© Laurent Pascal/Total

Right material for the right application

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CONTENTS

1 TOTAL- AN OVERVIEW

2 TECHNOLOGY EVOLUTION OF POLYETHYLENE

3 TOTAL - AN INVINCIBLE PLAYER IN TECHNOLOGICAL EVOLUTION

4 ROTOMOULDING INDUSTRY – CURRENT SCENARIO

5 PRODUCT UP GRADATION BY TOTAL

6 PRODUCTS FOR CUSTOMIZED APPLICATIONS

8 CONCLUSIONS

6 CONDUCTIVE ALLOYS – CANBON NANO TECHNOLOGY (CNT)

3

TOTAL IN BRIEF

4

REFINING AND CHEMICALS @THE HEART OF TOTAL

OUR KEY INDICATORS IN 2016

5

MORE THAN 700 PRODUCTION

FACILITIES

$3.96 bn*

ADJUSTED

NET INCOME

* €3.6bn

$8.8 bn

ALLOCATED

TO R&D

between 2015

and 2019

$210.1 bn*

REVENUE

* €190.7bn

$26.4 bn*

ORGANIC

INVESTMENT

* €19.9bn

EMPLOYEES

97,126

REFINING & CHEMICALS KEY INDICATORS IN 2016

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No. 1 REFINER

IN WESTERN

EUROPE

A TOP

10

GLOBAL

REFINING AND

PETROCHEMICALS

COMPANY 26

PETROCHEMICALS

FACILITIES

MT OF ETHYLENE

PRODUCTION

CAPACITY

3.8

EMPLOYEES *

49,967

2 SPECIALITY

CHEMICALS

AFFILIATES*,

HUTCHINSON

AND ATOTECH WITH

NEARLY 100 SITES

WORLDWIDE

MB/DAY

OF REFINING

CAPACITY

WORLDWIDE

2.2

* Bostik sold in early 2015 * Employees present

as of Dec. 31, 2016

7 7

TOTAL’S INTEGRATED PLATFORMS

7

Refinery

Petrochemicals Plant

Refinery + Petrochemicals complex

La Porte, Texas Bayport, Texas Carville, Louisiana Foshan

China

Dalian China

Port Arthur Normandy Antwerp Jubail Qatar Daesan

Determines and controls molecular weight and structure of polymer

• Created by right

combination of process and

catalyst

• Determines Processing

parameter, Properties, and

Applications

8

Proces

Catalyst

Product

Technological

Advancement

1

2

3

Polymerization process

and technology harvests

products

TECHNOLOGICAL ADVANCEMENT OF POLYETHYLENE –

THREE CORNER STONES

THE TECHNOLOGICAL EVOLUTION CURVE OF PE

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REVOLUTION

breakthrough

innovation

EVOLUTION

incremental

innovation

Te

ch

no

log

ica

l E

vo

lutio

n

LDPE

Linear PE/PP

Cr, Z-N

Gas phase

Metallocene

Bimodal

1930 1940 1950 1960 1970 1980 1990 2000 2010 2020

-Nano

-Bio

-Organic

-Smart Materials Science

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Polymers and

Compounds

Formulation

Powder

Quality

Rotomoulding

machine

Process conditio

ns

Rotomolded part

TOTAL - GLOBAL TECHNICAL APPROACH FOR THE ROTOMOLDING

APPLICATIONS

TP-Picture® technology

Sintering – Densification analysis

Processing window determination

TP-Picture® technology

Polymer « sagging » studies

TP-Picture® technology

3D scans/Overall shrinkage

+

Structural calculations

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ROTOCOMPOSITE

PERFORMANCE DRIVEN DEVELOPMENTS

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2d GENERATION mPE’s

3rd

GENERATION

PE’s

miPP/PLA/EVA

TP-SEAL® TP-SEAL®

BIOTP-SEAL® BIO-TPSEAL®

CONDUCTIVE

AND HFFR

ALLOYS

TIME

PE

RF

OR

MA

NC

ES

TAILORMADE

COMPOUNDS

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ROTOMOULDING INDUSTRY - CURRENT SCENARIO

Ethos

• More than 95 % of the rotomolding market is based on Polyethylene

• MFI range is from 2.0 to 4.0 gm/10 min.

• Density range is from 0.930 to 0.940 g./cc

• Almost all available rotomoulding products are made out of conventional

ZN catalyst

Pathos

• Rotomoulding industries are not able to adequately expand application bases

• Finding limitations in product substitution

Logos

• Limitations in availability of high density products

• Inadequacy in rendering required long term properties

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ROTOMOULDING INDUSTRY - CURRENT SCENARIO

• Water Tank

• Road dividers

• Heating Oil tank

• Manhole Chambers

• Playing equipment

• Pallets

• Ice Boxes

• Floats

...........................................

Typical Applications

Do all the above applications demand

same product performance?

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Stiffness

Tensile

Impact at room temp

Short-term

Properties

Fatigue/Creep

Swelling/Bulging

HDT Long-term

Properties

Products made

by ZN Catalyst

SHORT-TERM AND LONG-TERM PROPERTIES

• TOTAL’s Metallocene catalyst based resins offer excellent short term and long term

properties.

• These are designed to combine the excellent mechanical properties with a trouble free

processing.

• These new resins are able to enter applications which have generally been restricted

previously to engineering polymers

Fit Not Fit

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TOTAL is pushing the boundaries toward stiffer materials/alloys with superior

functionality and surface properties

TOTAL PUSHING THE BOUNDARIES WITH PRODUCT UPGRADATION

TOTAL has overcome the conventional challenges with high density Rotomoulding

products (High Shrinkage, Low ESCR, Low Impact, Low Durability) with its proprietary

Metallocene technology

MFI 2.5

Density 0.935, 0.940

Modulus ~850 MPa

MFI 4.0 to 6.0

Density 0.947 to 0.951

MFI 3.0 to 10.0

Modulus 1100 + MPa

Modulus ~950 to 1000 MPa

M3581UV M4041UV M3421UV

MFI 6.0 4.0 2.7

Density 0.935 0.940 0.934

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GRADE SLATE

Specialty Compound

HDPE Compound

PP Compound

Foam Compound (4-5 AND 6-7 Expansion factor)

TPSeal® /BioTPSeal®

PLA Compound (Modulus 3500 MPa)

EVA Compound

Roto lining Compound

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FOAM COMPOUND: BASED ON TOTAL METALLOCENE POLYOLEFINS

(LUMICENE® PRODUCT RANGE)

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FOAMED STRUCTURES :TP-SEAL® AND BIO-TPSEAL® STIFFNESS

« BOOSTERS »

Skin/Foam/Skin samples have been compared to monolayer parts in compression test.

Total Bottle mould used for this purpose.

- First test: single skin part compared to skin/foam/skin TP-SEAL® part produced

with the same shot weight

• Single skin part = 7.0 mm thickness

• S/F/S part = 10-11 mm foam , 3 mm outer skin , 2 mm inner skin.

- Second test: foam layer was increased to 17 mm. This was done with TP-SEAL® and

BIO-TPSEAL® parts.

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A 20mm slice of the part was cut and tested

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TP-SEAL® AND BIOTPSEAL® ROTOMOULDING TECHNOLOGIES: BASED

ON TOTAL METALLOCENE POLYOLEFINS (LUMICENE® PRODUCT

RANGE)

TP-SEAL® BioTPSeal®

• Skin/Foam/Skin mPE / mPE / mPE

• Boats

• Structural parts

• Buoys

• Skin/Skin mPE / PA11

• Low fuel permeation

Fuel tanks

(CARB/EPA – USA)

(courtesy Elkamet Germany) (courtesy Sealver (France)

• mPE-PLA alloys

• Monolayers

• Multilayers

•Skin/Foam/Skin,

•Skin/Skin

• Structural parts.

• Low warpage parts.

• Very high stiffness parts

• Surface properties

• Paintable parts

• Design parts

From Polyolefin to new Material

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TP-SEAL® AND BIOTPSEAL® SOME APPLICATIONS

A project with unique material properties for each component of

the structure:

• Excellent Surface finish for exterior/interior walls - BIO-TPSEAL®

• Low Warpage and Shrinkage for wall panels - BIO-TPSEAL®

• Roof and floors produced from TPSEAL® and HDPE for rigidity

• TPSEAL® foam used for insulation purposes

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TP-SEAL® AND BIOTPSEAL® SOME APPLICATIONS

A projects requiring Low Warpage/Shrinkage to produce a 2.4

meter panel:

• This panel was produced using BIO-TPSEAL® with 1100 MPa modulus

• No post production jigging

CONDUCTIVE ALLOYS……TOTAL’S CARBON NANO TECHNOLOGY

(CNT):

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The need for conductive materials has been globally identified in different

segments:

Packaging : Sheets, Trays, Crates etc

Dangerous good transport: IBC’s, Fuel pumps, … rotomolding potential

For the rotomolding market, only carbon black compounds are available.

These carbon black compounds are generally very weak in mechanical

performances

It is almost impossible to get an ADR approval for a rotomolded IBC’s

(Aluminum is now one of the preferred materials for this market)

Total introduced Nanotechnology based solution to overcome existing

product’s limitations

BENEFITS OF CARBON NANO TECHNOLOGY (CNT) BASED

ALLOYS

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Over alternative compounds (carbon black, carbon fibers)

High Cleanliness

Low particle generation

Low volatile emmission

Fast transition & easy cleaning

Improved “ESD” performances

Lower conductive filler loading

Higher processability (lower viscosity)

Cycle time reduction

Improved conservation of mechanical properties

Recyclability

Not sensitive to humidity

CB in commercial PS-CB

CB aspect ratio ~ 1

TOTAL’s CNT

CNT aspect ratio ~ 100 - 1000

Alloys have been produced based

on Lumicene® mPE’s :

MI2 : 4 to 8 g./10

Tensile Modulus : 600 to 800 Mpa

Rotomolding : PIAT ~225°C

Recorded resistivity:

• 3.5 to 4.0 10 E+04 Ω

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TOTAL’S CNT ALLOYS FOR ROTOMOLDING :

EASY

PROCESSING

DUCTILE AT LOW TEMPERATURE

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CONCLUSIONS

• TOTAL has very rich experience (over 20 years) in rotomoulding

industry

•TOTAL is fully committed to rotomoulding industry with its global,

independent and dedicated team comprising of in house R&D and testing

facilities in line with the needs of an increasingly global industry

• Fully owned production assets in Europe and the US offering more

freedom for strategic decisions

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