2
Cooling o across an temperatu pressure, is a pract pressure rates, esp Fig. 5.22 process e separator of the sep pressure from the which dr temperatu gas mixtu Water wi temperatu F If the res hydrate t of natural ga n expansion v ure reductio , the absolute tical method available. It pecially if th 2 is a schema equipment is r, which rem parator, then gas. Some w high-pressu rops the pres ure occurs. D ure, a certain ill also cond ure. Fig. 5.22—Sc ulting tempe temperature Jou as can also b valve. This i n depends o e pressures a d to cool gas t is also a mo e gas rates fl atic drawing s the expansi moves the con n flows throu water and pe ure gas stream sure of the g Depending o n amount of dense to the e chematic dr erature of th at the operat ule Thom be achieved b is a constant n the pressu and the starti and extract h ore practical luctuate. of a typical ion valve or ndensed wat ugh a heat ex rhaps some m. The high- gas to the de on the gas co the mixture equilibrium w rawing of Jo e gas after th ting pressure mson Ex by expandin t enthalpy pr ure ratio of in ing temperat hydrocarbon process than Joule-Thom choke. The ter and any l xchanger, ex hydrocarbon -pressure ga sign pressur omposition a will conden water conten oule-Thoms he heat exch e, hydrates fo xpansion g high press rocess, and th nitial pressur ture, as well n liquids if th n the turbo-e mson expansi high-pressur iquid hydroc xchanging he n will conden s then flows re. Simultane and the press nse and form nt of the gas son expansio hanger or upo orm unless t n sure gas to a he amount o re divided by as the gas c here is a lot expander pro ion process. re gas enters carbons. The eat with the c nse in the he s through the eously, a red sure and tem m a liquid hyd at the final p on equipme on expansion the gas has b lower pressu of the y the final composition. of "free" ocess for low The main s through an e gas stream cooled, low- eat exchange e expansion v duction in mperature of t drocarbon st pressure and ent. n is below th been dehydra ure This w gas inlet s out - er valve, the tream. d he ated.

Joule Thomson Expansion

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Cooling oacross antemperatupressure,is a practpressure rates, esp Fig. 5.22process eseparatorof the seppressure from the which drtemperatugas mixtuWater witemperatu

     

F

If the reshydrate t

of natural gan expansion vure reductio, the absolutetical methodavailable. It

pecially if th

2 is a schemaequipment isr, which remparator, thengas. Some whigh-pressu

rops the presure occurs. Dure, a certainill also condure.

Fig. 5.22—Sc

ulting tempetemperature

Jou

as can also bvalve. This in depends oe pressures a

d to cool gas t is also a moe gas rates fl

atic drawing s the expansi

moves the conn flows throuwater and peure gas streamsure of the gDepending on amount of

dense to the e

chematic dr

erature of that the operat

ule Thom

be achieved bis a constantn the pressuand the startiand extract h

ore practical fluctuate.

of a typical ion valve or ndensed watugh a heat exrhaps some m. The high-gas to the deon the gas cof the mixture equilibrium w

rawing of Jo

e gas after thting pressure

mson Ex

by expandint enthalpy prure ratio of ining temperathydrocarbonprocess than

Joule-Thomchoke. The

ter and any lxchanger, exhydrocarbon-pressure gasign pressur

omposition awill conden

water conten

oule-Thoms

he heat exche, hydrates fo

xpansion

g high pressrocess, and thnitial pressurture, as welln liquids if thn the turbo-e

mson expansihigh-pressuriquid hydroc

xchanging hen will condens then flows

re. Simultaneand the pressnse and formnt of the gas

son expansio

hanger or upoform unless t

n

sure gas to a he amount ore divided by as the gas chere is a lot expander pro

ion process. re gas enterscarbons. Theeat with the cnse in the he

s through theeously, a redsure and tem

m a liquid hydat the final p

on equipme

on expansionthe gas has b

lower pressuof the y the final composition.of "free" ocess for low

The main s through an e gas streamcooled, low-eat exchangee expansion vduction in

mperature of tdrocarbon stpressure and

ent.

n is below thbeen dehydra

ure

This

w gas

inlet s out -er valve,

the tream. d

 

he ated.

To avoid the formation of hydrates in water saturated gas, a chemical hydrate inhibitor is added to the gas stream ahead of the heat exchanger. The chemical usually used to depress the hydrate temperature is ethylene glycol, but diethylene glycol can also be used. Fig. 5.22 shows the flow of the glycol and includes a reconcentration step. Ethylene glycol is usually regenerated to a lean concentration of about 75 or 80% by weight and is circulated at a rate such that the resulting final glycol concentration is sufficient to depress the hydrate forming temperature to about 5°F below the hydrate temperature of the gas at the final pressure. The required lean glycol circulation rate is determined by the Hammerschmidt equation (see the chapter on Phase Behavior of Water/Hydrocarbon Systems in the General Engineering volume of this Handbook) and depends on the water content of the gas, the concentration of the lean glycol, and the necessary hydrate temperature depression. A bypass line around the heat exchanger on the cold gas out of the low temperature separator allows for the control of the degree of cooling of the process gas. To aid the separation between the cold condensate and glycol, a heater can be included in the equipment. After heating, the liquids are flowed into a three-phase separator, where the small amount of gas, the condensate, and the rich glycol are separated. The glycol is then reconcentrated with a conventional reboiler and still and is re-injected into the process gas stream.