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ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland
Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL
Environmental Efficiency
A2-1
70 Montrose Avenue, Hillington Park, Glasgow, G52 4LAT: 0800 328 1821 (or + 44 161 432 3286 from overseas)
E: [email protected] Exova Catalyst Ireland Contact: John Healey (07826 916 681)
Mill LaneGlenside Works
Sun Chemical Inks Ltd
Dublin 20Palmerstown
Stack Reference
Industrial Emissions Licence: P0241-01
Stack Emissions Testing Report Commissioned by
Installation Name & Address
Team Leader
Team Leader
TE1 TE2 TE3 TE4MM 10 1061
MCERTS Level 2
Stephen DickReport Approved by
MM 10 1061MCERTS Level 2
Signature of Report Approver
Version 1
23rd March 2017
Job Reference NumberCEK-2474
Dates of the Monitoring Campaign
Report Written byStephen Dick
25th March 2017Report Date
TE1 TE2 TE3 TE4
Version
CAT-RT (Version BQ)CEK-2474 Environmental Efficiency - Sun Chemical - A2-1 Report Q1 2017
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EPA Export 05-06-2017:03:17:03
TITLE PAGE
CONTENTS
Summary of Sampling Deviations
EXECUTIVE SUMMARY
Monitoring Objectives
Monitoring Results
Monitoring Dates & Times
Process Details
Monitoring & Analytical Methods
Sampling Location
Plant Photos / Sample Points
APPENDIX 1 - Monitoring Personnel & List of Equipment
APPENDIX 2 - Raw Data, Sampling Equations & Charts
Opinions and interpretations expressed herein are outside the scope of Exova Catalyst Ireland's ISO 17025 accreditation.
9
3
5
6
8
CONTENTS
4
2
7
This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst Ireland.
The testing performed fully meets the technical requirements in Irish EPA Guidance Note, AG2.
CAT-RT (Version BQ)Page 2 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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Overall Aim of the Monitoring Campaign
Special Requirements
Target Parameters
Exova Catalyst Ireland were commissioned by Environmental Efficiency to carry out stack emissions testing for Sun Chemical Inks Ltd on the A2-1 at Palmerstown.
The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values (ELVs) as specified in the Site's Permit.
There were no special requirements.
Total VOCs (as Carbon)
MONITORING OBJECTIVES
Executive Summary(Page 1 of 7)
Sun Chemical Inks Ltd, PalmerstownA2-1
23rd March 2017
CAT-RT (Version BQ)Page 3 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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EPA Export 05-06-2017:03:17:03
where MU = Measurement Uncertainty associated with the Result
Parameter
Total VOCs (as Carbon) ¹ - -Stack Gas TemperatureStack Gas Velocity
¹
- -NOTE: VOLUMETRIC FLOW RATE & VELOCITY DATA TAKEN FROM THE PRELIMINARY VELOCITY TRAVERSE.
¹ Reference Conditions (REF) are: 273K, 101.3kPa, without correction for water vapour content.1 ELV for Total VOCs (as Carbon) applies at mass flows > 500 g/hr.
10400-
Sun Chemical Inks Ltd, Palmerstown
23rd March 2017
+/-Units Result
Concentration
MULimit 1
+/-
m³/hr 4676m³/hr 230
Executive Summary
Mass Emission
MONITORING RESULTS
A2-1
UnitsResult LimitMU
67.51.58
0.208.17m/s9.38
4444
°C
(Page 2 of 7)
15.2
Volumetric Flow Rate (ACTUAL)
-mg/m³ 7.86150 g/hr
242Volumetric Flow Rate (REF)
CAT-RT (Version BQ)Page 4 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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EPA Export 05-06-2017:03:17:03
Parameter
R1 -R2 -R3 -R1
All results are expressed at the respective reference conditions.1 ELV for Total VOCs (as Carbon) applies at mass flows > 500 g/hr.
Result Limit 1
16.10 15015.59 15013.88 150
Date(s)Mass Emission
10:45 - 10:50
MONITORING DATE(S) & TIMES
mins
A2-123rd March 2017
Executive Summary
Sampling
(Page 3 of 7)
Units
Sun Chemical Inks Ltd, Palmerstown
Times
mg/m³ 23/03/2017
Velocity & Volumetric Flow Rate 23/03/2017
Units DurationConcentration Sampling
g/hrg/hr 12:05 - 12:34mg/m³
11:05 - 11:34Total VOCs (as Carbon)
303030
11:35 - 12:0471.5
23/03/201723/03/2017
61.769.3
g/hrmg/m³
Total VOCs (as Carbon)
Total VOCs (as Carbon)
CAT-RT (Version BQ)Page 5 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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Standard Operating Conditions
Value
Sun Chemical Inks Ltd, Palmerstown
Feedstock (if applicable)
Capacity (of 100%) and Tonnes / HourContinuous or Batch Process
N/A
Process Status
A2-123rd March 2017
Abatement SystemAbatement System Running Status
Plume Appearance
None
Parameter
(Page 4 of 7)Executive Summary
PROCESS DETAILS
None Visible
Extraction from Process
N/A
Batch Process
Liquid Inks Production
N/A
Fuel
CAT-RT (Version BQ)Page 6 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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EPA Export 05-06-2017:03:17:03
YesEN 12619:2013 YesCAT-TP-20Yes CAT
CAT 0.32 mg/m³Total VOCs (as Carbon)Yes 1.2 m/s
(with short name reference as appears in the table above)
Flame Ionisation Detection by Sick 3006 FIDVelocity & Vol. Flow Rate
ANALYSIS LABORATORIES
MCERTS17025
Testing
Executive Summary
Procedure TestingLabISO
Lab
(Page 5 of 7)
Testing ISOStandard
Monitoring
ParameterProcedure
AnalyticalTechnical
Sun Chemical Inks Ltd, Palmerstown
Analysis
Analysis17025
Analysis
LOD(Average)
AnalyticalTechnique
A2-1
Deviation
MONITORING & ANALYTICAL METHODS
23rd March 2017
EN 16911-1 (MID) CAT-TP-41
SUMMARY OF SAMPLING DEVIATIONS
Parameter Run
All All There are no deviations associated with the sampling employed.
Pitot Tube and Thermocouple
CAT-RT (Version BQ)Page 7 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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Duct Characteristics Location of Sampling Platform
Platform Details
Sampling Location / Platform Improvement Recommendations
cm
-
Permanent
Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)
-
Sufficient working area to manipulate probe and operate the measuring instruments
Type0.45
Parameter
There are no obstructions present which hamper insertion of sampling equipment
Yes
-
Executive Summary(Page 6 of 7)
Units
Vertical
Yes
Platform has chains / self closing gates at top of laddersYes
Safe Access Available
General Platform Information
Permanent / Temporary PlatformInside / Outside
Circular
Value
All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.
Value
Platform has vertical base boards (approx. 0.25m high)
Width
YesNo
SUITABILITY OF SAMPLING LOCATION
Outside
No
0-
m²m
Sample Port Size
m
0.16
Orientation of Duct
Irish EPA Technical Guidance Note AG1 / EN 15259 Platform Requirements
Port Depth
Yes
Area
Hole
Easy Access Available
Depth
Value
EN 15259 Homogeneity Test Requirements
Sampling Plane Validation Criteria (from EN 15259)
Where NM = Not Measured as no Isokinetic sampling was performed.
NM
Units --
-
NM
--
NM
-
-
-
--m/s
Maximum Angle of Swirl
-Lowest Gas Velocity
m/s-
7.70-
-
Required
-
Compliant-
Yes-NM NM
No Local Negative Flow
Mean Velocity-
-
-
All platforms should be designed in accordance with the requirements in EPA Guidance Note AG1 and EN 15259.
Pa
-
-
> 5 Pa Yes
0.00
-
Criteria in EN 15259
--
There is no requirement to perform a EN 15259 Homogeneity Test on this Stack.
51.7
Yes
-
Traverse 1
m/s-8.17
< 3 : 1Ratio of Above 1.11°
-
8.550.00
Highest Gas Velocity: 1 Yes
NM0.00
--
-NM0.00
-
Lowest Differential Pressure
CAT-RT (Version BQ)Page 8 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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EPA Export 05-06-2017:03:17:03
PLANT PHOTOS
(Page 7 of 7)
SAMPLE POINTS
Executive Summary
= combustion gases sample point
Line A
A1
CAT-RT (Version BQ)Page 9 of 18
Sun Chemical Inks LtdPalmerstownA2-1
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EPA Export 05-06-2017:03:17:03
APPENDIX 1 - Stack Emissions Monitoring Personnel, List of Equipment & Methods and Technical Procedures Used
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDICES
APPENDIX CONTENTS
CAT-RT (Version BQ)Page 10 of 18
Sun Chemical Inks LtdPalmerstownA2-1
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Bioaerosols Temperature Logger -Electronic Refrigerator -
StopwatchServomex 4900
-
-
-
Position
CAT 3.94-
-
CAT 21S.28
MCERTS Number
-
-
Gasmet DX4000
Horiba PG-250
MM 10 1061 TE1 TE2 TE3 TE4Team Leader James Jackson MCERTS Level 2 MM 15 1356 TE1 & TE4
Eco Physics CLD 822Mh
-
Miscellaneous Items
ABB AO2020-URAS26
CAT 8.4-
- 1m Heated Line (2)Heated Probe (2)
Equipment Type
Control Box DGM (2)
-
Stephen Dick MCERTS Level 2
Mass Flow Controller (2) CAT 6.12
Equipment I.D.
STACK EMISSIONS MONITORING PERSONNEL
APPENDIX 1
15m Heated Line (1)
CAT 17.4
-
Heated Probe (1)
--
-
--
Mass View (2)
CAT 12.72
-Stack Thermocouple (2)
Mass View (1) -
500g / 1Kg Check Weights CAT 17.4Last Impinger Arm -Callipers
- 20m Heated Line (1)
Tubes Kit Thermocouple -
20m Heated Line (2)
-
Stack Thermocouple (1)
Gasmet Sampling System-
Extractive Sampling
LIST OF EQUIPMENT
MCERTS Accreditation
5m Heated Line (1)
-
-
Umbilical (2) Servomex 5200MP
Bernath 3006 FID
-
-
CAT 14.53
Single Channel Heater Controller
-
JCT JCC P1 Cooler
CAT 13.24
Mass Flow Controller (1)
Stack Thermocouple (3)
Technical Endorsements
Team Leader
S-Pitot (2) -
Equipment Type
Easylogger EN-EL-12 Bit
CAT 20.8
Equipment Type
CAT 4.934Barometer
Digital Manometer (2)
-
S-Pitot (1)
L-Pitot-
Digital Temperature Meter
Heated Probe (3) -CAT 6.11 -
Site Balance
Ankersmid APP100
Equipment I.D.
1m Heated Line (3)
Control Box DGM (1) CAT 3.94
Oven Box (1)
-Laboratory BalanceTape Measure CAT 16.3
-Oven Box (2)
Equipment I.D.Digital Manometer (1)Horiba PG-350E
Instrumental Analysers
CAT 23.22
Umbilical (1)Box Thermocouples (2)Box Thermocouples (1)
CAT 11.4Easylogger EN-EL-12 Bit -
Dual Channel Heater Controller -
1m Heated Line (1)
Name
METHODS & TECHNICAL PROCEDURES USED
Parameter
Total VOCs (as Carbon)EN 16911-1 (MID) CAT-TP-41Velocity & Vol. Flow Rate
Technical ProcedureStandard
CAT-TP-20EN 12619:2013
CAT-RT (Version BQ)Page 11 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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EPA Export 05-06-2017:03:17:03
General Stack Details
Stack Gas Composition & Molecular Weights
CO₂ (Estimated)
O₂ (Estimated)
Moisture (H₂O) (Estimated)
NOTE: Moisture has been estimated as no moisture test was performed on the date(s) of testing
Where: p = M / 22.41
pi = r x p
Calculation of Stack Gas Densities
Stack Diameter / Depth, DmStack Width, W
Stack Details (from Traverse)
APPENDIX 2
Stack Area, A
-
Volume
kPakPa
0.84
Value
0.45
99.6
Average Stack Gas Temperature, Ta
-0.030
°C
Average Stack Static Pressure, Pstatic
-
58.2
Molar Conc
m²
PRELIMINARY STACK SURVEY: CALCULATIONS
MassComponent
Units
Pa
Fraction Density
Dry
0.01206
20.80 32.00
Conc
0.16
Average Pitot Tube Calibration Coefficient, Cp
ppm kg/m³
Average Stack Gas Pressure
Conc Conc
MWet
r% v/v
1.50 18.02
kg/m³
9.4
Average Barometric Pressure, Pb
m
0.7914 28.01
1.96350.06
79.14 0.9891377.95
0.0006
p pi
--
0.20800.06
N₂1.4277 0.29696-
0.00118
0.0150
20.49
% v/v
-
0.8037-1.2498
44.01
Calculation of Stack Gas Densities
Where: P STD = sum of component concentrations, kg/m³ (not including water vapour)
P STW = sum of all wet concentrations / 100 x density, kg/m³ (including water vapour)
P Actual = P STD x (TSTP / (PSTP)) x ((Pstatic + Pb) / Ta)
P ActualW (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)
Calculation of Stack Gas Volumetric Flowrate, Q
Gas Volumetric Flowrate (from Traverse)
kg/m³
m³/hrGas Volumetric Flowrate (Actual)
Units
1.50
kg/m³
m³/hr
Total Pressure
Average Wet Density (Actual), P ActualW
Determinand
Actual
kg/m³
101.3
Result
1.287
9.499.6
Dry Density (STP), P STD
4444
Result
°C
m³/hr
REF ¹
1.216
Dry Density (Actual), P Actual
m³/hr
Temperature
Units
Gas Volumetric Flowrate (STP, Wet)
MoisturekPa
Gas Volumetric Flowrate (STP, Dry)
Units
1.50
kg/m³ 1.280
Duct gas flow conditions
44444676
1.223
Wet Density (STP), P STW
Gas Volumetric Flowrate REF ¹
%
-0.0
4377
CAT-RT (Version BQ)Page 12 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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EPA Export 05-06-2017:03:17:03
Parameter Parameter
Date of Survey Initial Pitot Leak CheckTime of Survey Final Pitot Leak CheckAtmospheric Pressure Orientation of DuctAverage Stack Static Pressure Pitot Tube, Cp
Result of Pitot Stagnation Test Number of Lines AvailableAre Water Droplets Present? Number of Lines UsedDevice Used
1.217
1
23/03/2017
Value
-
Units
0.84
S-Type Pitot with KIMO MP 200 (500Pa)
99.6Pass
Mean
0.11
9.43
9.4
8.38
7.70
Wet Density
Pa
-
-
TraversePoint --° -°C
-30.0
Depth
-
Velocity
Units
APPENDIX 2
Pass
-
-
(1 of 1)
1
Value
∆P --
-30 -
--10:45 - 10:50
Sampling Line A
PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID)
-
Vertical
Pass
m/sPa
1.216
mSTATIC (Units: Pa)
-
4
-1.216
-
51.72
0.42
Tempkg/m³
8.55
8.170.031
1.2169.40.34
63.7
-56.3 9.3
-
58.2 -
-61.2
-Swirl
No
kPa
-
-
-
- -
1.2168.04
9.4
--
---
-
- -
-
-
-
-
--
-
--
-
- --
-- -
--
-
--
-
-
-
- - -- - -
-
- -
-----
-
- -
-
-
-
-
-
---
---
-
--- -
-
---
--
----
CAT-RT (Version BQ)Page 13 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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u(Tc) 1.441
PRELIMINARY STACK SURVEY: VELOCITY TRAVERSE TO EN 16911-1 (MID) - MEASUREMENT UNCERTAINTY(1 of 1)
Standard uncertainty associated with the stack temperature
-Pa
m/s
-
u(φCO₂,d) 0.002
Standard uncertainty associated with the local velocities
u(Cf)
u(cal) 0.353
%
- Static PressureStandard uncertainty associated with the density in the duct
u(φH₂O) 0.077u(φO₂,w) 0.627
APPENDIX 2
1.216
Standard uncertainty associated with the mean velocity
20.488- 0.059
u(φO₂,d) 0.637
u(φCO₂,w) 0.002
Standard uncertainty associated with the mean velocity (95% Confidence), relative
- φCO₂,w- Oxygen, dry- Carbon Dioxide, dry
u(fit) 0.043
Standard Uncertainty associated with the mean local dynamic pressures-
- Resolution- Calibration
u(M) 0.00003
0.128u(v) 0.104
Uc(v)
- Drift- Lack of Fit
- Water Vapour- Oxygen, wet- Carbon Dioxide, wet
-
Standard uncertainty associated with the mean velocity (95% Confidence)
- Overall corrections to dynamic measurementsStandard uncertainty associated with the molar mass of the gas- φO₂,w
u(vi)
Ku(pc) 175.696 Pa
u(patm) 175.692u(pstat) 1.216
u(ρ) 0.00657
Standard Uncertainty on the coefficient of the Pitot Tube
m/sUc,rel(v) 2.50
0.205
Performance characteristics (Uncertainty Components) UnitsValueUncertaintyu(k) 0.005
u(∆pi) Pau(res) 0.00087
0.480
Standard uncertainty associated with the absolute pressure in the duct- Atmospheric Pressure
u(drift) 0.083
- 15236- 123.4
Uc,rel(qV,w) 5.17
%241.9 m³/hr
- u²(qV,w)0.00070
- u²(a)/a²- u²(qV,w)/q²V,w
-
Standard uncertainty associated with the mean velocity (95% Confidence), relative
0.00053-
Uc(qV,w)
%
Uc,rel(v) 2.50
- u(qV,w)Standard uncertainty associated with the volume flow rate (95% Confidence), relative
Standard uncertainty associated with the volume flow rate (95% Confidence)
CAT-RT (Version BQ)Page 14 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
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EPA Export 05-06-2017:03:17:03
Sample Runs
- - - -
- - - -
- - - -
- - - -
- - - -
General Sampling Information
Parameter Run 2
Value
Heated Head Filter Used
Span Gas Type Propane In Synthetic Air (5 Grade)
7.9 7.7 7.9
Parameter
Yes
1.6 1.6
Heated Line Temperature
CYC 1.0156a
mg/m³
1.6
15.2
CAT-TP-20
180°C
Span Gas Expiry Date
16.1
Filtration Type / Size 0.1µm Glass Fibre
Run 3Run 1
Standard
23/01/2020
Uncertainty
69.3 61.7
15.6
A2-1
TOTAL VOCs (as CARBON): RESULTS SUMMARY
67.5
1.6
APPENDIX 2
Mass Emission
Concentration
g/hr 71.5
Units
Probe Material Titanium
Uncertainty ±mg/m³
Mean
13.9
Span Gas Reference Number
Sun Chemical Inks Ltd, Palmerstown
±g/hr 8.0
EN 12619:2013Technical Procedure
FORMAT: Number Used / Number Required
FORMAT: Number Used / Number Required
Reference Conditions
Reference Conditions are: 273K, 101.3kPa, without correction for water vapour content.
A1
N/ASpan Gas Set Point (ppm) 80.40
Span Gas Start Pressure (bar) 35Gas Cylinder Concentration (ppm)
Number of Sampling Lines Used
Sample Point I.D.'s
Span Gas Uncertainty (%)
Span Gas Expiry Date
80.4
23/01/2020
Number of Sampling Points Used 1 / 1
Synthetic Air (5 Grade)Zero Gas Type
1 / 1
CAT-RT (Version BQ)Page 15 of 18
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Graphical Trend of Data
APPENDIX 2
TOTAL VOCs (as CARBON): DATA TREND
COVER ME WITH CHART/S
0.0
20.0
40.0
60.0
80.0
100.0
120.0
140.0
11:0
5
11:0
6
11:0
7
11:0
8
11:0
9
11:1
0
11:1
1
11:1
2
11:1
3
11:1
4
11:1
5
11:1
6
11:1
7
11:1
8
11:1
9
11:2
0
11:2
1
11:2
2
11:2
3
11:2
4
11:2
5
11:2
6
11:2
7
11:2
8
11:2
9
11:3
0
11:3
1
11:3
2
11:3
3
11:3
4
Conc
entr
atio
n (m
g/m
³)
Total VOCs At Reference Conditions
- Run 1
100.0
120.0
140.0
Conc
entr
atio
n (m
g/m
³)
Total VOCs At Reference Conditions
- Run 2
0.0
20.0
40.0
60.0
80.0
11:3
5
11:3
6
11:3
7
11:3
8
11:3
9
11:4
0
11:4
1
11:4
2
11:4
3
11:4
4
11:4
5
11:4
6
11:4
7
11:4
8
11:4
9
11:5
0
11:5
1
11:5
2
11:5
3
11:5
4
11:5
5
11:5
6
11:5
7
11:5
8
11:5
9
12:0
0
12:0
1
12:0
2
12:0
3
12:0
4
Conc
entr
atio
n (m
g/m
³)
0.0
20.0
40.0
60.0
80.0
100.0
120.0
140.0
12:0
5
12:0
6
12:0
7
12:0
8
12:0
9
12:1
0
12:1
1
12:1
2
12:1
3
12:1
4
12:1
5
12:1
6
12:1
7
12:1
8
12:1
9
12:2
0
12:2
1
12:2
2
12:2
3
12:2
4
12:2
5
12:2
6
12:2
7
12:2
8
12:2
9
12:3
0
12:3
1
12:3
2
12:3
3
12:3
4
Conc
entr
atio
n (m
g/m
³)
Total VOCs At Reference Conditions
- Run 3
CAT-RT (Version BQ)Page 16 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
For
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ectio
n pur
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.
Conse
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EPA Export 05-06-2017:03:17:03
Sampling Details
Quality Assurance
Zero Drift 0 0 0
Span Drift 0 0 0
- Yes
-
Zero Down Sampling Line (Pre)
-0.80ppm4.02
Units
ppm
Sampling Times -
ppm
11:35 - 12:04
79.00
CAL
1
Run 2
11:05 - 11:34
0.40
80.4 80.4100 100Instrument Range ppm 100
0.40
YesAllowable Zero Drift ± ppm
Run 1
ppm79.00Span Down Sampling Line (Post)
Run 3
APPENDIX 2
23/03/2017
4.02
0.40
4.02
80.4
Span Drift
Zero Down Sampling Line (Post) ppm
ppm 0.00
Span Down Sampling Line (Pre)
Units
-0.40
0.00
Zero Drift Acceptable
Run 2
79.0079.00ppm 79.00
Span Gas Value
Zero Drift
-0.40
4.02-0.80
4.02-
Run 3Units
°C
Test Conditions
Run Ambient Temperature Range 13 - 10.5 13 - 10.5
Yes
Span Drift AcceptableAllowable Span Drift ± ppm
Run 3
0.00
CAL
1
4.02Yes
13 - 10.5
YesYes
Run 1 Run 2
Run 1
TOTAL VOCs (as CARBON): SAMPLING DETAILS & QUALITY ASSURANCE
-0.40
79.00
23/03/2017Sampling Dates
Units Run 1 Run 2
Parameter
12:05 - 12:34
-0.80
23/03/2017
Run 3
Method Deviations
1 2 3
- - -
- - -
- - -
- - -
- - -
Nature of Deviation
(x = deviation applies to the associated run)
°C
Run Number
There are no deviations associated with the sampling employed.
Run Ambient Temperature Range 13 - 10.5 13 - 10.5 13 - 10.5
CAT-RT (Version BQ)Page 17 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
For
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ectio
n pur
pose
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Conse
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EPA Export 05-06-2017:03:17:03
Combined interference 0.45
RUN 1 RUN 2 RUN 3 UnitsStandard deviation of repeatability at zero
Range Used [A]
mg/m³Lower of [A] or [B]
2.00 2.00
45 45
15.0 15.0 15.0 mg/m³Cal gas conc. 129.1 129.1
0.45
use rep at span use rep at span use rep at span
Lack of fit 0.01
0.45
mg/m³Cal gas conc. 80.4 80.4 80.4 ppm
0.01
Performance characteristic
Performance characteristics
-1.01 -1.01 % full scaleSpan drift 0.00 0.00
1.60 1.60 % of full scale
45
mg/m³
ppm to mg/m³MCERTS Range [B] 15.0
% range0.50 0.50 0.50 % full scale/10V
Losses in the line (leak) 1.74 1.74 1.74 % of valueUncertainty of calibration gas 2.00 2.00 2.00 % of value
30
0.30 0.30
129.1 mg/m³
% of value/kPa
1.61
2.00
15.0 15.0
Measured concentrationTGN M2 Allowable MULimit value
% full scale
Conversion 1.61 1.61
Dependence on voltage
Standard deviation of repeatability at span level
0.00 0.00 % full scaleDeviation from linearity 0.08 0.08
15.0 %16.34 15.82 14.09 mg/m³ (STP, dry)
100.0
150.0 mg/m³ (REF)15.0 15.0
150.0
RUN 1 RUN 2 RUN 3 UnitsResponse time
Performance characteristics RUN 1 Units
TOTAL VOCs (as CARBON): MEASUREMENT UNCERTAINTY CALCULATIONS
RUN 3
160.6 160.6
Repeatability at zero
APPENDIX 2
RUN 2
1.40
mg/m³
150.0
Repeatability at span level 0.00
-
ppm
0.301.40 1.40 % full scale/10KAmbient temperature dependence
Range Used 100.0 100.0160.6
secondsNumber of readings in measurement
Atmospheric pressure dependence
30
0.00 0.00 0.000.01 mg/m³
0.08 % of valueZero drift -1.01
30
0.00 % full scaleVolume or pressure flow dependence 1.60
k =
mg/m³
N/A
Expanded uncertainty (with O₂) - at 95% Confidence N/A N/A N/A % at ELV
Overall Allowable uncertainty (with O₂) - at 95% Confidence N/AN/A N/A
mg/m³
Expanded uncertainty (with O₂) - at 95% Confidence
Result 16.34 15.82 14.09 mg/m³Combined uncertainty 0.82 0.82
RUN 1 RUN 2
mg/m³
mg/m³Losses in the line (leak) 0.16
0.20
RUN 3 Units
Dependence on voltage 0.06
0.18 0.16
Atmospheric pressure dependence 0.01 0.01 0.01 mg/m³
Lack of fit 0.01 0.01
0.00 mg/m³
N/A N/A % at ELVResult of Compliance with Uncertainty Requirement in M2
Result of Compliance with Uncertainty Requirement in M2 COMPLIANT COMPLIANT
Requirement for SRM is that Uncertainty should be <15% of the value at the ELV, on a dry gas basis, or if O₂ correction is applied less than 15% + the uncertainty associated with the O₂ correction (using sqrt of sum squares to add uncertainty components). Ref EA TGN M2.
COMPLIANT -
N/A N/A N/A
-
RUN 2 RUN 3 Units% of Value
RUN 1
0.06 0.06
RUN 1 RUN 2 RUN 3 Units
1.61 1.60 mg/m³
Uncertainty corrected to std conds. (O₂) 1.62 1.61 1.60 mg/m³ (REF)
Expanded uncertainty (no O₂) - at 95% Confidence 9.89 10.19 11.33 % of Value
0.01Drift -0.75 -0.75 -0.75Volume or pressure flow dependence 0.00 0.00
Measurement uncertainty
0.16 0.14 mg/m³Uncertainty of calibration gas 0.19
Expanded uncertainty (no O₂) - at 95% Confidence 1.08 1.07 1.06 % at ELV
Overall Allowable uncertainty (no O₂) - at 95% Confidence 15.0 15.0 15.0
mg/m³Combined interference (from MCERTS Certificate) 0.04 0.04 0.04
0.20 0.20
0.81 mg/m³
% at ELV
Ambient temperature dependence
Expanded uncertainty 1.96 1.62
CAT-RT (Version BQ)Page 18 of 18
Sun Chemical Inks LtdPalmerstownA2-1
Job Number: CEK-2474, Version 1Sample Date/s: 23rd March 2017
Industrial Emissions Licence: P0241-01
For
insp
ectio
n pur
pose
s only
.
Conse
nt of
copy
right
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r req
uired
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se.
EPA Export 05-06-2017:03:17:03