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PRE – FEASIBILITY PROJECT REPORT
for
CAPACITY EXPANSION
OF LPG BOTTLING PLANT,OF EASTERN GASES LIMITED
BIBINAGAR
Submitted by
BIBINAGAR, DISTRICT – NALGONDA
TELENGANA - 508126
EASTERN GASES LIMITED
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
BHARAT PETROLEUM CORPORATION LTD
OVERALL CONTENT
CLAUSE NO. DESCRIPTION PAGE NO.
EXECUTIVE SUMMARY 1-1
1.0 BACKGROUND INFORMATION 2-3
2.0 PROJECT DESCRIPTION 4-8
3.0 SITE ANALYSIS 9-10
4.0 PROPOSED INFRASTRUCTURE 10-11
5.0 REHABILITATION & RESETTLEMENT
PLAN
12-12
6.0 PROJECT SCHEDULE AND COST
ESTIMATE
12-12
7.0 ANALYSIS OF PROPOSAL 13-13
TABLE-1 CLIMATOLOGICAL DATA 14-14
FIG. - 1 SITE LOCATION MAP 15-15
ATTACHMENT - 1 PLOT PLAN
ATTACHMENT- 2 MATERIAL SAFETY DATA SHEET
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 1 - .
EXECUTIVE SUMMARY
Eastern Gases Limited is a well-known name in the Private LPG bottling and distribution
segment. The company caters to the requirement of industrial and commercial consumer. EGL
was incorporated in 1995 under company’s Act 1956 to deal in LPG and other allied products.
EGL deals in LPG, Propane, Butane and Ammonia for industrial and commercial usage. The
company is a “single-point source” for a Packed LPG & Bulk LPG under its own brand name
“East Gas”.
EGL has tie-up with Indian Oil Petronas Pvt. Ltd. (IPPL) who imports, markets and
distributes bulk LPG, Propane and Butane. EGL can efficiently cater to the requirement of
industrial user and packed users of LPG as well as Auto LPG segment. Currently, the
companies own Refilling Outlets chain of Auto LPG presently in Eastern India and company
has a vision to setup ALDS all over India. Apart from ALDS company has LPG Bottling
plants at Durgapur, Bangalore and Bibinagar.
The proposed project is an expansion project of the existing Plant with existing storage
capacity of 90 MT. After expansion, total storage capacity of the Plant will be 180 MT. The
Plant mainly has facilities for blending of Propane/Butane and storage & filling of LPG
Cylinders of different capacity.
The project envisages installation of 3 bullets. In two of their proposed bullets propane and
butane to be sourced from IPPL, Enore Plant, will be stored. Propane, Butane & Marcaptan
will be blended and LPG will be stored in the third bullet. All the mitigation measures for the
existing plant as well as for proposed expansion will be in line with the existing practice to
meet the environmental standards and environmental operating conditions for the expansion
project. Fire fighting facilities will be as per the recommendations of OISD 169. No R & R
issue is involved with proposed expansion.
Since the proposed expansion is not a major one, it is envisaged to complete the whole
expansion within One Year from the date of according Environmental Clearance (EC) for the
proposed Project.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 2 - .
1.0 BACKGROUND INFORMATION
1.1 Identification of Project and Project Proponent
Eastern Gases Limited is a well-known name in the Private LPG bottling and distribution
segment. The company caters to the requirement of industrial and commercial consumer. EGL
was incorporated in 1995 under company’s Act 1956 to deal in LPG and other allied products.
In the year 2002,. In companies own bottling plant located at Durgapur and Bibinagar at
Nalgonda, Telengana, cylinders of required sizes are filled for distribution to the industrial
commercial consumers.
EGL deals in LPG, Propane, Butane and Ammonia for industrial and commercial usage. The
company is a “single-point source” for a Packed LPG & Bulk LPG under its own brand name
“East Gas”.
EGL has tie-up with Indian Oil Petronas Pvt. Ltd. (IPPL) who imports, markets and
distributes bulk LPG, Propane and Butane. EGL can efficiently cater to the requirement of
industrial user and packed users of LPG as well as Auto LPG segment. Currently, the
companies own Refilling Outlets chain of Auto LPG in Eastern India and company has a
vision to setup ALDS all over India.
The proposed project is an expansion project of the existing Plant with existing storage
capacity of 90 MT. After expansion, total storage capacity of the Plant will be 180 MT. The
existing Plant mainly has facilities for storage & filling of LPG Cylinders of different capacity.
EGL has also many Terminals & LPG Bottling & ALDS Plant spread across the country. EGL
now proposes to expand the capacity of the existing LPG Plant at Bibinagar, Telengana by
adding three additional storage Vessels.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 3 - .
1.2 Nature of the Project The proposed project is an expansion project of the existing LPG storage & Bottling Plant.at
Bibinagar, at Telengana. 3 No. storage Vessel of 30 MT each for storage of Propane, Butane &
LPG are proposed to be installed are increasing storage in the existing plant with 180 MT
storage capacity.
1.3 Need for the Project and Its Importance
The proposed expansion project at Bibinagar in Telengana will improve supply position of the
LPG which is vital for economic growth as well as improving the quality of life. The
improved LPG supply will have strong logistical support for delivering the products to
customers without interruption. The project will also provide indirect employment to
unskilled, semiskilled and skilled categories.
1.4 Employment Generation Potential
At present total 14 no of employees are engaged for total operation of Bibinagar LPG Plant.
Out of 14 staffs, 1is Managerial staff, 5 semi-skilled workers, 4 unskilled workers & 4 are
security guard. Operation of the Plant will be managed with the exiting staffs after installation
of the Bullets.
However, the proposed project has the potential of indirect employment generation.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 4 - .
2.0 PROJECT DESCRIPTION
Type of Project
Project Proposal envisages enhancement of storage capacity by installation of 3 no. storage
Vessel of 30 MT each
Location
The Project Site is located at 12 km from the Bibinagar Village, 2 km away from NH-2
& 1.55 Km away from Bibinagar Railway Station.
The approximate longitude-latitude of the centroid of the proposed site is as
follows:
Longitude : 17028’28.21” N
Latitude : 78048’29.36”E The plant location is furnished in Fig. 1: Site Location Map.
Details of Alternate Sites
No alternative site is considered since the proposed tanks will be installed
within the premises of the existing LPG storage & Bottling plant in which all
infrastructure facilities exist.
Plant Capacity
The existing as well as capacity after proposed expansion of the plant is
furnished as follows:
Name of Product
Existing Capacity (MT)
Proposed Capacity Expansion(MT)
Total Capacity (MT)
LPG 3 x 30 - 90 PROPANE - 1 X 30 30 BUTANE - 1 X 30 30 LPG 1 X 30 30
Total Capacity After Expansion 180
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 5 - .
Plant Layout
The layout showing existing as well as proposed expansion is furnished as
Attachment - 1: Overall Plot Plan.
Process Description
The LPG Plant mainly has facilities for storage & filling of LPG Cylinders.
Brief process description is as follows:
o The product is received through Road Tanker.
o Product is stored in above ground bullets.
o Filling of cylinder of various capacity.,
o storage of filled cylinders and distribution to dealers by truck.
LPG STORAGE
LPG Pump
LPG BULK TANKER
LPG CYLINDER FILLING
QUALITY CHECKS
DESPATCH OF FILLED CYLINDERS
STORAGE OF FILLED CYLINDERS
LPG PUMP
PROPANE STORAGE
BUTANE STORAGE
PUMP
UNIT FILLING MACHINE
CYLINDER LOADING
HOT AIR SCALING
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 6 - .
Land Requirement
Total land area available in Bibinagar LPG Plant is around 7.06 acres. Total
land is under possession of EGL.
Water Requirement and Source
The maximum water consumption during operation (considering capacity
expansion) of the plant is 10Kl/day.
The water requirement is met through bore well within the premises.
Power Requirement
Power requirement for the existing plant is 125 KVA. For the existing project,
power is received from the substation of Southern Power Distribution
Company OF Telengana Ltd power requirement will remain same after the
proposed expansion.
DG Set
The following stand by generators have been installed for maintaining operation
during power cut.
Capacity (KVA) NOS
125 1
The DG sets have tall stack as specified by CPCB. DG stack height for the existing plant is 3 m. All the DG sets are provided with acoustic enclosures.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 7 - .
Vent Stack
Vent Stack height is provided as 65 m for the existing plant.
Details of Storage
Existing Storage
SL. NO. DESCRIPTION TOTAL
CAPACITY
1 3 No of Storage Vessel of capacity 30 MT each 90 MT
TOTAL CAPACITY 90 MT
Proposed Storage
SL. NO. DESCRIPTION TOTAL
CAPACITY
1 3 No. of Storage Vessel of capacity 30 MT each 90 MT
TOTAL CAPACITY 90 MT
Fire Water Storage
Existing fire water storage capacity is 650 KL (2 x 325kl). No additional fire water tank is envisaged for the proposed expansion as the existing fire water storage capacity is adequate for meeting emergencies.
.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 8 - .
Fire Water Pump
Sr.No Category No’s Capacity
1 Main Pump ( Fire Engine Driven) 2 171 m3/hr
2 Jockey Pump ( Electric Motor Driven) 1 16 m3/hr
Fire Fighting Facility
Existing fire fighting facility will be upgraded during the proposed expansion
of the Bibinagar LPG Plant at Bibinagar village. There will be provision of
fire fighting equipments for the proposed expansion as per OISD 169.
Fire Detection & Alarm System
2 fire alarm are installed, 5 manual call points are installed in the existing plant.
Fire Protection System
The existing fire water net work will be extended to form a loop around Plant.
The proposed Bullets will be provided with Medium Velocity water spray
system.
Hydrocarbon Detectors
One Hydrocarbon detectors are installed at strategic locations of the existing
plant.
Plant Automation System
LPG is pumped to unit LPG filling machines from which the cylinders of
different sizes are filled under pressure
The system described is intended for filling standard LPG cylinder for
industrial with a minimum number of operations, with process, production and
monitoring function carried out with the help of sophisticated equipment and
control system.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 9 - .
3.0 SITE ANALYSIS
Connectivity
The nearest railway station is Bibinagar which is about 1.55 km from the
Project Site. Nearest domestic airport is Rajiv Gandhi International Airport
which is at a distance of about 35 km from Project Site. Bibinagar Industrial
Area is well accessible by road
Existing Land Use
The project is an expansion project for installation of 3 No. of Bullets 30 MT
each. The new Bullets will be erected within the existing boundary; hence
additional space is not required. Thus, no change in land use is envisaged.
Location of Sensitive Receptors
There is 3 Reserve Forest within 10 km from the study area.
They are Bibinagar Reserve Forest, Kondamadugu Reserve forest & Naginenifalli
Reserve forest.
Land Ownership
The total land has been purchased from the erstwhile owner. And possession of
EGL.
Existing Infrastructure
All infrastructural facilities of the existing LPG Plant will be used for the
project.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 10 - .
Climatic Data from Secondary Sources
The permanent meteorological station, closest to the proposed site, is at
Bibinagar. Fifty years (1901- 2000) climatological data for Bibinagar
observatory, as published by India Meteorological Department is furnished as
Table 1. 4.0 PROPOSED INFRASTRUCTURE
Infrastructural Facilities
Since the proposed Project is an expansion of the existing LPG Plant, it will use
all the infrastructural facilities of the existing plant.
Air Pollution Management
The air pollution mitigative measures conceived for the project is summarized
below:
- Water spraying is conceived to minimize dust pollution during excavation
and earth work (during construction phase).
- The DG sets have tall stack as specified by CPCB
- A greenery is also developed along plant boundary to restrict air pollution.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 11 - .
Water Pollution Management
Wastewater Management philosophy is based on following:
- Sanitary waste water from toilets and wash rooms are treated in septic
tanks and disposed off through soak pits.
- Non-sanitary waste water generated during mock fire drills i.e. only
once in 6 month is passed discharged into natural drainage system.
- During rainy season, the rain water is recharged back to earth
Noise Pollution Management
The following noise abatement measures are practiced for the LPG bottling plant ,
Bibinagar village
- The equipment, which is the source of noise, has built-in type noise
control abatement technology.
- A greenery is already developed around plant boundary and other
strategic locations to reduce noise pollution.
Solid Waste Management
- Practically, no Solid Waste shall be generated from operation the plant
after expansion.
- Used oil, grease and empty drums shall be disposed of through
registered vendors as per Handling of Waste Material and
Transboundary Rules, 2008 and subsequent amendments.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 12 - .
5.0 REHABILITATION AND RESETTLEMENT (R & R) PLAN
No new land acquisition is involved with the proposed expansion of the LPG Plant . The
existing LPG Plant at Bibinagar has enough space within its plant boundary to
accommodate the expansion. Thus no R & R issue is involved with this proposed
expansion.
6.0 PROJECT SCHEDULE AND COST ESTIMATE
Project Schedule
Since the proposed expansion is not a major one, it is envisaged to complete
the whole expansion within one year from the date of according Environmental
Clearance (EC) for the proposed Project.
Project Cost
Total project cost for the proposed expansion is around Rs 1616.73 Lacs.
Details project cost enclosed in annexure
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 13 - .
7.0 ANALYSIS OF PROPOSAL
The different benefits of the proposed Project are furnished below:
Meeting National as well as Regional Demand
The proposed project will improve supply position of the LPG in Bibinagar as well as
in the state of Telengana, which is vital for economic growth as well as improving the
quality of life. The improved LPG supply will have strong logistic support for
delivering the products to customers without interruption. The project will also provide
indirect employment to unskilled, semiskilled and skilled categories.
Physical Infrastructure
Sate Highway runs in close proximity to the existing plant area. Establishment of large
developmental projects of this category will improve availability of the physical
infrastructures like approach roads, drainage, communication and transportation
facilities etc.
Social Infrastructure
Implementation of the project will indirectly boost up the social infrastructure of the
surrounding, like local education, medical and communication of the whole
surrounding area.
Employment Potential
The proposed expansion will indeed generate some indirect employment potential. In
addition to this, additional jobs will be generated by local business in supply of goods and
services.
Thus, the proposed project has ushered in the social and economic upliftment of the
persons living in the vicinity of the Project i.e. of society at large.
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 14 - .
Table-1
Monthly mean maximum & minimum temperature and total rainfall based upon
1901-2000
Month Period No.of Year Temperature ( 0c) Rainfall
(mm) Max Min
January 1901-2000 100 26.0 13.7 13.3
February 1901-2000 100 29.0 16.6 25.6
March 1901-2000 100 33.7 21.4 33.3
April 1901-2000 100 35.7 24.9 51.2
May 1901-2000 100 35.5 26.1 126.2
June 1901-2000 100 32.0 26.5 282.4
July 1901-2000 100 31.8 26.2 339.8
August 1901-2000 100 32.0 26.1 333.2
September 1901-2000 100 31.7 25.9 277.2
October 1901-2000 100 29.3 23.9 138.9
November 1901-2000 100 26.4 18.8 23.9
December 1901-2000 100 23.7 14.2 6.4
Data source : www.imd.gov.in
PRE-FEASIBILTY REPORT FOR CAPACITY EXPANSION OF BIBINAGAR LPG PLANT AT BIBINAGAR, TELENANA
EASTERN GASES LIMITED - 15 - .
FIG-1
- 16 -
Material Safety Data Sheet of Propane
1. Chemical Identification
Chemical Name : Propane Synonyms : Propane. Chemical classification : Flammable Gas - Category 1, Gases under Pressure - liquefied gas, Carcinogenicity - Category 1B, Mutagen city - Category 1B Specific Target Organ Toxcity (Single Exposure) - Category 3 Trade name : Propane U.N.No. : 1978 Formula : Propane, Component C.A.S No. Weight Propane 74-98-6 85-100 Propylene 115-07-1 0-15 Butane and heavier 106-97-8 0-2,5 Ethane 74-84-0 0-5 Ethyl Mercaptan (Odorant) 75-08-1 <0.0025 Shipping name : Propane. Regulated identification : Propane. Hazardous waste ID No. : NA. Hazchem No. : Class2.1
Hazardous Ingredients:-
Hazardous Approximate C.A.S. No. LD 50/LC 50 Exposures Ingredients. Concentration(%) specify species Limits. & Route.
a) Propane 50-60 200-827-9 Not available/inh 4hrs 1000 lpm.(OEL) & 658 g/m3. 1000 lpm(TLV1)
[ OEL= 8 hr Alberta Occupational Exposure Limit ] [ TLV = Threshold Limit Value ( 8 hrs) ] 1 As Aliphatic Hydrocarbon Gases
2. Physical & Chemical data
Physical state Liquefied Gas Boiling Range / points -42.110C
Molecular weight 44.096 g/mol Solid Phase: Melting Point: 187.680C Latent heat of fusion (1.012bar at
melting point):- 79.917 KJ/KG Liquid Density: 580.88 Kg/m3 Vapour Pressure(210C or 700F)) 8.587 bar Critical temperature: 96.740C Critical Pressure: 42.51 bar
Critical Density: 220.48 kg/m3 Triple point temperature 187.620C Triple point pressure 1.724x10-19 Solubility in water {1.013 bar and 200C
(680F)} 0.039 Val/Vol
Gas Density(1.013 bar at boiling point) 2.417 kg/m3 Specific gravity (liquid) 5.00-0.510(water=1) Specific Gravity (vapor) 1.52(Air=1) Specific Volume 0.546m3/kg
Liquid to vapor expansion ratio 1:270 Vapor pressure(maximum) 208PSIG@100degrees F)
3. Fire and Explosion Hazards Data: Appearance Flammability limits in air(STP) 2.2-9.5 LEL by volume 2.15 UEL by volume 9.6 Flash Point 1560F Evaporation rate: <1 diffuses readily) Sensitivity to Static discharge Yes, May ignite Means of extinction Foam, CO2, dry chemical Powder, Explosive
accumulations can build up in areas of poor ventilation.
Special Procedure Use water spray to cool fire exposed containers and disperse Gas if Leak has not ignited. If safe To do, cut off fuel and allow flame to burn out.
Hazardous Ploymerisation :
Combustible Liquid : Yes Explosive material : Yes Corrosive material : No Flammable material : Yes Oxidizer : NA Other : NA Pyrophoric material : NA Organic peroxide : NA
4. Reactivity Data
Chemical stability : Stable Condition : Not applicable Incompatibility with other material : Chlorine and other strong oxidizing agents. Reactivity : Yes Conditions : heat, strong sunlight Hazardous Reaction Product : On fire it will liberate some amount carbon monoxide, and Carbon-di-oxide.
5. Health Hazards Data
Routes of Entry : Inhalation , eye contact. Effects of Exposure symptoms : Inhalation can cause head ache, disorientation, dizziness
drossiness and possibly unconsciousness. Evidence exists that butane and propane can cause these effects at concentrations for below those require for oxygen deficiency, for example 10% LEL and above. As concentration increases, oxygen deficiency and asphyxiation may occur. Rapidly expanding gas are vaporized liquid may cause frostbite to skin and eyes.
Emergency Treatment : in case of contact with Skin flush with fresh with fresh water ,
remove containment clothing, in case of excessive inhalation move the victim to fresh air, obtain medical assistance.
Sensitization to Product : No Exposure limit of Product : 1000 lpm(OEL,TLV) Irritancy : Not available. Synergistic materials : None reported. Chronic exposure : Weakness, coughing, labored breathing, headache confusion
nausea/vomiting convulsions heart rate and pulse variations coma respiratory failure.
NFPA Hazards Health Flammability Instability Special Signals 1 4 0 none HMIS ratings Health Flammability physical hazards 1 4 1
6. Preventive measures: Personal Protective equipment : use Positive pressure self contained breathing apparatus
Or supplied air breathing apparatus when entering areas where high concentration may be presents.
a) Gloves: Insulated gloves. b) Respiratory Protection: SCBA ar SABA. c) Eye: splash goggles and face shield if SCBA or SABA not warn.
Handling and storage Precautions : Aroid contact with liquid cooled equipment, Avoid inhalation, avoid sparking condition store in a cool, dry, well ventilated area away from heat, strong sunlight and ignition source.
Keep away from fire, sparks & heated surfaces no smoking near
areas where material is stared or handled. The product should only be stored and handled in areas with intrinsically safe electrical classification.
7. Emergency and First aid measures:
Suitable Fire Extinguishing media : Foam, dry chemical powder, co2, containers which are not cooled with water spray
Extinguishing media to avoid : water Caution about specific danger in case of : Danger of violent reaction or explosion, vapors Fire and fire fighting procedures may travel considerable distances and cause
subsequent ignition. Vapors are heavier than air, may cumulate along the round in enclosed spaces – danger of explosion when burning; it emits carbon monoxide & CO2 and irritant fumes.
Fire Special procedures : Shut off leak, if safe to do so,. Keep non –involved
people away from spill site. Issue warning “ FLAMMABLE” . Eliminate all sources of ignition.
Unusual Hazards : Vapor heavier than Air it will spread along the the ground and collect in sewer. Exposure First Aid measures : Skin contact ; in freeze burn occurs, gently Bathe affected area in warm water (38-43)0C. Do not rub get medical attention Eye : Immediately flash with large amounts of Luke warm water for 15 minutes, lifting upper & lower lids at intervals. Seek medical attention If irritation persists.
Inhalation: Remove to fresh air, give oxygen, artificial respiration or CPR needed seek medical attention Ingestion : Usually no effect by this Route
Antidotes/Dosages : NA
Spills Steps to be taken : Shut off leak , if safe to do so, Keep non – Involved people away from spillage site.
Eliminate all sources of ignition. Prevent spill entering in to sewers, for Major spillage contact emergency services.
Waste disposal Method : NA
Material Safety Data Sheet of Butane
1. Chemical Identification
Chemical Name : Butane Synonyms : Butane. Chemical classification : Flammable Gas - Category 1, Gases under Pressure - liquefied gas, Carcinogenicity - Category 1B, Mutagen city - Category 1B Specific Target Organ Toxicity (Single Exposure) - Category 3 Trade name : Butane U.N.No. : 1075 Formula Component Description Butane (C4 H10) CH3- CH2-CH2-CH3 Shipping name : Butane. Regulated identification : Butane. Hazardous waste ID No. : NA. Hazchem No. : Class2.1
Hazardous Ingredients:-
Hazardous Approximate C.A.S. No. LD 50/LC 50 Exposures Ingredients. Concentration(%) specify species Limits. & Route.
a) Butane 50-60 106-97-8 Not available/inh 4hrs 1000 lpm.(OEL) & 658 g/m3. 1000 lpm(TLV1)
[ OEL= 8 hr Alberta Occupational Exposure Limit ] [ TLV = Threshold Limit Value ( 8 hrs) ] 1 As Aliphatic Hydrocarbon Gases
2. Physical & Chemical data
Physical state Liquefied Gas Boiling Range / points (-)0.50C Molecular Weight 58.122g/mol Solid Phase Melting Pointe (-138.290C) Appearance & Odour Colourless, Odourless Vapour Pressure(PSIG) 16.54 psig@700 F(210c) Solubility in water Not soluble Specific Gravity water 2.01@700 F(210c) @1 atm Critical Temperature 151.980C Critical Pressure 37.96bar Critical Density 228kg/m3 Triple Point Temperature -38.260C Triple Point Pressure 6.736x10-6 Viscosity 1.013bar & 00 C (320F) Thermal Conductive 013bar
3. Fire and Explosion Hazards Data: Appearance Flammability Limits in Air (STP Condensation) 1.5-8.5 LEL by volume 1.6 UEL by volume 8.4 Flash Point -760 F (690C) Auto ignition 5500F(2870C) Sensitivity to Static discharge Yes, May ignite Means of extinction Foam, CO2, dry chemical Powder, Explosive
accumulations can build up in areas of poor ventilation.
Special Procedure Use water spray to cool fire exposed containers and disperse Gas if Leak has not ignited. If safe To do, cut off fuel and allow flame to burn out.
Hazardous Ploymerisation :
Combustible Liquid : Yes Explosive material : Yes Corrosive material : No Flammable material : Yes Oxidizer : NA Other : NA Pyrophoric material : NA Organic peroxide : NA
4. Reactivity Data
Chemical stability : Stable Condition : Not applicable Incompatibility with other material : Chlorine and other strong oxidizing agents. Reactivity : Yes Conditions : heat, strong sunlight Hazardous Reaction Product : On fire it will liberate some amount carbon monoxide, and Carbon-di-oxide.
5. Health Hazards Data
Routes of Entry : Inhalation , eye contact. Effects of Exposure symptoms : Inhalation can cause head ache, disorientation, dizziness
drossiness and possibly unconsciousness. Evidence exists that butane and propane can cause these effects at concentrations for below those require for oxygen deficiency, for example 10% LEL and above. As concentration increases, oxygen deficiency and asphyxiation may occur. Rapidly expanding gas are vaporized liquid may cause frostbite to skin and eyes.
Emergency Treatment : in case of contact with Skin flush with fresh with fresh water ,
remove containment clothing, in case of excessive inhalation move the victim to fresh air, obtain medical assistance.
Sensitization to Product : No Exposure limit of Product : 1000 lpm(OEL,TLV) Irritancy : Not available. Synergistic materials : None reported. Chronic exposure : Weakness, coughing, labored breathing, headache confusion
nausea/vomiting convulsions heart rate and pulse variations coma respiratory failure.
NFPA Hazards Health Flammability Instability Special Signals 1 4 0 none HMIS ratings Health Flammability physical hazards 1 4 2
6. Preventive measures: Personal Protective equipment : use Positive pressure self contained breathing apparatus
Or supplied air breathing apparatus when entering areas where high concentration may be presents.
a) Gloves: Insulated gloves. b) Respiratory Protection: SCBA ar SABA. c) Eye: splash goggles and face shield if SCBA or SABA not warn.
Handling and storage Precautions : Aroid contact with liquid cooled equipment, Avoid inhalation, avoid sparking condition store in a cool, dry, well ventilated area away from heat, strong sunlight and ignition source.
Keep away from fire, sparks & heated surfaces no smoking near
areas where material is stared or handled. The product should only be stored and handled in areas with intrinsically safe electrical classification.
7. Emergency and First aid measures:
Suitable Fire Extinguishing media : Foam, dry chemical powder, co2, containers which are not cooled with water spray
Extinguishing media to avoid : water Caution about specific danger in case of : Danger of violent reaction or explosion, vapors Fire and fire fighting procedures may travel considerable distances and cause
subsequent ignition. Vapors are heavier than air, may cumulate along the round in enclosed spaces – danger of explosion when burning; it emits carbon monoxide & CO2 and irritant fumes.
Fire Special procedures : Shut off leak, if safe to do so,. Keep non –involved
people away from spill site. Issue warning “ FLAMMABLE” . Eliminate all sources of ignition.
Unusual Hazards : Vapor heavier than Air it will spread along the the ground and collect in sewer. Exposure First Aid measures : Skin contact ; in freeze burn occurs, gently Bathe affected area in warm water (38-43)0C. Do not rub get medical attention Eye : Immediately flash with large amounts of Luke warm water for 15 minutes, lifting upper & lower lids at intervals. Seek medical attention If irritation persists.
Inhalation: Remove to fresh air, give oxygen, artificial respiration or CPR needed seek medical attention Ingestion : Usually no effect by this Route
Antidotes/Dosages : NA
Spills Steps to be taken : Shut off leak , if safe to do so, Keep non – Involved people away from spillage site.
Eliminate all sources of ignition. Prevent spill entering in to sewers, for Major spillage contact emergency services.
Waste disposal Method : NA
Material Safety Data Sheet of LPG
1. Chemical Identification
Chemical Name : LPG Synonyms : Liquefied Petroleum Gas. Chemical classification : Flammable Gas - Category 1, Gases under Pressure - liquefied gas, Carcinogenicity - Category 1B, Mutagen city - Category 1B Specific Target Organ Toxcity (Single Exposure) - Category 3 Trade name : LPG U.N.No. : 1203 Formula : Mixture MAINLY Propane & Butane, Component C.A.S No. Weight Propane (C3 H8) 74-98-6 60-90% Butane (C4 H10) 106-97-8 10-30% Propane Propylene 115-07-1 1-5% Isobutene (C4 H10) 75-28-5 1-5% 1,3- Butadiene (C4 H6) 106-99-0 0-02% Shipping name : Liquified Petroleum gas. Regulated identification : LPG. Hazardous waste ID No. : NA. Hazchem No. : Class2.1
Hazardous Ingredients:-
Hazardous Approximate C.A.S. No. LD 50/LC 50 Exposures Ingredients. Concentration(%) specify species Limits. & Route.
a) Butane 50-60 106-97-8 Not available/inh 4hrs 1000 lpm.(OEL) & 658 g/m3. 1000 lpm(TLV1)
b) Ethane <5 74-84-0 Not available. 1000 lpm(TLV1) c) Propane 40-50 74-98-6 Not available 1000 lpm.
(OEL,TLV1) [ OEL= 8 hr Alberta Occupational Exposure Limit ] [ TLV = Threshold Limit Value ( 8 hrs) ] 1 As Aliphatic Hydrocarbon Gases
2. Physical & Chemical data
Physical state Liquefied Gas Boiling Range / points (-)270c Melting / freezing points (-) 170OC to (-) 187Oc Appearance & Odour Colorless, Odorless ( or may have
Mercaptan odour) Vapour Pressure(KPA) 1100 @ 200
C Vapour Density (Air-1) 1.6 - 2.0 Solubility in water Negligible Specific Gravity water 0.53 PH Not applicable. Evaporation rate Not available. Percent Volatiles, by volume 100 Odour Threshold (PPM) Range from 2500 to 5000. Coefficient of water / Oil Distribution <0.1
Initial Boiling point & range -0.50c (31.1F) at 1,013.25 hPa Relative density 0.56 at 150c
3. Fire and Explosion Hazards Data: Appearance Flammability Yes LEL by volume 1.8% to 5.3% UEL by volume 8.5% to 15% Flash Point (-)560c to (-)600c Auto ignition 4100c-5400c TDG Flammability classification Class 2.1 Sensitivity to impact Na. Sensitivity to Static discharge Yes, May ignite Means of extinction Foam, CO2, dry chemical Powder, Explosive
accumulations can build up in areas of poor ventilation.
Special Procedure Use water spray to cool fire exposed containers and disperse Gas if Leak has not ignited. If safe To do, cut off fuel and allow flame to burn out.
Hazardous Ploymerisation :
Combustible Liquid : Yes Explosive material : Yes Corrosive material : No Flammable material : Yes Oxidizer : NA Other : NA Pyrophoric material : NA Organic peroxide : NA
4. Reactivity Data
Chemical stability : Stable Condition : Not applicable Incompatibility with other material : Chlorine and other strong oxidizing agents. Reactivity : Yes Conditions : heat, strong sunlight Hazardous Reaction Product : On fire it will liberate some amount carbon monoxide, and Carbon-di-oxide.
5. Health Hazards Data
Routes of Entry : Inhalation , eye contact. Effects of Exposure symptoms : Inhalation can cause head ache, disorientation, dizziness
drossiness and possibly unconsciousness. Evidence exists that butane and propane can cause these effects at concentrations for below those require for oxygen deficiency, for example 10% LEL and above. As concentration increases, oxygen deficiency and asphyxiation may occur. Rapidly expanding gas are vaporized liquid may cause frostbite to skin and eyes.
Emergency Treatment : in case of contact with Skin flush with fresh with fresh water ,
remove containment clothing, in case of excessive inhalation move the victim to fresh air, obtain medical assistance.
Sensitization to Product : No Exposure limit of Product : 1000 lpm(OEL,TLV) Irritancy : Not available. Synergistic materials : None reported. Chronic exposure : Weakness, coughing, labored breathing, headache confusion
nausea/vomiting convulsions heart rate and pulse variations coma respiratory failure.
NFPA Hazards Health Flammability Instability Special Signals 2 4 0 none HMIS ratings Health Flammability physical hazards 1 4 2
6. Preventive measures: Personal Protective equipment : use Positive pressure self contained breathing apparatus
Or supplied air breathing apparatus when entering areas where high concentration may be presents.
a) Gloves: Insulated gloves. b) Respiratory Protection: SCBA ar SABA. c) Eye: splash goggles and face shield if SCBA or SABA not warn.
Handling and storage Precautions : Aroid contact with liquid cooled equipment, Avoid inhalation, avoid sparking condition store in a cool, dry, well ventilated area away from heat, strong sunlight and ignition source.
Keep away from fire, sparks & heated surfaces no smoking near
areas where material is stared or handled. The product should only be stored and handled in areas with intrinsically safe electrical classification.
7. Emergency and First aid measures:
Suitable Fire Extinguishing media : Foam, dry chemical powder, co2, containers which are not cooled with water spray
Extinguishing media to avoid : water Caution about specific danger in case of : Danger of violent reaction or explosion, vapors Fire and fire fighting procedures may travel considerable distances and cause
subsequent ignition. Vapors are heavier than air, may cumulate along the round in enclosed spaces – danger of explosion when burning; it emits carbon monoxide & CO2 and irritant fumes.
Fire Special procedures : Shut off leak, if safe to do so,. Keep non –involved
people away from spill site. Issue warning “ FLAMMABLE” . Eliminate all sources of ignition.
Unusual Hazards : Vapor heavier than Air it will spread along the the ground and collect in sewer. Exposure First Aid measures : Skin contact ; in freeze burn occurs, gently Bathe affected area in warm water (38-43)0C. Do not rub get medical attention Eye : Immediately flash with large amounts of Luke warm water for 15 minutes, lifting upper & lower lids at intervals. Seek medical attention If irritation persists.
Inhalation: Remove to fresh air, give oxygen, artificial respiration or CPR needed seek medical attention Ingestion : Usually no effect by this Route
Antidotes/Dosages : NA
Spills Steps to be taken : Shut off leak , if safe to do so, Keep non – Involved people away from spillage site.
Eliminate all sources of ignition. Prevent spill entering in to sewers, for Major spillage contact emergency services.
Waste disposal Method : NA