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MATHEMATICAL MODELING OF GOUNDWATER FLOW WITH THE EFFECTS OF ADVECTION AND DISPERSION IN A POROUS MEDIUM ADAM BIN SAMSUDIN UNIVERSITI TEKNOLOGI MALAYSIA

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MATHEMATICAL MODELING OF GOUNDWATER FLOW

WITH THE EFFECTS OF ADVECTION AND DISPERSION

IN A POROUS MEDIUM

ADAM BIN SAMSUDIN

UNIVERSITI TEKNOLOGI MALAYSIA

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MATHEMATICAL MODELING OF GROUNDWATER FLOW

WITH THE EFFECTS OF DISPERSION AND ADVECTION IN A MEDIUM

ADAM BIN SAMSUDIN

This thesis is submitted as a partial fulfillment

of the requirements for the award of the degree of

Master of Science (Engineering Mathematics)

Faculty of Science

Universiti Teknologi Malaysia

JANUARY 2014

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To my beloved Mak and Abah, for your love and support

To my family members, for your consideration and care

To my friends, for your concern, intelligence and guidance in life

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ACKNOWLEDGEMENT

All praise is due to Allah, the Lord of the world. Thankful for the strength

He has given me to complete my thesis.

This thesis has been compiled with contribution from many people whom

I wish to acknowledge for their dedication. I wish to express my sincere

appreciation to my supervisor, Assoc. Prof. Dr Shamsudin Bin Ahmad, of

Universiti Teknologi Malaysia (UTM) for his continuous guidance and

motivation.

I am also thankful to all my family members especially my parents for

their patience and support. They have given encouragement, advices and

motivation during my time in UTM.

I am also grateful to my wonderful friends for their willingness to support

and help me when I felt helpless. Your help I’m appreciated because it is very

valuable motivation to complete of the studied.

Once again, thanks to everyone who has directly or indirectly participated

in helping me to complete this dissertation.

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ABSTRACT

Groundwater is one of the most important fresh water resources in our earth .This

dissertation presents the mathematical model of groundwater flow with the effect of

advection and dispersion in a porous medium. The purpose of this dissertation is to

review in detail the one-dimensional advection-dispersion equation (ADE) for two

different groundwater problems that is continuous injection and instantaneous

injection. In this study, we are formulating a one dimensional mathematical model of

a groundwater flow with only the effect of advection and dispersion. We are using

Laplace transform to solve the advection dispersion equation for both cases but in a

different way. For continuous injection we introduce dependent variable, ( )

( ) (

) and apply the Duhamel’s theorem. While for instantaneous

injection, after transform the general equation into Laplace form we change it into

characteristic form and solve it using by applied the boundary condition. Lastly, we

solved the continuous injection problem used numerical method via Mathematica

programming. Results of the advection dispersion model of this problem are

presented by the graphical figures.

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ABSTRAK

Air bawah tanah merupakan salah satu sumber air tawar terpenting di

bumi kita. Disertasi ini membentangkan model matematik pengaliran air bawah

tanah dengan kesan olahan dan penyebaran dalam medium berliang. Tujuan

disertasi ini adalah untuk mengkaji secara terperinci persamaan satu dimensi

olahan-penyebaran atau singkatannya ADE untuk dua masalah air bawah tanah

yang berbeza iaitu suntikan berterusan dan suntikan serta-merta. Dalam kajian

ini, kami hanya fokus kepada model matematik satu dimensi aliran air bawah

tanah dengan hanya kesan olahan dan penyebaran. Penyelesaian tepat diperolehi

dengan menggunakan jelmaan Laplace untuk menyelesaikan persamaan

penyebaran olahan bagi kedua-dua masalah tetapi dengan cara yang berbeza. Un

tuk suntikan berterusan, kami memperkenalkan pemboleh ubah, ( )

( ) (

) dan menggunakan teorem Duhamel’s bagi menyelesaikan

masalah ini. Sementara, untuk suntikan serta merta selepas menukarkan

persamaan umum kepada Laplace dan persamaan karakteristik, seterusnya

selesaikan dengan menggunakan keadaan sempadan yang telah juga di ubah

kepada Laplace. Akhir sekali, kami menggunakan kaedah berangka melalui

pengaturcaraan Mathematica bagi menyelesaikan masalah suntikan berterusan.

Keputusan model penyebaran olahan masalah ini dibentangkan secara graf.

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TABLES OF CONTENTS

CHAPTER TITLE PAGE

DECLARATION ii

DEDICATION iii

ACKNOWLEDGEMENTS iv

ABSTRACT v

ABSTRAK vi

TABLE OF CONTENTS vii

LIST OF FIGURES ix

1 INTRODUCTION 1

1.1 Introduction 1

1.2 Background of the Problem 3

1.3 Statement of Problem 4

1.4 Objectives of the Study 4

1.5 Significance of the Study 5

1.6 Scope of the Study 5

1.7 Dissertation Organization 5

2 LITERATURE REVIEW 7

2.1 Introduction to Groundwater 7

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2.2 Groundwater Hydrology 9

2.2.1 Aquifers 10

2.2.1a Unconfined Aquifers 11

2.2.1b Confined Aquifers 11

2.3 Groundwater Movement 12

2.4 An Advection-dispersion equation 13

2.5 One-Dimensional ADE 14

2.6 The Definition of Advection-dispersion 16

2.7 History of ADE solution 17

2.7.1 Analytical Solution 18

2.7.2 Numerical Solution 19

2.8 Fick’s Law of Diffusion 21

3 METHODOLOGY 24

3.1 Introduction 24

3.2 Laplace Transform 25

3.3 Finite Difference Method 25

3.3.1 Formulation of FTCS scheme 26

4 ADVECTION DISPERSION MODEL 29

4.1 Introduction 29

4.2 Factors to set up an Advection-dispersion model 30

4.3 Mathematical Model of Groundwater flow 30

4.4 Analytical Solution of ADE 34

4.4.1 First Boundary Condition 34

4.4.2 Second Boundary Condition 43

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4.5 Analytical Results 46

4.6 FTCS Solution 55

4.7 FTCS Results 58

4.8 Discussion of Findings 61

5 CONCLUSION 62

5.1 Dissertation Summary 62

5.2 Recommendation For Future Research 63

REFERENCES 65

APPENDIX 69

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LIST OF FIGURES

FIGURE NO TITLE PAGE

1 Microscopic movement of fluid particles in pores 3

2.1 Cross-section of Groundwater area 8

2.2 Aquifers 10

2.3 The control volume used to derive Equation (2.13) 22

3.1 Computational molecules of 1D FTSC 26

4.1 Fluids with constant average linear velocity flowing 30

through a cylindrical column of porous material. A

representative elementary volume used to derive

𝑐 +𝑢𝑐 =𝐷1𝑐

4.5.1 3D concentration profile of first boundary 49

4.5.2 3D concentration profile of second boundary 50

4.5.3 Concentration against Distance for various dispersion 51

coefficients,D with the fixed t=1.5 of (4.28)

4.5.4 Concentration against Distance for various dispersion 52

Coefficients,D when ADE is more advection dominated

With the fixed t=4 of (4.28)

4.5.5 Concentartion against Distance for various velocities,u 52

with fixed t=2 of (4.28)

4.5.6 Concentration against Distance for various Dispersion 53

coefficients,D with fixed t=4 of (4.33)

4.5.7 Concentration against Distance for various velocities,u 54

With fixed t=4 of (4.33)

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4.5.8 Concentration against Distance for various amount of 54

A with fixed t=4 of (4.33)

4.5.9 Concentartion against Distance for various volumetric 55

Flow rate,Q with fixed t=4 of (4.33)

I. Graph of Analytical Results :

Graph(1) Concentration against Distance,m of (4.28) 47

with t=2.0, C0=1.0, D=1.0, and u=1.0

Graph(2) Concentration against Time,days of (4.28) 48

with x=3, C0=1.0, D=1.0 and u=1.0

Graph(3) Concentration against Distance,m of (4.33) 48

with A=1, Q=0.5, t=2, C0=1.0, and u=1.0

Graph(4) Concentration against Time,days of (4.33) 49

with A=1, Q=0.5, x=3, C0=1.0, and u=1.0

II. Graph of Numerical Results:

Graph(5) Concentartion against Distance,m of (4.28) 59

with t=2.0, C0=1.0, D=1.0 and u=1.0

Graph(6) Concentration against Time,days of (4.28) 61

with x=3, C0=1.0, D=1.0 and u=1.0

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CHAPTER 1

INTRODUCTION

1.1 Introduction

A pollutant or leachate may enter the groundwater zone directly to a

landfill site from an industrial site such as nuclear power plants, chemical

industries, construction industries etc by dumping of toxic waste, agriculture and

waste disposal. Radioactive waste is disposed under the ground and gets released

into groundwater because of advection, dispersion and diffusion.

In recent year‟s groundwater flow and contaminant transport model play

an important role in many projects dealing with groundwater exploitation,

protection and remediation. A groundwater flow model is essential for the

development of a contaminant transport model. Groundwater flow models are

used to calculate the rate and the direction of the movement of groundwater

through aquifers and confining units in the subsurface. Scientists facing lot of

problem in assessing extend of groundwater pollution and effectiveness remedial

action.

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In developing a groundwater flow or solute transport model the analyst

begins by preparing a conceptual model consisting of a list of physical and

chemical processes of the system under study (solute transport by advection,

dispersion and diffusion). The next step is to translate the conceptual model into

mathematical model consisting of one or one partial difference equations and set

of initial and boundary conditions. Advection-dispersion equation (ADE)

describes the solute transport due to combined effect of dispersion and

convection in a medium. Environmentalists, hydrologists, civil engineers and

mathematical modelers concentrate more on the advection-dispersion equations

to ensure the safe hydro-environment. The analytical and numerical solutions of

the advection-dispersion equations are useful to assess the time and position at

which the concentration level of the pollutants will start affecting the health of

the habitats in the polluted water eco-system. Also such solutions help estimate

and examine the rehabilitation process and management of a polluted water body

after elimination of the pollution. The analytical solution of dispersion problems

in ideal conditions is obtained by reducing the advection-dispersion equation into

a dispersion equation by eliminating the convective term.

The analytical solutions of advection-dispersion equation have been

discussed by many researchers like Bastian and Lapidus (1956), Ogata and Banks

(1961), Banks and Ali (1964), Lai and Jurinak (1971), Marino (1974), Al-Niami

and Rushton (1977), Atul Kumar et al. (2009), Dilip Kumar et al (2011) etc.

For finding the analytical or numerical solutions of dispersions problems,

the decision parameters of the model must have crisp value. But in groundwater

hydrology, uncertainties arise due to insufficient data or imprecise information in

the identification and classification of aquifers properties. Also, in real-world

applications certainty, reliability and precision of data are often not possible and

it involves high information costs. These uncertainties are due to insufficient data

or imprecise information. In this project, we model the uncertain parameters as

interval numbers.

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Figure 1: Microscopic movement of fluid particles in pores.

1.2 Background of the Problem

Groundwater is one of the most prominent water resources for domestic

and industrial uses to a large part of the human population. Groundwater refers to

the subsurface water that occur beneath the water table in soil and geologic

formations that are fully saturated. It is sometimes known as phreatic or plerotic

water although these words are less often found in literature to groundwater. In

some localities, the demand for groundwater has increased faster than for surface

water. As the result, the rate of groundwater withdrawal has exceeded the rate of

natural replenishment in these areas (Thomas, 1951). Concern of groundwater

environment has greatly stimulated research of solute transport phenomena which

is generally associated with the advection-diffusion equation (Leij et al., 1991).

As such, advection-diffusion is sometimes referred to as advection-dispersion,

convection-diffusion or convection-dispersion. It has also been referred to as

hydrodynamic dispersion or drift dispersion. In this research, the advection-

dispersion equation and its aliases are abbreviated as ADE.

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1.3 Statement of Problem

To help better understand our world, we often describe a particular

phenomenon mathematically. Such mathematical model is an idealization of the

real world phenomenon and never a completely accurate representation. In

modeling world, we often are interested in predicting the value of a variable at

some time in the future.

In this research, in order to study the groundwater flow with the effect of

dispersion and advection in a medium, we need to study a suitable mathematical

model that represents the physical phenomenon. In this purpose, we are

determining one-dimensional (1D) mathematical model of groundwater flow

with the effect of dispersion and advection.

1.4 Objectives of the Study

The objectives of this research are:

1. To formulate 1D mathematical modeling of groundwater flow with the

effect of dispersion and advection in a porous medium.

2. To solve 1D advection diffusion equation by analytical solution of

continuous injection and instantaneous injection condition.

3. To solve 1D advection diffusion equation by numerical method of

continuous injection.

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1.5 Significance of the Study

By studying the mathematical modeling of groundwater flow with the

effect of dispersion and advection in a medium we will get better understanding

of transportation of water in underground and pipe.

1.6 Scope of the Study

Our main project is to incorporate imprecise information into solute

transport process modeling using interval arithmetic. Where, in this project we

focus only on 1D advection-dispersion equation involving internal parameters of

longitudinal dispersion in porous media.

1.7 Dissertation Organization

This thesis is organized into six chapters. First chapter contains the study

framework. An introductory chapter where we briefly described background of

the problem, statement of the problem, objectives, scope, and significance of the

study are discussed in this chapter.

In Chapter two, present the literature review of this dissertation. This

chapter explained briefly the one dimensional advection-dispersion equation, the

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definition, the background and also the previous research on ADE solve

analytically and numerical method.

In Chapter three, the methodology of the study will be discussed. This

chapter will focus on Laplace transform method as analytical solution, while

finite difference method as numerical solution of ADE on this dissertation.

In Chapter four, we will show the complete analytical solution of ADE

for both boundary condition of groundwater flow. Also, the numerical solution

for ADE solve by Mathematica software. Where, in this chapter result analysis of

data will be considered.

In Chapter five, our focus is to discuss about the results and discussion of

the problem. Finally, some suggestion and conclusion of the study will be

discussed in the chapter six.

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REFERENCES

Abbott, M.B. (1979). Computational Hydraulics : Elements of the Theory of Free

Surface Flows. London : Pitman Publishers.

Al-Niami, A.N.S. and K.R. Rushton. (1977). Analysis of flow against dispersion

in porous media. J. of Hydrology. 33. 87-97.

Bear, J. & Verruijt, A. (1987). Modelling Groundwater Flow and Pollution.

Holland : D.Reidel Publishing Co.

Bertolazzi., E. and Manzini., G. (2004). Least square-based finite volumes for

solving the advection-diffusion of contaminants in porous media.

Bowden,K.F. (1983). Physical Oceanography of Coastal waters. Chicester : Ellis

Horwood Ltd.

Brannan, J. R. and Boyce, W. E. (2006).The Differential Equations: An

Introduction to Moderns & Application. New Jersey, USA:

John Wiley & Son.

Davis GB. (1985). A laplace transform technique for the analytical of a diffusion

convection equation over a finite domain. Appl. Math. Modelling 9:69-71.

Gane S. (2000). Solution of the advection equation using finite difference

schemes and the method of characteristiscs. Degree of Doctor of

Philosophy. University of Glasgow.

George F. Pinder. (2003). Groundwater modeling using geographical information

systems. John wiley & Sons, Inc.

Gorelick, S.M., Remson, I. & Cottle, R.W. (1979). “Management model of a

Groundwater system with a Transient Pollutant source.” Water resources

Research. 15(5); 1243-1249.

Guerrero JSP, Pimental LCG, Skaggs TH and Van Genuchten MT. 2009.

Analytical solution of the advection-diffusion transport equation using a

change of variable and integral transform technique. International

Journal of Heat and Mass Transfer 52:3297-3304.

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66

Gupta, A.D. & Yapa, P.N.D.D. (1982). “Saltwater Enroachment in an Aquifer :

A case study.” Water resources Research. 18(3); 546-556.

Heath, R.C. (1983). Basic ground-water hydrology. U.S. Geological survey

water supply paper 2220, 86.

Iwase, Y. and Sato, K., (2006). Groundwater Hydraulics. Veirlag Tokyo Berlin

Heidelberg, New York. Springer.

Jaiswal, D.K. and A.Kumar. Analytical Solutions of advection-diffusion equation

for varying pulse type input point source in one-dimension. International

journal of Engineering, Science and Technology. 3(1). 22-29.

Jaiswal, D.K. , A. Kumar, and N.Kumar. (2009). Analytical Solutions of one-

Dimensional advection-diffusion equation with variable coefficients in a

finite domain. J. Earth Syst.Sci. 5. 539-549.

Kreft,A. & Zuber, A. (1978). “On the Physical meaning of the Dispersion

Equation and its Solutions for different Initial and Boundary conditions.”

Chem. Eng. Science. 33; 1471-1480.

Lafolie,F. & Hayot, C.H. (1993). “One-Dimensional Solute Transport modeling

aggregated Porous Media,1. Model and Numerical Solution.”

J.Hydrology. 143(1-2); 63-83.

Leij, F.J., Skaggs, T.H & Van Genuchten, M. Th. (1991). “Analytical Solutions

for Solute Transport in Three-Dimensional semi-infinite Porous Media.”

Water Resources Research. 27(10); 2719-2733.

Leij, F.K. and Dane, J.H. (1990). Analytical solutions of the one-dimensional

advection equation or two-or three-dimensional dispersion equation.

Water resources Research 26: 1475-1482.

Lin, B.L. and Falconer, R.A. (1997). Tidal flow and transport modeling using

ULTIMATE QUICKEST scheme. Journal of Hydraulic Engineering-

Asce 123: 303-314.

Marino, M.A. (1974). Distribution of contaminants in porous media flow. Water

Resources Research. 10. 1013-1018.

Page 20: MATHEMATICAL MODELING OF GOUNDWATER FLOW WITH …eprints.utm.my/id/eprint/43942/1/AdamShamsudinMFS2014.pdf · The next step is to translate the conceptual model into mathematical

67

Murat S, Gurarslan G and Zeytinoglu A. (2010). High-order finite difference

schemes for solving the advection-diffusion equation. Mathematical and

computational Applications 15:449-460.

Novakowski, K.S. (1992). “An evaluation of Boundary Conditions for One-

Dimensional Solute Transport 1. Mathematical Development.” Water

Resources Research. 28(9); 2399-2410.

Ogata, A. and Banks, R.B.. (1961). A solution of the differential equation of

Longitudinal dispersion in porous media. U.S. Geol. Survey Professional

Paper. 411-A. 1-9.

Pengfei., F. and Dehong., S. (1996). Mathematical Modeling of Groundwater

Pollution. Springer.

R.B. Banks and J. Ali. (1964). Dispersion and adsorption in porous media flow.

J.Hydraul. Div. 90. 13-31.

Rigal, A. (1994). “High order difference Schemes for Unsteady One-

Dimensional Diffusion-Convection problems.” J. Comp. Physics. 114;

59-76.

Robert A. G. (1983). Flow phenomena in porous media. Marcel Dekker,Inc.

S.H. Lai and J.J. jurinak. (1971). Numerical approximation of cation exchange in

miscible displacement through soil columns. Soil Sci. Soc. Am. Proc. 35.

894-899.

Thomas, H.E. (1951). The Conservation of Groundwater. New York : McGraw

Hill Book Co.

Tyrrell HJV. (1964). the origin and present Status of Fick‟s law diffusion.

Journal Chemical Education. 41:397-400.

Van Geutchan MT, Alves WJ. (1982). Analytical Solutions of the One-

dimensional Convective-dispersive Solute Transport Equation. Technical

Bulletin No. 1661. United States Department of Agriculture, Washington.

Van Herwaaden, O.A. (1994). “Spread of Pollution by Dispersive Groundwater

Flow,” SIAM J. App. Math. 54(1); 26-41.

Verruijt. A., (1970). Theory of Groundwater Flow. Macmillan.

Page 21: MATHEMATICAL MODELING OF GOUNDWATER FLOW WITH …eprints.utm.my/id/eprint/43942/1/AdamShamsudinMFS2014.pdf · The next step is to translate the conceptual model into mathematical

68

W.C. Bastian and L. Lapidus. (1956). Longitudinal diffusion in ion-exchange

and

chromatographic columns. J.Phys.Chem.60. 816-817.

Wang, H.F. & Anderson, M.P. (1982). Introduction to Groundwater Modeling :

Finite Difference and Finite Elements Methods. San Francisco :

W.H.Freeman & Co.

Yamaguchi, T., Moldrup, P., Rolston, D.E., Ito, S. & Teranishi, S. (1996).

“Nitrification in Porous Media during rapid, Unsaturated water flow.”

Water Resource. 30(3); 531-540.

Yates, S.R. (1992). “An Analytical Solution for One-Dimensional Transport in

Porous Medium with an Exponential Dispersion Function,” Water

Resources Research. 28; 2149-2154.