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IntroductionWhat is solid?
Fixed shape & volume
Molecules closely packed, vibrates about fixed positions
Strong intermolecular bonds
What is liquid?Indefinite shape & fixed volume
Molecules in clusters, slide over one another
Weak intermolecular bonds
SolidsCrystalline molecular structure
Molecules vibrate about fixed positions
Heat increases vibrations
Melting pointmolecules start to flow
lose crystalline structure
Distinct phase transitionmelting/freezing involves heat of fusion
LiquidsViscosity: resistance to flow
e.g. water 0.01 poise; thick oil 1.0 poise
Cooling a liquid - increases viscosity
Below melting pointmolecules form crystals and solidify
Super-cooled liquid - remains liquid below freezing point
Depends on nucleation sites
What is Glass Made of?2 types:
Natural Glass and Man-made Glass
Natural GlassFormed when rocks melt
Lightning
Volcanic eruptions
Amorphous structure
High Silicon Dioxide(SiO2) capacity
Examples: Obsidian and Tektite
Man-made GlassMade of sand, soda ash & limestone
Heated to a high temperature
Cooled
Transparent, non-crystalline material formed
Who and How was Glass Discovered?
Natural glassIn use since the stone age
Man-made glassIn use as far back as 5000 years ago
Discovered by the ancient Egyptians
How Glass is FormedSupercooled liquid cools further
Molecules remain disordered
Develops rigidity
Becomes amorphous solid
e.g. amorphous ice forms at -137 °C
Glass is formed in this manner
Glass is Liquid?Old glass panes thicker at the bottom than the top
Some glass panes sagged
Some have rippled surfaces
Glass is a liquid with very high viscosity?
Solid has viscosity ≥ 1013 poiseLiquid has viscosity < 1013 poise
Proof: Glass does not flowExcellent images of telescope lenses
Stone age arrow heads remain sharp
Excellent condition of 1st century A.D. Roman glassware
Stone Age Arrow Head
1st Century A.D. Roman Glassware
Acknowledgementhttp://www.wisegeek.com/what-is-glass.htmhttp://www.glassonline.com/infoserv/history.htmlhttp://www.coleparmer.com/techinfo/techinfo.asp?htmlfile=Properties_Glass.htm&ID=608http://math.ucr.edu/home/baez/physics/General/Glass/glass.htmlhttp://abyss.uoregon.edu/~js/ast123/lectures/lec04.htmlhttp://www.google.com/imgres?imgurl=http://www.b14643.de/Tektites/Vredefort_1.jpg&imgrefurl=http://www.b14643.de/Tektites/index.htm&h=264&w=365&sz=16&tbnid=YXuCMoxBWuI06M:&tbnh=88&tbnw=121&prev=/images%3Fq%3Dnatural%2Bglasses&usg=__VrGWsbDtjM_owIIzwTP2wGCF3sU=&ei=wzXZS_PjOcOyrAeXtJTTDw&sa=X&oi=image_result&resnum=2&ct=image&ved=0CAgQ9QEwAQ
Acknowledgementhttp://wiki.answers.com/Q/Who_discovered_glasshttp://wiki.answers.com/Q/What_is_the_structure_of_glasshttp://en.wikipedia.org/wiki/Glasshttp://image.absoluteastronomy.com/images/encyclopediaimages/a/ar/arrowhead.jpghttp://www.youtube.com/watch?v=f2XQ97XHjVw&feature=relatedhttp://www.youtube.com/watch?v=gi-ITHJuTpQ&feature=relatedhttp://internationaltradecommodities.suite101.com/article.cfm/how_is_glass_made