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02.00.11 –

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2015

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«ИИИ» ИИИИИИИИИИИИ қ0ҚИИ . ИИИИИ қҚқ.қ3қ.40

- : Қ99004 - , . ., .4Қ/43, .

. . , ., 7/9.

www.spbu.ru.

« » қ0ҚИИ .

, Су Н а Г а

3

: ,

. қ0 , ,

, , , ,

. , ( )

, , , , .

, – ,

, , ,

( , , ).

, , ,

- - .

. , -

- ,

.

;

.

: - ( ) -

;

- NКCХ

- ; -

, , ; - ,

;

- ;

- .

: -

, ,

; , ;

4

- , : (V2) « » ( ), (τ /τ )

(k/b), (W2) (φ ) - (r3 );

τ /τ , . - - -

( - , - ) ;

- , ,

:

,

. , , .

, : - ( (Uef),

(ζSm ζW) ) 0.Қ9 – 1.02 (3.0 – 9.0)

NКCХ (0.001 – 0.Қ5 / ). , ζW ,

; -

, , - - -

( ). , - .

- ,

; - , -

, ; ,

;

- .

;

- , ( ) ( = 0.55 = 0.4қ ; = 0.қ3

= 0.Қ9 ) , . . ;

- , , , . ,

, , – . - .

5

: :

« », , қ6-қ8 қ0Ққ .; 8- -

. Ққ-Қ5 , - , қ0Ққ .; III « » " і" қ0Ққ;

– I : Қ7- - ( , қҚ – қ6 қ0Қ3 .); III

« – », -, қ5-қ6 қ0Қ3 ; IV IЧЭОrЧКЭТШЧКХ МШЧПОrОЧМО ШЧ МШХХШТНКХ МСОmТsЭrв КЧН

physicochemical mechanics. Moscow, 30 June – 05 July, 2013; 9th Saint-Petersburg Young Scientists Conference. November 11-14, 2013 Saint- PОЭОrsЛЮrР; IV

« – », - , Қ4-Қ5 қ0Қ4; – I : Қ8-

- ( ,қ0Қ4 .); V ё « » 6-Қ0 қ0Қ4; Қ0ЭС SКТЧЭ-Petersburg Young Scientists

Conference. November 10-14, 2014 Saint- PОЭОrsЛЮrР; II - « », - , Қ7

қ0Қ4 ; « -қ0Қ5» , қ0Қ5; V

« – », - , қ0-қҚ ; – I : Қ9- - ( , қ0 – қ4 қ0Қ5 .); IV « -қ0Қ5», . 3 – қ0Қ5 ; III

- , . - қ9 – Қ қ0Қ5 ; MШНОrЧ prШЛХОm of polymer Science. 11th International Saint-Petersburg Conference of Young Scientists. November 9-

12, 2015 Saint- PОЭОrsЛЮrР; III - « ». - , Қ0-ҚҚ қ0Қ5 .

: 36 , 3 – ,

, Қ – , , 32 , - .

: , ( ,

, ), , (қҚ3 ), Қ9қ , 7Қ , Қ5 қ

. :

, , .

– . . . . . . . . . . . , ; . . . . . ; . . . . .

, , . . . . .

. :

, , .

6

« » ;

; -

. « »

, .

, .

, N- , ( . [9-14]).

, – ( . Қ).

.Қ. = 0.55 ( ), = 0.4қ ( ).

SОЯОЧMЮХЭТ MОЭХОrTШХОНШ

( ). Қ .

.1. .

№

, ,

, 2/

,

μ / 2 1 0.23

-

-COOH

23.9 1.18

2 0.55 10.0 1.0

3 1.02 5.4 2.68

4 0.19

-NH2

29.0 0.85

5 0.42 13.1 0.78

6 0.45

12.2 0.34

7 0.50 11.0 -

( 7%),

, MКХЯОrЧГОЭКsТгОrNКЧШ-ZS. ( > 0.4 )

( қ0%), ( ~ 0.қ ) ( қ0%). « »

. .

7

III.1 NaCl

NКCХ . , ( = 0.55 , = Қ.0қ

= 0.4қ ) . - .

( = 0.23 = 0.Қ9 ) MКХЯОrЧГОЭКsТгОrNКЧШ-ZS. = 0.55

, , Uef

( .2 қ) , ( .қ Қ).

.2. ζ- ( = 0.55 ) ,

MКХЯОrЧГОЭКsТгОrNКЧШ-ZS (Қ) (қ),

NaCl = 0.0Қ / .

ζ- ; 9.0 ,

(7%). ζ- . ζ- ( АТОrsОmК) :

ζ- = 0.55 = 1.02 . = 0.23 ққ%,

. ζ-

, ( = 0.19 ) 34%, ,

( = 0.42 ) NaCl қ0%. ζ- ( .3, , ) .

.3. ζ- ( = 0.42 ) ( = 0.55 ) CNaCl = 0.001 (1,4); 0.01 (2,5); 0.1 (6); 0.15(3) / .

.3. ζ- ( = 0.19 )(1);( = 0.42 )(қ) ( = 0.23 )(3); ( = 0.55 )(4); ( = 1.02 )(5)

CNaCl = 0.0Қ / .

3 4 5 6 7 8 9

10

20

30

40

50

60

70

80

2

1

В

pH

(1)

(2)

3 4 5 6 7 8 9

-60

-40

-20

0

20

40

60

5

4

3

2

(3) а=0.23 (4) а=0.55 (5) а=1.02

CNaCl=0.01 /

(1) а=0.19 (2) а=0.42

,

pH

1

3 4 5 6 7 8 9

-60

-40

-20

0

20

40

60

а=0.55 (4) CNaCl=0.001 /

(5) CNaCl=0.01 /

(6) CNaCl=0.1 /6

4

5

3

2

,

pH

а=0.42 (1) CNaCl=0.001 /

(2) CNaCl=0.01 /

(3) CNaCl=0.15 /1

8

ζ( ) ( .3. , Қ-3) ζ- ,

. ζ- , .

. ζ-

( .3. ) , ζ-

( Қ,қ). , ζ- , .

III.2.

(3.0 - 9.0) 0.00Қ – 0.Қ5 / .

, - . ,

, m, (n0) (nt): m = n0/nt.

.4. ( = 0.23 ) 3.0 CNaCl = 0.0Қ / ,

(Қ) (n0 = 1.1×107 / 3) (2)

(n0 = 3.6×1011

/ 3)

( = 0.23 ) ( .4), m(t) , (

) . , , ,

.

.

( = 0.55 ) ( .5) ( ).

( = 0.55 ) NКCХ (0.00Қ, 0.0Қ 0.Қ / ) .6. .

. ( = 0.55 )

(Vmax

9

. ( .6. - ).

.5

.6 .5. ( = 0.55 ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NКCХ:

0.00Қ (Қ), 0.0Қ (қ), 0.Қ (3) / (n0 = 3.2×106 / 3) .6.

( = 0.55 ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NaCl: 0.001 (1), 0.01 (2), 0.1 (3) / .

( = 0.55 ) ,

V(h), NКCХ 2.

(W1) (W2).

20 40 60 80

-10

-5

0

5

10

(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.1 /

3

2 1

h,

V/kT

20 40 60 80

-10

-5

0

5

10

3

2 1V/kT

h,

(1) CNaCl=0.001 /

(2) CNaCl=0.01 / (3) CNaCl=0.1 /

20 40 60 80

-10

-5

0

5

10


3 2 1

V/kT

h,

V/kT

20 40 60 80

-10

-5

0

5

10

3 2 1

h,


50 100 150 200 250 3000

1

2

3

4

2

3


m

t,

1

50 100 150 200 250 3000

1

2

3

4


m

t,

50 100 150 200 250 3000

1

2

3

4


m

t,

50 100 150 200 250 3000

1

2

3

4


m

t,

6

10

қ. ( = 0.55 ) , NКCХ 3.0 – 9.0,

, .

2 , NaCl -

, - .

, , m.

.7 mt=300

3.0 - 9.0.

.7. ( = 0.55 )

300

3.0 - 9.0

, - . ,

= 0.55 .

pH CNaCl,

/ Vmа ,

kT

hmax,

-V2,

kT

hmin,

W1 W2 П а а а а у я

3.0

0.001 41.6 2.3 0.03 63.1 >1010

29.3

0.01 8.3 2.4 0.4 16.8 280 3.2

0.1 1.7 1.2 4.0 3.7 1.3 1.0 ( - )

4.0

0.001 287.5 0.9 0.01 112.0 >1010

84.8

0.01 80.3 1.1 0.2 24.5 >1010

5.4

0.1 31.8 0.6 2.7 4.9 >1010

1.0

5.8-

6.2

0.001 644.9 1.0 0.01 126.8 >1010

106.1

0.01 596.8 0.3 0.1 31.3 >1010

7.69

0.1 345.1 0.3 1.8 7.1 >1010

1.2

9.0

0.001 686.9 1.0 0.01 127.5 >1010

106.9

0.01 596.8 0.3 0.1 31.3 >1010

7.7

0.1 345.1 0.3 1.8 7.1 >1010

1.2

11

. , = 0.55

. .

= 0.4қ .8; .

, , 3.0.

( = 0.4қ ) , V(h), NКCХ (0.00Қ, 0.0Қ 0.Қ5 / ) .9.

.8

.9

.8. ( = 0.4қ ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NКCХ: 0.001 (1), 0.01

(қ), 0.Қ5 (3) / (n0 = 2.9×106 / 3) .9.

( = 0.42 ) 3.0 ( ), 4.0 ( ), ( ), 9.0 ( ) NaCl: 0.001 (1), 0.0Қ (қ), 0.Қ5 (3) / .

0 50 100 150 200 250 300

1

2

3

t,

1


m

2

3

0 50 100 150 200 250 300

1

2

3 (1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 /

t,

m

1

2

3

0 50 100 150 200 250 300

1

2

3


t,

1

m

2

3

0 50 100 150 200 250 300

1

2

3

(1) CNaCl=0.001 / (2) CNaCl=0.01 / (3) CNaCl=0.15 / 3

2

1

t,

m

20 40 60

-10

0

10

20

30

40


V/kT

h,

1

2

3

20 40 60

-10

0

10

20

30

40


V/kT

h,

12

3

20 40 60

-10

-5

0

5

10


h,

1

2

3

V/kT

12

. , ,

4.0 0.Қ5 / ( .9. , , 3). 9.0 ,

NaCl = 0.0Қ 0.15 / . , , .

= 0.23 , = 0.55 =1.02 .

, .

, .

, . V(h)

.10. (>30 kT) .

.10.

= 0.қ3 (Қ), = 0.55 (қ), = Қ.0қ (3)

.

,

, , , – , -.

- . ,

, « » .11. 1 0.2 – 1.8

( .ҚҚ, Қ), 0.7 ( .ҚҚ, қ).

= 0.Қ9 > 1.2 ( .Қ2). ,

, .

(τ ) (τ ), , , .

, τ /τ 0.05 0.55

1 , x = ( +С)/a, С - .

10 20 30

-5

0

5

(1) a = 0.23 (2) a= 0.55 (3) a= .02

h,

V/kT

1

2

3

10 200

50

100

150

200

250

300

350

V/kT

h,

13

, τ /τ Қ.3қ Қ.7 .

NКCХ (φ , φ ), –

(0.8 – 4.3)·10-7; - (r3 ) – (5 – 50)·10-15 3, . ,

φ , 9·10-6. (k) (b)

k/b = 2.8·10-16 – 3.9·10-13 3/ .

, Қ:Қ.

.

, ζ- . .13-14 m(t) = 0.55

= 0.42 , = 0.22 = 0.Қ9 . .

.Қ3. ( = 0.55 ) ( = 0.4қ ) . NaCl = 0.00Қ / , (ζ- : -6Қ.8 +қ0.3 ) (1); 4.0 (ζ- : -4Қ.қ + 40.5 ) (2).

.Қ4. ( = 0.23 ) ( = 0.19 ) . NaCl = 0.001 / , (ζ- : -54.0 + 53.3 ) (1); 4.0 (ζ- : -қҚ.7 +54.0 ) (2)

.ҚҚ (Қ)

(2) , 300 , « » . .Ққ ( = 0.Қ9 ) ,

300 , « » .

0 50 100 150 200 250 300

1

2

3

(1) pH (2) pH4.0

m

t, 0 50 100 150 200 250 300

5

10

15

(1) pH (2) pH4.0

m

t,

14

III.4. И И Ц .

, 1-(4- ) , : ζ-

+4қ , -3қ .

, ,

« » . = 0.45 .

( .Қ5), ( NaCl = 0.00Қ / )

.

.15.

(Қ,3)

(4,5) (Қ,4) , (3,5); қ –

.

, , . , ,

(-9 ), .

, - .

III.5. И - .

-

: , ( , .)

. .16 ζ- - .

, ζ- .

.Қ6. ζ- ( = 0.Қ9 )

( Қ,3) ( = 0.қ3 ) ( қ,4)

50 100 150 200 250 3000

1

2

54

3

2

2

1

m

t,

(1) ы, ы ы ФИ Ц (2) ы (3) ы, ы ы ФИ Ц ф . (4) ы, ы ы ФИ Ц (5) ы, ы ы ФИ Ц ф .

0 15 20 25 30

-60

-40

-20

0

20

40

60

4

3

2

1

% .

(1) - а=0.19 (2) - а=0.23 (3) - а=0.19 (4) - а=0.23

15

. ζ- , ,

. ( , ) қ5% .

. .17

( = 0.қ3 ) ( .Қ7. ) ( = 0.Қ9 ) ( .Қ7. ) - : ( Қ-3),

NaCl = 0.001 / . ( 4 .Қ7, , ).

.17. ( = 0.қ3 ) ( ) ( = 0.Қ9 ) ( ) -

( Қ-3) NaCl = 0.00Қ / . 4 .

w = Ққ% . . ,

; .

- , (Uef), (ζSm ζW)

, 0.19 – Қ.0қ (3.0 – 9.0) NКCХ (0.001 – 0.Қ5 / ).

, ζW ,

; -

- - -

( ). , - .

-

, ; - , -

ó , . ,

50 100 150 200 250 300

0

1

2

3

4

4

1

2

m

t,

(1) 12 % . (2) 21 % . (3) 32 % . (4) я 3

50 100 150 200 250 300

0

1

2

3

4

4

1

2

3

m

t,

(1) 12 % . (2) 21 % . (3) 32 % . (4) я

16

;

- ( ) –

(V2), « » ( ), ( / ) (k11/b11); ,

-

.

;

- , ( ) ( = 0.55 = 0.4қ ; = 0.қ3

= 0.Қ9 ) , . . ;

- , . ,

, , – ; - , ( Қ0% . 30% .)

, ; -

. - қ5% . .

, Ққ% .

, , К: 1. К .И., Ш И. , . .// Physicochemical properties of water–alcohol

mixtures. Glass physics and chemistry vol. 38 no. 5 2012, p 460-465.

2. Ш И. ., К .И., . ., Ш . ., . .// . Қ.

. . қ0Қ4. .37. №қ. .қ9-38.

3. Ш И. ., . ., Ш И. ., К . И., . ., Ш . ., . .// қ.

. . қ0Қ4. .39. №қ9. .98-106.

: 1. Ш . ., Ш И. , . . К .И.// -

- , Қ3-қ3 қ0Қ0 . -

, - қ0ҚҚ,, . Қ8-19 2. К .И., Ш И. , . .// - -

, - , 65- . I, - , қ0Қ0, . 109 – 112

3. Ш И. , Ш . ., К .И.// - - , Қ4

- . Қ, қ0Қ0, . 7Қ

http://butlerov.com/stat/users/details.asp?lang=ru&id=2843http://butlerov.com/stat/users/details.asp?lang=ru&id=2868http://butlerov.com/reg/step1/index.asp?type=2&name9=%C1%E5%EB%FF%E5%E2%20%C0%EB%E5%EA%F1%E5%E9%20%CF%E5%F2%F0%EE%E2%E8%F7http://butlerov.com/stat/users/details.asp?lang=ru&id=2873http://butlerov.com/stat/users/details.asp?lang=ru&id=2874

17

4. Ш И. , . . К .И.// , «

– » қ0-қҚ қ0ҚҚ . - , - , қ0ҚҚ, . ҚҚ3-114 5. Ш И. , К .И.//

, Қ5 - . Қ, қ0ҚҚ, 394

6. Ш И. , К .И.// ,

, 300- . . Қ50- . . . қ9

қ0ҚҚ . - , - , қ0ҚҚ, . 74-75 7. К .И., Ш И. , . .// -

- , , 300- . . Қ50-

. . . қ9 қ0ҚҚ . - , - , қ0ҚҚ, . 57-58

8. Ш И. , . . К .И.// - . - , II

« – » . . . Қ4 қ0ҚҚ . - , қ0ҚҚ ., . қ3-24

9. Ш И. ., . . .И. К , . . . И Ш . .// , II

« – » Қ8-Қ9 қ0Ққ . II, - қ0Ққ . .55-56

10. Ш И. ., . ., . ., Ш . ., К .И.// : ,

Қ6 - . қ0Ққ, . қ4қ

11. Ш И. ., . ., . ., Ш . ., К .И.// ( - ) –

. III . . қ9

-Қ қ0Ққ, . 6қ9-630 12. Ш И. ., К .И., . ., . ., Ш . .//

( - - ): .

. . , қ6-қ8 қ0Ққ ., . 3ққ

13. Ш И. ., . ., . ., К .И., Ш . .// ( - - ):

. 8- - . 12-15 , - , қ0Ққ ., . 112

14. Ш И. ., К .И., . ., . ., Ш . .//

. III « » " і" 2012, № 3 (65), . Қ76-180

15. Ш И. ., . ., К .И., Ш . ., . .//

М . – I : Қ7- -

18

( , қҚ – қ6 қ0Қ3 .). . , . , қҚ – қ6 қ0Қ3 ., .Қ66

16. I.Yu. Shirokova, A.P. Belyaev, V.I. Kuchuk, N.N. Shevchenko// Investigation of surface

electrical properties of monodisperse polystyrene latex particles. Book of abstracts IV International

conference on colloidal chemistry and physicochemical mechanics. Moscow, Russia, 30 June – 05 July, 2013, p.416-417.

17. Ш И. , . .,Ш И. ., К .И. . ., Ш . . //

. – I : Қ8- - ( , қҚ – 25 қ0Қ4 .).

. , . , қҚ – 25 қ0Қ4 ., .56. 18. Ш И. ., К .И., . ., Ш . ., . .//

- . V ё

« ». 6-Қ0 қ0Қ4 ./ . – .: , қ0Қ4 ., . Қ94-195.

19. Ш И. ., . ., . ., К .И., . .// p ё

NaCl. V ё « ». 6-Қ0 қ0Қ4 ./ . – .: , қ0Қ4 ., . Қ96-197.

20. Ш И. ., Ш И. . . . . . ., К .И. // - .

V « – », - , 20-қҚ қ0Қ5 . –

- , - , қ0Қ5, . 538-540. 21. Ш И. ., . ., К . И., . ., Ш . .//

. – I : Қ9- -

( , қ0 – 24 қ0Қ5 .). . , . , қ0 – 24 2015 ., .79-80.

22. Ш И. ., . ., . ., . ., Ш И. ., К .И., . ., Ш . ., . .//

. IV « -қ0Қ5», . 3 – қ0Қ5 . .87.

23. Ш И. ., . ., К .И., . ., . ., Ш . .//

. қ0Қ5. III - , . - қ9 – Қ қ0Қ5

. .50-51. 24. Shirokova I.Yu., Kuchuk V.I, Belyaev A.P., Pankova G.A., Shevchenko N.N., Baigildin

V.A., Pavlova I.D., Tereshchenko M.S. Investigation of surface electrical properties and agregatin

stability of monodisperse polystyrene latex particles with surface carboxyl and aminogroups. //

Modern problem of polymer Science. Program and Abstract Book of 11th International Saint-

Petersburg Conference of Young Scientists. November 9-12, 2015 Saint- Petersburg, p.105 25. Ш И. ., . ., . ., И. ., . .,

К .И., . . . III -

« ». - , Қ0-ҚҚ қ0Қ5 . – .: - , қ0Қ5 .50Қ-503

СпециальностьАВТОРЕФЕРАТУченый секретарьIII.1 Электрокинетическое поведение латексов полистирола в растворах NaClIII.2. Агрегативная устойчивость латексов полистирола с поверхностными функциональными группамиIII.4. Исследование электроповерхностных свойств и агарегативной устойчивости частиц ММА с модифицированной ФИТЦ поверхностью.III.5. Исследование электроповерхностных характеристик и агрегативной устойчивости латексов в водно-спиртовой дисперсионной среде.

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