18
Health Hazard Evaluation Report 84 -3 J7 -15 31 BI G DRY CREEK PLA NT \-JESTM INIST ER) CO L OP.ADO

Health Hazard Evaluation Report 84-0307-1581 · 2016-11-04 · Health Hazard Evaluation Report No. 84-307, Page 5 . membranes and thus potentially increase the overall exposure. Finally,

  • Upload
    others

  • View
    1

  • Download
    0

Embed Size (px)

Citation preview

  • Health Hazard Evaluation

    Report

    HET.~ 84-3J7-1531BIG DRY CREEK PLANT

    \-JESTMI NI STER) COLOP.ADO

  • PREFACE

    The Hazard Evaluations and Technical Assistance Branch of NIOSH conducts field investigations of possible health hazards in the workplace. T~ese investigations are conducted under the authority of Section 20(a)(£) of the Occupational Safety and Health Act of 1970, 2S U.S.C. 66S(a)(6) which authorizes the Secretary of Health and Human Services, following a written request from any employer or authorized representative of employees, to determine whether any substance normally found in the place of employment has potentially toxic effects in such concentrations as used or found.

    The Hazard Evaluations and Technical Assistance Branch also provides, upon request, medical, nursing, and industrial hygiene technical and consultative assistance (TA) to Federal, state, an-d local agencies; labor; industry and other groups or individuals to control occupational health hazards and to pre~ent related traurea and disease.

    ,/

    Mention of company names or products does not constitute endorsement by the National Institute for Occupational Safety and Health.

  • HETA 84-307-1581 NIOSH INVESTIGATORS: APRIL 1985 Paul Pryor, CIH BIG DRY CREEK PLANT WESTMINISTER, COLORADO

    I. SUMMARY

    In April 1984, the National Institute for Occupational Safety and Health (NIOSH) received a request for a Health Hazard Evaluation from Big Dry Creek Plant, a wastewater treatment facility in Hestminister, Colorado, to evaluate occupational exposures to acrylamide, butyl acetate, glacial. acetic acid, hydrogen sulfide and noise.

    On July 30, 1984 and on November 6 and 7, 1984, a NIOSH investigator conducted an industrial hygiene survey to determine airborne concentrations of the contaminants listed above.

    All air samples were below their respective standards or criteria. Levels for acrylamide (0.3 mg/M3 NIOSH/OSHA); butyl acetate (710 mg/M3 ACGIH/OSHA) and glacial acetic acid (25 mg/M3 ACGIH/OSHA) were all below their analytical detection levels. Hydrogen sulfide levels ranged from non-detectable to 3 parts per million (ppm) which is below the exposure criteria of 10 ppm recommended by the American Conference of Governmental Industrial Hygienists (ACGIH) and 20 ppm required by the Occupational Safety and Health Administration (OSHA).

    During the July and November survey, personal noise levels (range 87.4 to 90.9 dBA) exceeded the NIOSH recommended limit of 85 dBA 8-hour time weighted average (TWA). Noise level measurements taken in areas thought to contribute to the highest exposures in the sludge process building ranged from 85 to 100 dBA.

    On the the basis of the environmental data collected, NIOSH determined that a potential health hazard to those chemicals evaluated did not exist during the study periods. However, it was determined that a potential health hazard did exist from overexposures to noise. Recommendations to further assist in preventing noise exposures are included in this report.

    KEYWORDS: SIC 4959 (Sanitary Services - Sewerage Systems) wastewater treatment, sludge concentrator, air compressor; odor neutralizer, polymer flocculant systems; acrylamide, hydrogen sulfide, butyl acetate, glacial acetic acid and noise.

  • Health Hazard Evaluation Report No. 84-307 , Page 2

    II. INTRODUCTION

    The National Institute for Occupational Safety and Heal th (NIOSH) received a request in March 1984 from a representative of Big Dry Creek Pl ant ~ Westmi ni ster, Co1orado . The request \·Jas to detenni ne if there was a heal th hazard from vari·eus chemicals and noise created during particular , phases 0f the waste treatment process. These chemicals included acr.ylamide, butyl acetate, glacial acetic acid, and hydrogen sulfide. The noise exposures were being generated during various operations and maintenance procedures in the different buildings located at the plant . Environmental surveys were conducted on July 30, 1984 and again on November 6 and 7, 1984. Results from these surveys were given verbally to the requester and the employees as they became

    .. available and fonnally presented in December 1984.

    III. BAf.KGROUND

    Big Dry Creek Plant, located in Westminister, Colorado, is the largest wastewater treatment pl ant in the city of Westmi ni ster and has the capacity to treat over 5.0 million gallons per day. The wastewater to be treated at the plant consists of domestic and industrial wastewater from the Big Dry Creek basin. This treatment plant is referred to as a complete mix-activated sludge facility followed by aerated lagoons for effluent polishing.

    There are 18 full-time employees at the plant, with the majority of these performing a variety of duties. There was only one building, the sludge processing building where two to three employees spend the majority of the day overseeing the activities of the treatment process. Other than the administration and lab building, the other buildings at the treatment facility require only occasional acti vi ti es. Therefore, the concern for potential occupational health problems concentrated primarily in the sludge processing building. The following information is a brief description of the jobs and health concerns NIOSH evaluated :

    The initial health problem that was thought to exist was from the addition of the acrylamide polymer (flocculant/coagulating material) which is used in the sludge processing building prior to sludge concentration. The acrylamide enters the treatment process in either a 1i quid or solid micro bead form. It was the 1ater technique that was thought to be overexposing the operators. In this process, the operator is required to place a 50 pound bag of the flocculant material into a dry feeder hopper, cut the bag open, remove the contents, and dispose of the empty bag. This process was performed approximately 3 times per week and required only 10 to 15 minutes, including clean-up, to comp1ete. The hopper was equipped with an i nterna1 exhaust system \'>'hi ch 1vas activated by opening the hopper 1id. One hundred to 150 feet per minute (fpm) of air was pulled across the face of the hopper without a bag, which increased to 175 to 200 fpm when a.. bag was placed inside the hopper.

  • Health Hazard Evaluation Report No. 84-307, Page 3

    Other health concerns in~1uded overexposures to hydrogen sulfide, butyl acetate~ and glacial acetic acid. The concern for hydrogen sulfide occurred primarily during the initial stages of the start-up of any one of the four sludge concentrators in the sludge processing building. These units stand idle over the weekend and create an anoerobic condition in the sludge remainin~ in the lines.

    The concern for butyl acetate and glacial acetic acid resulted from an odor el imi nati ng agent which is used in the primary sludge pump station. This material is mixed in a large tank by one person. It takes approximately 10 minutes to mix and is very irritating during the pouring and mixing process .

    . The last exposure evaluated was noise , which is a potential problem in most of the buildings reviewed. As previously discussed the only building which is occupied for the majority of the day, other than the administration building is the sludge process building. There are numerous sources of noise in this building (e . g. concentrators, air compressors, flocculators, generators , pumps, etc.). The major source of noise in this building was three air compressors located at various locations in the building.

    In most operations evaluated, the employees were provided and did wear the appropriate personal protective clothing. This included noise protectors {ear muffs), goggles, aprons, gloves and boots. NIOSH/MSHA approved respirators were available; however, their use was optional.

    IV. ENVIRONMENTAL DESIGN AND METHODS

    A variety of sampling techniques were used to evaluate the suspected contaminants in the buildings. Personal samples were taken on the employees in each of the processes evaluated. The following is a description of the sampling techniques used :

    A. Acryl amide

    Acrylamide samples were collected by drawing air through a silica gel tube at approximately 200 cubic centimeters {cc) per minute. These were anal.yzed following the American Cyanamid Company method for acrylamide in air. The limit of detection was 0.5 milligrams (mg) per sample for acrylamide on silica gel tubes.

    B. Acetic Acid

    Acetic acid samples were collected by drawing air through ORB0-53 tubes at approximately 200 cc per minute and these were analyzed by NIOSH Method S-169. The limit of detection was 0.01 mg per sample for acetic acid.

  • Health Hazard Evaluation Report No. 84-307 , Page 4

    C. Butyl Acetate

    Butyl acetate air samples were collected by Grawing air through charcoal tubes at approximately 200 cc per minute . These samples were analyzed by NIOSH Metli'od S-47 with modifications . The 1imit of detection was 0. 01 mg per sample for butyl acetate.

    D. Hydrogen Sulfide

    Hydrogen sulfide was evaluated using a colorimetric gas detection device . These tubes have an accuracy of + 35 percent at one-half the exposure limit and an accuracy of + 2°5 percent at one to five times the exposure limit.

    E. NOISE

    Two personal noise level measurements were taken using Metrosonic noise dosemeters which register on a memory cell the dose or noise 1evel received during the exposure period. The data can then be displayed as a read-out (hard copy) for each minute at the end of the exposure period . The read-out al so describes, at the end of the sampling period the accumulated exposure for each hour and is ~escribed as the average noise exposure for each hour evaluated.

    Noise levels and sound pressure levels were also evaluated around the various buildings using a Bruel &Kjoer @ (B&K) Precision Sound Level Meter equipped with an octave band analyzer .

    V. EVALUATION CRITERIA AND TOXICOLOGY

    A. Environmental

    As a guide to the evaluation of the hazards posed by workplace exposures, NIOSH field staff employ environmental evaluation criteria for assessment of a number of chemical and physical agents . These criteria are intended to suggest levels of exposure to which most \"mrkers may be exposed up to 10 hours per day, 40 hours per week for a working lifetime without experiencing adverse heal th effects. Hov1ever. it is important to note that not all workers will be protected from adverse heal th effects if their exposures are maintained below these levels . A small percentage may experience adverse heal th effects because of i ndi vi dual suscepti.bi l ity , a pre-existing medical condition, and/or a hypersensiti vity (allergy) .

    In addition , sorne hazardous substances may act in combination with other workplace exposures, the general environment, or with medications or personal habits of the \"mrker to produce health effects even if the occupational exposures are controlled at the level set by the evaluation criterion. These c·ombin.ed effects are often not considered in the evaluation criteria. Also, some substances are absorbed by direct contact with the skin and mucous

    http:c�ombin.edhttp:suscepti.bi

  • Health Hazard Evaluation Report No. 84-307, Page 5

    membranes and thus potentially increase the overall exposure.Finally, evaluation . .criteria may change over the years as new information on the toxic effects of an agent become available.

    The primary sources of environmental evaluation criteria for the workplace are: 1) NIOSH Cr~teria Documents and recommendations, 2) the American Conference of Governmental Industrial Hygienists' (ACGIH)' Threshold Limit Values (TLV's), and 3) the U.S. Department of Labor (OSHA) occupationa 1 heal th standards. Often the NIOSH recommendations and ACGIH TLV 's are 1ower than the corresponding OSHA standards. Both NIOSH recommendations and ACGIH TLV's usually are based on more recent information than are the OSHA standards.

    The OSHA standards al so may be required to take into account the feasibility of controlling exposures in various industries where the agents are used; the NIOSH-recommended standards, by contrast, are based solely on concerns relating to the prevention of occupational disease. In evaluating the exposure levels and the recommendations for reducing these levels found in this report, it should be noted that industry is 1egally required to mee_t onlythose levels specified by an OSHA standard.

    A time-weighted average (TWA) exposure refers to the averageairborne concentration of a substance during a normal 8 to 10-hour workday. Some substances have recommended short-term exposure1imi ts or ceiling va1ues which are intended to supp1ement the Tl~A where there are recognized toxic effects from high short-term exposures.

    Except for noise , which is discussed below, the environmental and medical (toxicology) evaluation criteria used for those chemicals investigated in this study are presented in Table l. Recommended environmental limits and/or general information concerning each substance are 1isted, i.e., the source of the recommended 1imits, the present OSHA standard : and a brief description of the primary health effects known to date.

    Noise

    Exposure to high 1 evel s of noise may cause temporary and/or permanent hearing 1 oss. The extent of damage depends primarily upon the intensity of the noise and the duration of the exposure. There is abundant epidemiological and laborator_y evidence that protracted noise exposure above 90 decibels (dBA) causes hearing loss in a portion of the exposed population.

    OSHA 's existing standard for occupational exposure to noise (29 CFR 1910.95) specifies a maximum permissible noise exposure level of 90 dBA for a duration of 8 hours, ~l/ith higher levels allowed for shorter durations. NIOSH, in its Criteria for a Recommended Standard. proposed a limit of 5 dB less than the OSHA standard.

  • Health Hazard Evaluation Report No . 84-307, Page 6

    Time-weighted average noise limits as a function of exposure duration are shown beTow:

    Duration of Exposure Sound Level, dBA (hours/day) NIOSH OSHA

    16 80 8 85 90 4 90 95 2 95 100 1 100 105

    1/2 105 110 1/4 110 115* 1/8 115*

    140 dB** No exposure to continuous noise above 115 dBA. *

    No exposure to impact or impulse noise above 140 dB peak **

    sound pressure level (SPL).

    When workers are exposed to sound levels exceeding the OSHA standard, feasible engineering or administrative controls must be implemented to reduce levels to permissible limits. OSHA has recently issued a hearing conservation amendment to its noise Standard, however, it should be noted that as of this writing it is currently being contested. The amendment states, however, that for workers exposed at or above a TWA of 85 dB, noise exposure monitoring, employee education, and audiometric testing will be required . Review of audiograms have to be made by an audiologist, otolaryngologist or a qualified physician. Employees also must be notified of moni toring results within 21 days. Employee records must be kept by the employer for up to five years after termination of employment. Finally , for those employees exposed to noise levels exceeding 90 dBA for eight hours and/or where audiometric testing results indicate a hearing 1oss, ear protection must be worn.

    Noise, commonly defined as unwanted sound, covers the frequency range of sound which is implicated in harmful effects (4000-6000 Hz). Noise can be classified into many different types, including wide-band noise, narrowband noise, and impulse noise. To describe the spectrum of a noise, the audible frequency range is usually divided into eight frequency bands, each one-octave wide~ and sound pressure level (SPL) measurements are made in each band using a special sound level meter. A wide-band noise is one where the acoustical energy is distributed over a large range of frequencies. Examples of wide-band noise can be found in the \'leaving room of a textile 111ill and in jet aircraft operations.

  • Health Hazard Evaluation Report No. 84-307, Page 7

    Exposure to intense noise causes hearing losses which may be temporary, permanent", or a combination of the two. These impairments are reflected by elevated thresholds of audibility for discrete frequency sounds, with the increase in dB required to hear such sounds being used as a measure of the loss. Temporary hearing losses, also called auditory fatigue, represent threshold losses which are recoverable after a period of time away from the noise . Such 1 osses may occur after only a few minutes of exposure to intense noise. With prolonged and repeated exposures (months or years) to the same noise level, there may be only partial recoveryof the threshold losses, the residual loss being indicative of a developing permanent hearing impairment.

    Temporary hearing impairment has been extensively studied in relation to various conditions of noise exposure. Typical industrial noise exposures produce the 1argest temporary hearing losses at test frequencies of 4,000 and 6,000 Hertz (Hz) .

    The actual pattern of loss depends upon the spectrum of the noise itself. The greatest portion of the loss occurs within th~ first two hours of exposure. Recovery from such losses is greatest within one or two hours after exposure.

    The amount of temporary hearing lass from a given amount of noise varies considerably from individual to individual. For example . losses at a given frequency due to noise intensities of 100 dBA may range from 0 to more than 30 dB.

    Low frequency noise, below 300 Hz, must be considerably more intense than middle or lli gh frequency noise to produce s i gni ficant threshold losses.

    Considerably fewer temporary hearing losses result from intermittent than from continuous noise exposure, even though the total amount of noise exposure is the same in both instances .

    Physiologic reactions to a noise of sudden onset represent a typical startle pattern . There is a rise in blood pressure, an increase in sweating, an increase in heart rate, changes in breathing, and sharp contractions of the muscles over the whole body. These changes are often regarded as an emergency reaction of the body, increasing the effectiveness of any muscular exertion which may be required . However desirable in emergencies, these changes are not desirable for long periods since they could interfere with other necessary activities. Fortunately, these physiologic reactions subside with repeated presentations of the noise.

  • Health Hazard Evaluation Report No. 84-307, Page 8

    For performance on a task to remain unimpaired by noise, man must exert greater effo·rt than would be necessary under qui et conditions. Hhen measures of energy expenditure--for example, oxygen consumption and heart rate--are made during the early stages of work under noisy conditions, they show variations which are indicative of increased effort. Measurements in later stages under conti nu,ed exposure, however, show responses return to their norma 1 1evel.

    VI. RESULTS AND DISCUSSION

    Employee exposures to acryl amide, butyl acetate, glacial acetic acid, hydrogen sulfide and noise \'/ere evaluated. The following are the results of NIOSH's study .

    1. Acryl amide

    Acrylamide samples were all below the limit of detection and therefore;., were considered within the acceptable exposure level of 0.03 mg/M~ (refer to Table 1). This is not surprising since the amount of time spent performing the process was short, as well as the overall face velocity of the exhaust system used in the receiving hopper can be considered excellent (150 to 200 fpm).

    It was noted, however, that some spillage occurred during the transfer of the floccul ant material from the storage bend to the hopper, approximately twenty feet. This was due to insufficient sealing of the bags which should be resolved to eliminate unnecessary exposures to the employee.

    2. Butyl Acetate and Glacial Acetic Acid

    Two personal samples and one area sample were collected for both butyl acetate and glacial acetic acid. Each of the sample results were below their limit of detection , that is 0.01 mg per sample for each of the chemicals tested. This is primarily because of the short amount of time the operator spends preforming this activity.

    3. Hydrogen Sulfide

    Ten samples were taken at 1ocations along the dewatering pl ?tforrn during system start-up. The results ranged from non-detectable to 3 ppm, which is well below the criteria of 10 ppm, and therefore, not a health hazard.

    4. NOISE

    Two personal noise samples were taken on the equi pment operators working in the sludge processing building. An additional ten noise measurements were taken in various locations in th~ shop using a hand held dosemeter. Both of the personal samples exceeded the current NIOSH noise criteria of 85 dBA 8-hour HJA (refer to Table 2).

  • Health Hazard Evaluation Report No. 84-307, Page 9

    The area noise 1evel . measurements ranged from 65 to 100 dBA. The locations with the highest noise levels (87 to 100 dBA) were the work bench and air compressor areas. During the NIOSH investigation, recommendations for reducing the noise levels were made. This included adding. ~ rubber tubing to the pressure relief valve, and once in place, this reduced the noise levels at each of these 1-ocations to less than 83 dBA. The background noise levels in the shop ~1ere then 1owered to 1ess than 82 dBA, which can be considered a significant overall noise reduction.

    VII. CONCLUSIONS

    It was concluded that a health hazard did not exist from exposures to . hydrogen sulfide, butyl acetate, glacial acetic acid, and acrylamide. It should be noted that an improved method or technique should be devised to eliminate spillage when transferring the flocculant material.

    A potential health hazard did exist to the employees from excessive noise levels found in the sludge processing building. This situation was reduced significantly during tile survey period !Jy modifying the pressure relief valve on the air compressors. Modification consisted of placing a hose over the valve and venting it to the outside.

    VI I I. RECOMME~JDATIONS

    In view of the findings of NIOSHls environmental study, as well as personal communications with individuals at the Big Dry Creek Plant, Westminister, Colorado, the following recommendations are made to assist in providing a better work environment for the concerned employees:

    A. Hearing Protection

    Based on the alterations made on the compressors in the sludge processing building, a hearing protection program is not required. However , there was enough information presented to the NIOSH investigator regarding other potential noise problems in the various buildings surveyed at the plant to warrant the following recommendations:

    1. All air compressors should be evaluated to determine if a noise reducing device, similar to that devised for those in the sludge processing building, can be incorporated into other compressors in order to reduce the noise levels in these areas~

    2. Noise monitoring should be performed periodically in all buildings. This is especially necessary during maintenance operations where high noise levels are thought to exist. This will identify areas which even for short periods require hearing protection. All areas determined . to be high noise areas should be posted accordingly.

  • Health Hazard Evaluation Report No. 84-307 , Page 10

    3. To insure that ·full personal protection is being provided during those periods of high noise exposures, the Environmental Protection Agency's tJoise Reduction Ratings (NRR} should be applied when selecting hearing protection. Each protective device (ear plugs or muffs} has a NRR rating which, for that particular type and mo.del. describes what percent of noise attenuation may be obtained.

    It should be noted that these ratings can be misunderstood, that is, suppose muff (X) had good attenuation at all frequencies and excellent attenuation at 4000 Hertz, however , its overall NRR rating is only 25. Another muff (Y) has its overall NRR rating as 30 with great attenuation at all frequencies except at 4000 Hertz where its attenuation is poor. If the greatest intensity noise in the workplace was at 4000 Hertz and the company was using muff Y (tmR = 30) thinking the higher the rating the better the protection, this would be misleading. The hearing protector of choice, in this case, should be muff X (NRR = 25) which had excellent protect_ion at 4000 Hertz.

    4. An educational program to instruct new employees on the hazards of chemical and noise exposures should be implemented. Special attention should be placed on short term maintenance operations where high noise levels are know to be found.

    B. Other Concerns

    1 . The prob 1 em of spi 11 age of the acryl amide fl occul ant material during transferring should be eliminated. This could best be achieved by contacting the manufacture and requesting a more secure bag. An alternative would be placing the bags in a wheel barrel and transferring them to the hopper. This would reduce and/or eliminate spi 11 age and therefore the need for extensive clean-up.

    2. When spillage occurs, the most preferred method of clean-up is vacuuming, which will reduce the potential for airborne exposures, as well as confine the material for easy disposal.

    3. During clean-up, the appropriate personal protective clothing should be worn, including respirators , face shields, or goggles and gloves.

    4. If any of those chemicals evaluated by NIOSH (e.g . , acrylamide, butyl acetate, glacial acetic acid or hydrogen sulfide) come in contact with the skin . the material should Le washed off immediately' or in the case of eye contact, flushed repeatedly for at least fifteen minutes.

  • Health Hazard Evaluation Report No. 84-307, Page 11

    IX. REFERENCES

    1. National Institute for Occupational Safety and Health. The Industrial Environment - Its Evaluation and Control, {NIOSH) 1973~.~

    2. Industrial Hygiene and Tox~icology, second edition, Frank Patty (editor), Interscience Publishers, 1981.

    3. Encyclopedia of Occupational Heal th and Safety, International Labor Office, McGraw-Hill Book Company, New York.

    4. U.S. Department of Health, Education , and Welfare. Occupational Diseases, A Guide to Their Recognition, Public Health Service Publication {NIOSH) No. 77-181.

    5. Handbook of Noise Measurement, seventh edition, Arnold Peterson and Ervin Gross, 1974.

    6. Proctor, N.H. and Hughes, J.P . , Chemical Hazards of the Workplace, J.P. Lippincott Company, Philadelphia, 1978.

    7. National Institute for Occupational Safety and Health/Occupational Safety anci Heal th Administration. Occupational Safety and Heal th Guidelines for Chemical Hazards . NIOSH/Publication No. 81-123, Jan. 1981.

    8 American Conference of Governmental Industrial Hygienists , Documentation of the Threshould Limit Values for Substances in the Workroom Air, Updated periodically.

    9. American Conference of Governmental Industrial Hygienists, Threshold Limit Values {TLV 1 s) for Chemical Substances and Physical Agents in the Workroom Environment, 1983-84.

  • Health Hazard Evaluation Report No. 84-307, Page 12

    X. AUTHORSHIP AIJD ACKNOWLEDGMENTS

    Report Prepareci By: Paul Pryor , M. S , CIH

    Industrial Hygienist

    NIOSH - Region VIII

    Uenver , Colorado

    Originating Office: Hazard Evaluation and Technical Assistance Branch (HETAB)

    Division of Surveillance , Hazard Evaluations , and Field Studies (DSHEFS)

    NIOSH - Cincinnati, Ohio

    _.. Rep0rt Typed By: Muriel Mudge

    Secretary

    NIOSH - Region VIII

    Denver, Colorado

    NIOSH is thankful to the emp1 oyees at Big Dry Creek treatment p 1 ant for theicooperation and assistance with this Heal th Hazard Evaluation. The informatiogathered from this study will not only ass i st in maintaining the health andsafety of those persons working here, but also other facilities that performsimilar operations.

    XI. DISTRIBUTION AND AVAILABILITY

    Copies of this report are currently avai 1 able upon request from NIOSH , Di vision of Standard Development and Technology Transfer, Information Resources and Dissemination Section, 4676 Columbia Parkway , Cincinnati. Ohio 45226. After 90 days the report will be available through the National Technical Information Service (NTIS) , Springfield, Virginia. Information regarding its availability through NTIS can be obtained from NIOSH , Publications Office , at the Cincinnati address.

    Copies of this report have ueen sent to:

    1. Big Dry Creek Plant , Westminister , Col orado 2. U.S. Department of Labor/OSHA - Region VIII. 3. NIOSH - Region VIII. 4. Colorado Department of Health. 5. State Designated Agency.

    For the pt!rpose of informing affected employees , a copy of this report shall be posted in a prominent place accessible to the employees for a period cf 30 calendar days.

    r n

  • Health Hazard Evaluation Report No. 84-307, Page 13

    TABLE l

    EVALUATION CRITERIA AND TOXICOLOGY

    Big Dry Creek Plant Westminister, Colorado

    Recommended Environmental Reference OSHA

    Substance LimitA CriteriaB Primary Heal th Effects Standard

    Acrylamide 0.3 mg/M3 NIOSH Irritation eyes and skin; ataxia; numbness in limbs 0. 03 mg/M3 10 hour TWA and weak muscles; sweating hands; fatigue; and

    lethargy.

    Butyl Acetate 710 mg/M3 ACGIH Irritation of eyes and skin; headaches; drowsiness; 710 mg/M3 and upper respiratory irritation.

    Acetic Acid 25 mg/M3 ACGIH Eye, nose and throat irritation; edema; chrortic 25 mg/M3 bronchitis; skin sensitive; dental erosion; and hyper keratosi s

    Hydrogen Sulfide l O ppm ACGIH Irritation of the eyes and respiratory system; 20 ppm headaches, fatigue, dizziness and insomnia; apnea, convulsions and coma.

    A All air concentrations are expressed as time-weighted average (HIA) exposures for up to a 10 hour workday 1mless designated (C) for Ceiling which should not be exceeded even instantaneously.

    B Crite1"i a are 1evel s which are recommended by NIOSH or ACGIH = American Conference of Governmental Industrial Hygienists. These are only recommendations and not standards as designated by OSHA.

    ppm = Parts per million parts of air

    mg/M3 =Approximate milligrams of substance per cubic meter of air.

  • Health Hazard Evaluation Report No. 84-307 , Page 14

    TABLE 2

    Personal Noise Dosimeter Levels

    Big Dry Creek Plant

    Westminister, Colorado

    November 1984

    Job/Task Description Sampling Time

    (hours) 8-Hour HJA Noise (dBA)

    Equipment Operator Equipment Operator

    6 6

    90 9 87.4

    EVALUATION CRITERIA NIOSH 8-hour TWA OSHA 8-hnur TWA OSHA 8-hour TWA*

    85 dBA 90 dBA 85 dBA

    * OSHA Revised employers to exceed 85 dBA.

    Hearing institute

    Conservation a hearing

    Regulation, if mandated, protection program if TWA

    will ncise

    require levels

  • DE'?ARTMENT OF HEALTH AND HUMAN SERVICES PL.auc HEALTH SERVICE

    CENTERS FOR DISEASE CONTROL

    NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY ANO HEALTH

    ROBERT A. TAFT LABORATORIES

    4S76 COLUMBIA PARKWAY, CINCINNATI, OHIO 45226

    OFFICIAL BUSINESS Third Class Mail POSTAGE ANO FEES PAID

    PENALTY FOR PRIVATE USE. $300 U.S. DEPARTMENT OF HHS HHS396

  • Health Hazard Evaluation Report