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8/17/2019 Transitioning Metals
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in chemistry, the term transition metal (or transition element) has two possible meanings:
• The IUPAC definition[! defines a transition metal as "an element whose atom has a
partially filled d s#b$shell, or which can gi%e rise to cations with an incomplete d s#b$shell"&
• 'ost scientists describe a "transition metal" as any element in the d$bloc of the periodic
table, which incl#des gro#ps to * on the periodic table& [*![! In act#al practice, the f$
bloc lanthanide and actinide series are also
considered transition metals and are called
"inner transition metals"&
The + elements in gro#ps thro#gh * of theperiodic table are called "transition metals"& As withall metals, the transition elements are both d#ctileand malleable, and cond#ct electricity andheat& The interesting thing abo#t transitionmetals is that their %alence electrons, or theelectrons they #se to combine with otherelements, are present in more than one shell& Thisis the reason why they often ehibit se%eralcommon oidation states& There are threenoteworthy elements in the transition metalsfamily& These elements are iron, cobalt, and
nicel, and they are the only elements nown toprod#ce a magnetic field&
The Transition 'etals are:
-eca#se they possess the properties
of metals, the transition elements are
also nown as the transition metals& These
elements are %ery hard, with high melting
points and boiling points& 'o%ing from left to
right across the periodic table, the
fi%e d orbitals become more filled&
The d electrons are loosely bo#nd, which
contrib#tes to the high electrical cond#cti%ity
and malleability of the transition elements&
The transition elements ha%e low
ioni.ation energies& They ehibit a wide range
of oidation states or positi%ely
• /candi#
m
• Titani#m
• 0anadi#
m
• Chromi#
m
• 'angane
se
• Iron
• Cobalt
• 1icel
• Copper
• 2inc
• 3ttri#m
• 2irconi#
m
• 1iobi#m
• 'olybden
#m
• Techneti#
m
• 4#theni#
m
• 4hodi#m
• Palladi#
m
• /il%er
• Cadmi#m
• 5afni#m
• Tantal#m
• T#ngsten
• 4heni#m
• 6smi#m
• Iridi#m
• Platin#m
• 7old
• 'erc#ry
• 4#therford
i#m
• 8#bni#m
• /eaborgi#
m
• -ohri#m
• 5assi#m
• 'eitneri#
m
• Un#nnili#
m
• Un#n#ni#
m
• Un#nbi#m
•
http://en.wikipedia.org/wiki/IUPAChttp://en.wikipedia.org/wiki/IUPAChttp://en.wikipedia.org/wiki/Transition_metal#cite_note-1http://en.wikipedia.org/wiki/Chemical_elementhttp://en.wikipedia.org/wiki/Chemical_elementhttp://en.wikipedia.org/wiki/Electron_shellhttp://en.wikipedia.org/wiki/Cationhttp://en.wikipedia.org/wiki/Cationhttp://en.wikipedia.org/wiki/D-blockhttp://en.wikipedia.org/wiki/D-blockhttp://en.wikipedia.org/wiki/D-blockhttp://en.wikipedia.org/wiki/Periodic_tablehttp://en.wikipedia.org/wiki/Periodic_tablehttp://en.wikipedia.org/wiki/Periodic_tablehttp://en.wikipedia.org/wiki/Transition_metal#cite_note-2http://en.wikipedia.org/wiki/Transition_metal#cite_note-3http://en.wikipedia.org/wiki/F-blockhttp://en.wikipedia.org/wiki/F-blockhttp://en.wikipedia.org/wiki/Lanthanidehttp://en.wikipedia.org/wiki/Lanthanidehttp://en.wikipedia.org/wiki/Actinidehttp://chemistry.about.com/od/elementgroups/a/metals.htmhttp://chemistry.about.com/od/elementgroups/a/metals.htmhttp://chemistry.about.com/od/electronicstructure/a/Valences-Of-The-Elements.htmhttp://chemistry.about.com/od/electronicstructure/a/Valences-Of-The-Elements.htmhttp://www.chemicalelements.com/elements/sc.htmlhttp://www.chemicalelements.com/elements/sc.htmlhttp://www.chemicalelements.com/elements/ti.htmlhttp://www.chemicalelements.com/elements/v.htmlhttp://www.chemicalelements.com/elements/v.htmlhttp://www.chemicalelements.com/elements/cr.htmlhttp://www.chemicalelements.com/elements/cr.htmlhttp://www.chemicalelements.com/elements/mn.htmlhttp://www.chemicalelements.com/elements/mn.htmlhttp://www.chemicalelements.com/elements/fe.htmlhttp://www.chemicalelements.com/elements/co.htmlhttp://www.chemicalelements.com/elements/ni.htmlhttp://www.chemicalelements.com/elements/cu.htmlhttp://www.chemicalelements.com/elements/zn.htmlhttp://www.chemicalelements.com/elements/y.htmlhttp://www.chemicalelements.com/elements/zr.htmlhttp://www.chemicalelements.com/elements/zr.htmlhttp://www.chemicalelements.com/elements/nb.htmlhttp://www.chemicalelements.com/elements/mo.htmlhttp://www.chemicalelements.com/elements/mo.htmlhttp://www.chemicalelements.com/elements/tc.htmlhttp://www.chemicalelements.com/elements/tc.htmlhttp://www.chemicalelements.com/elements/ru.htmlhttp://www.chemicalelements.com/elements/ru.htmlhttp://www.chemicalelements.com/elements/rh.htmlhttp://www.chemicalelements.com/elements/pd.htmlhttp://www.chemicalelements.com/elements/pd.htmlhttp://www.chemicalelements.com/elements/ag.htmlhttp://www.chemicalelements.com/elements/cd.htmlhttp://www.chemicalelements.com/elements/hf.htmlhttp://www.chemicalelements.com/elements/ta.htmlhttp://www.chemicalelements.com/elements/w.htmlhttp://www.chemicalelements.com/elements/re.htmlhttp://www.chemicalelements.com/elements/os.htmlhttp://www.chemicalelements.com/elements/ir.htmlhttp://www.chemicalelements.com/elements/pt.htmlhttp://www.chemicalelements.com/elements/au.htmlhttp://www.chemicalelements.com/elements/hg.htmlhttp://www.chemicalelements.com/elements/rf.htmlhttp://www.chemicalelements.com/elements/rf.htmlhttp://www.chemicalelements.com/elements/db.htmlhttp://www.chemicalelements.com/elements/sg.htmlhttp://www.chemicalelements.com/elements/sg.htmlhttp://www.chemicalelements.com/elements/bh.htmlhttp://www.chemicalelements.com/elements/hs.htmlhttp://www.chemicalelements.com/elements/mt.htmlhttp://www.chemicalelements.com/elements/mt.htmlhttp://www.chemicalelements.com/elements/uun.htmlhttp://www.chemicalelements.com/elements/uun.htmlhttp://www.chemicalelements.com/elements/uuu.htmlhttp://www.chemicalelements.com/elements/uuu.htmlhttp://www.chemicalelements.com/elements/uub.htmlhttp://en.wikipedia.org/wiki/Transition_metal#cite_note-1http://en.wikipedia.org/wiki/Chemical_elementhttp://en.wikipedia.org/wiki/Electron_shellhttp://en.wikipedia.org/wiki/Cationhttp://en.wikipedia.org/wiki/D-blockhttp://en.wikipedia.org/wiki/Periodic_tablehttp://en.wikipedia.org/wiki/Periodic_tablehttp://en.wikipedia.org/wiki/Transition_metal#cite_note-2http://en.wikipedia.org/wiki/Transition_metal#cite_note-3http://en.wikipedia.org/wiki/F-blockhttp://en.wikipedia.org/wiki/F-blockhttp://en.wikipedia.org/wiki/Lanthanidehttp://en.wikipedia.org/wiki/Actinidehttp://chemistry.about.com/od/elementgroups/a/metals.htmhttp://chemistry.about.com/od/electronicstructure/a/Valences-Of-The-Elements.htmhttp://chemistry.about.com/od/electronicstructure/a/Valences-Of-The-Elements.htmhttp://www.chemicalelements.com/elements/sc.htmlhttp://www.chemicalelements.com/elements/sc.htmlhttp://www.chemicalelements.com/elements/ti.htmlhttp://www.chemicalelements.com/elements/v.htmlhttp://www.chemicalelements.com/elements/v.htmlhttp://www.chemicalelements.com/elements/cr.htmlhttp://www.chemicalelements.com/elements/cr.htmlhttp://www.chemicalelements.com/elements/mn.htmlhttp://www.chemicalelements.com/elements/mn.htmlhttp://www.chemicalelements.com/elements/fe.htmlhttp://www.chemicalelements.com/elements/co.htmlhttp://www.chemicalelements.com/elements/ni.htmlhttp://www.chemicalelements.com/elements/cu.htmlhttp://www.chemicalelements.com/elements/zn.htmlhttp://www.chemicalelements.com/elements/y.htmlhttp://www.chemicalelements.com/elements/zr.htmlhttp://www.chemicalelements.com/elements/zr.htmlhttp://www.chemicalelements.com/elements/nb.htmlhttp://www.chemicalelements.com/elements/mo.htmlhttp://www.chemicalelements.com/elements/mo.htmlhttp://www.chemicalelements.com/elements/tc.htmlhttp://www.chemicalelements.com/elements/tc.htmlhttp://www.chemicalelements.com/elements/ru.htmlhttp://www.chemicalelements.com/elements/ru.htmlhttp://www.chemicalelements.com/elements/rh.htmlhttp://www.chemicalelements.com/elements/pd.htmlhttp://www.chemicalelements.com/elements/pd.htmlhttp://www.chemicalelements.com/elements/ag.htmlhttp://www.chemicalelements.com/elements/cd.htmlhttp://www.chemicalelements.com/elements/hf.htmlhttp://www.chemicalelements.com/elements/ta.htmlhttp://www.chemicalelements.com/elements/w.htmlhttp://www.chemicalelements.com/elements/re.htmlhttp://www.chemicalelements.com/elements/os.htmlhttp://www.chemicalelements.com/elements/ir.htmlhttp://www.chemicalelements.com/elements/pt.htmlhttp://www.chemicalelements.com/elements/au.htmlhttp://www.chemicalelements.com/elements/hg.htmlhttp://www.chemicalelements.com/elements/rf.htmlhttp://www.chemicalelements.com/elements/rf.htmlhttp://www.chemicalelements.com/elements/db.htmlhttp://www.chemicalelements.com/elements/sg.htmlhttp://www.chemicalelements.com/elements/sg.htmlhttp://www.chemicalelements.com/elements/bh.htmlhttp://www.chemicalelements.com/elements/hs.htmlhttp://www.chemicalelements.com/elements/mt.htmlhttp://www.chemicalelements.com/elements/mt.htmlhttp://www.chemicalelements.com/elements/uun.htmlhttp://www.chemicalelements.com/elements/uun.htmlhttp://www.chemicalelements.com/elements/uuu.htmlhttp://www.chemicalelements.com/elements/uuu.htmlhttp://www.chemicalelements.com/elements/uub.htmlhttp://en.wikipedia.org/wiki/IUPAC
8/17/2019 Transitioning Metals
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charged forms& The positi%e oidation states allow transition elements to form many
different ionic and partially ionic compo#nds& The formation of complees ca#ses
the d orbitals to split into two energy s#ble%els, which enables many of the complees to
absorb specific fre9#encies of light& Th#s, the complees form characteristic colored
sol#tions and compo#nds& Compleation reactions sometimes enhance the relati%ely low
sol#bility of some compo#nds&
• 5igh melting points
• 5igh boiling points
• 5igh electrical cond#cti%ity
• 'alleable
• i%e d orbitals become more filled, from left to right on periodic table