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Realistic Ways to Drastically Reduce the CO 2 Emission of Cement and Concrete Farshad Rajabipour Department of Civil and Environmental Engineering Concrete is the #1 human-made material Annual world production: ~33 billion tons = 4.4 tons/person/year 1cm (Ashby 2013) Cement CO 2 emissions = 2.3 GT/yr (~6% of total anthropogenic CO 2 emissions) CaCO ୟ୲ CaO CO Limestone, clay 1450 o C Source: PCA Cement chemistry uses most abundant elements on earth New cement plants operate near thermodynamic efficiency Only scalable, impactful, and rapidly implementable solution to curb CO 2 emissions: Use less Portland cement 1. Replace cement with supplementary cementitious materials (SCM) 0 2 4 6 8 10 12 14 16 Silica fume Waste glass Biomass ashes Natural… Slag Fly ash Portland cement Limestone Calcined clay GT/yr LC 3 reduces CO 2 emissions of cement by up to 30% ~85GT CO 2 reduction over 30 years 0 1000 2000 3000 4000 5000 6000 0 10 20 30 Compressive strength (psi) Age (day) Control LC3 SC3 ~ 30% carbon < ~5% carbon 2. Improve (double) the service life of concrete structures (100+ years) ASR damage Corrosion Asset Management New NY Bridge Conclusions and Acknowledgements Only realistic way of drastically reducing the CO 2 emission of concrete is to reduce the use of Portland cement: Replace 50% of cement with SCMs Double the service life of concrete structures

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Realistic Ways to Drastically Reduce the CO2 Emission of Cement and Concrete

Farshad Rajabipour

Department of Civil and Environmental Engineering

Concrete is the #1 human-made materialAnnual world production:

~33 billion tons = 4.4 tons/person/year

1cm

(Ashby 2013)

Cement CO2 emissions = 2.3 GT/yr(~6% of total anthropogenic CO2 emissions)

CaCO CaO CO

Limestone, clay

1450oC

Source: PCA

• Cement chemistry uses most abundant elements on earth

• New cement plants operatenear thermodynamic efficiency

Only scalable, impactful, and rapidly implementable solution to curb CO2 emissions: Use less Portland cement

1. Replace cement with supplementary cementitious materials (SCM)

0 2 4 6 8 10 12 14 16

Silica fumeWaste glass

Biomass ashesNatural…

SlagFly ash

Portland cementLimestone

Calcined clay

GT/yr

LC3 reduces CO2 emissions of cement by up to 30% → ~85GT CO2 reduction over 30 years

0

1000

2000

3000

4000

5000

6000

0 10 20 30

Com

pres

sive

stre

ngth

(psi

)

Age (day)

Control LC3 SC3~ 30% carbon

< ~5% carbon

2. Improve (double) the service life of concrete structures (100+ years)

ASR damage Corrosion

Asset Management

New NY Bridge

Conclusions and AcknowledgementsOnly realistic way of drastically reducing the CO2 emission of concrete is to reduce the use of Portland cement:

• Replace 50% of cement with SCMs• Double the service life of concrete structures