PaceAnaly*calServicesKUResources

WasteWaterSampling Itinerary!  TypesofSamplingEquipment!  Composite&GrabSampling!  AutoSamplerSetUp!  Bottles,Labels,COC�s,HoldTimes!  ContaminationIssues!  VirtualLabTour

SamplingEquipmentISCOAutosamplerSubmersiblePumpBucketsSamplingPolesCrowbars

SamplingEquipmentEquipmentRentalCompanies

WasteWaterCompositeSampling

SetupProcedures1.Checkinwithplantcontact/safetypersonnel2.ReviewPermit(grab,composite,timeorflow)3.Readflowmetersandrecordreadings4.Determinedurationofcomposite

WasteWaterCompositeSampling

SetupTimeComposite1.Placesamplernearsamplingpoint2.Runnewtubingfromsamplingpointtosampler3.Determinetimebetweenaliquots4.Determineneedvolumeperaliquots>makesureyouhaveenoughvolumebutdonotexceedcontainer<

5.Programsampler&runamanualsample6.Icedowncompositesamplercontainer7.Startsamplerandrecordfieldnotes

WasteWaterCompositeSampling

SetupFlowComposite1.Determinesamplerpacingvolume2.Determineapprox24hrflowvolume3.Calculatevolumeofcompositesampleneeded4.Programsamplerforflowproportional5.Runamanualsample6.Icedownthecompositesamplercontainer7.Startsamplerandrecordfieldnotes

WasteWaterCompositeSampling

CollectionCompositeSample1.Haltsamplingandremovesamplercontainer2.Stirthecontainertoensureuniformity3.Filloutbottlelabels4.Fillallbottlesanddonotoverflow5.RecordFilednotes6.Placesamplesincoolerandicedown7.Completechainofcustody

WasteWaterCompositeSampling

CollectionGrabSample1.Samplingequipmentwilldependonaccessibility2.Samplebottle,bailerorISCOmaybeused3.Allequipmentshouldbecleanandappropriate

forlaboratoryanalyses4.Recordfielddata,labelbottles,completechain

ofcustodyandicedownsamplesincooler

WasteWaterCompositeSampling

CleaningEquipment1.CleansamplingequipmentwithAlconoxor

equivalent2.Rinsewithtapwater3.RinseagainwithDIwater4.Allowtodryandreturntostorage

WasteWaterSamplingSendSamplestotheLaboratory1.PrepareBottleLabels2.FillOutChainofCustody3.PackShippingCooler

Analy6calSamplingGuideParameterMethod ContainerVolumePresHoldTimeAlkalinityEPA 301.1 P,G 250 ml 4 C 14 Days Metals EPA 200.7 P,G 500 ml HNO3 / 4 C 6 Months Volatiles EPA 624 40 ml vial 3 vials HCL / 4 C 14 Days BOD EPA 405.1 P,G 500 ml 4 C 48 Hours Bacteria SM 9223 P 100 ml Na2SO3 24 Hours

Sampling&Bo<leWare

ChainofCustody

CommonProblems! NotEnoughInformation!  IncorrectInformation! UnreadableInformation! NoInformation! Labelinformationmustmatchchainofcustody

CHAIN-OF-CUSTODY / Analytical Request DocumentThe Chain-of-Custody is a LEGAL DOCUMENT. All relevant f ields must be completed accurately.

Section A Section B Section CRequired Client Information: Required Project Information: Invoice Information:

REGULATORY AGENCY

Phone: Fax:

Y/ N

DATE TIME DA T E TIME Unpre

serve

d H2

SO4

HNO3

HCI

NaOH

Na2S

2O3

Meth

anol

Othe

r

Ana

lysis

Test

Targe

t Com

poun

d VOC

- 826

0

Targe

t Ana

lyte M

etals -

6010

, 747

0

Targe

t Com

poun

d SVO

C - 82

70

Resid

ual C

hlorin

e (Y/N

)

1 SL G x x x

2 WT G x x x

3 WT G x

4 WT G x x x

5 WT G x x x

6

7

8

9

10

11

12

Requested Due Date/TAT:

Page: of

NPDES GROUND WATER DRINKING WATER

UST RCRA OTHER

Company:

Address:

Email To: Myemailaddress

4250 Route 6

Edinboro, PA 16412

ER&R Attention:

Company Name:

Address:

Report To:

Copy To:

PA

Your Name

P aceQuo teR eference:

Purchase Order No.:

DATEADDITIONAL COMMENTS RELINQUISHED BY / AFFILIATION TIME

Tim Reed Site Location

STATE:

DATE ACCEPTED BY / AFFILIATION

PRINT Name of SAMPLER:

SAMPLER NAME AND SIGNATURE

DATE Signed (MM/DD/YY):

SIGNATURE of SAMPLER:

South Groundwater SampleTrip Blank

Equipment Blank

SAMPLE ID (A-Z, 0-9 / ,-)

Sample IDs MUST BE UNIQUE SA

MPLE

TYPE

(G

=GRA

B C=

COMP

)

# OF

CONT

AINER

S

Preservatives

Rece

ived o

n Ice

(Y/N)

Temp

in °C

Custo

dy

Seale

d Coo

ler

(Y/N)

Samp

les In

tact

(Y/N)

SAMPLE CONDITIONS

ITEM

#

MAT

RIX CO

DE

South Core Sample

DR INK INGWATER WA TER WA S TE WA TER PR ODUC T S OIL/S OLID OILWIPE A IR OTHER T IS S UE

Valid Matrix Codes MA T R IX C OD E

Section D R e qu ire d C lientInfo rmation

DWWT WWP S LOLWPA R OT T S

Field Blank

TIME

SAMP

LE TE

MP AT

COLL

ECTIO

N

Requested Analysis Filtered (Y/N)

P aceP ro file# :

Pace Project No./ Lab I.D.

10 da y

COLLECTED

814 734-6411 Project Name:

Project Number:

ABC Site Assessment P aceP ro jec tManager:

COMPOSITE START

COMPOSITE END/GRAB

FieldContamina6onIssues!  Subpartperbillionanalysis!  SamplingEquipmentDecon! Gloves!  Samplefromlowtohighcontamination! Contaminationbroughtonsite(sunscreen,tape,gasoline,WD40,etc)

!  Ice! Marksuspectedcontaminationonfieldnotes

LaboratoryServices

SampleLogIn

> Unpack sample coolers > Take sample temperature > Review Chain of Custody with sample bottle labels > Log project into LIMS

Samplesareplacedincoldstorage

SamplePrepGroup

SamplePrepGroup

PrepareSamplesforVariousAnalyses! Digestions! Extractions!  Leachates

DistributiontoAnalyticalGroups

MetalsGroup

Instrumenta6on!  ICP(InductivelyCoupledPlasma)

!  As,Ba,Cd,Cr,Cr,Pb,Se,Ag………!  ICPMS(MassSpec)

!  LowerDetectionLevels! MercuryAnalyzer!  LowLevelMercuryAnalyzer! MethylMercuryAnalyzer! Otherlessusedinstruments–AA,GFAA

Vola6leOrganicsGroup

SemiVola6leOrganicsGroup

Instrumenta6on

! GC(GasChromatograph)! GCMS(MassSpec)! GCFID(FlameIonizationDetector)

WetChemistryGroup

Instrumenta6on

!  IC(IonChromatography)–fluoride,bromide,chloride

! TOCAnalyzer(TotalOrganicCarbon)! TOXAnalyzer(TotalOrganicHalogens)!  LachatAutomatedAnalyzer!  Spectrophotometers(colormetricanalyses)

CommonCompoundLists

MetalsVolatiles

SemiVolatilesPesticides

PCBs

RCRA(8)Metals

TargetAnalyte(TAL)Metals

PriorityPollutant(PP)Vola6les

TargetCompound(TCL)VOC�s

PriorityPollutant(PP)SemiVola6les

TargetCompound(TCL)SemiVola6les

(TCL)SemiVola6lescont.

PolyAroma6cHydrocarbons(PAH)

TargetCompound(TCL)Pes6cides

TargetCompound(TCL)PCBs

Conclusions!  FinalReportsarethesummationsofallsampleactivities:!  FieldSampling!  SampleReceiving!  SamplePreparation!  AnalyticalMethods! DataInterpretationandVerification