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    Borders of quantum physicsHenrik Ekerfelt, 2011-05-13

    I. INTRODUCTION

    The sometimes irrational behavior of quantum systems is considered complex and non-

    intuitive. They lack reference in our day-to-day life making them hard to grasp. For many of

    us quantum physics is regarded as a non-applicable mathematical theory. While at the same

    time, physicists claim that quantum physics is the best tool we have to describe reality. No

    other theory can make such exact predictions, but what are the limits? Plancks constant, a

    reoccurring figure in most quantum equations, is so small that when one tries to describe

    macroscopic objects the quantum effects would be insignificant. Even bacteria remain

    unaffected, but what happens if one looks inside the living organisms? Zooming in to a levelwhere the basic process of life is performed, one will be looking at the nanometer scale. Here

    quantum phenomena are expected to be directly influential. It is widely debated how much

    quantum laws have had a part in the development and the processes of life. While some

    scientist claim that there is no advanced underlying quantum mechanism in life, others even

    go as far and hypothesize that life itself could be a quantum phenomenon. But what can we

    say with certainty so far and what can we expect? In this paper I will discuss the borders

    between quantum and classical physics.

    II. BORDERLAND

    A. Quantum phenomena

    When speaking of quantum physics there

    are several phenomena involved, and it

    remains questionable if all of them end

    at the same experimental values.

    1. Quantum tunneling

    There is a chance for particles to tunnel

    through barriers that would be impossibleto cross in the classic world. This

    phenomenon is responsible for alpha-decay

    and also occurs in everyday electronic

    devices to name a few applications.

    2. Particle-wave duality

    A phenomenon in which all matter can be

    described both as a wave and as a particle.

    3. Discreteness of quantum measurements

    Nature seems to have a finite number ofenergy levels in which a particle can exist.

    4. Quantum entanglement

    States that if two particles are entangled

    one of them cantbe described without the

    other. This is the basis of e.g. quantum

    encryption and teleportation.

    5. The Pauli principle

    No two fermions can have the samequantum numbers.

    6. Quantum randomness

    As of now there is no method to predict the

    exact outcome of an experiment. The only

    possibility is to calculate the different

    probabilities.

    B. Experimental environment

    When observing the quantum phenomenain an experiment setting scientists most

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    likely will use an ultrahigh vacuum and

    ultralow temperature which renders an

    environment where the quantum effects are

    dominant. This makes it possible to

    measure the effects. However, one of the

    problems is that it leaves the question how

    much the quantum phenomena affect the

    macroscopic world unanswered e.g. the

    process in a living cell. (Arndt [2])

    In nature the thermal disturbance makes it

    hard to observe the coherence. Interaction

    with other particles leads to entanglement,

    resulting in collapsed wave function thus

    making it hard to define any exact borderfor the phenomena. (Arndt [2])

    1. The double slit

    It has been more than 200 years since

    Young first conducted his famous double

    slit experiment (see Fig. 1) proving light

    had wave properties, or in his case, that

    light was some kind of wave. Since then,

    modern physics has been developed at an

    increasing speed.

    Figure 1. The double slit experiment setup1

    .

    In the early years of the twentieth century,

    Albert Einstein, Niels Bohr, de Broglie,

    Erwin Schrdinger and Paul Dirac amongst

    others received the Nobel prize in physics

    for their contributions to theoretical atomic

    physics. They had all contributed to the

    theory of quantum mechanics and its

    widespread phenomena. In 1929 the first

    1http://upload.wikimedia.org/wikipedia/

    commons/4/4c/Ebohr1.svg

    slit experiments were setup with electrons,

    by Davisson and Germer (Davisson [4]),

    showing that they, just like light, also

    embodies wave characteristics like de

    Broglie had predicted.

    During the following 70 years, the same

    experiment was setup with neutrons, atoms

    and dimers, all showing the same expected

    results. But how complex can molecules

    get before the wave-function collapses?

    Theory and experiments shows that if any

    information about the particles path is

    obtained, the wave function collapses.

    In 1999 this experiment was successfully

    conducted with fullerenes, a spherical

    carbon molecule shaped almost like a

    football(see Fig. 2). The fullerene has a

    diameter of almost 1 nm which makes it at

    least a 100 000 bigger than a neutron. A

    comparison between the experimental

    results and theory tells us that the

    molecule acts as a single heavy particle.

    Another interesting aspect is the hightemperature in the molecules during the

    experiment, which shows that the thermal

    energy does not affect the superposition of

    de-Broglie-waves (Arndt [1]).

    Figure 2.The structure2.

    2

    Michael Strck (2006),http://upload.wikimedia.org/wikipedia/commons/4/

    41/C60a.png

    http://upload.wikimedia.org/wikipedia/http://upload.wikimedia.org/wikipedia/http://upload.wikimedia.org/wikipedia/http://upload.wikimedia.org/wikipedia/
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    C. Biology

    Studying the borders of quantum

    phenomena are especially interesting in

    molecular biology since this is where life,

    and all its mystery, begins. It is important

    to mention that today the scientific society

    just has begun exploring this school of

    science. There are a lot of hypotheses and

    much remains to be scientifically proven or

    disregarded. For example some scientists

    claim that our consciousness and mind are

    too complex to be described by classical

    physics.

    In a biological environment, quantumtunneling was first shown to appear in

    1956 (Marcus [3]). Since then it has been

    shown to be a part of the famous

    photosynthesis process (Blackenship [5])

    and it also plays a part in electron transport

    along DNA (Winkler [6]). More recently,

    protons have been experimentally proven

    to tunnel (Cha [7]). By replacing hydrogen

    cores with deuterium (hydrogen with an

    extra neutron) cores, it can be shown that

    tunneling is part of some processes since

    tunneling depends on the mass of the

    object. It has also been suggested that

    small molecules, consisting of a few atoms

    only, possibly could tunnel but this theory

    still lacks supports from experiments

    (Arndt [2]).

    Another widely discussed topic is quantumtunneling being a part of our sense of

    smell. The functions of the receptors are

    well defined by classic laws but some

    questions remain, e.g. how mankind are

    able to distinguish particles with similar

    size and characteristics, like OH and SH

    (Turin [8]).

    Entanglement has recently been shown to

    persist in macroscopic thermal states(Markham [9]) and can be traced in the

    thermodynamic variables. Despite the fact

    that there is a large loss of information

    compared to single atomic measurements it

    remains a very interesting discovery since

    it shows that entanglement influences the

    thermal state.

    1.Photosynthesis

    This widely known process that converts

    carbon dioxide into sugars by absorbing

    light is one of the basic facts about life, yet

    the specifics remain to be discovered.

    There are different kinds of photosynthesis

    on earth but common for all is that they

    absorb sunlight and turn it into chemicallybound energy. As evolution has developed

    this process over millions of years, it might

    not be very surprising that it serves as a

    role model for todays scientist when they

    try to create solar cells (Blankenship [10]).

    The more we study this process the more

    we learn that it involves more complex

    processes than we imagined. For example

    theres long ranged excitation transfer,hydrolysis (water is turned into hydrogen),

    proton transport, redox-reactions

    (molecules have their oxidations number

    changed) and phosphorylation (a process

    that activates or deactivates enzymes).

    Some of these may actually require

    coherence, tunneling or entanglement to be

    described fully. Worth mentioning is that

    all of these processes are extremely fast,measuring just a few femtoseconds

    (Brixner [11]).

    First, in photosynthesis a photon is

    absorbed by a pigment molecule. Then the

    energy is used to excite an electron which

    begins a very complex chain of energy

    transportation. All resulting in chemical

    potentials. Studies show that this transport

    is much optimized. A quick process is vitalsince any kind of delay most probably

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    would result in thermal instead of chemical

    energy (van Grondelle [12]).

    Attempts to explain this with classical

    physics fail to explain the speed efficiency

    of the transport. Delocalization and

    coherent excitation between the pigment

    proteins has been suggested as the most

    likely explanation (Arndt [2]). Coherence,

    lasting for as long as a few hundred

    femtoseconds over the width of several

    nanometers, has been observed in

    laboratories (Collini [13]).

    What part does the constructive/destructive

    interference play?

    In fact this process is so efficient that it has

    been considered that quantum information

    processing is used, could some kind of

    quantum algorithm provide the information

    on the fastest route? (Engel [14]) Another

    suggestion is quantum random walks,

    where the positions of the random walker

    would be a superposition of positions(Mohseni [15]).

    2. Evolution

    In 1988 John Cairns wrote an article on the

    spontaneity of mutations. He suggests that

    mutations might not be entirely random.

    Supporting his suggestion is an experiment

    which shows that starving bacteria have a

    higher mutation rate than those fed. This

    indicates that there might be somethingtriggering evolution (Cairns [16]).

    In the book Darwins black box, the

    biochemist Michael J Bethe mentions

    irreducible complexity. Here he claims that

    there are some things that are too complex

    to have evolved e.g. the human eye and the

    bacteria flagella. He states that if just one

    part is removed they will be useless. The

    existence of simpler eyes e.g. light

    sensitive cells makes this statement

    questionable. (McFadden [17])

    However he also mentions the chemical

    processes surrounding ATP (An energy

    transporter in the living cell). To the best

    of our knowledge, the only way to make

    ATP is from another molecule called

    AMP, which requires a thirteen step

    process each involving a specific enzyme.

    If one step is skipped it will be entirely

    useless. This is a problem for todays

    evolutionary biologists. How could this

    have evolved? Some suggests that it

    happened backwards, AMP could haveexisted in the primordial soup and when it

    ran out there was first a one step process to

    create it, and then two steps, etc.

    (McFadden [17]))

    McFadden on the other hand said this is

    highly unlikely since nothing supports the

    fact that AMP would have existed in

    sufficient amounts. Instead he suggests

    quantum physics has a big role to play inevolution (McFadden [17]).

    3. Mystery of life

    The biggest mystery of life is the question

    about how it all started, how did life really

    begin? The smallest self-replicating

    molecule found by scientists contains 32

    amino acids. Assuming that, even though

    its highly unlikely, the amino acids only

    could bind with other amino acids in the

    primordial soup, there would be

    possible proteins. This fact would suggest

    that occurrence of life is very unlikely

    (McFadden [17]).

    Taking into account that it seems as if life

    sprung into existence as soon as it was

    possible (when earth cooled down and

    primordial soups existed) this doesntmake sense. Indicating that there should be

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    something with the beginning of life that is

    yet to be discovered (McFadden [17]).

    III. DISCUSSION

    I expect that sooner rather than later,

    quantum physics will be a widely accepted

    part in the process of life. To what extent it

    influences is hard to tell, but personally I

    find it hard to believe that quantum physics

    wouldnt play a vital part. Today our

    knowledge of its part is limited to just a

    few molecules, but is it possible that there

    could be a bigger picture here as well? One

    could interpret the facts McFadden discussin his book as if the bigger picture actually

    exists. Still the whole idea is still on the

    hypothesis stage with few experiments

    supporting it.

    Maybe this topic will be one of the most

    investigated topics in the twenty-first

    century, who knows what will be found?

    IV. CONCLUSION

    The subject seems to have an increasing

    popularity throughout the scientific

    society. There are a lot of hypotheses on

    the subject, some more believable than

    others. Too few are tested, or could be

    tested, experimentally yet. In the following

    100 years, we may expect the picture of

    what life is will change.

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    3.Marcus, RA (1956). Theory of oxidation-reduction reactions involving

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