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Borders of quantum physicsHenrik Ekerfelt, 2011-05-13
I. INTRODUCTION
The sometimes irrational behavior of quantum systems is considered complex and non-
intuitive. They lack reference in our day-to-day life making them hard to grasp. For many of
us quantum physics is regarded as a non-applicable mathematical theory. While at the same
time, physicists claim that quantum physics is the best tool we have to describe reality. No
other theory can make such exact predictions, but what are the limits? Plancks constant, a
reoccurring figure in most quantum equations, is so small that when one tries to describe
macroscopic objects the quantum effects would be insignificant. Even bacteria remain
unaffected, but what happens if one looks inside the living organisms? Zooming in to a levelwhere the basic process of life is performed, one will be looking at the nanometer scale. Here
quantum phenomena are expected to be directly influential. It is widely debated how much
quantum laws have had a part in the development and the processes of life. While some
scientist claim that there is no advanced underlying quantum mechanism in life, others even
go as far and hypothesize that life itself could be a quantum phenomenon. But what can we
say with certainty so far and what can we expect? In this paper I will discuss the borders
between quantum and classical physics.
II. BORDERLAND
A. Quantum phenomena
When speaking of quantum physics there
are several phenomena involved, and it
remains questionable if all of them end
at the same experimental values.
1. Quantum tunneling
There is a chance for particles to tunnel
through barriers that would be impossibleto cross in the classic world. This
phenomenon is responsible for alpha-decay
and also occurs in everyday electronic
devices to name a few applications.
2. Particle-wave duality
A phenomenon in which all matter can be
described both as a wave and as a particle.
3. Discreteness of quantum measurements
Nature seems to have a finite number ofenergy levels in which a particle can exist.
4. Quantum entanglement
States that if two particles are entangled
one of them cantbe described without the
other. This is the basis of e.g. quantum
encryption and teleportation.
5. The Pauli principle
No two fermions can have the samequantum numbers.
6. Quantum randomness
As of now there is no method to predict the
exact outcome of an experiment. The only
possibility is to calculate the different
probabilities.
B. Experimental environment
When observing the quantum phenomenain an experiment setting scientists most
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likely will use an ultrahigh vacuum and
ultralow temperature which renders an
environment where the quantum effects are
dominant. This makes it possible to
measure the effects. However, one of the
problems is that it leaves the question how
much the quantum phenomena affect the
macroscopic world unanswered e.g. the
process in a living cell. (Arndt [2])
In nature the thermal disturbance makes it
hard to observe the coherence. Interaction
with other particles leads to entanglement,
resulting in collapsed wave function thus
making it hard to define any exact borderfor the phenomena. (Arndt [2])
1. The double slit
It has been more than 200 years since
Young first conducted his famous double
slit experiment (see Fig. 1) proving light
had wave properties, or in his case, that
light was some kind of wave. Since then,
modern physics has been developed at an
increasing speed.
Figure 1. The double slit experiment setup1
.
In the early years of the twentieth century,
Albert Einstein, Niels Bohr, de Broglie,
Erwin Schrdinger and Paul Dirac amongst
others received the Nobel prize in physics
for their contributions to theoretical atomic
physics. They had all contributed to the
theory of quantum mechanics and its
widespread phenomena. In 1929 the first
1http://upload.wikimedia.org/wikipedia/
commons/4/4c/Ebohr1.svg
slit experiments were setup with electrons,
by Davisson and Germer (Davisson [4]),
showing that they, just like light, also
embodies wave characteristics like de
Broglie had predicted.
During the following 70 years, the same
experiment was setup with neutrons, atoms
and dimers, all showing the same expected
results. But how complex can molecules
get before the wave-function collapses?
Theory and experiments shows that if any
information about the particles path is
obtained, the wave function collapses.
In 1999 this experiment was successfully
conducted with fullerenes, a spherical
carbon molecule shaped almost like a
football(see Fig. 2). The fullerene has a
diameter of almost 1 nm which makes it at
least a 100 000 bigger than a neutron. A
comparison between the experimental
results and theory tells us that the
molecule acts as a single heavy particle.
Another interesting aspect is the hightemperature in the molecules during the
experiment, which shows that the thermal
energy does not affect the superposition of
de-Broglie-waves (Arndt [1]).
Figure 2.The structure2.
2
Michael Strck (2006),http://upload.wikimedia.org/wikipedia/commons/4/
41/C60a.png
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C. Biology
Studying the borders of quantum
phenomena are especially interesting in
molecular biology since this is where life,
and all its mystery, begins. It is important
to mention that today the scientific society
just has begun exploring this school of
science. There are a lot of hypotheses and
much remains to be scientifically proven or
disregarded. For example some scientists
claim that our consciousness and mind are
too complex to be described by classical
physics.
In a biological environment, quantumtunneling was first shown to appear in
1956 (Marcus [3]). Since then it has been
shown to be a part of the famous
photosynthesis process (Blackenship [5])
and it also plays a part in electron transport
along DNA (Winkler [6]). More recently,
protons have been experimentally proven
to tunnel (Cha [7]). By replacing hydrogen
cores with deuterium (hydrogen with an
extra neutron) cores, it can be shown that
tunneling is part of some processes since
tunneling depends on the mass of the
object. It has also been suggested that
small molecules, consisting of a few atoms
only, possibly could tunnel but this theory
still lacks supports from experiments
(Arndt [2]).
Another widely discussed topic is quantumtunneling being a part of our sense of
smell. The functions of the receptors are
well defined by classic laws but some
questions remain, e.g. how mankind are
able to distinguish particles with similar
size and characteristics, like OH and SH
(Turin [8]).
Entanglement has recently been shown to
persist in macroscopic thermal states(Markham [9]) and can be traced in the
thermodynamic variables. Despite the fact
that there is a large loss of information
compared to single atomic measurements it
remains a very interesting discovery since
it shows that entanglement influences the
thermal state.
1.Photosynthesis
This widely known process that converts
carbon dioxide into sugars by absorbing
light is one of the basic facts about life, yet
the specifics remain to be discovered.
There are different kinds of photosynthesis
on earth but common for all is that they
absorb sunlight and turn it into chemicallybound energy. As evolution has developed
this process over millions of years, it might
not be very surprising that it serves as a
role model for todays scientist when they
try to create solar cells (Blankenship [10]).
The more we study this process the more
we learn that it involves more complex
processes than we imagined. For example
theres long ranged excitation transfer,hydrolysis (water is turned into hydrogen),
proton transport, redox-reactions
(molecules have their oxidations number
changed) and phosphorylation (a process
that activates or deactivates enzymes).
Some of these may actually require
coherence, tunneling or entanglement to be
described fully. Worth mentioning is that
all of these processes are extremely fast,measuring just a few femtoseconds
(Brixner [11]).
First, in photosynthesis a photon is
absorbed by a pigment molecule. Then the
energy is used to excite an electron which
begins a very complex chain of energy
transportation. All resulting in chemical
potentials. Studies show that this transport
is much optimized. A quick process is vitalsince any kind of delay most probably
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would result in thermal instead of chemical
energy (van Grondelle [12]).
Attempts to explain this with classical
physics fail to explain the speed efficiency
of the transport. Delocalization and
coherent excitation between the pigment
proteins has been suggested as the most
likely explanation (Arndt [2]). Coherence,
lasting for as long as a few hundred
femtoseconds over the width of several
nanometers, has been observed in
laboratories (Collini [13]).
What part does the constructive/destructive
interference play?
In fact this process is so efficient that it has
been considered that quantum information
processing is used, could some kind of
quantum algorithm provide the information
on the fastest route? (Engel [14]) Another
suggestion is quantum random walks,
where the positions of the random walker
would be a superposition of positions(Mohseni [15]).
2. Evolution
In 1988 John Cairns wrote an article on the
spontaneity of mutations. He suggests that
mutations might not be entirely random.
Supporting his suggestion is an experiment
which shows that starving bacteria have a
higher mutation rate than those fed. This
indicates that there might be somethingtriggering evolution (Cairns [16]).
In the book Darwins black box, the
biochemist Michael J Bethe mentions
irreducible complexity. Here he claims that
there are some things that are too complex
to have evolved e.g. the human eye and the
bacteria flagella. He states that if just one
part is removed they will be useless. The
existence of simpler eyes e.g. light
sensitive cells makes this statement
questionable. (McFadden [17])
However he also mentions the chemical
processes surrounding ATP (An energy
transporter in the living cell). To the best
of our knowledge, the only way to make
ATP is from another molecule called
AMP, which requires a thirteen step
process each involving a specific enzyme.
If one step is skipped it will be entirely
useless. This is a problem for todays
evolutionary biologists. How could this
have evolved? Some suggests that it
happened backwards, AMP could haveexisted in the primordial soup and when it
ran out there was first a one step process to
create it, and then two steps, etc.
(McFadden [17]))
McFadden on the other hand said this is
highly unlikely since nothing supports the
fact that AMP would have existed in
sufficient amounts. Instead he suggests
quantum physics has a big role to play inevolution (McFadden [17]).
3. Mystery of life
The biggest mystery of life is the question
about how it all started, how did life really
begin? The smallest self-replicating
molecule found by scientists contains 32
amino acids. Assuming that, even though
its highly unlikely, the amino acids only
could bind with other amino acids in the
primordial soup, there would be
possible proteins. This fact would suggest
that occurrence of life is very unlikely
(McFadden [17]).
Taking into account that it seems as if life
sprung into existence as soon as it was
possible (when earth cooled down and
primordial soups existed) this doesntmake sense. Indicating that there should be
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something with the beginning of life that is
yet to be discovered (McFadden [17]).
III. DISCUSSION
I expect that sooner rather than later,
quantum physics will be a widely accepted
part in the process of life. To what extent it
influences is hard to tell, but personally I
find it hard to believe that quantum physics
wouldnt play a vital part. Today our
knowledge of its part is limited to just a
few molecules, but is it possible that there
could be a bigger picture here as well? One
could interpret the facts McFadden discussin his book as if the bigger picture actually
exists. Still the whole idea is still on the
hypothesis stage with few experiments
supporting it.
Maybe this topic will be one of the most
investigated topics in the twenty-first
century, who knows what will be found?
IV. CONCLUSION
The subject seems to have an increasing
popularity throughout the scientific
society. There are a lot of hypotheses on
the subject, some more believable than
others. Too few are tested, or could be
tested, experimentally yet. In the following
100 years, we may expect the picture of
what life is will change.
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Vedral, (2009) Quantum physics meets biology,
HFSP Journal.
3.Marcus, RA (1956). Theory of oxidation-reduction reactions involving
electron transfer. J. Chem. Phys. 24(5), 966978.
4. Davisson, C.J. Germer, L.H. The scattering of
electron by a single crystal of nickel. Nature 119,
558-560 (1927).
5. Blankenship, RE (1989). Special issue -
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7. Cha, Y, Murray, C, and Klinman, J (1989).
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