Technical Report for Providence Engineering & Environmental

11/11/19

Technical Report for

Providence Engineering & Environmental

Bottle Art Lofts, University & Cameron, Lafayette, LA

SGS Job Number: LA58267

Sampling Date: 10/04/19

Report to:

Providence Engineering & Environmental1201 Main StreetBaton Rouge, LA [email protected]

ATTN: Ashlyn Holmes

Total number of pages in report:

Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31),NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257)

This report shall not be reproduced, except in its entirety, without the written approval of SGS.Test results relate only to samples analyzed.

SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: 337-237-4775

Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable.

Client Service contact: Amy Jackson 337-237-4775

Ron BenjaminLab Director

Scott, LA 11/11/19Reissue #1

e-Hardcopy 2.0Automated Report

283

SGS is the sole authority for authorizing edits or modifications to this document.Unauthorized modification of this report is strictly prohibited.Review standard terms at: http://www.sgs.com/en/terms-and-conditions

The results set forth herein are provided by SGS North America Inc.

Please share your ideas abouthow we can serve you better at:[email protected]

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SGS Scott, LA 500 Ambassador Caffery Parkway Scott, LA 70583, USA t +1 (0)337 237 4775 www.sgs.com

Member of the SGS Group (SGS SA)

SGS IS THE WORLD’S LEADING INSPECTION, VERIFICATION, TESTING AND CERTIFICATION COMPANY.

November 11, 2019

Providence Engineering and EnvironmentalATTN: Stephen Osborne1201 Main StreetBaton Rouge, LA 70802

RE: SGS Job #LA58267 “Bottle Art Lofts, University & Cameron, Lafayette, LA“

Dear Mr. Osborne,

The final report for SGS Job LA58267 has been amended from the original. This report replaces in its entirety any previously submitted copy.

The Nickel by EPA method 6020A result for B-7SS (0-2’) was originally reported as “-0.77mg/Kg” and has been corrected to <0.50 mg/Kg. The corrected results is included in this revised laboratory report. I apologize for the error and the inconvenience.

Sincerely,

Amy JacksonEnvironment, Health and SafetyProject ManagerSGS-Scott

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Table of Contents-1-

Sections:

Section 1: Sample Summary ................................................................................................... 5Section 2: Summary of Hits .................................................................................................... 7Section 3: Sample Results ........................................................................................................ 15

3.1: LA58267-1: C-2SS (0-2') ............................................................................................. 163.2: LA58267-2: C-2SS (22-24') ......................................................................................... 233.3: LA58267-3: C-2SS (28-30') ......................................................................................... 303.4: LA58267-4: B-4SS (0-2') ............................................................................................. 373.5: LA58267-5: B-4SS (8-10') ........................................................................................... 443.6: LA58267-6: B-4SS (18-20') ......................................................................................... 513.7: LA58267-7: B-7SS (0-2') ............................................................................................. 583.8: LA58267-8: B-7SS (14-16') ......................................................................................... 653.9: LA58267-9: B-7SS (18-20') ......................................................................................... 723.10: LA58267-10: B-7SS (8-10') ....................................................................................... 793.11: LA58267-11: B-8SS (0-2') .......................................................................................... 863.12: LA58267-12: B-8SS (10-12') ..................................................................................... 933.13: LA58267-13: B-8SS (23-25') ..................................................................................... 1003.14: LA58267-14: B-8SS (8-10') ....................................................................................... 1073.15: LA58267-15: B-1SS (0-2') ......................................................................................... 1143.16: LA58267-15A: B-1SS (0-2') ....................................................................................... 1213.17: LA58267-16: B-1SS (10-12') ..................................................................................... 1223.18: LA58267-17: B-1SS (18-20') ..................................................................................... 1293.19: LA58267-18: B-1SS (16-18') ..................................................................................... 1363.20: LA58267-19: BD-02 ................................................................................................... 1433.21: LA58267-20: FB-04 ................................................................................................... 1513.22: LA58267-21: TRIP BLANK ...................................................................................... 159

Section 4: Misc. Forms ............................................................................................................ 1614.1: Chain of Custody ........................................................................................................... 162

Section 5: MS Volatiles - QC Data Summaries ..................................................................... 1665.1: Method Blank Summary ................................................................................................ 1675.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1765.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 185

Section 6: MS Semi-volatiles - QC Data Summaries ............................................................ 1926.1: Method Blank Summary ................................................................................................ 1936.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1976.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 201

Section 7: GC Volatiles - QC Data Summaries ..................................................................... 2037.1: Method Blank Summary ................................................................................................ 2047.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 2107.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 216

Section 8: GC/LC Semi-volatiles - QC Data Summaries ..................................................... 2228.1: Method Blank Summary ................................................................................................ 2238.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 226

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Sections:

8.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 232Section 9: Metals Analysis - QC Data Summaries ................................................................ 236

9.1: Prep QC MP16530: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 2379.2: Prep QC MP16531: Hg .................................................................................................. 2489.3: Prep QC MP16534: Hg .................................................................................................. 2539.4: Prep QC MP16548: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 2589.5: Prep QC MP16691: As .................................................................................................. 268

Section 10: General Chemistry - QC Data Summaries ........................................................ 27210.1: Method Blank and Spike Results Summary ................................................................ 27310.2: Matrix Spike Results Summary ................................................................................... 27410.3: Matrix Spike Duplicate Results Summary .................................................................. 275

Section 11: Misc. Forms (SGS Houston, TX) ........................................................................ 27611.1: Chain of Custody ......................................................................................................... 277

Section 12: General Chemistry - QC Data (SGS Houston, TX) .......................................... 28012.1: Method Blank and Spike Results Summary ................................................................ 28112.2: Duplicate Results Summary ........................................................................................ 28212.3: Matrix Spike Results Summary ................................................................................... 283

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Sample Summary

Providence Engineering & EnvironmentalJob No: LA58267


Sample Collected Matrix ClientNumber Date Time By Received Code Type Sample ID

This report contains results reported as ND = Not detected. The following applies:Organics ND = Not detected above the RLMetals ND = Not detected above the RLGeneral Chemistry ND = Not detected above the RL

LA58267-1 10/04/19 15:55 SO 10/04/19 SO Soil C-2SS (0-2' )

LA58267-2 10/04/19 16:40 SO 10/04/19 SO Soil C-2SS (22-24' )

LA58267-3 10/04/19 17:10 SO 10/04/19 SO Soil C-2SS (28-30' )

LA58267-4 10/04/19 08:15 SO 10/04/19 SO Soil B-4SS (0-2' )

LA58267-4D 10/04/19 08:15 SO 10/04/19 SO Soil Dup/MSD B-4SS (0-2' )

LA58267-4S 10/04/19 08:15 SO 10/04/19 SO Soil Matrix Spike B-4SS (0-2' )

LA58267-5 10/04/19 09:00 SO 10/04/19 SO Soil B-4SS (8-10' )

LA58267-6 10/04/19 09:15 SO 10/04/19 SO Soil B-4SS (18-20' )

LA58267-7 10/04/19 09:35 SO 10/04/19 SO Soil B-7SS (0-2' )

LA58267-8 10/04/19 10:25 SO 10/04/19 SO Soil B-7SS (14-16' )

LA58267-9 10/04/19 10:40 SO 10/04/19 SO Soil B-7SS (18-20' )

Soil samples reported on a dry weight basis unless otherwise indicated on result page.

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Sample Summary(continued)




LA58267-10 10/04/19 11:15 SO 10/04/19 SO Soil B-7SS (8-10' )

LA58267-11 10/04/19 12:35 SO 10/04/19 SO Soil B-8SS (0-2' )

LA58267-12 10/04/19 13:20 SO 10/04/19 SO Soil B-8SS (10-12' )

LA58267-13 10/04/19 13:30 SO 10/04/19 SO Soil B-8SS (23-25' )

LA58267-14 10/04/19 13:45 SO 10/04/19 SO Soil B-8SS (8-10' )

LA58267-15 10/04/19 14:00 SO 10/04/19 SO Soil B-1SS (0-2' )

LA58267-15A 10/04/19 14:00 SO 10/04/19 SO Soil B-1SS (0-2' )

LA58267-16 10/04/19 14:35 SO 10/04/19 SO Soil B-1SS (10-12' )

LA58267-17 10/04/19 14:45 SO 10/04/19 SO Soil B-1SS (18-20' )

LA58267-18 10/04/19 14:55 SO 10/04/19 SO Soil B-1SS (16-18' )

LA58267-19 10/04/19 09:35 SO 10/04/19 SO Soil BD-02

LA58267-20 10/04/19 15:10 SO 10/04/19 AQ Field Blank Water FB-04

LA58267-21 10/04/19 00:00 SO 10/04/19 AQ Trip Blank Water TRIP BLANK


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Summary of Hits Page 1 of 8Job Number: LA58267Account: Providence Engineering & EnvironmentalProject: Bottle Art Lofts, University & Cameron, Lafayette, LACollected: 10/04/19

Lab Sample ID Client Sample ID Result/Analyte Qual RL MDL Units Method

LA58267-1 C-2SS (0-2')

Acetone 0.364 0.047 mg/kg SW846 8260BMethyl Ethyl Ketone 0.0186 0.012 mg/kg SW846 8260BArsenic 6.5 0.50 mg/kg SW846 6020ABarium 112 0.50 mg/kg SW846 6020AChromium 13.2 0.50 mg/kg SW846 6020ACobalt 8.8 0.50 mg/kg SW846 6020ACopper 9.6 0.50 mg/kg SW846 6020ALead 12.6 0.50 mg/kg SW846 6020ANickel 9.7 0.50 mg/kg SW846 6020ASelenium 3.8 2.5 mg/kg SW846 6020AVanadium 26.1 0.50 mg/kg SW846 6020AZinc 36.6 2.5 mg/kg SW846 6020A

LA58267-2 C-2SS (22-24')

Arsenic 3.3 0.46 mg/kg SW846 6020ABarium 54.7 0.46 mg/kg SW846 6020AChromium 10.5 0.46 mg/kg SW846 6020ACobalt 4.2 0.46 mg/kg SW846 6020ACopper 5.9 0.46 mg/kg SW846 6020ALead 7.6 0.46 mg/kg SW846 6020ANickel 8.1 0.46 mg/kg SW846 6020AVanadium 17.8 0.46 mg/kg SW846 6020AZinc 20.3 2.3 mg/kg SW846 6020A

LA58267-3 C-2SS (28-30')

Arsenic 5.8 0.47 mg/kg SW846 6020ABarium 54.0 0.47 mg/kg SW846 6020AChromium 8.8 0.47 mg/kg SW846 6020ACobalt 5.1 0.47 mg/kg SW846 6020ACopper 5.6 0.47 mg/kg SW846 6020ALead 5.5 0.47 mg/kg SW846 6020ANickel 8.1 0.47 mg/kg SW846 6020AVanadium 15.5 0.47 mg/kg SW846 6020AZinc 21.9 2.4 mg/kg SW846 6020A

LA58267-4 B-4SS (0-2')

Acetone 0.227 0.050 mg/kg SW846 8260BMethyl Ethyl Ketone 0.0131 0.013 mg/kg SW846 8260BArsenic 9.8 0.50 mg/kg SW846 6020ABarium 153 0.50 mg/kg SW846 6020A

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Beryllium 0.62 0.50 mg/kg SW846 6020AChromium 15.6 0.50 mg/kg SW846 6020ACobalt 9.0 0.50 mg/kg SW846 6020ACopper 14.4 0.50 mg/kg SW846 6020ALead 14.0 0.50 mg/kg SW846 6020ANickel 18.7 0.50 mg/kg SW846 6020ASelenium 3.4 2.5 mg/kg SW846 6020AVanadium 33.7 0.50 mg/kg SW846 6020AZinc 49.5 2.5 mg/kg SW846 6020A

LA58267-5 B-4SS (8-10')

Acetone 0.0967 0.050 mg/kg SW846 8260BArsenic 8.1 0.47 mg/kg SW846 6020ABarium 168 0.47 mg/kg SW846 6020AChromium 12.2 0.47 mg/kg SW846 6020ACobalt 7.1 0.47 mg/kg SW846 6020ACopper 12.6 0.47 mg/kg SW846 6020ALead 10.6 0.47 mg/kg SW846 6020ANickel 15.6 0.47 mg/kg SW846 6020ASelenium 2.8 2.4 mg/kg SW846 6020AVanadium 25.6 0.47 mg/kg SW846 6020AZinc 41.7 2.4 mg/kg SW846 6020A

LA58267-6 B-4SS (18-20')

Arsenic 10.6 0.48 mg/kg SW846 6020ABarium 224 0.48 mg/kg SW846 6020ABeryllium 1.8 0.48 mg/kg SW846 6020ACadmium 0.63 0.24 mg/kg SW846 6020AChromium 21.3 0.48 mg/kg SW846 6020ACobalt 17.1 0.48 mg/kg SW846 6020ACopper 13.7 0.48 mg/kg SW846 6020ALead 21.2 0.48 mg/kg SW846 6020ANickel 35.6 0.48 mg/kg SW846 6020ASelenium 3.4 2.4 mg/kg SW846 6020AVanadium 40.9 0.48 mg/kg SW846 6020AZinc 61.5 2.4 mg/kg SW846 6020A

LA58267-7 B-7SS (0-2')

Benzene 0.0770 0.00051 mg/kg SW846 8260BCarbon Disulfide 0.0044 0.0010 mg/kg SW846 8260B1,2-Dichloroethane 0.0021 0.0010 mg/kg SW846 8260BEthylbenzene 0.0071 0.0010 mg/kg SW846 8260B

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m,p-Xylene 0.0362 0.0020 mg/kg SW846 8260Bo-Xylene 0.0022 0.0010 mg/kg SW846 8260BXylene (total) 0.0384 0.0020 mg/kg SW846 8260BArsenic 3.3 0.50 mg/kg SW846 6020ABarium 114 0.50 mg/kg SW846 6020AChromium 8.3 0.50 mg/kg SW846 6020ACobalt 6.8 0.50 mg/kg SW846 6020ACopper 4.9 0.50 mg/kg SW846 6020ALead 11.5 0.50 mg/kg SW846 6020AVanadium 18.1 0.50 mg/kg SW846 6020AZinc 12.0 2.5 mg/kg SW846 6020A

LA58267-8 B-7SS (14-16')

Benzene 0.0071 0.00052 mg/kg SW846 8260B1,2-Dichloroethane 0.0088 0.0010 mg/kg SW846 8260BEthylbenzene 0.0047 0.0010 mg/kg SW846 8260BMethyl Ethyl Ketone 0.0232 0.013 mg/kg SW846 8260Bm,p-Xylene 0.0094 0.0021 mg/kg SW846 8260BXylene (total) 0.0103 0.0021 mg/kg SW846 8260BArsenic 3.8 0.50 mg/kg SW846 6020ABarium 96.2 0.50 mg/kg SW846 6020AChromium 14.6 0.50 mg/kg SW846 6020ACobalt 4.6 0.50 mg/kg SW846 6020ACopper 7.0 0.50 mg/kg SW846 6020ALead 9.6 0.50 mg/kg SW846 6020ANickel 8.1 0.50 mg/kg SW846 6020ASelenium 3.1 2.5 mg/kg SW846 6020AVanadium 21.2 0.50 mg/kg SW846 6020AZinc 26.1 2.5 mg/kg SW846 6020A

LA58267-9 B-7SS (18-20')

Benzene 0.0103 0.00051 mg/kg SW846 8260B1,2-Dichloroethane 0.0073 0.0010 mg/kg SW846 8260BEthylbenzene 0.0022 0.0010 mg/kg SW846 8260BMethyl Ethyl Ketone 0.0212 0.013 mg/kg SW846 8260Bm,p-Xylene 0.0045 0.0020 mg/kg SW846 8260BXylene (total) 0.0053 0.0020 mg/kg SW846 8260BArsenic 7.6 0.50 mg/kg SW846 6020ABarium 143 0.50 mg/kg SW846 6020ABeryllium 1.3 0.50 mg/kg SW846 6020AChromium 22.2 0.50 mg/kg SW846 6020ACobalt 5.9 0.50 mg/kg SW846 6020ACopper 16.4 0.50 mg/kg SW846 6020A

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Lead 16.5 0.50 mg/kg SW846 6020ANickel 19.7 0.50 mg/kg SW846 6020ASelenium 3.1 2.5 mg/kg SW846 6020AVanadium 35.2 0.50 mg/kg SW846 6020AZinc 59.5 2.5 mg/kg SW846 6020A

LA58267-10 B-7SS (8-10')

Benzene 2.25 0.025 mg/kg SW846 8260BEthylbenzene 4.53 0.050 mg/kg SW846 8260BToluene 0.0991 0.0050 mg/kg SW846 8260Bm,p-Xylene 14.1 0.10 mg/kg SW846 8260Bo-Xylene 0.344 0.050 mg/kg SW846 8260BXylene (total) 14.4 0.10 mg/kg SW846 8260BNaphthalene 0.0174 0.010 mg/kg SW846 8270DTPH-GRO (C6-C10) 847 20 mg/kg SW846 8015CArsenic 7.2 0.47 mg/kg SW846 6020ABarium 213 0.47 mg/kg SW846 6020ACadmium 0.32 0.24 mg/kg SW846 6020AChromium 12.6 0.47 mg/kg SW846 6020ACobalt 5.4 0.47 mg/kg SW846 6020ACopper 12.5 0.47 mg/kg SW846 6020ALead 9.2 0.47 mg/kg SW846 6020ANickel 18.0 0.47 mg/kg SW846 6020ASelenium 2.5 2.4 mg/kg SW846 6020AVanadium 22.5 0.47 mg/kg SW846 6020AZinc 57.9 2.4 mg/kg SW846 6020A

LA58267-11 B-8SS (0-2')

Benzene 0.0021 0.00052 mg/kg SW846 8260BEthylbenzene 0.0021 0.0010 mg/kg SW846 8260Bm,p-Xylene 0.0077 0.0021 mg/kg SW846 8260BXylene (total) 0.0080 0.0021 mg/kg SW846 8260BArsenic 8.9 0.46 mg/kg SW846 6020ABarium 117 0.46 mg/kg SW846 6020ABeryllium 0.53 0.46 mg/kg SW846 6020AChromium 18.4 0.46 mg/kg SW846 6020ACobalt 13.6 0.46 mg/kg SW846 6020ACopper 15.7 0.46 mg/kg SW846 6020ALead 13.7 0.46 mg/kg SW846 6020ANickel 16.3 0.46 mg/kg SW846 6020ASelenium 2.4 2.3 mg/kg SW846 6020AVanadium 33.8 0.46 mg/kg SW846 6020AZinc 47.1 2.3 mg/kg SW846 6020A

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LA58267-12 B-8SS (10-12')

Benzene 0.00086 0.00051 mg/kg SW846 8260BCarbon Disulfide 0.0018 0.0010 mg/kg SW846 8260Bm,p-Xylene 0.0026 0.0020 mg/kg SW846 8260BXylene (total) 0.0028 0.0020 mg/kg SW846 8260BArsenic 4.1 0.49 mg/kg SW846 6020ABarium 201 0.49 mg/kg SW846 6020ABeryllium 0.57 0.49 mg/kg SW846 6020AChromium 17.9 0.49 mg/kg SW846 6020ACobalt 4.6 0.49 mg/kg SW846 6020ACopper 10.6 0.49 mg/kg SW846 6020ALead 10.2 0.49 mg/kg SW846 6020ANickel 9.5 0.49 mg/kg SW846 6020ASelenium 2.9 2.5 mg/kg SW846 6020AVanadium 31.5 0.49 mg/kg SW846 6020AZinc 27.8 2.5 mg/kg SW846 6020A

LA58267-13 B-8SS (23-25')

Benzene 0.0051 0.00052 mg/kg SW846 8260B1,2-Dichloroethane 0.0059 0.0010 mg/kg SW846 8260BArsenic 3.3 0.50 mg/kg SW846 6020ABarium 174 0.50 mg/kg SW846 6020ABeryllium 1.2 0.50 mg/kg SW846 6020AChromium 25.5 0.50 mg/kg SW846 6020ACobalt 3.4 0.50 mg/kg SW846 6020ACopper 16.5 0.50 mg/kg SW846 6020ALead 11.8 0.50 mg/kg SW846 6020ANickel 15.5 0.50 mg/kg SW846 6020ASelenium 3.8 2.5 mg/kg SW846 6020AVanadium 28.9 0.50 mg/kg SW846 6020AZinc 64.2 2.5 mg/kg SW846 6020A

LA58267-14 B-8SS (8-10')

Benzene 0.0014 0.00050 mg/kg SW846 8260BEthylbenzene 0.0029 0.0010 mg/kg SW846 8260Bm,p-Xylene 0.0096 0.0020 mg/kg SW846 8260Bo-Xylene 0.0134 0.0010 mg/kg SW846 8260BXylene (total) 0.0229 0.0020 mg/kg SW846 8260BArsenic 7.3 0.49 mg/kg SW846 6020ABarium 144 0.49 mg/kg SW846 6020AChromium 12.6 0.49 mg/kg SW846 6020A

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Cobalt 8.6 0.49 mg/kg SW846 6020ACopper 13.2 0.49 mg/kg SW846 6020ALead 12.4 0.49 mg/kg SW846 6020ANickel 15.6 0.49 mg/kg SW846 6020ASelenium 3.4 2.5 mg/kg SW846 6020AVanadium 27.1 0.49 mg/kg SW846 6020AZinc 43.5 2.5 mg/kg SW846 6020A

LA58267-15 B-1SS (0-2')

Carbon Disulfide 0.0026 0.0010 mg/kg SW846 8260BArsenic 12.2 0.50 mg/kg SW846 6020ABarium 164 0.50 mg/kg SW846 6020ABeryllium 0.63 0.50 mg/kg SW846 6020AChromium 17.8 0.50 mg/kg SW846 6020ACobalt 7.9 0.50 mg/kg SW846 6020ACopper 15.7 0.50 mg/kg SW846 6020ALead 16.5 0.50 mg/kg SW846 6020ANickel 21.2 0.50 mg/kg SW846 6020ASelenium 3.5 2.5 mg/kg SW846 6020AVanadium 36.8 0.50 mg/kg SW846 6020AZinc 53.2 2.5 mg/kg SW846 6020A

LA58267-15A B-1SS (0-2')

Arsenic 0.0085 0.0010 mg/l SW846 6020A

LA58267-16 B-1SS (10-12')

TPH-GRO (C6-C10) 29.9 5.0 mg/kg SW846 8015CTPH-DRO (C10-C28) 16.9 5.0 mg/kg SW846 8015CArsenic 7.1 0.45 mg/kg SW846 6020ABarium 180 0.45 mg/kg SW846 6020ACadmium 0.31 0.23 mg/kg SW846 6020AChromium 12.3 0.45 mg/kg SW846 6020ACobalt 8.7 0.45 mg/kg SW846 6020ACopper 11.8 0.45 mg/kg SW846 6020ALead 11.8 0.45 mg/kg SW846 6020ANickel 15.8 0.45 mg/kg SW846 6020ASelenium 3.5 2.3 mg/kg SW846 6020AVanadium 25.7 0.45 mg/kg SW846 6020AZinc 44.7 2.3 mg/kg SW846 6020A

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LA58267-17 B-1SS (18-20')

Benzene 0.0011 0.00050 mg/kg SW846 8260B1,2-Dichloroethane 0.0015 0.0010 mg/kg SW846 8260BEthylbenzene 0.0012 0.0010 mg/kg SW846 8260BMethyl Ethyl Ketone 0.148 0.013 mg/kg SW846 8260BMethyl Tert Butyl Ether 0.0014 0.0010 mg/kg SW846 8260Bm,p-Xylene 0.0062 0.0020 mg/kg SW846 8260Bo-Xylene 0.0014 0.0010 mg/kg SW846 8260BXylene (total) 0.0075 0.0020 mg/kg SW846 8260BArsenic 5.4 0.49 mg/kg SW846 6020ABarium 163 0.49 mg/kg SW846 6020ABeryllium 1.0 0.49 mg/kg SW846 6020AChromium 19.0 0.49 mg/kg SW846 6020ACobalt 4.0 0.49 mg/kg SW846 6020ACopper 12.7 0.49 mg/kg SW846 6020ALead 14.4 0.49 mg/kg SW846 6020ANickel 13.8 0.49 mg/kg SW846 6020ASelenium 4.5 2.5 mg/kg SW846 6020AVanadium 27.1 0.49 mg/kg SW846 6020AZinc 41.7 2.5 mg/kg SW846 6020A

LA58267-18 B-1SS (16-18')

Methyl Ethyl Ketone 0.0137 0.013 mg/kg SW846 8260BMethyl Tert Butyl Ether 0.0026 0.0010 mg/kg SW846 8260Bm,p-Xylene 0.0027 0.0020 mg/kg SW846 8260BXylene (total) 0.0029 0.0020 mg/kg SW846 8260BArsenic 4.4 0.45 mg/kg SW846 6020ABarium 271 0.45 mg/kg SW846 6020ABeryllium 1.0 0.45 mg/kg SW846 6020ACadmium 0.31 0.23 mg/kg SW846 6020AChromium 17.9 0.45 mg/kg SW846 6020ACobalt 24.7 0.45 mg/kg SW846 6020ACopper 10.0 0.45 mg/kg SW846 6020ALead 31.7 0.45 mg/kg SW846 6020ANickel 32.3 0.45 mg/kg SW846 6020ASelenium 3.5 2.3 mg/kg SW846 6020AVanadium 29.9 0.45 mg/kg SW846 6020AZinc 30.4 2.3 mg/kg SW846 6020A

LA58267-19 BD-02

Benzene 0.00067 0.00051 mg/kg SW846 8260BArsenic 3.0 0.50 mg/kg SW846 6020A

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Barium 192 0.50 mg/kg SW846 6020AChromium 13.7 0.50 mg/kg SW846 6020ACobalt 4.4 0.50 mg/kg SW846 6020ACopper 10 0.50 mg/kg SW846 6020ALead 7.2 0.50 mg/kg SW846 6020ANickel 1.6 0.50 mg/kg SW846 6020AVanadium 15.9 0.50 mg/kg SW846 6020AZinc 34.8 2.5 mg/kg SW846 6020ANitrogen, Ammonia a 8.6 1.2 mg/kg EPA 350.1 MNitrogen, Nitrate a 5.7 4.9 mg/kg SW846 9056A

LA58267-20 FB-04

Diethyl Phthalate 0.0053 0.0050 mg/l SW846 8270DTPH-DRO (C10-C28) b 0.175 0.14 mg/l SW846 8015C

LA58267-21 TRIP BLANK

No hits reported in this sample.

(a) Analysis performed at SGS Houston, TX.(b) Confirmed by reextraction and reanalysis.

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Sample Results

Report of Analysis

Scott, LASection 3

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Report of Analysis Page 1 of 2

Client Sample ID: C-2SS (0-2' ) Lab Sample ID: LA58267-1 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8260B SW846 5035 Percent Solids: n/a a

Project: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2H0058887.D 1 10/13/19 17:20 PJ 10/04/19 17:00 n/a V2H2348Run #2

Initial WeightRun #1 5.3 gRun #2

VOA RECAP List

CAS No. Compound Result RL Units Q

67-64-1 Acetone 0.364 0.047 mg/kg71-43-2 Benzene ND 0.00047 mg/kg75-27-4 Bromodichloromethane ND 0.00094 mg/kg75-25-2 Bromoform ND 0.00094 mg/kg75-15-0 Carbon Disulfide ND 0.00094 mg/kg56-23-5 Carbon Tetrachloride ND 0.00094 mg/kg108-90-7 Chlorobenzene ND 0.00094 mg/kg75-00-3 Chloroethane ND 0.00094 mg/kg67-66-3 Chloroform ND 0.00094 mg/kg124-48-1 Dibromochloromethane ND 0.00094 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0047 mg/kg541-73-1 m-Dichlorobenzene ND 0.00094 mg/kg95-50-1 o-Dichlorobenzene ND 0.00094 mg/kg106-46-7 p-Dichlorobenzene ND 0.00094 mg/kg75-34-3 1,1-Dichloroethane ND 0.00094 mg/kg107-06-2 1,2-Dichloroethane ND 0.00094 mg/kg75-35-4 1,1-Dichloroethylene ND 0.00094 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.00094 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.00094 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0019 mg/kg78-87-5 1,2-Dichloropropane ND 0.00094 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.00094 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.00094 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.00094 mg/kg100-41-4 Ethylbenzene ND 0.00094 mg/kg67-72-1 Hexachloroethane ND 0.0047 mg/kg78-83-1 Isobutyl alcohol ND 0.094 mg/kg74-83-9 Methyl Bromide ND 0.0094 mg/kg74-87-3 Methyl Chloride ND 0.0047 mg/kg75-09-2 Methylene Chloride ND 0.0047 mg/kg78-93-3 Methyl Ethyl Ketone 0.0186 0.012 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.012 mg/kg

ND = Not detected J = Indicates an estimated valueRL = Reporting Limit B = Indicates analyte found in associated method blankE = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

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1634-04-4 Methyl Tert Butyl Ether ND 0.00094 mg/kg100-42-5 Styrene ND 0.00094 mg/kg630-20-6 1,1,1,2-Tetrachloroethane ND 0.00094 mg/kg79-34-5 1,1,2,2-Tetrachloroethane ND 0.00094 mg/kg127-18-4 Tetrachloroethylene ND 0.00094 mg/kg108-88-3 Toluene ND 0.0047 mg/kg71-55-6 1,1,1-Trichloroethane ND 0.00094 mg/kg79-00-5 1,1,2-Trichloroethane ND 0.00094 mg/kg79-01-6 Trichloroethylene ND 0.00094 mg/kg75-69-4 Trichlorofluoromethane ND 0.00094 mg/kg75-01-4 Vinyl Chloride ND 0.00094 mg/kg

m,p-Xylene ND 0.0019 mg/kg95-47-6 o-Xylene ND 0.00094 mg/kg1330-20-7 Xylene (total) ND 0.0019 mg/kg

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

17060-07-0 1,2-Dichloroethane-D4 114% 59-143%2037-26-5 Toluene-D8 101% 52-159%460-00-4 4-Bromofluorobenzene 105% 38-183%

(a) All results with the exception of 29B parameters are reported on a wet weight basis.


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Client Sample ID: C-2SS (0-2' ) Lab Sample ID: LA58267-1 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8270D SW846 3546 Percent Solids: n/a a


File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 C0051406.D 1 10/15/19 21:20 AA 10/11/19 11:45 OP15346 EC2049Run #2

Initial Weight Final VolumeRun #1 20.1 g 1.0 mlRun #2

ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.17 mg/kg120-83-2 2,4-Dichlorophenol ND 0.17 mg/kg105-67-9 2,4-Dimethylphenol ND 0.17 mg/kg51-28-5 2,4-Dinitrophenol b ND 0.66 mg/kg100-02-7 4-Nitrophenol c ND 0.66 mg/kg87-86-5 Pentachlorophenol ND 0.17 mg/kg108-95-2 Phenol ND 0.17 mg/kg58-90-2 2,3,4,6-Tetrachlorophenol ND 0.17 mg/kg95-95-4 2,4,5-Trichlorophenol ND 0.17 mg/kg88-06-2 2,4,6-Trichlorophenol ND 0.17 mg/kg83-32-9 Acenaphthene ND 0.010 mg/kg208-96-8 Acenaphthylene ND 0.010 mg/kg62-53-3 Aniline ND 0.050 mg/kg120-12-7 Anthracene ND 0.010 mg/kg56-55-3 Benzo(a)anthracene ND 0.010 mg/kg50-32-8 Benzo(a)pyrene ND 0.010 mg/kg205-99-2 Benzo(b)fluoranthene ND 0.010 mg/kg92-52-4 1,1' -Biphenyl ND 0.17 mg/kg207-08-9 Benzo(k)fluoranthene ND 0.010 mg/kg85-68-7 Butyl Benzyl Phthalate c ND 0.17 mg/kg106-47-8 4-Chloroaniline c ND 0.17 mg/kg111-44-4 bis(2-Chloroethyl)ether ND 0.17 mg/kg108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.17 mg/kg91-58-7 2-Chloronaphthalene ND 0.17 mg/kg218-01-9 Chrysene ND 0.010 mg/kg53-70-3 Dibenzo(a,h)anthracene ND 0.010 mg/kg132-64-9 Dibenzofuran ND 0.17 mg/kg91-94-1 3,3' -Dichlorobenzidine ND 0.17 mg/kg84-66-2 Diethyl Phthalate c ND 0.17 mg/kg131-11-3 Dimethyl Phthalate ND 0.17 mg/kg117-84-0 Di-n-octyl Phthalate c ND 0.17 mg/kg99-65-0 1,3-Dinitrobenzene ND 0.17 mg/kg


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ABN RECAP LIST


121-14-2 2,4-Dinitrotoluene ND 0.17 mg/kg606-20-2 2,6-Dinitrotoluene ND 0.17 mg/kg117-81-7 bis(2-Ethylhexyl)phthalate c ND 0.17 mg/kg206-44-0 Fluoranthene ND 0.010 mg/kg86-73-7 Fluorene ND 0.010 mg/kg118-74-1 Hexachlorobenzene ND 0.17 mg/kg87-68-3 Hexachlorobutadiene ND 0.17 mg/kg77-47-4 Hexachlorocyclopentadiene ND 0.66 mg/kg193-39-5 Indeno(1,2,3-cd)pyrene ND 0.010 mg/kg78-59-1 Isophorone ND 0.17 mg/kg91-57-6 2-Methylnaphthalene ND 0.010 mg/kg91-20-3 Naphthalene ND 0.010 mg/kg88-74-4 2-Nitroaniline c ND 0.66 mg/kg99-09-2 3-Nitroaniline ND 0.66 mg/kg100-01-6 4-Nitroaniline ND 0.66 mg/kg98-95-3 Nitrobenzene ND 0.17 mg/kg621-64-7 N-Nitroso-di-n-propylamine c ND 0.17 mg/kg86-30-6 N-Nitrosodiphenylamine ND 0.17 mg/kg85-01-8 Phenanthrene ND 0.010 mg/kg129-00-0 Pyrene ND 0.010 mg/kg95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.17 mg/kg120-82-1 1,2,4-Trichlorobenzene ND 0.17 mg/kg


367-12-4 2-Fluorophenol 61% 25-109%4165-62-2 Phenol-d5 65% 30-110%118-79-6 2,4,6-Tribromophenol 84% 27-127%4165-60-0 Nitrobenzene-d5 68% 24-123%321-60-8 2-Fluorobiphenyl 68% 32-112%1718-51-0 Terphenyl-d14 90% 41-115%

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Associated CCV outside of control limits high, sample was ND.(c) Associated CCV outside control limits low. A sensitivity check was analyzed at the project reporting limit

and met 8270D criteria. Sample ND.


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Client Sample ID: C-2SS (0-2' ) Lab Sample ID: LA58267-1 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8015C SW846 5035 Percent Solids: n/a a


File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LA346514.D 1 10/08/19 23:10 NN 10/04/19 17:00 n/a GLA2714Run #2

Initial Weight Final Volume Methanol AliquotRun #1 5.00 g 5.0 ml 100 ulRun #2


TPH-GRO (C6-C10) ND 5.0 mg/kg


460-00-4 4-Bromofluorobenzene 94% 63-139%540-36-3 1,4-Difluorobenzene 89% 52-140%



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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LG001454.D 1 10/14/19 17:15 PC 10/11/19 11:45 OP15347 GLG887Run #2



TPH-DRO (C10-C28) ND 4.9 mg/kgTPH-ORO (C28-C35) ND 4.9 mg/kg


84-15-1 o-Terphenyl 58% 31-127%



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Client Sample ID: C-2SS (0-2' ) Lab Sample ID: LA58267-1 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19

Percent Solids: n/a a


Metals Analysis

Analyte Result RL Units DF Prep Analyzed By Method Prep Method

Antimony ND 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Arsenic 6.5 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Barium 112 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Beryllium ND 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Cadmium ND 0.25 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Chromium 13.2 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Cobalt 8.8 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Copper 9.6 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Lead 12.6 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Mercury b ND 0.071 mg/kg 1 10/07/19 10/07/19 SA SW846 7471B 1 SW846 7471B 5

Nickel 9.7 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Selenium 3.8 2.5 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 3 SW846 3050B 4

Silver ND 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Thallium ND 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Vanadium 26.1 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

Zinc 36.6 2.5 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4

(1) Instrument QC Batch: MA17153(2) Instrument QC Batch: MA17173(3) Instrument QC Batch: MA17192(4) Prep QC Batch: MP16530(5) Prep QC Batch: MP16534

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Sample received outside the holding time.

RL = Reporting Limit ND = Not detected

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VOA RECAP List


67-64-1 Acetone ND 0.050 mg/kg71-43-2 Benzene ND 0.00050 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0050 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0050 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0050 mg/kg75-09-2 Methylene Chloride ND 0.0050 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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VOA RECAP List








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ABN RECAP LIST




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ABN RECAP LIST








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84-15-1 o-Terphenyl 58% 31-127%



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Metals Analysis




Barium 54.7 0.46 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 3









Selenium ND 2.3 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 3





(1) Instrument QC Batch: MA17153(2) Instrument QC Batch: MA17173(3) Prep QC Batch: MP16530(4) Prep QC Batch: MP16534



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VOA RECAP List




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ABN RECAP LIST




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ABN RECAP LIST








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84-15-1 o-Terphenyl 57% 31-127%



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Metals Analysis





















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Client Sample ID: B-4SS (0-2' ) Lab Sample ID: LA58267-4 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8260B SW846 5035 Percent Solids: n/a a


File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2H0058890.D 1 10/13/19 18:35 PJ 10/04/19 17:00 n/a V2H2348Run #2 b 2H0058852.D 1 10/12/19 22:22 PJ 10/04/19 17:00 n/a V2H2347

Initial WeightRun #1 5.0 gRun #2 5.0 g

VOA RECAP List


67-64-1 Acetone 0.227 0.050 mg/kg71-43-2 Benzene ND 0.00050 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0050 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0050 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0050 mg/kg75-09-2 Methylene Chloride ND 0.0050 mg/kg78-93-3 Methyl Ethyl Ketone 0.0131 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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VOA RECAP List





17060-07-0 1,2-Dichloroethane-D4 118% 119% 59-143%2037-26-5 Toluene-D8 106% 102% 52-159%460-00-4 4-Bromofluorobenzene 109% 106% 38-183%

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Sample used for QC purposes only.


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Client Sample ID: B-4SS (0-2' ) Lab Sample ID: LA58267-4 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8270D SW846 3546 Percent Solids: n/a a




ABN RECAP LIST




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ABN RECAP LIST








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Client Sample ID: B-4SS (0-2' ) Lab Sample ID: LA58267-4 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8015C SW846 5035 Percent Solids: n/a a










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84-15-1 o-Terphenyl 66% 31-127%



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Client Sample ID: B-4SS (0-2' ) Lab Sample ID: LA58267-4 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19



Metals Analysis





Beryllium 0.62 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4
















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VOA RECAP List


67-64-1 Acetone 0.0967 0.050 mg/kg71-43-2 Benzene ND 0.00050 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0050 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0050 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0050 mg/kg75-09-2 Methylene Chloride ND 0.0050 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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ABN RECAP LIST




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84-15-1 o-Terphenyl 57% 31-127%



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Metals Analysis





















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VOA RECAP List








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ABN RECAP LIST




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ABN RECAP LIST








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84-15-1 o-Terphenyl 56% 31-127%



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Metals Analysis






Cadmium 0.63 0.24 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 4















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VOA RECAP List


67-64-1 Acetone ND 0.051 mg/kg71-43-2 Benzene 0.0770 0.00051 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide 0.0044 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0051 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane 0.0021 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene 0.0071 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0051 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0051 mg/kg75-09-2 Methylene Chloride ND 0.0051 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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VOA RECAP List



m,p-Xylene 0.0362 0.0020 mg/kg95-47-6 o-Xylene 0.0022 0.0010 mg/kg1330-20-7 Xylene (total) 0.0384 0.0020 mg/kg





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ABN RECAP LIST




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ABN RECAP LIST








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84-15-1 o-Terphenyl 56% 31-127%



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Metals Analysis












Nickel < 0.50 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 3









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VOA RECAP List


67-64-1 Acetone ND 0.052 mg/kg71-43-2 Benzene 0.0071 0.00052 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0052 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane 0.0088 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0021 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene 0.0047 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0052 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0052 mg/kg75-09-2 Methylene Chloride ND 0.0052 mg/kg78-93-3 Methyl Ethyl Ketone 0.0232 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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m,p-Xylene 0.0094 0.0021 mg/kg95-47-6 o-Xylene ND 0.0010 mg/kg1330-20-7 Xylene (total) 0.0103 0.0021 mg/kg





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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 F0059505.D 1 10/17/19 21:09 SV 10/11/19 11:45 OP15346 EF2032Run #2


ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.17 mg/kg120-83-2 2,4-Dichlorophenol ND 0.17 mg/kg105-67-9 2,4-Dimethylphenol ND 0.17 mg/kg51-28-5 2,4-Dinitrophenol ND 0.65 mg/kg100-02-7 4-Nitrophenol ND 0.65 mg/kg87-86-5 Pentachlorophenol ND 0.17 mg/kg108-95-2 Phenol ND 0.17 mg/kg58-90-2 2,3,4,6-Tetrachlorophenol ND 0.17 mg/kg95-95-4 2,4,5-Trichlorophenol ND 0.17 mg/kg88-06-2 2,4,6-Trichlorophenol ND 0.17 mg/kg83-32-9 Acenaphthene ND 0.0098 mg/kg208-96-8 Acenaphthylene ND 0.0098 mg/kg62-53-3 Aniline ND 0.049 mg/kg120-12-7 Anthracene ND 0.0098 mg/kg56-55-3 Benzo(a)anthracene ND 0.0098 mg/kg50-32-8 Benzo(a)pyrene ND 0.0098 mg/kg205-99-2 Benzo(b)fluoranthene ND 0.0098 mg/kg92-52-4 1,1' -Biphenyl ND 0.17 mg/kg207-08-9 Benzo(k)fluoranthene ND 0.0098 mg/kg85-68-7 Butyl Benzyl Phthalate ND 0.17 mg/kg106-47-8 4-Chloroaniline ND 0.17 mg/kg111-44-4 bis(2-Chloroethyl)ether ND 0.17 mg/kg108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.17 mg/kg91-58-7 2-Chloronaphthalene ND 0.17 mg/kg218-01-9 Chrysene ND 0.0098 mg/kg53-70-3 Dibenzo(a,h)anthracene ND 0.0098 mg/kg132-64-9 Dibenzofuran ND 0.17 mg/kg91-94-1 3,3' -Dichlorobenzidine ND 0.17 mg/kg84-66-2 Diethyl Phthalate ND 0.17 mg/kg131-11-3 Dimethyl Phthalate ND 0.17 mg/kg117-84-0 Di-n-octyl Phthalate ND 0.17 mg/kg99-65-0 1,3-Dinitrobenzene ND 0.17 mg/kg


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121-14-2 2,4-Dinitrotoluene ND 0.17 mg/kg606-20-2 2,6-Dinitrotoluene ND 0.17 mg/kg117-81-7 bis(2-Ethylhexyl)phthalate ND 0.17 mg/kg206-44-0 Fluoranthene ND 0.0098 mg/kg86-73-7 Fluorene ND 0.0098 mg/kg118-74-1 Hexachlorobenzene ND 0.17 mg/kg87-68-3 Hexachlorobutadiene ND 0.17 mg/kg77-47-4 Hexachlorocyclopentadiene b ND 0.65 mg/kg193-39-5 Indeno(1,2,3-cd)pyrene ND 0.0098 mg/kg78-59-1 Isophorone ND 0.17 mg/kg91-57-6 2-Methylnaphthalene ND 0.0098 mg/kg91-20-3 Naphthalene ND 0.0098 mg/kg88-74-4 2-Nitroaniline ND 0.65 mg/kg99-09-2 3-Nitroaniline ND 0.65 mg/kg100-01-6 4-Nitroaniline ND 0.65 mg/kg98-95-3 Nitrobenzene ND 0.17 mg/kg621-64-7 N-Nitroso-di-n-propylamine ND 0.17 mg/kg86-30-6 N-Nitrosodiphenylamine ND 0.17 mg/kg85-01-8 Phenanthrene ND 0.0098 mg/kg129-00-0 Pyrene ND 0.0098 mg/kg95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.17 mg/kg120-82-1 1,2,4-Trichlorobenzene ND 0.17 mg/kg



(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Associated CCV outside of control limits high, sample was ND.


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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2H0058896.D 1 10/13/19 21:04 PJ 10/04/19 17:00 n/a V2H2348Run #2 1G111816.D 1 10/14/19 14:08 CP 10/04/19 17:00 n/a V1G5837

Initial Weight Final Volume Methanol AliquotRun #1 5.0 gRun #2 5.0 g 5.0 ml 100 ul

VOA RECAP List


67-64-1 Acetone ND 0.050 mg/kg71-43-2 Benzene 2.25 b 0.025 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0050 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene 4.53 b 0.050 mg/kg67-72-1 Hexachloroethane ND 0.0050 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0050 mg/kg75-09-2 Methylene Chloride ND 0.0050 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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1634-04-4 Methyl Tert Butyl Ether ND 0.0010 mg/kg100-42-5 Styrene ND 0.0010 mg/kg630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/kg79-34-5 1,1,2,2-Tetrachloroethane ND 0.0010 mg/kg127-18-4 Tetrachloroethylene ND 0.0010 mg/kg108-88-3 Toluene 0.0991 0.0050 mg/kg71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/kg79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/kg79-01-6 Trichloroethylene ND 0.0010 mg/kg75-69-4 Trichlorofluoromethane ND 0.0010 mg/kg75-01-4 Vinyl Chloride ND 0.0010 mg/kg

m,p-Xylene 14.1 b 0.10 mg/kg95-47-6 o-Xylene 0.344 b 0.050 mg/kg1330-20-7 Xylene (total) 14.4 b 0.10 mg/kg


17060-07-0 1,2-Dichloroethane-D4 493% c 102% 59-143%2037-26-5 Toluene-D8 106% 98% 52-159%460-00-4 4-Bromofluorobenzene 116% 101% 38-183%

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Result is from Run# 2(c) Outside control limits due to matrix interference. Confirmed by reanalysis at a dilution.


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121-14-2 2,4-Dinitrotoluene ND 0.17 mg/kg606-20-2 2,6-Dinitrotoluene ND 0.17 mg/kg117-81-7 bis(2-Ethylhexyl)phthalate ND 0.17 mg/kg206-44-0 Fluoranthene ND 0.010 mg/kg86-73-7 Fluorene ND 0.010 mg/kg118-74-1 Hexachlorobenzene ND 0.17 mg/kg87-68-3 Hexachlorobutadiene ND 0.17 mg/kg77-47-4 Hexachlorocyclopentadiene b ND 0.66 mg/kg193-39-5 Indeno(1,2,3-cd)pyrene ND 0.010 mg/kg78-59-1 Isophorone ND 0.17 mg/kg91-57-6 2-Methylnaphthalene ND 0.010 mg/kg91-20-3 Naphthalene 0.0174 0.010 mg/kg88-74-4 2-Nitroaniline ND 0.66 mg/kg99-09-2 3-Nitroaniline ND 0.66 mg/kg100-01-6 4-Nitroaniline ND 0.66 mg/kg98-95-3 Nitrobenzene ND 0.17 mg/kg621-64-7 N-Nitroso-di-n-propylamine ND 0.17 mg/kg86-30-6 N-Nitrosodiphenylamine ND 0.17 mg/kg85-01-8 Phenanthrene ND 0.010 mg/kg129-00-0 Pyrene ND 0.010 mg/kg95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.17 mg/kg120-82-1 1,2,4-Trichlorobenzene ND 0.17 mg/kg





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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LA347385.D 1 10/17/19 11:45 NN 10/04/19 17:00 n/a GLA2730Run #2 b LA347231.D 1 10/16/19 06:22 NN 10/04/19 17:00 n/a GLA2727Run #3 b LA347289.D 1 10/16/19 17:25 NN 10/04/19 17:00 n/a GLA2729

Initial Weight Final Volume Methanol AliquotRun #1 5.00 g 5.0 ml 25.0 ulRun #2 5.00 g 5.0 ml 25.0 ulRun #3 5.00 g 5.0 ml 100 ul


TPH-GRO (C6-C10) 847 20 mg/kg

CAS No. Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits

460-00-4 4-Bromofluorobenzene 97% 93% 81% 63-139%540-36-3 1,4-Difluorobenzene 120% 89% 220% c 52-140%

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Sample used for QC purposes only.(c) Confirmed by MS/MSD.


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67-64-1 Acetone ND 0.052 mg/kg71-43-2 Benzene 0.0021 0.00052 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0052 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0021 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene 0.0021 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0052 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0052 mg/kg75-09-2 Methylene Chloride ND 0.0052 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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67-64-1 Acetone ND 0.051 mg/kg71-43-2 Benzene 0.00086 0.00051 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide 0.0018 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0051 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0051 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0051 mg/kg75-09-2 Methylene Chloride ND 0.0051 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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67-64-1 Acetone ND 0.052 mg/kg71-43-2 Benzene 0.0051 0.00052 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0052 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane 0.0059 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0021 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0052 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0052 mg/kg75-09-2 Methylene Chloride ND 0.0052 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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67-64-1 Acetone ND 0.050 mg/kg71-43-2 Benzene 0.0014 0.00050 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0050 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene 0.0029 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0050 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0050 mg/kg75-09-2 Methylene Chloride ND 0.0050 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2H0058933.D 1 10/14/19 12:22 CP 10/04/19 17:00 n/a V2H2350Run #2


VOA RECAP List


67-64-1 Acetone ND 0.051 mg/kg71-43-2 Benzene ND 0.00051 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide 0.0026 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0051 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0051 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0051 mg/kg75-09-2 Methylene Chloride ND 0.0051 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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Client Sample ID: B-1SS (0-2' ) Lab Sample ID: LA58267-15A Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19

Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

Metals Analysis, SPLP Leachate SW846 1312

Analyte Result MCL RL Units DF Prep Analyzed By Method Prep Method

Arsenic 0.0085 0.0010 mg/l 1 10/22/19 10/23/19 RT SW846 6020A 1 SW846 3010A 2

(1) Instrument QC Batch: MA17314(2) Prep QC Batch: MP16691

RL = Reporting Limit ND = Not detectedMCL = Maximum Contamination Level (not available)

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VOA RECAP List




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VOA RECAP List








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ABN RECAP LIST




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ABN RECAP LIST







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TPH-GRO (C6-C10) 29.9 5.0 mg/kg





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TPH-DRO (C10-C28) 16.9 5.0 mg/kgTPH-ORO (C28-C35) ND 5.0 mg/kg


84-15-1 o-Terphenyl 59% 31-127%



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Metals Analysis





















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VOA RECAP List




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VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether 0.0014 0.0010 mg/kg100-42-5 Styrene ND 0.0010 mg/kg630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/kg79-34-5 1,1,2,2-Tetrachloroethane ND 0.0010 mg/kg127-18-4 Tetrachloroethylene ND 0.0010 mg/kg108-88-3 Toluene ND 0.0050 mg/kg71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/kg79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/kg79-01-6 Trichloroethylene ND 0.0010 mg/kg75-69-4 Trichlorofluoromethane ND 0.0010 mg/kg75-01-4 Vinyl Chloride ND 0.0010 mg/kg






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ABN RECAP LIST




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ABN RECAP LIST







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84-15-1 o-Terphenyl 61% 31-127%



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Metals Analysis





















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VOA RECAP List


67-64-1 Acetone ND 0.050 mg/kg71-43-2 Benzene ND 0.00050 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0050 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0050 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0050 mg/kg75-09-2 Methylene Chloride ND 0.0050 mg/kg78-93-3 Methyl Ethyl Ketone 0.0137 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether 0.0026 0.0010 mg/kg100-42-5 Styrene ND 0.0010 mg/kg630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/kg79-34-5 1,1,2,2-Tetrachloroethane ND 0.0010 mg/kg127-18-4 Tetrachloroethylene ND 0.0010 mg/kg108-88-3 Toluene ND 0.0050 mg/kg71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/kg79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/kg79-01-6 Trichloroethylene ND 0.0010 mg/kg75-69-4 Trichlorofluoromethane ND 0.0010 mg/kg75-01-4 Vinyl Chloride ND 0.0010 mg/kg






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ABN RECAP LIST







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84-15-1 o-Terphenyl 50% 31-127%



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Metals Analysis





















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Client Sample ID: BD-02Lab Sample ID: LA58267-19 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8260B SW846 5035 Percent Solids: n/a a




VOA RECAP List


67-64-1 Acetone ND 0.051 mg/kg71-43-2 Benzene 0.00067 0.00051 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0051 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0051 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0051 mg/kg75-09-2 Methylene Chloride ND 0.0051 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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VOA RECAP List








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Client Sample ID: BD-02Lab Sample ID: LA58267-19 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8270D SW846 3546 Percent Solids: n/a a




ABN RECAP LIST




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ABN RECAP LIST







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Client Sample ID: BD-02Lab Sample ID: LA58267-19 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19Method: SW846 8015C SW846 5035 Percent Solids: n/a a










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84-15-1 o-Terphenyl 59% 31-127%



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Client Sample ID: BD-02Lab Sample ID: LA58267-19 Date Sampled: 10/04/19Matrix: SO - Soil Date Received: 10/04/19



Metals Analysis









Copper 10 0.50 mg/kg 5 10/07/19 10/10/19 RT SW846 6020A 2 SW846 3050B 3












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General Chemistry

Analyte Result RL Units DF Analyzed By Method

Nitrogen, Ammonia b 8.6 1.2 mg/kg 1 10/10/19 ATX EPA 350.1 MNitrogen, Nitrate b 5.7 4.9 mg/kg 1 10/11/19 10:49 ATX SW846 9056ANitrogen, Nitrite b ND 4.9 mg/kg 1 10/11/19 10:49 ATX SW846 9056A

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Analysis performed at SGS Houston, TX.


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Client Sample ID: FB-04Lab Sample ID: LA58267-20 Date Sampled: 10/04/19Matrix: AQ - Field Blank Water Date Received: 10/04/19Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 1X0084822.D 1 10/08/19 01:58 CP n/a n/a V1X3810Run #2

Purge VolumeRun #1 5.0 mlRun #2

VOA RECAP List


67-64-1 Acetone ND 0.050 mg/l71-43-2 Benzene ND 0.0010 mg/l75-27-4 Bromodichloromethane ND 0.0010 mg/l75-25-2 Bromoform ND 0.0010 mg/l75-15-0 Carbon Disulfide ND 0.0010 mg/l56-23-5 Carbon Tetrachloride ND 0.0010 mg/l108-90-7 Chlorobenzene ND 0.0010 mg/l75-00-3 Chloroethane ND 0.0010 mg/l67-66-3 Chloroform ND 0.0010 mg/l124-48-1 Dibromochloromethane ND 0.0010 mg/l96-12-8 1,2-Dibromo-3-chloropropane ND 0.0010 mg/l541-73-1 m-Dichlorobenzene ND 0.0010 mg/l95-50-1 o-Dichlorobenzene ND 0.0010 mg/l106-46-7 p-Dichlorobenzene ND 0.0010 mg/l75-34-3 1,1-Dichloroethane ND 0.0010 mg/l107-06-2 1,2-Dichloroethane ND 0.0010 mg/l75-35-4 1,1-Dichloroethylene ND 0.0010 mg/l156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/l156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/l540-59-0 1,2-Dichloroethene (total) ND 0.0010 mg/l78-87-5 1,2-Dichloropropane ND 0.0010 mg/l10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/l10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/l542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/l100-41-4 Ethylbenzene ND 0.0010 mg/l67-72-1 Hexachloroethane ND 0.0010 mg/l78-83-1 Isobutyl Alcohol ND 0.10 mg/l74-83-9 Methyl Bromide ND 0.0010 mg/l74-87-3 Methyl Chloride ND 0.0010 mg/l75-09-2 Methylene Chloride ND 0.0010 mg/l78-93-3 Methyl Ethyl Ketone ND 0.013 mg/l108-10-1 4-Methyl-2-pentanone ND 0.013 mg/l


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VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether ND 0.0010 mg/l100-42-5 Styrene ND 0.0010 mg/l630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.00050 mg/l127-18-4 Tetrachloroethylene ND 0.0010 mg/l108-88-3 Toluene ND 0.0010 mg/l71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/l79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/l79-01-6 Trichloroethylene ND 0.0010 mg/l75-69-4 Trichlorofluoromethane ND 0.0010 mg/l75-01-4 Vinyl Chloride ND 0.0010 mg/l

m,p-Xylene ND 0.0020 mg/l95-47-6 o-Xylene ND 0.0010 mg/l1330-20-7 Xylene (total) ND 0.0020 mg/l




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Client Sample ID: FB-04Lab Sample ID: LA58267-20 Date Sampled: 10/04/19Matrix: AQ - Field Blank Water Date Received: 10/04/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 L0029648.D 1 10/11/19 16:35 AA 10/07/19 18:00 OP15315 EL785Run #2 a L0029770.D 1 10/24/19 03:53 PC 10/15/19 17:51 OP15452 EL789

Initial Volume Final VolumeRun #1 100 ml 1.0 mlRun #2 113 ml 1.0 ml

ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0050 mg/l120-83-2 2,4-Dichlorophenol ND 0.0050 mg/l105-67-9 2,4-Dimethylphenol ND 0.0050 mg/l51-28-5 2,4-Dinitrophenol ND 0.020 mg/l100-02-7 4-Nitrophenol ND 0.025 mg/l87-86-5 Pentachlorophenol ND 0.0010 mg/l108-95-2 Phenol ND 0.0050 mg/l58-90-2 2,3,4,6-Tetrachlorophenol ND 0.0050 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0050 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0050 mg/l83-32-9 Acenaphthene ND 0.00020 mg/l208-96-8 Acenaphthylene ND 0.00020 mg/l62-53-3 Aniline ND 0.0050 mg/l120-12-7 Anthracene ND 0.00020 mg/l56-55-3 Benzo(a)anthracene ND 0.00020 mg/l50-32-8 Benzo(a)pyrene ND 0.00020 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00020 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00020 mg/l92-52-4 1,1' -Biphenyl ND 0.010 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0050 mg/l106-47-8 4-Chloroaniline ND 0.0050 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0050 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0050 mg/l91-58-7 2-Chloronaphthalene ND 0.0050 mg/l218-01-9 Chrysene ND 0.00020 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00020 mg/l132-64-9 Dibenzofuran ND 0.0050 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.010 mg/l84-66-2 Diethyl Phthalate 0.0053 0.0050 mg/l131-11-3 Dimethyl Phthalate ND 0.0050 mg/l117-84-0 Di-n-octyl Phthalate ND 0.0050 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0050 mg/l


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ABN RECAP LIST


121-14-2 2,4-Dinitrotoluene ND 0.0050 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0050 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0050 mg/l206-44-0 Fluoranthene ND 0.00020 mg/l86-73-7 Fluorene ND 0.00020 mg/l118-74-1 Hexachlorobenzene ND 0.0010 mg/l87-68-3 Hexachlorobutadiene ND 0.00050 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.010 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00020 mg/l78-59-1 Isophorone ND 0.0050 mg/l91-57-6 2-Methylnaphthalene ND 0.00020 mg/l91-20-3 Naphthalene ND 0.00020 mg/l88-74-4 2-Nitroaniline ND 0.0050 mg/l99-09-2 3-Nitroaniline ND 0.0050 mg/l100-01-6 4-Nitroaniline b ND 0.0050 mg/l98-95-3 Nitrobenzene ND 0.0010 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0050 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0050 mg/l85-01-8 Phenanthrene ND 0.00020 mg/l129-00-0 Pyrene ND 0.00020 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.0010 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0050 mg/l


367-12-4 2-Fluorophenol 64% 58% 25-101%4165-62-2 Phenol-d5 52% 52% 17-79%118-79-6 2,4,6-Tribromophenol 94% 92% 40-144%4165-60-0 Nitrobenzene-d5 94% 108% 40-124%321-60-8 2-Fluorobiphenyl 83% 96% 27-124%1718-51-0 Terphenyl-d14 91% 105% 45-140%

(a) Confirmation run.(b) Associated CCV outside of control limits high, sample was ND.


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Client Sample ID: FB-04Lab Sample ID: LA58267-20 Date Sampled: 10/04/19Matrix: AQ - Field Blank Water Date Received: 10/04/19Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LA346388.D 1 10/07/19 23:06 NN n/a n/a GLA2711Run #2



TPH-GRO (C6-C10) ND 0.10 mg/l




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Client Sample ID: FB-04Lab Sample ID: LA58267-20 Date Sampled: 10/04/19Matrix: AQ - Field Blank Water Date Received: 10/04/19Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 GLH026567.D 1 10/17/19 23:45 PC 10/15/19 08:00 OP15370 GLH568Run #2

Initial Volume Final VolumeRun #1 54.2 ml 3.0 mlRun #2


TPH-DRO (C10-C28) a 0.175 0.14 mg/lTPH-ORO (C28-C35) b ND 0.14 mg/l


84-15-1 o-Terphenyl 105% 40-118%

(a) Confirmed by reextraction and reanalysis.(b) Associated CCV outside control limits high, sample was ND.


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Client Sample ID: FB-04Lab Sample ID: LA58267-20 Date Sampled: 10/04/19Matrix: AQ - Field Blank Water Date Received: 10/04/19


Total Metals Analysis


Antimony ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Arsenic ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Barium ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Beryllium ND 0.0010 mg/l 1 10/08/19 10/09/19 RT SW846 6020A 3 SW846 3010A 5

Cadmium ND 0.00050 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Chromium ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Cobalt ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Copper ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Lead ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Mercury a ND 0.00020 mg/l 1 10/07/19 10/07/19 SA SW846 7470A 1 SW846 7470A 4

Nickel -0.0053 0.0010 mg/l 1 10/08/19 10/09/19 RT SW846 6020A 3 SW846 3010A 5

Selenium ND 0.0050 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Silver ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Thallium ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Vanadium ND 0.0010 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5

Zinc ND 0.0050 mg/l 1 10/08/19 10/08/19 RT SW846 6020A 2 SW846 3010A 5


(a) Sample received outside the holding time.


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General Chemistry


Nitrogen, Ammonia a ND 0.10 mg/l 1 10/10/19 ATX EPA 350.1Nitrogen, Nitrate ND 0.050 mg/l 1 10/04/19 16:54 HD SW846 9056ANitrogen, Nitrite ND 0.050 mg/l 1 10/04/19 16:54 HD SW846 9056A

(a) Analysis performed at SGS Houston, TX.


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Client Sample ID: TRIP BLANK Lab Sample ID: LA58267-21 Date Sampled: 10/04/19Matrix: AQ - Trip Blank Water Date Received: 10/04/19Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



VOA RECAP List




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Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable:

• Chain of Custody

Scott, LASection 4

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LA58267: Chain of CustodyPage 1 of 4

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SGS Sample Receipt Summary

Job Number: LA58267 Client: PROVIDENCE

Date / Time Received: 10/4/2019 4:05:00 PM Delivery Method: Client

Project: BOTTLE ART LOFTS

4. No. Coolers: 4

Airbill #'s:

Cooler Security1. Custody Seals Present:

Y or N

2. Custody Seals Intact:

3. COC Present:

4. Smpl Dates/Time OK

2. Thermometer ID:

Cooler Temperature Y or N 1. Temp criteria achieved:

3. Cooler media:

DV439;

Ice (direct contact)

Quality Control Preservation Y or N N/A1. Trip Blank present / cooler:

2. Trip Blank listed on COC:

3. Samples preserved properly:

4. VOCs headspace free:

Sample Integrity - Documentation Y or N

1. Sample labels present on bottles:

2. Container labeling complete:

3. Sample container label / COC agree:

Sample Integrity - Condition Y or N

1. Sample recvd within HT:

3. Condition of sample:

2. All containers accounted for:

Sample Integrity - Instructions1. Analysis requested is clear:

2. Bottles received for unspecified tests

3. Sufficient volume recvd for analysis:

4. Compositing instructions clear:

5. Filtering instructions clear:

Intact

Y or N

Comments

Y or N N/A

Cooler Temps (Initial/Adjusted): #1: (1.8/1.8); #2: (2.1/2.1); #3: (1.6/1.6); #4: (2.4/2.4); DV439


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TAT

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MS Volatiles

QC Data Summaries


• Method Blank Summaries• Blank Spike Summaries• Matrix Spike and Duplicate Summaries

Scott, LASection 5

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5

Method Blank Summary Page 1 of 2Job Number: LA58267Account: PROVLABR Providence Engineering & EnvironmentalProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV2H2348-MB1 2H0058882.D 1 10/13/19 PJ n/a n/a V2H2348

The QC reported here applies to the following samples: Method: SW846 8260D

LA58267-1, LA58267-2, LA58267-3, LA58267-4, LA58267-5, LA58267-6, LA58267-7, LA58267-8, LA58267-9,LA58267-10, LA58267-17, LA58267-18, LA58267-19


67-64-1 Acetone ND 50 ug/kg71-43-2 Benzene ND 0.50 ug/kg75-27-4 Bromodichloromethane ND 1.0 ug/kg75-25-2 Bromoform ND 1.0 ug/kg75-15-0 Carbon Disulfide ND 1.0 ug/kg56-23-5 Carbon Tetrachloride ND 1.0 ug/kg108-90-7 Chlorobenzene ND 1.0 ug/kg75-00-3 Chloroethane ND 1.0 ug/kg67-66-3 Chloroform ND 1.0 ug/kg124-48-1 Dibromochloromethane ND 1.0 ug/kg96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 ug/kg541-73-1 m-Dichlorobenzene ND 1.0 ug/kg95-50-1 o-Dichlorobenzene ND 1.0 ug/kg106-46-7 p-Dichlorobenzene ND 1.0 ug/kg75-34-3 1,1-Dichloroethane ND 1.0 ug/kg107-06-2 1,2-Dichloroethane ND 1.0 ug/kg75-35-4 1,1-Dichloroethylene ND 1.0 ug/kg156-59-2 cis-1,2-Dichloroethylene ND 1.0 ug/kg156-60-5 trans-1,2-Dichloroethylene ND 1.0 ug/kg540-59-0 1,2-Dichloroethene (total) ND 2.0 ug/kg78-87-5 1,2-Dichloropropane ND 1.0 ug/kg10061-01-5 cis-1,3-Dichloropropene ND 1.0 ug/kg10061-02-6 trans-1,3-Dichloropropene ND 1.0 ug/kg542-75-6 1,3-Dichloropropene (total) ND 1.0 ug/kg100-41-4 Ethylbenzene ND 1.0 ug/kg67-72-1 Hexachloroethane ND 5.0 ug/kg78-83-1 Isobutyl alcohol ND 100 ug/kg74-83-9 Methyl Bromide ND 10 ug/kg74-87-3 Methyl Chloride ND 5.0 ug/kg75-09-2 Methylene Chloride ND 5.0 ug/kg78-93-3 Methyl Ethyl Ketone ND 13 ug/kg108-10-1 4-Methyl-2-pentanone ND 13 ug/kg1634-04-4 Methyl Tert Butyl Ether ND 1.0 ug/kg100-42-5 Styrene ND 1.0 ug/kg630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 ug/kg79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 ug/kg

167 of 283

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55.1.1






127-18-4 Tetrachloroethylene ND 1.0 ug/kg108-88-3 Toluene ND 5.0 ug/kg71-55-6 1,1,1-Trichloroethane ND 1.0 ug/kg79-00-5 1,1,2-Trichloroethane ND 1.0 ug/kg79-01-6 Trichloroethylene ND 1.0 ug/kg75-69-4 Trichlorofluoromethane ND 1.0 ug/kg75-01-4 Vinyl Chloride ND 1.0 ug/kg

m,p-Xylene ND 2.0 ug/kg95-47-6 o-Xylene ND 1.0 ug/kg1330-20-7 Xylene (total) ND 2.0 ug/kg

CAS No. Surrogate Recoveries Limits


168 of 283

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55.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV2H2350-MB1 2H0058932.D 1 10/14/19 CP n/a n/a V2H2350


LA58267-15, LA58267-16



169 of 283

LA58267

55.1.2




LA58267-15, LA58267-16






170 of 283

LA58267

55.1.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1X3810-MB4 1X0084818.D 1 10/08/19 CP n/a n/a V1X3810

The QC reported here applies to the following samples: Method: SW846 8260B

LA58267-20, LA58267-21


67-64-1 Acetone ND 50 ug/l71-43-2 Benzene ND 1.0 ug/l75-27-4 Bromodichloromethane ND 1.0 ug/l75-25-2 Bromoform ND 1.0 ug/l75-15-0 Carbon Disulfide ND 1.0 ug/l56-23-5 Carbon Tetrachloride ND 1.0 ug/l108-90-7 Chlorobenzene ND 1.0 ug/l75-00-3 Chloroethane ND 1.0 ug/l67-66-3 Chloroform ND 1.0 ug/l124-48-1 Dibromochloromethane ND 1.0 ug/l96-12-8 1,2-Dibromo-3-chloropropane ND 1.0 ug/l541-73-1 m-Dichlorobenzene ND 1.0 ug/l95-50-1 o-Dichlorobenzene ND 1.0 ug/l106-46-7 p-Dichlorobenzene ND 1.0 ug/l75-34-3 1,1-Dichloroethane ND 1.0 ug/l107-06-2 1,2-Dichloroethane ND 1.0 ug/l75-35-4 1,1-Dichloroethylene ND 1.0 ug/l156-59-2 cis-1,2-Dichloroethylene ND 1.0 ug/l156-60-5 trans-1,2-Dichloroethylene ND 1.0 ug/l540-59-0 1,2-Dichloroethene (total) ND 1.0 ug/l78-87-5 1,2-Dichloropropane ND 1.0 ug/l10061-01-5 cis-1,3-Dichloropropene ND 1.0 ug/l10061-02-6 trans-1,3-Dichloropropene ND 1.0 ug/l542-75-6 1,3-Dichloropropene (total) ND 1.0 ug/l100-41-4 Ethylbenzene ND 1.0 ug/l67-72-1 Hexachloroethane ND 1.0 ug/l78-83-1 Isobutyl Alcohol ND 100 ug/l74-83-9 Methyl Bromide ND 1.0 ug/l74-87-3 Methyl Chloride ND 1.0 ug/l75-09-2 Methylene Chloride ND 1.0 ug/l78-93-3 Methyl Ethyl Ketone ND 13 ug/l108-10-1 4-Methyl-2-pentanone ND 13 ug/l1634-04-4 Methyl Tert Butyl Ether ND 1.0 ug/l100-42-5 Styrene ND 1.0 ug/l630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 ug/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 ug/l

171 of 283

LA58267

55.1.3




LA58267-20, LA58267-21


127-18-4 Tetrachloroethylene ND 1.0 ug/l108-88-3 Toluene ND 1.0 ug/l71-55-6 1,1,1-Trichloroethane ND 1.0 ug/l79-00-5 1,1,2-Trichloroethane ND 1.0 ug/l79-01-6 Trichloroethylene ND 1.0 ug/l75-69-4 Trichlorofluoromethane ND 1.0 ug/l75-01-4 Vinyl Chloride ND 1.0 ug/l

m,p-Xylene ND 2.0 ug/l95-47-6 o-Xylene ND 1.0 ug/l1330-20-7 Xylene (total) ND 2.0 ug/l



172 of 283

LA58267

55.1.3




LA58267-11, LA58267-12, LA58267-13, LA58267-14



173 of 283

LA58267

55.1.4




LA58267-11, LA58267-12, LA58267-13, LA58267-14






174 of 283

LA58267

55.1.4


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1G5837-MB1 1G111810.D 1 10/14/19 CP n/a n/a V1G5837


LA58267-10


71-43-2 Benzene ND 25 ug/kg100-41-4 Ethylbenzene ND 50 ug/kg

m,p-Xylene ND 100 ug/kg95-47-6 o-Xylene ND 50 ug/kg1330-20-7 Xylene (total) ND 100 ug/kg



175 of 283

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55.1.5

Blank Spike/Blank Spike Duplicate Summary Page 1 of 2Job Number: LA58267Account: PROVLABR Providence Engineering & EnvironmentalProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV2H2348-BS1 2H0058879.D 1 10/13/19 PJ n/a n/a V2H2348V2H2348-BSD1 2H0058880.D 1 10/13/19 PJ n/a n/a V2H2348



Spike BSP BSP BSD BSD LimitsCAS No. Compound ug/kg ug/kg % ug/kg % RPD Rec/RPD

67-64-1 Acetone 50 49.6 99 43.3 87 14 40-153/3071-43-2 Benzene 20 19.9 100 19.7 99 1 67-135/3075-27-4 Bromodichloromethane 20 20.0 100 20.3 102 1 54-146/3075-25-2 Bromoform 20 18.9 95 18.2 91 4 49-145/3075-15-0 Carbon Disulfide 20 21.6 108 20.2 101 7 48-153/3056-23-5 Carbon Tetrachloride 20 22.5 113 20.0 100 12 50-152/30108-90-7 Chlorobenzene 20 18.7 94 19.1 96 2 57-144/3075-00-3 Chloroethane 20 19.9 100 17.6 88 12 38-176/3067-66-3 Chloroform 20 21.3 107 20.4 102 4 53-147/30124-48-1 Dibromochloromethane 20 19.8 99 21.1 106 6 54-146/3096-12-8 1,2-Dibromo-3-chloropropane 20 20.9 105 19.4 97 7 51-145/30541-73-1 m-Dichlorobenzene 20 21.2 106 20.3 102 4 54-147/3095-50-1 o-Dichlorobenzene 20 19.8 99 19.7 99 1 55-144/30106-46-7 p-Dichlorobenzene 20 21.4 107 19.9 100 7 54-147/3075-34-3 1,1-Dichloroethane 20 23.8 119 23.3 117 2 53-148/30107-06-2 1,2-Dichloroethane 20 22.3 112 22.9 115 3 55-144/3075-35-4 1,1-Dichloroethylene 20 20.1 101 19.0 95 6 49-153/30156-59-2 cis-1,2-Dichloroethylene 20 20.8 104 18.9 95 10 52-147/30156-60-5 trans-1,2-Dichloroethylene 20 19.6 98 18.8 94 4 51-152/30540-59-0 1,2-Dichloroethene (total) 40 40.4 101 37.7 94 7 52-149/3078-87-5 1,2-Dichloropropane 20 20.5 103 21.0 105 2 56-145/3010061-01-5 cis-1,3-Dichloropropene 20 20.5 103 20.1 101 2 54-148/3010061-02-6 trans-1,3-Dichloropropene 20 20.5 103 21.1 106 3 53-151/30542-75-6 1,3-Dichloropropene (total) 40 41.0 103 41.2 103 0 50-150/30 a

100-41-4 Ethylbenzene 20 19.2 96 18.9 95 2 69-136/3067-72-1 Hexachloroethane 20 22.2 111 20.9 105 6 46-150/3078-83-1 Isobutyl alcohol 200 214 107 182 91 16 37-154/3074-83-9 Methyl Bromide 20 24.1 121 22.4 112 7 40-170/3074-87-3 Methyl Chloride 20 24.1 121 22.6 113 6 39-152/3075-09-2 Methylene Chloride 20 20.0 100 19.2 96 4 51-142/3078-93-3 Methyl Ethyl Ketone 50 48.7 97 48.5 97 0 48-150/30108-10-1 4-Methyl-2-pentanone 50 50.7 101 52.0 104 3 50-151/301634-04-4 Methyl Tert Butyl Ether 20 22.3 112 21.9 110 2 61-142/30100-42-5 Styrene 20 19.6 98 19.2 96 2 56-145/30630-20-6 1,1,1,2-Tetrachloroethane 20 18.3 92 19.4 97 6 56-147/3079-34-5 1,1,2,2-Tetrachloroethane 20 21.8 109 19.7 99 10 55-141/30

* = Outside of Control Limits.

176 of 283

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55.2.1






127-18-4 Tetrachloroethylene 20 21.2 106 18.8 94 12 54-156/30108-88-3 Toluene 20 18.4 92 19.7 99 7 71-135/3071-55-6 1,1,1-Trichloroethane 20 18.7 94 17.7 89 5 52-153/3079-00-5 1,1,2-Trichloroethane 20 20.4 102 19.4 97 5 55-144/3079-01-6 Trichloroethylene 20 20.1 101 21.1 106 5 56-151/3075-69-4 Trichlorofluoromethane 20 20.8 104 20.5 103 1 36-171/3075-01-4 Vinyl Chloride 20 21.9 110 19.7 99 11 42-155/30

m,p-Xylene 40 46.4 116 46.5 116 0 70-140/3095-47-6 o-Xylene 20 20.9 105 19.8 99 5 70-132/301330-20-7 Xylene (total) 60 67.3 112 66.2 110 2 69-138/30

CAS No. Surrogate Recoveries BSP BSD Limits


(a) Advisory control limits.


177 of 283

LA58267

55.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV2H2350-BS1 2H0058929.D 1 10/14/19 CP n/a n/a V2H2350V2H2350-BSD1 2H0058930.D 1 10/14/19 CP n/a n/a V2H2350


LA58267-15, LA58267-16





178 of 283

LA58267

55.2.2




LA58267-15, LA58267-16








179 of 283

LA58267

55.2.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1X3810-BS2 1X0084812.D 1 10/07/19 CP n/a n/a V1X3810V1X3810-BSD2 1X0084814.D 1 10/08/19 CP n/a n/a V1X3810


LA58267-20, LA58267-21

Spike BSP BSP BSD BSD LimitsCAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD

67-64-1 Acetone 50 39.1 78 45.2 90 14 35-173/2071-43-2 Benzene 20 19.0 95 21.3 107 11 82-119/1175-27-4 Bromodichloromethane 20 20.0 100 22.2 111 10 76-124/1175-25-2 Bromoform 20 20.3 102 22.5 113 10 52-131/1475-15-0 Carbon Disulfide 20 15.0 75 17.6 88 16* 69-135/1456-23-5 Carbon Tetrachloride 20 18.2 91 21.1 106 15* 73-127/13108-90-7 Chlorobenzene 20 18.6 93 20.7 104 11 82-118/1175-00-3 Chloroethane 20 22.4 112 21.8 109 3 57-146/2067-66-3 Chloroform 20 18.4 92 21.1 106 14* 77-122/12124-48-1 Dibromochloromethane 20 20.1 101 22.5 113 11 68-126/1296-12-8 1,2-Dibromo-3-chloropropane 20 17.3 87 18.8 94 8 57-132/17541-73-1 m-Dichlorobenzene 20 18.9 95 20.5 103 8 78-122/1295-50-1 o-Dichlorobenzene 20 19.1 96 21.2 106 10 78-122/12106-46-7 p-Dichlorobenzene 20 18.5 93 20.4 102 10 79-119/1275-34-3 1,1-Dichloroethane 20 17.6 88 20.3 102 14 77-124/14107-06-2 1,2-Dichloroethane 20 19.6 98 22.0 110 12* 71-124/1175-35-4 1,1-Dichloroethylene 20 15.9 80 18.2 91 13 77-125/14156-59-2 cis-1,2-Dichloroethylene 20 18.5 93 21.2 106 14* 79-121/13156-60-5 trans-1,2-Dichloroethylene 20 18.5 93 21.0 105 13 77-124/14540-59-0 1,2-Dichloroethene (total) 40 37.0 93 42.2 106 13 80-121/1378-87-5 1,2-Dichloropropane 20 18.5 93 20.9 105 12* 81-117/1110061-01-5 cis-1,3-Dichloropropene 20 19.2 96 21.8 109 13* 77-123/1110061-02-6 trans-1,3-Dichloropropene 20 18.7 94 20.9 105 11 74-127/12542-75-6 1,3-Dichloropropene (total) 40 38.0 95 42.7 107 12* 76-124/11100-41-4 Ethylbenzene 20 18.4 92 20.6 103 11 82-120/1167-72-1 Hexachloroethane 20 19.4 97 21.3 107 9 54-132/1578-83-1 Isobutyl Alcohol 200 197 99 244 122 21 37-152/3074-83-9 Methyl Bromide 20 18.4 92 21.0 105 13 46-165/2074-87-3 Methyl Chloride 20 15.3 77 17.6 88 14 55-140/1875-09-2 Methylene Chloride 20 19.6 98 21.8 109 11 73-132/1478-93-3 Methyl Ethyl Ketone 50 42.4 85 49.2 98 15 55-149/19108-10-1 4-Methyl-2-pentanone 50 44.0 88 49.8 100 12 63-137/171634-04-4 Methyl Tert Butyl Ether 20 19.0 95 21.8 109 14 73-124/14100-42-5 Styrene 20 19.9 100 22.5 113 12 80-126/12630-20-6 1,1,1,2-Tetrachloroethane 20 19.3 97 21.5 108 11 77-126/1279-34-5 1,1,2,2-Tetrachloroethane 20 17.9 90 19.5 98 9 69-134/14


180 of 283

LA58267

55.2.3




LA58267-20, LA58267-21



m,p-Xylene 40 38.7 97 43.4 109 11 82-123/1195-47-6 o-Xylene 20 19.6 98 22.1 111 12* 81-123/111330-20-7 Xylene (total) 60 58.3 97 65.5 109 12* 82-122/11




181 of 283

LA58267

55.2.3




LA58267-11, LA58267-12, LA58267-13, LA58267-14





182 of 283

LA58267

55.2.4




LA58267-11, LA58267-12, LA58267-13, LA58267-14








183 of 283

LA58267

55.2.4


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1G5837-BS1 1G111806.D 1 10/14/19 CP n/a n/a V1G5837V1G5837-BSD1 1G111808.D 1 10/14/19 CP n/a n/a V1G5837


LA58267-10


71-43-2 Benzene 20 20.1 101 21.5 108 7 82-119/11100-41-4 Ethylbenzene 20 20.5 103 21.8 109 6 82-120/11





184 of 283

LA58267

55.2.5

Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2Job Number: LA58267Account: PROVLABR Providence Engineering & EnvironmentalProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58146-4MS 1X0084846.D 100 10/08/19 CP n/a n/a V1X3810LA58146-4MSD 1X0084848.D 100 10/08/19 CP n/a n/a V1X3810LA58146-4 a 1X0084844.D 100 10/08/19 CP n/a n/a V1X3810


LA58267-20, LA58267-21

LA58146-4 Spike MS MS Spike MSD MSD LimitsCAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

67-64-1 Acetone 138 5000 3260 62 5000 3430 66 5 11-126/2271-43-2 Benzene 3630 2000 5490 93 2000 5680 103 3 41-155/1475-27-4 Bromodichloromethane ND 2000 2070 104 2000 2180 109 5 65-125/1475-25-2 Bromoform ND 2000 2090 105 2000 2180 109 4 39-127/1875-15-0 Carbon Disulfide ND 2000 1630 82 2000 1670 84 2 55-139/2056-23-5 Carbon Tetrachloride ND 2000 2110 106 2000 2110 106 0 60-131/20108-90-7 Chlorobenzene ND 2000 1920 96 2000 1970 99 3 71-124/1475-00-3 Chloroethane 2140 2000 2050 -5* 2000 2450 16* 18 44-163/3167-66-3 Chloroform ND 2000 1980 99 2000 2040 102 3 65-130/15124-48-1 Dibromochloromethane ND 2000 2110 106 2000 2140 107 1 57-125/1596-12-8 1,2-Dibromo-3-chloropropane ND 2000 1780 89 2000 1820 91 2 43-132/22541-73-1 m-Dichlorobenzene ND 2000 1860 93 2000 1990 100 7 67-124/1495-50-1 o-Dichlorobenzene ND 2000 1900 95 2000 1970 99 4 67-124/14106-46-7 p-Dichlorobenzene ND 2000 1860 93 2000 1900 95 2 66-122/1575-34-3 1,1-Dichloroethane ND 2000 1920 96 2000 1980 99 3 65-132/17107-06-2 1,2-Dichloroethane ND 2000 2050 103 2000 2180 109 6 61-130/1375-35-4 1,1-Dichloroethylene ND 2000 1750 88 2000 1750 88 0 62-136/20156-59-2 cis-1,2-Dichloroethylene ND 2000 1940 97 2000 2010 101 4 68-129/15156-60-5 trans-1,2-Dichloroethylene ND 2000 1920 96 2000 1950 98 2 65-132/18540-59-0 1,2-Dichloroethene (total) ND 4000 3860 97 4000 3960 99 3 66-130/1578-87-5 1,2-Dichloropropane ND 2000 1830 92 2000 1950 98 6 71-123/1410061-01-5 cis-1,3-Dichloropropene ND 2000 1870 94 2000 1980 99 6 61-125/1510061-02-6 trans-1,3-Dichloropropene ND 2000 1870 94 2000 1900 95 2 59-128/14542-75-6 1,3-Dichloropropene (total) ND 4000 3740 94 4000 3880 97 4 61-126/14100-41-4 Ethylbenzene 912 2000 2820 95 2000 2900 99 3 50-147/1567-72-1 Hexachloroethane ND 2000 1920 96 2000 2010 101 5 42-122/2178-83-1 Isobutyl Alcohol ND 20000 13600 68 20000 22900 115 51* 6-168/4174-83-9 Methyl Bromide ND 2000 1650 83 2000 1970 99 18 24-163/2874-87-3 Methyl Chloride ND 2000 1610 81 2000 1610 81 0 37-151/2275-09-2 Methylene Chloride 47.5 2000 2070 101 2000 2110 103 2 63-137/1678-93-3 Methyl Ethyl Ketone ND 5000 3980 80 5000 4090 82 3 35-137/21108-10-1 4-Methyl-2-pentanone ND 5000 4150 83 5000 4670 93 12 48-146/211634-04-4 Methyl Tert Butyl Ether 378 2000 2390 101 2000 2400 101 0 48-143/15100-42-5 Styrene 34.0 2000 2090 103 2000 2150 106 3 58-140/18630-20-6 1,1,1,2-Tetrachloroethane ND 2000 2010 101 2000 2090 105 4 67-127/1579-34-5 1,1,2,2-Tetrachloroethane ND 2000 1810 91 2000 1880 94 4 62-139/16


185 of 283

LA58267

55.3.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58146-4MS 1X0084846.D 100 10/08/19 CP n/a n/a V1X3810LA58146-4MSD 1X0084848.D 100 10/08/19 CP n/a n/a V1X3810LA58146-4 a 1X0084844.D 100 10/08/19 CP n/a n/a V1X3810


LA58267-20, LA58267-21


127-18-4 Tetrachloroethylene ND 2000 1980 99 2000 2050 103 3 68-127/19108-88-3 Toluene 9050 2000 10800 88 2000 10800 88 0 40-153/1571-55-6 1,1,1-Trichloroethane ND 2000 2130 107 2000 2160 108 1 68-132/1879-00-5 1,1,2-Trichloroethane ND 2000 1880 94 2000 1920 96 2 62-137/1679-01-6 Trichloroethylene ND 2000 2030 102 2000 2100 105 3 67-124/1675-69-4 Trichlorofluoromethane ND 2000 2170 109 2000 2200 110 1 65-134/1775-01-4 Vinyl Chloride ND 2000 1690 85 2000 1740 87 3 60-133/16

m,p-Xylene 5640 4000 9590 99 4000 9690 101 1 47-153/1595-47-6 o-Xylene 2990 2000 5030 102 2000 5120 107 2 50-149/141330-20-7 Xylene (total) 8630 6000 14600 100 6000 14800 103 1 46-154/15

CAS No. Surrogate Recoveries MS MSD LA58146-4 Limits

17060-07-0 1,2-Dichloroethane-D4 98% 96% 95% 81-120%2037-26-5 Toluene-D8 99% 100% 99% 93-105%460-00-4 4-Bromofluorobenzene 104% 101% 104% 89-107%

(a) Sample used for QC purposes only.


186 of 283

LA58267

55.3.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58267-4MS 2H0058863.D 1 10/13/19 PJ n/a n/a V2H2347LA58267-4MSD 2H0058864.D 1 10/13/19 PJ n/a n/a V2H2347LA58267-4 a 2H0058852.D 1 10/12/19 PJ n/a n/a V2H2347


LA58267-11, LA58267-12, LA58267-13, LA58267-14

LA58267-4 Spike MS MS Spike MSD MSD LimitsCAS No. Compound ug/kg Q ug/kg ug/kg % ug/kg ug/kg % RPD Rec/RPD

67-64-1 Acetone 324 49 234 -184* b 49 455 267* b 64* c 19-170/3471-43-2 Benzene ND 19.6 29.6 151 19.6 30.9 158 4 15-162/3375-27-4 Bromodichloromethane ND 19.6 31.2 159* c 19.6 33.2 169* c 6 48-124/1475-25-2 Bromoform ND 19.6 35.6 182* c 19.6 37.3 190* c 5 20-128/1675-15-0 Carbon Disulfide ND 19.6 24.9 127 19.6 26.6 136 7 4-140/3156-23-5 Carbon Tetrachloride ND 19.6 24.4 124 19.6 25.6 131 5 25-136/17108-90-7 Chlorobenzene ND 19.6 26.1 133 19.6 26.3 134 1 31-153/1275-00-3 Chloroethane ND 19.6 22.4 114 19.6 23.7 121 6 1-171/6467-66-3 Chloroform ND 19.6 28.4 145 19.6 28.0 143 1 26-153/42124-48-1 Dibromochloromethane ND 19.6 35.5 181* c 19.6 36.8 188* c 4 26-131/1496-12-8 1,2-Dibromo-3-chloropropane ND 19.6 21.7 111 19.6 22.6 115 4 18-141/68541-73-1 m-Dichlorobenzene ND 19.6 24.6 125 19.6 24.0 122 2 22-152/1595-50-1 o-Dichlorobenzene ND 19.6 27.0 138 19.6 26.3 134 3 27-150/12106-46-7 p-Dichlorobenzene ND 19.6 26.5 135 19.6 25.0 128 6 19-154/1275-34-3 1,1-Dichloroethane ND 19.6 31.1 159* c 19.6 32.3 165* c 4 31-147/13107-06-2 1,2-Dichloroethane ND 19.6 34.8 177* c 19.6 36.3 185* c 4 31-147/1375-35-4 1,1-Dichloroethylene ND 19.6 26.0 133 19.6 27.2 139 5 22-148/19156-59-2 cis-1,2-Dichloroethylene ND 19.6 26.9 137 19.6 27.2 139 1 25-145/15156-60-5 trans-1,2-Dichloroethylene ND 19.6 25.7 131 19.6 27.7 141 7 24-145/17540-59-0 1,2-Dichloroethene (total) ND 39.2 52.5 134 39.2 55.0 140 5 30-142/1578-87-5 1,2-Dichloropropane ND 19.6 32.2 164* c 19.6 34.5 176* c 7 36-141/1310061-01-5 cis-1,3-Dichloropropene ND 19.6 30.6 156* c 19.6 31.1 159* c 2 27-143/1210061-02-6 trans-1,3-Dichloropropene ND 19.6 31.6 161* c 19.6 32.4 165* c 2 46-130/14542-75-6 1,3-Dichloropropene (total) ND 39.2 62.2 159* c 39.2 63.6 162* c 2 50-150/30 d

100-41-4 Ethylbenzene ND 19.6 19.4 99 19.6 20.1 103 4 14-168/1367-72-1 Hexachloroethane ND 19.6 22.2 113 19.6 20.2 103 9 4-136/1978-83-1 Isobutyl alcohol ND 196 310 158 196 302 154 3 16-172/1674-83-9 Methyl Bromide ND 19.6 28.2 144 19.6 30.4 155 8 1-178/4074-87-3 Methyl Chloride ND 19.6 30.1 154* c 19.6 31.1 159* c 3 1-151/3775-09-2 Methylene Chloride ND 19.6 31.2 159* c 19.6 35.0 179* c 11 27-147/1878-93-3 Methyl Ethyl Ketone 16.6 49 83.9 137 49 82.0 133 2 29-156/32108-10-1 4-Methyl-2-pentanone ND 49 90.4 184* c 49 91.6 187* c 1 33-160/231634-04-4 Methyl Tert Butyl Ether ND 19.6 35.5 181* c 19.6 35.9 183* c 1 37-145/14100-42-5 Styrene ND 19.6 3.1 16* c 19.6 3.1 16* c 0 24-165/13630-20-6 1,1,1,2-Tetrachloroethane ND 19.6 30.4 155* c 19.6 31.4 160* c 3 33-140/1379-34-5 1,1,2,2-Tetrachloroethane ND 19.6 34.3 175* c 19.6 33.3 170* c 3 33-146/48


187 of 283

LA58267

55.3.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58267-4MS 2H0058863.D 1 10/13/19 PJ n/a n/a V2H2347LA58267-4MSD 2H0058864.D 1 10/13/19 PJ n/a n/a V2H2347LA58267-4 a 2H0058852.D 1 10/12/19 PJ n/a n/a V2H2347


LA58267-11, LA58267-12, LA58267-13, LA58267-14


127-18-4 Tetrachloroethylene ND 19.6 24.7 126 19.6 26.3 134 6 21-149/18108-88-3 Toluene ND 19.6 25.2 129 19.6 26.1 133 4 11-173/4371-55-6 1,1,1-Trichloroethane ND 19.6 22.9 117 19.6 23.1 118 1 31-142/1679-00-5 1,1,2-Trichloroethane ND 19.6 36.1 184 19.6 36.6 187* c 1 11-185/1679-01-6 Trichloroethylene ND 19.6 28.6 146 19.6 31.6 161* c 10 21-154/1575-69-4 Trichlorofluoromethane ND 19.6 21.2 108 19.6 22.4 114 6 1-163/2775-01-4 Vinyl Chloride ND 19.6 28.4 145 19.6 28.5 145 0 32-153/15

m,p-Xylene ND 39.2 47.5 121 39.2 47.6 121 0 14-175/1295-47-6 o-Xylene ND 19.6 25.1 128 19.6 25.4 130 1 19-167/131330-20-7 Xylene (total) ND 58.8 72.6 123 58.8 73.1 124 1 14-172/12



(a) Sample used for QC purposes only.(b) Outside control limits due to high level in sample relative to spike amount.(c) Outside control limits due to matrix interference. Blank Spike meets acceptance criteria.(d) Advisory control limits.


188 of 283

LA58267

55.3.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58237-8MS 1G111818.D 1 10/14/19 CP n/a n/a V1G5837LA58237-8MSD 1G111820.D 1 10/14/19 CP n/a n/a V1G5837LA58237-8 1G111814.D 1 10/14/19 CP n/a n/a V1G5837


LA58267-10


71-43-2 Benzene ND 1820 1910 105 1820 2040 112 7 15-162/33100-41-4 Ethylbenzene ND 1820 1950 107 1820 2030 112 4 14-168/13

m,p-Xylene ND 3640 4130 114 3640 4360 120 5 14-175/1295-47-6 o-Xylene ND 1820 2110 116 1820 2280 125 8 19-167/131330-20-7 Xylene (total) ND 5450 6240 114 5450 6640 122 6 14-172/12




189 of 283

LA58267

55.3.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58344-4MS 2H0058945.D 1 10/14/19 CP n/a n/a V2H2350LA58344-4MSD 2H0058946.D 1 10/14/19 CP n/a n/a V2H2350LA58344-4 2H0058940.D 1 10/14/19 CP n/a n/a V2H2350


LA58267-15, LA58267-16


67-64-1 Acetone 308 50 230 -156* a 52.1 68.5 -460* a 108* 19-170/3471-43-2 Benzene 0.62 20 14.3 68 20.8 14.6 67 2 15-162/3375-27-4 Bromodichloromethane ND 20 15.4 77 20.8 14.6 70 5 48-124/1475-25-2 Bromoform ND 20 17.4 87 20.8 16.7 80 4 20-128/1675-15-0 Carbon Disulfide ND 20 11.6 58 20.8 12.9 62 11 4-140/3156-23-5 Carbon Tetrachloride ND 20 13.3 67 20.8 13.6 65 2 25-136/17108-90-7 Chlorobenzene ND 20 14.5 73 20.8 14.0 67 4 31-153/1275-00-3 Chloroethane ND 20 10.2 51 20.8 10.1 48 1 1-171/6467-66-3 Chloroform ND 20 13.2 66 20.8 13.9 67 5 26-153/42124-48-1 Dibromochloromethane ND 20 16.9 85 20.8 16.8 81 1 26-131/1496-12-8 1,2-Dibromo-3-chloropropane ND 20 11.3 57 20.8 13.3 64 16 18-141/68541-73-1 m-Dichlorobenzene ND 20 15.3 77 20.8 14.7 71 4 22-152/1595-50-1 o-Dichlorobenzene ND 20 15.1 76 20.8 14.8 71 2 27-150/12106-46-7 p-Dichlorobenzene ND 20 15.5 78 20.8 14.8 71 5 19-154/1275-34-3 1,1-Dichloroethane ND 20 14.7 74 20.8 15.1 72 3 31-147/13107-06-2 1,2-Dichloroethane ND 20 17.6 88 20.8 16.9 81 4 31-147/1375-35-4 1,1-Dichloroethylene ND 20 12.0 60 20.8 11.8 57 2 22-148/19156-59-2 cis-1,2-Dichloroethylene ND 20 12.9 65 20.8 13.2 63 2 25-145/15156-60-5 trans-1,2-Dichloroethylene ND 20 12.7 64 20.8 13.1 63 3 24-145/17540-59-0 1,2-Dichloroethene (total) ND 40 25.6 64 41.7 26.3 63 3 30-142/1578-87-5 1,2-Dichloropropane ND 20 15.1 76 20.8 16.1 77 6 36-141/1310061-01-5 cis-1,3-Dichloropropene ND 20 15.0 75 20.8 15.8 76 5 27-143/1210061-02-6 trans-1,3-Dichloropropene ND 20 17.1 86 20.8 15.7 75 9 46-130/14542-75-6 1,3-Dichloropropene (total) ND 40 32.1 80 41.7 31.5 76 2 50-150/30 b

100-41-4 Ethylbenzene ND 20 13.1 66 20.8 13.1 63 0 14-168/1367-72-1 Hexachloroethane ND 20 16.2 81 20.8 16.1 77 1 4-136/1978-83-1 Isobutyl alcohol ND 200 142 71 208 156 75 9 16-172/1674-83-9 Methyl Bromide ND 20 12.0 60 20.8 13.5 65 12 1-178/4074-87-3 Methyl Chloride ND 20 12.2 61 20.8 12.9 62 6 1-151/3775-09-2 Methylene Chloride ND 20 13.7 69 20.8 11.3 54 19* 27-147/1878-93-3 Methyl Ethyl Ketone 22.0 50 50.6 57 52.1 41.1 37 21 29-156/32108-10-1 4-Methyl-2-pentanone ND 50 44.2 88 52.1 42.3 81 4 33-160/231634-04-4 Methyl Tert Butyl Ether ND 20 16.5 83 20.8 16.2 78 2 37-145/14100-42-5 Styrene ND 20 9.5 48 20.8 11.8 57 22* 24-165/13630-20-6 1,1,1,2-Tetrachloroethane ND 20 15.3 77 20.8 14.5 70 5 33-140/1379-34-5 1,1,2,2-Tetrachloroethane ND 20 16.8 84 20.8 17.3 83 3 33-146/48


190 of 283

LA58267

55.3.4




LA58267-15, LA58267-16


127-18-4 Tetrachloroethylene ND 20 16.8 84 20.8 16.5 79 2 21-149/18108-88-3 Toluene ND 20 14.2 71 20.8 13.5 65 5 11-173/4371-55-6 1,1,1-Trichloroethane ND 20 10.8 54 20.8 12.0 58 11 31-142/1679-00-5 1,1,2-Trichloroethane ND 20 18.3 92 20.8 16.7 80 9 11-185/1679-01-6 Trichloroethylene ND 20 14.3 72 20.8 16.5 79 14 21-154/1575-69-4 Trichlorofluoromethane ND 20 10.4 52 20.8 11.1 53 7 1-163/2775-01-4 Vinyl Chloride ND 20 11.3 57 20.8 12.7 61 12 32-153/15

m,p-Xylene 0.59 40 32.7 80 41.7 32.5 77 1 14-175/1295-47-6 o-Xylene ND 20 14.0 70 20.8 14.0 67 0 19-167/131330-20-7 Xylene (total) ND 60 46.7 78 62.5 46.5 74 0 14-172/12



(a) Outside control limits due to high level in sample relative to spike amount.(b) Advisory control limits.


191 of 283

LA58267

55.3.4


MS Semi-volatiles

QC Data Summaries



Scott, LASection 6

192 of 283

LA58267

6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15346-MB C0051387.D 1 10/15/19 AA 10/11/19 OP15346 EC2049


LA58267-1, LA58267-2, LA58267-3, LA58267-4, LA58267-5, LA58267-6, LA58267-7, LA58267-8, LA58267-9,LA58267-10, LA58267-11, LA58267-12, LA58267-13, LA58267-14, LA58267-15, LA58267-16, LA58267-17, LA58267-18, LA58267-19


95-57-8 2-Chlorophenol ND 170 ug/kg120-83-2 2,4-Dichlorophenol ND 170 ug/kg105-67-9 2,4-Dimethylphenol ND 170 ug/kg51-28-5 2,4-Dinitrophenol ND 660 ug/kg100-02-7 4-Nitrophenol ND 660 ug/kg87-86-5 Pentachlorophenol ND 170 ug/kg108-95-2 Phenol ND 170 ug/kg58-90-2 2,3,4,6-Tetrachlorophenol ND 170 ug/kg95-95-4 2,4,5-Trichlorophenol ND 170 ug/kg88-06-2 2,4,6-Trichlorophenol ND 170 ug/kg83-32-9 Acenaphthene ND 10 ug/kg208-96-8 Acenaphthylene ND 10 ug/kg62-53-3 Aniline ND 170 ug/kg120-12-7 Anthracene ND 10 ug/kg56-55-3 Benzo(a)anthracene ND 10 ug/kg50-32-8 Benzo(a)pyrene ND 10 ug/kg205-99-2 Benzo(b)fluoranthene ND 10 ug/kg92-52-4 1,1' -Biphenyl ND 170 ug/kg207-08-9 Benzo(k)fluoranthene ND 10 ug/kg85-68-7 Butyl Benzyl Phthalate ND 170 ug/kg106-47-8 4-Chloroaniline ND 170 ug/kg111-44-4 bis(2-Chloroethyl)ether ND 170 ug/kg108-60-1 2,2' -Oxybis(1-chloropropane) ND 170 ug/kg91-58-7 2-Chloronaphthalene ND 170 ug/kg218-01-9 Chrysene ND 10 ug/kg53-70-3 Dibenzo(a,h)anthracene ND 10 ug/kg132-64-9 Dibenzofuran ND 170 ug/kg91-94-1 3,3' -Dichlorobenzidine ND 170 ug/kg84-66-2 Diethyl Phthalate ND 170 ug/kg131-11-3 Dimethyl Phthalate ND 170 ug/kg117-84-0 Di-n-octyl Phthalate ND 170 ug/kg99-65-0 1,3-Dinitrobenzene ND 170 ug/kg121-14-2 2,4-Dinitrotoluene ND 170 ug/kg606-20-2 2,6-Dinitrotoluene ND 170 ug/kg117-81-7 bis(2-Ethylhexyl)phthalate ND 170 ug/kg206-44-0 Fluoranthene ND 10 ug/kg

193 of 283

LA58267

66.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15346-MB C0051387.D 1 10/15/19 AA 10/11/19 OP15346 EC2049




86-73-7 Fluorene ND 10 ug/kg118-74-1 Hexachlorobenzene ND 170 ug/kg87-68-3 Hexachlorobutadiene ND 170 ug/kg77-47-4 Hexachlorocyclopentadiene ND 660 ug/kg193-39-5 Indeno(1,2,3-cd)pyrene ND 10 ug/kg78-59-1 Isophorone ND 170 ug/kg91-57-6 2-Methylnaphthalene ND 10 ug/kg91-20-3 Naphthalene ND 10 ug/kg88-74-4 2-Nitroaniline ND 660 ug/kg99-09-2 3-Nitroaniline ND 660 ug/kg100-01-6 4-Nitroaniline ND 660 ug/kg98-95-3 Nitrobenzene ND 170 ug/kg621-64-7 N-Nitroso-di-n-propylamine ND 170 ug/kg86-30-6 N-Nitrosodiphenylamine ND 170 ug/kg85-01-8 Phenanthrene ND 10 ug/kg129-00-0 Pyrene ND 10 ug/kg95-94-3 1,2,4,5-Tetrachlorobenzene ND 170 ug/kg120-82-1 1,2,4-Trichlorobenzene ND 170 ug/kg



194 of 283

LA58267

66.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15315-MB L0029640.D 1 10/11/19 AA 10/07/19 OP15315 EL785


LA58267-20


95-57-8 2-Chlorophenol ND 5.0 ug/l120-83-2 2,4-Dichlorophenol ND 5.0 ug/l105-67-9 2,4-Dimethylphenol ND 5.0 ug/l51-28-5 2,4-Dinitrophenol ND 20 ug/l100-02-7 4-Nitrophenol ND 25 ug/l87-86-5 Pentachlorophenol ND 10 ug/l108-95-2 Phenol ND 5.0 ug/l58-90-2 2,3,4,6-Tetrachlorophenol ND 5.0 ug/l95-95-4 2,4,5-Trichlorophenol ND 5.0 ug/l88-06-2 2,4,6-Trichlorophenol ND 5.0 ug/l83-32-9 Acenaphthene ND 0.20 ug/l208-96-8 Acenaphthylene ND 0.20 ug/l62-53-3 Aniline ND 5.0 ug/l120-12-7 Anthracene ND 0.20 ug/l56-55-3 Benzo(a)anthracene ND 0.20 ug/l50-32-8 Benzo(a)pyrene ND 0.20 ug/l205-99-2 Benzo(b)fluoranthene ND 0.20 ug/l207-08-9 Benzo(k)fluoranthene ND 0.20 ug/l92-52-4 1,1' -Biphenyl ND 10 ug/l85-68-7 Butyl Benzyl Phthalate ND 5.0 ug/l106-47-8 4-Chloroaniline ND 5.0 ug/l111-44-4 bis(2-Chloroethyl)ether ND 5.0 ug/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 5.0 ug/l91-58-7 2-Chloronaphthalene ND 5.0 ug/l218-01-9 Chrysene ND 0.20 ug/l53-70-3 Dibenzo(a,h)anthracene ND 0.20 ug/l132-64-9 Dibenzofuran ND 5.0 ug/l91-94-1 3,3' -Dichlorobenzidine ND 10 ug/l84-66-2 Diethyl Phthalate ND 5.0 ug/l131-11-3 Dimethyl Phthalate ND 5.0 ug/l117-84-0 Di-n-octyl Phthalate ND 5.0 ug/l99-65-0 1,3-Dinitrobenzene ND 5.0 ug/l121-14-2 2,4-Dinitrotoluene ND 5.0 ug/l606-20-2 2,6-Dinitrotoluene ND 5.0 ug/l117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 ug/l206-44-0 Fluoranthene ND 0.20 ug/l

195 of 283

LA58267

66.1.2




LA58267-20


86-73-7 Fluorene ND 0.20 ug/l118-74-1 Hexachlorobenzene ND 5.0 ug/l87-68-3 Hexachlorobutadiene ND 5.0 ug/l77-47-4 Hexachlorocyclopentadiene ND 10 ug/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.20 ug/l78-59-1 Isophorone ND 5.0 ug/l91-57-6 2-Methylnaphthalene ND 0.20 ug/l91-20-3 Naphthalene ND 0.20 ug/l88-74-4 2-Nitroaniline ND 5.0 ug/l99-09-2 3-Nitroaniline ND 5.0 ug/l100-01-6 4-Nitroaniline ND 5.0 ug/l98-95-3 Nitrobenzene ND 5.0 ug/l621-64-7 N-Nitroso-di-n-propylamine ND 5.0 ug/l86-30-6 N-Nitrosodiphenylamine ND 5.0 ug/l85-01-8 Phenanthrene ND 0.20 ug/l129-00-0 Pyrene ND 0.20 ug/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 5.0 ug/l120-82-1 1,2,4-Trichlorobenzene ND 5.0 ug/l



196 of 283

LA58267

66.1.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15346-BS C0051388.D 1 10/15/19 AA 10/11/19 OP15346 EC2049OP15346-BSD C0051389.D 1 10/15/19 AA 10/11/19 OP15346 EC2049




95-57-8 2-Chlorophenol 2500 2190 88 2220 90 1 67-104/14120-83-2 2,4-Dichlorophenol 2500 2350 94 2460 100 5 70-106/15105-67-9 2,4-Dimethylphenol 2500 2070 83 2110 86 2 67-108/1551-28-5 2,4-Dinitrophenol 2500 2910 116 3050 124* a 5 49-119/23100-02-7 4-Nitrophenol 2500 1680 67 1690 69 1 55-123/1887-86-5 Pentachlorophenol 2500 2460 98 2530 103 3 61-106/20108-95-2 Phenol 2500 2450 98 2410 98 2 63-110/1458-90-2 2,3,4,6-Tetrachlorophenol 2500 2670 107 2840 115 6 65-115/1995-95-4 2,4,5-Trichlorophenol 2500 2460 98 2550 104 4 66-114/1788-06-2 2,4,6-Trichlorophenol 2500 2250 90 2380 97 6 66-112/1783-32-9 Acenaphthene 2500 2280 91 2350 95 3 68-102/15208-96-8 Acenaphthylene 2500 2160 86 2230 91 3 69-106/1562-53-3 Aniline 2500 2140 86 2300 93 7 64-110/16120-12-7 Anthracene 2500 2330 93 2370 96 2 70-105/1656-55-3 Benzo(a)anthracene 2500 3020 121* a 3050 124* a 1 66-102/1650-32-8 Benzo(a)pyrene 2500 2430 97 2500 101 3 69-110/16205-99-2 Benzo(b)fluoranthene 2500 2500 100 2600 106 4 66-109/1892-52-4 1,1' -Biphenyl 2500 2160 86 2210 90 2 67-104/15207-08-9 Benzo(k)fluoranthene 2500 2630 105 2710 110 3 68-110/1785-68-7 Butyl Benzyl Phthalate 2500 1440 58* b 1520 62* b 5 64-117/18106-47-8 4-Chloroaniline 2500 1830 73 1930 78 5 66-113/15111-44-4 bis(2-Chloroethyl)ether 2500 1940 78 2010 82 4 58-109/17108-60-1 2,2' -Oxybis(1-chloropropane) 2500 1950 78 1990 81 2 48-115/1691-58-7 2-Chloronaphthalene 2500 2150 86 2250 91 5 69-103/15218-01-9 Chrysene 2500 2550 102 2600 106* c 2 66-104/1653-70-3 Dibenzo(a,h)anthracene 2500 2720 109* c 2770 112* c 2 68-108/16132-64-9 Dibenzofuran 2500 2400 96 2440 99 2 68-103/1691-94-1 3,3' -Dichlorobenzidine 2500 2280 91 2440 99 7 64-116/1884-66-2 Diethyl Phthalate 2500 2020 81 2080 84 3 68-108/17131-11-3 Dimethyl Phthalate 2500 2170 87 2250 91 4 69-106/16117-84-0 Di-n-octyl Phthalate 2500 1340 54* b 1420 58* b 6 62-115/1899-65-0 1,3-Dinitrobenzene 2500 2240 90 2400 97 7 69-114/17121-14-2 2,4-Dinitrotoluene 2500 2190 88 2220 90 1 68-117/16606-20-2 2,6-Dinitrotoluene 2500 2230 89 2340 95 5 69-113/17117-81-7 bis(2-Ethylhexyl)phthalate 2500 1680 67 1720 70 2 63-116/19206-44-0 Fluoranthene 2500 2540 102 2550 104 0 70-108/17


197 of 283

LA58267

66.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15346-BS C0051388.D 1 10/15/19 AA 10/11/19 OP15346 EC2049OP15346-BSD C0051389.D 1 10/15/19 AA 10/11/19 OP15346 EC2049




86-73-7 Fluorene 2500 2330 93 2440 99 5 69-104/16118-74-1 Hexachlorobenzene 2500 2960 118* c 3040 123* a 3 68-107/1787-68-3 Hexachlorobutadiene 2500 2730 109* c 2750 112* c 1 64-107/1477-47-4 Hexachlorocyclopentadiene 2500 2340 94 2520 102 7 51-120/16193-39-5 Indeno(1,2,3-cd)pyrene 2500 2660 106 2730 111* c 3 68-108/1678-59-1 Isophorone 2500 2000 80 2080 84 4 65-111/1691-57-6 2-Methylnaphthalene 2500 2330 93 2430 99 4 70-102/1491-20-3 Naphthalene 2500 2190 88 2240 91 2 68-100/1488-74-4 2-Nitroaniline 2500 1820 73 1940 79 6 67-113/1799-09-2 3-Nitroaniline 2500 2020 81 2140 87 6 66-112/17100-01-6 4-Nitroaniline 2500 1940 78 1910 78 2 68-111/1798-95-3 Nitrobenzene 2500 1990 80 2120 86 6 68-106/14621-64-7 N-Nitroso-di-n-propylamine 2500 1890 76 1960 80 4 61-111/1686-30-6 N-Nitrosodiphenylamine 2500 2390 96 2450 99 2 69-106/1785-01-8 Phenanthrene 2500 2320 93 2340 95 1 68-101/16129-00-0 Pyrene 2500 2350 94 2410 98 3 67-107/1695-94-3 1,2,4,5-Tetrachlorobenzene 2500 2650 106 2770 112* c 4 65-106/15120-82-1 1,2,4-Trichlorobenzene 2500 2490 100 2510 102 1 67-104/14



(a) Outside control limits biased high. Analyte not detected in associated samples.(b) Outside control limits. MS/MSD meets criteria.(c) Outside laboratory control limits but within reasonable method acceptance limits.


198 of 283

LA58267

66.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15315-BS L0029641.D 1 10/11/19 AA 10/07/19 OP15315 EL785OP15315-BSD L0029642.D 1 10/11/19 AA 10/07/19 OP15315 EL785


LA58267-20


95-57-8 2-Chlorophenol 5 5.3 106 4.8 96 10 48-123/17120-83-2 2,4-Dichlorophenol 5 5.9 118 5.5 110 7 52-135/17105-67-9 2,4-Dimethylphenol 5 4.6 92 5.0 100 8 47-132/2151-28-5 2,4-Dinitrophenol 25 30.4 122 28.6 114 6 32-139/25100-02-7 4-Nitrophenol 25 22.0 88 21.2 85 4 15-105/2287-86-5 Pentachlorophenol 25 27.4 110 26.2 105 4 51-131/19108-95-2 Phenol 5 3.3 66 3.1 62 6 19-92/2358-90-2 2,3,4,6-Tetrachlorophenol 5 5.8 116 5.5 110 5 57-136/1995-95-4 2,4,5-Trichlorophenol 5 5.6 112 5.4 108 4 51-143/1788-06-2 2,4,6-Trichlorophenol 5 5.8 116 5.6 112 4 59-132/1983-32-9 Acenaphthene 5 5.1 102 4.9 98 4 50-120/16208-96-8 Acenaphthylene 5 5.2 104 5.0 100 4 48-126/1662-53-3 Aniline 5 0.085 2* a 1.0 20 169* b 10-112/50120-12-7 Anthracene 5 5.4 108 5.1 102 6 53-128/1656-55-3 Benzo(a)anthracene 5 5.3 106 5.1 102 4 54-129/1950-32-8 Benzo(a)pyrene 5 5.4 108 5.2 104 4 55-135/19205-99-2 Benzo(b)fluoranthene 5 5.7 114 5.3 106 7 54-139/23207-08-9 Benzo(k)fluoranthene 5 5.4 108 5.2 104 4 58-132/2292-52-4 1,1' -Biphenyl 5 5.0 100 4.8 96 4 44-127/1785-68-7 Butyl Benzyl Phthalate 5 6.1 122 5.8 116 5 63-141/20106-47-8 4-Chloroaniline 5 0.19 4* a 1.8 36 162* b 19-126/38111-44-4 bis(2-Chloroethyl)ether 5 5.4 108 5.0 100 8 45-123/17108-60-1 2,2' -Oxybis(1-chloropropane) 5 5.2 104 4.7 94 10 29-126/1791-58-7 2-Chloronaphthalene 5 5.0 100 4.7 94 6 44-123/20218-01-9 Chrysene 5 5.5 110 5.2 104 6 57-127/2053-70-3 Dibenzo(a,h)anthracene 5 5.9 118 5.4 108 9 58-141/21132-64-9 Dibenzofuran 5 5.3 106 5.0 100 6 48-126/1791-94-1 3,3' -Dichlorobenzidine 5 1.2 24 2.9 58 83* b 10-188/4084-66-2 Diethyl Phthalate 5 5.5 110 5.2 104 6 54-133/17131-11-3 Dimethyl Phthalate 5 5.5 110 5.2 104 6 56-132/17117-84-0 Di-n-octyl Phthalate 5 5.4 108 5.1 102 6 66-139/2199-65-0 1,3-Dinitrobenzene 25 28.7 115 27.3 109 5 64-133/16121-14-2 2,4-Dinitrotoluene 5 5.9 118 5.5 110 7 67-132/20606-20-2 2,6-Dinitrotoluene 5 5.9 118 5.4 108 9 56-138/20117-81-7 bis(2-Ethylhexyl)phthalate 5 6.2 124 5.8 116 7 60-142/20206-44-0 Fluoranthene 5 5.6 112 5.2 104 7 57-133/18


199 of 283

LA58267

66.2.2




LA58267-20


86-73-7 Fluorene 5 5.5 110 5.1 102 8 52-125/15118-74-1 Hexachlorobenzene 5 5.1 102 4.9 98 4 47-127/2187-68-3 Hexachlorobutadiene 5 4.7 94 4.4 88 7 14-121/3077-47-4 Hexachlorocyclopentadiene 5 1.6 32 1.4 28 13 10-114/31193-39-5 Indeno(1,2,3-cd)pyrene 5 5.8 116 5.4 108 7 58-142/1978-59-1 Isophorone 5 5.6 112 5.2 104 7 52-130/1891-57-6 2-Methylnaphthalene 5 5.3 106 4.9 98 8 43-123/1891-20-3 Naphthalene 5 5.1 102 4.8 96 6 45-120/1688-74-4 2-Nitroaniline 25 29.9 120 27.8 111 7 63-132/1799-09-2 3-Nitroaniline 25 10.4 42 20.4 82 65* b 31-144/23100-01-6 4-Nitroaniline 25 28.3 113 27.1 108 4 22-154/2598-95-3 Nitrobenzene 5 5.9 118 5.5 110 7 52-128/17621-64-7 N-Nitroso-di-n-propylamine 5 5.5 110 5.0 100 10 48-129/2086-30-6 N-Nitrosodiphenylamine 5 5.0 100 4.9 98 2 26-146/2885-01-8 Phenanthrene 5 5.2 104 5.0 100 4 54-124/17129-00-0 Pyrene 5 5.6 112 5.3 106 6 56-132/1995-94-3 1,2,4,5-Tetrachlorobenzene 5 4.6 92 4.4 88 4 33-121/24120-82-1 1,2,4-Trichlorobenzene 5 4.7 94 4.5 90 4 34-118/23



(a) Outside control limits biased low. Unable to re-extract sample within holding time.(b) Analytical precision exceeds laboratory control limits.


200 of 283

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66.2.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15346-MS C0051403.D 1 10/15/19 AA 10/11/19 OP15346 EC2049OP15346-MSD C0051404.D 1 10/15/19 AA 10/11/19 OP15346 EC2049LA58267-4 C0051405.D 1 10/15/19 AA 10/11/19 OP15346 EC2049




95-57-8 2-Chlorophenol ND 2480 1930 78 2450 1850 75 4 47-110/30120-83-2 2,4-Dichlorophenol ND 2480 2140 86 2450 2090 85 2 44-121/32105-67-9 2,4-Dimethylphenol ND 2480 1590 64 2450 1580 64 1 41-122/3151-28-5 2,4-Dinitrophenol ND 2480 2260 91 2450 2280 93 1 10-116/42100-02-7 4-Nitrophenol ND 2480 1620 65 2450 1630 67 1 31-127/3787-86-5 Pentachlorophenol ND 2480 2300 93 2450 2450 100 6 28-113/37108-95-2 Phenol ND 2480 2190 88 2450 2100 86 4 44-113/3358-90-2 2,3,4,6-Tetrachlorophenol ND 2480 2430 98 2450 2470 101 2 38-122/3495-95-4 2,4,5-Trichlorophenol ND 2480 2240 90 2450 2200 90 2 46-118/3388-06-2 2,4,6-Trichlorophenol ND 2480 2050 83 2450 2040 83 0 50-112/3283-32-9 Acenaphthene ND 2480 2000 81 2450 1950 80 3 41-115/32208-96-8 Acenaphthylene ND 2480 1990 80 2450 1930 79 3 47-113/3162-53-3 Aniline ND 2480 1790 72 2450 1690 69 6 35-120/30120-12-7 Anthracene ND 2480 1980 80 2450 2020 82 2 48-111/3656-55-3 Benzo(a)anthracene ND 2480 2650 107* a 2450 2720 111* a 3 47-106/3350-32-8 Benzo(a)pyrene ND 2480 2250 91 2450 2320 95 3 49-115/32205-99-2 Benzo(b)fluoranthene ND 2480 2260 91 2450 2350 96 4 45-114/3592-52-4 1,1' -Biphenyl ND 2480 1870 76 2450 1810 74 3 48-109/33207-08-9 Benzo(k)fluoranthene ND 2480 2240 90 2450 2310 94 3 47-114/2485-68-7 Butyl Benzyl Phthalate ND 2480 1860 75 2450 1930 79 4 43-123/35106-47-8 4-Chloroaniline ND 2480 1410 57 2450 1360 55 4 40-122/39111-44-4 bis(2-Chloroethyl)ether ND 2480 2250 91 2450 2180 89 3 39-117/37108-60-1 2,2' -Oxybis(1-chloropropane) ND 2480 1940 78 2450 1890 77 3 30-118/3191-58-7 2-Chloronaphthalene ND 2480 1910 77 2450 1840 75 4 50-108/33218-01-9 Chrysene ND 2480 2120 86 2450 2160 88 2 47-109/3553-70-3 Dibenzo(a,h)anthracene ND 2480 2390 97 2450 2520 103 5 48-112/23132-64-9 Dibenzofuran ND 2480 2110 85 2450 2060 84 2 47-110/3591-94-1 3,3' -Dichlorobenzidine ND 2480 2130 86 2450 2230 91 5 32-124/4184-66-2 Diethyl Phthalate ND 2480 1860 75 2450 1880 77 1 52-110/34131-11-3 Dimethyl Phthalate ND 2480 1940 78 2450 1950 80 1 52-108/34117-84-0 Di-n-octyl Phthalate ND 2480 1650 67 2450 1700 69 3 43-120/2799-65-0 1,3-Dinitrobenzene ND 2480 2030 82 2450 2080 85 2 51-116/38121-14-2 2,4-Dinitrotoluene ND 2480 1930 78 2450 1960 80 2 46-122/36606-20-2 2,6-Dinitrotoluene ND 2480 2030 82 2450 2030 83 0 50-117/35117-81-7 bis(2-Ethylhexyl)phthalate ND 2480 2070 84 2450 2130 87 3 45-119/28206-44-0 Fluoranthene ND 2480 2260 91 2450 2330 95 3 47-118/34


201 of 283

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66.3.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15346-MS C0051403.D 1 10/15/19 AA 10/11/19 OP15346 EC2049OP15346-MSD C0051404.D 1 10/15/19 AA 10/11/19 OP15346 EC2049LA58267-4 C0051405.D 1 10/15/19 AA 10/11/19 OP15346 EC2049




86-73-7 Fluorene ND 2480 2150 87 2450 2090 85 3 37-121/33118-74-1 Hexachlorobenzene ND 2480 2830 114* a 2450 2860 117* a 1 49-111/3887-68-3 Hexachlorobutadiene ND 2480 2530 102 2450 2480 101 2 45-112/3377-47-4 Hexachlorocyclopentadiene ND 2480 2230 90 2450 2200 90 1 17-125/35193-39-5 Indeno(1,2,3-cd)pyrene ND 2480 2420 98 2450 2490 102 3 47-113/3178-59-1 Isophorone ND 2480 1960 79 2450 1930 79 2 41-125/3491-57-6 2-Methylnaphthalene ND 2480 1970 80 2450 1940 79 2 44-117/3891-20-3 Naphthalene ND 2480 1910 77 2450 1860 76 3 34-125/3788-74-4 2-Nitroaniline ND 2480 1800 73 2450 1800 73 0 51-116/3399-09-2 3-Nitroaniline ND 2480 1810 73 2450 1810 74 0 48-117/32100-01-6 4-Nitroaniline ND 2480 1590 64 2450 1630 67 2 43-120/3498-95-3 Nitrobenzene ND 2480 1940 78 2450 1910 78 2 39-124/32621-64-7 N-Nitroso-di-n-propylamine ND 2480 1950 79 2450 1920 78 2 36-127/3286-30-6 N-Nitrosodiphenylamine ND 2480 1850 75 2450 1880 77 2 50-112/3485-01-8 Phenanthrene ND 2480 2010 81 2450 2050 84 2 43-111/41129-00-0 Pyrene ND 2480 2020 82 2450 2070 84 2 42-120/3895-94-3 1,2,4,5-Tetrachlorobenzene ND 2480 2370 96 2450 2340 95 1 48-108/33120-82-1 1,2,4-Trichlorobenzene ND 2480 2210 89 2450 2160 88 2 44-113/32


367-12-4 2-Fluorophenol 69% 67% 69% 25-109%4165-62-2 Phenol-d5 73% 73% 70% 30-110%118-79-6 2,4,6-Tribromophenol 98% 104% 92% 27-127%4165-60-0 Nitrobenzene-d5 80% 80% 75% 24-123%321-60-8 2-Fluorobiphenyl 80% 79% 75% 32-112%1718-51-0 Terphenyl-d14 98% 103% 94% 41-115%

(a) Outside control limits.


202 of 283

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66.3.1


GC Volatiles

QC Data Summaries



Scott, LASection 7

203 of 283

LA58267

7


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLA2711-MB2 LA346354.D 1 10/07/19 NN n/a n/a GLA2711

The QC reported here applies to the following samples: Method: SW846 8015C

LA58267-20





204 of 283

LA58267

77.1.1




LA58267-1, LA58267-2, LA58267-3, LA58267-5, LA58267-6





205 of 283

LA58267

77.1.2




LA58267-4, LA58267-7, LA58267-8, LA58267-9, LA58267-12, LA58267-13, LA58267-14, LA58267-15, LA58267-18,LA58267-19





206 of 283

LA58267

77.1.3




LA58267-11, LA58267-17





207 of 283

LA58267

77.1.4




LA58267-16





208 of 283

LA58267

77.1.5




LA58267-10





209 of 283

LA58267

77.1.6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLA2711-BS1 LA346344.D 1 10/07/19 NN n/a n/a GLA2711GLA2711-BSD1 LA346346.D 1 10/07/19 NN n/a n/a GLA2711


LA58267-20

Spike BSP BSP BSD BSD LimitsCAS No. Compound mg/l mg/l % mg/l % RPD Rec/RPD

TPH-GRO (C6-C10) 1 0.984 98 0.999 100 2 81-119/10


460-00-4 4-Bromofluorobenzene 93% 92% 80-132%540-36-3 1,4-Difluorobenzene 93% 92% 66-136%


210 of 283

LA58267

77.2.1




LA58267-1, LA58267-2, LA58267-3, LA58267-5, LA58267-6

Spike BSP BSP BSD BSD LimitsCAS No. Compound mg/kg mg/kg % mg/kg % RPD Rec/RPD

TPH-GRO (C6-C10) 50 42.6 85 41.6 83 2 79-121/6




211 of 283

LA58267

77.2.2






TPH-GRO (C6-C10) 50 46.9 94 48.0 96 2 79-121/6




212 of 283

LA58267

77.2.3




LA58267-11, LA58267-17


TPH-GRO (C6-C10) 50 49.0 98 48.7 97 1 79-121/6




213 of 283

LA58267

77.2.4




LA58267-16


TPH-GRO (C6-C10) 50 45.2 90 46.6 93 3 79-121/6




214 of 283

LA58267

77.2.5




LA58267-10


TPH-GRO (C6-C10) 50 45.4 91 45.3 91 0 79-121/6




215 of 283

LA58267

77.2.6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58166-3MS LA346376.D 2 10/07/19 NN n/a n/a GLA2711LA58166-3MSD LA346378.D 2 10/07/19 NN n/a n/a GLA2711LA58166-3 LA346366.D 1 10/07/19 NN n/a n/a GLA2711


LA58267-20

LA58166-3 Spike MS MS Spike MSD MSD LimitsCAS No. Compound mg/l Q mg/l mg/l % mg/l mg/l % RPD Rec/RPD

TPH-GRO (C6-C10) ND 2 1.82 91 2 1.81 91 1 40-149/10


460-00-4 4-Bromofluorobenzene 91% 93% 91% 80-132%540-36-3 1,4-Difluorobenzene 90% 91% 89% 66-136%


216 of 283

LA58267

77.3.1




LA58267-1, LA58267-2, LA58267-3, LA58267-5, LA58267-6

LA58186-4 Spike MS MS Spike MSD MSD LimitsCAS No. Compound mg/kg Q mg/kg mg/kg % mg/kg mg/kg % RPD Rec/RPD

TPH-GRO (C6-C10) ND 100 78.9 79 100 78.0 78* a 1 79-121/6



(a) Outside control limits due to matrix interference. Blank Spike meets acceptance criteria.


217 of 283

LA58267

77.3.2






TPH-GRO (C6-C10) ND 48.1 31.3 65* a 48.1 29.9 62* a 5 79-121/6





218 of 283

LA58267

77.3.3




LA58267-11, LA58267-17


TPH-GRO (C6-C10) ND 47.2 40.6 86 47.2 40.6 86 0 79-121/6




219 of 283

LA58267

77.3.4


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58267-10MS LA347233.D 1 10/16/19 NN n/a n/a GLA2727LA58267-10MSD LA347235.D 1 10/16/19 NN n/a n/a GLA2727LA58267-10 a LA347231.D 1 10/16/19 NN n/a n/a GLA2727


LA58267-16


TPH-GRO (C6-C10) 32.3 500 438 81 500 433 80 1 79-121/6





220 of 283

LA58267

77.3.5




LA58267-10


TPH-GRO (C6-C10) ND 51 48.9 96 51 48.5 95 1 79-121/6




221 of 283

LA58267

77.3.6


GC/LC Semi-volatiles

QC Data Summaries



Scott, LASection 8

222 of 283

LA58267

8


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15348-MB LG001426.D 1 10/14/19 PC 10/11/19 OP15348 GLG887


LA58267-19




84-15-1 o-Terphenyl 64% 31-127%

223 of 283

LA58267

88.1.1




LA58267-1, LA58267-2, LA58267-3, LA58267-4, LA58267-5, LA58267-6, LA58267-7, LA58267-8, LA58267-9,LA58267-10, LA58267-11, LA58267-12, LA58267-13, LA58267-14, LA58267-15, LA58267-16, LA58267-17, LA58267-18


TPH-DRO (C10-C28) 0.555 5.0 mg/kg JTPH-ORO (C28-C35) ND 5.0 mg/kg


84-15-1 o-Terphenyl 66% 31-127%

224 of 283

LA58267

88.1.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15370-MB GLH026470.D 1 10/16/19 PC 10/15/19 OP15370 GLH567


LA58267-20


TPH-DRO (C10-C28) 0.0451 0.056 mg/l JTPH-ORO (C28-C35) ND 0.056 mg/l


84-15-1 o-Terphenyl 96% 40-118%

225 of 283

LA58267

88.1.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15348-BS1 LG001427.D 1 10/14/19 PC 10/11/19 OP15348 GLG887OP15348-BSD1 LG001428.D 1 10/14/19 PC 10/11/19 OP15348 GLG887


LA58267-19


TPH-DRO (C10-C28) 148 106 72 110 74 4 49-118/19


84-15-1 o-Terphenyl 69% 71% 31-127%


226 of 283

LA58267

88.2.1




LA58267-19


TPH-ORO (C28-C35) 59.1 37.3 63 40.9 69 9 52-102/16


84-15-1 o-Terphenyl 72% 75% 31-127%


227 of 283

LA58267

88.2.2






TPH-DRO (C10-C28) 150 107 71 107 72 0 49-118/19


84-15-1 o-Terphenyl 70% 68% 31-127%


228 of 283

LA58267

88.2.3






TPH-ORO (C28-C35) 59.4 38.0 64 36.6 61 4 52-102/16


84-15-1 o-Terphenyl 71% 70% 31-127%


229 of 283

LA58267

88.2.4


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15370-BS1 GLH026471.D 1 10/16/19 PC 10/15/19 OP15370 GLH567OP15370-BSD1 GLH026472.D 1 10/16/19 PC 10/15/19 OP15370 GLH567


LA58267-20


TPH-DRO (C10-C28) 11.1 9.40 85 9.87 89 5 72-112/18


84-15-1 o-Terphenyl 95% 99% 40-118%


230 of 283

LA58267

88.2.5




LA58267-20


TPH-ORO (C28-C35) 4.48 8.15 182* a 8.10 182* a 1 60-112/18


84-15-1 o-Terphenyl 95% 94% 40-118%

(a) Outside control limits biased high. Sample ND.


231 of 283

LA58267

88.2.6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15347-MS1 LG001445.D 1 10/14/19 PC 10/11/19 OP15347 GLG887OP15347-MSD1 LG001446.D 1 10/14/19 PC 10/11/19 OP15347 GLG887LA58267-4 LG001457.D 1 10/14/19 PC 10/11/19 OP15347 GLG887




TPH-DRO (C10-C28) ND 150 98.5 66 149 111 74 12 23-150/28


84-15-1 o-Terphenyl 68% 74% 66% 31-127%


232 of 283

LA58267

88.3.1






TPH-ORO (C28-C35) ND 59.4 38.3 64 60 38.9 65 2 16-142/35


84-15-1 o-Terphenyl 76% 77% 66% 31-127%


233 of 283

LA58267

88.3.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15370-MS1 GLH026475.D 1 10/16/19 PC 10/15/19 OP15370 GLH567OP15370-MSD1 GLH026476.D 1 10/16/19 PC 10/15/19 OP15370 GLH567LA58344-14 GLH026490.D 1 10/16/19 PC 10/15/19 OP15370 GLH567


LA58267-20


TPH-DRO (C10-C28) ND 11.2 9.66 86 11 9.34 85 3 41-136/29


84-15-1 o-Terphenyl 95% 94% 98% 40-118%


234 of 283

LA58267

88.3.3




LA58267-20


TPH-ORO (C28-C35) ND 4.49 17.4 194* a 4.44 8.26 186* b 4 c 20-135/18


84-15-1 o-Terphenyl 104% 101% 98% 40-118%

(a) Outside control limits biased high. Sample ND. Recovery corrected for double spike.(b) Outside control limits biased high. Sample ND.(c) RPD corrected for double spike.


235 of 283

LA58267

88.3.4


Metals Analysis

QC Data Summaries


• Method Blank Summaries• Matrix Spike and Duplicate Summaries• Blank Spike and Lab Control Sample Summaries• Serial Dilution Summaries

Scott, LASection 9

236 of 283

LA58267

9

BLANK RESULTS SUMMARY Part 2 - Method Blanks

Login Number: LA58267 Account: PROVLABR - Providence Engineering & Environmental


QC Batch ID: MP16530 Methods: SW846 6020A Matrix Type: SOLID Units: mg/kg

Prep Date: 10/07/19

MB

10/07/19

Metal RL IDL MDL raw final

Aluminum 10 .14 5.2

Antimony 0.10 .00063 .094 -0.0039 <0.10

Arsenic 0.10 .0062 .042 -0.0066 <0.10

Barium 0.10 .00089 .046 -0.0047 <0.10

Beryllium 0.10 .00096 .045 -0.025 <0.10

Boron 2.0 .15 .16

Cadmium 0.050 .00081 .033 -0.0015 <0.050

Calcium 10 .47 3.7

Cerium 0.10 .00019 .057

Chromium 0.10 .0059 .043 -0.0025 <0.10

Cobalt 0.10 .00082 .046 -0.0069 <0.10

Copper 0.10 .027 .048 -0.019 <0.10

Iron 10 .28 4.1

Lanthanum 0.10 .00019 .042

Lithium 0.20 .03 .052

Lead 0.10 .00045 .046 -0.013 <0.10

Magnesium 10 .11 1.5

Manganese 0.10 .01 .046

Molybdenum 0.10 .019 .061

Nickel 0.10 .0081 .036 -0.039 <0.10

Potassium 10 .5 4

Selenium 0.50 .03 .17 -0.019 <0.50

Silver 0.10 .00088 .033 -0.0013 <0.10

Silicon 50 .76 12

Sodium 10 .86 3.2

Strontium 0.10 .0063 .042

Thallium 0.10 .003 .062 -0.0069 <0.10

Tin 0.50 .0059 .19

Titanium 0.20 .0095 .15

Vanadium 0.10 .0035 .04 0.0019 <0.10

Uranium 0.10 .00019 .047

Zinc 0.50 .15 .13 0.00024 <0.50

Associated samples MP16530: LA58267-1, LA58267-2, LA58267-3, LA58267-4, LA58267-5, LA58267-6, LA58267-7,LA58267-8, LA58267-9, LA58267-10, LA58267-11, LA58267-12, LA58267-13, LA58267-14, LA58267-15, LA58267-16,_________________________________________________________________________________________________________

Page 1

237 of 283

LA58267

99.1.1





Prep Date: 10/07/19

MB

10/07/19


LA58267-17, LA58267-18, LA58267-19

Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 2

238 of 283

LA58267

99.1.1

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY




Prep Date: 10/07/19

LA58267-4 Spikelot

10/07/19

QCMetal Original MS MPICPMS6 % Rec Limits

Aluminum

Antimony 0.31 5.7 10 53.9N(a) 75-125

Arsenic 9.8 18.8 10 90.0 75-125

Barium 153 166 10 130.0(b) 75-125

Beryllium 0.62 10.7 10 100.8 75-125

Boron

Cadmium 0.089 10.2 10 101.1 75-125

Calcium

Cerium

Chromium 15.6 26.9 10 113.0 75-125

Cobalt 9.0 18.5 10 95.0 75-125

Copper 14.4 23.4 10 90.0 75-125

Iron

Lanthanum

Lithium

Lead 14.0 24.0 10 100.0 75-125

Magnesium

Manganese

Molybdenum

Nickel 18.7 27.3 10 86.0 75-125

Potassium

Selenium 3.4 42.5 50 78.2 75-125

Silver 0.018 7.6 10 75.8 75-125

Silicon

Sodium

Strontium

Thallium 0.38 10.6 10 102.2 75-125

Tin

Titanium

Vanadium 33.7 44.3 10 106.0 75-125

Uranium

Zinc 49.5 57.0 10 75.0 75-125


Page 1

239 of 283

LA58267

99.1.2





Prep Date: 10/07/19

LA58267-4 Spikelot

10/07/19


LA58267-17, LA58267-18, LA58267-19

Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Spike recovery indicates possible matrix interference or sample non-homogeneity.(b) Spike amount low relative to the sample amount. Refer to lab control or spike blank for recovery

information.

_________________________________________________________________________________________________________

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240 of 283

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Prep Date: 10/07/19

LA58267-4 Spikelot

10/07/19

MSD QCMetal Original MSD MPICPMS6 % Rec RPD Limit

Aluminum

Antimony 0.31 6.1 10 57.9N(a) 6.8 20

Arsenic 9.8 18.4 10 86.0 2.2 20

Barium 153 169 10 160.0(b) 1.8 20

Beryllium 0.62 10.7 10 100.8 0.0 20

Boron

Cadmium 0.089 10.4 10 103.1 1.9 20

Calcium

Cerium

Chromium 15.6 25.0 10 94.0 7.3 20

Cobalt 9.0 18.3 10 93.0 1.1 20

Copper 14.4 22.7 10 83.0 3.0 20

Iron

Lanthanum

Lithium

Lead 14.0 24.9 10 109.0 3.7 20

Magnesium

Manganese

Molybdenum

Nickel 18.7 27.4 10 87.0 0.4 20

Potassium

Selenium 3.4 41.8 50 76.8 1.7 20

Silver 0.018 7.7 10 76.8 1.3 20

Silicon

Sodium

Strontium

Thallium 0.38 10.7 10 103.2 0.9 20

Tin

Titanium

Vanadium 33.7 43.8 10 101.0 1.1 20

Uranium

Zinc 49.5 57.1 10 76.0 0.2 20


Page 3

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Prep Date: 10/07/19

LA58267-4 Spikelot

10/07/19


LA58267-17, LA58267-18, LA58267-19


information.

_________________________________________________________________________________________________________

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242 of 283

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99.1.2

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY




Prep Date: 10/07/19

LCS Spikelot

10/07/19

QCMetal Result LCSMETAL11% Rec Limits

Aluminum

Antimony 39.7 40 99.3 22-208

Arsenic 108 125 86.4 82-117

Barium 580 529 109.6 82-119

Beryllium 144 155 92.9 83-117

Boron

Cadmium 37.0 37.7 98.1 82-118

Calcium

Cerium

Chromium 53.6 58.3 91.9 82-118

Cobalt 186 196 94.9 84-117

Copper 66.6 78 85.4 84-116

Iron

Lanthanum

Lithium

Lead 101 111 91.0 82-117

Magnesium

Manganese

Molybdenum

Nickel 309 333 92.8 83-117

Potassium

Selenium 233 251 92.8 79-122

Silver 24.0 27.2 88.2 79-121

Silicon

Sodium

Strontium

Thallium 230 241 95.4 80-119

Tin

Titanium

Vanadium 114 125 91.2 79-121

Uranium

Zinc 317 351 90.3 80-119


Page 1

243 of 283

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99.1.3





Prep Date: 10/07/19

LCS Spikelot

10/07/19

QCMetal Result LCSMETAL11% Rec Limits

LA58267-17, LA58267-18, LA58267-19


_________________________________________________________________________________________________________

Page 2

244 of 283

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99.1.3

SERIAL DILUTION RESULTS SUMMARY



QC Batch ID: MP16530 Methods: SW846 6020A Matrix Type: SOLID Units: ug/l

Prep Date: 10/07/19

LA58267-4

10/07/19

QCMetal Original SDL 5:25 %DIF Limits

Aluminum

Antimony 3.14 1.47 53.2*(a) 0-10

Arsenic 97.6 95.9 1.7 0-10

Barium 1530 1270 17.5*(a) 0-10

Beryllium 6.15 0.00 100.0*(a 0-10

Boron

Cadmium 0.887 0.394 55.6 (b) 0-10

Calcium

Cerium

Chromium 156 133 15.3*(a) 0-10

Cobalt 90.2 77.7 13.9*(a) 0-10

Copper 144 132 7.9 0-10

Iron

Lanthanum

Lithium

Lead 140 118 15.9*(a) 0-10

Magnesium

Manganese

Molybdenum

Nickel 187 163 12.8*(a) 0-10

Potassium

Selenium 33.6 38.0 13.1 (b) 0-10

Silver 0.176 0.00 100.0(b) 0-10

Silicon

Sodium

Strontium

Thallium 3.81 2.93 22.9 (b) 0-10

Tin

Titanium

Vanadium 337 289 14.2*(a) 0-10

Uranium

Zinc 495 471 4.7 0-10


Page 1

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99.1.4





Prep Date: 10/07/19

LA58267-4

10/07/19


LA58267-17, LA58267-18, LA58267-19

Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Serial dilution indicates possible matrix interference.(b) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).

_________________________________________________________________________________________________________

Page 2

246 of 283

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99.1.4

POST DIGESTATE SPIKE SUMMARY




Prep Date: 10/07/19

Sample Final LA58267-4 PS Spike Spike Spike

10/07/19

QCMetal ml ml Raw Corr.** ug/l ml ug/ml ug/l % Rec Limits

Aluminum

Antimony 0.4 10 3.14 .1256 87.92 0.1 10 100 87.8 75-125

Boron

Calcium

Cerium

Iron

Lanthanum

Lithium

Magnesium

Manganese

Molybdenum

Potassium

Silicon

Sodium

Strontium

Tin

Titanium

Uranium

Associated samples MP16530: LA58267-1, LA58267-2, LA58267-3, LA58267-4, LA58267-5, LA58267-6, LA58267-7,LA58267-8, LA58267-9, LA58267-10, LA58267-11, LA58267-12, LA58267-13, LA58267-14, LA58267-15, LA58267-16,LA58267-17, LA58267-18, LA58267-19

Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(**) Corr. sample result = Raw * (sample volume / final volume)(anr) Analyte not requested

_________________________________________________________________________________________________________

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99.1.5




QC Batch ID: MP16531 Methods: SW846 7470A Matrix Type: AQUEOUS Units: ug/l

Prep Date: 10/07/19

MB

10/07/19


Mercury 0.20 .056 .081 0.0075 <0.20

Associated samples MP16531: LA58267-20


_________________________________________________________________________________________________________

Page 1

248 of 283

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99.2.1





Prep Date: 10/07/19

TD45655-1 Spikelot

10/07/19

QCMetal Original MS HGSPIKE1 % Rec Limits

Mercury 0.0 4.6 5 92.0 75-125


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 1

249 of 283

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99.2.2





Prep Date: 10/07/19

TD45655-1 Spikelot

10/07/19

MSD QCMetal Original MSD HGSPIKE1 % Rec RPD Limit

Mercury 0.0 4.7 5 94.0 2.2 20



_________________________________________________________________________________________________________

Page 2

250 of 283

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99.2.2





Prep Date: 10/07/19

BSP Spikelot

10/07/19

QCMetal Result HGSPIKE1 % Rec Limits

Mercury 4.6 5 92.0 80-120



_________________________________________________________________________________________________________

Page 1

251 of 283

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99.2.3





Prep Date: 10/07/19

TD45655-1

10/07/19


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

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99.2.4




QC Batch ID: MP16534 Methods: SW846 7471B Matrix Type: SOLID Units: mg/kg

Prep Date: 10/07/19

MB

10/07/19


Mercury 0.080 .0039 .0066 0.0070 <0.080



_________________________________________________________________________________________________________

Page 1

253 of 283

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99.3.1





Prep Date: 10/07/19

LA58267-4 Spikelot

10/07/19


Mercury 0.0 0.54 0.536 100.8 75-125



_________________________________________________________________________________________________________

Page 1

254 of 283

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99.3.2





Prep Date: 10/07/19

LA58267-4 Spikelot

10/07/19


Mercury 0.0 0.54 0.556 97.2 0.0 20



_________________________________________________________________________________________________________

Page 2

255 of 283

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99.3.2





Prep Date: 10/07/19

LCS Spikelot

10/07/19

QCMetal Result HGLCS10 % Rec Limits

Mercury 18.7 20.3 92.1 64-136



_________________________________________________________________________________________________________

Page 1

256 of 283

LA58267

99.3.3




QC Batch ID: MP16534 Methods: SW846 7471B Matrix Type: SOLID Units: ug/l

Prep Date: 10/07/19

LA58267-4

10/07/19


Mercury 0.00 0.267 NC 0-



_________________________________________________________________________________________________________

Page 1

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99.3.4





Prep Date: 10/08/19

MB

10/08/19


Aluminum 100 1.4 9.3

Antimony 1.0 .0063 .34 0.093 <1.0

Arsenic 1.0 .062 .26 -0.095 <1.0

Barium 1.0 .0089 .46 0.075 <1.0

Beryllium 1.0 .0096 .28 -0.25 <1.0

Boron 20 1.5 2.9

Cadmium 0.50 .0081 .12 -0.11 <0.50

Calcium 100 4.7 20

Cerium 1.0 .0019 .16

Chromium 1.0 .059 .15 -0.0072 <1.0

Cobalt 1.0 .0082 .14 -0.25 <1.0

Copper 1.0 .27 .74 -0.30 <1.0

Iron 100 2.8 16

Lanthanum 1.0 .0019 .41

Lithium 2.0 .3 .61

Lead 1.0 .0045 .13 -0.14 <1.0

Magnesium 100 1.1 11

Manganese 2.0 .1 .53


Nickel 1.0 .081 .2 -0.47 <1.0

Potassium 100 5 7.6

Selenium 5.0 .3 3.1 -0.59 <5.0

Silver 1.0 .0088 .13 -0.099 <1.0

Silicon 500 7.6 130

Sodium 100 8.6 9.9

Strontium 2.0 .063 .27

Thallium 1.0 .03 .86 -0.23 <1.0

Tin 2.0 .059 .19

Titanium 1.0 .095 .77

Uranium 1.0 .0019 .17

Vanadium 1.0 .035 .1 -0.047 <1.0

Zinc 5.0 1.5 1.1 1.8 <5.0


_________________________________________________________________________________________________________

Page 1

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99.4.1





Prep Date: 10/08/19

MB

10/08/19



_________________________________________________________________________________________________________

Page 2

259 of 283

LA58267

99.4.1





Prep Date: 10/08/19

LA58267-20 Spikelot

10/08/19


Aluminum

Antimony 0.067 94.7 100 94.6 75-125

Arsenic 0.0 90.4 100 90.4 75-125

Barium 0.15 93.7 100 93.6 75-125

Beryllium 0.0 97.8 100 97.8 75-125

Boron

Cadmium 0.0 95.3 100 95.3 75-125

Calcium

Cerium

Chromium 0.17 98.9 100 98.7 75-125

Cobalt 0.0 96.8 100 96.8 75-125

Copper 0.50 95.7 100 95.2 75-125

Iron anr

Lanthanum

Lithium

Lead 0.0 95.5 100 95.5 75-125

Magnesium

Manganese

Molybdenum

Nickel 0.0 88.3 100 88.3 75-125

Potassium

Selenium 0.0 436 500 87.2 75-125

Silver 0.0 99.4 100 99.4 75-125

Silicon

Sodium anr

Strontium

Thallium 0.0 96.0 100 96.0 75-125

Tin

Titanium

Uranium

Vanadium 0.0 95.6 100 95.6 75-125

Zinc 4.4 91.6 100 87.2 75-125


_________________________________________________________________________________________________________

Page 1

260 of 283

LA58267

99.4.2





Prep Date: 10/08/19

LA58267-20 Spikelot

10/08/19



_________________________________________________________________________________________________________

Page 2

261 of 283

LA58267

99.4.2





Prep Date: 10/08/19

LA58267-20 Spikelot

10/08/19


Aluminum

Antimony 0.067 93.4 100 93.3 1.4 20

Arsenic 0.0 91.6 100 91.6 1.3 20

Barium 0.15 92.5 100 92.4 1.3 20

Beryllium 0.0 98.8 100 98.8 1.0 20

Boron

Cadmium 0.0 96.9 100 96.9 1.7 20

Calcium

Cerium

Chromium 0.17 101 100 100.8 2.1 20

Cobalt 0.0 99.4 100 99.4 2.7 20

Copper 0.50 98.1 100 97.6 2.5 20

Iron anr

Lanthanum

Lithium

Lead 0.0 95.2 100 95.2 0.3 20

Magnesium

Manganese

Molybdenum

Nickel 0.0 90.1 100 90.1 2.0 20

Potassium

Selenium 0.0 445 500 89.0 2.0 20

Silver 0.0 100 100 100.0 0.6 20

Silicon

Sodium anr

Strontium

Thallium 0.0 99.7 100 99.7 3.8 20

Tin

Titanium

Uranium

Vanadium 0.0 98.1 100 98.1 2.6 20

Zinc 4.4 92.1 100 87.7 0.5 20


_________________________________________________________________________________________________________

Page 3

262 of 283

LA58267

99.4.2





Prep Date: 10/08/19

LA58267-20 Spikelot

10/08/19



_________________________________________________________________________________________________________

Page 4

263 of 283

LA58267

99.4.2





Prep Date: 10/08/19

BSP Spikelot

10/08/19

QCMetal Result MPICPMS6 % Rec Limits

Aluminum

Antimony 97.4 100 97.4 80-120

Arsenic 91.8 100 91.8 80-120

Barium 96.5 100 96.5 80-120

Beryllium 98.6 100 98.6 80-120

Boron

Cadmium 97.0 100 97.0 80-120

Calcium

Cerium

Chromium 100 100 100.0 80-120

Cobalt 99.9 100 99.9 80-120

Copper 97.6 100 97.6 80-120

Iron anr

Lanthanum

Lithium

Lead 98.6 100 98.6 80-120

Magnesium

Manganese

Molybdenum

Nickel 89.9 100 89.9 80-120

Potassium

Selenium 444 500 88.8 80-120

Silver 101 100 101.0 80-120

Silicon

Sodium anr

Strontium

Thallium 98.8 100 98.8 80-120

Tin

Titanium

Uranium

Vanadium 97.8 100 97.8 80-120

Zinc 93.9 100 93.9 80-120


_________________________________________________________________________________________________________

Page 1

264 of 283

LA58267

99.4.3





Prep Date: 10/08/19

BSP Spikelot

10/08/19



_________________________________________________________________________________________________________

Page 2

265 of 283

LA58267

99.4.3





Prep Date: 10/08/19

LA58267-20

10/08/19


Aluminum

Antimony 0.0675 0.212 214.8(a) 0-10

Arsenic 0.00 0.00 NC 0-10

Barium 0.148 0.322 116.9(a) 0-10

Beryllium 0.00 0.00 NC 0-10

Boron

Cadmium 0.00 0.00 NC 0-10

Calcium

Cerium

Chromium 0.172 0.00 100.0(a) 0-10

Cobalt 0.00 0.00 NC 0-10

Copper 0.496 0.00 100.0(a) 0-10

Iron anr

Lanthanum

Lithium

Lead 0.00 0.00 NC 0-10

Magnesium

Manganese

Molybdenum

Nickel 0.00 0.00 NC 0-10

Potassium

Selenium 0.00 0.00 NC 0-10

Silver 0.00 0.00 NC 0-10

Silicon

Sodium anr

Strontium

Thallium 0.00 0.00 NC 0-10

Tin

Titanium

Uranium

Vanadium 0.00 0.00 NC 0-10

Zinc 4.44 0.00 100.0(a) 0-10


_________________________________________________________________________________________________________

Page 1

266 of 283

LA58267

99.4.4





Prep Date: 10/08/19

LA58267-20

10/08/19


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).

_________________________________________________________________________________________________________

Page 2

267 of 283

LA58267

99.4.4




QC Batch ID: MP16691 Methods: SW846 6020A Matrix Type: LEACHATE Units: mg/l

Prep Date: 10/22/19

MB

10/22/19


Aluminum 0.10 .0014 .018

Antimony 0.0010 .0000063 .00025

Arsenic 0.0010 .000062 .00024 0.000099 <0.0010

Barium 0.0010 .0000089 .00059

Beryllium 0.0010 .0000096 .000085

Boron 0.020 .0015 .0015

Cadmium 0.00050 .0000081 .00015

Calcium 0.10 .0047 .026

Cerium 0.0010 .0000019 .00011

Chromium 0.0010 .000059 .00019

Cobalt 0.0010 .0000082 .00016

Copper 0.0010 .00027 .00019

Iron 0.10 .0028 .022

Lithium 0.0020 .0003 .000061

Lead 0.0010 .0000045 .000042

Magnesium 0.10 .0011 .011

Manganese 0.0010 .0001 .00028

Molybdenum 0.0010 .00019 .00028

Nickel 0.0010 .000081 .00074

Potassium 0.10 .005 .011

Selenium 0.0050 .0003 .0023

Silver 0.0010 .0000088 .00046

Sodium 0.10 .0086 .059

Strontium 0.0010 .000063 .00016

Thallium 0.0010 .00003 .00043

Tin 0.0010 .000059 .00024

Titanium 0.0010 .000095 .00083

Uranium 0.0010 .0000019 .00012

Vanadium 0.0010 .000035 .00036

Zinc 0.0060 .0015 .0016

Associated samples MP16691: LA58267-15A


_________________________________________________________________________________________________________

Page 1

268 of 283

LA58267

99.5.1





Prep Date: 10/22/19 10/22/19

LA58133-7A

10/22/19

QC LA58133-7A Spikelot

10/22/19

QCMetal Original DUP RPD Limits Original MS MPICPMS6 % Rec Limits

Aluminum

Antimony

Arsenic 0.00089 0.00080 10.7 0-20 0.00089 0.086 0.10 85.1 75-125

Barium anr

Beryllium

Boron

Cadmium

Calcium

Cerium

Chromium

Cobalt

Copper

Iron

Lithium

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium anr

Tin

Titanium

Uranium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested_________________________________________________________________________________________________________

Page 1

269 of 283

LA58267

99.5.2





Prep Date: 10/22/19

BSP Spikelot

10/22/19


Aluminum

Antimony

Arsenic 0.083 0.10 83.0 80-120

Barium anr

Beryllium

Boron

Cadmium

Calcium

Cerium

Chromium

Cobalt

Copper

Iron

Lithium

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium anr

Tin

Titanium

Uranium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

270 of 283

LA58267

99.5.3




QC Batch ID: MP16691 Methods: SW846 6020A Matrix Type: LEACHATE Units: ug/l

Prep Date: 10/22/19

LA58133-7A

10/22/19


Aluminum

Antimony

Arsenic 0.886 1.30 47.2 (a) 0-10

Barium anr

Beryllium

Boron

Cadmium

Calcium

Cerium

Chromium

Cobalt

Copper

Iron

Lithium

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium anr

Tin

Titanium

Uranium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL)._________________________________________________________________________________________________________

Page 1

271 of 283

LA58267

99.5.4


General Chemistry

QC Data Summaries


• Method Blank and Blank Spike Summaries• Duplicate Summaries• Matrix Spike Summaries

Scott, LASection 10

272 of 283

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10

METHOD BLANK AND SPIKE RESULTS SUMMARY GENERAL CHEMISTRY



MB Spike BSP BSP QCAnalyte Batch ID RL Result Units Amount Result %Recov Limits

Nitrogen, Nitrate GP7300/GN15790 0.050 0.0 mg/l 2.5 2.38 95.2 90-110% Nitrogen, Nitrite GP7300/GN15790 0.050 0.0 mg/l 2.5 2.36 94.4 90-110%

Associated Samples: Batch GP7300: LA58267-20(*) Outside of QC limits

__________________________________________________________________________________________________________________________

Page 1

273 of 283

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1010.1

MATRIX SPIKE RESULTS SUMMARY GENERAL CHEMISTRY



QC Original Spike MS QCAnalyte Batch ID Sample Units Result Amount Result %Rec Limits

Nitrogen, Nitrate GP7300/GN15790 LA58232-13 mg/l 0.0 2.5 2.4 96.0 80-120%Nitrogen, Nitrite GP7300/GN15790 LA58232-13 mg/l 0.013 2.5 2.4 96.0 80-120%

Associated Samples: Batch GP7300: LA58267-20(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits

__________________________________________________________________________________________________________________________

Page 1

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LA58267

1010.2

MATRIX SPIKE DUPLICATE RESULTS SUMMARY GENERAL CHEMISTRY



QC Original Spike MSD QCAnalyte Batch ID Sample Units Result Amount Result RPD Limit

Nitrogen, Nitrate GP7300/GN15790 LA58232-13 mg/l 0.0 2.5 2.4 0.0 20%Nitrogen, Nitrite GP7300/GN15790 LA58232-13 mg/l 0.013 2.5 2.5 4.1 20%

Associated Samples: Batch GP7300: LA58267-20(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits

__________________________________________________________________________________________________________________________

Page 1

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LA58267

1010.3


Misc. Forms


(SGS Houston, TX)



Scott, LASection 11

276 of 283

LA58267

11


SGS Houston, TX

277 of 283

LA58267

1111.1

Page 1 of 2Job Number: LA58267 Client: SGS LAF

Date / Time Received: 10/7/2019 11:50:00 PM Delv Method:


# of Coolers: 1

Airbill #'s:

Cooler Information1. Custody Seals Present:


4. Cooler temp verification:

3. Temp criteria achieved:

3. Cooler media: Ice (Bag)

Trip Blank Information Y or N

1. Trip Blank present / cooler:




Sample Information Y or N





8. Analysis requested is clear:



12. Special Instructions (compositing/filtering) clear:

Intact

Cooler Temps (Initial/Adjusted): #1: (5.6/5.6);

Therm ID: IR-8; Temp Adjustment Factor: 0;


Number of terracores:

Number of 5035 Field Kits:

Number of Lab Filtered Metals:

Residual Chlorine Test Strip Lot #:

Misc. Information

3. Type Of TB Received W or S N/A

Y or N N/A

6. Dates/Times/IDs on COC match Sample Label

13. Voa Soil Kits/Jars received past 48hrs?

14. % Solids Jar received?15. Residual Chlorine Present?

11. COC Present:

N/A

Test Strip Lot #s: pH 1-12: 10D4281 pH 12+: Other: (Specify)

Comments


278 of 283

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1111.1

Sample Receipt Log

Job #: LA58267 Date / Time Received: 10/7/2019 11:50:00 PM Initials: EC

Client: SGS LAF

Page 2 of 2

Sample ID: Bot #Cooler # Vol Location Pres pH Therm IDTherm

CFCorrected

TempInitialTemp

4oz 2-18 N/P Note #2 - Preservative check not applicable. IR-8 0 5.61 LA58267-19 5.61

A500 M2E H2SO4 pH < 2 IR-8 0 5.61 LA58267-20 5.61


279 of 283

LA58267

1111.1


General Chemistry

QC Data Summaries

(SGS Houston, TX)



Scott, LASection 12

280 of 283

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12


Login Number: LA58267 Account: ALLA - SGS Scott, LA

Project: PROVLABR: Bottle Art Lofts, University & Cameron, Lafayette, LA


Nitrogen, Ammonia GP55101/GN1729 0.10 0.0 mg/l 2 2.12 106.0 90-110% Nitrogen, Ammonia GP55103/GN1729 1.2 0.0 mg/kg 24 23.9 99.6 90-110% Nitrogen, Nitrate GP55117/GN1755 5.0 0.0 mg/kg 100 102 102.0 90-110% Nitrogen, Nitrite GP55117/GN1755 5.0 0.0 mg/kg 100 105 105.0 90-110%

Associated Samples: Batch GP55101: LA58267-20Batch GP55103: LA58267-19Batch GP55117: LA58267-19(*) Outside of QC limits

__________________________________________________________________________________________________________________________

Page 1

281 of 283

LA58267

1212.1

DUPLICATE RESULTS SUMMARY GENERAL CHEMISTRY



QC Original DUP QCAnalyte Batch ID Sample Units Result Result RPD Limits

Nitrogen, Ammonia GP55101/GN1729 LA58267-20 mg/l -0.038 0.0 0.0 0-20%Nitrogen, Ammonia GP55103/GN1729 LA58267-19 mg/kg 8.6 8.5 1.2 0-20%Nitrogen, Nitrate GP55117/GN1755 LA58267-19 mg/kg 5.7 5.8 1.7 0-20%Nitrogen, Nitrite GP55117/GN1755 LA58267-19 mg/kg 0.0 0.0 0.0 0-20%

Associated Samples: Batch GP55101: LA58267-20Batch GP55103: LA58267-19Batch GP55117: LA58267-19(*) Outside of QC limits

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Nitrogen, Ammonia GP55101/GN1729 LA58267-20 mg/l -0.038 2 1.8 90.0 90-110%Nitrogen, Ammonia GP55103/GN1729 LA58267-19 mg/kg 8.6 24 31.4 95.1 90-110%Nitrogen, Nitrate GP55117/GN1755 LA58267-19 mg/kg 5.7 98.4 96.8 92.6 80-120%Nitrogen, Nitrite GP55117/GN1755 LA58267-19 mg/kg 0.0 98.4 98.8 100.4 80-120%

Associated Samples: Batch GP55101: LA58267-20Batch GP55103: LA58267-19Batch GP55117: LA58267-19(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits

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Sampling Date: 10/09/19

Report to:


ATTN: Ashlyn Holmes










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November 7, 2019

Providence Engineering & EnvironmentalATTN: Stephen Osborne1201 Main StreetBaton Rouge, LA 70802


Dear Mr. Osborne,


Dissolved Metals analyses by EPA methods 6020A and 7470A were originally omitted from sample B-7GW due to a laboratory error. The analyses were performed and are included in this revised laboratory report. I apologize for the error and the inconvenience.

Sincerely,


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Sections:


3.1: LA58360-1: B-8GW ..................................................................................................... 113.2: LA58360-1F: B-8GW ................................................................................................... 203.3: LA58360-2: B-7GW ..................................................................................................... 213.4: LA58360-2FR: B-7GW ................................................................................................ 293.5: LA58360-3: B-4GW ..................................................................................................... 303.6: LA58360-4: FB-07 ....................................................................................................... 373.7: LA58360-5: RB-04 ....................................................................................................... 453.8: LA58360-6: D-1 FSW .................................................................................................. 533.9: LA58360-6A: D-1 FSW ............................................................................................... 563.10: LA58360-7: D-1 SWS ................................................................................................ 573.11: LA58360-7A: D-1 SWS ............................................................................................. 603.12: LA58360-8: TRIP BLANK ........................................................................................ 61


Section 5: MS Volatiles - QC Data Summaries ..................................................................... 675.1: Method Blank Summary ................................................................................................ 685.2: Leachate Blank Summary .............................................................................................. 725.3: Blank Spike/Blank Spike Duplicate Summary .............................................................. 735.4: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 78

Section 6: MS Semi-volatiles - QC Data Summaries ............................................................ 836.1: Method Blank Summary ................................................................................................ 846.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 876.3: Matrix Spike Summary .................................................................................................. 90


Section 8: GC/LC Semi-volatiles - QC Data Summaries ..................................................... 1038.1: Method Blank Summary ................................................................................................ 1048.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1078.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 111

Section 9: Metals Analysis - QC Data Summaries ................................................................ 1139.1: Prep QC MP16573: Hg .................................................................................................. 1149.2: Prep QC MP16584: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 1199.3: Prep QC MP16588: As,Ba,Cd,Cr,Pb,Se,Ag .................................................................. 1309.4: Prep QC MP16599: Hg .................................................................................................. 1349.5: Prep QC MP16665: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 1399.6: Prep QC MP16668: Hg .................................................................................................. 1519.7: Prep QC MP16825: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 156

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9.8: Prep QC MP16848: Hg .................................................................................................. 166Section 10: General Chemistry - QC Data Summaries ........................................................ 171

10.1: Method Blank and Spike Results Summary ................................................................ 17210.2: Matrix Spike Results Summary ................................................................................... 17310.3: Matrix Spike Duplicate Results Summary .................................................................. 174



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Sample Summary





LA58360-1 10/09/19 09:20 SO 10/09/19 AQ Ground Water B-8GW

LA58360-1F 10/09/19 09:20 SO 10/09/19 AQ Groundwater Filtered B-8GW



LA58360-2FR 10/09/19 10:05 SO 10/09/19 AQ Groundwater Filtered B-7GW




LA58360-5 10/09/19 11:45 SO 10/09/19 AQ Water RB-04

LA58360-6 10/09/19 11:55 SO 10/09/19 AQ Ground Water D-1 FSW

LA58360-6A 10/09/19 11:55 SO 10/09/19 AQ Ground Water D-1 FSW


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LA58360-7 10/09/19 12:45 SO 10/09/19 SO Soil D-1 SWS

LA58360-7A 10/09/19 12:45 SO 10/09/19 SO Soil D-1 SWS



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LA58360-1 B-8GW

Naphthalene 0.00094 0.00018 mg/l SW846 8270DTPH-GRO (C6-C10) 0.634 0.10 mg/l SW846 8015CAliphatics > C10-C12 (Unadj.) 0.304 0.14 mg/l MADEP EPH REV 1.1TPH-DRO (C10-C28) 0.946 0.14 mg/l SW846 8015CArsenic 0.0895 0.0010 mg/l SW846 6020ABarium 0.858 0.0010 mg/l SW846 6020ACadmium 0.0023 0.00050 mg/l SW846 6020AChromium 0.0203 0.0010 mg/l SW846 6020ACobalt 0.0138 0.0010 mg/l SW846 6020ACopper 0.0308 0.0010 mg/l SW846 6020ALead 0.0213 0.0010 mg/l SW846 6020ANickel 0.0212 0.0010 mg/l SW846 6020AVanadium 0.0415 0.0010 mg/l SW846 6020AZinc 0.0494 0.0050 mg/l SW846 6020A

LA58360-1F B-8GW

Arsenic 0.0690 0.0010 mg/l SW846 6020ABarium 0.420 0.0010 mg/l SW846 6020AChromium 0.0013 0.0010 mg/l SW846 6020ACobalt 0.0053 0.0010 mg/l SW846 6020ALead 0.0034 0.0010 mg/l SW846 6020ANickel 0.0043 0.0010 mg/l SW846 6020AVanadium 0.0011 0.0010 mg/l SW846 6020AZinc 0.0207 0.0050 mg/l SW846 6020A

LA58360-2 B-7GW

Acetone 0.339 0.050 mg/l SW846 8260BBenzene 2.78 0.10 mg/l SW846 8260B1,2-Dichloroethane 0.0055 0.0010 mg/l SW846 8260BEthylbenzene 1.49 0.10 mg/l SW846 8260BMethyl Ethyl Ketone 0.0528 0.013 mg/l SW846 8260BStyrene 0.0099 0.0010 mg/l SW846 8260BToluene 0.828 0.10 mg/l SW846 8260Bm,p-Xylene 4.62 0.20 mg/l SW846 8260Bo-Xylene 0.705 0.10 mg/l SW846 8260BXylene (total) 5.33 0.20 mg/l SW846 8260B2-Methylnaphthalene 0.0277 0.00091 mg/l SW846 8270DNaphthalene 0.102 0.0091 mg/l SW846 8270DTPH-GRO (C6-C10) 70.8 5.0 mg/l SW846 8015CTPH-DRO (C10-C28) 7.77 0.14 mg/l SW846 8015CAntimony 0.0011 0.0010 mg/l SW846 6020A

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Arsenic 0.0374 0.0010 mg/l SW846 6020ABarium 1.07 0.0010 mg/l SW846 6020ABeryllium 0.0013 0.0010 mg/l SW846 6020ACadmium 0.0158 0.00050 mg/l SW846 6020AChromium 0.0488 0.0010 mg/l SW846 6020ACobalt 0.0269 0.0010 mg/l SW846 6020ACopper 0.0801 0.0010 mg/l SW846 6020ALead 0.0581 0.0010 mg/l SW846 6020ANickel 0.0540 0.0010 mg/l SW846 6020ASelenium 0.0081 0.0050 mg/l SW846 6020AVanadium 0.0868 0.0010 mg/l SW846 6020AZinc 0.149 0.0050 mg/l SW846 6020A

LA58360-2FR B-7GW

Antimony 0.0019 0.0010 mg/l SW846 6020AArsenic 0.0161 0.0010 mg/l SW846 6020ABarium 0.358 0.0010 mg/l SW846 6020ACadmium 0.0020 0.00050 mg/l SW846 6020ACobalt 0.0044 0.0010 mg/l SW846 6020ACopper 0.0022 0.0010 mg/l SW846 6020ALead 0.0098 0.0010 mg/l SW846 6020ANickel 0.0045 0.0010 mg/l SW846 6020AVanadium 0.0015 0.0010 mg/l SW846 6020AZinc 0.0091 0.0050 mg/l SW846 6020A

LA58360-3 B-4GW

Arsenic 0.0027 0.0010 mg/l SW846 6020ABarium 0.301 0.0010 mg/l SW846 6020AChromium 0.0088 0.0010 mg/l SW846 6020ACobalt 0.0019 0.0010 mg/l SW846 6020ACopper 0.0051 0.0010 mg/l SW846 6020ALead 0.0078 0.0010 mg/l SW846 6020ANickel 0.0061 0.0010 mg/l SW846 6020AVanadium 0.0108 0.0010 mg/l SW846 6020AZinc 0.0186 0.0050 mg/l SW846 6020A

LA58360-4 FB-07

Acetone 0.0538 0.050 mg/l SW846 8260BCopper 0.0680 0.0010 mg/l SW846 6020A

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LA58360-5 RB-04

Acetone 0.0584 0.050 mg/l SW846 8260BCopper 0.0186 0.0010 mg/l SW846 6020AMercury 0.00037 0.00020 mg/l SW846 7470ANitrogen, Nitrate 0.058 0.050 mg/l SW846 9056A

LA58360-6 D-1 FSW


LA58360-6A D-1 FSW

Corrosivity as pH a 7.3 su SW846 9045C/9045DIgnitability (Flashpoint) b > 200 Deg. F SW846 1010/1010A

LA58360-7 D-1 SWS


LA58360-7A D-1 SWS

Corrosivity as pH c 7.9 su SW846 9045C/9045DIgnitability (Flashpoint) b > 200 Deg. F SW846 1010/1010A



(a) temp. 22.1 c Analysis performed at SGS Houston, TX.(b) Analysis performed at SGS Houston, TX.(c) temp. 22.0 c Analysis performed at SGS Houston, TX.

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Sample Results

Report of Analysis

Scott, LASection 3

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Client Sample ID: B-8GWLab Sample ID: LA58360-1 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 1Q0451014.D 1 10/17/19 14:51 CP n/a n/a V1Q2505Run #2


VOA RECAP List




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VOA RECAP List





17060-07-0 1,2-Dichloroethane-D4 123% a 81-120%2037-26-5 Toluene-D8 103% 93-105%460-00-4 4-Bromofluorobenzene 99% 89-107%

(a) Outside control limits biased high. Sample contains no hits above client requested reporting limits.


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Client Sample ID: B-8GWLab Sample ID: LA58360-1 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 L0029762.D 1 10/24/19 00:27 PC 10/13/19 02:00 OP15355 EL789Run #2 a L0030004.D 1 10/29/19 01:50 PC 10/26/19 11:40 OP15487 EL795


ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0045 mg/l120-83-2 2,4-Dichlorophenol ND 0.0045 mg/l105-67-9 2,4-Dimethylphenol ND 0.0045 mg/l51-28-5 2,4-Dinitrophenol ND 0.018 mg/l100-02-7 4-Nitrophenol b ND 0.023 mg/l87-86-5 Pentachlorophenol ND 0.00091 mg/l108-95-2 Phenol ND 0.0045 mg/l58-90-2 2,3,4,6-Tetrachlorophenol b ND 0.0045 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0045 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0045 mg/l83-32-9 Acenaphthene ND 0.00018 mg/l208-96-8 Acenaphthylene ND 0.00018 mg/l62-53-3 Aniline ND 0.0045 mg/l120-12-7 Anthracene ND 0.00018 mg/l56-55-3 Benzo(a)anthracene ND 0.00018 mg/l50-32-8 Benzo(a)pyrene ND 0.00018 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00018 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00018 mg/l92-52-4 1,1' -Biphenyl ND 0.0091 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0045 mg/l106-47-8 4-Chloroaniline b ND 0.0045 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0045 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0045 mg/l91-58-7 2-Chloronaphthalene ND 0.0045 mg/l218-01-9 Chrysene ND 0.00018 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00018 mg/l132-64-9 Dibenzofuran ND 0.0045 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.0091 mg/l84-66-2 Diethyl Phthalate ND 0.0045 mg/l131-11-3 Dimethyl Phthalate ND 0.0045 mg/l117-84-0 Di-n-octyl Phthalate ND 0.0045 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0045 mg/l


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ABN RECAP LIST


121-14-2 2,4-Dinitrotoluene ND 0.0045 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0045 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0045 mg/l206-44-0 Fluoranthene ND 0.00018 mg/l86-73-7 Fluorene ND 0.00018 mg/l118-74-1 Hexachlorobenzene ND 0.00091 mg/l87-68-3 Hexachlorobutadiene ND 0.00045 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.0091 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00018 mg/l78-59-1 Isophorone ND 0.0045 mg/l91-57-6 2-Methylnaphthalene ND 0.00018 mg/l91-20-3 Naphthalene 0.00094 0.00018 mg/l88-74-4 2-Nitroaniline ND 0.0045 mg/l99-09-2 3-Nitroaniline b ND 0.0045 mg/l100-01-6 4-Nitroaniline b ND 0.0045 mg/l98-95-3 Nitrobenzene ND 0.00091 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0045 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0045 mg/l85-01-8 Phenanthrene ND 0.00018 mg/l129-00-0 Pyrene ND 0.00018 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.00091 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0045 mg/l





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Client Sample ID: B-8GWLab Sample ID: LA58360-1 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: MADEP VPH REV 1.1 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LC053080.D 1 10/21/19 22:28 NN n/a n/a GLC2394Run #2


Volatile Petroleum Hydrocarbons (VPH)


Aliphatics C6-C8 (Unadj.) ND 0.15 mg/lAliphatics > C8-C10 (Unadj.) ND 0.15 mg/lAromatics > C8-C10 (Unadj.) ND 0.15 mg/l


615-59-8 2,5-Dibromotoluene 106% a 70-130%615-59-8 2,5-Dibromotoluene 107% b 70-130%

(a) Recovery from Aliphatics fraction.(b) Recovery from Aromatics fraction.


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Client Sample ID: B-8GWLab Sample ID: LA58360-1 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA




TPH-GRO (C6-C10) 0.634 0.10 mg/l




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Client Sample ID: B-8GWLab Sample ID: LA58360-1 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: MADEP EPH REV 1.1 SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 X0012245.D 1 10/19/19 12:58 LS 10/17/19 08:00 OP15390 GLB2101Run #2 Y0012245.D 1 10/19/19 12:59 LS 10/17/19 08:00 OP15390 GLB2102

Initial Volume Final VolumeRun #1 54.4 ml 4.0 mlRun #2 54.4 ml 4.0 ml

Louisiana EPH Ranges


Aliphatics > C10-C12 (Unadj.)) 0.304 a 0.14 mg/lAliphatics > C12-C16 (Unadj.)) ND a 0.14 mg/lAliphatics > C16-C35 (Unadj.)) ND a 0.14 mg/lAromatics > C10-C12 (Unadj.))ND 0.14 mg/lAromatics > C12-C16 (Unadj.))ND 0.14 mg/lAromatics > C16-C21 (Unadj.))ND 0.14 mg/lAromatics > C21-C35 (Unadj.))ND 0.14 mg/l


3386-33-2 1-Chlorooctadecane 76% 40-140%84-15-1 o-Terphenyl 89% 40-140%321-60-8 2-Fluorobiphenyl 84% 40-140%

(a) Result is from Run# 2


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Client Sample ID: B-8GWLab Sample ID: LA58360-1 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA




TPH-DRO (C10-C28) 0.946 0.14 mg/lTPH-ORO (C28-C35) a ND 0.14 mg/l


84-15-1 o-Terphenyl 102% 40-118%

(a) Associated CCV outside control limits high, sample was ND.


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Client Sample ID: B-8GWLab Sample ID: LA58360-1 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19






Barium 0.858 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5


Cadmium 0.0023 0.00050 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5

Chromium 0.0203 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5

Cobalt 0.0138 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5

Copper 0.0308 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5

Lead 0.0213 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5

Mercury ND 0.00020 mg/l 1 10/10/19 10/10/19 SA SW846 7470A 1 SW846 7470A 4

Nickel 0.0212 0.0010 mg/l 1 10/10/19 10/14/19 RT SW846 6020A 3 SW846 3010A 5




Vanadium 0.0415 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5

Zinc 0.0494 0.0050 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 5



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Client Sample ID: B-8GWLab Sample ID: LA58360-1F Date Sampled: 10/09/19Matrix: AQ - Groundwater Filtered Date Received: 10/09/19


Dissolved Metals Analysis




















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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2G111965.D 1 10/16/19 20:54 CP n/a n/a V2G5842Run #2 1Q0451016.D 100 10/17/19 15:17 CP n/a n/a V1Q2505

Purge VolumeRun #1 5.0 mlRun #2 5.0 ml

VOA RECAP List


67-64-1 Acetone 0.339 0.050 mg/l71-43-2 Benzene 2.78 a 0.10 mg/l75-27-4 Bromodichloromethane ND 0.0010 mg/l75-25-2 Bromoform ND 0.0010 mg/l75-15-0 Carbon Disulfide ND 0.0010 mg/l56-23-5 Carbon Tetrachloride ND 0.0010 mg/l108-90-7 Chlorobenzene ND 0.0010 mg/l75-00-3 Chloroethane ND 0.0010 mg/l67-66-3 Chloroform ND 0.0010 mg/l124-48-1 Dibromochloromethane ND 0.0010 mg/l96-12-8 1,2-Dibromo-3-chloropropane ND 0.0010 mg/l541-73-1 m-Dichlorobenzene ND 0.0010 mg/l95-50-1 o-Dichlorobenzene ND 0.0010 mg/l106-46-7 p-Dichlorobenzene ND 0.0010 mg/l75-34-3 1,1-Dichloroethane ND 0.0010 mg/l107-06-2 1,2-Dichloroethane 0.0055 0.0010 mg/l75-35-4 1,1-Dichloroethylene ND 0.0010 mg/l156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/l156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/l540-59-0 1,2-Dichloroethene (total) ND 0.0010 mg/l78-87-5 1,2-Dichloropropane ND 0.0010 mg/l10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/l10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/l542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/l100-41-4 Ethylbenzene 1.49 a 0.10 mg/l67-72-1 Hexachloroethane ND 0.0010 mg/l78-83-1 Isobutyl Alcohol ND 0.10 mg/l74-83-9 Methyl Bromide ND 0.0010 mg/l74-87-3 Methyl Chloride ND 0.0010 mg/l75-09-2 Methylene Chloride ND 0.0010 mg/l78-93-3 Methyl Ethyl Ketone 0.0528 0.013 mg/l108-10-1 4-Methyl-2-pentanone ND 0.013 mg/l


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VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether ND 0.0010 mg/l100-42-5 Styrene 0.0099 0.0010 mg/l630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.00050 mg/l127-18-4 Tetrachloroethylene ND 0.0010 mg/l108-88-3 Toluene 0.828 a 0.10 mg/l71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/l79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/l79-01-6 Trichloroethylene ND 0.0010 mg/l75-69-4 Trichlorofluoromethane ND 0.0010 mg/l75-01-4 Vinyl Chloride ND 0.0010 mg/l

m,p-Xylene 4.62 a 0.20 mg/l95-47-6 o-Xylene 0.705 a 0.10 mg/l1330-20-7 Xylene (total) 5.33 a 0.20 mg/l


17060-07-0 1,2-Dichloroethane-D4 127% b 111% 81-120%2037-26-5 Toluene-D8 105% 100% 93-105%460-00-4 4-Bromofluorobenzene 106% 98% 89-107%

(a) Result is from Run# 2(b) Outside control limits due to matrix interference. Confirmed by reanalysis at a dilution.


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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 L0029763.D 1 10/24/19 00:53 PC 10/13/19 02:00 OP15355 EL789Run #2 a L0030005.D 1 10/29/19 02:16 PC 10/26/19 11:40 OP15487 EL795Run #3 L0030142.D 5 11/01/19 14:38 PC 10/13/19 14:00 OP15355 EL799Run #4 L0030151.D 50 11/01/19 18:28 PC 10/13/19 14:00 OP15355 EL799

Initial Volume Final VolumeRun #1 110 ml 1.0 mlRun #2 110 ml 1.0 mlRun #3 110 ml 1.0 mlRun #4 110 ml 1.0 ml

ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0045 mg/l120-83-2 2,4-Dichlorophenol ND 0.0045 mg/l105-67-9 2,4-Dimethylphenol ND 0.0045 mg/l51-28-5 2,4-Dinitrophenol ND 0.018 mg/l100-02-7 4-Nitrophenol b ND 0.023 mg/l87-86-5 Pentachlorophenol ND 0.00091 mg/l108-95-2 Phenol ND 0.0045 mg/l58-90-2 2,3,4,6-Tetrachlorophenol b ND 0.0045 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0045 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0045 mg/l83-32-9 Acenaphthene ND 0.00018 mg/l208-96-8 Acenaphthylene ND 0.00018 mg/l62-53-3 Aniline ND 0.0045 mg/l120-12-7 Anthracene ND 0.00018 mg/l56-55-3 Benzo(a)anthracene ND 0.00018 mg/l50-32-8 Benzo(a)pyrene ND 0.00018 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00018 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00018 mg/l92-52-4 1,1' -Biphenyl ND 0.0091 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0045 mg/l106-47-8 4-Chloroaniline b ND 0.0045 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0045 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0045 mg/l91-58-7 2-Chloronaphthalene ND 0.0045 mg/l218-01-9 Chrysene ND 0.00018 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00018 mg/l132-64-9 Dibenzofuran ND 0.0045 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.0091 mg/l


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ABN RECAP LIST


84-66-2 Diethyl Phthalate ND 0.0045 mg/l131-11-3 Dimethyl Phthalate ND 0.0045 mg/l117-84-0 Di-n-octyl Phthalate ND 0.0045 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0045 mg/l121-14-2 2,4-Dinitrotoluene ND 0.0045 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0045 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0045 mg/l206-44-0 Fluoranthene ND 0.00018 mg/l86-73-7 Fluorene ND 0.00018 mg/l118-74-1 Hexachlorobenzene ND 0.00091 mg/l87-68-3 Hexachlorobutadiene ND 0.00045 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.0091 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00018 mg/l78-59-1 Isophorone ND 0.0045 mg/l91-57-6 2-Methylnaphthalene 0.0277 c 0.00091 mg/l91-20-3 Naphthalene 0.102 d 0.0091 mg/l88-74-4 2-Nitroaniline ND 0.0045 mg/l99-09-2 3-Nitroaniline b ND 0.0045 mg/l100-01-6 4-Nitroaniline b ND 0.0045 mg/l98-95-3 Nitrobenzene ND 0.00091 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0045 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0045 mg/l85-01-8 Phenanthrene ND 0.00018 mg/l129-00-0 Pyrene ND 0.00018 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.00091 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0045 mg/l


367-12-4 2-Fluorophenol 35% 21% e 28% 25-101%4165-62-2 Phenol-d5 32% 33% 50% 17-79%118-79-6 2,4,6-Tribromophenol 108% 113% 65% 40-144%4165-60-0 Nitrobenzene-d5 160% f 44% 122% 40-124%321-60-8 2-Fluorobiphenyl 83% 89% 57% 27-124%1718-51-0 Terphenyl-d14 90% 91% 60% 45-140%

(a) Confirmation run.(b) Associated CCV outside of control limits high, sample was ND.(c) Result is from Run# 3(d) Result is from Run# 4


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ABN RECAP LIST


(e) Outside control limits biased low. Analytical run used for confirmation only.(f) Outside control limits due to matrix interference.


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TPH-GRO (C6-C10) 70.8 5.0 mg/l




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84-15-1 o-Terphenyl 100% 40-118%



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Antimony 0.0011 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 4



Beryllium 0.0013 0.0010 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 4








Selenium 0.0081 0.0050 mg/l 1 10/10/19 10/12/19 RT SW846 6020A 2 SW846 3010A 4







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Client Sample ID: B-7GWLab Sample ID: LA58360-2FR Date Sampled: 10/09/19Matrix: AQ - Groundwater Filtered Date Received: 10/09/19




Antimony 0.0019 0.0010 mg/l 1 11/05/19 11/05/19 RT SW846 6020A 1 SW846 3010A 3


















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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2G111963.D 1 10/16/19 20:25 CP n/a n/a V2G5842Run #2


VOA RECAP List




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VOA RECAP List







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ABN RECAP LIST




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ABN RECAP LIST


121-14-2 2,4-Dinitrotoluene ND 0.0044 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0044 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0044 mg/l206-44-0 Fluoranthene ND 0.00018 mg/l86-73-7 Fluorene ND 0.00018 mg/l118-74-1 Hexachlorobenzene ND 0.00088 mg/l87-68-3 Hexachlorobutadiene ND 0.00044 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.0088 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00018 mg/l78-59-1 Isophorone ND 0.0044 mg/l91-57-6 2-Methylnaphthalene ND 0.00018 mg/l91-20-3 Naphthalene ND 0.00018 mg/l88-74-4 2-Nitroaniline ND 0.0044 mg/l99-09-2 3-Nitroaniline b ND 0.0044 mg/l100-01-6 4-Nitroaniline b ND 0.0044 mg/l98-95-3 Nitrobenzene ND 0.00088 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0044 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0044 mg/l85-01-8 Phenanthrene ND 0.00018 mg/l129-00-0 Pyrene ND 0.00018 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.00088 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0044 mg/l





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TPH-DRO (C10-C28) ND 0.14 mg/lTPH-ORO (C28-C35) a ND 0.14 mg/l


84-15-1 o-Terphenyl 102% 40-118%



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VOA RECAP List


67-64-1 Acetone 0.0538 0.050 mg/l71-43-2 Benzene ND 0.0010 mg/l75-27-4 Bromodichloromethane ND 0.0010 mg/l75-25-2 Bromoform ND 0.0010 mg/l75-15-0 Carbon Disulfide ND 0.0010 mg/l56-23-5 Carbon Tetrachloride ND 0.0010 mg/l108-90-7 Chlorobenzene ND 0.0010 mg/l75-00-3 Chloroethane ND 0.0010 mg/l67-66-3 Chloroform ND 0.0010 mg/l124-48-1 Dibromochloromethane ND 0.0010 mg/l96-12-8 1,2-Dibromo-3-chloropropane ND 0.0010 mg/l541-73-1 m-Dichlorobenzene ND 0.0010 mg/l95-50-1 o-Dichlorobenzene ND 0.0010 mg/l106-46-7 p-Dichlorobenzene ND 0.0010 mg/l75-34-3 1,1-Dichloroethane ND 0.0010 mg/l107-06-2 1,2-Dichloroethane ND 0.0010 mg/l75-35-4 1,1-Dichloroethylene ND 0.0010 mg/l156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/l156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/l540-59-0 1,2-Dichloroethene (total) ND 0.0010 mg/l78-87-5 1,2-Dichloropropane ND 0.0010 mg/l10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/l10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/l542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/l100-41-4 Ethylbenzene ND 0.0010 mg/l67-72-1 Hexachloroethane ND 0.0010 mg/l78-83-1 Isobutyl Alcohol ND 0.10 mg/l74-83-9 Methyl Bromide ND 0.0010 mg/l74-87-3 Methyl Chloride ND 0.0010 mg/l75-09-2 Methylene Chloride ND 0.0010 mg/l78-93-3 Methyl Ethyl Ketone ND 0.013 mg/l108-10-1 4-Methyl-2-pentanone ND 0.013 mg/l


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VOA RECAP List







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ABN RECAP LIST




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ABN RECAP LIST







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84-15-1 o-Terphenyl 103% 40-118%



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Nickel ND 0.0010 mg/l 1 10/10/19 10/14/19 RT SW846 6020A 3 SW846 3010A 5








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General Chemistry





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Client Sample ID: RB-04Lab Sample ID: LA58360-5 Date Sampled: 10/09/19Matrix: AQ - Water Date Received: 10/09/19Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



VOA RECAP List




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VOA RECAP List







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Client Sample ID: RB-04Lab Sample ID: LA58360-5 Date Sampled: 10/09/19Matrix: AQ - Water Date Received: 10/09/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA


Initial Volume Final VolumeRun #1 110 ml 1.0 mlRun #2 95.0 ml 1.0 ml

ABN RECAP LIST




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ABN RECAP LIST







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Client Sample ID: RB-04Lab Sample ID: LA58360-5 Date Sampled: 10/09/19Matrix: AQ - Water Date Received: 10/09/19Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA








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Client Sample ID: RB-04Lab Sample ID: LA58360-5 Date Sampled: 10/09/19Matrix: AQ - Water Date Received: 10/09/19Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA






84-15-1 o-Terphenyl 109% 40-118%



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Client Sample ID: RB-04Lab Sample ID: LA58360-5 Date Sampled: 10/09/19Matrix: AQ - Water Date Received: 10/09/19













Mercury 0.00037 0.00020 mg/l 1 10/10/19 10/10/19 SA SW846 7470A 2 SW846 7470A 4









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General Chemistry


Nitrogen, Ammonia a ND 0.10 mg/l 1 10/17/19 ATX EPA 350.1Nitrogen, Nitrate 0.058 0.050 mg/l 1 10/09/19 16:55 HD SW846 9056ANitrogen, Nitrite ND 0.050 mg/l 1 10/09/19 16:55 HD SW846 9056A



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Client Sample ID: D-1 FSW Lab Sample ID: LA58360-6 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: SW846 8260B SW846 1311 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 1J0070356.D 100 10/11/19 22:57 CP 10/10/19 11:00 OP15340 V1J2315Run #2


VOA TCLP List TCLP Leachate method SW846 1311

CAS No. Compound Result HW# MCL RL Units Q

71-43-2 Benzene ND D018 0.50 0.10 mg/l56-23-5 Carbon Tetrachloride ND D019 0.50 0.10 mg/l108-90-7 Chlorobenzene ND D021 100 0.10 mg/l67-66-3 Chloroform ND D022 6.0 0.10 mg/l107-06-2 1,2-Dichloroethane ND D028 0.50 0.10 mg/l75-35-4 1,1-Dichloroethylene ND D029 0.70 0.10 mg/l78-93-3 Methyl Ethyl Ketone ND D035 200 1.3 mg/l127-18-4 Tetrachloroethylene ND D039 0.70 0.10 mg/l79-01-6 Trichloroethylene ND D040 0.50 0.10 mg/l75-01-4 Vinyl Chloride ND D043 0.20 0.10 mg/l



ND = Not detected J = Indicates an estimated valueMCL = Maximum Contamination Level (40 CFR 261 7/1/11) B = Indicates analyte found in associated method blankE = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

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Client Sample ID: D-1 FSW Lab Sample ID: LA58360-6 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 C0051523.D 1 10/19/19 08:33 PC 10/15/19 08:00 OP15372 EC2055Run #2

Initial Volume Final VolumeRun #1 100 ml 1.0 mlRun #2

ABN TCLP List TCLP Leachate method SW846 1311


95-48-7 2-Methylphenol ND D023 200 0.050 mg/l3&4-Methylphenol ND D024 200 0.050 mg/l

87-86-5 Pentachlorophenol ND D037 100 0.010 mg/l95-95-4 2,4,5-Trichlorophenol ND D041 400 0.050 mg/l88-06-2 2,4,6-Trichlorophenol ND D042 2.0 0.050 mg/l106-46-7 1,4-Dichlorobenzene ND D027 7.5 0.050 mg/l121-14-2 2,4-Dinitrotoluene ND D030 0.13 0.050 mg/l118-74-1 Hexachlorobenzene ND D032 0.13 0.010 mg/l87-68-3 Hexachlorobutadiene ND D033 0.50 0.0050 mg/l67-72-1 Hexachloroethane ND D034 3.0 0.050 mg/l98-95-3 Nitrobenzene ND D036 2.0 0.010 mg/l110-86-1 Pyridine ND D038 5.0 0.050 mg/l




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Client Sample ID: D-1 FSW Lab Sample ID: LA58360-6 Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19


Metals Analysis, TCLP Leachate SW846 1311

Analyte Result HW# MCL RL Units DF Prep Analyzed By Method Prep Method

Arsenic ND D004 5.0 0.50 mg/l 1 10/11/19 10/12/19 RD SW846 6010C 1 SW846 3010A 3

Barium ND D005 100 5.0 mg/l 1 10/11/19 10/12/19 RD SW846 6010C 1 SW846 3010A 3

Cadmium ND D006 1.0 0.50 mg/l 1 10/11/19 10/12/19 RD SW846 6010C 1 SW846 3010A 3

Chromium ND D007 5.0 0.50 mg/l 1 10/11/19 10/12/19 RD SW846 6010C 1 SW846 3010A 3

Lead ND D008 5.0 0.50 mg/l 1 10/11/19 10/12/19 RD SW846 6010C 1 SW846 3010A 3

Mercury ND D009 0.20 0.020 mg/l 1 10/14/19 10/14/19 SA SW846 7470A 2 SW846 7470A 4

Selenium ND D010 1.0 0.50 mg/l 1 10/11/19 10/12/19 RD SW846 6010C 1 SW846 3010A 3

Silver ND D011 5.0 0.50 mg/l 1 10/11/19 10/12/19 RD SW846 6010C 1 SW846 3010A 3


RL = Reporting Limit ND = Not detectedMCL = Maximum Contamination Level (40 CFR 261 7/1/11)

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Client Sample ID: D-1 FSW Lab Sample ID: LA58360-6A Date Sampled: 10/09/19Matrix: AQ - Ground Water Date Received: 10/09/19


General Chemistry


Corrosivity as pH a 7.3 su 1 10/11/19 18:20 ATX SW846 9045C/9045DCyanide Reactivity b ND 0.40 mg/l 1 10/12/19 12:37 ATX SW846 CHAP7Ignitability (Flashpoint) b > 200 Deg. F 1 10/15/19 12:40 ATX SW846 1010/1010ASulfide Reactivity b ND 20 mg/l 1 10/12/19 14:30 ATX SW846 CHAP7

(a) temp. 22.1 c Analysis performed at SGS Houston, TX.(b) Analysis performed at SGS Houston, TX.


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Client Sample ID: D-1 SWS Lab Sample ID: LA58360-7 Date Sampled: 10/09/19Matrix: SO - Soil Date Received: 10/09/19Method: SW846 8260B SW846 1311 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 1J0070357.D 100 10/11/19 23:21 CP 10/10/19 11:00 OP15340 V1J2315Run #2








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Client Sample ID: D-1 SWS Lab Sample ID: LA58360-7 Date Sampled: 10/09/19Matrix: SO - Soil Date Received: 10/09/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 C0051524.D 1 10/19/19 08:54 PC 10/15/19 08:00 OP15372 EC2055Run #2









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Client Sample ID: D-1 SWS Lab Sample ID: LA58360-7 Date Sampled: 10/09/19Matrix: SO - Soil Date Received: 10/09/19














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Client Sample ID: D-1 SWS Lab Sample ID: LA58360-7A Date Sampled: 10/09/19Matrix: SO - Soil Date Received: 10/09/19



General Chemistry


Corrosivity as pH b 7.9 su 1 10/11/19 18:15 ATX SW846 9045C/9045DCyanide Reactivity c ND 0.40 mg/kg 1 10/12/19 12:37 ATX SW846 CHAP7Ignitability (Flashpoint) c > 200 Deg. F 1 10/15/19 12:40 ATX SW846 1010/1010ASulfide Reactivity c ND 20 mg/kg 1 10/12/19 14:30 ATX SW846 CHAP7

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) temp. 22.0 c Analysis performed at SGS Houston, TX.(c) Analysis performed at SGS Houston, TX.


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VOA RECAP List




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VOA RECAP List







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Misc. Forms




Scott, LASection 4

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4


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4. No. Coolers: 3

Airbill #'s:


Y or N


3. COC Present:


2. Thermometer ID:


3. Cooler media:

DV439;



















Intact

Y or N

Comments

Y or N N/A

Cooler Temps (Initial/Adjusted): #1: (2.1/2.1); #2: (2.6/2.6); #3: (3.1/3.1); DV439


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MS Volatiles

QC Data Summaries



Scott, LASection 5

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Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1Q2505-MB2 1Q0451012.D 1 10/17/19 CP n/a n/a V1Q2505


LA58360-1, LA58360-2



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LA58360-1, LA58360-2





17060-07-0 1,2-Dichloroethane-D4 124%* 81-120%2037-26-5 Toluene-D8 97% 93-105%460-00-4 4-Bromofluorobenzene 88%* 89-107%

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LA58360-2, LA58360-3, LA58360-4, LA58360-5, LA58360-8


67-64-1 Acetone 1.7 50 ug/l J71-43-2 Benzene ND 1.0 ug/l75-27-4 Bromodichloromethane ND 1.0 ug/l75-25-2 Bromoform ND 1.0 ug/l75-15-0 Carbon Disulfide ND 1.0 ug/l56-23-5 Carbon Tetrachloride ND 1.0 ug/l108-90-7 Chlorobenzene ND 1.0 ug/l75-00-3 Chloroethane ND 1.0 ug/l67-66-3 Chloroform ND 1.0 ug/l124-48-1 Dibromochloromethane ND 1.0 ug/l96-12-8 1,2-Dibromo-3-chloropropane ND 1.0 ug/l541-73-1 m-Dichlorobenzene ND 1.0 ug/l95-50-1 o-Dichlorobenzene ND 1.0 ug/l106-46-7 p-Dichlorobenzene ND 1.0 ug/l75-34-3 1,1-Dichloroethane ND 1.0 ug/l107-06-2 1,2-Dichloroethane ND 1.0 ug/l75-35-4 1,1-Dichloroethylene ND 1.0 ug/l156-59-2 cis-1,2-Dichloroethylene ND 1.0 ug/l156-60-5 trans-1,2-Dichloroethylene ND 1.0 ug/l540-59-0 1,2-Dichloroethene (total) ND 1.0 ug/l78-87-5 1,2-Dichloropropane ND 1.0 ug/l10061-01-5 cis-1,3-Dichloropropene ND 1.0 ug/l10061-02-6 trans-1,3-Dichloropropene ND 1.0 ug/l542-75-6 1,3-Dichloropropene (total) ND 1.0 ug/l100-41-4 Ethylbenzene ND 1.0 ug/l67-72-1 Hexachloroethane ND 1.0 ug/l78-83-1 Isobutyl Alcohol ND 100 ug/l74-83-9 Methyl Bromide ND 1.0 ug/l74-87-3 Methyl Chloride ND 1.0 ug/l75-09-2 Methylene Chloride ND 1.0 ug/l78-93-3 Methyl Ethyl Ketone ND 13 ug/l108-10-1 4-Methyl-2-pentanone ND 13 ug/l1634-04-4 Methyl Tert Butyl Ether ND 1.0 ug/l100-42-5 Styrene ND 1.0 ug/l630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 ug/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 ug/l

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LA58360-2, LA58360-3, LA58360-4, LA58360-5, LA58360-8






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Leachate Blank Summary Page 1 of 1Job Number: LA58360Account: PROVLABR Providence Engineering & EnvironmentalProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15340-LB 1J0070344.D 100 10/11/19 CP 10/10/19 OP15340 V1J2315


LA58360-6, LA58360-7


71-43-2 Benzene ND 100 ug/l56-23-5 Carbon Tetrachloride ND 100 ug/l108-90-7 Chlorobenzene ND 100 ug/l67-66-3 Chloroform ND 100 ug/l107-06-2 1,2-Dichloroethane 43.2 100 ug/l J75-35-4 1,1-Dichloroethylene ND 100 ug/l78-93-3 Methyl Ethyl Ketone ND 1300 ug/l127-18-4 Tetrachloroethylene ND 100 ug/l79-01-6 Trichloroethylene ND 100 ug/l75-01-4 Vinyl Chloride ND 100 ug/l



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Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1Q2505-BS1 1Q0451006.D 1 10/17/19 CP n/a n/a V1Q2505V1Q2505-BSD1 1Q0451008.D 1 10/17/19 CP n/a n/a V1Q2505


LA58360-1, LA58360-2


67-64-1 Acetone 50 74.7 149 69.2 138 8 35-173/2271-43-2 Benzene 20 22.2 111 21.4 107 4 82-119/1475-27-4 Bromodichloromethane 20 24.4 122 21.8 109 11 76-124/1475-25-2 Bromoform 20 24.2 121 21.6 108 11 52-131/1875-15-0 Carbon Disulfide 20 24.3 122 22.5 113 8 69-135/2056-23-5 Carbon Tetrachloride 20 23.3 117 21.5 108 8 73-127/20108-90-7 Chlorobenzene 20 21.8 109 20.3 102 7 82-118/1475-00-3 Chloroethane 20 17.1 86 16.1 81 6 57-146/3167-66-3 Chloroform 20 21.6 108 19.6 98 10 77-122/15124-48-1 Dibromochloromethane 20 22.0 110 21.1 106 4 68-126/1596-12-8 1,2-Dibromo-3-chloropropane 20 22.9 115 20.7 104 10 57-132/22541-73-1 m-Dichlorobenzene 20 22.1 111 20.2 101 9 78-122/1495-50-1 o-Dichlorobenzene 20 21.3 107 20.2 101 5 78-122/14106-46-7 p-Dichlorobenzene 20 22.4 112 20.3 102 10 79-119/1575-34-3 1,1-Dichloroethane 20 22.4 112 20.9 105 7 77-124/17107-06-2 1,2-Dichloroethane 20 22.6 113 22.1 111 2 71-124/1375-35-4 1,1-Dichloroethylene 20 22.0 110 20.4 102 8 77-125/20156-59-2 cis-1,2-Dichloroethylene 20 21.6 108 19.6 98 10 79-121/15156-60-5 trans-1,2-Dichloroethylene 20 20.5 103 19.3 97 6 77-124/18540-59-0 1,2-Dichloroethene (total) 40 42.1 105 38.9 97 8 80-121/1578-87-5 1,2-Dichloropropane 20 20.6 103 19.7 99 4 81-117/1410061-01-5 cis-1,3-Dichloropropene 20 20.5 103 19.4 97 6 77-123/1510061-02-6 trans-1,3-Dichloropropene 20 23.3 117 20.8 104 11 74-127/14542-75-6 1,3-Dichloropropene (total) 40 43.7 109 40.1 100 9 76-124/14100-41-4 Ethylbenzene 20 22.4 112 21.5 108 4 82-120/1567-72-1 Hexachloroethane 20 23.5 118 21.1 106 11 54-132/2178-83-1 Isobutyl Alcohol 200 191 96 188 94 2 37-152/4174-83-9 Methyl Bromide 20 17.6 88 15.4 77 13 46-165/2874-87-3 Methyl Chloride 20 7.2 36* 7.9 40* 9 55-140/2275-09-2 Methylene Chloride 20 22.9 115 19.0 95 19* 73-132/1678-93-3 Methyl Ethyl Ketone 50 60.6 121 58.3 117 4 55-149/21108-10-1 4-Methyl-2-pentanone 50 54.9 110 52.5 105 4 63-137/211634-04-4 Methyl Tert Butyl Ether 20 19.9 100 18.9 95 5 73-124/15100-42-5 Styrene 20 19.9 100 18.1 91 9 80-126/18630-20-6 1,1,1,2-Tetrachloroethane 20 22.5 113 20.6 103 9 77-126/1579-34-5 1,1,2,2-Tetrachloroethane 20 23.0 115 21.3 107 8 69-134/16


73 of 182

LA58360

55.3.1




LA58360-1, LA58360-2







74 of 182

LA58360

55.3.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1J2315-BS2 1J0070340.D 100 10/11/19 CP n/a n/a V1J2315V1J2315-BSD2 1J0070342.D 100 10/11/19 CP n/a n/a V1J2315


LA58360-6, LA58360-7


71-43-2 Benzene 2000 1900 95 1930 97 2 78-116/3056-23-5 Carbon Tetrachloride 2000 2110 106 2040 102 3 74-116/30108-90-7 Chlorobenzene 2000 1850 93 1900 95 3 87-111/3067-66-3 Chloroform 2000 2020 101 2010 101 0 79-114/30107-06-2 1,2-Dichloroethane 2000 2250 113 2320 116 3 73-123/3075-35-4 1,1-Dichloroethylene 2000 1890 95 1990 100 5 71-126/3078-93-3 Methyl Ethyl Ketone 5000 5500 110 5470 109 1 69-123/30127-18-4 Tetrachloroethylene 2000 1890 95 1910 96 1 81-116/3079-01-6 Trichloroethylene 2000 1930 97 1990 100 3 53-149/3075-01-4 Vinyl Chloride 2000 1840 92 1910 96 4 68-125/30




75 of 182

LA58360

55.3.2




LA58360-2, LA58360-3, LA58360-4, LA58360-5, LA58360-8


67-64-1 Acetone 50 56.5 113 52.9 106 7 35-173/2071-43-2 Benzene 20 20.8 104 19.7 99 5 82-119/1175-27-4 Bromodichloromethane 20 20.5 103 18.4 92 11 76-124/1175-25-2 Bromoform 20 19.6 98 18.1 91 8 52-131/1475-15-0 Carbon Disulfide 20 21.3 107 19.9 100 7 69-135/1456-23-5 Carbon Tetrachloride 20 20.0 100 18.9 95 6 73-127/13108-90-7 Chlorobenzene 20 21.4 107 19.8 99 8 82-118/1175-00-3 Chloroethane 20 18.6 93 21.0 105 12 57-146/2067-66-3 Chloroform 20 18.6 93 20.1 101 8 77-122/12124-48-1 Dibromochloromethane 20 19.2 96 18.2 91 5 68-126/1296-12-8 1,2-Dibromo-3-chloropropane 20 18.6 93 17.7 89 5 57-132/17541-73-1 m-Dichlorobenzene 20 21.5 108 20.6 103 4 78-122/1295-50-1 o-Dichlorobenzene 20 21.4 107 20.4 102 5 78-122/12106-46-7 p-Dichlorobenzene 20 20.1 101 19.6 98 3 79-119/1275-34-3 1,1-Dichloroethane 20 21.5 108 20.5 103 5 77-124/14107-06-2 1,2-Dichloroethane 20 21.6 108 20.7 104 4 71-124/1175-35-4 1,1-Dichloroethylene 20 20.8 104 19.5 98 6 77-125/14156-59-2 cis-1,2-Dichloroethylene 20 22.2 111 21.7 109 2 79-121/13156-60-5 trans-1,2-Dichloroethylene 20 21.2 106 19.2 96 10 77-124/14540-59-0 1,2-Dichloroethene (total) 40 43.4 109 41.0 103 6 80-121/1378-87-5 1,2-Dichloropropane 20 21.4 107 20.4 102 5 81-117/1110061-01-5 cis-1,3-Dichloropropene 20 19.7 99 18.8 94 5 77-123/1110061-02-6 trans-1,3-Dichloropropene 20 20.6 103 19.5 98 5 74-127/12542-75-6 1,3-Dichloropropene (total) 40 40.3 101 38.3 96 5 76-124/11100-41-4 Ethylbenzene 20 21.9 110 20.4 102 7 82-120/1167-72-1 Hexachloroethane 20 20.5 103 18.6 93 10 54-132/1578-83-1 Isobutyl Alcohol 200 203 102 206 103 1 37-152/3074-83-9 Methyl Bromide 20 18.3 92 21.1 106 14 46-165/2074-87-3 Methyl Chloride 20 18.5 93 18.7 94 1 55-140/1875-09-2 Methylene Chloride 20 19.8 99 17.8 89 11 73-132/1478-93-3 Methyl Ethyl Ketone 50 45.4 91 44.0 88 3 55-149/19108-10-1 4-Methyl-2-pentanone 50 54.9 110 51.9 104 6 63-137/171634-04-4 Methyl Tert Butyl Ether 20 22.2 111 21.2 106 5 73-124/14100-42-5 Styrene 20 20.8 104 19.4 97 7 80-126/12630-20-6 1,1,1,2-Tetrachloroethane 20 20.4 102 18.7 94 9 77-126/1279-34-5 1,1,2,2-Tetrachloroethane 20 21.8 109 20.4 102 7 69-134/14


76 of 182

LA58360

55.3.3




LA58360-2, LA58360-3, LA58360-4, LA58360-5, LA58360-8







77 of 182

LA58360

55.3.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchTD45787-1MS 1J0070348.D 100 10/11/19 CP n/a n/a V1J2315TD45787-1MSD 1J0070349.D 100 10/11/19 CP n/a n/a V1J2315TD45787-1 1J0070345.D 100 10/11/19 CP 10/10/19 OP15340 V1J2315


LA58360-6, LA58360-7

TD45787-1 Spike MS MS Spike MSD MSD LimitsCAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene ND 2000 1930 97 2000 1870 94 3 31-161/1556-23-5 Carbon Tetrachloride ND 2000 2190 110 2000 2130 107 3 53-133/36108-90-7 Chlorobenzene ND 2000 1890 95 2000 1830 92 3 74-122/3467-66-3 Chloroform ND 2000 2060 103 2000 1990 100 3 65-130/24107-06-2 1,2-Dichloroethane ND 2000 2330 117 2000 2260 113 3 51-141/3975-35-4 1,1-Dichloroethylene ND 2000 2060 103 2000 1970 99 4 48-139/3778-93-3 Methyl Ethyl Ketone ND 5000 5320 106 5000 5170 103 3 54-142/39127-18-4 Tetrachloroethylene ND 2000 1980 99 2000 1850 93 7 58-135/3779-01-6 Trichloroethylene ND 2000 2010 101 2000 1950 98 3 57-131/3675-01-4 Vinyl Chloride ND 2000 1880 94 2000 1810 91 4 22-155/49

CAS No. Surrogate Recoveries MS MSD TD45787-1 Limits



78 of 182

LA58360

55.4.1




LA58360-2, LA58360-3, LA58360-4, LA58360-5, LA58360-8


67-64-1 Acetone ND 1000 863 86 1000 929 93 7 11-126/2271-43-2 Benzene 6.1 400 418 103 400 417 103 0 41-155/1475-27-4 Bromodichloromethane ND 400 388 97 400 385 96 1 65-125/1475-25-2 Bromoform ND 400 347 87 400 353 88 2 39-127/1875-15-0 Carbon Disulfide ND 400 421 105 400 412 103 2 55-139/2056-23-5 Carbon Tetrachloride ND 400 401 100 400 389 97 3 60-131/20108-90-7 Chlorobenzene ND 400 396 99 400 400 100 1 71-124/1475-00-3 Chloroethane ND 400 419 105 400 378 95 10 44-163/3167-66-3 Chloroform ND 400 432 108 400 433 108 0 65-130/15124-48-1 Dibromochloromethane ND 400 373 93 400 370 93 1 57-125/1596-12-8 1,2-Dibromo-3-chloropropane ND 400 330 83 400 372 93 12 43-132/22541-73-1 m-Dichlorobenzene ND 400 403 101 400 410 103 2 67-124/1495-50-1 o-Dichlorobenzene ND 400 406 102 400 409 102 1 67-124/14106-46-7 p-Dichlorobenzene ND 400 385 96 400 384 96 0 66-122/1575-34-3 1,1-Dichloroethane 120 400 582 116 400 566 112 3 65-132/17107-06-2 1,2-Dichloroethane 267 400 690 106 400 685 105 1 61-130/1375-35-4 1,1-Dichloroethylene 60.8 400 467 102 400 446 96 5 62-136/20156-59-2 cis-1,2-Dichloroethylene 4880 E 400 5450 143* a 400 5420 135* a 1 68-129/15156-60-5 trans-1,2-Dichloroethylene 264 400 669 101 400 627 91 6 65-132/18540-59-0 1,2-Dichloroethene (total) 5140 E 800 6120 123 800 6050 114 1 66-130/1578-87-5 1,2-Dichloropropane 7.8 400 429 105 400 431 106 0 71-123/1410061-01-5 cis-1,3-Dichloropropene ND 400 376 94 400 375 94 0 61-125/1510061-02-6 trans-1,3-Dichloropropene ND 400 386 97 400 373 93 3 59-128/14542-75-6 1,3-Dichloropropene (total) ND 800 762 95 800 748 94 2 61-126/14100-41-4 Ethylbenzene ND 400 410 103 400 410 103 0 50-147/1567-72-1 Hexachloroethane ND 400 365 91 400 348 87 5 42-122/2178-83-1 Isobutyl Alcohol ND 4000 3190 80 4000 4050 101 24 6-168/4174-83-9 Methyl Bromide ND 400 364 91 400 348 87 4 24-163/2874-87-3 Methyl Chloride ND 400 361 90 400 357 89 1 37-151/2275-09-2 Methylene Chloride ND 400 368 92 400 374 94 2 63-137/1678-93-3 Methyl Ethyl Ketone ND 1000 784 78 1000 810 81 3 35-137/21108-10-1 4-Methyl-2-pentanone ND 1000 990 99 1000 1020 102 3 48-146/211634-04-4 Methyl Tert Butyl Ether ND 400 421 105 400 428 107 2 48-143/15100-42-5 Styrene ND 400 382 96 400 388 97 2 58-140/18630-20-6 1,1,1,2-Tetrachloroethane ND 400 375 94 400 378 95 1 67-127/1579-34-5 1,1,2,2-Tetrachloroethane ND 400 407 102 400 418 105 3 62-139/16


79 of 182

LA58360

55.4.2




LA58360-2, LA58360-3, LA58360-4, LA58360-5, LA58360-8


127-18-4 Tetrachloroethylene 80.8 400 464 96 400 471 98 1 68-127/19108-88-3 Toluene ND 400 405 101 400 402 101 1 40-153/1571-55-6 1,1,1-Trichloroethane ND 400 420 105 400 399 100 5 68-132/1879-00-5 1,1,2-Trichloroethane 38.4 400 432 98 400 441 101 2 62-137/1679-01-6 Trichloroethylene 41.9 400 437 99 400 431 97 1 67-124/1675-69-4 Trichlorofluoromethane ND 400 412 103 400 393 98 5 65-134/1775-01-4 Vinyl Chloride 730 400 1070 85 400 1050 80 2 60-133/16




(a) Outside control limits due to high level in sample relative to spike amount.


80 of 182

LA58360

55.4.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58360-2MS 1Q0451024.D 100 10/17/19 CP n/a n/a V1Q2505LA58360-2MSD 1Q0451026.D 100 10/17/19 CP n/a n/a V1Q2505LA58360-2 1Q0451016.D 100 10/17/19 CP n/a n/a V1Q2505


LA58360-1, LA58360-2


67-64-1 Acetone ND 5000 6190 124 5000 5540 111 11 11-126/2271-43-2 Benzene 2780 2000 5470 135 2000 5270 125 4 41-155/1475-27-4 Bromodichloromethane ND 2000 2360 118 2000 2110 106 11 65-125/1475-25-2 Bromoform ND 2000 2320 116 2000 2090 105 10 39-127/1875-15-0 Carbon Disulfide ND 2000 2440 122 2000 2210 111 10 55-139/2056-23-5 Carbon Tetrachloride ND 2000 2380 119 2000 2150 108 10 60-131/20108-90-7 Chlorobenzene ND 2000 2160 108 2000 1980 99 9 71-124/1475-00-3 Chloroethane ND 2000 1490 75 2000 1630 82 9 44-163/3167-66-3 Chloroform ND 2000 2220 111 2000 2000 100 10 65-130/15124-48-1 Dibromochloromethane ND 2000 2250 113 2000 2100 105 7 57-125/1596-12-8 1,2-Dibromo-3-chloropropane ND 2000 2390 120 2000 2200 110 8 43-132/22541-73-1 m-Dichlorobenzene ND 2000 2150 108 2000 2070 104 4 67-124/1495-50-1 o-Dichlorobenzene ND 2000 2180 109 2000 2070 104 5 67-124/14106-46-7 p-Dichlorobenzene ND 2000 2190 110 2000 2010 101 9 66-122/1575-34-3 1,1-Dichloroethane ND 2000 2310 116 2000 2090 105 10 65-132/17107-06-2 1,2-Dichloroethane ND 2000 2250 113 2000 2050 103 9 61-130/1375-35-4 1,1-Dichloroethylene ND 2000 2150 108 2000 2070 104 4 62-136/20156-59-2 cis-1,2-Dichloroethylene ND 2000 2300 115 2000 2130 107 8 68-129/15156-60-5 trans-1,2-Dichloroethylene ND 2000 2250 113 2000 2050 103 9 65-132/18540-59-0 1,2-Dichloroethene (total) ND 4000 4550 114 4000 4190 105 8 66-130/1578-87-5 1,2-Dichloropropane ND 2000 2100 105 2000 1970 99 6 71-123/1410061-01-5 cis-1,3-Dichloropropene ND 2000 2180 109 2000 2010 101 8 61-125/1510061-02-6 trans-1,3-Dichloropropene ND 2000 2370 119 2000 2180 109 8 59-128/14542-75-6 1,3-Dichloropropene (total) ND 4000 4550 114 4000 4190 105 8 61-126/14100-41-4 Ethylbenzene 1490 2000 3880 120 2000 3670 109 6 50-147/1567-72-1 Hexachloroethane ND 2000 2330 117 2000 2140 107 9 42-122/2178-83-1 Isobutyl Alcohol ND 20000 23400 117 20000 24100 121 3 6-168/4174-83-9 Methyl Bromide ND 2000 1510 76 2000 1540 77 2 24-163/2874-87-3 Methyl Chloride ND 2000 685 34* 2000 659 33* 4 37-151/2275-09-2 Methylene Chloride ND 2000 2250 113 2000 2030 102 10 63-137/1678-93-3 Methyl Ethyl Ketone ND 5000 6110 122 5000 5580 112 9 35-137/21108-10-1 4-Methyl-2-pentanone ND 5000 6400 128 5000 5800 116 10 48-146/211634-04-4 Methyl Tert Butyl Ether ND 2000 2310 116 2000 2160 108 7 48-143/15100-42-5 Styrene ND 2000 2110 106 2000 1950 98 8 58-140/18630-20-6 1,1,1,2-Tetrachloroethane ND 2000 2240 112 2000 2050 103 9 67-127/1579-34-5 1,1,2,2-Tetrachloroethane ND 2000 2250 113 2000 2130 107 5 62-139/16


81 of 182

LA58360

55.4.3




LA58360-1, LA58360-2


127-18-4 Tetrachloroethylene ND 2000 2170 109 2000 1950 98 11 68-127/19108-88-3 Toluene 828 2000 2780 98 2000 2650 91 5 40-153/1571-55-6 1,1,1-Trichloroethane ND 2000 2390 120 2000 2190 110 9 68-132/1879-00-5 1,1,2-Trichloroethane ND 2000 2190 110 2000 2090 105 5 62-137/1679-01-6 Trichloroethylene ND 2000 2180 109 2000 2050 103 6 67-124/1675-69-4 Trichlorofluoromethane ND 2000 1870 94 2000 1770 89 5 65-134/1775-01-4 Vinyl Chloride ND 2000 1730 87 2000 1920 96 10 60-133/16





82 of 182

LA58360

55.4.3


MS Semi-volatiles

QC Data Summaries



Scott, LASection 6

83 of 182

LA58360

6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15372-MB C0051513.D 1 10/19/19 PC 10/15/19 OP15372 EC2055


LA58360-6, LA58360-7


95-48-7 2-Methylphenol ND 50 ug/l3&4-Methylphenol ND 50 ug/l

87-86-5 Pentachlorophenol ND 100 ug/l95-95-4 2,4,5-Trichlorophenol ND 50 ug/l88-06-2 2,4,6-Trichlorophenol ND 50 ug/l106-46-7 1,4-Dichlorobenzene ND 50 ug/l121-14-2 2,4-Dinitrotoluene ND 50 ug/l118-74-1 Hexachlorobenzene ND 50 ug/l87-68-3 Hexachlorobutadiene ND 50 ug/l67-72-1 Hexachloroethane ND 50 ug/l98-95-3 Nitrobenzene ND 50 ug/l110-86-1 Pyridine ND 50 ug/l



84 of 182

LA58360

66.1.1




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


95-57-8 2-Chlorophenol ND 5.0 ug/l120-83-2 2,4-Dichlorophenol ND 5.0 ug/l105-67-9 2,4-Dimethylphenol ND 5.0 ug/l51-28-5 2,4-Dinitrophenol ND 20 ug/l100-02-7 4-Nitrophenol ND 25 ug/l87-86-5 Pentachlorophenol ND 10 ug/l108-95-2 Phenol ND 5.0 ug/l58-90-2 2,3,4,6-Tetrachlorophenol ND 5.0 ug/l95-95-4 2,4,5-Trichlorophenol ND 5.0 ug/l88-06-2 2,4,6-Trichlorophenol ND 5.0 ug/l83-32-9 Acenaphthene ND 0.20 ug/l208-96-8 Acenaphthylene ND 0.20 ug/l62-53-3 Aniline ND 5.0 ug/l120-12-7 Anthracene ND 0.20 ug/l56-55-3 Benzo(a)anthracene ND 0.20 ug/l50-32-8 Benzo(a)pyrene ND 0.20 ug/l205-99-2 Benzo(b)fluoranthene ND 0.20 ug/l207-08-9 Benzo(k)fluoranthene ND 0.20 ug/l92-52-4 1,1' -Biphenyl ND 10 ug/l85-68-7 Butyl Benzyl Phthalate ND 5.0 ug/l106-47-8 4-Chloroaniline ND 5.0 ug/l111-44-4 bis(2-Chloroethyl)ether ND 5.0 ug/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 5.0 ug/l91-58-7 2-Chloronaphthalene ND 5.0 ug/l218-01-9 Chrysene ND 0.20 ug/l53-70-3 Dibenzo(a,h)anthracene ND 0.20 ug/l132-64-9 Dibenzofuran ND 5.0 ug/l91-94-1 3,3' -Dichlorobenzidine ND 10 ug/l84-66-2 Diethyl Phthalate 0.068 5.0 ug/l J131-11-3 Dimethyl Phthalate ND 5.0 ug/l117-84-0 Di-n-octyl Phthalate ND 5.0 ug/l99-65-0 1,3-Dinitrobenzene ND 5.0 ug/l121-14-2 2,4-Dinitrotoluene ND 5.0 ug/l606-20-2 2,6-Dinitrotoluene ND 5.0 ug/l117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 ug/l206-44-0 Fluoranthene ND 0.20 ug/l

85 of 182

LA58360

66.1.2




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5





86 of 182

LA58360

66.1.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15372-BS C0051514.D 1 10/19/19 PC 10/15/19 OP15372 EC2055OP15372-BSD C0051515.D 1 10/19/19 PC 10/15/19 OP15372 EC2055


LA58360-6, LA58360-7


95-48-7 2-Methylphenol 500 328 66 308 62 6 54-97/183&4-Methylphenol 500 325 65 300 60 8 47-92/19

87-86-5 Pentachlorophenol 500 503 101 490 98 3 52-120/2995-95-4 2,4,5-Trichlorophenol 500 482 96 461 92 4 67-119/2188-06-2 2,4,6-Trichlorophenol 500 514 103 503 101 2 67-120/21106-46-7 1,4-Dichlorobenzene 500 363 73 351 70 3 52-109/28121-14-2 2,4-Dinitrotoluene 500 490 98 484 97 1 73-122/21118-74-1 Hexachlorobenzene 500 484 97 471 94 3 67-117/2387-68-3 Hexachlorobutadiene 500 397 79 385 77 3 42-120/3567-72-1 Hexachloroethane 500 371 74 362 72 2 44-115/3298-95-3 Nitrobenzene 500 502 100 503 101 0 69-116/21110-86-1 Pyridine 500 205 41 207 41 1 5-78/50




87 of 182

LA58360

66.2.1




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


95-57-8 2-Chlorophenol 5 5.3 106 5.9 118 11 48-123/17120-83-2 2,4-Dichlorophenol 5 5.9 118 7.0 140* a 17 52-135/17105-67-9 2,4-Dimethylphenol 5 5.7 114 5.7 114 0 47-132/2151-28-5 2,4-Dinitrophenol 25 29.5 118 34.8 139 16 32-139/25100-02-7 4-Nitrophenol 25 23.1 92 23.6 94 2 15-105/2287-86-5 Pentachlorophenol 25 28.4 114 32.3 129 13 51-131/19108-95-2 Phenol 5 3.4 68 3.8 76 11 19-92/2358-90-2 2,3,4,6-Tetrachlorophenol 5 5.8 116 7.0 140* a 19 57-136/1995-95-4 2,4,5-Trichlorophenol 5 6.0 120 6.8 136 13 51-143/1788-06-2 2,4,6-Trichlorophenol 5 5.9 118 6.7 134* a 13 59-132/1983-32-9 Acenaphthene 5 5.1 102 5.4 108 6 50-120/16208-96-8 Acenaphthylene 5 5.0 100 2.1 42* b 82* c 48-126/1662-53-3 Aniline 5 0.080 2* b 0.075 2* b 6 10-112/50120-12-7 Anthracene 5 5.5 110 5.2 104 6 53-128/1656-55-3 Benzo(a)anthracene 5 5.5 110 5.9 118 7 54-129/1950-32-8 Benzo(a)pyrene 5 5.4 108 4.0 80 30* c 55-135/19205-99-2 Benzo(b)fluoranthene 5 5.7 114 6.8 136 18 54-139/23207-08-9 Benzo(k)fluoranthene 5 5.7 114 6.8 136* a 18 58-132/2292-52-4 1,1' -Biphenyl 5 5.2 104 5.8 116 11 44-127/1785-68-7 Butyl Benzyl Phthalate 5 6.2 124 6.2 124 0 63-141/20106-47-8 4-Chloroaniline 5 0.30 6* b ND 0* b 200* c 19-126/38111-44-4 bis(2-Chloroethyl)ether 5 5.4 108 6.0 120 11 45-123/17108-60-1 2,2' -Oxybis(1-chloropropane) 5 5.2 104 5.8 116 11 29-126/1791-58-7 2-Chloronaphthalene 5 5.2 104 5.8 116 11 44-123/20218-01-9 Chrysene 5 5.5 110 6.1 122 10 57-127/2053-70-3 Dibenzo(a,h)anthracene 5 5.9 118 7.0 140 17 58-141/21132-64-9 Dibenzofuran 5 5.3 106 6.0 120 12 48-126/1791-94-1 3,3' -Dichlorobenzidine 5 ND 0* b ND 0* b nc 10-188/4084-66-2 Diethyl Phthalate 5 5.4 108 5.9 118 9 54-133/17131-11-3 Dimethyl Phthalate 5 5.5 110 6.2 124 12 56-132/17117-84-0 Di-n-octyl Phthalate 5 5.7 114 7.0 140* a 20 66-139/2199-65-0 1,3-Dinitrobenzene 25 28.5 114 32.3 129 13 64-133/16121-14-2 2,4-Dinitrotoluene 5 6.0 120 6.6 132 10 67-132/20606-20-2 2,6-Dinitrotoluene 5 5.7 114 6.5 130 13 56-138/20117-81-7 bis(2-Ethylhexyl)phthalate 5 6.4 128 7.0 140 9 60-142/20206-44-0 Fluoranthene 5 5.6 112 5.7 114 2 57-133/18


88 of 182

LA58360

66.2.2




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


86-73-7 Fluorene 5 5.5 110 6.0 120 9 52-125/15118-74-1 Hexachlorobenzene 5 5.3 106 5.9 118 11 47-127/2187-68-3 Hexachlorobutadiene 5 5.5 110 5.5 110 0 14-121/3077-47-4 Hexachlorocyclopentadiene 5 1.3 26 1.6 32 21 10-114/31193-39-5 Indeno(1,2,3-cd)pyrene 5 5.7 114 6.6 132 15 58-142/1978-59-1 Isophorone 5 5.6 112 6.4 128 13 52-130/1891-57-6 2-Methylnaphthalene 5 5.6 112 6.3 126* a 12 43-123/1891-20-3 Naphthalene 5 5.5 110 5.9 118 7 45-120/1688-74-4 2-Nitroaniline 25 27.4 110 1.5 6* b 179* c 63-132/1799-09-2 3-Nitroaniline 25 1.4 6* b ND 0* b 200* c 31-144/23100-01-6 4-Nitroaniline 25 14.5 58 0.84 3* b 178* c 22-154/2598-95-3 Nitrobenzene 5 6.2 124 6.7 134* a 8 52-128/17621-64-7 N-Nitroso-di-n-propylamine 5 5.3 106 6.1 122 14 48-129/2086-30-6 N-Nitrosodiphenylamine 5 2.5 50 0.13 3* b 180* c 26-146/2885-01-8 Phenanthrene 5 5.4 108 5.8 116 7 54-124/17129-00-0 Pyrene 5 5.6 112 2.8 56 67* c 56-132/1995-94-3 1,2,4,5-Tetrachlorobenzene 5 5.0 100 5.4 108 8 33-121/24120-82-1 1,2,4-Trichlorobenzene 5 5.3 106 5.6 112 6 34-118/23



(a) Outside control limits biased high. Analyte not detected in associated samples.(b) Outside control limits biased low. Unable to re-extract associated samples due to expired sample holding

time.(c) Analytical precision exceeds laboratory control limits.


89 of 182

LA58360

66.2.2

Matrix Spike Summary Page 1 of 1Job Number: LA58360Account: PROVLABR Providence Engineering & EnvironmentalProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15372-MS C0051516.D 1 10/19/19 PC 10/15/19 OP15372 EC2055LA58350-1 C0051522.D 1 10/19/19 PC 10/15/19 OP15372 EC2055


LA58360-6, LA58360-7

LA58350-1 Spike MS MSCAS No. Compound ug/l Q ug/l ug/l % Limits

95-48-7 2-Methylphenol ND 500 329 66 54-973&4-Methylphenol ND 500 308 62 47-92

87-86-5 Pentachlorophenol ND 500 474 95 52-12095-95-4 2,4,5-Trichlorophenol ND 500 452 90 67-11988-06-2 2,4,6-Trichlorophenol ND 500 500 100 67-120106-46-7 1,4-Dichlorobenzene ND 500 353 71 52-109121-14-2 2,4-Dinitrotoluene ND 500 479 96 73-122118-74-1 Hexachlorobenzene ND 500 477 95 67-11787-68-3 Hexachlorobutadiene ND 500 371 74 42-12067-72-1 Hexachloroethane ND 500 355 71 44-11598-95-3 Nitrobenzene ND 500 512 102 69-116110-86-1 Pyridine ND 500 252 50 5-78

CAS No. Surrogate Recoveries MS LA58350-1 Limits



90 of 182

LA58360

66.3.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15355-MS L0029708.D 1 10/14/19 AA 10/13/19 OP15355 EL787LA58344-14 L0029758.D 1 10/23/19 PC 10/13/19 OP15355 EL789


LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


95-57-8 2-Chlorophenol ND 4.63 4.4 95 47-126120-83-2 2,4-Dichlorophenol ND 4.63 5.2 112 49-137105-67-9 2,4-Dimethylphenol ND 4.63 4.7 102 49-12351-28-5 2,4-Dinitrophenol ND 23.1 25.8 111 37-146100-02-7 4-Nitrophenol ND 23.1 17.2 74 19-9787-86-5 Pentachlorophenol ND 23.1 25.2 109 46-146108-95-2 Phenol 0.045 4.63 2.5 53 20-8758-90-2 2,3,4,6-Tetrachlorophenol ND 4.63 5.5 119 61-13795-95-4 2,4,5-Trichlorophenol ND 4.63 5.5 119 61-13388-06-2 2,4,6-Trichlorophenol ND 4.63 5.3 114 61-13383-32-9 Acenaphthene ND 4.63 4.5 97 43-122208-96-8 Acenaphthylene ND 4.63 4.6 99 48-12162-53-3 Aniline ND 4.63 0.057 1* a 10-110120-12-7 Anthracene ND 4.63 4.9 106 46-13756-55-3 Benzo(a)anthracene ND 4.63 4.9 106 54-13050-32-8 Benzo(a)pyrene ND 4.63 5.0 108 60-129205-99-2 Benzo(b)fluoranthene ND 4.63 5.1 110 56-136207-08-9 Benzo(k)fluoranthene ND 4.63 5.1 110 53-13892-52-4 1,1' -Biphenyl ND 4.63 4.2 91 40-12685-68-7 Butyl Benzyl Phthalate ND 4.63 5.9 127 63-144106-47-8 4-Chloroaniline ND 4.63 1.5 32 10-122111-44-4 bis(2-Chloroethyl)ether ND 4.63 4.5 97 30-135108-60-1 2,2' -Oxybis(1-chloropropane) ND 4.63 4.3 93 22-13091-58-7 2-Chloronaphthalene ND 4.63 4.2 91 43-117218-01-9 Chrysene ND 4.63 4.7 102 57-12653-70-3 Dibenzo(a,h)anthracene ND 4.63 5.2 112 51-142132-64-9 Dibenzofuran ND 4.63 4.6 99 34-14291-94-1 3,3' -Dichlorobenzidine ND 4.63 6.4 138* a 10-12684-66-2 Diethyl Phthalate 0.30 4.63 5.4 110 53-130131-11-3 Dimethyl Phthalate 0.028 4.63 5.2 112 53-134117-84-0 Di-n-octyl Phthalate 1.9 4.63 5.0 67 62-14299-65-0 1,3-Dinitrobenzene ND 23.1 27.1 117 60-132121-14-2 2,4-Dinitrotoluene ND 4.63 5.5 119 65-132606-20-2 2,6-Dinitrotoluene 0.039 4.63 5.4 116 60-130117-81-7 bis(2-Ethylhexyl)phthalate ND 4.63 5.8 125 52-152206-44-0 Fluoranthene ND 4.63 5.1 110 46-144


91 of 182

LA58360

66.3.2




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


86-73-7 Fluorene ND 4.63 4.8 104 50-122118-74-1 Hexachlorobenzene ND 4.63 3.9 84 34-13287-68-3 Hexachlorobutadiene ND 4.63 3.0 65 13-11077-47-4 Hexachlorocyclopentadiene ND 4.63 0.82 18 10-100193-39-5 Indeno(1,2,3-cd)pyrene ND 4.63 5.1 110 54-13978-59-1 Isophorone ND 4.63 5.0 108 54-12591-57-6 2-Methylnaphthalene ND 4.63 4.2 91 39-12191-20-3 Naphthalene 0.018 4.63 4.1 88 39-12288-74-4 2-Nitroaniline ND 23.1 27.2 118 59-13399-09-2 3-Nitroaniline ND 23.1 28.0 121 17-135100-01-6 4-Nitroaniline ND 23.1 31.7 137* a 12-13398-95-3 Nitrobenzene ND 4.63 5.4 117 44-141621-64-7 N-Nitroso-di-n-propylamine ND 4.63 4.7 102 37-13986-30-6 N-Nitrosodiphenylamine ND 4.63 4.2 91 38-13485-01-8 Phenanthrene 0.014 4.63 4.8 103 37-135129-00-0 Pyrene 0.0091 4.63 5.2 112 44-14295-94-3 1,2,4,5-Tetrachlorobenzene ND 4.63 3.4 73 30-114120-82-1 1,2,4-Trichlorobenzene ND 4.63 3.5 76 30-114





92 of 182

LA58360

66.3.2


GC Volatiles

QC Data Summaries



Scott, LASection 7

93 of 182

LA58360

7


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLC2394-MB2 LC053062.D 1 10/21/19 NN n/a n/a GLC2394

The QC reported here applies to the following samples: Method: MADEP VPH REV 1.1

LA58360-1


Aliphatics C6-C8 (Unadj.) ND 30 ug/lAliphatics > C8-C10 (Unadj.) 7.9 50 ug/l JAromatics > C8-C10 (Unadj.) 8.6 50 ug/l J




94 of 182

LA58360

77.1.1




LA58360-1, LA58360-4, LA58360-5





95 of 182

LA58360

77.1.2




LA58360-2, LA58360-3





96 of 182

LA58360

77.1.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLC2394-BS1 LC053057.D 1 10/21/19 NN n/a n/a GLC2394GLC2394-BSD1 LC053058.D 1 10/21/19 NN n/a n/a GLC2394


LA58360-1


Aliphatics C6-C8 (Unadj.) 150 164 109 152 101 8 70-130/30Aliphatics > C8-C10 (Unadj.) 250 276 110 260 104 6 70-130/30Aromatics > C8-C10 (Unadj.) 250 269 108 251 100 7 70-130/30


615-59-8 2,5-Dibromotoluene 97% a 95% a 70-130%615-59-8 2,5-Dibromotoluene 93% b 92% b 70-130%



97 of 182

LA58360

77.2.1




LA58360-1, LA58360-4, LA58360-5


TPH-GRO (C6-C10) 1 0.963 96 0.945 95 2 81-119/10




98 of 182

LA58360

77.2.2




LA58360-2, LA58360-3


TPH-GRO (C6-C10) 1 0.997 100 0.972 97 3 81-119/10




99 of 182

LA58360

77.2.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58360-1MS LC053084.D 20 10/22/19 NN n/a n/a GLC2394LA58360-1MSD LC053085.D 20 10/22/19 NN n/a n/a GLC2394LA58360-1 LC053080.D 1 10/21/19 NN n/a n/a GLC2394


LA58360-1


Aliphatics C6-C8 (Unadj.) 40.7 3000 3050 100 3000 3110 102 2 70-130/50Aliphatics > C8-C10 (Unadj.) 137 5000 5190 101 5000 5280 103 2 70-130/50Aromatics > C8-C10 (Unadj.) 106 5000 5430 106 5000 5220 102 4 70-130/50


615-59-8 2,5-Dibromotoluene 94% a 97% a 106% a 70-130%615-59-8 2,5-Dibromotoluene 92% b 96% b 107% b 70-130%



100 of 182

LA58360

77.3.1




LA58360-1, LA58360-4, LA58360-5


TPH-GRO (C6-C10) 0.634 20 17.4 84 20 17.8 86 2 40-149/10




101 of 182

LA58360

77.3.2




LA58360-2, LA58360-3


TPH-GRO (C6-C10) ND 20 17.0 85 20 16.7 84 2 40-149/10




102 of 182

LA58360

77.3.3



QC Data Summaries



Scott, LASection 8

103 of 182

LA58360

8


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-MB X0012233.D 1 10/19/19 LS 10/17/19 OP15390 GLB2101

The QC reported here applies to the following samples: Method: MADEP EPH REV 1.1

LA58360-1


Aromatics > C10-C12 (Unadj.))ND 140 ug/lAromatics > C12-C16 (Unadj.))ND 140 ug/lAromatics > C16-C21 (Unadj.))ND 140 ug/lAromatics > C21-C35 (Unadj.))ND 140 ug/l


84-15-1 o-Terphenyl 91% 40-140%321-60-8 2-Fluorobiphenyl 84% 40-140%

104 of 182

LA58360

88.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-MB Y0012233.D 1 10/19/19 LS 10/17/19 OP15390 GLB2102


LA58360-1


Aliphatics > C10-C12 (Unadj.)) ND 140 ug/lAliphatics > C12-C16 (Unadj.)) ND 140 ug/lAliphatics > C16-C35 (Unadj.)) ND 140 ug/l


3386-33-2 1-Chlorooctadecane 89% 40-140%

105 of 182

LA58360

88.1.2




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5




84-15-1 o-Terphenyl 96% 40-118%

106 of 182

LA58360

88.1.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-BS X0012234.D 1 10/19/19 LS 10/17/19 OP15390 GLB2101OP15390-BSD X0012235.D 1 10/19/19 LS 10/17/19 OP15390 GLB2101


LA58360-1


Aromatics > C10-C12 (Unadj.)461 371 80 366 79 1 40-140/30Aromatics > C12-C16 (Unadj.)1380 1080 78 1060 76 2 40-140/30Aromatics > C16-C21 (Unadj.)2310 1780 77 1780 77 0 40-140/30Aromatics > C21-C35 (Unadj.)3690 3340 91 3320 90 1 40-140/30


84-15-1 o-Terphenyl 82% 82% 40-140%321-60-8 2-Fluorobiphenyl 81% 77% 40-140%


107 of 182

LA58360

88.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-BS Y0012234.D 1 10/19/19 LS 10/17/19 OP15390 GLB2102OP15390-BSD Y0012235.D 1 10/19/19 LS 10/17/19 OP15390 GLB2102


LA58360-1


Aliphatics > C10-C12 (Unadj.) 461 271 59 345 75 24 40-140/30Aliphatics > C12-C16 (Unadj.) 923 538 58 688 74 24 40-140/30Aliphatics > C16-C35 (Unadj.) 4150 2270 55 2970 71 27 40-140/30


3386-33-2 1-Chlorooctadecane 61% 79% 40-140%


108 of 182

LA58360

88.2.2




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


TPH-DRO (C10-C28) 11.1 9.40 85 9.87 89 5 72-112/18


84-15-1 o-Terphenyl 95% 99% 40-118%


109 of 182

LA58360

88.2.3




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


TPH-ORO (C28-C35) 4.48 8.15 182* a 8.10 182* a 1 60-112/18


84-15-1 o-Terphenyl 95% 94% 40-118%



110 of 182

LA58360

88.2.4




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


TPH-DRO (C10-C28) ND 11.2 9.66 86 11 9.34 85 3 41-136/29


84-15-1 o-Terphenyl 95% 94% 98% 40-118%


111 of 182

LA58360

88.3.1




LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


TPH-ORO (C28-C35) ND 4.49 17.4 194* a 4.44 8.26 186* b 4 c 20-135/18


84-15-1 o-Terphenyl 104% 101% 98% 40-118%



112 of 182

LA58360

88.3.2


Metals Analysis

QC Data Summaries



Scott, LASection 9

113 of 182

LA58360

9





Prep Date: 10/10/19

MB

10/10/19


Mercury 0.20 .056 .081 -0.039 <0.20

Associated samples MP16573: LA58360-1, LA58360-2, LA58360-3, LA58360-4, LA58360-5


_________________________________________________________________________________________________________

Page 1

114 of 182

LA58360

99.1.1





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Mercury 0.0 5.6 5 112.0 75-125



_________________________________________________________________________________________________________

Page 1

115 of 182

LA58360

99.1.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Mercury 0.0 5.8 5 116.0 3.5 20



_________________________________________________________________________________________________________

Page 2

116 of 182

LA58360

99.1.2





Prep Date: 10/10/19

BSP Spikelot

10/10/19


Mercury 5.0 5 100.0 80-120



_________________________________________________________________________________________________________

Page 1

117 of 182

LA58360

99.1.3





Prep Date: 10/10/19

LA58344-14

10/10/19


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

Page 1

118 of 182

LA58360

99.1.4





Prep Date: 10/10/19

MB

10/10/19



Antimony 1.0 .0063 .34 0.025 <1.0

Arsenic 1.0 .062 .26 0.19 <1.0

Barium 1.0 .0089 .46 -0.0043 <1.0

Beryllium 1.0 .0096 .28 -0.21 <1.0

Boron 20 1.5 2.9

Cadmium 0.50 .0081 .12 0.029 <0.50

Calcium 100 4.7 20

Cerium 1.0 .0019 .16

Chromium 1.0 .059 .15 -0.071 <1.0

Cobalt 1.0 .0082 .14 -0.15 <1.0

Copper 1.0 .27 .74 -0.24 <1.0

Iron 100 2.8 16

Lanthanum 1.0 .0019 .41

Lithium 2.0 .3 .61

Lead 1.0 .0045 .13 -0.085 <1.0




Nickel 1.0 .081 .2 -0.091 <1.0

Potassium 100 5 7.6

Selenium 5.0 .3 3.1 -0.15 <5.0

Silver 1.0 .0088 .13 -0.044 <1.0

Silicon 500 7.6 130

Sodium 100 8.6 9.9


Thallium 1.0 .03 .86 -0.11 <1.0

Tin 2.0 .059 .19

Titanium 1.0 .095 .77

Uranium 1.0 .0019 .17

Vanadium 1.0 .035 .1 0.11 <1.0

Zinc 5.0 1.5 1.1 -1.2 <5.0


_________________________________________________________________________________________________________

Page 1

119 of 182

LA58360

99.2.1





Prep Date: 10/10/19

MB

10/10/19



_________________________________________________________________________________________________________

Page 2

120 of 182

LA58360

99.2.1





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Aluminum anr

Antimony 0.28 97.1 100 96.8 75-125

Arsenic 3.1 91.4 100 88.3 75-125

Barium 292 431 100 139.0N(a 75-125

Beryllium 0.0 83.5 100 83.5 75-125

Boron

Cadmium 0.43 96.0 100 95.6 75-125

Calcium anr

Cerium

Chromium 3.9 106 100 102.1 75-125

Cobalt 4.4 108 100 103.6 75-125

Copper 3.7 92.3 100 88.6 75-125

Iron anr

Lanthanum

Lithium anr

Lead 2.2 97.1 100 94.9 75-125

Magnesium anr

Manganese anr

Molybdenum

Nickel 5.7 99.6 100 93.9 75-125

Potassium anr

Selenium 4.0 395 500 78.2 75-125

Silver 0.0 101 100 101.0 75-125

Silicon

Sodium anr

Strontium anr

Thallium 0.087 96.0 100 95.9 75-125

Tin

Titanium

Uranium

Vanadium 7.0 107 100 100.0 75-125

Zinc 11.7 95.8 100 84.1 75-125


_________________________________________________________________________________________________________

Page 1

121 of 182

LA58360

99.2.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Spike recovery indicates possible matrix interference or sample non-homogeneity.

_________________________________________________________________________________________________________

Page 2

122 of 182

LA58360

99.2.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Aluminum anr

Antimony 0.28 95.4 100 95.1 1.8 20

Arsenic 3.1 93.1 100 90.0 1.8 20

Barium 292 416 100 124.0 3.5 20

Beryllium 0.0 82.6 100 82.6 1.1 20

Boron

Cadmium 0.43 97.8 100 97.4 1.9 20

Calcium anr

Cerium

Chromium 3.9 109 100 105.1 2.8 20

Cobalt 4.4 110 100 105.6 1.8 20

Copper 3.7 93.9 100 90.2 1.7 20

Iron anr

Lanthanum

Lithium anr

Lead 2.2 96.4 100 94.2 0.7 20

Magnesium anr

Manganese anr

Molybdenum

Nickel 5.7 102 100 96.3 2.4 20

Potassium anr

Selenium 4.0 405 500 80.2 2.5 20

Silver 0.0 103 100 103.0 2.0 20

Silicon

Sodium anr

Strontium anr

Thallium 0.087 98.0 100 97.9 2.1 20

Tin

Titanium

Uranium

Vanadium 7.0 111 100 104.0 3.7 20

Zinc 11.7 98.1 100 86.4 2.4 20


_________________________________________________________________________________________________________

Page 3

123 of 182

LA58360

99.2.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19



_________________________________________________________________________________________________________

Page 4

124 of 182

LA58360

99.2.2





Prep Date: 10/10/19

BSP Spikelot

10/10/19


Aluminum anr

Antimony 105 100 105.0 80-120

Arsenic 99.5 100 99.5 80-120

Barium 102 100 102.0 80-120

Beryllium 91.5 100 91.5 80-120

Boron

Cadmium 104 100 104.0 80-120

Calcium anr

Cerium

Chromium 112 100 112.0 80-120

Cobalt 113 100 113.0 80-120

Copper 103 100 103.0 80-120

Iron anr

Lanthanum

Lithium anr

Lead 106 100 106.0 80-120

Magnesium anr

Manganese anr

Molybdenum

Nickel 108 100 108.0 80-120

Potassium anr

Selenium 459 500 91.8 80-120

Silver 98.3 100 98.3 80-120

Silicon

Sodium anr

Strontium anr

Thallium 106 100 106.0 80-120

Tin

Titanium

Uranium

Vanadium 109 100 109.0 80-120

Zinc 108 100 108.0 80-120


_________________________________________________________________________________________________________

Page 1

125 of 182

LA58360

99.2.3





Prep Date: 10/10/19

BSP Spikelot

10/10/19



_________________________________________________________________________________________________________

Page 2

126 of 182

LA58360

99.2.3





Prep Date: 10/10/19

LA58344-14

10/10/19


Aluminum anr

Antimony 0.277 0.470 69.6 (a) 0-10

Arsenic 3.10 3.90 25.8 (a) 0-10

Barium 292 289 1.2 0-10


Boron

Cadmium 0.433 0.529 22.1*(b) 0-10

Calcium anr

Cerium

Chromium 3.91 4.41 12.9*(b) 0-10

Cobalt 4.42 3.89 12.1*(b) 0-10

Copper 3.71 3.05 17.6 (a) 0-10

Iron anr

Lanthanum

Lithium anr

Lead 2.16 1.88 13.1*(b) 0-10

Magnesium anr

Manganese anr

Molybdenum

Nickel 5.72 5.52 3.6 0-10

Potassium anr

Selenium 3.98 4.07 2.2 0-10

Silver 0.00 0.00 NC 0-10

Silicon

Sodium anr

Strontium anr

Thallium 0.0875 0.00 100.0(a) 0-10

Tin

Titanium

Uranium

Vanadium 6.95 7.11 2.2 0-10

Zinc 11.7 17.6 50.4 (a) 0-10


_________________________________________________________________________________________________________

Page 1

127 of 182

LA58360

99.2.4





Prep Date: 10/10/19

LA58344-14

10/10/19


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).(b) Serial dilution indicates possible matrix interference.

_________________________________________________________________________________________________________

Page 2

128 of 182

LA58360

99.2.4





Prep Date: 10/10/19


10/10/19


Barium 2 10 292.1 58.42 152 0.1 10 100 93.6 75-125

Boron

Cerium

Lanthanum

Molybdenum

Silicon

Tin

Titanium

Uranium



_________________________________________________________________________________________________________

Page 1

129 of 182

LA58360

99.2.5




QC Batch ID: MP16588 Methods: SW846 6010C Matrix Type: LEACHATE Units: mg/l

Prep Date: 10/11/19

MB

10/11/19


Aluminum 0.50 .03 .28

Antimony 0.50 .0071 .015

Arsenic 0.50 .014 .018 -0.0015 <0.50

Barium 5.0 .0005 .02 0.0031 <5.0

Beryllium 0.50 .0003 .0015

Boron 0.50 .0026 .15

Cadmium 0.50 .00075 .002 -0.0015 <0.50

Calcium 0.50 .093 .46

Chromium 0.50 .0017 .01 0.00040 <0.50

Cobalt 0.50 .0016 .0085

Copper 0.50 .0022 .019

Iron 0.50 .01 .086

Lead 0.50 .0054 .016 0.0083 <0.50

Lithium 0.50 .0055 .04

Magnesium 0.50 .078 .45

Manganese 0.50 .0008 .006

Molybdenum 0.50 .00075 .005

Nickel 0.50 .0033 .025

Potassium 2.5 .068 1.1

Selenium 0.50 .012 .023 0.0077 <0.50

Silver 0.50 .0021 .014 -0.0039 <0.50

Sodium 2.5 .026 .87

Strontium 0.50 .00025 .016

Thallium 0.50 .0067 .026

Tin 0.50 .0036 .012

Titanium 0.50 .0014 .012

Vanadium 0.50 .001 .012

Zinc 0.50 .0065 .019

Associated samples MP16588: LA58360-6, LA58360-7


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99.3.1





Prep Date: 10/11/19 10/11/19

TD45908-1 Spikelot

10/11/19

QC TD45908-1

10/11/19

QCMetal Original MS ICPSPIKE1% Rec Limits Original DUP RPD Limits

Aluminum

Antimony

Arsenic 0.0 10.1 10.0 101.0 75-125 0.0 0.0 NC 0-20

Barium 0.21 9.1 10. 88.9 75-125 0.21 0.21 0.0 0-20

Beryllium

Boron

Cadmium 0.0 10.2 10.0 102.0 75-125 0.0 0.0 NC 0-20

Calcium

Chromium 0.0085 9.0 10. 89.9 75-125 0.0085 0.0076 11.2 0-20

Cobalt

Copper

Iron

Lead 0.0083 9.8 10. 97.9 75-125 0.0083 0.014 51.1 (a) 0-20

Lithium

Magnesium

Manganese

Molybdenum

Nickel anr

Potassium

Selenium 0.0 10.0 10.0 100.0 75-125 0.0 0.0 NC 0-20

Silver 0.0 9.1 10. 91.0 75-125 0.0 0.0 NC 0-20

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium anr

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) RPD acceptable due to low duplicate and sample concentrations.

_________________________________________________________________________________________________________

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131 of 182

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Prep Date: 10/11/19

BSP Spikelot

10/11/19

QCMetal Result ICPSPIKE1% Rec Limits

Aluminum

Antimony

Arsenic 10.0 10.0 100.0 80-120

Barium 9.0 10. 90.0 80-120

Beryllium

Boron

Cadmium 10.1 10.0 101.0 80-120

Calcium

Chromium 8.8 10. 88.0 80-120

Cobalt

Copper

Iron

Lead 9.6 10. 96.0 80-120

Lithium

Magnesium

Manganese

Molybdenum

Nickel anr

Potassium

Selenium 10 10. 100.0 80-120

Silver 9.0 10. 90.0 80-120

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium anr

Zinc



_________________________________________________________________________________________________________

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132 of 182

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99.3.3




QC Batch ID: MP16588 Methods: SW846 6010C Matrix Type: LEACHATE Units: ug/l

Prep Date: 10/11/19

TD45908-1

10/11/19


Aluminum

Antimony

Arsenic 0.00 0.00 NC 0-10

Barium 41.4 42.3 2.1 0-10

Beryllium

Boron

Cadmium 0.00 0.00 NC 0-10

Calcium

Chromium 1.70 0.00 100.0(a) 0-10

Cobalt

Copper

Iron

Lead 1.65 0.00 100.0(a) 0-10

Lithium

Magnesium

Manganese

Molybdenum

Nickel anr

Potassium

Selenium 0.00 0.00 NC 0-10

Silver 0.00 0.00 NC 0-10

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium anr

Zinc



_________________________________________________________________________________________________________

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133 of 182

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99.3.4





Prep Date: 10/14/19

MB

10/14/19


Mercury 0.020 .0017 .0024 -0.000085<0.020



_________________________________________________________________________________________________________

Page 1

134 of 182

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99.4.1





Prep Date: 10/14/19

TD45908-1 Spikelot

10/14/19


Mercury 0.0 0.14 0.15 93.3 75-125



_________________________________________________________________________________________________________

Page 1

135 of 182

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99.4.2





Prep Date: 10/14/19

TD45908-1 Spikelot

10/14/19


Mercury 0.0 0.14 0.15 93.3 0.0 20



_________________________________________________________________________________________________________

Page 2

136 of 182

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99.4.2





Prep Date: 10/14/19

BSP Spikelot

10/14/19


Mercury 0.14 0.15 93.3 80-120



_________________________________________________________________________________________________________

Page 1

137 of 182

LA58360

99.4.3





Prep Date: 10/14/19

TD45908-1

10/14/19


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

Page 1

138 of 182

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99.4.4





Prep Date: 10/21/19

MB

10/21/19



Antimony 1.0 .0063 .34 0.28 <1.0

Arsenic 1.0 .062 .26 0.066 <1.0

Barium 1.0 .0089 .46 0.22 <1.0

Beryllium 1.0 .0096 .28 -0.17 <1.0

Boron 20 1.5 2.9

Cadmium 0.50 .0081 .12 0.061 <0.50

Calcium 100 4.7 20

Cerium 1.0 .0019 .16

Chromium 1.0 .059 .15 0.033 <1.0

Cobalt 1.0 .0082 .14 -0.0036 <1.0

Copper 1.0 .27 .74 -0.18 <1.0

Iron 100 2.8 16

Lanthanum 1.0 .0019 .41

Lithium 2.0 .3 .61

Lead 1.0 .0045 .13 -0.14 <1.0




Nickel 1.0 .081 .2 -0.069 <1.0

Potassium 100 5 7.6

Selenium 5.0 .3 3.1 -0.82 <5.0

Silver 1.0 .0088 .13 -0.0054 <1.0

Silicon 500 7.6 130

Sodium 100 8.6 9.9


Thallium 1.0 .03 .86 -0.13 <1.0

Tin 2.0 .059 .19

Titanium 1.0 .095 .77

Uranium 1.0 .0019 .17

Vanadium 1.0 .035 .1 0.092 <1.0

Zinc 5.0 1.5 1.1 -0.44 <5.0

Associated samples MP16665: LA58360-1F

_________________________________________________________________________________________________________

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139 of 182

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99.5.1





Prep Date: 10/21/19

MB

10/21/19



_________________________________________________________________________________________________________

Page 2

140 of 182

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99.5.1





Prep Date: 10/21/19

TD46457-2F Spikelot

10/21/19


Aluminum anr

Antimony 4.3 79.6 100 75.3 75-125

Arsenic 4.2 83.8 100 79.6 75-125

Barium 194 222 100 28.0N(a) 75-125

Beryllium 0.0 69.8 100 69.8N(a) 75-125

Boron

Cadmium 0.72 77.1 100 76.4 75-125

Calcium anr

Cerium

Chromium 2.1 79.7 100 77.6 75-125

Cobalt 0.0 79.1 100 79.1 75-125

Copper 13.8 86.8 100 73.0N(a) 75-125

Iron anr

Lanthanum

Lithium anr

Lead 0.16 77.8 100 77.6 75-125

Magnesium anr

Manganese anr

Molybdenum

Nickel 11.3 86.8 100 75.5 75-125

Potassium anr

Selenium 0.0 370 500 74.0N(a) 75-125

Silver 0.0 67.7 100 67.7N(a) 75-125

Silicon

Sodium anr

Strontium anr

Thallium 0.0 73.7 100 73.7N(a) 75-125

Tin

Titanium

Uranium

Vanadium 4.2 82.8 100 78.6 75-125

Zinc 581 531 100 -50.0(b) 75-125


_________________________________________________________________________________________________________

Page 1

141 of 182

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99.5.2





Prep Date: 10/21/19

TD46457-2F Spikelot

10/21/19



information.

_________________________________________________________________________________________________________

Page 2

142 of 182

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99.5.2





Prep Date: 10/21/19

TD46457-2F Spikelot

10/21/19


Aluminum anr

Antimony 4.3 76.4 100 72.1N(a) 4.1 20

Arsenic 4.2 77.2 100 73.0N(a) 8.2 20

Barium 194 222 100 28.0N(a) 0.0 20

Beryllium 0.0 80.4 100 80.4 12.4 20

Boron

Cadmium 0.72 74.0 100 73.3N(a) 4.1 20

Calcium anr

Cerium

Chromium 2.1 79.1 100 77.0 0.8 20

Cobalt 0.0 75.9 100 75.9 4.1 20

Copper 13.8 83.6 100 69.8N(a) 3.8 20

Iron anr

Lanthanum

Lithium anr

Lead 0.16 73.8 100 73.6N(a) 5.3 20

Magnesium anr

Manganese anr

Molybdenum

Nickel 11.3 74.2 100 62.9N(a) 15.7 20

Potassium anr

Selenium 0.0 299 500 59.8N(a) 21.2 (b) 20

Silver 0.0 73.8 100 73.8N(a) 8.6 20

Silicon

Sodium anr

Strontium anr

Thallium 0.0 73.6 100 73.6N(a) 0.1 20

Tin

Titanium

Uranium

Vanadium 4.2 81.0 100 76.8 2.2 20

Zinc 581 466 100 -115.0(c 13.0 20


_________________________________________________________________________________________________________

Page 3

143 of 182

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99.5.2





Prep Date: 10/21/19

TD46457-2F Spikelot

10/21/19


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Spike recovery indicates possible matrix interference or sample non-homogeneity.(b) Outside control limits due to matrix interference.(c) Spike amount low relative to the sample amount. Refer to lab control or spike blank for recovery

information.

_________________________________________________________________________________________________________

Page 4

144 of 182

LA58360

99.5.2





Prep Date: 10/21/19

BSP Spikelot

10/21/19


Aluminum anr

Antimony 97.6 100 97.6 80-120

Arsenic 99.2 100 99.2 80-120

Barium 94.5 100 94.5 80-120

Beryllium 99.7 100 99.7 80-120

Boron

Cadmium 95.6 100 95.6 80-120

Calcium anr

Cerium

Chromium 96.6 100 96.6 80-120

Cobalt 97.3 100 97.3 80-120

Copper 94.7 100 94.7 80-120

Iron anr

Lanthanum

Lithium anr

Lead 96.7 100 96.7 80-120

Magnesium anr

Manganese anr

Molybdenum

Nickel 95.4 100 95.4 80-120

Potassium anr

Selenium 501 500 100.2 80-120

Silver 92.3 100 92.3 80-120

Silicon

Sodium anr

Strontium anr

Thallium 97.6 100 97.6 80-120

Tin

Titanium

Uranium

Vanadium 99.0 100 99.0 80-120

Zinc 104 100 104.0 80-120


_________________________________________________________________________________________________________

Page 1

145 of 182

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99.5.3





Prep Date: 10/21/19

BSP Spikelot

10/21/19



_________________________________________________________________________________________________________

Page 2

146 of 182

LA58360

99.5.3





Prep Date: 10/21/19

TD46457-2F

10/21/19

QCMetal Original SDL 10:50%DIF Limits

Aluminum anr

Antimony 4.27 16.6 288.2*(a 0-10

Arsenic 4.18 6.48 55.0 (b) 0-10

Barium 194 180 6.8 0-10


Boron

Cadmium 0.719 2.66 270.6(b) 0-10

Calcium anr

Cerium

Chromium 2.07 11.9 474.3(b) 0-10

Cobalt 0.00 0.00 NC 0-10

Copper 13.8 0.00 100.0(b) 0-10

Iron anr

Lanthanum

Lithium anr

Lead 0.161 0.00 100.0(b) 0-10

Magnesium anr

Manganese anr

Molybdenum

Nickel 11.3 7.82 31.0 (b) 0-10

Potassium anr

Selenium 0.00 0.00 NC 0-10

Silver 0.00 0.00 NC 0-10

Silicon

Sodium anr

Strontium anr

Thallium 0.00 0.00 NC 0-10

Tin

Titanium

Uranium

Vanadium 4.24 11.1 160.7(b) 0-10

Zinc 581 563 3.1 0-10


_________________________________________________________________________________________________________

Page 1

147 of 182

LA58360

99.5.4





Prep Date: 10/21/19

TD46457-2F

10/21/19



_________________________________________________________________________________________________________

Page 2

148 of 182

LA58360

99.5.4





Prep Date: 10/21/19

Sample Final TD46457-2F PS Spike Spike Spike

10/21/19


Aluminum

Antimony 0.2 10 4.266 .08532 85.27 0.1 10 100 85.2 75-125

Arsenic 0.2 10 4.177 .08354 84.53 0.1 10 100 84.4 75-125

Barium 0.2 10 193.5 3.87 92.61 0.1 10 100 88.7 75-125

Beryllium 0.2 10 101.8 0.1 10 100 101.8 75-125

Boron

Cadmium 0.2 10 .7185 .01437 86.44 0.1 10 100 86.4 75-125

Calcium

Cerium

Chromium

Cobalt

Copper 0.2 10 13.81 .2762 87.75 0.1 10 100 87.5 75-125

Iron

Lanthanum

Lithium

Lead 0.2 10 .1608 .003216 89.8 0.1 10 100 89.8 75-125

Magnesium

Manganese

Molybdenum

Nickel 0.2 10 11.33 .2266 88.27 0.1 10 100 88.0 75-125

Potassium

Selenium 0.2 10 391.2 0.1 50 500 78.2 75-125

Silver 0.2 10 97.99 0.1 10 100 98.0 75-125

Silicon

Sodium

Strontium

Thallium 0.2 10 91.85 0.1 10 100 91.9 75-125

Tin

Titanium

Uranium

Vanadium

Zinc


_________________________________________________________________________________________________________

Page 1

149 of 182

LA58360

99.5.5





Prep Date: 10/21/19


10/21/19



_________________________________________________________________________________________________________

Page 2

150 of 182

LA58360

99.5.5





Prep Date: 10/21/19

MB

10/21/19


Mercury 0.20 .056 .081 -0.011 <0.20



_________________________________________________________________________________________________________

Page 1

151 of 182

LA58360

99.6.1





Prep Date: 10/21/19

TD46460-1 Spikelot

10/21/19


Mercury 0.0 4.8 5 96.0 75-125



_________________________________________________________________________________________________________

Page 1

152 of 182

LA58360

99.6.2





Prep Date: 10/21/19

TD46460-1 Spikelot

10/21/19


Mercury 0.0 4.7 5 94.0 2.1 20



_________________________________________________________________________________________________________

Page 2

153 of 182

LA58360

99.6.2





Prep Date: 10/21/19

BSP Spikelot

10/21/19


Mercury 4.8 5 96.0 80-120



_________________________________________________________________________________________________________

Page 1

154 of 182

LA58360

99.6.3





Prep Date: 10/21/19

TD46460-1

10/21/19


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

Page 1

155 of 182

LA58360

99.6.4





Prep Date: 11/05/19

MB

11/05/19



Antimony 1.0 .0063 .34 0.21 <1.0

Arsenic 1.0 .062 .26 -0.0082 <1.0

Barium 1.0 .0089 .46 0.43 <1.0

Beryllium 1.0 .0096 .28 -0.26 <1.0

Boron 20 1.5 2.9

Cadmium 0.50 .0081 .12 0.023 <0.50

Calcium 100 4.7 20

Cerium 1.0 .0019 .16

Chromium 1.0 .059 .15 0.066 <1.0

Cobalt 1.0 .0082 .14 0.016 <1.0

Copper 1.0 .27 .74 -0.17 <1.0

Iron 100 2.8 16

Lanthanum 1.0 .0019 .41

Lithium 2.0 .3 .61

Lead 1.0 .0045 .13 -0.11 <1.0




Nickel 1.0 .081 .2 -0.059 <1.0

Potassium 100 5 7.6

Selenium 5.0 .3 3.1 1.3 <5.0

Silver 1.0 .0088 .13 0.0088 <1.0

Silicon 500 7.6 130

Sodium 100 8.6 9.9


Thallium 1.0 .03 .86 -0.014 <1.0

Tin 2.0 .059 .19

Titanium 1.0 .095 .77

Uranium 1.0 .0019 .17

Vanadium 1.0 .035 .1 0.12 <1.0

Zinc 5.0 1.5 1.1 0.14 <5.0

Associated samples MP16825: LA58360-2FR

_________________________________________________________________________________________________________

Page 1

156 of 182

LA58360

99.7.1





Prep Date: 11/05/19

MB

11/05/19



_________________________________________________________________________________________________________

Page 2

157 of 182

LA58360

99.7.1





Prep Date: 11/05/19

LA59044-11 Spikelot

11/05/19


Aluminum

Antimony 3.0 112 100 109.0 75-125

Arsenic 12.0 127 100 115.0 75-125

Barium 2960 3410 100 450.0(a) 75-125

Beryllium 0.0 108 100 108.0 75-125

Boron

Cadmium 0.30 109 100 108.7 75-125

Calcium

Cerium

Chromium 1.2 112 100 110.8 75-125

Cobalt 0.66 106 100 105.3 75-125

Copper 0.0 104 100 104.0 75-125

Iron anr

Lanthanum

Lithium

Lead 0.0 102 100 102.0 75-125

Magnesium

Manganese anr

Molybdenum

Nickel 0.0 107 100 107.0 75-125

Potassium

Selenium 10.9 588 500 115.4 75-125

Silver 0.19 108 100 107.8 75-125

Silicon

Sodium

Strontium

Thallium 0.69 111 100 110.3 75-125

Tin

Titanium

Uranium

Vanadium 1.4 114 100 112.6 75-125

Zinc 0.00 117 100 117.0 75-125


_________________________________________________________________________________________________________

Page 1

158 of 182

LA58360

99.7.2





Prep Date: 11/05/19

LA59044-11 Spikelot

11/05/19


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Spike amount low relative to the sample amount. Refer to lab control or spike blank for recovery

information.

_________________________________________________________________________________________________________

Page 2

159 of 182

LA58360

99.7.2





Prep Date: 11/05/19

LA59044-11 Spikelot

11/05/19


Aluminum

Antimony 3.0 119 100 116.0 6.1 20

Arsenic 12.0 131 100 119.0 3.1 20

Barium 2960 3640 100 680.0(a) 6.5 20

Beryllium 0.0 115 100 115.0 6.3 20

Boron

Cadmium 0.30 115 100 114.7 5.4 20

Calcium

Cerium

Chromium 1.2 115 100 113.8 2.6 20

Cobalt 0.66 109 100 108.3 2.8 20

Copper 0.0 106 100 106.0 1.9 20

Iron anr

Lanthanum

Lithium

Lead 0.0 109 100 109.0 6.6 20

Magnesium

Manganese anr

Molybdenum

Nickel 0.0 109 100 109.0 1.9 20

Potassium

Selenium 10.9 623 500 122.4 5.8 20

Silver 0.19 110 100 109.8 1.8 20

Silicon

Sodium

Strontium

Thallium 0.69 113 100 112.3 1.8 20

Tin

Titanium

Uranium

Vanadium 1.4 116 100 114.6 1.7 20

Zinc 0.00 121 100 121.0 3.4 20


_________________________________________________________________________________________________________

Page 3

160 of 182

LA58360

99.7.2





Prep Date: 11/05/19

LA59044-11 Spikelot

11/05/19



information.

_________________________________________________________________________________________________________

Page 4

161 of 182

LA58360

99.7.2





Prep Date: 11/05/19

BSP Spikelot

11/05/19


Aluminum

Antimony 86.3 100 86.3 80-120

Arsenic 86.2 100 86.2 80-120

Barium 83.8 100 83.8 80-120

Beryllium 93.3 100 93.3 80-120

Boron

Cadmium 87.3 100 87.3 80-120

Calcium

Cerium

Chromium 89.6 100 89.6 80-120

Cobalt 88.1 100 88.1 80-120

Copper 88.6 100 88.6 80-120

Iron anr

Lanthanum

Lithium

Lead 85.4 100 85.4 80-120

Magnesium

Manganese anr

Molybdenum

Nickel 89.8 100 89.8 80-120

Potassium

Selenium 416 500 83.2 80-120

Silver 91.4 100 91.4 80-120

Silicon

Sodium

Strontium

Thallium 90.8 100 90.8 80-120

Tin

Titanium

Uranium

Vanadium 88.7 100 88.7 80-120

Zinc 87.0 100 87.0 80-120


_________________________________________________________________________________________________________

Page 1

162 of 182

LA58360

99.7.3





Prep Date: 11/05/19

BSP Spikelot

11/05/19



_________________________________________________________________________________________________________

Page 2

163 of 182

LA58360

99.7.3





Prep Date: 11/05/19

LA59044-11

11/05/19


Aluminum

Antimony 3.04 9.27 204.9(a) 0-10

Arsenic 12.0 8.48 29.4 (a) 0-10

Barium 2960 2440 17.5*(b) 0-10


Boron

Cadmium 0.304 0.943 209.6(a) 0-10

Calcium

Cerium

Chromium 1.17 3.98 239.2(a) 0-10

Cobalt 0.655 1.24 88.8 (a) 0-10

Copper 0.00 0.00 NC 0-10

Iron anr

Lanthanum

Lithium

Lead 0.00 0.00 NC 0-10

Magnesium

Manganese anr

Molybdenum

Nickel 0.00 0.00 NC 0-10

Potassium

Selenium 10.9 46.3 323.1(a) 0-10

Silver 0.191 0.591 208.9(a) 0-10

Silicon

Sodium

Strontium

Thallium 0.688 0.00 100.0(a) 0-10

Tin

Titanium

Uranium

Vanadium 1.36 5.80 327.2(a) 0-10

Zinc 0.00 0.00 NC 0-10


_________________________________________________________________________________________________________

Page 1

164 of 182

LA58360

99.7.4





Prep Date: 11/05/19

LA59044-11

11/05/19



_________________________________________________________________________________________________________

Page 2

165 of 182

LA58360

99.7.4





Prep Date: 11/06/19

MB

11/06/19


Mercury 0.20 .056 .081 0.0027 <0.20



_________________________________________________________________________________________________________

Page 1

166 of 182

LA58360

99.8.1





Prep Date: 11/06/19

LA59045-3F Spikelot

11/06/19


Mercury 0.0 3.3 5 66.0N(a) 75-125



_________________________________________________________________________________________________________

Page 1

167 of 182

LA58360

99.8.2





Prep Date: 11/06/19

LA59045-3F Spikelot

11/06/19


Mercury 0.0 3.3 5 66.0N(a) 0.0 20



_________________________________________________________________________________________________________

Page 2

168 of 182

LA58360

99.8.2





Prep Date: 11/06/19

BSP Spikelot

11/06/19


Mercury 4.5 5 90.0 80-120



_________________________________________________________________________________________________________

Page 1

169 of 182

LA58360

99.8.3





Prep Date: 11/06/19

LA59045-3F

11/06/19


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

Page 1

170 of 182

LA58360

99.8.4


General Chemistry

QC Data Summaries



Scott, LASection 10

171 of 182

LA58360

10





Bromide GP7302/GN15792 0.25 0.0 mg/l 12.5 12.7 101.6 90-110% Chloride GP7302/GN15792 0.25 0.0 mg/l 12.5 13.1 104.8 90-110% Nitrogen, Nitrate GP7302/GN15792 0.050 0.0 mg/l 2.5 2.44 97.6 90-110% Nitrogen, Nitrite GP7302/GN15792 0.050 0.0 mg/l 2.5 2.46 98.4 90-110% Sulfate GP7302/GN15792 0.25 0.0 mg/l 12.5 13.2 105.6 90-110%

Associated Samples: Batch GP7302: LA58360-4, LA58360-5(*) Outside of QC limits

__________________________________________________________________________________________________________________________

Page 1

172 of 182

LA58360

1010.1





Bromide GP7302/GN15792 LA58360-4 mg/l 0.0 12.5 13.0 104.0 80-120%Chloride GP7302/GN15792 LA58360-4 mg/l 0.0 12.5 12.6 100.8 80-120%Nitrogen, Nitrate GP7302/GN15792 LA58360-4 mg/l 0.0 2.5 2.5 100.0 80-120%Nitrogen, Nitrite GP7302/GN15792 LA58360-4 mg/l 0.037 2.5 2.5 98.5 80-120%Sulfate GP7302/GN15792 LA58360-4 mg/l 0.0 12.5 12.7 101.6 80-120%

Associated Samples: Batch GP7302: LA58360-4, LA58360-5(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits

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Bromide GP7302/GN15792 LA58360-4 mg/l 0.0 12.5 13.0 0.0 20%Chloride GP7302/GN15792 LA58360-4 mg/l 0.0 12.5 12.6 0.0 20%Nitrogen, Nitrate GP7302/GN15792 LA58360-4 mg/l 0.0 2.5 2.5 0.0 20%Nitrogen, Nitrite GP7302/GN15792 LA58360-4 mg/l 0.037 2.5 2.4 4.1 20%Sulfate GP7302/GN15792 LA58360-4 mg/l 0.0 12.5 12.6 0.8 20%


__________________________________________________________________________________________________________________________

Page 1

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1010.3


Misc. Forms


(SGS Houston, TX)



Scott, LASection 11

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11


SGS Houston, TX

176 of 182

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1111.1

Page 1 of 2Job Number: LA58360 Client: SGS

Date / Time Received: 10/9/2019 11:20:00 PM Delv Method: SGS-GP

Project: BOTTLE

# of Coolers: 1

Airbill #'s:




















Intact








Misc. Information


Y or N N/A




11. COC Present:

N/A


Comments


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1111.1

Sample Receipt Log

Job #: LA58360 Date / Time Received: 10/9/2019 11:20:00 PM Initials: BELINDG

Client: SGS

Page 2 of 2


CFCorrected

TempInitialTemp

500AML M2E H2SO4 pH < 2 IR-4 0 1.31 LA58360-4 1.31

500AML M2E H2SO4 pH < 2 IR-4 0 1.31 LA58360-5 1.31

1000ml M3B N/P Note #2 - Preservative check not applicable. IR-4 0 1.31 LA58360-6 1.31



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General Chemistry

QC Data Summaries

(SGS Houston, TX)



Scott, LASection 12

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Cyanide Reactivity GP55107/GN1772 0.40 0.0 mg/kg 10 1.3 13.4 2-33%Cyanide Reactivity GP55118/GN1772 0.40 0.0 mg/l 10 1.3 13.4 8-23%Nitrogen, Ammonia GP55201/GN1889 0.10 0.0 mg/l 2 2.19 109.5 90-110% Sulfide Reactivity GP55108/GN1796 20 0.0 mg/kg 1600 400 25.0 13-28%Sulfide Reactivity GP55119/GN1783 20 0.0 mg/l 1600 400 25.0 .5-48%

Associated Samples: Batch GP55107: LA58360-7ABatch GP55108: LA58360-7ABatch GP55118: LA58360-6ABatch GP55119: LA58360-6ABatch GP55201: LA58360-4, LA58360-5(*) Outside of QC limits

__________________________________________________________________________________________________________________________

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Corrosivity as pH GN1759 LA58360-6A su 7.3 7.3 0.0 0-%Corrosivity as pH GN1762 LA58360-7A su 7.9 7.9 0.0 0-%Cyanide Reactivity GP55107/GN1772 TD46061-1 mg/kg 0.0 0.0 0.0 0-10%Cyanide Reactivity GP55118/GN1772 LA58360-6A mg/l -0.085 0.0 0.0 0-20%Ignitability (Flashpoint) GN1830 LA58276-3A Deg. F >200 >200 0.0 0-10%Ignitability (Flashpoint) GN1831 LA58276-1A Deg. F >200 >200 0.0 0-10%Nitrogen, Ammonia GP55201/GN1889 LA58360-4 mg/l -0.019 0.0 0.0 0-20%Sulfide Reactivity GP55108/GN1796 TD46061-1 mg/kg 0.0 0.0 0.0 0-10%Sulfide Reactivity GP55119/GN1783 LA58360-6A mg/l 0.0 0.0 0.0 0-20%

Associated Samples: Batch GN1759: LA58360-6ABatch GN1762: LA58360-7ABatch GN1830: LA58360-6ABatch GN1831: LA58360-7ABatch GP55107: LA58360-7ABatch GP55108: LA58360-7ABatch GP55118: LA58360-6ABatch GP55119: LA58360-6ABatch GP55201: LA58360-4, LA58360-5(*) Outside of QC limits

__________________________________________________________________________________________________________________________

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Nitrogen, Ammonia GP55201/GN1889 LA58360-4 mg/l -0.019 2 1.5 75.0 90-110%


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Page 1

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1212.3

01/29/20




1249-001


Sampling Dates: 01/08/20 - 01/09/20

Report to:


ATTN: Ashlyn Holmes








Scott, LA 01/29/20


187




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Sections:


3.1: LA60782-1: DB-4SS (28-30') ....................................................................................... 133.2: LA60782-1A: DB-4SS (28-30') .................................................................................... 153.3: LA60782-2: DB-4SS (32-34') ....................................................................................... 163.4: LA60782-3: DB-4SS (34-36') ....................................................................................... 183.5: LA60782-4: DB-3SS (28-30') ....................................................................................... 203.6: LA60782-5: DB-3SS (42-44') ....................................................................................... 223.7: LA60782-6: DB-3SS (44-46') ....................................................................................... 243.8: LA60782-7: DB-3SS (48-50') ....................................................................................... 263.9: LA60782-8: BD-01SS .................................................................................................. 283.10: LA60782-9: FB-01 ..................................................................................................... 303.11: LA60782-10: DB-0GW .............................................................................................. 363.12: LA60782-11: DUP-01GW .......................................................................................... 423.13: LA60782-12: TRIP BLANK ...................................................................................... 483.14: LA60782-13: DB-1SS (6-8') ....................................................................................... 503.15: LA60782-13A: DB-1SS (6-8') .................................................................................... 523.16: LA60782-14: DB-1SS (28-30') ................................................................................... 543.17: LA60782-14A: DB-1SS (28-30') ................................................................................ 563.18: LA60782-15: DB-2SS (18-20') ................................................................................... 573.19: LA60782-15A: DB-2SS (18-20') ................................................................................ 593.20: LA60782-16: DB-2SS (28-30') ................................................................................... 613.21: LA60782-16A: DB-2SS (28-30') ................................................................................ 633.22: LA60782-17: RINSE-01 ............................................................................................. 643.23: LA60782-18: DB-3GW .............................................................................................. 703.24: LA60782-19: FB-02 ................................................................................................... 763.25: LA60782-20: D-2 FSW .............................................................................................. 823.26: LA60782-20A: D-2 FSW ........................................................................................... 853.27: LA60782-21: D-2 SWS .............................................................................................. 863.28: LA60782-21A: D-2 SWS ........................................................................................... 893.29: LA60782-22: TRIP BLANK ...................................................................................... 903.30: LA60782-23: TRIP BLANK ...................................................................................... 923.31: LA60782-24: TRIP BLANK ...................................................................................... 94


Section 5: MS Volatiles - QC Data Summaries ..................................................................... 1045.1: Method Blank Summary ................................................................................................ 1055.2: Leachate Blank Summary .............................................................................................. 1135.3: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1165.4: Matrix Spike Summary .................................................................................................. 1275.5: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 129

12

34

56

78

910

11

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Sections:

Section 6: MS Semi-volatiles - QC Data Summaries ............................................................ 1396.1: Method Blank Summary ................................................................................................ 1406.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1426.3: Matrix Spike Summary .................................................................................................. 1446.4: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 145

Section 7: GC Volatiles - QC Data Summaries ..................................................................... 1467.1: Method Blank Summary ................................................................................................ 1477.2: Leachate Blank Summary .............................................................................................. 1497.3: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1507.4: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 153

Section 8: GC/LC Semi-volatiles - QC Data Summaries ..................................................... 1568.1: Method Blank Summary ................................................................................................ 1578.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1588.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 159

Section 9: Metals Analysis - QC Data Summaries ................................................................ 1609.1: Prep QC MP17402: As .................................................................................................. 1619.2: Prep QC MP17409: As,Ba,Cd,Cr,Pb,Se,Ag .................................................................. 1729.3: Prep QC MP17416: Hg .................................................................................................. 176


Section 11: General Chemistry - QC Data (SGS Houston, TX) .......................................... 18511.1: Method Blank and Spike Results Summary ................................................................ 18611.2: Duplicate Results Summary ......................................................................................... 187

12

34

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11

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Sample Summary


Bottle Art Lofts, University & Cameron, Lafayette, LAProject No: 1249-001



LA60782-1 01/08/20 11:40 SO 01/09/20 SO Soil DB-4SS (28-30' )

LA60782-1A 01/08/20 11:40 SO 01/09/20 SO Soil DB-4SS (28-30' )

LA60782-2 01/08/20 12:00 SO 01/09/20 SO Soil DB-4SS (32-34' )

LA60782-3 01/08/20 12:15 SO 01/09/20 SO Soil DB-4SS (34-36' )

LA60782-4 01/08/20 14:05 SO 01/09/20 SO Soil DB-3SS (28-30' )

LA60782-5 01/08/20 16:45 SO 01/09/20 SO Soil DB-3SS (42-44' )

LA60782-6 01/08/20 16:55 SO 01/09/20 SO Soil DB-3SS (44-46' )

LA60782-7 01/08/20 17:15 SO 01/09/20 SO Soil DB-3SS (48-50' )

LA60782-8 01/08/20 14:05 SO 01/09/20 SO Soil BD-01SS


LA60782-10 01/09/20 07:15 SO 01/09/20 AQ Ground Water DB-0GW


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LA60782-10D 01/09/20 07:15 SO 01/09/20 AQ Water Dup/MSD DB-0GW

LA60782-10S 01/09/20 07:15 SO 01/09/20 AQ Water Matrix Spike DB-0GW

LA60782-11 01/09/20 07:15 SO 01/09/20 AQ Ground Water DUP-01GW


LA60782-13 01/09/20 09:30 SO 01/09/20 SO Soil DB-1SS (6-8' )


LA60782-14 01/09/20 10:30 SO 01/09/20 SO Soil DB-1SS (28-30' )


LA60782-14D 01/09/20 10:30 SO 01/09/20 SO Soil Dup/MSD DB-1SS (28-30' )

LA60782-14S 01/09/20 10:30 SO 01/09/20 SO Soil Matrix Spike DB-1SS (28-30' )

LA60782-15 01/09/20 11:50 SO 01/09/20 SO Soil DB-2SS (18-20' )


LA60782-16 01/09/20 12:20 SO 01/09/20 SO Soil DB-2SS (28-30' )


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LA60782-17 01/09/20 13:00 SO 01/09/20 AQ Water RINSE-01

LA60782-18 01/09/20 13:30 SO 01/09/20 AQ Ground Water DB-3GW


LA60782-20 01/09/20 14:30 SO 01/09/20 AQ Ground Water D-2 FSW

LA60782-20A 01/09/20 14:30 SO 01/09/20 AQ Ground Water D-2 FSW

LA60782-21 01/09/20 14:40 SO 01/09/20 SO Soil D-2 SWS

LA60782-21A 01/09/20 14:40 SO 01/09/20 SO Soil D-2 SWS





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Summary of Hits Page 1 of 5Job Number: LA60782Account: Providence Engineering & EnvironmentalProject: Bottle Art Lofts, University & Cameron, Lafayette, LACollected: 01/08/20 thru 01/09/20


LA60782-1 DB-4SS (28-30')

Benzene 0.0848 0.024 mg/kg SW846 8260BEthylbenzene 0.155 0.048 mg/kg SW846 8260BXylene (total) 0.668 0.096 mg/kg SW846 8260B

LA60782-1A DB-4SS (28-30')

Benzene 0.0434 0.0010 mg/l SW846 8260B

LA60782-2 DB-4SS (32-34')


LA60782-3 DB-4SS (34-36')


LA60782-4 DB-3SS (28-30')


LA60782-5 DB-3SS (42-44')

Toluene 0.354 0.25 mg/kg SW846 8260BEthylbenzene 2.56 0.050 mg/kg SW846 8260BXylene (total) 17.5 0.10 mg/kg SW846 8260BAliphatics C6-C8 (Unadj.) 6.69 1.5 mg/kg MADEP VPH REV 1.1Aliphatics > C8-C10 (Unadj.) 43.2 2.5 mg/kg MADEP VPH REV 1.1Aromatics > C8-C10 (Unadj.) 57.4 2.5 mg/kg MADEP VPH REV 1.1

LA60782-6 DB-3SS (44-46')


LA60782-7 DB-3SS (48-50')


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2



LA60782-8 BD-01SS


LA60782-9 FB-01


LA60782-10 DB-0GW

1,2-Dichloroethane 0.0011 0.0010 mg/l SW846 8260BMethyl Tert Butyl Ether 0.0767 0.0010 mg/l SW846 8260BTPH-GRO (C6-C10) 0.300 0.10 mg/l SW846 8015CArsenic 0.0045 0.0010 mg/l SW846 6020A

LA60782-11 DUP-01GW

Methyl Tert Butyl Ether 0.0868 0.0010 mg/l SW846 8260BTPH-GRO (C6-C10) 0.280 0.10 mg/l SW846 8015CArsenic 0.0033 0.0010 mg/l SW846 6020A



LA60782-13 DB-1SS (6-8')

Benzene 6.96 0.025 mg/kg SW846 8260BToluene 2.89 0.25 mg/kg SW846 8260BEthylbenzene 15.1 0.20 mg/kg SW846 8260BXylene (total) 64.1 0.40 mg/kg SW846 8260BAliphatics C6-C8 (Unadj.) 146 1.5 mg/kg MADEP VPH REV 1.1Aliphatics > C8-C10 (Unadj.) 161 2.5 mg/kg MADEP VPH REV 1.1Aromatics > C8-C10 (Unadj.) 181 2.5 mg/kg MADEP VPH REV 1.1

LA60782-13A DB-1SS (6-8')

Benzene 0.0147 0.010 mg/l SW846 8260BXylene (total) 0.157 0.020 mg/l SW846 8260BAliphatics C6-C8 (Unadj.) 0.0897 0.030 mg/l MADEP VPH REV 1.1Aliphatics > C8-C10 (Unadj.) 0.246 0.050 mg/l MADEP VPH REV 1.1Aromatics > C8-C10 (Unadj.) 0.310 0.050 mg/l MADEP VPH REV 1.1

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2



LA60782-14 DB-1SS (28-30')


LA60782-14A DB-1SS (28-30')


LA60782-15 DB-2SS (18-20')

Benzene 2.83 0.025 mg/kg SW846 8260BToluene 8.11 0.25 mg/kg SW846 8260BEthylbenzene 7.12 0.050 mg/kg SW846 8260BXylene (total) 2.89 0.39 mg/kg SW846 8260BAliphatics C6-C8 (Unadj.) 72.8 1.5 mg/kg MADEP VPH REV 1.1Aliphatics > C8-C10 (Unadj.) 62.4 2.5 mg/kg MADEP VPH REV 1.1Aromatics > C8-C10 (Unadj.) 81.2 2.5 mg/kg MADEP VPH REV 1.1

LA60782-15A DB-2SS (18-20')


LA60782-16 DB-2SS (28-30')

Benzene 0.508 0.026 mg/kg SW846 8260BToluene 0.377 0.26 mg/kg SW846 8260BEthylbenzene 0.211 0.051 mg/kg SW846 8260BXylene (total) 1.05 0.10 mg/kg SW846 8260BAliphatics C6-C8 (Unadj.) 1.80 1.5 mg/kg MADEP VPH REV 1.1

LA60782-16A DB-2SS (28-30')


LA60782-17 RINSE-01


LA60782-18 DB-3GW

Benzene 0.316 0.010 mg/l SW846 8260B1,2-Dichloroethane 0.0197 0.010 mg/l SW846 8260BEthylbenzene 1.05 0.010 mg/l SW846 8260B

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2



Toluene 1.52 0.010 mg/l SW846 8260Bm,p-Xylene 3.78 0.020 mg/l SW846 8260Bo-Xylene 1.48 0.010 mg/l SW846 8260BXylene (total) 5.26 0.020 mg/l SW846 8260B2-Methylnaphthalene 0.0230 0.0018 mg/l SW846 8270DNaphthalene 0.0707 0.0018 mg/l SW846 8270DTPH-GRO (C6-C10) 25.3 0.50 mg/l SW846 8015CTPH-DRO (C10-C28) 4.03 0.14 mg/l SW846 8015CArsenic a 0.0512 0.010 mg/l SW846 6020A

LA60782-19 FB-02


LA60782-20 D-2 FSW


LA60782-20A D-2 FSW

Corrosivity as pH b 7.5 su SW846 9045C/9045DIgnitability (Flashpoint) c > 200 Deg. F SW846 1010/1010A

LA60782-21 D-2 SWS


LA60782-21A D-2 SWS

Corrosivity as pH d 7.9 su SW846 9045C/9045DIgnitability (Flashpoint) c > 200 Deg. F SW846 1010/1010A







(a) Elevated reporting limit due to dilution required for internal standard failure.

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2



(b) temp. 23.0 c Analysis performed at SGS Houston, TX.(c) Analysis performed at SGS Houston, TX.(d) temp. 21.7 c Analysis performed at SGS Houston, TX.

11 of 187

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2


Sample Results

Report of Analysis

Scott, LASection 3

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3



Client Sample ID: DB-4SS (28-30' ) Lab Sample ID: LA60782-1 Date Sampled: 01/08/20Matrix: SO - Soil Date Received: 01/09/20Method: SW846 8260B SW846 5035 Percent Solids: n/a a


File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2Q0455825.D 1 01/14/20 19:20 CP 01/10/20 16:51 n/a V2Q2663Run #2


Purgeable Aromatics


71-43-2 Benzene 0.0848 0.024 mg/kg108-88-3 Toluene ND 0.24 mg/kg100-41-4 Ethylbenzene 0.155 0.048 mg/kg1330-20-7 Xylene (total) 0.668 0.096 mg/kg





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33.1



Client Sample ID: DB-4SS (28-30' ) Lab Sample ID: LA60782-1 Date Sampled: 01/08/20Matrix: SO - Soil Date Received: 01/09/20Method: MADEP VPH REV 1.1 SW846 5035 Percent Solids: n/a a


File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LE367383.D 1 01/15/20 07:46 NN 01/10/20 16:51 n/a GLE1982Run #2




Aliphatics C6-C8 (Unadj.) ND 1.4 mg/kgAliphatics > C8-C10 (Unadj.) ND 2.4 mg/kgAromatics > C8-C10 (Unadj.) ND 2.4 mg/kg


615-59-8 2,5-Dibromotoluene 102% b 70-130%615-59-8 2,5-Dibromotoluene 101% c 70-130%

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Recovery from Aliphatics fraction.(c) Recovery from Aromatics fraction.


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33.1



Client Sample ID: DB-4SS (28-30' ) Lab Sample ID: LA60782-1A Date Sampled: 01/08/20Matrix: SO - Soil Date Received: 01/09/20Method: SW846 8260B SW846 1312 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2Q0456163.D 1 01/23/20 14:36 CP 01/21/20 08:00 OP16048 V2Q2678Run #2


SPLP Leachate method SW846 1312

CAS No. Compound Result MCL RL Units Q

71-43-2 Benzene 0.0434 0.0010 mg/l



ND = Not detected J = Indicates an estimated valueMCL = Maximum Contamination Level (not available) B = Indicates analyte found in associated method blankE = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

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33.2







Purgeable Aromatics


71-43-2 Benzene ND 0.025 mg/kg108-88-3 Toluene ND 0.25 mg/kg100-41-4 Ethylbenzene ND 0.050 mg/kg1330-20-7 Xylene (total) ND 0.10 mg/kg





16 of 187

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33.3














17 of 187

LA60782

33.3







Purgeable Aromatics







18 of 187

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33.4














19 of 187

LA60782

33.4







Purgeable Aromatics







20 of 187

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33.5














21 of 187

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33.5







Purgeable Aromatics


71-43-2 Benzene ND 0.025 mg/kg108-88-3 Toluene 0.354 0.25 mg/kg100-41-4 Ethylbenzene 2.56 0.050 mg/kg1330-20-7 Xylene (total) 17.5 0.10 mg/kg





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33.6









Aliphatics C6-C8 (Unadj.) 6.69 1.5 mg/kgAliphatics > C8-C10 (Unadj.) 43.2 2.5 mg/kgAromatics > C8-C10 (Unadj.) 57.4 2.5 mg/kg





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33.6







Purgeable Aromatics







24 of 187

LA60782

33.7














25 of 187

LA60782

33.7







Purgeable Aromatics







26 of 187

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33.8














27 of 187

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33.8



Client Sample ID: BD-01SSLab Sample ID: LA60782-8 Date Sampled: 01/08/20Matrix: SO - Soil Date Received: 01/09/20Method: SW846 8260B SW846 5035 Percent Solids: n/a a




Purgeable Aromatics







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33.9



Client Sample ID: BD-01SSLab Sample ID: LA60782-8 Date Sampled: 01/08/20Matrix: SO - Soil Date Received: 01/09/20Method: MADEP VPH REV 1.1 SW846 5035 Percent Solids: n/a a











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33.9






VOA RECAP List


67-64-1 Acetone ND 0.050 mg/l71-43-2 Benzene ND 0.0010 mg/l75-27-4 Bromodichloromethane ND 0.0010 mg/l75-25-2 Bromoform ND 0.0010 mg/l75-15-0 Carbon Disulfide ND 0.0010 mg/l56-23-5 Carbon Tetrachloride ND 0.0010 mg/l108-90-7 Chlorobenzene ND 0.0010 mg/l75-00-3 Chloroethane ND 0.0010 mg/l67-66-3 Chloroform ND 0.0010 mg/l124-48-1 Dibromochloromethane ND 0.0010 mg/l541-73-1 m-Dichlorobenzene ND 0.0010 mg/l95-50-1 o-Dichlorobenzene ND 0.0010 mg/l106-46-7 p-Dichlorobenzene ND 0.0010 mg/l75-34-3 1,1-Dichloroethane ND 0.0010 mg/l107-06-2 1,2-Dichloroethane ND 0.0010 mg/l75-35-4 1,1-Dichloroethylene ND 0.0010 mg/l156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/l156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/l540-59-0 1,2-Dichloroethene (total) ND 0.0010 mg/l78-87-5 1,2-Dichloropropane ND 0.0010 mg/l10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/l10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/l542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/l100-41-4 Ethylbenzene ND 0.0010 mg/l67-72-1 Hexachloroethane ND 0.0010 mg/l78-83-1 Isobutyl Alcohol ND 0.10 mg/l74-83-9 Methyl Bromide ND 0.0010 mg/l74-87-3 Methyl Chloride ND 0.0010 mg/l75-09-2 Methylene Chloride ND 0.0010 mg/l78-93-3 Methyl Ethyl Ketone ND 0.013 mg/l108-10-1 4-Methyl-2-pentanone ND 0.013 mg/l1634-04-4 Methyl Tert Butyl Ether ND 0.0010 mg/l


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VOA RECAP List


100-42-5 Styrene ND 0.0010 mg/l630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.00050 mg/l127-18-4 Tetrachloroethylene ND 0.0010 mg/l108-88-3 Toluene ND 0.0010 mg/l71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/l79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/l79-01-6 Trichloroethylene ND 0.0010 mg/l75-69-4 Trichlorofluoromethane ND 0.0010 mg/l75-01-4 Vinyl Chloride ND 0.0010 mg/l





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33.10




File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 a L0031747.D 1 01/13/20 19:25 AA 01/13/20 10:30 OP15992 EL864Run #2


BN PAH List


83-32-9 Acenaphthene b ND 0.00020 mg/l208-96-8 Acenaphthylene b ND 0.00020 mg/l120-12-7 Anthracene b ND 0.00020 mg/l56-55-3 Benzo(a)anthracene b ND 0.00020 mg/l50-32-8 Benzo(a)pyrene b ND 0.00020 mg/l205-99-2 Benzo(b)fluoranthene b ND 0.00020 mg/l207-08-9 Benzo(k)fluoranthene b ND 0.00020 mg/l218-01-9 Chrysene b ND 0.00020 mg/l53-70-3 Dibenzo(a,h)anthracene b ND 0.00020 mg/l206-44-0 Fluoranthene b ND 0.00020 mg/l86-73-7 Fluorene b ND 0.00020 mg/l193-39-5 Indeno(1,2,3-cd)pyrene b ND 0.00020 mg/l91-57-6 2-Methylnaphthalene b ND 0.00020 mg/l91-20-3 Naphthalene b ND 0.00020 mg/l85-01-8 Phenanthrene b ND 0.00020 mg/l129-00-0 Pyrene b ND 0.00020 mg/l


4165-60-0 Nitrobenzene-d5 96% 17-131%321-60-8 2-Fluorobiphenyl 77% 11-122%1718-51-0 Terphenyl-d14 98% 21-144%

(a) Elevated reporting limits due to limited sample volume.(b) RL manually adusted to meet client limits. The calibration and MDL supports this adjustment.


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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LA357730.D 1 01/14/20 15:52 LR n/a n/a GLA2866Run #2







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TPH-DRO (C10-C28) ND 0.14 mg/l


84-15-1 o-Terphenyl 97% 40-118%


34 of 187

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Client Sample ID: DB-0GWLab Sample ID: LA60782-10 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



VOA RECAP List


67-64-1 Acetone ND 0.050 mg/l71-43-2 Benzene ND 0.0010 mg/l75-27-4 Bromodichloromethane ND 0.0010 mg/l75-25-2 Bromoform ND 0.0010 mg/l75-15-0 Carbon Disulfide ND 0.0010 mg/l56-23-5 Carbon Tetrachloride ND 0.0010 mg/l108-90-7 Chlorobenzene ND 0.0010 mg/l75-00-3 Chloroethane ND 0.0010 mg/l67-66-3 Chloroform ND 0.0010 mg/l124-48-1 Dibromochloromethane ND 0.0010 mg/l96-12-8 1,2-Dibromo-3-chloropropane ND 0.0010 mg/l541-73-1 m-Dichlorobenzene ND 0.0010 mg/l95-50-1 o-Dichlorobenzene ND 0.0010 mg/l106-46-7 p-Dichlorobenzene ND 0.0010 mg/l75-34-3 1,1-Dichloroethane ND 0.0010 mg/l107-06-2 1,2-Dichloroethane 0.0011 0.0010 mg/l75-35-4 1,1-Dichloroethylene ND 0.0010 mg/l156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/l156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/l540-59-0 1,2-Dichloroethene (total) ND 0.0010 mg/l78-87-5 1,2-Dichloropropane ND 0.0010 mg/l10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/l10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/l542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/l100-41-4 Ethylbenzene ND 0.0010 mg/l67-72-1 Hexachloroethane ND 0.0010 mg/l78-83-1 Isobutyl Alcohol ND 0.10 mg/l74-83-9 Methyl Bromide ND 0.0010 mg/l74-87-3 Methyl Chloride ND 0.0010 mg/l75-09-2 Methylene Chloride ND 0.0010 mg/l78-93-3 Methyl Ethyl Ketone ND 0.013 mg/l108-10-1 4-Methyl-2-pentanone ND 0.013 mg/l


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VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether 0.0767 0.0010 mg/l100-42-5 Styrene ND 0.0010 mg/l630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.00050 mg/l127-18-4 Tetrachloroethylene ND 0.0010 mg/l108-88-3 Toluene ND 0.0010 mg/l71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/l79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/l79-01-6 Trichloroethylene ND 0.0010 mg/l75-69-4 Trichlorofluoromethane ND 0.0010 mg/l75-01-4 Vinyl Chloride ND 0.0010 mg/l





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Client Sample ID: DB-0GWLab Sample ID: LA60782-10 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 L0031748.D 1 01/13/20 19:50 AA 01/13/20 10:30 OP15992 EL864Run #2


BN PAH List


83-32-9 Acenaphthene ND 0.00018 mg/l208-96-8 Acenaphthylene ND 0.00018 mg/l120-12-7 Anthracene ND 0.00018 mg/l56-55-3 Benzo(a)anthracene ND 0.00018 mg/l50-32-8 Benzo(a)pyrene ND 0.00018 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00018 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00018 mg/l218-01-9 Chrysene ND 0.00018 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00018 mg/l206-44-0 Fluoranthene ND 0.00018 mg/l86-73-7 Fluorene ND 0.00018 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00018 mg/l91-57-6 2-Methylnaphthalene ND 0.00018 mg/l91-20-3 Naphthalene ND 0.00018 mg/l85-01-8 Phenanthrene ND 0.00018 mg/l129-00-0 Pyrene ND 0.00018 mg/l




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Client Sample ID: DB-0GWLab Sample ID: LA60782-10 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA




TPH-GRO (C6-C10) 0.300 0.10 mg/l




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Client Sample ID: DB-0GWLab Sample ID: LA60782-10 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA






84-15-1 o-Terphenyl 93% 40-118%


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Client Sample ID: DB-0GWLab Sample ID: LA60782-10 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20







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Client Sample ID: DUP-01GWLab Sample ID: LA60782-11 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



VOA RECAP List




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Client Sample ID: DUP-01GWLab Sample ID: LA60782-11 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether 0.0868 0.0010 mg/l100-42-5 Styrene ND 0.0010 mg/l630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.00050 mg/l127-18-4 Tetrachloroethylene ND 0.0010 mg/l108-88-3 Toluene ND 0.0010 mg/l71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/l79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/l79-01-6 Trichloroethylene ND 0.0010 mg/l75-69-4 Trichlorofluoromethane ND 0.0010 mg/l75-01-4 Vinyl Chloride ND 0.0010 mg/l





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Client Sample ID: DUP-01GWLab Sample ID: LA60782-11 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



BN PAH List






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Client Sample ID: DUP-01GWLab Sample ID: LA60782-11 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA




TPH-GRO (C6-C10) 0.280 0.10 mg/l




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Client Sample ID: DUP-01GWLab Sample ID: LA60782-11 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA






84-15-1 o-Terphenyl 93% 40-118%


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Client Sample ID: DUP-01GWLab Sample ID: LA60782-11 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20







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VOA RECAP List




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VOA RECAP List







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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2Q0455817.D 1 01/14/20 17:37 CP 01/10/20 16:51 n/a V2Q2663Run #2 2Q0455883.D 1 01/15/20 16:38 CP 01/10/20 16:51 n/a V2Q2665

Initial Weight Final Volume Methanol AliquotRun #1 5.0 g 5.0 ml 100 ulRun #2 5.0 g 5.0 ml 25.0 ul

Purgeable Aromatics


71-43-2 Benzene 6.96 0.025 mg/kg108-88-3 Toluene 2.89 0.25 mg/kg100-41-4 Ethylbenzene 15.1 b 0.20 mg/kg1330-20-7 Xylene (total) 64.1 b 0.40 mg/kg



(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) Result is from Run# 2


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Aliphatics C6-C8 (Unadj.) 146 1.5 mg/kgAliphatics > C8-C10 (Unadj.) 161 2.5 mg/kgAromatics > C8-C10 (Unadj.) 181 2.5 mg/kg





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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 1X0090371.D 10 01/24/20 16:34 PJ 01/23/20 01:00 OP16055 V1X4043Run #2




71-43-2 Benzene 0.0147 0.010 mg/l1330-20-7 Xylene (total) 0.157 0.020 mg/l




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Client Sample ID: DB-1SS (6-8' ) Lab Sample ID: LA60782-13A Date Sampled: 01/09/20Matrix: SO - Soil Date Received: 01/09/20Method: MADEP VPH REV 1.1 SW846 1312 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LC082035.D 1 01/24/20 23:31 NN 01/23/20 01:00 OP16056 GLC2598Run #2


Volatile Petroleum Hydrocarbons (VPH) SPLP Leachate method SW846 1312


Aliphatics C6-C8 (Unadj.) 0.0897 0.030 mg/lAliphatics > C8-C10 (Unadj.) 0.246 0.050 mg/lAromatics > C8-C10 (Unadj.) 0.310 0.050 mg/l





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Purgeable Aromatics







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71-43-2 Benzene ND 0.0010 mg/l




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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2Q0455821.D 1 01/14/20 18:29 CP 01/10/20 16:51 n/a V2Q2663Run #2 2Q0455885.D 1 01/15/20 17:04 CP 01/10/20 16:51 n/a V2Q2665


Purgeable Aromatics


71-43-2 Benzene 2.83 0.025 mg/kg108-88-3 Toluene 8.11 0.25 mg/kg100-41-4 Ethylbenzene 7.12 0.050 mg/kg1330-20-7 Xylene (total) 2.89 b 0.39 mg/kg





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Aliphatics C6-C8 (Unadj.) 72.8 1.5 mg/kgAliphatics > C8-C10 (Unadj.) 62.4 2.5 mg/kgAromatics > C8-C10 (Unadj.) 81.2 2.5 mg/kg





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Client Sample ID: DB-2SS (18-20' ) Lab Sample ID: LA60782-15A Date Sampled: 01/09/20Matrix: SO - Soil Date Received: 01/09/20Method: MADEP VPH REV 1.1 SW846 1312 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LC082036.D 1 01/24/20 23:58 NN 01/23/20 01:00 OP16056 GLC2598Run #2


Volatile Petroleum Hydrocarbons (VPH) SPLP Leachate method SW846 1312


Aliphatics C6-C8 (Unadj.) ND 0.030 mg/lAliphatics > C8-C10 (Unadj.) ND 0.050 mg/lAromatics > C8-C10 (Unadj.) ND 0.050 mg/l





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Purgeable Aromatics


71-43-2 Benzene 0.508 0.026 mg/kg108-88-3 Toluene 0.377 0.26 mg/kg100-41-4 Ethylbenzene 0.211 0.051 mg/kg1330-20-7 Xylene (total) 1.05 0.10 mg/kg





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Aliphatics C6-C8 (Unadj.) 1.80 1.5 mg/kgAliphatics > C8-C10 (Unadj.) ND 2.6 mg/kgAromatics > C8-C10 (Unadj.) ND 2.6 mg/kg





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33.20












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33.21



Client Sample ID: RINSE-01Lab Sample ID: LA60782-17 Date Sampled: 01/09/20Matrix: AQ - Water Date Received: 01/09/20Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



VOA RECAP List




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Client Sample ID: RINSE-01Lab Sample ID: LA60782-17 Date Sampled: 01/09/20Matrix: AQ - Water Date Received: 01/09/20Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

VOA RECAP List







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Client Sample ID: RINSE-01Lab Sample ID: LA60782-17 Date Sampled: 01/09/20Matrix: AQ - Water Date Received: 01/09/20Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



BN PAH List






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Client Sample ID: RINSE-01Lab Sample ID: LA60782-17 Date Sampled: 01/09/20Matrix: AQ - Water Date Received: 01/09/20Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA








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Client Sample ID: RINSE-01Lab Sample ID: LA60782-17 Date Sampled: 01/09/20Matrix: AQ - Water Date Received: 01/09/20Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA






84-15-1 o-Terphenyl 91% 40-118%


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Client Sample ID: RINSE-01Lab Sample ID: LA60782-17 Date Sampled: 01/09/20Matrix: AQ - Water Date Received: 01/09/20







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VOA RECAP List


67-64-1 Acetone ND 0.50 mg/l71-43-2 Benzene 0.316 0.010 mg/l75-27-4 Bromodichloromethane ND 0.010 mg/l75-25-2 Bromoform ND 0.010 mg/l75-15-0 Carbon Disulfide ND 0.010 mg/l56-23-5 Carbon Tetrachloride ND 0.010 mg/l108-90-7 Chlorobenzene ND 0.010 mg/l75-00-3 Chloroethane ND 0.010 mg/l67-66-3 Chloroform ND 0.010 mg/l124-48-1 Dibromochloromethane ND 0.010 mg/l96-12-8 1,2-Dibromo-3-chloropropane ND 0.010 mg/l541-73-1 m-Dichlorobenzene ND 0.010 mg/l95-50-1 o-Dichlorobenzene ND 0.010 mg/l106-46-7 p-Dichlorobenzene ND 0.010 mg/l75-34-3 1,1-Dichloroethane ND 0.010 mg/l107-06-2 1,2-Dichloroethane 0.0197 0.010 mg/l75-35-4 1,1-Dichloroethylene ND 0.010 mg/l156-59-2 cis-1,2-Dichloroethylene ND 0.010 mg/l156-60-5 trans-1,2-Dichloroethylene ND 0.010 mg/l540-59-0 1,2-Dichloroethene (total) ND 0.010 mg/l78-87-5 1,2-Dichloropropane ND 0.010 mg/l10061-01-5 cis-1,3-Dichloropropene ND 0.010 mg/l10061-02-6 trans-1,3-Dichloropropene ND 0.010 mg/l542-75-6 1,3-Dichloropropene (total) ND 0.010 mg/l100-41-4 Ethylbenzene 1.05 0.010 mg/l67-72-1 Hexachloroethane ND 0.010 mg/l78-83-1 Isobutyl Alcohol ND 1.0 mg/l74-83-9 Methyl Bromide ND 0.010 mg/l74-87-3 Methyl Chloride ND 0.010 mg/l75-09-2 Methylene Chloride ND 0.010 mg/l78-93-3 Methyl Ethyl Ketone ND 0.13 mg/l108-10-1 4-Methyl-2-pentanone ND 0.13 mg/l


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VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether ND 0.010 mg/l100-42-5 Styrene ND 0.010 mg/l630-20-6 1,1,1,2-Tetrachloroethane ND 0.010 mg/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.0050 mg/l127-18-4 Tetrachloroethylene ND 0.010 mg/l108-88-3 Toluene 1.52 0.010 mg/l71-55-6 1,1,1-Trichloroethane ND 0.010 mg/l79-00-5 1,1,2-Trichloroethane ND 0.010 mg/l79-01-6 Trichloroethylene ND 0.010 mg/l75-69-4 Trichlorofluoromethane ND 0.010 mg/l75-01-4 Vinyl Chloride ND 0.010 mg/l

m,p-Xylene 3.78 0.020 mg/l95-47-6 o-Xylene 1.48 0.010 mg/l1330-20-7 Xylene (total) 5.26 0.020 mg/l




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Client Sample ID: DB-3GWLab Sample ID: LA60782-18 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 a L0031751.D 1 01/13/20 21:08 AA 01/13/20 10:30 OP15992 EL864Run #2 L0031775.D 10 01/14/20 10:10 BH 01/13/20 10:30 OP15992 EL865


BN PAH List


83-32-9 Acenaphthene ND 0.00018 mg/l208-96-8 Acenaphthylene ND 0.00018 mg/l120-12-7 Anthracene ND 0.00018 mg/l56-55-3 Benzo(a)anthracene ND 0.00018 mg/l50-32-8 Benzo(a)pyrene ND 0.00018 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00018 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00018 mg/l218-01-9 Chrysene ND 0.00018 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00018 mg/l206-44-0 Fluoranthene ND 0.00018 mg/l86-73-7 Fluorene ND 0.00018 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00018 mg/l91-57-6 2-Methylnaphthalene 0.0230 b 0.0018 mg/l91-20-3 Naphthalene 0.0707 b 0.0018 mg/l85-01-8 Phenanthrene ND 0.00018 mg/l129-00-0 Pyrene ND 0.00018 mg/l


4165-60-0 Nitrobenzene-d5 58% 61% 17-131%321-60-8 2-Fluorobiphenyl 38% 38% 11-122%1718-51-0 Terphenyl-d14 32% 32% 21-144%

(a) rr for dilution 10x(b) Result is from Run# 2


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Client Sample ID: DB-3GWLab Sample ID: LA60782-18 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA




TPH-GRO (C6-C10) 25.3 0.50 mg/l




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33.23



Client Sample ID: DB-3GWLab Sample ID: LA60782-18 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA




TPH-DRO (C10-C28) 4.03 0.14 mg/l


84-15-1 o-Terphenyl 93% 40-118%


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Client Sample ID: DB-3GWLab Sample ID: LA60782-18 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20




Arsenic a 0.0512 0.010 mg/l 10 01/13/20 01/14/20 RT SW846 6020A 1 SW846 3010A 2


(a) Elevated reporting limit due to dilution required for internal standard failure.


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VOA RECAP List




76 of 187

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33.24




VOA RECAP List







77 of 187

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33.24






BN PAH List






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33.24











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84-15-1 o-Terphenyl 91% 40-118%


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Client Sample ID: D-2 FSW Lab Sample ID: LA60782-20 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8260B SW846 1311 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA









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33.25



Client Sample ID: D-2 FSW Lab Sample ID: LA60782-20 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA










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33.25



Client Sample ID: D-2 FSW Lab Sample ID: LA60782-20 Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20














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Client Sample ID: D-2 FSW Lab Sample ID: LA60782-20A Date Sampled: 01/09/20Matrix: AQ - Ground Water Date Received: 01/09/20


General Chemistry


Corrosivity as pH a 7.5 su 1 01/16/20 14:30 ATX SW846 9045C/9045DCyanide Reactivity b ND 0.40 mg/l 1 01/17/20 14:39 ATX SW846 CHAP7Ignitability (Flashpoint) b > 200 Deg. F 1 01/16/20 15:00 ATX SW846 1010/1010ASulfide Reactivity b ND 20 mg/l 1 01/16/20 12:00 ATX SW846 CHAP7

(a) temp. 23.0 c Analysis performed at SGS Houston, TX.(b) Analysis performed at SGS Houston, TX.


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Client Sample ID: D-2 SWS Lab Sample ID: LA60782-21 Date Sampled: 01/09/20Matrix: SO - Soil Date Received: 01/09/20Method: SW846 8260B SW846 1311 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA









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33.27



Client Sample ID: D-2 SWS Lab Sample ID: LA60782-21 Date Sampled: 01/09/20Matrix: SO - Soil Date Received: 01/09/20Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA










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33.27



Client Sample ID: D-2 SWS Lab Sample ID: LA60782-21 Date Sampled: 01/09/20Matrix: SO - Soil Date Received: 01/09/20














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Client Sample ID: D-2 SWS Lab Sample ID: LA60782-21A Date Sampled: 01/09/20Matrix: SO - Soil Date Received: 01/09/20



General Chemistry


Corrosivity as pH b 7.9 su 1 01/17/20 17:30 ATX SW846 9045C/9045DCyanide Reactivity c ND 0.40 mg/kg 1 01/17/20 14:39 ATX SW846 CHAP7Ignitability (Flashpoint) c > 200 Deg. F 1 01/16/20 15:00 ATX SW846 1010/1010ASulfide Reactivity c ND 20 mg/kg 1 01/16/20 12:00 ATX SW846 CHAP7

(a) All results with the exception of 29B parameters are reported on a wet weight basis.(b) temp. 21.7 c Analysis performed at SGS Houston, TX.(c) Analysis performed at SGS Houston, TX.


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33.28






VOA RECAP List




90 of 187

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33.29




VOA RECAP List







91 of 187

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33.29






VOA RECAP List




92 of 187

LA60782

33.30




VOA RECAP List







93 of 187

LA60782

33.30






VOA RECAP List




94 of 187

LA60782

33.31




VOA RECAP List







95 of 187

LA60782

33.31


Misc. Forms




Scott, LASection 4

96 of 187

LA60782

4


97 of 187

LA60782

44.1


98 of 187

LA60782

44.1


99 of 187

LA60782

44.1

Job Number: LA60782 Client: PROVIDENCE ENVIRONMENTAL AND EN

Date / Time Received: 1/9/2020 3:55:00 PM Delivery Method: Accutest Courier


4. No. Coolers: 4

Airbill #'s:


Y or N


3. COC Present:


2. Thermometer ID:


3. Cooler media:

DV439; DV440;

Ice (Bag)


















Intact

Y or N

Comments DB-0 GW time on coc is 0715, time for MS/MSD DB-0 GW is 0915, ziploc bag stated BD-01 SS 1/8/20 @ 1405, bottles state DUP-1SS 1/8/20 @ 1405. DB3 SS(34-36) 1/8/20 @ 1500, Rec'd 1-8oz jar 2-40ml methaol, not on coc. Diss leads are expired.

Y or N N/A

Cooler Temps (Initial/Adjusted): #1: (2.1/2.1); #2: (2.9/2.9); #3: (2.3/2.3); #4: (2/2); #0: (2/2);



100 of 187

LA60782

44.1

Page 2 of 2

Problem Resolution

CSR: Response Date:

Response:

Job Number: LA60782


101 of 187

LA60782

44.1

TAT

(Day

s):

7

Rec

eive

d D

ate:

1/9/

2020

Due

Dat

e:1/

20/2

020

Proj

ect D

escr

iptio

n:B

ottle

Art

Lofts

, Uni

vers

ity &

Cam

eron

, Laf

ayet

te, L

Acco

unt N

ame:

Pro

vide

nce

Engi

neer

ing

& E

nviro

n

Del

iver

able

:C

OM

MB

Req

uest

ed D

ate:

1/22

/202

0

Job

Cha

nge

Ord

er:

LA60

782

PM:

AJ

C/O

Initi

ated

By:

AJ

Sam

ple

#:LA

6078

2-1A

DB

-4SS

(28-

30')

Cha

nge:

Rel

og Z

HE

SPLP

, V82

60SP

LPB

NZ.

Exp

ires

on 1

/22/

20.

Dep

t:

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

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====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

TAT:

7

Sam

ple

#:LA

6078

2-13

A

DB

-1SS

(6-8

')

Cha

nge:

Rel

og Z

HE

SPLP

, V82

60SP

LPB

NZ,

VM

S+X

YL, V

LAVP

HSP

LP. V

PH S

PLP

for C

8-C

10 a

rom

atic

s an

d C

8-C

10 a

lipha

tics.

Dep

t:

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

TAT:

7

Sam

ple

#:LA

6078

2-14

A

DB

-1SS

(28-

30')

Cha

nge:

Rel

og Z

HE

SPLP

, V82

60SP

LPB

NZ.

Dep

t:

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

TAT:

7

Sam

ple

#:LA

6078

2-15

A

DB

-2SS

(18-

20')

Cha

nge:

Rel

og Z

HE

SPLP

, V82

60SP

LPB

NZ,

VLA

VPH

SPL

P fo

r C8-

C10

Aro

mat

ics

only

.D

ept:

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

TAT:

7

Abov

e C

hang

es P

er:

To C

lient

: Th

is C

hang

e O

rder

is c

onfir

mat

ion

of th

e re

visi

ons,

pre

viou

sly

disc

usse

d w

ith th

e C

lient

Ser

vice

Rep

rese

ntat

ive.

Dat

e/Ti

me:

1/22

/202

0 10

:42:

47 A

M

Pag

e 1

of 2

Ste

phen

Osb

orne


102 of 187

LA60782

44.1

TAT

(Day

s):

7

Rec

eive

d D

ate:

1/9/

2020

Due

Dat

e:1/

20/2

020

Proj

ect D

escr

iptio

n:B

ottle

Art

Lofts

, Uni

vers

ity &

Cam

eron

, Laf

ayet

te, L

Acco

unt N

ame:

Pro

vide

nce

Engi

neer

ing

& E

nviro

n

Del

iver

able

:C

OM

MB

Req

uest

ed D

ate:

1/22

/202

0

Job

Cha

nge

Ord

er:

LA60

782

PM:

AJ

C/O

Initi

ated

By:

AJ

Sam

ple

#:LA

6078

2-16

A

DB

-2SS

(28-

30')

Cha

nge:

Rel

og Z

HE

SPLP

, V82

60SP

LPB

NZ.

Dep

t:

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

====

TAT:

7

Abov

e C

hang

es P

er:

To C

lient

: Th

is C

hang

e O

rder

is c

onfir

mat

ion

of th

e re

visi

ons,

pre

viou

sly

disc

usse

d w

ith th

e C

lient

Ser

vice

Rep

rese

ntat

ive.

Dat

e/Ti

me:

1/22

/202

0 10

:42:

47 A

M

Pag

e 2

of 2

Ste

phen

Osb

orne


103 of 187

LA60782

44.1


MS Volatiles

QC Data Summaries



Scott, LASection 5

104 of 187

LA60782

5




LA60782-9, LA60782-12, LA60782-19


67-64-1 Acetone ND 50 ug/l71-43-2 Benzene ND 1.0 ug/l75-27-4 Bromodichloromethane ND 1.0 ug/l75-25-2 Bromoform ND 1.0 ug/l75-15-0 Carbon Disulfide ND 1.0 ug/l56-23-5 Carbon Tetrachloride ND 1.0 ug/l108-90-7 Chlorobenzene ND 1.0 ug/l75-00-3 Chloroethane ND 1.0 ug/l67-66-3 Chloroform ND 1.0 ug/l124-48-1 Dibromochloromethane ND 1.0 ug/l541-73-1 m-Dichlorobenzene ND 1.0 ug/l95-50-1 o-Dichlorobenzene ND 1.0 ug/l106-46-7 p-Dichlorobenzene ND 1.0 ug/l75-34-3 1,1-Dichloroethane ND 1.0 ug/l107-06-2 1,2-Dichloroethane ND 1.0 ug/l75-35-4 1,1-Dichloroethylene ND 1.0 ug/l156-59-2 cis-1,2-Dichloroethylene ND 1.0 ug/l156-60-5 trans-1,2-Dichloroethylene ND 1.0 ug/l540-59-0 1,2-Dichloroethene (total) ND 1.0 ug/l78-87-5 1,2-Dichloropropane ND 1.0 ug/l10061-01-5 cis-1,3-Dichloropropene ND 1.0 ug/l10061-02-6 trans-1,3-Dichloropropene ND 1.0 ug/l542-75-6 1,3-Dichloropropene (total) ND 1.0 ug/l100-41-4 Ethylbenzene ND 1.0 ug/l67-72-1 Hexachloroethane ND 1.0 ug/l78-83-1 Isobutyl Alcohol ND 100 ug/l74-83-9 Methyl Bromide ND 1.0 ug/l74-87-3 Methyl Chloride ND 1.0 ug/l75-09-2 Methylene Chloride ND 1.0 ug/l78-93-3 Methyl Ethyl Ketone ND 13 ug/l108-10-1 4-Methyl-2-pentanone ND 13 ug/l1634-04-4 Methyl Tert Butyl Ether ND 1.0 ug/l100-42-5 Styrene ND 1.0 ug/l630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 ug/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 ug/l127-18-4 Tetrachloroethylene ND 1.0 ug/l

105 of 187

LA60782

55.1.1




LA60782-9, LA60782-12, LA60782-19


108-88-3 Toluene ND 1.0 ug/l71-55-6 1,1,1-Trichloroethane ND 1.0 ug/l79-00-5 1,1,2-Trichloroethane ND 1.0 ug/l79-01-6 Trichloroethylene ND 1.0 ug/l75-69-4 Trichlorofluoromethane ND 1.0 ug/l75-01-4 Vinyl Chloride ND 1.0 ug/l




106 of 187

LA60782

55.1.1




LA60782-22, LA60782-23, LA60782-24


67-64-1 Acetone 2.1 50 ug/l J71-43-2 Benzene ND 1.0 ug/l75-27-4 Bromodichloromethane ND 1.0 ug/l75-25-2 Bromoform ND 1.0 ug/l75-15-0 Carbon Disulfide ND 1.0 ug/l56-23-5 Carbon Tetrachloride ND 1.0 ug/l108-90-7 Chlorobenzene ND 1.0 ug/l75-00-3 Chloroethane ND 1.0 ug/l67-66-3 Chloroform ND 1.0 ug/l124-48-1 Dibromochloromethane ND 1.0 ug/l96-12-8 1,2-Dibromo-3-chloropropane ND 1.0 ug/l541-73-1 m-Dichlorobenzene ND 1.0 ug/l95-50-1 o-Dichlorobenzene ND 1.0 ug/l106-46-7 p-Dichlorobenzene ND 1.0 ug/l75-34-3 1,1-Dichloroethane ND 1.0 ug/l107-06-2 1,2-Dichloroethane ND 1.0 ug/l75-35-4 1,1-Dichloroethylene ND 1.0 ug/l156-59-2 cis-1,2-Dichloroethylene ND 1.0 ug/l156-60-5 trans-1,2-Dichloroethylene ND 1.0 ug/l540-59-0 1,2-Dichloroethene (total) ND 1.0 ug/l78-87-5 1,2-Dichloropropane ND 1.0 ug/l10061-01-5 cis-1,3-Dichloropropene ND 1.0 ug/l10061-02-6 trans-1,3-Dichloropropene ND 1.0 ug/l542-75-6 1,3-Dichloropropene (total) ND 1.0 ug/l100-41-4 Ethylbenzene ND 1.0 ug/l67-72-1 Hexachloroethane ND 1.0 ug/l78-83-1 Isobutyl Alcohol ND 100 ug/l74-83-9 Methyl Bromide ND 1.0 ug/l74-87-3 Methyl Chloride ND 1.0 ug/l75-09-2 Methylene Chloride ND 1.0 ug/l78-93-3 Methyl Ethyl Ketone ND 13 ug/l108-10-1 4-Methyl-2-pentanone ND 13 ug/l1634-04-4 Methyl Tert Butyl Ether ND 1.0 ug/l100-42-5 Styrene ND 1.0 ug/l630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 ug/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 ug/l

107 of 187

LA60782

55.1.2




LA60782-22, LA60782-23, LA60782-24






108 of 187

LA60782

55.1.2




LA60782-1, LA60782-2, LA60782-3, LA60782-4, LA60782-5, LA60782-6, LA60782-7, LA60782-8, LA60782-13,LA60782-14, LA60782-15, LA60782-16


71-43-2 Benzene ND 25 ug/kg100-41-4 Ethylbenzene ND 50 ug/kg108-88-3 Toluene ND 250 ug/kg1330-20-7 Xylene (total) ND 100 ug/kg



109 of 187

LA60782

55.1.3




LA60782-10, LA60782-11, LA60782-17, LA60782-18



110 of 187

LA60782

55.1.4




LA60782-10, LA60782-11, LA60782-17, LA60782-18






111 of 187

LA60782

55.1.4




LA60782-13, LA60782-15


100-41-4 Ethylbenzene ND 50 ug/kg1330-20-7 Xylene (total) ND 100 ug/kg



112 of 187

LA60782

55.1.5


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15996-LB 1Q0455864.D 100 01/15/20 CP 01/13/20 OP15996 V1Q2665


LA60782-20, LA60782-21


71-43-2 Benzene ND 100 ug/l56-23-5 Carbon Tetrachloride ND 100 ug/l108-90-7 Chlorobenzene ND 100 ug/l67-66-3 Chloroform ND 100 ug/l107-06-2 1,2-Dichloroethane 32.0 100 ug/l J75-35-4 1,1-Dichloroethylene ND 100 ug/l78-93-3 Methyl Ethyl Ketone ND 1300 ug/l127-18-4 Tetrachloroethylene ND 100 ug/l79-01-6 Trichloroethylene ND 100 ug/l75-01-4 Vinyl Chloride ND 100 ug/l



113 of 187

LA60782

55.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP16048-LB 2Q0456155.D 1 01/23/20 CP 01/21/20 OP16048 V2Q2678


LA60782-1A


71-43-2 Benzene ND 1.0 ug/l



114 of 187

LA60782

55.2.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP16055-LB 1X0090369.D 1 01/24/20 PJ 01/23/20 OP16055 V1X4043


LA60782-13A, LA60782-14A, LA60782-15A, LA60782-16A


71-43-2 Benzene ND 1.0 ug/l1330-20-7 Xylene (total) ND 2.0 ug/l



115 of 187

LA60782

55.2.3




LA60782-9, LA60782-12, LA60782-19


67-64-1 Acetone 50 48.9 98 47.4 95 3 35-173/2071-43-2 Benzene 20 20.3 102 19.5 98 4 82-119/1175-27-4 Bromodichloromethane 20 21.2 106 20.2 101 5 76-124/1175-25-2 Bromoform 20 18.9 95 17.9 90 5 52-131/1475-15-0 Carbon Disulfide 20 20.1 101 18.1 91 10 69-135/1456-23-5 Carbon Tetrachloride 20 19.9 100 18.3 92 8 73-127/13108-90-7 Chlorobenzene 20 21.8 109 20.8 104 5 82-118/1175-00-3 Chloroethane 20 21.5 108 20.5 103 5 57-146/2067-66-3 Chloroform 20 20.4 102 19.4 97 5 77-122/12124-48-1 Dibromochloromethane 20 19.7 99 18.6 93 6 68-126/12541-73-1 m-Dichlorobenzene 20 21.4 107 20.0 100 7 78-122/1295-50-1 o-Dichlorobenzene 20 20.7 104 19.8 99 4 78-122/12106-46-7 p-Dichlorobenzene 20 20.6 103 19.6 98 5 79-119/1275-34-3 1,1-Dichloroethane 20 19.7 99 18.8 94 5 77-124/14107-06-2 1,2-Dichloroethane 20 22.7 114 21.6 108 5 71-124/1175-35-4 1,1-Dichloroethylene 20 19.6 98 18.7 94 5 77-125/14156-59-2 cis-1,2-Dichloroethylene 20 18.8 94 17.6 88 7 79-121/13156-60-5 trans-1,2-Dichloroethylene 20 19.6 98 18.5 93 6 77-124/14540-59-0 1,2-Dichloroethene (total) 40 38.4 96 36.1 90 6 80-121/1378-87-5 1,2-Dichloropropane 20 20.0 100 19.3 97 4 81-117/1110061-01-5 cis-1,3-Dichloropropene 20 19.5 98 19.1 96 2 77-123/1110061-02-6 trans-1,3-Dichloropropene 20 21.3 107 20.0 100 6 74-127/12542-75-6 1,3-Dichloropropene (total) 40 40.8 102 39.1 98 4 76-124/11100-41-4 Ethylbenzene 20 21.4 107 20.4 102 5 82-120/1167-72-1 Hexachloroethane 20 20.1 101 19.2 96 5 54-132/1578-83-1 Isobutyl Alcohol 200 128 64 135 68 5 37-152/3074-83-9 Methyl Bromide 20 22.1 111 22.8 114 3 46-165/2074-87-3 Methyl Chloride 20 17.7 89 17.4 87 2 55-140/1875-09-2 Methylene Chloride 20 19.4 97 17.6 88 10 73-132/1478-93-3 Methyl Ethyl Ketone 50 44.5 89 43.2 86 3 55-149/19108-10-1 4-Methyl-2-pentanone 50 49.6 99 47.3 95 5 63-137/171634-04-4 Methyl Tert Butyl Ether 20 18.7 94 17.9 90 4 73-124/14100-42-5 Styrene 20 21.3 107 20.0 100 6 80-126/12630-20-6 1,1,1,2-Tetrachloroethane 20 21.5 108 20.3 102 6 77-126/1279-34-5 1,1,2,2-Tetrachloroethane 20 20.8 104 20.7 104 0 69-134/14127-18-4 Tetrachloroethylene 20 21.2 106 20.5 103 3 79-121/13


116 of 187

LA60782

55.3.1




LA60782-9, LA60782-12, LA60782-19


108-88-3 Toluene 20 20.7 104 19.4 97 6 82-118/1271-55-6 1,1,1-Trichloroethane 20 21.4 107 19.5 98 9 79-126/1379-00-5 1,1,2-Trichloroethane 20 20.3 102 20.2 101 0 80-120/1279-01-6 Trichloroethylene 20 19.9 100 19.7 99 1 78-121/1275-69-4 Trichlorofluoromethane 20 19.7 99 19.4 97 2 74-129/1475-01-4 Vinyl Chloride 20 17.2 86 17.4 87 1 74-125/14





117 of 187

LA60782

55.3.1




LA60782-22, LA60782-23, LA60782-24


67-64-1 Acetone 50 58.5 117 53.0 106 10 35-173/2071-43-2 Benzene 20 19.8 99 18.4 92 7 82-119/1175-27-4 Bromodichloromethane 20 20.4 102 19.5 98 5 76-124/1175-25-2 Bromoform 20 17.8 89 16.8 84 6 52-131/1475-15-0 Carbon Disulfide 20 19.9 100 17.9 90 11 69-135/1456-23-5 Carbon Tetrachloride 20 20.5 103 18.1 91 12 73-127/13108-90-7 Chlorobenzene 20 20.3 102 18.4 92 10 82-118/1175-00-3 Chloroethane 20 21.2 106 19.3 97 9 57-146/2067-66-3 Chloroform 20 19.9 100 18.2 91 9 77-122/12124-48-1 Dibromochloromethane 20 20.8 104 19.3 97 7 68-126/1296-12-8 1,2-Dibromo-3-chloropropane 20 16.9 85 16.7 84 1 57-132/17541-73-1 m-Dichlorobenzene 20 21.3 107 19.5 98 9 78-122/1295-50-1 o-Dichlorobenzene 20 21.2 106 19.5 98 8 78-122/12106-46-7 p-Dichlorobenzene 20 20.0 100 18.3 92 9 79-119/1275-34-3 1,1-Dichloroethane 20 20.7 104 18.7 94 10 77-124/14107-06-2 1,2-Dichloroethane 20 20.1 101 19.4 97 4 71-124/1175-35-4 1,1-Dichloroethylene 20 21.3 107 19.1 96 11 77-125/14156-59-2 cis-1,2-Dichloroethylene 20 20.7 104 19.1 96 8 79-121/13156-60-5 trans-1,2-Dichloroethylene 20 19.8 99 18.3 92 8 77-124/14540-59-0 1,2-Dichloroethene (total) 40 40.5 101 37.4 94 8 80-121/1378-87-5 1,2-Dichloropropane 20 20.1 101 19.1 96 5 81-117/1110061-01-5 cis-1,3-Dichloropropene 20 19.0 95 17.7 89 7 77-123/1110061-02-6 trans-1,3-Dichloropropene 20 21.5 108 19.9 100 8 74-127/12542-75-6 1,3-Dichloropropene (total) 40 40.5 101 37.7 94 7 76-124/11100-41-4 Ethylbenzene 20 20.5 103 18.9 95 8 82-120/1167-72-1 Hexachloroethane 20 19.9 100 18.4 92 8 54-132/1578-83-1 Isobutyl Alcohol 200 173 87 159 80 8 37-152/3074-83-9 Methyl Bromide 20 23.7 119 20.6 103 14 46-165/2074-87-3 Methyl Chloride 20 20.1 101 18.3 92 9 55-140/1875-09-2 Methylene Chloride 20 19.8 99 17.7 89 11 73-132/1478-93-3 Methyl Ethyl Ketone 50 48.6 97 46.4 93 5 55-149/19108-10-1 4-Methyl-2-pentanone 50 45.4 91 42.7 85 6 63-137/171634-04-4 Methyl Tert Butyl Ether 20 20.9 105 19.4 97 7 73-124/14100-42-5 Styrene 20 19.4 97 18.0 90 7 80-126/12630-20-6 1,1,1,2-Tetrachloroethane 20 20.5 103 18.5 93 10 77-126/1279-34-5 1,1,2,2-Tetrachloroethane 20 20.3 102 18.6 93 9 69-134/14


118 of 187

LA60782

55.3.2




LA60782-22, LA60782-23, LA60782-24







119 of 187

LA60782

55.3.2




LA60782-10, LA60782-11, LA60782-17, LA60782-18


67-64-1 Acetone 50 55.3 111 54.9 110 1 35-173/2071-43-2 Benzene 20 19.1 96 18.7 94 2 82-119/1175-27-4 Bromodichloromethane 20 19.8 99 19.5 98 2 76-124/1175-25-2 Bromoform 20 15.9 80 16.0 80 1 52-131/1475-15-0 Carbon Disulfide 20 15.8 79 18.3 92 15* 69-135/1456-23-5 Carbon Tetrachloride 20 18.2 91 18.6 93 2 73-127/13108-90-7 Chlorobenzene 20 19.5 98 19.2 96 2 82-118/1175-00-3 Chloroethane 20 21.2 106 21.1 106 0 57-146/2067-66-3 Chloroform 20 18.5 93 18.5 93 0 77-122/12124-48-1 Dibromochloromethane 20 19.0 95 19.1 96 1 68-126/1296-12-8 1,2-Dibromo-3-chloropropane 20 16.1 81 16.0 80 1 57-132/17541-73-1 m-Dichlorobenzene 20 20.4 102 19.9 100 2 78-122/1295-50-1 o-Dichlorobenzene 20 20.1 101 20.5 103 2 78-122/12106-46-7 p-Dichlorobenzene 20 19.5 98 19.5 98 0 79-119/1275-34-3 1,1-Dichloroethane 20 19.3 97 19.1 96 1 77-124/14107-06-2 1,2-Dichloroethane 20 19.1 96 19.3 97 1 71-124/1175-35-4 1,1-Dichloroethylene 20 20.1 101 20.0 100 0 77-125/14156-59-2 cis-1,2-Dichloroethylene 20 18.5 93 19.1 96 3 79-121/13156-60-5 trans-1,2-Dichloroethylene 20 18.3 92 17.8 89 3 77-124/14540-59-0 1,2-Dichloroethene (total) 40 36.8 92 36.9 92 0 80-121/1378-87-5 1,2-Dichloropropane 20 18.6 93 19.1 96 3 81-117/1110061-01-5 cis-1,3-Dichloropropene 20 17.3 87 17.5 88 1 77-123/1110061-02-6 trans-1,3-Dichloropropene 20 19.9 100 20.2 101 1 74-127/12542-75-6 1,3-Dichloropropene (total) 40 37.2 93 37.7 94 1 76-124/11100-41-4 Ethylbenzene 20 19.8 99 19.5 98 2 82-120/1167-72-1 Hexachloroethane 20 19.3 97 18.3 92 5 54-132/1578-83-1 Isobutyl Alcohol 200 154 77 155 78 1 37-152/3074-83-9 Methyl Bromide 20 21.8 109 21.6 108 1 46-165/2074-87-3 Methyl Chloride 20 19.4 97 19.5 98 1 55-140/1875-09-2 Methylene Chloride 20 18.4 92 18.4 92 0 73-132/1478-93-3 Methyl Ethyl Ketone 50 44.4 89 45.7 91 3 55-149/19108-10-1 4-Methyl-2-pentanone 50 43.4 87 43.2 86 0 63-137/171634-04-4 Methyl Tert Butyl Ether 20 18.0 90 18.6 93 3 73-124/14100-42-5 Styrene 20 18.3 92 17.8 89 3 80-126/12630-20-6 1,1,1,2-Tetrachloroethane 20 19.5 98 19.8 99 2 77-126/1279-34-5 1,1,2,2-Tetrachloroethane 20 18.7 94 19.4 97 4 69-134/14


120 of 187

LA60782

55.3.3




LA60782-10, LA60782-11, LA60782-17, LA60782-18







121 of 187

LA60782

55.3.3






71-43-2 Benzene 1000 957 96 870 87 10 67-135/30100-41-4 Ethylbenzene 1000 1030 103 962 96 7 69-136/30108-88-3 Toluene 1000 976 98 919 92 6 71-135/301330-20-7 Xylene (total) 3000 3010 100 2840 95 6 69-138/30




122 of 187

LA60782

55.3.4




LA60782-13, LA60782-15


100-41-4 Ethylbenzene 1000 1100 110 1030 103 7 69-136/301330-20-7 Xylene (total) 3000 3280 109 3120 104 5 69-138/30




123 of 187

LA60782

55.3.5




LA60782-20, LA60782-21


71-43-2 Benzene 2000 1990 100 1950 98 2 78-116/3056-23-5 Carbon Tetrachloride 2000 1950 98 1930 97 1 74-116/30108-90-7 Chlorobenzene 2000 2030 102 2000 100 1 87-111/3067-66-3 Chloroform 2000 1910 96 1960 98 3 79-114/30107-06-2 1,2-Dichloroethane 2000 2040 102 2010 101 1 73-123/3075-35-4 1,1-Dichloroethylene 2000 2070 104 2030 102 2 71-126/3078-93-3 Methyl Ethyl Ketone 5000 5120 102 4590 92 11 69-123/30127-18-4 Tetrachloroethylene 2000 2180 109 2070 104 5 81-116/3079-01-6 Trichloroethylene 2000 1870 94 1960 98 5 53-149/3075-01-4 Vinyl Chloride 2000 1900 95 1920 96 1 68-125/30




124 of 187

LA60782

55.3.6




LA60782-1A


71-43-2 Benzene 20 19.8 99 19.0 95 4 78-116/30




125 of 187

LA60782

55.3.7


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchV1X4043-BS1 1X0090361.D 1 01/24/20 PJ n/a n/a V1X4043V1X4043-BSD1 1X0090363.D 1 01/24/20 PJ n/a n/a V1X4043


LA60782-13A, LA60782-14A, LA60782-15A, LA60782-16A


71-43-2 Benzene 20 19.9 100 20.9 105 5 82-119/111330-20-7 Xylene (total) 60 66.4 111 66.8 111 1 82-122/11




126 of 187

LA60782

55.3.8


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-14MS 2Q0455829.D 1 01/14/20 CP n/a n/a V2Q2663LA60782-14 2Q0455819.D 1 01/14/20 CP n/a n/a V2Q2663



LA60782-14 Spike MS MSCAS No. Compound ug/kg Q ug/kg ug/kg % Limits

71-43-2 Benzene 200 2000 2150 98 15-162100-41-4 Ethylbenzene 120 2000 2170 103 14-168108-88-3 Toluene 96.5 2000 2070 99 11-1731330-20-7 Xylene (total) 462 6000 6720 104 14-172




127 of 187

LA60782

55.4.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-14MS 2Q0455831.D 1 01/14/20 CP n/a n/a V2Q2663LA60782-14 2Q0455819.D 1 01/14/20 CP n/a n/a V2Q2663



LA60782-14 Spike MS MSCAS No. Compound ug/kg Q ug/kg ug/kg % Limits

71-43-2 Benzene 200 2000 2050 93 15-162100-41-4 Ethylbenzene 120 2000 2070 98 14-168108-88-3 Toluene 96.5 2000 1950 93 11-1731330-20-7 Xylene (total) 462 6000 6410 99 14-172




128 of 187

LA60782

55.4.2




LA60782-9, LA60782-12, LA60782-19


67-64-1 Acetone 5400 5000 9600 84 5000 9710 86 1 11-126/2271-43-2 Benzene 7110 2000 8840 87 2000 9220 106 4 41-155/1475-27-4 Bromodichloromethane ND 2000 1940 97 2000 1970 99 2 65-125/1475-25-2 Bromoform ND 2000 1740 87 2000 1710 86 2 39-127/1875-15-0 Carbon Disulfide ND 2000 1420 71 2000 1470 74 3 55-139/2056-23-5 Carbon Tetrachloride ND 2000 1800 90 2000 1800 90 0 60-131/20108-90-7 Chlorobenzene ND 2000 1840 92 2000 1900 95 3 71-124/1475-00-3 Chloroethane ND 2000 2030 102 2000 2050 103 1 44-163/3167-66-3 Chloroform ND 2000 1880 94 2000 1930 97 3 65-130/15124-48-1 Dibromochloromethane ND 2000 1760 88 2000 1810 91 3 57-125/15541-73-1 m-Dichlorobenzene ND 2000 1680 84 2000 1730 87 3 67-124/1495-50-1 o-Dichlorobenzene ND 2000 1760 88 2000 1800 90 2 67-124/14106-46-7 p-Dichlorobenzene ND 2000 1620 81 2000 1740 87 7 66-122/1575-34-3 1,1-Dichloroethane ND 2000 1970 99 2000 2010 101 2 65-132/17107-06-2 1,2-Dichloroethane ND 2000 2080 104 2000 2150 108 3 61-130/1375-35-4 1,1-Dichloroethylene ND 2000 1650 83 2000 1710 86 4 62-136/20156-59-2 cis-1,2-Dichloroethylene ND 2000 1690 85 2000 1750 88 3 68-129/15156-60-5 trans-1,2-Dichloroethylene ND 2000 1560 78 2000 1660 83 6 65-132/18540-59-0 1,2-Dichloroethene (total) ND 4000 3260 82 4000 3410 85 4 66-130/1578-87-5 1,2-Dichloropropane ND 2000 1860 93 2000 1890 95 2 71-123/1410061-01-5 cis-1,3-Dichloropropene ND 2000 1300 65 2000 1320 66 2 61-125/1510061-02-6 trans-1,3-Dichloropropene ND 2000 1370 69 2000 1390 70 1 59-128/14542-75-6 1,3-Dichloropropene (total) ND 4000 2670 67 4000 2710 68 1 61-126/14100-41-4 Ethylbenzene 240 2000 2060 91 2000 2110 94 2 50-147/1567-72-1 Hexachloroethane ND 2000 1730 87 2000 1660 83 4 42-122/2178-83-1 Isobutyl Alcohol ND 20000 14700 74 20000 11900 60 21 6-168/4174-83-9 Methyl Bromide ND 2000 1590 80 2000 1920 96 19 24-163/2874-87-3 Methyl Chloride ND 2000 1540 77 2000 1610 81 4 37-151/2275-09-2 Methylene Chloride 29.4 2000 1790 88 2000 1790 88 0 63-137/1678-93-3 Methyl Ethyl Ketone 390 5000 4330 79 5000 4510 82 4 35-137/21108-10-1 4-Methyl-2-pentanone ND 5000 4700 94 5000 4710 94 0 48-146/211634-04-4 Methyl Tert Butyl Ether ND 2000 1760 88 2000 1780 89 1 48-143/15100-42-5 Styrene ND 2000 1810 91 2000 1810 91 0 58-140/18630-20-6 1,1,1,2-Tetrachloroethane ND 2000 1970 99 2000 1990 100 1 67-127/1579-34-5 1,1,2,2-Tetrachloroethane ND 2000 1980 99 2000 1990 100 1 62-139/16127-18-4 Tetrachloroethylene ND 2000 1520 76 2000 1670 84 9 68-127/19


129 of 187

LA60782

55.5.1




LA60782-9, LA60782-12, LA60782-19


108-88-3 Toluene 5870 2000 7020 58 2000 7350 74 5 40-153/1571-55-6 1,1,1-Trichloroethane ND 2000 1880 94 2000 1920 96 2 68-132/1879-00-5 1,1,2-Trichloroethane ND 2000 1890 95 2000 1920 96 2 62-137/1679-01-6 Trichloroethylene ND 2000 1660 83 2000 1740 87 5 67-124/1675-69-4 Trichlorofluoromethane ND 2000 1780 89 2000 1810 91 2 65-134/1775-01-4 Vinyl Chloride ND 2000 1500 75 2000 1640 82 9 60-133/16





130 of 187

LA60782

55.5.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60806-14MS 1Q0455776.D 20 01/14/20 CP n/a n/a V1Q2661LA60806-14MSD 1Q0455778.D 20 01/14/20 CP n/a n/a V1Q2661LA60806-14 a 1Q0455774.D 10 01/14/20 CP n/a n/a V1Q2661


LA60782-22, LA60782-23, LA60782-24


67-64-1 Acetone 16.0 1000 811 80 1000 793 78 2 11-126/2271-43-2 Benzene 13.4 400 397 96 400 407 98 2 41-155/1475-27-4 Bromodichloromethane ND 400 415 104 400 414 104 0 65-125/1475-25-2 Bromoform ND 400 318 80 400 327 82 3 39-127/1875-15-0 Carbon Disulfide ND 400 371 93 400 382 96 3 55-139/2056-23-5 Carbon Tetrachloride ND 400 384 96 400 407 102 6 60-131/20108-90-7 Chlorobenzene ND 400 383 96 400 392 98 2 71-124/1475-00-3 Chloroethane ND 400 374 94 400 440 110 16 44-163/3167-66-3 Chloroform ND 400 391 98 400 407 102 4 65-130/15124-48-1 Dibromochloromethane ND 400 376 94 400 396 99 5 57-125/1596-12-8 1,2-Dibromo-3-chloropropane ND 400 309 77 400 307 77 1 43-132/22541-73-1 m-Dichlorobenzene ND 400 404 101 400 395 99 2 67-124/1495-50-1 o-Dichlorobenzene ND 400 400 100 400 400 100 0 67-124/14106-46-7 p-Dichlorobenzene ND 400 376 94 400 386 97 3 66-122/1575-34-3 1,1-Dichloroethane ND 400 402 101 400 423 106 5 65-132/17107-06-2 1,2-Dichloroethane ND 400 402 101 400 415 104 3 61-130/1375-35-4 1,1-Dichloroethylene ND 400 408 102 400 420 105 3 62-136/20156-59-2 cis-1,2-Dichloroethylene ND 400 403 101 400 412 103 2 68-129/15156-60-5 trans-1,2-Dichloroethylene ND 400 376 94 400 389 97 3 65-132/18540-59-0 1,2-Dichloroethene (total) ND 800 779 97 800 801 100 3 66-130/1578-87-5 1,2-Dichloropropane ND 400 393 98 400 403 101 3 71-123/1410061-01-5 cis-1,3-Dichloropropene ND 400 316 79 400 327 82 3 61-125/1510061-02-6 trans-1,3-Dichloropropene ND 400 370 93 400 383 96 3 59-128/14542-75-6 1,3-Dichloropropene (total) ND 800 686 86 800 710 89 3 61-126/14100-41-4 Ethylbenzene ND 400 388 97 400 390 98 1 50-147/1567-72-1 Hexachloroethane ND 400 360 90 400 354 89 2 42-122/2178-83-1 Isobutyl Alcohol ND 4000 3370 84 4000 3040 76 10 6-168/4174-83-9 Methyl Bromide ND 400 434 109 400 456 114 5 24-163/2874-87-3 Methyl Chloride ND 400 415 104 400 425 106 2 37-151/2275-09-2 Methylene Chloride ND 400 409 102 400 403 101 1 63-137/1678-93-3 Methyl Ethyl Ketone ND 1000 879 88 1000 836 84 5 35-137/21108-10-1 4-Methyl-2-pentanone ND 1000 912 91 1000 886 89 3 48-146/211634-04-4 Methyl Tert Butyl Ether ND 400 388 97 400 402 101 4 48-143/15100-42-5 Styrene ND 400 363 91 400 359 90 1 58-140/18630-20-6 1,1,1,2-Tetrachloroethane ND 400 388 97 400 392 98 1 67-127/1579-34-5 1,1,2,2-Tetrachloroethane ND 400 397 99 400 392 98 1 62-139/16


131 of 187

LA60782

55.5.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60806-14MS 1Q0455776.D 20 01/14/20 CP n/a n/a V1Q2661LA60806-14MSD 1Q0455778.D 20 01/14/20 CP n/a n/a V1Q2661LA60806-14 a 1Q0455774.D 10 01/14/20 CP n/a n/a V1Q2661


LA60782-22, LA60782-23, LA60782-24


127-18-4 Tetrachloroethylene ND 400 392 98 400 380 95 3 68-127/19108-88-3 Toluene 9.7 400 386 94 400 393 96 2 40-153/1571-55-6 1,1,1-Trichloroethane ND 400 398 100 400 416 104 4 68-132/1879-00-5 1,1,2-Trichloroethane ND 400 382 96 400 390 98 2 62-137/1679-01-6 Trichloroethylene ND 400 377 94 400 383 96 2 67-124/1675-69-4 Trichlorofluoromethane ND 400 441 110 400 430 108 3 65-134/1775-01-4 Vinyl Chloride ND 400 406 102 400 413 103 2 60-133/16

m,p-Xylene 5.1 800 831 103 800 855 106 3 47-153/1595-47-6 o-Xylene ND 400 350 88 400 360 90 3 50-149/141330-20-7 Xylene (total) 6.8 1200 1180 98 1200 1210 100 3 46-154/15





132 of 187

LA60782

55.5.2




LA60782-10, LA60782-11, LA60782-17, LA60782-18


67-64-1 Acetone 2.3 100 71.2 69 100 63.6 61 11 11-126/2271-43-2 Benzene ND 40 38.3 96 40 35.0 88 9 41-155/1475-27-4 Bromodichloromethane ND 40 37.6 94 40 35.6 89 5 65-125/1475-25-2 Bromoform ND 40 30.1 75 40 29.8 75 1 39-127/1875-15-0 Carbon Disulfide ND 40 35.8 90 40 32.9 82 8 55-139/2056-23-5 Carbon Tetrachloride ND 40 37.1 93 40 33.6 84 10 60-131/20108-90-7 Chlorobenzene ND 40 38.4 96 40 36.1 90 6 71-124/1475-00-3 Chloroethane ND 40 40.7 102 40 37.6 94 8 44-163/3167-66-3 Chloroform ND 40 36.8 92 40 33.8 85 8 65-130/15124-48-1 Dibromochloromethane ND 40 37.1 93 40 34.5 86 7 57-125/1596-12-8 1,2-Dibromo-3-chloropropane ND 40 30.5 76 40 28.3 71 7 43-132/22541-73-1 m-Dichlorobenzene ND 40 40.1 100 40 37.2 93 8 67-124/1495-50-1 o-Dichlorobenzene ND 40 40.0 100 40 36.9 92 8 67-124/14106-46-7 p-Dichlorobenzene ND 40 38.4 96 40 35.8 90 7 66-122/1575-34-3 1,1-Dichloroethane ND 40 38.2 96 40 36.9 92 3 65-132/17107-06-2 1,2-Dichloroethane 1.1 40 39.6 96 40 35.8 87 10 61-130/1375-35-4 1,1-Dichloroethylene ND 40 39.9 100 40 36.1 90 10 62-136/20156-59-2 cis-1,2-Dichloroethylene ND 40 37.7 94 40 35.3 88 7 68-129/15156-60-5 trans-1,2-Dichloroethylene ND 40 35.7 89 40 33.0 83 8 65-132/18540-59-0 1,2-Dichloroethene (total) ND 80 73.4 92 80 68.3 85 7 66-130/1578-87-5 1,2-Dichloropropane ND 40 39.1 98 40 34.7 87 12 71-123/1410061-01-5 cis-1,3-Dichloropropene ND 40 32.3 81 40 31.0 78 4 61-125/1510061-02-6 trans-1,3-Dichloropropene ND 40 38.0 95 40 36.9 92 3 59-128/14542-75-6 1,3-Dichloropropene (total) ND 80 70.3 88 80 67.8 85 4 61-126/14100-41-4 Ethylbenzene 0.48 40 39.8 98 40 37.6 93 6 50-147/1567-72-1 Hexachloroethane ND 40 34.6 87 40 33.3 83 4 42-122/2178-83-1 Isobutyl Alcohol ND 400 270 68 400 271 68 0 6-168/4174-83-9 Methyl Bromide ND 40 43.8 110 40 41.1 103 6 24-163/2874-87-3 Methyl Chloride ND 40 37.0 93 40 35.9 90 3 37-151/2275-09-2 Methylene Chloride ND 40 35.1 88 40 34.1 85 3 63-137/1678-93-3 Methyl Ethyl Ketone ND 100 73.8 74 100 69.9 70 5 35-137/21108-10-1 4-Methyl-2-pentanone ND 100 80.4 80 100 77.5 78 4 48-146/211634-04-4 Methyl Tert Butyl Ether 76.7 40 116 98 40 113 91 3 48-143/15100-42-5 Styrene ND 40 35.4 89 40 34.1 85 4 58-140/18630-20-6 1,1,1,2-Tetrachloroethane ND 40 38.6 97 40 36.3 91 6 67-127/1579-34-5 1,1,2,2-Tetrachloroethane ND 40 38.3 96 40 36.2 91 6 62-139/16


133 of 187

LA60782

55.5.3




LA60782-10, LA60782-11, LA60782-17, LA60782-18


127-18-4 Tetrachloroethylene ND 40 39.9 100 40 37.2 93 7 68-127/19108-88-3 Toluene ND 40 38.6 97 40 35.3 88 9 40-153/1571-55-6 1,1,1-Trichloroethane ND 40 37.8 95 40 35.2 88 7 68-132/1879-00-5 1,1,2-Trichloroethane ND 40 38.0 95 40 36.6 92 4 62-137/1679-01-6 Trichloroethylene ND 40 36.6 92 40 33.2 83 10 67-124/1675-69-4 Trichlorofluoromethane ND 40 42.6 107 40 40.0 100 6 65-134/1775-01-4 Vinyl Chloride ND 40 39.0 98 40 36.5 91 7 60-133/16

m,p-Xylene ND 80 86.2 108 80 79.3 99 8 47-153/1595-47-6 o-Xylene ND 40 35.5 89 40 33.6 84 5 50-149/141330-20-7 Xylene (total) ND 120 122 102 120 113 94 8 46-154/15




134 of 187

LA60782

55.5.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60752-1AMS 2Q0455867.D 1 01/15/20 CP n/a n/a V2Q2665LA60752-1AMSD 2Q0455869.D 1 01/15/20 CP n/a n/a V2Q2665LA60752-1A 2Q0455865.D 1 01/15/20 CP n/a n/a V2Q2665


LA60782-13, LA60782-15

LA60752-1A Spike MS MS Spike MSD MSD LimitsCAS No. Compound ug/kg Q ug/kg ug/kg % ug/kg ug/kg % RPD Rec/RPD

100-41-4 Ethylbenzene 11400 100000 108000 97 100000 104000 93 4 14-168/131330-20-7 Xylene (total) 140000 300000 461000 107 300000 448000 103 3 14-172/12

CAS No. Surrogate Recoveries MS MSD LA60752-1A Limits



135 of 187

LA60782

55.5.4


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-21MS 1Q0455890.D 100 01/15/20 CP n/a n/a V1Q2665LA60782-21MSD 1Q0455892.D 100 01/15/20 CP n/a n/a V1Q2665LA60782-21 1Q0455884.D 100 01/15/20 CP 01/13/20 OP15996 V1Q2665


LA60782-20, LA60782-21


71-43-2 Benzene ND 2000 1630 82 2000 1850 93 13 31-161/1556-23-5 Carbon Tetrachloride ND 2000 1600 80 2000 1850 93 14 53-133/36108-90-7 Chlorobenzene ND 2000 1690 85 2000 1880 94 11 74-122/3467-66-3 Chloroform ND 2000 1650 83 2000 1820 91 10 65-130/24107-06-2 1,2-Dichloroethane ND 2000 1760 88 2000 1910 96 8 51-141/3975-35-4 1,1-Dichloroethylene ND 2000 1740 87 2000 1930 97 10 48-139/3778-93-3 Methyl Ethyl Ketone ND 5000 3430 69 5000 3730 75 8 54-142/39127-18-4 Tetrachloroethylene ND 2000 1660 83 2000 1960 98 17 58-135/3779-01-6 Trichloroethylene ND 2000 1610 81 2000 1760 88 9 57-131/3675-01-4 Vinyl Chloride ND 2000 1810 91 2000 1860 93 3 22-155/49




136 of 187

LA60782

55.5.5


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-1AMS 2Q0456165.D 10 01/23/20 CP n/a n/a V2Q2678LA60782-1AMSD 2Q0456166.D 10 01/23/20 CP n/a n/a V2Q2678LA60782-1A 2Q0456163.D 1 01/23/20 CP 01/21/20 OP16048 V2Q2678


LA60782-1A

LA60782-1A Spike MS MS Spike MSD MSD LimitsCAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene 43.4 200 247 102 200 233 95 6 31-161/15




137 of 187

LA60782

55.5.6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-13AMS 1X0090379.D 10 01/24/20 PJ n/a n/a V1X4043LA60782-13AMSD 1X0090381.D 10 01/24/20 PJ n/a n/a V1X4043LA60782-13A 1X0090371.D 10 01/24/20 PJ 01/23/20 OP16055 V1X4043


LA60782-13A, LA60782-14A, LA60782-15A, LA60782-16A

LA60782-13ASpike MS MS Spike MSD MSD LimitsCAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene 14.7 200 216 101 200 202 94 7 31-161/151330-20-7 Xylene (total) 157 600 801 107 600 750 99 7 41-154/29

CAS No. Surrogate Recoveries MS MSD LA60782-13ALimits



138 of 187

LA60782

55.5.7


MS Semi-volatiles

QC Data Summaries



Scott, LASection 6

139 of 187

LA60782

6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP16004-MB F0062813.D 1 01/14/20 BH 01/14/20 OP16004 EF2141


LA60782-20, LA60782-21


95-48-7 2-Methylphenol ND 50 ug/l3&4-Methylphenol ND 50 ug/l

87-86-5 Pentachlorophenol ND 100 ug/l95-95-4 2,4,5-Trichlorophenol ND 50 ug/l88-06-2 2,4,6-Trichlorophenol ND 50 ug/l106-46-7 1,4-Dichlorobenzene ND 50 ug/l121-14-2 2,4-Dinitrotoluene ND 50 ug/l118-74-1 Hexachlorobenzene ND 50 ug/l87-68-3 Hexachlorobutadiene ND 50 ug/l67-72-1 Hexachloroethane ND 50 ug/l98-95-3 Nitrobenzene ND 50 ug/l110-86-1 Pyridine ND 50 ug/l



140 of 187

LA60782

66.1.1




LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


83-32-9 Acenaphthene ND 0.20 ug/l208-96-8 Acenaphthylene ND 0.20 ug/l120-12-7 Anthracene ND 0.20 ug/l56-55-3 Benzo(a)anthracene ND 0.20 ug/l50-32-8 Benzo(a)pyrene ND 0.20 ug/l205-99-2 Benzo(b)fluoranthene ND 0.20 ug/l207-08-9 Benzo(k)fluoranthene ND 0.20 ug/l218-01-9 Chrysene ND 0.20 ug/l53-70-3 Dibenzo(a,h)anthracene ND 0.20 ug/l206-44-0 Fluoranthene ND 0.20 ug/l86-73-7 Fluorene ND 0.20 ug/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.20 ug/l91-57-6 2-Methylnaphthalene ND 0.20 ug/l91-20-3 Naphthalene ND 0.20 ug/l85-01-8 Phenanthrene ND 0.20 ug/l129-00-0 Pyrene ND 0.20 ug/l



141 of 187

LA60782

66.1.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP16004-BS F0062814.D 1 01/14/20 BH 01/14/20 OP16004 EF2141OP16004-BSD F0062815.D 1 01/14/20 BH 01/14/20 OP16004 EF2141


LA60782-20, LA60782-21


95-48-7 2-Methylphenol 500 329 66 333 67 1 54-97/183&4-Methylphenol 500 303 61 306 61 1 47-92/19

87-86-5 Pentachlorophenol 500 442 88 452 90 2 52-120/2995-95-4 2,4,5-Trichlorophenol 500 481 96 467 93 3 67-119/2188-06-2 2,4,6-Trichlorophenol 500 466 93 487 97 4 67-120/21106-46-7 1,4-Dichlorobenzene 500 365 73 371 74 2 52-109/28121-14-2 2,4-Dinitrotoluene 500 490 98 488 98 0 73-122/21118-74-1 Hexachlorobenzene 500 471 94 478 96 1 67-117/2387-68-3 Hexachlorobutadiene 500 370 74 377 75 2 42-120/3567-72-1 Hexachloroethane 500 348 70 352 70 1 44-115/3298-95-3 Nitrobenzene 500 437 87 428 86 2 69-116/21110-86-1 Pyridine 500 156 31 175 35 11 5-78/50




142 of 187

LA60782

66.2.1




LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


83-32-9 Acenaphthene 5 3.8 76 4.0 80 5 19-119/30208-96-8 Acenaphthylene 5 4.0 80 4.1 82 2 25-123/30120-12-7 Anthracene 5 4.2 84 4.1 82 2 33-126/3056-55-3 Benzo(a)anthracene 5 5.2 104 5.1 102 2 38-126/3050-32-8 Benzo(a)pyrene 5 4.6 92 4.5 90 2 38-123/30205-99-2 Benzo(b)fluoranthene 5 5.4 108 5.2 104 4 43-132/30207-08-9 Benzo(k)fluoranthene 5 4.6 92 4.5 90 2 45-132/30218-01-9 Chrysene 5 5.0 100 5.0 100 0 34-129/3053-70-3 Dibenzo(a,h)anthracene 5 4.7 94 4.6 92 2 42-132/30206-44-0 Fluoranthene 5 5.0 100 4.8 96 4 39-129/3086-73-7 Fluorene 5 4.0 80 4.1 82 2 26-123/30193-39-5 Indeno(1,2,3-cd)pyrene 5 4.7 94 4.6 92 2 38-132/3091-57-6 2-Methylnaphthalene 5 4.2 84 4.4 88 5 19-110/3091-20-3 Naphthalene 5 4.2 84 4.4 88 5 19-115/3085-01-8 Phenanthrene 5 4.3 86 4.2 84 2 32-121/30129-00-0 Pyrene 5 5.1 102 4.9 98 4 33-131/30


4165-60-0 Nitrobenzene-d5 90% 95% 17-131%321-60-8 2-Fluorobiphenyl 80% 83% 11-122%1718-51-0 Terphenyl-d14 115% 111% 21-144%


143 of 187

LA60782

66.2.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP16004-MS F0062816.D 1 01/14/20 BH 01/14/20 OP16004 EF2141LA60681-1 F0062817.D 1 01/14/20 BH 01/14/20 OP16004 EF2141


LA60782-20, LA60782-21


95-48-7 2-Methylphenol ND 500 321 64 54-973&4-Methylphenol ND 500 302 60 47-92

87-86-5 Pentachlorophenol ND 500 471 94 52-12095-95-4 2,4,5-Trichlorophenol ND 500 472 94 67-11988-06-2 2,4,6-Trichlorophenol ND 500 480 96 67-120106-46-7 1,4-Dichlorobenzene ND 500 346 69 52-109121-14-2 2,4-Dinitrotoluene ND 500 513 103 73-122118-74-1 Hexachlorobenzene ND 500 493 99 67-11787-68-3 Hexachlorobutadiene ND 500 354 71 42-12067-72-1 Hexachloroethane ND 500 321 64 44-11598-95-3 Nitrobenzene ND 500 426 85 69-116110-86-1 Pyridine ND 500 187 37 5-78




144 of 187

LA60782

66.3.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15992-MS L0031741.D 1 01/13/20 AA 01/13/20 OP15992 EL864OP15992-MSD L0031742.D 1 01/13/20 AA 01/13/20 OP15992 EL864LA60782-10 L0031748.D 1 01/13/20 AA 01/13/20 OP15992 EL864


LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


83-32-9 Acenaphthene ND 4.72 3.1 66 4.76 2.9 61 7 19-119/38208-96-8 Acenaphthylene ND 4.72 3.3 70 4.76 3.2 67 3 25-123/40120-12-7 Anthracene ND 4.72 3.4 72 4.76 3.4 71 0 33-126/3056-55-3 Benzo(a)anthracene ND 4.72 4.2 89 4.76 4.6 97 9 38-126/3250-32-8 Benzo(a)pyrene ND 4.72 3.1 66 4.76 3.4 71 9 38-123/33205-99-2 Benzo(b)fluoranthene ND 4.72 3.9 83 4.76 4.0 84 3 43-132/34207-08-9 Benzo(k)fluoranthene ND 4.72 2.8 59 4.76 3.4 71 19 45-132/27218-01-9 Chrysene ND 4.72 3.9 83 4.76 4.3 90 10 34-129/2853-70-3 Dibenzo(a,h)anthracene ND 4.72 2.8 59 4.76 3.2 67 13 42-132/29206-44-0 Fluoranthene ND 4.72 4.2 89 4.76 4.4 92 5 39-129/2786-73-7 Fluorene ND 4.72 3.3 70 4.76 3.1 65 6 26-123/39193-39-5 Indeno(1,2,3-cd)pyrene ND 4.72 2.8 59 4.76 3.0 63 7 38-132/3291-57-6 2-Methylnaphthalene 0.044 4.72 3.4 71 4.76 3.2 66 6 19-110/3791-20-3 Naphthalene 0.036 4.72 3.4 71 4.76 3.2 66 6 19-115/3985-01-8 Phenanthrene 0.022 4.72 3.5 74 4.76 3.4 71 3 32-121/30129-00-0 Pyrene ND 4.72 4.3 91 4.76 4.4 92 2 33-131/32


4165-60-0 Nitrobenzene-d5 81% 77% 85% 17-131%321-60-8 2-Fluorobiphenyl 65% 61% 69% 11-122%1718-51-0 Terphenyl-d14 93% 97% 102% 21-144%


145 of 187

LA60782

66.4.1


GC Volatiles

QC Data Summaries



Scott, LASection 7

146 of 187

LA60782

7


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLE1982-MB1 LE367366.D 1 01/14/20 NN n/a n/a GLE1982




Aliphatics C6-C8 (Unadj.) 280 1500 ug/kg JAliphatics > C8-C10 (Unadj.) 469 2500 ug/kg JAromatics > C8-C10 (Unadj.) 828 2500 ug/kg J




147 of 187

LA60782

77.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLA2866-MB2 LA357716.D 1 01/14/20 LR n/a n/a GLA2866


LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19





148 of 187

LA60782

77.1.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP16056-LB LC082020.D 1 01/24/20 NN 01/23/20 OP16056 GLC2598


LA60782-13A, LA60782-15A


Aliphatics C6-C8 (Unadj.) ND 30 ug/lAliphatics > C8-C10 (Unadj.) ND 50 ug/lAromatics > C8-C10 (Unadj.) ND 50 ug/l




149 of 187

LA60782

77.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLE1982-BS2 LE367364.D 1 01/14/20 NN n/a n/a GLE1982GLE1982-BSD2 LE367365.D 1 01/14/20 NN n/a n/a GLE1982









150 of 187

LA60782

77.3.1




LA60782-13A, LA60782-15A







151 of 187

LA60782

77.3.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchGLA2866-BS1 LA357706.D 1 01/14/20 LR n/a n/a GLA2866GLA2866-BSD1 LA357708.D 1 01/14/20 LR n/a n/a GLA2866


LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


TPH-GRO (C6-C10) 1 0.931 93 0.928 93 0 81-119/10




152 of 187

LA60782

77.3.3


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-14MS LE367377.D 1 01/15/20 NN n/a n/a GLE1982LA60782-14MSD LE367378.D 1 01/15/20 NN n/a n/a GLE1982LA60782-14 LE367394.D 1 01/15/20 NN n/a n/a GLE1982




Aliphatics C6-C8 (Unadj.) 1110 7500 7900 91 7500 7880 90 0 70-130/50Aliphatics > C8-C10 (Unadj.) 2190 12500 12600 83 12500 12500 82 1 70-130/50Aromatics > C8-C10 (Unadj.) 1980 12500 13400 91 12500 13300 91 1 70-130/50


615-59-8 2,5-Dibromotoluene 104% 104% 97% a 70-130%615-59-8 2,5-Dibromotoluene 104% 103% 96% b 70-130%



153 of 187

LA60782

77.4.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-15AMS LC082037.D 20 01/25/20 NN n/a n/a GLC2598LA60782-15AMSD LC082038.D 20 01/25/20 NN n/a n/a GLC2598LA60782-15A LC082036.D 1 01/24/20 NN 01/23/20 OP16056 GLC2598


LA60782-13A, LA60782-15A

LA60782-15ASpike MS MS Spike MSD MSD LimitsCAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

Aliphatics C6-C8 (Unadj.) 8.3 3000 2750 91 3000 2820 94 3 70-130/50Aliphatics > C8-C10 (Unadj.) ND 5000 4730 95 5000 4890 98 3 70-130/50Aromatics > C8-C10 (Unadj.) ND 5000 4790 96 5000 4960 99 3 70-130/50

CAS No. Surrogate Recoveries MS MSD LA60782-15ALimits




154 of 187

LA60782

77.4.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA60782-10MS LA357844.D 2 01/15/20 LR n/a n/a GLA2866LA60782-10MSD LA357846.D 2 01/15/20 LR n/a n/a GLA2866LA60782-10 LA357734.D 1 01/14/20 LR n/a n/a GLA2866


LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


TPH-GRO (C6-C10) 0.300 2 1.84 77 2 1.77 74 4 40-149/10




155 of 187

LA60782

77.4.3



QC Data Summaries



Scott, LASection 8

156 of 187

LA60782

8


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15991-MB GLH027705A.D1 01/14/20 PC 01/13/20 OP15991 GLH602


LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


TPH-DRO (C10-C28) 0.0420 0.056 mg/l J


84-15-1 o-Terphenyl 95% 40-118%

157 of 187

LA60782

88.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15991-BS GLH027706A.D1 01/14/20 PC 01/13/20 OP15991 GLH602OP15991-BSD GLH027707A.D1 01/14/20 PC 01/13/20 OP15991 GLH602


LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


TPH-DRO (C10-C28) 11 8.47 77 9.45 85 11 72-112/18


84-15-1 o-Terphenyl 86% 95% 40-118%


158 of 187

LA60782

88.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15991-MS GLH027710.D 1 01/14/20 PC 01/13/20 OP15991 GLH602OP15991-MSD GLH027711.D 1 01/14/20 PC 01/13/20 OP15991 GLH602LA60782-10 GLH027713.D 1 01/14/20 PC 01/13/20 OP15991 GLH602


LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19


TPH-DRO (C10-C28) 0.0876 10.9 8.18 74 11 8.31 75 2 41-136/29


84-15-1 o-Terphenyl 83% 85% 93% 40-118%


159 of 187

LA60782

88.3.1


Metals Analysis

QC Data Summaries



Scott, LASection 9

160 of 187

LA60782

9





Prep Date: 01/13/20

MB

01/13/20


Aluminum 100 1.1 24

Antimony 1.0 .023 .57

Arsenic 1.0 .038 .64 0.040 <1.0

Barium 1.0 .052 .49

Beryllium 1.0 .0029 .49

Boron 20 1.8 5.9

Cadmium 0.50 .008 .29

Calcium 100 21 84

Cerium 1.0 .0018 .9

Chromium 1.0 .026 .54

Cobalt 1.0 .0056 .48

Copper 1.0 .11 .74

Iron 100 1.1 43

Lanthanum 1.0 .0015 .56

Lithium 2.0 .4 1.8

Lead 1.0 .0054 .83

Magnesium 100 .81 27



Nickel 1.0 .24 .72

Potassium 100 4.5 75

Selenium 5.0 .21 .6

Silver 1.0 .0021 .22

Silicon 500 10 100

Sodium 100 4.5 24


Thallium 1.0 .017 .71

Tin 2.0 .12 .74

Titanium 1.0 .13 .85

Uranium 1.0 .0015 .76

Vanadium 1.0 .019 .43

Zinc 5.0 .65 .74

Associated samples MP17402: LA60782-9, LA60782-10, LA60782-11, LA60782-17, LA60782-18, LA60782-19

_________________________________________________________________________________________________________

Page 1

161 of 187

LA60782

99.1.1





Prep Date: 01/13/20

MB

01/13/20



_________________________________________________________________________________________________________

Page 2

162 of 187

LA60782

99.1.1





Prep Date: 01/13/20

LA60782-10 Spikelot

01/13/20


Aluminum

Antimony anr

Arsenic 4.5 85.1 100 80.6 75-125

Barium anr

Beryllium anr

Boron

Cadmium anr

Calcium

Cerium

Chromium anr

Cobalt anr

Copper anr

Iron

Lanthanum

Lithium

Lead anr

Magnesium

Manganese

Molybdenum

Nickel anr

Potassium

Selenium anr

Silver anr

Silicon

Sodium

Strontium

Thallium anr

Tin anr

Titanium

Uranium

Vanadium anr

Zinc anr


_________________________________________________________________________________________________________

Page 1

163 of 187

LA60782

99.1.2





Prep Date: 01/13/20

LA60782-10 Spikelot

01/13/20



_________________________________________________________________________________________________________

Page 2

164 of 187

LA60782

99.1.2





Prep Date: 01/13/20

LA60782-10 Spikelot

01/13/20


Aluminum

Antimony anr

Arsenic 4.5 85.0 100 80.5 0.1 20

Barium anr

Beryllium anr

Boron

Cadmium anr

Calcium

Cerium

Chromium anr

Cobalt anr

Copper anr

Iron

Lanthanum

Lithium

Lead anr

Magnesium

Manganese

Molybdenum

Nickel anr

Potassium

Selenium anr

Silver anr

Silicon

Sodium

Strontium

Thallium anr

Tin anr

Titanium

Uranium

Vanadium anr

Zinc anr


_________________________________________________________________________________________________________

Page 3

165 of 187

LA60782

99.1.2





Prep Date: 01/13/20

LA60782-10 Spikelot

01/13/20



_________________________________________________________________________________________________________

Page 4

166 of 187

LA60782

99.1.2





Prep Date: 01/13/20

BSP Spikelot

01/13/20


Aluminum

Antimony anr

Arsenic 100 100 100.0 80-120

Barium anr

Beryllium anr

Boron

Cadmium anr

Calcium

Cerium

Chromium anr

Cobalt anr

Copper anr

Iron

Lanthanum

Lithium

Lead anr

Magnesium

Manganese

Molybdenum

Nickel anr

Potassium

Selenium anr

Silver anr

Silicon

Sodium

Strontium

Thallium anr

Tin anr

Titanium

Uranium

Vanadium anr

Zinc anr


_________________________________________________________________________________________________________

Page 1

167 of 187

LA60782

99.1.3





Prep Date: 01/13/20

BSP Spikelot

01/13/20



_________________________________________________________________________________________________________

Page 2

168 of 187

LA60782

99.1.3





Prep Date: 01/13/20

LA60782-10

01/13/20


Aluminum

Antimony anr

Arsenic 4.53 5.55 22.4*(a) 0-10

Barium anr

Beryllium anr

Boron

Cadmium anr

Calcium

Cerium

Chromium anr

Cobalt anr

Copper anr

Iron

Lanthanum

Lithium

Lead anr

Magnesium

Manganese

Molybdenum

Nickel anr

Potassium

Selenium anr

Silver anr

Silicon

Sodium

Strontium

Thallium anr

Tin anr

Titanium

Uranium

Vanadium anr

Zinc anr


_________________________________________________________________________________________________________

Page 1

169 of 187

LA60782

99.1.4





Prep Date: 01/13/20

LA60782-10

01/13/20


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Serial dilution indicates possible matrix interference.

_________________________________________________________________________________________________________

Page 2

170 of 187

LA60782

99.1.4





Prep Date: 01/13/20


01/13/20


Aluminum

Boron

Calcium

Cerium

Iron

Lanthanum

Lithium

Magnesium

Manganese

Molybdenum

Potassium

Silicon

Sodium

Strontium

Titanium

Uranium

Zinc



_________________________________________________________________________________________________________

Page 1

171 of 187

LA60782

99.1.5





Prep Date: 01/14/20

MB

01/14/20


Aluminum 0.50 .088 .3

Antimony 0.50 .007 .024

Arsenic 0.50 .0089 .025 0.013 <0.50

Barium 5.0 .0008 .005 -0.00095 <5.0

Beryllium 0.50 .00025 .001

Boron 0.50 .0033 .039

Cadmium 0.50 .0007 .0025 -0.00030 <0.50

Calcium 0.50 .017 .12

Chromium 0.50 .0009 .0065 -0.00050 <0.50

Cobalt 0.50 .0011 .0035

Copper 0.50 .0032 .023

Iron 0.50 .043 .21

Lead 0.50 .0056 .021 -0.0046 <0.50

Lithium 0.50 .0064 .014

Magnesium 0.50 .064 .19

Manganese 0.50 .0004 .004

Molybdenum 0.50 .00055 .0035

Nickel 0.50 .0017 .035

Potassium 2.5 .17 .5

Selenium 0.50 .0069 .026 0.0045 <0.50

Silver 0.50 .0024 .022 -0.00095 <0.50

Sodium 2.5 .044 .47

Strontium 0.50 .00025 .002

Thallium 0.50 .0059 .0095

Tin 0.50 .0018 .005

Titanium 0.50 .001 .0045

Vanadium 0.50 .0016 .0045

Zinc 0.50 .0026 .058



_________________________________________________________________________________________________________

Page 1

172 of 187

LA60782

99.2.1





Prep Date: 01/14/20 01/14/20

LA60734-1 Spikelot

01/14/20

QC LA60734-1

01/14/20

QCMetal Original MS ICPSPIKE1% Rec Limits Original DUP RPD Limits

Aluminum

Antimony

Arsenic 0.012 10.3 10.0 102.9 75-125 0.012 0.018 40.0 (a) 0-20

Barium 0.48 10.4 10.0 99.2 75-125 0.48 0.49 2.1 0-20

Beryllium

Boron

Cadmium 0.089 10.2 10.0 101.1 75-125 0.089 0.088 1.1 0-20

Calcium

Chromium 0.0079 9.0 10. 89.9 75-125 0.0079 0.0071 10.7 0-20

Cobalt

Copper

Iron

Lead 0.0 9.1 10. 91.0 75-125 0.0 0.0 NC 0-20

Lithium

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium 0.013 10.7 10.0 106.9 75-125 0.013 0.012 8.0 0-20

Silver 0.0 9.8 10. 98.0 75-125 0.0 0.0 NC 0-20

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) RPD acceptable due to low duplicate and sample concentrations.

_________________________________________________________________________________________________________

Page 1

173 of 187

LA60782

99.2.2





Prep Date: 01/14/20

BSP Spikelot

01/14/20

QCMetal Result ICPSPIKE1% Rec Limits

Aluminum

Antimony

Arsenic 10.4 10.0 104.0 80-120

Barium 9.7 10. 97.0 80-120

Beryllium

Boron

Cadmium 10.1 10.0 101.0 80-120

Calcium

Chromium 9.4 10. 94.0 80-120

Cobalt

Copper

Iron

Lead 9.2 10. 92.0 80-120

Lithium

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium 10.8 10.0 108.0 80-120

Silver 10.0 10.0 100.0 80-120

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

174 of 187

LA60782

99.2.3




QC Batch ID: MP17409 Methods: SW846 6010C Matrix Type: LEACHATE Units: ug/l

Prep Date: 01/14/20

LA60734-1

01/14/20


Aluminum

Antimony

Arsenic 2.42 0.00 100.0(a) 0-10

Barium 95.7 99.7 4.1 0-10

Beryllium

Boron

Cadmium 17.9 17.6 1.2 0-10

Calcium

Chromium 1.57 1.42 9.6 0-10

Cobalt

Copper

Iron

Lead 0.00 0.00 NC 0-10

Lithium

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium 2.50 0.00 100.0(a) 0-10

Silver 0.00 0.00 NC 0-10

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium

Zinc



_________________________________________________________________________________________________________

Page 1

175 of 187

LA60782

99.2.4





Prep Date: 01/15/20

MB

01/15/20


Mercury 0.020 .00059 .0018 -0.00094 <0.020



_________________________________________________________________________________________________________

Page 1

176 of 187

LA60782

99.3.1





Prep Date: 01/15/20

LA60794-1 Spikelot

01/15/20


Mercury 0.0 0.14 0.15 93.3 75-125



_________________________________________________________________________________________________________

Page 1

177 of 187

LA60782

99.3.2





Prep Date: 01/15/20

LA60794-1 Spikelot

01/15/20


Mercury 0.0 0.14 0.15 93.3 0.0 20



_________________________________________________________________________________________________________

Page 2

178 of 187

LA60782

99.3.2





Prep Date: 01/15/20

BSP Spikelot

01/15/20


Mercury 0.14 0.15 93.3 80-120



_________________________________________________________________________________________________________

Page 1

179 of 187

LA60782

99.3.3





Prep Date: 01/15/20

LA60794-1

01/15/20


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

Page 1

180 of 187

LA60782

99.3.4


Misc. Forms


(SGS Houston, TX)



Scott, LASection 10

181 of 187

LA60782

10


SGS Houston, TX

182 of 187

LA60782

1010.1

Page 1 of 2

Job Number: LA60782 Client: SGS-LAF


Project: BOTTLE ART LOFTS. UNIVERSITY & CAMER

# of Coolers: 1

Airbill #'s:




















Intact








Misc. Information


Y or N N/A




11. COC Present:

N/A

Test Strip Lot #s: pH 1-12: 10D0391 pH 12+: Other: (Specify) N/A

Comments


183 of 187

LA60782

1010.1

Sample Receipt Log

Job #: LA60782 Date / Time Received: 1/13/2020 11:25:00 PM Initials: MAURICIM

Client: SGS-LAF


CFCorrected

TempInitialTemp

Page 2 of 2

1000ml M1A N/P Note #2 - Preservative check not applicable. IR-3 0 1.61 LA60782-20 1.61



184 of 187

LA60782

1010.1


General Chemistry

QC Data Summaries

(SGS Houston, TX)



Scott, LASection 11

185 of 187

LA60782

11





Cyanide Reactivity GP56379/GN3851 0.40 0.055 mg/l 10 1.3 12.8 8-23%Cyanide Reactivity GP56380/GN3851 0.40 0.055 mg/kg 10 1.3 12.8 2-33%Sulfide Reactivity GP56381/GN3799 20 0.0 mg/l 1600 400 25.0 .5-48%Sulfide Reactivity GP56382/GN3797 20 0.0 mg/kg 1600 400 25.0 13-28%

Associated Samples: Batch GP56379: LA60782-20ABatch GP56380: LA60782-21ABatch GP56381: LA60782-20ABatch GP56382: LA60782-21A(*) Outside of QC limits

__________________________________________________________________________________________________________________________

Page 1

186 of 187

LA60782

1111.1





Corrosivity as pH GN3812 TD49887-1 su 8.2 8.2 0.0 0-%Corrosivity as pH GN3856 TD49735-1 su 9.8 9.8 0.0 0-%Cyanide Reactivity GP56379/GN3851 TD49887-1 mg/l 0.065 0.0 0.0 0-20%Cyanide Reactivity GP56380/GN3851 LA60794-1A mg/kg 0.0 0.090 0.0 0-10%Ignitability (Flashpoint) GN3814 LA60859-1A Deg. F >200 >200 0.0 0-10%Ignitability (Flashpoint) GN3815 LA60782-21A Deg. F >200 >200 0.0 0-10%Sulfide Reactivity GP56381/GN3799 TD49887-1 mg/l 0.0 0.0 0.0 0-20%Sulfide Reactivity GP56382/GN3797 LA60794-1A mg/kg 0.0 0.0 0.0 0-10%

Associated Samples: Batch GN3812: LA60782-20ABatch GN3814: LA60782-20ABatch GN3815: LA60782-21ABatch GN3856: LA60782-21ABatch GP56379: LA60782-20ABatch GP56380: LA60782-21ABatch GP56381: LA60782-20ABatch GP56382: LA60782-21A(*) Outside of QC limits

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Sampling Dates: 10/07/19 - 10/08/19

Report to:


ATTN: Ashlyn Holmes










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Providence Engineering and EnvironmentalATTN: Ashlyn Holmes1201 Main StreetBaton Rouge, LA 70802


Dear Ms. Holmes,


The reporting limits for the Volatile Organic Compounds by EPA method 8260B results for sample B-5SS (28-30’) were lowered to attempt to meet RECAP screening standards. The reporting limit adjustments are supported by the instrument calibration and method detection limits (MDLs). The adjusted reporting limits are included in this revised laboratory report.

Sincerely,


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Sections:


3.1: LA58344-1: B-2SS (0-2') ............................................................................................. 153.2: LA58344-1A: B-2SS (0-2') ........................................................................................... 223.3: LA58344-2: B-2SS (28-30) .......................................................................................... 233.4: LA58344-2A: B-2SS (28-30) ....................................................................................... 303.5: LA58344-3: B-2SS (26-28') ......................................................................................... 313.6: LA58344-4: B-3SS (0-2') ............................................................................................. 383.7: LA58344-5: B-3SS (28-30') ......................................................................................... 453.8: LA58344-6: B-5SS (0-2') ............................................................................................. 523.9: LA58344-7: B-5SS (28-30') ......................................................................................... 593.10: LA58344-7A: B-5SS (28-30') ..................................................................................... 663.11: LA58344-8: BD-03 ..................................................................................................... 673.12: LA58344-9: RB-01 ..................................................................................................... 743.13: LA58344-10: RB-02 ................................................................................................... 823.14: LA58344-11: FB-05 .................................................................................................... 903.15: LA58344-12: FB-06 ................................................................................................... 983.16: LA58344-13: RB-03 ................................................................................................... 1063.17: LA58344-14: A-3GW ................................................................................................. 1143.18: LA58344-15: A-2GW ................................................................................................. 1213.19: LA58344-16: B-1GW ................................................................................................. 1283.20: LA58344-16F: B-1GW ............................................................................................... 1373.21: LA58344-17: BD-01 ................................................................................................... 1383.22: LA58344-18: TRIP BLANK ...................................................................................... 145


Section 5: MS Volatiles - QC Data Summaries ..................................................................... 1515.1: Method Blank Summary ................................................................................................ 1525.2: Leachate Blank Summary .............................................................................................. 1605.3: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1615.4: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 170

Section 6: MS Semi-volatiles - QC Data Summaries ............................................................ 1796.1: Method Blank Summary ................................................................................................ 1806.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 1846.3: Matrix Spike Summary .................................................................................................. 1886.4: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 190


Section 8: GC/LC Semi-volatiles - QC Data Summaries ..................................................... 221

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8.1: Method Blank Summary ................................................................................................ 2228.2: Blank Spike/Blank Spike Duplicate Summary .............................................................. 2268.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 232

Section 9: Metals Analysis - QC Data Summaries ................................................................ 2369.1: Prep QC MP16573: Hg .................................................................................................. 2379.2: Prep QC MP16578: Hg .................................................................................................. 2429.3: Prep QC MP16584: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 2479.4: Prep QC MP16586: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 2589.5: Prep QC MP16665: Sb,As,Ba,Be,Cd,Cr,Co,Cu,Pb,Ni,Se,Ag,Tl,V,Zn .......................... 2709.6: Prep QC MP16668: Hg .................................................................................................. 2829.7: Prep QC MP16691: Ba,Tl .............................................................................................. 287

Section 10: General Chemistry - QC Data Summaries ........................................................ 29310.1: Method Blank and Spike Results Summary ................................................................ 29410.2: Matrix Spike Results Summary ................................................................................... 29510.3: Matrix Spike Duplicate Results Summary .................................................................. 296



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Sample Summary





LA58344-1 10/07/19 09:20 SO 10/08/19 SO Soil B-2SS (0-2' )

LA58344-1A 10/07/19 09:20 SO 10/08/19 SO Soil B-2SS (0-2' )

LA58344-2 10/07/19 10:25 SO 10/08/19 SO Soil B-2SS (28-30)

LA58344-2A 10/07/19 10:25 SO 10/08/19 SO Soil B-2SS (28-30)

LA58344-3 10/07/19 10:45 SO 10/08/19 SO Soil B-2SS (26-28' )

LA58344-4 10/07/19 11:15 SO 10/08/19 SO Soil B-3SS (0-2' )

LA58344-4D 10/07/19 11:15 SO 10/08/19 SO Soil Dup/MSD B-3SS (0-2' )

LA58344-4S 10/07/19 11:15 SO 10/08/19 SO Soil Matrix Spike B-3SS (0-2' )

LA58344-5 10/07/19 12:10 SO 10/08/19 SO Soil B-3SS (28-30' )

LA58344-6 10/07/19 13:40 SO 10/08/19 SO Soil B-5SS (0-2' )

LA58344-7 10/07/19 14:40 SO 10/08/19 SO Soil B-5SS (28-30' )


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LA58344-7A 10/07/19 14:40 SO 10/08/19 SO Soil B-5SS (28-30' )

LA58344-8 10/07/19 09:20 SO 10/08/19 SO Soil BD-03

LA58344-9 10/07/19 11:35 SO 10/08/19 AQ Water RB-01

LA58344-10 10/07/19 15:25 SO 10/08/19 AQ Water RB-02



LA58344-13 10/08/19 10:25 SO 10/08/19 AQ Water RB-03

LA58344-14 10/08/19 11:00 SO 10/08/19 AQ Ground Water A-3GW

LA58344-14D 10/08/19 11:00 SO 10/08/19 AQ Water Dup/MSD A-3GW

LA58344-14F 10/08/19 11:00 SO 10/08/19 AQ Groundwater Filtered A-3GW

LA58344-14S 10/08/19 11:00 SO 10/08/19 AQ Water Matrix Spike A-3GW

LA58344-15 10/08/19 13:30 SO 10/08/19 AQ Ground Water A-2GW

LA58344-15F 10/08/19 13:30 SO 10/08/19 AQ Groundwater Filtered A-2GW


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LA58344-17 10/08/19 13:30 SO 10/08/19 AQ Ground Water BD-01



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LA58344-1 B-2SS (0-2')

Benzene 0.00066 0.00050 mg/kg SW846 8260BAntimony 0.62 0.50 mg/kg SW846 6020AArsenic 9.9 0.50 mg/kg SW846 6020ABarium 1920 0.50 mg/kg SW846 6020ABeryllium 0.52 0.50 mg/kg SW846 6020ACadmium 0.31 0.25 mg/kg SW846 6020AChromium 17.0 0.50 mg/kg SW846 6020ACobalt 37.0 0.50 mg/kg SW846 6020ACopper 19.0 0.50 mg/kg SW846 6020ALead 33.9 0.50 mg/kg SW846 6020ANickel 10.2 0.50 mg/kg SW846 6020ASelenium 3.1 2.5 mg/kg SW846 6020AThallium 0.64 0.50 mg/kg SW846 6020AVanadium 47.8 0.50 mg/kg SW846 6020AZinc 53.3 2.5 mg/kg SW846 6020A

LA58344-1A B-2SS (0-2')

Barium 0.91 0.0010 mg/l SW846 6020A

LA58344-2 B-2SS (28-30)

Benzene 0.0631 0.00050 mg/kg SW846 8260B1,2-Dichloroethane 0.0092 0.0010 mg/kg SW846 8260BEthylbenzene 0.161 0.0010 mg/kg SW846 8260BMethyl Ethyl Ketone 0.0615 0.013 mg/kg SW846 8260BToluene 0.133 0.0050 mg/kg SW846 8260Bm,p-Xylene 0.355 0.10 mg/kg SW846 8260Bo-Xylene 0.153 0.050 mg/kg SW846 8260BXylene (total) 0.507 0.10 mg/kg SW846 8260BArsenic 1.3 0.45 mg/kg SW846 6020ABarium 31.2 0.45 mg/kg SW846 6020AChromium 8.8 0.45 mg/kg SW846 6020ACobalt 1.8 0.45 mg/kg SW846 6020ACopper 5.6 0.45 mg/kg SW846 6020ALead 4.9 0.45 mg/kg SW846 6020ANickel 3.9 0.45 mg/kg SW846 6020AVanadium 10.0 0.45 mg/kg SW846 6020AZinc 12.9 2.3 mg/kg SW846 6020A

LA58344-2A B-2SS (28-30)


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LA58344-3 B-2SS (26-28')

Acetone 0.0812 0.049 mg/kg SW846 8260BBenzene 0.0013 0.00049 mg/kg SW846 8260BEthylbenzene 0.0057 0.00098 mg/kg SW846 8260BMethyl Ethyl Ketone 0.0140 0.012 mg/kg SW846 8260Bm,p-Xylene 0.0254 0.0020 mg/kg SW846 8260Bo-Xylene 0.0108 0.00098 mg/kg SW846 8260BXylene (total) 0.0362 0.0020 mg/kg SW846 8260BArsenic 0.98 0.50 mg/kg SW846 6020ABarium 25.1 0.50 mg/kg SW846 6020AChromium 9.0 0.50 mg/kg SW846 6020ACobalt 1.6 0.50 mg/kg SW846 6020ACopper 5.8 0.50 mg/kg SW846 6020ALead 4.1 0.50 mg/kg SW846 6020ANickel 3.3 0.50 mg/kg SW846 6020AVanadium 8.3 0.50 mg/kg SW846 6020AZinc 10.5 2.5 mg/kg SW846 6020A

LA58344-4 B-3SS (0-2')

Acetone 0.308 0.050 mg/kg SW846 8260BBenzene 0.00062 0.00050 mg/kg SW846 8260BMethyl Ethyl Ketone 0.0220 0.013 mg/kg SW846 8260BArsenic 6.2 0.50 mg/kg SW846 6020ABarium 134 0.50 mg/kg SW846 6020AChromium 15.7 0.50 mg/kg SW846 6020ACobalt 2.3 0.50 mg/kg SW846 6020ACopper 13.3 0.50 mg/kg SW846 6020ALead 5.9 0.50 mg/kg SW846 6020ANickel 13.5 0.50 mg/kg SW846 6020ASelenium 2.6 2.5 mg/kg SW846 6020AVanadium 23.5 0.50 mg/kg SW846 6020AZinc 38.8 2.5 mg/kg SW846 6020A

LA58344-5 B-3SS (28-30')

Benzene 0.00068 0.00049 mg/kg SW846 8260B1,2-Dichloroethane 0.0037 0.00098 mg/kg SW846 8260BEthylbenzene 0.0400 0.00098 mg/kg SW846 8260Bm,p-Xylene 0.0984 0.0020 mg/kg SW846 8260Bo-Xylene 0.0169 0.00098 mg/kg SW846 8260BXylene (total) 0.115 0.0020 mg/kg SW846 8260BArsenic 0.85 0.50 mg/kg SW846 6020A

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Barium 56.9 0.50 mg/kg SW846 6020AChromium 13.0 0.50 mg/kg SW846 6020ACobalt 2.3 0.50 mg/kg SW846 6020ACopper 5.8 0.50 mg/kg SW846 6020ALead 8.5 0.50 mg/kg SW846 6020ANickel 6.6 0.50 mg/kg SW846 6020AVanadium 13.9 0.50 mg/kg SW846 6020AZinc 25.5 2.5 mg/kg SW846 6020A

LA58344-6 B-5SS (0-2')

Benzene 0.0027 0.00052 mg/kg SW846 8260B1,2-Dichloroethane 0.0015 0.0010 mg/kg SW846 8260BEthylbenzene 0.0024 0.0010 mg/kg SW846 8260Bm,p-Xylene 0.0072 0.0021 mg/kg SW846 8260BXylene (total) 0.0072 0.0021 mg/kg SW846 8260BArsenic 1.9 0.48 mg/kg SW846 6020ABarium 132 0.48 mg/kg SW846 6020AChromium 7.0 0.48 mg/kg SW846 6020ACobalt 2.4 0.48 mg/kg SW846 6020ACopper 5.5 0.48 mg/kg SW846 6020ALead 6.9 0.48 mg/kg SW846 6020ANickel 2.1 0.48 mg/kg SW846 6020AVanadium 11.9 0.48 mg/kg SW846 6020AZinc 15.2 2.4 mg/kg SW846 6020A

LA58344-7 B-5SS (28-30')

Benzene 0.852 0.025 mg/kg SW846 8260BEthylbenzene 31.0 0.49 mg/kg SW846 8260BToluene 26.4 2.5 mg/kg SW846 8260Bm,p-Xylene 117 0.98 mg/kg SW846 8260Bo-Xylene 51.3 0.49 mg/kg SW846 8260BXylene (total) 168 0.98 mg/kg SW846 8260BNaphthalene 0.0099 0.0099 mg/kg SW846 8270DTPH-GRO (C6-C10) 267 4.9 mg/kg SW846 8015CArsenic 0.93 0.45 mg/kg SW846 6020ABarium 38.7 0.45 mg/kg SW846 6020AChromium 10.8 0.45 mg/kg SW846 6020ACobalt 2.6 0.45 mg/kg SW846 6020ACopper 5.3 0.45 mg/kg SW846 6020ALead 8.6 0.45 mg/kg SW846 6020ANickel 4.6 0.45 mg/kg SW846 6020AVanadium 12.0 0.45 mg/kg SW846 6020AZinc 19.0 2.3 mg/kg SW846 6020A

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LA58344-7A B-5SS (28-30')

Toluene 0.0028 0.0010 mg/l SW846 8260BEthylbenzene 0.0043 0.0010 mg/l SW846 8260BXylene (total) 0.0273 0.0020 mg/l SW846 8260B

LA58344-8 BD-03

Benzene 0.00056 0.00050 mg/kg SW846 8260BArsenic 2.4 0.50 mg/kg SW846 6020ABarium 231 0.50 mg/kg SW846 6020AChromium 10.7 0.50 mg/kg SW846 6020ACobalt 3.0 0.50 mg/kg SW846 6020ACopper 8.6 0.50 mg/kg SW846 6020ALead 9.2 0.50 mg/kg SW846 6020ANickel 2.5 0.50 mg/kg SW846 6020AVanadium 16.3 0.50 mg/kg SW846 6020AZinc 20.1 2.5 mg/kg SW846 6020A

LA58344-9 RB-01

Diethyl Phthalate 0.0781 0.047 mg/l SW846 8270DTPH-DRO (C10-C28) a 0.190 0.14 mg/l SW846 8015CCopper 0.0025 0.0010 mg/l SW846 6020A

LA58344-10 RB-02

Diethyl Phthalate b 0.179 0.10 mg/l SW846 8270DTPH-DRO (C10-C28) a 0.368 0.14 mg/l SW846 8015CCopper 0.0118 0.0010 mg/l SW846 6020A

LA58344-11 FB-05

TPH-DRO (C10-C28) a 0.397 0.14 mg/l SW846 8015CCopper 0.0219 0.0010 mg/l SW846 6020A

LA58344-12 FB-06

Copper 0.0089 0.0010 mg/l SW846 6020A

LA58344-13 RB-03

Nitrogen, Nitrate 0.057 0.050 mg/l SW846 9056A

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LA58344-14 A-3GW


LA58344-15 A-2GW


LA58344-16 B-1GW

Acetone 0.431 0.050 mg/l SW846 8260BXylene (total) 0.0021 0.0020 mg/l SW846 8260B2,4-Dimethylphenol 0.0082 0.0044 mg/l SW846 8270DAcenaphthene 0.00027 0.00018 mg/l SW846 8270DFluorene 0.00027 0.00018 mg/l SW846 8270DAliphatics C6-C8 (Unadj.) 5.41 0.75 mg/l MADEP VPH REV 1.1Aliphatics > C8-C10 (Unadj.) 2.77 0.15 mg/l MADEP VPH REV 1.1Aromatics > C8-C10 (Unadj.) 1.97 0.15 mg/l MADEP VPH REV 1.1TPH-GRO (C6-C10) 11.3 0.50 mg/l SW846 8015CAliphatics > C10-C12 (Unadj.) 1.56 0.14 mg/l MADEP EPH REV 1.1Aliphatics > C12-C16 (Unadj.) 0.197 0.14 mg/l MADEP EPH REV 1.1Aromatics > C12-C16 (Unadj.) 0.245 0.14 mg/l MADEP EPH REV 1.1TPH-DRO (C10-C28) 1.93 0.14 mg/l SW846 8015CArsenic 0.0982 0.0010 mg/l SW846 6020ABarium 0.501 0.0010 mg/l SW846 6020ACadmium 0.0014 0.00050 mg/l SW846 6020AChromium 0.0104 0.0010 mg/l SW846 6020ACobalt 0.0071 0.0010 mg/l SW846 6020ACopper 0.0133 0.0010 mg/l SW846 6020A

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Lead 0.0126 0.0010 mg/l SW846 6020ANickel 0.0107 0.0010 mg/l SW846 6020AVanadium 0.0167 0.0010 mg/l SW846 6020AZinc 0.0283 0.0050 mg/l SW846 6020A

LA58344-16F B-1GW


LA58344-17 BD-01




(a) Confirmed by reextraction and reanalysis.(b) RL manually adusted to report result at dilution. The calibration and MDL supports this adjustment.

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Sample Results

Report of Analysis

Scott, LASection 3

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VOA RECAP List




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VOA RECAP List








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ABN RECAP LIST




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ABN RECAP LIST







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84-15-1 o-Terphenyl 66% 31-127%



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Metals Analysis


Antimony 0.62 0.50 mg/kg 5 10/10/19 10/11/19 RT SW846 6020A 1 SW846 3050B 6









Mercury ND 0.074 mg/kg 1 10/10/19 10/10/19 BB SW846 7471B 2 SW846 7471B 5




Thallium 0.64 0.50 mg/kg 5 10/10/19 10/11/19 RT SW846 6020A 1 SW846 3050B 6



(1) Instrument QC Batch: MA17210(2) Instrument QC Batch: MA17213(3) Instrument QC Batch: MA17219(4) Instrument QC Batch: MA17227(5) Prep QC Batch: MP16578(6) Prep QC Batch: MP16586



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Client Sample ID: B-2SS (0-2' ) Lab Sample ID: LA58344-1A Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19


Metals Analysis, SPLP Leachate SW846 1312

Analyte Result MCL RL Units DF Prep Analyzed By Method Prep Method




RL = Reporting Limit ND = Not detectedMCL = Maximum Contamination Level (not available)

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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2 Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8260B SW846 5035 Percent Solids: n/a a


File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2H0058938.D 1 10/14/19 14:26 CP 10/10/19 12:25 n/a V2H2350Run #2 2X0085293.D 1 10/15/19 16:07 CP 10/10/19 12:25 n/a V2X3839

Initial Weight Final Volume Methanol AliquotRun #1 5.0 gRun #2 5.0 g 5.0 ml 100 ul

VOA RECAP List




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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2 Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8260B SW846 5035 Percent Solids: n/a a


VOA RECAP List


1634-04-4 Methyl Tert Butyl Ether ND 0.0010 mg/kg100-42-5 Styrene ND 0.0010 mg/kg630-20-6 1,1,1,2-Tetrachloroethane ND 0.0010 mg/kg79-34-5 1,1,2,2-Tetrachloroethane ND 0.0010 mg/kg127-18-4 Tetrachloroethylene ND 0.0010 mg/kg108-88-3 Toluene 0.133 0.0050 mg/kg71-55-6 1,1,1-Trichloroethane ND 0.0010 mg/kg79-00-5 1,1,2-Trichloroethane ND 0.0010 mg/kg79-01-6 Trichloroethylene ND 0.0010 mg/kg75-69-4 Trichlorofluoromethane ND 0.0010 mg/kg75-01-4 Vinyl Chloride ND 0.0010 mg/kg

m,p-Xylene 0.355 b 0.10 mg/kg95-47-6 o-Xylene 0.153 b 0.050 mg/kg1330-20-7 Xylene (total) 0.507 b 0.10 mg/kg





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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2 Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8270D SW846 3546 Percent Solids: n/a a




ABN RECAP LIST




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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2 Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8270D SW846 3546 Percent Solids: n/a a


ABN RECAP LIST







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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2 Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8015C SW846 5035 Percent Solids: n/a a










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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2 Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8015C SW846 3546 Percent Solids: n/a a







84-15-1 o-Terphenyl 59% 31-127%



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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2 Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19



Metals Analysis





















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Client Sample ID: B-2SS (28-30) Lab Sample ID: LA58344-2A Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8260B SW846 1312 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 1G112368.D 1 10/23/19 19:26 CP 10/21/19 03:00 OP15437 V1G5856Run #2








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VOA RECAP List


67-64-1 Acetone 0.0812 0.049 mg/kg71-43-2 Benzene 0.0013 0.00049 mg/kg75-27-4 Bromodichloromethane ND 0.00098 mg/kg75-25-2 Bromoform ND 0.00098 mg/kg75-15-0 Carbon Disulfide ND 0.00098 mg/kg56-23-5 Carbon Tetrachloride ND 0.00098 mg/kg108-90-7 Chlorobenzene ND 0.00098 mg/kg75-00-3 Chloroethane ND 0.00098 mg/kg67-66-3 Chloroform ND 0.00098 mg/kg124-48-1 Dibromochloromethane ND 0.00098 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0049 mg/kg541-73-1 m-Dichlorobenzene ND 0.00098 mg/kg95-50-1 o-Dichlorobenzene ND 0.00098 mg/kg106-46-7 p-Dichlorobenzene ND 0.00098 mg/kg75-34-3 1,1-Dichloroethane ND 0.00098 mg/kg107-06-2 1,2-Dichloroethane ND 0.00098 mg/kg75-35-4 1,1-Dichloroethylene ND 0.00098 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.00098 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.00098 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.00098 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.00098 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.00098 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.00098 mg/kg100-41-4 Ethylbenzene 0.0057 0.00098 mg/kg67-72-1 Hexachloroethane ND 0.0049 mg/kg78-83-1 Isobutyl alcohol ND 0.098 mg/kg74-83-9 Methyl Bromide ND 0.0098 mg/kg74-87-3 Methyl Chloride ND 0.0049 mg/kg75-09-2 Methylene Chloride ND 0.0049 mg/kg78-93-3 Methyl Ethyl Ketone 0.0140 0.012 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.012 mg/kg


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VOA RECAP List








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ABN RECAP LIST




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ABN RECAP LIST







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84-15-1 o-Terphenyl 42% 31-127%



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Metals Analysis





















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VOA RECAP List


67-64-1 Acetone 0.308 0.050 mg/kg71-43-2 Benzene 0.00062 0.00050 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0050 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane ND 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene ND 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0050 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0050 mg/kg75-09-2 Methylene Chloride ND 0.0050 mg/kg78-93-3 Methyl Ethyl Ketone 0.0220 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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84-15-1 o-Terphenyl 68% 31-127%



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67-64-1 Acetone ND 0.049 mg/kg71-43-2 Benzene 0.00068 0.00049 mg/kg75-27-4 Bromodichloromethane ND 0.00098 mg/kg75-25-2 Bromoform ND 0.00098 mg/kg75-15-0 Carbon Disulfide ND 0.00098 mg/kg56-23-5 Carbon Tetrachloride ND 0.00098 mg/kg108-90-7 Chlorobenzene ND 0.00098 mg/kg75-00-3 Chloroethane ND 0.00098 mg/kg67-66-3 Chloroform ND 0.00098 mg/kg124-48-1 Dibromochloromethane ND 0.00098 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0049 mg/kg541-73-1 m-Dichlorobenzene ND 0.00098 mg/kg95-50-1 o-Dichlorobenzene ND 0.00098 mg/kg106-46-7 p-Dichlorobenzene ND 0.00098 mg/kg75-34-3 1,1-Dichloroethane ND 0.00098 mg/kg107-06-2 1,2-Dichloroethane 0.0037 0.00098 mg/kg75-35-4 1,1-Dichloroethylene ND 0.00098 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.00098 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.00098 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0020 mg/kg78-87-5 1,2-Dichloropropane ND 0.00098 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.00098 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.00098 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.00098 mg/kg100-41-4 Ethylbenzene 0.0400 0.00098 mg/kg67-72-1 Hexachloroethane ND 0.0049 mg/kg78-83-1 Isobutyl alcohol ND 0.098 mg/kg74-83-9 Methyl Bromide ND 0.0098 mg/kg74-87-3 Methyl Chloride ND 0.0049 mg/kg75-09-2 Methylene Chloride ND 0.0049 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.012 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.012 mg/kg


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84-15-1 o-Terphenyl 76% 31-127%



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67-64-1 Acetone ND 0.052 mg/kg71-43-2 Benzene 0.0027 0.00052 mg/kg75-27-4 Bromodichloromethane ND 0.0010 mg/kg75-25-2 Bromoform ND 0.0010 mg/kg75-15-0 Carbon Disulfide ND 0.0010 mg/kg56-23-5 Carbon Tetrachloride ND 0.0010 mg/kg108-90-7 Chlorobenzene ND 0.0010 mg/kg75-00-3 Chloroethane ND 0.0010 mg/kg67-66-3 Chloroform ND 0.0010 mg/kg124-48-1 Dibromochloromethane ND 0.0010 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.0052 mg/kg541-73-1 m-Dichlorobenzene ND 0.0010 mg/kg95-50-1 o-Dichlorobenzene ND 0.0010 mg/kg106-46-7 p-Dichlorobenzene ND 0.0010 mg/kg75-34-3 1,1-Dichloroethane ND 0.0010 mg/kg107-06-2 1,2-Dichloroethane 0.0015 0.0010 mg/kg75-35-4 1,1-Dichloroethylene ND 0.0010 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.0010 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.0010 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.0021 mg/kg78-87-5 1,2-Dichloropropane ND 0.0010 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.0010 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.0010 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.0010 mg/kg100-41-4 Ethylbenzene 0.0024 0.0010 mg/kg67-72-1 Hexachloroethane ND 0.0052 mg/kg78-83-1 Isobutyl alcohol ND 0.10 mg/kg74-83-9 Methyl Bromide ND 0.010 mg/kg74-87-3 Methyl Chloride ND 0.0052 mg/kg75-09-2 Methylene Chloride ND 0.0052 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.013 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.013 mg/kg


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84-15-1 o-Terphenyl 73% 31-127%



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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2X0085177.D 1 10/11/19 19:19 CP 10/10/19 12:25 n/a V2X3833Run #2 1G111826.D 1 10/14/19 16:35 CP 10/10/19 12:25 n/a V1G5837


VOA RECAP List


67-64-1 Acetone ND 2.5 mg/kg71-43-2 Benzene 0.852 0.025 mg/kg75-27-4 Bromodichloromethane ND 0.050 mg/kg75-25-2 Bromoform ND 0.050 mg/kg75-15-0 Carbon Disulfide ND 0.050 mg/kg56-23-5 Carbon Tetrachloride ND 0.050 mg/kg108-90-7 Chlorobenzene ND 0.050 mg/kg75-00-3 Chloroethane ND 0.025 mg/kg67-66-3 Chloroform ND 0.050 mg/kg124-48-1 Dibromochloromethane ND 0.050 mg/kg96-12-8 1,2-Dibromo-3-chloropropane ND 0.25 mg/kg541-73-1 m-Dichlorobenzene ND 0.050 mg/kg95-50-1 o-Dichlorobenzene ND 0.050 mg/kg106-46-7 p-Dichlorobenzene ND 0.050 mg/kg75-34-3 1,1-Dichloroethane ND 0.050 mg/kg107-06-2 1,2-Dichloroethane ND 0.025 mg/kg75-35-4 1,1-Dichloroethylene ND 0.050 mg/kg156-59-2 cis-1,2-Dichloroethylene ND 0.050 mg/kg156-60-5 trans-1,2-Dichloroethylene ND 0.050 mg/kg540-59-0 1,2-Dichloroethene (total) ND 0.10 mg/kg78-87-5 1,2-Dichloropropane ND 0.025 mg/kg10061-01-5 cis-1,3-Dichloropropene ND 0.050 mg/kg10061-02-6 trans-1,3-Dichloropropene ND 0.050 mg/kg542-75-6 1,3-Dichloropropene (total) ND 0.033 mg/kg100-41-4 Ethylbenzene 31.0 b 0.49 mg/kg67-72-1 Hexachloroethane ND 0.25 mg/kg78-83-1 Isobutyl alcohol ND 5.0 mg/kg74-83-9 Methyl Bromide ND 0.50 mg/kg74-87-3 Methyl Chloride ND 0.10 mg/kg75-09-2 Methylene Chloride ND 0.25 mg/kg78-93-3 Methyl Ethyl Ketone ND 0.63 mg/kg108-10-1 4-Methyl-2-pentanone ND 0.63 mg/kg


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1634-04-4 Methyl Tert Butyl Ether ND 0.050 mg/kg100-42-5 Styrene ND 0.050 mg/kg630-20-6 1,1,1,2-Tetrachloroethane ND 0.025 mg/kg79-34-5 1,1,2,2-Tetrachloroethane ND 0.050 mg/kg127-18-4 Tetrachloroethylene ND 0.050 mg/kg108-88-3 Toluene 26.4 b 2.5 mg/kg71-55-6 1,1,1-Trichloroethane ND 0.050 mg/kg79-00-5 1,1,2-Trichloroethane ND 0.050 mg/kg79-01-6 Trichloroethylene ND 0.050 mg/kg75-69-4 Trichlorofluoromethane ND 0.050 mg/kg75-01-4 Vinyl Chloride ND 0.050 mg/kg

m,p-Xylene 117 b 0.98 mg/kg95-47-6 o-Xylene 51.3 b 0.49 mg/kg1330-20-7 Xylene (total) 168 b 0.98 mg/kg





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ABN RECAP LIST


121-14-2 2,4-Dinitrotoluene ND 0.17 mg/kg606-20-2 2,6-Dinitrotoluene ND 0.17 mg/kg117-81-7 bis(2-Ethylhexyl)phthalate ND 0.17 mg/kg206-44-0 Fluoranthene ND 0.0099 mg/kg86-73-7 Fluorene ND 0.0099 mg/kg118-74-1 Hexachlorobenzene ND 0.17 mg/kg87-68-3 Hexachlorobutadiene ND 0.17 mg/kg77-47-4 Hexachlorocyclopentadiene b ND 0.65 mg/kg193-39-5 Indeno(1,2,3-cd)pyrene ND 0.0099 mg/kg78-59-1 Isophorone ND 0.17 mg/kg91-57-6 2-Methylnaphthalene ND 0.0099 mg/kg91-20-3 Naphthalene 0.0099 0.0099 mg/kg88-74-4 2-Nitroaniline ND 0.65 mg/kg99-09-2 3-Nitroaniline ND 0.65 mg/kg100-01-6 4-Nitroaniline ND 0.65 mg/kg98-95-3 Nitrobenzene ND 0.17 mg/kg621-64-7 N-Nitroso-di-n-propylamine ND 0.17 mg/kg86-30-6 N-Nitrosodiphenylamine ND 0.17 mg/kg85-01-8 Phenanthrene ND 0.0099 mg/kg129-00-0 Pyrene ND 0.0099 mg/kg95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.17 mg/kg120-82-1 1,2,4-Trichlorobenzene ND 0.17 mg/kg





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TPH-GRO (C6-C10) 267 4.9 mg/kg





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84-15-1 o-Terphenyl 64% 31-127%



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Client Sample ID: B-5SS (28-30' ) Lab Sample ID: LA58344-7A Date Sampled: 10/07/19Matrix: SO - Soil Date Received: 10/08/19Method: SW846 8260B SW846 1312 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 1G112370.D 1 10/23/19 19:56 CP 10/21/19 03:00 OP15437 V1G5856Run #2


Purgeable Aromatics SPLP Leachate method SW846 1312


71-43-2 Benzene ND 0.0010 mg/l108-88-3 Toluene 0.0028 0.0010 mg/l100-41-4 Ethylbenzene 0.0043 0.0010 mg/l1330-20-7 Xylene (total) 0.0273 0.0020 mg/l




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84-15-1 o-Terphenyl 68% 31-127%



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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 L0029710.D 1 10/14/19 13:56 AA 10/13/19 02:00 OP15355 EL787Run #2 a L0029995.D 1 10/28/19 21:56 PC 10/26/19 11:40 OP15487 EL795Run #3 L0029755.D 10 10/23/19 21:26 PC 10/13/19 02:00 OP15355 EL789

Initial Volume Final VolumeRun #1 106 ml 1.0 mlRun #2 113 ml 1.0 mlRun #3 106 ml 1.0 ml

ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0047 mg/l120-83-2 2,4-Dichlorophenol ND 0.0047 mg/l105-67-9 2,4-Dimethylphenol ND 0.0047 mg/l51-28-5 2,4-Dinitrophenol ND 0.019 mg/l100-02-7 4-Nitrophenol b ND 0.024 mg/l87-86-5 Pentachlorophenol ND 0.00094 mg/l108-95-2 Phenol ND 0.0047 mg/l58-90-2 2,3,4,6-Tetrachlorophenol ND 0.0047 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0047 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0047 mg/l83-32-9 Acenaphthene ND 0.00019 mg/l208-96-8 Acenaphthylene ND 0.00019 mg/l62-53-3 Aniline ND 0.0047 mg/l120-12-7 Anthracene ND 0.00019 mg/l56-55-3 Benzo(a)anthracene ND 0.00019 mg/l50-32-8 Benzo(a)pyrene ND 0.00019 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00019 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00019 mg/l92-52-4 1,1' -Biphenyl ND 0.0094 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0047 mg/l106-47-8 4-Chloroaniline b ND 0.0047 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0047 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0047 mg/l91-58-7 2-Chloronaphthalene ND 0.0047 mg/l218-01-9 Chrysene ND 0.00019 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00019 mg/l132-64-9 Dibenzofuran ND 0.0047 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.0094 mg/l84-66-2 Diethyl Phthalate 0.0781 c 0.047 mg/l131-11-3 Dimethyl Phthalate ND 0.0047 mg/l


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ABN RECAP LIST


117-84-0 Di-n-octyl Phthalate ND 0.0047 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0047 mg/l121-14-2 2,4-Dinitrotoluene ND 0.0047 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0047 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0047 mg/l206-44-0 Fluoranthene ND 0.00019 mg/l86-73-7 Fluorene ND 0.00019 mg/l118-74-1 Hexachlorobenzene ND 0.00094 mg/l87-68-3 Hexachlorobutadiene ND 0.00047 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.0094 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00019 mg/l78-59-1 Isophorone ND 0.0047 mg/l91-57-6 2-Methylnaphthalene ND 0.00019 mg/l91-20-3 Naphthalene ND 0.00019 mg/l88-74-4 2-Nitroaniline ND 0.0047 mg/l99-09-2 3-Nitroaniline b ND 0.0047 mg/l100-01-6 4-Nitroaniline b ND 0.0047 mg/l98-95-3 Nitrobenzene ND 0.00094 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0047 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0047 mg/l85-01-8 Phenanthrene ND 0.00019 mg/l129-00-0 Pyrene ND 0.00019 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.00094 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0047 mg/l



(a) Confirmation run.(b) Associated CCV outside of control limits high, sample was ND.(c) Result is from Run# 3


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TPH-DRO (C10-C28) a 0.190 0.14 mg/lTPH-ORO (C28-C35) ND 0.14 mg/l


84-15-1 o-Terphenyl 99% 40-118%

(a) Confirmed by reextraction and reanalysis.


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File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 L0029756.D 1 10/23/19 21:52 PC 10/13/19 14:00 OP15355 EL789Run #2 a L0029996.D 1 10/28/19 22:22 PC 10/26/19 11:40 OP15487 EL795Run #3 L0030098.D 100 10/31/19 20:22 PC 10/13/19 14:00 OP15355 EL798

Initial Volume Final VolumeRun #1 107 ml 1.0 mlRun #2 110 ml 1.0 mlRun #3 107 ml 1.0 ml

ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0047 mg/l120-83-2 2,4-Dichlorophenol ND 0.0047 mg/l105-67-9 2,4-Dimethylphenol ND 0.0047 mg/l51-28-5 2,4-Dinitrophenol ND 0.019 mg/l100-02-7 4-Nitrophenol b ND 0.023 mg/l87-86-5 Pentachlorophenol ND 0.00093 mg/l108-95-2 Phenol ND 0.0047 mg/l58-90-2 2,3,4,6-Tetrachlorophenol b ND 0.0047 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0047 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0047 mg/l83-32-9 Acenaphthene ND 0.00019 mg/l208-96-8 Acenaphthylene ND 0.00019 mg/l62-53-3 Aniline ND 0.0047 mg/l120-12-7 Anthracene ND 0.00019 mg/l56-55-3 Benzo(a)anthracene ND 0.00019 mg/l50-32-8 Benzo(a)pyrene ND 0.00019 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00019 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00019 mg/l92-52-4 1,1' -Biphenyl ND 0.0093 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0047 mg/l106-47-8 4-Chloroaniline b ND 0.0047 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0047 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0047 mg/l91-58-7 2-Chloronaphthalene ND 0.0047 mg/l218-01-9 Chrysene ND 0.00019 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00019 mg/l132-64-9 Dibenzofuran ND 0.0047 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.0093 mg/l84-66-2 Diethyl Phthalate c 0.179 d 0.10 mg/l131-11-3 Dimethyl Phthalate ND 0.0047 mg/l


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ABN RECAP LIST


117-84-0 Di-n-octyl Phthalate ND 0.0047 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0047 mg/l121-14-2 2,4-Dinitrotoluene ND 0.0047 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0047 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0047 mg/l206-44-0 Fluoranthene ND 0.00019 mg/l86-73-7 Fluorene ND 0.00019 mg/l118-74-1 Hexachlorobenzene ND 0.00093 mg/l87-68-3 Hexachlorobutadiene ND 0.00047 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.0093 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00019 mg/l78-59-1 Isophorone ND 0.0047 mg/l91-57-6 2-Methylnaphthalene ND 0.00019 mg/l91-20-3 Naphthalene ND 0.00019 mg/l88-74-4 2-Nitroaniline ND 0.0047 mg/l99-09-2 3-Nitroaniline b ND 0.0047 mg/l100-01-6 4-Nitroaniline b ND 0.0047 mg/l98-95-3 Nitrobenzene ND 0.00093 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0047 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0047 mg/l85-01-8 Phenanthrene ND 0.00019 mg/l129-00-0 Pyrene ND 0.00019 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.00093 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0047 mg/l


367-12-4 2-Fluorophenol 71% 69% 0% e 25-101%4165-62-2 Phenol-d5 50% 50% 0% e 17-79%118-79-6 2,4,6-Tribromophenol 98% 100% 77% 40-144%4165-60-0 Nitrobenzene-d5 98% 99% 122% 40-124%321-60-8 2-Fluorobiphenyl 78% 82% 104% 27-124%1718-51-0 Terphenyl-d14 92% 96% 129% 45-140%

(a) Confirmation run.(b) Associated CCV outside of control limits high, sample was ND.(c) RL manually adusted to report result at dilution. The calibration and MDL supports this adjustment.(d) Result is from Run# 3(e) Outside control limits due to dilution.


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84-15-1 o-Terphenyl 103% 40-118%



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ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0044 mg/l120-83-2 2,4-Dichlorophenol ND 0.0044 mg/l105-67-9 2,4-Dimethylphenol ND 0.0044 mg/l51-28-5 2,4-Dinitrophenol ND 0.018 mg/l100-02-7 4-Nitrophenol b ND 0.022 mg/l87-86-5 Pentachlorophenol ND 0.00088 mg/l108-95-2 Phenol ND 0.0044 mg/l58-90-2 2,3,4,6-Tetrachlorophenol ND 0.0044 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0044 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0044 mg/l83-32-9 Acenaphthene ND 0.00018 mg/l208-96-8 Acenaphthylene ND 0.00018 mg/l62-53-3 Aniline ND 0.0044 mg/l120-12-7 Anthracene ND 0.00018 mg/l56-55-3 Benzo(a)anthracene ND 0.00018 mg/l50-32-8 Benzo(a)pyrene ND 0.00018 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00018 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00018 mg/l92-52-4 1,1' -Biphenyl ND 0.0088 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0044 mg/l106-47-8 4-Chloroaniline b ND 0.0044 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0044 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0044 mg/l91-58-7 2-Chloronaphthalene ND 0.0044 mg/l218-01-9 Chrysene ND 0.00018 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00018 mg/l132-64-9 Dibenzofuran ND 0.0044 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.0088 mg/l84-66-2 Diethyl Phthalate ND 0.0044 mg/l131-11-3 Dimethyl Phthalate ND 0.0044 mg/l117-84-0 Di-n-octyl Phthalate ND 0.0044 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0044 mg/l


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ABN RECAP LIST







93 of 304

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33.14











94 of 304

LA58344

33.14









84-15-1 o-Terphenyl 98% 40-118%



95 of 304

LA58344

33.14

























96 of 304

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33.14





General Chemistry





97 of 304

LA58344

33.14






VOA RECAP List




98 of 304

LA58344

33.15




VOA RECAP List







99 of 304

LA58344

33.15






ABN RECAP LIST




100 of 304

LA58344

33.15




ABN RECAP LIST







101 of 304

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33.15











102 of 304

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TPH-DRO (C10-C28) ND 0.14 mg/lTPH-ORO (C28-C35) ND 0.14 mg/l


84-15-1 o-Terphenyl 102% 40-118%


103 of 304

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33.15

























104 of 304

LA58344

33.15





General Chemistry





105 of 304

LA58344

33.15






VOA RECAP List




106 of 304

LA58344

33.16




VOA RECAP List







107 of 304

LA58344

33.16






ABN RECAP LIST




108 of 304

LA58344

33.16




ABN RECAP LIST







109 of 304

LA58344

33.16











110 of 304

LA58344

33.16









84-15-1 o-Terphenyl 100% 40-118%


111 of 304

LA58344

33.16

























112 of 304

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33.16





General Chemistry


Nitrogen, Ammonia a ND 0.10 mg/l 1 10/17/19 ATX EPA 350.1Nitrogen, Nitrate 0.057 0.050 mg/l 1 10/08/19 16:56 HD SW846 9056ANitrogen, Nitrite ND 0.050 mg/l 1 10/08/19 16:56 HD SW846 9056A



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Client Sample ID: A-3GWLab Sample ID: LA58344-14 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



VOA RECAP List




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33.17




VOA RECAP List







115 of 304

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33.17



Client Sample ID: A-3GWLab Sample ID: LA58344-14 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



ABN RECAP LIST




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33.17




ABN RECAP LIST







117 of 304

LA58344

33.17



Client Sample ID: A-3GWLab Sample ID: LA58344-14 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA








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33.17



Client Sample ID: A-3GWLab Sample ID: LA58344-14 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA






84-15-1 o-Terphenyl 98% 40-118%


119 of 304

LA58344

33.17



Client Sample ID: A-3GWLab Sample ID: LA58344-14 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19






















120 of 304

LA58344

33.17






VOA RECAP List




121 of 304

LA58344

33.18




VOA RECAP List







122 of 304

LA58344

33.18






ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0045 mg/l120-83-2 2,4-Dichlorophenol b ND 0.0045 mg/l105-67-9 2,4-Dimethylphenol ND 0.0045 mg/l51-28-5 2,4-Dinitrophenol c ND 0.018 mg/l100-02-7 4-Nitrophenol ND 0.023 mg/l87-86-5 Pentachlorophenol ND 0.00091 mg/l108-95-2 Phenol ND 0.0045 mg/l58-90-2 2,3,4,6-Tetrachlorophenol ND 0.0045 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0045 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0045 mg/l83-32-9 Acenaphthene ND 0.00018 mg/l208-96-8 Acenaphthylene ND 0.00018 mg/l62-53-3 Aniline ND 0.0045 mg/l120-12-7 Anthracene ND 0.00018 mg/l56-55-3 Benzo(a)anthracene ND 0.00018 mg/l50-32-8 Benzo(a)pyrene ND 0.00018 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00018 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00018 mg/l92-52-4 1,1' -Biphenyl ND 0.0091 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0045 mg/l106-47-8 4-Chloroaniline b ND 0.0045 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0045 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0045 mg/l91-58-7 2-Chloronaphthalene ND 0.0045 mg/l218-01-9 Chrysene ND 0.00018 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00018 mg/l132-64-9 Dibenzofuran ND 0.0045 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.0091 mg/l84-66-2 Diethyl Phthalate ND 0.0045 mg/l131-11-3 Dimethyl Phthalate ND 0.0045 mg/l117-84-0 Di-n-octyl Phthalate ND 0.0045 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0045 mg/l


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ABN RECAP LIST


121-14-2 2,4-Dinitrotoluene ND 0.0045 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0045 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0045 mg/l206-44-0 Fluoranthene ND 0.00018 mg/l86-73-7 Fluorene ND 0.00018 mg/l118-74-1 Hexachlorobenzene ND 0.00091 mg/l87-68-3 Hexachlorobutadiene ND 0.00045 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.0091 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00018 mg/l78-59-1 Isophorone b ND 0.0045 mg/l91-57-6 2-Methylnaphthalene ND 0.00018 mg/l91-20-3 Naphthalene ND 0.00018 mg/l88-74-4 2-Nitroaniline ND 0.0045 mg/l99-09-2 3-Nitroaniline b ND 0.0045 mg/l100-01-6 4-Nitroaniline b ND 0.0045 mg/l98-95-3 Nitrobenzene ND 0.00091 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0045 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0045 mg/l85-01-8 Phenanthrene ND 0.00018 mg/l129-00-0 Pyrene ND 0.00018 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.00091 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0045 mg/l



(a) Confirmation run.(b) Associated CCV outside of control limits high, sample was ND.(c) Associated CCV outside control limits low. A sensitivity check was analyzed at the project reporting limit



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Client Sample ID: A-2GWLab Sample ID: LA58344-15 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA








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33.18



Client Sample ID: A-2GWLab Sample ID: LA58344-15 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA






84-15-1 o-Terphenyl 102% 40-118%


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33.18



Client Sample ID: A-2GWLab Sample ID: LA58344-15 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19






















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33.18




File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 2X0085227.D 1 10/14/19 17:10 CP n/a n/a V2X3835Run #2 a 2X0085545.D 1 10/18/19 15:57 CP n/a n/a V2X3846


VOA RECAP List




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VOA RECAP List



m,p-Xylene ND 0.0020 mg/l95-47-6 o-Xylene ND 0.0010 mg/l1330-20-7 Xylene (total) 0.0021 0.0020 mg/l


17060-07-0 1,2-Dichloroethane-D4 115% 98% 81-120%2037-26-5 Toluene-D8 108% b 97% 93-105%460-00-4 4-Bromofluorobenzene 122% c 119% 89-107%

(a) Confirmation run for surrogate recoveries.(b) Outside statistical control limits biased high. However, surrogate passes CCV criteria of 80-120.(c) Outside control limits due to matrix interference. Confirmed by reanalysis.


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ABN RECAP LIST


95-57-8 2-Chlorophenol ND 0.0044 mg/l120-83-2 2,4-Dichlorophenol ND 0.0044 mg/l105-67-9 2,4-Dimethylphenol 0.0082 0.0044 mg/l51-28-5 2,4-Dinitrophenol ND 0.018 mg/l100-02-7 4-Nitrophenol b ND 0.022 mg/l87-86-5 Pentachlorophenol ND 0.00088 mg/l108-95-2 Phenol ND 0.0044 mg/l58-90-2 2,3,4,6-Tetrachlorophenol b ND 0.0044 mg/l95-95-4 2,4,5-Trichlorophenol ND 0.0044 mg/l88-06-2 2,4,6-Trichlorophenol ND 0.0044 mg/l83-32-9 Acenaphthene 0.00027 0.00018 mg/l208-96-8 Acenaphthylene ND 0.00018 mg/l62-53-3 Aniline ND 0.0044 mg/l120-12-7 Anthracene ND 0.00018 mg/l56-55-3 Benzo(a)anthracene ND 0.00018 mg/l50-32-8 Benzo(a)pyrene ND 0.00018 mg/l205-99-2 Benzo(b)fluoranthene ND 0.00018 mg/l207-08-9 Benzo(k)fluoranthene ND 0.00018 mg/l92-52-4 1,1' -Biphenyl ND 0.0088 mg/l85-68-7 Butyl Benzyl Phthalate ND 0.0044 mg/l106-47-8 4-Chloroaniline b ND 0.0044 mg/l111-44-4 bis(2-Chloroethyl)ether ND 0.0044 mg/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 0.0044 mg/l91-58-7 2-Chloronaphthalene ND 0.0044 mg/l218-01-9 Chrysene ND 0.00018 mg/l53-70-3 Dibenzo(a,h)anthracene ND 0.00018 mg/l132-64-9 Dibenzofuran ND 0.0044 mg/l91-94-1 3,3' -Dichlorobenzidine b ND 0.0088 mg/l84-66-2 Diethyl Phthalate ND 0.0044 mg/l131-11-3 Dimethyl Phthalate ND 0.0044 mg/l117-84-0 Di-n-octyl Phthalate ND 0.0044 mg/l99-65-0 1,3-Dinitrobenzene ND 0.0044 mg/l


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ABN RECAP LIST


121-14-2 2,4-Dinitrotoluene ND 0.0044 mg/l606-20-2 2,6-Dinitrotoluene ND 0.0044 mg/l117-81-7 bis(2-Ethylhexyl)phthalate ND 0.0044 mg/l206-44-0 Fluoranthene ND 0.00018 mg/l86-73-7 Fluorene 0.00027 0.00018 mg/l118-74-1 Hexachlorobenzene ND 0.00088 mg/l87-68-3 Hexachlorobutadiene ND 0.00044 mg/l77-47-4 Hexachlorocyclopentadiene ND 0.0088 mg/l193-39-5 Indeno(1,2,3-cd)pyrene ND 0.00018 mg/l78-59-1 Isophorone ND 0.0044 mg/l91-57-6 2-Methylnaphthalene ND 0.00018 mg/l91-20-3 Naphthalene ND 0.00018 mg/l88-74-4 2-Nitroaniline ND 0.0044 mg/l99-09-2 3-Nitroaniline b ND 0.0044 mg/l100-01-6 4-Nitroaniline b ND 0.0044 mg/l98-95-3 Nitrobenzene ND 0.00088 mg/l621-64-7 N-Nitroso-di-n-propylamine ND 0.0044 mg/l86-30-6 N-Nitrosodiphenylamine ND 0.0044 mg/l85-01-8 Phenanthrene ND 0.00018 mg/l129-00-0 Pyrene ND 0.00018 mg/l95-94-3 1,2,4,5-Tetrachlorobenzene ND 0.00088 mg/l120-82-1 1,2,4-Trichlorobenzene ND 0.0044 mg/l





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Client Sample ID: B-1GWLab Sample ID: LA58344-16 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: MADEP VPH REV 1.1 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 LC053081.D 1 10/21/19 22:59 NN n/a n/a GLC2394Run #2 LC053271.D 5 10/22/19 17:34 NN n/a n/a GLC2397




Aliphatics C6-C8 (Unadj.) 5.41 a 0.75 mg/lAliphatics > C8-C10 (Unadj.) 2.77 0.15 mg/lAromatics > C8-C10 (Unadj.) 1.97 0.15 mg/l


615-59-8 2,5-Dibromotoluene 125% b 101% b 70-130%615-59-8 2,5-Dibromotoluene 124% c 102% c 70-130%

(a) Result is from Run# 2(b) Recovery from Aliphatics fraction.(c) Recovery from Aromatics fraction.


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TPH-GRO (C6-C10) 11.3 0.50 mg/l




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Client Sample ID: B-1GWLab Sample ID: LA58344-16 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: MADEP EPH REV 1.1 SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 X0012244.D 1 10/19/19 12:35 LS 10/18/19 16:00 OP15390 GLB2101Run #2 Y0012244.D 1 10/19/19 12:34 LS 10/18/19 16:00 OP15390 GLB2102

Initial Volume Final VolumeRun #1 53.3 ml 4.0 mlRun #2 53.3 ml 4.0 ml

Louisiana EPH Ranges


Aliphatics > C10-C12 (Unadj.)) 1.56 a 0.14 mg/lAliphatics > C12-C16 (Unadj.)) 0.197 a 0.14 mg/lAliphatics > C16-C35 (Unadj.)) ND a 0.14 mg/lAromatics > C10-C12 (Unadj.))ND 0.14 mg/lAromatics > C12-C16 (Unadj.))0.245 0.14 mg/lAromatics > C16-C21 (Unadj.))ND 0.14 mg/lAromatics > C21-C35 (Unadj.))ND 0.14 mg/l


3386-33-2 1-Chlorooctadecane 58% 40-140%84-15-1 o-Terphenyl 88% 40-140%321-60-8 2-Fluorobiphenyl 89% 40-140%

(a) Result is from Run# 2


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84-15-1 o-Terphenyl 99% 40-118%



135 of 304

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136 of 304

LA58344

33.19



Client Sample ID: B-1GWLab Sample ID: LA58344-16F Date Sampled: 10/08/19Matrix: AQ - Groundwater Filtered Date Received: 10/08/19






















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Client Sample ID: BD-01Lab Sample ID: LA58344-17 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



VOA RECAP List




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Client Sample ID: BD-01Lab Sample ID: LA58344-17 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8260B Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

VOA RECAP List







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Client Sample ID: BD-01Lab Sample ID: LA58344-17 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA



ABN RECAP LIST




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Client Sample ID: BD-01Lab Sample ID: LA58344-17 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8270D SW846 3510C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA

ABN RECAP LIST







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Client Sample ID: BD-01Lab Sample ID: LA58344-17 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8015C Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA








142 of 304

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Client Sample ID: BD-01Lab Sample ID: LA58344-17 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19Method: SW846 8015C SW846 3511 Percent Solids: n/aProject: Bottle Art Lofts, University & Cameron, Lafayette, LA






84-15-1 o-Terphenyl 104% 40-118%



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Client Sample ID: BD-01Lab Sample ID: LA58344-17 Date Sampled: 10/08/19Matrix: AQ - Ground Water Date Received: 10/08/19






















144 of 304

LA58344

33.21






VOA RECAP List




145 of 304

LA58344

33.22




VOA RECAP List







146 of 304

LA58344

33.22


Misc. Forms




Scott, LASection 4

147 of 304

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4


148 of 304

LA58344

44.1


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44.1




4. No. Coolers: 6

Airbill #'s:


Y or N


3. COC Present:




3. Cooler media:

IR Gun



















Intact

Y or N

Comments Received 6 sets of Trip Blanks only 1 set on COC.

Y or N N/A

Cooler Temps: #1: (1.8/1.8); #2: (2.3/2.3); #3: (2.1/2.1); #4: (2.9/2.9); #5: (1.7/1.7); #6: (2.6/2.6);


Analyze all trip blanks as one set.

Amy Jackson 11/4/2019Responded to by: Response Date:


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44.1


MS Volatiles

QC Data Summaries



Scott, LASection 5

151 of 304

LA58344

5




LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-8



152 of 304

LA58344

55.1.1




LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-8






153 of 304

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55.1.1




LA58344-7


67-64-1 Acetone ND 50 ug/l71-43-2 Benzene ND 1.0 ug/l75-27-4 Bromodichloromethane ND 1.0 ug/l75-25-2 Bromoform ND 1.0 ug/l75-15-0 Carbon Disulfide ND 1.0 ug/l56-23-5 Carbon Tetrachloride ND 1.0 ug/l108-90-7 Chlorobenzene ND 1.0 ug/l75-00-3 Chloroethane ND 1.0 ug/l67-66-3 Chloroform ND 1.0 ug/l124-48-1 Dibromochloromethane ND 1.0 ug/l96-12-8 1,2-Dibromo-3-chloropropane 1.2 1.0 ug/l541-73-1 m-Dichlorobenzene ND 1.0 ug/l95-50-1 o-Dichlorobenzene 0.30 1.0 ug/l J106-46-7 p-Dichlorobenzene 0.27 1.0 ug/l J75-34-3 1,1-Dichloroethane ND 1.0 ug/l107-06-2 1,2-Dichloroethane ND 1.0 ug/l75-35-4 1,1-Dichloroethylene ND 1.0 ug/l156-59-2 cis-1,2-Dichloroethylene ND 1.0 ug/l156-60-5 trans-1,2-Dichloroethylene ND 1.0 ug/l540-59-0 1,2-Dichloroethene (total) ND 1.0 ug/l78-87-5 1,2-Dichloropropane ND 1.0 ug/l10061-01-5 cis-1,3-Dichloropropene ND 1.0 ug/l10061-02-6 trans-1,3-Dichloropropene ND 1.0 ug/l542-75-6 1,3-Dichloropropene (total) ND 1.0 ug/l67-72-1 Hexachloroethane ND 1.0 ug/l78-83-1 Isobutyl Alcohol ND 100 ug/l74-83-9 Methyl Bromide ND 1.0 ug/l74-87-3 Methyl Chloride ND 1.0 ug/l75-09-2 Methylene Chloride ND 1.0 ug/l78-93-3 Methyl Ethyl Ketone 1.4 13 ug/l J108-10-1 4-Methyl-2-pentanone ND 13 ug/l1634-04-4 Methyl Tert Butyl Ether ND 1.0 ug/l100-42-5 Styrene ND 1.0 ug/l630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 ug/l79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 ug/l127-18-4 Tetrachloroethylene ND 1.0 ug/l

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LA58344-7


71-55-6 1,1,1-Trichloroethane ND 1.0 ug/l79-00-5 1,1,2-Trichloroethane ND 1.0 ug/l79-01-6 Trichloroethylene ND 1.0 ug/l75-69-4 Trichlorofluoromethane ND 1.0 ug/l75-01-4 Vinyl Chloride ND 1.0 ug/l



155 of 304

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55.1.2




LA58344-7


100-41-4 Ethylbenzene ND 50 ug/kg108-88-3 Toluene ND 250 ug/kg

m,p-Xylene ND 100 ug/kg95-47-6 o-Xylene ND 50 ug/kg1330-20-7 Xylene (total) ND 100 ug/kg



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55.1.3




LA58344-9, LA58344-10, LA58344-11, LA58344-12, LA58344-13, LA58344-14, LA58344-15, LA58344-16, LA58344-17, LA58344-18



157 of 304

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55.1.4










158 of 304

LA58344

55.1.4




LA58344-2





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55.1.5


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15437-LB 1G112348.D 1 10/23/19 CP 10/21/19 OP15437 V1G5856


LA58344-2A, LA58344-7A


71-43-2 Benzene ND 1.0 ug/l100-41-4 Ethylbenzene ND 1.0 ug/l108-88-3 Toluene ND 1.0 ug/l1330-20-7 Xylene (total) ND 2.0 ug/l



160 of 304

LA58344

55.2.1




LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-8





161 of 304

LA58344

55.3.1




LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-8








162 of 304

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55.3.1




LA58344-7


67-64-1 Acetone 50 45.4 91 46.6 93 3 35-173/2071-43-2 Benzene 20 20.9 105 20.0 100 4 82-119/1175-27-4 Bromodichloromethane 20 20.8 104 19.7 99 5 76-124/1175-25-2 Bromoform 20 19.9 100 19.1 96 4 52-131/1475-15-0 Carbon Disulfide 20 22.1 111 21.4 107 3 69-135/1456-23-5 Carbon Tetrachloride 20 21.4 107 20.6 103 4 73-127/13108-90-7 Chlorobenzene 20 20.7 104 19.7 99 5 82-118/1175-00-3 Chloroethane 20 22.0 110 20.5 103 7 57-146/2067-66-3 Chloroform 20 21.7 109 21.0 105 3 77-122/12124-48-1 Dibromochloromethane 20 20.5 103 20.1 101 2 68-126/1296-12-8 1,2-Dibromo-3-chloropropane 20 19.2 96 20.4 102 6 57-132/17541-73-1 m-Dichlorobenzene 20 20.9 105 20.7 104 1 78-122/1295-50-1 o-Dichlorobenzene 20 20.2 101 20.2 101 0 78-122/12106-46-7 p-Dichlorobenzene 20 20.4 102 20.2 101 1 79-119/1275-34-3 1,1-Dichloroethane 20 21.9 110 21.3 107 3 77-124/14107-06-2 1,2-Dichloroethane 20 19.4 97 18.7 94 4 71-124/1175-35-4 1,1-Dichloroethylene 20 21.5 108 20.9 105 3 77-125/14156-59-2 cis-1,2-Dichloroethylene 20 21.9 110 20.7 104 6 79-121/13156-60-5 trans-1,2-Dichloroethylene 20 22.0 110 20.8 104 6 77-124/14540-59-0 1,2-Dichloroethene (total) 40 43.9 110 41.5 104 6 80-121/1378-87-5 1,2-Dichloropropane 20 21.3 107 20.4 102 4 81-117/1110061-01-5 cis-1,3-Dichloropropene 20 21.4 107 20.2 101 6 77-123/1110061-02-6 trans-1,3-Dichloropropene 20 21.6 108 20.1 101 7 74-127/12542-75-6 1,3-Dichloropropene (total) 40 43.1 108 40.3 101 7 76-124/1167-72-1 Hexachloroethane 20 19.0 95 19.1 96 1 54-132/1578-83-1 Isobutyl Alcohol 200 232 116 210 105 10 37-152/3074-83-9 Methyl Bromide 20 19.8 99 19.4 97 2 46-165/2074-87-3 Methyl Chloride 20 39.7 199* 39.0 195* 2 55-140/1875-09-2 Methylene Chloride 20 21.8 109 20.3 102 7 73-132/1478-93-3 Methyl Ethyl Ketone 50 44.5 89 44.3 89 0 55-149/19108-10-1 4-Methyl-2-pentanone 50 47.1 94 48.1 96 2 63-137/171634-04-4 Methyl Tert Butyl Ether 20 21.0 105 20.8 104 1 73-124/14100-42-5 Styrene 20 22.0 110 21.2 106 4 80-126/12630-20-6 1,1,1,2-Tetrachloroethane 20 21.0 105 20.3 102 3 77-126/1279-34-5 1,1,2,2-Tetrachloroethane 20 19.8 99 20.2 101 2 69-134/14127-18-4 Tetrachloroethylene 20 20.7 104 19.6 98 5 79-121/13


163 of 304

LA58344

55.3.2




LA58344-7


71-55-6 1,1,1-Trichloroethane 20 21.5 108 21.0 105 2 79-126/1379-00-5 1,1,2-Trichloroethane 20 20.8 104 20.2 101 3 80-120/1279-01-6 Trichloroethylene 20 20.3 102 19.9 100 2 78-121/1275-69-4 Trichlorofluoromethane 20 21.5 108 21.1 106 2 74-129/1475-01-4 Vinyl Chloride 20 21.5 108 20.3 102 6 74-125/14




164 of 304

LA58344

55.3.2




LA58344-7


100-41-4 Ethylbenzene 20 20.5 103 21.8 109 6 82-120/11108-88-3 Toluene 20 19.6 98 20.6 103 5 82-118/12





165 of 304

LA58344

55.3.3






67-64-1 Acetone 50 53.4 107 50.3 101 6 35-173/2071-43-2 Benzene 20 20.7 104 20.1 101 3 82-119/1175-27-4 Bromodichloromethane 20 20.8 104 20.2 101 3 76-124/1175-25-2 Bromoform 20 21.0 105 20.6 103 2 52-131/1475-15-0 Carbon Disulfide 20 21.3 107 20.6 103 3 69-135/1456-23-5 Carbon Tetrachloride 20 20.8 104 19.9 100 4 73-127/13108-90-7 Chlorobenzene 20 20.6 103 19.6 98 5 82-118/1175-00-3 Chloroethane 20 19.5 98 18.6 93 5 57-146/2067-66-3 Chloroform 20 21.3 107 20.9 105 2 77-122/12124-48-1 Dibromochloromethane 20 21.0 105 20.2 101 4 68-126/1296-12-8 1,2-Dibromo-3-chloropropane 20 21.6 108 21.8 109 1 57-132/17541-73-1 m-Dichlorobenzene 20 21.2 106 20.6 103 3 78-122/1295-50-1 o-Dichlorobenzene 20 20.9 105 20.3 102 3 78-122/12106-46-7 p-Dichlorobenzene 20 20.7 104 20.2 101 2 79-119/1275-34-3 1,1-Dichloroethane 20 21.7 109 21.1 106 3 77-124/14107-06-2 1,2-Dichloroethane 20 19.6 98 18.5 93 6 71-124/1175-35-4 1,1-Dichloroethylene 20 21.3 107 20.7 104 3 77-125/14156-59-2 cis-1,2-Dichloroethylene 20 21.7 109 21.0 105 3 79-121/13156-60-5 trans-1,2-Dichloroethylene 20 20.9 105 20.3 102 3 77-124/14540-59-0 1,2-Dichloroethene (total) 40 42.6 107 41.2 103 3 80-121/1378-87-5 1,2-Dichloropropane 20 21.1 106 20.2 101 4 81-117/1110061-01-5 cis-1,3-Dichloropropene 20 21.8 109 20.7 104 5 77-123/1110061-02-6 trans-1,3-Dichloropropene 20 21.3 107 20.6 103 3 74-127/12542-75-6 1,3-Dichloropropene (total) 40 43.1 108 41.3 103 4 76-124/11100-41-4 Ethylbenzene 20 20.5 103 19.7 99 4 82-120/1167-72-1 Hexachloroethane 20 20.2 101 20.5 103 1 54-132/1578-83-1 Isobutyl Alcohol 200 224 112 203 102 10 37-152/3074-83-9 Methyl Bromide 20 17.1 86 17.3 87 1 46-165/2074-87-3 Methyl Chloride 20 19.1 96 34.7 174* 58* 55-140/1875-09-2 Methylene Chloride 20 21.4 107 20.2 101 6 73-132/1478-93-3 Methyl Ethyl Ketone 50 51.7 103 50.1 100 3 55-149/19108-10-1 4-Methyl-2-pentanone 50 55.4 111 52.2 104 6 63-137/171634-04-4 Methyl Tert Butyl Ether 20 22.0 110 21.0 105 5 73-124/14100-42-5 Styrene 20 21.9 110 21.1 106 4 80-126/12630-20-6 1,1,1,2-Tetrachloroethane 20 20.8 104 20.0 100 4 77-126/1279-34-5 1,1,2,2-Tetrachloroethane 20 21.4 107 20.2 101 6 69-134/14


166 of 304

LA58344

55.3.4











167 of 304

LA58344

55.3.4




LA58344-2






168 of 304

LA58344

55.3.5




LA58344-2A, LA58344-7A


71-43-2 Benzene 20 21.5 108 19.3 97 11 82-119/11100-41-4 Ethylbenzene 20 21.1 106 19.1 96 10 82-120/11108-88-3 Toluene 20 20.4 102 18.2 91 11 82-118/121330-20-7 Xylene (total) 60 65.8 110 61.0 102 8 82-122/11




169 of 304

LA58344

55.3.6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58336-1MS 2X0085179.D 1 10/11/19 CP n/a n/a V2X3833LA58336-1MSD 2X0085181.D 1 10/11/19 CP n/a n/a V2X3833LA58336-1 2X0085153.D 1 10/11/19 CP n/a n/a V2X3833


LA58344-7


67-64-1 Acetone ND 13300 11900 89 13300 11800 89 1 19-170/3471-43-2 Benzene 40.6 5330 4970 92 5330 4990 93 0 15-162/3375-27-4 Bromodichloromethane ND 5330 4870 91 5330 5000 94 3 48-124/1475-25-2 Bromoform ND 5330 4540 85 5330 4750 89 5 20-128/1675-15-0 Carbon Disulfide ND 5330 4410 83 5330 4310 81 2 4-140/3156-23-5 Carbon Tetrachloride ND 5330 4880 92 5330 4970 93 2 25-136/17108-90-7 Chlorobenzene ND 5330 4680 88 5330 4610 86 2 31-153/1275-00-3 Chloroethane 19600 5330 18300 -24* a 5330 24500 92 29 1-171/6467-66-3 Chloroform ND 5330 5220 98 5330 5190 97 1 26-153/42124-48-1 Dibromochloromethane ND 5330 4910 92 5330 4880 92 1 26-131/1496-12-8 1,2-Dibromo-3-chloropropane ND 5330 4880 92 5330 5400 101 10 18-141/68541-73-1 m-Dichlorobenzene ND 5330 4780 90 5330 4870 91 2 22-152/1595-50-1 o-Dichlorobenzene ND 5330 4830 91 5330 4930 92 2 27-150/12106-46-7 p-Dichlorobenzene ND 5330 4650 87 5330 4740 89 2 19-154/1275-34-3 1,1-Dichloroethane ND 5330 5270 99 5330 5320 100 1 31-147/13107-06-2 1,2-Dichloroethane 281 5330 4960 88 5330 5090 90 3 31-147/1375-35-4 1,1-Dichloroethylene ND 5330 4800 90 5330 4770 89 1 22-148/19156-59-2 cis-1,2-Dichloroethylene ND 5330 4930 92 5330 4880 92 1 25-145/15156-60-5 trans-1,2-Dichloroethylene ND 5330 4770 89 5330 4630 87 3 24-145/17540-59-0 1,2-Dichloroethene (total) ND 10700 9700 91 10700 9510 89 2 30-142/1578-87-5 1,2-Dichloropropane ND 5330 5220 98 5330 5400 101 3 36-141/1310061-01-5 cis-1,3-Dichloropropene ND 5330 4860 91 5330 4800 90 1 27-143/1210061-02-6 trans-1,3-Dichloropropene ND 5330 4800 90 5330 4590 86 4 46-130/14542-75-6 1,3-Dichloropropene (total) ND 10700 9660 91 10700 9390 88 3 50-150/30 b

67-72-1 Hexachloroethane ND 5330 4540 85 5330 4900 92 8 4-136/1978-83-1 Isobutyl alcohol ND 53300 56400 106 53300 53400 100 5 16-172/1674-83-9 Methyl Bromide ND 5330 2900 54 5330 3010 56 4 1-178/4074-87-3 Methyl Chloride ND 5330 9600 180* 5330 9430 177* 2 1-151/3775-09-2 Methylene Chloride ND 5330 4830 91 5330 4960 93 3 27-147/1878-93-3 Methyl Ethyl Ketone 805 13300 11600 81 13300 12800 90 10 29-156/32108-10-1 4-Methyl-2-pentanone ND 13300 15000 113 13300 13000 98 14 33-160/231634-04-4 Methyl Tert Butyl Ether ND 5330 5400 101 5330 5550 104 3 37-145/14100-42-5 Styrene ND 5330 4920 92 5330 4960 93 1 24-165/13630-20-6 1,1,1,2-Tetrachloroethane ND 5330 5310 100 5330 5310 100 0 33-140/1379-34-5 1,1,2,2-Tetrachloroethane ND 5330 5340 100 5330 5390 101 1 33-146/48127-18-4 Tetrachloroethylene ND 5330 4760 89 5330 4460 84 7 21-149/18


170 of 304

LA58344

55.4.1




LA58344-7


71-55-6 1,1,1-Trichloroethane ND 5330 5150 97 5330 5180 97 1 31-142/1679-00-5 1,1,2-Trichloroethane ND 5330 5170 97 5330 5090 95 2 11-185/1679-01-6 Trichloroethylene ND 5330 4820 90 5330 4740 89 2 21-154/1575-69-4 Trichlorofluoromethane ND 5330 4670 88 5330 4730 89 1 1-163/2775-01-4 Vinyl Chloride 6880 5330 14600 145 5330 16800 186* 14 32-153/15





171 of 304

LA58344

55.4.1




LA58344-7


100-41-4 Ethylbenzene ND 1820 1950 107 1820 2030 112 4 14-168/13108-88-3 Toluene ND 1820 1850 102 1820 1960 108 6 11-173/43





172 of 304

LA58344

55.4.2




LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-8


67-64-1 Acetone 308 50 230 -156* a 52.1 68.5 -460* a 108* 19-170/3471-43-2 Benzene 0.62 20 14.3 68 20.8 14.6 67 2 15-162/3375-27-4 Bromodichloromethane ND 20 15.4 77 20.8 14.6 70 5 48-124/1475-25-2 Bromoform ND 20 17.4 87 20.8 16.7 80 4 20-128/1675-15-0 Carbon Disulfide ND 20 11.6 58 20.8 12.9 62 11 4-140/3156-23-5 Carbon Tetrachloride ND 20 13.3 67 20.8 13.6 65 2 25-136/17108-90-7 Chlorobenzene ND 20 14.5 73 20.8 14.0 67 4 31-153/1275-00-3 Chloroethane ND 20 10.2 51 20.8 10.1 48 1 1-171/6467-66-3 Chloroform ND 20 13.2 66 20.8 13.9 67 5 26-153/42124-48-1 Dibromochloromethane ND 20 16.9 85 20.8 16.8 81 1 26-131/1496-12-8 1,2-Dibromo-3-chloropropane ND 20 11.3 57 20.8 13.3 64 16 18-141/68541-73-1 m-Dichlorobenzene ND 20 15.3 77 20.8 14.7 71 4 22-152/1595-50-1 o-Dichlorobenzene ND 20 15.1 76 20.8 14.8 71 2 27-150/12106-46-7 p-Dichlorobenzene ND 20 15.5 78 20.8 14.8 71 5 19-154/1275-34-3 1,1-Dichloroethane ND 20 14.7 74 20.8 15.1 72 3 31-147/13107-06-2 1,2-Dichloroethane ND 20 17.6 88 20.8 16.9 81 4 31-147/1375-35-4 1,1-Dichloroethylene ND 20 12.0 60 20.8 11.8 57 2 22-148/19156-59-2 cis-1,2-Dichloroethylene ND 20 12.9 65 20.8 13.2 63 2 25-145/15156-60-5 trans-1,2-Dichloroethylene ND 20 12.7 64 20.8 13.1 63 3 24-145/17540-59-0 1,2-Dichloroethene (total) ND 40 25.6 64 41.7 26.3 63 3 30-142/1578-87-5 1,2-Dichloropropane ND 20 15.1 76 20.8 16.1 77 6 36-141/1310061-01-5 cis-1,3-Dichloropropene ND 20 15.0 75 20.8 15.8 76 5 27-143/1210061-02-6 trans-1,3-Dichloropropene ND 20 17.1 86 20.8 15.7 75 9 46-130/14542-75-6 1,3-Dichloropropene (total) ND 40 32.1 80 41.7 31.5 76 2 50-150/30 b

100-41-4 Ethylbenzene ND 20 13.1 66 20.8 13.1 63 0 14-168/1367-72-1 Hexachloroethane ND 20 16.2 81 20.8 16.1 77 1 4-136/1978-83-1 Isobutyl alcohol ND 200 142 71 208 156 75 9 16-172/1674-83-9 Methyl Bromide ND 20 12.0 60 20.8 13.5 65 12 1-178/4074-87-3 Methyl Chloride ND 20 12.2 61 20.8 12.9 62 6 1-151/3775-09-2 Methylene Chloride ND 20 13.7 69 20.8 11.3 54 19* 27-147/1878-93-3 Methyl Ethyl Ketone 22.0 50 50.6 57 52.1 41.1 37 21 29-156/32108-10-1 4-Methyl-2-pentanone ND 50 44.2 88 52.1 42.3 81 4 33-160/231634-04-4 Methyl Tert Butyl Ether ND 20 16.5 83 20.8 16.2 78 2 37-145/14100-42-5 Styrene ND 20 9.5 48 20.8 11.8 57 22* 24-165/13630-20-6 1,1,1,2-Tetrachloroethane ND 20 15.3 77 20.8 14.5 70 5 33-140/1379-34-5 1,1,2,2-Tetrachloroethane ND 20 16.8 84 20.8 17.3 83 3 33-146/48


173 of 304

LA58344

55.4.3




LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-8


127-18-4 Tetrachloroethylene ND 20 16.8 84 20.8 16.5 79 2 21-149/18108-88-3 Toluene ND 20 14.2 71 20.8 13.5 65 5 11-173/4371-55-6 1,1,1-Trichloroethane ND 20 10.8 54 20.8 12.0 58 11 31-142/1679-00-5 1,1,2-Trichloroethane ND 20 18.3 92 20.8 16.7 80 9 11-185/1679-01-6 Trichloroethylene ND 20 14.3 72 20.8 16.5 79 14 21-154/1575-69-4 Trichlorofluoromethane ND 20 10.4 52 20.8 11.1 53 7 1-163/2775-01-4 Vinyl Chloride ND 20 11.3 57 20.8 12.7 61 12 32-153/15

m,p-Xylene 0.59 40 32.7 80 41.7 32.5 77 1 14-175/1295-47-6 o-Xylene ND 20 14.0 70 20.8 14.0 67 0 19-167/131330-20-7 Xylene (total) ND 60 46.7 78 62.5 46.5 74 0 14-172/12





174 of 304

LA58344

55.4.3






67-64-1 Acetone ND 100 56.4 56 100 60.8 61 8 11-126/2271-43-2 Benzene ND 40 41.0 103 40 40.5 101 1 41-155/1475-27-4 Bromodichloromethane ND 40 41.0 103 40 41.6 104 1 65-125/1475-25-2 Bromoform ND 40 39.9 100 40 40.4 101 1 39-127/1875-15-0 Carbon Disulfide ND 40 42.1 105 40 42.6 107 1 55-139/2056-23-5 Carbon Tetrachloride ND 40 41.9 105 40 43.0 108 3 60-131/20108-90-7 Chlorobenzene ND 40 38.7 97 40 39.4 99 2 71-124/1475-00-3 Chloroethane ND 40 43.8 110 40 41.2 103 6 44-163/3167-66-3 Chloroform ND 40 42.5 106 40 43.7 109 3 65-130/15124-48-1 Dibromochloromethane ND 40 40.0 100 40 41.3 103 3 57-125/1596-12-8 1,2-Dibromo-3-chloropropane ND 40 38.5 96 40 42.3 106 9 43-132/22541-73-1 m-Dichlorobenzene ND 40 40.1 100 40 39.9 100 1 67-124/1495-50-1 o-Dichlorobenzene ND 40 38.5 96 40 38.3 96 1 67-124/14106-46-7 p-Dichlorobenzene ND 40 39.5 99 40 38.5 96 3 66-122/1575-34-3 1,1-Dichloroethane ND 40 43.1 108 40 43.9 110 2 65-132/17107-06-2 1,2-Dichloroethane ND 40 39.2 98 40 38.9 97 1 61-130/1375-35-4 1,1-Dichloroethylene ND 40 41.4 104 40 41.6 104 0 62-136/20156-59-2 cis-1,2-Dichloroethylene ND 40 42.9 107 40 43.0 108 0 68-129/15156-60-5 trans-1,2-Dichloroethylene ND 40 41.8 105 40 43.3 108 4 65-132/18540-59-0 1,2-Dichloroethene (total) ND 80 84.7 106 80 86.3 108 2 66-130/1578-87-5 1,2-Dichloropropane ND 40 41.1 103 40 42.2 106 3 71-123/1410061-01-5 cis-1,3-Dichloropropene ND 40 40.8 102 40 40.9 102 0 61-125/1510061-02-6 trans-1,3-Dichloropropene ND 40 41.3 103 40 41.2 103 0 59-128/14542-75-6 1,3-Dichloropropene (total) ND 80 82.1 103 80 82.1 103 0 61-126/14100-41-4 Ethylbenzene ND 40 39.2 98 40 39.7 99 1 50-147/1567-72-1 Hexachloroethane ND 40 39.4 99 40 38.7 97 2 42-122/2178-83-1 Isobutyl Alcohol ND 400 467 117 400 442 111 6 6-168/4174-83-9 Methyl Bromide ND 40 34.8 87 40 36.4 91 4 24-163/2874-87-3 Methyl Chloride ND 40 71.3 178* 40 72.6 182* 2 37-151/2275-09-2 Methylene Chloride ND 40 41.5 104 40 43.3 108 4 63-137/1678-93-3 Methyl Ethyl Ketone ND 100 76.9 77 100 79.0 79 3 35-137/21108-10-1 4-Methyl-2-pentanone ND 100 103 103 100 105 105 2 48-146/211634-04-4 Methyl Tert Butyl Ether ND 40 43.1 108 40 43.7 109 1 48-143/15100-42-5 Styrene ND 40 40.9 102 40 41.4 104 1 58-140/18630-20-6 1,1,1,2-Tetrachloroethane ND 40 40.4 101 40 41.6 104 3 67-127/1579-34-5 1,1,2,2-Tetrachloroethane ND 40 40.9 102 40 41.0 103 0 62-139/16


175 of 304

LA58344

55.4.4






127-18-4 Tetrachloroethylene ND 40 38.6 97 40 39.4 99 2 68-127/19108-88-3 Toluene ND 40 39.6 99 40 41.1 103 4 40-153/1571-55-6 1,1,1-Trichloroethane ND 40 42.6 107 40 43.4 109 2 68-132/1879-00-5 1,1,2-Trichloroethane ND 40 39.5 99 40 40.3 101 2 62-137/1679-01-6 Trichloroethylene ND 40 39.3 98 40 39.2 98 0 67-124/1675-69-4 Trichlorofluoromethane ND 40 40.8 102 40 41.4 104 1 65-134/1775-01-4 Vinyl Chloride ND 40 38.4 96 40 39.2 98 2 60-133/16

m,p-Xylene ND 80 81.1 101 80 83.1 104 2 47-153/1595-47-6 o-Xylene ND 40 39.8 100 40 40.7 102 2 50-149/141330-20-7 Xylene (total) ND 120 121 101 120 124 103 2 46-154/15




176 of 304

LA58344

55.4.4




LA58344-2






177 of 304

LA58344

55.4.5


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchLA58344-2AMS 1G112372.D 10 10/23/19 CP n/a n/a V1G5856LA58344-2AMSD 1G112374.D 10 10/23/19 CP n/a n/a V1G5856LA58344-2A 1G112368.D 1 10/23/19 CP 10/21/19 OP15437 V1G5856


LA58344-2A, LA58344-7A

LA58344-2A Spike MS MS Spike MSD MSD LimitsCAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene ND 200 212 106 200 195 98 8 31-161/15100-41-4 Ethylbenzene ND 200 200 100 200 187 94 7 47-146/30108-88-3 Toluene ND 200 197 99 200 184 92 7 36-155/171330-20-7 Xylene (total) ND 600 646 108 600 588 98 9 41-154/29




178 of 304

LA58344

55.4.6


MS Semi-volatiles

QC Data Summaries



Scott, LASection 6

179 of 304

LA58344

6


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15357-MB F0059499.D 1 10/17/19 SV 10/14/19 OP15357 EF2032


LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-7, LA58344-8


95-57-8 2-Chlorophenol ND 170 ug/kg120-83-2 2,4-Dichlorophenol ND 170 ug/kg105-67-9 2,4-Dimethylphenol ND 170 ug/kg51-28-5 2,4-Dinitrophenol ND 650 ug/kg100-02-7 4-Nitrophenol ND 650 ug/kg87-86-5 Pentachlorophenol ND 170 ug/kg108-95-2 Phenol ND 170 ug/kg58-90-2 2,3,4,6-Tetrachlorophenol ND 170 ug/kg95-95-4 2,4,5-Trichlorophenol ND 170 ug/kg88-06-2 2,4,6-Trichlorophenol ND 170 ug/kg83-32-9 Acenaphthene ND 9.9 ug/kg208-96-8 Acenaphthylene ND 9.9 ug/kg62-53-3 Aniline ND 170 ug/kg120-12-7 Anthracene ND 9.9 ug/kg56-55-3 Benzo(a)anthracene ND 9.9 ug/kg50-32-8 Benzo(a)pyrene ND 9.9 ug/kg205-99-2 Benzo(b)fluoranthene ND 9.9 ug/kg92-52-4 1,1' -Biphenyl ND 170 ug/kg207-08-9 Benzo(k)fluoranthene ND 9.9 ug/kg85-68-7 Butyl Benzyl Phthalate ND 170 ug/kg106-47-8 4-Chloroaniline ND 170 ug/kg111-44-4 bis(2-Chloroethyl)ether ND 170 ug/kg108-60-1 2,2' -Oxybis(1-chloropropane) ND 170 ug/kg91-58-7 2-Chloronaphthalene ND 170 ug/kg218-01-9 Chrysene ND 9.9 ug/kg53-70-3 Dibenzo(a,h)anthracene ND 9.9 ug/kg132-64-9 Dibenzofuran ND 170 ug/kg91-94-1 3,3' -Dichlorobenzidine ND 170 ug/kg84-66-2 Diethyl Phthalate ND 170 ug/kg131-11-3 Dimethyl Phthalate ND 170 ug/kg117-84-0 Di-n-octyl Phthalate ND 170 ug/kg99-65-0 1,3-Dinitrobenzene ND 170 ug/kg121-14-2 2,4-Dinitrotoluene ND 170 ug/kg606-20-2 2,6-Dinitrotoluene ND 170 ug/kg117-81-7 bis(2-Ethylhexyl)phthalate ND 170 ug/kg206-44-0 Fluoranthene ND 9.9 ug/kg

180 of 304

LA58344

66.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15357-MB F0059499.D 1 10/17/19 SV 10/14/19 OP15357 EF2032




86-73-7 Fluorene ND 9.9 ug/kg118-74-1 Hexachlorobenzene ND 170 ug/kg87-68-3 Hexachlorobutadiene ND 170 ug/kg77-47-4 Hexachlorocyclopentadiene ND 650 ug/kg193-39-5 Indeno(1,2,3-cd)pyrene ND 9.9 ug/kg78-59-1 Isophorone ND 170 ug/kg91-57-6 2-Methylnaphthalene ND 9.9 ug/kg91-20-3 Naphthalene ND 9.9 ug/kg88-74-4 2-Nitroaniline ND 650 ug/kg99-09-2 3-Nitroaniline ND 650 ug/kg100-01-6 4-Nitroaniline ND 650 ug/kg98-95-3 Nitrobenzene ND 170 ug/kg621-64-7 N-Nitroso-di-n-propylamine ND 170 ug/kg86-30-6 N-Nitrosodiphenylamine ND 170 ug/kg85-01-8 Phenanthrene ND 9.9 ug/kg129-00-0 Pyrene ND 9.9 ug/kg95-94-3 1,2,4,5-Tetrachlorobenzene ND 170 ug/kg120-82-1 1,2,4-Trichlorobenzene ND 170 ug/kg



181 of 304

LA58344

66.1.1




LA58344-9, LA58344-10, LA58344-11, LA58344-12, LA58344-13, LA58344-14, LA58344-15, LA58344-16, LA58344-17


95-57-8 2-Chlorophenol ND 5.0 ug/l120-83-2 2,4-Dichlorophenol ND 5.0 ug/l105-67-9 2,4-Dimethylphenol ND 5.0 ug/l51-28-5 2,4-Dinitrophenol ND 20 ug/l100-02-7 4-Nitrophenol ND 25 ug/l87-86-5 Pentachlorophenol ND 10 ug/l108-95-2 Phenol ND 5.0 ug/l58-90-2 2,3,4,6-Tetrachlorophenol ND 5.0 ug/l95-95-4 2,4,5-Trichlorophenol ND 5.0 ug/l88-06-2 2,4,6-Trichlorophenol ND 5.0 ug/l83-32-9 Acenaphthene ND 0.20 ug/l208-96-8 Acenaphthylene ND 0.20 ug/l62-53-3 Aniline ND 5.0 ug/l120-12-7 Anthracene ND 0.20 ug/l56-55-3 Benzo(a)anthracene ND 0.20 ug/l50-32-8 Benzo(a)pyrene ND 0.20 ug/l205-99-2 Benzo(b)fluoranthene ND 0.20 ug/l207-08-9 Benzo(k)fluoranthene ND 0.20 ug/l92-52-4 1,1' -Biphenyl ND 10 ug/l85-68-7 Butyl Benzyl Phthalate ND 5.0 ug/l106-47-8 4-Chloroaniline ND 5.0 ug/l111-44-4 bis(2-Chloroethyl)ether ND 5.0 ug/l108-60-1 2,2' -Oxybis(1-chloropropane) ND 5.0 ug/l91-58-7 2-Chloronaphthalene ND 5.0 ug/l218-01-9 Chrysene ND 0.20 ug/l53-70-3 Dibenzo(a,h)anthracene ND 0.20 ug/l132-64-9 Dibenzofuran ND 5.0 ug/l91-94-1 3,3' -Dichlorobenzidine ND 10 ug/l84-66-2 Diethyl Phthalate 0.068 5.0 ug/l J131-11-3 Dimethyl Phthalate ND 5.0 ug/l117-84-0 Di-n-octyl Phthalate ND 5.0 ug/l99-65-0 1,3-Dinitrobenzene ND 5.0 ug/l121-14-2 2,4-Dinitrotoluene ND 5.0 ug/l606-20-2 2,6-Dinitrotoluene ND 5.0 ug/l117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 ug/l206-44-0 Fluoranthene ND 0.20 ug/l

182 of 304

LA58344

66.1.2









183 of 304

LA58344

66.1.2


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15357-BS F0059500.D 1 10/17/19 SV 10/14/19 OP15357 EF2032OP15357-BSD F0059501.D 1 10/17/19 SV 10/14/19 OP15357 EF2032




95-57-8 2-Chlorophenol 2500 2400 96 2570 103 7 67-104/14120-83-2 2,4-Dichlorophenol 2500 2520 101 2630 106 4 70-106/15105-67-9 2,4-Dimethylphenol 2500 2110 84 2200 88 4 67-108/1551-28-5 2,4-Dinitrophenol 2500 2370 95 2430 98 3 49-119/23100-02-7 4-Nitrophenol 2500 2290 92 2280 92 0 55-123/1887-86-5 Pentachlorophenol 2500 2490 100 2510 101 1 61-106/20108-95-2 Phenol 2500 2390 96 2530 102 6 63-110/1458-90-2 2,3,4,6-Tetrachlorophenol 2500 2440 98 2440 98 0 65-115/1995-95-4 2,4,5-Trichlorophenol 2500 2730 109 2770 111 1 66-114/1788-06-2 2,4,6-Trichlorophenol 2500 2550 102 2610 105 2 66-112/1783-32-9 Acenaphthene 2500 2270 91 2310 93 2 68-102/15208-96-8 Acenaphthylene 2500 2440 98 2490 100 2 69-106/1562-53-3 Aniline 2500 2410 96 2530 102 5 64-110/16120-12-7 Anthracene 2500 2400 96 2400 96 0 70-105/1656-55-3 Benzo(a)anthracene 2500 2640 106* a 2630 106* a 0 66-102/1650-32-8 Benzo(a)pyrene 2500 2680 107 2680 108 0 69-110/16205-99-2 Benzo(b)fluoranthene 2500 2700 108 2680 108 1 66-109/1892-52-4 1,1' -Biphenyl 2500 2300 92 2360 95 3 67-104/15207-08-9 Benzo(k)fluoranthene 2500 2620 105 2620 105 0 68-110/1785-68-7 Butyl Benzyl Phthalate 2500 2560 102 2590 104 1 64-117/18106-47-8 4-Chloroaniline 2500 2020 81 2050 82 1 66-113/15111-44-4 bis(2-Chloroethyl)ether 2500 2350 94 2490 100 6 58-109/17108-60-1 2,2' -Oxybis(1-chloropropane) 2500 2120 85 2240 90 6 48-115/1691-58-7 2-Chloronaphthalene 2500 2280 91 2350 94 3 69-103/15218-01-9 Chrysene 2500 2550 102 2520 101 1 66-104/1653-70-3 Dibenzo(a,h)anthracene 2500 2810 112* a 2820 113* a 0 68-108/16132-64-9 Dibenzofuran 2500 2320 93 2380 96 3 68-103/1691-94-1 3,3' -Dichlorobenzidine 2500 2770 111 2760 111 0 64-116/1884-66-2 Diethyl Phthalate 2500 2400 96 2390 96 0 68-108/17131-11-3 Dimethyl Phthalate 2500 2410 96 2400 96 0 69-106/16117-84-0 Di-n-octyl Phthalate 2500 2360 94 2340 94 1 62-115/1899-65-0 1,3-Dinitrobenzene 2500 2320 93 2360 95 2 69-114/17121-14-2 2,4-Dinitrotoluene 2500 2480 99 2500 101 1 68-117/16606-20-2 2,6-Dinitrotoluene 2500 2350 94 2340 94 0 69-113/17117-81-7 bis(2-Ethylhexyl)phthalate 2500 2520 101 2520 101 0 63-116/19206-44-0 Fluoranthene 2500 2620 105 2640 106 1 70-108/17


184 of 304

LA58344

66.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15357-BS F0059500.D 1 10/17/19 SV 10/14/19 OP15357 EF2032OP15357-BSD F0059501.D 1 10/17/19 SV 10/14/19 OP15357 EF2032




86-73-7 Fluorene 2500 2350 94 2370 95 1 69-104/16118-74-1 Hexachlorobenzene 2500 2910 116* a 2950 119* a 1 68-107/1787-68-3 Hexachlorobutadiene 2500 2740 110* a 2910 117* a 6 64-107/1477-47-4 Hexachlorocyclopentadiene 2500 3100 124* b 3210 129* b 3 51-120/16193-39-5 Indeno(1,2,3-cd)pyrene 2500 2790 112* a 2800 113* a 0 68-108/1678-59-1 Isophorone 2500 2400 96 2470 99 3 65-111/1691-57-6 2-Methylnaphthalene 2500 2210 88 2300 92 4 70-102/1491-20-3 Naphthalene 2500 2250 90 2370 95 5 68-100/1488-74-4 2-Nitroaniline 2500 2320 93 2350 94 1 67-113/1799-09-2 3-Nitroaniline 2500 2350 94 2370 95 1 66-112/17100-01-6 4-Nitroaniline 2500 2270 91 2260 91 0 68-111/1798-95-3 Nitrobenzene 2500 2330 93 2460 99 5 68-106/14621-64-7 N-Nitroso-di-n-propylamine 2500 2470 99 2530 102 2 61-111/1686-30-6 N-Nitrosodiphenylamine 2500 2130 85 2160 87 1 69-106/1785-01-8 Phenanthrene 2500 2330 93 2380 96 2 68-101/16129-00-0 Pyrene 2500 2480 99 2470 99 0 67-107/1695-94-3 1,2,4,5-Tetrachlorobenzene 2500 2700 108* a 2760 111* a 2 65-106/15120-82-1 1,2,4-Trichlorobenzene 2500 2350 94 2510 101 7 67-104/14



(a) Outside laboratory control limits but within reasonable method acceptance limits.(b) Outside control limits biased high. Analyte not detected in associated samples.


185 of 304

LA58344

66.2.1






95-57-8 2-Chlorophenol 5 5.3 106 5.9 118 11 48-123/17120-83-2 2,4-Dichlorophenol 5 5.9 118 7.0 140* a 17 52-135/17105-67-9 2,4-Dimethylphenol 5 5.7 114 5.7 114 0 47-132/2151-28-5 2,4-Dinitrophenol 25 29.5 118 34.8 139 16 32-139/25100-02-7 4-Nitrophenol 25 23.1 92 23.6 94 2 15-105/2287-86-5 Pentachlorophenol 25 28.4 114 32.3 129 13 51-131/19108-95-2 Phenol 5 3.4 68 3.8 76 11 19-92/2358-90-2 2,3,4,6-Tetrachlorophenol 5 5.8 116 7.0 140* a 19 57-136/1995-95-4 2,4,5-Trichlorophenol 5 6.0 120 6.8 136 13 51-143/1788-06-2 2,4,6-Trichlorophenol 5 5.9 118 6.7 134* a 13 59-132/1983-32-9 Acenaphthene 5 5.1 102 5.4 108 6 50-120/16208-96-8 Acenaphthylene 5 5.0 100 2.1 42* b 82* c 48-126/1662-53-3 Aniline 5 0.080 2* b 0.075 2* b 6 10-112/50120-12-7 Anthracene 5 5.5 110 5.2 104 6 53-128/1656-55-3 Benzo(a)anthracene 5 5.5 110 5.9 118 7 54-129/1950-32-8 Benzo(a)pyrene 5 5.4 108 4.0 80 30* c 55-135/19205-99-2 Benzo(b)fluoranthene 5 5.7 114 6.8 136 18 54-139/23207-08-9 Benzo(k)fluoranthene 5 5.7 114 6.8 136* a 18 58-132/2292-52-4 1,1' -Biphenyl 5 5.2 104 5.8 116 11 44-127/1785-68-7 Butyl Benzyl Phthalate 5 6.2 124 6.2 124 0 63-141/20106-47-8 4-Chloroaniline 5 0.30 6* b ND 0* b 200* c 19-126/38111-44-4 bis(2-Chloroethyl)ether 5 5.4 108 6.0 120 11 45-123/17108-60-1 2,2' -Oxybis(1-chloropropane) 5 5.2 104 5.8 116 11 29-126/1791-58-7 2-Chloronaphthalene 5 5.2 104 5.8 116 11 44-123/20218-01-9 Chrysene 5 5.5 110 6.1 122 10 57-127/2053-70-3 Dibenzo(a,h)anthracene 5 5.9 118 7.0 140 17 58-141/21132-64-9 Dibenzofuran 5 5.3 106 6.0 120 12 48-126/1791-94-1 3,3' -Dichlorobenzidine 5 ND 0* b ND 0* b nc 10-188/4084-66-2 Diethyl Phthalate 5 5.4 108 5.9 118 9 54-133/17131-11-3 Dimethyl Phthalate 5 5.5 110 6.2 124 12 56-132/17117-84-0 Di-n-octyl Phthalate 5 5.7 114 7.0 140* a 20 66-139/2199-65-0 1,3-Dinitrobenzene 25 28.5 114 32.3 129 13 64-133/16121-14-2 2,4-Dinitrotoluene 5 6.0 120 6.6 132 10 67-132/20606-20-2 2,6-Dinitrotoluene 5 5.7 114 6.5 130 13 56-138/20117-81-7 bis(2-Ethylhexyl)phthalate 5 6.4 128 7.0 140 9 60-142/20206-44-0 Fluoranthene 5 5.6 112 5.7 114 2 57-133/18


186 of 304

LA58344

66.2.2






86-73-7 Fluorene 5 5.5 110 6.0 120 9 52-125/15118-74-1 Hexachlorobenzene 5 5.3 106 5.9 118 11 47-127/2187-68-3 Hexachlorobutadiene 5 5.5 110 5.5 110 0 14-121/3077-47-4 Hexachlorocyclopentadiene 5 1.3 26 1.6 32 21 10-114/31193-39-5 Indeno(1,2,3-cd)pyrene 5 5.7 114 6.6 132 15 58-142/1978-59-1 Isophorone 5 5.6 112 6.4 128 13 52-130/1891-57-6 2-Methylnaphthalene 5 5.6 112 6.3 126* a 12 43-123/1891-20-3 Naphthalene 5 5.5 110 5.9 118 7 45-120/1688-74-4 2-Nitroaniline 25 27.4 110 1.5 6* b 179* c 63-132/1799-09-2 3-Nitroaniline 25 1.4 6* b ND 0* b 200* c 31-144/23100-01-6 4-Nitroaniline 25 14.5 58 0.84 3* b 178* c 22-154/2598-95-3 Nitrobenzene 5 6.2 124 6.7 134* a 8 52-128/17621-64-7 N-Nitroso-di-n-propylamine 5 5.3 106 6.1 122 14 48-129/2086-30-6 N-Nitrosodiphenylamine 5 2.5 50 0.13 3* b 180* c 26-146/2885-01-8 Phenanthrene 5 5.4 108 5.8 116 7 54-124/17129-00-0 Pyrene 5 5.6 112 2.8 56 67* c 56-132/1995-94-3 1,2,4,5-Tetrachlorobenzene 5 5.0 100 5.4 108 8 33-121/24120-82-1 1,2,4-Trichlorobenzene 5 5.3 106 5.6 112 6 34-118/23



(a) Outside control limits biased high. Analyte not detected in associated samples.(b) Outside control limits biased low. Unable to re-extract associated samples due to expired sample holding

time.(c) Analytical precision exceeds laboratory control limits.


187 of 304

LA58344

66.2.2






95-57-8 2-Chlorophenol ND 4.63 4.4 95 47-126120-83-2 2,4-Dichlorophenol ND 4.63 5.2 112 49-137105-67-9 2,4-Dimethylphenol ND 4.63 4.7 102 49-12351-28-5 2,4-Dinitrophenol ND 23.1 25.8 111 37-146100-02-7 4-Nitrophenol ND 23.1 17.2 74 19-9787-86-5 Pentachlorophenol ND 23.1 25.2 109 46-146108-95-2 Phenol 0.045 4.63 2.5 53 20-8758-90-2 2,3,4,6-Tetrachlorophenol ND 4.63 5.5 119 61-13795-95-4 2,4,5-Trichlorophenol ND 4.63 5.5 119 61-13388-06-2 2,4,6-Trichlorophenol ND 4.63 5.3 114 61-13383-32-9 Acenaphthene ND 4.63 4.5 97 43-122208-96-8 Acenaphthylene ND 4.63 4.6 99 48-12162-53-3 Aniline ND 4.63 0.057 1* a 10-110120-12-7 Anthracene ND 4.63 4.9 106 46-13756-55-3 Benzo(a)anthracene ND 4.63 4.9 106 54-13050-32-8 Benzo(a)pyrene ND 4.63 5.0 108 60-129205-99-2 Benzo(b)fluoranthene ND 4.63 5.1 110 56-136207-08-9 Benzo(k)fluoranthene ND 4.63 5.1 110 53-13892-52-4 1,1' -Biphenyl ND 4.63 4.2 91 40-12685-68-7 Butyl Benzyl Phthalate ND 4.63 5.9 127 63-144106-47-8 4-Chloroaniline ND 4.63 1.5 32 10-122111-44-4 bis(2-Chloroethyl)ether ND 4.63 4.5 97 30-135108-60-1 2,2' -Oxybis(1-chloropropane) ND 4.63 4.3 93 22-13091-58-7 2-Chloronaphthalene ND 4.63 4.2 91 43-117218-01-9 Chrysene ND 4.63 4.7 102 57-12653-70-3 Dibenzo(a,h)anthracene ND 4.63 5.2 112 51-142132-64-9 Dibenzofuran ND 4.63 4.6 99 34-14291-94-1 3,3' -Dichlorobenzidine ND 4.63 6.4 138* a 10-12684-66-2 Diethyl Phthalate 0.30 4.63 5.4 110 53-130131-11-3 Dimethyl Phthalate 0.028 4.63 5.2 112 53-134117-84-0 Di-n-octyl Phthalate 1.9 4.63 5.0 67 62-14299-65-0 1,3-Dinitrobenzene ND 23.1 27.1 117 60-132121-14-2 2,4-Dinitrotoluene ND 4.63 5.5 119 65-132606-20-2 2,6-Dinitrotoluene 0.039 4.63 5.4 116 60-130117-81-7 bis(2-Ethylhexyl)phthalate ND 4.63 5.8 125 52-152206-44-0 Fluoranthene ND 4.63 5.1 110 46-144


188 of 304

LA58344

66.3.1






86-73-7 Fluorene ND 4.63 4.8 104 50-122118-74-1 Hexachlorobenzene ND 4.63 3.9 84 34-13287-68-3 Hexachlorobutadiene ND 4.63 3.0 65 13-11077-47-4 Hexachlorocyclopentadiene ND 4.63 0.82 18 10-100193-39-5 Indeno(1,2,3-cd)pyrene ND 4.63 5.1 110 54-13978-59-1 Isophorone ND 4.63 5.0 108 54-12591-57-6 2-Methylnaphthalene ND 4.63 4.2 91 39-12191-20-3 Naphthalene 0.018 4.63 4.1 88 39-12288-74-4 2-Nitroaniline ND 23.1 27.2 118 59-13399-09-2 3-Nitroaniline ND 23.1 28.0 121 17-135100-01-6 4-Nitroaniline ND 23.1 31.7 137* a 12-13398-95-3 Nitrobenzene ND 4.63 5.4 117 44-141621-64-7 N-Nitroso-di-n-propylamine ND 4.63 4.7 102 37-13986-30-6 N-Nitrosodiphenylamine ND 4.63 4.2 91 38-13485-01-8 Phenanthrene 0.014 4.63 4.8 103 37-135129-00-0 Pyrene 0.0091 4.63 5.2 112 44-14295-94-3 1,2,4,5-Tetrachlorobenzene ND 4.63 3.4 73 30-114120-82-1 1,2,4-Trichlorobenzene ND 4.63 3.5 76 30-114





189 of 304

LA58344

66.3.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15357-MS F0059540.D 1 10/18/19 SV 10/14/19 OP15357 EF2033OP15357-MSD F0059541.D 1 10/18/19 SV 10/14/19 OP15357 EF2033LA58344-4 F0059543.D 1 10/18/19 SV 10/14/19 OP15357 EF2033




95-57-8 2-Chlorophenol ND 2460 2170 88 2480 2350 95 8 47-110/30120-83-2 2,4-Dichlorophenol ND 2460 2230 91 2480 2370 96 6 44-121/32105-67-9 2,4-Dimethylphenol ND 2460 1760 71 2480 1890 76 7 41-122/3151-28-5 2,4-Dinitrophenol ND 2460 1650 67 2480 1620 65 2 10-116/42100-02-7 4-Nitrophenol ND 2460 2000 81 2480 2130 86 6 31-127/3787-86-5 Pentachlorophenol ND 2460 2220 90 2480 2370 96 7 28-113/37108-95-2 Phenol ND 2460 2120 86 2480 2280 92 7 44-113/3358-90-2 2,3,4,6-Tetrachlorophenol ND 2460 2120 86 2480 2310 93 9 38-122/3495-95-4 2,4,5-Trichlorophenol ND 2460 2380 97 2480 2590 105 8 46-118/3388-06-2 2,4,6-Trichlorophenol ND 2460 2220 90 2480 2360 95 6 50-112/3283-32-9 Acenaphthene ND 2460 1980 80 2480 2140 86 8 41-115/32208-96-8 Acenaphthylene ND 2460 2130 86 2480 2300 93 8 47-113/3162-53-3 Aniline ND 2460 2020 82 2480 2340 95 15 35-120/30120-12-7 Anthracene ND 2460 2090 85 2480 2210 89 6 48-111/3656-55-3 Benzo(a)anthracene 6.3 2460 2280 92 2480 2420 98 6 47-106/3350-32-8 Benzo(a)pyrene ND 2460 2320 94 2480 2460 99 6 49-115/32205-99-2 Benzo(b)fluoranthene ND 2460 2230 91 2480 2470 100 10 45-114/3592-52-4 1,1' -Biphenyl ND 2460 1980 80 2480 2140 86 8 48-109/33207-08-9 Benzo(k)fluoranthene ND 2460 2420 98 2480 2410 97 0 47-114/2485-68-7 Butyl Benzyl Phthalate ND 2460 2210 90 2480 2360 95 7 43-123/35106-47-8 4-Chloroaniline ND 2460 1770 72 2480 1890 76 7 40-122/39111-44-4 bis(2-Chloroethyl)ether ND 2460 2170 88 2480 2350 95 8 39-117/37108-60-1 2,2' -Oxybis(1-chloropropane) ND 2460 1970 80 2480 2100 85 6 30-118/3191-58-7 2-Chloronaphthalene ND 2460 1980 80 2480 2120 86 7 50-108/33218-01-9 Chrysene ND 2460 2180 89 2480 2320 94 6 47-109/3553-70-3 Dibenzo(a,h)anthracene ND 2460 2250 91 2480 2390 97 6 48-112/23132-64-9 Dibenzofuran ND 2460 2020 82 2480 2160 87 7 47-110/3591-94-1 3,3' -Dichlorobenzidine ND 2460 2350 95 2480 2630 106 11 32-124/4184-66-2 Diethyl Phthalate ND 2460 2090 85 2480 2230 90 6 52-110/34131-11-3 Dimethyl Phthalate ND 2460 2050 83 2480 2220 90 8 52-108/34117-84-0 Di-n-octyl Phthalate ND 2460 1980 80 2480 2150 87 8 43-120/2799-65-0 1,3-Dinitrobenzene ND 2460 2100 85 2480 2260 91 7 51-116/38121-14-2 2,4-Dinitrotoluene ND 2460 2190 89 2480 2360 95 7 46-122/36606-20-2 2,6-Dinitrotoluene ND 2460 2080 84 2480 2220 90 7 50-117/35117-81-7 bis(2-Ethylhexyl)phthalate ND 2460 2160 88 2480 2300 93 6 45-119/28206-44-0 Fluoranthene ND 2460 2250 91 2480 2400 97 6 47-118/34


190 of 304

LA58344

66.4.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15357-MS F0059540.D 1 10/18/19 SV 10/14/19 OP15357 EF2033OP15357-MSD F0059541.D 1 10/18/19 SV 10/14/19 OP15357 EF2033LA58344-4 F0059543.D 1 10/18/19 SV 10/14/19 OP15357 EF2033




86-73-7 Fluorene ND 2460 2040 83 2480 2170 88 6 37-121/33118-74-1 Hexachlorobenzene ND 2460 2500 101 2480 2670 108 7 49-111/3887-68-3 Hexachlorobutadiene ND 2460 2420 98 2480 2550 103 5 45-112/3377-47-4 Hexachlorocyclopentadiene ND 2460 2860 116 2480 3070 124 7 17-125/35193-39-5 Indeno(1,2,3-cd)pyrene ND 2460 2270 92 2480 2380 96 5 47-113/3178-59-1 Isophorone ND 2460 2190 89 2480 2300 93 5 41-125/3491-57-6 2-Methylnaphthalene ND 2460 2010 82 2480 2120 86 5 44-117/3891-20-3 Naphthalene ND 2460 2040 83 2480 2170 88 6 34-125/3788-74-4 2-Nitroaniline ND 2460 2090 85 2480 2260 91 8 51-116/3399-09-2 3-Nitroaniline ND 2460 2090 85 2480 2250 91 7 48-117/32100-01-6 4-Nitroaniline ND 2460 1960 80 2480 2100 85 7 43-120/3498-95-3 Nitrobenzene ND 2460 2140 87 2480 2250 91 5 39-124/32621-64-7 N-Nitroso-di-n-propylamine ND 2460 2290 93 2480 2480 100 8 36-127/3286-30-6 N-Nitrosodiphenylamine ND 2460 1840 75 2480 1970 80 7 50-112/3485-01-8 Phenanthrene 1.7 2460 2030 82 2480 2150 87 6 43-111/41129-00-0 Pyrene ND 2460 2160 88 2480 2300 93 6 42-120/3895-94-3 1,2,4,5-Tetrachlorobenzene ND 2460 2270 92 2480 2440 99 7 48-108/33120-82-1 1,2,4-Trichlorobenzene ND 2460 2110 86 2480 2240 90 6 44-113/32




191 of 304

LA58344

66.4.1


GC Volatiles

QC Data Summaries



Scott, LASection 7

192 of 304

LA58344

7




LA58344-16


Aliphatics > C8-C10 (Unadj.) 7.9 50 ug/l JAromatics > C8-C10 (Unadj.) 8.6 50 ug/l J




193 of 304

LA58344

77.1.1




LA58344-16


Aliphatics C6-C8 (Unadj.) ND 30 ug/l




194 of 304

LA58344

77.1.2




LA58344-1





195 of 304

LA58344

77.1.3




LA58344-2





196 of 304

LA58344

77.1.4









197 of 304

LA58344

77.1.5




LA58344-3, LA58344-5, LA58344-6, LA58344-8





198 of 304

LA58344

77.1.6




LA58344-16





199 of 304

LA58344

77.1.7




LA58344-4





200 of 304

LA58344

77.1.8




LA58344-7





201 of 304

LA58344

77.1.9




LA58344-16


Aliphatics > C8-C10 (Unadj.) 250 276 110 260 104 6 70-130/30Aromatics > C8-C10 (Unadj.) 250 269 108 251 100 7 70-130/30





202 of 304

LA58344

77.2.1




LA58344-16


Aliphatics C6-C8 (Unadj.) 150 150 100 156 104 4 70-130/30





203 of 304

LA58344

77.2.2




LA58344-1


TPH-GRO (C6-C10) 50 49.0 98 48.7 97 1 79-121/6




204 of 304

LA58344

77.2.3






TPH-GRO (C6-C10) 1 0.954 95 0.962 96 1 81-119/10




205 of 304

LA58344

77.2.4




LA58344-2


TPH-GRO (C6-C10) 50 45.2 90 46.6 93 3 79-121/6




206 of 304

LA58344

77.2.5




LA58344-16


TPH-GRO (C6-C10) 1 0.872 87 0.885 89 1 81-119/10




207 of 304

LA58344

77.2.6




LA58344-3, LA58344-5, LA58344-6, LA58344-8


TPH-GRO (C6-C10) 50 45.4 91 44.2 88 3 79-121/6




208 of 304

LA58344

77.2.7




LA58344-4


TPH-GRO (C6-C10) 50 45.4 91 45.3 91 0 79-121/6




209 of 304

LA58344

77.2.8




LA58344-7


TPH-GRO (C6-C10) 50 48.4 97 49.2 98 2 79-121/6




210 of 304

LA58344

77.2.9




LA58344-16


Aliphatics > C8-C10 (Unadj.) 137 5000 5190 101 5000 5280 103 2 70-130/50Aromatics > C8-C10 (Unadj.) 106 5000 5430 106 5000 5220 102 4 70-130/50





211 of 304

LA58344

77.3.1




LA58344-16


Aliphatics C6-C8 (Unadj.) 5410 3000 6690 43* a 3000 6540 38* a 2 70-130/50


615-59-8 2,5-Dibromotoluene 96% b 96% b 101% b 70-130%615-59-8 2,5-Dibromotoluene 91% c 91% c 102% c 70-130%

(a) Outside control limits due to high level in sample relative to spike amount.(b) Recovery from Aliphatics fraction.(c) Recovery from Aromatics fraction.


212 of 304

LA58344

77.3.2




LA58344-1


TPH-GRO (C6-C10) ND 47.2 40.6 86 47.2 40.6 86 0 79-121/6




213 of 304

LA58344

77.3.3




LA58344-17


TPH-GRO (C6-C10) ND 20 17.9 90 20 17.5 88 2 40-149/10




214 of 304

LA58344

77.3.4




LA58344-2


TPH-GRO (C6-C10) 32.3 500 438 81 500 433 80 1 79-121/6





215 of 304

LA58344

77.3.5




LA58344-3, LA58344-5, LA58344-6, LA58344-8


TPH-GRO (C6-C10) 1010 E 500 1290 56* b 500 1300 58* b 1 79-121/6


460-00-4 4-Bromofluorobenzene 92% 92% 81% 63-139%540-36-3 1,4-Difluorobenzene 99% 99% 220%* c 52-140%

(a) Sample used for QC purposes only.(b) Outside control limits due to high level in sample relative to spike amount.(c) Confirmed by MS/MSD.


216 of 304

LA58344

77.3.6




LA58344-16


TPH-GRO (C6-C10) 4.91 20 20.7 79 20 21.0 80 1 40-149/10



(a) Sample was diluted due to high sediment.


217 of 304

LA58344

77.3.7




LA58344-9, LA58344-10, LA58344-11, LA58344-12, LA58344-13, LA58344-14, LA58344-15


TPH-GRO (C6-C10) ND 2 1.66 83 2 1.62 81 2 40-149/10




218 of 304

LA58344

77.3.8




LA58344-4


TPH-GRO (C6-C10) ND 51 48.9 96 51 48.5 95 1 79-121/6




219 of 304

LA58344

77.3.9




LA58344-7


TPH-GRO (C6-C10) ND 532 433 81 532 414 78* a 4 79-121/6





220 of 304

LA58344

77.3.10



QC Data Summaries



Scott, LASection 8

221 of 304

LA58344

8


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-MB X0012233.D 1 10/19/19 LS 10/17/19 OP15390 GLB2101


LA58344-16


Aromatics > C10-C12 (Unadj.))ND 140 ug/lAromatics > C12-C16 (Unadj.))ND 140 ug/lAromatics > C16-C21 (Unadj.))ND 140 ug/lAromatics > C21-C35 (Unadj.))ND 140 ug/l


84-15-1 o-Terphenyl 91% 40-140%321-60-8 2-Fluorobiphenyl 84% 40-140%

222 of 304

LA58344

88.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-MB Y0012233.D 1 10/19/19 LS 10/17/19 OP15390 GLB2102


LA58344-16


Aliphatics > C10-C12 (Unadj.)) ND 140 ug/lAliphatics > C12-C16 (Unadj.)) ND 140 ug/lAliphatics > C16-C35 (Unadj.)) ND 140 ug/l


3386-33-2 1-Chlorooctadecane 89% 40-140%

223 of 304

LA58344

88.1.2








84-15-1 o-Terphenyl 96% 40-118%

224 of 304

LA58344

88.1.3






TPH-DRO (C10-C28) 0.587 4.9 mg/kg JTPH-ORO (C28-C35) ND 4.9 mg/kg


84-15-1 o-Terphenyl 89% 31-127%

225 of 304

LA58344

88.1.4


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-BS X0012234.D 1 10/19/19 LS 10/17/19 OP15390 GLB2101OP15390-BSD X0012235.D 1 10/19/19 LS 10/17/19 OP15390 GLB2101


LA58344-16


Aromatics > C10-C12 (Unadj.)461 371 80 366 79 1 40-140/30Aromatics > C12-C16 (Unadj.)1380 1080 78 1060 76 2 40-140/30Aromatics > C16-C21 (Unadj.)2310 1780 77 1780 77 0 40-140/30Aromatics > C21-C35 (Unadj.)3690 3340 91 3320 90 1 40-140/30


84-15-1 o-Terphenyl 82% 82% 40-140%321-60-8 2-Fluorobiphenyl 81% 77% 40-140%


226 of 304

LA58344

88.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP15390-BS Y0012234.D 1 10/19/19 LS 10/17/19 OP15390 GLB2102OP15390-BSD Y0012235.D 1 10/19/19 LS 10/17/19 OP15390 GLB2102


LA58344-16


Aliphatics > C10-C12 (Unadj.) 461 271 59 345 75 24 40-140/30Aliphatics > C12-C16 (Unadj.) 923 538 58 688 74 24 40-140/30Aliphatics > C16-C35 (Unadj.) 4150 2270 55 2970 71 27 40-140/30


3386-33-2 1-Chlorooctadecane 61% 79% 40-140%


227 of 304

LA58344

88.2.2






TPH-DRO (C10-C28) 11.1 9.40 85 9.87 89 5 72-112/18


84-15-1 o-Terphenyl 95% 99% 40-118%


228 of 304

LA58344

88.2.3






TPH-ORO (C28-C35) 4.48 8.15 182* a 8.10 182* a 1 60-112/18


84-15-1 o-Terphenyl 95% 94% 40-118%



229 of 304

LA58344

88.2.4






TPH-DRO (C10-C28) 150 172 115 157 105 9 49-118/19


84-15-1 o-Terphenyl 110% 101% 31-127%


230 of 304

LA58344

88.2.5






TPH-ORO (C28-C35) 60 47.7 80 47.7 80 0 52-102/16


84-15-1 o-Terphenyl 93% 94% 31-127%


231 of 304

LA58344

88.2.6






TPH-DRO (C10-C28) ND 11.2 9.66 86 11 9.34 85 3 41-136/29


84-15-1 o-Terphenyl 95% 94% 98% 40-118%


232 of 304

LA58344

88.3.1






TPH-ORO (C28-C35) ND 4.49 17.4 194* a 4.44 8.26 186* b 4 c 20-135/18


84-15-1 o-Terphenyl 104% 101% 98% 40-118%



233 of 304

LA58344

88.3.2






TPH-DRO (C10-C28) 0.641 149 150 100 148 104 70 36* a 23-150/28


84-15-1 o-Terphenyl 99% 73% 68% 31-127%

(a) High RPD. Both the BS and BSD meet recovery criteria.


234 of 304

LA58344

88.3.3






TPH-ORO (C28-C35) ND 59.7 41.5 70 60 46.2 77 11 16-142/35


84-15-1 o-Terphenyl 80% 94% 68% 31-127%


235 of 304

LA58344

88.3.4


Metals Analysis

QC Data Summaries



Scott, LASection 9

236 of 304

LA58344

9





Prep Date: 10/10/19

MB

10/10/19


Mercury 0.20 .056 .081 -0.039 <0.20

Associated samples MP16573: LA58344-9, LA58344-10, LA58344-11, LA58344-12, LA58344-13, LA58344-14,LA58344-15, LA58344-16, LA58344-17


_________________________________________________________________________________________________________

Page 1

237 of 304

LA58344

99.1.1





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Mercury 0.0 5.6 5 112.0 75-125



_________________________________________________________________________________________________________

Page 1

238 of 304

LA58344

99.1.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Mercury 0.0 5.8 5 116.0 3.5 20



_________________________________________________________________________________________________________

Page 2

239 of 304

LA58344

99.1.2





Prep Date: 10/10/19

BSP Spikelot

10/10/19


Mercury 5.0 5 100.0 80-120



_________________________________________________________________________________________________________

Page 1

240 of 304

LA58344

99.1.3





Prep Date: 10/10/19

LA58344-14

10/10/19


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

Page 1

241 of 304

LA58344

99.1.4





Prep Date: 10/10/19

MB

10/10/19


Mercury 0.080 .0039 .0066 -0.0019 <0.080

Associated samples MP16578: LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-7,LA58344-8


_________________________________________________________________________________________________________

Page 1

242 of 304

LA58344

99.2.1





Prep Date: 10/10/19

LA58344-4 Spikelot

10/10/19


Mercury 0.0 0.59 0.577 102.3 75-125



_________________________________________________________________________________________________________

Page 1

243 of 304

LA58344

99.2.2





Prep Date: 10/10/19

LA58344-4 Spikelot

10/10/19


Mercury 0.0 0.57 0.6 95.0 3.4 20



_________________________________________________________________________________________________________

Page 2

244 of 304

LA58344

99.2.2





Prep Date: 10/10/19

LCS Spikelot

10/10/19

QCMetal Result HGLCS10 % Rec Limits

Mercury 16.8 20.3 82.8 64-136



_________________________________________________________________________________________________________

Page 1

245 of 304

LA58344

99.2.3




QC Batch ID: MP16578 Methods: SW846 7471B Matrix Type: SOLID Units: ug/l

Prep Date: 10/10/19

LA58344-4

10/10/19


Mercury 0.00 0.252 NC 0-



_________________________________________________________________________________________________________

Page 1

246 of 304

LA58344

99.2.4





Prep Date: 10/10/19

MB

10/10/19



Antimony 1.0 .0063 .34 0.025 <1.0

Arsenic 1.0 .062 .26 0.19 <1.0

Barium 1.0 .0089 .46 -0.0043 <1.0

Beryllium 1.0 .0096 .28 -0.21 <1.0

Boron 20 1.5 2.9

Cadmium 0.50 .0081 .12 0.029 <0.50

Calcium 100 4.7 20

Cerium 1.0 .0019 .16

Chromium 1.0 .059 .15 -0.071 <1.0

Cobalt 1.0 .0082 .14 -0.15 <1.0

Copper 1.0 .27 .74 -0.24 <1.0

Iron 100 2.8 16

Lanthanum 1.0 .0019 .41

Lithium 2.0 .3 .61

Lead 1.0 .0045 .13 -0.085 <1.0




Nickel 1.0 .081 .2 -0.091 <1.0

Potassium 100 5 7.6

Selenium 5.0 .3 3.1 -0.15 <5.0

Silver 1.0 .0088 .13 -0.044 <1.0

Silicon 500 7.6 130

Sodium 100 8.6 9.9


Thallium 1.0 .03 .86 -0.11 <1.0

Tin 2.0 .059 .19

Titanium 1.0 .095 .77

Uranium 1.0 .0019 .17

Vanadium 1.0 .035 .1 0.11 <1.0

Zinc 5.0 1.5 1.1 -1.2 <5.0

Associated samples MP16584: LA58344-9, LA58344-10, LA58344-11, LA58344-12, LA58344-13, LA58344-14,LA58344-15, LA58344-16, LA58344-17_________________________________________________________________________________________________________

Page 1

247 of 304

LA58344

99.3.1





Prep Date: 10/10/19

MB

10/10/19



_________________________________________________________________________________________________________

Page 2

248 of 304

LA58344

99.3.1





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Aluminum anr

Antimony 0.28 97.1 100 96.8 75-125

Arsenic 3.1 91.4 100 88.3 75-125

Barium 292 431 100 139.0N(a 75-125

Beryllium 0.0 83.5 100 83.5 75-125

Boron

Cadmium 0.43 96.0 100 95.6 75-125

Calcium anr

Cerium

Chromium 3.9 106 100 102.1 75-125

Cobalt 4.4 108 100 103.6 75-125

Copper 3.7 92.3 100 88.6 75-125

Iron anr

Lanthanum

Lithium anr

Lead 2.2 97.1 100 94.9 75-125

Magnesium anr

Manganese anr

Molybdenum

Nickel 5.7 99.6 100 93.9 75-125

Potassium anr

Selenium 4.0 395 500 78.2 75-125

Silver 0.0 101 100 101.0 75-125

Silicon

Sodium anr

Strontium anr

Thallium 0.087 96.0 100 95.9 75-125

Tin

Titanium

Uranium

Vanadium 7.0 107 100 100.0 75-125

Zinc 11.7 95.8 100 84.1 75-125


Page 1

249 of 304

LA58344

99.3.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19



_________________________________________________________________________________________________________

Page 2

250 of 304

LA58344

99.3.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19


Aluminum anr

Antimony 0.28 95.4 100 95.1 1.8 20

Arsenic 3.1 93.1 100 90.0 1.8 20

Barium 292 416 100 124.0 3.5 20

Beryllium 0.0 82.6 100 82.6 1.1 20

Boron

Cadmium 0.43 97.8 100 97.4 1.9 20

Calcium anr

Cerium

Chromium 3.9 109 100 105.1 2.8 20

Cobalt 4.4 110 100 105.6 1.8 20

Copper 3.7 93.9 100 90.2 1.7 20

Iron anr

Lanthanum

Lithium anr

Lead 2.2 96.4 100 94.2 0.7 20

Magnesium anr

Manganese anr

Molybdenum

Nickel 5.7 102 100 96.3 2.4 20

Potassium anr

Selenium 4.0 405 500 80.2 2.5 20

Silver 0.0 103 100 103.0 2.0 20

Silicon

Sodium anr

Strontium anr

Thallium 0.087 98.0 100 97.9 2.1 20

Tin

Titanium

Uranium

Vanadium 7.0 111 100 104.0 3.7 20

Zinc 11.7 98.1 100 86.4 2.4 20


Page 3

251 of 304

LA58344

99.3.2





Prep Date: 10/10/19

LA58344-14 Spikelot

10/10/19



_________________________________________________________________________________________________________

Page 4

252 of 304

LA58344

99.3.2





Prep Date: 10/10/19

BSP Spikelot

10/10/19


Aluminum anr

Antimony 105 100 105.0 80-120

Arsenic 99.5 100 99.5 80-120

Barium 102 100 102.0 80-120

Beryllium 91.5 100 91.5 80-120

Boron

Cadmium 104 100 104.0 80-120

Calcium anr

Cerium

Chromium 112 100 112.0 80-120

Cobalt 113 100 113.0 80-120

Copper 103 100 103.0 80-120

Iron anr

Lanthanum

Lithium anr

Lead 106 100 106.0 80-120

Magnesium anr

Manganese anr

Molybdenum

Nickel 108 100 108.0 80-120

Potassium anr

Selenium 459 500 91.8 80-120

Silver 98.3 100 98.3 80-120

Silicon

Sodium anr

Strontium anr

Thallium 106 100 106.0 80-120

Tin

Titanium

Uranium

Vanadium 109 100 109.0 80-120

Zinc 108 100 108.0 80-120


Page 1

253 of 304

LA58344

99.3.3





Prep Date: 10/10/19

BSP Spikelot

10/10/19



_________________________________________________________________________________________________________

Page 2

254 of 304

LA58344

99.3.3





Prep Date: 10/10/19

LA58344-14

10/10/19


Aluminum anr

Antimony 0.277 0.470 69.6 (a) 0-10

Arsenic 3.10 3.90 25.8 (a) 0-10

Barium 292 289 1.2 0-10


Boron

Cadmium 0.433 0.529 22.1*(b) 0-10

Calcium anr

Cerium

Chromium 3.91 4.41 12.9*(b) 0-10

Cobalt 4.42 3.89 12.1*(b) 0-10

Copper 3.71 3.05 17.6 (a) 0-10

Iron anr

Lanthanum

Lithium anr

Lead 2.16 1.88 13.1*(b) 0-10

Magnesium anr

Manganese anr

Molybdenum

Nickel 5.72 5.52 3.6 0-10

Potassium anr

Selenium 3.98 4.07 2.2 0-10

Silver 0.00 0.00 NC 0-10

Silicon

Sodium anr

Strontium anr

Thallium 0.0875 0.00 100.0(a) 0-10

Tin

Titanium

Uranium

Vanadium 6.95 7.11 2.2 0-10

Zinc 11.7 17.6 50.4 (a) 0-10


Page 1

255 of 304

LA58344

99.3.4





Prep Date: 10/10/19

LA58344-14

10/10/19



_________________________________________________________________________________________________________

Page 2

256 of 304

LA58344

99.3.4





Prep Date: 10/10/19


10/10/19


Barium 2 10 292.1 58.42 152 0.1 10 100 93.6 75-125

Boron

Cerium

Lanthanum

Molybdenum

Silicon

Tin

Titanium

Uranium



_________________________________________________________________________________________________________

Page 1

257 of 304

LA58344

99.3.5





Prep Date: 10/10/19

MB

10/10/19


Aluminum 10 .14 5.2

Antimony 0.10 .00063 .094 0.0050 <0.10

Arsenic 0.10 .0062 .042 0.015 <0.10

Barium 0.10 .00089 .046 -0.0011 <0.10

Beryllium 0.10 .00096 .045 -0.022 <0.10

Boron 2.0 .15 .16

Cadmium 0.050 .00081 .033 0.0034 <0.050

Calcium 10 .47 3.7

Cerium 0.10 .00019 .057

Chromium 0.10 .0059 .043 -0.0069 <0.10

Cobalt 0.10 .00082 .046 -0.017 <0.10

Copper 0.10 .027 .048 -0.024 <0.10

Iron 10 .28 4.1

Lanthanum 0.10 .00019 .042

Lithium 0.20 .03 .052

Lead 0.10 .00045 .046 -0.0085 <0.10

Magnesium 10 .11 1.5

Manganese 0.10 .01 .046


Nickel 0.10 .0081 .036 -0.0059 <0.10

Potassium 10 .5 4

Selenium 0.50 .03 .17 -0.022 <0.50

Silver 0.10 .00088 .033 -0.0043 <0.10

Silicon 50 .76 12

Sodium 10 .86 3.2

Strontium 0.10 .0063 .042

Thallium 0.10 .003 .062 -0.010 <0.10

Tin 0.50 .0059 .19

Titanium 0.20 .0095 .15

Vanadium 0.10 .0035 .04 0.011 <0.10

Uranium 0.10 .00019 .047

Zinc 0.50 .15 .13 -0.11 <0.50

Associated samples MP16586: LA58344-1, LA58344-2, LA58344-3, LA58344-4, LA58344-5, LA58344-6, LA58344-7,LA58344-8_________________________________________________________________________________________________________

Page 1

258 of 304

LA58344

99.4.1





Prep Date: 10/10/19

MB

10/10/19



_________________________________________________________________________________________________________

Page 2

259 of 304

LA58344

99.4.1





Prep Date: 10/10/19

LA58344-4 Spikelot

10/10/19


Aluminum

Antimony 0.32 8.0 10 76.8 75-125

Arsenic 6.2 15.6 10 94.0 75-125

Barium 134 321 10 1870.0(a 75-125

Beryllium 0.38 8.8 10 84.2 75-125

Boron

Cadmium 0.052 10.6 10 105.5 75-125

Calcium

Cerium

Chromium 15.7 34.7 10 190.0N(b 75-125

Cobalt 2.3 15.7 10 134.0N(b 75-125

Copper 13.3 36.5 10 232.0N(b 75-125

Iron

Lanthanum

Lithium

Lead 5.9 17.3 10 114.0 75-125

Magnesium

Manganese

Molybdenum

Nickel 13.5 32.3 10 188.0N(b 75-125

Potassium

Selenium 2.6 40.5 50 75.8 75-125

Silver 0.0 10.6 10 106.0 75-125

Silicon anr

Sodium

Strontium

Thallium 0.26 10.8 10 105.4 75-125

Tin

Titanium

Vanadium 23.5 45.8 10 223.0N(b 75-125

Uranium

Zinc 38.8 60.5 10 217.0N(b 75-125


Page 1

260 of 304

LA58344

99.4.2





Prep Date: 10/10/19

LA58344-4 Spikelot

10/10/19



information.(b) Spike recovery indicates possible matrix interference or sample non-homogeneity.

_________________________________________________________________________________________________________

Page 2

261 of 304

LA58344

99.4.2





Prep Date: 10/10/19

LA58344-4 Spikelot

10/10/19


Aluminum

Antimony 0.32 7.6 10 72.8N(a) 5.1 20

Arsenic 6.2 17.1 10 109.0 9.2 20

Barium 134 369 10 2350.0(b 13.9 20

Beryllium 0.38 9.8 10 94.2 10.8 20

Boron

Cadmium 0.052 10.5 10 104.5 0.9 20

Calcium

Cerium

Chromium 15.7 35.4 10 197.0N(a 2.0 20

Cobalt 2.3 14.3 10 120.0 9.3 20

Copper 13.3 31.1 10 178.0N(a 16.0 20

Iron

Lanthanum

Lithium

Lead 5.9 17.7 10 118.0 2.3 20

Magnesium

Manganese

Molybdenum

Nickel 13.5 29.9 10 164.0N(a 7.7 20

Potassium

Selenium 2.6 40.6 50 76.0 0.2 20

Silver 0.0 10.4 10 104.0 1.9 20

Silicon anr

Sodium

Strontium

Thallium 0.26 10.6 10 103.4 1.9 20

Tin

Titanium

Vanadium 23.5 52.1 10 286.0N(a 12.9 20

Uranium

Zinc 38.8 57.5 10 187.0N(a 5.1 20


Page 3

262 of 304

LA58344

99.4.2





Prep Date: 10/10/19

LA58344-4 Spikelot

10/10/19



information.

_________________________________________________________________________________________________________

Page 4

263 of 304

LA58344

99.4.2





Prep Date: 10/10/19 10/10/19

BSP Spikelot

10/10/19

QC LCS Spikelot

10/10/19

QCMetal Result MPICPMS6 % Rec Limits Result LCSMETAL11% Rec Limits

Aluminum

Antimony 47.6 40 119.0 22-208

Arsenic 112 125 89.6 82-117

Barium 614 529 116.1 82-119

Beryllium 148 155 95.5 83-117

Boron

Cadmium 43.7 37.7 115.9 82-118

Calcium

Cerium

Chromium 60.9 58.3 104.5 82-118

Cobalt 211 196 107.7 84-117

Copper 76.7 78 98.3 84-116

Iron

Lanthanum

Lithium

Lead 108 111 97.3 82-117

Magnesium

Manganese

Molybdenum

Nickel 331 333 99.4 83-117

Potassium

Selenium 236 251 94.0 79-122

Silver 27.0 27.2 99.3 79-121

Silicon anr

Sodium

Strontium

Thallium 276 241 114.5 80-119

Tin

Titanium

Vanadium 128 125 102.4 79-121

Uranium

Zinc 335 351 95.4 80-119


Page 1

264 of 304

LA58344

99.4.3





Prep Date: 10/10/19 10/10/19

BSP Spikelot

10/10/19

QC LCS Spikelot

10/10/19

QCMetal Result MPICPMS6 % Rec Limits Result LCSMETAL11% Rec Limits


_________________________________________________________________________________________________________

Page 2

265 of 304

LA58344

99.4.3





Prep Date: 10/10/19

LA58344-4

10/10/19


Aluminum

Antimony 3.23 3.58 10.8*(a) 0-10

Arsenic 62.0 63.6 2.5 0-10

Barium 1340 1190 11.7*(a) 0-10

Beryllium 3.83 0.00 100.0*(a 0-10

Boron

Cadmium 0.524 1.04 98.0 (b) 0-10

Calcium

Cerium

Chromium 157 145 7.9 0-10

Cobalt 23.0 18.9 17.6*(a) 0-10

Copper 133 137 3.2 0-10

Iron

Lanthanum

Lithium

Lead 58.9 51.7 12.2*(a) 0-10

Magnesium

Manganese

Molybdenum

Nickel 135 148 9.5 0-10

Potassium

Selenium 26.3 20.6 21.8 (b) 0-10

Silver 0.00 0.00 NC 0-10

Silicon anr

Sodium

Strontium

Thallium 2.61 1.27 51.5 (b) 0-10

Tin

Titanium

Vanadium 235 221 6.3 0-10

Uranium

Zinc 388 374 3.6 0-10


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10/10/19


Aluminum

Antimony 0.4 10 3.233 .12932 97.89 0.1 10 100 97.8 75-125

Arsenic

Barium

Boron

Cadmium

Calcium

Cerium

Chromium 0.4 10 156.9 6.276 109.5 0.1 10 100 103.2 75-125

Cobalt 0.4 10 22.96 .9184 98.88 0.1 10 100 98.0 75-125

Copper 0.4 10 133.1 5.324 100.3 0.1 10 100 95.0 75-125

Iron

Lanthanum

Lithium

Lead

Magnesium

Manganese

Molybdenum

Nickel 0.4 10 135.1 5.404 96.95 0.1 10 100 91.5 75-125

Potassium

Selenium

Silver

Silicon

Sodium

Strontium

Thallium

Tin

Titanium

Vanadium 0.4 10 235.4 9.416 111.1 0.1 10 100 101.7 75-125

Uranium

Zinc 0.4 10 388.2 15.528 109.8 0.1 10 100 94.3 75-125


Results < IDL are shown as zero for calculation purposes_________________________________________________________________________________________________________

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10/10/19


(*) Outside of QC limits(**) Corr. sample result = Raw * (sample volume / final volume)(anr) Analyte not requested

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Prep Date: 10/21/19

MB

10/21/19



Antimony 1.0 .0063 .34 0.28 <1.0

Arsenic 1.0 .062 .26 0.066 <1.0

Barium 1.0 .0089 .46 0.22 <1.0

Beryllium 1.0 .0096 .28 -0.17 <1.0

Boron 20 1.5 2.9

Cadmium 0.50 .0081 .12 0.061 <0.50

Calcium 100 4.7 20

Cerium 1.0 .0019 .16

Chromium 1.0 .059 .15 0.033 <1.0

Cobalt 1.0 .0082 .14 -0.0036 <1.0

Copper 1.0 .27 .74 -0.18 <1.0

Iron 100 2.8 16

Lanthanum 1.0 .0019 .41

Lithium 2.0 .3 .61

Lead 1.0 .0045 .13 -0.14 <1.0




Nickel 1.0 .081 .2 -0.069 <1.0

Potassium 100 5 7.6

Selenium 5.0 .3 3.1 -0.82 <5.0

Silver 1.0 .0088 .13 -0.0054 <1.0

Silicon 500 7.6 130

Sodium 100 8.6 9.9


Thallium 1.0 .03 .86 -0.13 <1.0

Tin 2.0 .059 .19

Titanium 1.0 .095 .77

Uranium 1.0 .0019 .17

Vanadium 1.0 .035 .1 0.092 <1.0

Zinc 5.0 1.5 1.1 -0.44 <5.0


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Prep Date: 10/21/19

TD46457-2F Spikelot

10/21/19


Aluminum anr

Antimony 4.3 79.6 100 75.3 75-125

Arsenic 4.2 83.8 100 79.6 75-125

Barium 194 222 100 28.0N(a) 75-125

Beryllium 0.0 69.8 100 69.8N(a) 75-125

Boron

Cadmium 0.72 77.1 100 76.4 75-125

Calcium anr

Cerium

Chromium 2.1 79.7 100 77.6 75-125

Cobalt 0.0 79.1 100 79.1 75-125

Copper 13.8 86.8 100 73.0N(a) 75-125

Iron anr

Lanthanum

Lithium anr

Lead 0.16 77.8 100 77.6 75-125

Magnesium anr

Manganese anr

Molybdenum

Nickel 11.3 86.8 100 75.5 75-125

Potassium anr

Selenium 0.0 370 500 74.0N(a) 75-125

Silver 0.0 67.7 100 67.7N(a) 75-125

Silicon

Sodium anr

Strontium anr

Thallium 0.0 73.7 100 73.7N(a) 75-125

Tin

Titanium

Uranium

Vanadium 4.2 82.8 100 78.6 75-125

Zinc 581 531 100 -50.0(b) 75-125


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information.

_________________________________________________________________________________________________________

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Prep Date: 10/21/19

TD46457-2F Spikelot

10/21/19


Aluminum anr

Antimony 4.3 76.4 100 72.1N(a) 4.1 20

Arsenic 4.2 77.2 100 73.0N(a) 8.2 20

Barium 194 222 100 28.0N(a) 0.0 20

Beryllium 0.0 80.4 100 80.4 12.4 20

Boron

Cadmium 0.72 74.0 100 73.3N(a) 4.1 20

Calcium anr

Cerium

Chromium 2.1 79.1 100 77.0 0.8 20

Cobalt 0.0 75.9 100 75.9 4.1 20

Copper 13.8 83.6 100 69.8N(a) 3.8 20

Iron anr

Lanthanum

Lithium anr

Lead 0.16 73.8 100 73.6N(a) 5.3 20

Magnesium anr

Manganese anr

Molybdenum

Nickel 11.3 74.2 100 62.9N(a) 15.7 20

Potassium anr

Selenium 0.0 299 500 59.8N(a) 21.2 (b) 20

Silver 0.0 73.8 100 73.8N(a) 8.6 20

Silicon

Sodium anr

Strontium anr

Thallium 0.0 73.6 100 73.6N(a) 0.1 20

Tin

Titanium

Uranium

Vanadium 4.2 81.0 100 76.8 2.2 20

Zinc 581 466 100 -115.0(c 13.0 20


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10/21/19


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Spike recovery indicates possible matrix interference or sample non-homogeneity.(b) Outside control limits due to matrix interference.(c) Spike amount low relative to the sample amount. Refer to lab control or spike blank for recovery

information.

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Prep Date: 10/21/19

BSP Spikelot

10/21/19


Aluminum anr

Antimony 97.6 100 97.6 80-120

Arsenic 99.2 100 99.2 80-120

Barium 94.5 100 94.5 80-120

Beryllium 99.7 100 99.7 80-120

Boron

Cadmium 95.6 100 95.6 80-120

Calcium anr

Cerium

Chromium 96.6 100 96.6 80-120

Cobalt 97.3 100 97.3 80-120

Copper 94.7 100 94.7 80-120

Iron anr

Lanthanum

Lithium anr

Lead 96.7 100 96.7 80-120

Magnesium anr

Manganese anr

Molybdenum

Nickel 95.4 100 95.4 80-120

Potassium anr

Selenium 501 500 100.2 80-120

Silver 92.3 100 92.3 80-120

Silicon

Sodium anr

Strontium anr

Thallium 97.6 100 97.6 80-120

Tin

Titanium

Uranium

Vanadium 99.0 100 99.0 80-120

Zinc 104 100 104.0 80-120


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10/21/19



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Page 2

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99.5.3





Prep Date: 10/21/19

TD46457-2F

10/21/19


Aluminum anr

Antimony 4.27 16.6 288.2*(a 0-10

Arsenic 4.18 6.48 55.0 (b) 0-10

Barium 194 180 6.8 0-10


Boron

Cadmium 0.719 2.66 270.6(b) 0-10

Calcium anr

Cerium

Chromium 2.07 11.9 474.3(b) 0-10

Cobalt 0.00 0.00 NC 0-10

Copper 13.8 0.00 100.0(b) 0-10

Iron anr

Lanthanum

Lithium anr

Lead 0.161 0.00 100.0(b) 0-10

Magnesium anr

Manganese anr

Molybdenum

Nickel 11.3 7.82 31.0 (b) 0-10

Potassium anr

Selenium 0.00 0.00 NC 0-10

Silver 0.00 0.00 NC 0-10

Silicon

Sodium anr

Strontium anr

Thallium 0.00 0.00 NC 0-10

Tin

Titanium

Uranium

Vanadium 4.24 11.1 160.7(b) 0-10

Zinc 581 563 3.1 0-10


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10/21/19



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Prep Date: 10/21/19


10/21/19


Aluminum

Antimony 0.2 10 4.266 .08532 85.27 0.1 10 100 85.2 75-125

Arsenic 0.2 10 4.177 .08354 84.53 0.1 10 100 84.4 75-125

Barium 0.2 10 193.5 3.87 92.61 0.1 10 100 88.7 75-125

Beryllium 0.2 10 101.8 0.1 10 100 101.8 75-125

Boron

Cadmium 0.2 10 .7185 .01437 86.44 0.1 10 100 86.4 75-125

Calcium

Cerium

Chromium

Cobalt

Copper 0.2 10 13.81 .2762 87.75 0.1 10 100 87.5 75-125

Iron

Lanthanum

Lithium

Lead 0.2 10 .1608 .003216 89.8 0.1 10 100 89.8 75-125

Magnesium

Manganese

Molybdenum

Nickel 0.2 10 11.33 .2266 88.27 0.1 10 100 88.0 75-125

Potassium

Selenium 0.2 10 391.2 0.1 50 500 78.2 75-125

Silver 0.2 10 97.99 0.1 10 100 98.0 75-125

Silicon

Sodium

Strontium

Thallium 0.2 10 91.85 0.1 10 100 91.9 75-125

Tin

Titanium

Uranium

Vanadium

Zinc


_________________________________________________________________________________________________________

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10/21/19



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Prep Date: 10/21/19

MB

10/21/19


Mercury 0.20 .056 .081 -0.011 <0.20



_________________________________________________________________________________________________________

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10/21/19


Mercury 0.0 4.8 5 96.0 75-125



_________________________________________________________________________________________________________

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10/21/19


Mercury 0.0 4.7 5 94.0 2.1 20



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Mercury 4.8 5 96.0 80-120



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10/21/19


Mercury 0.00 0.00 NC 0-



_________________________________________________________________________________________________________

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Prep Date: 10/22/19

MB

10/22/19


Aluminum 0.10 .0014 .018

Antimony 0.0010 .0000063 .00025

Arsenic 0.0010 .000062 .00024

Barium 0.0010 .0000089 .00059 0.00020 <0.0010

Beryllium 0.0010 .0000096 .000085

Boron 0.020 .0015 .0015

Cadmium 0.00050 .0000081 .00015

Calcium 0.10 .0047 .026

Cerium 0.0010 .0000019 .00011

Chromium 0.0010 .000059 .00019

Cobalt 0.0010 .0000082 .00016

Copper 0.0010 .00027 .00019

Iron 0.10 .0028 .022

Lithium 0.0020 .0003 .000061

Lead 0.0010 .0000045 .000042

Magnesium 0.10 .0011 .011

Manganese 0.0010 .0001 .00028

Molybdenum 0.0010 .00019 .00028

Nickel 0.0010 .000081 .00074

Potassium 0.10 .005 .011

Selenium 0.0050 .0003 .0023

Silver 0.0010 .0000088 .00046

Sodium 0.10 .0086 .059

Strontium 0.0010 .000063 .00016

Thallium 0.0010 .00003 .00043 -0.0000083<0.0010

Tin 0.0010 .000059 .00024

Titanium 0.0010 .000095 .00083

Uranium 0.0010 .0000019 .00012

Vanadium 0.0010 .000035 .00036

Zinc 0.0060 .0015 .0016



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Prep Date: 10/22/19 10/22/19

LA58133-7A

10/22/19


10/22/19


Aluminum

Antimony

Arsenic anr

Barium 0.016 0.016 0.0 0-20 0.016 0.11 0.10 94.0 75-125

Beryllium

Boron

Cadmium

Calcium

Cerium

Chromium

Cobalt

Copper

Iron

Lithium

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium 0.000091 0.0 200.0(a) 0-20 0.000091 0.090 0.10 89.9 75-125

Tin

Titanium

Uranium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested_________________________________________________________________________________________________________

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Prep Date: 10/22/19 10/22/19

LA58133-7A

10/22/19


10/22/19


(a) RPD acceptable due to low duplicate and sample concentrations.

_________________________________________________________________________________________________________

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Prep Date: 10/22/19

BSP Spikelot

10/22/19


Aluminum

Antimony

Arsenic anr

Barium 0.089 0.10 89.0 80-120

Beryllium

Boron

Cadmium

Calcium

Cerium

Chromium

Cobalt

Copper

Iron

Lithium

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium 0.089 0.10 89.0 80-120

Tin

Titanium

Uranium

Vanadium

Zinc



_________________________________________________________________________________________________________

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99.7.3





Prep Date: 10/22/19

LA58133-7A

10/22/19


Aluminum

Antimony

Arsenic anr

Barium 16.2 18.7 16.0*(a) 0-10

Beryllium

Boron

Cadmium

Calcium

Cerium

Chromium

Cobalt

Copper

Iron

Lithium

Lead

Magnesium

Manganese

Molybdenum

Nickel

Potassium

Selenium

Silver

Sodium

Strontium

Thallium 0.0915 0.00 100.0(b) 0-10

Tin

Titanium

Uranium

Vanadium

Zinc


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Serial dilution indicates possible matrix interference._________________________________________________________________________________________________________

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(b) Percent difference acceptable due to low initial sample concentration (< 50 times IDL).

_________________________________________________________________________________________________________

Page 2

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99.7.4


General Chemistry

QC Data Summaries



Scott, LASection 10

293 of 304

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Nitrogen, Nitrate GP7304/GN15794 0.050 0.0 mg/l 2.5 2.43 97.2 90-110% Nitrogen, Nitrite GP7304/GN15794 0.050 0.020 mg/l 2.5 2.44 97.6 90-110%

Associated Samples: Batch GP7304: LA58344-9, LA58344-10, LA58344-11, LA58344-12, LA58344-13(*) Outside of QC limits

__________________________________________________________________________________________________________________________

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Nitrogen, Nitrate GP7304/GN15794 LA58344-9Q mg/l 0.038 U 2.5 2.5 100.0 80-120%Nitrogen, Nitrite GP7304/GN15794 LA58344-9Q mg/l 0.29 2.5 2.6 92.4 80-120%

Associated Samples: Batch GP7304: LA58344-9, LA58344-10, LA58344-11, LA58344-12, LA58344-13(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits

__________________________________________________________________________________________________________________________

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Nitrogen, Nitrate GP7304/GN15794 LA58344-9Q mg/l 0.038 U 2.5 2.5 0.0 20%Nitrogen, Nitrite GP7304/GN15794 LA58344-9Q mg/l 0.29 2.5 2.6 0.0 20%


__________________________________________________________________________________________________________________________

Page 1

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1010.3


Misc. Forms


(SGS Houston, TX)



Scott, LASection 11

297 of 304

LA58344

11


SGS Houston, TX

298 of 304

LA58344

1111.1

Page 1 of 2Job Number: LA58344 Client: SGS


Project: BOTTLE

# of Coolers: 1

Airbill #'s:




















Intact








Misc. Information


Y or N N/A




11. COC Present:

N/A


Comments


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Sample Receipt Log

Job #: LA58344 Date / Time Received: 10/9/2019 11:20:00 PM Initials: BELINDG

Client: SGS

Page 2 of 2


CFCorrected

TempInitialTemp

500AML M2E H2SO4 pH < 2 IR-4 0 1.51 LA58344-9 1.51

500AML M2E H2SO4 pH < 2 IR-4 0 1.51 LA58344-10 1.51

500AML M2E H2SO4 pH < 2 IR-4 0 1.51 LA58344-11 1.51

500AML M2E H2SO4 pH < 2 IR-4 0 1.51 LA58344-12 1.51

500AML M2E H2SO4 pH < 2 IR-4 0 1.51 LA58344-13 1.51


300 of 304

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General Chemistry

QC Data Summaries

(SGS Houston, TX)



Scott, LASection 12

301 of 304

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12





Nitrogen, Ammonia GP55200/GN1889 0.10 0.0 mg/l 2 1.97 98.5 90-110%


__________________________________________________________________________________________________________________________

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1212.1





Nitrogen, Ammonia GP55200/GN1889 LA58344-9 mg/l -0.018 0.0 0.0 0-20%


__________________________________________________________________________________________________________________________

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Nitrogen, Ammonia GP55200/GN1889 LA58344-9 mg/l -0.018 2 1.5 75.0 90-110%


__________________________________________________________________________________________________________________________

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1212.3

ACADIANA PLANNING COMMISSION

1249-001-009DK BAL PII ESA Rpt PROVIDENCE

APPENDIX E

95% UCL CALCULATIONS

Arsenic Concentration

0-2' 6.320-22' 5.728-30' 0.86

0-2' 7.714-16' 4.418-20' 9.1

0-2' 9.68-10' 8.0

18-20' 3.70-2' 10.4

20-22' 2.328-30' 3.0

0-2' 8.622-24' 1.228-30' 1.3

0-2' 8.424-26' 1.928-30' 1.4

0-2' 6.220-22' 1.028-30' 0.73

0-2' 12.820-22' 3.228-30' 4.0

0-2' 6.524-26' 3.328-30' 8.9

0-2' 12.210-12' 7.116-18' 4.418-20' 5.4

0-2' 9.926-28' 0.9828-30' 1.3

0-2' 6.228-30' 0.85

0-2' 9.88-10' 8.1

18-20' 10.60-2' 1.9

B-2

A-1

A-2

A-3

A-4

A-5

Boring Location

B-3

B-4

B-5

A-6

A-7

A-8

A-9

B-1

28-30' 0.930-2' 3.3

8-10' 7.214-16' 3.818-20' 7.6

0-2' 8.98-10' 7.3

10-12' 4.123-25' 3.3

0-2' 9.818-20' 2.328-30' 3.3

0-2' 6.522-24' 3.328-30' 5.8

0-2' 8.220-22' 3.528-30' 5.4

C-2

C-3

Arsenic ArithmeticMean 5.41

B-5

B-7

B-8

C-1

5% Shapiro Wilk P Value 0.00613 Data Not Lognormal at 5% Significance Level

LLognormal GOF Test

Shapiro Wilk Test Statistic 0.936 SShapiro Wilk Lognormal GOF Test

Assuming Gamma Distribution

95% Approximate Gamma UCL (use when n>=50)) 177.7 95% Adjusted Gamma UCL (use when n<50) 178.6

Adjusted Level of Significance 0.0459 Adjusted Chi Square Value 139.1

MLE Mean (bias corrected) 147.2 MLE Sd (bias corrected) 122

Approximate Chi Square Value (0.05) 139.8

Theta hat (MLE) 96.65 Theta star (bias corrected MLE) 101.1

nu hat (MLE) 176.6 nu star (bias corrected) 168.8

Gamma Statistics

k hat (MLE) 1.523 k star (bias corrected MLE) 1.455

5% K-S Critical Value 0.119 Data Not Gamma Distributed at 5% Significance Level

Data Not Gamma Distributed at 5% Significance Level

5% A-D Critical Value 0.768 Data Not Gamma Distributed at 5% Significance Level

K-S Test Statistic 0.182 KKolmogorov-Smirnov Gamma GOF Test

Gamma GOF Test

A-D Test Statistic 2.199 AAnderson-Darling Gamma GOF Test

95% Student's-t UCL 200.9 95% Adjusted-CLT UCL (Chen-1995) 231

95% Modified-t UCL (Johnson-1978) 205.7

Data Not Normal at 5% Significance Level

Assuming Normal Distribution

95% Normal UCL 95% UCLs (Adjusted for Skewness)

Lilliefors Test Statistic 0.344 LLilliefors GOF Test

5% Lilliefors Critical Value 0.116 Data Not Normal at 5% Significance Level

Normal GOF Test

Shapiro Wilk Test Statistic 0.337 SShapiro Wilk GOF Test

5% Shapiro Wilk P Value 0 Data Not Normal at 5% Significance Level

Coefficient of Variation 1.663 Skewness 6.88

Maximum 1920 Median 115.5

SD 244.8 Std. Error of Mean 32.14

Number of Missing Observations 0

Minimum 19.2 Mean 147.2

General Statistics

Total Number of Observations 58 Number of Distinct Observations 54

Number of Bootstrap Operations 2000

Barium

From File metals.xls

Full Precision OFF

Confidence Coefficient 95%

UCL Statistics for Data Sets with Non-Detects

User Selected Options

Date/Time of Computation ProUCL 5.13/2/2020 8:36:05 AM

PProUCL computes and outputs H-statistic based UCLs for historical reasons only.

H-statistic often results in unstable (both high and low) values of UCL95 as shown in examples in the Technical Guide.

It is therefore recommended to avoid the use of H-statistic based 95% UCLs.

Use of nonparametric methods are preferred to compute UCL95 for skewed data sets which do not follow a gamma distribution.

Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL.

Recommendations are based upon data size, data distribution, and skewness.

These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006).

However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician.

Suggested UCL to Use

95% H-UCL 166.8

90% Chebyshev(Mean, Sd) UCL 243.6 95% Chebyshev(Mean, Sd) UCL 287.3

97.5% Chebyshev(Mean, Sd) UCL 347.9 99% Chebyshev(Mean, Sd) UCL 467

95% Hall's Bootstrap UCL 413.1 95% Percentile Bootstrap UCL 206.4

95% BCA Bootstrap UCL 254.2

95% CLT UCL 200 95% Jackknife UCL 200.9

95% Standard Bootstrap UCL 200.6 95% Bootstrap-t UCL 310.2

Nonparametric Distribution Free UCL Statistics

Data appear to follow a Discernible Distribution at 5% Significance Level

Nonparametric Distribution Free UCLs

95% Chebyshev (MVUE) UCL 199 97.5% Chebyshev (MVUE) UCL 226.8

99% Chebyshev (MVUE) UCL 281.4

Assuming Lognormal Distribution

95% H-UCL 166.8 90% Chebyshev (MVUE) UCL 179

Maximum of Logged Data 7.56 SD of logged Data 0.75

Lognormal Statistics

Minimum of Logged Data 2.955 Mean of logged Data 4.628

5% Lilliefors Critical Value 0.116 Data appear Lognormal at 5% Significance Level

Data appear Approximate Lognormal at 5% Significance Level

Lilliefors Test Statistic 0.115 LLilliefors Lognormal GOF Test


1249-001-009DK BAL PII ESA Rpt PROVIDENCE

APPENDIX F

MO-1 RECAP FORMS


1249-001-009DK BAL VRIR App F MO-1 RECAP Forms Updated Form 10-1 PROVIDENCE

RECAP FORM 10 SCREENING OPTION SUBMITTAL FOR SOIL

SOIL - Identification of the Limiting SO SS:

COC [ ] SoilSSi [X] SoilSSni SoilSSGW Limiting SS Aliphatics >C8-C10 120 5300 120 Aromatics >C8-C10 65 65 65 Barium 550 2,000 550 Benzene 1.5 0.051 0.051 Chromium 23 100 23 Thallium 0.55 4 0.55 TPH-GRO 65 65 65 Xylene 18 150 18 1,2-dibromo-3-chloropropane 0.18 0.01 0.01 Cis-1,2-dichloroethylene 4.8 0.49 0.49 Cis-1,3-dichloropropene 3.1 0.04 0.04 Trans-1,3-dichloropropene 3.1 0.04 0.04 Methyl bromide 0.43 0.04 0.04 Vinyl chloride 0.24 0.013 0.013

SOIL – Identification of the AOIC:

COC Maximum Concentration (mg/Kg) Aliphatics >C8-C10 161 Aromatics >C8-C10 181 Barium 1,920 Benzene 6.96 Chromium 25.5 Thallium 0.64 TPH-GRO 847 Xylene 64.1 1,2-dibromo-3-chloropropane <0.25 Cis-1,2-dichloroethylene <0.050 Cis-1,3-dichloropropene <0.050



COC Maximum Concentration (mg/Kg) Trans-1,3-dichloropropene <0.050 Methyl bromide <0.50 Vinyl chloride <0.050

SO SOIL RECAP ASSESSMENT:

COC Limiting SS (mg/Kg) Maximum Concentration (mg/Kg) AOIC Exceeds LSS? Aliphatics >C8-C10 120 161 Yes Aromatics >C8-C10 65 181 Yes Barium 550 1,920 Yes Benzene 0.051 6.96 Yes Chromium 23 25.5 Yes Thallium 0.55 0.64 Yes TPH-GRO 65 847 Yes Xylene 18 64.1 Yes 1,2-dibromo-3-chloropropane 0.01 <0.25 Yes Cis-1,2-dichloroethylene 0.49 <0.050 Yes Cis-1,3-dichloropropene 0.04 <0.050 Yes Trans-1,3-dichloropropene 0.04 <0.050 Yes Methyl bromide 0.04 <0.50 Yes Vinyl chloride 0.013 <0.050 Yes

Notes: - AOIC = maximum detected concentration or the sample quantitation limit (SQL) for non-detects. - The Soil Limiting SS applied are the lower of the Non-industrial Soil (SoilSSni) and the Soil Protective of Groundwater (SoilSSGW) SS. - Constituents with maximum detected concentrations (or proxy SQL concentrations for non-detects) exceeding the LSS were further compared to calculated MO-1 RECAP Standards.



RECAP FORM 11 MANAGEMENT OPTION 1 SUBMITTAL FOR SOIL 0-15 FT BGS

SOIL 0-15 ft bgs - Identification of the Limiting MO-1RS:

COC [ ] Soili [X] Soilni

Additivity Divisor

Final [ ] Soili [X] Soilni

[ ] SoilGW1 [ ] SoilGW2 [] SoilGW3DW [X] SoilGW3NDW

[ ] NO DF [ ] DF2 [ ] DF3 [X] DF3

Final SoilGW

Soiles Soilsat Limiting MO-1 RS

Aliphatics >C8-C10 1,200 2 600 10,000 NA 10,000 86 NA 86 Aromatics >C8-C10 650 2 325 260 440 114,400 150 NA 150 Barium 5,500 NA 5,500 2,000 NA 2,000 NA NA 2,000 Benzene 1.5 NA 1.5 0.011 440 4.84 1 900 1 Thallium 5.5 2 2.75 4.0 NA 4.0 NA NA 2.75 TPH-GRO 650 NA 650 6,100 440 18,300 86 NA 86 Xylene 180 2 90 180 440 540 15 150 15

Notes: - Concentrations shown in milligrams per kilogram (mg/Kg). - NA = Not applicable. - Management Option 1 Limiting RECAP Standards (MO-1 LRS) applied were the lowest of the adjusted Non-industrial Soil (Soilni), the Soil Saturation (Soilsat), the Soil Enclosed Space (Soiles), and

the Soil Protective of Groundwater Classification 3 Drinking Water (SoilGW3DW) standards from Table 2 of RECAP (LDEQ 2003). SOIL 0-15 ft bgs – Identification of the AOIC:

COC Maximum Concentration 95%UCL-AM Concentration AOI Concentration Aliphatics >C8-C10 161 Not Calculated 161 Aromatics >C8-C10 181 Not Calculated 181 Barium 1,920 Not Calculated 1,920 Benzene 6.96 Not Calculated 6.96 Thallium 0.64 Not Calculated 0.64 TPH-GRO 847 Not Calculated 847 Xylene 64.1 Not Calculated 64.1

Notes: - Concentrations shown in mg/Kg.



MO-1 SOIL 0-15 ft bgs RECAP ASSESSMENT:

COC Limiting MO-1 RS AOI Concentration AOIC Exceeds MO-1 LRS? Aliphatics >C8-C10 86 161 Yes Aromatics >C8-C10 150 181 Yes Barium 2,000 1,920 No Benzene 1 6.96 Yes Thallium 2.75 0.64 No TPH-GRO 86 847 Yes Xylene 15 64.1 Yes

Notes: - Concentrations shown in milligrams per kilogram (mg/Kg). - AOIC were the maximum detected concentrations or one-half the SQL for non-detects. - A Voluntary Remedial Action Plan will be completed to address exceedances.



RECAP FORM 12 MANAGEMENT OPTION 1 SUBMITTAL FOR SOIL > 15 FT BGS

SOIL >15 ft bgs - Identification of the Limiting MO-1RS:

COC [ ] SoilGW1 [ ] SoilGW2 [ ] SoilGW3DW [X] SoilGW3NDW

[ ] NO DF [ ] DF2 [ ] DF3 [X] DF3

Final SoilGW

Soilsat Limiting MO-1RS

Aromatics >C8-C10 6,100 440 3,904,000 NA 3,904,000 Benzene 0.131 440 57.2 900 57.2 Chromium 100 NA 100 NA 100 TPH-GRO 6,100 440 18,300 NA 18,300 Xylene 180 440 540 150 150 1,2-dibromo-3-chloropropane 0.0026 440 1.144 780 1.144 Cis-1,2-dichloroethylene 12 440 5,280 1,200 1,200 Cis-1,3-dichloropropene 1.3 440 572 1,100 572 Trans-1,3-dichloropropene 1.3 440 572 1,100 572 Methyl bromide 2.1 440 924 3,000 924 Vinyl chloride 0.24 440 105.6 920 105.6

Notes: - Concentrations shown in milligrams per kilogram (mg/Kg). - NA = Not applicable. - Management Option 1 Limiting RECAP Standards (MO-1 LRS) applied were the lowest of the Soil Saturation (Soilsat), and the Soil Protective of Groundwater Classification 3 Non-Drinking Water

(SoilGW3NDW) standards from Table 2 of RECAP (LDEQ 2003).



SOIL >15 ft bgs – Identification of the AOIC:

COC Maximum Concentration 95%UCL-AM Concentration AOI Concentration Aromatics >C8-C10 81.2 Not Calculated 81.2 Benzene 2.83 Not Calculated 2.83 TPH-GRO 267 Not Calculated 267 Chromium 25.5 14.91 14.91 Xylene 168 Not Calculated 168 1,2-dibromo-3-chloropropane <0.125 Not Calculated <0.125 Cis-1,2-dichloroethylene <0.025 Not Calculated <0.025 Cis-1,3-dichloropropene <0.025 Not Calculated <0.025 Trans-1,3-dichloropropene <0.025 Not Calculated <0.025 Methyl bromide <0.25 Not Calculated <0.25 Vinyl chloride <0.025 Not Calculated <0.025

Notes: - Concentrations shown in mg/Kg. - Proxy one-half the SQL was applied for non-detects.

MO-1 SOIL > 15 FT BGS RECAP ASSESSMENT:

COC Limiting MO-1 RS AOI Concentration AOIC Exceeds MO-1 LRS? Aromatics >C8-C10 114,400 81.2 No Benzene 4.84 2.83 No Chromium 100 14.91 No TPH-GRO 18,300 267 No Xylene 150 168 Yes 1,2-dibromo-3-chloropropane 1.144 <0.125 No Cis-1,2-dichloroethylene 1,200 <0.025 No Cis-1,3-dichloropropene 572 <0.025 No Trans-1,3-dichloropropene 572 <0.025 No Methyl bromide 924 <0.25 No Vinyl chloride 105.6 <0.025 No

Notes: - Concentrations shown in milligrams per kilogram (mg/Kg). - AOIC were the maximum detected concentrations or one-half the SQL for non-detects. - A Voluntary Remedial Action Plan will be completed to address exceedances.



RECAP FORM 15 SCREENING OPTION SUBMITTAL FOR GROUNDWATER (SHALLOW ZONE)

GROUNDWATER - Identification of the SO SS:

COC GWSS (mg/L) Acetone 0.1 Benzene 0.005 1,2-dibromo-3chloropropane 0.0002 1,2-dichloroethane 0.005 Ethylbenzene 0.7 Methyl Tert Butyl Ether 0.02 2-Methylnaphthalene 0.00062 Naphthalene 0.01 Arsenic 0.01 Aliphatics C6-C8 3.2 Aliphatics >C8-C10 0.15 Aromatics >C8-C10 0.15 Aliphatics >C10-C12 0.15 Aliphatics >C12-C16 0.15 Aromatics >C12-C16 0.15 TPH-DRO 0.15 TPH-GRO 0.15

GROUNDWATER – Compliance Concentration:

COC Compliance Concentration (mg/L) Acetone 0.431 Benzene 2.78 1,2-dibromo-3chloropropane <0.0005 1,2-dichloroethane 0.0197 Ethylbenzene 1.49 Methyl Tert Butyl Ether 0.0767 2-Methylnaphthalene 0.0277 Naphthalene 0.102 Arsenic 0.0862 Aliphatics C6-C8 5.41 Aliphatics >C8-C10 2.77



Aromatics >C8-C10 1.97 Aliphatics >C10-C12 1.56 Aliphatics >C12-C16 0.197 Aromatics >C12-C16 0.245 TPH-DRO 7.77 TPH-GRO 70.8

SO GROUNDWATER RECAP ASSESSMENT:

COC GWSS (mg/L) Compliance Concentration (mg/L) CC Exceeds SS? Acetone 0.1 0.431 Yes Benzene 0.005 2.78 Yes 1,2-dibromo-3chloropropane 0.0002 <0.0005 Yes 1,2-dichloroethane 0.005 0.0197 Yes Ethylbenzene 0.7 1.49 Yes Methyl Tert Butyl Ether 0.02 0.0767 Yes 2-Methylnaphthalene 0.00062 0.0277 Yes Naphthalene 0.01 0.102 Yes Arsenic 0.01 0.0862 Yes Aliphatics C6-C8 3.2 5.41 Yes Aliphatics >C8-C10 0.15 2.77 Yes Aromatics >C8-C10 0.15 1.97 Yes Aliphatics >C10-C12 0.15 1.56 Yes Aliphatics >C12-C16 0.15 0.197 Yes Aromatics >C12-C16 0.15 0.245 Yes TPH-DRO 0.15 7.77 Yes TPH-GRO 0.15 70.8 Yes

Notes: - CC = maximum detected concentration or the sample quantitation limit for non-detects - Constituents with maximum detected concentrations (or proxy SQL concentrations for non-detects) exceeding the LSS were identified as requiring further evaluation under RECAP and were

further compared to calculated MO-1 RECAP Standards.

RECAP FORM 15 SCREENING OPTION SUBMITTAL FOR GROUNDWATER (DEEP ZONE)

GROUNDWATER - Identification of the SO SS:

COC GWSS (mg/L) Benzene 0.005 1,2-dichloroethane 0.005 Ethylbenzene 0.7 Toluene 1 2-Methylnaphthalene 0.00062 Naphthalene 0.01 Arsenic 0.01 TPH-DRO 0.15 TPH-GRO 0.15

GROUNDWATER – Compliance Concentration:

COC Compliance Concentration (mg/L) Benzene 0.316 1,2-dichloroethane 0.0197 Ethylbenzene 1.05 Toluene 1.52 2-Methylnaphthalene 0.023 Naphthalene 0.0707 Arsenic 0.0512 TPH-DRO 4.03 TPH-GRO 25.3

SO GROUNDWATER RECAP ASSESSMENT:

COC GWSS (mg/L) Compliance Concentration (mg/L) CC Exceeds SS? Benzene 0.005 0.316 Yes 1,2-dichloroethane 0.005 0.0197 Yes Ethylbenzene 0.7 1.05 Yes Toluene 1 1.52 Yes 2-Methylnaphthalene 0.00062 0.023 Yes Naphthalene 0.01 0.0707 Yes Arsenic 0.01 0.0512 Yes TPH-DRO 0.15 4.03 Yes TPH-GRO 0.15 25.3 Yes

Notes: - CC = maximum detected concentration or the sample quantitation limit for non-detects - Constituents with maximum detected concentrations (or proxy SQL concentrations for non-detects) exceeding the LSS were identified as requiring further evaluation under RECAP and were

further compared to calculated MO-1 RECAP Standards.