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MATERIALS Corrosion & Advances Surfaces June 2016

MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

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Page 1: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

MATERIALS Corrosion & Advances Surfaces June 2016

Page 2: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion

What is corrosion?

Testing & Analysis: Labscale & Outdoor

Corrosion Protection

Consultancies & Advice

2 ▌

Corrosion Monitoring

Associations & Stantards

Research & Development

Page 3: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

What is corrosion? There have been several attempts to define corrosion, Corrosion is the disintegration of an engineered

material into its constituent atoms due to chemical reactions with its surroundings.

Corrosion is the spontaneous degradation of a material when it reacts with its environment.

but one of the most commonly accepted is the following Corrosion is an electrochemical reaction between a material and its environment that produces a loss of their properties.

Your partner

against corrosion

problems

TECNALIA’s OFFER

3 ▌

Page 4: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

One of the leading organizations in Europe in the field of corrosion and corrosion protection.

Partner and coordinator of numerous R&D projects in collaboration with the Industry.

Task force of 18 researchers, engineers and technicians.

Indoor labs and outdoor corrosion expositions sites (i.e.: in natural seawater).

Your partner

against corrosion

problems

TECNALIA’s OFFER

4 ▌

Page 5: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Oil & Gas Industry

Offshore, harbour and seawater systems

Transport Industry

Construction, building and infrastructure

Corrosion Reseach & Development

Energy

Chemical and process industry

Page 6: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Oil & Gas Industry Materials selection for specific applications. Evaluation of the resistance of materials to corrosion. Pitting and crevice corrosion testing Electrochemical corrosion testing Evaluation of the resistance of materials to Hydrogen Induced Cracking

(HIC, SOHIC) and sulfide stress corrosion cracking (SSC). Evaluation of the resistance of materials to corrosion fatigue in sea water. Hydrogen embrittlement Non standard testing and assessment of materials

Research & Development

6 ▌

Page 7: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Autoclaves for high pressure tests High T (up to 350ºC) and P (up to 300 bar) autoclaves. Immersion testing, coupons Electrochemical testing Slow Strain Rate Testing (SSRT) Specific media preparation (chemical products, gases, T

and P)

Research & Development

Oil & Gas Industry

7 ▌

Page 8: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Offshore, harbour and seawater systems

Assessment of the corrosion resistance of materials in seawater

Development and optimization of corrosion protection methods

Fulfill the environmental strengths and reduction of the costs

Early detection of corrosion mechanisms

Sensor Techniques & Remote monitoring

Diagnostics

Atmospheric zone

ENVI

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MEN

TAL

CON

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Splash zone

Inside the tower

Sub-merged zone

Research & Development

8 ▌

Page 10: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Degradation evaluation of aerial cable. Ageing cycles: salt spray, UV/Condensation,

thermal, erosion

Corrosion of painting systems for metallic structures: specification and in situ control

Research & Development

10 ▌

Page 11: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion in Biomass / Waste

Fired Plants

Corrosion evaluation for

biomass power plant: failure

analysis

Selection of the most suitable materials and welding procedures for containers

to final disposal of HLW (High Level Waste) in geological formations

Corrosion evaluation for solar power plants: Container material analysis and design for CSP heat exchanger and thermal energy storage units based on molten salt.

Material selection for macroencapsulation of different PCM composite materials for thermal energy storage

Research & Development

11 ▌

Energy

Page 12: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Energy

Porosity test for electrical insulator: Dye penetration test in electrical insulator porcelain.

Characterization of coatings designed for transformers: adherence test, impact test, cupping test, bend test, etc.

Material selection for oil and gas industry: refinery and pipelines

317L 2205 2507

Research & Development

12 ▌

Page 13: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Behaviour of the polymeric part of the underwater cables at high pressure and temperature

Corrosion of galvanized/painted systems for metallic structures: specification, in situ control and corrosion monitorization

Corrosion evaluation under impressed current

Energy (Electrical applications)

Research & Development

13 ▌

Page 14: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Transport industry

Improvement of the quality and the durability of materials. Development of new corrosion testing methods. Assessment of the corrosion and fatigue properties of joined materials.

Cyclic test in dissimilar joints with screws (train components)

Before test After test

Inspection of coating after service

Research & Development

14 ▌

Page 15: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion Testing & Analysis: Labscale & Outdoor

Page 16: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Lab Scale

16 ▌

Materials Testing & Failure Analysis Material testing and characterization (i.e.

chemical composition determination, microstructure, mechanical properties: tensile test, fatigue,…).

Surface properties, i.e.: surface roughness, coating adherence, wettability, hardness, …).

Failure analysis Corrosion analysis, forecasting,

assessment, control and monitoring. Wear and friction characterization. Paints and paints characterization.

Standards and Accreditations Materials testing under NADCAP, ASTM, NACE, DIN, UNE, …)

ENAC Accreditation

Labs equipped with testing facilities allowing a large number of corrosion tests in atmosphere, immersion or under mechanical solicitation to be performed according to standardized or specific demands.

Page 17: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Lab Scale

17 ▌

Labs equipped with testing facilities allowing a large number of corrosion tests in atmosphere, immersion or under mechanical solicitation to be performed according to standardized or specific demands.

Accelerated atmospheric corrosion testing H2S Corrosion testing Corrosion/degradation under stress & corrosion

fatigue In immersion (aggressive media) with or without

mechanical load.

Page 18: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Lab Scale - Erosion

18 ▌

Based on ASTM G76-95. Standard Test Method for Conducting Erosion Tests by Solid Particle Impingement Using Gas Jets, ASTM G40 Terminology relating to wear and Erosion, and MIL-STD-3033 Particle / Sand erosion testing of rotor blade protective materials. Test procedures are typically tailored to the working condition

specifications, i.e. among others particle composition, test duration, air velocity (directly related with the outlet pressure of the sand) and the angle of incidence.

Evaluation of material/component degradation is also tailored to the application. E.g. study the Erosion Rate as the weight loss of specimen material relative to the total flux of abrasive particles that impact the specimen. Profilemetry / Optical properties.

Often in combination with wear, friction and corrosion resistance characterization.

Application on e.g.:

Erosion tests by solid particle impingement using gas jets

Page 19: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Outdoor

19 ▌

Corrosion assessment, material degradation mechanism and lifetime forecasting

Unique facilities for research, development, testing & evaluation.

Materials characterization (cost-savings and life-cycle management).

Assessment of the corrosion resistance of materials in real environment and comparison with laboratory accelerated ageing assays.

Development and optimization of corrosion protection methods.

Anticorrosion coatings development. In-situ corrosion monitoring. Biofouling and anti-fouling efficiency

assessment.

Atmospheric parameters: • Wind direction

and speed • Air temperature

and humidity • Atmospheric

pressure • Rainfall • UV irradiation • ….

Water parameters: • Temperature • Dissolved oxygen • Conductivity • Depth • Transparency • …

Periodic analysis of corrosion effects: materials weight loss, ultrasonic testing, 3D laser profilometry, visual inspection, ...

Monitoring of relevant environment parameters, depending on the exposure zone and specific objectives of each assay

19 ▌

Page 20: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Outdoor

20 ▌

Natural offshore marine exposure sites for material degradation testing

Originally designed for testing and demonstrating prototype devices for harnessing ocean energy prior to their full-scale commercial development, it turned to be an ideal location for offshore material degradation exposure tests as well.

Located near the village of Armintza-Lemoiz (Bizkaia, Spain), covers a total surface area of 5.3 km2. The nearest point to land is 1,700 m away.

Fully equipped with modern subsea infrastructure for onshore grid connection and a comprehensive remote monitoring and control system for the systematic compilation and analysis of data on the systems being tested at sea.

Tecnalia placed two degradation testing exposure sites at BIMEP:

• Buoy • HARSH LAB

BiMEP (Biscay Marine Energy Platform)

Page 21: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Outdoor Natural offshore marine exposure site #1 for material degradation testing:

Real offshore environment. Equipped with two exposure zones: immersion and splash. Easy to manipulate racks with place for up to 160 standardized coupons

(80 in splash and 80 in immersion zone)

Coupons and components assays in splash zone

Coupons and components assays in immersion zone

Buoy

21 ▌

Page 22: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Outdoor

22 ▌

Coupons and components assays in atmospheric zone.

Coupons and components assays in splash zone

Coupons and components assays in confined zone

Coupons and components assays in seabed zone (60m)

Coupons and components assays in immersion zone.

Mooring component assays: Suspension zone for different mooring components. Potentially inserted in HarshLab mooring lines.

Umbilicals, connectors and risers assays : Possibility of connection both in the bottom and sides of HarshLab.

Natural offshore marine exposure site #2 for material degradation testing:

Harsh Lab (located at BiMEP)

*expected in Autumn’17

Page 23: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Outdoor

23 ▌

Natural marine exposure site #3 for material degradation testing:

Samples are exposed in Pasaia’s port (Gipuzkoa, Spain).

Immersion zone in floating jetty (no tidal).

Easy access and monitoring of environmental parameters.

Estuarine port conditions with a mix of sea water (Cantabrian sea) and fresh water (Oiartzun river).

• Salinity: 27.4 usp • Water temperature: 16.8 ºC • Dissolved oxygen: 69.0 % sat • pH: 8.0 • Transparency: 1.1m

Immersion exposure site Average environmental conditions (Jul’15-Jul’15)

Page 24: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Testing & Analysis · Outdoor

24 ▌

Research and protection

Samples exposed in the terrace of M2 Tecnalia’s building in Donostia-San Sebastian (Gipuzkoa, Spain).

Atmospheric corrosivity category established as C2 (according to ISO 9223:2012).

Test bench for services to industry and own developments and technologies.

Detailed meteorological and air quality data available thanks to nearby monitoring stations:

• NOX • NO2 • NO

Monitored meteorological parameters

Atmospheric exposure site #4 for material degradation testing

Monitored air quality parameters

• SO2 • SH2

• PM10 • PM2,5

• Rainfall • Irradiance • Humidity

• Temperature • Atmospheric pressure • Wind speed and direction

Page 25: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion monitoring

Page 26: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Offshore environment, as well as oil and gas environment, is extremely aggressive:

Necessity to anticipate the possible problem

Maintenance forecasting and planning

Solution: MONITORING!!

Atmospheric zone

ENVI

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MEN

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CON

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Splash zone

Inside the tower

Sub-merged zone

ELECTRICAL RESISTANCE

Electrochemical techniques like Electrical Resistance (ER) and Electrochemical Impedance Spectroscopy (EIS) are very useful for corrosion monitoring. A remote monitoring system based in these techniques has been developed in order to diminish the maintenance costs in Offshore conditions.

Corrosion Monitoring

26 ▌

Page 27: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion monitoring: corrosion detection under coatings

Investigation of a plane tail with Pulsed Thermography (Marc Genest et al.)

Principle of Pulsed

Thermography (D. Wu et al.)

Microwave imaging (pits under paint, principle) (DOI 10.1109 / TIM.2005.851086)

THz imaging (principle, example) (Robert F. Anastasi et al.)

Corrosion Monitoring

27 ▌

Page 28: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion Protection (see Advances Surfaces)

Page 29: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion Consultancies & Advices

Page 30: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Consultancies and advices Failure analysis Qualification of materials according to the

specifications. TECNALIA offers a large range of testing and investigation equipment to follow qualification specifications

Choice of materials Design of structures Protection methods : cathodic protection,

painting, .. Risks assessment Technical and scientific survey

Consultancies & Advices

30 ▌

Page 31: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion Associations & Standards

Page 32: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

TECNALIA is member of: AENOR: Grupo de Normalización Corrosión. CTN 112. www.aenor.es NACE: National Association of Corrosion Engineers.. www.nace.org EFC: European Federation of Corrosion. WG4. www.eurocorr.org ANQUE: Asociación Nacional de Químicos de España. www.anque.es

Associations & Standards; DIN, ASTM, NACE,…), ACCREDITATIONS (ENAC, NADCAP)

32 ▌

Page 33: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

DIN 50018, ASTM G87-02: Sulfur dioxide corrosion testing in a saturated atmosphere, Standard Practice for Conducting Moist SO 2 Tests ASTM G34-01

ASTM G66-99(2005) e1: Standard Test Method for Exfoliation Corrosion Susceptibility in 2XXX and 7XXX Series Aluminum Alloys, Standard Test Method for Visual Assessment of Exfoliation Corrosion Susceptibility of 5XXX Series Aluminum Alloys

ASTM G110-92 (2003)e1, ASTM G67-04, Standard practice for evaluating intergranular corrosion resistance of heat treatable aluminum alloys, Standard Test Method for Determining the Susceptibility to Intergranular Corrosion of 5XXX Series Aluminum Alloys by Mass Loss

ASTM G31.72(2004): Standard Practice for Laboratory Immersion Corrosion Testing of Metals ASTM G61-86(2003) e1: Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements

for Localized Corrosion Susceptibility of Iron-, Nickel-, or Cobalt-Based Alloys. ASTM G59-97 (2003), ASTM G102-89 (2004)e1: Standard Test Method for Conducting Potentiodynamic Polarization

Resistance Measurements ASTM B117-09, ASTM G75-09 A1, UNE-EN ISO 9227 (2007): Standard Practice for Operating Salt Spray (Fog)

Apparatus NACE TM0177 2005 A and C: Laboratory Testing of Metals for Resistance to Sulfide Stress Cracking and Stress

Corrosion Cracking in H2S Environments. ASTM G36-94(2006): Standard Practice for Evaluating Stress-Corrosion-Cracking Resistance of Metals and Alloys in

a Boiling Magnesium Chloride Solution ASTM G48-03 A, B, C, E: Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels

and Related Alloys by Use of Ferric Chloride Solution ASTM G28-02(2008), ASTM A 262-02a (2008) B, C, E, F, ASTM A763-93 (2004), UNE-En ISO 3651-2. 1999:

Standard Test Methods for Detecting Susceptibility to Intergranular Corrosion in Wrought, Nickel-Rich, Chromium-Bearing Alloys

Associations & Standards; DIN, ASTM, NACE,…), ACCREDITATIONS (ENAC, NADCAP)

33 ▌

Page 34: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

NACE TM 0284- 2003: Evaluation of Pipeline and Pressure Vessel Steels for Resistance to Hydrogen-Induced Cracking

ASTM A 262-02ª (2008) A: Standard Practices for Detecting Susceptibility to Intergranular Attack in Austenitic Stainless Steels

ASTM D3359-09 A,B, UNE-EN ISO 2409 2007: Standard Test Methods for Measuring Adhesion by Tape Test, Paints and varnishes - Cross-cut test ASTMD4541-09 B, UNE-EN ISO 11507 2007 A, ASTM D523-08: Standard Test Method for Pull-Off Strength of Coatings Using Portable Adhesion Testers, Standard Test Method for Specular Gloss

UNE 48269:1995, ASTM D3363-05: Standard Test Method for Film Hardness by Pencil Test

UNE-EN ISO 1522 2007: Paints and varnishes - Pendulum damping test

ASTM D2794-93 (2004), UNE-EN ISO 6272-1 2004: Standard Test Method for Resistance of Organic Coatings to the Effects of Rapid Deformation (Impact)

UNE-EN ISO 2808: 2007, 6A, 7C, 7D, Internal procedure 53-O-034: PAINTS AND VARNISHES - DETERMINATION OF FILM THICKNESS

ASTM D2247-02, UNE-EN ISO 6270-2 2006: ASTM D2247-02: Standard Practice for Testing Water Resistance of Coatings in 100% Relative Humidity, Paints and varnishes - Determination of resistance to humidity - Part 2: Procedure for exposing test specimens in condensation-water atmospheres.

ISO 3231_1993, ASTM G87-02: Determination of resistance to humid atmospheres containing sulfur dioxide, Standard Practice for Conducting Moist SO2 Tests

ASTM D5222-93a (2008) A, UNE-EN ISO 6860 2007: Standard Specification for High Fire-Point Mineral Electrical Insulating Oils, Paints and varnishes - Bend test

UNE-EN ISO 1520 2007: Paints and varnishes - Cupping test

34 ▌

Associations & Standards; DIN, ASTM, NACE,…), ACCREDITATIONS (ENAC, NADCAP)

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35 ▌

Page 36: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Advanced Surfaces

Research & Development

Applications

36 ▌

Technologies: dry & wet

Page 37: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Advances Surfaces: Research & Development

Page 38: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Advanced surfaces and coatings to: Solve industrial problems as wear, fatigue, aging, corrosion, resistivity… … through the correct selection of materials, coatings and surface treatments processes.

Develop or modifies coating and surface modification processes, specifically for each industrial need

Assists companies in the correct material selection and the application of heat treatments and surface treatments or coatings

Evaluates the behaviour of materials under “laboratory” and “industrial” conditions

Collaborates in the development of specialised equipment or helps in its selection

Provides coating and surface modification services & provides technology transfer

Advanced surfaces

38 ▌

Page 39: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Advances Surfaces: Technologies: dry & wet

Page 40: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Physical Vapour Deposition (PVD)

Advanced surfaces: Dry technologies

40 ▌

Plasma surface termo-chemical treatments

Chemical Vapour Deposition (CVD) Thermal Spraying

E.g.: active screen plasma nitriding or post-discharge plasma nitriding, nitrocarburizing, post-oxidizing,... for wear and corrosion protection.

PVD Magnetron Sputtering, e.g.: dry films lubricants

based on doped MoS2, DLC, ultra-hard nanostructured

coatings, corrosion protection, optical and

biomedical properties….

E.g. plasma polymers deposition for wear and corrosion resistance, adhesion of aluminium on different supports, conductive layers for de-icing, grafting, functionalization, biomedical coatings with antibiotic properties, self-cleaning and wettability modification,.etc

APS: atmospheric plasma spraying HVOF: High velocity oxy-fuel coating

spraying Detonation T

Page 41: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Coatings for space, aeronautical, automotive, energy… applications. New solutions based on Ionic Liquids. Electrochemical synthesis of materials

Nano-cromium deposited layer

Chromium coatings with tailored surface finishing & aesthetic

Aluminium coatings on steels Zinc/tin deposited layer

Dense and porous coatings Single layer and multilayer Different substrates: metals and metallic alloys,

polymers, glass

Ionic liquids allow electroplating metal and alloys impossible to deposit using aqueous technology: Al, Ti, Si...

Better quality than with aqueous technology Reduced environmental impact

Multifunctional Sol-Gel coatings Inorganic and hybrid coatings for different applications

SOL-GEL technology

Chemical conversion coatings, Metal&alloy plating, Anodizing, Polymeric coatings…

Advanced surfaces: wet technologies

41 ▌

Ionic Liquids

Page 42: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Texturing

MICRO-NANOPRINTING: Based on NIL processes we develop and adapt the texture to injection moulding or to thermoforming to obtain large areas.

Metal (alloy) plating and Texturing

Electroless plating system

Metallic (single metals and alloys) coatings for different applications. Possibility to deposit metallic coatings onto conductive and non-conductive substrates.

Advanced surfaces : wet technologies

42 ▌

INJECTION MOULDING and THERMOFORMING with nanostructured inserts.

INSERTS and MOULD Surface Modification: inserts and solutions for your moulds on different materials: rigid (metallic substrate and glass) and flexible(silicones, acetates, polyimides, etc..)

Electro-Less Plating Technology

Page 43: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion Wear

Energy Electrical

Optical & Electrical

Advances Surfaces: Applications

Tribology

Biocide

Page 44: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Corrosion resistant coatings for Magnesium Alloys

Sol-Gel corrosion protective coatings

Environmental friendly corrosion resistant coatings

Advanced surfaces: Corrosion

On Aluminium alloys

On Galvanized Steel

> 800h on going

> 500h on going

Conversion coating of Mg alloys based on phosphates and permanganates chemistry

Conversion coatings on aluminum alloys- SSF Tested panels (336 hours). Patented. Collaboration Boeing TECNALIA

Conversion coatings on magnesium alloys: TECNALIA patented process

CrVI free conversion coatings for light alloys

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Page 45: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Surface cleaning for aged architectural Titanium

Surface protection & Aesthetic

Pickling: Improvement of corrosion resistance

Advanced surfaces: Corrosion and Staining

Acid treatment for stainless steel that removes metallic contamination from corrosion products and high temperature scale produced in welding, heat treatment or hot working

Pickled Not Pickled

Visual appearance Scanning electron microscope

(SEM) High-Humidity Test (ASTM

A380/ASTM97) Copper sulfate Test (ASTM A380) Ferroxyl Test (ASTM A380) Salt Spray Test (B117/ASTM967) Pen surface tension TEST Sessil drop test (contact angle)

Characterisation

Guggenheim museum. Bilbao

Coatings on magnesium Alloys: Corrosion protection and aesthetic applications

45 ▌

Page 46: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Surface protection Plasma surface functionalization of polymers

Advanced surfaces: Functionalization and protection

Functionalization Hydrophobic and hydrophilic surfaces, surface conditioning for metal polymer bonding, surface energy of various polymers can be improved by plasma treatment for improved wetting with water based varnish.

As-received

After plasma treating

Selective Corrosion Protection of Electronic by plasma treatment Deposit thin, transparent and insulating plasma-polymer anti-aging coatings and to selectively protect electronic units and especially printed circuit boards.

Page 47: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Antiabrasion and erosion coatings

Abrasion / erosion dedicated tests Test designed to the application

Nano-structured hard coatings for metal-mechanical applications and/or corrosion protection

Advanced surfaces: Wear

47 ▌

nano-structured coating with high hardness, high toughness and improved wear resistance

CrAlN nanocrystalline multiphase coatings

UNimerco coated cemented carbide mills

Antiabrasion

Antierosion

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Novel Plasma Nitriding of Tool steel

Novel Plasma Nitriding of Stainless Steel

Novel Plasma Nitriding of Low allow steel

Advanced surfaces : Wear, surface hardness, fatigue of steels, cast irons, and titanuium alloys

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Active Screen Plasma Nitriding on St-52 provide hardened surfaces (>5 µm thickness), wear resistance and low friction coefficients.

Micrograph. Cross section of nitrided steel

Glow discharge on complex geometries

Active Screen Plasma Nitriding on H13 provide hardened surfaces (>50 µm thickness), wear resistance and low friction coefficients.

Active Screen Plasma Nitriding on 316L complex geometries provide hardened surfaces with high corrosion resistance in salt spray test.

Active screen glow discharge (process)

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Tribology dedicated tests Multilayer hard coatings by PVD & Solid Lubricants

Tribology* of energy conversion technologies as a whole system

Advanced surfaces : Tribology

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Science of lubrication, friction and wear

Sand and liquid particle erosion of blades

Gearbox performance Bearing Oil/grease lubrication systems Dry lubricants

Wear parts for 2 and 4 stroke engines

Dry machining. High speed machining

Coatings for space applications at the ISS * Tribology: science and engineering of interacting

surfaces in relative motion

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Protective coatings on HT and LT bipolar plates for Fuel Cells

Gas separation Plasma-polymer membranes

Gas separation Palladium-based membranes

Advanced surfaces : Tribology

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Membranes that can be operated at high temperatures

H2 purity > 99.99% Simple, compact separation

systems design Pd and its alloys are excellent

catalysts for dissociation of H2 Permeability, function of

solubility and diffusion rate of atomic hydrogen

Potential perfect selectivity

Pd-Ag supported membrane

Pd-Ag membrane layer

Coated bipolar plates

CrN coating on 316L stainless steel

Plasma polymer on cellulose acetate on polyamide …

Support

selective layer

Surface SEM image

selective layer

Support

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Sol-Gel coatings on CPV modules

Preventing Corona Effects Anti-soiling hydrophobic dielectric coatings

Anti-soiling hydrophobic dielectric coatings on HV electric components against flashover.

Anti-soiling Sol-Gel coatings with high transmittance properties for concentrating photovoltaic - CPV - power generation.

Advanced and cost-effective surface treatment for preventing corona effects

Advanced surfaces: Energy

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Optical coatings by sol-gel method

Optical coatings by PVD technology

Antiabrasion

Coloured coatings

High transmittance in the whole solar spectrum

Hydrofobic films (105º WCA) to avoid dust accumulation

Self cleaning

Light interference in thin coating

Antireflection coatings High reflection coatings Metallic mirrors, high and partially

reflective coatings Absorbers coatings based on

cermet materials Filters coatings

Customized coating solutions with optimal

tailored designs

Electrical insulators. PVD coatings

DLC Based Insulator coatings for Transmission Systems Low friction, wear resistant conductive coatings on HVDC switch gear. PVD coatings vs. controlled resistivity, i.e. leak current

Advanced surfaces : Optical & Electrical properties

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Page 53: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Surfaces with antimicrobial properties: release (plasma based surfaces)

Coatings with antimicrobial properties by PVD technology

Antibiotic plasma polymers with controlled release of Silylated Ciprofloxacin (antibiotic)

PVD coatings: Antimicrobial activity Wear resistance

Plasma polymers with attached antibiotic, e.g. vancomycine. A “Plasma-Click” Dual Procedure.

Surfaces with antimicrobial properties: attachment (plasma based surfaces)

Orthopaedic and dental applications

Advanced surfaces : Biomedical

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Page 54: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

AEROSTAR COATINGS Company that manufactures HFPD thermal spraying equipment (own technology) and develops industrial applications. Tratamientos Superficiales IONTECH Subcontracting company, provides coating and surface treatment

services, mainly for aeronautical and also for petro-chemical, biomedical, etc. industries

Processes: Thermal Spraying, PVD & Ion Implantation (through TECNALIA)

LifeNova Biomedical SA (www.lifenova.com) Company performing surface treatments and coatings for biomedical

field (dental implants)

TECNALIA has contributed with their developments to the creation of 3 companies related to ADVANCED SURFACES & COATINGS

Technology-Based Companies

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Thank you for your attention

For more information, please contact:

Pablo Corengia / [email protected]

Iñaki Azkarate / [email protected]

Page 56: MATERIALS - Tecnalia · Evaluation of the resistance of materials to corrosion fatigue in sea water. ... Erosion . 18 Based on ASTM G76-95. Standard Test Method for Conducting Erosion

Visit our blog: http://blogs.tecnalia.com/inspiring-blog/

www.tecnalia.com