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ATTACHED TO REPORTS 17.45282R1 – 17.45283R1 – 17.45286R1 Page 1 of 2 APPLICANT DATE: 25/10/2017 DATE REVISION: 9/11/2017 BENETTON GROUP Srl PAGE: 3 Via Villa Minelli, 1 31050 Ponzano Veneto (TV) Facility: TINTORIA INDUSTRIALE S. GIORGIO, Via Volta 9 - 35042 Este (PD) Sample Description: INCOMING WATER Date and hour of sampling: 05/10/2017 Start: h 10:15 – End: h 13:15 Sampling location: Well water mixing canal Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: MICI0510201701 Sample Description: RAW WASTEWATER Date and hour of sampling: 05/10/2017 Start: h 9:45 – End: h 12:45 Sampling location: Homogenization tank Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: MICI0510201701 Sample Description: TREATED WATER Date and hour of sampling: 05/10/2017 Start: h 9:30 – End: h 12:30 Sampling location: Inspection Well Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: MICI0510201701 NOTE: NOTE ON REVISED: We revised this report in order to update the grid, as requested by the Client.

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Page 1: TINTORIA INDUSTRIALE S. GIORGIO - Benetton Groupstatic.benettongroup.com/wp-content/uploads/2018/... · TSS -Total suspended solid Exceeded COD - Chemical oxygen demand Exceeded pH

ATTACHED TO REPORTS 17.45282R1 – 17.45283R1 – 17.45286R1

Page 1 of 2

APPLICANT

DATE: 25/10/2017 DATE REVISION: 9/11/2017

BENETTON GROUP Srl PAGE: 3

Via Villa Minelli, 1

31050 Ponzano Veneto (TV)

Facility: TINTORIA INDUSTRIALE S. GIORGIO, Via Volta 9 - 35042 Este (PD)

Sample Description:

INCOMING WATER Date and hour of sampling: 05/10/2017 Start: h 10:15 – End: h 13:15 Sampling location: Well water mixing canal Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: MICI0510201701

Sample Description:

RAW WASTEWATER Date and hour of sampling: 05/10/2017 Start: h 9:45 – End: h 12:45 Sampling location: Homogenization tank Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: MICI0510201701

Sample Description:

TREATED WATER Date and hour of sampling: 05/10/2017 Start: h 9:30 – End: h 12:30 Sampling location: Inspection Well Sampling method: COMPOSITE SAMPLE Sampling by: UL In-charge Technician Sampling Record N°: MICI0510201701

NOTE: NOTE ON REVISED: We revised this report in order to update the grid, as requested by the Client.

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Page 2 of 2

1A) CONVENTIONAL PARAMETERS (TREATED WATER 17.45286R1)

Foundational Progressive Aspirational

Temperature X TSS -Total suspended solid Exceeded

COD - Chemical oxygen demand Exceeded pH - Colour X BOD5 - Biological oxygen demand (5 days) Exceeded Total-P - Total phosphorus X Oil and Grease X Phenol X Metals X As Cr (VI) - Hexavalent Chromium X Total-N - Total nitrogen X Ammonium-N - Ammonium nitrogen Exceeded Sulfide X Sulfite Exceeded Persistent Foam - Cyanide X AOX X Coliform X

ZDHC MRSL PARAMETERS INCOMING WATER (17.45282R1)

RAW WASTEWATER (17.45283R1)

TREATED WATER (17.45286R1)

2A) Alkylphenol and Alkylphenol ethoxylates N/R ! N/R 2B) Chlorinated Benzenes and Toluenes N/R ! N/R 2C) Chlorophenols N/R ! N/R 2D) Azo-dyes N/R ! N/R 2E) Colourants - Carcinogenic N/R ! N/R 2F) Colourants – Disperse N/R ! N/R 2G) Flame Retardants N/R ! N/R 2H) Glycols N/R ! N/R 2I) Halogenated solvents N/R ! N/R 2J) Organotin compounds N/R ! N/R 2K) Perfluorinated compounds (PFCs) N/R ! N/R 2L) Phthalates N/R ! N/R 2M) Polycyclic aromatic hydrocarbons N/R ! N/R 2N) Organic Volatile compounds ! " N/R Metals " " " Cr (VI) - Hexavalent Chromium ! " ! Cyanide N/R ! !

Note/Key:

" : Detected ! : Not Detected N/R : Not Requested N/A : Not Applicable

Chemical Laboratory Supervisor Claudio Sironi

REMARKS 1. It is prohibited the partial reproduction, any changes or modifications of this test report. The results are

exclusively referred to the samples tested.

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Issue date:06 Oct 2017201725 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45282R1a Rev. No.: 1 dated 9 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45282R1

17.45282R1a

This report cancels and replaces the previous one (17.45282) issued on 25/10/17.

Cr VIIdentification Parts

Incoming water - TINTORIA INDUSTRIALE S. GIORGIO, Via Volta 9 - 35042 Este (PD)SAMPLE DESCRIPTION (no. 372797)

Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

Incoming water < 0,001

The results expressed are in mg/L.

The symbol < followed by a number indicates that the concentration of the substance is lower than the limit of

quantification (LOQ)

Legend:

Requirements:

Conclusion: See results.

Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:

page 1 of 3MD Standard Report CH_v5/14

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Identification Parts

52012

TEST REPORT: 17.45282R1a Rev. No.: 1 dated 09 November 2017

Volatile Organic Compounds

Method: According to ISO 11423-1

Instrument: GC-MS headspace

T F A RD

This report cancels and replaces the previous one (17.45282) issued on 25/10/17.

BenzeneXyleneo-cresolp-cresolm-cresol

71-43-21330-20-795-48-7106-44-5108-39-4

< 1< 1< 1< 1< 1

Incoming water

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 11423-1 Volatile Organic Compounds (VOC)Requirements:

Conclusion: See results.Reference:

Note:

page 2 of 3MD Standard Report CH_v5/14

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Identification Parts

52024

TEST REPORT: 17.45282R1a Rev. No.: 1 dated 09 November 2017

Metals

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

T F A RD

Compound

This report cancels and replaces the previous one (17.45282) issued on 25/10/17.

PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,001< 0,010,036

< 0,01< 0,25< 0,05

< 0,5< 0,05

< 0,005

Incoming water

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO17294-2 (2016) and ISO 11885 (2007) MetalsRequirements:

Conclusion: See results.Reference:

Note:

page 3 of 3MD Standard Report CH_v5/14 ••• END OF REPORT •••

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Issue date:06 Oct 2017201725 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 9 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45283R1

17.45283R1a

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

Cr VIIdentification Parts

Raw wastewater - TINTORIA INDUSTRIALE S. GIORGIO, Via Volta 9 - 35042 Este (PD)SAMPLE DESCRIPTION (no. 372798)

Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

Raw wastewater 0,010

The results expressed are in mg/L.

The symbol < followed by a number indicates that the concentration of the substance is lower than the limit of

quantification (LOQ)

Legend:

Requirements:

Conclusion: See results.

Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:

page 1 of 16MD Standard Report CH_v5/14

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CyanideIdentification Parts

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 9 Nov 2017

Cyanide

Method: ISO 6703-1:1984

Instrument: UV-Visible Spectrophotometer

T F A RD

52040

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

Raw wastewater < 0,05

The results expressed are in mg/L.

The symbol < followed by a number indicates that the concentration of the substance is less than the limit of

quantification (LOQ)

Legend:

Requirements:

Conclusion: .

Reference: According to ISO 6703-1:1984 Cyanide

Note:

page 2 of 16MD Standard Report CH_v5/14

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Identification Parts Result

52000

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Chlorobenzenes and Chlorotoluenes

Method: According to USEPA 8260B, 8270D

Instrument: Gaschromatograph with Mass detector

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

Monochlorobenzene1,2-dichlorobenzene1,3-dichlorobenzene1,4-dichlorobenzene1,2,3-trichlorobenzene1,2,4-trichlorobenzene1,3,5-trichlorobenzene1,2,3,4-tetrachlorobenzene1,2,3,5-tetrachlorobenzene1,2,4,5-tetrachlorobenzenePentachlorobenzeneHexachlorobenzene2-chlorotoluene3-chlorotoluene4-chlorotoluene2,3-dichlorotoluene2,4-dichlorotoluene2,5-dichlorotoluene2,6-dichlorotoluene3,4-dichlorotoluene3,5-dichlorotoluene2,3,4-trichlorotoluene2,3,6-trichlorotoluene2,4,5-trichlorotoluene2,4,6-trichlorotoluene3,4,5-trichlorotoluene2,3,4,5-tetrachlorotoluene2,3,5,6-tetrachlorotoluene2,3,4,6-tetrachlorotoluenePentachlorotoluene

108-90-795-50-1541-73-1106-46-787-61-6120-82-1108-70-3634-66-2634-90-295-94-3608-93-5118-74-195-49-8108-41-8106-43-432768-54-095-73-819398-61-9118-69-495-75-025186-47-47359-72-02077-46-56639-30-123749-65-721472-86-676057-12-029733-70-8875-40-1877-11-2

< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2< 0,2

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8260B, 8270D Chlorobenzenes and ChlorotoluenesRequirements:

Conclusion: See results.Reference:

Note:

page 3 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52001

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Chlorophenols

Method: According to USEPA 8270D

Instrument: Gas Chromatograph with Mass Detector (MS)

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

2-Chlorophenol3-Chlorophenol4-Chlorophenol2,3-Dichlorophenol2,4-Dichlorophenol2,5-Dichlorophenol2,6-Dichlorophenol3,4-Dichlorophenol3,5-Dichlorophenol2,3,4-Trichlorophenol2,3,5-Trichlorophenol2,3,6-Trichlorophenol2,4,5-Trichlorophenol2,4,6-Trichlorophenol3,4,5-Trichlorophenol2,3,4,5-Tetrachlorophenol2,3,4,6-Tetrachlorophenol2,3,5,6-TetrachlorophenolPentachlorophenol

95-57-8108-43-0106-48-9576-24-9120-83-2583-78-887-65-095-77-2591-35-515950-66-0933-78-8933-75-595-95-488-06-2609-19-84901-51-358-90-2935-95-587-86-5

< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5< 0,5

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270D ChlorophenolsRequirements:

Conclusion: See results.Reference:

Note:

page 4 of 16MD Standard Report CH_v5/14

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Identification Parts

52002

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Dyes - Azo

Method: According to EN ISO 14362-1:2017 , EN ISO 14362-3:2017

Instrument: Liquid chromatograph with Mass selective detector (HPLC -MS); Gas chromatograph with Mas selective detector (GC -MS).

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

4,4’-methylene-bis-(2-chloro-aniline)4,4’-methylenedianiline4,4’-oxydianiline4-chloroaniline3,3’-dimethoxylbenzidine3,3’-dimethylbenzidine6-methoxy-m-toluidine2,4,5-trimethylaniline4,4’-thiodianiline4-aminoazobenzene4-methoxy-m-phenylenediamine4,4’-methylene-di-o-toluidine2,6-xylidineo-anisidine2-naphthylamine3,3’-dichlorobenzidine4-aminodiphenylBenzidineo-toluidine2,4-xylidine4-chloro-o-toluidine4-methyl-m-phenylenediamineo-aminoazotoluene5-nitro-o-toluidine

101-14-4101-77-9101-80-4106-47-8119-90-4119-93-7120-71-8137-17-7139-65-160-09-3615-05-4838-88-087-62-790-04-091-59-891-94-192-67-192-87-595-53-495-68-195-69-295-80-797-56-399-55-8

< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1< 0,1

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration for every Aromatic Amines detected (See listbelow) is lower than the limit of quantification (LOQ).

Legend:

According to EN ISO 14362-1:2017 , EN ISO 14362-3:2017 Dyes - AzoRequirements:

Conclusion: The results found COMPLY with the above requirements.Reference:

Note:

page 5 of 16MD Standard Report CH_v5/14

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Identification Parts

52003

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Alkylphenol and Alkylphenol Ethoxylates

Method: According to ISO 18857-2 and ISO 18254-1

Instrument: H.P.L.C.with DAD/MSD detectors and Gaschromatograph with mass detector (GC-MS)

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

Nonylphenol (NP)

Octylphenol (OP)

Octylphenol ethoxylates, (OPEO)

Nonylphenol ethoxylates(NPEO)

104-40-511066-49-225154-52-384852-15-3140-66-91806-26-427193-28-89002-93-19036-19-568987-90-69016-45-926027-38-337205-87-168412-54-4127087-87-0

< 5

< 5

< 5

< 5

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 18857-2 and ISO 18254-1 Alkylohenol and Alkylphenol EthoxylatesRequirements:

Conclusion: See results.Reference:

Note:

page 6 of 16MD Standard Report CH_v5/14

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Identification Parts Result

52004

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Dyes Carcinogenic and Disperse

Method: According to DIN 54231

Instrument: Liquid cromatograph with DAD and MS detector

T F A RD

Compound

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

Disperse DyesCarcinogenic Dyes

< 50< 500

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

According to DIN 54231 Dyes - Carcinogenic and DisperseRequirements:

Conclusion: The results found COMPLY with the above requirements.Reference:

List of Disperse Dyes detected (Which are classified to be allergenic) - CAS Number––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Disperse Yellow 1 119-15-3 11 Disperse Red 17 3179-89-32 Disperse Blue 102 12222-97-8 12 Disperse Blue 7 3179-90-63 Dipserse Blue 106 12223-01-7 13 Disperse Blue 26 3860-63-74 Disperse Yellow 39 12236-29-2 14 Disperse Yellow 49 54824-37-25 Disperse Orange 37/76/59 13301-61-6 15 Disperse Blue 35 12222-75-26 Disperse Brown 1 23355-64-8 16 Disperse Blue 124 61951-51-77 Disperse Orange 1 2581-69-3 17 Disperse Yellow 9 6373-73-58 Disperse Yellow 3 2832-40-8 18 Disperse Orange 3 730-40-59 Disperse Red 11 2872-48-2 19 Disperse Blue 35 56524-77-710 Disperse Red 1 2872-52-8

List of Dyes detected (Which are classified to be carcinogenic) - CAS Number–––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––1 Acid Red 26 3761-53-3 9 Disperse Blue 3 2475-46-92 Basic Red 9 569-61-9 10 Basic Blue 26 2580-56-53 Basic Violet 14 632-99-5 11 Basic Green 4 569-64-2/2437-29-8/10309-95-24 Direct Black 38 1937-37-75 Direct Blue 6 2602-46-26 Direct Red 28 573-58-07 Disperse Blue 1 2475-45-88 Disperse Orange 11 82-28-0

Note:

page 7 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52005

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Flame Retardants

Method: According to ISO 22032:2006

Instrument: Gaschromatograph with mass detector (GC-MS)

T F A RD

Compound

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

TCEPdecaBDETRISpentaBDEoctaBDEBISTEPAPBBTBBPAHBCDDBBMPTDCPSCCP

115-96-81163-19-5126-72-732534-81-932536-52-05412-25-9545-55-159536-65-179-94-73194-55-63296-90-013674-87-885535-84-8

< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5< 5

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)The substances determined are:TCEP : Tris(2-chloroethyl)phosphate; - DecaBDE : Decabromodiphenyl ether; - TRIS : Tris(2,3-dibromopropyl)-phosphate; - PentaBDE : Pentabromodiphenyl ether; - OctaBDE : Octabromodiphenyl ether; - BIS : Bis(2,3-dibromopropyl)phosphate; - TEPA : Tris(1-aziridinyl)phosphine oxide; - PBB : Polybromobiphenyls; - TBBPA :Tetrabromobisphenol A; - HBCDD : Hexabromocyclododecane; - BBMP : 2,2-bis(bromomethyl)-1,3-propanediol ; -TDCP : Tris(1,3-dichloro-isopropyl)phosphate ; - SCCP : Short-chain chlorinated paraffins

Legend:

According to ISO 22032:2006 Flame RetardantsRequirements:

Conclusion: See results.Reference:

Note:

page 8 of 16MD Standard Report CH_v5/14

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Identification Parts

52006

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Glycols

Method: According to USEPA 8270

Instrument: Gaschromatograph with Mass Detector

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

Bis(2-methoxyethyl)-ether2-ethoxyethanol2-ethoxyethyl acetateEthylene glycol dimethyl ether2-methoxyethanol2-methoxyethylacetate2-methoxypropylacetateTriethylene glycol dimethyl ether

111-96-6110-80-5111-15-9110-71-4109-86-4110-49-670657-70-4112-49-2

< 50< 50< 50< 50< 50< 50< 50< 50

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270 GlycolsRequirements:

Conclusion: See results.Reference:

Note:

page 9 of 16MD Standard Report CH_v5/14

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Identification Parts

52007

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Halogenated Solvents

Method: According to USEPA 8260B

Instrument: Gaschromatograph with FID and Mass Detector

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

1,2-DichloroethaneMethylene chlorideTrichloroethyleneTetrachloroethylene

107-06-275-09-279-01-6127-18-4

< 1< 1< 1< 1

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8260B Halogenated SolventsRequirements:

Conclusion: See results.Reference:

Note:

page 10 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52008

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Organotin Compounds

Method: According to ISO 17353

Instrument: Gas - Chromatograph with Mass Detector (GC-MSD)

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

METDMTTMTMBTDBTTBTMPTDPTTPTMOTDOTTOT

MultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultipleMultiple

< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01< 0,01

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)MET : Monomethyltin; - DMT: Dimethyltin; - TMT : Trimethyltin; MBT : Monobutyltin; - DBT : Dibutyltin; - TBT :Tributyltin; - MPT : Monophenyltin; - DPT : Diphenyltin; - TPT : Triphenyltin; - MOT : Monooctyltin; - DOT : Dioctyltin; -TOT : Trioctyltin.

Legend:

According to ISO 17353 Organotin CompoundsRequirements:

Conclusion: See results.Reference:

Note:

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Identification Parts

52009

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Perfluorinated and Polyfluorinated Chemicals (PFCs)

Method: According to DIN 38407-42

Instrument: Liquid Chromatograph with Mass detector and Gas Chromatography with mass detector

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

PFOS

PFOAPFBS

PFHxA8:2 FTOH6:2 FTOH

355-46-4432-50-7335-67-129420-49-329420-43-3307-24-4678-39-7647-42-7

< 0,01

< 0,01< 0,01

< 0,01< 1< 1

Raw wastewater

The results expressed are in µg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to DIN 38407-42 Perfluorinated and Polyfluorinated Chemicals (PFCs)Requirements:

Conclusion: See results.Reference:

Note:

page 12 of 16MD Standard Report CH_v5/14

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Identification Parts

52010

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Phthalates

Method: According to USEPA 8270D

Instrument: Gascromatograph with Mass Detector - Liquid Cromatograph with DAD and Mass detector

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

DEHPBBPDBPDEPDNOPDINPDIDPDIBPDnHPDMEPDPRPDIOPDCHPDNPDHNUPDIHP

117-81-785-68-784-74-284-66-2117-84-028553-12-026761-40-084-69-584-75-3117-82-8131-16-827554-26-384-61-784-76-468515-42-471888-89-6

< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10< 10

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the analyte is lower than the limit ofquantification (LOQ)

The phthalates determined are:DEHP : Bis (2-ethylhexyl) phthalate ; - BBP : Butyl benzyl phthalate ; - DBP : Di-n-butyl phthalate ; - DEP : Diethylphthalate; - DNOP : Di-n-octyl phthalate; - DINP : Di-isononyl phthalate; - DIDP : Di-iso-decyl phthalate ; - DIBP : Di-isobutyl phthalate ; - DnHP : Di-n-hexyl phthalate; - DMEP : Dimethoxyethyl phthalate; - DPRP : Di-n-propyl phthalate;- DIOP : Di-iso-octyl phthalate; - DCHP : Di-cyclohexyl phthalate; - DNP : Dinonyl phthalate; - DIHP : Di-isoheptylphthalate; - DHNUP : 1,2-Benzene-di-carboxylic acid, di-C7-11-branched and linear alkyl esters.

Legend:

According to USEPA 8270D PhthalatesRequirements:

Conclusion: The results found COMPLY with the above requirements.Reference:

Note:

page 13 of 16MD Standard Report CH_v5/14

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Identification Parts Results

52011

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Polycyclic Aromatic Hydrocarbons (PAH)

Method: According to USEPA 8270

Instrument: Gascromatograph with Mass Detector

T F A RD

Compound

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

Benzo(a)pyreneBenzo(e)pyreneBenzo(a)anthraceneBenzo(b)fluorantheneBenzo(j)fluorantheneBenzo(k)fluorantheneChryseneDibenzo(a,h)anthracene

AcenaphteneAcenaphthyleneAnthraceneBenzo(g,h,i)peryleneFluorantheneFluoreneIndeno(1,2,3-cd)pyreneNaphthalenePhenanthrenePyrene

50-32-8192-97-256-55-3205-99-2205-82-3207-08-9218-01-953-70-3

83-32-9208-96-8120-12-7191-24-2206-44-086-73-7193-39-591-20-385-01-8129-00-0

< 1< 1< 1< 1< 1< 1< 1< 1

< 1< 1< 1< 1< 1< 1< 1< 1< 1< 1

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number inicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to USEPA 8270 Polycyclic Aromatic Hydrocarbons (PAH)Requirements:

Conclusion: See results.Reference:

Note:

page 14 of 16MD Standard Report CH_v5/14

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Identification Parts

52012

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Volatile Organic Compounds

Method: According to ISO 11423-1

Instrument: GC-MS headspace

T F A RD

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

BenzeneXyleneo-cresolp-cresolm-cresol

71-43-21330-20-795-48-7106-44-5108-39-4

< 1< 1< 11,5< 1

Raw wastewater

The results are expressed in µg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

According to ISO 11423-1 Volatile Organic Compounds (VOC)Requirements:

Conclusion: See results.Reference:

Note:

page 15 of 16MD Standard Report CH_v5/14

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Identification Parts

52024

TEST REPORT: 17.45283R1a Rev. No.: 1 dated 09 November 2017

Metals

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

T F A RD

Compound

This report cancels and replaces the previous one (17.45283) issued on 25/10/17.

PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,001< 0,010,018

< 0,01< 0,25< 0,050,7490,143

< 0,005

Raw wastewater

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO17294-2 (2016) and ISO 11885 (2007) MetalsRequirements:

Conclusion: See results.Reference:

Note:

page 16 of 16MD Standard Report CH_v5/14 ••• END OF REPORT •••

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Issue date:06 Oct 2017201725 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45286R1

17.45286R1a

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

T°Identification Parts

Treated water - TINTORIA INDUSTRIALE S. GIORGIO, Via Volta 9 - 35042 Este (PD)

SAMPLE DESCRIPTION (no. 372799)

TemperatureMethod: According to US EPA 170.1

Instrument: Digital Thermometer

Treated water 27,3

The results are expressed in °C.Legend:

Requirements:

Conclusion: See results.Reference: According to US EPA 170.1 Temperature

Note:

page 1 of 18MD Standard Report CH_v5/14

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Persistent FoamIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Persistent Foam

Method: N/A

Instrument: Laboratory equipment

T F A RD

52014

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water Visible

//.Legend:

Requirements:

Conclusion: See results.Reference: N/A Persistent Foam

Note:

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TSSIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

TSS -Total suspended solid

Method: According to APAT CNR IRSA 2090B-MAN 29 2003

Instrument: Laboratory equipment

T F A RD

52015

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 58

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 2090B-MAN 29 2003 TSS- Total suspended solid

Note:

page 3 of 18MD Standard Report CH_v5/14

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CODIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

COD - Chemical oxygen demand

Method: According to APATCNR IRSA 5130

Instrument: Laboratory equipment

T F A RD

52016

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 248

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APATCNR IRSA 5130 COD - Chemical oxygen demand

Note:

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pHIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

pH

Method: According to APAT CNR IRSA 2060

Instrument: pH Meter

T F A RD

52017

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 7,6

//.Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 2060 pH

Note:

page 5 of 18MD Standard Report CH_v5/14

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BOD5Identification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

BOD5 - Biological oxygen demand (5 days)

Method: According to USEPA 405.1 (5DAYS)

Instrument: Laboratory equipment

T F A RD

52019

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 72

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is less than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.

Reference: According to USEPA 405.1 (5DAYS) BOD5 - Biological oxygen demand (5 days)

Note:

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Total-PIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Total-P - Total phosphorus

Method: According to ISO 15587:2002, ISO 11885:2007

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES)

T F A RD

52020

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 0,92

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to ISO 15587:2002, ISO 11885:2007 Total-P - Total phosphorus

Note:

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Oil and GreeseIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Oil and Greese

Method: According to APAT CNR IRSA 5160A

Instrument: Laboratory equipment

T F A RD

52021

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 10,0

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the substances is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 5160A Oil and Greese

Note:

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Cr VIIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Cr (VI) - Hexavalent Chromium

Method: According to USEPA 218.6

Instrument: Ion Cromatograph coupled with MS/UV detector

T F A RD

52025

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water < 0,001

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to USEPA 218.6 Chromium (VI) - Hexavalent Chromium

Note:

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Total-NIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Total-N - Total nitrogen

Method: According to APAT CNR IRSA 4060 Man. 29 2003

Instrument: UV-Visible Spectrophotometer

T F A RD

52026

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 17,5

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4060 Man. 29 2003 Total-N - Total nitrogen

Note:

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Ammonium-NIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Ammonium-N - Ammonium nitrogen

Method: ISO 7150-1:1984

Instrument: UV-Visible Spectrophotometer

T F A RD

52027

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 10,2

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4030 Man. 29 2003 Ammonium-N - Ammonium nitrogen

Note:

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SulfideIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Sulfide

Method: According to APAT CNR IRSA 4160 MAN 29 2003

Instrument: Laboratory equipment

T F A RD

52028

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water < 0,01

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4160 MAN 29 2003 Sulfide

Note:

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SulfiteIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Sulfite

Method: According to APAT CNR IRSA 4150B MAN 29 2003

Instrument: Laboratory equipment

T F A RD

52029

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water 4,7

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to APAT CNR IRSA 4150B MAN 29 2003 Sulfite

Note:

page 13 of 18MD Standard Report CH_v5/14

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CyanideIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

Cyanide

Method: ISO 6703-1:1984

Instrument: UV-Visible Spectrophotometer

T F A RD

52040

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water < 0,05

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is less than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to ISO 6703-1:1984 Cyanide

Note:

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AOXIdentification Parts

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 9 Nov 2017

AOX

Method: According to EPA 5030+EPA8260

Instrument: Gaschromatograph with Mass Detector (GC-MSD)

T F A RD

52041

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Treated water < 0,1

The results expressed are in mg/L.The symbol < followed by a number indicates that the concentration of the substance is lower than the limit ofquantification (LOQ)

Legend:

Requirements:

Conclusion: See results.Reference: According to EPA 5030+EPA8260 AOX

Note:

page 15 of 18MD Standard Report CH_v5/14

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Identification Parts

52018

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 09 November 2017

Colour

Method: According to ISO 7887-B:2011

Instrument: UV-Visible Spectrophotometer

T F A RD

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Spectral absorption coefficient λ = 436 nmSpectral absorption coefficient λ = 525 nmSpectral absorption coefficient λ = 620 nmpH value after filtration

< 2 m-1< 1 m-1< 1 m-1

7,66

Treated water

//.Legend:

According to ISO 7887-B:2011 Colour [Pt-Co]Requirements:

Conclusion: See results.Reference:

Note:

page 16 of 18MD Standard Report CH_v5/14

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Identification Parts

52022

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 09 November 2017

Phenol

Method: According to APAT CNR IRSA 5070 A1 Man 29 2003

Instrument: UV-Visible Spectrophotometer

T F A RD

Compound

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Phenol 0,33Treated water

The results expressed are in mg/L.The symbol < followed by a number indicates that the concetration fo the substance is lower than the detection limitexpressed by that number.

Legend:

According to APAT CNR IRSA 5070 A1 Man 29 2003 PhenolRequirements:

Conclusion: See results.Reference:

Note:

page 17 of 18MD Standard Report CH_v5/14

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Identification Parts

52024

TEST REPORT: 17.45286R1a Rev. No.: 1 dated 09 November 2017

Metals

Method: According to ISO17294-2 (2016) and ISO 11885 (2007)

Instrument: Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and Inductively Coupled Plasma with Mass Detector (ICP-MS)

T F A RD

Compound

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

PbCdHgSbAsCoCuNiZnCrAg

< 0,01< 0,01

< 0,001< 0,010,009

< 0,01< 0,25< 0,05

< 0,5< 0,05

< 0,005

Treated water

The results are expressed in mg/L.The symbol < followed by a number indicates that the concentration of the element is lower than the limit ofquantification (LOQ)

Legend:

According to ISO17294-2 (2016) and ISO 11885 (2007) MetalsRequirements:

Conclusion: See results.Reference:

Note:

page 18 of 18MD Standard Report CH_v5/14

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Issue date:06 Oct 2017201725 Oct 2017

Test beginning:

DATES APPLICANT

BENETTON GROUP Srl

TEST REPORT: 17.45286R1b Rev. No.: 1 dated 9 November 2017

T F A RD

This section is an integral part of the TEST REPORT 17.45286R1

17.45286R1b

This report cancels and replaces the previous one (17.45286) issued on 25/10/17.

Coliform (UFC/100ml)Identification Parts

Treated water - TINTORIA INDUSTRIALE S. GIORGIO, Via Volta 9 - 35042 Este (PD)

SAMPLE DESCRIPTION (no. 372799)

Coliform (UFC/100ml)

Method: According to ISO 9308-1:2014

Instrument: Laboratory equipment

Treated water 110

The results expressed are in UFC/100 ml.

The symbol < followed by a number indicates that the concetration fo the substance is lower than the detection limit

expressed by that number.

Results expressed according to ISO 8199:2005

Legend:

Requirements:

Conclusion: See results.

Reference: According to ISO 9308-1:2014 Coliform (UFC/100ml)

Note:

page 1 of 1MD Standard Report MB_v5/14 ••• END OF REPORT •••