of 26 /26
May 15, 2017 May 17, 2017 Cairo, Egypt Alexandria, Egypt A unified approach to enhance your refinery performance Unity TM Hydroprocessing Catalysts Aravindan Kandasamy UOP Limited, Guildford, UK 2017 Honeywell Oil & Gas Technologies Symposium

UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

  • Upload
    haduong

  • View
    305

  • Download
    7

Embed Size (px)

Citation preview

Page 1: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

May 15, 2017May 17, 2017

Cairo, Egypt Alexandria, Egypt

A unified approach to enhance your refinery performanceUnityTM Hydroprocessing CatalystsAravindan Kandasamy

UOP Limited, Guildford, UK

2017 Honeywell Oil & Gas Technologies Symposium

Page 2: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

UOP 7804F-1

1

Outline

– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel

– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel

• Key Learnings

Page 3: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

UOP 7804F-2

2

Outline

– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel

– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel

• Key Learnings

Page 4: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Unity

Honeywell UOP

UOP 7804F-3

3

Page 5: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Honeywell UOP Unity Portfolio4

UOP Unity Hydrotreating catalysts available to you

Unity portfolio includes:hydrotreating catalystshydrocracking catalysts

UnityHoneywell UOP

Page 6: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Honeywell UOP Unity Portfolio5

UOP 7804F-5

Page 7: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Honeywell UOP Unity Portfolio6

UOP 7804F-6

Page 8: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Honeywell UOP Unity Portfolio7

UOP 7804F-7

Page 9: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Flexibility Through Comprehensive Choice:8

Flexibility allows profitability

UnityHoneywell UOP

• Hydrotreating and Hydrocracking• Unified approach to drive profitability• Intended to meet your Needs

Page 10: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Fundamental R&D Knowledge - An Enabler:9

Fundamental R&D results in UOP Unity

3 ring aromatics

UOP’s Fundamental knowledge developed over time:• Alumina technology, particle morphology and surface chemistry• Forming techniques and precise control of pore size distribution• Catalyst physical properties impact on diffusion properties and reactivity• Feed characterization• Manufacturing techniques and methods for metals loading

Page 11: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

UOP Unity | Hydrocracking Pretreat Catalysts10

Rigorous R&D and manufacturing – Robust performance

• Effective on a wide range of feeds– Atmospheric and Vacuum Gas Oil – Heavy Coker Gas Oil– Light Cycle Oil– Deasphalted Oil

• Designed to deliver the required HDN, HDA and HDS performance

• Prepare feeds for improved conversion to desired products

Commercially Proven

Page 12: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

UOP 7804F-11

11

Outline

– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel

– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel

• Key Learnings

Page 13: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

HYT-6219 Commercial Experience: Improved Profitability Through increased Diesel

12

Maximum Diesel with Stringent Specification

Cycle Objectives• Achieve cycle length of 2 years• Produce EURO V diesel quality product• Increase diesel yields

Type of hydrocracking technology• Non-UOP design of single stage recycle

with Recycle to R-1

Feed Composition• CGO, AGO, VGO • Opportunistic feedsConversion: • 95% volCut Point: • ASTM 370°C (698°F)

Unity

Hydroprocessing Catalysts

UOP Unity

HYT-6219

UOP Unity

Flexible HC

UOP Catalyst solution:

Page 14: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

HYT-6219 in Hydrocracking Pretreat Service

Enhance performance of both catalyst systems

Hydrotreating Hydrocracking

13

Unity

Hydroprocessing Catalysts

Products

Feed

TM

Generates high yields of either middle distillates or naphtha

HYT

8119

HYT

6219

HC

150

State-of-the-arthydrodemetallization catalyst with high capacity for nickel and vanadium uptake

Distillate selective flexible catalyst that produces higher distillate yields

Desulfurization and saturation catalyst for hydrocracking and ULSD applications

HC

140

Page 15: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

0 50 100 150 200 250 300 350 400 450 500

Nitr

ogen

at o

utle

t, w

t-ppm

HT

WA

BT, °

C

Days on Stream

HYT-6219 Performance

Hydrotreating WABT

Expected Deactivation

Nitrogen at outlet

Nitrogen Target

Hydrocracking Pretreat Catalyst Performance14

Robust activity and stability to enable cycle

HYT-6219 delivers excellent HDN

activity and stability

HYT-6219 delivers excellent nitrogen

removal

Page 16: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

0 50 100 150 200 250 300 350 400 450 500

HC

WA

BT, °

C

Days on Stream

HC Catalyst Performance

Hydrocracking WABT

Expected Deactivation

Hydrocracking Catalyst Performance15

The extra activity enables options for profitability

Hydrocracking catalyst activity and

stability enables CHOICE

• Longer cycle?• Drive operation to max diesel?• Customize loading for next cycleExpected cycle to exceed

target cycle length by 15%** Assuming increased operating window while

feed properties and targets remain same, based on HYT and HC activity & stability

Page 17: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Excellent Diesel Product Properties16

Enabling Profitability

• Diesel quality is better than EURO V, enabling more options for the diesel pool and overall refinery economics

Specification Target Achieved

Density @15C, kg/m3 Max 845 <<845

Sulphur, wppm Max 10 <<10

ASTM D86 T95%, °C Max 360 <360

Cetane Number Min 51 >51

0 50 100 150 200 250 300 350 400 450 500

Die

sel S

p G

ravi

ty

Cet

ane

Inde

x

Days on Stream

Cetane Index

Cetane Index Target

Diesel Sp Gravity

Diesel Sp Gravity Target

Page 18: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Unity Case Story: Improved Profitability Through increased Diesel

17

UOP Unity helps refiners increase profitability

Cycle Objectives• Achieve cycle length• Produce EURO V diesel quality

product• Increase middle distillate yields

UOP Unity Results:Expected to exceed target

cycle length by 25%, based on catalyst activity and stability

Diesel product properties better than EURO V

Unity

HydroprocessingCatalysts

UOP Unity

HYT-6219

UOP Unity

Flexible HC

• Hydrotreating and Hydrocracking• Unified approach• Intended to meet your Needs

Page 19: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

UOP 7804F-18

18

Outline

– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel

– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel

• Key Learnings

Page 20: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Commercial ULSD Unit with HYT-621919

Feed Details BlendSource Imported

Blend 45% LCGO

27% CN15% SRD13% LCO

API 43Sp Gravity 0.81Sulfur, wt-% 0.3Nitrogen, wt-ppm 1100Bromine Number 35150 °C + content, Wt-% 85*

* Est from Naphtha Yield

Operating Conditions ValueReactor I/L H2 PP, MPag 7.0

SOR WABT (Main Catalyst), °C 350H2 to Oil, Nm3/m3 740

UOP 7804F-19

19

Feed

MU H2

Separator

To Fractionation

Hydrotreater

Page 21: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

HYT-6219 Improves Unit to Meet ULSD Specifications

20

Product Quality Previous Cycle

Sulfur, wt-ppm 50 – 150

Cetane Index 46 – 51

Pour Point, °C -5 to – 18

CFPP, °C -3

Flash Point, °C 64 – 66

Producing Profitable Euro V Diesel

After Reload with HYT-6219

3 - 8

48 – 53

-13 to < -20

– 10

60 - 68

Page 22: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

UOP 7804F-21

21

Outline

– UOP UnityTM Hydroprocessing Portfolio– UnityTM Case Story A: Profitability through Increased Diesel

– UnityTM Case Story B: Profitability through upgrading to Exportable Diesel

• Key Learnings

Page 23: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Unity Hydrotreating Catalysts

• Manufactured in USA• State-of-the-art catalyst technology for high performance• Commercially proven in several challenging applications

– HC Pretreat– VGO Pretreat– ULSD– Mild hydrocracking

• Combine with HYT-8109 and HYT-8119 for demet of challenging feeds• Combine with Cat Trap for feeds with fouling tendencies

Unity

Hydroprocessing Catalysts

22

Page 24: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

Key Learnings What Can UOP Unity Catalysts Do For You?

23

• Unity - Honeywell UOP hydrotreating and hydrocracking catalyst portfolio

Now UOP Unity is available to you!

• Benefit from Tailored Performance through UOP Unity portfolio

• Extra Profitability for your Hydroprocessing units within your refineries and petrochemical complexes

• Complete Solution from UOP: – Process technology – Catalyst Solutions – Equipment Solutions – and Operational Support

Page 25: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

24

UnityTM

Unified approach | Hydrotreating and Hydrocracking | Universal compatibility

Honeywell UOP

Hydroprocessing Catalysts

UOP 7804F-24

Page 26: UnityTM Hydroprocessing Catalysts - Honeywell Process · PDF file1 Outline – UOP UnityTM Hydroprocessing Portfolio – UnityTM Case Story A: Profitability through Increased Diesel

25

UOP 7804F-25