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Practical Aspects of Supercritical Carbon Dioxide Brayton System Testing Bechtel Marine Propulsion Corporation Bettis Atomic Power Laboratory West Mifflin, PA Page 1 Supercritical CO 2 Power Cycles Symposium September 9-10, 2014 Brayton System Testing Eric Clementoni Timothy Cox

Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

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Page 1: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Practical Aspects of

Supercritical Carbon Dioxide

Brayton System Testing

Bechtel Marine Propulsion CorporationBettis Atomic Power LaboratoryWest Mifflin, PA

Page 1Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Brayton System Testing

Eric Clementoni

Timothy Cox

Page 2: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Presentation Summary

• S-CO2 Brayton Cycle Integrated Systems Test (IST)

Overview and Operating Experience

• Best Practices for S-CO2 Power Cycle Operation

– Design Considerations

– Loop Cleanliness

– System Fill and Leakage

Page 2Supercritical CO2 Power Cycles Symposium September 9-10, 2014

– System Fill and Leakage

– Instrumentation

• Conclusions

Page 3: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

• 100 kWe IST has been main S-CO2

development focus of BMPC

• Simple Brayton cycle

– Single variable speed turbine-compressor

– Single constant speed turbine-generator

IST Overview

Page 3Supercritical CO2 Power Cycles Symposium September 9-10, 2014

– Single constant speed turbine-generator

– Single recuperator

• Focus on system control

– Rapid startup

– Power changes

– Shutdown

CompressorTurbine

Heat

Source

Generator Turbine

Recuperator

Precooler

Sea WaterCooling

Water

Page 4: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

IST Physical Layout

Turbo-Generator

Page 4Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Recuperator

Precooler

Turbo-Compressor (not

visible)

Page 5: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Operational Experience• Shakedown started in Fall 2011

• Brayton cycle operation started in Spring 2012

• Over 165 hours of Brayton system operation

• Achieved 40% of design power

Page 5Supercritical CO2 Power Cycles Symposium September 9-10, 2014

**40 kW on

power

analyzer

Page 6: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

System Transient Modeling

• IST design supported by transient model

predictions

– Pipe size, valve resistance, valve stroke time,

support equipment operating requirements

Page 6Supercritical CO2 Power Cycles Symposium September 9-10, 2014

support equipment operating requirements

• Transient model valuable for startup and low

power operation

– Closed system more difficult to startup and get to

full power condition than open Brayton cycle

Page 7: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Mechanical Connections

• IST utilizes the following fittings in CO2 systems

– Grayloc fittings for main loop piping/component

connections

– ¼” Swagelok fittings welded to pipe for instrumentation

– ¼”-2” Swagelok fittings and 2” ANSI flanges for support

system connections

Page 7Supercritical CO2 Power Cycles Symposium September 9-10, 2014

system connections

• Fittings all leak tight when installed properly

• Bolt selection considerations– Thermal fatigue from heatup

and cooldown cycles

– Brittle fracture from low

temperature of leaking CO2

Page 8: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Thermal Stress Consideration• Small equipment allows for compact system arrangement

• Compact arrangements can make thermal stress more difficult

to accommodate

• IST design considered thermal stress from the beginning

– 4 thermal expansion loops included in Brayton loop piping to

accommodate thermal expansion

Page 8Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Page 9: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Material Quality / Cleanliness

• Supercritical CO2 is a strong solvent

• Materials testing and loop operating

experience has shown that some polymer

materials are incompatible with the

Page 9Supercritical CO2 Power Cycles Symposium September 9-10, 2014

materials are incompatible with the

supercritical CO2 environment

• BMPC test loops have implemented material

quality and cleanliness controls which have

shown effective at eliminating system

contamination

Page 10: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Turbine Nozzle Erosion

Page 10Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Page 11: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

System Fill and Leakage

• IST uses Coleman Instrument grade (99.99%)

CO2 for fill

• Three cycles of pulling vacuum and filling to

atmospheric pressure before full fill

Page 11Supercritical CO2 Power Cycles Symposium September 9-10, 2014

atmospheric pressure before full fill

• Low leakage levels from valve stem packing

and large shaft seals

Page 12: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Instrumentation• Temperature and pressure measurements give good

indication of loop conditions

• Coriolis flow meters used to determine both flow

rate and density of CO2

– Flow meters give good results for single phase or

supercritical flow

Page 12Supercritical CO2 Power Cycles Symposium September 9-10, 2014

supercritical flow

– Can give invalid readings during loop startup if installed

orientation allows for low point for liquid collection

Page 13: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Density Calculations using

REFPROP with T & P

Page 13Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Page 14: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Summary

• No inherent issues with S-CO2 Brayton power

cycle operation identified in IST operation

• Off-design operations, thermal stress analysis,

instrumentation orientation, cleanliness, and

Page 14Supercritical CO2 Power Cycles Symposium September 9-10, 2014

instrumentation orientation, cleanliness, and

material compatability are important design

considerations

• Experience from small-scale testing will

minimize rework and operational issues for

larger systems

Page 15: Practical Aspects Presentationsco2symposium.com/papers2014/testing/11PPT-Clementoni.pdf · • BMPC test loops have implemented material quality and cleanliness controls which have

Acknowledgements

• This paper summarizes work that has been

performed a number of devoted engineers,

scientists, technicians, and support personnel

at the Bechtel Marine Propulsion Corporation

Page 15Supercritical CO2 Power Cycles Symposium September 9-10, 2014

at the Bechtel Marine Propulsion Corporation

and our subcontractors. This paper would not

be possible without the efforts of this team.