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New material for new era
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7/21/2019 Graphene Fibre
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Graphene Fiber Unique Material with Unique Prope
201
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Intoduction
• "Graphene" is a combination of graphite and the su! ene#
%anns&eter 'oehm(
• ) 2* mono+a$er of carbon atoms pac,ed into a hone$comb +
• The credit of Graphene in-ention goes to )ndre Geim a/o-ose+o- at The ni-ersit$ of anchester e!tracted sing+ecr$sta++ites from bu+, graphite(
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ontd((
This materia+ gains immense recognition because of its fas
properties:
• %igh e+ectron mobi+it$1#2 high therma+ conducti-it$
• 3!traordinar$ e+asticit$ and stiness
• Strength 00 times that of stee+
• %igh+$ corrosion resistance
• Sca+ab+e
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Graphite
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• ain constituent of graphene is carbon
• )nd its e!tracted from Graphite
• 1mm of Graphite 6 i++ion +a$ers of Graphene
• arbon atom in Graphene are distributed in %one$ oformation
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*ierent ethods of e!traction has been suggested for e!traGraphene from Graphite
• hemica+ *eposition ethod
• 3!fo+iation of mined graphite to produce a,es
• Thermoengineering method
• Graphite o!ide reduction
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Graphene sing+e+a$er T3
Graphene mu+t+a$er T3
Source )S materia+s website9&roduct speci:cation;
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Graphene o!ide S3 '$ )S<educed Graphene o!ide S3
Graphenea
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)/=)T<>/G ?= G<)&%3/3=>'3<
• @et spinning
• hemica+ -apor deposition
• =rom a+igned /T sheets to graphene $arns
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@3T S&>//>/G ethod 1
Graphene o!idedispersion
G+ass s$ringe
&ressure61(5&a
%e+d b$ /2
3!trusionoagu+ation
/a?%Aethano+
Ta,e up @ashing withethano+
These Gcon-ered:bre b$ with %$d80Cc for
washing
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S3 of chemica++$ reduced:ber
G? :ber bound n a Teondrum
S3 of G? :ber
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3T%?* 24
>n this method the procedure is same as the pre-iouse!pect
oncentration of G? used is 10mgAm+
oagu+ation bath of he!adec$+trimeth$+ammonium bromide 9T)'; at 0(5mgAm+
@et spinning of G? :ber withdoub+e Det pump
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. , . , . , .
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3==3T ?= /?ZZE3 S>Z3 )/* ?/3/T<)?/ =>'<3 *>)3T3<
a b c d
=iber dia for dierent noFF+e siFes 9a; 0(11 9b;
0(29c; 0(41 and 9d; 0( mm
a
c
=iber dia for dierent concentrst
10 and 9d; 22 mgA
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?*>=>3* @3T S&>//>/G5"G
Graphene o!ide
ethano+
ethan
o+
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/3.E)3E>.3 G<)&%3/3 ?H>*3 %=
The inner capi++ar$ of the spinneret is pumped with air
the .+Amethano+ so+ution(
)t a set ow rate of 1# 1(5# and 2 mEAmin
nG%=s were obtained b$ therma+ or chemica+ reductio
%=s
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%o++ow G? :bre
Sing+e microsphere of the nG?%=
'
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%3>)E I)&?< *3&?S>T>?/ 3T%?*
)rA%2Aethan
e
400A100A0m+Amin
Graphene depositedo-er copper foi+
3tching of grb$ 0(5 =
<insing graphene :deioniFed w
9oats
=i+m in ethano+so+ution
9starts sin,ing;
*raw out Graphene:bre with the he+p
of tweeFers
)t 1000Ccfor 5 min
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=+oatingGraphene :+m
in water
Sin,ingGraphene :+m
in ethano+
Graphene :ber
drawn out
T
G
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3%)/>)E &<?&3<T>3S ?= G<)&%3/3 =
FibreTensile
strength
Graphene?!ide
145&a
Graphene 182&a
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)&&E>)T>?/S
• Graphene :bre ha-e fo++owing
uniJue properties +i,e te!ti+e
• echanica+ e!ibi+it$
• Eight weight
• 3as$ to functiona+iFe
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G= actuators
•
3!ce++ent humidit$ responsi-e bendingAunbendinabi+it$
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*$esensitiFed photo-o+taic wire prepared b$using a grapheneA&t composite :ber as thecounter e+ectrode
G= ')S3* S&3< )&)>T?<
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G= ')S3* S&3< )&)>T?<
• >t is used ine+ectrochemica+
capacitor(• %igh surface area andhigh e+ectroconducti-it$
crosssectiona+ -iew of a G=L*G shographene :ber 9G=; surrounded b$ stasheets( Sca+e bars 100mm(
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S?E>* &%)S3 ><? 3HT<)T>?/ S?<
•&resent+$ a-ai+ab+e materia+s ha-e some
drawbac, +i,e
• %igh cost#
• Therma+# mechanica+ andAor chemica+
instabi+it$
• >nsucient se+ecti-it$
• =ragi+it$ of the fusedsi+ica substrate# and
• Eimited range of po+arit$ and reuse times
Graphene o$ers folload%antages
• %igh ecienc$
• Superior therma+ and mec
stabi+it$
• 3!ce++ent durabi+it$ 9M10
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T&'() Y*U