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Methane Mapping Chris Rella, Ph. D., Director of R&D ([email protected]) Picarro, Inc.

Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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This map shows results of drive-by emissions sampling in DISH, Texas and neighboring Flower Mound as well as other parts of the Dallas-Fort Worth Area. The large plumes are possible indications of emissions of toxic VOCs from natural gas compression and storage facilities.

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Page 1: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

Methane Mapping

Chris Rella, Ph. D., Director of R&D ([email protected])

Picarro, Inc.

Page 2: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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What is Methane?

• Present in the atmosphere at low levels – 1.8 parts-per-million (ppm)

• Primary constituent of natural gas• Emitted by a variety of sources

– Farms– Landfills– Wetlands– Industrial activities of all types

• Powerful greenhouse gas• Non-toxic at ppm levels

– Sometimes accompanied by other more toxic chemicals

Page 3: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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Methane Mapping

• Our goal is to provide a map of airborne methane for:– Rapid hunting and tracking of natural gas product leaks– Distinguishing between different sources of methane (both natural

and human)– Identifying areas of concern for more careful, quantitative studies of

airborne emissions

• We need to build a methane measurement tool that is– Fast – responds in seconds– Accurate – Measures methane, and only methane, very accurately– Easy – something anyone can use

Page 4: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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World’s Highest Performance and Easiest to Use Analyzers

10”

What is Picarro?

Page 5: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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Picarro – world class greenhouse gas monitors

• Picarro Technology chosen as the Gold Standard by the UN’s World Meteorological Organization (WMO)

• Hundreds of units installed in 45 countries and on all 7 continents and in every ecosystem imaginable

• Used by virtually every major international GHG monitoring network:- NOAA - Australia CSIRO- Chinese Meteorological Agency - Environment Canada- EU’s ICOS - German EPA- France’s LSCE - Irish EPA- Japan’s NIES - Swiss EPA- Korean Meteorological Association - Too many universities to mention

Page 6: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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What’s inside the box?

• Cavity Ringdown Spectroscopy– “Cavity” – 10 inches long, but 10 mile path length = parts-per-billion– “Ringdown” – this is a measurement of time = accurate– “Spectroscopy” – measures ONLY methane = not confused by other

chemicals

• Ruggedized for use in the field

Page 7: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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Measure Anywhere

Vessels

Aircraft

Highways

Telecom

Buildings

Cities

Fields

Mountains

Blimps Landfills

Page 8: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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Methane measurements on the road

• Picarro CRDS methane (model G1202)– ppb resolution for both

gases in just a few seconds

– Accurate, robust, and easy-to-deploy

• High resolution GPS• Batteries for mobile

operation• Reporting of data

directly into Google Earth to make the maps

Gas snorkelGPS antenna

batteriesPicarro CRDS

Page 9: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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A typical map

• The “ribbon” of data shows where we traveled

• The height above the ground shows the methane concentration at that location

800 ft above ground = 1 ppm of methane

55 mph

Methane: +0.1 ppm

Page 10: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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DISH, Tx – Wind Data

Measurements taken @ 1-3 pm

Wind from the NWwww.wunderground.com

Page 11: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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• Width of peak + direction of wind indicates a rough “footprint” of where the source is likely to be

• Measurements with different wind directions can be used to triangulate the source wind

Where is the source?

Page 12: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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Roadside source, looking downwind

• No obvious source visible on satellite image from 2001

• On-site inspection would reveal likely source

• Remember: high concentrations does not necessarily mean big emissions!– Distance to source– Wind speed– Still air vs. turbulent air

• Methane mapping is not the same as emissions quantification

Methane: +11 ppm

wind

Page 13: Methane Maps of DISH and Flower Mound (Texas) - Likely Indication of Benzene and VOCs

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Outlook for methane mapping

• Measuring methane accurately, in real time, from a vehicle is a powerful tool to help identify and quantify sources of methane– Leak detection– Source identification– Choosing target areas for future measurements

• Further work: to extend this technique to provide quantification of emissions (in tons / year) for methane and other chemicals