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Supporting Information BN-heteroacene-cored Luminogens with Dual Channel Detection for Fluoride Anion Jing Zhou, a, † Ruizhi Tang, a , † Xinyang Wang, a Wanzheng Zhang, a Xiaodong Zhuang, a Fan Zhang *,a Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is © The Royal Society of Chemistry 2015

Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

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Page 1: Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

Supporting Information

BN-heteroacene-cored Luminogens with Dual Channel

Detection for Fluoride Anion

Jing Zhou,a, † Ruizhi Tang,a , † Xinyang Wang,a Wanzheng Zhang,a Xiaodong Zhuang,a Fan Zhang*,a

Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.This journal is © The Royal Society of Chemistry 2015

Page 2: Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

1H, 13CNMR and HRMS spectra for new compounds

Figure S1. 1H NMR spectra of compound 2

Figure S2. 13C NMR spectra of compound 2

Page 3: Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

Figure S3. 1H NMR spectra of compound 3

Figure S4. 13C NMR spectra of compound 3

Page 4: Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

Figure S3. 1H NMR spectra of compound 4

Figure S4. 13C NMR spectra of compound 4

Page 5: Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

Figure S5. 1H NMR spectra of compound 6a

Figure S6. 13C NMR spectra of compound 6a

Page 6: Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

Figure S7. 1H NMR spectra of compound 6b

Figure S8. 13C NMR spectra of compound 6b

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Figure S9. 1H NMR spectra of compound 6c

Figure S10. 13C NMR spectra of compound 6c

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Figure S11. 1H NMR spectra of compound 6d

Figure S12. 13C NMR spectra of compound 6d

Page 9: Supporting InformationScan Beg Scan End Intens x104 420 Meas. m/z 441.2384 Active 50 miz 600 m/z 425 Formula C26H37N2S2 Set Dry Heater Set Dry Gas Set Divert Valve 430 Score 100.00

Figure S13. HRMS of 3

Figure S14. HRMS of 4

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Figure S15. HRMS of 6a

Figure S16. HRMS of 6b

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Figure S17. NMRS of 6c

Figure S18. HRMS of 6d

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Figure S19. Fluorescence decay curve for 4 in CHCl3 solution (1×10-5 M).

Figure

Figure S20. Fluorescence decay curve for 6a in CHCl3 solution (1×10-5 M).

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Figure S21. Fluorescence decay curve for 6b in CHCl3 solution (1×10-5 M).

Figure S22. Fluorescence decay curve for 6c in CHCl3 solution (1×10-5 M).

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Figure S23. Fluorescence decay curve for 6d in CHCl3 solution (1×10-5 M).