HSE Professionals _ Compressed Gas Safety

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    Occupational Health & Safety Professionals

    HSE Professionals

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    Compressed Gas Safety

    Thousands of products are available which contain gases and mixtures of gases stored under

    pressure in cylinders. Most of these gases are classified as "compressed gases" according to WHMIS

    technical criteria. The Controlled Products Regulations contain details of these criteria.

    There are three major groups of compressed gases stored in cylinders: liquefied, non-liquefied and

    dissolved gases. In each case, the pressure of the gas in the cylinder is commonly given in units of

    kilopascals (kPa) or pounds per square inch gauge (psig).

    Gauge pressure = Total gas pressure inside cylinder - atmospheric pressure

    Atmospheric pressure is normally about 101.4 kPa (14.7 psi). Note that compressed gas cylinder

    with a pressure gauge reading of 0 kPa or 0 psig is not really empty. It still contains gas atatmospheric pressure.

    Liquefied gases are gases which can become liquids at normal temperatures when they are inside

    cylinders under pressure. They exist inside the cylinder in a liquid-vapour balance or equilibrium.

    Initially the cylinder is almost full of liquid, and gas fills the space above the liquid. As gas is

    removed from the cylinder, enough liquid evaporates to replace it, keeping the pressure in the

    cylinder constant. Anhydrous ammonia, chlorine, propane, nitrous oxide and carbon dioxide are

    examples of liquefied gases.

    Non-liquefied gases are also known as compressed, pressurized or permanent gases. These gases do

    not become liquid when they are compressed at normal temperatures, even at very high pressures.

    Common examples of these are oxygen, nitrogen, helium and argon.

    Acetylene is the only common dissolved gas. Acetylene is chemically very unstable. Even at

    atmospheric pressure, acetylene gas can explode. Nevertheless, acetylene is routinely stored and

    used safely in cylinders at high pressures (up to 250 psig at 21C).

    This is possible because acetylene cylinders are fully packed with an inert, porous filler. The filler is

    saturated with acetone or other suitable solvent. When acetylene gas is added to the cylinder, the

    gas dissolves in the acetone. Acetylene in solution is stable.

    What are compressed gases?

    What are the three major groups of compressed gases?

    Liquefied Gases

    Non-Liquefied Gases

    Dissolved Gases

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