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To Our Valued Customer During the past few years we have been asked many a time to respond to customers questionnaires, quality forms, and other related requests for information. In time we had collected a large number of these requests and responded in kind. As our business has evolved the process to assimilate and respond to these questionnaires has become tedious. As a course of action to help recover the cost associated with this, we began requiring our customers to pay for such requests. Regarding that business action, we took it upon ourselves to help and respond with a detailed packet of information that we have found to be asked most frequently. Our hope is that this package of information answers all of your company’s needs. As a supplier of Dry Ice, we want to continue on focusing on our customers utilization of our products better. When we are requested to respond to the information requests, it unavoidable removes our staff from the manufacturing and quality process. We respectfully request that the detailed amount of information enclosed satisfy any of your internal needs. If they do not and there are additional requests required, please be aware there is a fee associated for gathering them. Thank you for your understanding in this matter. Continental will continue adding more data as we see fit. As always, thank for your business. Very truly yours,
Mark M Weir Vice President
Table of Contents: Certificate of Conformance (Carbon Dioxide, Solid / Dry Ice) Continuing Letter of Guarantee for Block Dry Ice Product Continuing Letter of Guarantee for Pelletized Dry Ice Product W9 Information SDS – Carbon Dioxide, Solid / Dry Ice Safe Handling of Dry Ice CUSMA / USMCA / T-MEC Certification of Origin Dry Ice Technical Specifications Typical Frequently Asked Quality Questions Ingredient Criteria Questionnaire Lot Code Explanation
ANNUAL CERTIFICATE OF CONFORMANCE
Food Grade Carbon Dioxide
This certifies that all product labeled as Food Grade Carbon Dioxide provided by Continental Carbonic
Products, Inc. meets or exceeds the Compressed Gas Association’s (“CGA”) G-6.2 Quality Verification
Level H specifications for Food Grade Carbon Dioxide as outlined in the table below.
CHARACTERISTIC CGA G-6.2 QVL H
FOOD
Identification -
Carbon Dioxide (min) 99.5%
Acetaldehyde 0.5 ppm
Carbon Monoxide 10 ppm
Carbonyl Sulfide 0.5 ppm
Nitric Oxide 5 ppm
Oxygen 50 ppm
Sulfur Dioxide 5 ppm
Total Sulfur 0.5 ppm
Total Hydrocarbon Content (as methane)
50 ppm
Hydrogen Sulfide 0.5 ppm
Nonvolatile Residues 10 ppm
Odor/Taste a
Water 20 ppm
a Free of Foreign Odor or Taste
CERTIFIED BY: Andrew Gregory, VP Production DATE: 01-01-21This annual certificate is good for a period of one (1) year.
To whom it may concern:
The pelletized dry ice our company produces is made with food grade liquid carbon
dioxide with no additives. Dry ice is considered Generally Recognized as Safe (GRAS)
by the FDA under FDA 21CFR184.1240. Continental Carbonic meets or exceeds federal
requirements set forth under the U.S. FDA 21CFR184.1240 Carbon Dioxide and the
FDA Food Safety Modernization Act (FSMA), specifically 21CFR117. Continental
Carbonic supports our food safety program through the utilization of a Food Safety Plan,
supporting pre-requisite programs and annual 3rd party GFSI based audits. Primary
elements of the Food Safety Management System include the following:
Prerequisite Programs: Documented prerequisite programs covering material receiving,
pest control, food defense, sanitation, and safe product handling during production,
storage and distribution.
Recall & Traceability: Procedures for the effective retrieval of product including
contact information for responsible parties, requirements for tracing ingredients,
packaging and finished product one-step forward and one-step back.
Allergen Control: Allergens are not present in the manufacturing/processing of dry ice.
An awareness program addressing regulated allergens and ingredients is maintained to
address personnel practices and housekeeping.
The finished liquid carbon dioxide produced by our company and used to produce our
food grade dry ice is tested using specifications and procedures established by the
Compressed Gas Association (CGA) in its Commodity Specification for Carbon Dioxide
CGA G-6.2—2011.
This letter will serve as the Continuing Letter of Guarantee for all pelletized dry ice
unless otherwise notified by supplier, effective January 1, 2021 through December 31,
2021.
Very truly yours,
Andrew Gregory
Vice President, Production
AG/pss
To whom it may concern:
The Undersigned Continental Carbonic Products, Inc. (Seller) hereby represents that the
production process Seller uses in the production of dry ice produces dry ice that as of the
date of shipment the product is not adulterated or misbranded within the meaning of the
Federal Food, Drug and Cosmetic Act, and not an article which may not, under the
provisions of Section 404 or 405 of the Act, be introduced into interstate commerce.
The undersigned further represents that said dry ice is produced in such a manner that it is
not in violation of or adulterated or misbranded within the meaning of any State or
Municipal Act, the provisions which are identical or substantially the same as those in
federal act referenced above.
We certify only that any solid carbon dioxide (dry ice block) supplied which is
represented as containing no additives other than a food grade binding agent does not, to
the best of our knowledge and belief, contain any additive other than the food grade
binding agent, and that any solid carbon dioxide (dry ice block) so represented shall only
be of standard commercial quality.
SELLER MAKES NO WARRANTIES OR GUARANTEES, EXPRESS OR
IMPLIED, EXCEPT AS EXPRESSLY STATED HEREIN. SELLER DOES NOT
WARRANT OR GUARANTEE THAT THE DRY ICE SOLD IS FIT FOR ANY
PARTICULAR PURPOSE OR IS MERCHANTABLE.
This letter shall serve as an annual Continuing Letter of Guarantee for all dry ice block
unless notified by supplier effective January 1, 2021 through December 31, 2021.
This is a continuing representation and is subject to revocation upon receipt of written
notice thereof.
Sincerely,
Andrew Gregory
Vice President, Production
AG/pss
Please find enclosed our W9. Please see our contact information below.
CORPORATE OFFICE: Continental Carbonic Products, Inc. 3985 E. Harrison Avenue Decatur, IL 62526 800-DRYICE2
REMIT TO ADDRESS: Continental Carbonic Products, Inc. DEPT 3833 PO Box 123833 Dallas, TX 75312-3833 Email: [email protected]
Please visit our website for a complete list of all of our locations: www.continentalcarbonic.com
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 1 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
Material Name
Carbon Dioxide, Solid
Synonyms
DRY ICE; Gas ID 2187
Product Use
Industrial uses.
Restrictions on Use
None known.
Details of the supplier of the safety data sheet
Continental Carbonic Products, Inc.
3985 East Harrison Avenue
Decatur, IL 62526
Phone: 217-428-2068
Emergency Phone #: Outside the US: 703-527-3887 (Call collect)
Fax: 1-800-424-9300 (CHEMTREC)
Classification in accordance with paragraph (d) of 29 CFR 1910.1200.
Simple Asphyxiant
GHS Label Elements
Symbol(s)
None needed according to classification criteria.
Signal Word
Warning
Hazard Statement(s)
May displace oxygen and cause rapid suffocation.
Precautionary Statement(s)
Prevention
None needed according to classification criteria.
Response
None needed according to classification criteria.
Storage
None needed according to classification criteria.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Other Hazards
May cause asphyxia. May cause frostbite.
CAS Component Name Percent
124-38-9 Carbon dioxide, solid 100
Section 1 - PRODUCT AND COMPANY IDENTIFICATION
Section 2 - HAZARDS IDENTIFICATION
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 2 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
Inhalation
Remove person to fresh air and keep comfortable for breathing. If breathing is difficult, oxygen should be
administered by qualified personnel. If breathing has stopped, start artificial respiration at once. Get medical
attention.
Skin
If frostbite or freezing occur, immediately flush with plenty of lukewarm water (105-115°F; 41-46°C). DO NOT
USE HOT WATER. If warm water is not available, gently wrap affected parts in blankets. Get immediate medical
attention.
Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Ingestion
If swallowed, get medical attention.
Most Important Symptoms/Effects
Acute
May cause cryogenic burns, suffocation, frostbite
Delayed
no information on significant adverse effects.
Indication of any immediate medical attention and special treatment needed
For inhalation, consider oxygen.
Extinguishing Media
Suitable Extinguishing Media
Use extinguishing agents appropriate for surrounding fire.
Unsuitable Extinguishing Media
None known.
Special Hazards Arising from the Chemical
Negligible fire hazard.
Hazardous Combustion Products
Oxides of carbon
Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire
is out. Use extinguishing agents appropriate for surrounding fire. Evacuation radius: 800 meters (1/2 mile). Avoid
inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
Special Protective Equipment and Precautions for Firefighters
Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against
possible exposure.
Personal Precautions, Protective Equipment and Emergency Procedures
Wear personal protective clothing and equipment, see Section 8.
Methods and Materials for Containment and Cleaning Up
Do not touch spilled material. Stop leak if possible without personal risk. Keep unnecessary people away, isolate
hazard area and deny entry. Ventilate closed spaces before entering. Collect spilled material in appropriate container
for disposal.
Environmental Precautions
Avoid release to the environment. Avoid release to the environment.
Section 5 - FIRE FIGHTING MEASURES
Section 6 - ACCIDENTAL RELEASE MEASURES
Section 7 - HANDLING AND STORAGE
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 3 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
Precautions for Safe Handling
Avoid breathing dust, mist, fumes or vapors. Use only outdoors or in a well-ventilated area. Wear cold insulating
gloves/face shield/eye protection. Wash hands thoroughly after handling.
Conditions for Safe Storage, Including any Incompatibilities
None needed according to classification criteria.
Store in accordance with all current regulations and standards. Store in a well-ventilated area. Keep container tightly
closed. Keep locked up. Keep away from incompatible materials.
Incompatible Materials
combustible materials, oxidizing materials, metal salts, reducing agents, metal carbide, metals, bases
Component Exposure Limits
Carbon dioxide, solid 124-38-9
ACGIH: 5000 ppm TWA
30000 ppm STEL
NIOSH: 5000 ppm TWA ; 9000 mg/m3 TWA
30000 ppm STEL ; 54000 mg/m3 STEL
40000 ppm IDLH
Europe: 5000 ppm TWA ; 9000 mg/m3 TWA
OSHA (US): 5000 ppm TWA ; 9000 mg/m3 TWA
Mexico: 5000 ppm TWA VLE-PPT ; 9000 mg/m3 TWA VLE-PPT
15000 ppm STEL [PPT-CT ]; 27000 mg/m3 STEL [PPT-CT ]
ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI)
There are no biological limit values for any of this product's components.
Engineering Controls
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
Individual Protection Measures, such as Personal Protective Equipment
Eye/face protection
Wear splash resistant safety goggles with a faceshield. Contact lenses should not be worn. Provide an emergency
eye wash fountain and quick drench shower in the immediate work area.
Skin Protection
Wear appropriate protective, cold insulating clothing.
Respiratory Protection
The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. 40,000 ppm.
Any supplied-air respirator. Any self-contained breathing apparatus with a full facepiece. Emergency or planned
entry into unknown concentrations or IDLH conditions -. Any self-contained breathing apparatus that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode. Any supplied-air respirator with a
full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an
auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape -.
Any appropriate escape-type, self-contained breathing apparatus.
Glove Recommendations
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 4 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
Wear insulated gloves.
Appearance white flakes Physical State solid
Odor Not available Color white
Odor Threshold 0.14 ppm (Recognition
Arsine )
pH
Not available
Melting Point -70 °C (-94 °F ) Boiling Point -79 °C (-110 °F )
Boiling Point Range Not available Freezing point Not available
Evaporation Rate Not available Flammability (solid, gas) Not available
Autoignition
Temperature
Not available
Flash Point
(Not flammable )
Lower Explosive
Limit
Not available
Decomposition temperature
Not available
Upper Explosive
Limit
Not available
Vapor Pressure
569 mmHg @ -82 °C
Vapor Density
(air=1)
1.5
Specific Gravity (water=1)
1.56 at -79 °C
Water Solubility
1.6 % Partition coefficient: n-
octanol/water
Not available
Viscosity Not available Kinematic viscosity Not available
Solubility (Other) Not available Density 1.4 to 1.6 g/cm3
Physical Form
flakes
Sublimation -78.5 °C (-109 °F
Atmospheric pressure )
Molecular Formula CO2 Molecular Weight 44.01
Solvent Solubility
Soluble
Hydrocarbons, organic solvents
Reactivity
No reactivity hazard is expected.
Chemical Stability
Stable at normal temperatures and pressure.
Possibility of Hazardous Reactions
Will not polymerize.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Section 10 - STABILITY AND REACTIVITY
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 5 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
Conditions to Avoid
Protect from physical damage and heat. Containers may rupture or explode if exposed to heat. Avoid contact with
water or moisture.
Incompatible Materials
combustible materials, oxidizing materials, metal salts, reducing agents, metal carbide, metals, bases
Hazardous decomposition products
Oxides of carbon
Information on Likely Routes of Exposure
Inhalation
ringing in the ears, nausea, irregular heartbeat, headache, drowsiness, dizziness, loss of coordination, tingling
sensation, visual disturbances, suffocation, convulsions, coma
Skin Contact
blisters, frostbite
Eye Contact
irritation, blurred vision, frostbite
Ingestion
frostbite
Acute and Chronic Toxicity
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and no selected endpoints have been
identified.
Product Toxicity Data
Acute Toxicity Estimate
No data available.
Immediate Effects
May cause cryogenic burns, suffocation, frostbite
Delayed Effects
no information on significant adverse effects.
Irritation/Corrosivity Data
May cause cryogenic burns.
Respiratory Sensitization
No data available.
Dermal Sensitization
No data available.
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Germ Cell Mutagenicity
No data available.
Tumorigenic Data
No data available
Reproductive Toxicity
No data available.
Specific Target Organ Toxicity - Single Exposure
No target organs identified.
Specific Target Organ Toxicity - Repeated Exposure
No target organs identified.
Aspiration hazard
No data available.
Medical Conditions Aggravated by Exposure
Section 11 - TOXICOLOGICAL INFORMATION
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 6 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
None known.
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components.
Persistence and Degradability
No data available.
Bioaccumulative Potential
No data available.
Mobility
No data available.
Disposal Methods
Dispose in accordance with all applicable regulations.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.
US DOT Information:
Further information: Not regulated as a hazardous material when transported by highway. (Regulated when
transported by aircraft or vessel. )
IMDG Information:
Shipping Name: CARBON DIOXIDE, SOLID
Hazard Class: 9
UN#: UN1845
Required Label(s): 9
International Bulk Chemical Code
This material does not contain any chemicals required by the IBC Code to be identified as dangerous chemicals in
bulk.
U.S. Federal Regulations
None of this products components are listed under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA
Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan.
SARA Section 311/312 (40 CFR 370 Subparts B and C) reporting categories
Simple Asphyxiant
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA
Carbon dioxide, solid 124-38-9 Yes Yes Yes Yes Yes
Not listed under California Proposition 65
Canada Regulations
Canadian WHMIS Ingredient Disclosure List (IDL)
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Section 14 - TRANSPORT INFORMATION
Section 15 - REGULATORY INFORMATION
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 7 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List
is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS
criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL
Carbon dioxide, solid 124-38-9
1 %
Component Analysis - Inventory
Carbon dioxide, solid (124-38-9)
US
CA
EU
AU
PH
JP -
ENCS
JP -
ISHL
KR
KECI -
Annex
1
KR
KECI -
Annex
2
KR -
REACH
CCA
CN
NZ
MX
TW
VN -
NCI
(Draft)
Yes DSL EIN Yes Yes Yes Yes Yes No No Yes Yes Yes Yes Yes
NFPA Ratings
Health: 2 Fire: 0 Reactivity: 0 Other: SA
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Summary of Changes
Updated: 02/03/2017
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU -
Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CA/MA/MN/NJ/PA -
California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS - Chemical Abstracts Service; CERCLA -
Comprehensive Environmental Response, Compensation, and Liability Act; CFR - Code of Federal Regulations
(US); CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG -
Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous Substance Directive;
DSL - Domestic Substances List; EC – European Commission; EEC - European Economic Community; EIN -
European Inventory of (Existing Commercial Chemical Substances); EINECS - European Inventory of Existing
Commercial Chemical Substances; ENCS - Japan Existing and New Chemical Substance Inventory; EPA -
Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research
on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL -
Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime
Dangerous Goods; ISHL - Japan Industrial Safety and Health Law; IUCLID - International Uniform Chemical
Information Database; JP - Japan; Kow - Octanol/water partition coefficient; KR KECI Annex 1 - Korea Existing
Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL); KR KECI Annex 2 - Korea Existing
Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL) , KR - Korea; LD50/LC50 - Lethal Dose/
Lethal Concentration; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of LIsts™ -
ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL -
Maximum Exposure Limits; MX – Mexico; NDSL – Non-Domestic Substance List (Canada); NFPA - National Fire
Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade
Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health
Administration; PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource Conservation and Recovery
Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport;
SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TCCA – Korea
Toxic Chemicals Control Act; TDG - Transportation of Dangerous Goods; TLV - Threshold Limit Value; TSCA -
Toxic Substances Control Act; TW – Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit;
Section 16 - OTHER INFORMATION
Safety Data Sheet Material Name: Carbon Dioxide, Solid SDS ID: 00244557
Page 8 of 8 Issue date: 2020-01-14 Revision 1.14 Print date: 2020-01-14
UN/NA - United Nations /North American; US - United States; VLE - Exposure Limit Value (Mexico); VN NCI
(Draft) - Vietnam National Chemicals Inventory (NCI) (Draft); WHMIS - Workplace Hazardous Materials
Information System (Canada) .
Other Information
Disclaimer:
Continental Carbonic Products, Inc. makes no express or implied warranties, guarantees or representations regarding
the product or the information herein, including but not limited to any implied warranty or merchantability or fitness
for use. Continental Carbonic Products, Inc. shall not be liable for any personal injury, property or other damages of
any nature, whether compensatory, consequential, exemplary, or otherwise, resulting from any publication, use or
reliance upon the information herein.
intentional misuse of dry ice may be harmful or fatal.
DRY ICE SAFETY Safe Handling of dry ice
COULD CAUSE SUFFOCATIONDry ice changes to CO2 gas as it sublimates, causing a lack of oxygen. Only use dry ice in open or well-ventilated areas. Do not store in confined spaces such as vehicles or garages and never store near an area where people sleep as suffocation could occur.
DO NOT TOUCHDry ice is a skin and eye irritant. Avoid contact with skin, mouth, eyes and clothing. Dry ice will cause severe burns.
DO NOT EATDry ice is harmful if eaten or swallowed. If ingested, seek medical help immediately.
DO NOT PLACE IN AIRTIGHT CONTAINERSAirtight containers may explode as dry ice converts to CO2 gas.
ive in Excellence In Dry Ice C
CONTINENTAL~ CARBONIC 0
products, inc.
WffiwNw". Internatisnal
CUSMA / USMCA IT.MECCertification of Origin
1. Exporter: (Name, Address, Country, Phone, & Email) 2. Blanket Period (Cannot exceed 12 months)
p7sm. 07101120(Mrv/DDt/Y)
To: 06130121(MM/DDft'Y)
3. Producer: (Name, Address, Country, Phone, & Email)
Continental Carbonic Products, Inc.3985 E. Harrison AveDecatur. lL 62526
4. lmporter: (Name, Address, Country, Phone, & Email)
5. Description of Good(s): Including item, part, or SKUidentification numbers, where applicable, and must tie to thedescriotion in commercial invoice.
6. HS Tariff ClassificationNumber(s) (min.6 digits)
7. OriginCriterion
8. Country of Origin
Solid Carbon Dioxide (Dry lce) 2811.21.00.00 4.2@) US
9. I CERTTFY THAT: The goods described in this document qualify as originating and the information contained in this document istrue and accurate. I assume responsibility for proving such representations and agree to maintain and present upon request or tomake available during a verification visit, documentation necessary to support this certification.
This certification consists of 1 p"q"t, includinq allattachments.
9a. Authorized Signature*:
9b. Name and Title: Lennis Hollenbeck, Controller
ec. Phone: 217 -428-2068 Fax: Email:
9d. Certifier is the: Exnorter S eroducer Q lmoorter QDate:
(rvrvr/DDr/Y)
*This certification of origin must be completed following the instructions then signed and dated by the Ceftifier.
April2o2o rtrr - 49 Avenue N.E., Catgary, Alberta, Canada TzE 8Vz Phone:403-262-277rFaxi 403-262-730l
06/30/2020
Dry Ice Technical Specifications
Physical properties
Property Value
Formula CO2
Molecular Weight 44.01
Appearance Colorless, odorless gas; colorless liquid, or white opaque solid (dry ice)
Density Solid (Dry Ice) 97.5189 lb./ft.3 at -109.3° F
Density Liquid 63.69 lb./ft.3 at 0° F
Density Gas 0.1234 lb./ft.3 at 32° F
Melting Point -69.9° F, 75.1 PSIA
Boiling Point -109.3° F (Sublimes)
Triple Point -69.9° F, 75.1 PSIA
Critical Temperature 87.8° F
Critical Pressure 1069.4 PSIA
Critical Density 28.9519 lb./ft.3
Specific Heat Gas 0.1989 BTU/lb. ° F (60° F)
Specific Heat Liquid 0.53 BTU/lb. ° F (0° F)
Ratio of Heat Capacities 1.3
Latent Heat of Fusion (Triple Point) 85 BTU/lb. (69.9° F)
Latent Heat of Vaporization (Liquiflow)
122 BTU/lb. (0° F)
Latent Heat of Sublimation (Dry Ice) 246 BTU/lb. (-110° F)
Viscosity Gas 0.015 Centipoises (32° F)
Viscosity Liquid 0.14 Centipoises (0° F)
Thermal Conductivity Gas 0.0085 BTU ft./ft.2 ° F Hr. (32° F)
Thermal Conductivity Liquid 0.11 BTU ft./ft.2 ° F Hr. (0° F)
Surface Tension (Liquid) 8.23 Dynes/cm (0° F)
Solubility in H2O 1.79 ft.3 CO2 Gas/ft.3 H2O(32° F)
May 2020
Typical Frequently Asked Quality Questions Product: Carbon Dioxide (Dry Ice) Company Information Company Name Continental Carbonic Products, INC Address 3985 E. Harrison Avenue City Decatur State IL ZIP 62526
Quality Assurance & Recall Contact Contact Name Mr. Ben Centers Title Quality and Safety Specialists Office Phone 937-316-6160 Email [email protected]
FDA REGISTRATION #: 12717876044 Quality System Does your facility currently have a FSMA Compliant Preventive Controls Program in place and that is fully implemented? Yes If yes, has the program been reviewed or updated within the past 12 months? Yes Global Food Safety Initiative (GFSI) Certification: Does your facility have current GFSI Certification? No We follow the guidelines for GFSI, please refer to Continuing Letter of Guarantee. Product Recall: Have you had to recall a product within the last five years? No Do you have Mock Recall program in place? Yes Do you have a documented Quality System in place? Yes
Good Manufacturing Practices Does your company have a written GMP policy in place? Yes Our Employees are retrained annually, contractors and visitors are to complete upon arrival. Are there hand wash sinks that are easily accessible from each workstation? Yes Sanitation/ Pest Control Is there a Master Sanitation Schedule in place? Yes All areas of the facility are maintained and records are kept by plant personnel. What methods are used to verify the effectiveness of the cleaning processes that are in place and how often is this done (ex. ATP swabs, protein swabs, etc.)? ATP Swabbing, Routinely Is there a pest control program present at your facility? Yes We contract this service out and it is done monthly. Water Please describe the source of water for the plant (i.e. well, city): Our facilities utilize city water. We test our water source annually for physical, chemical and microbiological contaminants. Any problems occurred in the last two years in regards to your water source? No Transportation of Ingredients, Products and Packaging Is there a documented shipping and receiving program in place to ensure the integrity and food safety of all transportation vehicles? Yes Are tamper evident seals being applied and documented on the Bill of Lading by a company employee on all shipments leaving your facility? Yes for Pellet type customers Do you document incoming raw material inspection, including lot # and expiration date? No
Product Labeling Does your company have a program in place to ensure that any changes to product processes or formulation are reflected on product labels are appropriate? N/A
Does your facility possess the necessary Kosher documents for the Kosher and product produced at your facilities? N/A Does your facility possess the necessary Halal documents or certificate for the product produced at your facilities? N/A If your facility produces Non-GMO product, do you have up-to-date documents that meet Non-GMO? N/A If your facility produces a gluten-free product, do you have the necessary documents? We do not produce a gluten-free product Do you conduct finished product gluten testing and if so, what are your limits (must guarantee product to be < 20 ppm)? Our product is not edible
We do not produce non-vegan food. Does your facility conduct animal testing with your products? No
Are any ingredients or processing aids from animal or insect origin (i.e. bone char, carmine, castoreum, gelatin, etc.) used when making your product? This includes raw materials and processing aids from your supplier(s). No
Does your product contain artificial ingredients, colors, or flavors? No Does your product contain natural flavors/spices? No Does your product contain maltodextrin? No
Do any of the ingredients in your product(s) contain the following or derivatives of the following: Black Pepper, Alliums (i.e. onions, leeks, garlic, etc.), potato, corn, Solanaceae (i.e. tomatoes, peppers, potatoes, eggplants, etc.), cilantro, corn (or corn derivatives), coriander, cumin, ginger, rosemary, MSG, or anise? No
Food Allergens Does your company have an allergen control program in place? Yes How often is this reviewed and updated? Annually Does your facility have a dedicated system for products that contain allergens? N/A, please refer to Continuing Letter of Guarantee Does your facility use separate scheduling and sanitation as a way to manage products containing an allergen? No Does your facility have documentation of allergen cleaning procedures that explain how to clean allergen effected equipment and visually inspect it for cleanliness? No Is the allergen-cleaning program validated for effectiveness? No Is a dual sign-off required on allergen cleaning documentation? No Microbiological Control Program Do you conduct pathogen testing on any finished products? No Do you have a proper Hold and Release program in place, if you do conduct finished product pathogen testing? No Do you have an environmental microorganism/pathogen monitoring program? Yes This is done quarterly, four per zones and plant air samples. Would you be able to supply us with a pre-shipment sample, so we would be able to conduct our own pathogen testing to make sure it meets our specifications? Yes
Warehousing / Shipping Are stocked materials being held properly in an organized manner to prevent shipping of non-conforming materials? Yes Is there a program in place to review the condition of stocked materials? No Are defective or out-of-date materials removed from inventory? Yes Is a packing slip generated for each shipment? Yes Is the packing slip checked to verify that the item description, item code, manufacturing date, shelf life, lot number, and quantity are all correct? Yes Does your facility have a stock rotation system in place (i.e. First-in, First-out)? Yes Food Safety Modernization Act (FSMA) Are you compliant with the sanitary transportation of Human & Animal Food Final Rule? Yes Are you compliant with Preventative Controls for Human Food Final Rule? Yes HARPC / FOOD Safety Plan Do you have a validated HARPC Program in Place? Yes Does your HARPC Plan address, Biological, Chemical and Physical hazards? Yes Crisis Management Do you have a written crisis management plan in place? Yes Do you have written contingency plan in place? Yes Metal Detection Does your company perform metal detection on all products that are sold? No The nature of dry ice due to extreme low temperature (-109°F). We have put clamshells on all of our machines where bolts are used. Food Defense Is your facility registered by the US Public Health Security & Bioterrorism Preparedness & Response act of 2002? Yes
Employee Training Do you have a written employee training program in place? Yes How do you verify competency of your employees following training? Our employees have continuous JTO and auditing of performance. Are all full time, part time, contract and temporary employees trained upon hire? Yes How often do you perform complete refresher training? Annually Other Do you irradiate your products? No Do you test for indicator organisms, such as APC, Coliforms, Yeast and Mold, etc.? Yes We have a 3rd party laboratory for bacteria and mold. It’s done with swabbing. What foreign material controls do you currently have in place (sieve, trays, metal detection, x-ray, etc.)? Due to the low temperature of dry ice, we do not use x-ray.
If foreign material is found, what corrective actions are taken? We move to ensure product will follow our non-conformance policy Is your company inspected by a regulatory body (USDA, FDA, etc.)? Yes We have inspections by the following agencies: OSHA & EPA Are any of the ingredients or products that you sell imported from outside the United States? No Prop 65 Responses: Please see SDS Page 6; section 15 Please explain your numbering/code date below: Our Dry Ice produced and shipped in an insulated container. The containers are marked on all four sides, tracked by digital video throughout manufacturing process. Each container has a sticker showing date / time of production along with a scannable bar code for tracking. See additional information enclosed.
INGREDIENT CRITERIA QUESTIONNAIRE
CONTAINS / PROCESSED WITH YES* NO TYPE / SOURCE
Recombinant Bovine Growth Hormone (rBGH)
X
Animal Products, Animal Tissue (excluding dairy)
X
Animal Rennet X Method of Microbial Reduction or Lethality Step
X
Irradiation Ethylene Oxide (ETO) Propylene Oxide (PPO) Steam Pasteurization Spray Drying – Time____ Temp_____ Other ______
Microbial Testing or Validation Study
X
Ethoxyquin Treatment X ppm:
Modified Food Starch
X
Source: Process:
Acid Hydrolysis Enzyme Hydrolysis Other
Maltodextrin
X
Source: Process: Acid Hydrolysis Enzyme Hydrolysis
Other Dextrose Equivalent:
Vegetable Gum (e.g. Xanthan, Acacia, etc.)
X
Hydrogenated Oil X Partially Hydrogenated Oil X Palm Oil
X Sustainably Sourced
Not Sustainably Sourced Refined, Bleached, Deodorized (RBD) Oil
X
Refined Sugars (Beet, Cane, Corn, etc.)
X
Artificial Preservatives X Artificial Sweeteners X Artificial Flavors X
Artificial Colors (e.g. Yellow 5 Tartrazine)
X
Synthetic Ingredients X Chemical Solvents X Process Aids (e.g. Propylene Glycol)
X
Yellow Prussiate of Soda X
Monosodium Glutamate (MSG) X
Added Naturally Occurring
Hydrolyzed Vegetable Protein (HVP) X Grown on land exposed to sewage sludge. X
ALLERGENS/SENSITIVITIES
Contains the Following Allergen/Sensitivity
Present in
Product (yes*/no)
Present in Other Products
Manufactured on Same Line
(yes/no)
Present in the Same
Manufacturing Plant
(yes/no)
Source of the
Allergen / Sensitivity
Present in Product
Egg No No No N/a Milk/Dairy No No No N/a Wheat No No No N/a Soy/Soybeans (not including refined oil)
No No No N/a
Fin Fish No No No N/a Crustacean Shellfish Examples: Crab, crayfish, lobster, shrimp
No No No N/a
Tree Nuts (not including refined oil)
No No No N/a
Peanuts (not including refined oil)
No No No N/a
Sensitivities N/a Celery or derivatives No No No N/a Mollusks Examples: Clams, mussels, oysters, scallops
No No No N/a
Mustard or derivatives No No No N/a Rye, barley or derivatives No No No N/a Oats or derivatives No No No N/a Seeds (Poppy, Sunflower, Cottonseed, not including refined oil)
No No No N/a
Sesame Seeds or derivatives
No No No N/a
Sulfites No No No
Added ppm: Naturally ccurring ppm:
GENERAL QUESTIONS: (please answer all questions) YES* NO EXPLANATION
Processing:
Mechanically Processed? X
Chemically Processed? X List Chemicals: CO2
Fermentation? X
Enzyme Modification? X
Other? (Please explain) N/A
Oils and Oleoresins:
Solvent extracted X List Solvents:
CO2 extracted X
Mechanically extracted (cold pressed, etc.) X
Other? (Please explain)
Miscellaneous Information:
Organic Certified? (If yes, please provide certificate) X
Organic Compatible? (i.e. not organic certified, but meets NOP requirements and can be used in organic products, other than 100% organic)
X
Contains GMO (Genetically Modified Material) X
Non-GMO: This ingredient (including processing aids, diluents & carriers) was not derived from a Genetically Engineered source material. (If ingredient complies with the statement given, please mark “Yes”)
X
IP Controlled: This ingredient (including processing aids, diluents & carriers) was not derived from Genetically Engineered source material and a documented IdentityPreserved Program is in place at the manufacture site.
X
PCR Negative: This ingredient (including processing aids, diluents & carriers) will test “negative” if a PCR test is performed
X
Continental Carbonic Products, Inc.
Lot Code Explanation
Our dry ice is produced and shipped in insulated containers. These containers are marked
with serial numbers on all four sides and are tracked by digital video throughout the
manufacturing process. Each container has a sticker showing date and time of production
(sample photo below) and is tagged with a scannable bar code which is used for tracking.