Lanitz Prena Folien Factory GmbH Safety Data Sheet · according to Regulation (EC) No 1907/2006 Safety Data Sheet Lanitz Prena Folien Factory GmbH Orastick® self- adhesive Revision

according to Regulation (EC) No 1907/2006

Safety Data SheetLanitz Prena Folien Factory GmbH

Orastick® self- adhesive

Revision date: 25.01.2019 Page 1 of 22

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Adhesives, sealants

1.3. Details of the supplier of the safety data sheet

Lanitz Prena Folien Factory GmbHCompany name:

Street: Am Ritterschlösschen 20

04179 LeipzigPlace:

Frau Ploss / AlbrechtContact person: +49 - 341 - 44 23 05 - 34Telephone:

e-mail: [email protected]

+49 (0)6132-84463 (24 h)1.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008

Hazard categories:

Flammable liquid: Flam. Liq. 2

Skin corrosion/irritation: Skin Irrit. 2

Serious eye damage/eye irritation: Eye Irrit. 2

Specific target organ toxicity - single exposure: STOT SE 3

Hazardous to the aquatic environment: Aquatic Chronic 2

Hazard Statements:

Highly flammable liquid and vapour.

Causes skin irritation.

Causes serious eye irritation.

May cause drowsiness or dizziness.

Toxic to aquatic life with long lasting effects.

2.2. Label elements

Regulation (EC) No. 1272/2008

Hazard components for labellingethyl acetate

propan-2-ol; isopropyl alcohol; isopropanol

heptane; n-heptane

Signal word: Danger

Pictograms:

H225 Highly flammable liquid and vapour.

H315 Causes skin irritation.

Hazard statements

GB - EN Print date: 28.01.2019Revision No: 1,0





H319 Causes serious eye irritation.

H336 May cause drowsiness or dizziness.

H411 Toxic to aquatic life with long lasting effects.

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P312 Call a POISON CENTER/doctor if you feel unwell.

P403+P235 Store in a well-ventilated place. Keep cool.

P501 Dispose of waste according to applicable legislation.

Precautionary statements

EUH208 Contains 2-ethylhexyl acrylate, methyl acrylate; methyl propenoate. May produce an

allergic reaction.

Special labelling of certain mixtures

This substance does not meet the criteria for classification as PBT or vPvB.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures






Hazardous components

QuantityChemical nameCAS No

EC No Index No REACH No

Classification according to Regulation (EC) No. 1272/2008 [CLP]

141-78-6 ethyl acetate 50 - < 55 %

205-500-4 607-022-00-5 01-2119475103-46

Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 EUH066

67-63-0 propan-2-ol; isopropyl alcohol; isopropanol 5 - < 10 %

200-661-7 603-117-00-0 01-2119457558-25

Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336

142-82-5 heptane; n-heptane 5 - < 10 %

205-563-8 601-008-00-2 01-2119475515-33

Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Acute 1, Aquatic Chronic 1; H225

H315 H336 H304 H400 H410

108-87-2 methylcyclohexane 5 - < 10 %

203-624-3 601-018-00-7 01-2119486992-20

Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304

H411

64742-49-0 Naphtha (petroleum), hydrotreated light; < 0,1 % Benzol 5 - < 10 %

265-151-9 649-328-00-1 01-2119475514-35

Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304

H411

67-56-1 methanol 1 - < 5 %

200-659-6 603-001-00-X 01-2119433307-44

Flam. Liq. 2, Acute Tox. 3, Acute Tox. 3, Acute Tox. 3, STOT SE 1; H225 H331 H311 H301 H370

64-17-5 ethanol, ethyl alcohol 1 - < 5 %

200-578-6 603-002-00-5 01-2119457610-43

Flam. Liq. 2, Eye Irrit. 2; H225 H319

108-88-3 toluene 1 - < 5 %

203-625-9 601-021-00-3 01-2119471310-51

Flam. Liq. 2, Repr. 2, Skin Irrit. 2, STOT SE 3, STOT RE 2, Asp. Tox. 1, Aquatic Chronic 3; H225

H361d H315 H336 H373 H304 H412

103-11-7 2-ethylhexyl acrylate < 1 %

203-080-7 607-107-00-7 01-2119453158-37

Skin Irrit. 2, Skin Sens. 1, STOT SE 3, Aquatic Chronic 3; H315 H317 H335 H412

96-33-3 methyl acrylate; methyl propenoate < 1 %

202-500-6 01-2119459302-44

Flam. Liq. 2, Acute Tox. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1, STOT

SE 3, Aquatic Chronic 3; H225 H331 H312 H302 H315 H319 H317 H335 H412

123-54-6 acetylacetone, pentane-2,4-dione < 1 %

204-634-0 606-029-00-0 01-2119458968-15

Flam. Liq. 3, Acute Tox. 3, Acute Tox. 3, Acute Tox. 4; H226 H331 H311 H302

Full text of H and EUH statements: see section 16.






SECTION 4: First aid measures

4.1. Description of first aid measures

Move victim out of danger zone. Remove contaminated, saturated clothing immediately. Get medical

advice/attention if you feel unwell. If unconscious place in recovery position and seek medical advice.

Self-protection of the first aider

General information

Provide fresh air. Medical treatment necessary. If breathing is irregular or stopped, administer artificial

respiration.

After inhalation

Wash with plenty of soap and water. Take off immediately all contaminated clothing and wash it before reuse . If

skin irritation occurs: Get medical advice/attention.

After contact with skin

After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time , then consult an

ophthalmologist immediately. Remove contact lenses, if present and easy to do. Continue rinsing.

After contact with eyes

Rinse mouth thoroughly with water. Call a doctor. Do NOT induce vomiting.After ingestion

4.2. Most important symptoms and effects, both acute and delayed

Narcotic effects. Respiratory complaints. Headache. Dizziness.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically. Subsequent observance for pneumonia and lung oedema. To supervise the blood

circulation.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Co-ordinate fire-fighting measures to the fire surroundings.

Suitable extinguishing media

No information available.

Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Highly flammable. In use may form flammable/explosive vapour-air mixture. The vapour of the product is

heavier than air and may accumulate below ground level, in pits, channels and basements in higher

concentration.

Formation of: Carbon monoxide. Carbon dioxide (CO2).

Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.

In case of fire and/or explosion do not breathe fumes.

5.3. Advice for firefighters

Use water spray jet to protect personnel and to cool endangered containers. Suppress gases/vapours/mists

with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or

surface water.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures






Remove all sources of ignition. Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid

contact with skin, eyes and clothes. Use personal protection equipment. Remove persons to safety. In case of

insufficient ventilation, wear suitable respiratory equipment.

Do not allow uncontrolled discharge of product into the environment. Danger of explosion6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the

recovered material as prescribed in the section on waste disposal.

6.3. Methods and material for containment and cleaning up

Safe handling: see section 7

Personal protection equipment: see section 8

Disposal: see section 13

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Vapours can form explosive mixtures

with air.

Advice on safe handling

Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.

Ground and bond container and receiving equipment. Use only antistatically equipped (spark-free) tools.

Advice on protection against fire and explosion

Wash hands thoroughly after handling.

Further information on handling

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed. Keep in a cool, well-ventilated place.

Requirements for storage rooms and vessels

Do not store together with: Oxidizing agent. Pyrophoric or self-heating substances. Keep away from food, drink

and animal feedingstuffs. Protect against direct sunlight.

Hints on joint storage

7.3. Specific end use(s)

Adhesives, sealants

SECTION 8: Exposure controls/personal protection

8.1. Control parameters






Exposure limits (EH40)

Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin

TWA (8 h)1000Ethanol64-17-5 1920 WEL

TWA (8 h)200Ethyl acetate141-78-6 - WEL

STEL (15 min)400 - WEL

TWA (8 h)200Methanol67-56-1 266 WEL

STEL (15 min)250 333 WEL

TWA (8 h)5Methyl acrylate96-33-3 18 WEL


TWA (8 h)400Propan-2-ol67-63-0 999 WEL


TWA (8 h)50Toluene108-88-3 191 WEL


TWA (8 h)500n-Heptane142-82-5 2085 WEL






DNEL/DMEL values

CAS No Substance

DNEL type Exposure route Effect Value

141-78-6 ethyl acetate

Worker DNEL, acute inhalation local 1468 mg/m³

Worker DNEL, acute inhalation systemic 1468 mg/m³

Worker DNEL, long-term inhalation local 734 mg/m³

Worker DNEL, long-term dermal systemic 63 mg/kg bw/day

Worker DNEL, long-term inhalation systemic 734 mg/m³

Consumer DNEL, acute inhalation systemic 734 mg/m³

Consumer DNEL, acute inhalation local 734 mg/m³

Consumer DNEL, long-term dermal systemic 37 mg/kg bw/day

Consumer DNEL, long-term inhalation systemic 367 mg/m³

Consumer DNEL, long-term inhalation local 367 mg/m³

Consumer DNEL, long-term oral systemic 4,5 mg/kg bw/day

67-63-0 propan-2-ol; isopropyl alcohol; isopropanol





Consumer DNEL, long-term oral systemic 26 mg/kg bw/day

142-82-5 heptane; n-heptane






108-87-2 methylcyclohexane






64742-49-0 Naphtha (petroleum), hydrotreated light; < 0,1 % Benzol






67-56-1 methanol






Worker DNEL, acute dermal systemic 40 mg/kg bw/day






Consumer DNEL, acute dermal systemic 8 mg/kg bw/day


Consumer DNEL, acute oral systemic 8 mg/kg bw/day





Consumer DNEL, long-term inhalation local 50 mg/m³

64-17-5 ethanol, ethyl alcohol








108-88-3 toluene








Consumer DNEL, long-term inhalation systemic 56,5 mg/m³


Consumer DNEL, long-term oral systemic 8,13 mg/kg

bw/day

103-11-7 2-ethylhexyl acrylate

Worker DNEL, long-term inhalation local 37,5 mg/m³

Worker DNEL, acute inhalation local 37,5 mg/m³

Worker DNEL, acute dermal local 0,242 mg/cm²

Consumer DNEL, long-term inhalation local 4,5 mg/m³

Consumer DNEL, acute inhalation local 4,5 mg/m³






Consumer DNEL, acute dermal local 0,242 mg/cm²

96-33-3 methyl acrylate; methyl propenoate


Worker DNEL, acute dermal local 0,49 mg/cm²

Consumer DNEL, acute inhalation local 2,1 mg/m³






PNEC values

SubstanceCAS No

Environmental compartment Value


Freshwater 0,26 mg/l

Freshwater (intermittent releases) 1,65 mg/l

Marine water 0,026 mg/l

Freshwater sediment 1,25 mg/kg

Marine sediment 0,125 mg/kg

Secondary poisoning 200 mg/kg

Micro-organisms in sewage treatment plants (STP) 650 mg/l

Soil 0,24 mg/kg



Freshwater (intermittent releases) 140,9 mg/kg


Freshwater sediment 552 mg/kg

Marine sediment 552 mg/kg



Soil 28 mg/kg





Marine water (intermittent releases) 0,0326 mg/l



Micro-organisms in sewage treatment plants (STP) 0,338 mg/l

Soil 0,0237 mg/kg

67-56-1 methanol


Freshwater (intermittent releases) 1540 mg/l


Freshwater sediment 77 mg/kg



Soil 3,18 mg/kg













Soil 0,63 mg/kg

108-88-3 toluene




Marine water (intermittent releases) 0,68 mg/kg




Soil 2,89 mg/kg








Soil 1 mg/kg







Secondary poisoning 0,0011 mg/kg


Soil 1 mg/kg

8.2. Exposure controls

Provide adequate ventilation.

Appropriate engineering controls






Do not breathe gas/fumes/vapour/spray. Remove contaminated, saturated clothing immediately. Draw up and

observe skin protection programme. Wash hands and face before breaks and after work and take a shower if

necessary. When using do not eat or drink.

Protective and hygiene measures

Tightly sealed safety glasses.

Eye/face protection

Wear suitable gloves. When handling with chemical substances, protective gloves must be worn with the

CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be

chosen as a function of the specific working place concentration and quantity of hazardous substances. For

special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned

above together with the supplier of these gloves. (EN 374)

Hand protection

Flame-retardant protective clothing. Wear anti-static footwear and clothing

Skin protection

In case of inadequate ventilation wear respiratory protection.

Respiratory protection

Do not allow to enter into surface water or drains.

Environmental exposure controls

not determined

LiquidPhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

not determinedOdour:

pH-Value: not determined

Changes in the physical state

not determinedMelting point:

77,1 °CInitial boiling point and boiling range:

-7 °CFlash point:

Flammability

not applicableSolid:

not applicableGas:

Vapours can form explosive mixtures with air.

Explosive properties

not determinedLower explosion limits:

not determinedUpper explosion limits:

220 °CIgnition temperature:

Auto-ignition temperature

not applicableSolid:

not applicableGas:

not determinedDecomposition temperature:

Not oxidising.

Oxidizing properties






Vapour pressure: not determined

Density: 0,892 g/cm³

Water solubility: practically insoluble

Solubility in other solvents

not determined

not determinedPartition coefficient:

Viscosity / dynamic: not determined

Viscosity / kinematic: not determined

Flow time: (4 mm) 90 s

Vapour density: not determined

not determinedEvaporation rate:

9.2. Other information

17,76 %Solid content:

Odour threshold: not determined

SECTION 10: Stability and reactivity

10.1. Reactivity

Highly flammable. Ignition hazard.

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Vapours can form explosive mixtures with air.

Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form explosive

mixtures with air. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.

10.4. Conditions to avoid

Oxidizing agents.

10.5. Incompatible materials

In case of fire: Carbon monoxide. Carbon dioxide (CO2).

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity

Based on available data, the classification criteria are not met.






Chemical nameCAS No

SourceSpeciesDoseExposure route Method


RatLD50 6100

mg/kgManufactureroral

RabbitLD50 >18000

mg/kgManufacturerdermal


RatLD50 5840


RabbitLD50 12870


inhalation (4 h) vapour LC50 72,6 mg/l Rat Manufacturer


RatLD50 > 5840


67-56-1 methanol

ATE 100

mg/kgoral

ATE 300

mg/kgdermal

inhalation vapour ATE 3 mg/l

inhalation aerosol ATE 0,5 mg/l


RatLD50 13700


108-88-3 toluene

RatLD50 5580


RabbitLD50 >5000


inhalation (4 h) vapour LC50 28,1 mg/l Rat Manufacturer


RatLD50 4435

mg/kgManufactureroral OECD 401

RabbitLD50 7522



RatLD50 768

mg/kgManufactureroral OECD 401

RabbitLD50 1250

mg/kgManufacturerdermal Draize Test

inhalation (4 h) vapour LC50 6,5 mg/l Rat Manufacturer OECD 403


123-54-6 acetylacetone, pentane-2,4-dione






RatLD50 570


RabbitLD50 790


inhalation vapour ATE 3 mg/l


Irritation and corrosivity

Causes skin irritation.

Causes serious eye irritation.

Sensitising effects

Contains 2-ethylhexyl acrylate, methyl acrylate; methyl propenoate. May produce an allergic reaction.

Carcinogenic/mutagenic/toxic effects for reproduction


STOT-single exposure

May cause drowsiness or dizziness. (ethyl acetate)


STOT-repeated exposure

Aspiration hazard


SECTION 12: Ecological information

12.1. Toxicity

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.






CAS No Chemical name

[h] | [d]Aquatic toxicity Dose SourceSpecies Method

ethyl acetate141-78-6

Acute fish toxicity 96 h ManufacturerLC50 270 mg/l Leuciscus idus

(golden orfe)

DIN 38412-15

Acute algae toxicity 96 h ManufacturerErC50 > 2000

mg/l

Pseudokirchneriella

subcapitata

OECD 201

Acute crustacea toxicity 48 h ManufacturerEC50 164 mg/l Daphnia magna (Big

water flea)

OECD 202

Algea toxicity NOEC 2000

mg/l

4 d Selenastrum

capricornutum

Manufacturer OECD 201

Crustacea toxicity NOEC 2,4 mg/l 21 d Daphnia magna (Big

water flea)


propan-2-ol; isopropyl alcohol; isopropanol67-63-0

Acute fish toxicity 96 h ManufacturerLC50 > 9640-

10000 mg/l

Pimephales promelas

(fathead minnow)

OECD 203

Acute algae toxicity 96 h ManufacturerErC50 > 1000

mg/l

Scenedesmus

subspicatus

OECD 201

Algea toxicity NOEC 1000

mg/l

4 d Scenedesmus

subspicatus


Crustacea toxicity NOEC 30 mg/l 21 d Daphnia magna (Big

water flea)


Acute bacteria toxicity (> 1000 mg/l) 3 h Manufacturer OECD 209

methanol67-56-1

Acute fish toxicity 96 h ManufacturerLC50 > 1000

mg/l

Leuciscus idus

(golden orfe)

DIN 38412 / part

15

Acute crustacea toxicity 48 h ManufacturerEC50 > 10000

mg/l

Daphnia magna (Big

water flea)

Fish toxicity NOEC 7900

mg/l

8 d Oryzias latipes

(Ricefish)


ethanol, ethyl alcohol64-17-5

Acute fish toxicity 96 h ManufacturerLC50 14200

mg/l

Pimephales promelas

(fathead minnow)

Acute crustacea toxicity 48 h ManufacturerEC50 9268 -

14221 mg/l

Daphnia magna OECD 202

Crustacea toxicity NOEC 2 mg/l 10 d Daphnia magna Manufacturer

toluene108-88-3

Acute fish toxicity 96 h ManufacturerLC50 5,5 mg/l Oncorhynchus kisutch OECD 204

Acute algae toxicity 72 h ManufacturerErC50 12 mg/l Selenastrum

capricornutum

OECD 201

Acute crustacea toxicity 48 h ManufacturerEC50 11,5 mg/l Daphnia magna (Big

water flea)

OECD 202

Crustacea toxicity NOEC 0,74

mg/l

7 d Ceriodaphnia spec Manufacturer

2-ethylhexyl acrylate103-11-7

Acute fish toxicity 96 h ManufacturerLC50 1,81

mg/l

Oncorhynchus mykiss

(Rainbow trout)

OECD 203






Acute algae toxicity 72 h ManufacturerErC50 1,71

mg/l

Desmodesmus

subspicatus

OECD 201


water flea)

OECD 202

Algea toxicity NOEC 0,45

mg/l

3 d Scenedesmus

subspicatus



mg/l

21 d Daphnia magna (Big

water flea)

Manufacturer EPA OTS

791.1330

methyl acrylate; methyl propenoate96-33-3

Acute fish toxicity 96 h ManufacturerLC50 3,4 mg/l Oncorhynchus mykiss

(Rainbow trout)

OECD 203

Acute algae toxicity 72 h ManufacturerErC50 3,55

mg/l

Selenastrum

capricornutum

OECD 201


water flea)

OECD 202


mg/l

21 d Daphnia magna (Big

water flea)


acetylacetone, pentane-2,4-dione123-54-6

Acute fish toxicity 96 h ManufacturerLC50 71,7

mg/l

Oncorhynchus mykiss

(Rainbow trout)

OECD 203

Acute crustacea toxicity 48 h ManufacturerEC50 47,6

mg/l

Daphnia magna (Big

water flea)

OECD 202

12.2. Persistence and degradability

Readily biodegradable (according to OECD criteria).






CAS No Chemical name

SourceValueMethod d

Evaluation

ethyl acetate141-78-6

OECD 301D/ EEC 92/69/V, C.4-E 100 % Manufacturer


propan-2-ol; isopropyl alcohol; isopropanol67-63-0

EU Method C.4-E 70-84 % Manufacturer


Naphtha (petroleum), hydrotreated light; < 0,1 % Benzol64742-49-0

OECD 301F/ ISO 9408/ EEC 92/69/V, C.4-D 89 % Manufacturer


methanol67-56-1

OECD 301D/ EEC 92/69/V, C.4-E 82 - 92 % Manufacturer


ethanol, ethyl alcohol64-17-5

OECD 301D 80-85 % 28 Manufacturer


toluene108-88-3

OECD 301D 80 % Manufacturer


2-ethylhexyl acrylate103-11-7

EU Method C.4-D 70-80% Manufacturer


methyl acrylate; methyl propenoate96-33-3

OECD 310 90-100 % Manufacturer


acetylacetone, pentane-2,4-dione123-54-6

OECD 301C 79-88 % Manufacturer


12.3. Bioaccumulative potential

The product has not been tested.

Partition coefficient n-octanol/water

Log PowChemical nameCAS No

141-78-6 0,6ethyl acetate

67-63-0 0,05propan-2-ol; isopropyl alcohol; isopropanol

142-82-5 4,66heptane; n-heptane

108-87-2 3,61methylcyclohexane

64742-49-0 4-5,7Naphtha (petroleum), hydrotreated light; < 0,1 % Benzol

67-56-1 -0,77methanol

64-17-5 -0,31ethanol, ethyl alcohol

108-88-3 2,73toluene

103-11-7 4,64 (25°C)2-ethylhexyl acrylate

96-33-3 0,739methyl acrylate; methyl propenoate

123-54-6 0,4acetylacetone, pentane-2,4-dione






BCF

SourceSpeciesBCFChemical nameCAS No

108-88-3 toluene 90 Manufacturer

96-33-3 methyl acrylate; methyl propenoate 3,16


12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

The product has not been tested.


12.6. Other adverse effects

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

Further information

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste

according to applicable legislation.

Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the

substance itself.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1133

Adhesives14.2. UN proper shipping name:

314.3. Transport hazard class(es):

14.4. Packing group: II

Hazard label: 3

Classification code: F1

Special Provisions: 640D

Limited quantity: 5 L

Excepted quantity: E2

Transport category: 2

33Hazard No:

Tunnel restriction code: D/E

Inland waterways transport (ADN)


14.2. UN proper shipping name: Adhesives

14.3. Transport hazard class(es): 3







Hazard label: 3

F1Classification code:

640DSpecial Provisions:



Marine transport (IMDG)



14.3. Transport hazard class(es): 3


Hazard label: 3

-Special Provisions:



EmS: F-E, S-D

Air transport (ICAO-TI/IATA-DGR)



314.3. Transport hazard class(es):

II14.4. Packing group:

Hazard label: 3

Special Provisions: A3

Limited quantity Passenger: 1 L

Y341Passenger LQ:


353IATA-packing instructions - Passenger:

5 LIATA-max. quantity - Passenger:

364IATA-packing instructions - Cargo:

60 LIATA-max. quantity - Cargo:

14.5. Environmental hazards

yesENVIRONMENTALLY HAZARDOUS:






heptane; n-heptane,methylcyclohexane,Naphtha (Erdöl), mit Wasserstoff

behandelte leichte < 0,1% benzene

Danger releasing substance:

14.6. Special precautions for user

Warning: Combustible liquid.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

Restrictions on use (REACH, annex XVII):

Entry 3: ethyl acetate; heptane; n-heptane; methylcyclohexane; ethanol, ethyl alcohol; 2-ethylhexyl acrylate;

methyl acrylate; methyl propenoate; acetylacetone, pentane-2,4-dione

Entry 40: propan-2-ol; isopropyl alcohol; isopropanol; Ethylacetat; Heptan; n-Heptan; Naphtha (Erdöl), mit

Wasserstoff behandelt, leicht, < 0,1 % Benzol; Methylcyclohexan; Methanol; Toluol; Ethanol (vgl.

Methylalkohol); Methylacrylat

Entry 48: toluene

Entry 69: methanol

85 %2010/75/EU (VOC):

85 %2004/42/EC (VOC):

Information according to 2012/18/EU

(SEVESO III):P5c FLAMMABLE LIQUIDS

E2Additional information:

National regulatory information

Observe restrictions to employment for juvenils according to the 'juvenile

work protection guideline' (94/33/EC).

Employment restrictions:

2 - clearly water contaminatingWater contaminating class (D):

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route

(European Agreement concerning the International Carriage of Dangerous Goods by Road )

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service

LC50: Lethal concentration, 50%

LD50: Lethal dose, 50%






Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]

Classification procedureClassification

Flam. Liq. 2; H225 On basis of test data

Skin Irrit. 2; H315 Calculation method

Eye Irrit. 2; H319 Calculation method

STOT SE 3; H336 Calculation method

Aquatic Chronic 2; H411 Calculation method

H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour.

H301 Toxic if swallowed.

H302 Harmful if swallowed.

H304 May be fatal if swallowed and enters airways.

H311 Toxic in contact with skin.

H312 Harmful in contact with skin.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.

H331 Toxic if inhaled.

H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

H361d Suspected of damaging the unborn child.

H370 Causes damage to organs.

H373 May cause damage to organs through prolonged or repeated exposure.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H411 Toxic to aquatic life with long lasting effects.

H412 Harmful to aquatic life with long lasting effects.

EUH066 Repeated exposure may cause skin dryness or cracking.

EUH208 Contains 2-ethylhexyl acrylate, methyl acrylate; methyl propenoate. May produce an

allergic reaction.

Relevant H and EUH statements (number and full text)

The information is based on present level of our knowledge. It does not, however, give assurances of product

properties and establishes no contract legal rights. The receiver of our product is singulary responsible for

adhering to existing laws and regulations.

Further Information

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety

data sheet.)


Documents

Lanitz Prena Folien Factory GmbH Safety Data Sheet · according to Regulation (EC) No 1907/2006 Safety Data Sheet Lanitz Prena Folien Factory GmbH Orastick® self- adhesive Revision