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Page 1: GENERAL PURPOSE LACQUER THINNERimages.myautoproducts.com/images/Product_Media/...Product nameGENERAL PURPOSE LACQUER THINNER Product codeFPR5000 Date of issue7 December 2010Version6.01
Page 2: GENERAL PURPOSE LACQUER THINNERimages.myautoproducts.com/images/Product_Media/...Product nameGENERAL PURPOSE LACQUER THINNER Product codeFPR5000 Date of issue7 December 2010Version6.01

GENERAL PURPOSE LACQUER THINNERProduct name

6.01Product code Date of issue VersionFPR5000 7 December 2010

Composition/information on ingredients3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.

Methyl acetate 79-20-9 30 - 60Methanol 67-56-1 10 - 30Toluene 108-88-3 10 - 30Ligroine 8032-32-4 7 - 13Tetrahydrofuran 109-99-9 1 - 5Ethanol 64-17-5 0.1 - 1

Name CAS number %

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.

Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open. Seek immediate medical attention.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognized skin cleanser. Do NOT use solvents or thinners.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.

If swallowed, seek medical advice immediately and show this container or label.Keep person warm and at rest. Do not induce vomiting.

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of thisproduct, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have MaterialSafety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measures

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.

Flammable liquid. In a fire or if heated, a pressure increase will occur and the containermay burst, with the risk of a subsequent explosion. Vapors may accumulate in low orconfined areas or travel a considerable distance to a source of ignition and flash back.Runoff to sewer may create fire or explosion hazard.

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Special exposure hazards :

Do not use water jet.

Suitable :

Not suitable :

Hazardous combustionproducts

: Decomposition products may include the following materials:carbon oxides

Flammability of the product :

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Do not breathe vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see Section 8).

Environmental precautions

Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains andsewers. Inform the relevant authorities if the product has caused environmental pollution(sewers, waterways, soil or air).

Personal precautions :

6 .

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GENERAL PURPOSE LACQUER THINNERProduct name

6.01Product code Date of issue VersionFPR5000 7 December 2010

Accidental release measures6 .Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Use spark-proof tools and explosion-proof equipment. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place incontainer for disposal according to local regulations (see section 13). Dispose of via alicensed waste disposal contractor. Contaminated absorbent material may pose thesame hazard as the spilled product. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble or absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor.

Small spill :

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination. Do not store above thefollowing temperature: 120F / 49C.

Put on appropriate personal protective equipment (see Section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Do not breathe vapor or mist. Do not swallow. Do not get in eyes or on skinor clothing. Use only with adequate ventilation. Wear appropriate respirator whenventilation is inadequate. Do not enter storage areas and confined spaces unlessadequately ventilated. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Store and use awayfrom heat, sparks, open flame or any other ignition source. Use explosion-proofelectrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. Vapors are heavier thanair and may spread along floors. To avoid fire or explosion, dissipate static electricityduring transfer by grounding and bonding containers and equipment before transferringmaterial. Empty containers retain product residue and can be hazardous. Do not reusecontainer. If this material is part of a multiple component system, read the MaterialSafety Data Sheet(s) for the other component or components before blending as theresulting mixture may have the hazards of all of its parts.

Handling and storageHandling

Storage

:

:

7 .

Exposure controls/personal protection8 .

Methyl acetate TWA 200 ppm 200 ppm 200 ppm 200 ppm Notestablished

STEL 250 ppm Notestablished

250 ppm 250 ppm Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________Methanol TWA 200 ppm S 200 ppm 200 ppm S 200 ppm S Not

establishedSTEL 250 ppm S Not

established250 ppm S 250 ppm S Not

established____________________________ ___________ ___________ ___________ ___________ ___________ ___________Toluene TWA 20 ppm 200 ppm Z 20 ppm 50 ppm S Not

establishedSTEL Not

established500 ppm Z A300 ppm Z C

Notestablished

Notestablished

Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

Name Result ACGIH OSHA Ontario Mexico PPG

Page: 3/8United States - Canada - Mexico

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GENERAL PURPOSE LACQUER THINNERProduct name

6.01Product code Date of issue VersionFPR5000 7 December 2010

Exposure controls/personal protection8 .

Acceptable Maximum PeakA =ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

Potential skin absorptionSSR = Respiratory sensitization

= Skin sensitizationSS

TD = Total dust

Key to abbreviations

If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.

Safety glasses with side shields.

Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.

Personal protection

Eyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:

nitrile, neopreneGloves :

Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Recommended monitoringprocedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.

= Threshold Limit ValueTLVTWA = Time Weighted Average

Hands : Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.

Fume=FIPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHAR = Respirable

OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

Ligroine TWA Notestablished

Notestablished

Notestablished

300 ppm Notestablished

STEL Notestablished

Notestablished

Notestablished

400 ppm Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________Tetrahydrofuran TWA 50 ppm S 200 ppm 50 ppm S 200 ppm Not

establishedSTEL 100 ppm S Not

established100 ppm S 250 ppm Not

established____________________________ ___________ ___________ ___________ ___________ ___________ ___________Ethanol TWA Not

established1000 ppm Not

established1000 ppm Not

establishedSTEL 1000 ppm Not

established1000 ppm Not

establishedNotestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________

STEL =

=

Short term Exposure limit values

Page: 4/8United States - Canada - Mexico

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GENERAL PURPOSE LACQUER THINNERProduct name

6.01Product code Date of issue VersionFPR5000 7 December 2010

>37.78°C (>100°F)

Liquid.

100% (v/v), 100% (w/w)

Not available.

Not available.

0.85

Not available.

7 kPa (52.5 mm Hg) [20°C]

Not available.

Not available.

Not available.

Boiling/condensation point

Melting/freezing point

73 (butyl acetate = 1)

Physical and chemical propertiesPhysical state

pH

Specific gravity

Vapor pressure

Vapor density

Volatility

Odor threshold

Evaporation rate

Odor

Color

:

:

:

:

:

:

:

:

:

:

:

:

Flash point : Open cup: -14.44°C (6°F)

Explosion limits : Lower: 5.1%

9 .

Partition coefficient: n-octanol/water

: Not available.

% Solid. (w/w) : Not available.

Density ( lbs / gal ) : 7.09

Stable under recommended storage and handling conditions (see section 7).

Reactive or incompatible with the following materials:,oxidizing materials,strongacids,strong alkalis

Under normal conditions of storage and use, hazardous polymerization will not occur.

Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.

Stability and reactivityStability

Conditions to avoid

Materials to avoid

Hazardous decompositionproducts

Hazardous polymerization

:

:

:

:

:

10 .

Toxicological information11 .

Methyl acetate LD50 Oral Rat 3.705 g/kg -LD50 Dermal Rabbit >5 g/kg -

Methanol LD50 Oral Rat 5600 mg/kg -LD50 Dermal Rabbit 15800 mg/kg -LC50 InhalationVapor

Rat 64000 ppm 4 hours

LC50 Inhalation Rat 145000 ppm 1 hoursToluene LD50 Oral Rat 636 mg/kg -

LD50 Dermal Rabbit 8.39 g/kg -LC50 Inhalation Rat 49 g/m3 4 hours

Ligroine LC50 Inhalation Rat 3400 ppm 4 hoursTetrahydrofuran LD50 Oral Rat 1650 mg/kg -

LC50 InhalationVapor

Rat 18190 ppm 4 hours

LC50 InhalationVapor

Rat 80975 ppm 1 hours

Ethanol LD50 Oral Rat 7 g/kg -LC50 Inhalation Rat 124700 mg/m3 4 hours

Product/ingredient name Result Species Dose ExposureAcute toxicity

Page: 5/8United States - Canada - Mexico

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GENERAL PURPOSE LACQUER THINNERProduct name

6.01Product code Date of issue VersionFPR5000 7 December 2010

Toxicological information11 .Chronic toxicity

Conclusion/Summary : Not available.

Carcinogenicity

Mutagenicity

Teratogenicity

Reproductive toxicity

Classification

Toluene A4 3 - - - -Tetrahydrofuran A3 - - - - -

Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Developmental effects : Contains material which may cause developmental abnormalities, based on animal data.

Fertility effects : Contains material which may impair female fertility, based on animal data.

Teratogenicity : Contains material which may cause birth defects, based on animal data.

Defatting irritant? : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ordermatitis.

Target organs : Contains material which causes damage to the following organs: liver, brain.Contains material which may cause damage to the following organs: blood, kidneys,mucous membranes, heart, gastrointestinal tract, upper respiratory tract, skin, eyes,central nervous system (CNS).

Ecological informationEnvironmental effects : No known significant effects or critical hazards.

12 .

Aquatic ecotoxicity

Methyl acetate Acute LC50 320000 to 348000 ug/LFresh water

Fish - Fathead minnow - Pimephalespromelas

96 hours

______________________ _________________________________ ________________________________ __________Methanol Acute LC50 >100000 ug/L Fresh water Fish - Fathead minnow - Pimephales

promelas96 hours

_________________________________ ________________________________ __________Acute LC50 3289 to 4395 mg/L Freshwater

Daphnia - Water flea - Daphnia magna 48 hours

_________________________________ ________________________________ __________Chronic NEL 320 mg/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours

______________________ _________________________________ ________________________________ __________Toluene Acute LC50 5800 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss96 hours

_________________________________ ________________________________ __________Acute EC50 6000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours_________________________________ ________________________________ __________Chronic NOEC 28000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________Tetrahydrofuran Acute LC50 2160000 to 2360000 ug/L

Fresh waterFish - Fathead minnow - Pimephalespromelas

96 hours

______________________ _________________________________ ________________________________ __________Ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout -

Oncorhynchus mykiss4 days

_________________________________ ________________________________ __________Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours_________________________________ ________________________________ __________Chronic NOEC <6.3 g/L Fresh water Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________

Product/ingredientname

SpeciesResult Exposure

Page: 6/8United States - Canada - Mexico

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GENERAL PURPOSE LACQUER THINNERProduct name

6.01Product code Date of issue VersionFPR5000 7 December 2010

The generation of waste should be avoided or minimized wherever possible. Significantquantities of waste product residues should not be disposed of via the foul sewer butprocessed in a suitable effluent treatment plant. Dispose of surplus and non-recyclableproducts via a licensed waste disposal contractor. Disposal of this product, solutionsand any by-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authority requirements.Waste packaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible. This material and its container must be disposed of in asafe way. Care should be taken when handling emptied containers that have not beencleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphereinside the container. Do not cut, weld or grind used containers unless they have beencleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contactwith soil, waterways, drains and sewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations.

:

13 .

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees. Section 6. Accidental release measures

Transport information14 .

Regulation UN number Proper shipping name Classes PG*

UN 1263 PAINT RELATED MATERIAL 3 II

Additional information

-

IMDG 1263 PAINT RELATED MATERIAL 3 -II

DOT -1263 3PAINT RELATED MATERIAL II

CERCLA: Hazardous substances.: Toluene: 1000 lbs. (454 kg); Methanol: 5000 lbs. (2270 kg);Tetrahydrofuran: 1000 lbs. (454 kg);

Reportable quantity RQ :

PG* : Packing group

Regulatory information

U.S. Federal regulations :

United States

15 .

CERCLA: Hazardous substances.: Toluene: 1000 lbs. (454 kg); Methanol: 5000 lbs. (2270 kg); Tetrahydrofuran: 1000lbs. (454 kg);

All components are listed or exempted.

All components are listed or exempted.

Not determined.

All components are listed or exempted.

Not determined.

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.United States inventory (TSCA 8b) :

Australia inventory (AICS)

Canada inventory ( DSL ) :

China inventory (IECSC) :

Japan inventory (ENCS) :

Korea inventory (KECI) :

New Zealand ( NZIoC ) :

Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material.

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: Ligroine; Toluene; Methanol; Tetrahydrofuran; Methyl acetate

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

Methyl acetate 79-20-9 Y N Y N NMethanol 67-56-1 Y Y Y N NToluene 108-88-3 Y Y Y N NLigroine 8032-32-4 Y N Y N NTetrahydrofuran 109-99-9 Y N Y Y N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

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GENERAL PURPOSE LACQUER THINNERProduct name

6.01Product code Date of issue VersionFPR5000 7 December 2010

Regulatory information15 .

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductiveharm.

WHMIS (Canada) Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-1B:Material causing immediate and serious toxic effects (Toxic). Class D-2A: Materialcausing other toxic effects (Very toxic). Class D-2B: Material causing other toxic effects(Toxic).

:

SARA 313

Canada

Mexico

3 3 0HealthFlammability Reactivity

Classification

California Prop. 65

: : :

CAS number Concentration

Additional environmental information is contained on the Environmental Data Sheet for this product, which canbe obtained from your PPG representative.

Supplier notification : Methanol 67-56-1 10 - 30Toluene 108-88-3 10 - 30

Product as-supplied : Y Y Y N N

Chemical name

Other informationHazardous Material Information System (U.S.A.)

3

03

National Fire Protection Association (U.S.A.)

Health InstabilityFlammability

Health Flammability Physical hazards

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.

Date of previous issue 11/23/2010.:

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implementedHMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version.

Organization that preparedthe MSDS

: EHS

:: :

: : :3 *

3

0( * ) - Chroniceffects

Page: 8/8United States - Canada - Mexico