly anomalous data, but include no "background" data).

Appendix 3 contains histograms, summary statistics and threshold calculations for Au, As, Cr, Cu, Br, Fe, Sc, La and U for humus. Appendix 4 contains the same data for Au, As, Cr, Br, Fe, Sc and La for bark.

Tables 1 and 2 summarize the population data and thresholds accepted.

3.2 ANOMALIES GENERATED:

Appendix 5 contains profiles, by line and element for the relevant elements on Showing 2; the same presentation for Showing 5 is made in Appendix 6. These, combined with the calculated thresholds, allow anomalous portions of sample lines to be defined these are tabulated in Tables 3 and 4.

Table 5 combines the anomalies for humus and bark on each line and allots points for each element which is anomalous in the interval (gold scores double, elements which form a

-13

Na

Sc

U

TABLE 1

LAMOTHE HUMUS POPULATION SUMMARY

Au

1 1.2 ppb (-) 0.5 ppb

12

2

3.1 ppb

7.7 (+) 3.1 ppb

As

0

2.0

(-) 1.0

15

2

7.0

22.3 (+) 4.0

Br 0 12.0 (-) 6.2

(+) 23.3

15 2 29.9 9.5

cr 0 9.2 (-) 3.17

(+) 26.7

15 3 Lwr 5.4

Upp 38.1

15.9

13.4

Cu 1 11.8 (-) 5.4

(+) 25.9

15 2 32.0 6.0

Fe

0

0.4%

(-) 0.1% 12 2 1.3%

10.4 (+) 1.3%

LA

1 6.3

(-) 2.2 12 2 29.2 4.4 (+) 17.9

1381.8 J (-) 428.2 12 3

(+) 4458.8 Lwr 406.6

Upp 5858.0

20.6

12.5

0

o

1 0.3 (-) 0.07

(+) 1.18

12 2

8.6 3.7

2.5 6.3

1.5

(-) 0.6 j 15

(+) 4.1 2

(1) ppm except where stated

-14-

TABLE 2

LAMOTHE BLACK SPRUCE BARK POPULATION SUMMARY

(-) 0.3 ppb

(+) 1.5 ppb

(-) 0.02%

(+) 0.03%

(-) 37.7

(+) 58_9

(+) 13.9

(-)0.4

(-) 0.3

(+) 0.5

(-) 8.9

(.4 0.1

(+) 0.2

(+) 1.1

ELEMENT

Au

As

Br

Cr

Fe

La

Na

Sc

No. of EXCLUDED

DATA

MEAN

1 0.7 ppb

0 0.3

0 11.1

3 0.6

1 0.02%

0 0.2

1 47.1

Unable to be modelled

No. of

POPULA-

12 2

12 2

12 2

12 2

12 2

12 3

12 2

(1) ppm unless otherwise stated

-15-

1 I I 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1

TABLE 3

LAMOTHE HUMUS - ANOMALOUS LINE INTERVALS

ELEMENT

THRESHOLD

. : . Au A

a.1 ppb (1)

.. s : .. . :

..7.0

. ...Or:. :: . ;299.'. .

• . :et

- S8.1-

.

'

Cu ; ..

• '324' 1 3% 292 ...' ''. 58680 :.

So 86

. U 2.5

LINE INTERVAL ABOVE ANOMALOUS THRESHOLD (METRES)

SHOWING 2 '

Line 1 35 35 35 20

70

Line 2 30-40 30-35 30-35 (30) (35) 30-35 (30) 30

90 (2') 90(2) 90(2*) 90(2) 70,90(2) 90(2*)

Line 3 20 20 20

, (40) 50 40-50 40-45 40-55 40-445) 40,55 45

(65) 75 90(2*) 80 80 90 (2') 80_90(2*) 90(2*) 90(2*)

Line 4 (25-30),35,(40) 30 20,30,40 40 40 35-40 20

SHOWING 5

Line 1 20 (20) 20 20 20

(60) 65

Line 2 70

(100) (100) (100)

Line 3 45

(60)

Line 4 0 0

35-50 30-50 35-40,50 35-50 50 30-50 (30),40,50 30-50 I

75-90 (2') 60-75,90 (2*) 90 8090(2*)

i 1

(1) ppm unless otherwise stated

(2*) Open beyond 90 m (end of line)

Figures in brackets are defined peaks, just below threshold

TABLE 4

LAMOTHE BLACK SPRUCE BARK - ANOMALOUS LINE INTERVALS

i1414l~1IT . Or e fiiRE5110I31 >Z2 t <0:0' . >14:3: <9;3 ci0:om `

41) ~ 3 .

LINE INTERVAL ABOVE/BELOW ANOMALOUS THRESHOLD

SlG 2

Line 1 20-50 30, 45 10-35, 45 10 10 65 55

80-100 (2*)

Line 2 10 20

35-40 (30)45

(55) 60 50

80 (70-80)

Line 3 10-20

50-55 (65)

(90) 80-90 (90)

Line 4 30-35 20

55-60

90 (2*) 80-90 (2*) 80

SHOWIN.. ............. ... .. ................. 30 0 30 Line 1

60 50-55 60-65 60 40-55 40-55,65 100-110 100-110

Line 2 0-10 0-20 0-20 0-10 60-90 45-55 90 90 50-55

100

Line 3 0-20 10,20 20-40 35 40, 50 40-60

75 60,75 85

Line 4 0,20 30 40 45-50

65-80 75 90

(1) ppm unless otherwise stated

(2*) Open beyond 90 m (end of line)

-17-

X Humus X X

ANOMALOUS ELEMENTS (X = anomalous, (X) = peak present, but sub-anomalous)

X X

X Bark

(X) X x X X

X X X X Humus (X) 80-90

PQ (X) X Bark

Humus X X

X X

7) 8.0

1)

7) 9.0

2}

4

3

Bark

X

Line 3 40-55

Line 4 30-40 Humus X X 7) 8.0 1) 0) 4.0

4)

X X

X X 4

3

Bark X

80-90 Humus

Bark X X X

TARIF 5

MAJOR NET LINE ANOMALIES AT LAMOTHE

Line 2

30-35 Humus

X X X (X) (X) X

X

7.5) 10.5

2

Bark

X

X

3}

Humus

Bark

X X X X X 7) 7.0

0)

6

SHOWING S '.'. ...... Line 1 20

Humus

X (X) X X

X

4.5) 4.5

7

Bark

Humus Î (X)

0}

50-60

1) 7.0

6)

5

Bark X X X X X X

Line 2 0-20

Humus 0) 4.0

4}

7 Bark

X

X X

XIXIX

Line 3 (nil)

Line 4 30-50 9) 12.0

3}

5) 6.0

1)

Humus X X 1

8

Bark

X

X X

90 Humus X

X X

Bark

X

(1) Approximate metre interval along line. Elements may not be anomalous along

entire interval and/or may continue anomalism outside interval.

(2) Scores: Each X scores 1, except gold scores 2; each (X) scores 112

except gold scores 1.

(3) Ranking: Based on highest net score; corresponding anomalies on adjacent lines given same rating.

-18-

sub-anomalous peack in the in the interval score half). Net scores are then combined to arrive at a net anomaly ranking, which is also allotted to the apparently corresponding interval on the adjacent line. Adjacent lines' scores were not added as the line positions did not always overlap and hence it could not be certain that they were due to the same structure. The anomalies are portrayed in Figures 5 and 6.

3.2.1 Anomaly 1 (Showing 5, Line 4, 30 - 50 m):

This is the strongest individual line anomaly and yet the only one of the top 4 anomalies not to stretch over two lines. The anomaly is characterized by good humus development (+ 30 cm) (which was wet when sampled), and is just offset from the projected position of the shear (55 m) so may in fact be attribuable to the mapped structure. The absence of an anomaly on the intervening line 3 may be due to the poor humus formation between 30 and 55 metres on that line.

3.2.2 Anomaly 2 (Showing 2, Line 1, 35 - 40 m, Line 2, 30 - 55 m):

This anomaly, although narrow is well defined over two lines and is gold anomalous in the humus on both lines and bark on one line. As for anomaly 1, the humus was well developed (+ 10 cm thick) and wet on line 2. The anomaly is 10 - 20 m offset from the projected position of the mapped shear so may be a fault-offset or a new structure.

3.2.3 Anomaly 3 (Showing 2, Line 3, 80 - 90 m, Line 4, 80 - 90 m):

This anomaly ranks relatively high because of "smoothing" applied to the line intervals. For most elements, anomalism is at 80 or 90 metres; also a duplicate sample taken at 90 metres does not match the original sample's assays very well. Never-the-less, the anomaly is detectable over two lines in bark, with gold sub-anomalous in the humus on line 3 and anomalous in bark on line 4. The anomaly is open at the ends of the lines (90 metres).

3.2.4 Anomaly 4 (Showing 2, Line 3, 40 - 55 m, Line 4, 30 - 40 m):

Anomaly 4 is essentially a humus-only anomaly and although the intervals are slightly offset across the two lines, it may be considered as one anomaly due to

-19-

the similarity in elements which are anomalous. The anomaly occurs in wet, well developed humus in an area where a small braided creek flows around rocks and tree roots, mostly concealed by a thick moss layer. Cedars and tamarack are present here. The anomalies are just offset (by 5 m, line 3) and well offset (by 20 m, line 4) from the strike projection of the mapped shear. This may indicate a fault offset or a change in strike of the shear where it is concealed.

3.2.5 Anomaly 5 (Showing 5, Line 1, 50 - 60 m):

Anomaly 5 is essentially a bark-only anomaly, but gold is sub-anomalous in the "humus". In fact, true humus is not developed here, which may account for the lack of "humus" signature. The anomaly is along strike of the projected shear and as there are no other strong anomalies on this line, it may be the expression of the shear.

3.2.6 Anomalies 6 - 8:

These are all relatively weak anomalies, usually confined to a single medium on a single line. The anomalies may be of greater significance when higher ranked anomalies are explained.

-20-

4.0 CONCLUSIONS AND RECOMMENDATIONS

4.1 CONCLUSIONS:

Final conclusions concerning this sampling exercise can not be drawn until the bedrock beneath the anomalies is exposed and/or the source of the anomalies explained.

For the moment, however, ignoring the source of the anomalies, the following conclusions may be drawn.

I) Design of biogeochemical surveys to detect mineralisation hosted by narrow shears and concealed by varying thicknesses of overburden is very difficult due to the inhomogenity of most sample media, poor understanding of the metal uptake and transport characteristics of plants in various environments and the possibility of concealed faults severely disrupting anomaly trends.

II) Even in inhomogenious media (such as "humus"), given close spaced sampling, a sufficient number of data and low enough analytical detection limits, "anomalous" populations of various elements may be recognized and form moderately coherent multiple element anomalies.

III) In this exercise, there was generally poor agreement between the particular anomalous elements in bark and "humus" for any given "anomalous" interval.

IV) Gold appears to more readily form anomalies in humus than in black spruce bark, whilst arsenic appears to more readily form a depletion anomaly in bark than an accumulation anomaly in humus. Where gold is anomalous in humus, there also tends to be an arsenic anomaly in humus.

V) Copper appears to rarely be in anomalous quantities in areas anomalous in other elements, although it is present in humus in anomaly 1 and sub-anomalous on one line of anomaly 2 humus. Copper often forms peaks above background, but not to threshold levels at other defined anomalies. The very high copper values on showing 5, line 4 35-50 metres (100 ppm) may have uriduely skewed the statistics and set a high threshold.

VI) Correlations:

The best mathematical correlations between elements for humus is between Cu U (0.88) and Cu La (0.80). Gold best correlates with Cr (0.68), La (0.51) and Cu (0.48). Other good to moderate correlations are Br .

-21-

La (0.63) and As : Fe (0 .60) . The latter is the only significant correlation involving As. Nearly all other coefficients involving As are <0.1, with As : Cu being -0.04.

4.2 RECOMMENDATIONS:

I) The following line intervals should be cleared of overburden and the bedrock mapped and any structures present sampled.

a) Showing 5, Line 4, 25 - 55 m

b) Showing 2, Lines 1 and 2, 25 - 50 m

c) Showing 2, Line 3, 35 - 60 m, 75 - 95 m Line 4, 25 - 45 m, 75 - 95 m

II) If structures are present beneath the intervals listed, 50 metres step-out lines should be biogeochemically sampled and consideration given to excavating all anomalies defined so far. If no structures are present, then some time should be devoted to explaining the biogeochemical anomalies by other means.

III) Regardless of the outcome at Lamothe, orientation biogeochemical sampling should continue in the Chibougamau district, as suitable locations become available. B horizon soils should be sampled at the same time.

IV) Sampling of the new spring growth of Black Spruce twigs should be undertaken at Lamothe over the lines already sampled, providing excavation has been restricted.

-22-

5.0 REFERENCES AND BIBLIOGRAPHY

ANDREWS, M.J., and FUGE, R., 1990; Cupriferous bogs of the Coed y Brenin area, North Wales and their significance in mineral exploration, Applied Geochemistry, Vol. 1, pp. 519-525.

BAKER, W.E., 1986; Gold in vegetation as a prospecting method in Tasmania, Aus., (Carlisle, D. ed.) Rubey Volume no. 5, Prentice Hall, pp. 150-158.

BAKER, W.E., 1986; Humis substances and their role in the solubilization and transport of metals, (Carlisle, D. ed.) Rubey Volume no. 5, Prentice Hall, pp. 377-407.

BAKER, W.E., 1990; The application of soil humic substances soil geochemical exploration, Tasmania Department of Resources and Energy, Division of Mines and Mineral Resources, Report 1990/03, 3 p.

BERRY, W.L., 1986; Plant factors influencing the use of plant analysis as a tool for biogeochemical prospecting, (Carlisle, D. ed.) Rubey Vol. no. 5, Prentice Hall, pp. 13-32.

BREE, D.G., 1990; The nature of gold in humus; Implications for geochemical exploration, Unpublished M.Sc. Thesis, Queen's University, 258 p.

BROOKS, R.R., 1982; Biological methods of prospecting for gold, Journal of Geochemical Exploration, Vol. 17, pp. 109-122.

BROOKS, R.R., 1986; Present status of botanical exploration using higher plants, (Carlisle, D. ed.) Rubey Vol. no. 5, Prentice Hall, pp. 98-132.

BROOKS, R.R. et a1, 1979; Biogeochemical anomalies in Fennoscandia: A study of Cu-Pb and Ni levels in Melandrium dioicum and viscaria alpine, Journal of Geochemical Exploration, Vol. 11, pp. 73-87.

-- BROOKS, R.R., and NAIDU, S.D., 1985; The determination of gold in vegetation by electrothermal atomic absorption spectrometry, Analytical Chimir_a Acta, Vol. 170, pp. 325-329.

BRUNDIN, H.H., and SELINUS, O.C., 1987; Biogeochemical studies of plants from stream banks in northern Sweden, Journal of Geochemical Exploration, Vol. 27, pp. 157-188.

BUSCHE,F., 1989; Using plants as an exploration tool for gold, Journal of Geochemical Exploration, Vol. 32, nos. 1-3, pp. 199-210.

CHAMPAGNE, P., 1990; Rapport des travaux, Eté 1990, Projet 4003-Option Lamothe, Canton Lemoine, Unpublished WMC Report, 14 p.

COHEN, D.R., 1986; Biogeochemistry, a geochemical method for gold exploration in the Canadian Shield, Unpublished M.Sc. Thesis, Queen's University.

COHEN, D.R., 1988; Effect of seasonal and site variations on the design of biogeochemical gold exploration programs, Bicentennial Gold 88, extended abstracts, poster programme, Vol. 23, nos. 1-2, pp. 515-517.

COHEN, D.R., HOFFMAN, E.L. and NICHOL, I., 1987; — Biogeochemistry, a geochemical methods for gold exploration

in the Canadian Shield, Journal of Geochemical Exploration, Vol. 29, pp. 49-73.

COKER, W.B., and DILABIO, R.N.W., 1987; Geochemical exploration in glaciated terrain; Geochemical Responses, Exploration 1987; Ontario Geology Survey Publication, No. 3, pp. 336-

- 383.

COKER, W.B., SEXTON, A. and LAWYER, I., 1988; Bedrock, till and --

soil geochemistry signatures at the Beaver Dam gold deposit, Nova Scotia, Prospecting in areas of glacial terrain 1988, C.I.M. Special Volume, pp. 241-254.

CURTIN, G.C., and KING, H.D., 1986; Utility of mull in geochemical exploration, (Carlisle, D. ed.) Rubey Vol. no. 5, Prentice Hall, pp. 356-376.

DUNN, C.E., 1983; Biogeochemical investigations in northern Saskatchewan; Preliminary data on tungsten, gold, platinum, rare earths, Saskatchewan Geology Survey, Summary of Investigations for 1983, Miscellaneous Report, No. 83-4, pp. 106-122.

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DUNN, C.E., 1985; Biogeochemical exploration for gold in La Ronde Belt, 1985, Saskatchewan Geology Survey, Miscellaneous Report, No. 85-4, pp. 37-49.

DUNN, C.E., 1986a; Biogeochemistry as an aid to exploration for gold, platinum and palladium in the northern forests of Saskatchewan, Canada, Journal of Geochemical Exploration, Vol. 25, pp. 21-40.

DUNN, C.E., 1986b; Biogeochemical studies in the Saskatchewan Gold Belt, 1986, Saskatchewan Geology Survey, Summary of Investigations for 1986, Miscellaneous Report, No. 86-4, pp. 129-135.

DUNN, C.E., 1987a; Developments in biogeochemical exploration, Exploration 1987, Ontario Geological Survey, Special Publication No. 3, pp. 417-438.

DUNN, C.E., 1987b; Precious metals in vegetation from northern Saskatchewan, Saskatchewan Geology Survey, Miscellaneous Report, No. 87-4, pp. 136-139.

DUNN, C.E., 1988; Reconnaissance level biogeochemistry surveys for gold in Canada, Prospecting in areas of glacial terrain, C.I.M. Special Volume, pp. 422-448.

DUNN, C.E., 1989a; Reconnaissance level biogeochemistry surveys .1011.

for gold in Canada, I.M.M. Trans., Vol. 98, Section b, pp. B153-B161.

DUNN, C.E., 1989b; Notes for workshop on biogeochemical exploration, Prepared for 13th International Symposium on Exploration Geochemistry.

DUNN, C.E., and SCAGEL, R.K., 1989; Tree-top sampling from a helicopter - A new approach to gold exploration, Journal of Geochemical Exploration, Vol. 34, pp. 255-270.

DUNN, C.E., and BANVILLE, R.M.P., 1989; Reconnaissance biogeochemical survey, Eastern Nova Scotia, Geological Survey of Canada Open File, No. 2002, p. 95, 30 maps.

DUNN, C.E., GEORGE, H. and SPIRITO, S., 1989; Patterns of metal 100011.

enrichment in vegetation in relation to geology and gold mineralisation, Star Lake Area, Saskatchewan, Preprint of paper for Proceedings volume of the Saskatchewan Geological Society Symposium, "Modern Exploration Techniques", 22 p.

DUNN, C.E., and SCHWANN, P.L., 1990; Site investigation of a biogeochemical gold anomaly near Wadin Bay, Lac La Ronge, Saskatchewan Energy and Mines, Summary of Investigations 1990, Saskatchewan Geological Survey, pp. 158-162.

ERDMAN, J.A., and MOTOOKA, J.M., 1985; Biogeochemical response at the Greens Creek massive sulphide deposit, Admiralty Island, U.S.G.S., Circ., No. 945, pp. 88-91.

^- ERDMAN, J.A., and KOKKOLA, M., 1984; Biogeochemistry in mineral exploration, Journal of Geochemical Exploration, Vol. 21, pp. 123-238.

ERDMAN, J.A., and OLSON, J.C., 1985; The use of plants in prospecting for gold; A brief overview with a selected bibliography and topic index, Journal of Geochemical Exploration, Vol. 24, pp. 281-304.

FEDIKOW, M.A.F., 1985; The vegetation geochemical signature of the Agassiz stratabound Au-Ag deposit, Lynn Lake, Manitoba, Manitoba Geology Survey Open File, No. 85-6, 94 p.

FEDIKOW, M.A.F., 1986; Mercury gas surveys over base and precious metal mineral deposits in the Lynn Lake and Snow Lake areas, Manitoba, Manitoba Energy and Mines, Open File Report, No. OF85-11, 45 p.

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- PLANT, J.A. and SLATER, D., 1986; Regional Geochemistry -

potential developments, I.M.M. Trans. Vol. 95, pp. B63-B70.

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-- 271-284.

ROGERS, P.J. and DUNN, C.E., 1989; Regional biogeochemical surveys for gold in eastern Nova Scotia, Canada, Nova Scotia Department of Mines and Energy, Preprint for PDA, 13 p.

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TOVERUD, O., 1979; Humus - A new sampling medium in geochemical prospecting for tungsten in Sweden, I.M.M. Prospecting in Areas of Glaciated Terrain, 1979, pp. 74-79.

WARREN, H.V. and HORSKY, S.J., 1986; Thallium, a biogeochemical prospecting tool for gold, Journal of Geochemical Exploration, Vol. 26, pp. 215-226.

APPENDIX 1

ANALYTICAL DATA FOR HUMUS

SAMPLING OF HUMUS AT LAMMOTHE

SEPTEMBER 1990 M. WARD, L. ARDOUIN

ANALYSIS OF DRIED WHOLE SAMPLES

ANALYSED BY ACTIVATION LABORATORIES, ANCASTER,ON.

VALUES LESS THAN DETECTION LIMIT MAY BE SET TO ZERO

DETECTION LIMITS (PPM EXCbPT WHERE SHOWN) : AU AG AS BA CU BR CA

1 PPB 2 1 100 1 1 0.1 %

CO CR CS FE HF HG IR 1 1 0.5 0.05 % 0.5 0.5 5 PPB

MO NA NI RB SB SC SE 0.5 100 10 20 0.1 0.1 2

SR TA TH U W ZN LA 100 0.5 0.5 0.1 1 20 0.1

CE ND SM EU TB YB LU 1 3 0.1 0.2 0.2 0.1 0.1

SAMP. LINE SAMP. STRAT. W F M C GEO SL D NO. POS. DEPTH

REMARKS

12778 0 30 S,R,G 2 2 1 BK T,OH U 1 12779 10 35 M,R,G 1 2 1 BN T,LH D 1 12780 10 35 M,R,G 1 2 1 BN T,LH D 1 12781 20 25 M,R,G 2 2 1 BK T,OH U 1 12782 30 35 S,R,G 1 3 1 BN T,LH U 1 12783 35 50 M,S,H 1 1 1 BK T,OH U 1 12784 40 70 M,S,H 1 2 1 BK T,OH D 1 12785 45 25 M,R,G 1 1 1 BK T,OH D 1 12786 50 30 M,R,G 1 2 1 BK T,OH D 1 12787 50 32 M,R,G 1 2 1 BK T,OH D 1 12788 55 30 M,R,G 1 2 1 BN T,OH U 1 12789 60 35 M,R,G 1 2 1 BN T,LH D 1 12790 65 20 M,R,G 1 2 1 BK T,OH 0 1 DRILL TRACK 12791 70 35 M,R,G 1 1 1 BK T,OH U 1 12792 80 40 M,R,G 2 1 1 BK T,OH U 1 12793 90 40 M,R,G 1 1 1 BK T,OH D 1 12794 100 35 M,R,T 1 1 1 BK T,OH U 1

SAMP. NO.

LINE SAMP. POS. DEPTH

S [RAT. W F M C GEO SL D REMARKS

12795 0 40 M,R,G 1 2 1 BK T,LH D 1 12796 10 15 M,R,G 2 1 1 BK T,OH D 1 12797 20 25 M,R,G 2 2 1 BK T,OH U 1 12798 30 30 M,R,H 2 1 1 BK T,OH D 2 ROCK @ 45CM;15CM HUM 12799 35 20 M,R,H 2 1 1 BK T,OH 0 2 12800 40 40 M,R,G 1 2 1 BN T,LH U 2 12851 45 40 M,R,G 1 2 1 BN T,LH 0 2 ONLY 1CM HUMUS 12852 50 30 M,R,G 3 2 1 BK T,OH 0 2 STRIKE PROJ. SHEAR 12853 55 30 M,R,G 1 2 1 BN T,LH 0 1 12854 60 35 M,R,G 2 1 1 BK T,OH D 1 12855 70 40 M,R,G 1 2 2 BK T,LH 0 1 EDGE OF TRACK 12856 80 35 M,R,H 3 2 1 BN T,LH 0 2 EDGE OF TRACK 12857 90 30 M,R,H 2 1 1 BK T,OH 0 1

-

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF

SHOWING AU

PPB

ORGANICS) AT LAMOTHE

2 LINE 1....BASE OF ORGANICS

AG AS BA

PPM PPM PPM

(HUMUS) CU

PPM BR PPM

12778 0 5 -2 4 170 15 12 12779 10 1 -2 2 0 4 12 12780 10 1 -2 2 0 5 10 12781 20 0 -2 3 0 7 20 12782 30 1 -2 2 0 9 12783 35 28 -2 2 290 6 9 12784 40 1 -2 1 0 17 18 12785 45 0 -2 0 0 5 14 12786 50 1 -2 2 200 18 19 12787 50 0 -2 2 0 10 15 12788 55 1 -2 1 0 7 15 12789 60 0 -2 0 0 4 13 12790 65 0 -2 2 130 8 9 12791 70 13 -2 1 130 24 19 12792 80 1 -2 2 100 19 18 12793 90 0 -2 0 0 15 16 12794 100 0 -2 1 150 6 14

SAMPLE NUMBER

LINE POSITION

SHOWING 2 AU

PPB

LINE 2....BASE OF

AG AS

PPM PPM

ORGANICS BA

PPM

(HUMUS) CU

PPM BR

PPM 12795 0 4 -2 2 180 16 15 12796 10 1 -2 3 0 8 20 12797 20 1 -2 2 0 9 14 12798 30 9 -2 5 400 21 32 12799 35 13 -2 10 430 28 50 12800 40 3 -2 0 0 3 13 12851 45 1 -2 0 0 4 11 12852 50 1 -2 0 0 28 13 12853 55 0 -2 0 0 4 10 12854 60 1 -2 2 0 8 14 12855 70 0 -2 2 140 7 14 12856 80 1 -2 1 0 7 11 12857 90 19 -2 2 370 38 11

-

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

CA CO % PPM

AT LAMOTHE

CR PPM

CS PPM

FE %

'FE*10 %

12778 0 -0.2 2 10 1 0.51 5.1 12779 10 0.3 -1 3 -0.5 0.1 1 12780 10 0.9 -1 2 -0.5 0.07 0.7 12781 20 2.6 3 5 -0.5 0.31 3.1 12782 30 0.5 -1 1 -0.5 0.07 0.7 12783 35 0.5 2 160 1 0.63 6.3 12784 40 -0.1 3 8 -0.5 0.55 5.5 12785 45 -0.1 1 5 -0.5 0.28 2.8 12786 50 -0.2 3 22 0.6 1.05 10.5 12787 50 1.9 1 5 -0.5 0.33 3.3 12788 55 1 1 1 -0.5 0.09 0.9 12789 60 -0.1 2 7 -0.5 0.21 2.1 12790 65 -0.1 2 20 0.8 0.41 4.1 12791 70 -0.1 2 7 -0.5 0.36 3.6 12792 80 3.8 7 10 -0.5 0.59 5.9 12793 90 3 -1 3 -0.5 0.31 3.1 12794 100 0.4 2 6 -0.5 0.27 2.7

SAMPLE LINE CA CO CR CS FE FE*10 NUMBER POSITION % PPM PPM PPM % % 12795 0 -0.2 5 19 -0.5 0.57 5.7 12796 10 2.8 2 7 0.5 0.7 7 12797 20 3.8 2 3 -0.5 0.27 2.7 12798 30 2.4 25 34 1.6 3.67 36.7 12799 35 3.2 35 27 1.1 4.25 42.5 12800 40 0.3 -1 2 -0.5 0.1 1 12851 45 0.7 1 1 -0.5 0.08 0.8 12852 50 1.2 2 11 -0.5 0.7 7 12853 55 -0.1 -1 7 -0.5 0.15 1.5 12854 60 -0.1 1 21 -0.5 0.41 4.1 12855 70 1.4 1 19 -0.5 0.61 6.1 12856 80 1.8 1 2 -0.5 0.34 3.4 12857 90 2.3 7 70 1.4 1.52 15.2

SAMPLING OF HUMUS

^ SAMPLE LINE NUMBER POSITION

(BASE OF

HF PPM

ORGANICS) AT

HG PPM

LAMOTHE

IR PPB

MO PPM

NA PPM

NA/10 PPM

12778 0 2.6 -0.5 -5 1.5 7950 795 _, 12779 10 -0.5 -0.5 -5 -0.5 244 24.4

12780 10 -0.5 -0.5 -5 -0.5 188 18.8 12781 20 -0.5 -0.5 -5 -0.5 597 59.7 12782 30 -0.5 -0.5 -5 0.6 414 41.4 12783 35 7.9 -0.5 -5 0.6 11200 1120 12784 40 0.6 -0.5 -5 0.6 617 61.7 12785 45 -0.5 -0.5 -5 0.9 1030 103

-- 12786 50 1.7 -0.5 -5 0.7 2990 299 12787 50 0.7 -0.5 -5 -0.5 1160 116 12788 55 -0.5 -0.5 -5 -0.5 207 20.7 12789 60 -0.5 -0.5 -5 1.1 1150 115 12790 65 1.4 -0.5 -5 -0.5 3980 398 12791 70 0.5 -0.5 -5 0.6 382 38.2 12792 80 -0.5 -0.5 -5 0.9 537 53.7 12793 90 -0.5 -0.5 -5 -0.5 483 48.3 12794 100 -0.5 -0.5 -5 -0.5 2140 214

11100..

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

MO PPM

NA PPM

NA/10 PPM

12795 - 0 2.4 -0.5 -5 -0.5 3960 396 12796 10 0.9 -0.5 -5 1.3 1760 176 12797 20 -0.5 -0.5 -5 0.8 302 30.2 12798 30 2.2 -0.5 -5 1.1 5750 575

-- 12799 35 1.9 -0.5 -5 -0.5 3230 323 12800 40 -0.5 -0.5 -5 -0.5 184 18.4 12851 45 -0.5 -0.5 -5 -0.5 170 17

,_ 12852 50 -0.5 -0.5 -5 -0.5 580 58 12853 55 1.7 -0.5 -5 -0.5 1350 135 12854 60 2.5 -0.5 -5 0.9 2990 299 12855 70 4.5 -0.5 -5 -0.5 18100 1810

- 12856 80 -0.5 -0.5 -5 -0.5 225 22.5 12857 90 8.4 -0.6 -5 -0.5 18100 1810

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

NI RB

PPM PPM

AT LAMOTHE

SB PPM

SC PPM

SE PPM

SR PPM

12778 0 -10 -20 0.6 3 -2 -100 12779 10 -10 -20 0.2 0.4 -2 -100 12780 10 -10 -20 0.2 0.3 -2 -100 12781 20 -10 -20 0.3 2.4 -2 -100 12782 30 -10 -20 0.2 0.2 -2 -100 12783 35 52 28 -0.1 4.6 -2 110 12784 40 -10 -20 -0.1 1.8 -2 -100 12785 45 -10 -20 -0.1 1.5 -2 -100 12786 50 -10 -20 0.2 5.1 -2 -100 12787 50 -10 -20 0.2 1.6 -2 -100 12788 55 -10 -20 0.1 0.3 -2 -100 12789 60 -10 -20 0.1 1.4 -2 -100 12790 65 -10 -20 0.2 2.2 -2 -100 12791 70 -10 -20 0.1 2.8 -2 -100 12792 80 -10 -20 0.3 2.3 -2 -100 12793 90 -10 -20 -0.1 0.9 -2 -100 12794 100 -10 -20 -0.1 1.4 -2 -100

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SE PPM

SR PPM

12795 0 -10 -20 0.1 3.7 -2 -100 12796 10 -10 -20 0.3 1.6 -2 -100 12797 20 -10 -20 0.3 0.6 -2 -100 12798 30 -10 -20 0.2 5.3 -2 -100 12799 35 -10 -20 0.3 4.6 -2 -100 12800 40 -10 -20 -0.1 0.4 -2 -100 12851 45 -10 -20 -0.1 0.3 -2 -100 12852 50 -10 -20 -0.1 2.7 -2 -100 12853 55 -10 -20 -0.1 0.5 -2 -100 12854 60 -10 -20 0.2 2.3 -2 -100 12855 70 -10 -20 0.1 2.2 -2 -100 12856 80 -10 -20 0.2 0.6 -2 -100 12857 90 -10 42 0.3 11 -2 390

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

TA TH

PPM PPM

AT LAMOTHE

U PPM

W PPM

ZN PPM

LA PPM

12778 0 -0.5 1.6 0.4 -1 62 9.2 12779 10 -0.5 -0.5 0.1 -1 36 1.5 12780 10 -0.5 -0.5 0 -1 33 1.2 12781 20 -0.5 0.8 5.1 3 55 7 12782 30 -0.5 -0.5 0 -1 43 1 12783 35 -0.5 3.2 0.9 -1 40 14 12784 40 -0.5 1 0.5 -1 45 8.4 12785 45 -0.5 0.6 0 -1 37 2.9 12786 50 -0.5 2.3 0.9 -1 63 19 12787 50 -0.5 1 0.4 -1 28 6.3 12788 55 -0.5 -0.5 0 -1 49 1.1 12789 60 -0.5 0.6 0 -1 67 2.6 12790 65 -0.5 1.6 0 -1 34 7.5 12791 70 -0.5 1.7 0.8 -1 42 10 12792 80 -0.5 1.1 0.7 -1 68 11 12793 90 -0.5 0.7 0.3 -1 34 5.8 12794 100 -0.5 0.6 0 -1 60 3.6

SAMPLE NUMBER

LINE POSITION

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

LA PPM

12795 0 -0.5 2.1 0.7 2 45 27 12796 10 -0.5 1 0.3 -1 61 9 12797 20 -0.5 -0.5 0 -1 51 5.3 12798 30 -0.5 2.8 1.4 -1 120 24 12799 35 -0.5 2.5 1.5 -1 200 22 12800 40 -0.5 -0.5 0.1 -1 44 2 12851 45 -0.5 -0.5 0.1 -1 38 1.8 12852 50 -0.5 1.3 0.6 -1 44 15 12853 55 -0.5 0.7 0.3 -1 36 3 12854 60 -0.5 1.7 0.6 -1 51 8.9 12855 70 -0.5 2.7 0.8 -1 45 13 12856 80 -0.5 -0.5 0.2 -1 36 3.1 12857 90 -0.5 6.8 2.3 -1 53 51

--

SAMPLING OF HUMUS (BASE

SAMPLE LINE NUMBER POSITION

OF

CE PPM

ORGANICS) AT

ND PPM

LAMOTHE

SM PPM

EU PPM

TB PPM

YB PPM

12778 0 11 6 1.1 0.2 -0.2 0.5 12779 10 2 -3 0.2 -0.2 -0.2 -0.1 12780 10 2 -3 0.2 -0.2 -0.2 -0.1 12781 20 8 4 0.8 -0.2 -0.2 0.2 12782 30 1 -3 0.1 -0.2 -0.2 -0.1 12783 35 17 8 1.2 0.3 0.2 0.8 12784 40 10 4 0.8 -0.2 -0.2 0.2 12785 45 4 -3 0.3 -0.2 -0.2 0.1 12786 50 21 11 1.9 0.4 -0.2 0.6 12787 50 6 -3 0.6 -0.2 -0.2 0.2 12788 55 2 -3 0.1 -0.2 -0.2 -0.1 12789 60 3 -3 0.3 -0.2 -0.2 0.2 12790 65 9 -3 0.7 -0.2 -0.2 0.2 12791 70 11 4 0.9 -0.2 -0.2 0.2 12792 80 12 9 1.3 0.2 -0.2 0.3 12793 90 6 5 0.7 -0.2 -0.2 0.2 12794 100 4 -3 0.4 -0.2 -0.2 0.1

SAMPLE NUMBER

LINE POSITION

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

YB PPM

12795 0 33 17 2.6 0.5 0.3 0.7 12796 10 10 5 1 -0.2 -0.2 0.4 12797 20 4 4 0.6 -0.2 -0.2 0.1 12798 30 32 14 2.8 0.5 -0.2 0.8 12799 35 33 13 2.6 0.5 -0.2 0.7 12800 40 2 -3 0.2 -0.2 -0.2 -0.1 12851 45 2 -3 0.2 -0.2 -0.2 -0.1 12852 50 16 9 1.4 0.2 -0.2 0.3 12853 55 3 -3 0.3 -0.2 -0.2 0.2 12854 60 11 8 0.9 -0.2 -0.2 0.4 12855 70 13 6 1.1 -0.2 -0.2 0.4 12856 80 3 -3 0.3 -0.2 -0.2 -0.1 12857 90 66 30 5.2 1.2 0.6 1.8

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

LU Mass

PPM g 12778 0 -0.1 30 12779 10 -0.1 30 12780 10 -0.1 30 12781 20 -0.1 30 12782 30 -0.1 25.38 12783 35 0.2 30 12784 40 -0.1 30 12785 45 -0.1 30 12786 50 -0.1 30 12787 50 -0.1 30 12788 55 -0.1 30 12789 60 -0.1 30 12790 65 -0.1 30 12791 70 -0.1 30 12792 80 -0.1 30 12793 90 -0.1 30 12794 100 -0.1 30

SAMPLE NUMBER

LINE POSITION

LU PPM

Mass g

12795 0 0.1 30 12796 10 -0.1 30 12797 20 -0.1 30 12798 30 0.2 30 12799 35 0.1 30 12800 40 -0.1 30 12851 45 -0.1 30 12852 50 -0.1 30 12853 55 -0.1 30 12854 60 -0.1 30 12855 70 -0.1 30 12856 80 -0.1 30 12857 90 0.2 30

AT LAMOTHE

SAMP. NO.

LINE SAMP. POS. DEPTH

STRAT. W F M C GEO SL D REMARKS

12858 0 30 M,R,H 2 2 1 BK S,OH 0 2 IN COUPE DE FORET 12859 10 30 M,R,H 2 1 1 BK S,OH 0 2 EDGE OF COUPE 12860 20 32 M,R,H 2 2 1 BK S,OH 0 2 AULNES PRESENT 12861 30 50 M,R,H 2 1 1 BK S,OH 0 2 THICK HUMUS; NO BASE 12862 35 40 M,R,G 2 1 1 BK T,OH 0 2 ROCK AT BASE 12863 40 30 M,R,T 1 1 1 BK T,OH 0 2 12864 45 32 M,R,T- 2 1 1 BK T,OH U 2 SWAMPY CREEK 12865 50 25 M,R,G 3 2 1 BK T,OH U 4 'UNDERGROUND' CREE 12866 55 23 M,R,R 2 1 1 BK T,OH U 2 12867 60 30 M,R,P 2 1 1 BK T,OH U 2 DUPLICATE 12868 60 20 M,R,G 2 1 1 BK T,OH U 2 12869 65 21 M,R,G 1 1 1 BK T,OH U 2 12870 70 30 M,R,G 1 1 1 BK T,OH U 2 12871 75 25 M,R,G 1 1 1 BK T,OH U 2 'UNDERGROUND' CREE 12872 80 20 M,R,G 2 1 2 BK T,OH 0 2 12873 90 25 M,R,G 3 1 1 BK T,OH 0 4 2M TO NE OF L 7S 12874 90 25 M,R,G 3 1 1 BK T,OH 0 4

alite.ff fa

SAMP. NO.

LINE SAMP. POS. DEPTH

STRAT. W F M C GEO SL D REMARKS

12875 0 30 M,R,H 2 1 1 BK S,OH 0 2 EDGE OF COUPE DE FOR 12876 10 35 M,R,H 2 1 1 BK S,OH 0 2 12877 20 20 M,R,G 1 1 1 BK G,OH 0 2 12878 25 30 M,R,G 2 2 1 BK T,OH 0 3 MELEZE PRESENT 12879 30 25 M,R,G 2 2 1 BK T,OH 0 4 12880 35 25 M,R,G 2 2 1 BK G,OH 0 3 12881 40 35 M,R,G 3 1 1 BK P,OH 0 2 12882 45 60 M,R,G 1 2 1 BK P,OH 0 1 12883 50 65 M,R,G 1 2 1 BN P,OH 0 1 12884 55 30 M,R,G 1 2 1 BN P,OH 0 1 12885 60 40 M,R,H 1 1 1 BK S,OH 0 1 12886 70 20 M,R,P 1 2 1 BK P,OH 0 1 12887 80 30 M,R,H 2 2 1 BK S,OH 0 1 12888 90 25 M,R,H 2 2 1 BK S,OH 0 1

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS) AT LAMOTHE

SHOWING 2 LINE 3....BASE OF ORGANICS

AU AG AS BA

PPB PPM PPM PPM

(HUMUS) CU

PPM BR PPM

12858 0 1 -2 3 100 6 18 12859 10 1 -2 2 110 7 25 12860 20 0 -2 3 240 9 35 12861 30 1 -2 0 0 2 14 12862 35 12863 40 3 -2 4 350 19 35 12864 45 0 -2 4 360 28 37 12865 50 0 -2 8 190 17 43 12866 55 1 -2 5 280 16 24 12867 60 0 -2 0 0 9 15 12868 60 2 -2 3 180 24 27 12869 65 3 -2 2 150 15 17 12870 70 0 -2 1 0 6 12 12871 75 1 -2 1 0 35 13 12872 80 1 -2 8 960 14 39 12873 90 0 -2 2 120 14 12 12874 90 3 -2 5 150 17 14

SAMPLE NUMBER

LINE POSITION

SHOWING 2 AU

PPB

LINE 4....BASE OF

AG AS

PPM PPM

ORGANICS BA

PPM

(HUMUS) CU

PPM BR

PPM 12875 0 0 -2 2 0 5 17 12876 10 0 -2 2 0 6 25 12877 20 0 -2 4 340 12 37 12878 25 3 -2 3 220 19 21 12879 30 3 -2 9 390 18 37 12880 35 4 -2 3 410 15 22 12881 40 3 -2 2 320 27 37 12882 45 1 -2 0 0 8 16 12883 50 0 -2 0 0 3 13 12884 55 1 -2 0 0 5 14 12885 60 1 -2 0 0 18 14 12886 70 0 -2 4 260 19 25 12887 80 1 -2 1 0 12 12888 90 1 -2 2 120 10 22

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

CA CO PPM

AT LAMOTHE

CR PPM

CS PPM

FE FE*10

12858 0 2.6 12 5 -0.5 1.31 13.1 12859 10 3.3 5 6 -0.5 1.41 14.1 12860 20 2.3 12 5 -0.5 3.32 33.2 12861 30 1.5 -1 0 -0.5 0.11 1.1 12862 35 12863 40 3 7 43 1.2 3.5 35 12864 45 2 15 38 1.1 4.96 49.6 12865 50 2.6 18 15 0.8 2.97 29.7 12866 55 3 19 28 0.7 2.42 24.2 12867 60 3.4 -1 4 -0.5 0.16 1.6 12868 60 3.3 6 14 0.7 0.86 8.6 12869 65 2.1 2 11 -0.5 0.45 4.5 12870 70 0.4 -1 2 -0.5 0.18 1.8 12871 75 0.5 1 5 0.6 0.31 3.1 12872 80 2.2 120 24 1.1 5.89 58.9 12873 90 3.3 14 78 -0.5 2.63 26.3 12874 90 2.1 5 24 0.9 3.61 36.1

SAMPLE LINE CA CO CR CS FE FE*10 NUMBER POSITION % PPM PPM PPM % % 12875 0 3.3 2 2 -0.5 0.32 3.2 12876 10 3.6 3 3 -0.5 0.86 8.6 12877 20 2 22 24 0.8 5 50 12878 25 2.4 15 11 0.7 2.78 27.8 12879 30 2 28 20 0.9 5.48 54.8 12880 35 2.5 20 31 1 2.4 24 12881 40 3.4 9 43 2.2 1.94 19.4 12882 45 1 -1 2 -0.5 0.18 1.8 12883 50 0.7 1 5 -0.5 0.12 1.2 12884 55 0.6 -1 5 -0.5 0.32 3.2 12885 60 0.4 -1 9 -0.5 0.28 2.8 12886 70 2.4 24 29 0.6 2.2 22 12887 80 2.9 -1 3 -0.5 0.54 5.4 12888 90 3.2 2 8 -0.5 1.01 10.1

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

HF HG

PPM PPM

AT LAMOTHE

IR PPB

MO PPM

NA PPM

NA/10 PPM

12858 0 -0.5 -0.5 -5 1.1 250 25 12859 10 -0.5 -0.5 -5 1.1 253 25.3 12860 20 -0.5 -0.5 -5 3.6 181 18.1 12861 30 -0.5 -0.5 -5 0.5 105 10.5 12862 35 12863 40 2.1 -0.5 -5 -0.5 9550 955 12864 45 1.1 -0.5 -5 -0.5 1880 188 12865 50 0.7 -0.5 -5 1 858 85.8 12866 55 1.9 -0.5 -5 -0.5 6570 657 12867 60 -0.5 -0.5 -5 -0.5 604 60.4 12868 60 1.1 -0.5 -5 0.8 2300 230 12869 65 1.7 -0.5 -5 -0.5 1680 168 12870 70 0.5 -0.5 -5 -0.5 579 57.9 12871 75 -0.5 -0.5 -5 -0.5 910 91 12872 80 -0.5 -0.5 -5 3.8 721 72.1 12873 90 -0.5 -0.5 -5 -0.5 8380 838 12874 90 1 -0.5 -5 1.2 1410 141

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

MO PPM

NA PPM

NA/10 PPM

12875 0 -0.5 -0.5 -5 -0.5 149 14.9 12876 10 -0.5 -0.5 -5 0.7 242 24.2 12877 20 0.7 -0.5 -5 3.5 922 92.2 12878 25 -0.5 -0.5 -5 1.3 337 33.7 12879 30 0.5 -0.5 -5 1.6 550 55 12880 35 2.4 -0.5 -5 1.5 8230 823 12881 40 5.1 -0.5 -5 2.2 9090 909 12882 45 -0.5 -0.5 -5 -0.5 286 28.6 12883 50 -0.5 -0.5 -5 -0.5 288 28.8 12884 55 0.6 -0.5 -5 -0.5 1300 130 12885 60 0.5 -0.5 -5 -0.5 400 40 12886 70 0.9 0.9 -5 1.6 2300 230 12887 80 -0.5 -0.5 -5 0.7 188 18.8 12888 90 -0.5 -0.5 -5 -0.5 413 41.3

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

NI RB

PPM PPM

AT LAMOTHE

SB PPM

SC PPM

SE PPM

SR PPM

12858 0 -10 -20 0.2 0.5 -2 -100 12859 10 -10 -20 0.2 0.6 -2 -100 12860 20 -10 -20 0.1 0.5 -2 -100 12861 30 -10 -20 -0.1 0.3 -2 -100 12862 35 12863 40 -12 21 -0.1 6.6 -2 -100 12864 45 -10 -20 0.2 5.5 -2 -100 12865 50 -10 -20 0.4 2.3 -2 140 12866 55 -10 -20 0.3 3.6 -2 -100 12867 60 -10 -20 0.1 0.6 -2 -100 12868 60 -10 -20 0.2 2.3 -2 190 12869 65 -10 -20 0.2 2.7 -2 -100 12870 70 -10 -20 -0.1 0.9 -2 -100 12871 75 -10 -20 0.1 2.5 -2 -100 12872 80 -10 -20 0.3 3.2 -2 -100 12873 90 32 -20 0.2 9.6 -2 270 12874 90 -10 -20 0.1 4.6 -2 -100

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SE PPM

SR PPM

12875 0 -10 -20 0.2 0.3 -2 -100 12876 10 -10 -20 0.1 0.4 -2 -100 12877 20 -10 -20 0.2 4 -2 -100 12878 25 -10 -20 0.2 1.8 -2 -100 12879 30 -10 -20 0.3 3.1 -2 -100 12880 35 -10 -20 0.2 4.1 -2 -100 12881 40 -11 28 -0.1 7.2 -2 -100 12882 45 -10 -20 -0.1 1.2 -2 -100 12883 50 -10 -20 -0.1 0.7 -2 -100 12884 55 -10 -20 0.1 0.8 -2 -100 12885 60 -10 -20 -0.1 2.5 -2 -100 12886 70 -10 -20 0.2 3.9 -2 -100 12887 80 -10 -20 0.2 0.4 -2 -100 12888 90 -10 -20 0.2 1.6 -2 -100

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

TA TH

PPM PPM

AT LAMOTHE

U PPM

W PPM

ZN PPM

LA PPM

12858 0 -0.5 -0.5 0 -1 28 2 12859 10 -0.5 0.5 0 -1 43 4.6 12860 20 -0.5 -0.5 3.5 -1 50 5.3 12861 30 -0.5 -0.5 0 -1 23 2.3 12862 35 12863 40 -0.5 3.3 1.8 -1 100 34 12864 45 -0.5 3.5 2.8 -1 110 28 12865 50 -0.5 1.5 0.8 -1 110 15 12866 55 -0.5 1.6 0.7 -1 86 16 12867 60 -0.5 -0.5 0.2 -1 40 1.8 12868 60 -0.5 1.1 0.6 -1 53 15 12869 65 -0.5 1 0 -1 63 7.9 12870 70 -0.5 0.6 0.2 -1 40 3.4 12871 75 -0.5 0.6 0 -1 49 5.7 12872 80 -0.5 2 0.6 -1 120 13 12873 90 -0.5 1 0.7 -1 38 6.4 12874 90 -0.5 2.7 1.4 -1 44 15

SAMPLE NUMBER

LINE POSITION

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

LA PPM

12875 0 -0.5 0 0 -1 49 1.1 12876 10 -0.5 0 0.4 -1 36 2.9 12877 20 -0.5 2.6 2.7 -1 83 19 12878 25 -0.5 0.9 0.9 -1 71 13 12879 30 -0.5 2.1 1.4 -1 120 19 12880 35 0.6 1.8 0.9 -1 69 18 12881 40 -0.5 4.5 2.1 -1 -20 32 12882 45 -0.5 0.5 0.3 -1 24 2.9 12883 50 -0.5 0.5 0 -1 -20 1.9 12884 55 -0.5 0.6 0.2 -1 37 2.9 12885 60 -0.5 1.6 0.4 -1 46 8.6 12886 70 -0.5 2.6 1.3 -1 25 15 12887 80 -0.5 0 0 -1 38 2.3 12888 90 -0.5 1.2 0.5 -1 48 4.6

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

CE ND

PPM PPM

AT LAMOTHE

SM PPM

EU PPM

TB PPM

YB PPM

12858 0 3 -3 0.3 -0.2 -0.2 0.1 12859 10 6 -3 0.4 -0.2 -0.2 0.2 12860 20 6 -3 0.6 -0.2 -0.2 0.2 12861 30 3 -3 0.2 -0.2 -0.2 -0.1 12862 35 12863 40 45 27 3.9 0.8 -0.2 1.2 12864 45 37 17 3.2 0.6 0.3 1 12865 50 14 10 1.6 0.3 -0.2 0.5 12866 55 17 10 1.9 0.4 -0.2 0.7 12867 60 2 -3 0.2 -0.2 -0.2 -0.1 12868 60 12 11 1.7 0.3 0.2 0.5 12869 65 9 4 0.9 -0.2 -0.2 0.3 12870 70 4 3 0.3 -0.2 -0.2 0.1 12871 75 6 3 0.6 -0.2 -0.2 0.2 12872 80 29 8 1.5 0.3 -0.2 0.6 12873 90 7 4 0.9 0.3 -0.2 0.5 12874 90 19 12 1.7 0.3 -0.2 0.5

SAMPLE NUMBER

LINE POSITION

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

YB PPM

12875 0 1 -3 0.2 -0.2 -0.2 -0.1 12876 10 3 -3 0.3 -0.2 -0.2 0.1 12877 20 25 14 2.3 0.4 -0.2 0.7 12878 25 15 13 1.5 0.3 -0.2 0.5 12879 30 28 12 2.2 0.3 -0.2 0.6 12880 35 21 13 2.1 0.5 -0.2 0.7 12881 40 30 20 3.8 0.8 -0.2 1.2 12882 45 4 -3 0.3 -0.2 -0.2 -0.1 12883 50 2 -3 0.2 -0.2 -0.2 0.1 12884 55 3 -3 0.3 -0.2 -0.2 0.2 12885 60 10 6 0.9 0.2 -0.2 0.3 12886 70 13 11 1.6 0.3 -0.2 0.5 12887 80 2 -3 0.3 -0.2 -0.2 0.1 12888 90 5 -3 0.5 -0.2 -0.2 0.2

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

LU Mass

PPM g 12858 0 -0.1 30 12859 10 -0.1 30 12860 20 -0.1 30 12861 30 -0.1 30 12862 35 12863 40 0.2 30 12864 45 0.2 30 12865 50 -0.1 30 12866 55 0.1 30 12867 60 -0.1 30 12868 60 -0.1 30 12869 65 -0.1 30 12870 70 -0.1 30 12871 75 -0.1 30 12872 80 0.1 30 12873 90 0.1 30 12874 90 -0.1 30

AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

LU PPM

Mass g

12875 0 -0.1 30 12876 10 -0.1 30 12877 20 0.1 30 12878 25 -0.1 30 12879 30 0.1 30 12880 35 0.1 30 12881 40 0.2 30 12882 45 -0.1 30 12883 50 -0.1 30 12884 55 -0.1 30 12885 60 -0.1 30 12886 70 0.1 30 12887 80 -0.1 30 12888 90 -0.1 30

SAMP. NO.

LINE SAMP. POS. DEPTH

STRAT. W F M C GEO SL D REMARKS

12701 0 15 M 1 2 1 BN G,OH 0 1 ADJ. TO CREEK 12702 10 20 M,S,R 1 2 2 BN G,OH U 1 12703 20 10 R 1 2 2 BK G,OH U 1 DISTURBED; TRACK 12704 30 20 M,R,T 1 2 1 BK T,OH U 1 NO HUMUS 12705 35 20 M,R,T T,LF U 1 ORGANIC HORIZON 12706 40 15 M,R,T T,LF U 1 DITTO 12707 45 20 M,R,T T,LF U 1 DITTO 12708 SO 20 M,R,T 1 2 2 BN T,LF U 1 SANDY TILL W. COBBLES 12709 55 20 M,R,T 1 2 2 BK T,LF U 1 STRIKE PROJ. SHEAR 12710 60 20 M,R 1 3 1 BN T,LF 0 1 12711 60 20 M,R 1 3 1 BN T,LF 0 1 DUPLICATE 12712 65 20 M,R 1 3 2 BN T,LF U 1 12713 70 20 M,R 2 3 1 BN T,LF U 1 DRILL TRACK 12714 80 15 M,R 1 3 1 BN T,LF U 1 12715 90 20 M,R 1 3 1 BN T,LF U 1 12716 100 20 M,R 1 3 1 BN T,LF U 1 12717 110 8 M,C 1 2 2 BN A,LF U 1 SUB OUTCROP 12718 120 6 M,C 1 2 2 BN A,LF U 1 16M TO L16S 535W

SAMP. NO.

LINE SAMP. POS. DEPTH

STRAT. W F M C GEO SL D REMARKS

12719 0 30 M,R,T 2 2 1 BN P,OH 0 1 12720 10 25 M,R,T 2 2 1 BN G,OH U 1 DRILL TRACK 12721 20 20 M,R,T 1 2 2 BN P,LH U 1 DRILL TRACK 12722 30 20 M,R,T 1 2 1 BN T,LH U 1 12723 35 22 M,R,T 1 2 1 BN T,LH U 1 12724 35 22 M,R,T 1 2 1 BN T,LH U 1 E-W GEOPHYSICS LINE 12725 40 20 M,R,T 1 2 2 BN T,LH U 1 12726 45 15 M,R,T 1 2 1 BN T,LH U 1 12727 50 25 M,R,T 1 2 1 BK T,LH U 1 12728 55 20 M,R,T 1 2 1 BK T,LH U 1 12729 60 23 M,R,T 1 2 1 BK T,LH U 1 N-S CLAIM LINE 12730 70 30 M,R,T 1 2 1 BK T,LH 0 1 EDGE OF DRILL TRACK 12731 80 21 M,R,T 1 2 1 BN T,LH U 1 EDGE OF DRILL TRACK 12732 90 20 M,R,T 1 2 1 BN T,LH U 1 12733 100 10 M,R,T 1 2 1 BK T,FH U 1 12734 100 10 M,R,T 1 3 1 BK T,FH U 1 12735 110 8 M,R,A 1 3 1 BK A,FH U 1 ROCK AT BASE OF HOLE 12736 120 8 M,R,A 2 3 1 BK A,FH U 1 9M TO GEOPH. LINE

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS) AT LAMOTHE

SHOWING 5 LINE 1....BASE OF ORGANICS

AU AG AS BA

PPB PPM PPM PPM

(HUMUS):: CU

PPM BR

PPM 12701 0 0 -2 7 290 45 39 12702 10 0 -2 2 150 10 10 12703 20 2 -2 2 280 30 8 12704 30 1 -2 4 180 28 6 12705 35 0 -2 2 150 8 4 12706 40 1 -2 3 160 14 6 12707 45 0 -2 2 220 10 4 12708 50 0 -2 2 100 6 8 12709 55 2 -2 2 0 9 5 12710 60 2 -2 3 120 20 7 12711 60 3 -2 3 130 16 4 12712 65 2 -2 2 120 10 4 12713 70 1 -2 3 170 21 5 12714 80 0 -2 2 0 8 4 12715 90 1 -2 3 0 7 7 12716 100 1 -2 3 0 10 9 12717 110 0 -2 3 130 11 10 12718 120 0 -2 3 100 13 7

SHOWING 5 LINE 2....BASE OF ORGANICS (HUMUS) SAMPLE LINE AU AG AS BA CU BR NUMBER POSITION PPB PPM PPM PPM PPM PPM 12719 0 1 -2 1 0 7 12 12720 10 0 -2 0 130 5 5 12721 20 1 -2 4 120 8 7 12722 30 0 -2 3 120 6 6 12723 35 0 -2 4 120 7 9 12724 35 2 -2 4 120 9 12725 40 1 -2 4 0 8 7 12726 45 0 -2 3 100 10 5 12727 50 1 -2 2 110 7 4 12728 55 0 -2 2 0 8 7 12729 60 2 -2 3 0 4 7 12730 70 0 2 3 170 35 7 12731 80 1 -2 2 0 7 5 12732 90 1 3 4 0 7 7 12733 100 0 -2 7 160 14 13 12734 100 1 -2 4 150 12 11 12735 110 1 -2 2 110 9 5 12736 120 0 -2 2 210 9 5

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

CA CO PPM

AT LAMOTHE

CR PPM

CS PPM

FE FE*10

12701 0 2.4 40 21 0.8 5.24 52.4 12702 10 -0.1 -1 6 -0.5 0.26 2.6 12703 20 -0.2 7 44 1.1 1.3 13 12704 30 0.5 2 8 0.6 0.28 2.8 12705 35 -0.1 3 11 -0.5 0.23 2.3 12706 40 -0.1 2 14 0.7 0.3 3 12707 45 -0.1 2 8 -0.5 0.19 1.9 12708 50 -0.1 1 4 -0.5 0.13 1.3 12709 55 0.4 -1 3 -0.5 0.09 0.9 12710 60 -0.1 2 14 -0.5 0.34 3.4 12711 60 -0.1 1 7 -0.5 0.25 2.5 12712 65 -0.1 2 60 -0.5 0.34 3.4 12713 70 0.4 2 9 -0.5 0.35 3.5 12714 80 0.4 1 6 -0.5 0.15 1.5 12715 90 -0.1 1 4 -0.5 0.13 1.3 12716 100 -0.1 1 5 -0.5 0.13 1.3 12717 110 -0.1 3 14 0.5 0.38 3.8 12718 120 -0.1 1 8 -0.5 0.24 2.4

SAMPLE NUMBER

LINE POSITION

CA %

CO PPM

CR PPM

CS PPM

FE FE*10

12719 0 2 -1 2 -0.5 0.17 1.7 12720 10 -0.1 1 4 -0.5 0.25 2.5 12721 20 -0.1 2 7 -0.5 0.17 1.7 12722 30 -0.1 1 3 -0.5 0.13 1.3 12723 35 0.6 4 2 -0.5 0.08 0.8 12724 35 -0.1 2 3 -0.5 0.14 1.4 12725 40 -0.1 1 5 -0.5 0.14 1.4 12726 45 0.5 1 5 -0.5 0.16 1.6 12727 50 -0.1 1 3 -0.5 0.11 1.1 12728 55 -0.1 2 3 -0.5 0.1 1 12729 60 -0.1 -1 2 -0.5 0.07 0.7 12730 70 -0.1 3 8 -0.5 0.44 4.4 12731 80 0.3 -1 3 -0.5 0.09 0.9 12732 90 -0.1 2 4 -0.5 0.23 2.3 12733 100 -0.2 2 18 0.7 0.59 5.9 12734 100 0.6 2 74 0.6 0.57 5.7 12735 110 -0.1 1 7 -0.5 0.21 2.1 12736 120 -0.1 1 12 -0.5 0.24 2.4

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

HF HG

PPM PPM

AT LAMOTHE

IR PPB

MO PPM

NA PPM

NA/10 PPM

12701 0 -0.5 -0.5 -5 -0.5 2170 217 12702 10 1.2 -0.5 -5 0.7 3870 387 12703 20 2.1 -0.5 -5 -0.5 5890 589 12704 30 0.7 -0.5 -5 -0.5 1280 128 12705 35 1.2 -0.5 -5 0.9 2680 268 12706 40 1.2 -0.5 -5 -0.5 2940 294 12707 45 1.1 -0.5 -5 -0.5 2080 208 12708 50 0.8 -0.5 -5 -0.5 1510 151 12709 55 -0.5 -0.5 -5 -0.5 654 65.4 12710 60 0.9 -0.5 -5 -0.5 1950 195 12711 60 -0.5 -0.5 -5 0.6 1060 106 12712 65 0.8 -0.5 -5 -0.5 2290 229 12713 70 1.9 -0.5 -5 -0.5 3640 364 12714 80 0.5 -0.5 -5 -0.5 1140 114 12715 90 -0.5 -0.5 -5 -0.5 766 76.6 12716 100 -0.5 -0.5 -5 1 620 62 12717 110 1.9 -0.5 -5 1.5 3010 301 12718 120 1.2 -0.5 -5 -0.5 2000 200

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

MO PPM

NA PPM

NA/10 PPM

12719 0 -0.5 -0.5 -5 1.3 290 29 12720 10 0.9 -0.5 -5 -0.5 4870 487 12721 20 1.1 -0.5 -5 -0.5 1740 174 12722 30 0.6 -0.5 -5 -0.5 964 96.4 12723 35 -0.5 -0.5 -5 -0.5 239 23.9 12724 35 -0.5 -0.5 -5 -0.5 491 49.1 12725 40 0.5 -0.5 -5 -0.5 571 57.1 12726 45 -0.5 -0.5 -5 -0.5 1010 101 12727 50 0.6 -0.5 -5 -0.5 1620 162 12728 55 -0.5 -0.5 -5 -0.5 349 34.9 12729 60 -0.5 -0.5 -5 -0.5 388 38.8 12730 70 0.6 -0.5 -5 -0.5 1180 118 12731 80 -0.5 -0.5 -5 -0.5 441 44.1 12732 90 -0.5 -0.5 -5 -0.5 1090 109 12733 100 2.8 -0.5 -5 -0.5 5590 559 12734 100 1.4 -0.5 -5 -0.5 3750 375 12735 110 1.1 -0.5 -5 -0.5 2550 255 12736 120 2.7 -0.5 -5 -0.5 4510 451

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

NI RB

PPM PPM

AT LAMOTHE

SB PPM

SC PPM

SE PPM

SR PPM

12701 0 -10 -20 0.3 4.1 -2 -100 12702 10 -10 -20 0.1 1.1 -2 -100 12703 20 -10 28 -0.1 4.1 -2 -100 12704 30 -10 -20 0.4 1.5 -2 -100 12705 35 -10 -20 0.4 1.2 -2 -100 12706 40 -10 -20 0.6 1.7 -2 -100 12707 45 -10 -20 0.4 1.1 -2 -100 12708 50 -10 -20 0.2 0.9 -2 -100 12709 55 -10 -20 0.6 0.4 -2 -100 12710 60 -10 -20 0.7 1.5 -2 -100 12711 60 -10 -20 0.6 1.3 -2 -100 12712 65 -10 -20 0.6 1 -2 -100 12713 70 -10 -20 0.4 1.8 -2 -100 12714 80 -10 -20 0.5 0.8 -2 120 12715 90 -10 -20 0.6 0.5 -2 -100 12716 100 -10 -20 0.7 0.6 -2 -100 12717 110 -10 -20 0.7 1.7 -2 -100 12718 120 -10 -20 0.8 1.2 -2 -100

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SE PPM

SR PPM

12719 0 -10 -20 0.1 0.4 -2 -100 12720 10 -10 -20 -0.1 0.5 -2 -100 12721 20 -10 -20 0.6 0.9 -2 -100 12722 30 -10 -20 0.7 0.6 -2 -100 12723 35 -10 -20 0.5 0.3 -2 -100 12724 35 -10 -20 0.7 0.6 -2 -100 12725 40 -10 -20 0.9 0.6 -2 -100 12726 45 -10 -20 0.9 0.8 -2 -100 12727 50 -10 -20 0.4 0.7 -2 -100 12728 55 -10 -20 0.2 0.5 -2 -100 12729 60 -10 -20 0.2 0.3 -2 -100 12730 70 -10 -20 0.2 1.6 -2 -100 12731 80 -10 -20 0.5 0.4 -2 -100 12732 90 -10 -20 0.4 1.2 -2 -100 12733 100 -10 -20 0.4 2.6 -2 -100 12734 100 -10 -20 0.4 2.1 -2 -100 12735 110 -10 -20 0.6 0.9 -2 -100 12736 120 -10 -20 0.4 1.2 -2 -100

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

TA TH

PPM PPM

AT LAMOTHE

U PPM

W PPM

ZN PPM

LA PPM

12701 0 -0.5 1.9 5.2 -1 95 44 12702 10 -0.5 1.3 0.4 -1 27 4.8 12703 20 -0.5 2 0.9 -1 27 17 12704 30 -0.5 1.2 0.3 -1 28 8.9 12705 35 -0.5 0.6 0.2 -1 29 4.1 12706 40 -0.5 0.7 0.3 -1 41 6 12707 45 -0.5 0.6 0 -1 45 4.6 12708 50 -0.5 -0.5 0.2 -1 32 2.9 12709 55 -0.5 -0.5 0 -1 95 1.4 12710 60 -0.5 0.7 0 -1 76 6 12711 60 -0.5 0.7 0.2 -1 53 5.1 12712 65 -0.5 0.5 0 -1 56 3.9 12713 70 -0.5 1 0.4 -1 55 6.2 12714 80 -0.5 -0.5 0 -1 46 3.1 12715 90 -0.5 -0.5 0 -1 57 1.8 12716 100 -0.5 -0.5 0 -1 51 2.2 12717 110 -0.5 1.2 0 -1 58 7.5 12718 120 -0.5 0.6 0.3 -1 81 3.5

SAMPLE NUMBER

LINE POSITION

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

LA PPM

12719 0 -0.5 -0.5 0.2 -1 34 3 12720 10 -0.5 -0.5 0.4 -1 79 2 12721 20 -0.5 0.7 0 -1 55 3.4 12722 30 -0.5 -0.5 0.2 -1 61 2.3 12723 35 -0.5 -0.5 0 -1 92 2.6 12724 35 -0.5 -0.5 0 -1 72 2.3 12725 40 -0.5 -0.5 0.2 -1 62 2.8 12726 45 -0.5 -0.5 0.2 -1 76 2.4 12727 50 -0.5 0.5 0 -1 55 3.5 12728 55 -0.5 -0.5 0 -1 54 2.4 12729 60 -0.5 -0.5 0 -1 51 1.1 12730 70 -0.5 0.5 0 -1 24 8.5 12731 80 -0.5 -0.5 0.1 -1 57 1.6 12732 90 -0.5 0.6 0 -1 34 3.7 12733 100 -0.5 1.9 0.7 -1 34 9.5 12734 100 -0.5 1.1 0 -1 25 7 12735 110 -0.5 0.9 0.3 -1 38 3.7 12736 120 -0.5 0.9 0.2 -1 36 5.4

T SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF

CE PPM

ORGANICS) AT

ND PPM

LAMOTHE

SM PPM

EU PPM

TB PPM

YB PPM

12701 0 31 19 3.6 0.6 -0.2 0.9 12702 10 5 -3 0.5 -0.2 -0.2 0.3 12703 20 17 11 1.6 0.3 -0.2 0.7 12704 30 10 4 0.8 -0.2 -0.2 0.3 12705 35 5 4 0.5 -0.2 -0.2 0.2 12706 40 7 -3 0.6 -0.2 -0.2 0.2 12707 45 4 -3 0.4 -0.2 -0.2 0.2 12708 50 4 -3 0.3 -0.2 -0.2 0.1 12709 55 2 -3 0.2 -0.2 -0.2 -0.1 12710 60 8 3 0.7 -0.2 -0.2 0.3 12711 60 6 4 0.6 -0.2 -0.2 0.2 12712 65 5 -3 0.4 -0.2 -0.2 0.2 12713 70 7 4 0.6 -0.2 -0.2 0.3 12714 80 4 3 0.3 -0.2 -0.2 0.1 12715 90 2 -3 0.2 -0.2 -0.2 -0.1 12716 100 3 -3 0.3 -0.2 -0.2 0.2 12717 110 8 6 0.8 -0.2 -0.2 0.4 12718 120 4 3 0.4 -0.2 -0.2 0.3

SAMPLE NUMBER

LINE POSITION

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

YB PPM

12719 0 3 -3 0.3 -0.2 -0.2 0.1 12720 10 3 -3 0.2 -0.2 -0.2 0.2 12721 20 4 -3 0.4 -0.2 -0.2 0.2 12722 30 3 -3 0.3 -0.2 -0.2 0.2 12723 35 2 -3 0.2 -0.2 -0.2 -0.1 12724 35 3 -3 0.3 -0.2 -0.2 0.1 12725 40 4 -3 0.3 -0.2 -0.2 0.1 12726 45 3 -3 0.3 -0.2 -0.2 0.1 12727 50 4 -3 0.3 -0.2 -0.2 0.2 12728 55 2 -3 0.3 -0.2 -0.2 -0.1 12729 60 -1 -3 0.2 -0.2 -0.2 -0.1 12730 70 10 5 0.8 -0.2 -0.2 0.2 12731 80 2 -3 0.2 -0.2 -0.2 0.1 12732 90 4 -3 0.4 -0.2 -0.2 0.1 12733 100 10 5 0.9 -0.2 -0.2 0.5 12734 100 8 4 0.8 -0.2 -0.2 0.3 12735 110 5 -3 0.4 -0.2 -0.2 0.2 12736 120 6 -3 0.6 -0.2 -0.2 0.4

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

LU Mass

PPM g 12701 0 0.1 30 12702 10 -0.1 30 12703 20 0.1 30 12704 30 -0.1 30 12705 35 -0.1 30 12706 40 -0.1 30 12707 45 -0.1 30 12708 50 -0.1 30 12709 55 -0.1 30 12710 60 -0.1 30 12711 60 -0.1 30 12712 65 -0.1 30 12713 70 -0.1 30 12714 80 -0.1 30 12715 90 -0.1 30 12716 100 -0.1 30 12717 110 -0.1 30 12718 120 -0.1 30

-

-

AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

LU PPM

Mass g

12719 0 -0.1 30 12720 10 -0.1 30 12721 20 -0.1 30 12722 30 -0.1 30 12723 35 -0.1 30 12724 35 -0.1 30 12725 40 -0.1 30 12726 45 -0.1 30 12727 50 -0.1 30 12728 55 -0.1 30 12729 60 -0.1 30 12730 70 -0.1 30 12731 80 -0.1 30 12732 90 -0.1 30 12733 100 -0.1 30 12734 100 -0.1 30 12735 110 -0.1 30 12736 120 -0.1 30

SAMP. NO.

LINE SAMP. POS. DEPTH

STRAT. W F M C GEO SL D REMARKS

12737 0 35 M,R,T 1 2 2 BK T,LH U 1 ^ 12738 10 15 M,R,T 1 3 1 BN T,LH U 1

12739 20 20 M,R,T 1 2 1 BN T,LH 0 1 12740 20 18 M,R,T 1 3 1 BN T,LH 0 1 DUPLICATE

- 12741 30 18 M,R,T 1 2 1 BN T,LH 0 1 12742 35 15 M,R,T 2 2 1 BK T,LH D 1 12743 40 20 M,R,T 1 2 1 BK T,LH D 1

•- 12744 45 18 M,R,P 1 1 1 BK P,OH 0 1 12745 50 18 M,R,T 1 2 1 BN T,LH U 1 12746 55 35 M,R,P 1 1 1 BK P,LH 0 1

- 12747 60 20 M,R,T 1 2 1 BN P,LH U 1 12748 60 30 M,R,T 1 2 2 BN P,LH U 1 DUPLICATE 12749 65 26 M,R,T 1 2 1 BN P,LH 0 1

_. 12750 70 40 M,R,T 1 1 1 BK T,OH 0 1 12751 75 20 M,R,T 1 2 1 BN T,LH 0 1 12752 80 15 M,R,T 1 1 1 BK T,OH U 1

. 12753 85 20 M,R,P 1 3 2 BN T,LH 0 1 12754 90 30 M,R,T 1 2 1 BN T,LH D 1 15M TO CREEK

- SAMP. NO.

LINE SAMP. POS. DEPTH

STRAT. W F M C GEO SL D REMARKS

12755 0 35 M,R,T 2 1 1 BK T,OH 0 2 - 12756 10 25 M,R,T 1 1 1 BK T,OH 0 2

12757 20 20 M,R,G 1. 2 1 BN T,OH 0 1 12758 30 35 M,R,T 3 1 1 BK T,OH 0 2

- 12759 35 30 S,R,T 3 1 1 BK T,OH 0 2 12760 40 35 M,R,T 3 1 1 BK T,OH 0 2 12761 45 35 M,R 3 1 1 BK T,OH 0 2 NO BASE TO HUMUS

- 12762 50 30 M,R 2 1 1 BK T,OH U 2 DITTO 12763 50 40 M,R 2 1 1 BK T,OH U 2 DITTO 12764 55 25 M,R,T 1 2 1 BK T,OH U 1 STRIKE PROJ OF SHEAR 12765 60 15 M,R,G 1 2 2 BN T,LF U 1 12766 65 12 M,R,G 1 2 2 BN T,LF 0 1 12767 70 13 M,R,G 1 2 1 BN T,LF D 1 12768 75 15 M,R,T 1 2 1 BN T,OH D 1 COBBLE TILL 12769 80 20 M,R,T 2 1 1 BK T,OH D 1 ROCKS, NO SANDY TILL 12770 90 30 M,R 2 1 1 BK T,OH D 1 NO BASE TO HUMUS

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS) AT LAMOTHE

SHOWING 5 LINE 3....BASE OF ORGANICS

AU AG AS BA

PPB PPM PPM PPM

(HUMUS).: CU

PPM BR

PPM 12737 0 2 -2 3 210 24 8 12738 10 0 -2 2 210 11 7 12739 20 1 -2 4 0 8 12740 20 2 -2 3 200 8 6 12741 30 2 -2 3 180 10 8 12742 35 1 -2 2 190 7 6 12743 40 2 -2 2 300 14 7 12744 45 1 -2 2 220 11 5 12745 50 2 -2 3 180 14 6 12746 55 0 -2 2 0 9 6 12747 60 1 -2 3 150 9 8 12748 60 3 -2 3 110 9 7 12749 65 1 -2 1 110 13 10 12750 70 2 -2 1 120 7 13 12751 75 1 -2 2 210 16 7 12752 80 0 -2 2 170 13 14 12753 85 1 -2 3 180 23 5 12754 90 0 -2 1 0 7 6

SAMPLE NUMBER

LINE POSITION

SHOWING 5 AU

PPB

LINE 4....BASE OF ORGANICS

AG AS BA

PPM PPM PPM

(HUMUS) CU

PPM BR PPM

12755 0 1 -2 0 190 15 22 12756 10 0 -2 2 110 12 13 12757 20 2 -2 3 0 8 6 12758 30 2 -2 1 100 48 12759 35 16 -2 2 170 420 43 12760 40 5 -2 2 230 210 35 12761 45 5 -2 1 120 130 44 12762 50 9 -2 2 130 120 29 12763 50 4 -2 2 160 105 50 12764 55 1 -2 2 110 31 23 12765 60 3 -2 2 250 9 10 12766 65 3 -2 2 120 15 5 12767 70 1 -2 4 180 8 11 12768 75 10 -2 1 230 8 6 12769 80 10 -2 2 140 55 23 12770 90 19 -2 0 300 190 19

-

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

CA CO PPM

AT LAMOTHE

CR PPM

CS PPM

FE %

FE*10 %

12737 0 -0.1 1 10 -0.5 0.2 2 12738 10 -0.1 -1 8 -0.5 0.16 1.6 12739 20 -0.1 1 5 -0.5 0.13 1.3 12740 20 0.7 1 13 -0.5 0.26 2.6 12741 30 0.4 1 7 -0.5 0.15 1.5 12742 35 -0.1 1 14 -0.5 0.23 2.3 12743 40 -0.1 3 13 -0.5 0.43 4.3 12744 45 -0.1 2 19 -0.5 0.47 4.7 12745 50 -0.1 1 6 -0.5 0.14 1.4 12746 55 -0.1 1 5 -0.5 0.19 1.9 12747 60 0.3 -1 6 -0.5 0.16 1.6 12748 60 -0.1 1 13 -0.5 0.22 2.2 12749 65 -0.1 2 6 -0.5 0.2 2 12750 70 1 2 5 -0.5 0.18 1.8 12751 75 0.5 2 18 0.6 0.33 3.3 12752 80 -0.1 3 11 -0.5 0.38 3.8 12753 85 -0.1 1 16 0.7 0.25 2.5 12754 90 0.4 2 9 -0.5 0.14 1.4

SAMPLE LINE CA CO CR CS FE FE*10 NUMBER POSITION % PPM PPM PPM % % 12755 0 -0.2 4 62 0.6 0.81 8.1 12756 10 -0.1 2 11 -0.5 0.44 4.4 12757 20 0.5 -1 3 -0.5 0.11 1.1 12758 30 2.3 2 29 -0.5 0.29 2.9 12759 35 4.4 12 47 -0.5 0.87 8.7 12760 40 2.3 4 48 -0.5 0.5 5 12761 45 2.3 5 28 1 1.11 11.1 12762 50 3.1 4 40 -0.5 1.9 19 12763 50 2 19 49 0.9 5.76 57.6 12764 55 1.4 2 16 -0.5 0.82 8.2 12765 60 0.9 -1 28 -0.5 0.56 5.6 12766 65 -0.1 -1 11 -0.5 0.23 2.3 12767 70 -0.2 -1 8 1.3 0.47 4.7 12768 75 -0.3 3 33 0.9 0.93 9.3 12769 80 1.4 5 28 0.8 1.11 11.1 12770 90 1.3 6 68 1.4 1.31 13.1

-- SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

HF HG

PPM PPM

AT LAMOTHE

IR PPB

MO PPM

NA PPM

NA/10 PPM

12737 0 2.2 -0.5 -5 0.9 3240 324 12738 10 1.7 -0.5 -5 -0.5 1580 158 12739 20 0.6 -0.5 -5 -0.5 796 79.6 12740 20 1.2 -0.5 -5 -0.5 3100 310 12741 30 1 -0.5 -5 0.7 1470 147 12742 35 1.7 -0.5 -5 -0.5 3420 342 12743 40 1.3 -0.5 -5 -0.5 3040 304 12744 45 2.3 -0.5 -5 -0.5 6210 621 12745 50 0.8 -0.5 -5 -0.5 994 99.4 12746 55 -0.5 -0.5 -5 -0.5 922 92.2 12747 60 0.6 -0.5 -5 0.8 1300 130 12748 60 1 -0.5 -5 -0.5 3070 307 12749 65 -0.5 -0.5 -5 0.8 1520 152 12750 70 -0.5 -0.5 -5 0.8 713 71.3 12751 75 1.2 -0.5 -5 2 3970 397 12752 80 0.6 -0.5 -5 -0.5 2260 226 12753 85 1.5 -0.5 -5 0.9 2760 276 12754 90 0.8 -0.5 -5 -0.5 1960 196

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

MO PPM

NA PPM

NA/100 PPM

12755 0 1.8 -0.5 -5 1.4 6600 66 12756 10 0.6 -0.5 -5 -0.5 2100 21 12757 20 -0.5 -0.5 -5 0.8 887 8.87 12758 30 -0.5 -0.5 -5 -0.5 747 7.47 12759 35 -0.5 -0.5 -5 -0.5 1920 19.2 12760 40 0.6 -0.5 -5 -0.5 1420 14.2 12761 45 0.6 -0.5 -5 -0.5 1450 14.5 12762 50 1.2 -0.5 -5 -0.5 2410 24.1 12763 50 1.2 -0.5 -5 -0.5 1650 16.5 12764 55 1 -0.5 -5 2.1 2930 29.3 12765 60 4.8 -0.5 -5 0.7 8960 89.6 12766 65 2.3 -0.5 -5 -0.5 6700 67 12767 70 1.4 -0.5 -5 -0.5 10700 107 12768 75 6.7 -0.5 -5 -0.5 16800 168 12769 80 1 -0.5 -5 -0.5 2060 20.6 12770 90 3.3 -0.5 -5 -0.5 7140 71.4

--

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

NI RB

PPM PPM

AT LAMOTHE

SB PPM

SC PPM

SE PPM

SR PPM

12737 0 -10 -20 0.3 1.1 -2 -100 12738 10 -10 -20 0.3 1.3 -2 -100 12739 20 -10 -20 0.6 0.5 -2 -100 12740 20 -10 -20 0.5 1.3 -2 -100 12741 30 -10 -20 0.3 0.8 -2 -100 12742 35 -10 -20 0.4 1.3 -2 -100 12743 40 -10 -20 0.2 2.1 -2 -100 12744 45 -10 20 0.3 2.8 -2 -100 12745 50 -10 -20 0.3 0.8 -2 -100 12746 55 -10 -20 0.3 1 -2 -100 12747 60 -10 -20 0.3 0.9 -2 -100 12748 60 -10 -20 0.6 1 -2 -100 12749 65 -10 -20 0.1 1.1 -2 -100 12750 70 -10 -20 0.2 1.2 -2 -100 12751 75 -10 -20 0.4 2 -2 -100 12752 80 -10 -20 0.2 2.3 -2 -100 12753 85 -10 -20 0.4 1.9 -2 -100 12754 90 -10 -20 -0.1 0.8 -2 -100

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SE PPM

SR PPM

12755 0 -10 27 0.1 6.3 -2 -100 12756 10 -10 -20 0.1 2.6 -2 -100 12757 20 -10 -20 0.6 0.4 -2 -100 12758 30 -10 -20 0.1 8.8 -2 -100 12759 35 -13 -20 0.2 7.7 -2 -100 12760 40 -15 -20 0.2 16 -2 -100 12761 45 19 -20 0.2 7.4 -2 -100 12762 50 -13 -20 0.1 13 -2 -100 12763 50 -14 -20 -0.1 11 -2 -100 12764 55 -10 -20 0.2 4.8 -2 -100 12765 60 -11 -20 0.2 3.3 -2 -100 12766 65 -10 -20 0.2 1.6 -2 -100 12767 70 -11 -20 0.4 1.6 -2 -100 12768 75 -14 38 0.2 5.6 -2 -100 12769 80 -10 -20 0.2 6 -2 -100 12770 90 -14 26 0.2 16 -2 -100

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

TA TH

PPM PPM

AT LAMOTHE

U PPM

W PPM

ZN PPM

LA PPM

12737 0 -0.5 1.1 0.2 -1 64 5.8 12738 10 -0.5 1 0.3 -1 57 6 12739 20 -0.5 -0.5 0.2 -1 82 2 12740 20 -0.5 0.8 0.3 -1 54 4 12741 30 -0.5 0.7 0 -1 46 3.3 12742 35 -0.5 0.8 0 -1 41 4.3 12743 40 -0.5 1 0.4 -1 41 8 12744 45 -0.5 1.4 0.3 -1 59 8 12745 50 -0.5 0.7 0.2 -1 74 3.3 12746 55 -0.5 -0.5 0.2 -1 46 3.9 12747 60 -0.5 -0.5 0 -1 60 2.7 12748 60 -0.5 0.5 0 -1 85 3.1 12749 65 -0.5 0.6 0.4 -1 39 4.5 12750 70 -0.5 0.7 0.3 -1 36 3.6 12751 75 -0.5 1.1 0 -1 55 6.8 12752 80 -0.5 1.1 0.5 -1 31 7.8 12753 85 -0.5 2.2 0.4 -1 55 8.7 12754 90 -0.5 -0.5 0 -1 35 1.9

SAMPLE NUMBER

LINE POSITION

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

LA PPM

12755 0 -0.5 2.8 1 -1 24 17 12756 10 -0.5 1.2 0.6 -1 56 8.3 12757 20 -0.5 -0.5 0 -1 75 1.9 12758 30 -0.5 2.4 4.9 -1 62 80 12759 35 -0.5 2.4 14 -1 160 100 12760 40 -0.5 5.1 8 -1 49 130 12761 45 -0.5 3.1 3.4 -1 47 59 12762 50 -0.5 4.8 5.6 -1 70 81 12763 50 -0.5 4.4 5.7 -1 62 86 12764 55 0.8 1.4 1.4 -1 55 14 12765 60 -0.5 2 0.8 -1 46 12 12766 65 -0.5 1.3 0.3 -1 43 5.6 12767 70 -0.5 0.9 0.7 -1 57 5.4 12768 75 -0.5 3 1.3 -1 0 25 12769 80 -0.5 3.1 2.7 -1 52 48 12770 90 -0.5 7.7 6.4 -1 51 93

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

CE ND

PPM PPM

AT LAMOTHE

SM PPM

EU PPM

TB PPM

YB PPM

12737 0 6 4 0.6 -0.2 -0.2 0.4 12738 10 7 5 0.6 -0.2 -0.2 0.3 12739 20 3 -3 0.3 -0.2 -0.2 0.1 12740 20 5 -3 0.5 -0.2 -0.2 0.3 12741 30 3 -3 0.4 -0.2 -0.2 0.2 12742 35 5 -3 0.5 -0.2 -0.2 0.3 12743 40 9 5 0.8 -0.2 -0.2 0.3 12744 45 9 -3 0.9 -0.2 -0.2 0.5 12745 50 4 -3 0.4 -0.2 -0.2 0.2 12746 55 5 -3 0.4 -0.2 -0.2 0.2 12747 60 3 -3 0.3 -0.2 -0.2 0.2 12748 60 3 -3 0.4 -0.2 -0.2 0.2 12749 65 5 4 0.5 -0.2 -0.2 0.2 12750 70 4 4 0.4 -0.2 -0.2 0.2 12751 75 7 5 0.8 -0.2 -0.2 0.3 12752 80 8 4 0.8 -0.2 -0.2 0.3 12753 85 10 5 0.9 -0.2 -0.2 0.4 12754 90 3 -3 0.2 -0.2 -0.2 0.1

SAMPLE NUMBER

LINE POSITION

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

YB PPM

12755 0 18 9 1.8 0.4 -0.2 0.6 12756 10 9 5 0.8 -0.2 -0.2 0.3 12757 20 2 -3 0.2 -0.2 -0.2 0.1 12758 30 55 53 8 1.6 0.8 2.3 12759 35 45 61 11 1.9 0.8 2.1 12760 40 77 71 17 2.9 1.6 4.1 12761 45 37 24 6.6 1.2 0.4 1.7 12762 50 52 38 9 1.7 0.8 2 12763 50 60 50 10 1.9 0.9 2.3 12764 55 13 4 1.5 0.3 -0.2 0.4 12765 60 11 4 1.2 0.3 -0.2 0.7 12766 65 6 4 0.6 -0.2 -0.2 0.4 12767 70 4 5 0.6 -0.2 -0.2 0.3 12768 75 28 16 2.1 0.5 -0.2 1 12769 80 36 24 5.3 1 -0.2 1.1 12770 90 70 55 13 2.1 -0.2 2.6

SAMPLING OF HUMUS

SAMPLE LINE NUMBER POSITION

(BASE OF ORGANICS)

LU Mass

PPM g 12737 0 -0.1 30 12738 10 -0.1 30 12739 20 -0.1 24.07 12740 20 -0.1 30 12741 30 -0.1 30 12742 35 -0.1 30 12743 40 -0.1 30 12744 45 -0.1 30 12745 50 -0.1 30 12746 55 -0.1 30 12747 60 -0.1 30 12748 60 -0.1 30 12749 65 -0.1 30 12750 70 -0.1 30 12751 75 -0.1 30 12752 80 -0.1 30 12753 85 -0.1 30 12754 90 -0.1 30

SAMPLE NUMBER

LINE POSITION

LU PPM

Mass g

12755 0 -0.1 30 12756 10 -0.1 30 12757 20 -0.1 30 12758 30 0.4 30 12759 35 0.4 30 12760 40 0.7 30 12761 45 0.3 30 12762 50 0.4 30 12763 50 0.4 30 12764 55 -0.1 30 12765 60 0.1 30 12766 65 -0.1 30 12767 70 -0.1 30 12768 75 0.1 30 12769 80 0.2 30 12770 90 0.5 30

AT LAMOTHE

APPENDIX 2

ANALYTICAL DATA FOR BARK

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

AUGUST 1990 M. WARD, L. ARDOUIN

ANALYSIS OF DRIED, UNASHED SAMPLE (LAB PACKAGE 2B)

ANALYSED BY AC [NATION LABORATORIES,ANCASTER,ONT WORK ORDER 2038, INVOICE 2064

VALUES LESS THAN DETECTION LIMIT MAY BE SET TO ZERO

DETECTION LIMITS (PPM EXCEPT WHERE SHOWN) : AU AG AS BA BR CA CO

0.1 PPB 0.2 0.01 5 0.01 0.01 % 0.1

CR CS FE HF HG IR K 0.3 0.05 0.05 % 0.05 0.05 0.1 0.01 %

MO NA NI RB SB SC SE 0.05 1 2 1 0.005 0.01 0.1

SR TA TH U W ZN LA 10 0.05 0.1 0.01 0.05 2 0.01

CE ND SM EU TB YB LU 0.1 0.3 0.001 0.05 0.1 0.005 0.001

SAMP. LINE DIA DIA DEN REMARKS NO. POS. #1 #2 12978 0 10 12 1 2 3M N OF LINE 7S 12979 10 8 71 2 12980 10 10 12 1 1 DUPLICATE 12981 20 7 12 1 1 12982 30 15 1 1 ONE TREE 12983 35 15 10 1 1 12984 40 15 1 2 LARGE SAMP. 12985 45 12 81 2 12986 50 8 12 2 2 EDGE OF CREEK WITH SHEAR 12987 50 10 11 2 2 DUPLICATE 12988 55 15 9 1 2 LARGE SAMP. 12989 60 14 6 1 2 SMALL SAMP. 12990 65 11 1 2 12991 70 8 10 1 2 12992 80 8 11 1 2 12993 90 8 12 1 2 12994 100 10 12 1 2 LARGE SAMP.

SAMP. LINE DIA DIA DEN REMARKS NO. POS. #1 #2 12995 0 8 81 1 12996 10 8 10 1 3 12997 20 10 12 3 2 MELEZE & BOULEAU ADJ 12998 30 10 14 3 3 MELEZE & CEDER 12999 35 10 12 2 2 DITTO 13000 40 10 11 2 2 DITTO 12801 45 13 8 2 2 MELEZE 12802 50 8 12 2 3 STRIKE PROJ OF SHEAR 12803 55 10 81 2 12804 60 11 10 1 2 12805 70 8 10 1 2 12806 80 8 72 2 12807 90 8 13 2 2 ALDERS

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

SHOWING 2 LINE 1....ECORCE DE EPINETTE NOIR

AU AG AS BA BR

PPB PPM PPM PPM PPM BR/10 PPM

12978 0 0.5 -0.3 0.46 65 14 1.4 12979 10 0.6 -0.3 0.28 88 13 1.3 12980 10 0.9 -0.3 0.39 62 13 1.3 12981 20 0.3 -0.3 0.24 89 11 1.1 12982 30 0.4 -0.3 0.15 110 4.8 0.48 12983 35 0.4 -0.3 0.22 63 6.4 0.64 12984 40 0.3 -0.3 0.27 58 8.4 0.84 12985 45 0.5 -0.3 0.19 51 8.2 0.82 12986 50 0.5 -0.3 0.18 110 9.2 0.92 12987 50 0.3 -0.3 0.23 130 10 1 12988 55 0.7 -0.3 0.36 120 12 1.2 12989 60 0.6 -0.3 0.4 84 11 1.1 12990 65 0.8 -0.3 0.44 82 13 1.3 12991 70 0.5 -0.3 0.53 43 12 1.2 12992 80 0.9 -0.3 0.63 110 13 1.3 12993 90 0.8 -0.3 0.37 110 12 1.2 12994 100 0.7 -0.3 0.42 92 11 1.1

SAMPLE NUMBER

LINE POSITION

SHOWING 2 AU

PPB

LINE 2....ECORCE DE

AG AS

PPM PPM

EPINETTE BA

PPM

NOIR BR

PPM BR/10

PPM 12995 0 0.6 -0.3 0.39 83 12 1.2 12996 10 0.8 -0.3 0.28 73 7.6 0.76 12997 20 0.6 -0.3 0.5 93 11 1.1 12998 30 0.8 -0.3 0.53 120 14 1.4 12999 35 21.3 -0.3 0.45 110 11 1.1 13000 40 9.6 -0.3 0.33 85 10 1 12801 45 0.8 -0.3 0.42 140 15 1.5 12802 50 1.4 -0.3 0.35 92 11 1.1 12803 55 1.5 -0.3 0.37 84 14 1.4 12804 60 1 -0.3 0.5 100 16 1.6 12805 70 1.2 -0.3 0.33 63 11 1.1 12806 80 0.8 -0.3 0.47 180 13 1.3 12807 90 1 -0.3 0.45 140 13 1.3

-

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

CA CO PPM

CR PPM

CS PPM

FE %

FE*10 %

12978 0 1.02 0.5 0.7 -0.05 0.023 0.23 12979 10 0.93 0.5 0.9 -0.05 0.028 0.28 12980 10 0.69 0.3 0.8 -0.05 0.019 0.19 12981 20 0.87 0.3 0.5 -0.05 0.02 0.2 12982 30 1.74 0.2 0.1 -0.05 0.011 0.11 12983 35 1.21 0.3 0.7 -0.05 0.018 0.18 12984 40 1.38 0.3 0.8 -0.05 0.021 0.21 12985 45 1.22 0.3 0.1 -0.05 0.013 0.13 12986 50 0.86 0.4 1.1 -0.05 0.022 0.22 12987 50 0.7 0.3 0.7 0.07 0.021 0.21 12988 55 1.34 0.4 0.9 -0.05 0.023 0.23 12989 60 0.77 0.4 0.8 -0.05 0.022 0.22 12990 65 0.87 0.4 0.5 -0.05 0.017 0.17 12991 70 0.81 0.4 0.6 -0.05 0.021 0.21 12992 80 1.21 0.5 0.7 -0.05 0.017 0.17 12993 90 0.58 0.4 0.7 -0.05 0.018 0.18 12994 100 0.9 0.4 0.7 -0.05 0.015 0.15

SAMPLE LINE CA CO CR CS FE FE*10 NUMBER POSITION % PPM PPM PPM % % 12995 0 0.71 0.4 0.8 -0.05 0.026 0.26 12996 10 0.97 0.2 0.5 -0.05 0.016 0.16 12997 20 1.03 0.4 0.1 -0.05 0.017 0.17 12998 30 0.88 0.4 0.9 -0.05 0.018 0.18 12999 35 0.86 0.4 0.6 -0.05 0.015 0.15 13000 40 0.8 0.3 0.6 -0.05 0.018 0.18 12801 45 1.13 0.5 0.8 -0.05 0.022 0.22 12802 50 1.06 0.4 0.1 -0.05 0.016 0.16 12803 55 0.89 0.5 0.9 -0.05 0.02 0.2 12804 60 1.95 0.6 0.7 -0.05 0.023 0.23 12805 70 1.14 0.5 0.9 -0.05 0.024 0.24 12806 80 1.34 0.5 0.7 0.08 0.026 0.26 12807 90 1.14 0.5 1 -0.05 0.022 0.22

--

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

HF HG

PPM PPM IR

PPB K

% MO

PPM NA

PPM 12978 0 -0.05 0.27 -0.1 0.02 -0.05 58.1 12979 10 0.05 0.37 -0.1 0.017 -0.05 79.8 12980 10 -0.05 0.22 -0.1 0.04 -0.05 45.6 12981 20 -0.05 0.27 -0.1 0.048 -0.05 45.2 12982 30 -0.05 0.07 -0.1 0.025 -0.05 28.3 12983 35 -0.05 0.08 -0.1 0.03 -0.05 37.3 12984 40 -0.05 0.15 -0.1 0.026 -0.05 43.9 12985 45 -0.05 0.13 -0.1 0.04 -0.05 33.5 12986 50 -0.05 0.28 -0.1 0.052 -0.05 55.2 12987 50 -0.05 0.3 -0.1 0.087 -0.05 47.1 12988 55 -0.05 0.23 -0.2 0.051 -0.05 69.8 12989 60 -0.05 0.36 -0.1 0.039 -0.05 55.7 12990 65 -0.05 0.32 -0.1 0.01 -0.05 39.1 12991 70 -0.05 0.24 -0.1 0.029 -0.05 42.8 12992 80 -0.05 0.28 -0.1 0.028 -0.05 40.6 12993 90 -0.05 0.26 -0.1 0.041 -0.05 40.3 12994 100 -0.05 0.15 -0.1 0.049 -0.05 35.8

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

K %

MO PPM

NA PPM

12995 0 -0.05 0.26 -0.1 0.034 -0.05 46 12996 10 -0.05 0.18 -0.1 0.036 -0.05 35.8 12997 20 -0.05 0.21 -0.1 0.021 -0.05 40 12998 30 0.05 0.22 -0.1 0.043 -0.05 42.6 12999 35 -0.05 0.2 -0.1 0.051 -0.05 37.3 13000 40 -0.05 0.25 -0.1 0.03 -0.05 40.8 12801 45 -0.05 0.32 -0.2 0.055 -0.05 53.1 12802 50 0.06 0.2 -0.2 0.048 -0.05 37.1 12803 55 -0.05 0.24 -0.2 0.034 -0.05 45 12804 60 -0.05 0.28 -0.2 0.054 -0.05 54.6 12805 70 -0.05 0.28 -0.2 0.048 -0.05 58.2 12806 80 -0.05 0.32 -0.2 0.07 -0.05 59.1 12807 90 -0.05 0.31 -0.2 0.051 -0.05 51.5

-

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

12978 0 -5 -1 0.069 0.06 0.6 -0.1 12979 10 -5 -1 0.068 0.07 0.7 -0.1 12980 10 -5 -1 0.065 0.04 0.4 -0.1 12981 20 -5 -1 0.049 0.04 0.4 0.3 12982 30 -5 1 0.029 0.02 0.2 -0.1 12983 35 -5 -1 0.042 0.04 0.4 0.2 12984 40 -5 -1 0.063 0.05 0.5 -0.1 12985 45 -5 -1 0.035 0.03 0.3 -0.1 12986 50 -5 -1 0.047 0.05 0.5 0.3 12987 50 -5 -1 0.05 0.04 0.4 -0.1 12988 55 -5 -1 0.057 0.07 0.7 0.4 12989 60 -5 1 0.061 0.04 0.4 0.1 12990 65 -5 -1 0.053 0.03 0.3 0.1 12991 70 -5 3 0.046 0.04 0.4 -0.1 12992 80 -5 -1 0.06 0.03 0.3 -0.1 12993 90 -5 -1 0.054 0.04 0.4 -0.1 12994 100 -5 -1 0.041 0.03 0.3 0.3

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SC*10 PPM

SE PPM

12995 0 -5 -1 0.056 0.04 0.4 0.5 12996 10 -5 -1 0.032 0.03 0.3 -0.1 12997 20 -5 2 0.057 0.03 0.3 0.3 12998 30 -5 -1 0.054 0.04 0.4 -0.1 12999 35 -5 -1 0.036 0.03 0.3 0.2 13000 40 -5 -1 0.049 0.04 0.4 -0.1 12801 45 -5 -1 0.06 0.05 0.5 0.2 12802 50 -5 -1 0.046 0.04 0.4 -0.1 12803 55 -5 -1 0.058 0.05 0.5 0.2 12804 60 -5 -1 0.056 0.05 0.5 0.3 12805 70 -5 -1 0.057 0.05 0.5 -0.1 12806 80 -5 3 0.081 0.06 0.6 0.3 12807 90 -5 -1 0.059 0.05 0.5 0.1

-- SAMPLE LINE NI RB SB SC SC*10 SE NUMBER POSITION PPM PPM PPM PPM PPM PPM

--

-

r

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

SR PPM

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

12978 0 -10 -0.05 -0.1 -0.01 -0.05 64 12979 10 -10 -0.05 -0.1 -0.01 -0.05 55 12980 10 -10 -0.05 -0.1 -0.01 -0.05 46 12981 20 -10 -0.05 -0.1 -0.01 -0.05 47 12982 30 22 -0.05 -0.1 -0.01 -0.05 67 12983 35 -10 -0.05 -0.1 -0.01 -0.05 62 12984 40 17 -0.05 -0.1 -0.01 -0.05 43 12985 45 -10 -0.05 -0.1 -0.01 -0.05 56 12986 50 -10 -0.05 -0.1 -0.01 -0.05 56 12987 50 -10 -0.05 -0.1 -0.01 -0.05 57 12988 55 -10 -0.05 -0.1 -0.01 -0.05 72 12989 60 -10 -0.05 -0.1 -0.01 -0.05 44 12990 65 -10 -0.05 -0.1 -0.01 -0.05 34 12991 70 -10 -0.05 -0.1 -0.01 -0.05 41 12992 80 -10 -0.05 -0.1 -0.01 -0.05 71 12993 90 -10 -0.05 -0.1 -0.01 -0.05 44 12994 100 -10 -0.05 -0.1 -0.01 -0.05 52

SAMPLE NUMBER

LINE POSITION

SR PPM

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

12995 0 -10 -0.05 -0.1 -0.01 -0.05 42 12996 10 26 -0.05 -0.1 -0.01 -0.05 75 12997 20 -10 -0.05 -0.1 0.04 -0.05 71 12998 30 -10 -0.05 -0.1 -0.01 -0.05 65 12999 35 -10 -0.05 -0.1 -0.01 -0.05 62 13000 40 19 -0.05 -0.1 -0.01 -0.05 43 12801 45 -10 -0.05 -0.1 -0.01 -0.05 67 12802 50 -10 -0.05 -0.1 -0.01 -0.05 52 12803 55 -10 -0.05 -0.1 -0.01 -0.05 42 12804 60 -10 -0.05 -0.1 -0.01 -0.05 57 12805 70 -10 -0.05 -0.1 -0.01 -0.05 64 12806 80 -10 -0.05 -0.1 -0.01 -0.05 76 12807 90 -10 -0.05 -0.1 -0.01 -0.05 82

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

LA PPM

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

12978 0 0.21 0.3 -0.3 0.034 -0.05 -0.1 12979 10 0.25 0.4 -0.3 0.04 -0.05 -0.1 12980 10 0.17 0.2 -0.3 0.025 -0.05 -0.1 12981 20 0.18 0.3 -0.3 0.025 -0.05 -0.1 12982 30 0.1 -0.1 -0.3 0.014 -0.05 -0.1 12983 35 0.15 0.4 -0.3 0.024 -0.05 -0.1 12984 40 0.2 0.3 -0.3 0.03 -0.05 -0.1 12985 45 0.1 0.1 -0.3 0.014 -0.05 -0.1 12986 50 0.19 -0.1 -0.3 0.027 -0.05 -0.1 12987 50 0.17 0.3 -0.3 0.022 -0.05 -0.1 12988 55 0.17 0.3 -0.3 0.023 -0.05 -0.1 12989 60 0.2 0.3 -0.3 0.021 -0.05 -0.1 12990 65 0.15 -0.1 -0.3 0.017 -0.05 -0.1 12991 70 0.16 0.2 -0.3 0.019 -0.05 -0.1 12992 80 0.14 -0.1 -0.3 0.015 -0.05 -0.1 12993 90 0.14 -0.1 -0.3 0.02 -0.05 -0.1 12994 100 0.11 -0.1 -0.3 0.014 -0.05 -0.1

SAMPLE NUMBER

LINE POSITION

LA PPM

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

12995 0 0.19 0.2 -0.3 0.027 -0.05 -0.1 12996 10 0.12 0.1 -0.3 0.015 -0.05 -0.1 12997 20 0.13 0.3 -0.3 0.014 -0.05 -0.1 12998 30 0.16 0.2 -0.3 0.019 -0.05 -0.1 12999 35 0.13 -0.1 -0.3 0.016 -0.05 -0.1 13000 40 0.17 0.2 -0.3 0.02 -0.05 -0.1 12801 45 0.2 0.4 -0.3 0.028 -0.05 -0.1 12802 50 0.13 0.3 -0.3 0.018 -0.05 -0.1 12803 55 0.18 0.3 -0.3 0.025 -0.05 -0.1 12804 60 0.19 0.2 -0.3 0.026 -0.05 -0.1 12805 70 0.18 0.4 -0.3 0.029 -0.05 -0.1 12806 80 0.23 -0.1 -0.3 0.034 -0.05 -0.1 12807 90 0.18 0.4 -0.3 0.026 -0.05 -0.1

-

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK

YB PPM

AT LAMOTHE

LU PPM

Mass g

12978 0 -0.005 0.004 30 12979 10 -0.005 0.006 30 12980 10 -0.005 -0.001 30 12981 20 0.02 -0.001 30 12982 30 -0.005 -0.001 30 12983 35 -0.005 -0.001 30 12984 40 -0.005 -0.001 30 12985 45 -0.005 -0.001 30 12986 50 -0.005 -0.001 30 12987 50 -0.005 -0.001 30 12988 55 0.02 0.003 30 12989 60 -0.005 -0.001 30 12990 65 -0.005 -0.001 30 12991 70 -0.005 0.003 30 12992 80 -0.005 -0.001 30 12993 90 0.015 -0.001 30 12994 100 -0.005 -0.001 30

SAMPLE NUMBER

LINE POSITION

YB PPM

LU PPM

Mass g

12995 0 0.019 0.003 30 12996 10 0.014 -0.001 30 12997 20 0.013 0.003 30 12998 30 -0.005 -0.001 30 12999 35 -0.005 -0.001 30 13000 40 -0.005 -0.001 30 12801 45 -0.005 -0.001 30 12802 50 -0.005 -0.001 30 12803 55 0.024 0.004 30 12804 60 -0.005 -0.001 30 12805 70 -0.005 -0.001 30 12806 80 -0.005 -0.001 30 12807 90 -0.005 0.007 30

-

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

YB LU

PPM PPM Mass

g 12978 0 -0.005 0.004 30 12979 10 -0.005 0.006 30 12980 10 -0.005 -0.001 30 12981 20 0.02 -0.001 30 12982 30 -0.005 -0.001 30 12983 35 -0.005 -0.001 30 12984 40 -0.005 -0.001 30 12985 45 -0.005 -0.001 30 12986 50 -0.005 -0.001 30 12987 50 -0.005 -0.001 30 12988 55 0.02 0.003 30 12989 60 -0.005 -0.001 30 12990 65 -0.005 -0.001 30 12991 70 -0.005 0.003 30 12992 80 -0.005 -0.001 30 12993 90 0.015 -0.001 30 12994 100 -0.005 -0.001 30

SAMPLE NUMBER

LINE POSITION

YB PPM

LU PPM

Mass g

12995 0 0.019 0.003 30 12996 10 0.014 -0.001 30 12997 20 0.013 0.003 30 12998 30 -0.005 -0.001 30 12999 35 -0.005 -0.001 30 13000 40 -0.005 -0.001 30 12801 45 -0.005 -0.001 30 12802 50 -0.005 -0.001 30 12803 55 0.024 0.004 30 12804 60 -0.005 -0.001 30 12805 70 -0.005 -0.001 30 12806 80 -0.005 -0.001 30 12807 90 -0.005 0.007 30

SAMP. LINE DIA DIA DEN REMARKS NO. POS. #1 #2 12808 0 NO SAMP. COUPE DE FORET 12809 10 8 8 2 3 EDGE OF COUPE 12810 20 8 11 2 2 12811 30 10 8 2 2 ALDERS 12812 35 10 11 2 2 12813 40 6 8 2 2 LARGE MELEZE 12814 45 6 8 2 2 LARGE MELEZE; SWAMPY 12815 50 8 7 2 4 SWAMPY;LARGE MELEZE 12816 55 7 9 2 3 PROJ.SHEAR;U'GROUND CK 12817 60 8 6 2 3 PROJ.SHEAR;THIN SPRUCE 12818 60 8 8 2 3 DITTO;ALDER & MELEZE 12819 65 9 11 2 3 12820 70 12 16 2 2 LARGE SAMP. 12821 75 10 11 2 2 ALDER 12822 80 9 11 2 2 ALDER 12823 90 8 10 4 1 12824 90 10 77 4 1 MELEZE

SAMP. LINE DIA DIA DEN REMARKS NO. POS. #1 #2 12825 0 8 18 2 2 EDGE OF COUPE 12826 10 10 15 2 2 12827 20 7 14 2 2 12828 25 6 10 3 2 MELEZE PRESENT 12829 30 6 14 4 2 DITTO 12830 35 6 8 3 2 MELEZE & CEDAR 12831 40 6 8 2 2 CEDAR 12832 45 6 11 1 2 12833 50 12 15 1 2 12834 55 6 20 1 2 12835 60 6 12 1 2 12836 70 7 10 1 3 12837 80 16 1 3 L 7S 12+85E 12838 90 11 15 1 2

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SHOWING 2 LINE 3....ECORCE DE EPINETTE NOIR SAMPLE LINE AU AG AS BA BR BR/10 NUMBER POSITION PPB PPM PPM PPM PPM PPM 12808 0 12809 10 0.9 -0.3 0.27 130 8.5 0.85 12810 20 0.8 -0.3 0.26 72 8.5 0.85 12811 30 0.3 -0.3 0.36 46 11 1.1 12812 35 1 -0.3 0.34 140 12 1.2 12813 40 0.6 -0.3 0.33 110 11 1.1 12814 45 0.8 -0.3 0.3 160 12 1.2 12815 50 0.6 -0.3 0.25 120 10 1 12816 55 0.6 -0.3 0.27 130 9.4 0.94 12817 60 0.8 -0.3 0.55 140 10 1 12818 60 0.2 -0.3 0.29 150 12 1.2 12819 65 0.2 -0.3 0.31 170 14 1.4 12820 70 0.7 -0.3 0.39 130 10 1 12821 75 0.3 -0.3 0.34 140 11 1.1 12822 80 0.8 -0.3 0.5 84 15 1.5 12823 90 0.5 -0.3 0.36 150 15 1.5 12824 90 0.7 -0.3 0.29 130 13 1.3

SAMPLE NUMBER

LINE POSITION

SHOWING 2 AU

PPB

LINE 4 AG

PPM

ECORCE DE AS

PPM

EPINETTE BA

PPM

NOIR BR

PPM BR/10 PPM

12825 0 0.4 -0.3 0.27 94 8.7 0.87 12826 10 0.8 0.3 0.34 87 9.6 0.96 12827 20 0.6 -0.3 0.41 120 15 1.5 12828 25 1.2 -0.3 0.37 130 14 1.4 12829 30 0.5 -0.3 0.19 100 8.1 0.81 12830 35 0.8 -0.3 0.29 140 9.5 0.95 12831 40 1 -0.3 0.39 120 12 1.2 12832 45 0.6 -0.3 0.33 120 11 1.1 12833 50 0.8 -0.3 0.39 67 13 1.3 12834 55 0.2 -0.3 0.39 110 10 1 12835 60 0.3 -0.3 0.36 85 9.9 0.99 12836 70 0.6 -0.3 0.32 98 9.9 0.99 12837 80 0.4 -0.3 0.22 90 6 0.6 12838 90 7.1 -0.3 0.2 65 7.5 0.75

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER 12808

LINE POSITION

0

CA %

CO PPM

CR PPM

CS PPM

FE %

FE*10 %

12809 10 0.91 0.4 0.7 -0.05 0.022 0.22 12810 20 0.91 0.3 0.6 -0.05 0.015 0.15 12811 30 0.93 0.3 0.6 -0.05 0.019 0.19 12812 35 1.19 0.3 0.8 -0.05 0.017 0.17 12813 40 0.64 0.4 0.8 -0.05 0.021 0.21 12814 45 0.9 0.4 0.8 -0.05 0.023 0.23 12815 50 0.8 0.4 0.1 -0.05 0.02 0.2 12816 55 0.6 0.3 0.8 0.09 0.02 0.2 12817 60 1.24 0.6 1 -0.05 0.12 1.2 12818 60 1.2 0.4 0.5 -0.05 0.021 0.21 12819 65 0.81 0.5 0.7 -0.05 0.019 0.19 12820 70 0.98 0.4 0.7 -0.05 0.016 0.16 12821 75 1.08 0.4 0.9 -0.05 0.017 0.17 12822 80 0.7 0.5 0.7 -0.05 0.022 0.22 12823 90 1.31 0.5 0.5 -0.05 0.024 0.24 12824 90 1.09 0.5 0.7 -0.05 0.018 0.18

SAMPLE LINE CA CO CR CS FE FE*10 NUMBER POSITION % PPM PPM PPM % % 12825 0 1.18 0.3 0.4 -0.05 0.013 0.13 12826 10 0.87 0.4 0.5 -0.05 0.02 0.2 12827 20 0.93 0.5 0.8 -0.05 0.024 0.24 12828 25 0.87 0.5 1 -0.05 0.024 0.24 12829 30 0.94 0.4 0.7 0.09 0.015 0.15 12830 35 0.91 0.4 0.6 -0.05 0.018 0.18 12831 40 1.04 0.4 0.4 -0.05 0.017 0.17 12832 45 0.99 0.4 0.7 0.06 0.018 0.18 12833 50 0.9 0.4 0.5 -0.05 0.018 0.18 12834 55 0.79 0.4 0.1 -0.05 0.016 0.16 12835 60 0.88 0.4 0.1 -0.05 0.016 0.16 12836 70 0.75 0.3 0.3 -0.05 0.017 0.17 12837 80 0.72 0.3 0.1 -0.05 0.013 0.13 12838 90 0.63 0.3 0.6 0.06 0.014 0.14

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE LINE HF HG IR K MO NA NUMBER POSITION PPM PPM PPB % PPM PPM 12808 0 12809 10 -0.05 0.26 -0.1 0.025 -0.05 46.4 12810 20 0.07 0.15 -0.1 0.045 -0.05 37.2 12811 30 -0.05 0.15 -0.1 0.037 -0.05 39.5 12812 35 0.06 0.25 -0.2 0.053 -0.05 44.8 12813 40 0.07 0.18 -0.1 0.047 -0.05 57.4 12814 45 -0.05 0.29 -0.2 0.033 -0.05 38.1 12815 50 -0.05 0.29 -0.1 0.045 -0.05 38.7 12816 55 0.07 0.23 -0.2 0.039 0.2 38.4 12817 60 -0.05 0.18 -0.2 0.03 -0.05 40.7 12818 60 -0.05 0.24 -0.2 0.046 -0.05 40.3 12819 65 -0.05 0.24 -0.2 0.059 -0.05 38 12820 70 -0.05 0.27 -0.2 0.047 -0.05 43.1 12821 75 -0.05 0.25 -0.2 0.045 -0.05 38.7 12822 80 -0.05 0.18 -0.2 0.03 -0.05 43.9 12823 90 -0.05 0.35 -0.1 0.046 -0.05 47.8 12824 90 -0.05 0.3 -0.2 0.056 -0.05 44.3

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

K %

MO PPM

NA PPM

12825 0 -0.05 0.15 -0.1 0.036 -0.05 32.7 12826 10 -0.05 0.14 -0.1 0.032 -0.05 37.8 12827 20 -0.05 0.32 -0.2 0.051 -0.05 45.9 12828 25 -0.05 0.27 -0.2 0.051 -0.05 42.6 12829 30 -0.05 0.14 -0.1 0.04 -0.05 32.4 12830 35 -0.05 0.16 -0.1 0.048 -0.05 40.7 12831 40 -0.05 0.19 -0.2 0.061 -0.05 42.1 12832 45 -0.05 0.13 -0.1 0.029 -0.05 38.3 12833 50 -0.05 0.19 -0.2 0.048 -0.05 45.3 12834 55 -0.05 0.19 -0.1 0.073 -0.05 48.4 12835 60 -0.05 0.15 -0.1 0.031 -0.05 42.5 12836 70 -0.05 0.14 -0.1 0.038 -0.05 34.5 12837 80 -0.05 0.07 -0.1 0.023 0.11 27.2 12838 90 -0.05 0.18 -0.1 0.016 -0.05 30

._

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER 12808

LINE POSITION

0

NI PPM

RB PPM

SB PPM

SC PPM

SC*5 PPM

SE PPM

12809 10 -5 -1 0.065 0.05 0.25 0.2 12810 20 -5 -1 0.035 0.03 0.15 -0.1 12811 30 -5 -1 0.033 0.03 0.15 -0.1 12812 35 -5 -1 0.043 0.04 0.2 -0.1 12813 40 -5 -1 0.054 0.05 0.25 -0.1 12814 45 -5 -1 0.044 0.05 0.25 0.1 12815 50 -5 -1 0.048 0.04 0.2 -0.1 12816 55 -5 -1 0.05 0.04 0.2 -0.1 12817 60 -5 -1 0.042 0.04 0.2 -0.1 12818 60 -5 -1 0.047 0.04 0.2 0.2 12819 65 -5 -1 0.072 0.04 0.2 0.1 12820 70 -5 -1 0.029 0.04 0.2 -0.1 12821 75 -5 -1 0.048 0.03 0.15 -0.1 12822 80 -5 -1 0.059 0.04 0.2 0.6 12823 90 -5 -1 0.076 0.04 0.2 0.2 12824 90 -5 2 0.08 0.05 0.25 0.4

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SC*10 PPM

SE PPM

12825 0 -5 -1 0.025 0.03 0.3 0.3 12826 10 -5 -1 0.029 0.03 0.3 -0.1 12827 20 -5 1 0.07 0.05 0.5 -0.1 12828 25 -5 2 0.061 0.05 0.5 0.1 12829 30 -5 -1 0.04 0.03 0.3 0.4 12830 35 -5 -1 0.046 0.04 0.4 -0.1 12831 40 -5 2 0.048 0.03 0.3 -0.1 12832 45 -5 -1 0.041 0.03 0.3 0.3 12833 50 -5 -1 0.056 0.04 0.4 0.3 12834 55 -5 -1 0.042 0.04 0.4 -0.1 12835 60 -5 -1 0.038 0.04 0.4 0.1 12836 70 -5 -1 0.046 0.03 0.3 -0.1 12837 80 -5 -1 0.02 0.02 0.2 -0.1 12838 90 -5 -1 0.036 0.03 0.3 0.3

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER 12808

LINE POSITION

0

SR PPM

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

12809 10 33 -0.05 -0.1 -0.01 -0.05 83 12810 20 -10 -0.05 -0.1 -0.01 -0.05 68 12811 30 -10 -0.05 -0.1 0.01 -0.05 50 12812 35 -10 -0.05 -0.1 -0.01 -0.05 60 12813 40 -10 -0.05 -0.1 -0.01 -0.05 45 12814 45 23 -0.05 -0.1 -0.01 -0.05 56 12815 50 -10 0.07 -0.1 -0.01 0.07 63 12816 55 -10 -0.05 -0.1 -0.01 -0.05 53 12817 60 44 -0.05 -0.1 -0.01 -0.05 70 12818 60 24 -0.05 -0.1 -0.01 0.1 67 12819 65 -10 -0.05 -0.1 -0.01 -0.05 49 12820 70 -10 -0.05 -0.1 -0.01 -0.05 66 12821 75 -10 -0.05 -0.1 -0.01 -0.05 63 12822 80 -10 -0.05 -0.1 -0.01 -0.05 58 12823 90 -10 -0.05 -0.1 -0.01 -0.05 57 12824 90 -10 -0.05 -0.1 -0.01 -0.05 48

SAMPLE NUMBER

LINE POSITION

SR PPM

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

12825 0 -10 -0.05 -0.1 -0.01 -0.05 70 12826 10 -10 -0.05 -0.1 -0.01 -0.05 54 12827 20 -10 -0.05 -0.1 -0.01. -0.05 46 12828 25 -10 -0.05 -0.1 -0.01 -0.05 51 12829 30 -10 -0.05 -0.1 -0.01 -0.05 65 12830 35 -10 -0.05 -0.1 -0.01 -0.05 86 12831 40 -10 -0.05 -0.1 -0.01 -0.05 76 12832 45 -10 -0.05 -0.1 -0.01 -0.05 56 12833 50 -10 -0.05 -0.1 -0.01 -0.05 58 12834 55 -10 -0.05 -0.1 -0.01 -0.05 47 12835 60 -10 -0.05 -0.1 -0.01 -0.05 67 12836 70 -10 -0.05 -0.1 -0.01 -0.05 52 12837 80 -10 -0.05 -0.1 -0.01 -0.05 60 12838 90 -10 -0.05 -0.1 -0.01 -0.05 34

-

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE LINE LA CE NUMBER POSITION PPM PPM 12808 0

ND PPM

SM PPM

EU PPM

TB PPM

12809 10 0.19 0.3 -0.3 0.029 -0.05 -0.1 12810 20 0.11 -0.1 -0.3 0.015 -0.05 -0.1 12811 30 0.13 0.2 -0.3 0.019 -0.05 -0.1 12812 35 0.17 0.3 -0.3 0.025 -0.05 -0.1 12813 40 0.18 0.4 -0.3 0.027 -0.05 -0.1 12814 45 0.15 -0.1 -0.3 0.023 -0.05 -0.1 12815 50 0.15 0.3 -0.3 0.02 -0.05 -0.1 12816 55 0.15 0.2 -0.3 0.026 -0.05 -0.1 12817 60 0.15 0.4 -0.3 0.023 -0.05 -0.1 12818 60 0.16 -0.1 -0.3 0.024 -0.05 -0.1 12819 65 0.15 -0.1 -0.3 0.024 -0.05 -0.1 12820 70 0.11 -0.1 -0.3 0.017 -0.05 -0.1 12821 75 0.13 -0.1 -0.3 0.019 -0.05 -0.1 12822 80 0.17 0.2 -0.3 0.028 -0.05 -0.1 12823 90 0.22 0.5 -0.3 0.03 -0.05 -0.1 12824 90 0.19 -0.1 -0.3 0.029 -0.05 -0.1

SAMPLE NUMBER

LINE POSITION

LA PPM

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

12825 0 0.1 -0.1 -0.3 0.014 -0.05 -0.1 12826 10 0.14 -0.1 -0.3 0.016 -0.05 -0.1 12827 20 0.18 0.4 -0.3 0.028 -0.05 -0.1 12828 25 0.18 -0.1 -0.3 0.027 -0.05 -0.1 12829 30 0.12 0.2 -0.3 0.021 -0.05 -0.1 12830 35 0.16 -0.1 -0.3 0.025 -0.05 -0.1 12831 40 0.14 0.3 -0.3 0.021 -0.05 -0.1 12832 45 0.14 -0.1 -0.3 0.021 -0.05 -0.1 12833 50 0.15 -0.1 -0.3 0.024 -0.05 -0.1 12834 55 0.15 0.3 -0.3 0.021 -0.05 -0.1 12835 60 0.15 0.3 -0.3 0.023 -0.05 -0.1 12836 70 0.12 0.2 -0.3 0.017 -0.05 -0.1 12837 80 0.09 0.2 -0.3 0.013 -0.05 -0.1 12838 90 0.1 0.2 -0.3 0.017 -0.05 -0.1

-

-

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER 12808

LINE POSITION

0

LA PPM

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

12809 10 0.19 0.3 -0.3 0.029 -0.05 -0.1 12810 20 0.11 -0.1 -0.3 0.015 -0.05 -0.1 12811 30 0.13 0.2 -0.3 0.019 -0.05 -0.1 12812 35 0.17 0.3 -0.3 0.025 -0.05 -0.1 12813 40 0.18 0.4 -0.3 0.027 -0.05 -0.1 12814 45 0.15 -0.1 -0.3 0.023 -0.05 -0.1 12815 50 0.15 0.3 -0.3 0.02 -0.05 -0.1 12816 55 0.15 0.2 -0.3 0.026 -0.05 -0.1 12817 60 0.15 0.4 -0.3 0.023 -0.05 -0.1 12818 60 0.16 -0.1 -0.3 0.024 -0.05 -0.1 12819 65 0.15 -0.1 -0.3 0.024 -0.05 -0.1 12820 70 0.11 -0.1 -0.3 0.017 -0.05 -0.1 12821 75 0.13 -0.1 -0.3 0.019 -0.05 -0.1 12822 80 0.17 0.2 -0.3 0.028 -0.05 -0.1 12823 90 0.22 0.5 -0.3 0.03 -0.05 -0.1 12824 90 0.19 -0.1 -0.3 0.029 -0.05 -0.1

SAMPLE NUMBER

LINE POSITION

LA PPM

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

12825 0 0.1 -0.1 -0.3 0.014 -0.05 -0.1 12826 10 0.14 -0.1 -0.3 0.016 -0.05 -0.1 12827 20 0.18 0.4 -0.3 0.028 -0.05 -0.1 12828 25 0.18 -0.1 -0.3 0.027 -0.05 -0.1 12829 30 0.12 0.2 -0.3 0.021 -0.05 -0.1 12830 35 0.16 -0.1 -0.3 0.025 -0.05 -0.1 12831 40 0.14 0.3 -0.3 0.021 -0.05 -0.1 12832 45 0.14 -0.1 -0.3 0.021 -0.05 -0.1 12833 50 0.15 -0.1 -0.3 0.024 -0.05 -0.1 12834 55 0.15 0.3 -0.3 0.021 -0.05 -0.1 12835 60 0.15 0.3 -0.3 0.023 -0.05 -0.1 12836 70 0.12 0.2 -0.3 0.017 -0.05 -0.1 12837 80 0.09 0.2 -0.3 0.013 -0.05 -0.1 12838 90 0.1 0.2 -0.3 0.017 -0.05 -0.1

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE LINE YB LU Mass

NUMBER POSITION PPM PPM g 12808 0

- 12809 10 -0.005 -0.001 30 12810 20 -0.005 -0.001 30 12811 30 -0.005 -0.001 30

_ 12812 35 0.014 -0.001 30 12813 40 -0.005 -0.001 30 12814 45 0.013 0.004 30 12815 50 -0.005 -0.001 30

-- 12816 55 -0.005 -0.001 30 12817 60 -0.005 -0.001 30 12818 60 -0.005 -0.001 30

- 12819 65 -0.005 -0.001 30 12820 70 -0.005 -0.001 30 12821 75 -0.005 -0.001 30 12822 80 -0.005 -0.001 30 12823 90 -0.005 -0.001 30 12824 90 -0.005 -0.001 30

SAMPLE LINE YB LU Mass

NUMBER POSITION PPM PPM g 12825 0 -0.005 -0.001 30 12826 10 -0.005 0.004 30 12827 20 -0.005 -0.001 30 12828 25 -0.005 -0.001 30 12829 30 -0.005 -0.001 30 12830 35 -0.005 -0.001 30 12831 40 -0.005 -0.001 30 12832 45 -0.005 -0.001 30 12833 50 -0.005 -0.001 30 12834 55 -0.005 -0.001 30 12835 60 -0.005 -0.001 30 12836 70 -0.005 -0.001 30 12837 80 -0.005 -0.001 30 12838 90 0.014 -0.001 30

SAMP. LINE DIA DIA W DEN REMARKS NO. POS. #1 #2 12901 0 8 12 2 2 12902 10 6 11 1 2 12903 20 NO SAMP; DRILL TRACK 12904 30 9 17 1 2 12905 35 7 12 1 1 12906 40 8 13 1 1 12907 45 2 14 1 1 12908 50 12909 55 12910 60 9 11 1 2 12911 60 9 11 1 2 DUPLICATE 12912 65 9 12 1 1 12913 70 NO SAMP; DRILL TRACK 12914 80 8 12 1 1 12915 90 12 8 1 1 12916 100 20 10 1 2 12917 110 7 8 1 2 SUB OUTCROP 12918 120 7 5 1 3 1.5M TO L 16S 535W

SAMP. NO.

LINE POS.

DIA #1

DIA W DEN #2

REMARKS

12919 0 13 2 2 ADJ TO CREEK 12920 10 12 2 2 ADJ TO DRILL TRACK 12921 20 8 10 2 2 DITTO 12922 30 10 8 1 1 SOME SAP IN SAMP. 12923 35 15 10 1 1 12924 35 15 10 1 1 DUPLICATE 12925 40 10 12 1 1 MOSS IN SAMP. 12926 45 12 10 1 1 DITTO 12927 50 10 6 1 1 DITTO 12928 55 15 8 1 1 DITTO 12929 60 15 12 1 1 12930 70 15 12 1 1 ADJ. DRILL TRACK 12931 80 9 14 1 1 DITTO 12932 90 8 14 1 1 12933 100 9 14 1 1 12934 100 8 14 1 1 DUPLICATE 12935 110 8 14 1 1 12936 120 10 15 1 1 9M TO GEOPHYSICS LINE

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-.

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

SHOWING 5 AU

PPB

LINE 1...ECORCE DE

AG AS

PPM PPM

EPINETTE BA

PPM

NOIR BR PPM

BR/10 PPM

12901 0 1.7 -0.3 0.27 100 6.7 0.67 12902 10 1.6 -0.3 0.23 100 8.6 0.86 12903 20 12904 30 2.9 -0.3 0.4 60 13 1.3 12905 35 1.3 -0.3 0.3 98 9.2 0.92 12906 40 2 -0.3 0.45 110 13 1.3 12907 45 1.4 -0.3 0.36 45 13 1.3 12908 50 1 -0.3 0.51 110 15 1.5 12909 55 0.1 -0.3 0.5 77 15 1.5 12910 60 0.8 -0.3 0.24 88 9.6 0.96 12911 60 0.7 -0.3 0.23 74 9.7 0.97 12912 65 0.7 -0.3 0.41 83 11 1.1 12913 70 12914 80 0.6 -0.3 0.38 52 11 1.1 12915 90 0.5 -0.3 0.34 72 12 1.2 12916 100 0.4 -0.3 0.22 110 7.7 0.77 12917 110 0.4 -0.3 0.24 87 8.1 0.81 12918 120 0.2 -0.3 0.38 120 12 1.2

SAMPLE NUMBER

LINE POSITION

SHOWING 5 AU

PPB

LINE 2....ECORCE DE

AG AS

PPM PPM

EPINETTE BA

PPM

NOIR BR

PPM BR/10

PPM 12919 0 0.2 -0.3 0.21 98 7.2 0.72 12920 10 0.5 -0.3 0.19 62 7.5 0.75 12921 20 0.8 -0.3 0.26 67 8.7 0.87 12922 30 0.2 0.3 0.31 30 11 1.1 12923 35 0.9 -0.3 0.33 76 10 1 12924 35 1.2 -0.3 0.33 68 9.1 0.91 12925 40 0.2 -0.3 0.52 79 10 1 12926 45 0.9 -0.3 0.36 75 13 1.3 12927 50 0.2 -0.3 0.4 85 12 1.2 12928 55 1.6 -0.3 0.38 90 13 1.3 12929 60 0.9 -0.3 0.25 75 12 1.2 12930 70 0.7 -0.3 0.29 110 9.3 0.93 12931 80 0.8 -0.3 0.32 100 11 1.1 12932 90 0.7 -0.3 0.22 79 10 1 12933 100 0.8 -0.3 0.41 94 12 1.2 12934 100 0.2 -0.3 0.3 87 11 1.1 12935 110 0.5 -0.3 0.47 21 11 1.1 12936 120 0.4 -0.3 0.29 130 12 1.2

-- SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

CA %

CO PPM

CR PPM

CS PPM

FE %

FE*10

12901 0 0.7 0.3 0.3 -0.05 0.016 0.16 12902 10 0.51 0.5 0.8 -0.05 0.023 0.23 12903 20 12904 30 0.71 0.7 0.9 -0.05 0.026 0.26 12905 35 0.88 0.6 0.7 -0.05 0.023 0.23 12906 40 0.58 0.8 1.2 -0.05 0.034 0.34 12907 45 0.55 0.8 1 -0.05 0.034 0.34 12908 50 0.67 0.6 1.1 -0.05 0.031 0.31 12909 55 0.94 0.6 0.9 -0.05 0.027 0.27 12910 60 0.94 0.4 0 -0.05 0.018 0.18 12911 60 0.88 0.4 0.8 -0.05 0.021 0.21 12912 65 0.66 0.5 0 -0.05 0.025 0.25 12913 70 12914 80 0.98 0.4 0.5 -0.05 0.022 0.22 12915 90 0.68 0.4 0.9 -0.05 0.023 0.23 12916 100 0.69 0.3 0.5 0.06 0.017 0.17 12917 110 1.06 0.3 0.5 -0.05 0.016 0.16 12918 120 0.92 0.4 0.7 -0.05 0.023 0.23

SAMPLE LINE CA CO CR CS FE FE*10 NUMBER POSITION % PPM PPM PPM % % 12919 0 0.87 0.3 0.5 -0.05 0.014 0.14 12920 10 0.64 0.3 0.7 -0.05 0.016 0.16 12921 20 0.52 0.4 0.5 -0.05 0.017 0.17 12922 30 0.49 0.4 0.8 0.09 0.021 0.21 12923 35 0.64 0.5 0.8 -0.05 0.024 0.24 12924 35 0.67 0.5 0.9 -0.05 0.026 0.26 12925 40 0.72 0.4 0.8 0.08 0.021 0.21 12926 45 0.79 0.4 0.6 -0.05 0.025 0.25 12927 50 0.78 0.6 1.2 -0.05 0.029 0.29 12928 55 0.65 0.5 0.7 -0.05 0.03 0.3 12929 60 0.78 0.5 0.8 -0.05 0.022 0.22 12930 70 0.83 0.4 0.7 0.07 0.02 0.2 12931 80 0.85 0.4 0.9 0.09 0.022 0.22 12932 90 0.83 0.4 0.8 -0.05 0.019 0.19 12933 100 0.9 0.5 0.8 -0.05 0.025 0.25 12934 100 0.65 0.4 1 -0.05 0.02 0.2 12935 110 0.42 0.4 1 -0.05 0.027 0.27 12936 120 0.94 0.4 0.8 -0.05 0.023 0.23

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

K %

MO PPM

NA PPM

12901 0 -0.05 0.24 -0.1 0.026 -0.05 42.5 12902 10 -0.05 0.27 -0.1 0.037 -0.05 49.9 12903 20 12904 30 -0.05 0.25 -0.2 0.038 -0.05 67.8 12905 35 -0.05 0.46 -0.1 0.052 -0.05 54.1 12906 40 -0.05 0.31 -0.2 0.058 -0.05 75.2 12907 45 -0.05 0.33 -0.2 0.04 -0.05 75 12908 50 -0.05 0.41 -0.2 0.056 -0.05 83.2 12909 55 -0.05 0.35 -0.2 0.046 -0.05 66.3 12910 60 -0.05 0.38 -0.1 0.048 -0.05 57.5 12911 60 -0.05 0.26 -0.1 0.048 -0.05 45.5 12912 65 0.08 0.37 -0.1 0.047 -0.05 54.7 12913 70 12914 80 -0.05 0.27 -0.1 0.054 -0.05 46.7 12915 90 -0.05 0.35 -0.1 0.051 -0.05 54 12916 100 -0.05 0.14 -0.1 0.046 -0.05 38 12917 110 -0.05 0.22 -0.1 0.036 -0.05 39.7 12918 120 -0.05 0.3 -0.2 0.051 -0.05 49.9

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

K %

MO PPM

NA PPM

12919 0 -0.05 0.14 -0.1 0.04 -0.05 32.6 12920 10 0.05 0.24 -0.1 0.018 -0.05 42.2 12921 20 -0.05 0.25 -0.1 0.051 -0.05 44.1 12922 30 0.05 0.26 -0.2 0.047 -0.05 47.7 12923 35 -0.05 0.28 -0.2 0.03 -0.05 51.3 12924 35 -0.05 0.24 -0.1 0.035 -0.05 62.3 12925 40 -0.05 0.32 -0.1 0.049 -0.05 50.8 12926 45 -0.05 0.27 -0.2 0.045 -0.05 51.8 12927 50 -0.05 0.31 -0.2 0.05 -0.05 104 12928 55 -0.05 0.32 -0.2 0.065 -0.05 64.7 12929 60 -0.05 0.23 -0.1 0.049 -0.05 46.2 12930 70 -0.05 0.25 -0.1 0.05 -0.05 44.3 12931 80 -0.05 0.41 -0.1 0.026 -0.05 51.4 12932 90 -0.05 0.27 -0.1 0.05 -0.05 43.5 12933 100 0.05 0.32 -0.1 0.061 -0.05 58.7 12934 100 -0.05 0.26 -0.1 0.03 -0.05 51.6 12935 110 -0.05 0.24 -0.1 0.051 -0.05 52.8 12936 120 -0.05 0.1 -0.1 0.04 -0.05 40.9

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SC*10 PPM

SE PPM

12901 0 -5 2 0.05 0.04 0.4 -0.1 12902 10 -5 1 0.052 0.05 0.5 -0.1 12903 20 12904 30 -5 1 0.047 0.06 0.6 0.2 12905 35 -5 -1 0.043 0.05 0.5 -0.1 12906 40 -5 -1 0.076 0.07 0.7 0.2 12907 45 -5 1 0.085 0.07 0.7 -0.1 12908 50 -5 2 0.09 0.07 0.7 -0.1 12909 55 -5 2 0.083 0.06 0.6 -0.1 12910 60 -5 -1 0.056 0.05 0.5 -0.1 12911 60 -5 1 0.065 0.05 0.5 0.3 12912 65 -5 2 0.074 0.06 0.6 -0.1 12913 70 12914 80 -5 -1 0.058 0.04 0.4 -0.1 12915 90 -5 -1 0.063 0.06 0.6 -0.1 12916 100 -5 -1 0.032 0.04 0.4 0.1 12917 110 7 -1 0.043 0.04 0.4 -0.1 12918 120 -5 -1 0.055 0.05 0.5 -0.1

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SC*10 PPM

SE PPM

12919 0 -5 -1 0.018 0.03 0.3 -0.1 12920 10 -5 -1 0.02 0.03 0.3 -0.1 12921 20 -5 -1 0.021 0.03 0.3 -0.1 12922 30 -5 -1 0.033 0.05 0.5 -0.1 12923 35 -5 2 0.059 0.05 0.5 -0.1 12924 35 -5 -1 0.039 0.08 0.8 0.1 12925 40 -5 -1 0.057 0.05 0.5 -0.1 12926 45 -5 -1 0.043 0.04 0.4 -0.1 12927 50 -5 -1 0.05 0.08 0.8 -0.1 12928 55 10 -1 0.065 0.07 0.7 -0.1 12929 60 -5 -1 0.047 0.05 0.5 0.1 12930 70 -5 -1 0.046 0.04 0.4 0.1 12931 80 -5 -1 0.073 0.05 0.5 -0.1 12932 90 -5 -1 0.041 0.04 0.4 -0.1 12933 100 11 -1 0.064 0.06 0.6 -0.1 12934 100 -5 2 0.057 0.05 0.5 -0.1 12935 110 -5 -1 0.11 0.06 0.6 0.3 12936 120 -5 -1 0.053 0.04 0.4 0.2

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-

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

SR TA

PPM PPM TH

PPM U

PPM W

PPM ZN

PPM 12901 0 -10 -0.05 -0.1 -0.01 -0.05 55 12902 10 -10 -0.05 -0.1 -0.01 -0.05 38 12903 20 12904 30 -10 -0.05 -0.1 -0.01 -0.05 46 12905 35 -10 -0.05 -0.1 -0.01 -0.05 49 12906 40 -10 -0.05 -0.1 -0.01 -0.05 44 12907 45 -10 -0.05 -0.1 -0.01 0.06 35 12908 50 -10 -0.05 -0.1 -0.01 -0.05 52 12909 55 -10 -0.05 -0.1 -0.01 -0.05 52 12910 60 -10 -0.05 -0.1 -0.01 -0.05 45 12911 60 -10 -0.05 -0.1 -0.01 -0.05 42 12912 65 -10 -0.05 -0.1 -0.01 -0.05 47 12913 70 12914 80 -10 -0.05 -0.1 -0.01 -0.05 51 12915 90 -10 -0.05 -0.1 -0.01 -0.05 38 12916 100 -10 -0.05 -0.1 -0.01 -0.05 56 12917 110 -10 -0.05 -0.1 -0.01 -0.05 47 12918 120 -10 -0.05 -0.1 -0.01 -0.05 52

SAMPLE NUMBER

LINE POSITION

SR PPM

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

12919 0 -10 -0.05 -0.1 -0.01 -0.05 53 12920 10 -10 -0.05 -0.1 -0.01 -0.05 38 12921 20 -10 -0.05 -0.1 -0.01 -0.05 52 12922 30 -10 -0.05 -0.1 -0.01 -0.05 31 12923 35 -10 -0.05 -0.1 -0.01 -0.05 43 12924 35 -10 -0.05 -0.1 -0.01 -0.05 53 12925 40 -10 -0.05 -0.1 -0.01 -0.05 49 12926 45 -10 -0.05 -0.1 -0.01 -0.05 49 12927 50 28 -0.05 -0.1 -0.01 -0.05 43 12928 55 -10 -0.05 -0.1 -0.01 -0.05 54 12929 60 -10 -0.05 -0.1 -0.01 -0.05 50 12930 70 -10 -0.05 -0.1 -0.01 -0.05 50 12931 80 -10 -0.05 -0.1 -0.01 -0.05 38 12932 90 -10 -0.05 -0.1 -0.01 -0.05 48 12933 100 -10 -0.05 -0.1 0.04 -0.05 48 12934 100 -10 -0.05 -0.1 -0.01 -0.05 54 12935 110 -10 -0.05 -0.1 -0.01 -0.05 31 12936 120 -10 -0.05 -0.1 -0.01 -0.05 59

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

LA CE

PPM PPM ND

PPM SM

PPM EU

PPM TB

PPM 12901 0 0.16 0.3 -0.3 0.025 -0.05 -0.1 12902 10 0.19 0.3 -0.3 0.03 -0.05 -0.1 12903 20 12904 30 0.2 0.4 -0.3 0.029 -0.05 -0.1 12905 35 0.18 0.3 -0.3 0.027 -0.05 -0.1 12906 40 0.28 0.4 -0.3 0.042 -0.05 -0.1 12907 45 0.28 0.5 -0.3 0.042 -0.05 -0.1 12908 50 0.3 0.4 -0.3 0.042 -0.05 -0.1 12909 55 0.25 -0.1 -0.3 0.035 -0.05 -0.1 12910 60 0.19 0.2 -0.3 0.029 -0.05 -0.1 12911 60 0.21 -0.1 -0.3 0.03 -0.05 -0.1 12912 65 0.22 0.3 -0.3 0.034 -0.05 -0.1 12913 70 12914 80 0.19 0.3 -0.3 0.028 -0.05 -0.1 12915 90 0.2 -0.1 -0.3 0.03 -0.05 -0.1 12916 100 0.13 -0.1 -0.3 0.022 -0.05 -0.1 12917 110 0.15 0.3 -0.3 0.026 -0.05 -0.1 12918 120 0.21 -0.1 -0.3 0.031 -0.05 -0.1

SAMPLE NUMBER

LINE POSITION

LA PPM

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

12919 0 0.09 0.2 -0.3 0.017 -0.05 -0.1 12920 10 0.13 -0.1 -0.3 0.02 -0.05 -0.1 12921 20 0.11 -0.1 -0.3 0.018 -0.05 -0.1 12922 30 0.16 -0.1 -0.3 0.024 -0.05 -0.1 12923 35 0.18 -0.1 -0.3 0.024 -0.05 -0.1 12924 35 0.16 -0.1 -0.3 0.027 -0.05 -0.1 12925 40 0.19 0.4 -0.3 0.027 -0.05 -0.1 12926 45 0.19 -0.1 -0.3 0.029 -0.05 -0.1 12927 50 0.28 0.4 -0.3 0.039 -0.05 -0.1 12928 55 0.25 0.5 -0.3 0.043 -0.05 -0.1 12929 60 0.19 -0.1 -0.3 0.028 -0.05 -0.1 12930 70 0.17 0.2 -0.3 0.025 -0.05 -0.1 12931 80 0.21 0.2 -0.3 0.03 -0.05 -0.1 12932 90 0.15 0.3 -0.3 0.024 -0.05 -0.1 12933 100 0.25 0.4 -0.3 0.035 -0.05 -0.1 12934 100 0.19 0.3 -0.3 0.027 -0.05 -0.1 12935 110 0.23 0.4 -0.3 0.038 -0.05 -0.1 12936 120 0.17 0.3 -0.3 0.027 -0.05 -0.1

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

YB PPM

LU PPM

Mass g

12901 0 -0.005 -0.001 30 12902 10 -0.005 -0.001 30 12903 20 12904 30 -0.005 -0.001 30 12905 35 -0.005 -0.001 30 12906 40 0.019 -0.001 30 12907 45 0.013 -0.001 30 12908 50 -0.005 -0.001 30 12909 55 0.022 -0.001 30 12910 60 -0.005 -0.001 30 12911 60 -0.005 -0.001 30 12912 65 0.02 0.004 30 12913 70 12914 80 -0.005 -0.001 30 12915 90 -0.005 -0.001 30 12916 100 -0.005 -0.001 30 12917 110 -0.005 0.004 30 12918 120 -0.005 -0.001 30

SAMPLE NUMBER

LINE POSITION

YB PPM

LU PPM

Mass g

12919 0 -0.005 -0.001 30 12920 10 -0.005 -0.001 30 12921 20 -0.005 -0.001 30 12922 30 -0.005 -0.001 30 12923 35 -0.005 -0.001 30 12924 35 -0.005 0.003 30 12925 40 -0.005 -0.001 30 12926 45 -0.005 -0.001 30 12927 50 -0.005 -0.001 30 12928 55 0.02 -0.001 30 12929 60 -0.005 -0.001 30 12930 70 -0.005 -0.001 30 12931 80 -0.005 -0.001 30 12932 90 0.01 -0.001 30 12933 100 -0.005 -0.001 30 12934 100 0.023 -0.001 30 12935 110 -0.005 -0.001 30 12936 120 -0.005 -0.001 30

SAMP. NO.

LINE POS.

DIA #1

DIA W DEN #2

REMARKS

12937 0 10 8 1 2 PHOTO 12938 10 8 10 1 2 12939 20 10 14 1 2 12940 20 15 8 1 2 DUPLICATE; PHOTO 12941 30 10 10 1 2 12942 35 12 9 1 2 12943 40 10 9 1 2 12944 45 10 9 1 2 12945 50 17 12 2 2 12946 55 17 12 1 2 12947 60 15 14 1 2 STRIKE PROJ. OF SHEAR 12948 60 13 15 1 2 DITTO; DUPLICATE 12949 65 18 14 1 2 12950 70 18 13 1 2 12951 75 20 13 1 2 12952 80 10 8 1 2 PHOTOS; GEOPH. L 16S 12953 85 10 14 1 2 12954 90 12 8 1 2 15M TO CREEK

SAMP. LINE DIA DIA W DEN REMARKS NO. POS. #1 #2 12955 0 10 14 1 1 18M TO L 175 @ 478W 12956 10 12 9 1 1 12957 20 10 7 1 1 12958 30 6 12 1 2 BOGGY 12959 35 10 12 1 1 DITTO 12960 40 6 10 1 1 DITTO 12961 45 10 12 1 1 DITTO 12962 50 10 15 1 1 12963 50 10 15 1 1 DUPLICATE 12964 55 8 12 1 1 BOGGY 12965 60 10 12 2 1 12966 65 12 13 2 1 12967 70 10 12 2 1 12968 75 8 12 2 1 12969 80 8 10 2 1 12970 90 8 12 2 3 4M PAST GEOPH L 16S

--

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

SHOWING 5 AU

PPB

LINE 3....ECORCE DE EPINETTE NOIR

AG AS BA BR

PPM PPM PPM PPM BR/10 PPM

12937 0 8.5 -0.3 0.39 96 12 1.2 12938 10 4 -0.3 0.38 73 13 1.3 12939 20 2.3 -0.3 0.5 93 16 1.6 12940 20 1.5 -0.3 0.38 100 14 1.4 12941 30 1.9 -0.3 0.42 150 17 1.7 12942 35 1.6 -0.3 0.42 72 15 1.5 12943 40 1.3 -0.3 0.44 150 15 1.5 12944 45 1.1 -0.3 0.41 120 13 1.3 12945 50 0.6 -0.3 0.47 100 14 1.4 12946 55 0.2 -0.3 0.42 98 14 1.4 12947 60 1 -0.3 0.38 85 13 1.3 12948 60 0.9 -0.3 0.33 74 11 1.1 12949 65 0.2 -0.3 0.42 99 14 1.4 12950 70 1.6 -0.3 0.4 83 14 1.4 12951 75 0.6 -0.3 0.19 120 9.1 0.91 12952 80 0.5 -0.3 0.3 120 11 1.1 12953 85 0.4 -0.3 0.59 100 9 0.9 12954 90 0.5 -0.3 0.45 110 12 1.2

SAMPLE NUMBER

LINE POSITION

SHOWING 5 AU

PPB

LINE 4....ECORCE DE

AG AS

PPM PPM

EPINETTE BA

PPM

NOIR BR

PPM BR/10

PPM 12955 0 1.1 -0.3 0.35 100 11 1.1 12956 10 0.2 -0.3 0.31 73 11 1.1 12957 20 0.4 -0.3 0.48 100 14 1.4 12958 30 0.2 -0.3 0.28 150 14 1.4 12959 35 0.7 -0.3 0.44 150 11 1.1 12960 40 0.2 -0.3 0.39 91 13 1.3 12961 45 0.7 -0.3 0.38 92 13 1.3 12962 50 0.7 -0.3 0.37 84 12 1.2 12963 50 0.2 -0.3 0.44 140 10 1 12964 55 0.5 -0.3 0.41 48 13 1.3 12965 60 0.2 -0.3 0.33 89 13 1.3 12966 65 0.9 -0.3 0.39 71 13 1.3 12967 70 0.2 -0.3 0.44 97 15 1.5 12968 75 0.7 -0.3 0.59 150 19 1.9 12969 80 0.7 -0.3 0.42 160 14 1.4 12970 90 0.7 -0.3 0.28 140 9.8 0.98

--

-

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

CA %

CO PPM

CR PPM

CS PPM

FE FE*10 %

12937 0 0.76 0.5 0.6 -0.05 0.025 0.25 12938 10 1.14 0.4 0.9 -0.05 0.019 0.19 12939 20 1.24 0.6 0.9 -0.05 0.023 0.23 12940 20 0.73 0.6 0.8 -0.05 0.023 0.23 12941 30 1.51 0.5 0.8 -0.05 0.023 0.23 12942 35 0.81 0.5 0 -0.05 0.023 0.23 12943 40 1.01 0.5 1.1 -0.05 0.029 0.29 12944 45 0.83 0.5 1.1 0.09 0.024 0.24 12945 50 0.79 0.6 0.9 -0.05 0.028 0.28 12946 55 0.86 0.4 1 -0.05 0.024 0.24 12947 60 0.78 0.5 0.8 -0.05 0.027 0.27 12948 60 1.23 0.3 0.9 -0.05 0.018 0.18 12949 65 0.91 0.5 0.6 -0.05 0.023 0.23 12950 70 0.75 0.4 0.6 -0.05 0.022 0.22 12951 75 0.97 0.3 0.6 0.07 0.015 0.15 12952 80 0.81 0.4 0.9 -0.05 0.023 0.23 12953 85 0.65 0.3 1 0.09 0.021 0.21 12954 90 0.86 0.4 0.6 0.09 0.021 0.21

SAMPLE LINE CA CO CR CS FE FE*10 NUMBER POSITION % PPM PPM PPM % % 12955 0 0.95 0.3 0.6 -0.05 0.019 0.19 12956 10 0.68 0.3 0.6 -0.05 0.02 0.2 12957 20 1.22 0.4 0.9 0.12 0.018 0.18 12958 30 1.02 0.4 0.9 -0.05 0.02 0.2 12959 35 0.79 0.4 0.5 -0.05 0.02 0.2 12960 40 0.83 0.3 0.9 -0.05 0.018 0.18 12961 45 0.68 0.4 1.1 -0.05 0.023 0.23 12962 50 1.14 0.4 0.6 -0.05 0.023 0.23 12963 50 1.14 0.3 1 -0.05 0.023 0.23 12964 55 1.37 0.4 0.8 -0.05 0.021 0.21 12965 60 0.93 0.4 0.9 -0.05 0.02 0.2 12966 65 0.79 0.3 0.6 0.08 0.025 0.25 12967 70 0.87 0.5 0.8 -0.05 0.028 0.28 12968 75 1.43 0.6 1 0.11 0.025 0.25 12969 80 1.37 0.4 0.7 0.14 0.025 0.25 12970 90 1.03 0.3 0.6 -0.05 0.02 0.2

_

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

K MO PPM

NA PPM

12937 0 0.05 0.38 -0.2 0.033 -0.05 56.9 12938 10 -0.05 0.21 -0.2 0.05 -0.05 37.2 12939 20 -0.05 0.39 -0.2 0.052 -0.05 56.5 12940 20 -0.05 0.29 -0.2 0.047 -0.05 50.1 12941 30 -0.05 0.26 -0.2 0.05 -0.05 53.6 12942 35 -0.05 0.32 -0.2 0.039 -0.05 52.1 12943 40 -0.05 0.49 -0.2 0.069 -0.05 84.3 12944 45 -0.05 0.31 -0.2 0.02 -0.05 64 12945 50 0.06 0.45 -0.2 0.077 0.1 69.8 12946 55 -0.05 0.24 -0.1 0.061 0.1 59.8 12947 60 -0.05 0.33 -0.1 0.057 -0.05 65.6 12948 60 -0.05 0.11 -0.1 0.03 -0.05 43.4 12949 65 0.06 0.25 -0.1 0.042 -0.05 52.1 12950 70 -0.05 0.33 -0.1 0.04 -0.05 53.8 12951 75 -0.05 0.19 -0.1 0.035 -0.05 40.5 12952 80 -0.05 0.25 -0.1 0.049 -0.05 56.7 12953 85 -0.05 0.13 -0.1 0.056 -0.05 67.5 12954 90 -0.05 0.12 -0.1 0.051 -0.05 48

SAMPLE NUMBER

LINE POSITION

HF PPM

HG PPM

IR PPB

K %

MO PPM

NA PPM

12955 0 -0.05 0.3 -0.1 0.045 -0.05 42.7 12956 10 -0.05 0.4 -0.1 0.049 -0.05 51.2 12957 20 -0.05 0.46 -0.1 0.043 -0.05 47.3 12958 30 -0.05 0.36 -0.1 0.047 -0.05 52 12959 35 -0.05 0.31 -0.1 0.053 -0.05 48.3 12960 40 -0.05 0.31 -0.1 0.049 -0.05 51.3 12961 45 -0.05 0.29 -0.2 0.05 -0.05 54.2 12962 50 -0.05 0.38 -0.2 0.055 -0.05 60.3 12963 50 -0.05 0.26 -0.1 0.04 -0.05 52.1 12964 55 -0.05 0.36 -0.1 0.068 -0.05 54.3 12965 60 -0.05 0.32 -0.1 0.046 -0.05 48.7 12966 65 -0.05 0.33 -0.1 0.068 -0.05 54.6 12967 70 -0.05 0.28 -0.2 0.076 -0.05 59.1 12968 75 -0.05 0.38 -0.2 0.053 -0.05 62.9 12969 80 -0.05 0.31 -0.1 0.049 -0.05 59.5 12970 90 -0.05 0.25 -0.1 0.047 -0.05 41.6

--

SAMPLING OF BLACK SPRUCE BARK AT LAMOTHE

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SC*10 PPM

SE PPM

12937 0 -5 -1 0.083 0.06 0.6 0.2 12938 10 -5 2 0.04 0.04 0.4 -0.1 12939 20 -5 -1 0.074 0.06 0.6 -0.1 12940 20 -5 2 0.066 0.06 0.6 -0.1 12941 30 -5 -1 0.072 0.05 0.5 0.3 12942 35 -5 -1 0.057 0.05 0.5 -0.1 12943 40 -5 -1 0.1 0.08 0.8 0.2 12944 45 -5 -1 0.075 0.07 0.7 -0.1 12945 50 -5 2 0.089 0.07 0.7 0.1 12946 55 8 2 0.052 0.05 0.5 -0.1 12947 60 -5 3 0.078 0.06 0.6 -0.1 12948 60 -5 -1 0.055 0.04 0.4 -0.1 12949 65 -5 -1 0.073 0.05 0.5 0.1 12950 70 -5 -1 0.059 0.05 0.5 -0.1 12951 75 -5 -1 0.048 0.03 0.3 -0.1 12952 80 -5 -1 0.072 0.06 0.6 -0.1 12953 85 -5 2 0.068 0.05 0.5 0.1 12954 90 -5 -1 0.046 0.04 0.4 0.4

SAMPLE NUMBER

LINE POSITION

NI PPM

RB PPM

SB PPM

SC PPM

SC*10 PPM

SE PPM

12955 0 -5 -1 0.059 0.05 0.5 -0.1 12956 10 -5 -1 0.087 0.06 0.6 -0.1 12957 20 -5 -1 0.079 0.05 0.5 0.1 12958 30 -5 -1 0.073 0.05 0.5 -0.1 12959 35 -5 2 0.063 0.05 0.5 0.2 12960 40 -5 -1 0.062 0.05 0.5 -0.1 12961 45 -5 -1 0.078 0.06 0.6 0.1 12962 50 -5 -1 0.092 0.06 0.6 -0.1 12963 50 -5 -1 0.09 0.06 0.6 0.2 12964 55 -5 -1 0.081 0.06 0.6 0.1 12965 60 -5 -1 0.082 0.05 0.5 0.4 12966 65 -5 -1 0.077 0.06 0.6 0.4 12967 70 -5 2 0.079 0.06 0.6 0.3 12968 75 -5 -1 0.096 0.06 0.6 -0.1 12969 80 -5 2 0.085 0.06 0.6 -0.1 12970 90 -5 1 0.076 0.04 0.4 -0.1

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

SR TA

PPM PPM TH

PPM U

PPM W

PPM ZN

PPM 12937 0 -10 -0.05 -0.1 -0.01 -0.05 49 12938 10 -10 -0.05 -0.1 -0.01 -0.05 61 12939 20 -10 -0.05 -0.1 -0.01 -0.05 70 12940 20 -10 -0.05 -0.1 -0.01 -0.05 45 12941 30 -10 -0.05 -0.1 -0.01 -0.05 57 12942 35 -10 -0.05 -0.1 -0.01 -0.05 60 12943 40 -10 -0.05 -0.1 -0.01 -0.05 51 12944 45 -10 -0.05 -0.1 -0.01 -0.05 41 12945 50 -10 -0.05 -0.1 -0.01 -0.05 46 12946 55 -10 -0.05 -0.1 -0.01 -0.05 56 12947 60 -10 -0.05 -0.1 -0.01 -0.05 50 12948 60 -10 -0.05 -0.1 -0.01 -0.05 60 12949 65 -10 -0.05 -0.1 -0.01 -0.05 45 12950 70 31 -0.05 -0.1 -0.01 -0.05 49 12951 75 -10 -0.05 -0.1 -0.01 -0.05 52 12952 80 -10 -0.05 -0.1 -0.01 -0.05 44 12953 85 -10 -0.05 -0.1 -0.01 -0.05 63 12954 90 -10 -0.05 -0.1 -0.01 -0.05 54

SAMPLE NUMBER

LINE POSITION

SR PPM

TA PPM

TH PPM

U PPM

W PPM

ZN PPM

12955 0 -10 -0.05 -0.1 -0.01 -0.05 51 12956 10 -10 -0.05 -0.1 -0.01 -0.05 49 12957 20 -10 -0.05 -0.1 -0.01 -0.05 63 12958 30 -10 -0.05 -0.1 -0.01 -0.05 44 12959 35 -10 -0.05 -0.1 -0.01 -0.05 55 12960 40 -10 -0.05 -0.1 -0.01 -0.05 55 12961 45 -10 -0.05 -0.1 -0.01 0.06 48 12962 50 -10 -0.05 -0.1 -0.01 -0.05 44 12963 50 41 -0.05 -0.1 -0.01 -0.05 56 12964 55 41 -0.05 -0.1 -0.01 -0.05 66 12965 60 -10 -0.05 -0.1 -0.01 -0.05 61 12966 65 -10 -0.05 -0.1 -0.01 -0.05 48 12967 70 -10 -0.05 -0.1 -0.01 -0.05 52 12968 75 -10 -0.05 -0.1 -0.01 -0.05 64 12969 80 -10 -0.05 -0.1 -0.01 -0.05 60 12970 90 -10 -0.05 -0.1 -0.01 -0.05 73

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

LA CE

PPM PPM ND

PPM SM

PPM EU

PPM TB

PPM 12937 0 0.26 0.5 -0.3 0.044 -0.05 -0.1 12938 10 0.13 0.2 -0.3 0.021 -0.05 -0.1 12939 20 0.26 0.2 -0.3 0.04 -0.05 -0.1 12940 20 0.21 0.4 -0.3 0.033 -0.05 -0.1 12941 30 0.23 0.4 -0.3 0.035 -0.05 -0.1 12942 35 0.18 -0.1 -0.3 0.03 -0.05 -0.1 12943 40 0.31 0.4 -0.3 0.05 -0.05 -0.1 12944 45 0.23 0.3 -0.3 0.034 -0.05 -0.1 12945 50 0.28 -0.1 -0.3 0.04 -0.05 -0.1 12946 55 0.21 -0.1 -0.3 0.031 -0.05 -0.1 12947 60 0.23 0.3 -0.3 0.037 -0.05 -0.1 12948 60 0.17 0.3 -0.3 0.025 -0.05 -0.1 12949 65 0.21 0.4 -0.3 0.031 -0.05 -0.1 12950 70 0.2 -0.1 -0.3 0.03 -0.05 -0.1 12951 75 0.13 -0.1 -0.3 0.021 -0.05 -0.1 12952 80 0.22 0.4 -0.3 0.033 -0.05 -0.1 12953 85 0.22 0.3 -0.3 0.034 -0.05 -0.1 12954 90 0.17 0.3 -0.3 0.027 -0.05 -0.1

SAMPLE NUMBER

LINE POSITION

LA PPM

CE PPM

ND PPM

SM PPM

EU PPM

TB PPM

12955 0 0.19 0.2 -0.3 0.029 -0.05 -0.1 12956 10 0.21 0.4 -0.3 0.035 -0.05 -0.1 12957 20 0.22 0.4 -0.3 0.034 -0.05 -0.1 12958 30 0.22 -0.1 -0.3 0.032 -0.05 -0.1 12959 35 0.19 0.5 -0.3 0.03 -0.05 -0.1 12960 40 0.18 0.3 -0.3 0.029 -0.05 -0.1 12961 45 0.23 0.4 -0.3 0.036 -0.05 -0.1 12962 50 0.23 0.4 -0.3 0.033 -0.05 -0.1 12963 50 0.22 -0.1 -0.3 0.032 -0.05 -0.1 12964 55 0.22 -0.1 -0.3 0.037 -0.05 -0.1 12965 60 0.22 0.3 -0.3 0.03 -0.05 -0.1 12966 65 0.23 0.4 -0.3 0.034 -0.05 -0.1 12967 70 0.26 0.4 -0.3 0.04 -0.05 -0.1 12968 75 0.26 0.4 -0.3 0.04 -0.05 -0.1 12969 80 0.25 -0.1 -0.3 0.041 -0.05 -0.1 12970 90 0.21 0.3 -0.3 0.033 -0.05 -0.1

SAMPLING OF BLACK

SAMPLE LINE NUMBER POSITION

SPRUCE BARK AT LAMOTHE

YB LU

PPM PPM Mass

g 12937 0 -0.005 -0.001 30 12938 10 -0.005 -0.001 30 12939 20 -0.005 0.005 30 12940 20 -0.005 0.004 30 12941 30 0.03 -0.001 30 12942 35 -0.005 -0.001 30 12943 40 -0.005 -0.001 30 12944 45 0.026 -0.001 30 12945 50 -0.005 -0.001 30 12946 55 -0.005 -0.001 30 12947 60 -0.005 -0.001 30 12948 60 -0.005 -0.001 30 12949 65 -0.005 -0.001 30 12950 70 -0.005 -0.001 30 12951 75 -0.005 -0.001 30 12952 80 -0.005 -0.001 30 12953 85 0.017 -0.001 30 12954 90 -0.005 -0.001 30

SAMPLE NUMBER

LINE POSITION

YB PPM

LU PPM

Mass g

12955 0 -0.005 -0.001 30 12956 10 0.016 -0.001 30 12957 20 0.016 -0.001 30 12958 30 -0.005 0.004 30 12959 35 0.019 -0.001 30 12960 40 -0.005 0.003 30 12961 45 -0.005 -0.001 30 12962 50 -0.005 0.004 30 12963 50 0.022 -0.001 30 12964 55 -0.005 -0.001 30 12965 60 0.023 0.005 30 12966 65 0.025 0.004 30 12967 70 -0.005 -0.001 30 12968 75 0.023 0.005 30 12969 80 -0.005 -0.001 30 12970 90 -0.005 -0.001 30

APPENDIX 3

HISTOGRAMS AND THRESHOLD CALCULATIONS FOR Au, As, Br, Cu, Fe, Na, Sc, La and U FOR HUMUS

11:01:31 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = AU PPB Unit = N = 129

Mean = 2.136 Min = 0.500 1st Quartile = 0.500 Std. Dey. = 3.341 Max = 19.000 Median = 1.000

% 156.445 Skewness = 3.412 3rd Quartile = CV _ 2.000

% cum % cls int (# of bins = 12 - bin size = 1.682)

0.00 0.38 -0.341 68.22 68.08 1.341 ******************************* --> 62 20.16 88.08 3.023 ******************

2.33 90.38 4.705 **

2.33 92.69 6.386 **

0.00 92.69 8.068 1.55 94.23 9.750 * 1.55 95.77 11.432 * 1.55 97.31 13.114 * 0.00 97.31 14.795 0.78 98.08 16.477 * 0.00 98.08 18.159 1.55 99.62 19.841 *

0

1 2 3 4

########################################################################

Unit = AU PPB N = 129 Variable =

Anti-Log Mean = 1.222 Anti-Log

Std. Dey. : (-) 0.490

(+) 3.048

3 4 0

1 2

11:01:47 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Mean = Std. Dey. =

CV % =

0.0870 0.3970

456.3906

Min = Max =

Skewness =

-0.3010 1.2788 1.1537

1st Quartile = Median =

3rd Quartile =

-0.3010 0.0000 0.3010

cum % antilog cls int (# of bins = 12 - bin size = 0.1436)

0.00 31.78 0.00 36.43 0.00 11.63 8.53 2.33 2.33 0.00 3.10 2.33 1.55

0.38 31.92 31.92 68.08 68.08 79.62 88.08 90.38 92.69 92.69 95.77 98.08 99.62

0.424 0.590 0.821 1.143 1.591 2.214 3.082 4.290 5.972 8.312 11.570 16.104 22.416

-0.3728 -0.2292 -0.0856 0.0580 0.2016 0.3452 0.4889 0.6325 0.7761 0.9197 1.0633 1.2069 1.3506

*****************************

*********************************

***********

********

**

**

***

**

*

########################################################################

08:52:01 LAMOTHE HUMUS 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = AU PPB Unit = N = 129

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

-- 0 Observations Were Below the Minimum Value of 0.0010 1 Observations Were Above the Maximum Value of 20.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -282.902

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 0.951 - 0.527 92.30 + 1.717

2 8.679 - 5.543 7.70 + 13.588

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.292 3.100 2 3.541 21.274

########################################################################

08:56:24 LAMOTHE HUMUS 01/23/ 91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = AU PPB Unit = N = 129

N CI = 12

Transform = Logarithmic Number of Populations = 3

# of Missing Observations = 0.

-- 0 Observations Were Below the Minimum Value of 0.0010 1 Observations Were Above the Maximum Value of 20.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -269.080

Parameterized Degrees of Freedom = 5

Population Mean Std Dev Percentage

1 0.718 - 0.519 69.95 + 0.995

2 2.254 - 1.858 21.24 + 2.736

3 8.097 - 5.169 8.81 + 12.685

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.375 1.377 2 1.531 3.321 3 3.300 19.871

########################################################################

09:07:58 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = AS PPM Unit = N = 130

Mean = 2.477 Min = 0.500 1st Quartile = 2.000 Dey. = 1.685 -- Median Max = 10.000 Median = 2.000 CV % = 68.044 Skewness = 1.861 3rd Quartile = 3.000

% cum % cls int (# of bins = 15 - bin size = 0.679)

0.00 0.38 0.161 ~ 12.31 12.60 0.839 ***********

11.54 24.05 1.518 ***********

37.69 61.45 2.196 ***********************************

-- 0.00 61.45 2.875 20.77 82.06 3.554 *******************

10.77 92.75 4.232 **********

~ 0.00 92.75 4.911 2.31 95.04 5.589 **

0.00 95.04 6.268 0.00 95.04 6.946

~- 1.54 96.56 7.625 * 1.54 98.09 8.304 * 0.00 98.09 8.982

_ 0.77 98.85 9.661 * 0.77 99.62 10.339 *

0 1 2 3 4

########################################################################

09:08:09 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = AS PPM

Mean = 0.2984

Std. Dey. = 0.3046 CV % = 102.0864

Anti-Log Mean =

Unit = N = 130

Min = -0.3010 1st Quartile = 0.3010

Max = 1.0000 Median = 0.3010

Skewness = -0.4688 3rd Quartile = 0.4771

1.988 Anti-Log Std. Dey. : (-) 0.986

(+) 4.009

cum % antilog cls int (# of bins = 15 - bin size = 0.0929)

0.00 0.38 0.449 -0.3475 ~ 12.31 12.60 0.556 -0.2546 ***********

0.00 12.60 0.689 -0.1616 0.00 12.60 0.854 -0.0687

~ 11.54 24.05 1.057 0.0242 ***********

0.00 24.05 1.310 0.1172 0.00 24.05 1.622 0.2101 37.69 61.45 2.009 0.3030 ***********************************

- 0.00 61.45 2.489 0.3960 20.77 82.06 3.082 0.4889 *******************

0.00 82.06 3.818 0.5818 ~ 10.77 92.75 4.729 0.6747 **********

2.31 95.04 5.857 0.7677 **

1.54 96.56 7.254 0.8606 * 1.54 98.09 8.985 0.9535 *

-` 1.54 99.62 11.129 1.0465 *

0 1 2 3 4

########################################################################

09:11:18 LAMOTHE HUMUS 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = AS PPM Unit = N = 130

N CI = 15

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -326.205

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 1.821 - 0.930 77.68 + 3.566

2 2.034 - 1.561 22.32 + 2.650

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.475 6.983 2 1.198 3.452

########################################################################

08:59:03

LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Unit = N = 129

Min = 0.3010 1st Quartile = 0.8451

Max = 2.3222 Median = 1.0000

Skewness = 1.2008 3rd Quartile = 1.2304

11.844 Anti-Log Std. Dey. : (-) 5.422 (+) 25.875

Variable CU PPM

Mean = 1.0735 - Std. Dey. = 0.3394

CV % = 31.6126

Anti-Log Mean =

% cum % antilog cls int (# of bins = 15 - bin size = 0.1444)

0.00 0.38 1.694 0.2288 0.78 1.15 2.362 0.3732 * 1.55 2.69 3.293 0.5176 * 3.88 6.54 4.592 0.6620 ****

10.08 16.54 6.402 0.8063 21.71 38.08 8.927 0.9507 ********************

20.93 58.85 12.447 1.0951 *******************

17.05 75.77 17.356 1.2394 ****************

10.85 86.54 24.200 1.3838 **********

5.43 91.92 33.743 1.5282 3.10 95.00 47.049 1.6726 ***

0.78 95.77 65.603 1.8169 * 0.00 95.77 91.473 1.9613 1.55 97.31 127.545 2.1057 * 0.78 98.08 177.842 2.2500 * 1.55 99.62 247.973 2.3944 *

0

########################################################################

`~

08:58:48 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = CU PPM Unit = N = 129

Mean = 18.271 Min = 2.000 1st Quartile = 7.000 Std. Dey. = 29.288 Max = 210.000 Median = 10.000

CV % = 160.294 Skewness = 4.727 3rd Quartile = 17.000

--------------------------------------------------------------------- % cum % cls int (# of bins = 15 - bin size = 14.857)

0.00 0.38 -5.429 45.74 45.77 9.429 ******************************* --> 42 41.09 86.54 24.286 *************************************

7.75 94.23 39.143 *******

0.78 95.00 54.000 *

0.78 95.77 68.857 * 0.00 95.77 83.714 0.00 95.77 98.571 0.78 96.54 113.429 * 0.78 97.31 128.286 * 0.78 98.08 143.143 * 0.00 98.08 158.000 0.00 98.08 172.857 0.00 98.08 187.714 0.78 98.85 202.571 * 0.78 99.62 217.429 *

0 1 2 3 4

########################################################################

09:00:49 LAMOTHE HUMUS 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = CU PPM Unit = N = 129

N CI = 15

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

0 Observations Were Below the Minimum Value of 0.0100 1 Observations Were Above the Maximum Value of 240.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -268.332

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 10.407 - 5.929 94.03 + 18.270

2 51.400 - 24.257 5.97 + 108.913

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 3.377 32.071 2 11.448 230.780

########################################################################

09:10:10

LAMOTHE HUMUS 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = AS PPM Unit = N = 130 N CI = 15

Transform = Logarithmic Number of Populations = 3

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -313.569

Parameterized Degrees of Freedom = 5

Population Mean Std Dev Percentage

1 0.676 - 0.500 23.52 + 0.913

2 2.107 - 1.626 60.50 + 2.730

3 4.806 - 3.813 15.98 + 6.057

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.370 1.234 2 1.255 3.537 3 3.025 7.635

########################################################################

09:02:21 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = BR PPM Unit = N = 130

Mean = 15.108 Min = 4.000 1st Quartile = 7.000 Std. Dey. = 11.100 Max = 50.000 Median = 12.000

CV % = 73.473 Skewness = 1.465 3rd Quartile = 18.500

% cum % cls int (# of bins = 15 - bin size = 3.286)

0.00 0.38 2.357 12.31 12.60 5.643 ***********

22.31 34.73 8.929 *********************

17.69 52.29 12.214 ****************

16.92 69.08 15.500 ****************

5.38 74.43 18.786 *****

6.92 81.30 22.071 ******

4.62 85.88 25.357 ****

0.77 86.64 28.643 * 0.77 87.40 31.929 * 3.08 90.46 35.214 ***

3.08 93.51 38.500 ***

1.54 95.04 41.786 * 2.31 97.33 45.071 **

0.77 98.09 48.357 * 1.54 99.62 51.643 *

0

1 2 3 4

########################################################################

09:02:27 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = BR PPM Unit = N = 130

Mean = 1.0805 Min = 0.6021 1st Quartile = 0.8451 -- Std. Dey. = 0.2880 Max = 1.6990 Median = 1.0792

CV % = 26.6554 Skewness = 0.3296 3rd Quartile = 1.2670

Anti-Log Mean = 12.037 Anti-Log Std. Dey. : (-) 6.202

(+) 23.364

T

~

r

%

0.00 4.62 7.69 7.69

10.00 9.23 4.62 8.46 16.92 5.38 6.92 4.62 1.54 6.15 3.85 2.31

cum %

0.38 4.96

12.60 20.23 30.15 39.31 43.89 52.29 69.08 74.43 81.30 85.88 87.40 93.51 97.33 99.62

antilog

3.655 4.378 5.243 6.280 7.521 9.008

10.789 12.922 15.477 18.537 22.202 26.591 31.849 38.146 45.687 54.720

cls int

0.5629 0.6412 0.7196 0.7979 0.8763 0.9546 1.0330 1.1113 1.1897 1.2680 1.3464 1.4247 1.5031 1.5814 1.6598 1.7381

(# of bins = 15 -

******* ******* ********* ******** **** ******** **************** ***** ****** **** * ****** **** **

bin size = 0.0784)

########################################################################

09:06:59 LAMOTHE HUMUS 01/ 23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = BR PPM Unit = N = 130

N CI = 15

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -336.061

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 10.522 - 6.245 90.46 + 17.727

2 36.407 - 31.271 9.54 + 42.386

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 3.707 29.867 2 26.860 49.346

########################################################################

09:06:15 LAMOTHE HUMUS 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = BR PPM Unit = N = 130

N CI = 15

Transform = Logarithmic Number of Populations = 3

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -328.852

Parameterized Degrees of Freedom = 5

Population Mean Std Dev Percentage

1 6.013 - 4.568 42.04 + 7.914

2 15.183 - 11.377 46.54 + 20.263

3 35.613 - 30.576 11.43 + 41.480

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 3.470 10.417 2 8.525 27.043 3 26.251 48.314

########################################################################

08:56:07 LAMOTHE HUMUS 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = NA PPM Unit = N = 130

Mean = 2622.215 Min = 105.000 1st Quartile = 579.500 Std. Dey. = 3350.317 Max = 18100.000 Median = 1470.000

0 = 127.767 Skewness = 2.616 3rd Quartile = 3025.000 CV %

------------------------------------------------------------ % cum % cls int (# of bins = 12 - bin size = 1635.909)

0.00 0.38 -712.955 **********************************

36.92 37.02 922.955 ******************************

32.31 69.08 2558.864 *************

14.62 83.59 4194.773 ***

3.08 86.64 5830.682 ****

4.62 91.22 7466.591 ****

3.85 95.04 9102.500

1.54 96.56 10738.409 *

0.77 97.33 12374.318 *

0.00 97.33 14010.227

0.00 97.33 15646.136

0.77 98.09 17282.045 *

1.54 99.62 18917.955 *

0 1

2

3 4

########################################################################

08:57:34 LAMOTHE HUMUS 01/24/91

######################################################################## -- SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = NA PPM Unit = N = 130

Mean = 3.1405 Min = 2.0212 1st Quartile = 2.7631 Std. Dey. = 0.5088 Max = 4.2577 Median = 3.1673

CV % = 16.2004 Skewness = 0.0025 3rd Quartile = 3.4807

%

0.00 0.77 5.38 8.46 7.69

11.54 13.85 16.92 14.62 6.92 8.46 3.08 2.31

Anti-Log Mean

cum % antilog

0.38 83.087

1.15 132.693

6.49 211.917

14.89 338.440

22.52 540.505

33.97 863.211

47.71 1378.586

64.50 2201.665

79.01 3516.158

85.88 5615.463

94.27 8968.148

97.33 14322.538 99.62 22873.740

= 1381.834 Anti-Log Std.

cls int (# of bins = 12 -

1.9195 2.1228

***** 2.3262 ******** 2.5295 ******* 2.7328 *********** 2.9361 ************* 3.1394

3.3428 **************** ************* 3.5461 ****** 3.7494

3.9527 ********

4.1560 *** ** 4.3593

Dey. : (-) (+)

bin size =

428.243 4458.841

0.2033)

0

1 2 3 4

########################################################################

09:00:04 LAMOTHE HUMUS 01/24/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

-- Variable = NA PPM Unit = N = 130

N CI = 12

Transform = Logarithmic Number of Populations = 3-

# of Missing Observations = 0.

_ Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -285.083

Parameterized Degrees of Freedom = 5

Population Mean Std Dev Percentage

1 273.437 - 176.183 20.59 + 424.377

2 1542.573 - 791.578 66.88 + 3006.063

3 7055.066 - 5098.347 12.53 + 9762.764

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 113.519 658.637 2 406.201 5858.012 3 3684.324 13509.661

########################################################################

09:05:16 LAMOTHE HUMUS 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = SC PPM Unit = N = 130

Mean = 2.502 Min = 0.200 1st Quartile = 0.700 Std. Dey. = 2.933 Max = 16.000 Median = 1.500

CV % = 117.207 Skewness = 2.521 3rd Quartile = 2.800

% cum % cls int (# of bins = 15 - bin size = 1.129)

0.00 0.38 -0.364 ***********************

25.38 25.57 0.764 ********************************

34.62 59.92 1.893 ***************

16.15 75.95 3.021 *******

7.69 83.59 4.150 ****

3.85 87.40 5.279 ****

3.85 91.22 6.407 **

2.31 93.51 7.536

0.77 94.27 8.664 *

1.54 95.80 9.793 *

0.00 95.80 10.921

1.54 97.33 12.050 *

0.77 98.09 13.179 *

0.00 98.09 14.307

0.00 98.09 15.436

1.54 99.62 16.564 *

0 1 2 3 4

########################################################################

09:05:26 LAMOTHE HUMUS 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM

Variable = SC PPM Unit =

Mean = 0.1811 Min = -0.6990 1st Std. Dey. = 0.4306 Max = 1.2041

CV % = 237.8020 Skewness = 0.2433 3rd

LOGARITHMIC VALUES

N = 130

Quartile = -0.1549

Median = 0.1761

Quartile = 0.4472

Anti-Log Mean = 1.517 Anti-Log Std. Dey. : (-) 0.563 (+) 4.089

cum % antilog cls int (# of bins = 15 - bin size = 0.1359)

0.00 0.38 0.171 -0.7669 0.77 1.15 0.234 -0.6310 * 5.38 6.49 0.320 -0.4951 ***** 6.15 12.60 0.437 -0.3591 ****** 5.38 17.94 0.598 -0.2232 *****

12.31 30.15 0.818 -0.0873 *********** 10.00 40.08 1.119 0.0487 ********* 11.54 51.53 1.530 0.1846 *********** 10.00 61.45 2.092 0.3205 ********* 13.85 75.19 2.861 0.4565 ************* 5.38 80.53 3.912 0.5924 ***** 7.69 88.17 5.350 0.7283 ******* 4.62 92.75 7.316 0.8643 **** 3.08 95.80 10.005 1.0002 *** 2.31 98.09 13.682 1.1362 ** 1.54 99.62 18.711 1.2721 *

0

1 2 3 4

########################################################################

09:09:57 LAMOTHE HUMUS 01/24/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = SC PPM Unit = N = 130

N CI = 15

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -324.564

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 1.378 - 0.552 96.28 + 3.440

2 8.661 - 7.007 3.72 + 10.704

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.221 8.589 2 5.670 13.230

########################################################################

09:08:53 LAMOTHE HUMUS 01/24/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = SC PPM Unit = N = 130

N CI = 15

Transform = Logarithmic Number of Populations = 3

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -321.633

Parameterized Degrees of Freedom = 5

Population Mean Std Dev Percentage

1 0.317 - 0.255 9.88 + 0.395

2 1.224 - 0.643 67.82 + 2.331

3 4.888 - 2.925 22.30 + 8.168

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.204 0.492 2 0.338 4.438 3 1.751 13.649

########################################################################

09:23:13 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = U PPM Unit = N = 129

Mean = 0.797 Min = 0.050 1st Quartile = 0.050 Std. Dey. = 1.407 Max = 8.000 Median = 0.300

CV % = 176.505 Skewness = 2.965 3rd Quartile = 0.700

-------------------- ----------------------------------------

% cum cum cls int (# of bins = 12 - bin size = 0.723)

0.00 0.38 -0.311 64.34 64.23 0.411 ******************************* --> 59 18.60 82.69 1.134 *****************

6.20 88.85 1.857 ******

1.55 90.38 2.580 * 2.33 92.69 3.302 **

1.55 94.23 4.025 * 0.00 94.23 4.748 2.33 96.54 5.470 **

1.55 98.08 6.193 * 0.78 98.85 6.916 * 0.00 98.85 7.639 0.78 99.62 8.361 *

0 1 2 3 4

########################################################################

09:22:44 LAMOTHE HUMUS 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = U PPM Unit = N = 129

Mean = -0.5575 Min = -1.3010 1st Quartile = -1.3010 Std. Dey. = 0.6309 Max = 0.9031 Median = -0.5229

CV % = 113.1698 Skewness = 0.3488 3rd Quartile = -0.1549

Anti-Log Mean = 0.277 Anti-Log Std. Dey. : (-) 0.065 (+) 1.184

% cum % antilog cls int (# of bins = 12 - bin size = 0.2004)

0.00 0.38 0.040 -1.4012 31.01 31.15 0.063 -1.2008 ****************************

0.00 31.15 0.100 -1.0005 3.10 34.23 0.158 *** -0.8001

12.40 46.54 0.251 -0.5997 ***********

10.08 56.54 0.399 -0.3993 *********

13.95 70.38 0.632 -0.1990 *************

12.40 82.69 1.003 0.0014 ***********

5.43 88.08 1.591 0.2018 *****

2.33 90.38 2.524 ** 0.4022 3.88 94.23 4.004 0.6025 ****

3.88 98.08 6.352 0.8029 ****

1.55 99.62 10.076 1.0033 *

0 1 2 3 4

########################################################################

09:26:38 LAMOTHE HUMUS 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = U PPM Unit = N =

129

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

0 Observations Were Below the Minimum Value of 0.0010 1 Observations Were Above the Maximum Value of 9.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -317.886

Parameterized Degrees of Freedom = 3

'Population Mean Std Dev Percentage

1 0.220 - 0.065 93.69 + 0.747

2 3.869 - 2.623 6.31 + 5.709

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.019 2.531 2 1.778 8.422

########################################################################

09:25:43 LAMOTHE HUMUS 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = U PPM Unit = N = 129

N CI = 12

Transform = Logarithmic Number of Populations = 3

# of Missing Observations = 0.

-- 0 Observations Were Below the Minimum Value of 0.0010 1 Observations Were Above the Maximum Value of 9.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -264.046

Parameterized Degrees of Freedom = 5

Population Mean Std Dev Percentage

1 0.050 - 0.044 31.40 + 0.058

2 0.442 - 0.230 59.27 + 0.853

3 3.507 - 2.323 9.33 + 5.294

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.038 0.067 2 0.119 1.643 3 1.539 7.990

########################################################################

15:26:14 LAMOTHE HUMUS LA & BA 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = LA PPM

Unit = N = 129

Mean = 11.937 Min = 1.000 1st Quartile = 2.900 — Std. Dey. = 18.382 Max = 100.000 Median = 5.500

CV % = 153.991 Skewness = 3.134 3rd Quartile = 12.250

cum % cls int (# of bins = 12 - bin size = 9.000)

0.00 0.38 49.61 49.62 28.68 78.08 10.08 88.08 3.88 91.92 0.78 92.69 1.55 94.23 1.55 95.77 0.00 95.77 0.00 95.77 2.33 98.08 0.78 98.85 0.78 99.62

-3.500 5.500 14.500 23.500 32.500 41.500 50.500 59.500 68.500 77.500 86.500 95.500

104.500

******************************* ************************** ********* **** * * *

** * *

--> 45

0 1 2 3 4

########################################################################

N = 129

Quartile = 0.4624 Median = 0.7403

Quartile = 1.0879

Dey. : (-) 2.207 (+) 17.890

bin size = 0.1818)

Variable = LA PPM

Unit =

Mean = 0.7982

Min = 0.0000 1st

Std. Dey. = 0.4544

Max = 2.0000

CV % = 56.9346

Skewness = 0.6566 3rd

Anti-Log Mean = 6.283 Anti-Log Std.

cum %

antilog cls int (# of bins = 12 -

15:26:26 LAMOTHE HUMUS LA & BA 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

0.00 0.38 0.811 -0.0909 3.88 4.23 1.233 0.0909 4.65 8.85 1.874 0.2727 ****

13.95 22.69 2.848 0.4545 *************

19.38 41.92 4.329 0.6364 ******************

15.50 57.31 6.579 0.8182 **************

14.73 71.92 10.000 1.0000 *************

10.08 81.92 15.199 1.1818 *********

6.20 88.08 23.101 1.3636 ******

4.65 92.69 35.112 1.5455 ****

2.33 95.00 53.367 1.7273 **

2.33 97.31 81.113 1.9091 **

2.33 99.62 123.285 2.0909 **

0 1 2 3 4

########################################################################

15:28:56 LAMOTHE HUMUS LA & BA 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUMLA.DAT

Variable = LA PPM Unit = N = 129

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

0 Observations Were Below the Minimum Value of 0.1000 1 Observations Were Above the Maximum Value of 102.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -279.186

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1

5.312 - 2.266

95.61

+ 12.452

49.197 - 37.271

4.39

+ 64.939

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.967 29.190 2 28.236 85.717

########################################################################

09:20:50 LAMOTHE HUMUS 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = CR PPM

Unit = N = 130

Mean = 16.150

Min = 0.500 1st Quartile = 5.000

Std. Dey. = 20.776

Max = 160.000 Median = 8.000 ~ CV % _ 128.645 Skewness = 3.437 3rd Quartile = 19.500

% cum % cls int (# of bins = 15 - bin size = 11.393)

0.00 0.38 r

39.23 39.31 31.54 70.61 13.85 84.35 5.38 89.69 4.62 94.27 1.54 95.80 2.31 98.09 0.77 98.85 0.00 98.85 0.00 98.85 0.00 98.85 0.00 98.85 0.00 98.85 0.00 98.85

- 0.77 99.62

-5.196 6.196 17.589 28.982 40.375 51.768 63.161 74.554 85.946 97.339

108.732 120.125 131.518 142.911 154.304 165.696

************************************ ***************************** ************* ***** **** * ** *

*

0 1 2 3 4

########################################################################

09:21:02 LAMOTHE HUMUS 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = CR PPM Unit = N = 130

Mean = 0.9643 Min = -0.3010 1st Quartile = 0.6990

Std. Dey. = 0.4627 Max = 2.2041 Median = 0.9031

CV % = 47.9842 Skewness = 0.0838 3rd Quartile = 1.2899

Anti-Log Mean = 9.211 Anti-Log Std. Dey. : (-) 3.174

(+) 26.733

cum % antilog cls int (# of bins = 15 - bin size = 0.1789)

0.00 0.38 0.407 -0.3905 0.77 1.15 0.614 -0.2116 * 0.00 1.15 0.928 -0.0326 2.31 3.44 1.401 0.1463 ** 6.92 10.31 2.115 0.3253 ****** 9.23 19.47 3.193 0.5042 ******** 3.85 23.28 4.821 0.6831 ****

22.31 45.42 7.279 0.8621 ********************* 10.77 56.11 10.990 1.0410 ********** 14.62 70.61 16.594 1.2200 ************* 10.00 80.53 25.055 1.3989 ********* 7.69 88.17 37.830 1.5778 ******* 6.15 94.27 57.118 1.7568 ****** 4.62 98.85 86.240 1.9357 **** 0.00 98.85 130.212 2.1147 0.77 99.62 196.603 2.2936 *

0

1 2 3 4

########################################################################

09:22:27 LAMOTHE HUMUS 01/24/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM.DAT

Variable = CR PPM Unit = N = 130

N CI = 15

Transform = Logarithmic Number of Populations = 3

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -302.659

Parameterized Degrees of Freedom = 5

Population Mean Std Dey Percentage

1 1.976 - 1.190 15.91 + 3.283

2 9.347 - 4.629 70.67 + 18.874

3 45.688 - 32.226 13.43 + 64.773

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.716 5.453 2 2.293 38.112 3 22.731 91.830

########################################################################

11:44:52 LAMOTHE HUMUS 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = FE % Unit = N = 130

Mean = 0.861 Min = 0.070 1st Quartile = 0.170 Std. Dey. = 1.309 Max = 5.890 Median = 0.320

CV % _ 152.101 Skewness = 2.398 3rd Quartile = 0.755

% cum % cls int (# of bins = 12 - bin size = 0.529)

0.00 0.38 -0.195 ******************************* --> 49

53.08 53.05 0.335 ***********************

24.62 77.48 0.864

6.15 83.59 1.393 ******

2.31 85.88 ** 1.922 ***

3.08 88.93 2.451 **

2.31 91.22 2.980

1.54 92.75 3.509 *

1.54 94.27 4.038 *

0.77 95.04 4.567 *

1.54 96.56 5.096 *

1.54 98.09 5.625 *

1.54 99.62 6.155 *

0 1 2 3 4

########################################################################

11:44:52 LAMOTHE HUMUS 01/24/91

-- ######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

0 Unit =

Variable = FE % N = 130

Mean = 0.861 Min = 0.070 1st Quartile = 0.170 Std. Dey. = 1.309 Max = 5.890 Median = 0.320

CV % _ 152.101 Skewness = 2.398 3rd Quartile = 0.755

% cum % cls int (# of bins = 12 - bin size = 0.529)

0.00 0.38 -0.195 ******************************* --> 49

53.08 53.05 0.335 ***********************

24.62 77.48 0.864 ******

6.15 83.59 1.393 **

2.31 85.88 1.922 ***

3.08 88.93 2.451 **

2.31 91.22 2.980

1.54 92.75 3.509 *

1.54 94.27 4.038 *

0.77 95.04 4.567 *

1.54 96.56 5.096 *

1.54 98.09 5.625 *

1.54 99.62 6.155 *

0

1 2 3 4

########################################################################

11:46:08 LAMOTHE HUMUS 01/24/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMHUM2.DAT

Variable = FE % Unit = N = 130

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -279.158

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 0.285 - 0.132 89.61 + 0.615

2 2.763 - 1.956 10.39 + 3.902

Default Thresholds.

Standard Deviation Multiplier = 2.0

_-. Pop. Thresholds

1 0.061 1.328 2 1.385 5.512

########################################################################

APPENDIX 4

HISTOGRAMS AND THRESHOLD CALCULATIONS FOR Au, As, Br, Cr, Cu, Fe, Na, Sc, La and U FOR BARK

09:35:51 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = AU PPB Unit = N = 116

Mean = 0.984

Min = 0.100 1st Quartile = 0.500 -- Std. Dey. = 1.346

Max = 9.600 Median = 0.700 CV % = 136.697

Skewness = 4.710 3rd Quartile = 1.000

cum % cls int (# of bins = 12 - bin size = 0.864)

0.00 0.43 -0.332 � 34.48 34.62 0.532

50.86 85.04 1.395

9.48 94.44 2.259 — 1.72 96.15 3.123

0.00 96.15 3.986

0.86 97.01 4.850 p 0.00 97.01 5.714

0.00 97.01 6.577

0.86 97.86 7.441

0.00 97.86 8.305 -- 0.86 98.72 9.168

0.86 99.57 10.032

**************************** ******************************* ******** *

*

*

* *

--> 42

0 1 2 3 4

########################################################################

09:36:05 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = AU PPB Unit = N = 116

1st Quartile = -0.3010 Median = -0.1549

3rd Quartile = 0.0000

Std. Dey. : (-) 0.314 (+) 1.478

Mean = -0.1668

Min = -1.0000

Std. Dey. = 0.3364

Max 0.9823

CV % = 201.6400

Skewness 0.5816

Anti-Log Mean = 0.681 Anti-Log

% cum % antilog cls int (# of bins = 12 - bin size = 0.1802)

0.00 0.43 0.081 -1.0901

0.86 1.28 0.123 -0.9099 *

0.00 1.28 0.186 -0.7297

11.21 12.39 0.282 -0.5495 ~ 12.93 25.21 0.427 -0.3693

20.69 45.73 0.647 -0.1891

28.45 73.93 0.980 -0.0089 - 12.93 86.75 1.484 0.1713

7.76 94.44 2.247 0.3515

1.72 96.15 3.402 0.5318 w 0.86 97.01 5.152 0.7120

0.86 97.86 7.801 0.8922

1.72 99.57 11.813 1.0724

0 1 2 3 4

########################################################################

***********

*****************

***********************

***********

******

* * * *

09:38:01

LAMOTHE BLACK SPRUCE BARK 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK.DAT

Variable = AU PPB Unit = N = 116

N CI = 12

— Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

0 Observations Were Below the Minimum Value of 0.0010

1 Observations Were Above the Maximum Value of 11.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -218.508

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 0.638 - 0.341 96.90 + 1.196

2 2.744 - 1.450 3.10 + 5.192

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.182 2.242 2 0.766 9.826

########################################################################

--

09:39:07 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM

Variable = AS PPM Unit =

Mean = 0.354 Min = 0.150 1st Std. Dey. = 0.097 Max = 0.630

CV % = 27.424 Skewness = 0.222 3rd

----------------------------------------------------------------

ARITHMETIC VALUES

N = 117

Quartile = 0.280

Median = 0.360

Quartile = 0.413

% cum % cls int (# of bins = 12 - bin size = 0.044)

0.00 0.42 0.128 0.85 1.27 0.172 5.98 7.20 0.215

10.26 17.37 0.259 ********

16.24 33.47 0.303 *************

13.68 47.03 0.346 ***********

20.51 67.37 0.390 *****************

11.97 79.24 0.434 **********

9.40 88.56 0.477 ********

6.84 95.34 0.521 ******

2.56 97.88 0.565 **

0.85 98.73 0.608 * 0.85 99.58 0.652 *

########################################################################

09:39:14

LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM

Variable = AS PPM Unit =

Mean = -0.4677 Min = -0.8239 1st Std. Dey. = 0.1253 Max = -0.2007

CV % = 26.7974 Skewness = -0.4292 3rd

Anti-Log Mean = 0.341 Anti-Log Std.

cum % antilog cls int (# of bins = 12 -

0.00 0.42 0.141 -0.8522

0.85 1.27 0.160 -0.7956

0.85 2.12 0.182 -0.7389 *

4.27 6.36 ****

0.208 -0.6823

6.84 13.14 ******

0.237 -0.6256

5.98 19.07 *****

0.270 -0.5689

14.53 33.47 ************

0.307 -0.5123

15.38 48.73 *************

0.350 -0.4556

18.80 67.37 0.399 -0.3990 ****************

17.95 85.17 ***************

0.455 -0.3423

9.40 94.49 0.518 -0.2856 ********

4.27 98.73 ****

0.590 -0.2290

0.85 99.58 0.672 -0.1723

LOGARITHMIC VALUES

N = 117

Quartile = -0.5528

Median = -0.4437

Quartile = -0.3846

Dey. : (-) 0.255

(+) 0.455

bin size = 0.0567)

0 1 2 3 4

########################################################################

--

_ 09:40:02 LAMOTHE BLACK SPRUCE BARK 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK.DAT

Variable = AS PPM Unit = N = 117

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -249.565

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 0.220 - 0.188 16.48 + 0.258

2 0.370 - 0.301 83.52 + 0.455

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.160 0.302 2 0.245 0.559

########################################################################

09:40:29 LAMOTHE BLACK SPRUCE BARK 01/23/91 —

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = BR PPM Unit = N = 117

Mean = 11.356 Min = 4.800 1st Quartile = 9.850 Std. Dey. = 2.375 Max = 17.000 Median = 11.000

% Skewness = CV = 20.913 -0.153 3rd Quartile = 13.000

% cum cls int (# of bins = 12 - bin size = 1.109)

0.00 0.42 4.245 0.85 1.27 5.355 * 1.71 2.97 6.464 * 3.42 6.36 7.573 ***

7.69 13.98 8.682 ******

11.11 25.00 9.791 *********

9.40 34.32 10.900 ********

32.48 66.53 12.009 ***************************

13.68 80.08 13.118 ***********

10.26 90.25 14.227 ********

6.84 97.03 15.336 ******

1.71 98.73 16.445 * 0.85 99.58 17.555 *

0 1 2 3 4

########################################################################

--

000.

_.

_

09:40:35 LAMOTHE BLACK SPRUCE BARK 01/23/91

########################################################################

®

SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = BR PPM Unit = N = 117

Mean = 1.0449 Min = 0.6812 1st Quartile = 0.9934 Std. Dey. = 0.0978 Max = 1.2304 Median = 1.0414

CV % = 9.3621 Skewness = -0.8008 3rd Quartile = 1.1139

Anti-Log Mean = 11.090 Anti-Log Std. Dey. : (-) 8.853 (+) 13.892

% cum % antilog cls int (# of bins = 12 - bin size = 0.0499)

0.00 0.42 4.532 0.6563 0.85 1.27 5.084 0.7062 0.00 1.27 5.703 0.7561 0.85 2.12 6.398 0.8061

-- 1.71 3.81 7.178 0.8560 4.27 8.05 8.052 0.9059 **** 8.55 16.53 9.033 0.9558 *******

_ 17.95 34.32 10.134 1.0058 *************** 18.80 52.97 11.368 1.0557 **************** 13.68 66.53 12.753 1.1056 ***********

~ 23.93 90.25 14.307 1.1556 ******************** 8.55 98.73 16.050 1.2055 ******* 0.85 99.58 18.006 1.2554

0 1 2 3 4

########################################################################

09:42:05 LAMOTHE BLACK SPRUCE BARK 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK.DAT

Variable = BR PPM Unit = N = 117

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -233.833

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 9.891 - 8.217 65.01 + 11.907

2 13.446 - 12.273 34.99 + 14.731

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 6.826 14.333 2 11.202 16.139

########################################################################

09:45:24 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = NA PPM Unit = N = 116

Mean = 48.338 Min = 27.200 1st Quartile = 40.500 Std. Dey. = 11.310 Max = 84.300 Median = 46.000

CV % = 23.398 Skewness = 0.941 3rd Quartile = 54.100

% cum % cls int (# of bins = 12 - bin size = 5.191)

0.00 0.43 24.605 1.72 2.14 29.795 5.17 7.26 34.986 ****

16.38 23.50 40.177 *************

24.14 47.44 45.368 ********************

14.66 61.97 50.559 ************

17.24 79.06 55.750 **************

8.62 87.61 60.941 *******

3.45 91.03 66.132 ***

4.31 95.30 71.323 ****

1.72 97.01 76.514 * 0.86 97.86 81.705 * 1.72 99.57 86.895 *

0 1 2 3 4

########################################################################

-

--

09:45:35

LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM

Variable = NA PPM Unit =

Mean = 1.6733 Min = 1.4346 1st Std. Dey. = 0.0973 Max = 1.9258

CV % = 5.8120 Skewness = 0.2900 3rd

Anti-Log Mean = 47.126 Anti-Log Std.

% cum % antilog cls int (# of bins = 12 -

0.00 0.43 25.837 1.4122

1.72 2.14 28.635 1.4569

0.86 2.99 31.736 1.5016 * ****

4.31 7.26 35.174 1.5462

12.93 20.09 38.983 *********** 1.5909

18.10 38.03 43.205 1.6355 ***************

18.97 56.84 47.885 **************** 1.6802

14.66 71.37 53.071 ************ 1.7249

14.66 85.90 58.819 ************ 1.7695

4.31 90.17 65.190 **** 1.8142

5.17 95.30 72.250 **** 1.8588

2.59 97.86 80.075 ** 1.9035

1.72 99.57 88.748 1.9482 *

LOGARITHMIC VALUES

N = 116

Quartile = 1.6075

Median = 1.6628

Quartile = 1.7332

Dey. : (-) 37.671

(+) 58.954

bin size = 0.0447)

0 1 2 3 4

########################################################################

09:47:09 LAMOTHE BLACK SPRUCE BARK 01/ 23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK.DAT

Variable = NA PPM Unit = N = 116

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

0 Observations Were Below the Minimum Value of 0.1000

1 Observations Were Above the Maximum Value of 90.0000

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -243.931

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 43.948 - 36.874 83.61 + 52.379

2 61.485 - 53.727 16.39 + 70.363

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 30.939 62.428 2 46.948 80.524

########################################################################

09:47:35 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = SC PPM Unit = N = 117

Mean = 0.046 Min = 0.020 1st Quartile = 0.040 Std. Dey. = 0.013 Max = 0.080 Median = 0.045

CV % = 27.928 Skewness = 0.506 3rd Quartile = 0.050

% cum % cls int (# of bins = 12 - bin size = 0.005)

0.00 0.42 0.017 1.71 2.12 0.023 * 0.00 2.12 0.028 17.95 19.92 0.034 ***************

0.00 19.92 0.039 29.91 49.58 0.045 *************************

29.06 78.39 0.050 ************************

0.00 78.39 0.055 11.97 90.25 0.061 **********

0.00 90.25 0.066 6.84 97.03 0.072 ******

0.00 97.03 0.077 2.56 99.58 0.083 **

0 1 2 3 4

########################################################################

~-

--

09:47:40 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = SC PPM Unit = N = 117

Mean = -1.3519 Min = -1.6990 1st Quartile = -1.3979 Std. Dey. = 0.1232 Max = -1.0969 Median = -1.3495

CV % = 9.1093 Skewness = -0.2105 3rd Quartile = -1.3010

Anti-Log Mean = 0.044 Anti-Log Std. Dey. : (-) 0.033 (+) 0.059

% cum % antilog cls int (# of bins = 12 - bin size = 0.0547)

0.00 0.42 0.019 -1.7263 1.71 2.12 0.021 -1.6716 0.00 2.12 0.024 -1.6169 0.00 2.12 0.027 -1.5621 17.95 19.92 0.031 -1.5074 *************** 0.00 19.92 0.035 -1.4527 0.00 19.92 0.040 -1.3979 29.91 49.58 0.045 -1.3432 ************************* 29.06 78.39 0.051 -1.2885 ************************ 0.00 78.39 0.058 -1.2337 11.97 90.25 0.066 -1.1790 ********** 6.84 97.03 0.075 -1.1243 ****** 2.56 99.58 0.085 -1.0695 **

0 1 2 3 4

########################################################################

09:42:59 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM

Variable = CR PPM Unit =

Mean = 0.704 Min = 0.100 1st Std. Dey. = 0.246 Max = 1.200

CV % = 34.948 Skewness = -0.730 3rd

ARITHMETIC VALUES

N = 114

Quartile = 0.600

Median = 0.700

Quartile = 0.900

% cum % cls int (# of bins = 12 - bin size = 0.100)

0.00 0.43 0.050 7.02 7.39 0.150 0.00 7.39 0.250 1.75 9.13 0.350 *

1.75 10.87 0.450 *

11.40 22.17 0.550 ********* 13.16 35.22 0.650 *********** 17.54 52.61 0.750 ************** 19.30 71.74 0.850 **************** 15.79 87.39 0.950 ************* 7.02 94.35 1.050 ****** 3.51 97.83 1.150 *** 1.75 99.57 1.250 *

0 1 2 3 4

########################################################################

09:43:36 LAMOTHE BLACK SPRUCE BARK 01/23/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM LOGARITHMIC VALUES

Variable = CR PPM Unit = N = 114

~- Mean = -0.2001 Min = -1.0000 1st Quartile = -0.2218 Std. Dey. = 0.2482 Max = 0.0792 Median = -0.1549

CV % = 124.0072 Skewness = -2.2785 3rd Quartile = -0.0458

Anti-Log Mean = 0.631 Anti-Log Std. Dey. : (-) 0.356

(+) 1.117

% cum % antilog cls int (# of bins = 12 - bin size = 0.0981)

_ 0.00 0.43 0.089 -1.0491 7.02 7.39 0.112 -0.9509 0.00 7.39 0.140 -0.8528

~ 0.00 7.39 0.176 -0.7547 0.00 7.39 0.220 -0.6566 0.00 7.39 0.276 -0.5585 1.75 9.13 0.346 -0.4604 *

-- 1.75 10.87- 0.434 -0.3623 * 11.40 22.17 0.544 -0.2642 *********

13.16 35.22 0.682 -0.1661 ***********

36.84 71.74 0.855 -0.0680 ******************************

22.81 94.35 1.072 0.0301 ******************

5.26 99.57 1.343 0.1282 ****

0 1 2 3 4

########################################################################

09:44:27 LAMOTHE BLACK SPRUCE BARK 01/23/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK.DAT

Variable = CR PPM Unit = N = 114

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 3.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -196.766

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 0.110 - 0.075 8.13 + 0.163

2 0.721 - 0.566 91.87 + 0.918

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.050 0.242 2 0.445 1.168

########################################################################

11:59:07 LAMOTHE BLACK SPRUCE BARK 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM ARITHMETIC VALUES

Variable = FE Unit = N = 116

Mean = 0.021 Min = 0.011 1st Quartile = 0.018

Std. Dey. = 0.004 Max = 0.034 Median = 0.021 —

CV % = 21.004 Skewness = 0.409 3rd Quartile = 0.023

cum % cls int

(# of bins = 12 - bin size = 0.002)

0.00 0.43 0.86 1.28 4.31 5.56

11.21 16.67 17.24 33.76 12.07 45.73 17.24 62.82 19.83 82.48

-- 7.76 90.17 4.31 94.44 2.59 97.01 0.86 97.86 1.72 99.57

0.010 0.012 0.014 0.016 0.018 0.020 0.023 0.025 0.027 0.029 0.031 0.033 0.035

0 1 2 3 4

########################################################################

--

11:59:14 LAMOTHE BLACK SPRUCE BARK 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM

Variable = FE Unit =

Mean = -1.6891 Min = -1.9586 1st Std. Dey. _ 0.0922 Max = -1.4685

CV % _ 5.4605 Skewness = -0.2011 3rd

Anti-Log Mean = 0.020 Anti-Log Std.

% cum % antilog cls int (# of bins = 12 -

0.00 0.43 0.010 -1.9809

0.86 1.28 0.012 -1.9363

0.00 1.28 0.013 -1.8918 ****

4.31 5.56 0.014 -1.8472 ****

4.31 9.83 0.016 -1.8027 ************

14.66 24.36 0.017 -1.7581 ************

14.66 38.89 0.019 -1.7136 *************

15.52 54.27 0.021 -1.6690 ******************

21.55 75.64 0.024 -1.6245 ************

14.66 90.17 0.026 -1.5799 *****

6.03 96.15 0.029 -1.5354

1.72 97.86 0.032 -1.4908 *

1.72 99.57 0.036 -1.4462 *

LOGARITHMIC VALUES

N = 116

Quartile = -1.7447

Median = -1.6778

Quartile = -1.6383

Dey. : (-) 0.017

(+) 0.025

bin size = 0.0446)

0 1 2 3 4

########################################################################

C

12:00:05 LAMOTHE BLACK SPRUCE BARK 01/24/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK2.DAT

Variable = FE Unit = N = 116

N CI = 12

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

0 Observations Were Below the Minimum Value of 0.0010

1 Observations Were Above the Maximum Value of 0.0400

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -237.113

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 0.017 - 0.015 36.77 + 0.019

2 0.023 - 0.020 63.23 + 0.026

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.013 0.022 2 0.017 0.029

########################################################################

13:45:18

LAMOTHE BLACK SPRU CE BARK 01/24/91

###################### #################### ############################## SUMMARY STATISTICS and HISTOGRAM

ARITHMETIC VALUES

Variable =

Mean = Std. Dey. =

CV % =

% cum %

0.00 0.42

1.71 2.12

6.84 8.90

2.56 11.44

11.97 23.31

16.24 39.41

8.55 47.88

20.51 68.22

5.13 73.31

11.97 85.17

4.27 89.41

3.42 92.80

1.71 94.49

3.42 97.88

0.85 98.73

0.85 99.58

LA PPM

0.179 0.047 26.156

cls int

0.082 0.098 0.114 0.129 0.145 0.161 0.176 0.192 0.208 0.224 0.239 0.255 0.271 0.286 0.302 0.318

Unit =

Min = 0.090 1st

Max = 0.310

Skewness = 0.429 3rd

(# of bins = 15 -

**

**********

*************

*******

*****************

****

**********

****

***

* * * *

* *

N

Quartile Median

Quartile

bin size

=

= = =

=

117

0.150 0.180 0.210

0.016)

0

1

2

3 4

########################################################################

13:45:22 LAMOTHE BLACK SPRUCE BARK 01/24/91

######################################################################## SUMMARY STATISTICS and HISTOGRAM

Variable = LA PPM Unit =

Mean = -0.7624 Min = -1.0458 1st Std. Dey. = 0.1161 Max = -0.5086

CV % = 15.2261 Skewness = -0.2569 3rd

Anti-Log Mean = 0.173 Anti-Log Std.

% cum % antilog cls int (# of bins = 15 -

0.00 0.42 0.086 -1.0649

1.71 2.12 0.094 -1.0266 * ***

3.42 5.51 0.103 -0.9882 ***

3.42 8.90 0.112 -0.9498 **

2.56 11.44 0.123 -0.9115 ******

7.69 19.07 0.134 -0.8731

4.27 23.31 0.146 -0.8347 **** ********

10.26 33.47 0.160 -0.7964

14.53 47.88 0.175 -0.7580 ************ *****************

20.51 68.22 0.191 -0.7196 ****

5.13 73.31 0.208 -0.6813 **********

11.97 85.17 0.228 -0.6429 ****

4.27 89.41 0.249 -0.6046 ****

5.13 94.49 0.272 -0.5662

3.42 97.88 0.297 -0.5278 ***

1.71 99.58 0.324 -0.4895 *

LOGARITHMIC VALUES

N = 117

Quartile = -0.8239

Median = -0.7447

Quartile = -0.6778

Dey. : (-) 0.132

(+) 0.226

bin size = 0.0384)

0 1 2 3 4

########################################################################

15:07:15 LAMOTHE BLACK SPRUCE BARK 01/ 25/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK.DAT

Variable = LA PPM Unit = N = 117

N CI = 15

Transform = Logarithmic Number of Populations = 2

# of Missing Observations = 0.

Raw Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = 87.273

Parameterized Degrees of Freedom = 3

Population Mean Std Dev Percentage

1 0.164 - 0.124 72.78 + 0.217

2 0.197 - 0.168 27.22 + 0.231

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.094 0.288 2 0.143 0.271

########################################################################

13:46:11 LAMOTHE BLACK SPRUCE BARK 01/24/91

########################################################################

PARAMETER SUMMARY STATISTICS FOR PROBABILITY PLOT ANALYSIS

Data File Name = D:\PROBDAT\LAMBARK.DAT

Variable = LA PPM Unit = N = 117

N CI = 15

Transform = Logarithmic Number of Populations = 3

# of Missing Observations = 0.

Class Interval Data Maximum Likelihood Parameter Estimates

Maximum LN Likelihood Value = -284.700

Parameterized Degrees of Freedom = 5

Population Mean Std Dev Percentage

1 0.117 - 0.102 21.27 + 0.134

2 0.172 - 0.154 52.57 + 0.192

3 0.231 - 0.203 26.16 + 0.262

Default Thresholds.

Standard Deviation Multiplier = 2.0

Pop. Thresholds

1 0.088 0.154 2 0.138 0.215 3 0.179 0.297

########################################################################

APPENDIX 5

PROFILES FOR SELECTED ELEMENTS, BY LINES SHOWING 2

I

30 35 40 45 510 50 55 DUPLICATE

Line position (m) 65 60 0 10 10 20

DUPLICATE

AU PPB 1 AS PPM < CR PPM I FE*10 %

r--

LAMOTHE HUMUS SH2 LINE 1 AU, AS, CR & FE

AU

PP

B, A

S PP

M, F

E*1

0 %

LAMOTHE HUMUS SH2 LINE 1 AU, BR, Sc & LA

30

-25

-20

CO

-15 CL

-10

-5

25-

20

a: CO

5

0 0 10 10 20 30 40 45 50 50 55 60 65 70 80 90 100

DUPLICATE DURLICATE Line position (m)

--I- AU PPB --H- BR PPM K SC PPM I I LA PPM

LAMOTHE HUMUS SH2 LINE 1 AU, BA & NA

DUPLICATE DUB GATE Line position (m)

AU PPB -+-- BA PPM X NA/10 PPM

40

-35

-30

-10

-5

~ ~ 0 10 10 20 30 35 40 45 50 50 55 60 65 70 80 90 100

200

0

1200

1000

800

600

400

BA

, NA

/ 10

PP

M

AU

PP

B, C

U P

PM

LAMOTHE HUMUS SH2 LINE 1 AU, CU & U

0 10 10 20 30 35 40 45 50 50 55 60 65 70 80 90 100 DUPLICATE DUPLICATE

Line position (m)

AU PPB -+- CU PPM < U PPM

30

25-

20-

15-

10-

5--

0

CR

PP

M, F

E*1

O%

50

45

40

35

30

25

20

15

10

5.

0

20

18

16

14

12

10

8

6

4

2

0

AU

PP

B, A

S P

PM

Line position (m)

AU PPB -+- AS PPM CR PPM f FE*10 %

LAMOTHE HUMUS SH2 LINE 2 AU, AS, CR & FE

Line position (m)

20 60

-18

50 -16

-14 40

BR

, LA

PP

M

-12

30 10

-8

20 -6

-4 10

-2

0 0

AU PPB -T BR PPM >K SC PPM i LA PPM

LAMOTHE HUMUS SH2 LINE 2 AU, BR, SC & LA

AU

PP

B, S

C PP

M

NA/10 PPM AU PPB +- BA PPM

LAMOTHE HUMUS SH2 LINE 2 AU, BA & NA

2 points 20 1800 I F18

ppm -16

-14

-12 m d

-10 a

-8 Q

-6

-4

-2

10 20 i

35 40 45 ~

50 55 60 70 80 90 30 0

Line position (m)

1400

1200-

1000-

800-

600-

400-

200-

0

BA

, N

A/1

0 P

P M

I I f 10 20 30 35 40 45 50 55 60 70 80 90

0.5

2-

1

40

-35

-30

-25

-20

-15

-10

-5

0

2.5

LAMOTHE HUMUS SH2 LINE 2 AU, CU & U

Line position (m)

AU PPB -+- CU PPM )K U PPM

AU

PP

B, C

U PP

M

7

6

5

4

3

2

1

LAMOTHE HUMUS SH2 LINE 3 AU, AS, CR & FE

-~- r 7 0 0 10 20 30 35 40 45 50 55 60 60 65 70 75 80 90 90

DUPLICATE DUPLICATE Line position (m)

CR

PP

M,

FE

* 1 Q

%

80

70

60

50

40

30

20

10

0

AU

PP

B, A

S PP

M

AU PPB -+- AS PPM >' CR PPM I I FE*10 %

LAMOTHE HUMUS SH2 LINE 3 AU, BR, SC & LA

45

40

35

2 30 fl, 0- 25

20- CC- CO 15-

10

AU

PP

B, S

c PP

M

TT 0 10 20 30 35 40 5 50 60 60 65 70 75 80 90 90

Line positiliPLRE DUPLICATE

AU PPB BR PPM >i< Sc PPM I LA PPM

5

0-

AU PPM -+- BA PPM K NA/10 PPM

LAMOTHE HUMUS SH2 LINE 3 AU, BA & NA

BA

, NA

/ 10

PP

M

1000

900

800

700

600

500

400

300

200

100-

0 0 90 90

DUPLICATE 0 110 20 30 35 40

f 45 50 55 60 60 65

DUP C Line position mAE

70 75 80

40

35

-30

10

5

0

AU

PP

B, U

PP

M

4

3.5

3

2.5

2

1.5-

0.5

1-~

0

LAMOTHE HUMUS SH2 LINE 3 AU, CU & U

10 20 30 35 40 45 50 55 60 60 65 70 75 80 90 90

Line position DUP CA E DUPLICATE

(̀m)

--I- AU PPB ---I- CU PPM < U PPM

LAMOTHE HUMUS SH2 LINE 4 AU, AS, CR & FE

CR

PP

M, F

E*1

0 %

60

50

40

30

20

10

AU

PP

B, A

S P

PM

o T i r- 0 0 10 20 25 30 35 40 45 50 55 60 70 80 90

Line position (m)

AU PPB -+- AS PPM < CR PPM i i FE*10 %

AU PPM -+- BR PPM XK SC PPM ► LA PPM

AU

PP

B, S

C PP

M

LAMOTHE HUMUS SH2 LINE 4 AU, BR, SC & LA

0 ~

' ~

4~

10 20 25 30 35 0 45 50 55 60 70 80 90 0

Line position (m)

BR

, LA

PP

M

45

40-

35-

30-

25-

20-

15-

10-

5-

0-

AU PPB -F- BA PPM )K NA/10 PPM

LAMOTHE HUMUS SH2 LINE 4 AU, BA & NA

BA

, NA

/ 10 P

P M

1000-

900

800

700-

600

500-

400-

300

200-

100--

0

4

-3.5

-3

1

-0.5

r 0 10 20 25 30 35 40 45 50 55 60 70 80 90

Line position (m)

AU

PP

B, U

PP

M

4

3.5

3

2.5

2

1.5

1

0.5

0

LAMOTHE HUMUS SH2 LINE 4 AU, CU & U

30

-25

-5

' -~- 3~

3 4 55 90

1020 25 0 5 40 60 70 80 0

Line position (m)

AU PPB -+- CU PPM ) U PPM

LAMOTHE BLACK SPRUCE BARK SH2 LINE 1 AU, AS, CR & FE

I I 1 I T i I 1 1 1 f ( T I I 0.01 0 10 10 20 30 35 40 45 50 50 55 60 65 70 80 90 100

DUPLICATE DUEI.,JCATE Line position (m)

0.028

-0.026

-0.024

-0.022

-0.02 ô

W -0.018 LL.

-0.016

-0.014

-0.012

1.1

1

0.9-

0.8-

0.7-

0.6-

0.5-

0.4-

0.3-

0.2-

0.1

AU

PP

B, A

S, C

R P

PM

AU PPM -+- AS PPM < CR PPM I I FE %

I I I 1 I l ' I I I I I I I

10 10 20 30 35 40 45 50 50 55 60 65 70 80 90 100

LAMOTHE BLACK SPRUCE BARK SH2 LINE 1 AU, BR, SC & LA

DUPLICATE DUPLICATE Line position (m)

AU PPM -+- BR PPM >K SC*10 PPM i 1 LA PPM

AU

PP

B, S

C*1

0, L

A P

PM

-120

-40

LAMOTHE BLACK SPRUCE BARK SH2 LINE 1 AU, BA & NA

1

0.9

0.8

0.7

m 0.6 li a. 0.5- D < 0.4

0.3

0.2

0.1

0

140

1 1 I 1 1 1 ( < F 1 i- 1 1 f 1 1 1 20 0 10 10 20 30 35 40 45 50 50 55 60 65 70 80 90 100

DUPLICATE DUJ MCAT Line position (m)

AU PPB -± BA PPM K NA PPM

LAMOTHE BLACK SH2 LINE 2 AU,

SPRUCE BARK AS, CR & FE

20

25 1

-0.9

-0.8

-0.7

-0.6

-0.5

H0.4

-0.3

-0.2

AS

, CR

PP

M, F

E

5.4

~ ~ ~ ~ ~ ~ ~ 0.1 10 20 30 35 40 45 50 55 60 70 80 90

Line position (m)

AU PPB -+- AS PPM )K CR PPM n FE %

LAMOTHE BLACK SPRUCE BARK SH2 LINE 2 AU, BR, SC & LA

AU

PP

B, B

R P

PM

25

20

15

/

10

0.25

0.2

5

0

>K - 0.05

~ i i i i > > i i i i i 0 0 10 20 30 35 41-0 45 50 55 60 70 80 90

Line position (m)

AU PPB -+- BR PPM )K SC PPM 0 LA PPM

AU PPB -± BA PPM )K NA PPM

LAMOTHE BLACK SPRUCE BARK SH2 LINE 2 AU, BA & NA

180

-160

-140

-120

-100

1-80

-60

-40

I I I I ~ ~ ~ ~ I I I I I 0 10 20 30 35 40 45 50 55 60 70 80 90

20

Line position (m)

-0.12

-0.08 ,,,,,,,

W -0.06 ~

-0.04

0.1 ' ~ ~ T ~ ~

' ~ ~ ~ ~ ~ ~ ~

10 20 30 35 40 45 50 55 60 60 65 70 75 80 90 90 DUPLICATE QUL TE

Line positioPn

IC 0m)

AU PPB -+- AS PPM < CR PPM 1 1 FE %

AU

PP

B, A

S,

CR

PP

M

LAMOTHE BLACK SPRUCE BARK SH2 LINE 3 AU, AS, CR & FE

0.8

0.6

0.4

0.26

-0.24

-0.22

-0.2

-0.18

-0.16

-0.14

-0.12

SC

*5, L

A PP

M

LAMOTHE BLACK SPRUCE BARK SH2 LINE 3 AU, BR, SC & LA

AU

PP

B, B

R P

PM

0.2 > > r r r r r 0.1 10 20 30 35 40 45 50 55 60 60 65 70 75 80 90 90

DUPLICATE DUPLICATE Line position (m)

AU PPB -+- BR/10 PPM

SC*5 PPM n LA PPM

1.1

1

0.9

0.8 I

-100

-80

-60

-40

0.5

0.4

0.3

180

-160

-140

-120

AU PPB -+- BA PPM >K NA PPM

LAMOTHE BLACK SPRUCE BARK SH2 LINE 3 AU, BA & NA

0.2 r > > i i 20 10 20 30 35 40 45 50 55 60 60 65 70 75 80 90 90

DUPLICATE DUPLICATE Line position (m)

BA

, NA

PP

M

AU PPB -+- AS PPM >K CR PPM n FE %

LAMOTHE BLACK SPRUCE BARK SH2 LINE 4 AU, AS, CR & FE

1

0.9

0.8

~ 0.7

0.6 11. a_

0.5 CC U

0.4 ~

0.3

0.2

~ ~ ~ 10 20 25 30 35 40 45 50 55 60 70 80 90

Line position (m)

0.1

AU PPB -+- BR PPM K SC*10 PPM E LA PPM

AU

PP

B, B

R P

PM

LAMOTHE BLACK SPRUCE BARK SH2 LINE 4 AU, BR, SC & LA

0.5 16

14 -0.45

-0.4 12 /./4 -0.35 10 r

-0.3

-0.25

-0.2

= -0.15 .

vr

ar.

-0.1

0.05 1 1 1 I I I- 1 I 1 f 1 1 1 1

0 10 20 25 30 35 40 45 50 55 60 70 80 90

Line position (m)

AU PPB -+- BA PPM )K NA PPM

BA

&N

AP

PM

LAMOTHE BLACK SPRUCE BARK

SH2 LINE 4 AU, BA & NA 140

120-

100-

80-

60-

40-

20 I I I I I I ~ ~ 0 10 20 25 30 35 40 45 50 55 60 70 80 90

Line position (m)

APPENDIX 6

PROFILES FOR SELECTED ELEMENTS, BY LINES SHOWING 5

10 20 30 35 40 45 50 55 60 60 65 70 80 90 100 110 120

LAMOTHE HUMUS SH5 LINE 1 AU, AS, CR & FE

Line position (m)

AU PPB T AS PPM >< CR PPM I 1 FE*10%

LAMOTHE HUMUS SH5 LINE 1 AU, BR, SC & LA

BR

, LA

PP

M

AU

PP

B, S

C PP

M

~ 10 20 30 35 40 45 50 55 60 60 65 70 80 90 100 110 120

Line position (m)

AU PPB -+- BR PPM >K SC PPM I i LA PPM

18

16-

14-

12-

10-

8-

6-

4-

2-

0

3

2.5

-2

1.5

1

0.5

AU PPB -+- BA PPM NA/10 PPM i 1 ZN PPM

LAMOTHE HUMUS SH5 LINE 1 AU, BA, NA & ZN

600

500-

400

300

200

100

BA

, NA

/ 10, Z

N P

PM

~ ~ ~ ~ ~ ~ I 0 10 20 30 35 40 45 50 55 60 60 65 70 80 90 100 110 120

Line position (m)

o

LAMOTHE HUMUS SH5 LINE 1 AU, CU & U

AU

PP

B, U

PP

M

I

10 20 30T 35 40

T 45 50 55 60 60 65 70 80 90 100 110 120

DUPLICATE Line position (m)

AU PPB --i- CU PPM )K U PPM

LAMOTHE HUMUS SH5 LINE 2 AU, AS, CR & FE

80

-70

-60

4

3

-20

-10

I I 1 I I T I I I 1 0 0 10 20 30 35 35 40 45 50 55 60 70 80 90 100 100 110120

DUPLICATE DUPLICATE Line position (m)

AU

PP

B, A

S P

PM

, FE

*10 %

AU PPB -+- AS PPM >K CR PPM n FE*10 %

0

AU

PP

B, S

C P

PM

14

12-

10

ces

a.

co

LAMOTHE HUMUS SH5 LINE 2 AU, BR, SC & LA

0 10 20 30 35 35 40 45 50 55 60 70 80 90 100 100 110 120 DUPLICATE DUPLICATE

Line position (m)

AU PPB -+- BR PPM K SC PPM + ► LA PPM

~ 0 10 20 30 35 35 40 45 50 55 60 70 80 90 100 100 110 120

AU PPB -+- BA PPM K NA/100 PPM n ZN PPM

LAMOTHE HUMUS SH5 LINE 2 AU, BA, NA & ZN

BA

, NA

/ 100

, ZN

P P

M

DUPLICATE DUPLICATE Line position (m)

2

-1.8

-1.6

-1.4

-1.2 m a.

-1 0- D

-0.8 <

-0.6

-0.4

-0.2

0

-10

5

AU

PP

B, U

PP

M

2

1.8-

1.6-

1.4-

1.2-

1-

0.8-

0.6-

0.4-

0.2-

0

LAMOTHE HUMUS SH5 LINE 2 AU, Cu & U

41. 0 10 20 30 35 35 40 45 50 55 60 70 80 90 100 100 110 120

DUPLICATE DUPLICATE Line position (m)

35

-30

-25

AU PPB f CU PPM < U PPM

5

4.5-

4-

3.5-

3-

2.5-

2-

1.5-

1-

0.5-

0

AU

PP

B, A

S P

PM

, FE

* 10

%

AU PPB -+- AS PPM >K CR PPM n FE*10 %

LAMOTHE HUMUS SH5 LINE 3 AU, AS, CR & FE

I I I 1 I I I 1 I I I

0 10 20 20 30 35 40 45 50 55 60 60 65 70 75 80 85 90 DUPLICATE DUPLICATE

Line position (m)

-8

-6

4

20

-18

-16

BR

, LA

PP

M

LAMOTHE HUMUS SH5 LINE 3 AU, BR, SC & LA

14

12

10

AU

PP

B, S

C PP

M

0 10 20 20 310 35 40 45 50 55

DU0PLI 60 5 70 75 80 85 90

DUPLICATE Line position (m)

AU PPB -+- BR PPM X SC PPM n LA PPM

0

AU PPB -± BA PPM NA/100 PPM n ZN PPM

LAMOTHE HUMUS SH5 LINE 3 AU, BA, NA & ZN

0 0

300

250

200-

150

100-

50

1

0.5

3

2.5

-2

0 10 20 20 30 35 40 45 50 55 60 60 65 70 75 80 85 90 DUPLICATE DUPLICATE

Line position (m)

BA

, NA

/ 10

0, Z

N P

PM

AU PPB -+- CU PPM >K U PPM

AU

PP

B, U

PP

M

LAMOTHE HUMUS SH5 LINE 3 AU, CU & U

--r-- 1 I T 0 10 20 20 30 35 40 45 50 55 60 60 65 70 75 80 85 90

DUPLICATE DUPLICATE

Line position (m)

Line position (m)

20

18

16

14

12

10

8

6

4

2

0

70

-60

-50

-40

-30

-20

-10

10 20 30 35 40 45 50 50 55 60 65 70 75 80 90

AU PPB - i AS PPM >K CR PPM I FE %

AU

PP

B, A

S P

PM

LAMOTHE HUMUS

SH5 LINE 4 AU, AS, CR & FE

CR

PP

M, F

E*

10 %

140

120-

100

80-

60

40

20

0

BR

, LA

PP

M

LAMOTHE HUMUS SH5 LINE 4 AU, BR, SC & LA

20

-18

-16

-14

-12

-10

-8

-6

-4

-2

20 4

I 0 4

I 5

~ ~ I

60 6 I5

~

8~ 0

I 90

0 II - i

30 35 50 50 55 70 75

DUPLICATE

Line position (m)

AU

PP

B, S

C PP

M

AU PPB -+- BR PPM >K SC PPM ► i LA PPM

LAMOTHE HUMUS SH5 LINE 4 AU, BA, NA, ZN

BA

, NA

/ 100

, ZN

PP

M

300

250

200

150

100

50

AU PPB --I- BA PPM K NA/100 PPM n ZN PPM

Line position (m)

LAMOTHE HUMUS SH5 LINE 4 AU, Cu &U

4111 DUPLICATE

I I 0 10 20 3'0 40 45 5F -0 50 55 60 65 710

20- -

18-

16-

14

12

10-

8

6

4

2

0

450

-400

-350

-300

2 -250 0_

cL -200 D

o -150

-100

-50

80 90 I r 0

Line position (m)

AU PPB +- CU PPM >< U PPM

AU

PP

B, U

PP

M

LAMOTHE BLACK SPRUCE BARK SH5 LINE 1 AU, AS, CR & FE

~ ~ ~ r ~ ~ ~ r 1 1 I I I I 0

0 10 30 35 40 45 50 55 60 60 65 80 90 100 110 120 PL

nIGA E

Line posiQ ~io ~m)

AS

, CR

PP

M F

E*1

O %

-I AU PPB -4- AS PPM >K CR PPM I 1 FE*10 %

1.2

0.8-

0.6

0.4

0.2-

1

-0.5

LAMOTHE BLACK SPRUCE BARK SH5 LINE 1 AU, BA, NA & ZN

i

-0.5

30 ~ ~ ~ T g r~

0 10 30 35 40 45 0 55 60 60 65

Line position (m)

---+-- AU PPB - I BA PPM >K NA PPM + + ZN PPM

120

110

100

90

80

70

60

50-

40-

BA

, NA

, ZN

PP

M

80 90 160 110 120

X

►~

-6

-4 AU

PP

B, B

R P

PM

I\

-2

LAMOTHE BLACK SPRUCE BARK SH5 LINE 1 AU, BR, SC & LA

~TI ~ I! l //1 \\ ,

0.3 16

-14

SC

, LA

PP

M

0.25

0.2

0.15

0.1

0.05

I 1 1 I 1 I [ 1 I 1 1 I 1 I T 1 I I 0

0 10 20 30 35 40 45 50 55 60 60 65 70 80 90 100 110 120 UCT

Line posQition

A (m)

AU PPB -+- BR PPM )K SC PPM n LA PPM

LAMOTHE BLACK SPRUCE BARK SH5 LINE 2 AU, AS, CR & FE

CR

PP

M,

FE

* 1 Q

%

AU

PP

B, A

S P

PM

0 10 20 30 35 35 40 45 50 55 60 70 80 90 100 100 110 120 DUPLICATE

Line position (m)

--F— AU PPB -+- AS PPM )K CR PPM I I FE*10 %

0.8

0.6

0.4

0.2

1.6

-1.4

-1.2

-1

0.8

-0.6

-0.4

-0.2

o I 7 I I I I I I I I I I I I I I

AU PPB -+- BR/10 PPM X SC PPM LA PPM

SC

, LA

PP

M

LAMOTHE BLACK SPRUCE BARK SH5 LINE 2 AU, BR, SC & LA

0.3

0.25

0.2

0.15

0.1

0.05

i i i i T r i i i i 0.2 0 10 20 30 35 35 40 45 50 55 60 70 80 90 1001001100120

DUPLICATE DUPLICATE Line position (m)

AU

PP

B, B

R/ 1

0 PP

M

LAMOTHE BLACK SPRUCE BARK SH5 LINE 2 AU, BA, NA & ZN

140 1.6

120

100

80

60

40

20 10 20 30 35 35 40 45 50 55 60 70 80 90 100 100 110 120

DUPLICATE DUPLICATE Line position (m)

BA

, NA

, ZN

PP

M

-+-- AU PPB -+ BA PPM >K NA PPM Li ZN PPM

I I I

20 20 30 35 4 0 45 63 60 60 65 0 .i5 5 8 0 5 90 ° DUPLICATE DUPLICATE

Line position (m) 0 10

LAMOTHE BLACK SPRUCE BARK SH5 LINE 3 AU, AS, CR & FE

AS

, CR

PP

M, F

E*1

0 %

-I AU PPB -+- AS PPM >K CR PPM 1 1 FE*10 %

LAMOTHE BLACK SPRUCE BARK SH5 LINE 3 AU, BA, NA & ZN

160 9

BA

, NA

, ZN

PP

M

6 1[0 20 20 ks 35 45

I0 40 0 I0 65 70 75 80 85 60 ° DUPLICATE DUPLICATE

Line position (m)

---I— AU PPB —I— BA PPM < NA PPM n ZN PPM

LAMOTHE BLACK SPRUCE BARK SH5 LINE 3 AU, BR , SC & LA

18

-16

-14

-12

-10

-8

-6

0.3

0.25

0.2

0.15- .

0.35

0.1

0.05

0 10 20 20 30

DUPLICATE

-4

-2

i 1 0 85 90

I I I T 35 40 45 50 55

DUPLICATE Line position (m)

1 60 60 65 70

AU PPB I BR PPM >K SC PPM f I LA PPM

SC

, LA

PP

M

AU

PP

B, B

R PP

M

LAMOTHE BLACK SPRUCE BARK SH5 LINE 4 AU, BR, SC & LA

SC

*5, L

A PP

M

0.35

0.3

0.25

0.2

0.15

0.1

0.05

-1.8

-1.6 a_

-1.4 a a T

-1.2 ii-- co

-1 co- a.

-0.8 CL D

-0.6 <

-0.4

I r I I I 1 1 1 0.2 0 10 20 30 35 40 45 50 50 55 60 65 70 75 80 90

Line position (m)

AU PPB -+- BR/10 PPM )K SC*5 PPM n LA PPM

AU PPB -+- AS PPM X CR PPM ► + FE*10 %

LAMOTHE BLACK SPRUCE BARK SH5 LINE 4 AU, AS, CR & FE

CR

PP

M, F

E*

1 O %

0.9-

0.8-

0.7-

0.6

0.5

0.4

0.3

0.2

0.1

-0.9

-0.8

-0.7

-0.6

-0.5

0.2 0 10 20 30 35 40 45 50 50 55 60 65 70 75 80 90

Line position (m)

1.1

1

AU

PP

B, A

S P

PM

1.1

-0.9

0.8

0.5

-0.4

-0.3

10 20 30 35 40 45 50 50 55 60 65 70 75 80 90 1 2

BA

, N

A P

P M

160

140

120

100

80

60

40

LAMOTHE BLACK SPRUCE BARK SH5 LINE 4 AU, BA, & NA

Line position (m)

AU PPB —+~- BA PPM )K NA PPM