22
Viacom Inc. EPA Region 5 Records Ctr. Bloominglon Project One City Centre. Suite 108 Bloomiiigton. IN 47404 (812)334-0030 237477 (812)334-7855(Fax) VIACOM October 18,2001 BP:01-0091 To: DISTRIBUTION LIST USEPA Region 5 Indiana Department of Environmental Management Monroe County Health Department City of Bloomington Utilities Services Board TetraTech EM, Inc. Earth Tech Re: Post-Excavation Groundwater Monitoring Results for Bennett's Dump, Monroe County, Indiana This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc. at the Bennett's Dump site. In accordance with post-excavation interim monitoring requirements outlined in the Bennett's Dump Statement of Work (SOW), groundwater and surface water sampling was performed at the following locations: Middle Spring, Stout's Creek Upstream, Stout's Creek Downstream and Stout's Creek West Branch. Mound Spring was not flowing and could not be sampled. The general locations of these sampling points are shown on Figure 1 (attached). At spring and stream locations the samples were collected by carefully filling a new disposable beaker. The water was transferred from the beaker into a pre-cleaned amber glass 1-liter bottle supplied by the analytical laboratory. Routine sampling parameters including temperature and conductivity were measured and recorded. For quality assurance purposes a duplicate sample and a field blank were collected. All samples were labeled and logged onto a chain-of-custody form. The samples were stored and transported in insulated coolers. Custody of the water samples was maintained by Viacom until shipment to the analytical laboratory. Samples were analyzed by Heritage Lab of Indianapolis, Indiana. The samples were analyzed to a detection limit of 0.1 parts per billion (ppb) for all PCB parameters (except Aroclor 1221; detection limit 0.5 ppb) by EPA Method 608/SW-846 Method 8082. Field measurements, PCB analytical results, and QA/QC results for the August 2001 groundwater monitoring event are presented in Table 1 (attached). Historical PCB results for individual monitoring locations are presented in Tables 2 through 6.

LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

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Page 1: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

Viacom Inc. EPA Region 5 Records Ctr.Bloominglon ProjectOne City Centre. Suite 108Bloomiiigton. IN 47404(812)334-0030 237477(812)334-7855(Fax)

VIACOMOctober 18,2001

BP:01-0091

To: DISTRIBUTION LISTUSEPA Region 5Indiana Department of Environmental ManagementMonroe County Health DepartmentCity of Bloomington Utilities Services BoardTetraTech EM, Inc.Earth Tech

Re: Post-Excavation Groundwater Monitoring Results for Bennett's Dump,Monroe County, Indiana

This letter summarizes the results of the August 7,2001 groundwater sampling event performedby Viacom, Inc. at the Bennett's Dump site. In accordance with post-excavation interimmonitoring requirements outlined in the Bennett's Dump Statement of Work (SOW),groundwater and surface water sampling was performed at the following locations: MiddleSpring, Stout's Creek Upstream, Stout's Creek Downstream and Stout's Creek West Branch.Mound Spring was not flowing and could not be sampled. The general locations of thesesampling points are shown on Figure 1 (attached).

At spring and stream locations the samples were collected by carefully filling a new disposablebeaker. The water was transferred from the beaker into a pre-cleaned amber glass 1-liter bottlesupplied by the analytical laboratory. Routine sampling parameters including temperature andconductivity were measured and recorded.

For quality assurance purposes a duplicate sample and a field blank were collected. All sampleswere labeled and logged onto a chain-of-custody form. The samples were stored and transportedin insulated coolers. Custody of the water samples was maintained by Viacom until shipment tothe analytical laboratory. Samples were analyzed by Heritage Lab of Indianapolis, Indiana. Thesamples were analyzed to a detection limit of 0.1 parts per billion (ppb) for all PCB parameters(except Aroclor 1221; detection limit 0.5 ppb) by EPA Method 608/SW-846 Method 8082.

Field measurements, PCB analytical results, and QA/QC results for the August 2001groundwater monitoring event are presented in Table 1 (attached). Historical PCB results forindividual monitoring locations are presented in Tables 2 through 6.

Page 2: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

Distribution ListOctober 18, 2001Page 2

Copies of the field log, chain-of-custody, laboratory analytical reports and validation statementsfor these samples are also attached.

If you have questions regarding this sampling event or the results reported herein, please callMike McCann at (812) 334-0030.

Sincerely,

Dorothy M. AlkeProject Director

Attachments

DISTRIBUTIONTom Alcamo, USEPA Region 5Jessica Fliss, IDEMDennis Williamson, Monroe County Health Department

cc:John Langley, CBUV. Rajaram, Tetra Tech EM, Inc.John Bassett, Earth TechMike McCann, ViacomRuss Cepko, ViacomBP FilesProject File 30400.18 GWM

Page 3: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

ATTACHMENTS

Post-Excavation Ground Water Monitoring ResultsAugust 7,2001

Bennett's Dump

Figure 1 Sample Location MapTables of Sampling ResultsField LogChain-of-CustodyLaboratory Analytical Reports and Data Validation

Page 4: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

! 5\\S Stout's Creek\Y West Branch>.

^^N

Stout's CreekUpstream

MW-3 Monitoring Well

Surface Water Sample

I / IZZ/': / // i*

Bennetts Dump Sample Location Map

Page 5: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

TABLE 1

RESULTS OF SAMPLINGBENNETT'S DUMP POST-REMEDIATION GROUNDWATER & SURFACE WATER MONITORING

AUGUST 7, 2001

LocationStout's Cr. Upstrm

Middle Sp.Field Blank

W. Branch Stout's Cr.Stout's Cr. DnstrmStout's Cr. Dnstrm

SampleID

BD9213BD9214BD9215BD9216BD9217BD9218

PCBs(ppb)BDL12

BDLBDL0.310.39

TSS(mg/L)

5BDLBDLBDL

5BDL

Temperature(deg C)

23.016.7NA

25.824.724.7

Conductivity(us/cm)

589557NA532590590

Comments

Field Blank

BDL - below detection limit

Page 6: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

Table 2Bennett's Dump

History of PCB Analytical Results forStoufs Creek Upstream

DATE SAMPLED26-Aug-9912-Nov-9927-Jan-OO30-Mar-OO16-May-OO23-Jun-OO3-Oct-OO20-Dec-OO23-Feb-0111-Apr-0112-Jun-017-Aug-01

PCB CONCENTRATION (PPB)BDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDLBDL

BDL - Below Detection Limit

Table 3Bennett's Dump

History of PCB Analytical Results forWest Branch Stoufs Creek

DATE SAMPLED26-Aug-gg12-Nov-9927-Jan-OO30-Mar-OO16-May-OO23-Jun-OO3-Oct-OO20-Dec-OO23-Feb-0111-Apr-0112-Jun-017-Aug-01

PCB CONCENTRATION (PPB)0.14BDL0.02 JBDLBDLBDL0.1 5 JBDLBDLBDLBDLBDL

BDL - Below Detection LimitJ = Estimate

Table 4Bennett's Dump

History of PCB Analytical Results forStoufs Creek Downstream

DATE SAMPLED26-Aug-9912-Nov-9927-Jan-OO30-Mar-OO16-May-OO23-Jun-OO3-Oct-OO

20-Dec-OO23-Feb-0111-Apr-0112^Jun-017-Aug-01

PCB CONCENTRATION (PPB)BDLBDL0.3 JBDL

0.085 J0.24/0.23* J

0.21 J0.18J0.13 JBDL0.25

0.31/0.39*BDL - Below Detection LimitJ = Estimate* Duplicate sample

Page 7: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

Table 5Bennett's Dump

History of PCB Analytical Results forMiddle Spring

DATE SAMPLED30-Mar-OO16-May-OO23-Jun-OO3-Oct-OO

20-Dec-OO23-Feb-0111-Apr-0112-Jun-017-Aug-01

PCB CONCENTRATION (PPB)3.74.713138.94.14.81.812

Table 6Bennett's Dump

History of PCB Analytical Results forMound Spring

DATE SAMPLED23-Jun-OO3-Oct-OO

20-Dec-OO23-Feb-0111-Apr-0112-Jun-017-Aug-01

PCB CONCENTRATION (PPB)1.92.6NS1.2NS7.3NS

NS - Not sampled, no flow

Page 8: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc
Page 9: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

TO ENSURE PROPER HANDLING OF SWlPLES PLEASE COMPLETE THIS ENTIRE FORM

HERITAGE ENVIRONMENTAL SERVICESCOMMERCIAL LABORATORY OPERATIONS

7901 West Morns StreetIndianapolis, Indiana 46231 {317) 243-0811 Fax (317) 486-5095

I- 93385CS

. -^H^OD

CSCS

o. Name:

roject Name:

Quote No.: PO Noff-ENVIRONMENTAL PROGRAM:

WA NPDES IWP_

RCRA

SDWA. OTHFR

Sampled by: /J (

ClientID: Dale: "Time: fla Sample Description

Mat

rix):

. S

oil,

Oil.

Slud

ge,

Sam

ple

TD

W, G

W,

Analyses Requested(Note spec al daleclfon limits or metnods)

41

Add:

Report To:

Co:

Attn:Phone:

Accelerated Turnaround Requested _(Subject lo Additional Charge)

Result Request by:Mo Day Yr

(Date must be Accepted and Approved by Lab)

Remarks: LAB

Sample No.

£-7-0 J CC wsIJT'.io

a to t-3

vrjAMPM

K-wxfVVAMPMAM

_£MAM

-IM-AM

_PMDUWTtM ngu\«lti:(GlanUi[«)

0-6

Rrinqittwd by. (S»i»1ic»)

DUWTirw Ha«n«dby:(Skr»tur«) Re«nquith«d by: {SfgnMur*} Radioed fay: (SlgnUur*)

RgfinquUhed by. (Slgfutun) OUt/Tlnt n«»lMd hi Lib0(

Rtrnuto

Dislributton: White orig ral end Yellow copy to accompany sample to laboratory,Pink copy to be retained by client,

Page 10: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

Validation Results for the August 2001 Bennett's Dump Spring and Stream Water Samples

1. Validation of the following samples has been completed:

• BD9213-BD9218

2. Validation was performed per the requirements for level 4 data in the project QAPjP. This includes acheck for: Holding Time, Calibration, Blank Contamination, Precision, Accuracy, and Accuracy ofNominal Reporting Limits against method requirements. Based on this review, all methodrequirements were met and no data qualification flags are recommended.

3. The QAPjP requires an assessment of the overall data quality with respect to Precision, Accuracy,Representativeness, Completeness and Comparability (PARCC).

o Precision and accuracy: Precision and accuracy were assessed by reviewing the labperformance on lab spiked samples, lab spike duplicates and field duplicates. Allrequirements were met.

o Representativeness: The representativeness requirement involves an assessment of thefield sampling and lab analytical techniques. The field sampling locations and techniquesas well as lab procedures were in accordance with the approved sampling plan and QAPjP.There was one deviation from the sampling plan requirements. The lab noted the sample

temperature at receipt was 8 degrees C. The sampling requirement is to cool the samplesto 4 degrees C. The samples were delivered to the lab within one day of the sample date.This minor deviation should not affect the quality of this data and overall therepresentativeness requirement was met.

o Completeness: The completeness goal for the project was for all project data to be 90%accepted. Completeness is calculated by dividing the total number of acceptable analysesby the total performed. An acceptable analysis is defined as one that conformed to QCprotocols and is not rejected. All the noted sample analyses in this batch were accepted sothe completeness goal was met.

o Comparability: All the samples taken, analyzed and validated by Viacom were taken byViacom or its contractor's sampling crews using the same procedures as previous samplesat this location. Care should be observed when attempting to trend these results with thehistorical data from a different lab. These samples were analyzed by Heritage Labs.Heritage Labs has analyzed most of the previous samples from this site.

Overall, the main objective of the sampling event was to determine if PCBs are present at a concentrationof. 1 ppb or more. This data is of sufficient quality to satisfy this goal.

Page 11: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

C E R T I F I C A T E O F A N A L Y S I S

Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

10-AUG-01Complete

22-AUG-01Printed

22-AUG-01

Project

4602Lab ID

A562437PO Number

BL0177 ***Sampled

07-AUG-01 14:30

Report To

JIM PATRICKCBS CORPORATIONONE CITY CENTRE - SUITE 108BLOOMINGTON, IN 47404

Bill To

ACCOUNTS PAYABLEVIACOM, INC.120 WEST 7TH STREET - SUITEBLOOMINGTON, IN 47404

108

CLIENT ID: BD9213MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: BENNETTS DUMPSubmitter Code :2226

Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION;: Analyst: C. HIPSKtNS Analysis Date: lO-AUG^OV •

Parameter

INITIAL WEIGHT OR VOLUMEFINAL VOLUME :w- . m^m^mmm^m

SW846-3510CInstrument: PREP :

Result

9405mv::>€4f^->;;^:v:;.;->

Test: P230.1.C

Det. Limit

1

Units

mLW&K"^.-

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082 NELAC:YAnalyst: J. OSBORNE Analysis: bate:;: 13-AUfi-Ol .;:...'% Instrument: GC/ECD Test: 0301.7:0

Prept PCB SEPARATORY FUNNEL LIOUrO-LIQUID EXTRACTION SW846-3Slbc>23b. 1.0

Parameter

PCB AROCLOR 1016PCB AROCLOR 1221PCB AROCLOR 1232PCB AROCLOR 1242PCB AROCLOR 1248PCB AROCLOR 1254PCB AROCLOR 1260PC B AROCLOR 1 262

SURROGATE RECOVERY

DECACHLOROBIPHENYL IDCB)

Result

BDLBDLBDLBDLBDLBDLBDLBDL

72 ,

Det. Limit

0.10

o!io.Ov 10-

0.10

O.'lO0.10

Units

ug/L•::::Ug/L:x :v-vv--.:. :•:-.•••

ug/Lug/t ;

:':ug/L; :;;:::::..ug/Lug/L

% Rec

TOTALAnalyst

TOTAL707VI/.

PCB CALCULATION HLI3: JV OSBORNE : ; Ana I ys i s

Parameter

PCBSPCB DETECTION LIMIT DOES

Date;

NOT

J13-AUG-01 Instrument: GC/ECD Test: 0301. 3;0

BDLINCLUDE AROCLOR

Result Det. Limit

0.10Units

uq/L1221

Page 1 (continued on next page)

Page 12: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

HERITAGE ENVIRONMENTAL SERVICES. LLC Sample ID: A562437 BD9213TOTAL SUSPENDED SOLIDS EPA 160 .

;;-::Ar lyst:- 'IfiSCRAWFORD'-t, :tj;: ".-. •* *Ana lysis

SUSPENDED SOLIDSParameter

2 NELAC:YDate: 14-AUG-01 13:00 Test: G403.7.0

Result5

Det. Limit1

Unitsmq/L

BDL Below Detection LimitSample Comments

Sample was received on ice at temperature 8 C.All aqueous samples are reported on a wet weight basis unless otherwise noted.Sample chain of custody number 93385.

This Certificate shall not be reproduced, except in full,without the written approval of the lab.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.

Additional copies of this report sent to:RUSS CEPKO, CBS CORPORATION11 STANUIX STREET, PITTSBURG, PA 15222-1384

Approved Page 2 (last page)

Page 13: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

C E R T I F I C A T E O F A N A L Y S I S

Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

10-AUG-01Complete

22-AUG-01Printed

05-SEP-01

Project

4602Lab ID

A562438PO Number

BL0177 ***Sampled

07-AUG-01 15:10

Report To

JIM PATRICKCBS CORPORATIONONE CITY CENTRE - SUITE 108BLOOMINGTON, IN 47404

Bill To

ACCOUNTS PAYABLEVIACOM, INC.120 WEST 7TH STREET - SUITE 108BLOOMINGTON, IN 47404

CLIENT ID: BD9214MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WGSITE: BENNETTS DUMPSubmitter Code :2226

Sample Description

PCB SEPARATORS FUNNEL LIQUID-LIQUID EXTRACTIONAnalyst: C. HIPSK1NS : Analysis Date: 10-AUG-OT

Parameter

INITIAL WEIGHT OR VOLUMEFINAL VOLUME I i .v

SW846-3510CInstrument: PRCP

Result

900- . 5,.- ..... . . . . ..;,•.•,....•

Test: P230.i:t

Det. Limit

*•:' • '• '

Units

mLml

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082 NELAC:YAnalyst: J. OSBORNE Analysis Date: 13-AUG*01 Instrument: GC/ECD Test: 0301.7.0

Prep: PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW&46'3510CP230. 1.0

Parameter

PCB AROCLOR 1016PCB AROCLOR 1221PCB AROCLOR 1232PCB AROCLOR 1242 .' •,-.:.. • • " . • : • • ..:,,,:•,:•...,,:, •.:••.::: '•^^•^

PCB AROCLOR 1248PCB AROOLO* ^PCB AROCLOR 1260PCB AROCLOR 1262• • •

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCB)

Result

BDL>:>.:>BDE,.-.: . • : '• • -:-: v. : /,

BDL• :m±. •;+.::'. •^••••••^a :

BDL-•.BDL,. :--:::. v - - • • • • • • . • • ; • • • • • , . • . , : • ;

BDLBDL

18

Det. Limit

0.50•:•:•:••"••,„ ^SS

0.50::--::--: mM

0.50•>vv-vlm5P

0.500,50

Unitsug/L

• g^L:;:. . :•-:•-•

ug/Lmfc ..•:• :• : ••• :• : • ::-ug/L

m&& ' • •ug/Lug/L

::*:;::'ReG-:.: •:•'•-•: . • : - : ' - .

1:5 Dilution.

TOTAL PCB CALCULATION HLI3! • ; ; • Analysis Date: 13-AUG-01 Instrument: GC/ECD Test: 0301.3.0

Page 1 (continued on next page)

Page 14: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

HERITAGE ENVIRONMENTAL SERVICES, LLC Sample ID: A562438 BD9214

TOTAL PCBSParameter

12TOTAL PCB DETECTION LIMIT DOES NOT INCLUDE AROCLOR1:5 Dilution.

Result Det. Limit

0.50

UnitsUQ/L

1221

TOTAL SUSPENDEDlAhatyst: X- CRAWFORD

SUSPENDED SOLIDS

SOLIDS EPA 160,Analysis

Parameter

2 NELAC:YDate: 14-AUG-01 13:00 Test: G403.7iO

Result

BDLDet. Limit

1Units

mq/L

Sample CommentsAmended report: PCB results corrected per EMU. pks 05SEP01

BDL Below Detection Limit

Sample was received on ice at temperature 8 C.All aqueous samples are reported on a wet weight basis unless otherwise noted.Sample chain of custody number 93385.

This Certificate shall not be reproduced, except in full,without the written approval of the lab.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.

Additional copies of this report sent to:RUSS CEPKO, CBS CORPORATION11 STANwIX STREET, PITTSBURG, PA 15222-1384

Approved Page 2 (last page)

Page 15: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

C E R T I F I C A T E O F A N A L Y S I S

Service LocationHERITAGE ENVIRONMENTAL SERVICES, LLC

COMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

10-AUG-01Complete

22-AUG-01Printed

22-AUG-01

Project4602

Lab 10

A562439PO Number

BL0177 ***Sampled

07-AUG-01 15:10

Report To

JIM PATRICKCBS CORPORATIONONE CITY CENTRE - SUITE 108BLOOMINGTON, IN 47404

Bill To

ACCOUNTS PAYABLEVIACOM, INC.120 WEST 7TH STREET - SUITE 108BLOOMINGTON, IN 47404

CLIENT ID: BD9215MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: BENNETTS DUMPSubmitter Code :2226

Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTIONAnalyst: J. MONTGOMERY Analysis Date: 10-AUG-D1

ParameterINITIAL WEIGHT OR VOLUME

/FINAL:' VOLUME. '• ' "' 'v ' . '' -: ;->:,- - ::; ,:••:. « %. ;;>•,,;,: -:,..•: ;:•;:

SW846-3510Cinstrument: PREP

Result960

.-•5:i:::-:,' •••-:

Test: P230.1;(

Det. Limit

1

UnitsmlmL

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8Analyst: J. OSBORME Analysis Date: 13- AUG- 01

Prep: PCB: SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C

ParameterPCB AROCLOR 1016PCB AROCLOR 1221PCB AROCLOR 1232PCB AROCLOR 1242PCB AROCLOR 1248PCB AROCLOR 1254PCB AROCLOR 1260PCB AROCLOR 1262 '»;>• ... . . : ::.: • • • • ' / , • m- '• m:^• • •

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCB)

Q82Instrument: GC/ECDP230.1.0

ResultBDLBDLBDLBDLBDLBDLBDLBDL • ' • . • • ^ • • • ; ,.. :

76

Test: 0301 ,7,<

Det. Limit0.100.500.100. 100.100.100.10oao

NELAC:Y'::.

Unitsug/L

^ig/EL^v-.;ug/Lug/Lug/Lug/Lug/Lug/L

% Rec

TOTALAnalyst

TOTALTOTAL

PCB CALCULATION HLI3: J. OSBORNE Analysis

ParameterPCBSPCB DETECTION LIMIT DOES

Date:

NOT

13-AUG-01 Instrument: GC/ECD Test: 0301.3.0:

BDLINCLUDE AROCLOR

Result Det. Limit0.10

UnitsUQ/L

1221

Page 1 (continued on next page)

Page 16: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

HERITAGE ENVIRONMENTAL SERVICES. LLC Sample ID; A562439 BD9215TOTAL SUSPENDED

; -Aha tyst: : <;! CRAWFORD

SUSPENDED SOLIDS

SOLIDS EPA 160.:•';... •:. :;5;;::;:::.::. Analysis-

Parameter

2 NELACtYDate: U-AUG-01 13:00 Test: 0403.7,0

ResultBDL

Det. Limit

1

Units

mq/L

Sample CommentsBDL Below Detection Limit

Sample was received on ice at temperature 8 C.All aqueous samples are reported on a wet weight basis unless otherwise noted.Sample chain of custody number 93385.

This Certificate shall not be reproduced, except in full,without the written approval of the lab.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.

Additional copies of this report sent to:RUSS CEPKO, CBS CORPORATION11 STANUIX STREET, PITTSBURG, PA 15222-1384

Approved : }/C /<yu/tif\ ((fty Page 2 (last page)

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C E R T I F I C A T E O F A N A L Y S I S

Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received10-AUG-01Complete

22-AUG-01Printed

22-AUG-01

Project

4602Lab ID

A562440PO Number

BL0177 ***Sampled

07-AUG-01 15:20

Report To

JIM PATRICKCBS CORPORATIONONE CITY CENTRE - SUITE 108BLOOMINGTON, IN 47404

Bill To

ACCOUNTS PAYABLEVIACOM, INC.120 WEST 7TH STREET - SUITEBLOOMINGTON, IN 47404

108

CLIENT ID: BD9216MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: BENNETTS DUMPSubmitter Code :2226

Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTIONAnalyst: J. MONTGOMERY Analysis Date: 1Q-A1JG-01 ;

Parameter

INITIAL WEIGHT OR VOLUMEl::fiNALy-voIUMEr:-:v::::---::::::::;;;:::::::----v----:;:v:;-::;:; ,, ^ iMyt^w

SW846-351DCihstruraent; PREP:

Result920

•'•m±-^m'"' '"•::-,:': -4-

Test: P230.11C

Det. Limit

1

UnitsmL

iW-.:-"--:'-':-'

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082 NELAC:YAnalyst: J. OSBORNE Ana lysis .Date: 13rAUfi-01 : ihstrunient: GC/ECD Test: 0301 .7JO :

Prep: PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C P230.1.0

ParameterPCB AROCLOR 1016prR ARnn nc I??TT\>O rtl\Ul»LUt\ 1L.L.± •::•:•:•••

PCB AROCLOR 1232PCB AROCLOR 1242PCB AROCLOR 1248PCB AROCLOR 1254PCB AROCLOR 1260PC B AROCLOR 1 262

SURROGATE RECOVERY

DECACHLOROBIPHENYL (DCB)

ResultBDLBDL . : • • • ^ -^BDLB D L • • • • : • . • • . . . . - • / • . : • : .BDLBDLBDLBDL

74

Det. Limit0.100.500.10

••:, -rrafr0.10

4 OvlO0.100.10

Unitsug/Lmm ••••ug/Lmms- .,"•ug/L

•-:>Ug/:L';,. • • : • : • : - : : : :ug/Lug/L

% Rec

TOTALAnalyst

TOTALTOTAL

PCB CALCULATION HLI3: J. OSBORNE: xS ;• j- Analysis

Parameter

PCBSPCB DETECTION LIMIT DOES

Date:

NOT

il-AUCMJI instrument: GC/ECD Test: 0301.3.0

BDLINCLUDE AROCLOR

Result Det. Limit0.10

Unitsuq/L

1221

Page 1 (continued on next page)

Page 18: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

HERITAGE ENVIRONMENTAL SERVICES, LLC Sample ID; A562440 BD9216TOTAL SUSPENDED;; Analyst: K. CRAWFORD

SUSPENDED SOLIDS

SOLIDS EPA 160.• •••. •:• '.,.;••'.. Analysis

Parameter

Z NELAC:YDate: H-AUG-01 13:00 Test: G403.7.0

ResultBDL

Det. Limit1

Unitsmq/L

BDL Below Detection LimitSample Comments

Sample was received on ice at temperature 8 C.All aqueous samples are reported on a wet weight basis unless otherwise noted.Sample chain of custody number 93385.

This Certificate shall not be reproduced, except in full,without the written approval of the lab.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.

Additional copies of this report sent to:RUSS CEPKO, CBS CORPORATION11 STAMIX STREET, PITTSBURG, PA 15222-1384

Approved Page 2 (last page)

Page 19: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

C E R T I F I C A T E O F A N A L Y S I S

Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

10-AU6-01Complete

22-AUG-01Printed

22-AUG-01

Project

4602Lab ID

A562441PO Number

BL0177 ***Sampled

07-AUG-01 15:45

Report To

JIM PATRICKCBS CORPORATIONONE CITY CENTRE - SUITE 108BLOOMINGTON, IN 47404

Bill To

ACCOUNTS PAYABLEVIACOM, INC.120 WEST 7TH STREET - SUITE 108BLOOMINGTON, IN 47404

CLIENT ID: BD9217MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: BENNETTS DUMPSubmitter Code :2226

Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTIONAnalyst: J. MONTGOMERY Analysis Date: 10-AU6-01

Parameter

INITIAL WEIGHT OR VOLUMEI FINAL VOLUME- w^m^-mm*- Mmm^mmmmmmm

SW846-3510CInstrument: '..; PREP

Result

1000mmmW;.-± :: -mmmm.

Test: P230.l:(

Det. Limit

•.•;.:.;: '•'•'':: ' •

) """•'•• -

Units

mLmm ;:>••'•'••••"'

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846-8082 NELACrYAnalyst: J* OSBORNE Analysis .Date: j -AUE-Oty:::::: :: ^ Test: 0301.7:0 : ;; ;

Prep: PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW8<6»3510C P23Q.1.0 .': >. .;'-

Parameter

PCB AROCLOR 1016PCB AROCLOR 1221PCB AROCLOR 1232PCB AROCLOR 1242PCB AROCLOR 1248PCB AROCLQR 1254PCB AROCLOR 1260PCB AROeiDR 1262 W :: > . ... ••' •' •••^•m^-m.

iURROGATE RECOVERY

DECACHLOROBIPHENYL (DCB)

ResultBDLBDL0.31BDLBDLBDLBDL

::./BDL:::.:..V..: • .-/•:. : ••

76

Det. Limit

0.10

0.500.100;100.100. 100.100,10

Units

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

9i RecDegraded Aroclor 1232 pattern.

TOTAL PCB CALCULATIONHLI3Analyst: J. OSBOfiNE Analysts Date: 13-AUG-01 Instrument: GC/ECD Test: 0301.3.0

Page 1 (continued on next page)

Page 20: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

HERITAGE ENVIRONMENTAL SERVICES, LLC Sample ID: A562441 BD9217Parameter

TOTAL PCBSResult

0.31Det. Limit

0.10Uni ts

uq/LTOTAL PCB DETECTION LIMIT DOES NOT INCLUDE AROCLOR 1221

TOTAL SUSPENDEDAnalyst: K, CRAWFORD

SUSPENDED SOLIDS

SOLIDS EPA 160.Analyst's

Parameter

2 NELAC-.YDate: H-AUG-01 13iOO Test: G403.7.0 :

Result5

Det. Limit1

Unitsmq/L

BDL Below Detection LimitSample Comments

Sample was received on ice at temperature 8 C.All aqueous samples are reported on a wet weight basis unless otherwise noted.Sample chain of custody number 93385.

This Certificate shall not be reproduced, except in full,without the written approval of the lab.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.

Additional copies of this report sent to:RUSS CEPKO, CBS CORPORATION11 STANHIX STREET, PITTSBURG, PA 15222-1384

Approved Page 2 (last page)

Page 21: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

C E R T I F I C A T E O F A N A L Y S I S

Service Location

HERITAGE ENVIRONMENTAL SERVICES, LLCCOMMERCIAL LABORATORY OPERATIONS7901 W. MORRIS ST.INDIANAPOLIS, IN 46231(317)243-8304

Received

10-AUG-01Complete

22-AUG-01Printed

22-AUG-01

Project

4602Lab ID

A562442PO Number

BL0177 ***Sampled

07-AUG-01 15:45

Report To

JIM PATRICKCBS CORPORATIONONE CITY CENTRE - SUITE 108BLOOMINGTON, IN 47404

Bill To

ACCOUNTS PAYABLEVIACOM, INC.120 WEST 7TH STREET - SUITE 108BLOOMINGTON, IN 47404

CLIENT ID: BD9218MATRIX TYPE: NON-SPECIFIC WATERMATRIX: WSSITE: BENNETTS DUMPSubmitter Code :2226

Sample Description

PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTIONAnalyst: J. MONTGOMERY Analysis bate: l O - A U E - D I V ; : :

Parameter

INITIAL WEIGHT OR VOLUME1 FINAL VOLUME .>•••.. -.r> - ^-^^M^-^m

SW846-3510C; Instrument: PREP :

Result

980::',-5::-:-i, ,:::•,:-•: " , ' ,|

Test: P230.1.(

Det. Limit

, . - - '

Units

mL11

PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SH846-8082 NELAC:YAnalyst: J* OSBORNE Ana lysis; Date: ife-W*Q^;''?&~.lminmentt GC/ECD Test: 0301.7:0

Prep: PCB SEPARATORY FUWNEL LIQUID-LIQUID EXTRACTION SU846-3510CP230. 1.0

Parameter

PCB AROCLOR 1016PCB AROCLOR 1221PCB AROCLOR 1232m mciMmtt- /^^ -^PCB AROCLOR 1248PCB AROCLOR 1254PCB AROCLOR 1260PCB AROCLOR 1262 ••> • ' ..:- - • • • .-- v> --™ •••-. :; •- :;

SURROGATE RECOVERY

DECAGHLOROBIPHENYL (DCB)

Result

BDLBDL :: : : : : : , . • : • . : . • • • • • • • • • • • • • • : : , ; • • :

0.39

BDL•....BDL '•••::" '• . . • . •••"" ' " • • ••;:

BDL• • • Oftl • ••'•'•'• OL/L. ••.••• . . • • • . .•

78 • • • - : ••••'••'--,,

Det. Limit

0.10

o!io

. . . . . . . O.TIO''"0.10

Unitsug/L

ug/L

ug/L

ug/L::Ug/L, ,,,

% RecDegraded Aroclor 1232 pattern.

TOTAL PCB CALCULATION HLI3Analyst; J.OSBORNE Analysis Date: 13-AUG-01 Instrument: GC/ECD Test: 0301.3.0

Page 1 (continued on next page)

Page 22: LETTER RE: POST-EXCAVATION GROUNDWATER MONITORING … · 2019-12-01 · This letter summarizes the results of the August 7,2001 groundwater sampling event performed by Viacom, Inc

HERITAGE ENVIRONMENTAL SERVICES, LLC Sample ID: A562442 BD9218

TOTALTOTAL

PCBSPCB

Parameter

DETECTION LIMIT DOES NOT

Result0.39

Det. Limit0.10

UnitsUQ/L

INCLUDE AROCLOR 1221

TOTAL SUSPENDEDAnalyst: X. CRAWFORD

SUSPENDED SOLIDS

SOLIDS EPA 160.Analysis

Parameter

2 NELAC :YDate: 14-AUG-01 13:00 Test: GA03.7.0:

ResultBDL

Det. Limit1

Unitsmq/L

BDL Below Detection LimitSample Comments

Sample was received on ice at temperature 8 C.An aqueous samples are reported on a wet weight basis unless otherwise noted.Sample chain of custody number 93385.

This Certificate shall not be reproduced, except in full,without the written approval of the lab.The sample results relate only to the analytes of interest testedor to the sample as received by the lab.Heritage Environmental Services, LLC certifies that the test resultsindicated as NELAC (National Environmental Laboratory AccreditationConference) accredited (Yes for NELAC) meet all requirements of NELAC andIllinois EPA Part 186 unless otherwise explained or justified as to thethe exact nature of the deviations.Heritage Environmental Services, LLC is accredited under Illinois NELACaccreditation number 100401.

Additional copies of this report sent to:RUSS CEPKO, CBS CORPORATION11 STANHIX STREET, PITTSBURG, PA 15222-1384

Approved : Page 2 (last page)