S a fe ty Da ta S he e t...C hem ic al identity ( or ingr edient nam e) : Silver B s olution ( 20x ) R ef er to Saf ety D ata Sheet ( SD S N o.G H S- 06865C E- 3) f or detailed inf

1/1

Date of issue :Revised by :

:

1. Identification of the substance or mixture and of the supplierProduct name :Name of supplier : NACALAI TESQUE, INC.

Address : 498 Higashitamaya-cho, Nijo Karasuma, Nakagyo-ku, Kyoto 604-0855 JapanDivision : Production Control DepartmentPhone : 075 932 1755F A X : 075 932 4872

Emergency phone No. : +81 75 251 1730 (International)Recommended use of the chemical(s) : Reagent, intermediate raw material of a/the chemistry articleProduct No. (SDS No.) : GHS-06865E-3

2. Composition/information on ingredientsSubstance/mixtute : MixtureChemical identity (or ingredient name) : Pretreatment stock solution (100x)

Refer to Safety Data Sheet (SDS No.GHS-06865AE-3) for detailed information.Chemical identity (or ingredient name) : Silver A solution (20x)

Refer to Safety Data Sheet (SDS No.GHS-06865BE-3) for detailed information.Chemical identity (or ingredient name) : Silver B solution (20x)

Refer to Safety Data Sheet (SDS No.GHS-06865CE-3) for detailed information.Chemical identity (or ingredient name) : Developing stock solution (20x)

Refer to Safety Data Sheet (SDS No.GHS-06865DE-3) for detailed information.

3. Other informationDISCLAIMER

For R&D use only. Not for drug, household or other uses.WARRANTY

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.

Safety Data Sheet

Sil-Best Stain One

Sil-Best Stain One, NACALAI TESQUE, INC., GHS-06865E-3, 06/01/2016

06/25/201306/01/2016

Date printed 05/27/2016

1/5


:



Emergency phone No. : +81 75 251 1730 (International)Recommended use of the chemical(s) : Reagent, intermediate raw material of a/the chemistry articleProduct No. (SDS No.) : GHS-06865AE-3

2. Hazards identificationGHS hazard class and category

PHYSICAL HAZARDS EXPLOSIVES -FLAMMABLE GASES -AEROSOLS -OXIDIZING GASES -GASES UNDER PRESSURE -FLAMMABLE LIQUIDS -FLAMMABLE SOLIDS -SELF-REACTIVE SUBSTANCES AND MIXTURES -PYROPHORIC LIQUIDS -PYROPHORIC SOLIDS -SELF-HEATING SUBSTANCES AND MIXTURES -

-

OXIDIZING LIQUIDS -OXIDIZING SOLIDS -ORGANIC PEROXIDES -CORROSIVE TO METALS -

HEALTH HAZARDS ACUTE TOXICITY - ORAL -ACUTE TOXICITY - DERMAL -ACUTE TOXICITY - INHALATION (GASES) -ACUTE TOXICITY - INHALATION (VAPOURS) -ACUTE TOXICITY - INHALATION (DUSTS AND MISTS) -SKIN CORROSION/IRRITATION -SERIOUS EYE DAMAGE/EYE IRRITATION -RESPIRATORY SENSITIZATION -SKIN SENSITIZATION -GERM CELL MUTAGENICITY -CARCINOGENICITY -REPRODUCTIVE TOXICITY -

-

-

ASPIRATION HAZARD -ENVIRONMENTAL HAZARDS -

-

HAZARDOUS TO THE OZONE LAYER -

- : Off the subject/not possible to classify

Pretreatment stock solution (100x), NACALAI TESQUE, INC., GHS-06865AE-3, 06/01/2016

06/25/201306/01/2016


HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD

SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE

HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD

Safety Data Sheet

Pretreatment stock solution (100x)

SUBSTANCES AND MIXTURES WHICH, INCONTACT WITH WATER, EMIT FLAMMABLE

SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE

2/5Pretreatment stock solution (100x), NACALAI TESQUE, INC., GHS-06865AE-3, 06/01/2016

SYMBOL -

SIGNAL WORD -

HAZARD STATEMENTSPREVENTIONRESPONSESTORAGEDISPOSAL

Other hazard statements

3. Composition/information on ingredientsSubstance/mixtute : Mixture (aqueous solution)Chemical identity (or ingredient name) : (Not available as confidential business information (CBI))Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance : None

4. First-aid measuresGeneral description of necessary first aid measures :

Inhalation :In case of accident by inhalation: remove casualty to fresh air and keep at rest.If breathing is week, irregular or has stopped, open his airway, loosen his collar and belt and administer artificial respiration.

Skin contact :Take off immediately all contaminated clothing.

Eye contact :

Ingestion :

Precaution for first-aid persons :Protect yourself by wearing rubber gloves and air-tight safety goggles.

5. Fire-fighting measuresExtinguishing media :

Incompatible extinguishing media :

Specific hazards arising from the chemical (and with regard to fire-fighting measures) :Toxic gases will form upon combustion of :

Specific fire-fighting measures :

Special protective equipment and precautions for fire-fighters :Fire-fighters should wear proper protective equipment.

-

In case of accident or if you feel unwell, seek medical advice immediately (show the label wherepossible).

After contact with skin, wash immediately with plenty of water.

Gently rinse the affected eyes with clean water for at least 15 minutes. Arrange for transport to thenearest medical facility for examination and treatment by a physician as soon as possible.

If swallowed, seek medical advice immediately and show this container or label.Rinse mouth with water. Give the person one or two glasses of water, try to get the victim to vomitby having the victim touch the back of their with a finger.Do not make an unconscious person vomit.

Not available

In case of fire, use water mist, foam/water resistant foam, powder, CO2, dry sand.Use extinguishing media appropriate to surrounding fire conditions.

Nothing particular

Move containers from fire area if it can be done without risk, if not possible, apply water from a safedistance to cool and protect surrounding area. Dry chemical powder or dry sand should be used forsmall fires.

----

Wear suitable protective clothing, gloves and eye/face protection.Avoid contact with skin and eyes.In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.In case of accident or if you feel unwell, seek medical advice immediately (showlabel where possible).


6. Accidental release measuresPersonal precautions, protective equipment and emergency procedures :

Environmental precautions :

Methods and materials for containment and clean up :

Appropriate containment techniques/clean up procedures :Shut off the leakage source and stop leak if you can do it without risk.

7. Handling and storagePrecautions for safe handling :

Countermeasure technique(s) :(Exposure control for handling personnel)Wear proper equipment and take measures according to [8. Exposure control/personal protection].

Local exhaust ventilation system/general ventilation :Ventilate according to [8. Exposure control/personal protection].

Preventive measures :

Incompatible contact(s) :See [10. Stability and reactivity].

Safety measures/incompatibility :

Conditions for safe storage, including any incompatibilities :Countermeasure technique(s) :

Incompatibilities :See [10. Stability and reactivity].

Storage :(Recommendation for storage)

Keep tightly closed in cold place.(Incompatible storage condition)

See [10. Stability and Reactivity].Recommended container and packaging materials :

Polyethylene, polypropylene, etc.

8. Exposure control/personal protectionAppropriate engineering controls :

Keep source tightly closed or install local exhaust ventilation. Provide shower and vanity unit nearby and make clear the location of these.

Control value :Japan control value

Adopted value :[JSOH]

[ACGIH]

Individual protection measures, such as personal protective equipment (PPE) :Eye/face protection :

Wear protective eyeglasses or chemical safety goggles.Wear face protection.

Hand protection :

Use with an enclosed system or a local exhaust ventilation.

Do not shock, overturn, drop, or drag containers.

Tightly closed in a well-ventilated place.

Not established.

Evacuate non-essential personnel.Wear appropriate protective clothing.

Attention should be given not to cause damage to the environment by flowing of spillage to rivers.

For small spill, absorb spill with absorbent and move to a chemical waste container. For large spill,prevent leakage by surrounded with earth and lead the spill to a safety place to collect.

Not established.

Not established.

Wear impervious glove made from chloroprene, as appropriate.


Skin and body protection :

Respiratory protection :

Protective mask

9. Physical and chemical propertiesAppearance (physical state, color, etc.) : Colorless liquidOdor : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Not availableFlash point : Not availableDensity/relative density : Not available Solubility(ies) :

Solubility in water ; Miscible

10. Stability and reactivityChemical stability :

Possibility of hazardous reactions :

Conditions to avoid :Sunlight, heat

Incompatible materials :Not available

Hazardous decomposition products (except for carbon monoxide, carbon dioxide and water) :Not available

11. Toxicological information

Acute toxicity :

Irritant properties :May irritate the eyes and skin.

Allergenic and sensitizing effects :Not available

Specific target organ systemic toxicity (single exposure, repeated exposure) :

Carcinogenic effects :Not available

Mutagenic effects :Not available

Toxicity for reproduction :Not available

12. Ecological information

Ecotoxicity :

Biotransportability :Not available

Persistence and degradability :Not available

Not available

(Insufficient data are available on the effect of this substance on human health, therefore utmostcare must be taken.)

To prevent any contact, wear impervious clothing such as apron, boots, or whole-bodysuits made from chloroprene, as appropriate.

Wear positive pressure self-contained breathing apparatus (SCBA).

Not available

Not available

(Insufficient data are available on the effect of this substance on the environment, therefore utmostcare must be taken.)

Not available

This product is considered a stable material under normal and anticipated storage and handlingconditions.


Bioaccumulative potential :Not available

13. Disposal considerationsContact a licensed professional waste disposal service to dispose of this material. Comply with all country, national and local regulations. Do not dump this product into sewers, on the ground or into any body of water.

14. Transport informationBasic classification information for the transporting/shipment :

Sea ; Not controlled under IMDG's regulations.Air ; Not controlled under IATA's regulations.

Special precautions which a user needs to be aware of or needs to comply with in connection with transport or conveyance either within or outside their premises :

15. Regulatory informationComply with all countries, national and local regulations.




Protect from direct sun light in transportation, and confirm the container does not leak. Carefullyload it onto a transporter without dropping, overturning or damaging so that it will stably stays onthe transporter.

1/6


:



Emergency phone No. : +81 75 251 1730 (International)Recommended use of the chemical(s) : Reagent, intermediate raw material of a/the chemistry articleProduct No. (SDS No.) : GHS-06865BE-3



-


HEALTH HAZARDS ACUTE TOXICITY - ORAL -ACUTE TOXICITY - DERMAL -ACUTE TOXICITY - INHALATION (GASES) -ACUTE TOXICITY - INHALATION (VAPOURS) -ACUTE TOXICITY - INHALATION (DUSTS AND MISTS) -SKIN CORROSION/IRRITATION Category 1SERIOUS EYE DAMAGE/EYE IRRITATION Category 1RESPIRATORY SENSITIZATION -SKIN SENSITIZATION -GERM CELL MUTAGENICITY -CARCINOGENICITY -REPRODUCTIVE TOXICITY -

Category 1

Category 2


-




Silver A solution (20x), NACALAI TESQUE, INC., GHS-06865BE-3, 06/01/2016

06/25/201306/01/2016




Safety Data Sheet

Silver A solution (20x)



2/6Silver A solution (20x), NACALAI TESQUE, INC., GHS-06865BE-3, 06/01/2016

SYMBOL

SIGNAL WORD Danger

HAZARD STATEMENTS

PREVENTION

RESPONSE

STORAGEDISPOSAL

3. Composition/information on ingredientsSubstance/mixtute : Mixture (aqueous solution)Chemical identity (or ingredient name) : Sodium Hydroxide, Ammonia

Chemical formula :

CAS No. :

Concentration or concentration range (or composition) (%):

Chemical No, Japan :

Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance : None


[Emergency Response Guidebook]

Causes serious eye damageCauses damage to organs (respiratory system)May cause damage to organs through prolonged or repeated exposure(respiratory system)Do not breathe dust/fume/gas/mist/vapours/spray.Wash hands thoroughly after handling.Do not eat, drink or smoke when using this product.Wear protective gloves/protective clothing/eye protection/face protection.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call aPOISON CENTER/doctor.

Store locked up.

Remove and isolate contaminated clothing and shoes.In case of contact with substance, immediately flush skin or eyes with running water for at least20 minutes.

Move victim to fresh air.Call emergency medical service.Apply artificial respiration if victim is not breathing.Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other properrespiratory medical device.

(Sodium Hydroxide) 1310-73-2(Ammonia) 1336-21-6

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skinwith water. Immediately call a POISON CENTER/doctor.IF INHALED: Remove person to fresh air and keep comfortable for breathing.Immediately call a POISON CENTER/doctor.IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. Immediately call a POISONCENTER/doctor.IF exposed or concerned: Call a POISON CENTER/doctor.Get medical advice/attention if you feel unwell.Wash contaminated clothing before reuse.

Dispose of contents/container in accordance with regulation.

(Sodium Hydroxide) (1)-410(Ammonia) (1)-314

Causes severe skin burns and eye damage

(Sodium Hydroxide) NaOH(Ammonia) NH3

(Sodium Hydroxide) 1.1 w/v(Ammonia) 5.4 w/v

Administer oxygen if breathing is difficult.

Keep victim warm and quiet.



Skin contact :[Emergency Response Guidebook]

Take off immediately all contaminated clothing.

Eye contact :

Ingestion :




Specific hazards arising from the chemical (and with regard to fire-fighting measures) :

Toxic gases will form upon combustion of :Specific fire-fighting measures :






Preventive measures for secondary accident :[Emergency Response Guidebook]

Keep unauthorized personnel away.


[Emergency Response Guidebook] Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.


[Emergency response guidebook] Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.Evacuate non-essential personnel.Wear appropriate protective clothing.


If swallowed, do not induce vomiting: seek medical advice immediately and show this container orlabel.If swallowed, rinse mouth with water (only if the person is conscious).Give plenty of water to drink.

nitrogen oxides (NOx)


Nothing particular

Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves.


For minor skin contact, avoid spreading material on unaffected skin.




Stay upwind.Keep out of low areas.Ventilate closed spaces before entering.Prevent entry into waterways, sewers, basements or confined areas.Do not get water inside containers.




Preventive measures :[Emergency Response Guidebook]













[ACGIH]



Hand protection :Wear impervious glove made from chloroprene, as appropriate.


Not established.

(Sodium Hydroxide) 2 mg/m3(Ammonia) 25ppm､17 mg/m3

(Sodium Hydroxide) STEL C 2 mg/m3(Ammonia) TWA 25 ppm､STEL 30 ppm

Avoid any skin contact.Effects of contact or inhalation may be delayed.






Gas mask

9. Physical and chemical propertiesAppearance (physical state, color, etc.) : Colorless liquidOdor : Not availablepH : Strong baseMelting point/freezing point : Not availableInitial boiling point and boiling range : Not availableFlash point : Not availableDensity/relative density : Not available Solubility(ies) :






Hazardous decomposition products (except for carbon monoxide, carbon dioxide and water) :Toxic fumes of nitrogen oxides (NOx)


Acute toxicity :[Labour Standards Law, Japan]

Toxic (Sodium Hydroxide, Ammonia)[Emergency Response Guidebook]

Oral toxicity ;rat LD50 350 mg/kg (as Ammonia Solution)

Irritant properties :Corrosive to the eyes, the skin.





Toxicity for reproduction :Not available

Causes damage to organs (respiratory system).May cause damage to organs through prolonged or repeated exposure (respiratory system).

TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death.


Not available


[Emergency Response Guidebook] Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.To prevent any contact, wear impervious clothing such as apron, boots, or whole-bodysuits made from chloroprene, as appropriate.

[Emergency Response Guidebook] Wear positive pressure self-contained breathing apparatus (SCBA).



Ecotoxicity :






Sea ; Controlled under IMDG's regulations.UN number : 3266UN Proper shipping name : CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.Class or Division : 8Subsidiary risk : -Packing group : IIMarine pollutant : Not applicable

Air ; Controlled under ICAO/IATA's regulations.UN number : 3266UN Proper shipping name : Corrosive liquid, basic, inorganic, n.o.s.Class or Division : 8Subsidiary risk : -Packing group : II






Not available



1/6


:



Emergency phone No. : +81 75 251 1730 (International)Recommended use of the chemical(s) : Reagent, intermediate raw material of a/the chemistry articleProduct No. (SDS No.) : GHS-06865CE-3



-


HEALTH HAZARDS ACUTE TOXICITY - ORAL -ACUTE TOXICITY - DERMAL -ACUTE TOXICITY - INHALATION (GASES) -ACUTE TOXICITY - INHALATION (VAPOURS) -ACUTE TOXICITY - INHALATION (DUSTS AND MISTS) -SKIN CORROSION/IRRITATION Category 1SERIOUS EYE DAMAGE/EYE IRRITATION Category 1RESPIRATORY SENSITIZATION -SKIN SENSITIZATION -GERM CELL MUTAGENICITY -CARCINOGENICITY -REPRODUCTIVE TOXICITY Category 2

Category 1

Category 1

ASPIRATION HAZARD -ENVIRONMENTAL HAZARDS Category 1

Category 1



Silver B solution (20x), NACALAI TESQUE, INC., GHS-06865CE-3, 06/01/2016

06/25/201306/01/2016




Safety Data Sheet

Silver B solution (20x)




2/6Silver B solution (20x), NACALAI TESQUE, INC., GHS-06865CE-3, 06/01/2016

SYMBOL

SIGNAL WORD Danger

HAZARD STATEMENTS

PREVENTION

RESPONSE

STORAGEDISPOSAL

3. Composition/information on ingredientsSubstance/mixtute : Substance (aqueous solution)Chemical identity (or ingredient name) : Silver Nitrate

Chemical formula :CAS No. : Concentration or concentration range (or composition) (%)

:Chemical No, Japan :

Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance : None


[Emergency Response Guidebook]

(1)-8

Causes severe skin burns and eye damage

AgNO3

12 w/v

Administer oxygen if breathing is difficult.Remove and isolate contaminated clothing and shoes.In case of contact with substance, immediately flush skin or eyes with running water for at least20 minutes.

Move victim to fresh air.Call emergency medical service.Apply artificial respiration if victim is not breathing.Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificialrespiration with the aid of a pocket mask equipped with a one-way valve or other properrespiratory medical device.

7761-88-8

Do not breathe dust/fume/gas/mist/vapours/spray.Wash hands thoroughly after handling.Do not eat, drink or smoke when using this product.Avoid release to the environment.Wear protective gloves/protective clothing/eye protection/face protection.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call aPOISON CENTER/doctor.

IF INHALED: Remove person to fresh air and keep comfortable for breathing.Immediately call a POISON CENTER/doctor.IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. Immediately call a POISONCENTER/doctor.IF exposed or concerned: Get medical advice/ attention.Get medical advice/attention if you feel unwell.Wash contaminated clothing before reuse.

Causes serious eye damageSuspected of damaging fertility or the unborn childCauses damage to organs (blood system)Causes damage to organs through prolonged or repeated exposure (lung,kidney, cardiovascular system)Very toxic to aquatic lifeVery toxic to aquatic life with long lasting effectsObtain special instructions before use.Do not handle until all safety precautions have been read and understood.

Store locked up.Dispose of contents/container in accordance with regulation.

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skinwith water. Immediately call a POISON CENTER/doctor.

Collect spillage.



Skin contact :[Emergency Response Guidebook]

Take off immediately all contaminated clothing.

Eye contact :

Ingestion :




Specific hazards arising from the chemical (and with regard to fire-fighting measures) :

Toxic gases will form upon combustion of :Specific fire-fighting measures :






Keep victim warm and quiet.Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves.


For minor skin contact, avoid spreading material on unaffected skin.



If swallowed, do not induce vomiting: seek medical advice immediately and show this container orlabel.If swallowed, rinse mouth with water (only if the person is conscious).Give plenty of water to drink.

nitrogen oxides (NOx) Silver oxides

This product itself is non-combustible.Use extinguishing media appropriate to surrounding fire conditions.

Nothing particular

For small spill, absorb spill with non-combustible absorbent and move to a chemical wastecontainer. For large spill, prevent leakage by surrounded with earth and lead the spill to a safetyplace to collect.

[Emergency Response Guidebook] Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Move containers from fire area if it can be done without risk, if not possible, apply water from a safedistance to cool and protect surrounding area.

[Emergency response guidebook] Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.Evacuate non-essential personnel.Wear appropriate protective clothing.

Do NOT let this product enter the environment.


Preventive measures for secondary accident :[Emergency Response Guidebook]

Keep unauthorized personnel away.Stay upwind.Keep out of low areas.Ventilate closed spaces before entering.Prevent entry into waterways, sewers, basements or confined areas.Do not get water inside containers.




Preventive measures :[Emergency Response Guidebook]













[ACGIH]



Hand protection :

Avoid any skin contact.Effects of contact or inhalation may be delayed.





Not established.

0.01 mg/m3 (as Ag)

TWA 0.01 mg/m3 (as Ag)




Gas mask

9. Physical and chemical propertiesAppearance (physical state, color, etc.) : Colorless liquidOdor : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Not availableFlash point : (Non-flammable)Density/relative density : Not available Solubility(ies) :




Conditions to avoid :Sunlight, heat, contact with incompatible materials

Incompatible materials :Combustible materials, reducing materials

Hazardous decomposition products (except for carbon monoxide, carbon dioxide and water) :Toxic fumes of nitrogen oxides (NOx)Toxic fumes of Silver oxides


Acute toxicity :[Emergency Response Guidebook]

Oral toxicity ;rat LD50 1173 mg/kg (as Silver Nitrate)

Irritant properties :Corrosive to the eyes, the skin.





Toxicity for reproduction :Suspected of damaging fertility or the unborn child.

[Emergency Response Guidebook] Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.To prevent any contact, wear impervious clothing such as apron, boots, or whole-bodysuits made from chloroprene, as appropriate.

[Emergency Response Guidebook] Wear positive pressure self-contained breathing apparatus (SCBA).


May react with combustible and reducing materials.


Causes damage to organs (blood system).Causes damage to organs through prolonged or repeated exposure (lung, kidney, cardiovascularsystem).

TOXIC; inhalation, ingestion, or skin contact with material may cause severe injury or death.



Ecotoxicity :

Fish toxicity :Crustacea (Daphnia magna) ; EC50/48H 0.0013 mg/L (as Silver Nitrate)



Bioaccumulative potential :There was bio-accumulation.



Sea ; Controlled under IMDG's regulations.UN number : 1760UN Proper shipping name : CORROSIVE LIQUID, N.O.S.Class or Division : 8Subsidiary risk : -Packing group : IIMarine pollutant : Not applicable

Air ; Controlled under ICAO/IATA's regulations.UN number : 1760UN Proper shipping name : Corrosive liquid, n.o.s.Class or Division : 8Subsidiary risk : -Packing group : II







Very toxic to acuatic organisms, may cause long-term adverse effects in the aquatic environment.


1/5


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Emergency phone No. : +81 75 251 1730 (International)Recommended use of the chemical(s) : Reagent, intermediate raw material of a/the chemistry articleProduct No. (SDS No.) : GHS-06865DE-3



-


HEALTH HAZARDS ACUTE TOXICITY - ORAL -ACUTE TOXICITY - DERMAL -ACUTE TOXICITY - INHALATION (GASES) -ACUTE TOXICITY - INHALATION (VAPOURS) -ACUTE TOXICITY - INHALATION (DUSTS AND MISTS) -SKIN CORROSION/IRRITATION -SERIOUS EYE DAMAGE/EYE IRRITATION -RESPIRATORY SENSITIZATION Category 1SKIN SENSITIZATION Category 1GERM CELL MUTAGENICITY -CARCINOGENICITY Category 1REPRODUCTIVE TOXICITY Category 1

-

-


-



Developing stock solution (20x), NACALAI TESQUE, INC., GHS-06865DE-3, 06/01/2016

06/25/201306/01/2016





Safety Data Sheet

Developing stock solution (20x)



2/5Developing stock solution (20x), NACALAI TESQUE, INC., GHS-06865DE-3, 06/01/2016

SYMBOL

SIGNAL WORD Danger

HAZARD STATEMENTS

PREVENTION

RESPONSE

STORAGEDISPOSAL

3. Composition/information on ingredientsSubstance/mixtute : Mixture (aqueous solution)Chemical identity (or ingredient name) :

Chemical formula :CAS No. : Concentration or concentration range (or composition) (%)

:Chemical No, Japan :

Impurities and stabilizing additives which are themselves classified and which contribute to the classification of the substance : Methanol approx.0.2w/v% (as stabilizer)



Skin contact :Take off immediately all contaminated clothing.

Eye contact :

Ingestion :


(Formaldehyde) 0.8w/v

FormaldehydeThe other ingredients are not available as confidentialbusiness information (CBI)

Take off contaminated clothing and wash it before reuse.Store locked up.Dispose of contents/container in accordance with regulation.

In case of inadequate ventilation, wear respiratory protection.IF ON SKIN: Wash with plenty of water.IF INHALED: Remove person to fresh air and keep comfortable for breathing.IF exposed or concerned: Get medical advice/ attention.If skin irritation or rash occurs: Get medical advice/attention.If experiencing respiratory symptoms: Call a POISON CENTER/doctor.

May cause an allergic skin reactionMay cause cancerMay damage fertility or the unborn childObtain special instructions before use.Do not handle until all safety precautions have been read and understood.Avoid breathing dust/fume/gas/mist/vapours/spray.Contaminated work clothing should not be allowed out of the workplace.Wear protective gloves/protective clothing/eye protection/face protection.




If swallowed, seek medical advice immediately and show this container or label.Rinse mouth with water. Give the person one or two glasses of water, try to get the victim to vomitby having the victim touch the back of their with a finger.Do not make an unconscious person vomit.

(Formaldehyde) 50-00-0

(Formaldehyde) (2)-482

May cause allergy or asthma symptoms or breathing difficulties if inhaled

(Formaldehyde) HCHO




Specific hazards arising from the chemical (and with regard to fire-fighting measures) :Toxic gases will form upon combustion of :

Specific fire-fighting measures :









Preventive measures :















Evacuate non-essential personnel.Wear appropriate protective clothing.



carbon monoxide


Nothing particular




[ACGIH]



Hand protection :



Protective mask

9. Physical and chemical propertiesAppearance (physical state, color, etc.) : Colorless liquidOdor : Not availablepH : Not availableMelting point/freezing point : Not availableInitial boiling point and boiling range : Not availableFlash point : Not availableDensity/relative density : Not available Solubility(ies) :






Hazardous decomposition products (except for carbon monoxide, carbon dioxide and water) :Not available


Acute toxicity :

Irritant properties :May irritate the eyes and skin.

Allergenic and sensitizing effects :May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause an allergic skin reaction.

Not available


Not available


(Formaldehyde) 0.1 ppm､0.12 mg/m3(Methanol) 200 ppm､260 mg/m3

(Formaldehyde) STEL C 0.3 ppm(Methanol) TWA 200 ppm､STEL 250 ppm

To prevent any contact, wear impervious clothing such as apron, boots, or whole-bodysuits made from chloroprene, as appropriate.

Wear positive pressure self-contained breathing apparatus (SCBA).


(Formaldehyde) 0.1 ppm(Methanol) 200 ppm



Carcinogenic effects :IARC-Gr.1 ; Carcinogenic to humans. (Formaldehyde)


Toxicity for reproduction :May damage fertility or the unborn child.


Ecotoxicity :






Sea ; Not controlled under IMDG's regulations.Air ; Not controlled under IATA's regulations.






Not available

Not available



Documents

S a fe ty Da ta S he e t...C hem ic al identity ( or ingr edient nam e) : Silver B s olution ( 20x ) R ef er to Saf ety D ata Sheet ( SD S N o.G H S- 06865C E- 3) f or detailed inf