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    054402 DESIGN AND ANALYSISLECTURE TWELVE

    Daniel R. Lewin, Technion1

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin1

    054402 Design and Analysis

    LECTURE 12: HAZARD AND OPERABILITY(HAZOP) STUDIES

    Daniel R. Lewin

    Department of Chemical EngineeringTechnion, Haifa, Israel

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin2

    ! Provide motivation for performing a HAZOP/HAZAN studyon a process

    ! This lecture provides instruction on how to carry out aHAZOP analysis" HAZOP is a technique for identifying hazards without waiting

    for an accident to occur.! Next lecture, we will learn about the tools and methods

    used in a HAZAN analysis" HAZAN is a technique for estimating the probability and

    consequences of a hazard.

    OUTLINE

     Sources: T. Kletz, HAZOP and HAZAN , 3rd Ed., IChemE (1992) T. Kletz, Learning from Accidents in Industry ,

    Butterworths (1988) T. Kletz, What Went Wrong? , 2nd Ed., Gulf Publishing Co. (1988)

     This lecture, and next week’s lecture:

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

    Daniel R. Lewin, Technion2

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin3

    FEED SECTION OF PROPOSED OD PLANT 

    Restriction plateROPTemperature rec.TR

    Relief flareRFPress. controllerPICFlow indicatorFI

    Flow controllerFRCLevel controllerLICPressure guagePG

     FI

    #What can go wrong ?

    $ What will be the consequences?

    % How often will it occur ?

    & How can it be prevented ?

    ' Is the cost of prevention justified ?

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin4

    FROM “AN ATLAS OF SAFETY THINKING”

    The first and most importantstage in any hazard study is to

    identify the most importantthings that can go wrong andproduce accidents or operatingproblems.

     1. Identify what can go wrong.

    The ideas expressed in this section are best summarized in thefollowing frames.

    A HAZOP is a systematic procedure to analyze the hazardsassociated with each process pipeline, applying the followingguide words: NONE, MORE OF, LESS OF, REVERSE, OTHERTHAN, PART OF, MORE THAN.

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

    Daniel R. Lewin, Technion3

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin5

    FROM “AN ATLAS OF SAFETY THINKING”

    We need to know how often thehazard is likely to occur (HAZAN).

     3. How often will it occur?

     2. How big will the consequences be?

    We need to know theconsequences to employees,members of the public, plant andprofits, now and in the long term.

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin6

    FROM “AN ATLAS OF SAFETY THINKING”

    We should compare the risk(that is, the probability timesthe consequence) with generallyaccepted codes and standards orwith the other risks around us.

     5. What should we do?

     4. Prevention.

    How can we prevent the accidentoccurring, or make it lessprobable or protect people fromthe consequences?

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

    Daniel R. Lewin, Technion4

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin7

    FROM “AN ATLAS OF SAFETY THINKING”

    Perhaps our method of

    prevention has disadvantages,and better methods can besuggested. We should answerthis question before a table ismade and a glass ordered.

     6. Is it worth the cost?

    We should also compare the costof prevention with the cost ofthe accident to see if theremedy is ‘reasonably practical’or we should look for a cheapersolution.

     7. Prevention 2.

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin8

    DEVIATIONS GENERATED BY GUIDE WORDS

    PART OF

    OTHER THAN

    MORE THAN

    REVERSE

    LESS OF

    MORE OF

    NONE

    DeviationsGuide Word

    No forward flow when there should be: i.e. no flow

    More of any relevant physical property than thereshould be: e.g. higher F, higher T, higher P.

    Less of any relevant physical property than thereshould be: e.g. lower F, lower T, lower P.

    Composition of system different than it shouldbe: e.g. ratio different, or component missing.

    More components present than there should be:e.g. extra phase present, or impurities.

    What else can happen apart from NOC: e.g. start-up, shut-down, failure of services…

    Flow in the reverse direction than that expected

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

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    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin11

    HAZOP PROCEDURE

    Note: In addition to identifying each hazard, it is importantto also estimate its severity, on a scale of 1 (high) to 4(low), and likelihood, on a scale of 1 (high) to 4 (low).

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin12

    HAZOP PROCEDURE - SEVERITY

    Medium HighMedium High – Injury hazard or hazard leading to loss of

    1-6 months production or loss between $1-10M

    2

    LowLow – No injury hazard or hazard leading to loss of 6 months production or loss greater than $10M

    1

    SignificanceSeverity

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

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    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin13

    HAZOP PROCEDURE - LIKELIHOOD

    Medium HighMedium High – Hazard expected several times in theplant life.

    2

    LowLow – Hazard not expected at all in the plant life.4

    Medium LowMedium Low – Hazard not expected more than once inthe plant life.

    3

    HighHigh – Hazard expected more than 1/year1

    SignificanceLikelihood

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin14

    HAZOP PROCEDURE – RISK RANKING

    Almost acceptable risk levelAlmost acceptable risk level.. Acceptable if suitably controlledby management. Should check that suitable procedures and/orcontrol systems are in place.

    B

    Unacceptable risk level.Unacceptable risk level. Must be reduced to level B at themost by engineering or management control.

    D

    Undesirable risk levelUndesirable risk level.. Must be reduced to level B at the mostby engineering or management control.

    C

    Acceptable risk level.A

    SignificanceRanking

    AAAB4

    AABC3

    ABCD2

    ACDD1

    4321

     Severity

     Likelihood

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

    Daniel R. Lewin, Technion8

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin15

    DETAIL OF THE PROPOSED OD PLANT 

     FI

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin16

    HAZOP STUDY ON PROPOSED OD PLANT 

    B

    B

    B

    R

    2

    2

    2

    L

    3

    3

    3

    S

    (c) Installkickback on J1pumps.(d) Check designon J1 pumpstrainers.

    Covered by (b).

    (a) Ensurecommunicationwith intermediatestorage operator.

    (b) Install low

    level alarm onsettling tank LIC.

    Action Required

    As for (1). J1pumpoverheats.

    As for (1).

    Loss of feedto reactor.Polymerformed inHEX with noflow.

    Consequences

    NoFlow

    Dev’n

    (3) Lineblockage,isolation valveclosed inerror, or LCVfails shut.

    (2) J1 pumpfails.

    (1) No HCavailable atintermediatestorage.

    NONE

    PossibleCauses

    GuideWord

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

    Daniel R. Lewin, Technion9

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin17

    HAZOP STUDY ON PROPOSED OD PLANT 

    C

    C

    R

    2

    2

    L

    2

    2

    S

    Moreflow

    MOREOF

    (f) Install highlevel alarm on LICand check sizing ofrelief oppositeliquid overfilling.

    (g) Institutelocking offprocedure for LCVbypass if not in use.

    Covered by (b).

    (e) Instituteregular patrollingand inspection oftransfer line.

    Action Required

    Settling tankoverfills. Dangerof spillage ofHC. Fire hazard.

    As for (1).HC dischargedinto areaadjacent topublic highway.

    Consequences

    Noflow

    Dev’n

    (5) LCVfails openor LCVbypassopen in

    error.

    (4) Linefracture.

    NONE

    PossibleCauses

    GuideWord

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin18

    HAZOP STUDY ON PROPOSED OD PLANT 

    D

    B

    R

    1

    2

    L

    2

    3

    S

    Morepress-ure

    (j) Covered by(c) except whenkickback blockedor isolated.Check line andFI. Install a PGupstream of LCVand anindependent PGon settling tank.

    (h) Extend J2pump suction lineto 12” abovetank base.

    Action Required

    Transfer linesubject to fullpump deliveryor surgepressure.Possibility offracture andrelease of HC.

    Incompleteseparation ofwater phase intank, leadingto problems inreactor

    section.

    Consequences

    Moreflow

    Dev’n

    (6) Isolationvalve closedin error orLCV closeswith J1pumping.

    (5) LCV failsopen or LCVbypass openin error.

    MOREOF

    PossibleCauses

    GuideWord

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

    Daniel R. Lewin, Technion10

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin19

    HAZOP STUDY ON PROPOSED OD PLANT 

    C

    C

    R

    2

    2

    L

    2

    2

    S

    Moretemp.

    (l) Checkwhether thereis adequate

    warning of hightemperature atintermediatestorage. If not,install.

    (k) Installthermalexpansion reliefon valve section.

    Action Required

    High pressurein transferline and

    settling tank.

    Line fractureand possiblerelease of HC.

    Consequences

    Morepressure

    Dev’n

    (8) Highintermediatestorage

    temperature.

    (7) Thermalexpansion inisolatedvalve sectiondue to fireor strongsunlight.

    MOREOF

    PossibleCauses

    GuideWord

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin20

    HAZOP STUDY ON PROPOSED OD PLANT 

    Not applicable (n/a)REVERSE

    A

    C

    R

    1

    2

    L

    4

    2

    S

    Lesstemp.

    (m) Lag watersump down todrain valve andsteam tracevalve and drainlinedownstream.

    Covered by (e)and the checksin (j).

    Action Required

    Water sumpand drain linefreeze up.

    Material lossadjacent topublic highway.

    Consequences

    Lessflow

    Dev’n

    (10) Winterconditions.

    (9) Leakingflange ofvalved stubnot blankedand leaking.

    LESS OF

    PossibleCauses

    GuideWord

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

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    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin21

    HAZOP STUDY ON PROPOSED OD PLANT 

    4

    4

    S

    1

    1

    L

    A

    A

    R

    High con-centration

    of loweralkanes oralkenes instream.

    (p) Check thatsettling tank

    and piping,including reliefvalve, will copewith suddeninflow of morevolatile HCs.

    (n) Arrangefor frequentdraining off ofwater fromintermediatestorage.Install highinterface levelalarm on sump.

    ActionRequired

    Higher systempressure.

    Water sumpfills up morequickly. Morechance ofwater phasepassing toreactionsection.

    Consequences

    Highwaterconcent-ration instream.

    Dev’n

    (12) Disturb-ance on

    distillationcolumnsimmediatelyupstream ofintermediatestorage tank.

    (11) Highwater level inintermediatestorage tank.

    PARTOF

    PossibleCauses

    GuideWord

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin22

    HAZOP STUDY ON PROPOSED OD PLANT 

    A

    A

    R

    1

    1

    L

    4

    4

    S

    OTHER Mainten-ance.

    (r) Installlow-pointdrain and N2purge pointdownstreamof LCV. AlsoN2 vent onsettling tank.

    (q) Checksuitability ofmaterials ofconstruction.

    ActionRequired

    Line cannot becompletelydrained orpurged.

    Water sumpfills up morequickly. Morechance ofwater phasepassing to

    reactionsection.

    Consequences

    Organicacidspresent

    Dev’n

    (14) Equip-mentfailure,flange leak,etc.

    (13) As for(12).

    MORETHAN

    PossibleCauses

    GuideWord

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

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    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin23

    ! PROJECT or DESIGN ENGINEER – Often a MechE. Responsiblefor keeping costs within target. He/she will want to minimizechanges, but at the same time wants to find out now rather thanlater if there are any unknown hazards or operating problems.

    ! PROCESS ENGINEER – Usually a ChemE. The person who drewdeveloped the flowsheet.

    ! COMMISSIONING MANAGER – Usually a ChemE. He/she willhave to start-up and operate the plant, and will be in favor of anychanges that will make life easier.

    ! INSTRUMENT DESIGN ENGINEER – A modern plant containssophisticated control and trip systems, and HAZOPs often result

    in even more instrumentation.! RESEARCH CHEMIST – If new chemistry is involved.! INDEPENDENT CHAIRMAN – An expert in the HAZOP technique,

    but not the plant. If he/she is not a represntative of the plantsafety department, one needs to be present.

    WHO CARRIES OUT A HAZOP ? A HAZOP team for a new process consists of the following members:

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin24

    TRACKING ACTION ON HAZOP

    CMInstitute regular patrolling andinspection of transfer line.

    e

    IDEInstall high level alarm on LIC.More flowf

    DECheck design on J1 pumpstrainers.

    d

    b

    c

    Follow-upreviewcomments

    DE

    IDE

    CM

    Actionby

    No flow

    OperatingDeviation

    Install kickback on J1 pumps.

    Install low level alarm onsettling tank.

    Ensure communication withintermediate storage operator.

    a

    Action notes and queriesRef.No.

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

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    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin25

    CHECK OUT THIS “BIT OF PLANT”

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin26

    RLSAction RequiredConsequencesDev’n Possible CausesGuideWord

    HAZOP STUDY ON “BIT OF PLANT”

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    054402 DESIGN AND ANALYSISLECTURE TWELVE

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    CHECK OUT THIS “BIT OF PLANT”

    12 - HAZOPDESIGN AND ANALYSIS - (c) Daniel R. Lewin28

    " Applying the guide words systematically to identifythe most imporant hazards affecting each line in theprocess.

    " Categorizing each hazard according to its severity,likelyhood and cost.

    " Realizing that a HAZOP analysis is an ongoing processthat needs to be documented and followed up.

    SUMMARY

    On completing this week’s materials, you should be able tocarry out a HAZOP analysis:

    Next lecture, we will learn about the tools and methods usedin a HAZAN analysis, which is a technique for estimating theprobability and consequences of a hazard.