Material Characterization for Processing: CYTEC Cycom 5215 · Material Characterization for Processing: CYTEC Cycom 5215 Material Model Development Final Project Wrap-Up Prepared

Material Characterization for Processing:

CYTEC Cycom 5215Material Model Development

Final Project Wrap-Up

Prepared by: A. ShahkaramiReviewed by: D. Van EeApproved: A.PoursartipDate: November 15th, 2009Version: 1.0

2

Project Definition

Modeling performed for:

• Cure Kinetics

• Heat Capacity (Cp)

• Viscosity

Material: CYCOM 5215

3

Material Description• Cycom 5215 is a 160-180ºF cure modified epoxy system

• Material forms received from Cytec are as follows:- Unidirectional Tape Prepreg (T40/800 12K 145/33, received Sept 27, 2007)- Harness Satin Fabric Prepreg (WT650-35 6K-5HS, received Sept 27, 2007)- Plain Weave Fabric Prepreg (WT650-35 3K-70PW, received Oct 9, 2007)

• The tests were done on UD tape and comparison drawn with other forms

4

MRCCs

• The recommended cure cycle for 5215 is:– Ramp @ 1-6 F/min– Hold for (one of):

– 16hrs @ 160±10F– 4hrs @ 180±10F– 2hrs/1hr @ 180±10F / 350±10F

• Post cure: Ramp @ 1-6 F/min and hold for 4hrs at 350F

5

Cure Kinetics Model

6

NomenclatureIso

Int

Dyn

RES

x

x&

gT

CC

Holdx

or Isothermal: Conditioned isothermal DSC tests where the specimen is held at a constant temperature long enough so that the reaction slows down significantly due to diffusionor Interrupted: Isothermal tests where the hold segment terminates before the reaction stops due to diffusionor dynamic: DSC tests where the specimen temperature is increased at a constant rate until the reaction completesor Residual: Dynamic DSC tests performed after the hold segment of Iso and Int tests to complete the remainder of the chemical reaction

or DoC: Degree of Cure

or xdot: Cure Rate

Glass transition temperature

or CureCycle: DSC tests designed to recreate the recommended cure cycles for the material, interrupted at certain points to investigate the cure advancement during the cure cycle

Degree of cure at the end of the hold segment of isothermal tests

7

Nomenclature

ModelHR

preTestHR

HoldHR

RampHR

TestHR

TotalHR

avgIsoHR

avgDynHR

avgTotalHR

Model heat of reaction; the nominal value of total heat of reaction used in the model (J/g)

The heat of reaction released during the cure advancement in material before the start of the test (material handling, storing, etc.) (J/g)

The heat of reaction released during the hold segment of the DSC tests (mostly in all variation of isothermal tests) (J/g)

The heat of reaction released during the ramp segment of the DSC tests (in dynamic tests and the residual ramps of the isothermal tests) (J/g)

The total heat of reaction measured through the two stages of the DSC test (J/g)

The total heat of reaction of the material tested (J/g)

The average of the total heat of reaction measured through the various stages of the isothermal DSC tests (J/g)

The average of the total heat of reaction measured through the various stages of the dynamic DSC tests (J/g)

The average of the total heat of reaction measured through the various stages of all the DSC tests(J/g)

HF Heat Flow, measured in the DSC experiments (W)

( )RampHold HRHR +=

( )TestpreTest HRHR +=

8

HR Definition

-20ºC

Handling &Storage

Making Samples

DSC Test

Hold

Ramp

Time

preTestHR TestHR

HoldHR RampHR

TotalHR

9

Summary

• Differential Scanning Calorimetry (DSC) tests were performed to characterize the cure kinetics of Cycom5215. A Q1000 TA Instrument DSC was used for this purpose.

• Normal pans were used to perform the DSC tests on UD tape.

• Characterization was performed on the UD tape. Other forms of this resin (fabric prepreg) were also tested and compared to the UD tape.

10

DSC Test ProcedureIsothermal TestsIn isothermal tests, the sample is equilibrated at a very low temperature and then heated up to a predefined hold temperature at a very high rate. The sample is held at this temperature for a predetermined duration of time (i.e. until the reaction stops due to diffusion or full cure in the case of conditioned isothermal tests, or earlier as predefined for interrupted isothermal tests). The sample is then cooled down, followed by a residual ramp at a known rate (typically 1-4 cpm). The residual ramp ensures that the material is fully cured, and provides the material Tg at the end of hold, as well as the residual heat of reaction. A second ramp is also performed to determine the final (full cure) Tg.

Dynamic TestsIn dynamic tests, the sample is equilibrated at a very low temperature and then heated up at a predetermined rate. The goal is to fully cure the sample on the ramp. A second ramp follows to determine the final glass transition temperature (fully cured Tg).

11

DSC Tests Performed

A total of 45 DSC tests were performed:

• Dynamic tests: 13 tests @ 0.5, 1, 2, 3, 4(x2), 5, 6(x2), 7, 8, 9, 10cpm• Isothermal tests: 28 tests from 65ºC to 200ºC• Interrupted Isothermal tests: 4 tests at 110ºC• Cure Cycle tests: 6 tests

After careful examination of the results and investigation of the consistency of the data, the temperature range from 65ºC to 140ºC was consistent. Isothermal runs above 140°C cured too quickly to provide accurate historical data. Final Tg values for isothermals as up to 160°C were extracted, with higher temperature holds becoming less reliable.

12

DSC Tests Used in Model Fitting*Mass Rate Tempmax

(mg) (ºC/min) (ºC)5215-MDYN-05cpm-01 9.9 0.5 3005215-MDYN-1cpm-01 4.5 1 3005215-MDYN-2cpm-01 5.2 2 2805215-MDYN-3cpm-01 4.7 3 3005215-MDYN-4cpm-01 5.0 4 2805215-MDYN-4cpm-03 5.8 4 3205215-MDYN-5cpm-01 4.8 5 3005215-MDYN-6cpm-01 4.3 6 2805215-MDYN-6cpm-02 4.8 6 3005215-MDYN-7cpm-01 5.3 7 3505215-MDYN-8cpm-01 4.4 8 3305215-MDYN-9cpm-01 4.3 9 3005215-MDYN-10cpm-01 4.8 10 300

Tests

Mass Temp Time(mg) (ºC) (min)

5215-INT-110C-10min-01 100 10.005215-INT-110C-20min-01 100 205215-INT-110C-30min-01 100 305215-INT-110C-40min-01 100 40

Hold

Tests

Mass Temp Time(mg) (ºC) (min)

5215-MISO-65C-01 11.0 65 6605215-MISO-70C-01 4.6 70 6005215-MISO-75C-01 12.4 75 6005215-MISO-80C-01 4.5 80 5405215-MISO-85C-01 11.6 85 5405215-MISO-90C-01 3.9 90 4205215-MISO-95C-01 10.8 95 4805215-MISO-100C-01 5.3 100 4205215-MISO-105C-01 11.3 105 4805215-MISO-110C-01 4.7 110 4205215-MISO-115C-01 11.5 115 4205215-MISO-120C-01 4.7 120 3605215-MISO-125C-01 10.8 125 4205215-MISO-130C-01 4.7 130 3605215-MISO-135C-01 10.9 135 4205215-MISO-140C-01 5.4 140 360

Hold

Tests

13

Degree of Cure Calculation

Isothermal Baseline Definition Dynamic Baseline Definition

-0.025

-0.005

0.015

0.035

0.055

0.075

0.095

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Deg

ree

of C

ure

-0.05

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0 2000 4000 6000 8000 10000 12000 14000 16000

Time (s)

Spec

ific

heat

flow

(W/g

)

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Deg

ree

of C

ure

14

Cure Rate vs. DoC – Dyns

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

0 0.2 0.4 0.6 0.8 1

5215-MDYN-10cpm-01-HeatUp 5215-MDYN-9cpm-01-HeatUp 5215-MDYN-8cpm-01-HeatUp 5215-MDYN-7cpm-01-HeatUp 5215-MDYN-6cpm-01-HeatUp 5215-MDYN-5cpm-01-HeatUp 5215-MDYN-4cpm-01-HeatUp 5215-MDYN-3cpm-01-HeatUp 5215-MDYN-2cpm-01-HeatUp 5215-MDYN-1cpm-01-HeatUp 5215-MDYN-05cpm-01-HeatUp

15

Cure Rate vs. DoC – Isos

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

0 0.2 0.4 0.6 0.8 1

5215-MISO-140C-01-Hold 5215-MISO-135C-01-Hold








16

-0.01

0.00

0.01

0.02

0.03

0.04

0.05

0 10000 20000 30000 40000 50000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

Cur

e ra

te (1

/s)

Heat Flow Response – 0.5cpm

0.5ºCpm Dynamic TestHRRamp = 173.982 J/g

17

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 10000 20000 30000 40000 50000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

Cur

e ra

te (1

/s)

DoC and Cure Rate – 0.5cpm

0.5ºCpm Dynamic Test

18

-0.02

0.00

0.02

0.04

0.06

0.08

0.10

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

Cur

e ra

te (1

/s)

Heat Flow Response – 1cpm

1ºCpm Dynamic TestHRRamp = 171.434 J/g

19

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

Cur

e ra

te (1

/s)

DoC and Cure Rate – 1cpm

1ºCpm Dynamic Test

20

-0.02

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0.16

0.18

0 2000 4000 6000 8000 10000 12000 14000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

Cur

e ra

te (1

/s)



21

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 2000 4000 6000 8000 10000 12000 14000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

Cur

e ra

te (1

/s)


2ºCpm Dynamic Test

22

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0 2000 4000 6000 8000 10000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

Cur

e ra

te (1

/s)



23

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 2000 4000 6000 8000 10000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

Cur

e ra

te (1

/s)


3ºCpm Dynamic Test

24

-0.05

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0 1000 2000 3000 4000 5000 6000 7000 8000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)

Heat Flow Response – 4cpm-01

4ºCpm-01 Dynamic TestHRRamp = 166.529 J/g

25

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 1000 2000 3000 4000 5000 6000 7000 8000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)

DoC and Cure Rate – 4cpm-01

4ºCpm-01 Dynamic Test

26

-0.05

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0 1000 2000 3000 4000 5000 6000 7000 8000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

Cur

e ra

te (1

/s)



27

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 1000 2000 3000 4000 5000 6000 7000 8000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

Cur

e ra

te (1

/s)



28

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0 1000 2000 3000 4000 5000 6000 7000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)



29

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 1000 2000 3000 4000 5000 6000 7000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)


5ºCpm Dynamic Test

30

-0.05

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0 1000 2000 3000 4000 5000 6000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)



31

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 1000 2000 3000 4000 5000 6000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)



32

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0 1000 2000 3000 4000 5000 6000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)



33

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 1000 2000 3000 4000 5000 6000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)



34

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.50

0 1000 2000 3000 4000 5000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)



35

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 1000 2000 3000 4000 5000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)


7ºCpm Dynamic Test

36

-0.05

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.50

0 1000 2000 3000 4000 5000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)



37

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 1000 2000 3000 4000 5000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)


8ºCpm Dynamic Test

38

-0.10

0.00

0.10

0.20

0.30

0.40

0.50

0 500 1000 1500 2000 2500 3000 3500 4000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)



39

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 500 1000 1500 2000 2500 3000 3500 4000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)


9ºCpm Dynamic Test

40

-0.10

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0 500 1000 1500 2000 2500 3000 3500

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)



41

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 500 1000 1500 2000 2500 3000 3500

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)


10ºCpm Dynamic Test

42

0.00

0.00

0.00

0.00

0.00

0.00

0.00

0.00

0.00

0 10000 20000 30000 40000 50000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-06

4.00E-06

6.00E-06

8.00E-06

1.00E-05

1.20E-05

Cur

e ra

te (1

/s)

Heat Flow Response – 65ºC

65ºC Isothermal TestHRHold = 46.118 J/g

43

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 10000 20000 30000 40000 50000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-06

4.00E-06

6.00E-06

8.00E-06

1.00E-05

1.20E-05

Cur

e ra

te (1

/s)

DoC and Cure Rate – 65ºC

65ºC Isothermal TestDoCHold = 0.264

44

0.00

0.00

0.00

0.00

0.00

0.01

0.01

0.01

0.01

0.01

0.01

0 10000 20000 30000 40000 50000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-06

4.00E-06

6.00E-06

8.00E-06

1.00E-05

1.20E-05

1.40E-05

1.60E-05

Cur

e ra

te (1

/s)



45

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 10000 20000 30000 40000 50000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-06

4.00E-06

6.00E-06

8.00E-06

1.00E-05

1.20E-05

1.40E-05

1.60E-05

Cur

e ra

te (1

/s)



46

0.00

0.00

0.00

0.00

0.00

0.01

0.01

0.01

0.01

0.01

0.01

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-06

1.00E-05

1.50E-05

2.00E-05

2.50E-05

3.00E-05

3.50E-05

Cur

e ra

te (1

/s)



47

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-06

1.00E-05

1.50E-05

2.00E-05

2.50E-05

3.00E-05

3.50E-05

Cur

e ra

te (1

/s)



48

0.00

0.00

0.00

0.01

0.01

0.01

0.01

0.01

0.02

0.02

0.02

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

1.00E-05

2.00E-05

3.00E-05

4.00E-05

5.00E-05

6.00E-05

Cur

e ra

te (1

/s)



49

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-05

2.00E-05

3.00E-05

4.00E-05

5.00E-05

6.00E-05

Cur

e ra

te (1

/s)



50

0.00

0.00

0.00

0.01

0.01

0.01

0.01

0.01

0.02

0.02

0.02

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

1.00E-05

2.00E-05

3.00E-05

4.00E-05

5.00E-05

6.00E-05

7.00E-05

8.00E-05

9.00E-05

Cur

e ra

te (1

/s)



51

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-05

2.00E-05

3.00E-05

4.00E-05

5.00E-05

6.00E-05

7.00E-05

8.00E-05

9.00E-05

Cur

e ra

te (1

/s)



52

0.00

0.01

0.01

0.02

0.02

0.03

0.03

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-05

4.00E-05

6.00E-05

8.00E-05

1.00E-04

1.20E-04

1.40E-04

Cur

e ra

te (1

/s)



53

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-05

4.00E-05

6.00E-05

8.00E-05

1.00E-04

1.20E-04

1.40E-04

Cur

e ra

te (1

/s)



54

0.00

0.01

0.01

0.02

0.02

0.03

0.03

0.04

0.04

0 5000 10000 15000 20000 25000 30000 35000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

Cur

e ra

te (1

/s)



55

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

Cur

e ra

te (1

/s)



56

0.00

0.01

0.01

0.02

0.02

0.03

0.03

0.04

0.04

0.05

0.05

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

Cur

e ra

te (1

/s)



57

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

Cur

e ra

te (1

/s)



58

-0.01

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0.08

0 5000 10000 15000 20000 25000 30000 35000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

4.00E-04

4.50E-04

Cur

e ra

te (1

/s)



59

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

4.00E-04

4.50E-04

Cur

e ra

te (1

/s)



60

-0.01

0.01

0.03

0.05

0.07

0.09

0.11

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

Cur

e ra

te (1

/s)



61

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

Cur

e ra

te (1

/s)



62

-0.01

0.04

0.09

0.14

0.19

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

8.00E-04

9.00E-04

Cur

e ra

te (1

/s)



63

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

8.00E-04

9.00E-04

Cur

e ra

te (1

/s)



64

-0.02

0.03

0.08

0.13

0.18

0.23

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

Cur

e ra

te (1

/s)



65

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

Cur

e ra

te (1

/s)



66

-0.02

0.03

0.08

0.13

0.18

0.23

0.28

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)



67

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)



68

-0.02

0.03

0.08

0.13

0.18

0.23

0.28

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

2.00E-03

Cur

e ra

te (1

/s)



69

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

2.00E-03

Cur

e ra

te (1

/s)



70

-0.02

0.03

0.08

0.13

0.18

0.23

0.28

0.33

0.38

0.43

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)



71

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)



72

-0.05

0.05

0.15

0.25

0.35

0.45

0 5000 10000 15000 20000 25000 30000

Time (s)

Spec

ific

heat

flow

(W/g

)

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)



73

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)



74

Heat of Reaction ValuesResidual LeftOver Total

5215-MDYN-05cpm-01 173.98 0.0 174.05215-MDYN-1cpm-01 171.434 0.0 171.45215-MDYN-2cpm-01 165.405 4.0 169.45215-MDYN-3cpm-01 172.441 0.0 172.45215-MDYN-4cpm-01 146.529 20.0 166.55215-MDYN-4cpm-03 170.63 0.0 170.65215-MDYN-5cpm-01 173.912 0.0 173.95215-MDYN-6cpm-01 163.444 3.7 167.15215-MDYN-6cpm-02 170.476 0.0 170.55215-MDYN-7cpm-01 170.886 0.0 170.95215-MDYN-8cpm-01 168.902 0.0 168.95215-MDYN-9cpm-01 163.058 9.3 172.45215-MDYN-10cpm-01 169.462 5.0 174.5

Tests Heat of Reaction (J/g)Pre-Test Hold Ramp Total

5215-MISO-65C-01 0.0 42.3 128.6 170.85215-MISO-70C-01 0.0 50.2 112.0 162.25215-MISO-75C-01 0.0 70.3 89.7 160.05215-MISO-80C-01 0.0 87.6 82.2 169.85215-MISO-85C-01 0.0 88.5 74.9 163.35215-MISO-90C-01 0.0 98.8 68.7 167.55215-MISO-95C-01 0.0 97.2 63.7 160.95215-MISO-100C-01 0.0 107.4 54.2 161.65215-MISO-105C-01 0.0 112.9 54.1 167.05215-MISO-110C-01 0.0 123.8 46.9 170.75215-MISO-115C-01 0.0 123.3 45.0 168.35215-MISO-120C-01 0.0 138.5 44.5 183.05215-MISO-125C-01 0.0 124.2 36.8 161.15215-MISO-130C-01 0.0 118.3 28.7 146.95215-MISO-135C-01 0.0 123.8 28.3 152.15215-MISO-140C-01 2.4 137.2 28.6 168.1

Tests Heat of Reaction (J/g)

75

0

20

40

60

80

100

120

140

160

180

200

5215

-MIS

O-140C

-01

5215

-MIS

O-130C

-01

5215

-MIS

O-120C

-01

5215

-MIS

O-110C

-01

5215

-MIS

O-100C

-01

5215

-MIS

O-90C-01

5215

-MIS

O-80C-01

5215

-MIS

O-70C-01

5215

-MDYN-9c

pm-01

5215

-MDYN-7c

pm-01

5215

-MDYN-6c

pm-01

5215

-MDYN-4c

pm-03

5215

-MDYN-3c

pm-01

5215

-MDYN-1c

pm-01

Hea

t of R

eact

ion

(J/g

)

Dynamic (ramp) HRIsothermal (hold) HR

Total Heat of Reaction

J/g 96.170=avgDynHR

J/g 170=ModelHR

J/g 59.164=avgIsoHR

76

Tg TablesDoC Tg (ºC) DoC Tg (ºC)

5215-MISO-65C-01 0.000 9.7 0.25 47.085215-MISO-70C-01 0.000 10.3 0.31 66.765215-MISO-75C-01 0.000 9.7 0.44 86.325215-MISO-80C-01 0.000 10.6 0.52 98.865215-MISO-85C-01 0.000 10.7 0.54 104.075215-MISO-90C-01 0.000 9.8 0.59 112.785215-MISO-95C-01 0.000 9.5 0.60 116.875215-MISO-100C-01 0.000 10.1 0.66 123.595215-MISO-105C-01 0.000 9.8 0.68 128.645215-MISO-110C-01 0.000 12.6 0.73 133.635215-MISO-115C-01 0.000 10.5 0.73 1415215-MISO-120C-01 0.000 9.5 0.76 146.525215-MISO-125C-01 0.000 9.6 0.77 150.745215-MISO-130C-01 0.000 10.1 0.81 152.095215-MISO-135C-01 0.000 10.3 0.81 160.145215-MISO-140C-01 0.014 9.8 0.83 163.27

Tests Initial Post-Hold

DoC Tg (ºC) DoC Tg (ºC)5215-INT-110C-10min-01 0 10.3 0.18 37.05215-INT-110C-20min-01 0 10.1 0.47 72.45215-INT-110C-30min-01 0 10.2 0.58 100.25215-INT-110C-40min-01 0 10.8 0.65 113.3

Tests Initial Post-Hold

DoC Tg (ºC) DoC Tg (ºC)5215-MDYN-05cpm-01 0.000 9.93 1.00 156.575215-MDYN-1cpm-01 0.000 10.17 1.00 156.325215-MDYN-2cpm-01 0.000 9.61 0.98 163.75215-MDYN-3cpm-01 0.000 9.06 1.00 150.885215-MDYN-4cpm-01 0.000 9.11 0.88 160.25215-MDYN-4cpm-03 0.000 10.81 1.00 137.945215-MDYN-5cpm-01 0.000 9.41 1.00 143.775215-MDYN-6cpm-01 0.000 10.96 0.98 155.315215-MDYN-6cpm-02 0.000 9.18 1.00 150.515215-MDYN-7cpm-01 0.000 9.44 1.00 121.265215-MDYN-8cpm-01 0.000 10.71 1.00 129.095215-MDYN-9cpm-01 0.000 9.35 0.95 149.455215-MDYN-10cpm-01 0.000 8.77 0.97 141.55

Tests Initial Final

77

0

50

100

150

200

250

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Degree of Cure

Gla

ss T

rans

ition

Tem

pera

ture

(C)

Isothermal-post holdIsothermal-finalIsothermal-initialDynamic-finalDynamic-initialModelInterrupted PostHold

Glass Transition Temperature

CTg °=100

CTg °=∞

220

6.0=λ

Drop in Tg due to material degradation

78

Cure Kinetics Model

( ) 477.0245.244.456,105

31 )(104.2 Tbxex RT

c +××=−

&

( ) ( )3.04000,40

22 1100.6 xxex RT

i −××=−

&

ecic

k xxxx

x &&&&

& +⎟⎟⎠

⎞⎜⎜⎝

⎛+

+=−1

221

11

Chemical Reaction:

where

( )45.1000,37

42 05.1

1100.3 xxex RTc ⎟

⎠⎞

⎜⎝⎛ −××=

−

&

( )xex RTe −××=

−

1100.7000,72

4&

030.2)( where)( 18/3000

−<= −

ETbeTb T

79

Cure Kinetics Model

Diffusion Component:

( )xFeKx dfB

dd

−

= 0&

1000,2030.0

1××=

−f

d ex&

( ) bTTaf g +−=

⎪⎩

⎪⎨

⎧

°>°<<°

°<

×××

×=

−

−−

−

CTCTC

CTa

g

g

g

130130100

100

108.4108.4 and 100.1 bwLinear

100.1

4

43

3

2105.2 −×=b1

21

111−

⎟⎟⎠

⎞⎜⎜⎝

⎛++=

ddk xxxx

&&&&

Diffusion 1:

Diffusion 2: 10.550.0

2××=

−f

d ex&

⎪⎩

⎪⎨

⎧

°>°<<°

°<=

CTCTC

CTb

g

g

g

160160110

110

050.00.050 and 0.048 bwLinear

048.0

⎪⎩

⎪⎨

⎧

°>°<<°

°<

×××

×=

−

−−

−

CTCTC

CTa

g

g

g

12012085

85

108.4108.4 and 100.8 bwLinear

100.8

4

44

4

80

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)

Test Data-IsosTest Data-DynsTgModel - KineticsModel - Total x = 0.02

81

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)

Test Data-IsosTest Data-DynsModel - KineticsTgModel - Total

x = 0.04

82

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)


x = 0.06

83

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)


x = 0.08

84

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)


x = 0.1

85

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)

Test Data-IsosTest Data-DynsModel - KineticsModel - Total

x = 0.2

86

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)

Test Data-IsosTest Data-DynsModel - KineticsModel - Total

x = 0.3

87

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.002 0.0022 0.0024 0.0026 0.0028 0.003 0.0032

1/T (1/s)

Ln(x

dot)

Test Data-Isos

Test Data-Dyns

Model - Kinetics

Tg

Model - Total

x = 0.4

88

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.002 0.0022 0.0024 0.0026 0.0028 0.003

1/T (1/s)

Ln(x

dot)


x = 0.5

89

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0018 0.002 0.0022 0.0024 0.0026 0.0028

1/T (1/s)

Ln(x

dot)


x = 0.6

90

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0018 0.002 0.0022 0.0024 0.0026 0.0028

1/T (1/s)

Ln(x

dot)


x = 0.7

91

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0018 0.002 0.0022 0.0024 0.0026 0.0028

1/T (1/s)

Ln(x

dot)

Test Data-IsosTest Data-DynsTgModel - KineticsModel - Total

x = 0.8

92

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0018 0.002 0.0022 0.0024 0.0026 0.0028

1/T (1/s)

Ln(x

dot)


x = 0.9

93

Ln(xdot)-1/T

-14

-12

-10

-8

-6

-40.0018 0.00185 0.0019 0.00195 0.002 0.00205 0.0021 0.00215 0.0022

1/T (1/s)

Ln(x

dot)


x = 0.98

94

Model Parameters - Kinetics

1.0

0.00.30.50.14.0

40,000600

i2

4.0

0.01.02.01.051.5

37,00030,000

c2

0.477

0.02.24517.2080.2940.0

105,4562,400

c1

0.00.00.0

0.0

1.01.0

72,000(J/mol)70,000(1/s)

eParameter

0.6220 (ºC)10 (ºC)

Value (unit)Parameter

aE

l

r

m

2n

b

n

0gT

∞gT

λ

0k

Model’s range of validity65ºC < Iso Temperature < 200ºC0ºC < Dyn Temperature < 300ºC

0.002C1bc

-18C1b2

3000c1b1

Value (unit)Parameter

95

Model Parameters - Diffusion

145 (ºC)85 (ºC)0.0250.025

130 (ºC)100 (ºC)

4.8E-04 (1/ºC)1.0E-03 (1/ºC)

0.320,000 (1/s)

Diffusion 1

160 (ºC)110 (ºC)

0.048120 (ºC)85 (ºC)

0.050

4.8E-04 (1/ºC)8.0E-04 (1/ºC)

0.55 (1/s)

Diffusion 2Parameter

0dk

B

1a

2a

1agT

2agT

1b2b

1bgT

2bgT

Model’s range of validity65ºC < Iso Temperature < 200ºC0ºC < Dyn Temperature < 300ºC

96

Dynamic Tests – 0.5cpm

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 -50 0 50 100 150 200 250 300 350

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

Cur

e ra

te (1

/s)

Degree of cureDegree of cure - ModelCure Rate (1/s)Cure Rate (1/s) - Model

97

Dynamic Tests – 1cpm

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

Cur

e ra

te (1

/s)


98


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 -50 0 50 100 150 200 250 300

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

Cur

e ra

te (1

/s)


99


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

Cur

e ra

te (1

/s)


100

Dynamic Tests – 4cpm-01

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 -50 0 50 100 150 200 250 300

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)


101


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)


102


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)


103


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 -50 0 50 100 150 200 250 300

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)


104


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)


105


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)


106


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)


107


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 -50 0 50 100 150 200 250 300 350

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)


108


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 -50 0 50 100 150 200 250 300 350

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

4.00E-03

Cur

e ra

te (1

/s)


109

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 10000 20000 30000 40000 50000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-06

4.00E-06

6.00E-06

8.00E-06

1.00E-05

1.20E-05

Cur

e ra

te (1

/s)


Isothermal Tests - 65ºC-01


110

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-06

4.00E-06

6.00E-06

8.00E-06

1.00E-05

1.20E-05

1.40E-05

1.60E-05

1.80E-05

2.00E-05

Cur

e ra

te (1

/s)




111

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-06

1.00E-05

1.50E-05

2.00E-05

2.50E-05

3.00E-05

3.50E-05

Cur

e ra

te (1

/s)




112

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-05

2.00E-05

3.00E-05

4.00E-05

5.00E-05

6.00E-05

Cur

e ra

te (1

/s)




113

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000 40000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-05

2.00E-05

3.00E-05

4.00E-05

5.00E-05

6.00E-05

7.00E-05

8.00E-05

9.00E-05

Cur

e ra

te (1

/s)




114

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-05

4.00E-05

6.00E-05

8.00E-05

1.00E-04

1.20E-04

1.40E-04

Cur

e ra

te (1

/s)


Isothermal Tests - 90ºC


115

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000 35000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

Cur

e ra

te (1

/s)




116

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 5000 10000 15000 20000 25000 30000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

Cur

e ra

te (1

/s)




117

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 6500 11500 16500 21500 26500 31500 36500

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

4.00E-04

4.50E-04

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 3500 5500 7500 9500

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

4.00E-04

4.50E-04

Cur

e ra

te (1

/s)


118

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 7000 12000 17000 22000 27000 32000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 3000 4000 5000 6000 7000 8000 9000 10000

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

Cur

e ra

te (1

/s)


119

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 6500 11500 16500 21500 26500 31500

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

8.00E-04

9.00E-04

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 2500 3500 4500 5500

Time (s)

Deg

ree

of c

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

8.00E-04

9.00E-04

Cur

e ra

te (1

/s)


120

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 7000 12000 17000 22000 27000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 2500 3000 3500 4000 4500 5000 5500 6000

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

Cur

e ra

te (1

/s)


121

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 6500 11500 16500 21500 26500 31500

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 2000 2500 3000 3500 4000 4500

Time (s)

Deg

ree

of c

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

Cur

e ra

te (1

/s)


122

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 7000 12000 17000 22000 27000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 2500 3000 3500 4000 4500 5000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

Cur

e ra

te (1

/s)


123

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 6500 11500 16500 21500 26500 31500

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

1500 2000 2500 3000 3500 4000 4500

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

Cur

e ra

te (1

/s)


124

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 7000 12000 17000 22000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)




0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

2000 2500 3000 3500 4000 4500 5000

Time (s)

Deg

ree

of c

ure

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

Cur

e ra

te (1

/s)


125

Isothermal Tests - 65ºC-R-01

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

8.00E-04

9.00E-04

1.00E-03

Cur

e ra

te (1

/s)


126


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

8.00E-04

9.00E-04

Cur

e ra

te (1

/s)


127


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

4.00E-04

4.50E-04

5.00E-04

Cur

e ra

te (1

/s)


128


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

4.00E-04

4.50E-04

Cur

e ra

te (1

/s)


129


0.00

0.10

0.20

0.30

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0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

Cur

e ra

te (1

/s)


130

Isothermal Tests - 90ºC-R

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

Cur

e ra

te (1

/s)


131


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

3.50E-04

Cur

e ra

te (1

/s)


132


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

Cur

e ra

te (1

/s)


133


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

3.00E-04

Cur

e ra

te (1

/s)


134


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 -50 0 50 100 150 200 250 300 350

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

Cur

e ra

te (1

/s)


135


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

Cur

e ra

te (1

/s)


136


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

Cur

e ra

te (1

/s)


137


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

5.00E-05

1.00E-04

1.50E-04

2.00E-04

2.50E-04

Cur

e ra

te (1

/s)


138


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-05

4.00E-05

6.00E-05

8.00E-05

1.00E-04

1.20E-04

1.40E-04

1.60E-04

1.80E-04

Cur

e ra

te (1

/s)


139


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-05

4.00E-05

6.00E-05

8.00E-05

1.00E-04

1.20E-04

1.40E-04

1.60E-04

1.80E-04

Cur

e ra

te (1

/s)


140


0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

-100 0 100 200 300 400

Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-05

4.00E-05

6.00E-05

8.00E-05

1.00E-04

1.20E-04

1.40E-04

1.60E-04

Cur

e ra

te (1

/s)


141

Dynamic Tests – All

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

50 100 150 200 250 300 350 400 450

Temperature (°C)

Deg

ree

of C

ure

DOC (5215-MDYN-10cpm-01, expt) DOC (5215-MDYN-10cpm-01, model)DOC (5215-MDYN-9cpm-01, expt) DOC (5215-MDYN-9cpm-01, model)DOC (5215-MDYN-8cpm-01, expt) DOC (5215-MDYN-8cpm-01, model)DOC (5215-MDYN-7cpm-01, expt) DOC (5215-MDYN-7cpm-01, model)DOC (5215-MDYN-6cpm-02, expt) DOC (5215-MDYN-6cpm-02, model)DOC (5215-MDYN-6cpm-01, expt) DOC (5215-MDYN-6cpm-01, model)DOC (5215-MDYN-5cpm-01, expt) DOC (5215-MDYN-5cpm-01, model)DOC (5215-MDYN-4cpm-03, expt) DOC (5215-MDYN-4cpm-03, model)DOC (5215-MDYN-4cpm-01, expt) DOC (5215-MDYN-4cpm-01, model)DOC (5215-MDYN-3cpm-01, expt) DOC (5215-MDYN-3cpm-01, model)DOC (5215-MDYN-2cpm-01, expt) DOC (5215-MDYN-2cpm-01, model)DOC (5215-MDYN-1cpm-01, expt) DOC (5215-MDYN-1cpm-01, model)DOC (5215-MDYN-05cpm-01, expt) DOC (5215-MDYN-05cpm-01, model)

142

Dynamic Tests – All

0.0E+00

5.0E-04

1.0E-03

1.5E-03

2.0E-03

2.5E-03

3.0E-03

3.5E-03

4.0E-03

50 100 150 200 250 300 350 400 450

Temperature (°C)

Cur

e ra

te (1

/s)Cure rate (5215-MDYN-10cpm-01, expt) Cure rate (5215-MDYN-10cpm-01, model)Cure rate (5215-MDYN-9cpm-01, expt) Cure rate (5215-MDYN-9cpm-01, model)Cure rate (5215-MDYN-8cpm-01, expt) Cure rate (5215-MDYN-8cpm-01, model)Cure rate (5215-MDYN-7cpm-01, expt) Cure rate (5215-MDYN-7cpm-01, model)Cure rate (5215-MDYN-6cpm-02, expt) Cure rate (5215-MDYN-6cpm-02, model)Cure rate (5215-MDYN-6cpm-01, expt) Cure rate (5215-MDYN-6cpm-01, model)Cure rate (5215-MDYN-5cpm-01, expt) Cure rate (5215-MDYN-5cpm-01, model)Cure rate (5215-MDYN-4cpm-03, expt) Cure rate (5215-MDYN-4cpm-03, model)Cure rate (5215-MDYN-4cpm-01, expt) Cure rate (5215-MDYN-4cpm-01, model)Cure rate (5215-MDYN-3cpm-01, expt) Cure rate (5215-MDYN-3cpm-01, model)Cure rate (5215-MDYN-2cpm-01, expt) Cure rate (5215-MDYN-2cpm-01, model)Cure rate (5215-MDYN-1cpm-01, expt) Cure rate (5215-MDYN-1cpm-01, model)Cure rate (5215-MDYN-05cpm-01, expt) Cure rate (5215-MDYN-05cpm-01, model)

143

Isothermal Tests

0.00

0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

0.90

1.00

0 10000 20000 30000 40000

Time (s)

Deg

ree

of C

ure

DOC 5215-MISO-140C-01 (expt)DOC 5215-MISO-140C-01 (model)DOC 5215-MISO-135C-01 (expt)DOC 5215-MISO-135C-01 (model)DOC 5215-MISO-130C-01 (expt)DOC 5215-MISO-130C-01 (model)DOC 5215-MISO-125C-01 (expt)DOC 5215-MISO-125C-01 (model)DOC 5215-MISO-120C-01 (expt)DOC 5215-MISO-120C-01 (model)DOC 5215-MISO-115C-01 (expt)DOC 5215-MISO-115C-01 (model)DOC 5215-MISO-110C-01 (expt)DOC 5215-MISO-110C-01 (model)DOC 5215-MISO-105C-01 (expt)DOC 5215-MISO-105C-01 (model)DOC 5215-MISO-100C-01 (expt)DOC 5215-MISO-100C-01 (model)DOC 5215-MISO-95C-01 (expt)DOC 5215-MISO-95C-01 (model)DOC 5215-MISO-90C-01 (expt)DOC 5215-MISO-90C-01 (model)DOC 5215-MISO-85C-01 (expt)DOC 5215-MISO-85C-01 (model)DOC 5215-MISO-80C-01 (expt)DOC 5215-MISO-80C-01 (model)DOC 5215-MISO-75C-01 (expt)DOC 5215-MISO-75C-01 (model)DOC 5215-MISO-70C-01 (expt)DOC 5215-MISO-70C-01 (model)DOC 5215-MISO-65C-01 (expt)

144

Isothermal Tests

0.0E+00

5.0E-04

1.0E-03

1.5E-03

2.0E-03

2.5E-03

3.0E-03

3.5E-03

2000 2500 3000 3500 4000 4500 5000 5500 6000

Time (s)

Cur

e ra

te (1

/s)

Cure rate (5215-MISO-140C-01, expt) Cure rate (5215-MISO-140C-01, model)Cure rate (5215-MISO-135C-01, expt) Cure rate (5215-MISO-135C-01, model)Cure rate (5215-MISO-130C-01, expt) Cure rate (5215-MISO-130C-01, model)Cure rate (5215-MISO-125C-01, expt) Cure rate (5215-MISO-125C-01, model)Cure rate (5215-MISO-120C-01, expt) Cure rate (5215-MISO-120C-01, model)Cure rate (5215-MISO-115C-01, expt) Cure rate (5215-MISO-115C-01, model)Cure rate (5215-MISO-110C-01, expt) Cure rate (5215-MISO-110C-01, model)Cure rate (5215-MISO-105C-01, expt) Cure rate (5215-MISO-105C-01, model)Cure rate (5215-MISO-100C-01, expt) Cure rate (5215-MISO-100C-01, model)Cure rate (5215-MISO-95C-01, expt) Cure rate (5215-MISO-95C-01, model)Cure rate (5215-MISO-90C-01, expt) Cure rate (5215-MISO-90C-01, model)Cure rate (5215-MISO-85C-01, expt) Cure rate (5215-MISO-85C-01, model)Cure rate (5215-MISO-80C-01, expt) Cure rate (5215-MISO-80C-01, model)Cure rate (5215-MISO-75C-01, expt) Cure rate (5215-MISO-75C-01, model)Cure rate (5215-MISO-70C-01, expt) Cure rate (5215-MISO-70C-01, model)Cure rate (5215-MISO-65C-01, expt) Cure rate (5215-MISO-65C-01, model)

145

Cure Rate vs. DoC – Dyns

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

4.00E-03

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

5215-MDYN-10cpm-01-HeatUp






















146

Cure Rate vs. DoC – Isos

0.00E+00

5.00E-04

1.00E-03

1.50E-03

2.00E-03

2.50E-03

3.00E-03

3.50E-03

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

5215-MISO-140C-01-Hold 5215-MISO-135C-01-Hold 5215-MISO-130C-01-Hold 5215-MISO-125C-01-Hold 5215-MISO-120C-01-Hold 5215-MISO-115C-01-Hold 5215-MISO-110C-01-Hold 5215-MISO-105C-01-Hold 5215-MISO-100C-01-Hold 5215-MISO-95C-01-Hold 5215-MISO-90C-01-Hold 5215-MISO-85C-01-Hold 5215-MISO-80C-01-Hold 5215-MISO-75C-01-Hold 5215-MISO-70C-01-Hold 5215-MISO-65C-01-Hold 5215-MISO-140C-01-Hold 5215-MISO-135C-01-Hold 5215-MISO-130C-01-Hold 5215-MISO-125C-01-Hold 5215-MISO-120C-01-Hold 5215-MISO-115C-01-Hold 5215-MISO-110C-01-Hold 5215-MISO-105C-01-Hold 5215-MISO-100C-01-Hold 5215-MISO-95C-01-Hold 5215-MISO-90C-01-Hold 5215-MISO-85C-01-Hold 5215-MISO-80C-01-Hold 5215-MISO-75C-01-Hold 5215-MISO-70C-01-Hold 5215-MISO-65C-01-Hold

147

0

20

40

60

80

100

120

140

160

180

200

220

240

5215

-MIS

O-65C-01

5215

-MIS

O-70C-01

5215

-MIS

O-75C-01

5215

-MIS

O-80C-01

5215

-MIS

O-85C-01

5215

-MIS

O-90C-01

5215

-MIS

O-95C-01

5215

-MIS

O-100C

-01

5215

-MIS

O-105C

-01

5215

-MIS

O-110C

-01

5215

-MIS

O-115C

-01

5215

-MIS

O-120C

-01

5215

-MIS

O-125C

-01

5215

-MIS

O-130C

-01

5215

-MIS

O-135C

-01

5215

-MIS

O-140C

-01

5215

-MIS

O-145C

-01

5215

-MIS

O-150C

-01

5215

-MIS

O-155C

-01

5215

-MIS

O-160C

-01

5215

-MIS

O-165C

-01

5215

-MIS

O-170C

-01

5215

-MIS

O-175C

-01

5215

-MIS

O-180C

-01

5215

-MIS

O-185C

-01

5215

-MIS

O-190C

-01

5215

-MIS

O-195C

-01

5215

-MIS

O-200C

-01

Test

Tg (C

)

TestModel

Final Tg Predictions - Iso Tests

Test Model ÷Tg %5215-MISO-65C-01 47.1 54.3 -7.2 3.4%5215-MISO-70C-01 66.8 80.1 -13.3 6.3%5215-MISO-75C-01 86.3 88.0 -1.7 0.8%5215-MISO-80C-01 98.9 93.2 5.7 2.7%5215-MISO-85C-01 104.1 98.4 5.7 2.7%5215-MISO-90C-01 112.8 104.1 8.7 4.1%5215-MISO-95C-01 116.9 111.4 5.5 2.6%

5215-MISO-100C-01 123.6 119.4 4.2 2.0%5215-MISO-105C-01 128.6 131.8 -3.2 1.5%5215-MISO-110C-01 133.6 137.1 -3.5 1.7%5215-MISO-115C-01 141.0 142.2 -1.2 0.6%5215-MISO-120C-01 146.5 147.1 -0.6 0.3%5215-MISO-125C-01 150.7 152.3 -1.6 0.7%5215-MISO-130C-01 152.1 157.2 -5.1 2.4%5215-MISO-135C-01 160.1 162.4 -2.3 1.1%5215-MISO-140C-01 163.3 167.3 -4.0 1.9%5215-MISO-145C-01 166.7 172.3 -5.6 2.6%5215-MISO-150C-01 170.2 176.8 -6.6 3.1%5215-MISO-155C-01 177.7 182.1 -4.4 2.1%5215-MISO-160C-01 179.6 186.8 -7.2 3.4%5215-MISO-165C-01 188.6 191.8 -3.2 1.5%5215-MISO-170C-01 188.0 196.4 -8.4 4.0%5215-MISO-175C-01 193.0 201.8 -8.8 4.2%5215-MISO-180C-01 199.4 205.3 -5.9 2.8%5215-MISO-185C-01 194.8 211.7 -16.9 8.1%5215-MISO-190C-01 195.4 214.6 -19.2 9.2%5215-MISO-195C-01 200.6 218.4 -17.8 8.5%5215-MISO-200C-01 200.1 219.7 -19.7 9.4%

Tests Post-Hold Tg (ºC) Error

148

Final Tg Predictions - Interrupted Tests

0

20

40

60

80

100

120

140

5215-INT-110C-10min-01

5215-INT-110C-20min-01

5215-INT-110C-30min-01

5215-INT-110C-40min-01

Test

Tg (C

)

TestModel

Test Model ⎠ Tg %5215-INT-110C-10min-01 37.0 32.0 5.0 2.4%5215-INT-110C-20min-01 72.4 81.4 -9.0 4.3%5215-INT-110C-30min-01 100.2 107.6 -7.4 3.5%5215-INT-110C-40min-01 113.3 117.3 -4.1 1.9%

Tests Post-Hold Tg (ºC) Error

149

Final Tg Predictions – Cure Cycle Tests

0

20

40

60

80

100

120

140

160

180

200

220

5215-CC-S10-01 5215-CC-S15-01 5215-CC-S20-01 5215-CC-S30-01 5215-CC-S35-01 5215-CC-S40-01

Test

Tg (C

)

TestModel

Test Model ÷Tg %5215-CC-S10-01 12.5 11.2 1.3 0.6%5215-CC-S15-01 19.6 21.4 1.8 0.9%5215-CC-S20-01 42.1 46.6 4.5 2.2%5215-CC-S30-01 185.3 191.5 6.2 2.9%5215-CC-S35-01 188.6 200.0 11.4 5.4%5215-CC-S40-01 189.8 203.5 13.7 6.5%

Tests Tg (ºC) Error

150

Goodness of Fit – Key Points

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0 5000 10000 15000 20000 25000 30000 35000Time (s)

Deg

ree

of C

ure

0.00E+00

2.00E-05

4.00E-05

6.00E-05

8.00E-05

1.00E-04

1.20E-04

1.40E-04

1.60E-04

1.80E-04

Cur

e R

ate

(1/s

)Degree of Cure - ExptDegree of Cure - ModelCure Rate (1/s) - ExptCure Rate (1/s) - ModelStart/End ThresholdKickoff/Slow Threshold

Peak Cure Rate

151

Goodness of Fit – Peak

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

2000 3000 4000 5000 6000 7000 8000 9000 10000Time (s)

Deg

ree

of C

ure

1.20E-04

1.30E-04

1.40E-04

1.50E-04

1.60E-04

1.70E-04

1.80E-04

Cur

e R

ate

(1/s

)

Degree of Cure - ExptDegree of Cure - ModelCure Rate (1/s) - ExptCure Rate (1/s) - Model

Model Peak

Expt Peak

152

Goodness of Fit – Other

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0 5000 10000 15000 20000 25000 30000 35000Time (s)

Deg

ree

of C

ure

0.00E+00

5.00E-06

1.00E-05

1.50E-05

2.00E-05

2.50E-05

3.00E-05

3.50E-05

4.00E-05

Cur

e R

ate

(1/s

)

Degree of Cure - ExptDegree of Cure - ModelCure Rate (1/s) - ExptCure Rate (1/s) - ModelStart/End ThresholdKickoff/Slow Threshold

Expt Slow

Model Slow

Model End

Expt End

Model/Expt Start

Model/Expt Kickoff

153

Goodness of Fit – Iso Timing

Values are: Exp - Model

-900

-600

-300

0

300

600

900

5215

-MIS

O-6

5C-0

1

5215

-MIS

O-7

0C-0

1

5215

-MIS

O-7

5C-0

1

5215

-MIS

O-8

0C-0

1

5215

-MIS

O-8

5C-0

1

5215

-MIS

O-9

0C-0

1

5215

-MIS

O-9

5C-0

1

5215

-MIS

O-1

00C

-01

5215

-MIS

O-1

05C

-01

5215

-MIS

O-1

10C

-01

5215

-MIS

O-1

15C

-01

5215

-MIS

O-1

20C

-01

5215

-MIS

O-1

25C

-01

5215

-MIS

O-1

30C

-01

5215

-MIS

O-1

35C

-01

5215

-MIS

O-1

40C

-01

Tim

e Er

ror (

sec)

Timing - StartTiming - KickoffTiming - PeakTiming - SlowTiming - End

154

Goodness of Fit – Iso DOC


-0.4

-0.35

-0.3

-0.25

-0.2

-0.15

-0.1

-0.05

0

0.05

0.1

5215

-MIS

O-6

5C-0

1

5215

-MIS

O-7

0C-0

1

5215

-MIS

O-7

5C-0

1

5215

-MIS

O-8

0C-0

1

5215

-MIS

O-8

5C-0

1

5215

-MIS

O-9

0C-0

1

5215

-MIS

O-9

5C-0

1

5215

-MIS

O-1

00C

-01

5215

-MIS

O-1

05C

-01

5215

-MIS

O-1

10C

-01

5215

-MIS

O-1

15C

-01

5215

-MIS

O-1

20C

-01

5215

-MIS

O-1

25C

-01

5215

-MIS

O-1

30C

-01

5215

-MIS

O-1

35C

-01

5215

-MIS

O-1

40C

-01

DO

C E

rror

DOC - StartDOC - KickoffDOC - PeakDOC - SlowDOC - End

155

Goodness of Fit – Dyn Timing


-120

-60

0

60

120

180

240

300

5215

-MD

YN

-05c

pm-

01

5215

-MD

YN

-10c

pm-

01

5215

-MD

YN-1

cpm

-01

5215

-MD

YN-2

cpm

-01

5215

-MD

YN-3

cpm

-01

5215

-MD

YN-4

cpm

-01

5215

-MD

YN-4

cpm

-03

5215

-MD

YN-5

cpm

-01

5215

-MD

YN-6

cpm

-01

5215

-MD

YN-6

cpm

-02

5215

-MD

YN-7

cpm

-01

5215

-MD

YN-8

cpm

-01

5215

-MD

YN-9

cpm

-01

Tim

e Er

ror (

sec)

Timing - Peak

156

Goodness of Fit – Dyn DOC


-0.1

-0.08

-0.06

-0.04

-0.02

0

0.02

0.04

0.06

5215

-MD

YN

-05c

pm-

01

5215

-MD

YN

-10c

pm-

01

5215

-MD

YN

-1cp

m-0

1

5215

-MD

YN

-2cp

m-0

1

5215

-MD

YN

-3cp

m-0

1

5215

-MD

YN

-4cp

m-0

1

5215

-MD

YN

-4cp

m-0

3

5215

-MD

YN

-5cp

m-0

1

5215

-MD

YN

-6cp

m-0

1

5215

-MD

YN

-6cp

m-0

2

5215

-MD

YN

-7cp

m-0

1

5215

-MD

YN

-8cp

m-0

1

5215

-MD

YN

-9cp

m-0

1

DO

C E

rror

DOC - Peak

157

Green: 1’-9’ @ 1’Red: 10’-50’ @ 10’Cyan: 60’-330’ @ 30’Magenta: 360’-1080’ @ 60’Yellow: Glass Transition Temp.

Cycom 5215 – Isothermal

158


Cycom 5215 – 1cpm

159


Cycom 5215 – 2cpm

160


Cycom 5215 – 3cpm

161


Cycom 5215 – 4cpm

162


Cycom 5215 – 5cpm

163


Cycom 5215 – Initial DOC = 0.001

164

Comparison of Forms – 1cpm

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

-100 -50 0 50 100 150 200 250 300Temperature (°C)

Deg

ree

of C

ure

0.00E+00

1.00E-04

2.00E-04

3.00E-04

4.00E-04

5.00E-04

6.00E-04

7.00E-04

Cur

e ra

te (1

/s)Degree of cure - UD Tape

Degree of cure - 5HS FabricDegree of cure - PW FabricDegree of cure - ModelCure Rate (1/s) - UD TapeCure Rate (1/s) - 5HS FabricCure Rate (1/s) - PW FabricCure Rate (1/s) - Model

165

Comparison of Forms – 4cpm

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

-100 -50 0 50 100 150 200 250 300Temperature (°C)

Deg

ree

of C

ure

0.00E+00

2.00E-04

4.00E-04

6.00E-04

8.00E-04

1.00E-03

1.20E-03

1.40E-03

1.60E-03

1.80E-03

2.00E-03

Cur

e ra

te (1

/s)Degree of cure - UD Tape

Degree of cure - 5HS FabricDegree of cure - PW FabricDegree of cure - ModelCure Rate (1/s) - UD TapeCure Rate (1/s) - 5HS FabricCure Rate (1/s) - PW FabricCure Rate (1/s) - Model

166

Heat Capacity (Cp) Model

167

NomenclatureCp Heat Capacity (J/gC)

168

Cp Measurement

• The DSC tests were temperature modulated to obtain a measure of the material’s heat capacity, Cp.

• Due to the small level of variability with the experimental data, a certain level of scatter was observed in the Cp response of various tests.

• The tests considered for model fitting were performed at a modulation period of 100 seconds.

169

Raw Data

0.5

0.7

0.9

1.1

1.3

1.5

1.7

1.9

-100 0 100 200 300 400

Temperature (C)

Cp

(J/g

ºC)

0.5cpm1cpm2cpm3cpm4cpm5cpm6cpm7cpm8cpm9cpm10cpm

170

0.5

0.7

0.9

1.1

1.3

1.5

1.7

1.9

-100 0 100 200 300 400Temperature (C)

Cp

(J/g

ºC)

0.5cpm1cpm2cpm3cpm4cpm5cpm6cpm7cpm8cpm9cpm10cpm

Raw Data – Shifted

Shifted to match the final rubbery response

171

Raw Data – 0.5cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

0.5 cpm - Test

172

Raw Data – 1cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

1cpm - Test

173

Raw Data – 2cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

2cpm - Test

174

Raw Data – 3cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

3cpm - Test

175

Raw Data – 4cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

4cpm - Test

176

Raw Data – 5cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

5cpm - Test

177

Raw Data – 6cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

6cpm - Test

178

Raw Data – 7cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

7cpm - Test

179

Raw Data – 8cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

8cpm - Test

180

Raw Data – 9cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

9cpm - Test

181

Raw Data – 10cpm

0.5

0.8

1.1

1.4

1.7

2

-100 0 100 200 300 400

Temperature (ºC)

Cp

(J/g

ºC)

10cpm - Test

182

Cp Model Basics• Glassy and rubbery Cp were assumed to be linear functions of temperature and DoC• Cp was assumed to transition between the glassy and rubbery responses with changes in T-Tg

0.5

1.0

1.5

2.0

2.5

-50 0 50 100 150 200 250 300Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

Rubbery

GlassyTotal Cp

T-Tg

183

Cp Model

30.0=k

The parameters of the Cp model are determined by fitting to the experimental results. The model is formulated as shown below:

004202.00 =gs

Valid for temperature values between -50ºC to 300ºC.

Glassy Rubbery

( )[ ]cg TTTkrpgp

rpp e

CCCC Δ−−+

−+=

1

0=Δ cT

Other parameters

( )∞==+= ,0 and , jgricTsC ijijijp

( )∞

+−=ipipp xCCxC

i 01

Virgin and cured responses:

Glassy or rubbery at x:

Total Cp response:

754926.00 =gc0036018.0=∞gs6842092.00 =gc

0027384.00 =rs9378419.00 =rc

002244.0=∞gs942797.00 =gc

184


0.5

1

1.5

2

2.5

-50 0 50 100 150 200 250 300Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

0.5cpm test

Cp (Model)

Cp (Test)

T-Tg

185


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

1cpm test

Cp (Model)

Cp (Test)

T-Tg

186


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

2cpm test

Cp (Model)

Cp (Test)

T-Tg

187


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

3cpm test

Cp (Model)

Cp (Test)

T-Tg

188


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

4cpm test

Cp (Model)

Cp (Test)

T-Tg

189


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

5cpm testCp (Model)

Cp (Test)

T-Tg

190


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

6cpm test

Cp (Model)

Cp (Test)

T-Tg

191


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

7cpm test

Cp (Model)

Cp (Test)

T-Tg

192


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

8cpm test

Cp (Model)

Cp (Test)

T-Tg

193


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

9cpm test

Cp (Model)

Cp (Test)

T-Tg

194


0.5

0.9

1.3

1.7

2.1

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

10cpm test

Cp (Model)

Cp (Test)

T-Tg

195


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

0.5 cpm - Test0.5 cpm - Model

196


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)

0.5 cpm - Test0.5 cpm - Model

197


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)

1cpm - Test1cpm - Model

198


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


199


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


200


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


201


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


202


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


203


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


204


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


205


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


206


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


207


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


208


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


209


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


210


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


211


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


212


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


213


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


214


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


215


0.5

0.8

1.1

1.4

1.7

2

-50 0 50 100 150 200 250 300

Temperature (ºC)

Cp

(J/g

ºC)


216


0.5

0.8

1.1

1.4

1.7

2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


217

Isothermal Tests – Raw Data

1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

1.45

1.5

0 100 200 300 400 500 600 700Time (min)

Cp

65C70C75C80C85C90C95C100C105C110C115C120C125C130C135C140C

218

Isothermal Tests – 65ºC

1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

65ºC test

Cp (Model)

Cp (Test)

T-Tg

219


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

70ºC test

Cp (Model)

Cp (Test)

T-Tg

220


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

75ºC test

Cp (Model)

Cp (Test)

T-Tg

221


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

80ºC test

Cp (Model)

Cp (Test)

T-Tg

222


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

85ºC test

Cp (Model)

Cp (Test)

T-Tg

223


1

1.05

1.1

1.15

1.2

1.25

1.3

0 50 100 150 200 250 300 350 400 450 500

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

T-Tg

(ºC

)

90ºC test

Cp (Model)

Cp (Test)

T-Tg

224


1

1.05

1.1

1.15

1.2

1.25

1.3

0 100 200 300 400 500 600

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

95ºC test

Cp (Model)

Cp (Test)

T-Tg

225


1

1.05

1.1

1.15

1.2

1.25

1.3

0 50 100 150 200 250 300 350 400 450 500

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

100ºC test

Cp (Model)

Cp (Test)

T-Tg

226


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 100 200 300 400 500 600

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

105ºC test

Cp (Model)

Cp (Test)

T-Tg

227


1

1.05

1.1

1.15

1.2

1.25

1.3

0 50 100 150 200 250 300 350 400 450 500

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

110ºC test

Cp (Model)

Cp (Test)

T-Tg

228


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 50 100 150 200 250 300

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

115ºC test

Cp (Model)

Cp (Test)

T-Tg

229


1

1.1

1.2

1.3

1.4

0 50 100 150 200 250 300 350 400 450

Time (min)

Cp

(J/g

ºC)

-60

-40

-20

0

20

40

60

80

100

120

T-Tg

(ºC

)

120ºC test

Cp (Model)

Cp (Test)

T-Tg

230


1

1.1

1.2

1.3

1.4

0 50 100 150 200 250 300

Time (min)

Cp

(J/g

ºC)

-40

-20

0

20

40

60

80

100

120

T-Tg

(ºC

)

125ºC test

Cp (Model)

Cp (Test)

T-Tg

231


1.1

1.2

1.3

1.4

0 50 100 150 200 250 300 350 400 450

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

130ºC test

Cp (Model)

Cp (Test)

T-Tg

232


1.1

1.2

1.3

1.4

0 50 100 150 200 250 300 350 400 450

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

135ºC test

Cp (Model)

Cp (Test)

T-Tg

233


1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 50 100 150 200 250 300 350 400 450

Time (min)

Cp

(J/g

ºC)

-50

0

50

100

150

T-Tg

(ºC

)

140ºC test

Cp (Model)

Cp (Test)

T-Tg

234


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)

65C - Test65C - Model

235


1

1.05

1.1

1.15

1.2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


236


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)


237


1

1.05

1.1

1.15

1.2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


238


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)


239


1

1.05

1.1

1.15

1.2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


240


1

1.05

1.1

1.15

1.2

0 100 200 300 400 500 600 700

Time (min)

Cp

(J/g

ºC)


241


1

1.05

1.1

1.15

1.2

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


242


1

1.05

1.1

1.15

1.2

1.25

1.3

0 100 200 300 400 500 600

Time (min)

Cp

(J/g

ºC)


243


1

1.05

1.1

1.15

1.2

1.25

1.3

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


244


1

1.05

1.1

1.15

1.2

1.25

1.3

0 100 200 300 400 500

Time (min)

Cp

(J/g

ºC)


245


1

1.05

1.1

1.15

1.2

1.25

1.3

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


246


1

1.05

1.1

1.15

1.2

1.25

1.3

0 100 200 300 400 500 600

Time (min)

Cp

(J/g

ºC)


247


1

1.05

1.1

1.15

1.2

1.25

1.3

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


248


1

1.05

1.1

1.15

1.2

1.25

1.3

0 100 200 300 400 500

Time (min)

Cp

(J/g

ºC)


249


1

1.05

1.1

1.15

1.2

1.25

1.3

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


250


1

1.05

1.1

1.15

1.2

1.25

1.3

0 100 200 300 400 500 600

Time (min)

Cp

(J/g

ºC)


251


1

1.05

1.1

1.15

1.2

1.25

1.3

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


252


1

1.05

1.1

1.15

1.2

1.25

1.3

0 100 200 300 400 500

Time (min)

Cp

(J/g

ºC)


253


1

1.05

1.1

1.15

1.2

1.25

1.3

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


254


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 50 100 150 200 250 300

Time (min)

Cp

(J/g

ºC)


255


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


256


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 100 200 300 400 500

Time (min)

Cp

(J/g

ºC)


257


1

1.1

1.2

1.3

1.4

1.5

1.6

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


258


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 50 100 150 200 250 300

Time (min)

Cp

(J/g

ºC)


259


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


260


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 100 200 300 400 500

Time (min)

Cp

(J/g

ºC)


261


1

1.1

1.2

1.3

1.4

1.5

1.6

1.7

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


262


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 100 200 300 400 500

Time (min)

Cp

(J/g

ºC)


263


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


264


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 100 200 300 400 500

Time (min)

Cp

(J/g

ºC)


265


1

1.05

1.1

1.15

1.2

1.25

1.3

1.35

1.4

0 0.2 0.4 0.6 0.8 1

Degree of Cure

Cp

(J/g

ºC)


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Material Characterization for Processing: CYTEC Cycom 5215 · Material Characterization for Processing: CYTEC Cycom 5215 Material Model Development Final Project Wrap-Up Prepared