The following list contains the Material Safety Data ... · S.A.R.A. Ti tle III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health Hazard S.A.R.A. Title III Section

The following list contains the Material Safety Data Sheets you requested. Please scoll down to view the requested MSDS(s).

Product MSDS Distributor Format Language Quantity

5870025 1429099 Hach Company OSHA English 15870025 1429449 Hach Company OSHA English 15870025 1457799 Hach Company OSHA English 15870025 1457799 Hach Company ROWGHS English 15870025 1429099 Hach Company ROWGHS English 15870025 1429449 Hach Company ROWGHS English 1__________________________________________________________________________________________________________Total Enclosures: 6

World HeadquartersHach CompanyP.O.Box 389 MSDS No: M00067Loveland, CO USA 80539(970) 669-3050

MATERIAL SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: AluVer ® 3 Aluminum ReagentCatalog Number: 1429099

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00067Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: Not applicableHazard: Causes severe eye irritation.Date of MSDS Preparation:

Day: 17Month: AprilYear: 2012

_____________________________________________________________________________2. COMPOSITION / INFORMATION ON INGREDIENTS

Disodium SuccinateCAS No.: 6106-21-4TSCA CAS Number: 150-90-3Percent Range: 20.0 - 30.0Percent Range Units: weight / weightLD50: None reportedLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: May cause irritation.

Succinic AcidCAS No.: 110-15-6TSCA CAS Number: 110-15-6Percent Range: 70.0 - 80.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 2260 mg/kgLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: Causes severe eye irritation.

Aurintricarboxylic Acid, Calcium SaltCAS No.: 63451-31-0TSCA CAS Number: 63451-31-0Percent Range: 1.0 - 5.0Percent Range Units: weight / weightLD50: None reportedLC50: None reportedTLV: Not established

PEL: Not establishedHazard: Toxic properties unknown.

_____________________________________________________________________________3. HAZARDS IDENTIFICATION

Emergency Overview:Appearance: Red to Reddish brown powderOdor: Irritating

CAUSES EYE IRRITATION MAY CAUSE RESPIRATORY TRACT IRRITATIONHMIS:

Health: 2Flammability: 1Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 2Flammability: 1Reactivity: 0Symbol: Not applicable

Potential Health Effects:Eye Contact: Causes severe irritationSkin Contact: Causes mild irritationSkin Absorption: No effects anticipated

Target Organs: Not applicableIngestion: May cause: diarrhea weakness gastrointestinal disturbances

Target Organs: None reportedInhalation: May cause: respiratory tract irritation

Target Organs: None reportedMedical Conditions Aggravated: Pre-existing: Eye conditions Respiratory conditionsChronic Effects: Chronic overexposure may cause central nervous system effectsCancer / Reproductive Toxicity Information:

This product does NOT contain any OSHA listed carcinogens.This product does NOT contain any IARC listed chemicals.This product does NOT contain any NTP listed chemicals.Additional Cancer / Reproductive Toxicity Information: None reported

Toxicologically Synergistic Products: None reported_____________________________________________________________________________4. FIRST AID

Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.Skin Contact (First Aid): Wash skin with plenty of water.Ingestion (First Aid): Give large quantities of water. Call physician immediately.Inhalation: Remove to fresh air.

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Can burn in fire, releasing toxic vapors.Flash Point: Not applicableMethod: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not availableHazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.Fire / Explosion Hazards: None reported

Static Discharge: None reported.Mechanical Impact: None reported

Extinguishing Media: Use media appropriate to surrounding fire conditionsFire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill

according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.Special Instructions (for accidental release): Not applicable304 EHS RQ (40 CFR 355): Not applicableD.O.T. Emergency Response Guide Number: None

_____________________________________________________________________________7. HANDLING / STORAGE

Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrialhygiene practices when using this product.Storage: Protect from: heat Keep away from: oxidizers Store at 10 - 30°C.

Flammability Class: Not applicable_____________________________________________________________________________8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT

Engineering Controls: Maintain general industrial hygiene practices when using this product.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves In the EU, the selected gloves must satisfy the specifications of EU Directive89/686/EEC and standard EN 374 derived from it. lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling. Protect from:heat Keep away from: oxidizersTLV: Not establishedPEL: Not established

_____________________________________________________________________________9. PHYSICAL / CHEMICAL PROPERTIES

Appearance: Red to Reddish brown powderPhysical State: SolidMolecular Weight: Not applicableOdor: IrritatingpH: 10% solution = 3.85Vapor Pressure: Not applicableVapor Density (air = 1): Not applicableBoiling Point: Not availableMelting Point: 145°C; 293°FSpecific Gravity/ Relative Density (water = 1; air =1): 1.66Evaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicablePartition Coefficient (n-octanol / water): Not applicableSolubility:

Water: SolubleAcid: SolubleOther: Not determined

Metal Corrosivity:Steel: 0.061 in/yrAluminum: 0.001 in/yr

_____________________________________________________________________________10. STABILITY / REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: HeatReactivity / Incompatibility: May react violently in contact with: oxidizersHazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.Hazardous Polymerization: Will not occur.

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Product Toxicological Data:LD50: None reportedLC50: None reportedDermal Toxicity Data: None reportedSkin and Eye Irritation Data: Succinic acid: Eye rabbit 1179 µg SEVEREMutation Data: None reportedReproductive Effects Data: None reported

Ingredient Toxicological Data: Succinic Acid: Oral rat LD50 = 2260 mg/kg_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product. Mobility in soil: No data available

Ingredient Ecological Information: --No ecological data available for the ingredients of this product.

_____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: NoneSpecial Instructions (Disposal): Dilute material with excess water making a weaker than 5% solution. Adjust to a pHbetween 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tap completely, slowly pour thereacted material to the drain. Allow cold water to run for 5 minutes to completely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Not Currently Regulated--

DOT Hazard Class: NADOT Subsidiary Risk: NADOT ID Number: NADOT Packing Group: NA

I.C.A.O.:I.C.A.O. Proper Shipping Name: Not Currently Regulated--

ICAO Hazard Class: NAICAO Subsidiary Risk: NAICAO ID Number: NAICAO Packing Group: NA

I.M.O.:I.M.O. Proper Shipping Name: Not Currently Regulated--

I.M.O. Hazard Class: NAI.M.O. Subsidiary Risk: NAI.M.O. ID Number: NAI.M.O. Packing Group: NA

Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item ISpart of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the itemis not regulated, the Chemical Kit classification does not apply.

_____________________________________________________________________________15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the Hazard Communication Standard.(29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reportingrequirements of Section 313 of Title III of SARA.--

302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Contains no RCRA regulated substances.

C.P.S.C.: Not applicableState Regulations:

California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): None

California Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicableNational Inventories:

U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).TSCA CAS Number: Not applicable

_____________________________________________________________________________16. OTHER INFORMATION

Intended Use: Laboratory Reagent Determination of aluminumReferences: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. In-house information. CCINFO RTECS.Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Technical Judgment.Revision Summary: Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).

_____________________________________________________________________________

Legend:NA - Not Applicable w/w - weight/weightND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safetyprograms in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATAOR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2012



Product Name: Bleaching 3 ReagentCatalog Number: 1429449


MSDS Number: M00068Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: Not applicableHazard: Causes eye burns.Date of MSDS Preparation:

Day: 15Month: OctoberYear: 2009


Sodium PyrophosphateCAS No.: 13472-36-1TSCA CAS Number: 7722-88-5Percent Range: 45.0 - 55.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 4000 mg/kg; oral mouse LD50 = 2980 mg/kgLC50: None reportedTLV: 5 mg/m3

PEL: 5 mg/m3

Hazard: Causes irritation.

Potassium PyrosulfateCAS No.: 7790-62-7TSCA CAS Number: 7790-62-7Percent Range: 45.0 - 55.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 2340 mg/kgLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: Causes eye burns.

Magnesium SulfateCAS No.: 10034-99-8TSCA CAS Number: 7487-88-9Percent Range: 1.0 - 5.0Percent Range Units: weight / weightLD50: Oral mouse LDLo = 5000 mg/kgLC50: None reportedTLV: Not established

PEL: Not establishedHazard: May cause irritation.


Emergency Overview:Appearance: White powderOdor: Irritating

CAUSES EYE BURNS MAY CAUSE RESPIRATORY TRACT IRRITATION

HMIS:Health: 3Flammability: 0Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.


Potential Health Effects:Eye Contact: Causes eye burns.Skin Contact: No effects are anticipatedSkin Absorption: None reported

Target Organs: None reportedIngestion: May cause: nausea vomiting irritation of the mouth and esophagus diarrhea

Target Organs: None reportedInhalation: May cause: respiratory tract irritation coughing sore throat

Target Organs: None reportedMedical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditionsChronic Effects: None reportedCancer / Reproductive Toxicity Information:

This product does NOT contain any OSHA listed carcinogens.

This product does NOT contain any IARC listed chemicals.

This product does NOT contain any NTP listed chemicals.

Additional Cancer / Reproductive Toxicity Information: In laboratory tests, when magnesium sulfate was given topregnant rats, a sharp reduction of both the number and the weight of the offspring was observed. Contains: anexperimental mutagen.

Toxicologically Synergistic Products: None reported_____________________________________________________________________________4. FIRST AID

Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.Skin Contact (First Aid): Wash skin with plenty of water.Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately. Never giveanything by mouth to an unconscious person.Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.


Flammable Properties: During a fire, this product decomposes to form toxic gases.Flash Point: Not applicableMethod: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicable

Upper Explosion Limits: Not applicableAutoignition Temperature: Not applicableHazardous Combustion Products: Toxic fumes of: sulfur oxides. phosphorus oxidesFire / Explosion Hazards: May react violently with: strong reducers


Extinguishing Media: Use media appropriate to surrounding fire conditionsFire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.



according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)when: a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.Special Instructions (for accidental release): Not applicable304 EHS RQ (40 CFR 355): Not applicableD.O.T. Emergency Response Guide Number: None


Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain generalindustrial hygiene practices when using this product.Storage: Keep away from: reducers Protect from: moisture heat


Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using thisproduct.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves lab coatInhalation Protection: dust / mist mask

Precautionary Measures: Keep away from: reducers Protect from: moisture heatTLV: Not establishedPEL: Not established


Appearance: White powderPhysical State: SolidMolecular Weight: Not applicableOdor: IrritatingpH: 5% solution = 3.85Vapor Pressure: Not applicableVapor Density (air = 1): Not applicableBoiling Point: Not applicableMelting Point: decomposes @ 210°C; 410°FSpecific Gravity (water = 1): 2.48Evaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicablePartition Coefficient (n-octanol / water): Not applicable

Solubility:Water: SolubleAcid: SolubleOther: Not determined

Metal Corrosivity:Steel: 0.001 in/yrAluminum: 0.016 in/yr


Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: Excess moisture Heating to decomposition.Reactivity / Incompatibility: Incompatible with: reducersHazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: phosphorus oxides sulfuroxidesHazardous Polymerization: Will not occur.


Product Toxicological Data:LD50: None reportedLC50: None reportedDermal Toxicity Data: None reportedSkin and Eye Irritation Data: None reportedMutation Data: None reportedReproductive Effects Data: Magnesium Sulfate - intraperitoneal rat TDLo = 750 mg/kg (17-21 days pregnant) TER -Sharp reduction in both the number and weight of offspring was observed.

Ingredient Toxicological Data: Potassium Pyrosulfate Oral rat LD50 = 2340 mg/kg; Sodium Pyrophosphate Oral rat LD50= 4000 mg/kg; Magnesium Sulfate Oral mouse LDLo = 5000 mg/kg

_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product.



EPA Waste ID Number: NoneSpecial Instructions (Disposal): Dilute material with excess water making a weaker than 5% solution. Adjust to a pHbetween 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tap completely, slowly pour thereacted material to the drain. Allow cold water to run for 5 minutes to completely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information.















California Perchlorate Rule CCR Title 22 Chap 33:Trade Secret Registry: Not applicableNational Inventories:



Intended Use: Determination of aluminumReferences: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. CCINFO RTECS. Canadian Centre forOccupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. In-house information. Outside Testing.Technical Judgment. Vendor Information.Revision Summary: Updates in Section(s) 14,

_____________________________________________________________________________




HACH COMPANY ©2009



Product Name: Ascorbic AcidCatalog Number: 1457799


MSDS Number: M00075Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: Not applicableHazard: Practically non-toxic.Date of MSDS Preparation:

Day: 15Month: OctoberYear: 2009


Ascorbic AcidCAS No.: 50-81-7TSCA CAS Number: 50-81-7Percent Range: > 99.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 11900 mg/kgLC50: None reportedTLV: Not establishedPEL: Not establishedHazard: Practically non-toxic.

Other componentCAS No.: Not applicableTSCA CAS Number: Not applicablePercent Range: < 1.0Percent Range Units: weight / weightLD50: Not applicableLC50: Not applicableTLV: Not establishedPEL: Not establishedHazard: Any ingredient(s) of this product listed as "Other component(s)" is not considered a health hazard to the user ofthis product.


Emergency Overview:Appearance: White to light yellow crystalsOdor: Sweet



Potential Health Effects:Eye Contact: No effects are anticipatedSkin Contact: No effects are anticipatedSkin Absorption: No effects anticipated

Target Organs: Not applicableIngestion: Very large doses may cause: gastrointestinal irritation diarrhea

Target Organs: None reportedInhalation: No effects anticipated

Target Organs: Not applicableMedical Conditions Aggravated: None reportedChronic Effects: No effects anticipatedCancer / Reproductive Toxicity Information:

O.S.H.A. Listed: No

IARC Listed: No

NTP Listed: No

Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.Toxicologically Synergistic Products: None reported

_____________________________________________________________________________4. FIRST AID

Eye Contact: Flush eyes with water. Call physician if irritation develops.Skin Contact (First Aid): Wash skin with soap and plenty of water.Ingestion (First Aid): Give large quantities of water. Call physician immediately.Inhalation: Remove to fresh air.


Flammable Properties: Can burn in fire, releasing toxic vapors.Flash Point: Not applicableMethod: Not applicableFlammability Limits:


Autoignition Temperature: Not availableHazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.Fire / Explosion Hazards: May react violently with: strong oxidizers


Extinguishing Media: Carbon dioxide Dry chemical. Water.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.


Spill Response Notice:

Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spillaccording to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drain with a large excess of water.Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of theevacuation.Special Instructions (for accidental release): Not applicable304 EHS RQ (40 CFR 355): Not applicableD.O.T. Emergency Response Guide Number: None


Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrialhygiene practices when using this product.Storage: Keep away from: oxidizers



Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling. Keep awayfrom: oxidizersTLV: Not establishedPEL: Not established


Appearance: White to light yellow crystalsPhysical State: SolidMolecular Weight: Not applicableOdor: SweetpH: 5% solution = 2.3Vapor Pressure: Not applicableVapor Density (air = 1): Not applicableBoiling Point: Not applicableMelting Point: 192°C; 378°FSpecific Gravity (water = 1): 1.65Evaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicablePartition Coefficient (n-octanol / water): Not applicableSolubility:

Water: SolubleAcid: Not determinedOther: Soluble in alcohol, glycerol

Metal Corrosivity:Steel: Not determinedAluminum: Not determined


Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: Excess moistureReactivity / Incompatibility: Incompatible with: oxidizers alkalies copper iron

Hazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.Hazardous Polymerization: Will not occur.


Product Toxicological Data:LD50: None reportedLC50: None reportedDermal Toxicity Data: None reportedSkin and Eye Irritation Data: None reportedMutation Data: Ascorbic acid - DNA damage human fibroblast 200 µmol/L; DNA damage human cell types 200µmol/L; DNA inhibition human HeLa cell 2500 µmol/LReproductive Effects Data: Ascorbic acid - Oral guinea pig TDLo 19500 mg/kg effects on newborn - biochemical andmetabolic; Oral guinea pig TDLo 5800 mg/kg effects on newborn - stillbirth; Oral guinea pig TDLo 2471 mg/kg effectson newborn - growth statistics

Ingredient Toxicological Data: Ascorbic acid Oral rat LD50 = 11900 mg/kg

_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: No information available on this product.

Ingredient Ecological Information: No ingredient information available.


EPA Waste ID Number: NoneSpecial Instructions (Disposal): Work in an approved fume hood. Dilute to 3 to 5 times the volume with cold water.Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tap completely,slowly pour the reacted material to the drain. Allow cold water to run for 5 minutes to completely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information.








Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item IS

part of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the itemis not regulated, the Chemical Kit classification does not apply.


U.S. Federal Regulations:O.S.H.A.: This product does not meet the criteria for a hazardous substance as defined in the Hazard CommunicationStandard. (29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): This product is not hazardous under 29CFR.1910.1200 and therefore is not covered by Title III under SARA.S.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reportingrequirements of Section 313 of Title III of SARA.--




California Perchlorate Rule CCR Title 22 Chap 33:Trade Secret Registry: Not applicableNational Inventories:



Intended Use: Laboratory ReagentReferences: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway,New Jersey: Merck and Co., Inc., 1989. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York:Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore:The Williams and Wilkins Co., 1984. Vendor Information. In-house information. Technical Judgment.Revision Summary: Updates in Section(s) 14,

_____________________________________________________________________________




HACH COMPANY ©2009



Product Name: Ascorbic AcidCatalog Number: 1457799


MSDS Number: M00075Chemical Name: Not applicableCAS Number: Not applicableAdditional CAS No. (for hydrated forms):Chemical Formula: Not applicableChemical Family: Not applicableIntended Use: Laboratory Reagent


This mixture is not classified as hazardous per GHS (UN publication ST/SG/AC.10/36/Add.3)GHS Classification:

Hazard categories: Not applicableGHS Label Elements:

Hazard statements: Not applicablePrecautionary statements: Not applicable



WHMIS Hazard Classification: Not applicableWHMIS Symbols: Not applicable


Hazardous Components according to GHS: NoAscorbic Acid

CAS Number: 50-81-7 Chemical Formula: C6H8O6

GHS Classification: Not applicablePercent Range: > 99.0Percent Range Units: weight / weight

PEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicableMagnesium Sulfate

CAS Number: 7487-88-9 Chemical Formula: MgSO4

GHS Classification: Not applicablePercent Range: < 1.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicable_____________________________________________________________________________4. FIRST AID MEASURES

General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to adoctor.Advice to doctor: Treat symptomatically.Eye Contact: Flush eyes with water. Call physician if irritation develops.Skin Contact (First Aid): Wash skin with soap and plenty of water.Inhalation: Remove to fresh air.Ingestion (First Aid): Give large quantities of water. Call physician immediately.


Flammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHScriteria.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.Extinguishing Media: Carbon dioxide Dry chemical. Water.Extinguishing Media NOT To Be Used: Not applicableFire / Explosion Hazards: May react violently with: strong oxidizersHazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.



according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: If permitted by regulation, Scoop up spilled material into a large beaker and dissolve with water.Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drainwith a large excess of water. Decontaminate the area of the spill with a soap solution. Otherwise, Pick up spill for disposaland place in a closed container Dispose of in accordance with local, state and federal regulations or laws.Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of theevacuation.DOT Emergency Response Guide Number: Not applicable

_____________________________________________________________________________7. HANDLING AND STORAGE

Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrialhygiene practices when using this product.Storage: Keep away from: oxidizersFlammability Class: Not applicable

_____________________________________________________________________________8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling. Keep awayfrom: oxidizersTLV: Not establishedPEL: Not establishedFor Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:

_____________________________________________________________________________9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: White to light yellow crystalsPhysical State: SolidMolecular Weight: Not applicableOdor: SweetOdor Threshold: Not availablepH: 5% solution = 2.3Metal Corrosivity:

Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.Steel: Not determinedAluminum: Not determined

Specific Gravity/ Relative Density (water = 1; air =1): 1.65Viscosity:Solubility:

Water: SolubleAcid: Not determinedOther: Soluble in alcohol, glycerol

Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point:Decomposition Temperature:Boiling Point: Not applicableVapor Pressure: Not applicableVapor Density (air = 1): Not applicableEvaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicableFlammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHScriteria.Flash Point: Not applicable

Method: Not applicableFlammability Limits:


Autoignition Temperature: Not availableExplosive Properties:Not classified according to GHS criteria.

Oxidizing Properties:Not classified according to GHS criteria.

Reactivity Properties:Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according to GHS

criteria.Gas under Pressure:Not classified according to GHS criteria.

_____________________________________________________________________________10. STABILITY AND REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reported

Static Discharge: None reported.Reactivity / Incompatibility: Incompatible with: oxidizers alkalies copper ironHazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.Conditions to Avoid: Excess moisture


Toxicokinetics, Metabolism and Distribution: No information available for mixture.Toxicologically Synergistic Products: None reportedAcute Toxicity:Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classification criteriaare not met.Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Based on classification principles, the classification criteria are not met.Eye Damage: Based on classification principles, the classification criteria are not met.Sensitization: Based on classification principles, the classification criteria are not met.CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): No germ cell mutagenicity, carcinogenicityor reproductive toxicity data found.IARC Listed: NoNTP Listed: NoO.S.H.A. Listed: No

Symptoms/Effects:Ingestion: Very large doses may cause: gastrointestinal tract irritation diarrheaInhalation: No effects anticipatedSkin Absorption: No effects anticipatedChronic Effects: No effects anticipated

Medical Conditions Aggravated: None reported_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: No information available on this product.Ingredient Ecological Information: No ingredient information available.


EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Work in an approved fume hood. Dilute to 3 to 5 times the volume with cold water.Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tap completely,slowly pour the reacted material to the drain. Allow cold water to run for 5 minutes to completely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.



Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

T.D.G.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NA

UN Number/PIN: NAPacking Group: NA



I.M.O.:Proper Shipping Name: Not Currently Regulated--




U.S. Federal Regulations:O.S.H.A.: This product does not meet the criteria for a hazardous substance as defined in the Hazard CommunicationStandard. (29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): This product is not hazardous under 29CFR.1910.1200 and therefore is not covered by Title III under SARA.S.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reportingrequirements of Section 313 of Title III of SARA.--


State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): NoneCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable

National Inventories:U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).

CAS Number: Not applicableCanadian Inventory Status: All ingredients of this product are DSL Listed.EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.Australian Inventory (AICS) Status: All ingredients are listed.New Zealand Inventory (NZIoC) Status: All components either listed or exempt.Korean Inventory (KECI) Status: All components of this product are either listed, listed as the anhydrous compound orexempt.Japan (ENCS) Inventory Status: Some ingredients are not listed or exempt.China (PRC) Inventory (MEP) Status: All components either listed or exempt.


References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54, No.12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway,New Jersey: Merck and Co., Inc., 1989. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York:

Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products, 5th Ed. Baltimore:The Williams and Wilkins Co., 1984. Vendor Information. In-house information. Technical Judgment.Complete Text of H phrases referred to in Section 3: Not applicableRevision Summary: . . Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).Date of MSDS Preparation:

Day: 24Month: JuneYear: 2013

MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350CCOHS Evaluation Note: It is offered under exemption from WHMIS labeling as specified in the Controlled ProductsRegulation (CPR) Section 17. It is offered under the interim policy that was established by Health Canada permitting useof GHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified andlabeled in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3). This SDS has been prepared in accordancewith the requirements of GHS (ST/SG/AC.10/36/Add.3).

_____________________________________________________________________________




HACH COMPANY ©2013



Product Name: AluVer ® 3 Aluminum ReagentCatalog Number: 1429099


MSDS Number: M00067Chemical Name: Not applicableCAS Number: Not applicableAdditional CAS No. (for hydrated forms): Not applicableChemical Formula: Not applicableChemical Family: Not applicableIntended Use: Laboratory Reagent Determination of aluminum


GHS Classification:Hazard categories: . Serious Eye Damage/Eye Irritation:Eye Irrit. 2 Skin Corrosion/Irritation: Skin Irrit. 2 SpecificTarget Organ Toxicity - Single Exposure: STOT SE 3

GHS Label Elements:

Hazard statements: . Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation.Precautionary statements: Wash thoroughly after handling. Wear protective gloves / protective clothing / eye protection/ face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Ifeye irritation persists: Get medical advice/attention. Avoid breathing dust/fume/gas/mist/vapours/spray. Use onlyoutdoors or in a well-ventilated area. IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathing. Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. IF ONSKIN: Wash with plenty of soap and water. P321 Specific treatment (see supplemental first aid instructions on thislabel). If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.



WHMIS Hazard Classification: Class D, Division 2, Subdivision B - Toxic material (other toxic effects)WHMIS Symbols: Other Toxic Effects


Hazardous Components according to GHS:Succinic Acid

CAS Number: 110-15-6 Chemical Formula: HOOCCH2CH2COOHGHS Classification: skin irr 2, H315; ey erri 2A, H319Percent Range: 70.0 - 80.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Other Toxic EffectsDisodium Succinate

CAS Number: 150-90-3 Chemical Formula: C4H4O4Na2

GHS Classification: Acute Tox. Orl. 4, H302Percent Range: 20.0 - 30.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Not applicableAurintricarboxylic Acid, Calcium Salt

CAS Number: 63451-31-0 Chemical Formula: C44H22O18Ca3

GHS Classification: Aquat. Ch. 3, H412Percent Range: 1.0 - 5.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established


General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to adoctor.Advice to doctor: Treat symptomatically.Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.Skin Contact (First Aid): Wash skin with plenty of water.Inhalation: Remove to fresh air.Ingestion (First Aid): Give large quantities of water. Call physician immediately.


Flammable Properties: Can burn in fire, releasing toxic vapors.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.Extinguishing Media: Use media appropriate to surrounding fire conditionsExtinguishing Media NOT To Be Used: Not applicableFire / Explosion Hazards: None reportedHazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide.



according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: If permitted by regulation, Scoop up spilled material into a large beaker and dissolve with water.Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drainwith a large excess of water. Decontaminate the area of the spill with a soap solution. Otherwise, Pick up spill for disposaland place in a closed container Dispose of in accordance with local, state and federal regulations or laws.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan) when:a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.DOT Emergency Response Guide Number: Not applicable


Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrialhygiene practices when using this product.Storage: Protect from: heat Keep away from: oxidizers Store at 10 - 30°C.Flammability Class: Not applicable



Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves In the EU, the selected gloves must satisfy the specifications of EU Directive89/686/EEC and standard EN 374 derived from it. lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling. Protect from:heat Keep away from: oxidizersTLV: Not establishedPEL: Not establishedFor Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:


Appearance: Red to Reddish brown powderPhysical State: SolidMolecular Weight: Not applicableOdor: IrritatingOdor Threshold: Not availablepH: 10% solution = 3.85Metal Corrosivity:

Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.Steel: 0.061 in/yrAluminum: 0.001 in/yr

Specific Gravity/ Relative Density (water = 1; air =1): 1.66Viscosity: Not determinedSolubility:


Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point: 145°C; 293°FDecomposition Temperature: Not determinedBoiling Point: Not availableVapor Pressure: Not applicableVapor Density (air = 1): Not applicableEvaporation Rate (water = 1): Not applicable

Volatile Organic Compounds Content: Not applicableFlammable Properties: Can burn in fire, releasing toxic vapors.Flash Point: Not applicable



Autoignition Temperature: Not availableExplosive Properties:Not classified according to GHS criteria.



criteria.Gas under Pressure:Not classified according to GHS criteria.Not determined


Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reportedStatic Discharge: None reported.Reactivity / Incompatibility: May react violently in contact with: oxidizersHazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.Conditions to Avoid: Heat


Toxicokinetics, Metabolism and Distribution: No information available for mixture.Toxicologically Synergistic Products: None reportedAcute Toxicity: Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity DataATE Oral Rat LD50 = 1894 mg/kg

Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classification criteriaare not met. Respiratory TractSpecific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Irritating to skin.Eye Damage: Irritating to eyes.Sensitization: Based on classification principles, the classification criteria are not met.CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): No germ cell mutagenicity, carcinogenicityor reproductive toxicity data found.This product does NOT contain any IARC listed chemicals.This product does NOT contain any NTP listed chemicals.This product does NOT contain any OSHA listed carcinogens.

Symptoms/Effects:Ingestion: May cause: diarrhea weakness gastrointestinal disturbancesInhalation: May cause: respiratory tract irritationSkin Absorption: No effects anticipatedChronic Effects: Chronic overexposure may cause central nervous system effects

Medical Conditions Aggravated: Pre-existing: Eye conditions Respiratory conditions_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product. Mobility in soil: No data availableCEPA Categorization: Not Persistent or Bioaccumulative. Not inherently toxic to aquatic organisms.


_____________________________________________________________________________

13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Dilute material with excess water making a weaker than 5% solution. Adjust to a pHbetween 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tap completely, slowly pour thereacted material to the drain. Allow cold water to run for 5 minutes to completely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.





Hazard Class: NASubsidiary Risk: NAUN Number/PIN: NAPacking Group: NA









302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicable

RCRA: Contains no RCRA regulated substances.State Regulations:

California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): NoneCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable


CAS Number: Not applicableCanadian Inventory Status: All ingredients of this product are DSL Listed.EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.Australian Inventory (AICS) Status: Some ingredients are not listed.New Zealand Inventory (NZIoC) Status: All components either listed or exempt.Korean Inventory (KECI) Status: Some ingredients are not listed or exempt.Japan (ENCS) Inventory Status: All components either listed or exempt.China (PRC) Inventory (MEP) Status: Some ingredients are not listed or exempt.


References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54, No.12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. In-house information. CCINFO RTECS.Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Technical Judgment.Complete Text of H phrases referred to in Section 3: H319 Causes serious eye irritation.Revision Summary: . Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).Date of MSDS Preparation:

Day: 17Month: AprilYear: 2013


_____________________________________________________________________________




HACH COMPANY ©2013



Product Name: Bleaching 3 ReagentCatalog Number: 1429449


MSDS Number: M00068Chemical Name: Not applicableCAS Number: Not applicableAdditional CAS No. (for hydrated forms): Not applicableChemical Formula: Not applicableChemical Family: Not applicableIntended Use: Laboratory Reagent Determination of aluminum


GHS Classification:Hazard categories: Serious Eye Damage/Eye Irritation:Eye Irrit. 2 Specific Target Organ Toxicity - Single Exposure:STOT SE 3

GHS Label Elements:

Hazard statements: Causes serious eye irritation. May cause respiratory irritation.Precautionary statements: Wash thoroughly after handling. Wear protective gloves / protective clothing / eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Use only outdoors or in a well-ventilated area. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Calla POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep container tightlyclosed. P405 Store locked up. P501 Dispose of contents/container according to state, local, federal or nationalregulations.



WHMIS Hazard Classification: Class D, Division 2, Subdivision B - Toxic material (other toxic effects)WHMIS Symbols: Other Toxic Effects


Hazardous Components according to GHS:Sodium Pyrophosphate

CAS Number: 7722-88-5 Chemical Formula: Na4P2O7

GHS Classification: Acute Tox. Orl 5, H303; Acute Tox. Derm. 3, H311; Skin Irrit. 3, H316; Eye Dam. 1, H318; STOTSingle 3, H335Percent Range: 45.0 - 55.0Percent Range Units: weight / weightPEL: 5 mg/m3

TLV: 5 mg/m3

WHMIS Symbols: Other Toxic EffectsPotassium Pyrosulfate

CAS Number: 7790-62-7 Chemical Formula: K2S2O7

GHS Classification: Eye Irrit. 2, H319Percent Range: 45.0 - 55.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established

WHMIS Symbols: Other Toxic EffectsHazardous Components according to GHS: No

Magnesium Sulfate

CAS Number: 7487-88-9 Chemical Formula: MgSO4

GHS Classification: Not applicablePercent Range: 1.0 - 5.0Percent Range Units: weight / weightPEL: Not establishedTLV: Not established


General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to adoctor.Advice to doctor: Treat symptomatically.Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.Skin Contact (First Aid): Wash skin with plenty of water.Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately. Never giveanything by mouth to an unconscious person.


Flammable Properties: During a fire, this product decomposes to form toxic gases.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.Extinguishing Media: Use media appropriate to surrounding fire conditionsExtinguishing Media NOT To Be Used: Not applicableFire / Explosion Hazards: May react violently with: strong reducersHazardous Combustion Products: Toxic fumes of: sulfur oxides. phosphorus oxides

_____________________________________________________________________________

6. ACCIDENTAL RELEASE MEASURES


according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: If permitted by regulation, Scoop up spilled material into a large beaker and dissolve with water.Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Flush reacted material to the drainwith a large excess of water. Decontaminate the area of the spill with a soap solution. Otherwise, Pick up spill for disposaland place in a closed container Dispose of in accordance with local, state and federal regulations or laws.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan) when:a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.DOT Emergency Response Guide Number: Not applicable


Handling: Avoid contact with eyes skin Do not breathe dust. Wash thoroughly after handling. Maintain generalindustrial hygiene practices when using this product.Storage: Keep away from: reducers Protect from: moisture heatFlammability Class: Not applicable



Eye Protection: safety glasses with top and side shieldsSkin Protection: disposable latex gloves In the EU, the selected gloves must satisfy the specifications of EU Directive89/686/EEC and standard EN 374 derived from it. lab coatInhalation Protection: dust / mist mask

Precautionary Measures: Keep away from: reducers Protect from: moisture heatTLV: Not establishedPEL: Not establishedFor Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:


Appearance: White powderPhysical State: SolidMolecular Weight: Not applicableOdor: IrritatingOdor Threshold: Not availablepH: 5% solution = 3.85Metal Corrosivity:

Corrosivity Classification: Not classified as corrosive to metals according to GHS criteria.Steel:Aluminum:

Specific Gravity/ Relative Density (water = 1; air =1): 2.48Viscosity: Not determinedSolubility:


Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point: decomposes @ 210 °C (410 °F)Decomposition Temperature: Not determinedBoiling Point: Not applicableVapor Pressure: Not applicableVapor Density (air = 1): Not applicable

Evaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicableFlammable Properties: During a fire, this product decomposes to form toxic gases.Flash Point: Not applicable



Autoignition Temperature: Not applicableExplosive Properties:Not classified according to GHS criteria.



criteria.Gas under Pressure:Not classified according to GHS criteria.Not determined


Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reportedStatic Discharge: None reported.Reactivity / Incompatibility: Incompatible with: reducersHazardous Decomposition: Heating to decomposition releases toxic and/or corrosive fumes of: phosphorus oxides sulfuroxidesConditions to Avoid: Excess moisture Heating to decomposition.


Toxicokinetics, Metabolism and Distribution: No information available for mixture.Toxicologically Synergistic Products: None reportedAcute Toxicity: Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity DataATE Oral LD50 = 2661 mg/kgATE Dermal LD50 = 626 mg/kg

Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classification criteriaare not met. Respiratory TractSpecific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Mildly irritating to skin.Eye Damage: Irritating to eyes.Sensitization: Based on classification principles, the classification criteria are not met.CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): No germ cell mutagenicity, carcinogenicityor reproductive toxicity data found.This product does NOT contain any NTP listed chemicals.This product does NOT contain any OSHA listed carcinogens.

Symptoms/Effects:Ingestion: May cause: nausea vomiting irritation of the mouth and esophagus diarrheaInhalation: May cause: respiratory tract irritation coughing sore throatSkin Absorption: None ReportedChronic Effects: None reported

Medical Conditions Aggravated: Pre-existing: Eye conditions Skin conditions Respiratory conditions_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product. Mobility in soil: No data availableCEPA Categorization: Persistent Not Bioaccumulative Not inherently toxic to aquatic organisms

Ingredient Ecological Information: --

No ecological data available for the ingredients of this product._____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Dilute material with excess water making a weaker than 5% solution. Adjust to a pHbetween 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. Open cold water tap completely, slowly pour thereacted material to the drain. Allow cold water to run for 5 minutes to completely flush the system.Empty Containers: Rinse three times with an appropriate solvent. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.





Hazard Class: NASubsidiary Risk: NAUN Number/PIN: NAPacking Group: NA









302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable

304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Contains no RCRA regulated substances.

State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): NoneCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable


CAS Number: Not applicableCanadian Inventory Status: All ingredients of this product are DSL Listed.EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.Australian Inventory (AICS) Status: All ingredients are listed.New Zealand Inventory (NZIoC) Status: All components either listed or exempt.Korean Inventory (KECI) Status: All components of this product are either listed, listed as the anhydrous compound orexempt.Japan (ENCS) Inventory Status: All components either listed or exempt.China (PRC) Inventory (MEP) Status: All components either listed or exempt.


References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54, No.12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices for1992-1993. American Conference of Governmental Industrial Hygienists, 1992. CCINFO RTECS. Canadian Centre forOccupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. In-house information. Outside Testing.Technical Judgment. Vendor Information.Complete Text of H phrases referred to in Section 3: H319 Causes serious eye irritation.Revision Summary: Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).Date of MSDS Preparation:

Day: 06Month: JanuaryYear: 2013


_____________________________________________________________________________




HACH COMPANY ©2013

Documents

The following list contains the Material Safety Data ... · S.A.R.A. Ti tle III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health Hazard S.A.R.A. Title III Section