Basf - Multipurpose solutions for surface clean

Home Care Hard Surface Cleaning

Multipurpose Solutions for Surface Clean

Juraci Marques da Silva,Technical Consultant

August, 2016

28/24/2016

1 | Driving Forces to Innovation and Claims to choose

2 | Conclusions

3

Multipurpose Solutions for Surface Clean!Claims to choose

Convenient Cleaning

SpotlessDrying

Easy-to-clean-again

Effect

High-Performance Cleaning

Primary Cleaning

BoostGlossy &

Streak-Free

Gentle Cleaning

Skin CareSurface

Care

Sustainable Cleaning

Renewable Base and

Biodegradable

Convenience: Ease of Use, Emotional Purchase

Safeness: Hygiene, Material Protection…

Performance

Sustainable Solutions: Environmentally friendly product, water and energy efficiency, packaging/refill

Convenient Cleaning

4

SpotlessDrying

Easy-to-clean-again Effect

Multipurpose Solutions for Surface Clean!Claims to choose – Convenient Cleaning

Multipurpose Solutions for Surface Clean!The Polyquart® Types

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Aqueous solution of acrylic copolymerYellowish clear liquid

21.5 – 22.5 % active

Stable at pH ranges from 3 – 10

Dosage 0.2% - 1.0% as is

Polyquart® 149

Starch acrylic copolymerYellowish clear liquid

21.5 – 22.5 % active

Stable at pH ranges from 3 – 10

Dosage 0.5% - 1.5% as is

Polyquart® EcocleanAerobic and anaerobicbiodegradability

Surface ModificationPolyquart® 149

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0

20

40

60

80

100

120

Ceramic Glass Stainless Steel Car Panel PVC PP

Con

tact

Ang

le [°

]

Untreated Surface

Polyquart 149

More hydrophobic

More hydrophilic

Uniform and quick drying Uniform wetting

Surface ModificationPolyquart® Ecoclean

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0

10

20

30

40

50

60

70

80

90

Ceramic Glass Stainless Steel Plastics*

Con

tact

Ang

le [°

]

Untreated Surface

Polyquart Ecoclean

More hydrophilic

* PVC

Excellent wetting & uniform drying Unchanged surface

Multipurpose Solutions for Surface Clean!Test Method Water Drainage / Sheeting

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1. Pretreatment with test solution

Test solution ( e.g. 0.5% active surfactant and 0.1% active polymer or a cleaner formulation) is dropped on a ceramic tile 15x15cm by 25 drops, 5x5 drops in square.

These drops are wiped via Kim Wipe in twice, 10 wiping cycles in both directionsto get a homogenous film

2. Air drying

Drying at roomtemperature for 24 hours

3. Rinse with water stream

Pretreated plate is placed vertical and a water stream isplaced on the upper end from the right to the left corner in order to rinse the ceramic.After stopping the water stream,you can evaluate the sheeting effect)

Multipurpose Solutions for Surface Clean!Water Drainage / Sheeting Effect

Water sheeting effect

caused by hydrophilization ofthe surface

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No effect

on a non treated surface

Water drainage effect

caused by hydrophobization ofthe surface

Multipurpose Solutions for Surface Clean!Water Drainage / Sheeting

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1 11

-0.5

1

-0.5

Lutensol® Lutensol®/ Glucopon® 425 (1:3)

0.5% active surfactant 1% active surfactant 2% active surfactant without polymer

hydr

opho

biza

tion

hydr

ophi

lizat

ion

Water drainage

no effect - rip

Water sheeting

Multipurpose Solutions for Surface Clean!Water Drainage by Polyquart® 149

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1 1

4

6


0.5% active surfactant 0.5% active surfactant + 0.1% active Polyquart® 149

hydr

opho

biza

tion

hydr

ophi

lizat

ion

Water drainage

Water sheeting

Multipurpose Solutions for Surface Clean!Water Sheeting by Polyquart® Ecoclean

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1 1

-1 -1


0.5% active 0.5% active + 0.1% active Polyquart® Ecoclean

hydr

opho

biza

tion

hydr

ophi

lizat

ion

Water drainage

Water sheeting

Multipurpose Solutions for Surface Clean!Water Drainage / Sheeting

Effect on water sheeting / drainage by Polyquart® typesfor a spotless drying:

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Polyquart® 149

Polyquart® Ecoclean

Strength of water sheeting / drainage effect

quick & spotless dryingspotless drying & anti-rain

Convenient Cleaning

14

SpotlessDrying Easy-to-clean-

again Effect

Multipurpose Solutions for Surface Clean!Effect to choose – Convenient Cleaning

Multipurpose Solutions for Surface Clean!Test Method Easy-to-clean-again

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1. Pretreatment with test solutione.g. 1% active surfactant and 0.1% active polymer is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile.These drops are wiped via Kim Wipe in twice 10 wipingcycles in both directions to get a homogenous film.

2. Air drying

Drying at roomtemperature for 24 hours.

3. Soiling tile with Ca-Stearate by air brush3 ml soil is sprayed homgenous on the hole area of tile.(Soil: 5% Ca-Stearate, 10% Water, 85% Ethanolthe soil should be stirred by Ultra Turrax and Ultra Sonic Bath and stored under usual stiring for 1 day)

4. Heating at for melting the Stearate layer(30 Minutes at 180°C)

5. Wiping with sponge under rinsing tap waterWiping with constant low pressure under water stream for 10 cycles.

6. Evaluation

Multipurpose Solutions for Surface Clean!Easy-to-clean-again Effect

Evaluation:

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left side of tileuntreated

right side of tilepretreated

Grading examples (0 to 3):

0 1 2 3

Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® 149

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0

1

0

1

2

3


0.5% active surfactant + 0.1% active Polyquart® 1492% active surfactant + 0.1% active Polyquart® 149

0 0

No effect with 0.5% active surfactant, slight effect on Lutensol® and Glucopon® mixtures with 2.0% active surfactant and 0.1%

Polyquart® 149.

Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® 149

188/24/2016

1

0

1 1

0

1

2

3


0.5% active surfactant + 0.2% active Polyquart® 1492% active surfactant + 0.2% active Polyquart® 149

Slight effect with 0.5% / 2.0% active surfactant and 0.2% Polyquart®149.

Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® Ecoclean

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1 1

3

1

0

1

2

3


0.5% active surfactant + 0.1% active Polyquart® Ecoclean2% active + 0.1% active Polyquart® Ecoclean

Slight effect with 0.5% active surfactant, excellent effect on Lutensol®but not on Glucopon® mixtures with 2.0% active surfactant and 0.1%

Polyquart® Ecoclean.

Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® Ecoclean

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1 1

2 2

0

1

2

3


0.5% active surfactant + 0.2% active Polyquart® Ecoclean2% active + 0.2% active Polyquart® Ecoclean

Slight effect with 0.5% active surfactant, significant effect on Lutensol®and Glucopon® mixtures with 2.0% active surfactant and 0.2%

Polyquart® Ecoclean.

Multipurpose Solutions for Surface Clean!Easy-to-clean-again

Easy-to-clean-again effect by Polyquart® types:

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Polyquart® 149


Strength of easy-to-clean-again effect*

*using Ca-stearate based soil

22

Home CareClaims to choose – High-Performance

Primary Cleaning

BoostGlossy &

Streak-Free


Multipurpose Solutions for Surface Clean!Test Method Primary Cleaning

Modified Gardner test method by automatic test equipment

0.5% / 1% / 2 % active surfactant in distilled water

25 °C

Using oil soil (IPP 83/21) on polyvinylchloride (PVC) strips

Evaluation of cleaned PVC strips after 10 wipes

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Oily Soil (IPP 83/21)% Content

17.0 Myritol 318 (caprylic / capric triglyceride)40.0 Nytex 801 (Nynas; processing oil, naphthenic)36.0 Benzine (80/110)

7.0 Special Carbon Black (Orion Engineered Carbons,D-60528 Francfort, Germany)

(1) Soiling by brush (2) Analysis of soiled surface

(4) Wiping with sponge(3) Applying test solution

(6) Analysis of cleaned surface(5) Rinsing with water

Multipurpose Solutions for Surface Clean!Primary Cleaning Performance

Soi

lRem

oval

[%]

Test in distilled water at 25 °C, using the modified Gardner test on PVC with oil soil

50 51

6255

5852

0

10

20

30

40

50

60

70


0.5% active surfactant 1% active surfactant 2% active surfactant

Multipurpose Solutions for Surface Clean!Primary Cleaning – Polyquart® 149

Soi

lRem

oval

[%]

Test in distilled water at 25 °C, using modified Gardner test on PVC with oil soil

6255

50 51

6371

0

10

20

30

40

50

60

70

80


1% active surfactant0.5% active surfactant0.5% active surfactant + 0.1% active Polyquart® 149

Excellent primary cleaning boost of Lutensol® / Glucopon® combination (3:1) by 0.1% active Polyquart® 149.

Multipurpose Solutions for Surface Clean!Primary Cleaning – Polyquart® Ecoclean

Soi

lRem

oval

[%]

Test in distilled water at 25 °C, using modified Gardner test on PVC with oil soil

6255

50 5158

54

0

10

20

30

40

50

60

70


1% active surfactant0.5% active surfactant0.5% active surfactant + 0.1% active Polyquart® Ecoclean

Excellent primary cleaning boost of Lutensol® / Glucopon® combination(3:1) by 0.1% active Polyquart® Ecoclean.

Multipurpose Solutions for Surface Clean!Primary Cleaning

Boost effect on primary cleaning by Polyquart® types:

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Polyquart® 149


Strength of primary cleaning boost effect

28

Home CareClaims to choose – High-Performance

PrimaryCleaning

Boost

Glossy & Streak-

Free


Multipurpose Solutions for Surface Clean!Test Method Gloss Retention

1. Measure reflection of clean ceramic tile

2. Pretreatment with test solution (1% active surfactant is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile. These drops are wiped via Kim Wipe in twice 10 wiping cycles in both directions to get a homogenous film)

3. Air drying at room temperature

4. Measure reflection of treated ceramic tile

5. Calculate gloss retention out of 1. and 4.

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20°

60°

85°

N

Multipurpose Solutions for Surface Clean!Gloss Retention – Polyquart® 149

Glo

ssR

eten

tion

[%]

Test in distilled water at 20 °C on black ceramic tiles

78.2

96.691.8 95.379.7 85.280.4

88.2

0102030405060708090

100


0.5% active surfactant0.5% active surfactant + 0.1% Polyquart® 1492.0% active surfactant2.0% active surfactant + 0.1% Polyquart® 149

Gloss retention boost by Polyquart® 149 only on Lutensol® types –mixtures with Glucopon® show already excellent gloss retention; better

results with 0.5% active surfactant.

Multipurpose Solutions for Surface Clean!Gloss Retention – Polyquart® Ecoclean

Glo

ssR

eten

tion

[%]

78.2

96.692.2 98.2

79.7 85.288 87.5

0102030405060708090

100


0.5% active surfactant0.5% active surfactant + 0.1% Polyquart® Ecoclean2.0% active surfactant2.0% active surfactant + 0.1% Polyquart® Ecoclean

Gloss retention boost by Polyquart® Ecoclean only on Lutensol® types; better results at 0.5% active surfactant.

Test in distilled water at 20 °C on black ceramic tiles

Multipurpose Solutions for Surface Clean!Gloss Retention / Streak-Free Effect

Effect on gloss retention / streak-free boost with Polyquart® types:

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Polyquart® 149


Strength of gloss retention / streak-free effect

Only with alkoxylatedsurfactants like Lutensol®types; no boost ofmixtures with Glucopon®

types!

Gentle Cleaning

33

Home CareClaims to choose – Gentle Cleaning

Skin Care

SurfaceCare

Multipurpose Solutions for Surface Clean!Skin Care – Glucopon®

Glucopon® surfactants are

significantly less skin irritating than

comparable to nonionic and anionic

(LAS) surfactants.

Glucopon® surfactants can even

reduce the skin irritation factor of

other surfactants when being used in

combination.

Perfect mildness to skin.

Test Method:Modified Duhring - Chamber Test

Tested Surfactants: Alkyl Polyglucoside - APG®

Linear Alkylbenzene Sulphonate - LAS Fatty Alcohol Ether Sulfate - FAES Sodium Alkene Sulfate - SAS Fatty Alcohol Sulfate – FAS Mixtures of other surfactants with APG®

Test Conditions:20 subjects (male and female)Mode of application: once, occlusive, for 24 hoursConcentration of the test solution: 1% active substance

Multipurpose Solutions for Surface Clean!Skin Care - Glucopon®

Relative irritation score (%)

APG®

LAS

FAES

SAS

FAS C12/14

LAS / APG® (1:1)

FAES / APG® (1:1)

SAS / APG® (1:1)

FAS / APG® (1:1)

0 100 200 400300

Multipurpose Solutions for Surface Clean!Skin Care - Glucopon®

Test Method: Modified Duhring - Chamber Test

Test Conditions: 20 subjects (male and female). Mode of Application:once, occlusive, for 24 hours The concentration of the test solution was 1% active substance.

Gentle Cleaning

37

Home CareClaims to choose – Gentle Cleaning

SkinCare

SurfaceCare

Multipurpose Solutions for Surface Clean!Test Method Plastic Compatibility

ISO 22088-4 test method (spline / corrosion test)

A test method to determine the plastic compatibility of hard surface cleaner ingredients like surfactants, solvents, acids, alkaline and further components.

Methodology:

The plastic test strip, containing a stainless steal pin in a hole (tension), is dipped shortly into the test solution (1% active). The test strip is checked visually after

4 hours

3 days

7 days and

14 days test period

388/24/2016

unchanged

fissures

through-cracks

fraction

Multipurpose Solutions for Surface Clean!Plastic Compatibility (PMMA)

4 hours

3 days

7 days14 days

Lutensol®Lutensol® /Glucopon®

425Lutensol® /Glucopon®

425 /Polyquart®

149

Lutensol® /Glucopon®

425 /Polyquart®Ecoclean

Test solution: 1% active surfactant – Lutensol® :Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® typeSubstrate: Plexiglass 8N80 (PMMA - Polymethylmethacrylat)

Superior plastic compatibility with high content of Glucopon® types; noinfluence by Polyquart® types.

unchanged

fissures

through-cracks

fraction

Multipurpose Solutions for Surface Clean!Plastic Compatibility (PC)

4 hours

3 days

7 days14 days



425 /Polyquart®

149




Test solution: 1% active surfactant – Lutensol® :Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® typeSubstrate: Makrolon 3103 (PC - Polycarbonate)

unchanged

fissures

through-cracks

fraction

Multipurpose Solutions for Surface Clean!Plastic Compatibility (ABS)

4 hours

3 days

7 days14 days



425 /Polyquart®

149




Test solution: 1% active surfactant – Lutensol®: Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® typeSubstrate: Polylac PA 727 (ABS - Acrylnitril Butadien Styrol)

unchanged

fissures

through-cracks

fraction

42

Multipurpose Solutions for Surface Clean!Claims to choose – Sustainable Cleaning


RenewableBase

Multipurpose Solutions for Surface Clean!Renewable Base

Renewable Base:

Glucopon® types (alkyl polyglucoside) = sugar / fatty alcohol

Polyquart® Ecoclean = teric modified starch

Existing statement for vegetable origin of Polyquart® Ecoclean

Aerobic and anaerobic biodegradability, no labelling for the following products:

Glucopon® types,

Lutensol® types


438/24/2016

Home Care and I&IGlucopon® types

44

Product information Application: Home Care and I&I

Focus Hard Surface Cleaning

Customer industry: Consumer Goods and I&I

Market: Global

Differentiation potential Customer

Performance in modern formulations

Health and safety

Consumer

Health & safety

Material protection

A balanced surfactant combining efficiency with an excellent eco-tox profile

Sustainability performance Gloss improvement, foam stabilization

Cleaning performance

100% renewable based

Meets eco-label requirements – aerobic and anaerobic biodegradable

Registered in main chemical inventories

Home Care and I&IPolyquart® Ecoclean

45

Product information Application: Home Care and I&I

Focus Hard Surface Cleaners

Customer industry: Consumer Goods and I&I

Market: Global

Differentiation potential Customer

Supported modern claims

Consumer

Health & safety

Convenience

Performance

A product that supports modern consumer needs

Sustainability performance Amphoteric modified starch

Excellent eco-tox profile

Aerobic and anaerobic biodegradable

Supports sustainable convenience claims such as easy-to-clean-again, time-saving, easy-to-use

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1 | Driving Forces to Innovation and Claims to choose

2 | Conclusions

Multipurpose Solutions for Surface Clean!The Elements

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Multipurpose Solutions!

Lutensol® typesExcellent wetting

EmulsificationDisperging

Polyquart® typesLong-lasting effects

High glossCleaning boost

Glucopon® typesSkin and surface care

FormulabilityFoam stabilization

High gloss

renewables sustainable

Convenient Cleaning

48

Gentle Cleaning



Multipurpose Solutions for Surface Clean!Summary

Easy-to-clean-again effect

Quick and spotless drying

Time-saving and effortless cleaning

Material protection

Skin protection

Excellent primary cleaning

Glossy and streak-free surfaces

Foam stability

Biodegradable products

Renewable based raw materials

Lutensol®, Glucopon® & Polyquart®:Multipurpose Solutions for Surface Clean!

Juraci M. da Silva [email protected]

Presentations & Public Speaking

Basf - Multipurpose solutions for surface clean