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25/10/2010
1
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
CASSEM Conference
Our Dynamic Earth
4 October 2010 1CASSEM Conference
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Introduction
D id C b ll S tti hPDavid Campbell, ScottishPower
4 October 2010 CASSEM Conference 2
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Key note speech
St M h ll S tti hPSteven Marshall, ScottishPower
4 October 2010 CASSEM Conference 3
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
CASSEM rationale and genesis
P f St t H ldi Prof. Stuart Haszeldine, University of Edinburgh
4 October 2010 CASSEM Conference 4
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CASSEMCCS BackgroundCASSEM was invented in December 2005 by Stuart Haszeldine (UoE) and Adrian Todd (H-WU)
At that time………..
• There was no UK CCS programme
• DTI had not become BERR, or DECC, or OCCS
• The BP-SSE project was the only one
4 October 2010 5
• There was no storage capacity assessment for the UK
• IEA still worked on Business as Usual
• “CCS” research was on efficiency and capture
CASSEMInternational Capture and Storage
Required emission reduction
CCS
4 October 2010 6
550 ppm Atmosphere maximum
Pacala and Socolow Science “Wedges” (2004)IPCC Special Report on CCS (2005)
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CASSEMUK CCS G8 commitment to CCS
4 October 2010 7
Forties had been evaluated for EOR with CO2 from Grangemouth
Miller EOR was the only global CCS powerplant project
CASSEMWhy CASSEM ?• How to assess “aquifers”- large volumes, old data, multiple owners, unclear seal
• Which coal plant ?- close to coast ==> storage offshore in saline formations
• How to work at this ?- Full chain project (not just capture), focus on storage
4 October 2010 8
Full chain project (not just capture), focus on storage
• Which companies and organisations ?- New entry organisations, KE, methods of working - Need a funder - DTI “CAT” programme large enough
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CASSEMWhich CASSEM partners ?
IDEA - a multi-discipline integrated examination of the entire capture and storage chain
Linking: 1) Capture at the power station -> 2) CO2 transport network
3) W ll h d d ll d i -> 3) Well head and well design -> 4) Injection
-> 5) Migration -> 6) Monitoring-> 7) Public acceptance
• Investigating two case studies : Firth of Forth & E England • Academic partners :
4 October 2010 9
• Academic partners : Scottish Centre for Carbon Storage, Tyndall Centre
• Industrial partners : AMEC, ScottishPower, Scottish and Southern Energy, Schlumberger, Marathon Energy
• Government bodies : British Geological Survey, • Funders : Industry, DTI (TSB), EPSRC
CASSEMStill relevant today ?YES !1) First comprehensive UK cost and value-chain ) p
2) Saline Formations host >90% possible storage UK may have 35% of EU storage
3) Integrated workflows from plant to store
4 October 2010 10
3) Integrated workflows from plant to store
4) CASSEM 1 - establish UK method CASSEM 2 - site identification and appraisal CASSEM 3 - license and DRILL saline formation
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CASSEMAnd so, eventually ….
CO2 source
Pi d iPipe design
Explore a reservoir
Reservoir model
4 October 2010 11
Reservoir model
Risk assessment
Linear ………… became ………. Integrated
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
CASSEM rationale and genesis
P f St t H ldi Prof. Stuart Haszeldine, University of Edinburgh
4 October 2010 CASSEM Conference 12
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7
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
From Surface to Store: From Surface to Store: Overview of CASSEM
methodology
D M ti S ith B iti h Dr. Martin Smith, British Geological Survey
4 October 2010 CASSEM Conference 13
CASSEMOutline of talk
• Background: philosophy and aims of the CASSEM j tCASSEM project
• ‘Guided tour’ of key activities
k l d d h l• Acknowledgments: support and help from all of the CASSEM Team and in particular to D Campbell, E Mackay and D Poulson
4 October 2010 14CASSEM Conference
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CASSEMProject Philosophy
• Understanding and transforming i d tmindsets
•JIP - Bringing skills together
•Developing an ‘entry path’
4 October 2010 15CASSEM Conference
•To improve investor confidence
CASSEM
Longannet
4 October 2010 16CASSEM ConferenceFerrybridge
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CASSEM
AMEC
• High level routing study
4 October 2010 17CASSEM Conference Univ. Edinburgh
g g y
• novel mixing scenarios before injection
CASSEM
4 October 2010 18CASSEM Conference
Storage process workflows
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CASSEMGeological ModelLINCS.
4 October 2010 19CASSEM ConferenceBGS and Univ. Edinburgh
CASSEMReservoir simulation
4 October 2010 20CASSEM ConferenceHeriot Watt Univ.
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CASSEMMonitorability
Electro-magnetics
Gravity
4 October 2010 21CASSEM ConferenceUniv. Edinburgh
Seismic
CASSEMUncertainty
Risk
4 October 2010 22CASSEM ConferenceFlow simulation sensitivity analysis
Univ. Edinburgh
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CASSEMPublic Perception
4 October 2010 23CASSEM Conference Tyndall Centre, Univ. Manchester
CASSEMIn Summary,
• CASSEM project has delivered a series f i t t d kfl d of process-orientated workflows and
scientific insights aimed at new entrants to CCS
• Key focus on– Analysis of sub-surface storesAnalysis of sub surface stores– Uncertainty and risk– Full costing model– Public perception
4 October 2010 24CASSEM Conference
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
From Surface to Store: From Surface to Store: Overview of CASSEM
methodology
D M ti S ith B iti h Dr. Martin Smith, British Geological Survey
4 October 2010 CASSEM Conference 25
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
CASSEM Conference
O D i E thOur Dynamic Earth
4 October 2010 CASSEM Conference 26
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
C i & H dli f Compression & Handling of Carbon Dioxide
J W tt AMECJames Watt, AMEC
4 October 2010 CASSEM Conference 27
Work Summary
To provide a realistic linkage between the potential sources of large
volumes of CO2 and the geology of typical saline formations.
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Appreciation of the whole scheme makes a difference
• Early decision making by the asset team can have a profound affect pon the end product and cost
• CCS as a whole scheme needs to be better understood to– Inform ongoing discussions– Enable early decisions
• Typically we need to consider– Can it be done? – What needs to be done?– How can we do it?– How much will it cost?
• Understanding the process scheme, options and interactions is critical
Project Timeline
• If you consider a capture plant 800MW in size
BFD/PFD
• Using IEA metrics a CCS system might cost £940 million
• Traditionally engineering design costs are 15% of the purchased cost of equipment
• PCE = £210 million approx• Engineering costs in the region of
£31 million£31 million• 45,000 manhours, 237 man years• Concept = £1.5 million• FEL = £11 million• Engineering = £18.5 million
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CASSEMBlock/Process Flow including capture and injection
Determining ParametersComposition, ppmWaterSOxNOx H2S
G, m³/sQ, kg/s
Determining ParametersComposition, ppmWaterSOxNOx H2SLean/Rich Amine concLean Amine return conc and flowarteAmine G, m³/sAmine Q kg/s
Determining Parameters
Determining ParametersComposition, ppm/%Water SOxNOx H2SCO2O2
Determining ParametersComposition, ppm/%Water SOxNOx H2SCO2
Determining ParametersComposition, ppm/%Water SOxNOx H2SCO2O2
Determining Parameters Determining Parameters
GRID CONNECTION
Determining Parameters
Grid Demand, MWe
Determining ParametersComposition, ppm/%Water SOxNOx H2SCO2
Determining ParametersComposition, ppm/%Water SOxNOx H2SCO2O2H2
Boiler
Steam Turbine
Particulate Control Flue Gas Desulphurisation CO2 Absorber CO2 Stripper Dehydration Compression Pipeline
Reboiler
Absorbent Day Tank
Feed Pumps & Feed Cooling
Boosting
TEG Reboiler
TEG Stock Tank
Density, kg/m³T, °CP, barSteam kg/h, T & P
VariablesLean Amine recirculationAmine TemperatureAmine conc%HSS content
Amine Q, kg/sDensity, kg/m³T, °CP, barSteam kg/h, T & P
VariablesReboiler DutyCooler DutyLean/Rich InterchangerColumn T & P
Composition, ppmWater (Key)SOxNOx H2S
G, m³/sQ, kg/sDensity, kg/m³T, °CP, barSteam kg/h, T & P
VariablesReboiler DutyCooler DutyGlycol recirculationUnit entry T & P
O2H2N2CH4GlycolAmine
G, m³/sQ, kg/sDensity, kg/m³T, °CP, bar inlet and outletPipeline pressure dropStorage pressure requirementsPower availability
VariablesCompressor stagesOutlet pressurePower availability (limiting factor)
CO2O2H2N2CH4GlycolAmine
G, m³/sQ, kg/sDensity, kg/m³T, °CP, bar inlet and outletLength
VariablesLine sizeLine LengthDistance to boosting
O2H2N2CH4GlycolAmine
G, m³/sQ, kg/sDensity, kg/m³T, °CP, bar inlet and outletPipeline pressure dropStorage pressure requirements
VariablesCompressor stagesOutlet pressurePower
Determining ParametersComposition, ppm/%Water SOxNOx
Composition, ppmWaterSOxNOx H2S
Capture plant tolerance to SOx and NOx
G, m³/sQ, kg/sDensity, kg/m³T, °CP, bar
VariablesAbsorbent type (lime/water)Polishing scrubber requirementNumber and size of units
Direct Contact Cooling and Pre-
Treatment
Composition, ppmWaterSOxNOx H2S
G, m³/sQ, kg/sDensity, kg/m³T, °CP, barRequired T for CaptureRequired SOx level for capture plantVariablesQuench water rate
Determining ParametersGrid Demand, MWeSteam flow, kg/hCoal CompositionLHV/HHV
Coal -G, m³/sQ, kg/s
Steam -T, °CP, bar
Generators
Coal Feeding
Determining Parameters
Grid Demand, MweCarbon Capture parasitic loadSteam rate
Determining ParametersGrid Demand, MWeSteam flow, kg/hCoal CompositionLHV/HHV
Coal -G, m³/sQ, kg/s
Steam -T, °CP, bar
DeNOxSCR/nSCR
Lean Amine
Storage
Rich Amine
Storage
Nocturnal Processing Option for Amine Stripping
Pipeline
CO2O2H2N2CH4GlycolAmine
G, m³/sQ, kg/sDensity, kg/m³T, °CP, bar inlet and outletLength
VariablesLine sizeLine LengthDistance to boosting
Offshore Boosting(if required)
This option is limited. Very dependent on the age of the target asset, space available and the onsite power capability.
Subsea Completion
Assumptions
Load Factor 80%Availability 95%Ramp rate 100 MW/hr (TBC)Efficiency 45%
LG = 3 off 800MW s/cFB = 2 off 800MW s/c
H2N2CH4GlycolAmine
G, m³/sQ, kg/sDensity, kg/m³T, °CP, bar inlet and outletPipeline pressure dropStorage pressure requirementsPower availability
VariablesCompressor stagesOutlet pressurePower availability (limiting factor)
Storage
Absorbent Stock Tank
Absorbent Loading/Unloading
Waste Absorbent TEG Loading/Unloading
H2SCO2O2H2N2CH4GlycolAmine
G, m³/sQ, kg/sDensity, kg/m³T, °CP, bar inlet and outletReservoir pressureInjection patternInjection pressurePorosity
VariablesNumber of well headsDepth of reservoirFlowrateInjection Pressure
BHP 220 barWHP 150 barD = 1200mRes Pressure = 120 bar1million t/year per well head
,
Variables
,
Variables
Casing
Wellhead
Biomass/Gas COGEN Steam and power supply for
Capture (Option)
CASSEMDesign Influences Example
The report examines the blocks and the relationships between them and the variablesthem and the variables and constraints.
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CASSEMWork Activities
• 1 HSE Considerations and Liaison• 2 Interim Route Selection• 3 Build Compression & Handling System• 3 Build Compression & Handling System• 4 Interim Compressor Selection and Station Location• 5 Verify Route Selection • 6 Verify Compressor Selection and Station Location• 7 Well Characterisation
• DeliverablesHSE of Carbon Dioxide for CCS Report– HSE of Carbon Dioxide for CCS Report
– Route Selection for Exemplar Power Stations– Compressor Selection Report– Exemplar Station Block Flow Diagram
• Included design criteria mapping
CASSEMHealth and Safety Review
HSE Considerations– Initial work was focused on HSE issues around CCS– During the project both DNV and EI have studied the same
subject– The document summarises the HSE issues for Carbon Dioxide
streams in CCS– It does not cover capture chemicals.– Provides common baseline for all partners– Has since been adopted by AMEC to ensure competency of Has since been adopted by AMEC to ensure competency of
personnel in CCS– Currently a baseline reference standard on all AMEC CCS
projects
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CASSEMRoute Selection – key activity• Two Exemplar Power Stations
– Ferrybridge, 1600MW s/c coal firedFerrybridge, 1600MW s/c coal fired– Longannet, 2400MW s/c coal fired
• Objective to test possibility of transport by pipeline to hypothetical store
• Provide reference material for pipeline routing activitiesDefine methodology for CCS pipelines• Define methodology for CCS pipelines
• Demonstrate route issues, selections and decision making
Ferrybridge Route assumptions – only for the CASSEM theoretical study
Option 2 – Alternate RouteThis picture illustrates how route options are developed
Other CO2 sources considered in routings
Option 3 – Shortened Cross Country
Option 1 – Assumed general wayleave Corridor
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CASSEMLongannet Route assumption - only for the CASSEM theoretical study
CASSEMCompressor Selection
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CASSEMKey Learning
• Geology of storage has a major influence on design• Uncertainty in geological stores was highy g g g• Overall the relationship between transport and store is now better
understood. More complex than we knew, but we have mitigated a lot of risk and understanding the constituent parts.
• Whilst not solved the impact of storage issues can be seen through the scheme.
• Guidance and reports from CASSEM are now core competency documents for AMEC CCS.documents for AMEC CCS.
CASSEMContactJames WattTechnical ManagerEngineering Execution Centreg gLion CourtWynyard Business ParkStockton 0n TeesTS22 5FDUK
[email protected] es.Watt@a ec.co
+44 (0) 1740646082 mobile +44 (0) 7779 590193
Or Alastair Rennie, Project Director, [email protected]+44 (0) 7889 486 827
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
C i & H dli f Compression & Handling of Carbon Dioxide
J W tt AMECJames Watt, AMEC
4 October 2010 CASSEM Conference 41
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Modelling CCS Costs
M k O k d S tti hPMark Ockendon, ScottishPower
4 October 2010 CASSEM Conference 42
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CASSEMPurpose
• Existing Studies (McKinsey, Harvard…)
• Consistency, transparency, comparable
• CASSEM = methodologies & workflows, l l ’not necessarily actual £’s
4 October 2010 43CASSEM Conference
CASSEMScope
Generation & capture
Transport Storagecapture
• Supercritical Coal• Fully Integrated• Post Combustion• Amine Based
• Pipeline• Compression
• Aquifer• North Sea
4 October 2010 CASSEM Conference 44
• CASSEM mainly Storage focused• CCS costs cover full chain
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CASSEMPower Station Size
Power Station
+ 450 MW Power for Capture Plant
= 1,600 MW total station size
42%
‐12%
= 30%
1,150 MW Electricity to GridCoal
4 October 2010 CASSEM Conference 45
Assumptions:1 tonne coal produces 2.2 tonnes CO2 when burned.1 tonne coal contains 25GJ energy.Capture process requires 3.2 GJ energy per tonne of CO2 captured.Supercritical plant is 42% efficient.
Indicative power & efficiency numbers
CASSEMCosting options
Power Station Power StationIncremental investment Opportunity cost
+ 450 MW
1,150 MW = 1,150 MW
1,600 MW total
– 450 MWSame electricaloutput to the
grid
‘Cost’:+ CapEx+ Coal+ Carbon+ OpEx+ Return
‘Cost’:– Sales
Are existing studies clear about which method is used?
4 October 2010 CASSEM Conference 46
= 1,600 MW total
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CASSEMModel - Overview
• Financial Model + Discussion Paper• Excel based, no macros, not locked• Data sources referenced• Available to download (soon!) from:
Scottish CCS website (www.geos.ed.ac.uk/sccs), or CASSEM website ( t)or CASSEM website (www.cassem.net)
4 October 2010 CASSEM Conference 47
CASSEMModel - Structure
Costs‘Cost’
(Basis 1)
Schedule
Operating Assumptions
MacroEconomicData
FinancialModel
‘Cost’(Basis 2)
‘Cost’(Basis 3)
‘Cost’(Basis 4)
4 October 2010 CASSEM Conference 48
CO2 Abated vs Captured/Transported/Stored
Real vs Nominal (inflated) cashflows
Cost vs Price
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CASSEMModel - Sources
Generation & capture
Transport Storagecapture
•Incremental cost of CCS vs non-CCS station(Scottish Power)
• Pipeline & Compressor calculations, per the IEA model (Amec)
• Seismic data(Slumberger)
• Well costs(Marathon Oil)
4 October 2010 CASSEM Conference 49
• Aquifer Classification (per the SCCS study)
•Macroeconomic data:(Ofgem ‘Project Discovery’)
CASSEMModel - Current Status
• Initial peer review complete • Wider peer review & open source• Feedback
• Benchmarking existing studies, update d ll ddata sources, collate and incorporate feedback...CASSEM 2?
4 October 2010 CASSEM Conference 50
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Modelling CCS Costs
M k O k d S tti hPMark Ockendon, ScottishPower
4 October 2010 CASSEM Conference 51
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Process Engineering S i fStrategies for
CO2 Injection into Saline Formations
D P l Ek U i it f Dr. Paul Eke, University of Edinburgh
4 October 2010 CASSEM Conference 52
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CASSEMWork ScopeWork Scope
Injection strategies designs & simulationsInjection strategies designs & simulations
Process facilities sizing & optimizationProcess facilities sizing & optimization
Injection facilities costingInjection facilities costing
Surface & subsurface interfacingSurface & subsurface interfacing
4 October 2010 53CASSEM Conference
CASSEMBackgroundBackground
How could COHow could CO22 remain underground?remain underground?
COCO22 Storage security depends on a Storage security depends on a combination of various trappings.combination of various trappings.
Over time, residual COOver time, residual CO22 trapping, trapping, solubility trapping and mineral solubility trapping and mineral trapping increasetrapping increase
4 October 2010 54CASSEM Conference
trapping increase.trapping increase.
Modified after IPCC 2005
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CASSEMAimAim
Design, Development of tools, Technology, Design, Development of tools, Technology, Protocols & Best Practices to enhance COProtocols & Best Practices to enhance CO Storage Storage
BackgroundBackground
Protocols & Best Practices to enhance COProtocols & Best Practices to enhance CO22 Storage Storage
Simulations to investigate behaviour of COSimulations to investigate behaviour of CO22 in the in the surface & subsurface injection facilitiessurface & subsurface injection facilities
Design of injection strategies to maximize CODesign of injection strategies to maximize CO
ObjectivesObjectives
Design of injection strategies to maximize CODesign of injection strategies to maximize CO22storage storage
Apply results to enhance storage permanence in Apply results to enhance storage permanence in geological formationsgeological formations
4 October 2010 55CASSEM Conference
CASSEMProposed StrategiesProposed Strategies
Option 1: Standard COOption 1: Standard CO22 InjectionInjection
Option 2: COOption 2: CO22––Brine Surface Mixing & Brine Surface Mixing & InjectionInjection
Option 3: COOption 3: CO22––Water Surface Mixing & Water Surface Mixing & InjectionInjectionInjectionInjection
Option 4: COOption 4: CO22 Alternating Brine (CAB) Alternating Brine (CAB) InjectionInjection
4 October 2010 56CASSEM Conference
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CASSEMStandard COStandard CO22 InjectionInjection
4 October 2010 57CASSEM Conference
CASSEMCOCO22––Brine Surface Mixing & InjectionBrine Surface Mixing & Injection
4 October 2010 58CASSEM Conference
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CASSEMCOCO22––Water Surface Mixing & InjectionWater Surface Mixing & Injection
4 October 2010 59CASSEM Conference
CASSEMCOCO22 Alternating Brine (CAB) InjectionAlternating Brine (CAB) Injection
4 October 2010 60CASSEM Conference
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CASSEMCalculations & Simulations ResultsCalculations & Simulations Results
ForthForth
4 October 2010 61CASSEM Conference
(a) Solubility of CO(a) Solubility of CO22 in fresh water and brinein fresh water and brine
(b) Density of CO(b) Density of CO22 and fluidsand fluids
(c) Zoom in on the fluid densities(c) Zoom in on the fluid densities
CASSEMCalculations & Simulations ResultsCalculations & Simulations Results
Lincolnshire Lincolnshire
4 October 2010 62CASSEM Conference
(a) Solubility of CO(a) Solubility of CO22 in fresh water and brine in fresh water and brine
(b) Density of CO(b) Density of CO22 and fluidsand fluids
(c) Zoom in on the fluid densities(c) Zoom in on the fluid densities
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CASSEMMassive volume required to be handledMassive volume required to be handled
15 MT CO15 MT CO22/yr in H2O/brine requires:/yr in H2O/brine requires:
ChallengesChallenges
15 MT CO15 MT CO22/yr in H2O/brine requires:/yr in H2O/brine requires:
0.5M ~ 5.4M b/d0.5M ~ 5.4M b/d
198M ~ 1.9B b/yr198M ~ 1.9B b/yr
198 wells198 wells~198 wells~198 wells
11 ~ 104 wells @ 50000 b/d/well11 ~ 104 wells @ 50000 b/d/well
8 ~ 74 wells @ 70000 b/d/well8 ~ 74 wells @ 70000 b/d/well4 October 2010 63CASSEM Conference
CASSEMSurface & subsurface interfaceSurface & subsurface interface
Forth Nodal AnalysisForth Nodal Analysis
Initial Reservoir PressureInitial Reservoir PressureMax. allowableMax. allowableBottom Hole PressureBottom Hole Pressure
4 October 2010 64CASSEM Conference
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CASSEMSurface & subsurface interfaceSurface & subsurface interface
Lincolnshire Nodal AnalysisLincolnshire Nodal Analysis
4 October 2010 65CASSEM Conference
Max. allowableMax. allowableBottom Hole PressureBottom Hole PressureInitial Reservoir PressureInitial Reservoir Pressure
CASSEMConclusions & RecommendationsConclusions & Recommendations
Tubing head pressure of ~90 and ~100 bars for Tubing head pressure of ~90 and ~100 bars for Lincolnshire and Forth reservoir respectivelyLincolnshire and Forth reservoir respectivelyLincolnshire and Forth reservoir respectively.Lincolnshire and Forth reservoir respectively.
Completion options, which use 7” tubing, offer Completion options, which use 7” tubing, offer a slight injection (lower head pressure) a slight injection (lower head pressure) advantage over 4.5” tubing.advantage over 4.5” tubing.
4 October 2010 66CASSEM Conference
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CASSEMConclusions & RecommendationsConclusions & Recommendations
COCO22--brine surface dissolution produces CObrine surface dissolution produces CO22--saturatedsaturated brine with density slightly higher brine with density slightly higher saturatedsaturated--brine with density slightly higher brine with density slightly higher than original brine in the formation than original brine in the formation
This eliminates the buoyancy force which is a This eliminates the buoyancy force which is a strong driving force to bring COstrong driving force to bring CO22 to the surfaceto the surface
4 October 2010 67CASSEM Conference
CASSEMConclusions & RecommendationsConclusions & Recommendations
These strategies speed up COThese strategies speed up CO22 dissolution as the dissolution as the period of time needed to achieve same in the period of time needed to achieve same in the period of time needed to achieve same in the period of time needed to achieve same in the subsurface formation is enhanced.subsurface formation is enhanced.
Hence, eliminating the dependence on long Hence, eliminating the dependence on long term dissolution and mineralization mechanisms term dissolution and mineralization mechanisms and significantly reduces long term monitoring and significantly reduces long term monitoring and significantly reduces long term monitoring and significantly reduces long term monitoring costs.costs.
4 October 2010 68CASSEM Conference
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CASSEMConclusions & RecommendationsConclusions & Recommendations
Strategies for accelerating COStrategies for accelerating CO22 dissolution and dissolution and Strategies for accelerating COStrategies for accelerating CO22 dissolution and dissolution and solubility trapping exsolubility trapping ex--situ proposedsitu proposed
Injection strategies studied are directly linked Injection strategies studied are directly linked with capability of enhancing permanent COwith capability of enhancing permanent CO22storage in the geological formationsstorage in the geological formationsstorage in the geological formationsstorage in the geological formations
4 October 2010 69CASSEM Conference
CASSEMConclusions & RecommendationsConclusions & Recommendations
Injection processes have been established and Injection processes have been established and require demonstrations. require demonstrations.
The application requires pilot plant validation The application requires pilot plant validation on a realistic scale, considering typical on a realistic scale, considering typical injection facilities sizes.injection facilities sizes.
4 October 2010 70CASSEM Conference
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CASSEMThanks for listeningThanks for listening
4 October 2010 71CASSEM Conference
[email protected] [email protected] Source: RBD virtual IPP
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Process Engineering S i fStrategies for
CO2 Injection into Saline Formations
D P l Ek U i it f Dr. Paul Eke, University of Edinburgh
4 October 2010 CASSEM Conference 72
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
G l i l i i Geological interpretation and storage modelling
D id L B iti h David Lawrence, British Geological Survey
4 October 2010 CASSEM Conference 73
CASSEMHow do I find a suitable store for my CO2?
4 October 2010 CASSEM Conference 74
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CASSEMSite Screening
Evaluation/Decision Gate 1
Level I: the Basic Geological Model
CASSEMSite Screening
Evaluation/Decision Gate 1
Level I: the Basic Geological ModelLevel I: the Basic Geological Model
Evaluation/Decision Gate 2
Level II: the Intermediate Model
Level I: the Basic Geological Model
Evaluation/Decision Gate 2
Level II: the Intermediate Model
Geological Interpretation and Modelling
Workflow
4 October 2010 CASSEM Conference 75
Level II: the Intermediate Model
Evaluation/Decision Gate 3
Level III: the High level Model
Level II: the Intermediate Model
Evaluation/Decision Gate 3
Level III: the High level Model
Workflow
CASSEM
4 October 2010 CASSEM Conference 76
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CASSEMCriteria Positive indicators Cautionary indicatorsSaline aquifer present Salinity >100 gl-1 Salinity <10 gl-1
Aquifer depth > 800 m <2500 m <800 m >2500 mTrap geometry exists Good trap structure Accepted at start of workflow
that no major trap structures
Initial area and site selection screening criteria
existCaprock exists >100 m thick <20 m thickAvailability of geological data
3D seismic data, uniform coverage
Old 2D seismic data, variable coverage
Proximity to power plant
<75km >100km
Suitable porosity >20% <10%Suitable permeability >500 mD <200 mDStratigraphy - geological complexity
Uniform Complex lateral variation and complex connectivity
Aquifer volume >100m thick sandstone over <20m thick sandstone
4 October 2010 CASSEM Conference 77
Aquifer volume >100m thick sandstone over 5.5 km2 or for a 30 m thick sandstone 10 km2
<20m thick sandstone
Igneous rocks An appreciation of their existence, geometry and effect on surrounding rock
Little knowledge of geometry and effect on surrounding rock
Containment Knowledge of minimal routes to surface/high level from aquifer/seal – faults, boreholes, mineworkings etc
Little knowledge of routes to surface, including faults and boreholes
(Modified after Chadwick et al, 2008)
CASSEM
Vertical exaggeration X10
Longannet
Vertical Exaggeration X70
Ferrybridge
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CASSEMBritish East Midlands and Lincolnshire
Geological Modelling
CASSEMData availability: seismic Target-wide coverage of modern 3D seismic None or restricted early 2D
seismic
Data availability: wells Regular spread of modern wells None or few early wells
Multiple thick persistent sands suggested by
Lincolnshire- Scoring of potential areas 5=favourable 1=unfavourable
Reservoir Geology: sands Multiple thick persistent sands suggested by scoping Inferred sand bodies only
Reservoir Geology: traps Appropriate trap lithology and structure suggested by scoping Inferred trap only
Reservoir Geology: complexity / generic confidence Scoping suggests that structure may be recognised and represented
Structural complexity not known or indeterminable
Target Seismic data availability
Well data availability
ReservoirGeology Complexity Modelling
score RANK
Saltfleetby 5 3.5 4 4.5 17 1
Welton 5 5 4 2.5 16.5 2
4 October 2010 CASSEM Conference 80
Gainsborough 2 4 5 2.5 13.5 3
Eakring 3 3.5 3 2.5 12 4
Hatfield Moors 3 2.5 3 3 11.5 5
South Humber 4 1 2 2 9 6
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CASSEM
5 6
4
3 1
24
CASSEM
Firth of ForthFirth of Forth
Lincolnshire
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CASSEM
CASSEM
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CASSEMData types
• Boreholes, wells
• Mining contour d tdata
• Seismic data
• Maps and surface outcrop information and
• Existing regional geological models
• Geological knowledge/ interpretation
CASSEMFirth of Forth
25/10/2010
44
CASSEM
Good
Quality of 3D seismic data in east
Lincolnshire
PoorGood
Medium
CASSEM
Level IMODEL
Level II MODEL
Level III MODEL
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CASSEMSandstone sample from outcrop
Sherwood Sherwood Sandstone exposed in a quarry
Images ©BGS/NERC.
Cleethorpes borehole core: Sherwood Sandstone aquifer from 1.2 km
CASSEMCASSEM sample analysis: Backscattered Scanning Electron Microscopy (BSEM) imagery
Brightness variations represent different phases:
•BLACK = void space;
•DULL GREY = quartz, albite, dolomite;
•MID GREY = K-feldspar, muscovite, illite;
•LIGHT GREY = anhydrite and calcite
Example of BSEM petrographical image of siltstone from the Mercia Mudstone Group, Cropwell Bishop borehole [upper SEAL to Sherwood Sandstone]
Field of view c.200 microns
Image ©BGS/NERC.
25/10/2010
46
CASSEM
Work flow diagram for image processing and
analysis
Image ©BGS/NERC.
CASSEMYorkshire-Lincolnshire Summary Porosity Data by Formation
U. Permian Marl (1 Siltstone) Mean Macroporosity
Sherwood Sandstone
Marl Slate
Basal Permian
Mean Meso + Microporosity
Porosity Range (Min -
+/- 1 Standard
Macroporosity / Meso + Microporosity cut-off set at 15µm 2D pore equivalent circular diameter
0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0
Mercia Mudstone
Sherwood Sandstone
Porosity %
circular diameter
Image ©BGS/NERC.
Primary aquifer
Primary seal
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CASSEM
Level IMODEL
CASSEMSeismic data – Firth of Forth CASSEM
Seismic shown with permission of Phoenix Data Solutions
Leven li
Base seal/top aquifer at c.-2200m ±?100m
Forth anticline
syncline
Image ©BGS/NERC.
25/10/2010
48
CASSEMExample of data scatter, base Carboniferous (in aquifer)
Seismic interpretation
Borehole data (Glenrothes)
Fault gap
Gocad calculates triangulated mesh based on
Outcrop
Fault gapXYZ data points
Add geological interpretation in data poor areas
CASSEM
MAIN TARGET AQUIFER UNIT
MAIN TARGET SEAL UNIT
Firth of Forth - Preliminary surfaces and faults
25/10/2010
49
CASSEMFirth of Forth - Estimated uncertainty map for the Base Ballagan Formation modelled surface
4 October 2010 CASSEM Conference 97
CASSEM
Level IMODEL
25/10/2010
50
First Response Tools• structural validity
– an initial quick test of whether preliminary f h i ll ibl surfaces are physically possible
• critical depth regions for CO2 phase behaviour– indicates likely densities, viscosities and
solubilities of CO2 under initial conditions
• critical surface regions for CO2migration– Assesses pathways for buoyant CO2 migration
along the upper surface of the target aquifer4 October 2010CASSEM Conference 99
CASSEMClosure and fetch analysis and single map migration (MPath)
Plan view area ~2 X 5 km2Spill point
25/10/2010
51
CASSEMFirst response Tools:Mpath Single Map Migration modelling on principal saline aquifer/caprock boundary
4 October 2010 CASSEM Conference 101
Firth of Forth
Lincolnshire
CASSEM
25/10/2010
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CASSEM
Seismic shown with permission of Phoenix Data Solutions
Reprocessing courtesy of Schlumberger Ltd.
4 October 2010 CASSEM Conference 103Before reprocessing After reprocessing
2000m
CASSEMChange in depth of Base of Ballagan Formation (seal) after reinterpretation of reprocessed seismic data.
4 October 2010 CASSEM Conference 104
25/10/2010
53
CASSEM
Original Original interpretation of Base Ballagan in brown.
New interpretation of area with reprocessed seismic reprocessed seismic in blue.
CASSEM
25/10/2010
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CASSEM
CASSEMFirth of Forth - Overview of model with all 11 modelled
horizons and 28 faults shown
25/10/2010
55
CASSEMflexural slip unfolding
Testing and validation of level II Firth of Forth model
eroded surface rebuilding
4 October 2010 CASSEM Conference 109
Smoothing
CASSEMExample seismic section through the
Lincolnshire Wolds 3D survey.
Image ©BGS/NERC.Seismic data shown with permission of UKOGL
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CASSEMMaximum error on depth of top of Sherwood Sandstone Group
4 October 2010 CASSEM Conference 111
CASSEM3D geological framework model for Lincolnshire Faults intersecting top Sherwood Sandstone Group – view to NE
4 October 2010 CASSEM Conference 112
25/10/2010
57
CASSEMMpath Fetch and Closure Analysis on the Lincolnshire Sherwood Sandstone group
4 October 2010 CASSEM Conference 113
CASSEM
25/10/2010
58
CASSEMFinal modelFirth of Forth
4 October 2010 CASSEM Conference 115
Final modelLincolnshire
CASSEMSummary (1)
• Establishment of an asset team is f d t l t ti l id tifi ti f fundamental to timely identification of major hurdles and difficulties
– Leads to rapid identification of inconsistencies in early stages of geological modelling and interpretationinterpretation
– Enables frequent interaction and communication of data limitations and uncertainty issues to partners
4 October 2010 CASSEM Conference 116
25/10/2010
59
CASSEMSummary (2)
• Use of First Response Tools
– Provides early assessment of site suitability for more detailed modelling and risking for capacity estimates
– Highlights inconsistencies in the geological interpretations
– Identifies areas that would benefit from improved data
4 October 2010 CASSEM Conference 117
CASSEMSummary (3)
• Reprocessing and reinterpretation of seismic data
– Can reduce uncertainty in the geological model with improved resolution of fault structures and constraining depths of key surfaces
f id ifi d l ll id – If identified at an early stage can allow more rapid progress to delivery of final model with consequent cost benefit
4 October 2010 CASSEM Conference 118
25/10/2010
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CASSEMSummary (4)
• Use of the two contrasting sites has enabled CASSEM to develop the workflow enabled CASSEM to develop the workflow and to demonstrate its application in different scenarios
– a relatively simple geological site with good data quality (Lincolnshire)
– a geological site with complicated geometries and structural features and limited data (Firth of Forth)
4 October 2010 CASSEM Conference 119
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
G l i l i i Geological interpretation and storage modelling
D id L B iti h David Lawrence, British Geological Survey
4 October 2010 CASSEM Conference 120
25/10/2010
61
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
CASSEM Conference
O D i E thOur Dynamic Earth
4 October 2010 CASSEM Conference 121
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Fate of CO2: Rock Mechanics, Fate of CO2: Rock Mechanics, Geochemistry & Aquifer Fluid
Flow
E i M k P t Old d
4 October 2010 CASSEM Conference 122
Eric Mackay, Peter Olden and Gillian Pickup, Heriot-Watt
University
25/10/2010
62
CASSEMOutline
• Introduction• Phases 1 and 2 Modelling• Fluid Flow Measurements• Geomechanical Measurements and
Modellingh d ll• Phase 3 Modelling
• Conclusions
4 October 2010 123CASSEM Conference
CASSEMAims
• Understand processes occurring in an ifaquifer
• Predict behaviour of CO2
– pressure build-up, migration, trapping
• Perform numerical simulations to identify fate of CO2
• Develop methodology for site assessment
4 October 2010 CASSEM Conference 124
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63
CASSEMOverview
laboratory measurements
BGSsurfaces
geologicalflow
simulation
4 October 2010 CASSEM Conference 125
modelpetrophysical data
CASSEMLinks with other activities
lab results
monitoringinjectionstrategy
4 October 2010 CASSEM Conference 126
risk economics
hydrogeology
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CASSEMExample Calculation of Fate of CO2
4 October 2010 CASSEM Conference 127
CASSEMThree Phases of Activity
Phase 1Simple modelsExisting Data
Phase 2Intermediate models
G1
Specific Geological Model
Invest
Hold
4 October 2010 CASSEM Conference 128
Phase 3Detailed models
G2
LaboratoryMeasurements
Invest
Hold
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CASSEMModelling Tools
• Reservoir Modelling– Petrel
• Flow Simulations– Eclipse 300 (CO2STORE)
• Geomechanical simulationsVISAGE
Schlumberger
Schlumberger
– VISAGE
• Geochemical simulations– GEM
4 October 2010 CASSEM Conference 129
Schlumberger
CMG
CASSEMOutline
• Introduction• Phases 1 and 2 Modelling• Fluid Flow Measurements• Geomechanical Measurements and
Modellingh d ll• Phase 3 Modelling
• Conclusions
4 October 2010 130CASSEM Conference
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CASSEMPhase 1
• Existing geological and petrophysical d t
Phase 1
data• Simple model• Initial storage assessment• Very low cost
k• Few person weeks
4 October 2010 CASSEM Conference 131
CASSEMForth Site
• Insufficient data to make a geological d l
Phase 1
model– used a cuboidal model– simple assessment of volumetrics
and boundary conditionsCO2
4 October 2010 CASSEM Conference 132
5 km
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CASSEMLincs Site
• Some geological surfaces available
Phase 1
– although aquifer formation not resolved
Zone 1
Zone 2
4 October 2010 CASSEM Conference 133
90 km
CASSEMSummary of Phase I
• Useful preliminary exercise
Phase 1
– setting up workflow– initial volumetrics– investigating effects of aquifer boundaries
• Insufficient geological data• Insufficient geological data
4 October 2010 CASSEM Conference 134
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68
CASSEMPhase 2
• Geological structure from BGS
Phase 2
• More detailed model• Storage assessment and plume migration• Low cost• 1 person year
4 October 2010 CASSEM Conference 135
CASSEMForth Site
Phase 2
4 October 2010 CASSEM Conference 136
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69
CASSEMForth Site
Phase 2
B ll
16 km
4 October 2010 CASSEM Conference 137
0.0 0.30.1 0.2
Porosity
Ballagan
Knox PulpitKinnesswood
Glenvale18 km
350 m
CASSEMCO2 Migration – end injection, 15 yrs
Phase 2
Injection rate15 Mt/yr
top KWD
injection well
CASSEM Conference 1380.00 0.23 0.47 0.70 0.93
Supercrit CO2 sat (frac)
4 October 2010
25/10/2010
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CASSEMCO2 Migration – 100 yrs after shut-in
Phase 2
inj
top KWD
injection well
CASSEM Conference 1390.00 0.23 0.47 0.70 0.93
Supercrit CO2 sat (frac)
4 October 2010
CASSEMCO2 Migration – 1000 yrs after shut-in
Phase 2
top KWD
injection well
CASSEM Conference 1400.00 0.23 0.47 0.70 0.93
Supercrit CO2 sat (frac)
4 October 2010
25/10/2010
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CASSEMLincs Site
Phase 2
main seal
4 October 2010 CASSEM Conference 141
target aquifer
lower formation
CASSEMLincs Site
Phase 2
PorositySherwood sdst
Mercia mdst
43 km30 km
4 October 2010 CASSEM Conference 142
0.0 0.30.1 0.2Roxby 700 m
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CASSEM
inj
CO2 Migration – End Injection,15 years
Phase 2
top SSG
4 October 2010 CASSEM Conference 143
0.00 0.17 0.35 0.52 0.70
Supercrit CO2 sat (frac)
CASSEM
inj
CO2 Migration – 100 yrs after shut-in
Phase 2
top SSG
4 October 2010 CASSEM Conference 144
0.00 0.17 0.35 0.52 0.70
Supercrit CO2 sat (frac)
25/10/2010
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CASSEM
inj
CO2 Migration – 1000 yrs after shut-in
Phase 2
top SSG
4 October 2010 CASSEM Conference 145
0.00 0.17 0.35 0.52 0.70
Supercrit CO2 sat (frac)
CASSEMStorage Efficiency
• CO2 does not fill the pore space in an if
Phase 2
aquifera) due to buoyancy, CO2 migrates to top of
aquiferb) often pressure build-up is the limiting
factor
4 October 2010 CASSEM Conference 146
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CASSEMStorage Efficiency
• Storage efficiency is defined as
Phase 2
2VolumeofCO stored intheaquiferE=
Volumeofporespace
• Typically, E may be a few percent, or less
4 October 2010 CASSEM Conference 147
CASSEMPhase 2 Estimates
• Efficiency for 15 years injection
Phase 2
• Maximum efficiency up to pressure limit
Forth LincsE (%) Time
(yrs)E (%) Time
(yrs)
4 October 2010 CASSEM Conference 148
(yrs) (yrs)Actual 0.25 15 0.27 15
Maximum 2.75 155 1.00 53
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CASSEMSummary of Phase 2
• Effect of topography of top of aquifer
Phase 2
– CO2 can migrate further under ridges
• Salinity gradient– salinity tends to increase with depth
• usually neglected
ff t di l ti f CO– affects dissolution of CO2
– convection of brine with dissolved CO2
4 October 2010 CASSEM Conference 149
CASSEMSummary of Phase 2
• The maximum storage efficiency is small
Phase 2
– Lincs, E ~ 1%– Forth, E ~ 3%
• Phase 2 models also used forncertaint assessment– uncertainty assessment
– monitoring
4 October 2010 CASSEM Conference 150
25/10/2010
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CASSEMOutline
• Introduction• Phases 1 and 2 Modelling• Fluid Flow Measurements• Geomechanical Measurements and
Modellingh d ll• Phase 3 Modelling
• Conclusions
4 October 2010 151CASSEM Conference
CASSEMFluid Flow Measurements
• Two types of test
Flow Lab
• Geochemical tests– investigate how brine with dissolved CO2
interacts with rock minerals
• Relative permeability measurements– measure how the presence of brine in the
aquifer affects the flow of CO2
4 October 2010 CASSEM Conference 152
25/10/2010
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CASSEM1. GeochemicalMeasurements
• Tests performed on core plugs from b h l
Flow Lab
boreholes– 138 bar and 38 oC– 1cc/hour
Inject brine with dissolved CO2
Analyse effluent
4 October 2010 CASSEM Conference 153
4 cm
CASSEMGeochemical Results
Flow Lab
Pressure increase
brine only
~ 3 psi = 0.2 bar
4 October 2010 CASSEM Conference 154
CO2 in brine
Time (days)
5 10 15 20 25 30
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CASSEMGeochemical Results
• Magnesium ions increasedTi l
Flow Lab
– dissolution of dolomite
• Strontium ions decreased– possible deposition SrSO4
• Pressure increased, either
Time-scale of days or
weeks
– deposition of minerals lowering the permeability
– movement of fine material blocking pores
4 October 2010 CASSEM Conference 155
CASSEM2. Relative PermeabilityMeasurements
• Permeability is the
Flow Lab
• Permeability is the property of a rock which allows a fluid to flow through it
4 October 2010 CASSEM Conference 156
• Need to measure relative permeabilities– depend on type of rock and fluid saturations
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CASSEMRelative Permeability Measurements
Pressure drop
Flow Lab
p
4 October 2010 CASSEM Conference 157
Relative permeability ~ flow rate/pressure drop
CASSEMRelative Permeability Curve
100% water saturation
Flow Lab
very low CO2rel perm
satu at o
as CO2 is introduced, water rel perm
decreases
4 October 2010 CASSEM Conference 158
irreducible water
rel perm to CO2 starts low and increases
25/10/2010
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CASSEMRelative Permeability Curve
Flow Lab
4 October 2010 CASSEM Conference 159
trapped CO2
CASSEMSummary of Fluid Flow Measurements
• Geochemical experiment
Flow Lab
– CO2 dissolved in brine interacts rapidly with the rock minerals
• Relative permeability measurements– our lab results are very different from curves – our lab results are very different from curves
often assumed for numerical simulation
4 October 2010 CASSEM Conference 160
25/10/2010
81
CASSEMOutline
• Introduction• Phases 1 and 2 Modelling• Fluid Flow Measurements• Geomechanical Measurements and
Modellingh d ll• Phase 3 Modelling
• Conclusions
4 October 2010 161CASSEM Conference
CASSEMGeomechanical Study
• Introduction to geomechanical effects
Rock Lab
• Description of geomechanical measurements
• Synthesis of results
• Coupled geomechanical and flow • Coupled geomechanical and flow modelling
4 October 2010 CASSEM Conference 162
25/10/2010
82
CASSEMBackground
• CO2 injection into a porous and permeable formationh
Rock Lab
• pressure changes→ deformation and stress→ alters porosity and permeability→ affects fluid flow
• Deformation and stress
4 October 2010 CASSEM Conference 163
• potential failure of aquifer and seal rock→ hydraulic fracturing and shear failure→ migration of fluids to other formations
CASSEMRock mass subjected to external and internal forces such as CO2 injection
Rock Lab
Geomechanical response primarily determined by fractures and faults
4 October 2010 CASSEM Conference 164
Measure force required to break the rock
Force at failure F
σo = F ⁄ A
Sample cross-section area A
25/10/2010
83
CASSEMIncreasing confinement σ3 increases the stress at which the rock fails σ1
σ1
σ3
Rock Lab
σ1
σ3
pore fluid pressure p
4 October 2010 CASSEM Conference 165
3
Effective stressσ′ = σ – pwhere σ isexternal stress
CASSEMRock Mechanical Triaxial Tests
Elastic deformation parameters:• Static properties determined by
Rock Lab
p p ystrain gauging:
Young’s modulus EstatPoisson’s ratio νstat
• Dynamic properties determined by acoustic velocities Vp, Vs
Edyn, νdyn
4 October 2010 CASSEM Conference 166
Failedrock
sampleHoek Cell
25/10/2010
84
CASSEMExample Laboratory Results
60Phase II correlation (static)Lab. data: static - dry Lab. data: dynamic - dry
Rock Lab
20
40
You
ng's
mod
ulus
GP
aLab. data: dynamic dryLab. data: dynamic - brine saturated
ung’
s M
odul
us (G
pa)
4 October 2010 167
00 10 20 30 40
Porosity %
You
Porosity %CASSEM Conference
CASSEMPermeability-Stress Sensitivity
1.0
Yorks-Lincs
A if ff ti t
Rock Lab
0.4
0.6
0.8
orm
aliz
ed p
erm
eabi
lity
Aquifer mean effective stress range
aliz
ed P
erm
eabi
lity
4 October 2010 CASSEM Conference 168
0.0
0.2
0 5000 10000 15000 20000 25000 30000
Stress kPa
No
2450 SSG 2453 SSG2459 SSG 2460 SSG
2461 SSG 2463 SSG2387 BPSG Average
Nor
ma
Stress (kPa)
25/10/2010
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CASSEMGeochemical Effects
5Pre geochemical testing
Permeability before and after geochemical testing
Rock Lab
2
3
4
Per
mea
bilit
y (m
D)
Pre-geochemical testingPost-geochemical testing
rmea
bilit
y (m
D)
4 October 2010 CASSEM Conference 169
0
1
0 5 10 15 20 25 30Effective Stress (MPa)
Per
Effective Stress (MPa)
CASSEMGeomechanical Modelling
Phase 3Rock Lab
Fluid FlowSimulator
Stress & Strain
Updated Porosity&
Permeability
Simulator(ECLIPSE)
Pore Pressure&
Temperature
4 October 2010 CASSEM Conference 170
Stress & Strain
Geomechanical Simulator(VISAGE)
25/10/2010
86
CASSEMExample Geomechanical Model
Lincs model
Phase 3Rock Lab
Lincs modelCoarse grid66,975 cells
4 October 2010 CASSEM Conference 171
CASSEMWorld Stress Map
No data for Forth model
Phase 3Rock Lab
Strike-slip
Maximum horizontal stress direction~35N
Sparse data for Lincs model
4 October 2010 CASSEM Conference 172
stress regimes
Unclassifiedstress
regimes
~35° Storage
site location
N
25/10/2010
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CASSEMPotential for Rock Failure
• Increase in pore pressure
Phase 3Rock Lab
– reduces effective stress
• Poro-elastic effect– alters σ1/σ3 σ1
σ3
pore fluid pressure p
4 October 2010 CASSEM Conference 173
CASSEM
• Failure of intact rock
Potential for Rock Failure
Phase 3Rock Lab
– new fractures
• Reactivation of old fault– slip failure σ1
σ3
pore fluid pressure p
4 October 2010 CASSEM Conference 174
25/10/2010
88
Lincs – Closeness to Failure of Intact Rock Time
years 15 25 ~100 ~1000 ~7000
Caprockupper
Phase 2 Phase 3Rock Lab
Caprocklowerlayer
layer
(a)
Caprockupper
Phase 2
4 October 2010 CASSEM Conference 175
pplayer
Caprocklowerlayer
(b)Phase 3
Forth – Potential for Fault Reactivation 1 6 15 25 ~1000Time
years
Caprockmiddlelayer
Phase 2 Phase 3Rock Lab
Aquifertop
layer
layer
(a)
Caprockmiddle
Phase 2
4 October 2010 CASSEM Conference 176
layer
Aquifertop
layer
(b)Phase 3
25/10/2010
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Forth – Phase 3 Results – 15 Wells 1 6 15 25 ~1000Time
years
CaprockmiddlelayerIntact
Phase 3Rock Lab
(a)Aquifer
toplayer
Caprockmiddle
Intactfailure
4 October 2010 CASSEM Conference 177
(b)
middlelayer
Aquifertop
layer
Faultreacti-vation
CASSEMGeomechanics Summary
• Laboratory measurements produced f l d t
Phase 3Rock Lab
useful data– porosities and permeabilities– effect of stress on permeability– geomechanical parameters used in flow
modellingg
4 October 2010 CASSEM Conference 178
25/10/2010
90
CASSEMGeomechanics Summary
• Coupled flow and geomechanical modelling
Phase 3Rock Lab
– estimate of risk of rock failure due to CO2injection
• new faults or re-activation of old faults
• Failure unlikely in Lincs site
C ld h f il i F h i• Could have failure in Forth site– risk reduced by multiple wells
4 October 2010 CASSEM Conference 179
CASSEMOutline
• Introduction• Phases 1 and 2 Modelling• Fluid Flow Measurements• Geomechanical Measurements and
Modellingh d ll• Phase 3 Modelling
• Conclusions
4 October 2010 180CASSEM Conference
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CASSEMPhase 3
• Most detailed models
Phase 3
• Level III geological model for Forth Site• Laboratory results used in modelling• Storage assessment and plume migration• Higher cost• Few person years
4 October 2010 CASSEM Conference 181
CASSEMRelative Permeabilities
Phase 1 Phase 2
Phase 2Phase 1 Phase 3Flow Lab
Phase 3
4 October 2010 CASSEM Conference 182
very low perm to CO2
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CASSEMRelative Permeabilities
• Implication of low CO2 lab relative bilit
Phase 3Flow Lab
permeability– CO2 mobility is lower
• migration will be significantly reduced• affects dissolution and residual trapping
– Pressure build-up at the well will be increased
4 October 2010 CASSEM Conference 183
CASSEMMultiple Wells
• Used single injection well for Phases 1 d 2
Phase 3
and 2– 15 Mt/year
• In Phase 315 wells
unrealistic
– 15 wells– each injecting 1 Mt/year
4 October 2010 CASSEM Conference 184
25/10/2010
93
CASSEMComparisons between Phases 2 and 3
• Models altered in stages between Phase 2 d Ph 3
Phase 2 Phase 3
and Phase 3• Useful sensitivity study• Identify which parameters have most
effect, egabsolute permeability– absolute permeability
– relative permeability– number of wells– compressibility
4 October 2010 CASSEM Conference 185
CASSEMForth Site
• New geological model
Phase 3Phase 2
• Lower absolute permeabilities– consistent with lab results
Forth, Phase 3BGN
KNW
KPFGEF
Forth, Phase 2 BGN
KNW
KPFGEF
4 October 2010 CASSEM Conference 186
17 km17 km
25/10/2010
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CASSEMCO2 Migration to Top of Aquifer
• 15 horizontal wells at base of aquifer
Phase 3Phase 2
Phase 3Phase 2
CASSEM Conference 1874 October 2010
CO2 saturation at top of aquifer after 1000 years
CASSEMCO2 TrappingPhase 2 Phase 3
Mobile CO2
Mobile CO2
Phase 2 Phase 3
• Less mobile CO in Phase 3 • Low level of dissolution
Immobile CO2
Dissolved
Immobile CO2
Dissolved
• Less mobile CO2 in Phase 3 at all times– 15 horizontal wells– increased dissolution and
residual trapping
• Low level of dissolution in Forth model– deep and therefore more
saline
4 October 2010 CASSEM Conference 188
25/10/2010
95
CASSEMLincs Site
• Same geological model as Phase 2
Phase 2 Phase 3
• Some modification of properties• Main difference was the lab relative
permeabilities
43 km30 km
4 October 2010 CASSEM Conference 189
0.0 0.30.1 0.2
Porosity700 m
CASSEMCO2 Migration to Top of Aquifer
• 15 vertical wells near base of aquifer
Phase 3Phase 2
Phase 3Phase 2
4 October 2010 CASSEM Conference 190
CO2 saturation at top of aquifer after 1000 years
25/10/2010
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CASSEMCO2 TrappingPhase 2 Phase 3
Mobile CO2
Mobile CO2
Phase 2 Phase 3
• End of injection (15 yrs) • After 5000 yrs
Immobile CO2
Dissolved
Immobile CO2
Dissolved
• End of injection (15 yrs)– more dissolution in Phase 3
• 15 wells
– less immobile CO2
• due to rel perms
• After 5000 yrs– slightly less dissolution
• lower CO2 rel perm
– no mobile CO2
• due to rel perms
4 October 2010 CASSEM Conference 191
CASSEMStorage Efficiency
• Forth Site
Phase 3
– Decrease in storage efficiency in Phase 3• from 0.25% to 0.17%• due to low permeability and high pressure
build-up
• Lincs Site– Storage efficiency similar to Phase 2
• 0.27%
4 October 2010 CASSEM Conference 192
25/10/2010
97
CASSEMPhase 3 Summary
• Thorough study of factors affecting CO2i ti d t i
Phase 3
migration and trapping– absolute permeability– relative permeability– number of wells– compressibilitycompressibility– vertical permeability– ratio of permeable to impermeable rock– updated geological model
4 October 2010 CASSEM Conference 193
CASSEMPhase 3 Summary
• Forth Site
Phase 3
– largest effect was lowering of absolute permeability
– changes in geological model had less effect
• Lincs SiteLincs Site– largest effect was the relative permeability
4 October 2010 CASSEM Conference 194
25/10/2010
98
CASSEMOutline
• Introduction• Phases 1 and 2 Modelling• Fluid Flow Measurements• Geomechanical Measurements and
Modellingh d ll• Phase 3 Modelling
• Conclusions
4 October 2010 195CASSEM Conference
CASSEMConclusions
• Phase 1– initial tests– showed importance of aquifer boundary
conditions
• Phase 2– indicated importance of geological structurep g g– topography of top of aquifer determines CO2
migration paths
4 October 2010 CASSEM Conference 196
25/10/2010
99
CASSEMConclusions
• Phase 3d t t d i t f l b t – demonstrated importance of laboratory measured relative permeability
– influences injectivity, migration of CO2 and trapping
• Coupled geomechanical and flow modelling ti t th i k f k f ilcan estimate the risk of rock failure
– more significant at Forth site
4 October 2010 CASSEM Conference 197
CASSEMConclusions
• Three levels of modelling each provided i t l k d t t i f i t t incremental key data to inform investment decision making
• Laboratory measurements required to generate input for more representative generate input for more representative models
4 October 2010 CASSEM Conference 198
25/10/2010
100
CASSEMConclusions
• Much experience gained during the CASSEM P j tCASSEM Project– Phase 3 results more realistic than Phase 1
• Howeverthere is still uncertainty in the models– there is still uncertainty in the models
– more data is required to reduce this uncertainty
4 October 2010 CASSEM Conference 199
CASSEMGuidelines for Future Projects
• It is critical for geologists andi t k t thengineers to work together
– asset team approach
• A wide variety of data is required– including geology, temperature, salinity, etc
• In order to evaluate uncertainty a range of models is required
4 October 2010 CASSEM Conference 200
25/10/2010
101
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Fate of CO2: Rock Mechanics, Fate of CO2: Rock Mechanics, Geochemistry & Aquifer Fluid
Flow
E i M k P t Old d Eric Mackay, Peter Olden and Gillian Pickup, Heriot-Watt
University
4 October 2010 CASSEM Conference 201
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Geophysical Monitoring
A h J f G d i fArash JafarGandomi, University of Edinburgh
4 October 2010 CASSEM Conference 202
25/10/2010
102
CASSEMMonitoring objectives
• Leakage detection• Migration• Volume/saturation• Reservoir characterisation/quality• Cap rock integrity
4 October 2010 203CASSEM Conference
CASSEMGeophysical methods
•Seismics•Electromagnetic (EM)
Time-lapse reflection seismic
remote measurements borehole measurements
•Resistivity•Gravimetry
4 October 2010 204CASSEM Conference
http://www.glossary.oilfield.slb.com/
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CASSEMSeismics & EM/Resistivity
Vp (
km/s
)
esis
tivi
ty (
ohm
.m)
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Re
CASSEMDefinition of Site Monitorability
Site Monitorability = Survey Practicality/Cost +Geophysical Resolution +Petrophysical Detectability +Petrophysical Resolution
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CASSEMWorkflow
Geology & Geography
Relative permeabilityReservoir
rock Sampling
Lab. measurements
Petrophysical modelling
Petrophysical detectability
Petrophysical resolutionMonitoring strategy
Relative permeability
Flow simulation Monitorability Assessment
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Geophysical resolution
Practicality & costRisk assessment
CASSEMPetrophysical modelling
Clashach sample taken from outcrop
Lab.
Note nonlinearity at lower
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Field
frequencies
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CASSEMDetectability Parameters
( )XstdXXX 0−
=δ
X: IP, IS, QP, QS, Density, Resistivity
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CASSEMControlled-Source EM
ReceiversTransmitter
Air (very resistive)
Sea water(very conductive)
High-resistivity
Aquifer
( y )
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( ) )(
02
∑−
=ij
ijCOij
NLstdM
χχχ
CO2 plume
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CASSEMPurpose of monitoringUtility of geophysical parameters
G h i l SeismicGeophysical method
Seismic
EMGravity
Density Ip Is Qp Qs Resistivity
Presence
Migration
Saturation
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Seal integrity
High Low
CASSEM
Petrophysical parameters resolution
1500
2000
1500
2000
1500
2000
1500
2000
1500
2000
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−4 −2 0 2 40
500
1000
1500
−4 −2 0 2 40
500
1000
1500
−4 −2 0 2 40
500
1000
1500
−4 −2 0 2 40
500
1000
1500
−4 −2 0 2 40
500
1000
1500
CO2 saturation
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CASSEMP-wave impedance (IP) inversion
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CASSEMJoint InversionSurface Well-based
INFORMATION 1 2 3
Well-based
Surface
INFORMATION(average over all Saturations)
1 2 3
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Uncertainties:IP, IS : 2%QP, QS : 4%Rho, r : 6%
(1) surface f=30 Hz(2) well-based f=3000 Hz
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CASSEMMonitorability of CASSEM sites
Factors that affect monitorability of the two sites :
Firth of Forth
of the two sites :
•Reservoir depth•Structural complexity•Reservoir rock properties•Over/underburden structure
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York-Lincolnshire
CASSEMSpatial distribution of information
−2500
−2000
Information from seismics (IP)
Dep
th (
m)
−3.45
−3.4Injection well
1−3000
D
−3000
−2500
−2000
Information from seismics (IP+Q
P)
Dep
th (
m)
Information from seismics + CSEM (I +Resistivity)
−3.5
−3.5
−3.4
−3.3
−3.2
2
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500 1000 1500 2000 2500 3000 3500
−3000
−2500
−2000
Information from seismics + CSEM (IP+Resistivity)
Distance (m)
Dep
th (
m)
−3.25
−3.2
−3.15
−3.1
3
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CASSEMPrior Information
Input from other activities (e.g., relative permeability)
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CASSEMConclusions
• Monitorability = ….• The purpose of monitoring has a significant impact on monitoring p p g g p g
design.• Information-based technique diagnostic of monitoring methods• Multiple techniques lead to particularly good results• Surface/well measurements trade off coverage/resolution• Electromagnetic measurements have a good potential to estimate
CO2 saturation when constrained also by seismic data.Monitorability depends on overburden and underburden– Monitorability depends on overburden and underburden.
• Integration of other a priori information may significantly improve site monitorability
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Geophysical Monitoring
A h J f G d i fArash JafarGandomi, University of Edinburgh
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Risk & uncertainty
D bbi P l U i it f Debbie Polson, University of Edinburgh
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CASSEM
Risk Analysis
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CASSEMRisk Register
Features, Events and Processes (FEP) define relevant scenarios and behaviour of CO2 in the storage system.
FEP’s assessed by experts for their likelihood of impacting the project, and the severity of this impact on a 1-5 scale.
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Allows for easy comparison between different FEP’s
Allows decision makers to target resources at highest risk areas
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CASSEMRisk Register
Risk = likelihood x severityUse a risk matrix to place risk into low, moderate or high band ( lt ti l t bl t t bl l(or alternatively acceptable, not acceptable, as low as reasonably practical)
Likelihood1 2 3 4 5
Severity 1 1 2 3 4 5
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y2 2 4 6 8 103 3 6 9 12 154 4 8 12 16 205 5 10 15 20 25
CASSEMRisk Register
SeverityProject Values
Financial Environment Research Industry Viability
Light 1 £500k No modification to initial Little to no progress to 1 Project lost time > 1day. Minor Light 1 < £500k state progress to 1 of 4 goals
j ycitations
Serious 2 £500k - £5m Modification to initial state within acceptable limits
Little to no progress to 2 of 4 goals
Project lost time > 1week. Regulatory notice with out fine. Local allegations of unethical practice or mismanagement
Major 3 £5m-£25mModification to initial state above acceptable limits but without damage
Little to no progress to 3 of 4 goals
Project lost time > 1month. Permit suspension. Major local opposition or substantial negative local media coverage
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Catastrophic 4 £25m-£50mModification to initial state above acceptable limit with repairable damage
Little to no progress to 4 of 4 goals
Project lost time > 1 year. International media coverage of law violations, questionable ethical practices or mismanagement.
Multi-Catastrophic 5 >£50m
Considerable modification to initial state which is not repairable with existing technologies
No gain in understanding applicable to future projects
Negative public experience results in legal ban on similar projects
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CASSEMCASSEM sites
Firth of Forth Lincolnshire
±400
±260
±15
±10
Firth of Forth Lincolnshire
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±430 ±15
CASSEM
FEP
4 October 2010 226Likelihood x Severity
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CASSEMFE
P
4 October 2010 227Likelihood x Severity
CASSEMThe selection criteria agreed were:Information Value
• Gap in knowledge in the current earth model• Generic value of the technique
Data Acquisition
• Generic value of the technique• Criticality of Risk, as identified by risk assessment
(Cost, Timescale and Risk related to providing additional data to the project)
Information Value
Gap in Existing Model Generic Value of Information Criticality of Risk (FEP’s)
5 Complete absence of information 0% Widely applicable Addresses multiple high
risks
4 Mainly absent 25% Applicable to majority of sites Addresses 1 high risks
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4 Mainly absent 25% Applicable to majority of sites Addresses 1 high risks
3Reasonable information available, but many also absent,50%
Applicable to some sites Addresses multiple moderate risks
2 Mainly complete for site, 75% Unique to one site Addresses 1 moderate risk
1 Complete information on Site 100% No applicable to any site Addresses no risks
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CASSEM
Data Acquisition Technique
S i i R d f Fi h f F h
Data Acquisition
Seismic Reprocessed for Firth of Forth
Proxy Borehole Archive (using existing samples from boreholes or outcrops as proxy for drilling new borehole)
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Hydro Geology Study for Lincolnshire
Relative Permeability
Monitorability Assessment
CASSEMInfluence of mitigation activities on perception of risk
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CASSEM
Uncertainty Analysis
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CASSEMInput 1 (e.g. surfaces’ depth) Input 2 (e.g. porosity)
Select most likely value
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CASSEMMeta-modelling
Example: Response Surface Methodology (RSM)
Represent response of simulation as function of input Represent response of simulation as function of input parameters
ε+++= ∑∑∑= ==
j
n
i
n
ijiij
n
iii xxaxaay
110
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Linear terms Interaction terms
CASSEMExample: Migration of CO2 into caprock
P0-P100
P10-P90P10 P90
P50
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CASSEMFirth of Forth
Top-down view
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CASSEMLincolnshire
Top-down view
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CASSEMConclusions
• New comprehensive method to analyse both risk (likelihood and impact) and resulting uncertainty analysis using meta-modelling impact) and resulting uncertainty analysis using meta modelling
• Firth of Forth perceived as higher risk than Lincolnshire
• Additional data acquisition and modelling addressed some high risk FEP’s for both sites
• Uncertainty analysis shows mobile CO2 migrating through caprock f Fi th f F th it b t t Li l hi
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of Firth of Forth site but not Lincolnshire
• Uncertainty in flow predictions from a simple (box) model could not be made to include the Phase II flow simulations
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Risk & uncertainty
D bbi P l U i it f Debbie Polson, University of Edinburgh
4 October 2010 CASSEM Conference 238
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
CASSEM Conference
O D i E thOur Dynamic Earth
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Public perceptions of CCS
S h M d T d ll C t f Sarah Mander, Tyndall Centre for Climate Change Research
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CASSEMContext
Public perceptions of new technologies arecentral to successful implementationcentral to successful implementation
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Source: Greenpeace Source: France 21
CASSEMContext
Public perceptions of new technologies arecentral to successful implementationcentral to successful implementation
Low levels of public awareness of CCS makesanticipating the social response to thetechnology difficult
Previous research highlights links between:– Understanding of climate change problem and perceptions
4 October 2010 242CASSEM Conference
Understanding of climate change problem and perceptions of CCS
– CCS must be placed in the context of energy supply and mitigation options
– Level of knowledge about CCS and perceptions of the technology
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CASSEMResearch challenges
Interviews and questionnaires are unlikely toprovide an accurate picture of publicprovide an accurate picture of publicperceptions
We needed to assess people’s perceptions atthe same time as providing informationabout the technology
Deliberative processes such as citizen’s
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Deliberative processes such as citizen spanels allow participants to learn about anew topic and discuss it with experts andeach other before coming to an opinion
CASSEMCase studies
Two case studies
P f (Y k hi )Pontefract (Yorkshire)
Dunfermline (Firth of Forth)
Within high emitting regions
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Important for CCS deployment
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CASSEMCitizen panel process
40 people in total
E h l hEach panel met on threeoccasions to discuss CCSwith experts
The process allowed the researchers to observe how the participants’
4 October 2010 245CASSEM Conference
how the participants perceptions of CCS evolved as their understanding increased
CASSEMBackground knowledge of CCS and climate change
Low awareness of CCS compared to otherelectricity supply technologies
People felt they did not know enough aboutCCS to make a judgement
People were keen to find out more about CCS
There was a range of views about climatechange
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change
There was reluctance to change behaviourfor reasons of climate change mitigation
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CASSEMInitial reactions to CCS
Lots of questions focusing on:– The risks associated with CCS– The risks associated with CCS– The implications of CO2 leakage
Majority of questions could be anticipated
Others demonstrated a lack of understandingof the science behind the technology and thenature of CO2:
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nature of CO2:– What happens if the CO2 explodes?– Why can’t we just send it in to space?
Better known technologies e.g. nuclear usedto construct ideas
CASSEMEvolving perceptions
Majority of concerns about the safety of CCSwere addressed
— Trust in the experts was key to this
Remaining concerns focused on the cost andgovernance of CCS.
— Lack of trust in government and business to safelyimplement CCS
Cl i di ti th t ti i t ld l
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Clear indication that participants would onlyaccept CCS if they understood wider climatechange and energy demand debates
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CASSEMCitizen involvement
The process and opportunity to learn wasvalued by participants
Participants wished to engage with newtechnology such as CCS, and were able to doso
People acknowledged their initial poorunderstanding of CCS and the need to
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structure participation around the provisionof information
CASSEMRisk society
Perceived risks of new technologies are oftena far greater threat financially politicallya far greater threat, financially, politicallyand socially than the original physical threat
The risk society phenomenon has importantimplications about the communication ofCCS, particularly in relation to:
– Trust
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– Communication of uncertainties related to both CCS and climate change
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CASSEMBuilding trust
Information was treated with caution untilpeople had been able to:
– Understand the information– Ascertain the reliability of the information– Decide whether they could trust the experts
Face to face interactions were crucial tobuild trust between experts and participants
Citi l d t t th l f
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Citizen panels demonstrate the value ofsocial transmission of knowledge
CASSEMSummary
Perceptions of CCS will influence deployment
It is challenging to assess public perceptionsIt is challenging to assess public perceptionsof new and emerging technologies
Lay people wish to, and can, engage withnew technologies
Trust is a key factor in the acceptance of risk
G fi d i i i
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Governance, finance and monitoring remainkey areas of public concern
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CASSEM
Thank you
4 October 2010 253CASSEM Conference
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Public perceptions of CCS
S h M d T d ll C t f Sarah Mander, Tyndall Centre for Climate Change Research
4 October 2010 CASSEM Conference 254
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
R fl i f Reflections from grant sponsoring bodies
J i Willi RCUK E Jacqui Williams, RCUK Energy Programme/EPSRC
4 October 2010 CASSEM Conference 255
CASSEMThe Energy LandscapePublic Sector organisations working together to provide coordinated activity and a complete innovation chain.
Reg
iona
ltio
nal
e Tr
ansf
er N
etw
ork
diss
emin
atin
g ov
idin
g fu
ndin
g ad
vice
.
Nat
Euro
pean
Ene
rgy
Gen
erat
ion
Know
ledg
ein
form
atio
n an
d pr
o
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CASSEMEnergy ProgrammeTo position the UK to meet its energy and environmental targets and policy goals through high quality research and postgraduate training.
To support a full spectrum of Energy research to help the UK meet the objectives and targets set out in the Energy White Paper
To work in partnership to contribute to the research and postgraduate training needs of energy-related business and other key stakeholders
To increase the international To expand the UK research visibility and level of international collaboration withinthe UK energy research Portfolio.
capacity in energy-relatedareas.
CASSEMWhy CASSEM?
• CCS/CAT a priority for Technology Strategy Board and Energy ProgrammeStrategy Board and Energy Programme
• At time little CCS research supported• Whole chain representation, strong team
and highly regarded proposal• Industrially led - pull through• Investment of £1.73m from EPSRC/Energy
Programme plus TSB management resources (December 2007).
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CASSEMThoughts now (1)
• CASSEM now part of a major RCUK/TSB portfolio in CCS/CATportfolio in CCS/CAT
• CASSEM includes range of topics from public perception, risk and uncertainty, financial modelling and all aspects of storage.
• More multidisciplinary and whole systems projects more generally now
• Public perception and education now recognised as major issue for CCS – CASSEM contributes here.
CASSEMThoughts now (2)
• KT/impact agenda – CASSEM has worked well to publicise outputs and be open well to publicise outputs and be open e.g. this event, publication
• Large project, many contributing partners so challenging to manage – well run to ensure focus maintained and kept on trackon track
• Pleased to see developments such as Scottish Power Academic Alliance.
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
R fl i f Reflections from grant sponsoring bodies
J i Willi RCUK E Jacqui Williams, RCUK Energy Programme/EPSRC
4 October 2010 CASSEM Conference 261
CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Taking the CASSEM Taking the CASSEM methodology into future
projects
D id C b ll S tti hPDavid Campbell, ScottishPower
4 October 2010 CASSEM Conference 262
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CASSEMCO2 Aquifer Storage Site Evaluation and Monitoring
Thank you.
A f th tiAny further questions:[email protected]
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