SAFETY DATA SHEET - Furniture Online · Sikadur 31 DW Comp. A SAFETY DATA SHEET Product name Sikadur 31 DW Comp. A Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United

Sikadur 31 DW Comp. A

SAFETY DATA SHEET

Product name

Sikadur 31 DW Comp. A

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

:

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

Liquid.Product type :

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of thecompany/undertaking

1.4 Emergency telephone number

Supplier

Telephone number : +44 (0)1707 363899 (available during office hours).

Not available.

+44 (0)1707 363899 (available during office hours).Emergency telephone number

Sika LimitedWatchmead Welwyn Garden CityHertfordshire. AL7 1BQUnited Kingdom

Manufacturer/Distributor

01707 394444Telephone no.

Fax no. 01707 329129

e-mail address of personresponsible for this SDS

[email protected]

:

:

:

:

:

Classification Xi; R36/38R43R52/53

:

:Human health hazards Irritating to eyes and skin. May cause sensitisation by skin contact.

:Environmental hazards Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.

See Section 11 for more detailed information on health effects and symptoms.

SECTION 2: Hazards identification2.1 Classification of the substance or mixture

Product definition : Mixture

See Section 16 for the full text of the R phrases or H statements declared above.

Classification according to Directive 1999/45/EC [DPD]

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

2.2 Label elements

Hazard symbol or symbols

R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

Risk phrases

:

:

IrritantIndication of danger :

Date of issue : 1/12210204MSDS no. :17.05.2011.


Sikadur 31 DW Comp. A 17.05.2011 2/12

SECTION 2: Hazards identification

:Other hazards which do notresult in classification

Not available.

Supplemental labelelements

: Contains epoxy constituents. See information supplied by the manufacturer.

Safety phrases S24- Avoid contact with skin.S37- Wear suitable gloves.

Hazardous ingredients

:

: reaction product: bisphenol A-(epichlorhydrin) epoxy resin (number averagemolecular weight <= 700)1,4-bis(2,3-epoxypropoxy)butane

2.3 Other hazards

reaction product: bisphenol A-(epichlorhydrin)epoxy resin (number average molecular weight<= 700)RRN: 01-2119456619-26EC: 500-033-5CAS: 25068-38-6Index: 603-074-00-8

>= 5 - < 25 Xi; R36/38

R43N; R51/53

Skin Irrit. 2, H315

Eye Irrit. 2, H319Skin Sens. 1, H317Aquatic Chronic 2, H411

[1]

1,4-bis(2,3-epoxypropoxy)butaneEC: 219-371-7CAS: 2425-79-8Index: 603-072-00-7

>= 1 - < 20 Xn; R20/21Xi; R36/38R43R52/53

Acute Tox. 4, H312Acute Tox. 4, H332Skin Irrit. 2, H315Eye Irrit. 2, H319Skin Sens. 1, H317

[1]

Calcium carbonateEC: 207-439-9CAS: 471-34-1

>= 1 - < 5 Xi; R36/38 Skin Irrit. 2, H315Eye Irrit. 2, H319

[1]

Substance/mixture Mixture

Occupational exposure limits, if available, are listed in Section 8.

:

67/548/EECProduct/ingredient nameIdentifiers

See section 16 forthe full text of theR-phrasesdeclared above

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrationsapplicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned aworkplace exposure limit and hence require reporting in this section.

SECTION 3: Composition/information on ingredients

%

Type

Regulation (EC) No.1272/2008 [CLP]

Classification

See Section 16 for thefull text of the Hstatements declaredabove.

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Type

Chemical family/Characteristics

: Filled and modified epoxy resin



Sikadur 31 DW Comp. A 17.05.2011 3/12

Do not induce vomiting unless directed to do so by medical personnel. Maintain anopen airway. Seek immediate medical attention.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing andshoes. Wash contaminated clothing thoroughly with water before removing it, or weargloves. Continue to rinse for at least 10 minutes. Get medical attention if symptomsoccur.

4.1 Description of first aid measures

Get medical attention if adverse health effects persist or are severe.

Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.

Ingestion

Inhalation

Eye contact

:

:

:

:

:

Specific treatments

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It maybe dangerous to the person providing aid to give mouth-to-mouth resuscitation. Washcontaminated clothing thoroughly with water before removing it, or wear gloves.

SECTION 4: First aid measures

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Inhalation : No known significant effects or critical hazards.

Irritating to mouth, throat and stomach.:Ingestion

Skin contact : Irritating to skin. May cause sensitisation by skin contact.

Irritating to eyes.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

Adverse symptoms may include the following:irritationredness

:

:

:

Eye contact : Adverse symptoms may include the following:irritationwateringredness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.:

Hazardous thermaldecomposition products

Hazards from thesubstance or mixture

Decomposition products may include the following materials:carbon dioxidecarbon monoxidehalogenated compoundsmetal oxide/oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Use an extinguishing agent suitable for the surrounding fire.

5.1 Extinguishing media

:

:

None known.

Suitable extinguishingmedia

:

Unsuitable extinguishingmedia

:

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters



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SECTION 5: Firefighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. This material is harmful to aquatic organisms. Fire water contaminatedwith this material must be contained and prevented from being discharged to anywaterway, sewer or drain.

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection forchemical incidents.

Special protectiveequipment for fire-fighters

:

Special protective actionsfor fire-fighters

:

6.2 Environmentalprecautions

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earthand place in container for disposal according to local regulations (see section 13).

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material.

Large spill :

Stop leak if without risk. Move containers from spill area. Absorb with an inertmaterial and place in an appropriate waste disposal container.

Small spill :

6.3 Methods and materials for containment and cleaning up

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

For non-emergencypersonnel

:

For emergency responders :

6.4 Reference to othersections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Avoid breathing vapour or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment.

If specialised clothing is required to deal with the spillage, take note of any informationin Section 8 on suitable and unsuitable materials. See also Section 8 for additionalinformation on hygiene measures.

:

:

SECTION 7: Handling and storage7.1 Precautions for safe handling

Protective measures :

Advice on generaloccupational hygiene

:

Put on appropriate personal protective equipment (see Section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist.Keep in the original container or an approved alternative made from a compatiblematerial, kept tightly closed when not in use. Empty containers retain product residueand can be hazardous.

Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipmentbefore entering eating areas. See also Section 8 for additional information on hygienemeasures.



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SECTION 7: Handling and storageStore in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatiblematerials (see section 10) and food and drink. Keep container tightly closed andsealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination.

7.2 Conditions for safestorage, including anyincompatibilities

7.3 Specific end use(s)

Recommendations :

:Industrial sector specificsolutions

Not available.

Not available.

:

Product/ingredient name Exposure limit values

Recommended monitoringprocedures

Occupational exposure limits

If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary. Reference number EN 374. Suitable for short time use orprotection against splashes: Butyl rubber/nitrile rubber gloves. (0,4 mm),breakthrough time <30 min. Contaminated gloves should be removed. Suitable forpermanent exposure: Viton gloves (0.4 mm), breakthrough time >30 min.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts.

Eye/face protection

:

:

:

Calcium carbonate EH40/2005 WELs (United Kingdom (UK), 8/2007).TWA: 10 mg/m³ 8 hour(s). Form: inhalable dust

TWA: 4 mg/m³ 8 hour(s). Form: respirable dust

Skin protection

Appropriate engineeringcontrols

: Good general ventilation should be sufficient to control worker exposure to airbornecontaminants. If this product contains ingredients with exposure limits, use processenclosures, local exhaust ventilation or other engineering controls to keep workerexposure below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing.

8.2 Exposure controls

Hygiene measures :

No DELs available.

Predicted effect concentrations

No PECs available.

SECTION 8: Exposure controls/personal protection8.1 Control parameters

Derived effect levels

Individual protection measures



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SECTION 8: Exposure controls/personal protection

No special measures required.Respiratory protection :

Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product. Recommended: Use barrier skin cream.

:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.

Body protection :

Other skin protection Appropriate footwear and any additional skin protection measures should be selectedbased on the task being performed and the risks involved and should be approved bya specialist before handling this product.

Not available.

Physical state

Melting point/freezing point

Initial boiling point and boilingrange

Vapour pressure

Relative density

Vapour density

Solubility(ies)

Paste.

Not available.

Not available.

Not available.

<0 kPa (<0.007 mm Hg)

Insoluble in the following materials: water

Odourless.Odour

pH

White.Colour

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: >101°C

Not available.

Not available.

Not available.

7.5 [Conc. (% w/w): 50%]

Viscosity Not available.

Not available.Odour threshold

Partition coefficient: n-octanol/water

Upper/lower flammability orexplosive limits

Explosive properties

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Not available.Oxidising properties :

9.1 Information on basic physical and chemical properties

Appearance

9.2 Other information

Burning time Not applicable.

Burning rate Not applicable.

:

:

Decomposition temperature : Not available.

SECTION 9: Physical and chemical properties

Flammability (solid, gas) : Not available.

No additional information.

Density : ~2 g/cm3 [20°C (68°F)]



Sikadur 31 DW Comp. A 17.05.2011 7/12

10.6 Hazardousdecomposition products

10.4 Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

The product is stable.10.2 Chemical stability

No specific data.

:

:

:

10.5 Incompatible materials :

10.3 Possibility of hazardousreactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Acute toxicity

reaction product: bisphenolA-(epichlorhydrin) epoxyresin (number averagemolecular weight <= 700)

LD50 Dermal Rabbit >20000 mg/kg -

LD50 Oral Rat >5000 mg/kg -1,4-bis(2,3-epoxypropoxy)butane

LD50 Dermal Rabbit 1130 mg/kg -

LD50 Oral Rat 1134 mg/kg -Calcium carbonate LD50 Oral Rat 6450 mg/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Not available.

Mutagenicity


Irritation/Corrosion

reaction product: bisphenolA-(epichlorhydrin) epoxyresin (number averagemolecular weight <= 700)

Eyes - Mild irritant Rabbit - 100milligrams

-

Eyes - Moderate irritant Rabbit - 24 hours 20milligrams

-

Eyes - Severe irritant Rabbit - 24 hours 5milligrams

-

Skin - Moderate irritant Rabbit - 24 hours 500microliters

-

Skin - Severe irritant Rabbit - 24 hours 2milligrams

-

1,4-bis(2,3-epoxypropoxy)butane

Eyes - Moderate irritant Rabbit - 100milligrams

-

Skin - Moderate irritant Rabbit - 24 hours 10milligrams

-

Calcium carbonate Eyes - Severe irritant Rabbit - 24 hours 750Micrograms

-


-

Product/ingredient name Result Score Exposure Observation


Sensitisation


Species

SECTION 11: Toxicological information11.1 Information on toxicological effects



Sikadur 31 DW Comp. A 17.05.2011 8/12

SECTION 11: Toxicological information

Potential chronic health effects


Inhalation : May cause irritation.

Irritating to mouth, throat and stomach.:Ingestion

Skin contact : Irritating to skin. May cause sensitisation by skin contact.

Irritating to eyes.:Eye contact

Once sensitized, a severe allergic reaction may occur when subsequently exposed tovery low levels.

General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Not available.


Carcinogenicity


Teratogenicity


Reproductive toxicity


Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion


No specific data.

Adverse symptoms may include the following:irritationredness

:

:

:

Eye contact : Adverse symptoms may include the following:irritationwateringredness

Not available.Information on the likelyroutes of exposure

:

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Long term exposure

Potential immediateeffects

Potential delayed effects :

:



:

Other information :

Not available.

Not available.

Not available.

Not available.

Not available.



Sikadur 31 DW Comp. A 17.05.2011 9/12

Mobility Not available.:

LogPow BCF Potential

12.3 Bioaccumulative potential

12.6 Other adverse effects No known significant effects or critical hazards.

Product/ingredient name

1,4-bis(2,3-epoxypropoxy)butane

-0.15 - low

12.1 Toxicity


12.2 Persistence and degradability


PBT : Not applicable.

vPvB : Not applicable.

SECTION 12: Ecological information

12.4 Mobility in soil

Soil/water partitioncoefficient (KOC)

Not available.:

12.5 Results of PBT and vPvB assessment

:

European waste catalogue (EWC)

packaging containing residues of or contaminated by dangerous substancesHazardous waste :

:Methods of disposal

SECTION 13: Disposal considerations13.1 Waste treatment methods

Product

Waste code Waste designation

08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances

The generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foulsewer but processed in a suitable effluent treatment plant. Dispose of surplus andnon-recyclable products via a licensed waste disposal contractor. Disposal of thisproduct, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.

Packaging : Completely emptied packaging or practically empty packaging containing dried/curedresidues, once relieved of all pressure can be disposed of as non-hazardous waste.

Packaging may still contain hazardous residues and disposal should undertaken by alicensed waste contractor.

Any disposal practice must be in compliance with local and national laws andregulations.



Sikadur 31 DW Comp. A 17.05.2011 10/12

-

-

-

-

Not regulated.

-

-

Not regulated. Not regulated.

- - -

SECTION 14: Transport information

ADR/RID - ADN/ADNR IMDG IATA

14.1 UN number

14.2 UN propershipping name

14.3 Transporthazard class(es)

14.4 Packing group

Additionalinformation

14.5 Environmentalhazards

14.6 Specialprecautions foruser

14.7 Transport in bulkaccording to Annex II ofMARPOL 73/78 and the IBCCode

No. No. No.

Not available. Not available. Not available.

: Not available.

Other EU regulations

Not applicable.Annex XVII - Restrictionson the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

:

Europe inventory : All components are listed or exempted.

References : Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP4)Control of Substances Hazardous to Health Regulations 2002 (COSHH) (asamended)Health & Safety at Work Act 1974The Environmental Protection (Duty of Care) Regulations 1991

SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

Substances of very high concern

None of the components are listed.

The Carriage of Dangerous Goods and Use of Transportable Pressure EquipmentRegulations 2007

Hazardous waste regulations 2005

VOC content (EU) : VOC (w/w): 0%

All substances contained in Sika Products are- preregistered or registered by our upstream suppliers, and/or- preregistered or registered by Sika, and/or- excluded from the regulation, and/or- exempted from the registration.

REACH Information: :



Sikadur 31 DW Comp. A 17.05.2011 11/12

SECTION 15: Regulatory information

15.2 Chemical SafetyAssessment

This product contains substances for which Chemical Safety Assessments are stillrequired.

:

Guidance Publications : Approved Code of Practice - Management of Health and Safety at Work, HSEGeneral Approved Code of Practice to COSHH Regulations, HSE.

R20/21- Harmful by inhalation and in contact with skin.R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

Full text of abbreviated Rphrases

:

Xn - HarmfulXi - IrritantN - Dangerous for the environment

:Full text of classifications[DSD/DPD]

Indicates information that has changed from previously issued version.

SECTION 16: Other information

Full text of abbreviated Hstatements

:

Abbreviations and acronyms : ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

Full text of classifications[CLP/GHS]

:

H312 Harmful in contact with skin.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H332 Harmful if inhaled.H411 Toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.

Acute Tox. 4, H312 ACUTE TOXICITY: SKIN - Category 4Acute Tox. 4, H332 ACUTE TOXICITY: INHALATION - Category 4Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC) - Category 2Aquatic Chronic 3, H412 AQUATIC TOXICITY (CHRONIC) - Category 3Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1

17.05.2011.

History

Date of printing

Date of issue 17.05.2011.

Notice to reader

Date of previous issue 04.05.2011.

:

:

:

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time ofpublication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consultthe product data sheet prior to any use and processing.



Sikadur 31 DW Comp. A 17.05.2011 12/12


Sikadur-31 DW Comp B

SAFETY DATA SHEET

Product name

Sikadur-31 DW Comp B


:

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

Liquid.Product type :

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of thecompany/undertaking

1.4 Emergency telephone number

Supplier

Telephone number : +44 (0)1707 363899 (available during office hours).

Not available.

+44 (0)1707 363899 (available during office hours).Emergency telephone number

Sika LimitedWatchmead Welwyn Garden CityHertfordshire. AL7 1BQUnited Kingdom

Manufacturer/Distributor

01707 394444Telephone no.

Fax no. 01707 329129

e-mail address of personresponsible for this SDS

[email protected]

:

:

:

:

:

Classification C; R34R43

:

:Human health hazards Causes burns. May cause sensitisation by skin contact.

See Section 11 for more detailed information on health effects and symptoms.

SECTION 2: Hazards identification2.1 Classification of the substance or mixture

Product definition : Mixture

See Section 16 for the full text of the R phrases or H statements declared above.

Classification according to Directive 1999/45/EC [DPD]

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

2.2 Label elements

Hazard symbol or symbols

Safety phrases S26- In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.S45- In case of accident or if you feel unwell, seek medical advice immediately (showthe label where possible).

R34- Causes burns.R43- May cause sensitisation by skin contact.

Risk phrases

:

:

:

CorrosiveIndication of danger :



Sikadur-31 DW Comp B 17.05.2011 2/11

SECTION 2: Hazards identification

:Other hazards which do notresult in classification

Not available.

Supplemental labelelements

: Not applicable.

Hazardous ingredients : Trimethylhexane-1,6-diamine

2.3 Other hazards

Trimethylhexane-1,6-diamineEC: 247-134-8CAS: 25620-58-0

>= 10 - < 20 Xn; R22C; R34R43R52/53

Acute Tox. 4, H302Skin Corr. 1B, H314Skin Sens. 1, H317Aquatic Chronic 3, H412

[1]

Calcium carbonateEC: 207-439-9CAS: 471-34-1

>= 10 - < 20 Xi; R36/38 Skin Irrit. 2, H315Eye Irrit. 2, H319

[1]

Substance/mixture Mixture

Occupational exposure limits, if available, are listed in Section 8.

:

67/548/EECProduct/ingredient nameIdentifiers

See section 16 forthe full text of theR-phrasesdeclared above

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrationsapplicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been assigned aworkplace exposure limit and hence require reporting in this section.

SECTION 3: Composition/information on ingredients

%

Type

Regulation (EC) No.1272/2008 [CLP]

Classification

See Section 16 for thefull text of the Hstatements declaredabove.

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Type

Chemical family/Characteristics

: Filled and modified polyamine

Get medical attention immediately. Do not induce vomiting unless directed to do soby medical personnel. Chemical burns must be treated promptly by a physician.Maintain an open airway.

Skin contact

Get medical attention immediately. Immediately flush eyes with plenty of water,occasionally lifting the upper and lower eyelids. Check for and remove any contactlenses. Continue to rinse for at least 10 minutes. Chemical burns must be treatedpromptly by a physician.

Get medical attention immediately. Flush contaminated skin with plenty of water.Remove contaminated clothing and shoes. Wash contaminated clothing thoroughlywith water before removing it, or wear gloves. Continue to rinse for at least 10minutes. Chemical burns must be treated promptly by a physician.

4.1 Description of first aid measures

Get medical attention immediately. If it is suspected that fumes are still present, therescuer should wear an appropriate mask or self-contained breathing apparatus.

Ingestion

Inhalation

Eye contact

:

:

:

:




Sikadur-31 DW Comp B 17.05.2011 3/11


Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.

:

Specific treatments

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it issuspected that fumes are still present, the rescuer should wear an appropriate maskor self-contained breathing apparatus. It may be dangerous to the person providingaid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughlywith water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed


Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratorysystem. Exposure to decomposition products may cause a health hazard. Seriouseffects may be delayed following exposure.

May cause burns to mouth, throat and stomach.:Ingestion

Skin contact : Corrosive to the skin. Causes burns. May cause sensitisation by skin contact.

Corrosive to eyes. Causes burns.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion


Adverse symptoms may include the following:stomach pains

Adverse symptoms may include the following:pain or irritationrednessblistering may occur

:

:

:

Eye contact : Adverse symptoms may include the following:painwateringredness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.:

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire.

Hazardous thermaldecomposition products

Hazards from thesubstance or mixture

Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidesmetal oxide/oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Use an extinguishing agent suitable for the surrounding fire.

5.1 Extinguishing media

:

:

None known.

Suitable extinguishingmedia

:

Unsuitable extinguishingmedia

:

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special protective actionsfor fire-fighters

:



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SECTION 5: Firefighting measuresFire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection forchemical incidents.

Special protectiveequipment for fire-fighters

:

6.2 Environmentalprecautions

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earthand place in container for disposal according to local regulations (see section 13).

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Absorb with an inertmaterial and place in an appropriate waste disposal container.

Small spill :

6.3 Methods and materials for containment and cleaning up

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

For non-emergencypersonnel

:

For emergency responders :

6.4 Reference to othersections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Do not breathe vapour or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment.

If specialised clothing is required to deal with the spillage, take note of any informationin Section 8 on suitable and unsuitable materials. See also Section 8 for additionalinformation on hygiene measures.

:

:

Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatiblematerials (see section 10) and food and drink. Keep container tightly closed andsealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination.

SECTION 7: Handling and storage7.1 Precautions for safe handling

Protective measures :

Advice on generaloccupational hygiene

:

7.2 Conditions for safestorage, including anyincompatibilities

7.3 Specific end use(s)

Put on appropriate personal protective equipment (see Section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Ifduring normal use the material presents a respiratory hazard, use only with adequateventilation or wear appropriate respirator. Keep in the original container or anapproved alternative made from a compatible material, kept tightly closed when not inuse. Empty containers retain product residue and can be hazardous.

Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipmentbefore entering eating areas. See also Section 8 for additional information on hygienemeasures.

:



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SECTION 7: Handling and storageRecommendations :

:Industrial sector specificsolutions

Not available.

Not available.

Product/ingredient name Exposure limit values

Recommended monitoringprocedures

Occupational exposure limits

If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

Hand protection

No special measures required.

Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary. Reference number EN 374. Suitable for short time use orprotection against splashes: Butyl rubber/nitrile rubber gloves. (0,4 mm),breakthrough time <30 min. Contaminated gloves should be removed. Suitable forpermanent exposure: Viton gloves (0.4 mm), breakthrough time >30 min.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts.

Eye/face protection

Respiratory protection :

:

:

:

Calcium carbonate EH40/2005 WELs (United Kingdom (UK), 8/2007).TWA: 10 mg/m³ 8 hour(s). Form: inhalable dust

TWA: 4 mg/m³ 8 hour(s). Form: respirable dust

Skin protection

Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product. Recommended: Use barrier skin cream.

:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.

Appropriate engineeringcontrols

: If user operations generate dust, fumes, gas, vapour or mist, use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure toairborne contaminants below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing.

8.2 Exposure controls

Hygiene measures :

No DELs available.

Predicted effect concentrations

No PECs available.

SECTION 8: Exposure controls/personal protection8.1 Control parameters

Derived effect levels

Individual protection measures

Body protection :

Other skin protection Appropriate footwear and any additional skin protection measures should be selectedbased on the task being performed and the risks involved and should be approved bya specialist before handling this product.



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SECTION 8: Exposure controls/personal protection

Not available.

Physical state

Melting point/freezing point

Initial boiling point and boilingrange

Vapour pressure

Relative density

Vapour density

Solubility(ies)

Paste.

Not available.

Not available.

Not available.

0 kPa (0.225 mm Hg)

Insoluble in the following materials: water

Amine-like.Odour

pH

Black.Colour

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: >101°C

Not available.

Not available.

Not available.

11 [Conc. (% w/w): 50%]

Viscosity Not available.

Not available.Odour threshold

Partition coefficient: n-octanol/water

Upper/lower flammability orexplosive limits

Explosive properties

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Not available.Oxidising properties :

9.1 Information on basic physical and chemical properties

Appearance

9.2 Other information

Burning time Not applicable.

Burning rate Not applicable.

:

:

Decomposition temperature : Not available.

SECTION 9: Physical and chemical properties

Flammability (solid, gas) : Not available.

No additional information.

Density : ~1.95 g/cm3 [20°C (68°F)]

10.6 Hazardousdecomposition products

10.4 Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

The product is stable.10.2 Chemical stability

No specific data.

:

:

:

10.5 Incompatible materials :

10.3 Possibility of hazardousreactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.



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Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratorysystem. May cause irritation.

May cause burns to mouth, throat and stomach.:Ingestion

Skin contact : Corrosive to the skin. Causes burns. May cause sensitisation by skin contact.

Corrosive to eyes. Causes burns.:Eye contact

Acute toxicity

Calcium carbonate LD50 Oral Rat 6450 mg/kg -

Product/ingredient name Result Species Dose Exposure


Carcinogenicity


Mutagenicity


Teratogenicity


Reproductive toxicity


Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion


Adverse symptoms may include the following:stomach pains

Adverse symptoms may include the following:pain or irritationrednessblistering may occur

:

:

:

Eye contact : Adverse symptoms may include the following:painwateringredness

Irritation/Corrosion

Calcium carbonate Eyes - Severe irritant Rabbit - 24 hours 750Micrograms

-


-

Product/ingredient name Result Score Exposure Observation


Sensitisation


Species

Not available.

SECTION 11: Toxicological information11.1 Information on toxicological effects

Information on the likelyroutes of exposure

:

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Long term exposure



:


:

Not available.

Not available.

Not available.



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SECTION 11: Toxicological information

Potential chronic health effects

Once sensitized, a severe allergic reaction may occur when subsequently exposed tovery low levels.

General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Not available.


Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.


Other information :

Not available.

Not available.

Mobility Not available.:

12.3 Bioaccumulative potential

12.6 Other adverse effects No known significant effects or critical hazards.

Not available.

12.1 Toxicity


12.2 Persistence and degradability


PBT : Not applicable.

vPvB : Not applicable.

SECTION 12: Ecological information

12.4 Mobility in soil

Soil/water partitioncoefficient (KOC)

Not available.:

12.5 Results of PBT and vPvB assessment

:

European waste catalogue (EWC)

packaging containing residues of or contaminated by dangerous substancesHazardous waste :

:Methods of disposal

SECTION 13: Disposal considerations13.1 Waste treatment methods

Product

The generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via the foulsewer but processed in a suitable effluent treatment plant. Dispose of surplus andnon-recyclable products via a licensed waste disposal contractor. Disposal of thisproduct, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.



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SECTION 13: Disposal considerations

Waste code Waste designation

08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances

Packaging : Completely emptied packaging or practically empty packaging containing dried/curedresidues, once relieved of all pressure can be disposed of as non-hazardous waste.

Packaging may still contain hazardous residues and disposal should undertaken by alicensed waste contractor.

Any disposal practice must be in compliance with local and national laws andregulations.

Corrosive solid, n.o.s.

8

III


8

III


UN1759

8

III

UN1759 UN1759

Tunnel code(E)

Emergency schedules (EmS)F-A, S-B

-

SECTION 14: Transport information

ADR/RID - ADN/ADNR IMDG IATA

14.1 UN number

14.2 UN propershipping name

14.3 Transporthazard class(es)

14.4 Packing group

Additionalinformation

14.5 Environmentalhazards

14.6 Specialprecautions foruser

14.7 Transport in bulkaccording to Annex II ofMARPOL 73/78 and the IBCCode

No. No. No.

Not available. Not available. Not available.

: Not available.

Trimethylhexamethylenediamines Trimethylhexamethylenediamines Trimethylhexamethylenediamines

Other EU regulations

Not applicable.Annex XVII - Restrictionson the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

:

SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

Substances of very high concern

None of the components are listed.

VOC content (EU) : VOC (w/w): 0%



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SECTION 15: Regulatory information

Europe inventory : All components are listed or exempted.

References : Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (CHIP4)Control of Substances Hazardous to Health Regulations 2002 (COSHH) (asamended)Health & Safety at Work Act 1974The Environmental Protection (Duty of Care) Regulations 1991

15.2 Chemical SafetyAssessment

This product contains substances for which Chemical Safety Assessments are stillrequired.

:

The Carriage of Dangerous Goods and Use of Transportable Pressure EquipmentRegulations 2007

Guidance Publications : Approved Code of Practice - Management of Health and Safety at Work, HSEGeneral Approved Code of Practice to COSHH Regulations, HSE.

Hazardous waste regulations 2005

All substances contained in Sika Products are- preregistered or registered by our upstream suppliers, and/or- preregistered or registered by Sika, and/or- excluded from the regulation, and/or- exempted from the registration.

REACH Information: :

R22- Harmful if swallowed.R34- Causes burns.R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.

Full text of abbreviated Rphrases

:

C - CorrosiveXn - HarmfulXi - Irritant

:Full text of classifications[DSD/DPD]

Indicates information that has changed from previously issued version.

SECTION 16: Other information

Full text of abbreviated Hstatements

:

Abbreviations and acronyms : ATE = Acute Toxicity EstimateCLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.1272/2008]DNEL = Derived No Effect LevelEUH statement = CLP-specific Hazard statementPNEC = Predicted No Effect ConcentrationRRN = REACH Registration Number

Full text of classifications[CLP/GHS]

:

H302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H412 Harmful to aquatic life with long lasting effects.

Acute Tox. 4, H302 ACUTE TOXICITY: ORAL - Category 4Aquatic Chronic 3, H412 AQUATIC TOXICITY (CHRONIC) - Category 3Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1BSkin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1

17.05.2011.

History

Date of printing

Date of issue 17.05.2011.

Date of previous issue 04.05.2011.

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:

:



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SECTION 16: Other informationNotice to reader

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time ofpublication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consultthe product data sheet prior to any use and processing.


Documents

SAFETY DATA SHEET - Furniture Online · Sikadur 31 DW Comp. A SAFETY DATA SHEET Product name Sikadur 31 DW Comp. A Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United